WO2019093765A2 - Multifunctional supported non-platinum catalyst for vehicle fuel cell and preparation method therefor - Google Patents

Abstract

Disclosed are a ternary multifunctional supported non-platinum catalyst having excellent oxygen evolution reaction (OER) activity and a preparation method therefor. A multifunctional supported non-platinum catalyst according to the present invention comprises: a support; and a ternary non-platinum particle supported on the support, wherein the ternary non-platinum particle includes iridium (Ir), ruthenium (Ru), and yttrium (Y).

Description

Multifunctional non-platinum supported catalyst for fuel cell for automobile and method for manufacturing the same

TECHNICAL FIELD The present invention relates to a multifunctional non-platinum supported catalyst, and more particularly to a ternary multifunctional non-platinum supported catalyst and a method for producing the same.

Fuel cells that convert the chemical energy generated by the oxidation of fuel into electrical energy are attracting attention as a next-generation energy source. Particularly, in the field of automobiles, researches for commercialization are being actively carried out because of advantages such as reduction of fuel consumption, emission gas reduction, and environmentally friendly image.

The fuel cell basically includes an anode, an oxygen cathode, and an electrolyte membrane disposed between the two electrodes, and this structure is referred to as a membrane / electrode assembly.

Automotive fuel cells must have high catalytic reactivity and ion permeability to obtain the desired amount of energy. In addition to electrolytes, electrode catalysts are an important determinant of total activity. As the electrode catalyst, platinum supported on a support is most widely used. Platinum is a catalyst capable of promoting oxidation of fuel (hydrogen or alcohol) and reduction of oxygen up to 100 ° C at room temperature.

However, platinum is expensive and reserves are limited. It is important to reduce the amount of platinum used or maximize the activity per unit weight. Further, in the case of the start / stop cycle of the fuel cell, when the fuel, which is the fuel, is not supplied smoothly to the fuel electrode, there is a problem that the durability is insufficient.

Therefore, in order to solve such a problem, it is necessary to study a multifunctional non-platinum supported catalyst which can replace platinum and commercialize it.

The background art related to the present invention is Korean Patent Laid-Open Publication No. 10-2017-0088137 (published on August 1, 2017), which discloses a multifunctional non-platinum supported catalyst and a production method thereof.

An object of the present invention is to provide a multifunctional non-platinum supported catalyst having an excellent oxygen generating reaction (OER) and a high hydrogen oxidation activity.

Another object of the present invention is to provide a process for producing the multifunctional non-platinum supported catalyst.

In order to accomplish the above object, the multifunctional non-platinum supported catalyst according to the present invention comprises a support; And ternary non-platinum particles supported on the support, wherein the ternary non-platinum particles include iridium (Ir), ruthenium (Ru), and yttrium (Y).

300 to 500 parts by weight of ruthenium (Ru) and 10 to 300 parts by weight of yttrium (Y) may be added to 100 parts by weight of the iridium (Ir).

The multifunctional non-platinum supported catalyst may include 5 to 50 parts by weight of the ternary non-platinum particles per 100 parts by weight of the carrier.

The support may be a carbon-based support containing at least one of activated carbon, graphene, graphite, mesoporous carbon and carbon nanotubes, or may be a carbon-based support containing at least one of titanium (Ti), aluminum (Al) , Niobium (Nb), tantalum (Ta), antimony (Sb), and indium (In).

According to another aspect of the present invention, there is provided a multifunctional non-platinum supported catalyst comprising a support; (Ir), ruthenium (Ru), scandium (Sc), lanthanum (La), cerium (Ce), and ternary platinum particles supported on the support. , Samarium (Sm), europium (Eu) or gadolinium (Gd).

In order to accomplish the above object, the present invention provides a process for preparing a multifunctional non-platinum supported catalyst comprising the steps of: (a) preparing a first mixture by mixing a carrier, an organic solvent and distilled water; (b) adding an iridium (Ir) precursor, a ruthenium (Ru) precursor and a yttrium (Y) precursor to the first mixture to form a second mixture; (c) irradiating the second mixture with an electron beam to reduce it; And (d) drying the third mixture irradiated with the electron beam.

After the step (d), (e) post-treating the dried third mixture in a hydrogen gas atmosphere.

In step (b), 300 to 500 parts by weight of the ruthenium (Ru) precursor and 10 to 300 parts by weight of the yttrium (Y) precursor may be added to 100 parts by weight of the iridium (Ir) precursor.

The iridium (Ir) precursor, the ruthenium (Ru) precursor and the yttrium (Y) precursor may be added in an amount of 5 to 50 parts by weight based on 100 parts by weight of the carrier.

The support may be a carbon-based support containing at least one of activated carbon, graphene, graphite, mesoporous carbon and carbon nanotubes, or may be a carbon-based support containing at least one of titanium (Ti), aluminum (Al) , Niobium (Nb), tantalum (Ta), antimony (Sb), and indium (In).

Between steps (a) and (b), ultrasound may be applied to the first mixture for 5 to 60 minutes to disperse the carrier.

In the step (c), an electron beam of 0.1 to 1 MeV may be irradiated for 10 to 60 minutes.

In the step (e), the post-treatment may be performed at 200 to 400 ° C for 30 minutes to 120 minutes.

The post-treatment may be performed in an atmosphere of an inert gas: hydrogen gas in a mixing ratio of 3: 1 to 5: 1.

According to another aspect of the present invention, there is provided a process for preparing a multifunctional non-platinum supported catalyst, comprising: (a) preparing a first mixture by mixing a carrier, an organic solvent, and distilled water; (Ir) precursor, a ruthenium (Ru) precursor, and a scandium (Sc) precursor, a lanthanum (La) precursor, a cerium (Ce) precursor, a samarium (Sm) precursor, a europium (Eu) precursor, Preparing a second mixture by adding one of a precursor or a gadolinium (Gd) precursor; (c) irradiating the second mixture with an electron beam to reduce it; And (d) drying the third mixture irradiated with the electron beam.

The non-platinum supported catalyst for fuel cells of the present invention includes iridium (Ir), ruthenium (Ru), and yttrium (Y) which are ternary non-platinum particles. Therefore, it is possible to show an oxygen evolution reaction (OER) superior to the conventional commercial non-platinum catalyst and platinum catalyst.

In addition, the non-platinum supported catalyst of the present invention has versatility to exhibit high activity for hydrogen oxidation reaction.

The multifunctional non-platinum supported catalyst of the present invention may contain one or more of scandium (Sc), lanthanum (La), cerium (Ce), samarium (Sm), europium (Eu), or gadolinium Including species. Therefore, it is possible to exhibit excellent oxygen generation reaction as compared with the existing commercialized non-platinum catalyst and platinum catalyst.

The method for producing the multifunctional non-platinum supported catalyst of the present invention uses an electron beam reduction method. Therefore, there is an advantage in that it is eco-friendly and simpler than the conventional gas phase reduction or solution reduction method.

1 is a flowchart showing a method for producing a multifunctional non-platinum supported catalyst according to the present invention.

Fig. 2 is a TEM photograph (a) of the dispersed metal particles of Example 1 according to the present invention and a TEM photograph (b) of observing the dispersed metal particles of Comparative Example 1. Fig.

FIG. 3 shows the results of comparison of the oxygen reduction (ORR) activities of Examples 1 to 5 and Comparative Examples 1 to 3 through a half cell.

FIG. 4 shows the hydrogen oxidation reaction (HOR) activity of Example 1, Example 2, Example 5, and Comparative Example 1 through a half cell.

5 is a result of an optoelectronic spectroscopy (XPS) test of Example 5 according to the present invention.

BRIEF DESCRIPTION OF THE DRAWINGS The advantages and features of the present invention and the manner of achieving them will become apparent with reference to the embodiments described in detail below with reference to the accompanying drawings. The present invention may, however, be embodied in many different forms and should not be construed as being limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the invention to those skilled in the art. Is provided to fully convey the scope of the invention to those skilled in the art, and the invention is only defined by the scope of the claims. Like reference numerals refer to like elements throughout the specification.

Hereinafter, a multifunctional non-platinum supported catalyst according to a preferred embodiment of the present invention and a method for producing the same will be described in detail with reference to the accompanying drawings.

The multifunctional non-platinum supported catalyst according to the present invention is an oxygen generating reaction (OER) catalyst. The catalyst is a multifunctional catalyst that is active in the hydrogen oxidation reaction while being a catalyst that decomposes water to generate oxygen. When the oxygen generating reaction catalyst exists in the fuel cell electrode, the catalyst carrier first decomposes the water before the catalyst is corroded due to the high potential atmosphere at the start / stop of the fuel cell. Therefore, the oxygen generating reaction catalyst can prevent the catalyst carrier from being corroded and prevent the catalyst activity from being lowered.

The multifunctional non-platinum supported catalyst according to the present invention comprises a support and ternary non-platinum particles.

The carrier is a carbon-based carrier containing at least one of activated carbon, graphene, graphite, mesoporous carbon and carbon nanotubes. Alternatively, the support may be a metal oxide fume containing at least one metal selected from the group consisting of titanium (Ti), aluminum (Al), tin (Sn), niobium (Nb), tantalum (Ta), antimony (Sb) It is delay. The mesoporous carbon refers to a porous carbon having mesopores. The mesopores may have an average diameter of 5 to 10 nm. The mesoporous carbon has a large specific surface area. When mesoporous carbon is used as the support, it is possible to support ternary non-platinum particles having better dispersibility than other support materials.

The ternary non-platinum particles are dispersed in the carrier. The ternary non-platinum particles include iridium (Ir), ruthenium (Ru), and yttrium (Y). The iridium (Ir), ruthenium (Ru), and yttrium (Y) are excellent in durability among noble platinum noble metals. By appropriately mixing them, the oxygen generating reaction (OER) of the catalyst can be increased.

The ternary non-platinum particles preferably include 300 to 500 parts by weight of ruthenium (Ru) and 10 to 300 parts by weight of yttrium (Y), based on 100 parts by weight of iridium (Ir). When the content of ruthenium (Ru) and yttrium (Y) is out of this range, The manufacturing cost is increased without improving the durability and oxygen generating reaction (OER) through the structural changes of the catalyst particles.

The multifunctional non-platinum supported catalyst may include 5 to 50 parts by weight of the ternary non-platinum particles per 100 parts by weight of the carrier. When this range is satisfied, non-platinum particles can be stably dispersed in the support. In addition, it has an effect of increasing the durability of the catalyst and the oxygen generating reaction (OER). On the other hand, when the temperature is outside this range, there is a problem that the catalytic activity is insufficient or the dispersity is lowered, resulting in deterioration of catalytic activity. Further, the non-platinum particles may be unstably supported on the support. Accordingly, there is a problem that a multi-phase is formed, which causes catalyst activity and durability deterioration.

1 is a flowchart showing a method for producing a multifunctional non-platinum supported catalyst according to the present invention. Referring to FIG. 1, a method for preparing a multifunctional non-platinum supported catalyst according to the present invention includes a first mixture preparation step (S110), a second mixture preparation step (S120), an electron beam irradiation step (S130), and a drying step (S140) .

The first mixture preparation step (S110)

First, a first mixture is prepared by mixing a carrier, an organic solvent, and distilled water.

The carrier is a carbon-based carrier containing at least one of activated carbon, graphene, graphite, mesoporous carbon and carbon nanotubes. Alternatively, the support may be a metal oxide fume containing at least one metal selected from the group consisting of titanium (Ti), aluminum (Al), tin (Sn), niobium (Nb), tantalum (Ta), antimony (Sb) It is delay.

The organic solvent may be at least one selected from the group consisting of ethylene glycol, 1,2-propylene glycol, 1,3-butanediol, 1,4-butanediol, neopentyl glycol, diethylene glycol, Diol and trimethylol propane; alcoholic solvents such as methanol, ethanol, isopropyl alcohol (IPA) and butanol; and mixtures thereof, but the present invention is not limited thereto. The organic solvent may serve not only to disperse the carrier but also to serve as a reducing agent. The organic solvent is preferably, for example, an ethylene glycol and an alcohol.

The carrier, organic solvent and distilled water are mixed and stirred. Therefore, the first mixture in which the carrier is uniformly dispersed can be produced.

The method may further include dispersing the carrier by irradiating the first mixture with ultrasonic waves for 5 to 60 minutes. The first mixture is stirred and dispersed using an ultrasound sonicator ultrasonic wave. Therefore, the support is uniformly dispersed in the first mixture. And then the metal precursor is uniformly supported to improve the activity and durability of the catalyst.

The second mixture preparation step (S120)

Next, an iridium (Ir) precursor, a ruthenium (Ru) precursor, and a yttrium (Y) precursor are added to the first mixture to prepare a second mixture. The iridium (Ir) precursor may be selected from, for example, iridium nitrate, iridium chloride, iridium sulfate, iridium acetate, iridium acetylacetonate, iridium cyanate, iridium isopropyl oxide, iridium butoxide, and H ₂ IrCl ₆ .6H ₂ O ≪ / RTI > The ruthenium (Ru) precursor may be, for example, a chloride-based compound of ruthenium, a sulfide-based compound, or the like. The yttrium (Y) precursor may be, for example, a chloride-based compound of yttrium, a nitride-based compound, an acetylacetonate-based compound, or the like.

300-500 parts by weight of the ruthenium (Ru) precursor and 10-300 parts by weight of the yttrium (Y) precursor may be added to 100 parts by weight of the iridium (Ir) precursor to prepare a second mixture. When the content of the ruthenium (Ru) precursor and the yttrium (Y) precursor is out of this range, only the manufacturing cost increases without the durability and the effect of the oxygen generating reaction (OER).

The content of the iridium (Ir) precursor, the ruthenium (Ru) precursor and the yttrium (Y) precursor may be 5 to 50 parts by weight based on 100 parts by weight of the carrier. When this range is satisfied, non-platinum particles can be stably carried on the carrier. In addition, it has an effect of increasing the durability of the catalyst and the oxygen generating reaction (OER). On the other hand, if it is outside this range, there is a problem that the catalytic activity is insufficient or the dispersity is lowered, resulting in deterioration of the catalytic activity. Further, the non-platinum particles may be unstably supported on the support. As a result, a multi-phase can be formed, which leads to a problem that catalyst activity and durability are lowered.

Subsequently, an alkaline solution is added to the second mixture to base it. Therefore, the pH of the second mixture is adjusted to 9 to 11, and the slurry state is prepared. In addition, as the amount reduced in the reducing process is reduced, the amount of the supported catalyst may decrease, or the supported catalysts may be aggregated with each other.

The electron beam irradiation step (S130)

Next, an electron beam is irradiated to the second mixture to reduce the precursors. Thus, metal precursors are formed into particles.

The electron beam is a projected bundle of electrons. The electron beam can improve the activity and durability of the catalyst by preventing the formation of the metal oxide catalyst compared to the conventional solution reduction method or the gas phase reduction method. This effect can be confirmed by the XPS result in FIG. Figure 5 is data demonstrating that the catalyst is in a metal state.

The electron beam is preferably irradiated with an electron beam of 0.1 to 1 MeV for 10 to 60 minutes. When the irradiation amount of the electron beam is less than 0.1 MeV, reduction of the metal precursor may be insufficient. On the other hand, if it exceeds 1 MeV, the efficiency and economical efficiency may be lowered.

In the drying step (S140)

Then, the third mixture irradiated with the electron beam is dried.

For example, the third mixture is distilled under reduced pressure at room temperature. It is then washed with distilled water and dried. The drying can be carried out at room temperature for 1 to 24 hours, but is not limited thereto.

Post-processing step

The method may further include post-treating the dried third mixture in a hydrogen gas atmosphere.

 The purpose of the post treatment is to improve the activity and durability of the catalyst. For this purpose, after surface treatment and electron beam irradiation, post treatment is performed to metallize a trace amount of metal oxide.

The post-treatment is preferably performed by heat-treating at 200 to 400 ° C for 30 minutes to 120 minutes. If the post-treatment temperature is lower than 200 ° C, the post-treatment temperature may be low and the activity of the non-platinum catalyst may be lowered, so that the effect of the post-treatment may be insufficient. When the temperature is higher than 400 ° C, the particles become more crystallized without increasing the durability as the post-treatment temperature becomes higher, and the activity of the stocking can be lowered.

Also, it is preferable that the post-treatment is performed in an atmosphere having an inert gas: hydrogen gas mixing ratio of 3: 1 to 5: 1. If the mixing ratio of the gas is out of this range, the cost of the manufacturing process can be increased without increasing the activity and durability of the catalyst.

The inert gas may include at least one of argon, helium, neon, xenon, and nitrogen.

The multifunctional non-platinum supported catalyst of the present invention for achieving another object is a catalyst containing at least one of scandium (Sc), lanthanum (La), cerium (Ce), samarium (Sm), europium (Eu) (Gd).

In this case, 300 to 500 parts by weight of ruthenium (Ru), 100 to 500 parts by weight of scandium (La), cerium (Ce), samarium (Sm) And 10 to 300 parts by weight of the europium (Eu) or gadolinium (Gd).

Platinum supported catalyst comprising one of scandium (Sc), lanthanum (La), cerium (Ce), samarium (Sm), europium (Eu) or gadolinium (Gd) in place of yttrium The preparation method is a method of preparing a precursor of a scandium (Sc) precursor, a lanthanum (La) precursor, a cerium (Ce) precursor, a samarium (Sm) precursor, a europium (Eu) precursor or a gadolinium (Gd) precursor instead of the yttrium To prepare a second mixture.

Thus, a method for preparing a multifunctional non-platinum supported catalyst comprises the steps of (a) preparing a first mixture by mixing a carrier, an organic solvent and distilled water, (b) adding an iridium (Ir) precursor, ruthenium ) Precursor and one of scandium (Sc) precursor, lanthanum precursor, cerium precursor, samarium precursor, europium (Eu) precursor or gadolinium (Gd) (C) irradiating the electron beam to the second mixture to reduce the electron beam, and (d) drying the third mixture irradiated with the electron beam.

10 to 300 parts by weight of a scandium (Sc) precursor, a lanthanum precursor, a cerium precursor, a samarium precursor, a europium precursor or a gadolinium precursor may be added.

As described above in step S110, step S130 and post-processing step, post-processing may be further performed after step (d). Between steps (a) and (b), the step of irradiating ultrasonic waves may further include dispersing the carrier.

When one kind of scandium (Sc) precursor, lanthanum (La) precursor, cerium (Ce) precursor, samarium (Sm) precursor, europium (Eu) precursor or gadolinium (Gd) precursor is selected instead of yttrium , It can exhibit excellent oxygen generation reaction (OER) as compared with the existing commercialized non-platinum catalyst and platinum catalyst. It can also exhibit high activity for hydrogen oxidation.

Specific examples of the multifunctional non-platinum supported catalyst and the production method thereof will be described as follows.

1. Preparation of multifunctional non-platinum supported catalyst

3 g of carbon, diethylene glycol (4.7 mol), secondary alcohol (0.8 mol) and 2 L of distilled water were mixed and dispersed by ultrasonic treatment for 10 minutes. Then, the iridium precursor, the ruthenium precursor, and the yttrium precursor were mixed in the composition ratio shown in Table 1 below. For example, in Example 1, 400 parts by weight of Ru and 10 parts by weight of Y are mixed with 100 parts by weight of Ir. The total content of the precursors in each of the experimental examples of Table 1 is 40 parts by weight based on 100 parts by weight of the carbon support. The pH of the mixture was then adjusted to 10 by the addition of 1 M sodium hydroxide solution. The mixture was then irradiated with a 0.2 MeV electron beam for 40 minutes to reduce the precursor. The resultant was then filtered, washed with distilled water and dried at room temperature. Subsequently, post-treatment was carried out according to the post-treatment conditions shown in Table 1 below to prepare a multifunctional non-platinum supported catalyst.

The electron beam irradiation was carried out only in Examples 1 to 5 and Comparative Example 1.

[Table 1]

* Comparative Example 2 (Preometek Co.), Comparative Example 3 (Altix (RTX))

2. Property evaluation method and result

Using the catalysts obtained according to Examples 1 to 5 and Comparative Examples 1 to 3, an electrode was prepared in the following manner.

0.02 g of the catalyst is dispersed in 10 g of ethylene glycol to prepare a dispersion of the catalyst. The dispersion of the catalyst is dropped into the carbon rotary electrode with a micropipette. Subsequently, it was dried under reduced pressure at 80 캜. Subsequently, 15 μL of a 5 wt% Nafion ethylene glycol solution was added dropwise into the electrode to which the catalyst was dropped. Then, the catalyst electrode was prepared by vacuum drying at 80 DEG C (see ACS Catal. 2012, 2, 1765-1772).

Oxygenation reactions were assessed by measuring the current-potential value 5 times for the reproducibility of the electrode evaluation (see ACS Catal.2016, 6, 8069-8097).

Hydrogen oxidation reaction activity was evaluated by measuring the current-potential value twice by scanning for reproducibility at 10 mV / s at 1600 rpm from -0.05 V to 1.0 V relative to RHE.

Fig. 2 is a TEM photograph (a) of the dispersed metal particles of Example 1 according to the present invention and a TEM photograph (b) of observing the dispersed metal particles of Comparative Example 1. Fig. Referring to FIG. 2, it can be confirmed that the non-platinum alloy particles synthesized through the electron beam are uniformly dispersed in the carbon support.

[Table 2]

* Oxygen Generation Reaction (OER) 5 ^th scan, 40 wt% metal standard: 20.4082 μg _PGM / cm ² _geo

Table 2 above compares the oxygen generating reaction activity of Examples 1 to 5 and Comparative Examples 1 to 3 through a half cell. Table 2 shows the current density at 0.25 V, 0.35 V overvoltage. The activity of the oxygen generating reaction catalyst can be considered as the smaller the starting potential value and the higher the current density, the better the efficiency. Referring to Table 2, the current densities of Examples 1 to 3 and Example 5 are higher than those of Comparative Examples 1 to 3, respectively.

In particular, comparing Example 2, Example 3, and Example 4 with Example 5, it can be seen that the current density of the electrode is higher when the post-treatment is performed than when the post-treatment is not performed. The current density of the embodiment performing the post-treatment Example 3 and Example 5 represents a 4.00mA / cm ² or higher in voltage 0.25V, represents a 14.00mA / cm ² or higher in voltage 0.35V. This result is attributed to the metallization of trace amounts of metal oxide catalyst by post-treatment after electron beam irradiation. These results indicate that the catalyst activity and durability are improved.

Therefore, it is preferable to carry out the post-treatment together with the electron beam irradiation in the production of the multifunctional non-platinum supported catalyst for automotive fuel cells.

FIG. 3 shows the results of comparison of oxygen generating reaction (OER) activity between Examples 1 to 5 and Comparative Examples 1 to 3 through a half cell. Referring to FIG. 3, the current densities of Examples 1 to 3 and 5 are significantly higher than those of Comparative Examples 1 to 3.

FIG. 4 shows the hydrogen oxidation reaction (HOR) activity of Example 1, Example 2, Example 5, and Comparative Example 1 through a half cell. Referring to FIG. 4, the hydrogen oxidation reaction activity of Example 1, Example 2, and Example 5, compared to Comparative Example 1, is more than 150%. In particular, the hydrogen oxidation reaction activity of Example 5 shows 200% or more. This is a result that the composition ratio of ternary non-platinum particles satisfies iridium (Ir): ruthenium (Ru): yttrium (Y) = 1: 3 to 5: 0.1 to 3. And, it shows that the post-treatment can show excellent oxygen generation reaction and hydrogen oxidation reaction of the catalyst.

[Table 3]

Table 3 and Figure 5 are the results of the photoelectron spectroscopy (XPS) test of Example 5 according to the present invention. Referring to Table 3 and FIG. 5, in the case of Example 5, it can be confirmed that all the ternary non-platinum components are in a metallic state.

Thus, a non-platinum catalyst comprising iridium (Ir), ruthenium (Ru) and yttrium (Y) is produced by electron beam reduction and post-treatment. Therefore, the activity for the oxygen generating reaction is high, and the production cost is low. In addition, there is an advantage that it can be obtained in a large amount. In addition, the non-platinum catalyst can replace the conventional platinum catalyst, and thus can exhibit a remarkable increase in price competitiveness.

Accordingly, the non-platinum catalyst according to the present invention can be applied to a polymer electrolyte fuel cell (PEMFC), a phosphoric acid fuel cell (PAFC), or a direct methanol fuel cell (DMFC).

While the present invention has been described in connection with what is presently considered to be practical exemplary embodiments, it is to be understood that the invention is not limited to the disclosed embodiments, but, on the contrary, It is to be understood that the invention may be embodied in other specific forms without departing from the spirit or essential characteristics thereof. It is therefore to be understood that the above-described embodiments are illustrative in all aspects and not restrictive.

Claims (15)

1. A carrier; And ternary non-platinum particles carried on the carrier,

   Wherein the ternary non-platinum particles include iridium (Ir), ruthenium (Ru), and yttrium (Y).
2. The method according to claim 1,

   300 to 500 parts by weight of ruthenium (Ru) and 10 to 300 parts by weight of yttrium (Y), based on 100 parts by weight of iridium (Ir).
3. The method according to claim 1,

   The multifunctional non-platinum supported catalyst

   The non-platinum supported catalyst according to any one of claims 1 to 3, wherein the non-platinum supported catalyst comprises 5 to 50 parts by weight of the ternary non-platinum particles per 100 parts by weight of the carrier.
4. The method according to claim 1,

   The support may be a carbon-based support containing at least one of activated carbon, graphene, graphite, mesoporous carbon, and carbon nanotubes,

   Characterized in that it is a metal oxide support comprising at least one metal selected from the group consisting of titanium (Ti), aluminum (Al), tin (Sn), niobium (Nb), tantalum (Ta), antimony (Sb) Multifunctional non-platinum supported catalyst.
5. A carrier; And ternary non-platinum particles carried on the carrier,

   The ternary non-platinum particles include iridium (Ir), ruthenium (Ru), and scandium (Sc), lanthanum (La), cerium (Ce), samarium (Sm), europium (Eu) Wherein the catalyst is a polyfunctional non-platinum supported catalyst.
6. (a) mixing a carrier, an organic solvent, and distilled water to prepare a first mixture;

   (b) adding an iridium (Ir) precursor, a ruthenium (Ru) precursor and a yttrium (Y) precursor to the first mixture to form a second mixture;

   (c) irradiating the second mixture with an electron beam to reduce it; And

   (d) drying the third mixture irradiated with the electron beam.
7. The method according to claim 6,

   And (e) after the step (d), post-treating the dried third mixture in a hydrogen gas atmosphere.
8. The method according to claim 6,

   Wherein 300 to 500 parts by weight of the ruthenium (Ru) precursor and 10 to 300 parts by weight of the yttrium (Y) precursor are added to 100 parts by weight of the iridium (Ir) precursor in the step (b) A method for producing a non-platinum supported catalyst.
9. The method according to claim 6,

   Wherein the iridium (Ir) precursor, the ruthenium (Ru) precursor and the yttrium (Y) precursor are added in an amount of 5 to 50 parts by weight based on 100 parts by weight of the carrier. .
10. The method according to claim 6,

    The support may be a carbon-based support containing at least one of activated carbon, graphene, graphite, mesoporous carbon, and carbon nanotubes,

    Characterized in that it is a metal oxide support comprising at least one metal selected from the group consisting of titanium (Ti), aluminum (Al), tin (Sn), niobium (Nb), tantalum (Ta), antimony (Sb) A method for producing a multifunctional non-platinum supported catalyst.
11. The method according to claim 6,

    Between the steps (a) and (b)

    And dispersing the carrier by irradiating the first mixture with ultrasonic waves for 5 to 60 minutes.
12. The method according to claim 6,

    Wherein in step (c), an electron beam of 0.1 to 1 MeV is irradiated for 10 to 60 minutes.
13. 8. The method of claim 7,

    Wherein the post-treatment is carried out at 200 to 400 ° C for 30 minutes to 120 minutes in the step (e).
14. 8. The method of claim 7,

    Wherein the post-treatment is performed in an atmosphere having an inert gas: hydrogen gas mixing ratio of 3: 1 to 5: 1.
15. (a) mixing a carrier, an organic solvent, and distilled water to prepare a first mixture;

    (Ir) precursor, a ruthenium (Ru) precursor, and a scandium (Sc) precursor, a lanthanum (La) precursor, a cerium (Ce) precursor, a samarium (Sm) precursor, a europium (Eu) precursor, Preparing a second mixture by adding one of a precursor or a gadolinium (Gd) precursor;

    (c) irradiating the second mixture with an electron beam to reduce it; And

    (d) drying the third mixture irradiated with the electron beam.

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