WO2019076291A1 - Curved glass sheet and method for manufacturing same, and electronic device - Google Patents

Curved glass sheet and method for manufacturing same, and electronic device Download PDF

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Publication number
WO2019076291A1
WO2019076291A1 PCT/CN2018/110400 CN2018110400W WO2019076291A1 WO 2019076291 A1 WO2019076291 A1 WO 2019076291A1 CN 2018110400 W CN2018110400 W CN 2018110400W WO 2019076291 A1 WO2019076291 A1 WO 2019076291A1
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WO
WIPO (PCT)
Prior art keywords
textured surface
glass sheet
glass plate
flat glass
etching
Prior art date
Application number
PCT/CN2018/110400
Other languages
French (fr)
Chinese (zh)
Inventor
杨光明
Original Assignee
Oppo广东移动通信有限公司
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Filing date
Publication date
Application filed by Oppo广东移动通信有限公司 filed Critical Oppo广东移动通信有限公司
Publication of WO2019076291A1 publication Critical patent/WO2019076291A1/en

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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C15/00Surface treatment of glass, not in the form of fibres or filaments, by etching
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B23/00Re-forming shaped glass
    • C03B23/02Re-forming glass sheets
    • C03B23/023Re-forming glass sheets by bending
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • HELECTRICITY
    • H04ELECTRIC COMMUNICATION TECHNIQUE
    • H04MTELEPHONIC COMMUNICATION
    • H04M1/00Substation equipment, e.g. for use by subscribers
    • H04M1/02Constructional features of telephone sets
    • H04M1/0202Portable telephone sets, e.g. cordless phones, mobile phones or bar type handsets
    • H04M1/026Details of the structure or mounting of specific components

Definitions

  • the present application relates to the field of sheet surface processing, and in particular to a curved glass sheet, a preparation method thereof, and an electronic device.
  • the present application proposes a method of preparing a curved glass sheet.
  • the method includes: performing a first treatment on a flat glass plate, forming a first textured surface on the flat glass plate; performing a second treatment on the planar glass plate subjected to the first process to form a second textured surface; Performing a bending process on the flat glass plate subjected to the second treatment to form a curved surface on the flat glass plate, wherein the first process and the second process are independently selected from dry etching and wet Etching and setting the pattern layer. Therefore, the method can realize the hierarchical three-dimensional texture on the curved glass plate, which greatly enriches the appearance effect of the curved glass.
  • the present application proposes a curved glass sheet.
  • the curved glass sheet includes: a curved surface formed by bending a flat glass sheet; a first textured surface, the first textured surface is disposed on the flat glass plate; and a second a textured surface, the second textured surface is disposed on the planar glass plate; wherein the first textured surface and the second textured surface are independently dried, wet etched, and patterned separately Formed by at least one of the layers.
  • the curved glass sheet can realize a layered three-dimensional texture, which greatly enriches the appearance of the curved glass.
  • the application proposes an electronic device.
  • the electronic device includes: a body; and a housing, at least a portion of which is made of a curved glass sheet as described above.
  • the electronic device has all the features and advantages of the curved glass plate described above, and details are not described herein.
  • the housing of the electronic device has a layered three-dimensional texture with a rich appearance.
  • FIG. 1 shows a flow chart of a method of preparing a curved glass sheet according to an embodiment of the present application
  • FIG. 2 is a partial cross-sectional structural view showing a curved glass sheet according to an embodiment of the present application
  • FIG. 3 is a partial cross-sectional structural view showing a curved glass sheet according to another embodiment of the present application.
  • FIG. 4 is a partial cross-sectional structural view showing a curved glass sheet according to still another embodiment of the present application.
  • FIG. 5 is a partial cross-sectional structural view showing a curved glass sheet according to still another embodiment of the present application.
  • FIG. 6 shows a flow chart of a method of wet etching according to an embodiment of the present application
  • FIG. 7 shows a flow chart of a portion of a method of preparing a curved glass sheet according to an embodiment of the present application
  • FIG. 8 is a cross-sectional structural view showing a curved glass sheet according to an embodiment of the present application.
  • FIG. 9 shows a schematic structural diagram of an electronic device according to an embodiment of the present application.
  • 100 a flat glass plate; 110: a first textured surface; 120: a second textured surface; 10: an overlapping area of the first textured surface and the second textured surface; 20: a curved surface; 200: a casing; 1000: an electronic device.
  • the appearance effect is achieved on the curved glass mainly by the surface modification method.
  • the surface modification method includes an inkjet method or a film coating method, and the surface effects produced by these methods are mostly a flat effect of color and gloss. Therefore, if a process can be provided to make the curved glass have a layered three-dimensional texture, it will greatly enrich the appearance of the curved glass.
  • the present application provides a method of making a curved glass sheet. According to an embodiment of the present application, referring to FIG. 1, the method includes:
  • the planar glass sheet is subjected to a first treatment to form a first textured surface on the flat glass sheet.
  • the shape, size, and thickness of the flat glass plate are not particularly limited, and those skilled in the art can make selections as needed.
  • the process of trimming a flat glass sheet may be further included before the first treatment of the flat glass sheet.
  • a flat glass plate can be cut using a numerically controlled machine tool and a diamond cutter to obtain a flat glass plate of a predetermined size.
  • the method of the first process is not particularly limited, and may be dry etching, wet etching, or setting a pattern layer.
  • a first treatment may be performed on at least a portion of the surface of the planar glass sheet to form a first textured surface on at least a portion of the surface of the planar glass sheet.
  • the dry etching may include at least one of a laser laser etching process, a plasma etching process, and a photolithography process.
  • a laser laser etching process etching process
  • a plasma etching process etching process
  • a photolithography process etching process
  • the first textured surface may be formed by laser laser engraving.
  • the high-intensity laser beam emitted by the laser can be used to focus on the focus to change the surface properties of the material, thereby forming a pattern to be etched on the surface of the material.
  • an ultraviolet laser engraving device may be used, and the laser light source may be ultraviolet light, and the etching power may be 5-10W. Therefore, the first textured surface can be formed on the flat glass plate simply and quickly, and the shape of the first textured surface and the etching depth can also be easily passed through parameters such as the laser light source, the etching path, and the laser etching power. Make adjustments.
  • the first textured surface may be formed by a plasma etching process.
  • the plasma generating device can be used to generate plasma, and the free radicals in the plasma can bombard or sputter the surface molecules of the etched material to form a volatile substance, thereby achieving the purpose of etching.
  • a mask may be previously disposed on the flat glass plate to define a region where the plasma can act, thereby realizing the first textured surface. The location is limited.
  • a template having a certain hollow pattern may be used as a mask, and a first textured surface having a specific pattern may be obtained.
  • the dry etching method can have various options and is convenient to operate.
  • the specific method and operating parameters of the dry etching are not particularly limited as long as the surface of the flat glass plate can be etched to form a texture.
  • the etching depth of the dry etching may be 0.01-1 mm. The range of the etch depth facilitates the formation of textures of different depths and ensures that the etched planar glass sheet still has good mechanical strength.
  • the first textured surface may also be formed by wet etching.
  • the flat glass plate may be etched by using an etching solution, that is, the flat glass plate is immersed in the etching liquid for etching.
  • the wet etching may include the following specific steps: first, a mask is provided on the surface of the flat glass plate.
  • the specific manner of setting the mask is not particularly limited. For example, a photosensitive ink may be printed on the surface of the flat glass plate, and a mask may be formed using the photosensitive ink to shield the flat glass plate region which is not required to be etched.
  • the side of the flat glass plate provided with the mask can be placed in the etching liquid for etching.
  • the kind of the etching liquid and the specific etching manner are not particularly limited as long as the etching texture can be formed on the flat glass plate, for example, according to a specific embodiment of the present application, printing can be performed.
  • the flat glass plate which shields the ink is immersed in an etching solution mainly composed of hydrofluoric acid for etching.
  • the mask is finally removed to form an etched texture pattern.
  • a masked ink can be removed by using a specific weakly alkaline (concentration: 1-5%) solution, whereby the flat glass plate of the ink shielding region is not etched, is a transparent gloss effect, and is etched.
  • the flat glass plate area is matte matte effect.
  • the etched flat glass sheet not only has a textured effect, but also has good mechanical strength.
  • the first textured surface may also be formed by providing a pattern layer.
  • the provision of the pattern layer may be achieved by at least one of an ultraviolet imprint process, a hot imprint process, and 3D printing.
  • the first textured surface may be formed by ultraviolet imprinting, specifically: the ultraviolet curable adhesive is coated on the surface of the flat glass plate, and a transparent stamper is disposed on the ultraviolet curable adhesive, and the embossed area is promoted by ultraviolet exposure.
  • the UV curable adhesive is polymerized and solidified to form a textured pattern.
  • the first textured surface may be formed by a hot stamping process.
  • the stamper may be pressed against the polymer film on the substrate under high temperature and high pressure, and then the temperature is lowered, and then the stamper is separated from the polymer layer. And forming a texture pattern.
  • the first textured surface may be formed by 3D printing.
  • the texture pattern may be formed by layer-by-layer printing using a bondable material such as powdered metal or plastic based on the digital model file.
  • the method of setting the pattern layer can have various options and is convenient to operate.
  • the specific method and operational parameters for providing the pattern layer are not particularly limited as long as the texture can be formed on the surface of the flat glass plate.
  • the ultraviolet imprint process may be used to provide a pattern layer on the surface of the flat glass plate.
  • the ultraviolet curable glue may be first imprinted on the glass substrate through the mold texture, and then the texture effect is exhibited by the post-stage coloring process.
  • the side of the pattern layer away from the flat glass plate has a stripe pattern having a width of 0.01 to 1 mm.
  • the width of the stripe pattern facilitates the preparation of finer textures and patterns.
  • the first processed flat glass sheet is subjected to a second treatment to form a second textured surface.
  • the method of the second process is not particularly limited, and may be dry etching, wet etching, or setting a pattern layer, and those skilled in the art may select as needed. A detailed description has been made in the foregoing, and will not be described again here.
  • the method of forming the second textured surface may be the same as or different from the method of forming the first textured surface. As long as the formed second textured surface has a difference from any of the first textured surface in the texture surface pattern, the position in the screen glass panel, or the coverage. Since the glass sheet itself has a certain transmittance, a sheet having a three-dimensional visual effect can be obtained by means of the first textured surface and the second textured surface.
  • the surface of the planar glass sheet 100 that is not covered by the first textured surface 110 may be subjected to a second treatment so that at least the planar glass sheet 100 is not covered by the first textured surface 110.
  • a portion of the surface forms a second textured surface 120.
  • different textures can be formed in different regions of the flat glass plate 100, so that the planar glass plate 100 as a whole has a well-defined three-dimensional texture effect.
  • the second textured surface 120 may be located at a different depth from the first textured surface 110 or at the same depth, and a person skilled in the art may select according to a specific texture effect that needs to be achieved.
  • the second textured surface 120 can be at the same depth as the first textured surface 110 at the planar glass sheet 100.
  • At least a portion of the first textured surface 110 may be subjected to a second process to further form the second textured surface 120 on at least a portion of the surface on which the first textured surface 110 is located on the planar glass sheet 100. And an overlapping region 10 of the first textured surface 110 and the second textured surface 120 is also formed. Thereby, different levels of texture can be formed in the same area of the flat glass plate 100, and the flat glass plate 100 can have a layered three-dimensional texture effect.
  • At least a portion of the surface of the planar glass sheet 100 that is not covered by the first textured surface 110, and at least a portion of the first textured surface 110 may be subjected to a second process so as not to be in the first texture
  • At least a portion of the surface covered by the face 110, and at least a portion of the first textured face 110 form a second textured face 120, and an overlap region 10 of the first textured face 110 and the second textured face 120 is also formed.
  • the second processed flat glass plate is bent to form a curved surface on the flat glass plate to form a curved glass plate having a layered three-dimensional texture effect.
  • the specific method of the bending process is not particularly limited.
  • the second processed flat glass plate may be subjected to hot pressing treatment, and the flat glass plate may be designed according to advance.
  • the 3D surface mold gets a 3D surface effect.
  • the direction of the bending process is not particularly limited, and the first textured surface and the second textured surface may be located on the front or back of the three-dimensional curved glass.
  • the method for preparing a curved glass plate may further include:
  • the flat glass plate on which the curved surface is formed is subjected to an optical coating process.
  • the optical coating can be performed on the back surface of the curved glass plate, that is, the optical glass is coated on the side of the curved glass away from the first textured surface and the second textured surface, thereby adjusting the curved glass plate.
  • the transmittance and reflectivity make the curved glass plate more transparent and achieve better texture.
  • the material, transmittance, and reflectance of the coating film are not particularly limited, and those skilled in the art may select according to needs, for example, according to a specific embodiment of the present application, the coating target may be silicon oxide, The superposition coating of the titanium oxide combination may have an optical transmittance of 75% to 95% and a reflectance of 5% to 20%.
  • the optically-coated glass sheet subjected to the optical coating treatment is subjected to an inkjet coloring treatment.
  • the color of the inkjet coloring process is not particularly limited, and the ink color can be formulated according to the designed pattern color.
  • colored ink adhesion can be performed by an inkjet method. After inkjet coloring, the fine texture produced by the previous step is more obvious, and with the transparency of the optical coating, a multi-layer texture interlacing stereo effect can be formed.
  • the method can realize the hierarchical three-dimensional texture on the curved glass plate, which greatly enriches the appearance of the curved glass.
  • the first treatment may include at least one of dry etching and wet etching, the first textured surface is formed on the surface of the flat glass plate, and the second The textured surface may be a patterned layer, and the patterned layer is used to form a second textured surface.
  • the first process may be wet etching.
  • the wet etching may include the following steps:
  • a mask is placed on the surface of the flat glass plate.
  • the specific manner of providing the mask is not particularly limited.
  • the flat glass plate may be subjected to photosensitive ink printing, and the photosensitive ink is used to shield the flat glass plate region which is not required to be etched.
  • the corresponding film sheets can be first made according to the designed texture or pattern, and then cured by exposure and development of the film sheets to form a mask for the corresponding texture or pattern.
  • one side of the flat glass plate provided with the mask is placed in the etching liquid for etching.
  • the kind of the etching liquid and the specific etching manner are not particularly limited as long as the etching texture can be formed on the flat glass plate, for example, according to a specific embodiment of the present application, printing can be performed.
  • the flat glass plate which shields the ink is immersed in an etching solution mainly composed of hydrofluoric acid for etching.
  • the mask is removed to form an etched first textured surface.
  • a masked ink can be removed by using a specific weakly alkaline (concentration: 1-5%) solution, whereby the flat glass plate of the ink shielding region is not etched, is a transparent gloss effect, and is etched.
  • the flat glass plate area forms the first textured surface, which is a matte matte effect.
  • the first textured surface and the unetched planar glass panel region constitute a first layer of depth and a visual texture pattern effect.
  • the first textured surface formed by the step may have a gloss of 25-65, a roughness of 0.1-0.2, a haze of 10%-20%, and a transmittance of not less than 70%, the reflectance can be no less than 10%.
  • the first textured surface may have a thickness of from 5 micrometers to 200 micrometers.
  • the second treatment may be to provide a pattern layer on the flat glass plate subjected to the first treatment, and the pattern layer constitutes the second texture surface.
  • a specific preparation method of the pattern layer is not particularly limited.
  • the pattern layer may be formed by at least one of an ultraviolet imprint process, a hot imprint process, and 3D printing. .
  • the patterned layer can be formed by ultraviolet imprinting.
  • the side of the pattern layer away from the flat glass plate may have a stripe pattern, and the stripe pattern may have a width of 0.01 to 1 mm. Thereby, the width of the stripe pattern is advantageous for preparing a finer pattern and achieving a more delicate texture effect.
  • the first processing may be to provide a pattern layer on the flat glass plate, the pattern layer constitutes the first texture surface, and then the first texture surface is performed.
  • the second process forms a second textured surface.
  • the pattern layer may be formed by at least one of an ultraviolet imprint process, a hot imprint process, and 3D printing.
  • the side of the pattern layer away from the flat glass plate may have a stripe pattern, and the stripe pattern may have a width of 0.01 to 1 mm.
  • the second textured surface is formed by performing a second treatment on the first textured surface. That is to say, the second process is performed on a flat glass plate of the same area as the first textured surface. Thereby, texture effects of different levels or different patterns can be formed in the same area of the flat glass plate.
  • the second process includes at least one of dry etching and wet etching.
  • the second process may be laser laser engraving, and an ultraviolet laser may be used.
  • the laser source used may be ultraviolet light
  • the etching power may be 5-10W.
  • the etching depth of the dry etching is 0.01-1 mm. Therefore, the etching depth is wide, which is favorable for forming textures of different depths, and can ensure that the planar glass plate after etching still has good mechanical strength.
  • the second process is performed for the pattern layer (first texture surface) formed by the first process, and therefore, the etching process in the second process does not affect the mechanical strength of the flat glass plate.
  • a hierarchical three-dimensional texture effect can be formed on the flat glass plate.
  • the present application proposes a curved glass sheet.
  • the curved glass sheet includes: a curved surface 20 formed by bending a flat glass sheet 100, a first textured surface 110 disposed on the flat glass sheet 100, and a second texture.
  • the curved glass plate may be prepared by the foregoing method, whereby the curved glass plate has all the features and advantages of the curved glass plate prepared by the method for preparing the curved glass plate described above. , will not repeat them here.
  • the projections of the first textured surface and the second textured surface on the flat glass plate may not overlap at all, may partially overlap, or may completely overlap. That is, the first textured surface may cover a portion of the surface of the planar glass sheet, and the second textured surface covers at least a portion of the planar glass sheet that is not covered by the first textured surface. Alternatively, the second textured surface covers at least a portion of the first textured surface. Alternatively, the first textured surface covers a portion of the surface of the planar glass sheet, the second textured surface covers at least a portion of the first textured surface, and the region of the planar glass sheet that is not covered by the first textured surface.
  • the etching depth of the dry etching may be 0.01-1 mm.
  • a stripe pattern may be provided on a side of the pattern layer away from the flat glass sheet, and the stripe pattern may have a width of 0.01 to 1 mm.
  • the first textured surface may have a gloss of 25 to 65, a roughness of 0.1-0.2, a haze of 10%-20%, and a transmittance of not less than 70. %, the reflectance is not less than 10%, and the thickness of the first textured surface may be 5 micrometers to 200 micrometers.
  • the curved glass sheet may have a plurality of (eg, two or four) curved surfaces at the edge of the sheet; or the upper surface of the curved glass sheet may have a curved surface as a whole.
  • the present application proposes an electronic device.
  • the electronic device 1000 includes: a body; and a housing 200, at least a portion of which is made of a curved glass sheet as described above.
  • the electronic device 1000 has all the features and advantages of the curved glass plate described above, and will not be described herein.

Abstract

Provided are a curved glass sheet and a method for manufacturing same, and an electronic device. The method comprises: performing first processing on a flat glass sheet to form a first textured surface on the flat glass sheet; performing second processing on the flat glass sheet having experienced the first processing to form a second textured surface; and bending the flat glass sheet having experienced the second processing to form a curved surface on the flat glass sheet, wherein the first processing and the second processing each is separately selected from dry etching, wet etching, and pattern layer forming.

Description

曲面玻璃板材及其制备方法、电子设备Curved glass plate, preparation method thereof, and electronic device
优先权信息Priority information
本申请请求2017年10月18日向中国国家知识产权局提交的、专利申请号为201710973186.2的专利申请的优先权和权益,并且通过参照将其全文并入此处。Priority is claimed on Japanese Patent Application No. 201710973186.2, the entire disclosure of which is hereby incorporated by reference.
技术领域Technical field
本申请涉及板材表面加工领域,具体地,涉及曲面玻璃板材及其制备方法、电子设备。The present application relates to the field of sheet surface processing, and in particular to a curved glass sheet, a preparation method thereof, and an electronic device.
背景技术Background technique
随着消费水平的提高,消费者对电子产品不仅追求功能的多样化,而且对其外观、质感等也有越来越高的要求。目前,玻璃材料已被广泛应用于电子设备市场,例如薄型平板玻璃被广泛用于制作电子设备的外壳。随着玻璃板材制造技术的发展,薄型平板玻璃的表面可以具有精美的纹理效果,极大地丰富了电子设备的外观。近年来随着曲面显示技术的发展,作为曲面屏幕的曲面玻璃也开始应用。With the improvement of consumption level, consumers not only pursue the diversification of functions of electronic products, but also have higher and higher requirements for their appearance and texture. At present, glass materials have been widely used in the electronic device market, for example, thin flat glass is widely used for making electronic device casings. With the development of glass sheet manufacturing technology, the surface of the thin flat glass can have a beautiful texture effect, which greatly enriches the appearance of electronic equipment. In recent years, with the development of curved surface display technology, curved glass as a curved screen has also begun to be applied.
然而,目前的曲面玻璃板材及其制备方法、电子设备还有待改进。However, the current curved glass sheet, its preparation method, and electronic equipment still need to be improved.
发明内容Summary of the invention
本申请提出了一种制备曲面玻璃板材的方法。该方法包括:对平面玻璃板进行第一处理,在所述平面玻璃板上形成第一纹理面;对经过所述第一处理的所述平面玻璃板进行第二处理,形成第二纹理面;对经过所述第二处理的所述平面玻璃板进行弯折处理,在所述平面玻璃板上形成曲面,所述第一处理以及所述第二处理分别独立地选自干法刻蚀、湿法刻蚀以及设置图案层。由此,该方法可以在曲面玻璃板材上实现层次分明的立体纹理,极大地丰富了曲面玻璃的外观效果。The present application proposes a method of preparing a curved glass sheet. The method includes: performing a first treatment on a flat glass plate, forming a first textured surface on the flat glass plate; performing a second treatment on the planar glass plate subjected to the first process to form a second textured surface; Performing a bending process on the flat glass plate subjected to the second treatment to form a curved surface on the flat glass plate, wherein the first process and the second process are independently selected from dry etching and wet Etching and setting the pattern layer. Therefore, the method can realize the hierarchical three-dimensional texture on the curved glass plate, which greatly enriches the appearance effect of the curved glass.
在本申请的另一方面,本申请提出了一种曲面玻璃板材。根据本申请的实施例,该曲面玻璃板材包括:通过对平面玻璃板进行弯折处理而形成的曲面;第一纹理面,所述第一纹理面设置在所述平面玻璃板上;以及第二纹理面,所述第二纹理面设置在所述平面玻璃板上;其中,所述第一纹理面以及所述第二纹理面是分别独立地通过干法刻蚀、湿法刻蚀以及设置图案层的至少之一而形成的。由此,该曲面玻璃板材可以实现层次分明的立体纹理,极大地丰富了曲面玻璃的外观效果。In another aspect of the present application, the present application proposes a curved glass sheet. According to an embodiment of the present application, the curved glass sheet includes: a curved surface formed by bending a flat glass sheet; a first textured surface, the first textured surface is disposed on the flat glass plate; and a second a textured surface, the second textured surface is disposed on the planar glass plate; wherein the first textured surface and the second textured surface are independently dried, wet etched, and patterned separately Formed by at least one of the layers. Thus, the curved glass sheet can realize a layered three-dimensional texture, which greatly enriches the appearance of the curved glass.
在本申请的另一方面,本申请提出了一种电子设备。根据本申请的实施例,该电子设备包括:本体;以及壳体,所述壳体的至少一部分是由前面所述的曲面玻璃板材制成的。所述电子设备具有前面所述的曲面玻璃板材所具有的全部特征以及优点,在此不再赘述。总的来说,该电子设备的壳体具有层次分明的立体纹理,具有丰富的外观效果。In another aspect of the application, the application proposes an electronic device. According to an embodiment of the present application, the electronic device includes: a body; and a housing, at least a portion of which is made of a curved glass sheet as described above. The electronic device has all the features and advantages of the curved glass plate described above, and details are not described herein. In general, the housing of the electronic device has a layered three-dimensional texture with a rich appearance.
附图说明DRAWINGS
图1显示了根据本申请一个实施例的制备曲面玻璃板材的方法流程图;1 shows a flow chart of a method of preparing a curved glass sheet according to an embodiment of the present application;
图2显示了根据本申请一个实施例的曲面玻璃板材的部分剖面结构示意图;2 is a partial cross-sectional structural view showing a curved glass sheet according to an embodiment of the present application;
图3显示了根据本申请另一个实施例的曲面玻璃板材的部分剖面结构示意图;3 is a partial cross-sectional structural view showing a curved glass sheet according to another embodiment of the present application;
图4显示了根据本申请又一个实施例的曲面玻璃板材的部分剖面结构示意图;4 is a partial cross-sectional structural view showing a curved glass sheet according to still another embodiment of the present application;
图5显示了根据本申请又一个实施例的曲面玻璃板材的部分剖面结构示意图;FIG. 5 is a partial cross-sectional structural view showing a curved glass sheet according to still another embodiment of the present application; FIG.
图6显示了根据本申请一个实施例的湿法刻蚀的方法流程图;6 shows a flow chart of a method of wet etching according to an embodiment of the present application;
图7显示了根据本申请一个实施例的制备曲面玻璃板材的部分方法流程图;7 shows a flow chart of a portion of a method of preparing a curved glass sheet according to an embodiment of the present application;
图8显示了根据本申请一个实施例的曲面玻璃板材的剖面结构示意图;以及8 is a cross-sectional structural view showing a curved glass sheet according to an embodiment of the present application;
图9显示了根据本申请一个实施例的电子设备的结构示意图。FIG. 9 shows a schematic structural diagram of an electronic device according to an embodiment of the present application.
附图标记说明:Description of the reference signs:
100:平面玻璃板;110:第一纹理面;120:第二纹理面;10:第一纹理面与第二纹理面的重叠区域;20:曲面;200:壳体;1000:电子设备。100: a flat glass plate; 110: a first textured surface; 120: a second textured surface; 10: an overlapping area of the first textured surface and the second textured surface; 20: a curved surface; 200: a casing; 1000: an electronic device.
具体实施方式Detailed ways
下面详细描述本申请的实施例,所述实施例的示例在附图中示出,其中自始至终相同或类似的标号表示相同或类似的元件或具有相同或类似功能的元件。下面通过参考附图描述的实施例是示例性的,仅用于解释本申请,而不能理解为对本申请的限制。The embodiments of the present application are described in detail below, and the examples of the embodiments are illustrated in the drawings, wherein the same or similar reference numerals are used to refer to the same or similar elements or elements having the same or similar functions. The embodiments described below with reference to the accompanying drawings are intended to be illustrative only, and are not to be construed as limiting.
需要说明的是,在本申请的各个方面中所描述的特征和效果可以互相适用,在此不再赘述。It should be noted that the features and effects described in the various aspects of the present application may be applied to each other, and are not described herein again.
本申请是基于发明人对以下事实和问题的发现和认识作出的:This application is based on the discovery and recognition of the following facts and issues by the inventors:
目前主要通过表面修饰的方法,在曲面玻璃上实现外观效果。具体的,表面修饰方法有喷墨法或贴膜法,这些方法产生的表面效果多为颜色、光泽的平面效果。因此,如果能够提供一种工艺方法,使曲面玻璃具有层次分明的立体纹理,将能极大地丰富曲面玻璃的外观效果。At present, the appearance effect is achieved on the curved glass mainly by the surface modification method. Specifically, the surface modification method includes an inkjet method or a film coating method, and the surface effects produced by these methods are mostly a flat effect of color and gloss. Therefore, if a process can be provided to make the curved glass have a layered three-dimensional texture, it will greatly enrich the appearance of the curved glass.
在本申请的一个方面,本申请提出了一种制备曲面玻璃板材的方法。根据本申请的实施例,参考图1,该方法包括:In one aspect of the present application, the present application provides a method of making a curved glass sheet. According to an embodiment of the present application, referring to FIG. 1, the method includes:
S100:形成第一纹理面S100: forming a first texture surface
在该步骤中,对平面玻璃板进行第一处理,以便在平面玻璃板上形成第一纹理面。根据本申请的实施例,平面玻璃板的形状、大小和厚度不受特别限制,本领域技术人员可以根 据需要进行选择。例如,根据本申请的实施例,可以在对平面玻璃板进行第一处理之前,进一步包括对平面玻璃板裁料的工序。根据本申请的具体实施例,在该工序中,可以采用数控机床并采用金刚石刀具对平面玻璃板进行裁切,以得到预定尺寸的平面玻璃板。根据本申请的实施例,第一处理的方法不受特别限制,可以为干法刻蚀、湿法刻蚀或者设置图案层。根据本申请的实施例,可以在平面玻璃板的至少一部分表面进行第一处理,以便在平面玻璃板的至少一部分表面形成第一纹理面。In this step, the planar glass sheet is subjected to a first treatment to form a first textured surface on the flat glass sheet. According to the embodiment of the present application, the shape, size, and thickness of the flat glass plate are not particularly limited, and those skilled in the art can make selections as needed. For example, according to an embodiment of the present application, the process of trimming a flat glass sheet may be further included before the first treatment of the flat glass sheet. According to a specific embodiment of the present application, in the process, a flat glass plate can be cut using a numerically controlled machine tool and a diamond cutter to obtain a flat glass plate of a predetermined size. According to an embodiment of the present application, the method of the first process is not particularly limited, and may be dry etching, wet etching, or setting a pattern layer. According to an embodiment of the present application, a first treatment may be performed on at least a portion of the surface of the planar glass sheet to form a first textured surface on at least a portion of the surface of the planar glass sheet.
根据本申请的实施例,上述干法刻蚀可以包括激光镭雕处理、等离子体刻蚀处理以及光刻处理的至少之一。下面对干法刻蚀的各个具体方法作简要说明:According to an embodiment of the present application, the dry etching may include at least one of a laser laser etching process, a plasma etching process, and a photolithography process. The following is a brief description of each specific method of dry etching:
根据本申请的实施例,可以采用激光镭雕处理形成上述第一纹理面。可以利用激光器发射的高强度激光束,聚焦打在焦点处,使材料表面性质发生变化,进而在材料表面形成要刻蚀的图形。例如,根据本申请的具体实施例,干法刻蚀为激光镭雕处理时,可以采用紫外型激光镭雕设备,所采用的激光光源可以为紫外光,刻蚀功率可以为5-10W。由此,可以简单、快速的在平面玻璃板上形成第一纹理面,且第一纹理面的形状、刻蚀深度,也可以简便地通过对激光光源、刻蚀路径、激光刻蚀功率等参数进行调节。According to an embodiment of the present application, the first textured surface may be formed by laser laser engraving. The high-intensity laser beam emitted by the laser can be used to focus on the focus to change the surface properties of the material, thereby forming a pattern to be etched on the surface of the material. For example, according to a specific embodiment of the present application, when the dry etching is laser laser engraving, an ultraviolet laser engraving device may be used, and the laser light source may be ultraviolet light, and the etching power may be 5-10W. Therefore, the first textured surface can be formed on the flat glass plate simply and quickly, and the shape of the first textured surface and the etching depth can also be easily passed through parameters such as the laser light source, the etching path, and the laser etching power. Make adjustments.
根据本申请的实施例,可以采用等离子体刻蚀处理形成上述第一纹理面。由此,可以利用等离子体发生装置产等离子体,令等离子体中的自由基轰击或溅射被刻蚀材料的表面分子,形成易挥发物质,从而实现刻蚀的目的。根据本申请的具体实施例,采用等离子体刻蚀处理形成上述第一纹理面时,可以预先在平面玻璃板上设置掩膜板,以限定等离子体可以作用的区域,从而实现对第一纹理面位置的限定。或者,也可以采用具有一定镂空图案的模板为掩膜板,进而可以获得具有特定图案的第一纹理面。According to an embodiment of the present application, the first textured surface may be formed by a plasma etching process. Thereby, the plasma generating device can be used to generate plasma, and the free radicals in the plasma can bombard or sputter the surface molecules of the etched material to form a volatile substance, thereby achieving the purpose of etching. According to a specific embodiment of the present application, when the first textured surface is formed by plasma etching, a mask may be previously disposed on the flat glass plate to define a region where the plasma can act, thereby realizing the first textured surface. The location is limited. Alternatively, a template having a certain hollow pattern may be used as a mask, and a first textured surface having a specific pattern may be obtained.
综上所述,干法刻蚀的方法可以有多种选择,且操作方便。根据本申请的实施例,干法刻蚀的具体方法和操作参数不受特别限制,只要能在平面玻璃板表面刻蚀形成纹理即可。根据本申请的实施例,干法刻蚀的刻蚀深度可以为0.01-1mm。该刻蚀深度的范围有利于形成不同深度的纹理,并且能保证刻蚀后的平面玻璃板仍然具有较好的机械强度。In summary, the dry etching method can have various options and is convenient to operate. According to the embodiment of the present application, the specific method and operating parameters of the dry etching are not particularly limited as long as the surface of the flat glass plate can be etched to form a texture. According to an embodiment of the present application, the etching depth of the dry etching may be 0.01-1 mm. The range of the etch depth facilitates the formation of textures of different depths and ensures that the etched planar glass sheet still has good mechanical strength.
根据本申请的另一些实施例,也可以采用湿法刻蚀,形成上述第一纹理面。具体的,可以采用刻蚀液对平面玻璃板进行刻蚀,即将平面玻璃板浸泡在蚀刻液内进行蚀刻。根据本申请的实施例,湿法刻蚀可以包括以下具体步骤:首先在平面玻璃板表面设置掩膜。设置掩膜的具体方式不受特别限制,例如,可以对平面玻璃板表面印刷感光油墨,利用感光油墨形成掩膜,用来遮蔽不需要进行蚀刻的平面玻璃板区域。接下来可以将平面玻璃板设置有掩膜的一侧置于刻蚀液中,进行刻蚀。根据本申请的实施例,刻蚀液的种类和具体的刻蚀方式不受特别限制,只要能够在平面玻璃板上形成刻蚀纹理即可,例如,根据本申请的具体实施例,可以将印刷好遮蔽油墨的平面玻璃板浸入以氢氟酸为主的蚀刻溶液中进行蚀 刻。最后去除掩膜,以便形成蚀刻后的纹理图案。根据本申请的实施例,可以采用特定的弱碱性(浓度:1-5%)溶液去除遮蔽的油墨,由此,油墨遮蔽区域的平面玻璃板不被蚀刻,为通透光泽效果,经过蚀刻的平面玻璃板区域为雾面哑光效果。由此,蚀刻后的平面玻璃板不仅具有纹理效果,而且依然具有良好的机械强度。According to further embodiments of the present application, the first textured surface may also be formed by wet etching. Specifically, the flat glass plate may be etched by using an etching solution, that is, the flat glass plate is immersed in the etching liquid for etching. According to an embodiment of the present application, the wet etching may include the following specific steps: first, a mask is provided on the surface of the flat glass plate. The specific manner of setting the mask is not particularly limited. For example, a photosensitive ink may be printed on the surface of the flat glass plate, and a mask may be formed using the photosensitive ink to shield the flat glass plate region which is not required to be etched. Next, the side of the flat glass plate provided with the mask can be placed in the etching liquid for etching. According to the embodiment of the present application, the kind of the etching liquid and the specific etching manner are not particularly limited as long as the etching texture can be formed on the flat glass plate, for example, according to a specific embodiment of the present application, printing can be performed. The flat glass plate which shields the ink is immersed in an etching solution mainly composed of hydrofluoric acid for etching. The mask is finally removed to form an etched texture pattern. According to an embodiment of the present application, a masked ink can be removed by using a specific weakly alkaline (concentration: 1-5%) solution, whereby the flat glass plate of the ink shielding region is not etched, is a transparent gloss effect, and is etched. The flat glass plate area is matte matte effect. Thus, the etched flat glass sheet not only has a textured effect, but also has good mechanical strength.
根据本申请的另一些实施例,还可以采用设置图案层的方式,形成上述第一纹理面。设置图案层可以是通过紫外压印处理、热压印处理以及3D打印的至少之一实现的。例如,可采用紫外压印处理形成第一纹理面,具体地:将紫外光固化胶涂覆在平面玻璃板表面,并在紫外光固化胶上设置透明压模,利用紫外曝光促使压印区域的紫外光固化胶发生聚合和固化成型,进而形成纹理图案。或者,可以采用热压印处理形成第一纹理面,具体的,可以在高温高压下,把压模压在基片上的聚合物薄膜上,然后把温度降低,再把压模与聚合物层相分离,进而形成纹理图案。或者,可以采用3D打印形成第一纹理面,具体的,可以以数字模型文件为基础,运用粉末状金属或塑料等可粘合材料,通过逐层打印的方式来形成纹理图案。由此,所述设置图案层的方法可有多种选择,且操作方便。根据本申请的实施例,设置图案层的具体方法和操作参数不受特别限制,只要能在平面玻璃板表面形成纹理即可。例如,可采用紫外压印处理在平面玻璃板表面设置图案层,具体的,可以首先将紫外光固化型胶通过模具纹理压印在玻璃基体上,然后通过后段着色工序后显现出纹理效果。根据本申请的实施例,图案层远离平面玻璃板的一侧具有条纹图案,该条纹图案的宽度为0.01~1mm。由此,该条纹图案的宽度有利于制备更加精细的纹理和图案。According to other embodiments of the present application, the first textured surface may also be formed by providing a pattern layer. The provision of the pattern layer may be achieved by at least one of an ultraviolet imprint process, a hot imprint process, and 3D printing. For example, the first textured surface may be formed by ultraviolet imprinting, specifically: the ultraviolet curable adhesive is coated on the surface of the flat glass plate, and a transparent stamper is disposed on the ultraviolet curable adhesive, and the embossed area is promoted by ultraviolet exposure. The UV curable adhesive is polymerized and solidified to form a textured pattern. Alternatively, the first textured surface may be formed by a hot stamping process. Specifically, the stamper may be pressed against the polymer film on the substrate under high temperature and high pressure, and then the temperature is lowered, and then the stamper is separated from the polymer layer. And forming a texture pattern. Alternatively, the first textured surface may be formed by 3D printing. Specifically, the texture pattern may be formed by layer-by-layer printing using a bondable material such as powdered metal or plastic based on the digital model file. Thus, the method of setting the pattern layer can have various options and is convenient to operate. According to the embodiment of the present application, the specific method and operational parameters for providing the pattern layer are not particularly limited as long as the texture can be formed on the surface of the flat glass plate. For example, the ultraviolet imprint process may be used to provide a pattern layer on the surface of the flat glass plate. Specifically, the ultraviolet curable glue may be first imprinted on the glass substrate through the mold texture, and then the texture effect is exhibited by the post-stage coloring process. According to an embodiment of the present application, the side of the pattern layer away from the flat glass plate has a stripe pattern having a width of 0.01 to 1 mm. Thus, the width of the stripe pattern facilitates the preparation of finer textures and patterns.
S200:形成第二纹理面S200: forming a second texture surface
根据本申请的实施例,在该步骤中,对经过第一处理的平面玻璃板进行第二处理,以便形成第二纹理面。根据本申请的实施例,第二处理的方法不受特别限制,可以为干法刻蚀、湿法刻蚀或者设置图案层,本领域技术人员可以根据需要进行选择。前面已经进行了详细的描述,在此不再赘述。需要说明的是,形成第二纹理面的方法,可以与形成第一纹理面的方法相同,也可以不相同。只要形成的第二纹理面,与第一纹理面在纹理面的图案、位于屏幕玻璃板中的位置或是覆盖范围的任意一项中具有差异即可。由于玻璃板自身具有一定的透过率,因此,可以借助于第一纹理面以及第二纹理面,获得具有三维视觉效果的板材。According to an embodiment of the present application, in this step, the first processed flat glass sheet is subjected to a second treatment to form a second textured surface. According to an embodiment of the present application, the method of the second process is not particularly limited, and may be dry etching, wet etching, or setting a pattern layer, and those skilled in the art may select as needed. A detailed description has been made in the foregoing, and will not be described again here. It should be noted that the method of forming the second textured surface may be the same as or different from the method of forming the first textured surface. As long as the formed second textured surface has a difference from any of the first textured surface in the texture surface pattern, the position in the screen glass panel, or the coverage. Since the glass sheet itself has a certain transmittance, a sheet having a three-dimensional visual effect can be obtained by means of the first textured surface and the second textured surface.
根据本申请的实施例,参考图2,可以对平面玻璃板100未被第一纹理面110覆盖的至少一部分表面进行第二处理,以便在平面玻璃板100未被第一纹理面110覆盖的至少一部分表面形成第二纹理面120。由此,可以在平面玻璃板100的不同区域形成不同的纹理,进而使平面玻璃板100整体上具有层次分明的立体纹理效果。根据本申请的实施例,第二纹理面120可以与第一纹理面110位于平面玻璃板100的不同深度,也可以位于同一深度, 本领域技术人员可以根据需要实现的具体纹理效果来进行选择。例如,根据本申请的具体实施例,参考图3,第二纹理面120可以与第一纹理面110位于平面玻璃板100的同一深度。According to an embodiment of the present application, with reference to FIG. 2, at least a portion of the surface of the planar glass sheet 100 that is not covered by the first textured surface 110 may be subjected to a second treatment so that at least the planar glass sheet 100 is not covered by the first textured surface 110. A portion of the surface forms a second textured surface 120. Thereby, different textures can be formed in different regions of the flat glass plate 100, so that the planar glass plate 100 as a whole has a well-defined three-dimensional texture effect. According to the embodiment of the present application, the second textured surface 120 may be located at a different depth from the first textured surface 110 or at the same depth, and a person skilled in the art may select according to a specific texture effect that needs to be achieved. For example, in accordance with a particular embodiment of the present application, referring to FIG. 3, the second textured surface 120 can be at the same depth as the first textured surface 110 at the planar glass sheet 100.
根据本申请的实施例,参考图4,可以对第一纹理面110的至少一部分进行第二处理,以便在平面玻璃板100上第一纹理面110所在表面的至少一部分进一步形成第二纹理面120,并且还形成了第一纹理面110与第二纹理面120的重叠区域10。由此,可以在平面玻璃板100的同一区域形成不同层次的纹理,进而使平面玻璃板100具有层次分明的立体纹理效果。According to an embodiment of the present application, with reference to FIG. 4, at least a portion of the first textured surface 110 may be subjected to a second process to further form the second textured surface 120 on at least a portion of the surface on which the first textured surface 110 is located on the planar glass sheet 100. And an overlapping region 10 of the first textured surface 110 and the second textured surface 120 is also formed. Thereby, different levels of texture can be formed in the same area of the flat glass plate 100, and the flat glass plate 100 can have a layered three-dimensional texture effect.
根据本申请的实施例,参考图5,可以在平面玻璃板100未被第一纹理面110覆盖的至少一部分表面,以及至少一部分第一纹理面110进行第二处理,以便在未被第一纹理面110覆盖的至少一部分表面,以及至少一部分第一纹理面110上形成第二纹理面120,并且还形成了第一纹理面110与第二纹理面120的重叠区域10。由此,可以在平面玻璃板100的不同区域形成不同的纹理,并且在同一区域的至少一部分形成不同层次的纹理,进而使平面玻璃板100具有层次分明的立体纹理效果。According to an embodiment of the present application, with reference to FIG. 5, at least a portion of the surface of the planar glass sheet 100 that is not covered by the first textured surface 110, and at least a portion of the first textured surface 110 may be subjected to a second process so as not to be in the first texture At least a portion of the surface covered by the face 110, and at least a portion of the first textured face 110 form a second textured face 120, and an overlap region 10 of the first textured face 110 and the second textured face 120 is also formed. Thereby, different textures can be formed in different regions of the flat glass sheet 100, and at least a portion of the same region can be formed with different levels of texture, thereby making the flat glass sheet 100 have a hierarchical three-dimensional texture effect.
S300:进行折弯处理S300: Perform bending treatment
在该步骤中,对经过第二处理的平面玻璃板进行弯折处理,以便在平面玻璃板上形成曲面,进而形成具有层次分明的立体纹理效果的曲面玻璃板。根据本申请的实施例,折弯处理的具体方法不受特别限制,例如,根据本申请的具体实施例,可以对经过第二处理的平面玻璃板进行热压处理,平面玻璃板可以根据提前设计的三维曲面模具得到三维曲面效果。根据本申请的实施例,折弯处理的方向不受特别限制,第一纹理面和第二纹理面可以位于三维曲面玻璃的正面或背面。In this step, the second processed flat glass plate is bent to form a curved surface on the flat glass plate to form a curved glass plate having a layered three-dimensional texture effect. According to the embodiment of the present application, the specific method of the bending process is not particularly limited. For example, according to the specific embodiment of the present application, the second processed flat glass plate may be subjected to hot pressing treatment, and the flat glass plate may be designed according to advance. The 3D surface mold gets a 3D surface effect. According to an embodiment of the present application, the direction of the bending process is not particularly limited, and the first textured surface and the second textured surface may be located on the front or back of the three-dimensional curved glass.
根据本申请的实施例,参考图7,在进行折弯处理后,制备曲面玻璃板材的方法还可以进一步包括:According to an embodiment of the present application, referring to FIG. 7, after the bending process is performed, the method for preparing a curved glass plate may further include:
S400:进行光学镀膜处理S400: Performing optical coating treatment
在该步骤中,对形成有曲面的平面玻璃板进行光学镀膜处理。根据本申请的实施例,可以在曲面玻璃板的背面进行光学镀膜,也即是说,在曲面玻璃远离第一纹理面和第二纹理面的一侧进行光学镀膜,以此来调整曲面玻璃板的透射率和反射率,使曲面玻璃板的通透感更强,可以实现更佳的纹理效果。根据本申请的实施例,镀膜的材料、透过率和反射率不受特别限制,本领域技术人员可以根据需要进行选择,例如,根据本申请的具体实施例,镀膜靶材可以为氧化硅、氧化钛组合的叠加镀层,光学镀膜的透射率可以为75%-95%,反射率可以为5%-20%。In this step, the flat glass plate on which the curved surface is formed is subjected to an optical coating process. According to the embodiment of the present application, the optical coating can be performed on the back surface of the curved glass plate, that is, the optical glass is coated on the side of the curved glass away from the first textured surface and the second textured surface, thereby adjusting the curved glass plate. The transmittance and reflectivity make the curved glass plate more transparent and achieve better texture. According to the embodiment of the present application, the material, transmittance, and reflectance of the coating film are not particularly limited, and those skilled in the art may select according to needs, for example, according to a specific embodiment of the present application, the coating target may be silicon oxide, The superposition coating of the titanium oxide combination may have an optical transmittance of 75% to 95% and a reflectance of 5% to 20%.
S500:进行喷墨着色处理S500: Performing inkjet coloring
在该步骤中,对经过光学镀膜处理的曲面玻璃板进行喷墨着色处理。根据本申请的实施 例,喷墨着色处理的颜色不受特别限制,可以根据设计的图案颜色调配油墨颜色。根据本申请的实施例,可以采用喷墨方式进行有色油墨附着。喷墨着色后,前面步骤所产生的精细纹理更加明显,再配合光学镀膜的通透感,可以形成多层纹理交织的立体效果。In this step, the optically-coated glass sheet subjected to the optical coating treatment is subjected to an inkjet coloring treatment. According to the embodiment of the present application, the color of the inkjet coloring process is not particularly limited, and the ink color can be formulated according to the designed pattern color. According to an embodiment of the present application, colored ink adhesion can be performed by an inkjet method. After inkjet coloring, the fine texture produced by the previous step is more obvious, and with the transparency of the optical coating, a multi-layer texture interlacing stereo effect can be formed.
综上所述,该方法可以在曲面玻璃板材上实现层次分明的立体纹理,极大地丰富了曲面玻璃的外观效果。In summary, the method can realize the hierarchical three-dimensional texture on the curved glass plate, which greatly enriches the appearance of the curved glass.
下面根据本申请的具体实施例,对上述方法进行详细描述:The above method is described in detail below according to a specific embodiment of the present application:
根据本申请的具体实施例,上述制备曲面玻璃板材的方法中,第一处理可以包括干法刻蚀以及湿法刻蚀的至少之一,第一纹理面形成在平面玻璃板的表面,第二纹理面可以为设置图案层,利用设置的图案层,构成第二纹理面。According to a specific embodiment of the present application, in the above method for preparing a curved glass sheet, the first treatment may include at least one of dry etching and wet etching, the first textured surface is formed on the surface of the flat glass plate, and the second The textured surface may be a patterned layer, and the patterned layer is used to form a second textured surface.
具体地,根据本申请的实施例,第一处理可以为湿法刻蚀,参考图6,湿法刻蚀可以包括以下步骤:Specifically, according to an embodiment of the present application, the first process may be wet etching. Referring to FIG. 6, the wet etching may include the following steps:
S10:在平面玻璃板表面设置掩膜S10: setting a mask on the surface of the flat glass plate
在该步骤中,在平面玻璃板表面设置掩膜。根据本申请的实施例,设置掩膜的具体方式不受特别限制,例如,可以对平面玻璃板进行感光油墨印刷,感光油墨用来遮蔽不需要进行蚀刻的平面玻璃板区域。具体的,根据本申请的实施例,可以首先根据设计的纹理或图案制作相应的菲林片,然后通过菲林片曝光显影固化,来形成对对应纹理或图案的遮蔽。In this step, a mask is placed on the surface of the flat glass plate. According to an embodiment of the present application, the specific manner of providing the mask is not particularly limited. For example, the flat glass plate may be subjected to photosensitive ink printing, and the photosensitive ink is used to shield the flat glass plate region which is not required to be etched. Specifically, according to the embodiment of the present application, the corresponding film sheets can be first made according to the designed texture or pattern, and then cured by exposure and development of the film sheets to form a mask for the corresponding texture or pattern.
S20:将平面玻璃板设置有掩膜的一侧置于刻蚀液中S20: placing one side of the flat glass plate with the mask in the etching liquid
在该步骤中,将平面玻璃板设置有掩膜的一侧置于刻蚀液中,进行刻蚀。根据本申请的实施例,刻蚀液的种类和具体的刻蚀方式不受特别限制,只要能够在平面玻璃板上形成刻蚀纹理即可,例如,根据本申请的具体实施例,可以将印刷好遮蔽油墨的平面玻璃板浸入以氢氟酸为主的蚀刻溶液中进行蚀刻。In this step, one side of the flat glass plate provided with the mask is placed in the etching liquid for etching. According to the embodiment of the present application, the kind of the etching liquid and the specific etching manner are not particularly limited as long as the etching texture can be formed on the flat glass plate, for example, according to a specific embodiment of the present application, printing can be performed. The flat glass plate which shields the ink is immersed in an etching solution mainly composed of hydrofluoric acid for etching.
S30:去除掩膜S30: remove the mask
在该步骤中,去除掩膜,以便形成蚀刻后的第一纹理面。根据本申请的实施例,可以采用特定的弱碱性(浓度:1-5%)溶液去除遮蔽的油墨,由此,油墨遮蔽区域的平面玻璃板不被蚀刻,为通透光泽效果,经过蚀刻的平面玻璃板区域形成了第一纹理面,为雾面哑光效果。由此,第一纹理面和未刻蚀的平面玻璃板区域组成了第一层深度上及视觉上的纹理图案效果。根据本申请的具体实施例,该步骤形成的第一纹理面的光泽度可以为25-65,粗糙度可以为0.1-0.2,雾度可以为10%-20%,透过率可以不低于70%,反射率可以不小于10%。本领域技术人员可以根据想到达到的纹理效果来进行选择。根据本申请的实施例,第一纹理面的厚度可以为5微米~200微米。由此,所形成的第一纹理面具有精美的纹理效果,并且蚀刻后的平面玻璃板依然具有良好的机械强度。In this step, the mask is removed to form an etched first textured surface. According to an embodiment of the present application, a masked ink can be removed by using a specific weakly alkaline (concentration: 1-5%) solution, whereby the flat glass plate of the ink shielding region is not etched, is a transparent gloss effect, and is etched. The flat glass plate area forms the first textured surface, which is a matte matte effect. Thus, the first textured surface and the unetched planar glass panel region constitute a first layer of depth and a visual texture pattern effect. According to a specific embodiment of the present application, the first textured surface formed by the step may have a gloss of 25-65, a roughness of 0.1-0.2, a haze of 10%-20%, and a transmittance of not less than 70%, the reflectance can be no less than 10%. One skilled in the art can make a selection based on the texture effect that is expected to be achieved. According to an embodiment of the present application, the first textured surface may have a thickness of from 5 micrometers to 200 micrometers. Thereby, the formed first textured surface has a fine texture effect, and the etched flat glass sheet still has good mechanical strength.
根据本申请的实施例,上述制备曲面玻璃板材的方法中,第二处理可以为在经过第一处 理的平面玻璃板上设置图案层,图案层构成第二纹理面。根据本申请的实施例,图案层的具体制备方法不受特别限制,例如,根据本申请的实施例,图案层可以是通过紫外压印处理、热压印处理以及3D打印的至少之一形成的。具体的,可以为紫外压印形成图案层。根据本申请的实施例,图案层远离平面玻璃板的一侧可以具有条纹图案,条纹图案的宽度可以为0.01~1mm。由此,所述条纹图案的宽度有利于制备更加精细的图案,实现更加精美的纹理效果。According to an embodiment of the present application, in the above method of preparing a curved glass sheet, the second treatment may be to provide a pattern layer on the flat glass plate subjected to the first treatment, and the pattern layer constitutes the second texture surface. According to an embodiment of the present application, a specific preparation method of the pattern layer is not particularly limited. For example, according to an embodiment of the present application, the pattern layer may be formed by at least one of an ultraviolet imprint process, a hot imprint process, and 3D printing. . Specifically, the patterned layer can be formed by ultraviolet imprinting. According to an embodiment of the present application, the side of the pattern layer away from the flat glass plate may have a stripe pattern, and the stripe pattern may have a width of 0.01 to 1 mm. Thereby, the width of the stripe pattern is advantageous for preparing a finer pattern and achieving a more delicate texture effect.
根据本申请的另一个具体实施例,上述制备曲面玻璃板材的方法中,第一处理可以为在平面玻璃板上设置图案层,图案层构成所述第一纹理面,随后对第一纹理面进行第二处理,形成第二纹理面。According to another embodiment of the present application, in the above method for preparing a curved glass sheet, the first processing may be to provide a pattern layer on the flat glass plate, the pattern layer constitutes the first texture surface, and then the first texture surface is performed. The second process forms a second textured surface.
根据本申请的实施例,图案层可以是通过紫外压印处理、热压印处理以及3D打印的至少之一形成的。根据本申请的实施例,图案层远离平面玻璃板的一侧可以具有条纹图案,条纹图案的宽度可以为0.01~1mm。根据本申请的实施例,第二纹理面是通过对第一纹理面进行第二处理而形成的。也即是说,第二处理是在与第一纹理面相同区域的平面玻璃板上进行的。由此,可以在平面玻璃板的相同区域形成不同层次或不同图案的纹理效果。根据本申请的实施例,第二处理包括干法刻蚀以及湿法刻蚀的至少之一,例如,根据本申请的具体实施例,第二处理可以为激光镭雕处理,可以采用紫外型激光镭雕设备,所采用的激光光源可以为紫外光,刻蚀功率可以为5-10W。根据本申请的实施例,干法刻蚀的刻蚀深度为0.01-1mm。由此,该刻蚀深度的范围较广,有利于形成不同深度的纹理,并且能保证刻蚀后的平面玻璃板仍然具有较好的机械强度。在本实施方案中,第二处理为针对第一处理形成的图案层(第一纹理面)而进行的,因此,第二处理中的刻蚀处理,不会影响平面玻璃板的机械强度。According to an embodiment of the present application, the pattern layer may be formed by at least one of an ultraviolet imprint process, a hot imprint process, and 3D printing. According to an embodiment of the present application, the side of the pattern layer away from the flat glass plate may have a stripe pattern, and the stripe pattern may have a width of 0.01 to 1 mm. According to an embodiment of the present application, the second textured surface is formed by performing a second treatment on the first textured surface. That is to say, the second process is performed on a flat glass plate of the same area as the first textured surface. Thereby, texture effects of different levels or different patterns can be formed in the same area of the flat glass plate. According to an embodiment of the present application, the second process includes at least one of dry etching and wet etching. For example, according to a specific embodiment of the present application, the second process may be laser laser engraving, and an ultraviolet laser may be used. For the laser engraving equipment, the laser source used may be ultraviolet light, and the etching power may be 5-10W. According to an embodiment of the present application, the etching depth of the dry etching is 0.01-1 mm. Therefore, the etching depth is wide, which is favorable for forming textures of different depths, and can ensure that the planar glass plate after etching still has good mechanical strength. In the present embodiment, the second process is performed for the pattern layer (first texture surface) formed by the first process, and therefore, the etching process in the second process does not affect the mechanical strength of the flat glass plate.
综上所述,根据本申请的具体实施例,经过第一处理和第二处理后,可以在平面玻璃板上形成层次分明的立体纹理效果。In summary, according to a specific embodiment of the present application, after the first process and the second process, a hierarchical three-dimensional texture effect can be formed on the flat glass plate.
在本申请的另一方面,本申请提出了一种曲面玻璃板材。根据本申请的实施例,参考图8,该曲面玻璃板材包括:通过对平面玻璃板100进行弯折处理而形成的曲面20、设置在平面玻璃板100上的第一纹理面110以及第二纹理面120,其中,第一纹理面110以及第二纹理面120是分别独立地通过干法刻蚀、湿法刻蚀以及设置图案层的至少之一而形成的。In another aspect of the present application, the present application proposes a curved glass sheet. According to an embodiment of the present application, referring to FIG. 8, the curved glass sheet includes: a curved surface 20 formed by bending a flat glass sheet 100, a first textured surface 110 disposed on the flat glass sheet 100, and a second texture. The face 120, wherein the first textured surface 110 and the second textured surface 120 are formed by independently performing at least one of dry etching, wet etching, and providing a pattern layer.
根据本申请的实施例,该曲面玻璃板材可以是利用前面的方法制备的,由此,该曲面玻璃板材具有前面所述的制备曲面玻璃板材的方法制备的曲面玻璃板材所具有的全部特征以及优点,在此不再赘述。According to an embodiment of the present application, the curved glass plate may be prepared by the foregoing method, whereby the curved glass plate has all the features and advantages of the curved glass plate prepared by the method for preparing the curved glass plate described above. , will not repeat them here.
根据本申请的具体实施例,第一纹理面以及第二纹理面在平面玻璃板上的投影,可以完全不重合,可以有部分重合,也可以完全重合。也即是说,第一纹理面可以覆盖平面玻璃 板的部分表面,第二纹理面覆盖平面玻璃板未被第一纹理面覆盖的至少一部分区域。或者,第二纹理面覆盖第一纹理面的至少一部分区域。或者,第一纹理面覆盖平面玻璃板的部分表面,第二纹理面覆盖第一纹理面的至少部分区域,以及平面玻璃板上未被第一纹理面覆盖的区域。According to a specific embodiment of the present application, the projections of the first textured surface and the second textured surface on the flat glass plate may not overlap at all, may partially overlap, or may completely overlap. That is, the first textured surface may cover a portion of the surface of the planar glass sheet, and the second textured surface covers at least a portion of the planar glass sheet that is not covered by the first textured surface. Alternatively, the second textured surface covers at least a portion of the first textured surface. Alternatively, the first textured surface covers a portion of the surface of the planar glass sheet, the second textured surface covers at least a portion of the first textured surface, and the region of the planar glass sheet that is not covered by the first textured surface.
根据本申请的实施例,由干法刻蚀形成第一纹理面时,干法刻蚀的刻蚀深度可以为0.01-1mm。由设置图案层形成第一纹理面时,在图案层远离平面玻璃板的一侧可以具有条纹图案,条纹图案的宽度可以为0.01~1mm。由湿法刻蚀形成第一纹理面时,第一纹理面的光泽度可以为25~65,粗糙度可以为0.1-0.2,雾度可以为10%-20%,透过率可不低于70%,反射率不小于10%,第一纹理面的厚度可以为5微米~200微米。According to an embodiment of the present application, when the first textured surface is formed by dry etching, the etching depth of the dry etching may be 0.01-1 mm. When the first textured surface is formed by providing the pattern layer, a stripe pattern may be provided on a side of the pattern layer away from the flat glass sheet, and the stripe pattern may have a width of 0.01 to 1 mm. When the first textured surface is formed by wet etching, the first textured surface may have a gloss of 25 to 65, a roughness of 0.1-0.2, a haze of 10%-20%, and a transmittance of not less than 70. %, the reflectance is not less than 10%, and the thickness of the first textured surface may be 5 micrometers to 200 micrometers.
需要说明的是,该曲面玻璃板材所具有的曲面的具体位置不受特别限制,本领域技术人员可以根据实际情况进行设计。如图8所示,该曲面玻璃板材可以在板材的边缘处,具有多个(如两个或四个)曲面;或者,该曲面玻璃板材的上表面可以整体为一个曲面。It should be noted that the specific position of the curved surface of the curved glass plate is not particularly limited, and those skilled in the art can design according to actual conditions. As shown in FIG. 8, the curved glass sheet may have a plurality of (eg, two or four) curved surfaces at the edge of the sheet; or the upper surface of the curved glass sheet may have a curved surface as a whole.
在本申请的又一方面,本申请提出了一种电子设备。根据本申请的实施例,参考图9,该电子设备1000包括:本体;以及壳体200,该壳体200的至少一部分是前面所述的曲面玻璃板材制成的。该电子设备1000具有前面所述的曲面玻璃板材所具有的全部特征以及优点,在此不再赘述。In yet another aspect of the present application, the present application proposes an electronic device. According to an embodiment of the present application, referring to FIG. 9, the electronic device 1000 includes: a body; and a housing 200, at least a portion of which is made of a curved glass sheet as described above. The electronic device 1000 has all the features and advantages of the curved glass plate described above, and will not be described herein.
以上详细描述了本申请的实施方式,但是,本申请并不限于上述实施方式中的具体细节,在本申请的技术构思范围内,可以对本申请的技术方案进行多种简单变型,这些简单变型均属于本申请的保护范围。The embodiments of the present application have been described in detail above. However, the present application is not limited to the specific details in the foregoing embodiments. Various simple modifications may be made to the technical solutions of the present application within the technical concept of the present application. It belongs to the scope of protection of this application.
另外需要说明的是,在上述具体实施方式中所描述的各个具体技术特征,在不矛盾的情况下,可以通过任何合适的方式进行组合。It should be further noted that the specific technical features described in the above specific embodiments may be combined in any suitable manner without contradiction.
此外,本申请的各种不同的实施方式之间也可以进行任意组合,只要其不违背本申请的思想,其同样应当视为本申请所公开的内容。In addition, any combination of various embodiments of the present application may be made as long as it does not contradict the idea of the present application, and it should also be regarded as the content disclosed in the present application.
在本申请的描述中,需要理解的是,术语“上”、“下”、“前”、“后”、“顶”、“底”、“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本申请和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本申请的限制。In the description of the present application, it is to be understood that the orientations or positions of the terms "upper", "lower", "front", "back", "top", "bottom", "inner", "outside", etc. are understood. The relationship is based on the orientation or positional relationship shown in the drawings, and is merely for the convenience of the description and the simplified description, and is not intended to indicate or imply that the device or component referred to has a specific orientation, and is constructed and operated in a specific orientation. It is not to be construed as limiting the application.

Claims (21)

  1. 一种制备曲面玻璃板材的方法,包括:A method of preparing a curved glass sheet, comprising:
    对平面玻璃板进行第一处理,在所述平面玻璃板上形成第一纹理面;Performing a first treatment on the flat glass plate to form a first textured surface on the flat glass plate;
    对经过所述第一处理的所述平面玻璃板进行第二处理,形成第二纹理面;Performing a second treatment on the planar glass sheet subjected to the first treatment to form a second textured surface;
    对经过所述第二处理的所述平面玻璃板进行弯折处理,在所述平面玻璃板上形成曲面,Performing a bending process on the flat glass plate subjected to the second treatment to form a curved surface on the flat glass plate,
    所述第一处理以及所述第二处理分别独立地选自干法刻蚀、湿法刻蚀以及设置图案层。The first process and the second process are each independently selected from the group consisting of dry etching, wet etching, and patterning layers.
  2. 根据权利要求1所述的方法,所述第一纹理面覆盖所述平面玻璃板的部分表面,对所述平面玻璃板未被所述第一纹理面覆盖的至少一部分区域进行所述第二处理,形成所述第二纹理面。The method according to claim 1, wherein the first textured surface covers a portion of a surface of the planar glass sheet, and the second treatment is performed on at least a portion of the planar glass sheet that is not covered by the first textured surface Forming the second textured surface.
  3. 根据权利要求1所述的方法,所述第二纹理面是通过对所述第一纹理面进行所述第二处理而形成的。The method of claim 1 wherein said second textured surface is formed by said second processing of said first textured surface.
  4. 根据权利要求1所述的方法,所述第一纹理面覆盖所述平面玻璃板的部分表面,对所述平面玻璃板未被所述第一纹理面覆盖的至少一部分区域,以及所述第一纹理面的至少一部分区域进行所述第二处理,形成所述第二纹理面。The method of claim 1, the first textured surface covering a portion of a surface of the planar glass sheet, at least a portion of the planar glass sheet not covered by the first textured surface, and the first At least a portion of the textured surface is subjected to the second process to form the second textured surface.
  5. 根据权利要求1所述的方法,所述干法刻蚀包括激光镭雕处理、等离子体刻蚀处理以及光刻处理的至少之一。The method according to claim 1, wherein the dry etching comprises at least one of a laser laser etching process, a plasma etching process, and a photolithography process.
  6. 根据权利要求5所述的方法,所述干法刻蚀的刻蚀深度为0.01-1mm。The method according to claim 5, wherein the dry etching has an etching depth of 0.01 to 1 mm.
  7. 根据权利要求6所述的方法,所述干法刻蚀为所述激光镭雕处理,激光光源为紫外光,刻蚀功率为5-10W。The method according to claim 6, wherein the dry etching is the laser laser engraving process, and the laser light source is ultraviolet light, and the etching power is 5-10W.
  8. 根据权利要求1所述的方法,所述设置图案层是通过紫外压印处理、热压印处理以及3D打印的至少之一实现的。The method according to claim 1, wherein the setting of the pattern layer is achieved by at least one of an ultraviolet imprint process, a hot imprint process, and 3D printing.
  9. 根据权利要求8所述的方法,所述图案层远离所述平面玻璃板的一侧具有条纹图案,所述条纹图案的宽度为0.01~1mm。The method according to claim 8, wherein a side of the pattern layer away from the flat glass plate has a stripe pattern, and the stripe pattern has a width of 0.01 to 1 mm.
  10. 根据权利要求1所述的方法,所述第一处理包括干法刻蚀以及湿法刻蚀的至少之一,所述第一纹理面形成在所述平面玻璃板的表面;The method of claim 1, the first processing comprising at least one of dry etching and wet etching, the first textured surface being formed on a surface of the planar glass sheet;
    所述第二处理为在经过所述第一处理的所述平面玻璃板上设置图案层,所述图案层构成所述第二纹理面。The second process is to provide a pattern layer on the flat glass plate subjected to the first process, and the pattern layer constitutes the second texture surface.
  11. 根据权利要求10所述的方法,所述第一处理为湿法刻蚀,所述湿法刻蚀包括:The method according to claim 10, wherein the first process is a wet etch, and the wet etch comprises:
    在所述平面玻璃板表面设置掩膜;Providing a mask on the surface of the flat glass plate;
    将所述平面玻璃板设置有所述掩膜的一侧置于刻蚀液中;以及Locating the side of the planar glass plate with the mask in an etching solution;
    去除所述掩膜。The mask is removed.
  12. 根据权利要求11所述的方法,所述第一纹理面的光泽度为25-65,粗糙度为0.1-0.2,雾度为10%-20%,透过率不低于70%,反射率不小于10%。The method according to claim 11, wherein the first textured surface has a gloss of 25-65, a roughness of 0.1-0.2, a haze of 10%-20%, a transmittance of not less than 70%, and a reflectance. Not less than 10%.
  13. 根据权利要求11所述的方法,所述第一纹理面的厚度为5微米~200微米。The method of claim 11 wherein said first textured surface has a thickness of from 5 microns to 200 microns.
  14. 根据权利要求10所述的方法,所述图案层是通过紫外压印处理、热压印处理以及3D打印的至少之一形成的,所述图案层远离所述平面玻璃板的一侧具有条纹图案,所述条纹图案的宽度为0.01~1mm。The method according to claim 10, wherein the pattern layer is formed by at least one of an ultraviolet imprint process, a hot imprint process, and a 3D printing, the pattern layer having a stripe pattern on a side away from the flat glass plate The stripe pattern has a width of 0.01 to 1 mm.
  15. 根据权利要求1所述的方法,所述第一处理为在所述平面玻璃板上设置图案层,所述图案层构成所述第一纹理面;The method according to claim 1, wherein the first processing is to provide a pattern layer on the flat glass plate, the pattern layer constituting the first texture surface;
    所述第二处理包括干法刻蚀以及湿法刻蚀的至少之一,所述第二纹理面是通过对所述第一纹理面进行所述第二处理而形成的。The second process includes at least one of dry etching and wet etching, the second textured surface being formed by performing the second processing on the first textured surface.
  16. 根据权利要求1所述的方法,进一步包括:The method of claim 1 further comprising:
    对形成有所述曲面的所述平面玻璃板进行光学镀膜处理;以及Performing an optical coating process on the planar glass plate on which the curved surface is formed;
    对经过所述光学镀膜处理的所述平面玻璃板进行喷墨着色处理。The flat glass plate subjected to the optical coating treatment is subjected to an inkjet coloring treatment.
  17. 一种曲面玻璃板材,包括:A curved glass sheet comprising:
    通过对平面玻璃板进行弯折处理而形成的曲面;a curved surface formed by bending a flat glass plate;
    第一纹理面,所述第一纹理面设置在所述平面玻璃板上;以及a first textured surface, the first textured surface being disposed on the planar glass sheet;
    第二纹理面,所述第二纹理面设置在所述平面玻璃板上;a second textured surface, the second textured surface being disposed on the planar glass plate;
    其中,所述第一纹理面以及所述第二纹理面是分别独立地通过干法刻蚀、湿法刻蚀以及设置图案层的至少之一而形成的。The first textured surface and the second textured surface are respectively formed by dry etching, wet etching, and at least one of the patterned layers.
  18. 根据权利要求17所述的曲面玻璃板材,所述第一纹理面覆盖所述平面玻璃板的部分表面,所述第二纹理面的覆盖区域,与所述第一纹理面的覆盖区域之间互不重叠。The curved glass sheet according to claim 17, wherein the first textured surface covers a part of the surface of the flat glass sheet, and the covering area of the second textured surface is mutually opposed to the covering area of the first textured surface Do not overlap.
  19. 根据权利要求17所述的曲面玻璃板材,所述第二纹理面覆盖所述第一纹理面。The curved glass sheet of claim 17, wherein the second textured surface covers the first textured surface.
  20. 根据权利要求17所述的曲面玻璃板材,所述第一纹理面覆盖所述平面玻璃板的部分表面,对所述平面玻璃板未被所述第一纹理面覆盖的至少一部分区域,以及所述第一纹理面的至少一部分区域进行第二处理,形成所述第二纹理面。A curved glass sheet according to claim 17, wherein said first textured surface covers a portion of a surface of said planar glass sheet, said at least a portion of said planar glass sheet not covered by said first textured surface, and said At least a portion of the first textured surface is subjected to a second process to form the second textured surface.
  21. 一种电子设备,包括:An electronic device comprising:
    本体;以及Ontology;
    壳体,所述壳体的至少一部分是由权利要求1-16任一项所述的方法制备的曲面玻璃板材,或者权利要求17-20任一项所述的曲面玻璃板材制成的。A housing, at least a portion of which is made of a curved glass sheet prepared by the method of any of claims 1-16, or a curved glass sheet of any of claims 17-20.
PCT/CN2018/110400 2017-10-18 2018-10-16 Curved glass sheet and method for manufacturing same, and electronic device WO2019076291A1 (en)

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