WO2019075228A1 - Colorants et compositions leuco - Google Patents

Colorants et compositions leuco Download PDF

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Publication number
WO2019075228A1
WO2019075228A1 PCT/US2018/055453 US2018055453W WO2019075228A1 WO 2019075228 A1 WO2019075228 A1 WO 2019075228A1 US 2018055453 W US2018055453 W US 2018055453W WO 2019075228 A1 WO2019075228 A1 WO 2019075228A1
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WO
WIPO (PCT)
Prior art keywords
leuco
composition
group
moiety
alkyl
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Application number
PCT/US2018/055453
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English (en)
Inventor
Haihu Qin
Sanjeev K. DEY
Wesley A. Freund
Randy D. Petrea
Gregory S. Miracle
Original Assignee
Milliken & Company
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Publication date
Application filed by Milliken & Company filed Critical Milliken & Company
Priority to JP2020520510A priority Critical patent/JP2020537011A/ja
Priority to BR112020006940-0A priority patent/BR112020006940A2/pt
Priority to EP18793155.5A priority patent/EP3694923A1/fr
Priority to CN201880080140.0A priority patent/CN111479878A/zh
Publication of WO2019075228A1 publication Critical patent/WO2019075228A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B11/00—Diaryl- or thriarylmethane dyes
    • C09B11/04—Diaryl- or thriarylmethane dyes derived from triarylmethanes, i.e. central C-atom is substituted by amino, cyano, alkyl
    • C09B11/10—Amino derivatives of triarylmethanes
    • C09B11/12—Amino derivatives of triarylmethanes without any OH group bound to an aryl nucleus
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B69/00—Dyes not provided for by a single group of this subclass
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707—Polyethers, e.g. polyalkyleneoxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C11D3/42—Brightening agents ; Blueing agents

Definitions

  • This application describes leuco compositions, laundry care compositions containing such leuco compositions, and the use of such compositions in the laundering of textile articles.
  • These types of compositions are provided in a stable, substantially colorless state and then may be transformed to an intense colored state upon exposure to certain physical or chemical changes such as, for example, exposure to oxygen, ion addition, exposure to light, and the like.
  • the laundry care compositions containing the leuco compounds are designed to enhance the apparent or visually perceived whiteness of, or to impart a desired hue to, textile articles washed or otherwise treated with the laundry care composition.
  • Leuco dyes are also known in the prior art to exhibit a change from a colorless or slightly colored state to a colored state upon exposure to specific chemical or physical triggers. The change in coloration that occurs is typically visually perceptible to the human eye. Many of these compounds have some absorbance in the visible light region (400-750 nm), and thus more or less have some color. In this invention, a dye is considered as a "leuco dye” if it did not render a significant color at its application concentration and conditions, but renders a significant color in its triggered form.
  • the color change upon triggering stems from the change of the molar attenuation coefficient (also known as molar extinction coefficient, molar absorption coefficient, and/or molar absorptivity in some literatures) of the leuco dye molecule in the 400-750 nm range, preferably in the 500-650 nm range, and most preferably in the 530-620 nm range.
  • the increase of the molar attenuation coefficient of a leuco dye before and after the triggering should be greater than 50%, more preferably greater than 200%, and most preferably greater than 500%.
  • Leuco compounds can be used as whitening agents in laundry care compositions (e.g., laundry detergents).
  • laundry care compositions e.g., laundry detergents
  • the addition of the leuco compound, which is an uncolored or only lightly colored state does not significantly affect the aesthetics of the laundry care composition.
  • the leuco compound can be converted to a colored state in which it imparts the desired whitening benefit to the textile substrate.
  • leuco colorants While many leuco colorants display a bias for depositing on consumer- sourced, aged cotton garments over new, clean cotton, we have found that substitution of certain ethoxylated derivatives of TAM dyes with propoxylate groups results in an improved bias. These leuco colorants with both EO and PO oxyalkylene groups display a larger bias than do the leuco colorants with only EO oxyalkylene units.
  • the inventive leuco colorants are thus better able to deliver whitening benefit where it is needed, and avoid hueing new, clean cotton garments where such hueing might well be considered undesirable.
  • the invention provides a leuco composition comprising at least one leuco compound, the leuco compound comprising a leuco moiety and a alkyleneoxy moiety covalently bound to the leuco moiety, wherein the alkyleneoxy moiety comprises at least one ethylene oxide group and at least one propylene oxide group.
  • the invention provides a laundry care composition comprising (a) at least one laundry care ingredient and (b) a leuco composition as described above.
  • the invention provides a method of treating a textile comprising the steps of (a) providing the laundry care composition as described herein; (b) adding the laundry care composition to a liquid medium; (c) placing textile articles in the liquid medium; (d) optionally, rinsing the textile; and (e) drying the textile articles
  • the invention provides a laundry care composition comprising a laundry care ingredient and a leuco composition as described herein.
  • the invention provides a laundry care composition comprising: (i) from 2 to 70 wt.% of a surfactant; and (ii) from 0.0001 to 20.0 wt.% of a leuco composition as described herein.
  • the invention provides a method of treating a textile comprises the steps of (a) providing a laundry care composition comprising a leuco composition as described herein, (b) adding the laundry care composition to a liquid medium; (c) placing textile articles in the liquid medium; (d) optionally, rinsing the textile, and (e) drying the textile.
  • alkoxy is intended to include Ci-Cs alkoxy and alkoxy derivatives of polyols having repeating units such as butylene oxide, glycidol oxide, ethylene oxide or propylene oxide.
  • alkyleneoxy and “oxyalkylene,” and the interchangeable terms “polyalkyleneoxy” and “polyoxyalkylene,” generally refer to molecular structures containing one or more than one, respectively, of the following repeating units: -C2H4O - , -C3H6O- , -C4H8O-, and any combinations thereof.
  • Non-limiting structures corresponding to these groups include -CH2CH2O- , -CH2CH2CH2O- , - CH2CH2CH2CH2O - , -CH 2 CH(CH 3 )0-, and -CH2CH(CH2CH 3 )0, for example.
  • the polyoxyalkylene constituent may be selected from the group consisting of one or more monomers selected from a C2-20 alkyleneoxy group, a glycidyl group, or mixtures thereof.
  • ethylene oxide "propylene oxide” and “butylene oxide” may be shown herein by their typical designation of “EO,” “PO” and “BO,” respectively.
  • alkyl and “alkyl capped” are intended to mean any univalent group formed by removing a hydrogen atom from a substituted or unsubstituted hydrocarbon.
  • Non- limiting examples include hydrocarbyl moieties which are branched or unbranched, substituted or unsubstituted including Ci-Cis alkyl groups, and in one aspect, Ci-C 6 alkyl groups.
  • aryl is intended to include C3-C12 aryl groups.
  • aryl refers to both carbocyclic and heterocyclic aryl groups.
  • alkaryl refers to any alkyl-substituted aryl substituents and aryl- substituted alkyl substituents. More specifically, the term is intended to refer to C7-16 alkyl- substituted aryl substituents and C7-16 aryl substituted alkyl substituents which may or may not comprise additional substituents.
  • detergent composition is a sub-set of laundry care composition and includes cleaning compositions including but not limited to products for laundering fabrics. Such compositions may be pre-treatment composition for use prior to a washing step or may be rinse added compositions, as well as cleaning auxiliaries, such as bleach additives and "stain-stick” or pre-treat types.
  • laundry care composition includes, unless otherwise indicated, granular, powder, liquid, gel, paste, unit dose, bar form and/or flake type washing agents and/or fabric treatment compositions, including but not limited to products for laundering fabrics, fabric softening compositions, fabric enhancing compositions, fabric freshening compositions, and other products for the care and maintenance of fabrics, and combinations thereof.
  • Such compositions may be pre-treatment compositions for use prior to a washing step or may be rinse added compositions, as well as cleaning auxiliaries, such as bleach additives and/or "stain-stick” or pre- treat compositions or substrate-laden products such as dryer added sheets.
  • leuco refers to an entity (e.g., organic compound or portion thereof) that, upon exposure to specific chemical or physical triggers, undergoes one or more chemical and/or physical changes that results in a shift from a first color state (e.g., uncolored or substantially colorless) to a second more highly colored state.
  • Suitable chemical or physical triggers include, but are not limited to, oxidation, pH change, temperature change, and changes in electromagnetic radiation (e.g., light) exposure.
  • Suitable chemical or physical changes that occur in the leuco entity include, but are not limited to, oxidation and non-oxidative changes, such as intramolecular cyclization.
  • a suitable leuco entity can be a reversibly reduced form of a chromophore.
  • the leuco moiety preferably comprises at least a first and a second ⁇ -system capable of being converted into a third combined conjugated ⁇ -system incorporating said first and second ⁇ -systems upon exposure to one or more of the chemical and/or physical triggers described above.
  • leuco composition or “leuco colorant composition” refers to a composition comprising at least two leuco compounds having independently selected structures as described in further detail herein.
  • average molecular weight of the leuco colorant is reported as a weight average molecular weight, as determined by its molecular weight distribution: as a consequence of their manufacturing process, the leuco colorants disclosed herein may contain a distribution of repeating units in their polymeric moiety.
  • maximum extinction coefficient and “maximum molar extinction coefficient” are intended to describe the molar extinction coefficient at the wavelength of maximum absorption (also referred to herein as the maximum wavelength), in the range of 400 nanometers to 750 nanometers.
  • first color is used to refer to the color of the laundry care composition before triggering, and is intended to include any color, including colorless and substantially colorless.
  • second color is used to refer to the color of the laundry care composition after triggering, and is intended to include any color that is distinguishable, either through visual inspection or the use of analytical techniques such as spectrophotometric analysis, from the first color of the laundry care composition.
  • converting agent refers to any oxidizing agent as known in the art other than molecular oxygen in any of its known forms (singlet and triplet states).
  • triggering agent refers to a reactant suitable for converting the leuco composition from a colorless or substantially colorless state to a colored state.
  • whitening agent refers to a dye or a leuco colorant that may form a dye once triggered that when on white cotton provides a hue to the cloth with a relative hue angle of 210 to 345, or even a relative hue angle of 240 to 320, or even a relative hue angle of 250 to 300 (e.g., 250 to 290).
  • cellulosic substrates are intended to include any substrate which comprises at least a majority by weight of cellulose.
  • Cellulose may be found in wood, cotton, linen, jute, and hemp.
  • Cellulosic substrates may be in the form of powders, fibers, pulp and articles formed from powders, fibers and pulp.
  • Cellulosic fibers include, without limitation, cotton, rayon (regenerated cellulose), acetate (cellulose acetate), triacetate (cellulose triacetate), and mixtures thereof.
  • Articles formed from cellulosic fibers include textile articles such as fabrics.
  • Articles formed from pulp include paper.
  • solid includes granular, powder, bar and tablet product forms.
  • fluid includes liquid, gel, paste and gas product forms.
  • test methods disclosed in the Test Methods Section of the present application should be used to determine the respective values of the parameters of Applicants' inventions.
  • component or composition levels are in reference to the active portion of that component or composition, and are exclusive of impurities, for example, residual solvents or by-products, which may be present in commercially available sources of such components or compositions.
  • the molar extinction coefficient of said second colored state at the maximum absorbance in the wavelength in the range 200 to 1,000 nm (more preferably 400 to 750 nm) is preferably at least five times, more preferably 10 times, even more preferably 25 times, most preferably at least 50 times the molar extinction coefficient of said first color state at the wavelength of the maximum absorbance of the second colored state.
  • the molar extinction coefficient of said second colored state at the maximum absorbance in the wavelength in the range 200 to 1,000 nm (more preferably 400 to 750 nm) is at least five times, preferably 10 times, even more preferably 25 times, most preferably at least 50 times the maximum molar extinction coefficient of said first color state in the corresponding wavelength range.
  • the first color state may have a maximum molar extinction coefficient in the wavelength range from 400 to 750 nm of as little as 10 M ⁇ cm "1
  • the second colored state may have a maximum molar extinction coefficient in the wavelength range from 400 to 750 nm of as much as 80,000 M ⁇ cm "1 or more, in which case the ratio of the extinction coefficients would be 8,000: 1 or more.
  • the maximum molar extinction coefficient of said first color state at a wavelength in the range 400 to 750 nm is less than 1000 M ⁇ cm "1
  • the maximum molar extinction coefficient of said second colored state at a wavelength in the range 400 to 750 nm is more than 5,000 M ' 1 , preferably more than 10,000, 25,000, 50,000 or even 100,000 M ' 1 .
  • a polymer comprising more than one leuco moiety may have a significantly higher maximum molar extinction coefficient in the first color state (e.g., due to the additive effect of a multiplicity of leuco moieties or the presence of one or more leuco moieties converted to the second colored state).
  • the present invention relates to a class of leuco colorants that may be useful for use in laundry care compositions, such as liquid laundry detergent, to provide a blue hue to whiten textile substrates.
  • Leuco colorants are compounds that are essentially colorless or only lightly colored but are capable of developing an intense color upon activation.
  • One advantage of using leuco compounds in laundry care compositions is that such compounds, being colorless until activated, allow the laundry care composition to exhibit its own color.
  • the leuco colorant generally does not alter the primary color of the laundry care composition.
  • manufacturers of such compositions can formulate a color that is most attractive to consumers without concern for added ingredients, such as bluing agents, affecting the final color value of the composition.
  • the range of textile articles encountered in the consumer home is quite large and often comprises garments constructed from a wide variety of both natural and synthetic fibers, as well as mixtures of these either in the same wash load or even in the same garment.
  • the articles can be constructed in a variety of ways and may comprise any of a vast array of finishes that may be applied by the manufacturer.
  • the amount of any such finish remaining on a consumer's textile article depends on a wide array of factors among which are the durability of the finish under the particular washing conditions employed by the consumer, the particular detergents and additives the consumer may have used as well as the number of cycles that the article has been washed.
  • finishes may be present to varying degrees or essentially absent, while other materials present in the wash or rinse cycles and contaminants encountered during wearing may start to accumulate on the article.
  • any detergent formulation used by consumers will encounter textile articles that represent the full range of possibilities and expects that there not only may be, but in fact will be, significant differences in the way the formulation performs on some textiles articles as opposed to others. These differences can be found through routine experimentation.
  • the leuco colorants of the present invention have been found to increase the whiteness of consumer aged garments and also garments to which fabric enhancers have been applied, more than they increase the whiteness of new garments from which the finishes have been removed with successive washes.
  • formulations comprising such leuco colorants may be preferred over traditional formulations, even formulations containing conventional hueing agents, since newer garments typically have less of a yellowing issue whereas older consumer aged garments are more prone to have an issue with yellowing.
  • the leuco colorants of the instant invention have a bias for increasing the whiteness of aged garments over clean new garments that is larger than the bias displayed by many traditional hueing agents.
  • the invention provides a leuco composition comprising at least one leuco compound, the leuco compound comprising a leuco moiety and a alkyleneoxy moiety covalently bound to the leuco moiety, wherein the alkyleneoxy moiety comprises at least one ethylene oxide group and at least one propylene oxide group.
  • the leuco compound can comprise any suitable leuco moiety as defined above.
  • the leuco moiety preferably is selected from the group consisting diarylmethane leuco moieties, triarylmethane leuco moieties, oxazine moieties, thiazine moieties, hydroquinone moieties, and arylaminophenol moieties.
  • Suitable diarylmethane leuco moieties for use herein include, but are not limited to, univalent or polyvalent diarylmethylene moieties capable of forming a second colored state as described herein. Suitable examples include, but are not limited to, moieties derived from Michler' s methane, a diarylmethylene substituted with an -OH group (e.g., Michler' s hydrol) and ethers and esters thereof, a diarylmethylene substituted with a photocleavable group, such as a - CN group (bis(para-N,N-dimethyl)phenyl)acetonitrile), and similar such moieties.
  • a photocleavable group such as a - CN group (bis(para-N,N-dimethyl)phenyl)acetonitrile
  • the leuco moiety is a univalent or polyvalent moiety derived by removal of one or more hydrogen atoms from a structure of Formula (I), (II), (III), (IV), or (V) below
  • ratio of Formula I-V to its oxidized form is at least 1 : 19, 1 :9, or 1 :3, preferably at least 1: 1, more preferably at least 3: 1, most preferably at least 9: 1 or even 19: 1.
  • each individual R 0 , R m and R p group on each of rings A, B and C is independently selected from the group consisting of hydrogen, deuterium and R 5 ; each R 5 is independently selected from the group consisting of halogens, nitro, alkyl, substituted alkyl, aryl, substituted aryl, alkaryl, substituted alkaryl, — (CH2) n — O— R 1 , -(CHi ⁇ -NR ⁇ 2 , -C(0)R 1 , -C(0)OR 1 , -C(0)0 " , -C(0)NR 1 R 2 , -OC(0)R 1 , -OC(0)OR 1 , -OC(0)NR 1 R 2 , -S(0) 2 R 1 , -S(0) 2 OR 1 , -S(0) 2 Cr, -S(0) 2 NR 1 R 2 , -NR 1 C(0)R 2 , -NR 1 C(0)OR 2 , -NR 1 C(0)SR 2
  • R is positioned ortho or para to the bridging amine moiety and is selected from the group consisting of—OR 38 and— NR 36 R 37 , each R 36 and R 37 is independently selected from the group consisting of hydrogen, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups, acyl groups, R 4 , — C(0)OR 1 , — C(0)R 1 , and — C(0)NR 1 R 2 ; R 38 is selected from the group consisting of hydrogen, acyl groups, — C(0)OR 1 , — C(0)R 1 , and— C(0)NR 1 R 2 ; g and h are independently integers from 0 to 4; each R 31 and R 32 is independently selected from the group consisting of alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups, alkaryl, substituted alkaryl,— (CH2) n — O— R 1 ,— (CH2) n — NR R 2
  • X 40 is selected from the group consisting of an oxygen atom, a sulfur atom, and NR 45 ;
  • R 45 is independently selected from the group consisting of hydrogen, deuterium, alkyl, substituted alkyl, aryl, substituted aryl, alkaryl, substituted alkaryl, -S(0) 2 OH, -S(0) 2 0 " , -C(0)OR 1 , -C(0)R 1 , and -C(0)NR 1 R 2 ;
  • R 40 and R 41 are independently selected from the group consisting of— (CH 2 ) n — O— R 1 ,— (CH 2 ) n — NR R 2 , wherein the index n is an integer from 0 to 4, preferably from 0 to 1, most preferably 0; j and k are independently integers from 0 to 3;
  • R 42 and R 43 are independently selected from the group consisting of alkyl, substituted alkyl, aryl, substituted aryl, alkaryl, substitute
  • any charge present in any of the preceding groups is balanced with a suitable independently selected internal or external counterion.
  • Suitable independently selected external counterions may be cationic or anionic.
  • suitable cations include but are not limited to one or more metals preferably selected from Group I and Group II, the most preferred of these being Na, K, Mg, and Ca, or an organic cation such as iminium, ammonium, and phosphonium.
  • Suitable anions include but are not limited to: fluoride, chloride, bromide, iodide, perchlorate, hydrogen sulfate, sulfate, aminosulfate, nitrate, dihydrogen phosphate, hydrogen phosphate, phosphate, bicarbonate, carbonate, methosulfate, ethosulfate, cyanate, thiocyanate, tetrachlorozincate, borate, tetrafluoroborate, acetate, chloroacetate, cyanoacetate, hydroxyacetate, aminoacetate, methylaminoacetate, di- and tri- chloroacetate, 2-chloro-propionate, 2-hydroxypropionate, glycolate, thioglycolate, thioacetate, phenoxyacetate, trimethylacetate, valerate, palmitate, acrylate, oxalate, malonate, crotonate, succinate, citrate, methylene-bis-thioglycol
  • the leuco compound comprises an alkyleneoxy moiety in addition to the leuco moiety.
  • the alkyleneoxy moiety comprises at least one ethylene oxide group and at least one propylene oxide group.
  • the alkyleneoxy moiety comprises from 1 to about 20 ethylene oxide groups and from 1 to about 20 propylene oxide groups.
  • the different alkyleneoxy groups can be arranged in a block configuration or in a random configuration.
  • the alkyleneoxy groups of the alkyleneoxy moiety are arranged in a block configuration.
  • the alkyleneoxy moiety can be covalently bound to the leuco moiety through any suitable linking group.
  • the alkyleneoxy moiety is coavalently bound to the leuco moiety through a linking group selected from the group consisting of an oxygen atom and a nitrogen atom.
  • a linking group selected from the group consisting of an oxygen atom and a nitrogen atom.
  • the linking group is an oxygen atom
  • one valence of the oxygen atom is occupied by the alkyleneoxy moiety and the second valence of the oxygen atom is occupied by the remainder of the leuco moiety.
  • the linking group is a nitrogen atom
  • one valence of nitrogen atom is occupied by the remainder of the leuco moiety and one valence of the nitrogen atom is occupied by the alkyleneoxy moiety.
  • the alkyleneoxy moiety preferably is covalently bound to the leuco moiety through a nitrogen atom.
  • the nitrogen atom and the alkyleneoxy moiety together have the structure — NR 1 (C2H40)n(C3H60) q H, where n and q are independently selected from integers from 1 to 5, and R 1 is selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, alkaryl, substituted alkaryl, and alkyleneoxy moieties.
  • the leuco compound comprises two alkyleneoxy moieties, each alkyleneoxy moiety being covalently bound to the leuco moiety through a nitrogen atom, the nitrogen atom and the alkyleneoxy moieties together having the structure
  • n, q, r, and s are independently selected from integers from 0 to 5, the sum of n and r is from 2 to 10, and the sum of q and s is from 2 to 10. In a more particular aspect, the sum of n and r is from 2 to 5, and the sum of q and s is from 2 to 5.
  • the leuco compound contained in the composition can have any suitable structure possessing the characteristics described above.
  • the leuco compound conforms to a structure of Formula (CI), (CII), (CIII), (CIV), or (CV) below
  • ratio of Formula CI-CV to its oxidized form is at least 1: 19, 1 :9, or 1:3, preferably at least 1: 1, more preferably at least 3: 1, most preferably at least 9: 1 or even 19: 1.
  • each individual R 0 , R m and R p group on each of rings A, B and C is independently selected from the group consisting of hydrogen, deuterium and R 5 ; each R 5 is independently selected from the group consisting of halogens, nitro, alkyl, substituted alkyl, aryl, substituted aryl, alkaryl, substituted alkaryl,— (CH 2 ) n — O— R 1 ,— (CH 2 ) n — NR X R 2 ,— C(0)R 1 , -C(0)OR 1 , -C(0)0 " , -C(0)NR 1 R 2 , -OC(0)R 1 , -OC(0)OR 1 , -OC(0)NR 1 R 2 , -SCO)* 1 , -S(0) 2 OR 1 , -S(0) 2 0 " , -SiO ⁇ NR ⁇ 2 , -NR 1 C(0)R 2 , -NR 1 C(0)OR 2 , -NR
  • each R 20 and R 21 is independently selected from the group consisting of halogens, a nitro group, alkyl groups, substituted alkyl groups,— NC(0)OR 1 ,— NC(0)SR 1 ,—OR 1 , and— NR R 2 ; each R 25 is independently selected from the group consisting of monosaccharide moiety, disaccharide moiety, oligosaccharide moiety, and polysaccharide moiety, — C(0)R 1 , — C(0)OR 1 ,— C(0)NR 1 R 2 ; and each R 22 and R 23 is independently selected from the group consisting of hydrogen, alkyl groups, and substituted alkyl groups.
  • R is positioned ortho or para to the bridging amine moiety and is selected from the group consisting of—OR 38 and— NR 36 R 37 , each R 36 and R 37 is independently selected from the group consisting of hydrogen, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups, acyl groups, R 4 , — C(0)OR 1 , — C(0)R 1 , and — C(0)NR 1 R 2 ; R 38 is selected from the group consisting of hydrogen, acyl groups, — C(0)OR 1 , — C(0)R 1 , and— C(0)NR 1 R 2 ; g and h are independently integers from 0 to 4; each R 31 and R 32 is independently selected from the group consisting of alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups, alkaryl, substituted alkaryl,— (CH2) n — O— R 1 ,— (CH2) n — NR R
  • X 40 is selected from the group consisting of an oxygen atom, a sulfur atom, and NR 45 ;
  • R 45 is independently selected from the group consisting of hydrogen, deuterium, alkyl, substituted alkyl, aryl, substituted aryl, alkaryl, substituted alkaryl, -S(0) 2 OH, -S(0) 2 0 " , -C(0)OR 1 , -C(0)R 1 , and -C(0)NR 1 R 2 ;
  • R 42 and R 43 are independently selected from the group consisting of alkyl, substituted alkyl, aryl, substituted aryl, alkaryl, substitute
  • R 1 , R 2 , R 3 , and R 15 are independently selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, alkaryl, substituted alkaryl, and R 4 ; wherein R 4 is a organic group composed of one or more organic monomers with said monomer molecular weights ranging from 28 to 500, preferably 43 to 350, even more preferably 43 to 250, wherein the organic group may be substituted with one or more additional leuco colorant moieties conforming to the structure of Formula I- V.
  • R 4 is selected from the group consisting of alkyleneoxy (polyether), oxoalkyleneoxy (polyesters), oxoalkyleneamine (polyamides), epichlorohydrin, quaternized epichlorohydrin, alkyleneamine, hydroxyalkylene, acyloxyalkylene, carboxyalkylene, carboalkoxyalkylene, and sugar.
  • any leuco colorant comprises an R 4 group with three or more contiguous monomers, that leuco colorant is defined herein as a "polymeric leuco colorant”.
  • R 1 , R 2 and R 3 are independently selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, alkaryl, substituted alkaryl, and R 4 .
  • R 4 is an alkyleneoxy moiety as described above.
  • any charge present in any of the preceding groups is balanced with a suitable independently selected internal or external counterion.
  • Suitable independently selected external counterions may be cationic or anionic.
  • suitable cations include but are not limited to one or more metals preferably selected from Group I and Group II, the most preferred of these being Na, K, Mg, and Ca, or an organic cation such as iminium, ammonium, and phosphonium.
  • Suitable anions include but are not limited to: fluoride, chloride, bromide, iodide, perchlorate, hydrogen sulfate, sulfate, aminosulfate, nitrate, dihydrogen phosphate, hydrogen phosphate, phosphate, bicarbonate, carbonate, methosulfate, ethosulfate, cyanate, thiocyanate, tetrachlorozincate, borate, tetrafluoroborate, acetate, chloroacetate, cyanoacetate, hydroxyacetate, aminoacetate, methylaminoacetate, di- and tri- chloroacetate, 2-chloro-propionate, 2-hydroxypropionate, glycolate, thioglycolate, thioacetate, phenoxyacetate, trimethylacetate, valerate, palmitate, acrylate, oxalate, malonate, crotonate, succinate, citrate, methylene-bis-thioglycol
  • the leuco compound is a triarylmethane leuco compound of Formula
  • each individual R 0 , Rm and R p group on each of rings A, B and C is independently selected from the group consisting of hydrogen, deuterium and R 5 ; wherein each R 5 is independently selected from the group consisting of halogens, nitro, alkyl, substituted alkyl, aryl, substituted aryl, alkaryl, substituted alkaryl, -(CH 2 )n-0- R 1 , -(CH 2 ) compassion-NR 1 R 2 , -C(0)R 1 , -C(0)OR 1 , -C(0)0 " , -C(0)NR 1 R 2 , -OQC R 1 , -OCiOOR 1 , -OCCONR ⁇ 2 , -SCO)* 1 , -SCO ⁇ OR 1 , -S(0) 2 0 " , -SCO ⁇ NR ⁇ 2 , -NR 1 C(0)R 2 , -NR
  • preferred leuco compounds include those conforming to the structure of Formula (CVI),
  • each R 4 is independently selected from the group consisting of H, Methyl, Ethyl, ((CH2CH20)a(C3H60)b)H, and mixtures thereof; preferably at least one R 4 group is ((CH2CH20)a(C3H60)b)H; wherein each index a is independently an integer from 1-100, each index b is independently an integer from 0-50, and wherein the sum of all the independently selected a integers in all R 4 groups is no more than 100, and the sum of all the independently selected b integers in all R 4 groups is no more than 50.
  • at least two R 4 groups are selected from Methyl and Ethyl, most preferably at least one N in structure (CVI) is substituted with two R 4 groups selected from Methyl and Ethyl, preferably Methyl.
  • highly preferred leuco compounds include those conforming to the structure of Formula (CVII),
  • each index c is independently 0, 1 or 2, preferably each c is 0 or 1, more preferably the two independently selected values for c are identical; each R 4 is independently selected from the group consisting of H, Me, Et, ((CH2CH20) a (C3H60)b)H, and mixtures thereof; preferably each R 4 is ((CH2CH20) a (C3H60)b)H wherein each index a is independently an integer from 1-50, more preferably 1-25, even more preferably 1-20, 1-15, 1-10, 1-5 or even 1-2; each index b is independently an integer from 0-25, more preferably 0-15, even more preferably 1-5 or even 1-3 and wherein the sum of all the independently selected a integers in the leuco colorant is no more than 100, more preferably no more than 80, most preferably no more than 60, 40, 20, 10 or even no more than 5, and the sum of all the independently selected b integers in the leuco colorant is no more than 50,
  • each index c is 1, each R 4 is ((CH2CH20) a (C3H60)b)H, each index a is an integer from 1-5, each index b is an integer from 1-5, the sum of all the independently selected a integers in the leuco compound is from 4 to 10, and the sum of all the independently selected b integers in the leuco colorant is from 5 to 15.
  • highly preferred leuco compounds include those conforming to the structure of Formula (CVIII),
  • R 8 is H or CH 3 and each index b is independently on average about 1 to 2.
  • leuco colorants of the instant invention have a Surface Tension Value of greater than 45 niN/m, more preferably greater than 47.5 mN/m, most preferably greater than 50 mN/m.
  • the second colored state of the leuco colorant has a Surface Tension Value of greater than 45 mN/m, more preferably greater than 47.5 mN/m, most preferably greater than 50 mN/m.
  • both the leuco colorant and its corresponding second colored state have a Surface Tension Value of greater than 45 mN/m, more preferably greater than 47.5 mN/m, most preferably greater than 50 mN/m.
  • the leuco triarylmethane compounds described herein can be produced by any suitable synthetic method.
  • such compounds can be produced via an acid catalyzed condensation reaction between an aromatic aldehyde and an electron-rich aryl coupler (e.g., in an amount of approximately 2 molar equivalents of aryl coupler to 1 molar equivalent of aromatic aldehyde).
  • the aromatic aldehyde can be any suitable compound comprising an aromatic moiety (e.g., an aryl moiety, a substituted aryl moiety, a heteroaromatic moiety, or a substituted heteroaromatic moiety) having an aldehyde group covalently attached thereto.
  • the aromatic aldehyde preferably is a substituted benzaldehyde comprising, preferably in the para position relative to the aldehyde group, a group having the structure -OR 1 or -NR ⁇ 2 .
  • the aromatic aldehyde preferably is a substituted benzaldeyde comprising the group -NR R 2 in the para position relative to the aldehyde group, wherein R 1 and R 2 are selected from the group consisting of hydrogen, methyl, or ethyl (more preferably methyl).
  • the condensation reaction utilizes an aryl coupler in addition to the aromatic aldehyde.
  • the condensation reaction generally utilizes at least two molar equivalents of aryl coupler for each molar equivalent of aromatic aldehyde.
  • the two molar equivalents of aryl coupler utilized in the reaction can be provided using a single aryl coupler compound.
  • the reaction can be performed using two molar equivalents of a mixture of two or more distinct aryl couplers.
  • the two or more distinct aryl couplers can be used in any combination or relative ratios provided the mixture sums to at least about two molar equivalents of aryl couplers for each molar equivalent of aromatic aldehyde.
  • the two or more distinct aryl couplers can differ in terms of, for example, the number and/or nature of the substituents attached to the aryl moiety.
  • the reaction can utilize a first aryl coupler comprising a first oxyalkylene or polyoxyalkylene moiety having a first distribution of oxyalkylene groups and a second aryl coupler comprising a second oxyalkylene or polyoxyalkylene moiety having a second distribution of oxyalkylene groups that is different from the first distribution.
  • the first aryl coupler can comprise an oxyalkylene moiety consisting of ethylene oxide groups, such as AC-I below
  • the second aryl coupler can comprise a polyoxyalkylene moiety consisting of ethylene oxide groups and propylene oxide groups, such as AC-II below.
  • AC II wherein the indices a, b, c and d are independently selected from integers from 0 to 5; the sum of a and b for a coupler selected from AC-I and AC-II is from 2 to 10, and the sum of c and d in AC- II is from 2 to 10.
  • the sum of a and b for a coupler selected from AC- I and AC-II is from 2 to 5
  • the sum of c and d in AC-II is from 2 to 5.
  • the sum of the indices a and b in AC-I is 2 or 3; the sum of the indices a and b in AC-II is 2 or 3 and the sum of the indices c and d in AC-II is 1 to 5, preferably 2 to 4 or even 2 to 3.
  • the couplers AC- I and AC_II may be combined in any proportion provided the amount of the couplers used is sufficient to provide at least two molar equivalents relative to the equivalents of the aromatic aldehyde used in the acid-catalyzed condensation reaction that gives rise to the leuco compound.
  • one equivalent of para-N,N-dimethylbenzaldehyde is condensed with a mixture of at least two molar equivalents of the aryl couplers AC-I and AC-II shown above wherein for aryl coupler AC-I, the indices a and b sum to 2 or 3, preferably 2, and wherein preferably a and b are each 1; and wherein for aryl coupler AC-II, the indices a and b sum to 2 or 3, preferably 2, and wherein preferably a and b are each 1, and the indices c and d sum to an average of about 2.5 to 3.0, and wherein at least one of c or d is 1.
  • the expected products from such a reaction will include leuco compounds comprised of non-distinct couplers (for as many distinct couplers as are used) as well as cross coupled leuco compounds comprising mixtures of the aryl couplers employed.
  • the product distribution excluding any perturbations caused by differences in reactivity, will comprise approximately 25% of a leuco compound containing two A couplers, 25% of a leuco compound containing two B couplers, and 50% of a leuco compound containing one A and one B coupler.
  • Example leuco compositions may be prepared following the general process below, described for compositions where the aryl aldehyde conforms to Ar-C(0)H, but is readily adaptable.
  • a four-neck flask is equipped with an overhead stirrer, a condenser, a temperature controller, a heating mantle and a Nitrogen inlet. Then, about 2 moles of the aryl coupler or mixture of aryl couplers is added to the flask and heated to about 65-71 °C. During heating, about 1 mole of Ar-C(0)H and catalytic amount (about 0.4 mole) urea pre-dissolved in small amount of water are added. After the above chemicals are mixed, about 1.2 mole of hydrochloric acid (in form of Muriatic acid) is added drop wise to control the temperature below 90-100 °C. After the addition of hydrochloric acid, the reaction is stirred at 95-100 °C for about 7 hours.
  • hydrochloric acid in form of Muriatic acid
  • One method is to neutralize the reaction product to pH about 9 and remove the water by rotary evaporation under reduced pressure.
  • the resulting viscous material is diluted with an organic solvent such as isopropanol and filtered to remove the inorganic salts.
  • the organic solvent is evaporated and the final product is obtained.
  • the invention provides a leuco composition obtained from the following steps: (i) providing one molar equivalent of an aromatic aldehyde, (ii) providing approximately two molar equivalents of an aryl coupler or mixture of aryl couplers wherein at least one aryl coupler comprises a covalently bound oxyalkylene or polyoxyalkylene moiety, wherein the oxyalkylene or polyoxyalkylene moiety comprises at least one ethylene oxide group and at least one propylene oxide group, (iii) combining said aromatic aldehyde and aryl coupler(s) in a suitable reaction vessel, (iv) adding between 0.01 and 0.5 equivalents of urea, (v) adding muriatic acid to achieve a pH of between about 0 and 3, (vi) heating the mixture between 60 to 120 °C for between 2 to 12 hours, (vii) adjusting the pH to at least about 7, and (viii) separating at least a portion of the salts formed upon neutralization from the liquid product;
  • said leuco composition comprises at least one leuco compound, the leuco compound comprising a leuco moiety and a alkyleneoxy moiety covalently bound to the leuco moiety, wherein the alkyleneoxy moiety comprises at least one ethylene oxide group and at least one propylene oxide group.
  • the leuco compound has the structure of Formula (CVII) above, wherein at least one independently selected index b has a value of at least 1.
  • the amount of leuco colorant used in the laundry care compositions of the present invention may be any level suitable to achieve an increase in the whiteness index (WI CIE) of white fabrics or textile articles.
  • the laundry care composition comprises leuco colorant in an amount from about 0.0001 wt% to about 1.0 wt%, preferably from 0.0005 wt% to about 0.5 wt%, even more preferably from about 0.0008 wt% to about 0.2 wt%, most preferably from 0.004 wt% to about 0.1 wt%.
  • the laundry care composition comprises leuco colorant in an amount from 0.0025 to 5.0 milliequivalents/kg, preferably from 0.005 to 2.5 milliequivalents/kg, even more preferably from 0.01 to 1.0 milliequivalents/kg, most preferably from 0.05 to 0.50 milliequivalents/kg, wherein the units of milliequivalents/kg refer to the milliequivalents of leuco moiety per kg of the laundry composition.
  • the number of milliequivalents is related to the number of millimoles of the leuco colorant by the following equation: (millimoles of leuco colorant) x (no.
  • milliequivalents of leuco moiety/millimole of leuco colorant milliequivalents of leuco moiety.
  • the leuco composition of the invention can comprise other compounds in addition to the leuco compound(s), antioxidant compound(s), and solvents(s) discussed above.
  • the leuco composition can contains up to about 2 wt.% salts such as sodium chloride or sodium sulfate, unreacted starting materials used in making the leuco compound(s), impurities resulting from side reactions of those starting materials, and degradation products of the leuco compounds or such impurities.
  • Specific non-limiting examples of such materials include compounds of Formula (DI) - (DV)
  • R and R are independently selected from the group consisting of hydrogen, alkyl (e.g., methyl), and oxyalkylene groups.
  • the oxyalkylene groups can contain any suitable number of oxyalkylene repeat units (e.g., ethylene oxide and/or propylene oxide), such as the ranges disclosed above for the leuco compounds present in the leuco composition.
  • the groups R 101 and R 102 can be combined to form a group having the structure— CH 2 CH 2 — O— CH 2 CH 2 — , which together with the nitrogen atom forms a morpholine ring.
  • Other compounds that may be present in the leuco composition include compounds of Formula (DVI) - (DIX)
  • Each aryl moiety of the compounds of Formula (DVI) - (DIX) can be independently unsubstituted or substituted, typically in the para position, with a nitro group or a group having the structure — NR 101 R 102 , with R 101 and R 102 being independently selected from the group described above.
  • Additional compounds that can be present in the leuco composition include phenols and amino phenols containing, typically in the para position relative to the hydroxy group, a group having the structure — NR 101 R 102 , with R 101 and R 102 being independently selected from the group described above.
  • the leuco composition can also contain compounds of Formula (DX) and (DXI)
  • the aryl moieties and the cyclohexadienyl moieties can be unsubstituted or substituted, typically in the para position, with a nitro group or a group having the structure — NR 101 R 102 , with R 101 and R 102 being independently selected from the group described above.
  • the leuco composition can also contain condensation products of some of the compounds described above, such as a compound of Formula (DXII)
  • the leuco composition can also contain the colored (e.g., oxidized) form of the leuco compound(s) present in the composition.
  • the oxidized form of the triarylmethane leuco colorant (which contains a central carbocation) can form an adduct with anions present in the leuco composition, such as the anions described above as suitable charge-balancing counterions for the leuco compound(s).
  • the unreacted starting materials and impurities described above can be present in the leuco composition in any suitable amount.
  • these materials and impurities are present in the leuco composition in a relatively minor amount which does not adversely affect the performance of the leuco colorant(s) to any material degree.
  • Excluding inorganic salts, unreacted starting materials and water, in a preferred embodiment such impurities will be present at less than 10 wt%, preferably less than 5 wt% and more preferably less than 2 wt% relative to the active leuco compound.
  • the leuco composition can comprise any suitable number of leuco compounds as described above. Further, the leuco composition can comprise any suitable solvent in addition to the leuco compound(s). In one aspect, the leuco composition comprises a solvent selected from the group consisting of group consisting of water, ethylene glycol, propylene glycol, glycerin, poly(ethylene glycol), poly(propylene glycol), copolymers of ethylene oxide and propylene oxide and mixtures thereof. In another aspect, the leuco composition comprises a solvent selected from the group consisting of poly(ethylene glycol), poly(propylene glycol), copolymers of ethylene oxide and propylene oxide, non-ionic surfactants as disclosed hereinbelow, and mixtures thereof. In one preferred embodiment, the leuco composition is dissolved in poly(ethylene glycol), such as PEG200, prior to incorporation into the laundry care composition.
  • poly(ethylene glycol) such as PEG200
  • the leuco composition further comprises an antioxidant compound in addition to the leuco compound(s) and any suitable solvent that may be present.
  • an antioxidant compound in addition to the leuco compound(s) and any suitable solvent that may be present.
  • the presence of the antioxidant compound serves to stabilize the composition and reduce the amount of leuco compound that is prematurely converted to the second color state.
  • any suitable antoxidant compound can be used.
  • the antioxidant compound is selected from the group consisting of hindered phenol (such as BHT, irganox 1135, irganox 1076, irganox 1010, irganox 1330, and irganox 1035), aromatic amine and its derivatives (such as irganox 5057), -, ⁇ -, ⁇ -, ⁇ -tocopherol, ethoxyquine, 2,2,4-trimethyl-l,2-dihydroquinoline, 2,6-di-tert-butyl hydroquinone, tert-butyl-hydroxy anisole, lignosulphonic acid and salts thereof, 6-hydroxy-2,5,7,8-tetra-methylchroman-2-carboxylic acid (TroloxTM), l,2-benzisothiazoline-3- one (Proxel GXLTM), a benzofuran or benzopyran derivative (such as Irganox® HP136 and AOX-1
  • the leuco composition of the invention should be stored and transported in a closed container to prevent contamination from dust, moisture or other foreign objects.
  • the leuco composition is stored and transported in air tight containers.
  • Suitable containers may be composed of materials wherein P x 10 10 is less than 10, more preferably less than 5 and most preferably less than 2 at 30°C. This limits the exposure of the material to oxygen and limits conversion of the leuco compound to the second colored state during storage and shipping.
  • Containers may consist of bulk loads in tank trucks, totes, drums, carboys or cylinders in any appropriate size. Most preferable containers are made from stainless steel or HDPE.
  • Containers may be open head or tight head containers.
  • Stainless steel containers may be unlined or optionally lined with any suitable coating, such as an epoxy or epoxy phenolic coating.
  • Some containers may contain at least one drain valve, and containers are preferably fortifiable, stackable, and DOT/UN approved.
  • Suitable packaging is available from a variety of suppliers such as General Steel, Mauser, Schiitz, Cardinal Packaging or other vendors.
  • the suitable containers can be the Ecobulk MX, Ecobulk MX-EX, Ecobulk MX-EV, Ecobulk MX, Cleancert, Ecobulk MX-EX-EV Cleancert, Ecobulk SX-EX, and Ecobulk MX impeller as offered by Schuetz, Mauser® SM 6, Mauser® SM 13, Mauser® SM 15, Mauser® SM EX, Mauser® SM LP as offered by Mauser.
  • HDPE containers may contain additives to protect the contents from UV and visible light, such as Mauser ® SM LP* totes or the like.
  • HDPE containers may contain additional protection provided by an EVOH permeation barrier or Dualprotect system available from Schiitz packaging systems.
  • the leuco composition of the invention is, as is explained above, relatively stable and no specific shipping or packing requirements are needed.
  • the material does not need to be packaged under an inert atmosphere or shipped with climate control to remain stable.
  • the storage stability of the leuco composition can be improved by implementing certain measures.
  • One way to generate the oxygen deficient atmosphere is to use inert gas such as nitrogen, argon or carbon dioxide.
  • the container may be purged with an inert gas for a period of time, or by evacuating and backfilling the container with the inert gas.
  • the purging time should be at least three time longer than the time needed to fill up the head space of the container, more preferably five times longer.
  • the inner pressure should be close to atmospheric pressure, or slightly higher than atmospheric pressure during the purge or backfill.
  • the preferred inner pressure range is from 0.5 to 2 atm, more preferably from 0.8 to 1.5 atm, and most preferably from 0.95 to 1.2 atm.
  • ideal pressures are the values under the conditions encountered during the purging or backfilling and the pressure of the gas will change when the temperature changes, approximatively following the ideal gas law.
  • the material itself may be purged with an inert gas by bubbling the inert gas through the product for a period of time before or after packaging.
  • the percentage of the container volume occupied by the material should be at least 50%, more preferably 80%, even more preferably 90% or even 95%, which in turn limits the volume that constitutes the headspace which is occupied by either ambient air, an inert gas, or mixtures thereof.
  • limiting the amount of oxygen present in the container will slow the conversion of the leuco compounds to the second colored state.
  • container designs that minimize the surface area of the interface between the material and the headspace are generally preferred. For this reason, shipping the material by means that limit the movement of the material within the container decrease the time average surface area and may contribute to increased stability of the material, especially material comprising somewhat less stable leuco compounds.
  • the material of the current invention is stable enough to store and transport without climate control wherein temperatures may range from -40 °C to 60 °C depending on the climate and location. However, lower temperatures are preferred. Suitable temperature ranges for storing and transporting the chemical are from -30 °C to 60 °C, more preferable from -10 °C to 50 °C, most preferable from 0 °C to 35 °C.
  • Additional protection of the product may be used such as oxygen scavengers in films, sachets or via direct incorporation into the packaging material to maintain an oxygen deficient atmosphere within the container.
  • the leuco compounds and compositions described above are believed to be suitable for use in the treatment of textile materials, such as in domestic laundering processes.
  • the leuco compounds will deposit onto the fibers of the textile material due to the nature of the leuco compound.
  • the leuco compound can be converted to a colored compound through the application of the appropriate chemical or physical triggers that will convert the leuco compound to its colored form.
  • the leuco compound can be converted to its colored form upon oxidation of the leuco compound to the oxidized compound.
  • the leuco compound can be designed to impart a desired hue to the textile material as the leuco compound is converted to its colored form.
  • a leuco compound that exhibits a blue hue upon conversion to its colored form can be used to counteract the yellowing of the textile material to normally occurs due to the passage of time and/or repeated launderings.
  • the invention provides laundry care compositions comprising the above-described leuco compound and domestic methods for treating a textile material (e.g., methods for washing an article of laundry or clothing).
  • the leuco compound when converted to its second color state, gives a hue to the cloth with a relative hue angle of 210 to 345, or even a relative hue angle of 240 to 320, or even a relative hue angle of 250 to 300 (e.g., 250 to 290).
  • the relative hue angle can be determined by any suitable method as known in the art. However, preferably it may be determined as described in further detail herein with respect to deposition of the leuco entity on cotton relative to cotton absent any leuco entity.
  • the invention provides a laundry care composition comprising a laundry care ingredient and a leuco composition as described herein.
  • the laundry care composition can comprise any suitable leuco composition or combination of leuco compositions as described herein.
  • the laundry care composition can comprise any suitable laundry care ingredient. Laundry care ingredients suitable for use in the invention are described in detail below.
  • the laundry care composition may comprise other suitable adjuncts which, in some aspects, can be wholly or partially incorporated. Adjuncts may be selected according to the laundry care composition's intended function.
  • the first composition may comprise an adjunct.
  • the adjuncts may be part of a non-first (e.g., second, third, fourth, etc.) composition encapsulated in compartments separate from the first composition.
  • the non-first composition may be any suitable composition.
  • the non-first composition may be in the form of a solid, a liquid, a dispersion, a gel, a paste or a mixture thereof. Where the unit dose comprises multiple compartments, the leuco colorant may be added to or present in one, two, or even all the compartments.
  • the leuco colorant is added to the larger compartment, leading to a lower concentration which may minimize any issues involved with potential contact staining.
  • concentrating an anti-oxidant with a leuco colorant in a smaller volume compartment may lead to a higher local concentration of antioxidant which may provide enhanced stability. Therefore, as one skilled in the art would appreciate, the formulator can select the location and amount of the leuco colorant according to the desired properties of the unit dose.
  • the laundry care composition may comprise a surfactant system.
  • the laundry care composition may comprise from about 1% to about 80%, or from 1% to about 60%, preferably from about 5% to about 50% more preferably from about 8% to about 40%, by weight of the laundry care composition, of a surfactant system
  • Suitable surfactants include anionic surfactants, non-ionic surfactant, cationic surfactants, zwitterionic surfactants and amphoteric surfactants and mixtures thereof.
  • Suitable surfactants may be linear or branched, substituted or un-substituted, and may be derived from petrochemical material or biomaterial.
  • Preferred surfactant systems comprise both anionic and nonionic surfactant, preferably in weight ratios from 90: 1 to 1 :90. In some instances a weight ratio of anionic to nonionic surfactant of at least 1: 1 is preferred. However a ratio below 10: 1 may be preferred.
  • the total surfactant level is preferably from 0.1% to 60%, from 1% to 50% or even from 5% to 40% by weight of the subject composition.
  • Anionic surfactant include, but are not limited to, those surface-active compounds that contain an organic hydrophobic group containing generally 8 to 22 carbon atoms or generally 8 to 18 carbon atoms in their molecular structure and at least one water- solubilizing group preferably selected from sulfonate, sulfate, and carboxylate so as to form a water-soluble compound.
  • the hydrophobic group will comprise a C8-C 22 alkyl, or acyl group.
  • Such surfactants are employed in the form of water-soluble salts and the salt-forming cation usually is selected from sodium, potassium, ammonium, magnesium and mono-, with the sodium cation being the usual one chosen.
  • Anionic surfactants of the present invention and adjunct anionic cosurfactants may exist in an acid form, and said acid form may be neutralized to form a surfactant salt which is desirable for use in the present detergent compositions.
  • Typical agents for neutralization include the metal counterion base such as hydroxides, e.g., NaOH or KOH.
  • Further preferred agents for neutralizing anionic surfactants of the present invention and adjunct anionic surfactants or cosurfactants in their acid forms include ammonia, amines, oligamines, or alkanolamines. Alkanolamines are preferred.
  • Amine neutralization may be done to a full or partial extent, e.g. part of the anionic surfactant mix may be neutralized with sodium or potassium and part of the anionic surfactant mix may be neutralized with amines or alkanolamines.
  • Suitable sulphonate surfactants include methyl ester sulphonates, alpha olefin sulphonates, alkyl benzene sulphonates, especially alkyl benzene sulphonates, preferably Cio-13 alkyl benzene sulphonate.
  • Suitable alkyl benzene sulphonate (LAS) is obtainable, preferably obtained, by sulphonating commercially available linear alkyl benzene (LAB).
  • Suitable LAB includes low 2- phenyl LAB, such as those supplied by Sasol under the tradename Isochem® or those supplied by Petresa under the tradename Petrelab®, other suitable LAB include high 2-phenyl LAB, such as those supplied by Sasol under the tradename Hyblene®.
  • a suitable anionic surfactant is alkyl benzene sulphonate that is obtained by DETAL catalyzed process, although other synthesis routes, such as HF, may also be suitable.
  • a magnesium salt of LAS is used.
  • Suitable sulphate surfactants include alkyl sulphate, preferably Cs-is alkyl sulphate, or predominantly C12 alkyl sulphate.
  • a preferred sulphate surfactant is alkyl alkoxylated sulphate, preferably alkyl ethoxylated sulphate, preferably a Cs-is alkyl alkoxylated sulphate, preferably a Cs-is alkyl ethoxylated sulphate, preferably the alkyl alkoxylated sulphate has an average degree of alkoxylation of from 0.5 to 20, preferably from 0.5 to 10, preferably the alkyl alkoxylated sulphate is a Cs-is alkyl ethoxylated sulphate having an average degree of ethoxylation of from 0.5 to 10, preferably from 0.5 to 5, more preferably from 0.5 to 3.
  • the alkyl alkoxylated sulfate may have a broad alkoxy distribnution or a peaked alkoxy distribution.
  • the alkyl sulphate, alkyl alkoxylated sulphate and alkyl benzene sulphonates may be linear or branched, including 2 alkyl substituted or mid chain branched type, substituted or un-substituted, and may be derived from petrochemical material or biomaterial.
  • the branching group is an alkyl.
  • the alkyl is selected from methyl, ethyl, propyl, butyl, pentyl, cyclic alkyl groups and mixtures thereof.
  • Single or multiple alkyl branches could be present on the main hydrocarbyl chain of the starting alcohol(s) used to produce the sulfated anionic surfactant used in the detergent of the invention.
  • the branched sulfated anionic surfactant is selected from alkyl sulfates, alkyl ethoxy sulfates, and mixtures thereof.
  • Alkyl sulfates and alkyl alkoxy sulfates are commercially available with a variety of chain lengths, ethoxylation and branching degrees.
  • Commercially available sulfates include those based on Neodol alcohols ex the Shell company, Lial - Isalchem and Safol ex the Sasol company, natural alcohols ex The Procter & Gamble Chemicals company.
  • alkyl ether carboxylates comprising a C10-C26 linear or branched, preferably C10-C20 linear, most preferably C16-C18 linear alkyl alcohol and from 2 to 20, preferably 7 to 13, more preferably 8 to 12, most preferably 9.5 to 10.5 ethoxylates.
  • the acid form or salt form such as sodium or ammonium salt, may be used, and the alkyl chain may contain one cis or trans double bond.
  • Alkyl ether carboxylic acids are available from Kao (Akypo®), Huntsman (Empicol®) and Clariant (Emulsogen®).
  • Non-ionic surfactant are selected from the group consisting of: Cg-Cis alkyl ethoxylates, such as, NEODOL® non-ionic surfactants from Shell; C 6 -Ci2 alkyl phenol alkoxylates wherein preferably the alkoxylate units are ethyleneoxy units, propyleneoxy units or a mixture thereof; Cn-Cis alcohol and C6-C12 alkyl phenol condensates with ethylene oxide/propylene oxide block polymers such as Pluronic® from BASF; alkylpolysaccharides, preferably alkylpolyglycosides; methyl ester ethoxylates; polyhydroxy fatty acid amides; ether capped poly(oxyalkylated) alcohol surfactants; and mixtures thereof.
  • Cg-Cis alkyl ethoxylates such as, NEODOL® non-ionic surfactants from Shell
  • Suitable non-ionic surfactants are alkylpolyglucoside and/or an alkyl alkoxylated alcohol.
  • Suitable non-ionic surfactants include alkyl alkoxylated alcohols, preferably Cs-is alkyl alkoxylated alcohol, preferably a Cs-is alkyl ethoxylated alcohol, preferably the alkyl alkoxylated alcohol has an average degree of alkoxylation of from 1 to 50, preferably from 1 to 30, or from 1 to 20, or from 1 to 10, preferably the alkyl alkoxylated alcohol is a Cs-is alkyl ethoxylated alcohol having an average degree of ethoxylation of from 1 to 10, preferably from 1 to 7, more preferably from 1 to 5 and most preferably from 3 to 7.
  • the alkyl alkoxylated alcohol is a C12- 15 alkyl ethoxylated alcohol having an average degree of ethoxylation of from 7 to 10.
  • the alkyl alkoxylated alcohol can be linear or branched, and substituted or un-substituted.
  • Suitable nonionic surfactants include those with the trade name Lutensol® from BASF.
  • Preferred cationic surfactants are quaternary ammonium compounds having the general formula: (R)(Ri)(R 2 )(R 3 )N + X wherein, R is a linear or branched, substituted or unsubstituted Ce-is alkyl or alkenyl moiety, Ri and R 2 are independently selected from methyl or ethyl moieties, R 3 is a hydroxyl, hydroxymethyl or a hydroxyethyl moiety, X is an anion which provides charge neutrality, preferred anions include: halides, preferably chloride; sulphate; and sulphonate.
  • the fabric care compositions of the present invention may contain up to about 30%, alternatively from about 0.01% to about 20%, more alternatively from about 0.1% to about 20%, by weight of the composition, of a cationic surfactant.
  • cationic surfactants include those which can deliver fabric care benefits.
  • Non-limiting examples of useful cationic surfactants include: fatty amines, imidazoline quat materials and quaternary ammonium surfactants, preferably N, N-bis(stearoyl-oxy-ethyl) ⁇ , ⁇ -dimethyl ammonium chloride, N,N- bis(tallowoyl-oxy-ethyl) ⁇ , ⁇ -dimethyl ammonium chloride, N,N-bis(stearoyl-oxy-ethyl) N-(2 hydroxyethyl) N-methyl ammonium methylsulfate; 1, 2 di (stearoyl-oxy) 3 trimethyl ammoniumpropane chloride; dialkylenedimethylammonium salts such as dicanoladimethylammonium chloride, di(hard)tallowdimethylammonium chloride dicanoladimethylammonium methylsulfate; 1 -methyl- 1 - stearoylamidoethyl-2- stea
  • Amphoteric and Zwitterionic surfactant include amine oxides, and/or betaines.
  • Preferred amine oxides are alkyl dimethyl amine oxide or alkyl amido propyl dimethyl amine oxide, more preferably alkyl dimethyl amine oxide and especially coco dimethyl amino oxide.
  • Amine oxide may have a linear or mid-branched alkyl moiety.
  • Typical linear amine oxides include water-soluble amine oxides containing one Rl C8- 18 alkyl moiety and 2 R2 and R3 moieties selected from the group consisting of CI -3 alkyl groups and Cl-3 hydroxyalkyl groups.
  • amine oxide is characterized by the formula Rl - N(R2)(R3) O wherein Rl is a C8-18 alkyl and R2 and R3 are selected from the group consisting of methyl, ethyl, propyl, isopropyl, 2-hydroxethyl, 2-hydroxypropyl and 3-hydroxypropyl.
  • the linear amine oxide surfactants in particular may include linear C10-C18 alkyl dimethyl amine oxides and linear C8-C12 alkoxy ethyl dihydroxy ethyl amine oxides.
  • surfactants include betaines, such as alkyl betaines, alkylamidobetaine, amidazoliniumbetaine, sulfobetaine (INCI Sultaines) as well as Phosphobetaines.
  • Another class of ingredients in the leuco colorants composition may be a diluent and/or solvent.
  • the purpose of the diluent and/or solvent is often, but not limited to, improving fluidity and/or reducing the viscosity of the leuco colorant.
  • water is often the preferred diluent and/or solvent given its low cost and non-toxicity, other solvent may also be used as well.
  • the preferred solvent is one having low cost and low hazards.
  • suitable solvents include, but are not limited to, ethylene glycol, propylene glycol, glycerin, alkoxylated polymers such as polyethylene glycol, polypropylene glycol, copolymers of ethylene oxide and propylene oxide, Tween 20®, Tween 40®, Tween 80®, and the like, and combinations thereof.
  • the ethylene oxide and propylene oxide copolymers may be preferred. These polymers often feature a cloud point with water, which can help the product separated from the water to remove the undesirable water soluble impurities.
  • ethylene oxide and propylene oxide copolymers include but not limited to the PLURONIC series polymers by BASF and TERGITOLTM series polymer and by Dow.
  • the laundry care compositions described herein may also include one or more of the following non-limiting list of ingredients: fabric care benefit agent; detersive enzyme; deposition aid; rheology modifier; builder; chelant; bleach; bleaching agent; bleach precursor; bleach booster; bleach catalyst; perfume and/or perfume microcapsules; perfume loaded zeolite; starch encapsulated accord; polyglycerol esters; whitening agent; pearlescent agent; enzyme stabilizing systems; scavenging agents including fixing agents for anionic dyes, complexing agents for anionic surfactants, and mixtures thereof; optical brighteners or fluorescers; polymer including but not limited to soil release polymer and/or soil suspension polymer; dispersants; antifoam agents; non-aqueous solvent; fatty acid; suds suppressors, e.g., silicone suds suppressors; cationic starches; scum dis
  • compositions may comprise surfactants, quaternary ammonium compounds, and/or solvent systems.
  • Quaternary ammonium compounds may be present in fabric enhancer compositions, such as fabric softeners, and comprise quaternary ammonium cations that are positively charged polyatomic ions of the structure NR 4 + , where R is an alkyl group or an aryl group
  • the composition may comprise an additional fabric shading agent.
  • Suitable fabric shading agents include dyes, dye-clay conjugates, and pigments.
  • Suitable dyes include small molecule dyes and polymeric dyes.
  • Suitable small molecule dyes include small molecule dyes selected from the group consisting of dyes falling into the Colour Index (C.I.) classifications of Direct Blue, Direct Red, Direct Violet, Acid Blue, Acid Red, Acid Violet, Basic Blue, Basic Violet and Basic Red, or mixtures thereof.
  • Preferered dyes include alkoxylated azothiophenes, Solvent Violet 13, Acid Violet 50 and Direct Violet 9.
  • the composition may comprise one or more aesthetic colorants.
  • Suitable aesthetic colorants include dyes, dye-clay conjugates, pigments, and Liquitint® polymeric colorants (Milliken & Company, Spartanburg, South Carolina, USA).
  • suitable dyes and pigments include small molecule dyes and polymeric dyes.
  • the aesthetic colorant may include at least one chromophore constituent selected from the group consisting of acridines, anthraquinones, azines, azos, benzodifuranes, benzodifuranones, carotenoids, coumarins, cyanines, diazahemicyanines, diphenylmethanes, formazans, hemicyanines, indigoids, methanes, methines, naphthalimides, naphthoquinones, nitros, nitrosos, oxazines, phenothiazine, phthalocyanines (such as copper phthalocyanines), pyrazoles, pyrazolones, quinolones, stilbenes, styryls, triarylmethanes (such as triphenylmethanes), xanthenes, and mixtures thereof.
  • acridines anthraquinones, azines, azos, benzodifuranes, be
  • aesthetic colorants include Liquitint® Blue AH, Liquitint® Blue BB, Liquitint® Blue 275, Liquitint® Blue 297, Liquitint® Blue BB, Cyan 15, Liquitint® Green 101, Liquitint® Orange 272, Liquitint® Orange 255, Liquitint® Pink AM, Liquitint® Pink AMC, Liquitint® Pink ST, Liquitint® Violet 129, Liquitint® Violet LS, Liquitint® Violet 291, Liquitint® Yellow FT, Liquitint® Blue Buf, Liquitint® Pink AM, Liquitint® Pink PV, Acid Blue 80, Acid Blue 182, Acid Red 33, Acid Red 52, Acid Violet 48, Acid Violet 126, Acid Blue 9, Acid Blue 1, and mixtures thereof.
  • the composition may comprise an encapsulated material.
  • an encapsulate comprising a core, a shell having an inner and outer surface, said shell encapsulating said core.
  • the core may comprise any laundry care adjunct, though typically the core may comprise material selected from the group consisting of perfumes; brighteners; hueing dyes; insect repellants; silicones; waxes; flavors; vitamins; fabric softening agents; skin care agents in one aspect, paraffins; enzymes; anti-bacterial agents; bleaches; sensates; and mixtures thereof; and said shell may comprise a material selected from the group consisting of poly ethylenes; polyamides; polyvinylalcohols, optionally containing other co-monomers; polystyrenes; polyisoprenes; polycarbonates; polyesters; polyacrylates; aminoplasts, in one aspect said aminoplast may comprise a polyureas, polyurethane, and/or polyureaurethane, in one aspect said polyurea may comprise polyoxymethyleneurea and
  • Preferred encapsulates comprise perfume.
  • Preferred encapsulates comprise a shell which may comprise melamine formaldehyde and/or cross linked melamine formaldehyde.
  • Other preferred capsules comprise a polyacrylate based shell.
  • Preferred encapsulates comprise a core material and a shell, said shell at least partially surrounding said core material, is disclosed. At least 75%, 85% or even 90% of said encapsulates may have a fracture strength of from 0.2 MPa to 10 MPa, and a benefit agent leakage of from 0% to 20%, or even less than 10% or 5% based on total initial encapsulated benefit agent.
  • Formaldehyde scavengers may be employed with encapsulates, for example, in a capsule slurry and/or added to a composition before, during or after the encapsulates are added to such composition.
  • Suitable capsules that can be made by following the teaching of USPA 2008/0305982 Al; and/or USPA 2009/0247449 Al.
  • suitable capsules can be purchased from Appleton Papers Inc. of Appleton, Wisconsin USA.
  • the composition may comprise a deposition aid, preferably in addition to encapsulates.
  • deposition aids are selected from the group consisting of cationic and nonionic polymers.
  • Suitable polymers include cationic starches, cationic hydroxyethylcellulose, polyvinylformaldehyde, locust bean gum, mannans, xyloglucans, tamarind gum, polyethyleneterephthalate and polymers containing dimethylaminoethyl methacrylate, optionally with one or more monomers selected from the group comprising acrylic acid and acrylamide.
  • compositions of the invention comprise perfume.
  • the composition comprises a perfume that comprises one or more perfume raw materials, selected from the group as described in WO08/87497.
  • any perfume useful in a laundry care composition may be used.
  • a preferred method of incorporating perfume into the compositions of the invention is via an encapsulated perfume particle comprising either a water-soluble hydroxylic compound or melamine-formaldehyde or modified polyvinyl alcohol.
  • the cleaning compositions of the present disclosure may comprise malodour reduction materials. Such materials are capable of decreasing or even eliminating the perception of one or more malodors. These materials can be characterized by a calculated malodor reduction value (“MORV”), which is calculated according to the test method shown in WO2016/049389. As used herein "MORV" is the calculated malodor reduction value for a subject material. A material's MORV indicates such material's ability to decrease or even eliminate the perception of one or more malodor s.
  • the cleaning compositions of the present disclosure may comprise a sum total of from about 0.00025% to about 0.5%, preferably from about 0.0025% to about 0.1%, more preferably from about 0.005% to about 0.075%, most preferably from about 0.01% to about 0.05%, by weight of the composition, of 1 or more malodor reduction materials.
  • the cleaning composition may comprise from about 1 to about 20 malodor reduction materials, more preferably 1 to about 15 malodor reduction materials, most preferably 1 to about 10 malodor reduction materials.
  • One, some, or each of the malodor reduction materials may have a MORV of at least 0.5, preferably from 0.5 to 10, more preferably from 1 to 10, most preferably from 1 to 5.
  • One, some, or each of the malodor reduction materials may have a Universal MORV, defined as all of the MORV values of >0.5 for the malodors tested as described herein.
  • the sum total of malodor reduction materials may have a Blocker Index of less than 3, more preferable less than about 2.5, even more preferably less than about 2, and still more preferably less than about 1, and most preferably about 0.
  • the sum total of malodor reduction materials may have a Blocker Index average of from about 3 to about 0.001.
  • the malodor reduction materials may have a Fragrance Fidelity Index of less than 3, preferably less than 2, more preferably less than 1 and most preferably about 0 and/or a Fragrance Fidelity Index average of 3 to about 0.001 Fragrance Fidelity Index. As the Fragrance Fidelity Index decreases, the malodor reduction material(s) provide less and less of a scent impact, while continuing to counteract malodors.
  • the cleaning compositions of the present disclosure may comprise a perfume.
  • the weight ratio of parts of malodor reduction composition to parts of perfume may be from about 1:20,000 to about 3000: 1, preferably from about 1: 10,000 to about 1,000: 1, more preferably from about 5,000: 1 to about 500: 1, and most preferably from about 1: 15 to about 1: 1.
  • the malodor reduction material(s) provide less and less of a scent impact, while continuing to counteract malodors. Tannins
  • the cleaning compositions of the present disclosure may comprise tannins. Tannins are polyphenolic secondary metabolites of higher plants, and are either galloyl esters and their derivatives, in which galloyl moieties or their derivatives are attached to a variety of polyol-, catechin- and triterpenoid cores (gallotannis, ellagitannins and complex tannins), or they are oligomeric and polymeric proanthocyanidis that can possess interflavanyl coupling and substitution patterns (condensed tannins).
  • the cleaning compositions of the present disclosure may comprise tannins selected from the group consisting of gallotannins, ellagitannins, complex tannins, condensed tannins, and combinations thereof
  • the composition may comprise one or more polymers.
  • Examples are optionally modified carboxymethylcellulose, poly(vinyl-pyrrolidone), poly (ethylene glycol), poly(vinyl alcohol), poly(vinylpyridine-N-oxide), poly(vinylimidazole), polycarboxylates such as polyacrylates, maleic/acrylic acid copolymers and lauryl methacrylate/acrylic acid co-polymers.
  • the composition may comprise one or more amphiphilic cleaning polymers. Such polymers have balanced hydrophilic and hydrophobic properties such that they remove grease particles from fabrics and surfaces.
  • Suitable amphiphilic alkoxylated grease cleaning polymers comprise a core structure and a plurality of alkoxylate groups attached to that core structure. These may comprise alkoxylated polyalkylenimines, especially ethoxylated polyethylene imines or polyethyleneimines having an inner polyethylene oxide block and an outer polypropylene oxide block. Typically these may be incorporated into the compositions of the invention in amounts of from 0.005 to 10 wt%, generally from 0.5 to 8 wt%.
  • the composition may comprise a modified hexamethylenediamine.
  • the modification of the hexamethylenediamine includes: (1) one or two alkoxylation modifications per nitrogen atom of the hexamethylenediamine.
  • the alkoxylation modification consisting of the replacement of a hydrogen atom on the nitrogen of the hexamethylenediamine by a (poly)alkoxylene chain having an average of about 1 to about 40 alkoxy moieties per modification, wherein the terminal alkoxy moiety of the alkoxylene chain is capped with hydrogen, a C1-C4 alkyl, sulfates, carbonates, or mixtures thereof; (2) a substitution of one C1-C4 alkyl moiety and one or two alkoxylation modifications per nitrogen atom of the hexamethylenediamine.
  • the alkoxylation modification consisting of the replacement of a hydrogen atom by a (poly)alkoxylene chain having an average of about 1 to about 40 alkoxy moieties per modification wherein the terminal alkoxy moiety of the alkoxylene chain is capped with hydrogen, a C1-C4 alkyl or mixtures thereof; or (3) a combination thereof
  • Alkoxylated polycarboxylates such as those prepared from polyacrylates are useful herein to provide additional grease removal performance. Such materials are described in WO 91/08281 and PCT 90/01815. Chemically, these materials comprise polyacrylates having one ethoxy side- chain per every 7-8 acrylate units.
  • the side-chains are of the formula -(CH 2 CH 2 0) m (CH 2 )nCH3 wherein m is 2-3 and n is 6-12.
  • the side-chains are ester- linked to the polyacrylate "backbone” to provide a "comb" polymer type structure.
  • the molecular weight can vary, but is typically in the range of about 2000 to about 50,000.
  • Such alkoxylated polycarboxylates can comprise from about 0.05% to about 10%, by weight, of the compositions herein.
  • Another suitable carboxylate polymer is a co-polymer that comprises: (i) from 50 to less than 98 wt% structural units derived from one or more monomers comprising carboxyl groups; (ii) from 1 to less than 49 wt% structural units derived from one or more monomers comprising sulfonate moieties; and (iii) from 1 to 49 wt% structural units derived from one or more types of monomers selected from ether bond-containing monomers represented by formulas (I) and (II):
  • Ro represents a hydrogen atom or CH 3 group
  • R represents a CH 2 group, CH 2 CH 2 group or single bond
  • X represents a number 0-5 provided X represents a number 1-5 when R is a single bond
  • Ri is a hydrogen atom or Ci to C 2 o organic group
  • Ro represents a hydrogen atom or CH 3 group
  • R represents a CH 2 group, CH 2 CH 2 group or single bond
  • X represents a number 0-5
  • Ri is a hydrogen atom or Ci to C 2 o organic group.
  • the polymer has a weight average molecular weight of at least 50kDa, or even at least 70kDa.
  • amphiphilic graft copolymers include amphiphilic graft copolymers.
  • Preferred amphiphilic graft copolymers comprise (i) polyethyelene glycol backbone; and (ii) and at least one pendant moiety selected from polyvinyl acetate, polyvinyl alcohol and mixtures thereof.
  • a preferred amphiphilic graft co-polymer is Sokalan HP22, supplied from BASF.
  • suitable polymers include random graft copolymers, preferably a polyvinyl acetate grafted polyethylene oxide copolymer having a polyethylene oxide backbone and multiple polyvinyl acetate side chains.
  • the molecular weight of the polyethylene oxide backbone is preferably about 6000 and the weight ratio of the polyethylene oxide to polyvinyl acetate is about 40 to 60 and no more than 1 grafting point per 50 ethylene oxide units. Typically these are incorporated into the compositions of the invention in amounts from 0.005 to 10 wt%, more usually from 0.05 to 8 wt%.
  • composition may comprise one or more soil release polymers.
  • soil release polymers having a structure as defined by one of the following Formula (VI), (VII) or (VIII):
  • Ar is a 1,4-substituted phenylene; sAr is 1,3-substituted phenylene substituted in position 5 with S0 3 Me;
  • Me is Li, K, Mg/2, Ca/2, Al/3, ammonium, mono-, di-, tri-, or tetraalkylammonium wherein the alkyl groups are Ci-Cis alkyl or C2-C10 hydroxyalkyl, or mixtures thereof;
  • R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are independently selected from H or Ci-Cis n- or iso-alkyl;
  • R 7 is a linear or branched Ci-Cis alkyl, or a linear or branched C 2 -C 3 o alkenyl, or a cycloalkyl group with 5 to 9 carbon atoms, or a Cs-C 3 o aryl group, or a C 6 -C 3 o arylalkyl group.
  • Suitable soil release polymers are polyester soil release polymers such as Repel-o-tex polymers, including Repel-o-tex SF, SF-2 and SRP6 supplied by Rhodia.
  • Other suitable soil release polymers include Texcare polymers, including Texcare SRA100, SRA300, SRN100, SRN170, SRN240, SRN300 and SRN325 supplied by Clariant.
  • Other suitable soil release polymers are Marloquest polymers, such as Marloquest SL supplied by Sasol.
  • the composition may also comprise one or more cellulosic polymer, including those selected from alkyl cellulose, alkyl alkoxyalkyl cellulose, carboxyalkyl cellulose, alkyl carboxyalkyl cellulose.
  • Preferred cellulosic polymers are selected from the group comprising carboxymethyl cellulose, methyl cellulose, methyl hydroxyethyl cellulose, methyl carboxymethyl cellulose, and mixures thereof.
  • the carboxymethyl cellulose has a degree of carboxymethyl substitution from 0.5 to 0.9 and a molecular weight from 100,000 Da to 300,000 Da.
  • Soil release polymer The composition may comprise a soil release polymer.
  • a suitable soil release polymer has a structure as defined by one of the following structures (I), (II) or (III):
  • a, b and c are from 1 to 200;
  • d, e and f are from 1 to 50;
  • Ar is a 1,4-substituted phenylene
  • sAr is 1,3-substituted phenylene substituted in position 5 with S0 3 Me;
  • Me is Li, K, Mg/2, Ca/2, Al/3, ammonium, mono-, di-, tri-, or tetraalkylammonium wherein the alkyl groups are Ci-Cis alkyl or C2-C10 hydroxyalkyl, or mixtures thereof;
  • R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are independently selected from H or Ci-Cis n- or iso-alkyl;
  • R 7 is a linear or branched Ci-Cis alkyl, or a linear or branched C 2 -C 3 o alkenyl, or a cycloalkyl group with 5 to 9 carbon atoms, or a Cs-C 3 o aryl group, or a C 6 -C 3 o arylalkyl group.
  • Suitable soil release polymers are sold by Clariant under the TexCare® series of polymers, e.g.
  • SRA polymeric soil release agents
  • SRA's can optionally be employed in the present detergent compositions. If utilized, SRA's will generally comprise from 0.01% to 10.0%, typically from 0.1% to 5%, preferably from 0.2% to 3.0% by weight, of the composition.
  • Preferred SRA's typically have hydrophilic segments to hydrophilize the surface of hydrophobic fibers such as polyester and nylon, and hydrophobic segments to deposit upon hydrophobic fibers and remain adhered thereto through completion of washing and rinsing cycles thereby serving as an anchor for the hydrophilic segments. This can enable stains occurring subsequent to treatment with SRA to be more easily cleaned in later washing procedures.
  • SRA's can include, for example, a variety of charged, e.g., anionic or even cationic (see U.S. Pat. No. 4,956,447), as well as noncharged monomer units and structures may be linear, branched or even star-shaped. They may include capping moieties which are especially effective in controlling molecular weight or altering the physical or surface-active properties. Structures and charge distributions may be tailored for application to different fiber or textile types and for varied detergent or detergent additive products. Suitable soil release polymers are polyester soil release polymers such as Repel-o-tex polymers, including Repel-o-tex, SF-2 and SRP6 supplied by Rhodia.
  • suitable soil release polymers include Texcare polymers, including Texcare SRA100, SRA300, SRN100, SRN170, SRN240, SRN300 and SRN325 supplied by Clariant.
  • suitable soil release polymers are Marloquest polymers, such as Marloquest SL supplied by Sasol Examples of SRAs are described in U.S. Pat. Nos.
  • Carboxylate polymer The composition may comprise a carboxylate polymer, such as a maleate/acrylate random copolymer or polyacrylate homopolymer.
  • Suitable carboxylate polymers include: polyacrylate homopolymers having a molecular weight of from 4,000 Da to 9,000 Da; maleate/acrylate random copolymers having a molecular weight of from 50,000 Da to 100,000 Da, or from 60,000 Da to 80,000 Da.
  • these materials may comprise polyacrylates having one ethoxy side-chain per every 7-8 acrylate units.
  • the side-chains are of the formula -(CH 2 CH 2 0) m (CH 2 )nCH3 wherein m is 2-3 and n is 6-12.
  • the side-chains are ester-linked to the polyacrylate "backbone” to provide a "comb" polymer type structure.
  • the molecular weight can vary, but is typically in the range of about 2000 to about 50,000.
  • Such alkoxylated polycarboxylates can comprise from about 0.05% to about 10%, by weight, of the compositions herein.
  • Another suitable carboxylate polymer is a co-polymer that comprises: (i) from 50 to less than 98 wt% structural units derived from one or more monomers comprising carboxyl groups; (ii) from 1 to less than 49 wt% structural units derived from one or more monomers comprising sulfonate moieties; and (iii) from 1 to 49 wt% structural units derived from one or more types of monomers selected from ether bond-containing monomers represented by formulas (I) and (II): formula (I):
  • Ro represents a hydrogen atom or CH 3 group
  • R represents a CH 2 group, CH 2 CH 2 group or single bond
  • X represents a number 0-5 provided X represents a number 1-5 when R is a single bond
  • Ri is a hydrogen atom or Ci to C20 organic group
  • Ro represents a hydrogen atom or CH 3 group
  • R represents a CH 2 group, CH 2 CH 2 group or single bond
  • X represents a number 0-5
  • Ri is a hydrogen atom or Ci to C 2 o organic group.
  • the polymer has a weight average molecular weight of at least 50kDa, or even at least 70kDa.
  • Such carboxylate based polymers can advantageously be utilized at levels from about 0.1% to about 7%, by weight, in the compositions herein,.
  • Suitable polymeric dispersing agents include carboxylate polymer such as a maleate/acrylate random copolymer or polyacrylate homopolymer.
  • carboxylate polymer is a polyacrylate homopolymer having a molecular weight of from 4,000 Daltons to 9,000 Daltons, or maleate/acrylate copolymer with a molecular weight 60,000 Daltons to 80,000 Daltons.
  • Polymeric polycarboxylates and polyethylene glycols can also be used.
  • Polyalkylene glycol-based graft polymer may prepared from the polyalkylene glycol- based compound and the monomer material, wherein the monomer material includes the carboxyl group-containing monomer and the optional additional monomer(s).
  • Optional additional monomers not classified as a carboxyl group-containing monomer include sulfonic acid group- containing monomers, amino group-containing monomers, allylamine monomers, quaternized allylamine monomers, N vinyl monomers, hydroxyl group -containing monomers, vinylaryl monomers, isobutylene monomers, vinyl acetate monomers, salts of any of these, derivatives of any of these, and mixtures thereof.
  • polymeric dispersing agents enhance overall detergent builder performance, when used in combination with other builders (including lower molecular weight polycarboxylates) by crystal growth inhibition, particulate soil release peptization, and anti-redeposition.
  • examples of polymeric dispersing agents are found in U.S. Pat. No. 3,308,067, European Patent Application No. 66915, EP 193,360, and EP 193,360.
  • Alkoxylated polyamine based polymers The composition may comprisse alkoxylated polyamines. Such materials include but are not limited to ethoxylated polyethyleneimine, ethoxylated hexamethylene diamine, and sulfated versions thereof. Polypropoxylated derivatives are also included. A wide variety of amines and polyaklyeneimines can be alkoxylated to various degrees, and optionally further modified to provide the abovementioned benefits. A useful example is 600g/mol polyethyleneimine core ethoxylated to 20 EO groups per NH and is available from BASF.
  • Useful alkoxylated polyamine based polymers include the alkoxylated polyethylene imine type where said alkoxylated polyalkyleneimine has a polyalkyleneimine core with one or more side chains bonded to at least one nitrogen atom in the polyalkyleneimine core, wherein said alkoxylated polyalkyleneimine has an empirical formula (I) of (PEI) a -(EO)b-Ri, wherein a is the average number- average molecular weight (MWPEI) of the polyalkyleneimine core of the alkoxylated polyalkyleneimine and is in the range of from 100 to 100,000 Daltons, wherein b is the average degree of ethoxylation in said one or more side chains of the alkoxylated polyalkyleneimine and is in the range of from 5 to 40, and wherein Ri is independently selected from the group consisting of hydrogen, C1-C4 alkyls, and combinations thereof.
  • alkoxylated polyalkyleneimine incldue those wherein said alkoxylated polyalkyleneimine has a polyalkyleneimine core with one or more side chains bonded to at least one nitrogen atom in the polyalkyleneimine core, wherein the alkoxylated polyalkyleneimine has an empirical formula (II) of (PEI) 0 -(EO) m (PO)n-R2 or (PEI) 0 -(PO) n (EO) M -R2, wherein o is the average number- average molecular weight (MWPEI) of the polyalkyleneimine core of the alkoxylated polyalkyleneimine and is in the range of from 100 to 100,000 Daltons, wherein m is the average degree of ethoxylation in said one or more side chains of the alkoxylated polyalkyleneimine which ranges from 10 to 50, wherein n is the average degree of propoxylation in said one or more side chains of the alkoxylated
  • Suitable polyethylene glycol polymers include random graft co-polymers comprising: (i) hydrophilic backbone comprising polyethylene glycol; and (ii) hydrophobic side chain(s) selected from the group consisting of: C4-C25 alkyl group, polypropylene, polybutylene, vinyl ester of a saturated Ci-Ce mono-carboxylic acid, Ci-Ce alkyl ester of acrylic or methacrylic acid, and mixtures thereof.
  • Suitable polyethylene glycol polymers have a polyethylene glycol backbone with random grafted polyvinyl acetate side chains.
  • the average molecular weight of the polyethylene glycol backbone can be in the range of from 2,000 Da to 20,000 Da, or from 4,000 Da to 8,000 Da.
  • the molecular weight ratio of the polyethylene glycol backbone to the polyvinyl acetate side chains can be in the range of from 1 : 1 to 1 :5, or from 1 : 1.2 to 1 :2.
  • the average number of graft sites per ethylene oxide units can be less than 1, or less than 0.8, the average number of graft sites per ethylene oxide units can be in the range of from 0.5 to 0.9, or the average number of graft sites per ethylene oxide units can be in the range of from 0.1 to 0.5, or from 0.2 to 0.4.
  • a suitable polyethylene glycol polymer is Sokalan HP22. Suitable
  • polyethylene glycol polymers are described in WO08/007320.
  • Cellulosic polymers may be used according to the invention. Suitable cellulosic polymers are selected from alkyl cellulose, alkyl alkoxyalkyl cellulose, carboxyalkyl cellulose, alkyl carboxyalkyl cellulose, sulphoalkyl cellulose, more preferably selected from carboxymethyl cellulose, methyl cellulose, methyl hydroxyethyl cellulose, methyl
  • Suitable carboxymethyl celluloses have a degree of carboxymethyl substitution from 0.5 to 0.9 and a molecular weight from 100,000 Da to 300,000 Da.
  • Suitable carboxymethyl celluloses have a degree of substitution greater than 0.65 and a degree of blockiness greater than 0.45, e.g. as described in WO09/154933.
  • the consumer products of the present invention may also include one or more cellulosic polymers including those selected from alkyl cellulose, alkylalkoxyalkyl cellulose, carboxyalkyl cellulose, alkyl carboxyalkyl cellulose.
  • the cellulosic polymers are selected from the group comprising carboxymethyl cellulose, methyl cellulose, methyl hydroxyethyl cellulose, methyl carboxymethyl cellulose, and mixtures thereof.
  • the carboxymethyl cellulose has a degree of carboxymethyl substitution from 0.5 to 0.9 and a molecular weight from 100,000 Da to 300,000 Da.
  • carboxymethylcellulose polymers are Carboxymethyl cellulose commercially sold by CPKelko as Finnfix ®GDA, hydrophobically modified carboxymethyl cellulose, for example the alkyl ketene dimer derivative of carboxymethylcellulose sold commercially by CPKelco as Finnfix®SHl, or the blocky carboxymethylcellulose sold commercially by CPKelco as Finnfix®V.
  • Cationic Polymers may also be used according to the invention. Suitable cationic polymers will have cationic charge densities of at least 0.5 meq/gm, in another embodiment at least 0.9 meq/gm, in another embodiment at least 1.2 meq/gm, in yet another embodiment at least 1.5 meq/gm, but in one embodiment also less than 7 meq/gm, and in another embodiment less than 5 meq/gm, at the pH of intended use of the composition, which pH will generally range from pH 3 to pH 9, in one embodiment between pH 4 and pH 8.
  • cationic charge density" of a polymer refers to the ratio of the number of positive charges on the polymer to the molecular weight of the polymer.
  • the average molecular weight of such suitable cationic polymers will generally be between 10,000 and 10 million, in one embodiment between 50,000 and 5 million, and in another embodiment between 100,000 and 3 million.
  • Suitable cationic polymers for use in the compositions of the present invention contain cationic nitrogen-containing moieties such as quaternary ammonium or cationic protonated amino moieties.
  • Any anionic counterions can be used in association with the cationic polymers so long as the polymers remain soluble in water, in the composition, or in a coacervate phase of the composition, and so long as the counterions are physically and chemically compatible with the essential components of the composition or do not otherwise unduly impair product performance, stability or aesthetics.
  • Nonlimiting examples of such counterions include halides (e.g., chloride, fluoride, bromide, iodide), sulfate and methylsulfate.
  • Nonlimiting examples of such polymers are described in the CTFA Cosmetic Ingredient Dictionary, 3rd edition, edited by Estrin, Crosley, and Haynes, (The Cosmetic, Toiletry, and Fragrance Association, Inc., Washington, D.C. (1982)).
  • Especially useful cationic polymers which may be used according to the invention include wherein said cationic polymer comprises a polymer selected from the group consisting of cationic celluloses, cationic guars, poly(acrylamide-co-diallyldimethylammonium chloride), poly(acrylamide-co-diallyldimethylammonium chloride-co-acrylic acid), poly(acrylamide-co- methacryloamidopropyl-pentamethyl- 1 ,3-propylene-2-ol-ammonium dichloride), poly(acrylamide-co-N,N-dimethylaminoethyl acrylate) and its quaternized derivatives, poly(acrylamide-co-N,N-dimethylaminoethyl methacrylate) and its quaternized derivatives, poly(acrylamide-methacrylamidopropyltrimethyl ammonium chloride), poly(acrylamide- methacrylamidopropyltrimethyl ammonium chloride-co-
  • Suitable cationic polymers for use in the composition include polysaccharide polymers, cationic guar gum derivatives, quaternary nitrogen-containing cellulose ethers, synthetic polymers, copolymers of etherified cellulose, guar and starch.
  • the cationic polymers herein are either soluble in the composition or are soluble in a complex coacervate phase in the composition formed by the cationic polymer and the anionic, amphoteric and/or zwitterionic surfactant component described hereinbefore.
  • Complex coacervates of the cationic polymer can also be formed with other charged materials in the composition.
  • Suitable cationic polymers are described in U.S. Pat. Nos. 3,962,418; 3,958,581; and U.S. Publication No. 2007/0207109A1.
  • the composition may comprise one or more dye transfer inhibiting agents.
  • the inventors have surprisingly found that compositions comprising polymeric dye transfer inhibiting agents in addition to the specified dye give improved performance. This is surprising because these polymers prevent dye deposition.
  • Suitable dye transfer inhibitors include, but are not limited to, polyvinylpyrrolidone polymers, polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimidazole, polyvinyloxazolidones and polyvinylimidazoles or mixtures thereof.
  • Suitable examples include PVP-K15, PVP-K30, ChromaBond S-400, ChromaBond S-403E and Chromabond S-100 from Ashland Aqualon, and Sokalan HP165, Sokalan HP50, Sokalan HP53, Sokalan HP59, Sokalan® HP 56K , Sokalan® HP 66 from BASF.
  • the dye control agent may be selected from (i) a sulfonated phenol / formaldehyde polymer; (ii) a urea derivative; (iii) polymers of ethylenically unsaturated monomers, where the polymers are molecularly imprinted with dye; (iv) fibers consisting of water- insoluble polyamide, wherein the fibers have an average diameter of not more than about 2 ⁇ ; (v) a polymer obtainable from polymerizing benzoxazine monomer compounds; and (vi) combinations thereof.
  • Other suitable DTIs are as described in WO2012/004134.
  • the dye transfer inhibiting agents may be present at levels from about 0.0001% to about 10%, from about 0.01% to about 5% or even from about 0.1% to about 3% by weight of the composition.
  • water soluble polymers examples include but are not limited to polyvinyl alcohols (PVA), modified PVAs; polyvinyl pyrrolidone; PVA copolymers such as PVA/polyvinyl pyrrolidone and PVA/ polyvinyl amine; partially hydrolyzed polyvinyl acetate; polyalkylene oxides such as polyethylene oxide; polyethylene glycols; acrylamide; acrylic acid; cellulose, alkyl cellulosics such as methyl cellulose, ethyl cellulose and propyl cellulose; cellulose ethers; cellulose esters; cellulose amides; polyvinyl acetates; polycarboxylic acids and salts; polyaminoacids or peptides; polyamides; poly acrylamide; copolymers of maleic/acrylic acids; polysaccharides including starch, modified starch; gelatin; alginates; xyloglucans, other hemicellulos
  • Non-limiting examples of amines include, but are not limited to, etheramines, cyclic amines, polyamines, oligoamines (e.g., triamines, diamines, pentamines, tetraamines), or combinations thereof.
  • the compositions described herein may comprise an amine selected from the group consisting of oligoamines, etheramines, cyclic amines, and combinations thereof.
  • the amine is not an alkanolamine.
  • the amine is not a poly alky leneimine .
  • Suitable oligoamines include tetraethylenepentamine, triethylenetetraamine, diethylenetriamine, and mixtures thereof
  • Etheramines may contain an etheramine.
  • the cleaning compositions may contain from about 0.1% to about 10%, or from about 0.2% to about 5%, or from about 0.5% to about 4%, by weight of the composition, of an etheramine.
  • the etheramines of the present disclosure may have a weight average molecular weight of less than about grams/mole 1000 grams/mole, or from about 100 to about 800 grams/mole, or from about 200 to about 450 grams/mole, or from about 290 to about 1000 grams/mole, or from about 290 to about 900 grams/mole, or from about 300 to about 700 grams/mole, or from about 300 to about 450 grams/mole.
  • the etheramines of the present invention may have a weight average molecular weight of from about 150, or from about 200, or from about 350, or from about 500 grams/mole, to about 1000, or to about 900, or to about 800 grams/mole.
  • the cleaning compositions of the present disclosure may include an alkoxylated phenol compound.
  • the alkoxylated phenol compound may be selected from the group consisting of an alkoxylated polyaryl phenol compound, an alkoxylated polyalkyl phenol compound, and mixtures thereof.
  • the alkoxylated phenol compound may be an alkoxylated polyaryl phenol compound.
  • the alkoxylated phenol compound may be an alkoxylated polyalkyl phenol compound.
  • the alkoxylated phenol compound may be present in the cleaning composition at a level of from about 0.2% to about 10%, or from about 0.5% to about 5%, by weight of the cleaning composition.
  • the alkoxylated phenol compound may have a weight average molecular weight between 280 and 2880.
  • the composition comprises one or more enzymes.
  • Preferred enzymes provide cleaning performance and/or fabric care benefits.
  • suitable enzymes include, but are not limited to, hemicellulases, peroxidases, proteases, cellulases, xylanases, lipases, phospholipases, esterases, cutinases, pectinases, mannanases, pectate lyases, keratinases, reductases, oxidases, phenoloxidases, lipoxygenases, ligninases, pullulanases, tannases, pentosanases, malanases, ⁇ -glucanases, arabinosidases, hyaluronidase, chondroitinase, laccase, and amylases, or mixtures thereof.
  • a typical combination is an enzyme cocktail that may comprise, for example, a protease and lipase in conjunction with amylase.
  • the aforementioned additional enzymes may be present at levels from about 0.00001% to about 2%, from about 0.0001% to about 1% or even from about 0.001% to about 0.5% enzyme protein by weight of the composition.
  • the composition comprises one or more proteases.
  • Suitable proteases include metalloproteases and serine proteases, including neutral or alkaline microbial serine proteases, such as subtilisins (EC 3.4.21.62).
  • Suitable proteases include those of animal, vegetable or microbial origin. In one aspect, such suitable protease may be of microbial origin.
  • the suitable proteases include chemically or genetically modified mutants of the aforementioned suitable proteases.
  • the suitable protease may be a serine protease, such as an alkaline microbial protease or/and a trypsin-type protease.
  • suitable neutral or alkaline proteases include:
  • subtilisins (EC 3.4.21.62), including those derived from Bacillus, such as Bacillus lentus, B. alkalophilus, B. subtilis, B. amyloliquefaciens, Bacillus pumilus and Bacillus gibsonii described in US 6,312,936 B l, US 5,679,630, US 4,760,025, US7,262,042 and WO09/021867.
  • trypsin-type or chymotrypsin-type proteases such as trypsin (e.g., of porcine or bovine origin), including the Fusarium protease described in WO 89/06270 and the chymotrypsin proteases derived from Cellumonas described in WO 05/052161 and WO 05/052146.
  • metalloproteases including those derived from Bacillus amyloliquefaciens described in WO 07/044993A2.
  • Preferred proteases include those derived from Bacillus gibsonii or Bacillus Lentus.
  • Suitable commercially available protease enzymes include those sold under the trade names Alcalase®, Savinase®, Primase®, Durazym®, Polarzyme®, Kannase®, Liquanase®, Liquanase Ultra®, Savinase Ultra®, Ovozyme®, Neutrase®, Everlase® and Esperase® by Novozymes A/S (Denmark), those sold under the tradename Maxatase®, Maxacal®, Maxapem®, Properase®, Purafect®, Purafect Prime®, Purafect Ox®, FN3® , FN4®, Excellase® and Purafect OXP® by Genencor International, those sold under the tradename Opticlean® and Optimase® by Solvay Enzymes, those available from Henkel/ Kemira, namely BLAP (sequence shown in Figure 29 of US 5,352,604 with the following mutations S99D + S 101 R + S
  • Amylases Preferably the composition may comprise an amylase.
  • Suitable alpha-amylases include those of bacterial or fungal origin. Chemically or genetically modified mutants (variants) are included.
  • a preferred alkaline alpha-amylase is derived from a strain of Bacillus, such as Bacillus licheniformis, Bacillus amyloliquefaciens, Bacillus stearothermophilus, Bacillus subtilis, or other Bacillus sp., such as Bacillus sp. NCIB 12289, NCIB 12512, NCIB 12513, DSM 9375 (USP 7,153,818) DSM 12368, DSMZ no. 12649, KSM AP1378 (WO 97/00324), KSM K36 or KSM K38 (EP 1,022,334).
  • Preferred amylases include:
  • variants exhibiting at least 90% identity with SEQ ID No. 4 in WO06/002643, the wild-type enzyme from Bacillus SP722, especially variants with deletions in the 183 and 184 positions and variants described in WO 00/60060, which is incorporated herein by reference.
  • variants exhibiting at least 95% identity with the wild-type enzyme from Bacillus sp.101 (SEQ ID NO:7 in US 6,093, 562), especially those comprising one or more of the following mutations M202, M208, S255, R172, and/or M261.
  • said amylase comprises one or more of M202L, M202V, M202S, M202T, M202I, M202Q, M202W, S255N and/or R172Q. Particularly preferred are those comprising the M202L or M202T mutations.
  • variants described in WO 09/149130 preferably those exhibiting at least 90% identity with SEQ ID NO: 1 or SEQ ID NO:2 in WO 09/149130, the wild-type enzyme from Geobacillus Stearophermophilus or a truncated version thereof.
  • Suitable commercially available alpha-amylases include DURAMYL®, LIQUEZYME®, TERM AM YL®, TERMAMYL ULTRA®, NATALASE®, SUPRAMYL®, STAINZYME®, STAINZYME PLUS®, FUNGAMYL® and BAN® (Novozymes A/S, Bagsvaerd, Denmark), KEMZYM® AT 9000 Biozym Biotech Trading GmbH Wehlistrasse 27b A- 1200 Wien Austria, RAPIDASE® , PURASTAR®, ENZYSIZE®, OPTISIZE HT PLUS®, POWERASE® and PURASTAR OXAM® (Genencor International Inc., Palo Alto, California) and KAM® (Kao, 14- 10 Nihonbashi Kayabacho, 1-chome, Chuo-ku Tokyo 103-8210, Japan).
  • suitable amylases include NATALASE®, STAINZYME® and STAINZYME PLUS
  • Lipases Preferably the invention comprises one or more lipases, including "first cycle lipases" such as those described in U.S. Patent 6,939,702 B l and US PA 2009/0217464. Preferred lipases are first-wash lipases. In one embodiment of the invention the composition comprises a first wash lipase.
  • First wash lipases includes a lipase which is a polypeptide having an amino acid sequence which: (a) has at least 90% identity with the wild-type lipase derived from Humicola lanuginosa strain DSM 4109; (b) compared to said wild-type lipase, comprises a substitution of an electrically neutral or negatively charged amino acid at the surface of the three-dimensional structure within 15A of El or Q249 with a positively charged amino acid; and (c) comprises a peptide addition at the C-terminal; and/or (d) comprises a peptide addition at the N-terminal and/or (e) meets the following limitations: i) comprises a negative amino acid in position E210 of said wild-type lipase; ii) comprises a negatively charged amino acid in the region corresponding to positions 90-101 of said wild-type lipase; and iii) comprises a neutral or negative amino acid at a position corresponding to N94 or said wild-type lipase and/or has
  • Preferred arevariants of the wild-type lipase from Thermomyces lanuginosus comprising one or more of the T231R and N233R mutations.
  • the wild-type sequence is the 269 amino acids (amino acids 23 - 291) of the Swissprot accession number Swiss-Prot 059952 (derived from Thermomyces lanuginosus (Humicola lanuginosa)).
  • Preferred lipases would include those sold under the tradenames Lipex® and Lipolex® and Lipoclean®.
  • Endoglucanases include microbial-derived endoglucanases exhibiting endo-beta-l,4-glucanase activity (E.C. 3.2.1.4), including a bacterial polypeptide endogenous to a member of the genus Bacillus which has a sequence of at least 90%, 94%, 97% and even 99% identity to the amino acid sequence SEQ ID NO:2 in US7,141,403B2) and mixtures thereof.
  • Suitable endoglucanases are sold under the tradenames Celluclean® and Whitezyme® (Novozymes A/S, Bagsvaerd, Denmark).
  • Pectate Lyases Other preferred enzymes include pectate lyases sold under the tradenames Pectawash®, Pectaway®, Xpect® and mannanases sold under the tradenames Mannaway® (all from Novozymes A/S, Bagsvaerd, Denmark), and Purabrite® (Genencor International Inc., Palo Alto, California).
  • the composition may comprise a nuclease enzyme.
  • the nuclease enzyme is an enzyme capable of cleaving the phosphodiester bonds between the nucleotide sub-units of nucleic acids.
  • the nuclease enzyme herein is preferably a deoxyribonuclease or ribonuclease enzyme or a functional fragment thereof.
  • functional fragment or part is meant the portion of the nuclease enzyme that catalyzes the cleavage of phosphodiester linkages in the DNA backbone and so is a region of said nuclease protein that retains catalytic activity.
  • it includes truncated, but functional versions, of the enzyme and/or variants and/or derivatives and/or homologues whose functionality is maintained.
  • Bleaching Agents It may be preferred for the composition to comprise one or more bleaching agents. Suitable bleaching agents other than bleaching catalysts include photobleaches, bleach activators, hydrogen peroxide, sources of hydrogen peroxide, pre-formed peracids and mixtures thereof. In general, when a bleaching agent is used, the compositions of the present invention may comprise from about 0.1% to about 50% or even from about 0.1% to about 25% bleaching agent or mixtures of bleaching agents by weight of the subject composition. Examples of suitable bleaching agents include:
  • photobleaches for example sulfonated zinc phthalocyanine sulfonated aluminium phthalocyanines, xanthene dyes, thioxanthones, and mixtures thereof;
  • Suitable preformed peracids include, but are not limited to compounds selected from the group consisting of pre-formed peroxyacids or salts thereof typically a percarboxylic acids and salts, percarbonic acids and salts, perimidic acids and salts, peroxymonosulfuric acids and salts, for example, Oxone ®, and mixtures thereof.
  • Particularly preferred peroxyacids are phthalimido-peroxy-alkanoic acids, in particular ⁇ - phthalimido peroxy hexanoic acid (PAP).
  • PAP ⁇ - phthalimido peroxy hexanoic acid
  • the peroxyacid or salt thereof has a melting point in the range of from 30°C to 60°C.
  • inorganic perhydrate salts including alkali metal salts such as sodium salts of perborate (usually mono- or tetra-hydrate), percarbonate, persulphate, perphosphate, persilicate salts and mixtures thereof.
  • inorganic perhydrate salts are typically present in amounts of from 0.05 to 40 wt%, or 1 to 30 wt% of the overall fabric and home care product and are typically incorporated into such fabric and home care products as a crystalline solid that may be coated.
  • Suitable coatings include, inorganic salts such as alkali metal silicate, carbonate or borate salts or mixtures thereof, or organic materials such as water-soluble or dispersible polymers, waxes, oils or fatty soaps; and
  • suitable leaving groups are benzoic acid and derivatives thereof - especially benzene sulphonate.
  • Suitable bleach activators include dodecanoyl oxybenzene sulphonate, decanoyl oxybenzene sulphonate, decanoyl oxybenzoic acid or salts thereof, 3,5,5-trimethyl hexanoyloxybenzene sulphonate, tetraacetyl ethylene diamine (TAED) and nonanoyloxybenzene sulphonate (NOBS).
  • dodecanoyl oxybenzene sulphonate decanoyl oxybenzene sulphonate
  • decanoyl oxybenzoic acid or salts thereof 3,5,5-trimethyl hexanoyloxybenzene sulphonate
  • TAED tetraacetyl ethylene diamine
  • NOBS nonanoyloxybenzene sulphonate
  • the compositions of the present invention may also include one or more bleach catalysts capable of accepting an oxygen atom from a peroxyacid and/or salt thereof, and transferring the oxygen atom to an oxidizeable substrate.
  • Suitable bleach catalysts include, but are not limited to: iminium cations and polyions; iminium zwitterions; modified amines; modified amine oxides; N-sulphonyl imines; N-phosphonyl imines; N-acyl imines; thiadiazole dioxides; perfluoroimines; cyclic sugar ketones and alpha amino-ketones and mixtures thereof.
  • One particularly preferred catalyst is acyl hydrazone type such as 4-(2-(2-(2- hydroxyphenylmethyl)methylene)-hydrazinyl)-2-oxoethyl)-4-methylchloride.
  • the composition may preferably comprise catalytic metal complexes.
  • metal-containing bleach catalyst is a catalyst system comprising a transition metal cation of defined bleach catalytic activity, such as copper, iron, titanium, ruthenium, tungsten, molybdenum, or manganese cations.
  • compositions herein can be catalyzed by means of a manganese compound.
  • a manganese compound such compounds and levels of use are well known in the art and include, for example, the manganese- based catalysts disclosed in U.S. 5,576,282.
  • an additional source of oxidant in the composition is not present, molecular oxygen from air providing the oxidative source.
  • Cobalt bleach catalysts useful herein are known, and are described, for example, in U.S. 5,597,936; U.S. 5,595,967.
  • the source of hydrogen peroxide/peracid and/or bleach activator is generally present in the composition in an amount of from about 0.1 to about 60 wt%, from about 0.5 to about 40 wt % or even from about 0.6 to about 10 wt% based on the fabric and home care product.
  • One or more hydrophobic peracids or precursors thereof may be used in combination with one or more hydrophilic peracid or precursor thereof.
  • hydrogen peroxide source and bleach activator will be incorporated together.
  • the amounts of hydrogen peroxide source and peracid or bleach activator may be selected such that the molar ratio of available oxygen (from the peroxide source) to peracid is from 1: 1 to 35: 1, or even 2: 1 to 10: 1.
  • the peroxide source and activator may be formulated at low pH, typically 3-5 together with a pH jump system such as borate/sorbitol.
  • the laundry care compositions of the present invention may be especially used in chlorinated water such as typically found in most domestic water supplies.
  • the leuco comprising systems may be used in conjunction with other sources of bleaching such as electrolysis and may be used in an autodosed system.
  • the composition may comprise one or more builders or a builder system.
  • the composition of the invention will typically comprise at least 1%, from 2% to 60% builder. It may be preferred that the composition comprises low levels of phosphate salt and/or zeolite, for example from 1 to 10 or 5 wt%.
  • the composition may even be substantially free of strong builder; substantially free of strong builder means "no deliberately added" zeolite and/or phosphate.
  • Typical zeolite builders include zeolite A, zeolite P and zeolite MAP.
  • a typical phosphate builder is sodium tri-polyphosphate.
  • the composition comprises chelating agents and/or crystal growth inhibitor.
  • Suitable molecules include copper, iron and/or manganese chelating agents and mixtures thereof.
  • Suitable molecules include hydroxamic acids, aminocarboxylates, aminophosphonates, succinates, salts thereof, and mixtures thereof.
  • suitable chelants for use herein include ethylenediaminetetracetates, N- (hydroxyethyl)ethylenediaminetriacetates, nitrilotriacetates, ethylenediamine tetraproprionates, triethylenetetraaminehexacetates, diethylenetriamine-pentaacetates , ethanoldiglycines , ethylenediaminetetrakis
  • chelants include the commercial DEQUEST series, and chelants from Monsanto, DuPont, and Nalco, Inc. Yet other suitable chelants include the pyridinyl N Oxide type
  • the composition comprises one or more fluorescent brightener.
  • fluorescent brightener Commercial optical brighteners which may be useful in the present invention can be classified into subgroups, which include, but are not limited to, derivatives of stilbene, pyrazoline, coumarin, carboxylic acid, methinecyanines, dibenzothiophene-5,5-dioxide, azoles, 5- and 6-membered-ring heterocycles, and other miscellaneous agents.
  • Particularly preferred brighteners are selected from: sodium 2 (4-styryl-3-sulfophenyl) -2H-napthol [1 , 2-d] triazole, disodium 4 , 4 ' -bis ⁇ [ (4-anilino- 6- (N methyl-N-2 hydroxyethyl) amino 1 , 3 , 5-triazin-2-yl) ] amino ⁇ stilbene-2-2- disulfonate, disodium 4, 4 ' -bis ⁇ [ (4-anilino-6-morpholino-l , 3, 5-triazin-2- yl) ] amino ⁇ stilbene-2-2 ' disulfonate, and disodium 4,4'- bis (2-sulfostyryl) biphenyl.
  • optical brighteners which are useful in the present compositions are those identified in U.S. Pat. No. 4,790,856 and U.S. Pat. No. 3,646,015.
  • a preferred brightener has the structure below:
  • Suitable fluorescent brightener levels include lower levels of from about 0.01, from about 0.05, from about 0.1 or even from about 0.2 wt % to upper levels of 0.5 or even 0.75 wt %.
  • the brightener may be loaded onto a clay to form a particle.
  • Preferred brighteners are totally or predominantly (typically at least 50wt%, at least 75wt%, at least 90wt%, at least 99wt%), in alpha-crystalline form.
  • a highly preferred brightener comprises C.I. fluorescent brightener 260, preferably having the following structure:
  • Enzyme Stabilizers The composition may preferably comprise enzyme stabilizers. Any conventional enzyme stabilizer may be used, for example by the presence of water-soluble sources of calcium and/or magnesium ions in the finished fabric and home care products that provide such ions to the enzymes.
  • a reversible protease inhibitor such as a boron compound including borate, or preferably 4-formyl phenylboronic acid, phenylboronic acid and derivatives thereof, or compounds such as calcium formate, sodium formate and 1,2-propane diol can be added to further improve stability.
  • Solvent System The solvent system in the present compositions can be a solvent system containing water alone or mixtures of organic solvents either without or preferably with water.
  • compositions may optionally comprise an organic solvent.
  • organic solvents include C4-14 ethers and diethers, glycols, alkoxylated glycols, C 6 -Ci6 glycol ethers, alkoxylated aromatic alcohols, aromatic alcohols, aliphatic branched alcohols, alkoxylated aliphatic branched alcohols, alkoxylated linear C1-C5 alcohols, linear C1-C5 alcohols, amines, Cg-Ci4 alkyl and cycloalkyl hydrocarbons and halohydrocarbons, and mixtures thereof.
  • organic solvents include 1,2- propanediol, 2,3 butane diol, ethanol, glycerol, ethoxylated glycerol, dipropylene glycol, methyl propane diol and mixtures thereof.
  • Other lower alcohols, C1-C4 alkanolamines such as monoethanolamine and triethanolamine, can also be used.
  • Solvent systems can be absent, for example from anhydrous solid embodiments of the invention, but more typically are present at levels in the range of from about 0.1% to about 98%, preferably at least about 1% to about 50%, more usually from about 5% to about 25%, alternatively from about 1% to about 10% by weight of the liquid detergent composition of said organic solvent.
  • These organic solvents may be used in conjunction with water, or they may be used without water
  • the composition is in the form of a structured liquid.
  • structured liquids can either be internally structured, whereby the structure is formed by primary ingredients (e.g. surfactant material) and/or externally structured by providing a three dimensional matrix structure using secondary ingredients (e.g. polymers, clay and/or silicate material), for use e.g. as thickeners.
  • the composition may comprise a structurant, preferably from 0.01wt% to 5wt%, from 0.1wt% to 2.0wt% structurant. Examples of suitable structurants are given in US2006/0205631A1, US2005/0203213A1, US7294611, US6855680.
  • the structurant is typically selected from the group consisting of diglycerides and triglycerides, ethylene glycol distearate, microcrystalline cellulose, cellulose-based materials, microfiber cellulose, hydrophobically modified alkali-swellable emulsions such as Polygel W30 (3VSigma), biopolymers, xanthan gum, gellan gum, hydrogenated castor oil, derivatives of hydrogenated castor oil such as non-ethoxylated derivatives thereof and mixtures thereof, in particular, those selected from the group of hydrogenated castor oil, derivatives of hydrogenated castor oil, microfibullar cellulose, hydroxyfunctional crystalline materials, long chain fatty alcohols, 12- hydroxystearic acids, clays and mixtures thereof.
  • diglycerides and triglycerides ethylene glycol distearate, microcrystalline cellulose, cellulose-based materials, microfiber cellulose, hydrophobically modified alkali-swellable emulsions such as Polygel W30 (3VSigma), biopolymers,
  • One preferred structurant is described in US Patent No. 6,855,680 which defines suitable hydroxyfunctional crystalline materials in detail.
  • Preferred is hydrogenated castor oil.
  • Some structurants have a thread-like structuring system having a range of aspect ratios.
  • Another preferred structurant is based on cellulose and may be derived from a number of sources including biomass, wood pulp, citrus fibers and the like.
  • the composition of the present invention may comprise a high melting point fatty compound.
  • the high melting point fatty compound useful herein has a melting point of 25°C or higher, and is selected from the group consisting of fatty alcohols, fatty acids, fatty alcohol derivatives, fatty acid derivatives, and mixtures thereof. Such compounds of low melting point are not intended to be included in this section.
  • Non-limiting examples of the high melting point compounds are found in International Cosmetic Ingredient Dictionary, Fifth Edition, 1993, and CTFA Cosmetic Ingredient Handbook, Second Edition, 1992.
  • the high melting point fatty compound is preferably included in the composition at a level of from 0.1% to 40%, preferably from 1% to 30%, more preferably from 1.5% to 16% by weight of the composition, from 1.5% to 8% in view of providing improved conditioning benefits such as slippery feel during the application to wet hair, softness and moisturized feel on dry hair.
  • compositions of the present invention may contain a cationic polymer. Concentrations of the cationic polymer in the composition typically range from 0.05% to 3%, in another embodiment from 0.075% to 2.0%, and in yet another embodiment from 0.1% to 1.0%. Suitable cationic polymers will have cationic charge densities of at least 0.5 meq/gm, in another embodiment at least 0.9 meq/gm, in another embodiment at least 1.2 meq/gm, in yet another embodiment at least 1.5 meq/gm, but in one embodiment also less than 7 meq/gm, and in another embodiment less than 5 meq/gm, at the pH of intended use of the composition, which pH will generally range from pH 3 to pH 9, in one embodiment between pH 4 and pH 8.
  • cationic charge density of a polymer refers to the ratio of the number of positive charges on the polymer to the molecular weight of the polymer.
  • the average molecular weight of such suitable cationic polymers will generally be between 10,000 and 10 million, in one embodiment between 50,000 and 5 million, and in another embodiment between 100,000 and 3 million.
  • Suitable cationic polymers for use in the compositions of the present invention contain cationic nitrogen-containing moieties such as quaternary ammonium or cationic protonated amino moieties.
  • Any anionic counterions can be used in association with the cationic polymers so long as the polymers remain soluble in water, in the composition, or in a coacervate phase of the composition, and so long as the counterions are physically and chemically compatible with the essential components of the composition or do not otherwise unduly impair product performance, stability or aesthetics.
  • Nonlimiting examples of such counterions include halides (e.g., chloride, fluoride, bromide, iodide), sulfate and methylsulfate.
  • Nonlimiting examples of such polymers are described in the CTFA Cosmetic Ingredient Dictionary, 3rd edition, edited by Estrin, Crosley, and Haynes, (The Cosmetic, Toiletry, and Fragrance Association, Inc., Washington, D.C. (1982)).
  • Suitable cationic polymers for use in the composition include polysaccharide polymers, cationic guar gum derivatives, quaternary nitrogen- containing cellulose ethers, synthetic polymers, copolymers of etherified cellulose, guar and starch.
  • the cationic polymers herein are either soluble in the composition or are soluble in a complex coacervate phase in the composition formed by the cationic polymer and the anionic, amphoteric and/or zwitterionic surfactant component described hereinbefore.
  • Complex coacervates of the cationic polymer can also be formed with other charged materials in the composition.
  • Suitable cationic polymers are described in U.S. Pat. Nos. 3,962,418; 3,958,581; and U.S. Publication No. 2007/0207109A1.
  • Nonionic Polymer The composition of the present invention may include a nonionic polymer as a conditioning agent.
  • a nonionic polymer as a conditioning agent.
  • Polyalkylene glycols having a molecular weight of more than 1000 are useful herein. Useful are those having the following general formula:
  • conditioning agents and in particular silicones, may be included in the composition.
  • the conditioning agents useful in the compositions of the present invention typically comprise a water insoluble, water dispersible, non-volatile, liquid that forms emulsified, liquid particles.
  • Suitable conditioning agents for use in the composition are those conditioning agents characterized generally as silicones (e.g., silicone oils, cationic silicones, silicone gums, high refractive silicones, and silicone resins), organic conditioning oils (e.g., hydrocarbon oils, polyolefins, and fatty esters) or combinations thereof, or those conditioning agents which otherwise form liquid, dispersed particles in the aqueous surfactant matrix herein.
  • Such conditioning agents should be physically and chemically compatible with the essential components of the composition, and should not otherwise unduly impair product stability, aesthetics or performance.
  • the concentration of the conditioning agent in the composition should be sufficient to provide the desired conditioning benefits. Such concentration can vary with the conditioning agent, the conditioning performance desired, the average size of the conditioning agent particles, the type and concentration of other components, and other like factors.
  • the concentration of the silicone conditioning agent typically ranges from about 0.01% to about 10%.
  • suitable silicone conditioning agents, and optional suspending agents for the silicone are described in U.S. Reissue Pat. No. 34,584, U.S. Pat. Nos. 5,104,646; 5,106,609; 4,152,416; 2,826,551; 3,964,500; 4,364,837; 6,607,717; 6,482,969; 5,807,956; 5,981,681; 6,207,782; 7,465,439; 7,041,767; 7,217,777; US Patent Application Nos. 2007/0286837A1; 2005/0048549A1; 2007/0041929A1; British Pat. No.
  • compositions of the present invention may also comprise from about 0.05% to about 3% of at least one organic conditioning oil as the conditioning agent, either alone or in combination with other conditioning agents, such as the silicones (described herein).
  • Suitable conditioning oils include hydrocarbon oils, polyolefins, and fatty esters.
  • Hygiene Agent The compositions of the present invention may also comprise components to deliver hygiene and/or malodour benefits such as one or more of zinc ricinoleate, thymol, quaternary ammonium salts such as Bardac®, polyethylenimines (such as Lupasol® from BASF) and zinc complexes thereof, silver and silver compounds, especially those designed to slowly release Ag+ or nano- silver dispersions.
  • composition may comprise probiotics, such as those described in WO2009/043709.
  • the composition may preferably comprise suds boosters if high sudsing is desired. Suitable examples are the C10-C16 alkanolamides or C10-C14 alkyl sulphates, which are preferably incorporated at 1%-10% levels.
  • the C10-C14 monoethanol and diethanol amides illustrate a typical class of such suds boosters. Use of such suds boosters with high sudsing adjunct surfactants such as the amine oxides, betaines and sultaines noted above is also advantageous.
  • water- soluble magnesium and/or calcium salts such as MgCl 2 , MgSC , CaCl 2 , CaSC and the like, can be added at levels of, typically, 0.1 %-2%, to provide additional suds and to enhance grease removal performance.
  • Suds Suppressor Compounds for reducing or suppressing the formation of suds may be incorporated into the compositions of the present invention. Suds suppression can be of particular importance in the so-called "high concentration cleaning process" as described in U.S. Pat. No. 4,489,455 and 4,489,574, and in front- loading -style washing machines.
  • a wide variety of materials may be used as suds suppressors, and suds suppressors are well known to those skilled in the art. See, for example, Kirk Othmer Encyclopedia of Chemical Technology, Third Edition, Volume 7, pages 430-447 (John Wiley & Sons, Inc., 1979).
  • suds suppressors include monocarboxylic fatty acid and soluble salts therein, high molecular weight hydrocarbons such as paraffin, fatty acid esters (e.g., fatty acid triglycerides), fatty acid esters of monovalent alcohols, aliphatic C18-C40 ketones (e.g., stearone), N-alkylated amino triazines, waxy hydrocarbons preferably having a melting point below about 100 °C, silicone suds suppressors, and secondary alcohols. Particularly useful silicone suds suppressors are based on diphenyl containing silicones.
  • Silicone suds suppressors are typically utilized in amounts up to 2.0%, by weight, of the detergent composition, although higher amounts may be used.
  • Pearlescent Agents Pearlescent agents as described in WO2011/163457 may be incorporated into the compositions of the invention.
  • the pearlescent agents can be crystalline or glassy solids, transparent or translucent compounds capable of reflecting and refracting light to produce a pearlescent effect.
  • the pearlescent agents are crystalline particles insoluble in the composition in which they are incorporated.
  • the pearlescent agents have the shape of thin plates or spheres. Particle size of the pearlescent agent is typically below 200microns, preferably below lOOmicrons, more preferably below 50microns.
  • Inorganic pearlescent agents include aluminosilicates and/or borosilicates.
  • aluminosilicates and/or borosilicates which have been treated to have a very high refractive index, preferably silica, metal oxides, oxychloride coated aluminosilicate and/or borosilicates.
  • More preferred inorganic pearlescent agent is mica, even more preferred titanium dioxide treated mica such as BASF Mearlin Superfine.
  • compositions may comprise from 0.005% to 3.0%wt, preferably from 0.01 % to 1%, by weight of the composition of the 100% active pearlescent agents.
  • the pearlescent agents may be organic or inorganic.
  • the composition can comprise organic and/or inorganic pearlescent agent.
  • composition comprises an organic pearlescent agent
  • it is comprised at an active level of from 0.05% to 2.0%wt, preferably from 0.1 % to 1.0% by weight of the composition of the 100% active organic pearlescent agents.
  • Suitable organic pearlescent agents include monoester and/or diester of alkylene glycols such as ethylene glycol distearate.
  • the composition might also comprise an inorganic pearlescent agent.
  • the composition comprises an inorganic pearlescent agent, it is comprised at an active level of from 0.005% to 1.0%wt, preferably from 0.01 % to 0.2% by weight of the composition of the 100% active inorganic pearlescent agents.
  • the composition further comprises a plurality of suspension particles at a level of from about 0.01 % to about 5% by weight, alternatively from about 0.05% to about 4% by weight, alternatively from about 0.1% to about 3% by weight.
  • suitable suspension particles are provided in U.S. Patent No. 7,169,741 and U.S. Patent Publ. No. 2005/0203213, the disclosures of which are incorporated herein by reference.
  • These suspended particles can comprise a liquid core or a solid core. Detailed description of these liquid core and solid core particles, as well as description of preferred particle size, particle shape, particle density, and particle burst strength are described in U.S. Patent Application No. 12/370,714, the disclosure of which is incorporated herein by reference.
  • the particles may be any discrete and visually distinguishable form of matter, including but not limiting to (deformable) beads, encapsulates, polymeric particles like plastic, metals (e.g. foil material, flakes, glitter), (interference) pigments, minerals (salts, rocks, pebbles, lava, glass/silica particles, talc), plant materials (e.g. pits or seeds, plant fibers, stalks, stems, leaves or roots), solid and liquid crystals, and the like. Different particle shapes are possible, ranging from spherical to tabular.
  • the suspension particles may be gas or air bubbles.
  • the diameter of each bubble may be from about 50 to about 2000 microns and may be present at a level of about 0.01 to about 5% by volume of the composition alternatively from about 0.05% to about 4% by volume of the composition, alternatively from about 0.1% to about 3% by volume of the composition.
  • the composition might also comprise an opacifier.
  • an "opacifier” is a substance added to a material in order to make the ensuing system opaque.
  • the opacifier is Acusol, which is available from Dow Chemicals.
  • Acusol opacifiers are provided in liquid form at a certain % solids level.
  • the pH of Acusol opacifiers ranges from 2.0 to 5.0 and particle sizes range from 0.17 to 0.45 um.
  • Acusol OP303B and 301 can be used.
  • the opacifier may be an inorganic opacifier.
  • the inorganic opacifier can be T1O2, ZnO, talc, CaC0 3 , and combination thereof.
  • the composite opacifier- microsphere material is readily formed with a preselected specific gravity, so that there is little tendency for the material to separate.
  • the composition may optionally comprises a hydrotrope in an effective amount, i.e. from about 0% to 15%, or about 1% to 10% , or about 3% to about 6%, so that compositions are compatible in water.
  • Suitable hydrotropes for use herein include anionic-type hydrotropes, particularly sodium, potassium, and ammonium xylene sulfonate, sodium, potassium and ammonium toluene sulfonate, sodium potassium and ammonium cumene sulfonate, and mixtures thereof, as disclosed in U.S. Patent 3,915,903.
  • the composition may optionally contain an anti-oxidant present in the composition from about 0.001 to about 2% by weight.
  • the antioxidant is present at a concentration in the range 0.01 to 0.08% by weight. Mixtures of anti-oxidants may be used.
  • Anti-oxidants are substances as described in Kirk-Othmer (Vol. 3, page 424) and In Ullmann' s Encyclopedia (Vol. 3, page 91).
  • alkylated phenols having the general formula:
  • R is C1-C22 linear or branched alkyl, preferably methyl or branched C 3 -C 6 alkyl, Ci-Ce alkoxy, preferably methoxy; Ri is a C 3 -C 6 branched alkyl, preferably tert-butyl; x is 1 or 2.
  • Hindered phenolic compounds are a preferred type of alkylated phenols having this formula.
  • a preferred hindered phenolic compound of this type is 3,5-di-tert-butyl-4-hydroxytoluene (BHT).
  • the anti-oxidant used in the composition may be selected from the group consisting of ⁇ -, ⁇ -, ⁇ -, ⁇ — tocopherol, ethoxyquin, 2,2,4-trimethyl- l,2-dihydroquinoline, 2,6-di-tert-butyl hydroquinone, tert-butyl hydroxyanisole, , lignosulphonic acid and salts thereof, and mixtures thereof.
  • ethoxyquin l,2-dihydro-6-ethoxy-2,2,4-trimethylquinoline
  • RaschigTM marketed under the name RaluquinTM by the company RaschigTM.
  • a further class of anti-oxidants which may be suitable for use in the composition is a benzofuran or benzopyran derivative having the formula:
  • Ri and R 2 are each independently alkyl or Ri and R 2 can be taken together to form a C5- Ce cyclic hydrocarbyl moiety;
  • B is absent or CH 2 ;
  • R 4 is Ci-Ce alkyl;
  • R5 is hydrogen or -C(0)R 3 wherein R 3 is hydrogen or C1-C19 alkyl;
  • R 6 is Ci-Ce alkyl;
  • R7 is hydrogen or Ci-Ce alkyl;
  • X is - CH 2 OH, or -CH 2 A wherein A is a nitrogen comprising unit, phenyl, or substituted phenyl.
  • Preferred nitrogen comprising A units include amino, pyrrolidino, piperidino, morpholino, piperazino, and mixtures thereof.
  • Anti-oxidants such as tocopherol sorbate, butylated hydroxyl benxoic acids and their salts, gallic acid and its alkyl esters, uric acid and its salts, sorbic acid and its salts, and dihydroxyfumaric acid and its salts may also be used.
  • the most preferred types of anti-oxidant for use in the composition are 3,5-di-tert-butyl-4-hydroxytoluene (BHT), -, ⁇ -, ⁇ -, ⁇ -tocopherol, 1,2- benzisothiazoline-3-one (Proxel GXLTM) and mixtures thereof.
  • the cleaning compositions of the present invention may also contain antimicrobial agents.
  • Cationic active ingredients may include but are not limited to n-alkyl dimethyl benzyl ammonium chloride, alkyl dimethyl ethyl benzyl ammonium chloride, dialkyl dimethyl quaternary ammonium compounds such as didecyl dimethyl ammonium chloride, N,N-didecyl-Nmethyl-poly(oxyethyl) ammonium propionate, dioctyl didecyl ammonium chloride, also including quaternary species such as benzethonium chloride and quaternary ammonium compounds with inorganic or organic counter ions such as bromine, carbonate or other moieties including dialkyl dimethyl ammonium carbonates, as well as antimicrobial amines such as Chlorhexidine Gluconate, PHMB (Polyhexamethylene biguanide), salt of a biguanide, a substituted biguanide
  • Packaging Any conventional packaging may be used and the packaging may be fully or partially transparent so that the consumer can see the color of the laundry care composition which may be provided or contributed to by the color of the dyes essential to the invention. UV absorbing compounds may be included in some or all of the packaging.
  • the laundry care compositions of the invention may be aqueous (typically above 2 wt% or even above 5 or 10 wt% total water, up to 90 or up to 80wt% or 70 wt% total water) or non-aqueous (typically below 2 wt% total water content).
  • the compositions of the invention will be in the form of an aqueous solution or uniform dispersion or suspension of surfactant, shading dye, and certain optional other ingredients, some of which may normally be in solid form, that have been combined with the normally liquid components of the composition, such as the liquid alcohol ethoxylate nonionic, the aqueous liquid carrier, and any other normally liquid optional ingredients.
  • the laundry care compositions of the invention preferably have viscosity from 1 to 1500 centipoises (1-1500 mPa*s), more preferably from 100 to 1000 centipoises (100-1000 mPa*s), and most preferably from 200 to 500 centipoises (200-500 mPa*s) at 20s- 1 and 21°C. Viscosity can be determined by conventional methods. Viscosity may be measured using an AR 550 rheometer from TA instruments using a plate steel spindle at 40 mm diameter and a gap size of 500 ⁇ .
  • the high shear viscosity at 20s- 1 and low shear viscosity at 0.05-1 can be obtained from a logarithmic shear rate sweep from 0.1- 1 to 25-1 in 3 minutes time at 21°C.
  • the preferred rheology described therein may be achieved using internal existing structuring with detergent ingredients or by employing an external rheology modifier.
  • the laundry care compositions, such as detergent liquid compositions have a high shear rate viscosity of from about 100 centipoise to 1500 centipoise, more preferably from 100 to 1000 cps.
  • Unit Dose laundry care compositions, such as detergent liquid compositions have high shear rate viscosity of from 400 to lOOOcps.
  • Laundry care compositions such as laundry softening compositions typically have high shear rate viscosity of from 10 to 1000, more preferably from 10 to 800 cps, most preferably from 10 to 500 cps.
  • Hand dishwashing compositions have high shear rate viscosity of from 300 to 4000 cps, more preferably 300 to 1000 cps.
  • the liquid compositions preferably the laundry care composition herein can be prepared by combining the components thereof in any convenient order and by mixing, e.g., agitating, the resulting component combination to form a phase stable liquid laundry care composition.
  • a liquid matrix is formed containing at least a major proportion, or even substantially all, of the liquid components, e.g., nonionic surfactant, the non- surface active liquid carriers and other optional liquid components, with the liquid components being thoroughly admixed by imparting shear agitation to this liquid combination.
  • the liquid components e.g., nonionic surfactant, the non- surface active liquid carriers and other optional liquid components
  • shear agitation for example, rapid stirring with a mechanical stirrer may usefully be employed. While shear agitation is maintained, substantially all of any anionic surfactants and the solid form ingredients can be added.
  • Agitation of the mixture is continued, and if necessary, can be increased at this point to form a solution or a uniform dispersion of insoluble solid phase particulates within the liquid phase.
  • particles of any enzyme material to be included e.g., enzyme prills, are incorporated.
  • one or more of the solid components may be added to the agitated mixture as a solution or slurry of particles premixed with a minor portion of one or more of the liquid components.
  • agitation of the mixture is continued for a period of time sufficient to form compositions having the requisite viscosity and phase stability characteristics. Frequently this will involve agitation for a period of from about 30 to 60 minutes.
  • the leuco colorants of the present invention have been found to be suitable for use in liquid laundry care compositions having a wide range of pH values.
  • the inventive leuco colorants have been found to be suitable for use in liquid laundry care compositions having a pH of greater than or equal to 10.
  • the inventive leuco colorants have also been found to be suitable for use in liquid laundry care compositions having a pH of less than 10.
  • the leuco colorant are stable in laundry care compositions having pH values of greater than or equal to 10 and less than or equal to 10.
  • the composition is provided in the form of a unitized dose, either tablet form or preferably in the form of a liquid/solid (optionally granules)/gel/paste held within a water-soluble film in what is known as a pouch or pod.
  • the composition can be encapsulated in a single or multi-compartment pouch. Multi-compartment pouches are described in more detail in EP-A-2133410.
  • the composition of the invention may be in one or two or more compartments, thus the dye may be present in one or more compartments, optionally all compartments. Non-shading dyes or pigments or other aesthetics may also be used in one or more compartments.
  • the composition is present in a single compartment of a multicompartment pouch.
  • Preferred film materials are polymeric materials.
  • the film material can be obtained, for example, by casting, blow-molding, extrusion or blown extrusion of the polymeric material, as known in the art.
  • Preferred polymers, copolymers or derivatives thereof suitable for use as pouch material are selected from polyvinyl alcohols, polyvinyl pyrrolidone, polyalkylene oxides, acrylamide, acrylic acid, cellulose, cellulose ethers, cellulose esters, cellulose amides, polyvinyl acetates, polycarboxylic acids and salts, polyaminoacids or peptides, polyamides, polyacrylamide, copolymers of maleic/acrylic acids, polysaccharides including starch and gelatine, natural gums such as xanthum and carragum.
  • More preferred polymers are selected from polyacrylates and water-soluble acrylate copolymers, methylcellulose, carboxymethylcellulose sodium, dextrin, ethylcellulose, hydroxyethyl cellulose, hydroxypropyl methylcellulose, maltodextrin, polymethacrylates, and most preferably selected from polyvinyl alcohols, polyvinyl alcohol copolymers and hydroxypropyl methyl cellulose (HPMC), and combinations thereof.
  • the level of polymer in the pouch material for example a PVA polymer, is at least 60%.
  • the polymer can have any weight average molecular weight, preferably from about 1000 to 1,000,000, more preferably from about 10,000 to 300,000 yet more preferably from about 20,000 to 150,000.
  • Mixtures of polymers can also be used as the pouch material. This can be beneficial to control the mechanical and/or dissolution properties of the compartments or pouch, depending on the application thereof and the required needs.
  • Suitable mixtures include for example mixtures wherein one polymer has a higher water-solubility than another polymer, and/or one polymer has a higher mechanical strength than another polymer.
  • mixtures of polymers having different weight average molecular weights for example a mixture of PVA or a copolymer thereof of a weight average molecular weight of about 10,000-40,000, preferably around 20,000, and of PVA or copolymer thereof, with a weight average molecular weight of about 100,000 to 300,000, preferably around 150,000.
  • polymer blend compositions for example comprising hydroly tic ally degradable and water-soluble polymer blends such as polylactide and polyvinyl alcohol, obtained by mixing polylactide and polyvinyl alcohol, typically comprising about 1-35% by weight polylactide and about 65% to 99% by weight polyvinyl alcohol.
  • polymers which are from about 60% to about 98% hydrolysed, preferably about 80% to about 90% hydrolysed, to improve the dissolution characteristics of the material.
  • compartments of the present invention may be employed in making the compartments of the present invention.
  • a benefit in selecting different films is that the resulting compartments may exhibit different solubility or release characteristics.
  • PVA films known under the MonoSol trade reference M8630, M8900, H8779 and those described in US 6 166 117 and US 6 787 512 and PVA films of corresponding solubility and deformability characteristics.
  • the film material herein can also comprise one or more additive ingredients.
  • plasticizers for example glycerol, ethylene glycol, diethyleneglycol, propylene glycol, sorbitol and mixtures thereof.
  • Other additives include functional detergent additives to be delivered to the wash water, for example organic polymeric dispersants, etc.
  • the laundry care compositions may be in a solid form. Suitable solid forms include tablets and particulate forms, for example, granular particles, flakes or sheets. Various techniques for forming detergent compositions in such solid forms are well known in the art and may be used herein.
  • the leuco colorant is provided in particulate form, optionally including additional but not all components of the laundry detergent composition.
  • the colorant particulate is combined with one or more additional particulates containing a balance of components of the laundry detergent composition.
  • the colorant, optionally including additional but not all components of the laundry care composition may be provided in an encapsulated form, and the shading dye encapsulate is combined with particulates containing a substantial balance of components of the laundry care composition.
  • compositions of this invention can be used to form aqueous washing/treatment solutions for use in the laundering/treatment of fabrics.
  • an effective amount of such compositions is added to water, for example in a conventional fabric automatic washing machine, to form such aqueous laundering solutions.
  • the aqueous washing solution so formed is then contacted, typically under agitation, with the fabrics to be laundered/treated therewith.
  • An effective amount of the liquid detergent compositions herein added to water to form aqueous laundering solutions can comprise amounts sufficient to form from about 500 to 7,000 ppm of composition in aqueous washing solution, or from about 1,000 to 3,000 ppm of the laundry care compositions herein will be provided in aqueous washing solution.
  • the wash liquor is formed by contacting the laundry care composition with wash water in such an amount so that the concentration of the laundry care composition in the wash liquor is from above Og/1 to 5g/l, or from lg/1, and to 4.5g/l, or to 4.0g/l, or to 3.5g/l, or to 3.0g/l, or to 2.5g/l, or even to 2. Og/1, or even to 1.5g/l.
  • the method of laundering fabric or textile may be carried out in a top-loading or front-loading automatic washing machine, or can be used in a handwash laundry application. In these applications, the wash liquor formed and concentration of laundry detergent composition in the wash liquor is that of the main wash cycle. Any input of water during any optional rinsing step(s) is not included when determining the volume of the wash liquor.
  • the wash liquor may comprise 40 liters or less of water, or 30 liters or less, or 20 liters or less, or 10 liters or less, or 8 liters or less, or even 6 liters or less of water.
  • the wash liquor may comprise from above 0 to 15 liters, or from 2 liters, and to 12 liters, or even to 8 liters of water.
  • from 0.01kg to 2kg of fabric per liter of wash liquor is dosed into said wash liquor.
  • from 0.01kg, or from 0.05kg, or from 0.07kg, or from 0.10kg, or from 0.15kg, or from 0.20kg, or from 0.25kg fabric per liter of wash liquor is dosed into said wash liquor.
  • the composition is contacted to water to form the wash liquor.
  • Such compositions are typically employed at concentrations of from about 500 ppm to about 15,000 ppm in solution.
  • the wash solvent is water
  • the water temperature typically ranges from about 5 °C to about 90 °C and, when the situs comprises a fabric, the water to fabric ratio is typically from about 1: 1 to about 30: 1.
  • the wash liquor comprising the laundry care composition of the invention has a pH of from 3 to 11.5.
  • such method comprises the steps of optionally washing and/or rinsing said surface or fabric, contacting said surface or fabric with any composition disclosed in this specification then optionally washing and/or rinsing said surface or fabric is disclosed, with an optional drying step.
  • the fabric may comprise any fabric capable of being laundered in normal consumer or institutional use conditions, and the invention is suitable for cellulosic substrates and in some aspects also suitable for synthetic textiles such as polyester and nylon and for treatment of mixed fabrics and/or fibers comprising synthetic and cellulosic fabrics and/or fibers.
  • synthetic fabrics are polyester, nylon, these may be present in mixtures with cellulosic fibers, for example, polycotton fabrics.
  • the solution typically has a pH of from 7 to 11, more usually 8 to 10.5.
  • the compositions are typically employed at concentrations from 500 ppm to 5,000 ppm in solution.
  • the water temperatures typically range from about 5°C to about 90°C.
  • the water to fabric ratio is typically from about 1: 1 to about 30: 1.
  • the invention provides a method of treating a textile.
  • the method preferably comprises the steps of (i) treating a textile with an aqueous solution containing a leuco composition as described herein, (ii) optionally, rinsing the textile, and (iii) drying the textile.
  • the invention provides a method of treating a textile comprising the steps of: (i) treating a textile with an aqueous solution containing a leuco composition as described herein, the aqueous solution comprising from 10 ppb to 5000 ppm of at least one leuco compound and from 0.0 g/L to 3 g/L of a surfactant; (ii) optionally rinsing; and (iii) drying the textile.
  • the leuco composition utilized in this method can be any of the leuco compositions described herein.
  • the aqueous solution utilized in the method can be created by adding a leuco composition directly to an aqueous medium or by adding a laundry care composition containing a leuco composition to an aqueous medium. Test Methods
  • Fabric swatches used in the test methods herein are obtained from Testfabrics, Inc. West Pittston, PA, and are 100% Cotton, Style 403 (cut to 2" x 2") and/or Style 464 (cut to 4" x 6"), and an unbrightened multifiber fabric, specifically Style 41 (5cm x 10cm).
  • All reflectance spectra and color measurements, including L*, a*, b*, K/S, and Whiteness Index (WI CIE) values on dry fabric swatches, are made using one of four spectrophotometers: (1) a Konica-Minolta 3610d reflectance spectrophotometer (Konica Minolta Sensing Americas, Inc., Ramsey, NJ, USA; D65 illumination, 10° observer, UV light excluded), (2) a LabScan XE reflectance spectrophotometer (HunterLabs, Reston, VA; D65 illumination, 10° observer, UV light excluded), (3) a Color-Eye® 7000A (GretagMacbeth, New Windsor, NY, USA; D65 light, UV excluded), or (4) a Color i7 spectrophotometer (X-rite, Inc., Grand Rapids, MI , USA; D65 light, UV excluded).
  • a Konica-Minolta 3610d reflectance spectrophotometer Konica Minol
  • Cotton swatches (Style 464) are stripped prior to use by washing at 49 °C two times with heavy duty liquid laundry detergent nil brightener (1.55 g/L in aqueous solution).
  • a concentrated stock solution of each leuco composition to be tested is prepared in a solvent selected from ethanol or 50:50 ethanokwater, preferably ethanol.
  • a base wash solution is prepared by dissolving AATCC heavy duty liquid laundry detergent nil brightener (5.23 g/1.0 L) in deionized water. Four stripped cotton swatches are weighed together and placed in a 250mL Erlenmeyer flask along with two 10mm glass marbles. A total of three such flasks are prepared for each wash solution to be tested. The base wash solution is dosed with the leuco conjugate stock to achieve a wash solution with the desired 2.00 x 10 "6 equivalents/L wash concentration of the leuco conjugate.
  • the flasks are placed on a Model 75 wrist action shaker (Burrell Scientific, Inc., Pittsburg, PA) and agitated at the maximum setting for 12 minutes, after which the wash solution is removed by aspiration, a volume of rinse water (0 gpg) equivalent to the amount of wash solution used is added.
  • a volume of rinse water (0 gpg) equivalent to the amount of wash solution used is added.
  • Each flask is dosed with a 1000 gpg stock hardness solution to achieve a final rinse hardness of 6 gpg (3: 1 Ca:Mg) before agitating 4 more minutes.
  • the rinse is removed by aspiration and the fabric swatches are spun dry (Mini Countertop Spin Dryer, The Laundry Alternative Inc., Nashua, NH) for 1 minute, then placed in a food dehydrator set at 135 °F to dry in the dark for 2 hours. Following this drying procedure, the samples can be stored in the dark or exposed to light for varying amounts of time before measuring the properties of the fabric.
  • Method I includes exposure of the dried fabrics to simulated sunlight for various increments of time before measurements are taken, and the LCE value is set to the maximum value obtained from the set of exposure times described below.
  • the values of the 12 swatches generated for each leuco colorant are averaged to arrive at the sample values for L*, a*, b* and WI CIE at each time point t.
  • control base wash solution is prepared using AATCC heavy duty liquid laundry detergent nil brightener (5.23 g/1.0 L) in deionized water
  • the leuco colorant efficiency (LCE) of the leuco colorant in the laundry care formulation is calculated based on the data collected at each time point t using the following equation:
  • AWI WI CIE (after wash) - WI CIE (before wash)
  • the specified cotton fabrics post-dry are exposed to simulated sunlight for 15 min, 30 min, 45 min, 60 min, 75 min, 90 min, 120 min, and 240 min.
  • the L*, a*, b*, and Whiteness Index (WI CIE) values for the cotton fabrics are measured on the swatches after each exposure period.
  • the calculation of the LCE and the AWI value at each exposure time point is as described in Method LA. above, and the LCE values and the AWI values for the sample and control laundry care formulations are set to the maximum values obtained from the set of exposure times listed.
  • the relative hue angle delivered by a leuco colorant to cotton fabrics treated according to Method I described above is determined as follows. a) The a* and b* values of the 12 swatches from each solution are averaged and the following formulas used to determine Aa* and Ab*:
  • b) If the absolute value of both Aa* and Ab* ⁇ 0.25, no Relative Hue Angle (RHA) is calculated. If the absolute value of either Aa* or Ab* is > 0.25, the RHA is determined using one of the following formulas:
  • RHA ATAN2(Aa*,Ab*) for Ab* > 0
  • RHA 360 + ATAN2(Aa*,Ab*) for Ab* ⁇ 0
  • a relative hue angle can be calculated for each time point where data is collected in either the dark post-dry or light post-dry assessments. Any of these points may be used to satisfy the requirements of a claim.
  • the material to be tested is either a leuco colorant according to the instant invention, or the dye that represents the second colored state of the leuco colorant (for example, a
  • triarylmethane dye A total of 250-255 mg of the material to be tested is weighed into a 4 oz. glass jar and 50.0 mL deionized water (Barnstead B-Pure System, about 17.27 ohm) is added along with a magnetic stir bar. The jar is capped, placed on a magnetic stir plate, and the mixture stirred for one hour at 22.0 °C. Thereafter the stirring is stopped and the mixture left to stand undisturbed for one hour. At the end of that time, 10.0 mL of solution is pulled into a syringe which is then fitted with a glass fiber Acrodisc® filter and the aliquot filtered into a 20 mL scintillation vial.
  • deionized water Barnstead B-Pure System, about 17.27 ohm
  • a VWR LabMax Pipettor is used to pipette to deliver 45.0 microliters of the filtered solution into each of eight separate wells of a 96-well plate.
  • the solutions are tested at approximately 22.0 °C with a Kibron Delta 8 Tensiometer and the average value of the eight measured replicates reported as the Surface Tension Value in mN/m.
  • leuco colorants 1 and 2 were tested using leuco colorants 1 and 2 to determine the extent to which the leuco compounds delivered improved whiteness to consumer-sourced aged cotton fabric and to clean, stripped new cotton fabric. The structures of the leuco colorants tested are shown below.
  • AMI Whiteness Index
  • the change in whiteness due to inclusion of the leuco colorant in the wash is obtained by comparing the change in Whiteness Index for the same fabrics washed in the two detergent formulations; the control (nil leuco colorant) and the sample (with leuco colorant), and is calculated by the equation provided in the method. Results of the wash testing are shown in Table 2 below.
  • a leuco colorant comprising moieties with both EO and PO oxyalkylene groups has a consistently larger bias for delivering whiteness to aged consumer cotton relative to new, clean cotton than the bias obtained from a leuco colorant comprising moieties with EO oxyalkylene units alone.
  • This means use of such leuco colorants (for example, 2) will provide the same whiteness benefit to aged cotton as do leuco compounds having only EO oxylakylene groups (for example, 1) without compromising the color integrity of new cotton garments.
  • the inventive leuco colorants of the present invention provide the consumer with a clear advantage, depositing effectively where they are needed (aged cotton prone to show yellowing) while avoiding deposition on new, clean fabrics where color adjustment is neither needed nor desired.
  • WI CIE Whiteness Index
  • AWI WI CIE (after wash) - WI CIE (before wash)
  • the change in whiteness due to inclusion of the leuco colorant J in the wash is obtained by comparing the change in whiteness Index for the same style # fabrics washed in the two detergent formulations A and B, and is calculated by the following equation:
  • 5AWI ciE AWI (Detergent B) - AWI (Detergent A)
  • Results for the fabrics are tabulated below, organized numerically by the value of the 5AWI CIE obtained. The identity of the fabrics tested is given in the Table 4 below along with the results.
  • Citric Acid 2.50 3.96 1.88 1.98 0.90 2.50 0.60
  • Optical Brightener 1 1.00 0.80 0.10 0.30 0.05 0.50 0.001
  • Chelant 1 0.15 0.15 0.11 0.07 0.50 0.11 0.80
  • Polymer 4 0.80 0.81 0.60 0.40 1.00 1.00 -
  • Amylase 1 0.30 - 0.30 0.10 - 0.40 0.10
  • compositions 8 to 12 comprise a single unit dose compartment.
  • the film used to encapsulate the compositions is polyvinyl- alcohol-based film.
  • Amylase 1 0.20 0.11 0.30 0.50 0.05
  • Amylase 2 0.11 0.20 0.10 - 0.50
  • Dispersin B 0.010 0.05 0.005 0.005 -
  • Enzyme levels are reported as raw material.
  • the unit dose has three compartments, but similar compositions can be made with two, four or five compartments.
  • the film used to encapsulate the compartments is polyvinyl alcohol. Ingredients % weight
  • Chelant 2 1.1 2.0 0.6 1.5
  • Amylase 1 0.20 0.20 0.200 0.30
  • AE1.8S is C 12-15 alkyl ethoxy (1.8) sulfate
  • AE3S is Cms alkyl ethoxy (3) sulfate
  • AE7 is C 12-13 alcohol ethoxylate, with an average degree of ethoxylation of 7
  • AE8 is C 12-13 alcohol ethoxylate, with an average degree of ethoxylation of 8
  • AE9 is C 12-13 alcohol ethoxylate, with an average degree of ethoxylation of 9
  • Amylase 1 is Stainzyme®, 15 mg active/g, supplied by Novozymes
  • Amylase 2 is Natalase®, 29 mg active/g, supplied by Novozymes
  • Xyloglucanase is Whitezyme®, 20mg active/g, supplied by Novozymes
  • Chelant 1 is diethylene triamine pentaacetic acid
  • Chelant 2 is 1-hydroxyethane 1,1-diphosphonic acid
  • Dispersin B is a glycoside hydrolase, reported as lOOOmg active/g DTI is either poly(4-vinylpyridine- 1 -oxide) (such as Chromabond S- 403E®), or poly(l-vinylpyrrolidone-co-l-vinylimidazole) (such as Sokalan HP56® ).
  • Dye control agent in accordance with the invention, for example
  • HSAS is mid-branched alkyl sulfate as disclosed in US 6,020,303 and
  • US6,060,443 LAS is linear alkylbenzenesulfonate having an average aliphatic carbon chain length C9-C15 (HLAS is acid form).
  • Lipase is Lipex®, 18 mg active/g, supplied by Novozymes
  • Liquitint ® V200 is a thiophene azo dye provided by Milliken
  • Mannanase is Mannaway®, 25 mg active/g, supplied by Novozymes
  • Nuclease is a Phosphodiesterase SEQ ID NO 1, reported as lOOOmg active/g
  • Optical Brightener 1 is disodium 4,4'-bis ⁇ [4-anilino-6-morpholino-s-triazin-2-yl] -amino ⁇ - 2,2'-stilbenedisulfonate
  • Optical Brightener 2 is disodium 4,4'-bis-(2-sulfostyryl)biphenyl (sodium salt)
  • Optical Brightener 3 is Optiblanc SPL10® from 3V Sigma Perfume encapsulate is a core-shell melamine formaldehyde perfume microcapsules.
  • Polymer 2 is ethoxylated (EO15) tetraethylene pentamine
  • Polymer 3 is ethoxylated polyethylenimine
  • Polymer 4 is ethoxylated hexamethylene diamine
  • Polymer 5 is Acusol 305, provided by Rohm&Haas Polymer 6 is a polyethylene glycol polymer grafted with vinyl acetate side chains, provided by BASF.
  • Protease is Purafect Prime®, 40.6 mg active/g, supplied by DuPont Structurant is Hydrogenated Castor Oil

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
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  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention concerne une composition leuco, comprenant au moins un composé leuco, le composé leuco comprenant une fraction leuco et une fraction polyalkylèneoxy liée de manière covalente à la fraction leuco. La fraction polyalkylèneoxy comprend au moins un groupe oxyde d'éthylène et au moins un groupe oxyde de propylène. Une composition de soin du linge comprend (a) au moins un ingrédient de soin du linge et (b) une composition leuco telle que décrite ci-dessus. Un procédé de traitement d'un textile comporte les étapes consistant : a) à fournir une telle composition de soin du linge ; (b) à ajouter la composition de soin du linge à un milieu liquide ; (c) à placer des articles textiles dans le milieu liquide ; (d) éventuellement à rincer les articles textiles ; et (e) à sécher les articles textiles.
PCT/US2018/055453 2017-10-12 2018-10-11 Colorants et compositions leuco WO2019075228A1 (fr)

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JP2020520510A JP2020537011A (ja) 2017-10-12 2018-10-11 ロイコ着色剤および組成物
BR112020006940-0A BR112020006940A2 (pt) 2017-10-12 2018-10-11 composições e corantes leuco
EP18793155.5A EP3694923A1 (fr) 2017-10-12 2018-10-11 Colorants et compositions leuco
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Publication number Priority date Publication date Assignee Title
WO2020023812A1 (fr) * 2018-07-27 2020-01-30 The Procter & Gamble Company Colorants leuco utilisés comme agents d'azurage dans des compositions d'entretien du linge
WO2020023897A1 (fr) * 2018-07-27 2020-01-30 Milliken & Company Compositions stabilisées comprenant des composés leuco
TWI715878B (zh) * 2017-10-12 2021-01-11 美商美力肯及公司 隱色著色劑及組成物

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WO2019089228A1 (fr) * 2017-11-01 2019-05-09 Milliken & Company Leucodérivés, composés colorants, et compositions les contenant

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TWI715878B (zh) * 2017-10-12 2021-01-11 美商美力肯及公司 隱色著色劑及組成物
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