WO2019061710A1 - Base structure of hydrogen-oxygen-separated electrolysis device and electrolysis device with base structure - Google Patents

Base structure of hydrogen-oxygen-separated electrolysis device and electrolysis device with base structure Download PDF

Info

Publication number
WO2019061710A1
WO2019061710A1 PCT/CN2017/110099 CN2017110099W WO2019061710A1 WO 2019061710 A1 WO2019061710 A1 WO 2019061710A1 CN 2017110099 W CN2017110099 W CN 2017110099W WO 2019061710 A1 WO2019061710 A1 WO 2019061710A1
Authority
WO
WIPO (PCT)
Prior art keywords
electrolysis
gas
water
electrode
hydrogen
Prior art date
Application number
PCT/CN2017/110099
Other languages
French (fr)
Chinese (zh)
Inventor
周陈兴
蔡婷婷
Original Assignee
福州品行科技发展有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 福州品行科技发展有限公司 filed Critical 福州品行科技发展有限公司
Publication of WO2019061710A1 publication Critical patent/WO2019061710A1/en

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • C25B1/04Hydrogen or oxygen by electrolysis of water
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70Assemblies comprising two or more cells
    • C25B9/73Assemblies comprising two or more cells of the filter-press type
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Definitions

  • the invention relates to the technical field of hydrogen-rich water cups, in particular to a seat structure of a hydrogen-oxygen separation electrolysis device and an electrolysis device with the same.
  • the process of electrolyzing water is actually a process of converting a liquid substance into a gaseous substance, and the obtained product is hydrogen, oxygen, ozone, chlorine, and the like.
  • hydrogen produced by electrolyzed water mainly has a hydrogen structure of a hydrogen-oxygen mixed system and a hydrogen structure of a hydrogen-oxygen separation system.
  • Hydrogen-oxygen mixed hydrogen structure is harmful to human body due to anode by-product components such as ozone, high-priced chlorine compounds, chlorine gas, etc., so it cannot be used in direct drinking water design; hydrogen-oxygen separation system hydrogen structure can produce cathode chamber products (hydrogen The products of the anode chamber (high-priced chlorine compounds, ozone, oxidation product gas, chlorine gas) are separated, so they can be used in the design of direct drinking water.
  • the use of electrolytic hydrogen production equipment must consider factors such as air tightness, water leakage prevention and gas pressure regulation of the device.
  • the hydrogen structure of the hydrogen-oxygen mixed system is generally provided with a gas pressure relief device at the top, which can solve the problem of an increase in the internal pressure of the container, but there is a problem of a decrease in sealing performance at the same time as the pressure relief, such as leakage and overflow at the pressure relief valve. Wait.
  • the hydrogen structure is used to separate the hydrogen structure. It is necessary to consider how the cathode chamber and the anode chamber ensure the airtightness and prevent the pressure surge.
  • the general pressure relief valve has the problem that the water and water are mixed and the water is discharged while the pressure is released. Therefore, the air tightness is greatly reduced.
  • the Chinese invention patent application with the publication number CN106820863A discloses a "hydrogen generator and a hydrogen-rich water cup", and specifically discloses that the hydrogen generation chamber includes a chamber upper cover, a chamber lower cover, The cathode platinized titanium plate, the grid type proton film and the anode platinized titanium plate form a PES electrolyzed water technical solution with hydrogen-oxygen separation, exhaust undrained and pressure-resistant characteristics.
  • the technical scheme adopts a hydrogen structure of hydrogen and oxygen separation system to realize hydrogen-oxygen separation.
  • the vacuum cup body and the cup cover portion do not have relevant pressure relief valves and the like to solve the problem of increased air pressure inside the container; meanwhile, the technical solution is
  • the bottom of the anode chamber is provided with an exhaust undrained passage, and the venting membrane is provided on the passage to achieve the purpose of venting the exhaust gas, but the waste water and the exhaust gas are not separated, and the waste water of the anode chamber is accumulated in the electrolytic chamber without the anode.
  • the wastewater in the chamber is effectively treated, and over time, the internal wastewater of the hydrogen-rich water cup will be fouled and stinky.
  • an object of the present invention is to provide a seat structure of a hydrogen-oxygen separation electrolysis device and an electrolysis device with the same, which can sufficiently ensure the airtightness of the structure or the device, and can automatically
  • the internal pressure of the control device is such that the gas and water are separated during the pressure relief process, thereby ensuring that the liquid does not overflow during the gas pressure relief process.
  • the present invention adopts the following technical solutions:
  • the structure of the hydrogen-oxygen separation electrolysis device comprises a casing, an electrode slot and an electrolysis electrode are arranged in the casing, a liquid adsorbent is contained in the electrode trough, and the liquid adsorbate adsorbs water used for preliminary electrolysis of the electric discharge electrode; the electrode trough
  • the bottom of the bottom is provided with an opening for discharging electrolytic waste water, and the electrolytic electrode comprises a cathode sheet, an anode sheet and a gas/water separator which is disposed between the cathode sheet and the anode sheet, and the gas/water separator is disposed on the shell above the electrode tank.
  • the gas/water separator On the inner wall, the gas/water separator has the characteristics that the water is not ventilated when the electrolysis electrode is electrolyzed and the water is not ventilated when the electrolysis electrode is not electrolyzed; the anode sheet is placed close to the liquid adsorbate, and the bottom of the casing is provided with the electrolysis electrode. The waste water and exhaust gas generated on the anode sheet side are separated and discharged to the outside of the casing Gas-water separation and discharge device.
  • the gas-water separation and discharge device comprises a lower air pressure safety valve and a waste water plug
  • the lower air pressure safety valve is disposed in a lower passage of the convex portion at the bottom of the housing, and the lower passage communicates with the inside of the housing and the outside of the housing.
  • the lower air pressure safety valve is in an open state by the interaction of the gravity of the seat body and the supporting force of the placement surface, and the waste water plug is disposed at the bottom of the housing, which is connected to the interior of the housing and the waste water port outside the housing.
  • the lower pneumatic safety valve comprises a lower sealing member with a lower sealing head, and the lower sealing member is fixedly connected to the lower limit member disposed outside the casing through the lower passage, and the lower sealing head is located above the convex portion in the casing, A lower elastic member is sleeved on the lower seal between the bottom of the casing and the lower limit member.
  • the liquid adsorbent is a sponge with a water storage and deodorization function.
  • the inside of the casing is separated into an upper electrolysis chamber and a lower waste gas exhaust chamber by an isolating device, and the electrode trough and the electrolysis electrode are disposed in the electrolysis chamber, and the bottom of the electrode trough is provided with a gas water pipe, and the upper end of the gas pipe is connected to the bottom of the electrode trough
  • the opening passes through the isolation device to communicate with the waste water chamber.
  • An electrolysis device having the above-mentioned seat structure, further comprising a main body and a cover body, wherein the base body, the main body and the cover body are sequentially connected.
  • the cover body is provided with an upper air pressure safety valve for keeping the air pressure in the main body within a preset value.
  • the upper pneumatic safety valve comprises an upper sealing member with a sealing head, and the upper sealing member is fixedly connected to the upper limit member disposed inside the cover body through the cover body, and the upper sealing head is located outside the cover body and on the upper sealing member An upper elastic member is disposed between the upper limit member and the cover.
  • a method of using the above electrolysis device comprising the steps of:
  • Water is added to the electrode slot of the seat body, and the liquid adsorbate adsorbs the added water to tighten the seat body and the body;
  • the anode sheet side of the electrolysis electrode is electrolyzed by water added in advance by the liquid adsorbent to generate an oxidation product gas; the water in the main body penetrates from the cathode sheet side through the gas/water separator to the anode sheet side, and is adsorbed by the liquid adsorbate to supply the counter electrode.
  • the anode piece continues to be used when electrolyzing water;
  • the oxidation product gas on the anode sheet side and the electrolytic waste water in the electrode tank are discharged into the casing, and the oxidation product gas is discharged through the lower gas pressure safety valve, and the electrolytic waste water is accumulated in the bottom of the waste gas exhaust chamber, and the waste water plug is pulled out to discharge the electrolytic waste water.
  • the electrolysis electrode starts to start electrolysis hydrogen production for 10 s ⁇ 5 s every 60 s ⁇ 10 s.
  • the invention can ensure the airtightness in the process of electrolytic hydrogen production, so that the liquid does not overflow, and the internal air pressure of the device can be controlled, thereby ensuring the practicability and stability of the device.
  • the invention adopts the hydrogen and oxygen separation structure design in the principle of hydrogen production, and can effectively prevent the user from isolating the oxidizing liquid when drinking the reducing liquid without causing harm to the human body; Moreover, when the user needs to prepare a strong oxidizing liquid, the reducing liquid can also be completely isolated to ensure the concentration and effectiveness of the oxidizing liquid.
  • the invention adopts the hydrogen structure design of hydrogen and oxygen separation system, the anode is located at the bottom of the device, and the liquid adsorbent is added on the surface thereof, which can effectively lock the amount of water required for the anode during electrolysis, and can realize the separation of gas and water. purpose.
  • the cover body of the invention adopts a novel pressure control mechanism in the top automatic air pressure control process, so that the gas and water are separated during the pressure relief process, thereby ensuring that the liquid does not overflow during the gas pressure release process; the automatic air pressure at the bottom of the seat body During the control process, the bottom pressure relief valve is opened by the gravity of the equipment itself, so as to ensure that the anode gas pressure is consistent with the atmospheric pressure of the use environment, and the gas and water separation design is adopted to ensure that the liquid overflow does not occur during the exhaust process. .
  • the seat structure of the present invention can be assembled into different cups, pot bodies and the like to realize hydrogen-rich water by individual production, and at the same time, the anode product can be effectively isolated, and a seat body is used. It is possible to realize mass production of a hydrogen-oxygen separation unit.
  • Figure 1 is a schematic view of the overall structure of the present invention
  • FIG. 2 is a schematic structural view of a seat body of the present invention
  • Figure 3 is a schematic structural view of a lower pneumatic safety valve of the present invention.
  • Fig. 4 is a schematic view showing the structure of a lid body of the present invention.
  • an electrolysis device includes a seat body 1, a main body 2 and a cover body 3 which are sequentially connected; specifically, the seat body 1 is disposed below the main body 2 and the upper portion of the seat body 1 and the lower portion of the main body 2
  • the cover body 3 is disposed above the main body 2 by a threaded sealing connection, and the cover body 3 is connected to the upper portion of the main body 2 by a screw seal; the seat body 1, the main body 2 and the cover body 3 together constitute a container for holding water.
  • the housing 1 includes a housing that is partitioned into an upper electrolytic chamber 11 and a lower wastewater exhaust chamber 12 by an isolating device 10 disposed at a lower portion of the interior of the housing 1.
  • the isolation device 10 is fixed.
  • the separator attached to the inner wall of the seat body 1 is sealed.
  • the isolating device 10 can be arranged differently depending on the needs of the different functions, for example to achieve a variable capacity function of the electrolysis chamber 11 and the waste gas exhaust chamber 12, which can be provided as a separator with a lifting device.
  • the electrolysis chamber 11 is provided with an electrode base 111, an electrode slot 112 and an electrolysis electrode 4.
  • the electrode base 111 is fixedly mounted on the isolator device 10, and an electrode driving device 41 is disposed in the electrode base 111.
  • the electrode slot 112 is fixedly mounted on the electrode base 111, and the electrode slot 112 is filled with liquid suction. Attachment 113, the liquid adsorbate 113 is adsorbed with water for preliminary electrolysis of the power supply counter electrode 4. In the embodiment, the liquid adsorbate 113 is a sponge with a water storage and deodorization function.
  • the bottom of the electrode slot 112 is provided with a gas pipe 114.
  • the upper end of the gas pipe 114 communicates with an opening provided at the bottom of the electrode groove 112, and the lower end of the gas pipe 114 extends through the isolating device 10 into the waste gas exhaust chamber 12 to communicate with the waste gas exhaust chamber 12.
  • the waste water and exhaust gas generated by the anode of the electrolysis electrode 4 are discharged into the waste gas exhaust chamber 12 through the gas pipe 114.
  • the electrolysis electrode 4 is fixedly mounted on the electrode slot 112.
  • the electrolysis electrode 4 includes a cathode sheet 42, an anode sheet 43, and a gas/water separator 44.
  • the gas/water separator 44 is seated on the seat body 1 above the electrode slot 112. On the inner wall.
  • the gas/water separator 44 is in a non-electrolytic state, that is, when the battery is not energized, the gas/water separator 44 inside the device is subjected to a pressure equal to gas/gas on the side of the cathode sheet 42 by setting the height of the device or the like.
  • the electrode 4 When the electrode 4 is energized and electrolyzed, the amount of hydrogen gas generated by the electrolysis of the cathode sheet 42 side is twice the amount of the oxidation product gas generated by the electrolysis of the anode sheet 43 side, resulting in the gas/water separator 44 inside the apparatus being subjected to the cathode sheet 42 side.
  • the pressure is greater than the pressure of the gas/water separator 44 on the side of the anode sheet 43, so that the gas/water separator 44 has a water-non-ventilating property at this time, and the water inside the water device permeates the liquid through the gas/water separator 44.
  • the adsorbent 113 is used for subsequent anode electrolysis; the cathode sheet 42 is disposed above the gas/water separator 44 and is disposed close to the upper surface of the gas/water separator 44, and the cathode sheet 42 passes through the cathode electrode column 421 and the electrode.
  • the driving device 41 is electrically connected; the anode piece 43 is disposed at / Water separator below the membrane 44, the upper surface of the anode sheet 43 in close contact with the air / water separator is provided at a film surface 44, the lower surface of the anode sheet 43 in close contact with the liquid sorbate 113, the anode piece 43 is electrically connected to the electrode driving device 41 through the anode electrode post 431.
  • the electrolysis electrode 4 When the electrolysis electrode 4 is not energized and electrolyzed, the water in the main body 2 is isolated in the main body 2 by the gas/water separator 44, and cannot enter the seat body 1 below the gas/water separator 44.
  • the electrolysis electrode 4 When the electrolysis electrode 4 is energized and electrolyzed, the water in the main body 2 permeates into the liquid adsorbate 113 in the electrode tank 112 through the gas/water separator 44, and the cathode sheet 42 generates hydrogen gas to be mixed in water to form hydrogen-rich water, and the cathode sheet 43 is produced.
  • Exhaust gas such as ozone, high-priced chlorine compounds and chlorine gas, and waste water remaining in the electrolysis flow into the waste gas exhaust chamber 12 through the gas pipe 114.
  • the waste water exhaust chamber 12 is provided with a gas-water separation and discharge device for separating the waste water and the exhaust gas generated by the anode piece 43 of the electrolytic electrode 4, and discharging the waste water and the exhaust gas to the outside of the seat body 1, respectively.
  • the bottom portion of the waste gas exhaust chamber 12 is provided with an upwardly convex portion 121 having a lower passage 1211 communicating with the waste water exhaust chamber 12 and the exterior of the base 1.
  • the lower passage 1211 is provided with a lower pneumatic safety valve 13 which is in a normally open state by the gravity of the device itself so as to exhaust the exhaust gas in the waste gas exhaust chamber 12 from time to time.
  • the lower air pressure safety valve 13 includes a lower sealing member 131 with a lower sealing head 1311.
  • the lower sealing member 131 is fixedly connected to the lower limit member 132 disposed outside the base body 1 through the lower passage 1211.
  • the sealing head 1311 is located in the waste water exhaust chamber 12, and a seal ring is disposed between the lower seal head 1311 and the top end of the convex portion 121.
  • the lower sealing member 131 is disposed between the bottom of the base body 1 and the lower limit member 132 with a lower elastic member 133.
  • the lower elastic member 133 is a spring.
  • a waste water port is disposed at a bottom of the waste gas exhaust chamber 12, and a waste water plug 14 is plugged into the waste water port.
  • the cover body 3 is provided with an upper air pressure safety valve 31 for keeping the air pressure in the main body 2 within a preset value.
  • the upper portion of the cover body 3 is provided with an upper passage 32 communicating with the outside of the cover body 3 and the inside of the cover body 3.
  • the upper pneumatic safety valve 31 is disposed on the upper passage 32, and the upper pneumatic safety valve 31 includes An upper sealing member 311 is attached to the sealing head 3111.
  • the upper sealing member 311 is fixedly connected to the upper limit member 312 disposed inside the cover body 3 through the upper passage 32.
  • the upper sealing head 3111 is located outside the cover body 3, A seal ring is disposed between the seal head 3111 and the lid body 3.
  • An upper elastic member 313 is disposed between the upper limit member 312 and the cover 3, and the upper elastic member 313 is a spring.
  • the inside of the cover body 3 is provided with a protection seat 33 on the outer side of the upper sealing member 311.
  • the protection seat covers a portion of the sealing member 311 in the cover body 3 and is fixedly connected to the cover body 3.
  • the protection seat 33 The bottom end is provided with a plurality of vent holes.
  • the upper elastic member 313 is pressed upward by the air pressure inside the main body 2, and the sealing head 1311 is separated from the upper surface of the cover body 3. After the gas inside the main body 2 is discharged, the air pressure inside and outside the main body 2 is uniform. After that, the spring rebound seal 131 is reset, and the internal pressure of the main body 2 is ensured at the same time to ensure the airtightness of the device and prevent water leakage.
  • the method of using the above electrolysis device comprises the following steps:
  • the electrolysis electrode 4 is started to start electrolyzing water, hydrogen gas is generated on the cathode sheet 42 side of the electrolysis electrode 4, a part of hydrogen gas is dissolved in water to form hydrogen-rich water, and the other part forms a bubble rising and accumulates between the lid body 3 and the liquid surface of the main body 2;
  • the anode sheet 43 side of the electrolytic electrode 4 is electrolyzed by water previously added by the liquid adsorbate 113 to generate an oxidation product gas;
  • the electrolytic electrode 4 When the electrolytic electrode 4 is electrolyzed, since the amount of hydrogen generated on the side of the cathode sheet 42 is larger than the amount of the oxidation product gas on the side of the anode sheet 43, the pressure on the side of the cathode sheet 42 of the gas/water separator 44 is larger than that of the anode/sheet 43 of the gas/water separator 44. On the side pressure, the water in the main body 2 permeates from the cathode sheet 42 side through the gas/water separator 44 to the anode sheet 43 side, and is adsorbed by the liquid adsorbate 113 when the anode sheet 43 of the supply counter electrode 4 continues to electrolyze water;
  • the electrolysis electrode 4 When the electrolysis electrode 4 is continuously electrolyzed, the oxidation product gas on the anode sheet 43 side is more and more, and the oxidation product gas and the electrolytic waste water in the electrode tank 112 are discharged into the waste gas exhaust chamber 12 through the gas pipe 114, oxygen The product gas is discharged through the lower air pressure safety valve 13, and the electrolytic waste water is accumulated in the bottom of the waste gas exhaust chamber 12, and the waste water plug 14 is pulled out to discharge the electrolytic waste water.
  • the electrolysis electrode 4 Since the hydrogen molecules are extremely difficult to dissolve in the liquid under low pressure and normal temperature environment, and the user rarely drinks the hydrogen water liquid in a very short time, in order to ensure the dissolved concentration of the hydrogen molecules in the liquid, it is necessary to continue to replenish due to the stoppage. Part of the hydrogen molecules lost after electrolysis. In order to ensure the concentration of hydrogen in the liquid, it is preferable that after the electrolysis electrode 4 stops hydrogen production, the electrolysis electrode 4 is again activated for 10 s ⁇ 5 s every 60 s ⁇ 10 s, and the liquid in the apparatus is supplemented with hydrogen.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

Provided are a base structure of a hydrogen-oxygen-separated electrolysis device and an electrolysis device with the base structure. The base structure comprises a housing, wherein an electrode groove (112) and an electrolysis electrode (4) are arranged in the housing, a liquid adsorbate (113) is accommodated in the electrode groove (112), and the liquid adsorbate (113) adsorbs water for the electrolysis electrode (4) to use during preliminary electrolysis; an opening is provided at the bottom of the electrode groove (112), the electrolysis electrode (4) comprises a cathode sheet (42), an anode sheet (43), and a gas/water isolating membrane (44) arranged between the cathode sheet and the anode sheet in a tightly attached manner, the gas/water isolating membrane (44) is clamped onto an inner wall of the housing above the electrode groove (112), and the gas/water isolating membrane (44) has the characteristic that the water passes through same, but the gas does not pass through same during the electrolysis of the electrolysis electrode (4), and neither the water nor the gas passes through same when the electrolysis electrode (4) does not perform electrolysis; and the anode sheet (43) is tightly attached to the liquid adsorbate (113), and a gas/water separated discharging device is arranged at the bottom of the housing for respectively separating and discharging waste water and waste gas generated on the side of the anode sheet (43) of the electrolysis electrode (4) from the housing.

Description

氢氧分离的电解装置的座体结构及带该座体的电解装置Seat structure of electrolysis device for hydrogen and oxygen separation and electrolysis device with the same 技术领域Technical field
本发明涉及富氢水杯技术领域,尤其涉及一种氢氧分离的电解装置的座体结构及带该座体的电解装置。The invention relates to the technical field of hydrogen-rich water cups, in particular to a seat structure of a hydrogen-oxygen separation electrolysis device and an electrolysis device with the same.
背景技术Background technique
电解水的过程实际是将液态物质转换为气态物质的过程,得到的产物有氢、氧、臭氧、氯气等。目前,电解水制氢主要有氢氧混合体制氢结构以及氢氧分离体制氢结构。The process of electrolyzing water is actually a process of converting a liquid substance into a gaseous substance, and the obtained product is hydrogen, oxygen, ozone, chlorine, and the like. At present, hydrogen produced by electrolyzed water mainly has a hydrogen structure of a hydrogen-oxygen mixed system and a hydrogen structure of a hydrogen-oxygen separation system.
采用氢氧混合体制氢结构由于阳极副产物成分如臭氧、高价氯化合物、氯气等对人体有害,因此不可用于直接饮用水的设计方案;氢氧分离体制氢结构能将阴极室的产物(氢气)、阳极室的产物(高价氯化合物、臭氧、氧化产物气体、氯气)分开,因此可用于直接饮用水的设计方案中。Hydrogen-oxygen mixed hydrogen structure is harmful to human body due to anode by-product components such as ozone, high-priced chlorine compounds, chlorine gas, etc., so it cannot be used in direct drinking water design; hydrogen-oxygen separation system hydrogen structure can produce cathode chamber products (hydrogen The products of the anode chamber (high-priced chlorine compounds, ozone, oxidation product gas, chlorine gas) are separated, so they can be used in the design of direct drinking water.
采用电解制氢装置必须考虑装置的气密性、防漏水和气体稳压等方面的因素。现有技术中,氢氧混合体制氢结构一般是在顶部设置气体泄压装置,能解决容器内部气压增大问题,但在泄压的同时存在密封性能降低问题,如泄压阀处漏水、溢水等。采用氢氧分离体制氢结构,必须考虑阴极室、阳极室如何同时确保气密性和防止气压激增问题,采用一般的泄压阀存在气、水混合后,在泄压的同时又排出水的问题,因此,气密性就大大降低。The use of electrolytic hydrogen production equipment must consider factors such as air tightness, water leakage prevention and gas pressure regulation of the device. In the prior art, the hydrogen structure of the hydrogen-oxygen mixed system is generally provided with a gas pressure relief device at the top, which can solve the problem of an increase in the internal pressure of the container, but there is a problem of a decrease in sealing performance at the same time as the pressure relief, such as leakage and overflow at the pressure relief valve. Wait. The hydrogen structure is used to separate the hydrogen structure. It is necessary to consider how the cathode chamber and the anode chamber ensure the airtightness and prevent the pressure surge. At the same time, the general pressure relief valve has the problem that the water and water are mixed and the water is discharged while the pressure is released. Therefore, the air tightness is greatly reduced.
经检索,公开号为CN106820863A的中国发明专利申请公开了一种“氢气发生器及富氢水杯”,具体公开了氢气发生室包括发生室上盖、发生室下盖、 阴极镀铂钛板、格栅式质子膜以及阳极镀铂钛板,形成具有氢氧分离的,排气不排水的,抗压式特征的PES电解水技术方案。本技术方案采用氢、氧分离体制氢结构实现了氢氧分离,但是,真空杯体和杯盖部分并未相关的泄压阀等来解决容器内部气压增加的问题;同时,该技术方案虽然在阳极室底部设置排气不排水通道,通过在通道上设置透气膜的方式来实现排气不排水的目的,但是没有对废水和废气进行分离,阳极室的废水蓄积在电解腔内,没有对阳极室的废水进行有效的处理,久而久之将导致富氢水杯内部废水淤积发臭。The Chinese invention patent application with the publication number CN106820863A discloses a "hydrogen generator and a hydrogen-rich water cup", and specifically discloses that the hydrogen generation chamber includes a chamber upper cover, a chamber lower cover, The cathode platinized titanium plate, the grid type proton film and the anode platinized titanium plate form a PES electrolyzed water technical solution with hydrogen-oxygen separation, exhaust undrained and pressure-resistant characteristics. The technical scheme adopts a hydrogen structure of hydrogen and oxygen separation system to realize hydrogen-oxygen separation. However, the vacuum cup body and the cup cover portion do not have relevant pressure relief valves and the like to solve the problem of increased air pressure inside the container; meanwhile, the technical solution is The bottom of the anode chamber is provided with an exhaust undrained passage, and the venting membrane is provided on the passage to achieve the purpose of venting the exhaust gas, but the waste water and the exhaust gas are not separated, and the waste water of the anode chamber is accumulated in the electrolytic chamber without the anode. The wastewater in the chamber is effectively treated, and over time, the internal wastewater of the hydrogen-rich water cup will be fouled and stinky.
发明内容Summary of the invention
为了解决上述问题,本发明的目的在于提供一种氢氧分离的电解装置的座体结构及带该座体的电解装置,该结构及装置能够充分保证结构或者装置的气密性,并且能够自动控制装置内部气压的大小,使装置在泄压过程中气、水分离,从而确保液体在气体泄压过程中不会外溢。In order to solve the above problems, an object of the present invention is to provide a seat structure of a hydrogen-oxygen separation electrolysis device and an electrolysis device with the same, which can sufficiently ensure the airtightness of the structure or the device, and can automatically The internal pressure of the control device is such that the gas and water are separated during the pressure relief process, thereby ensuring that the liquid does not overflow during the gas pressure relief process.
为实现上述目的,本发明采用以下技术方案:To achieve the above object, the present invention adopts the following technical solutions:
氢氧分离的电解装置的座体结构,包括壳体,壳体内设置有电极槽和电解电极,电极槽内容纳有液体吸附物,液体吸附物吸附有供电解电极初步电解使用的水;电极槽的底部设置有排出电解废水的开口,电解电极包括阴极片、阳极片以及紧贴设置在阴极片和阳极片之间的气/水隔离膜,气/水隔离膜卡设在电极槽上方的壳体内壁上,气/水隔离膜具有电解电极电解时过水不通气以及电解电极非电解时不过水不通气的特性;阳极片紧贴液体吸附物设置,壳体底部设置有用于将电解电极的阳极片侧产生的废水和废气分离后分别排至壳体外部 的气水分离排出装置。The structure of the hydrogen-oxygen separation electrolysis device comprises a casing, an electrode slot and an electrolysis electrode are arranged in the casing, a liquid adsorbent is contained in the electrode trough, and the liquid adsorbate adsorbs water used for preliminary electrolysis of the electric discharge electrode; the electrode trough The bottom of the bottom is provided with an opening for discharging electrolytic waste water, and the electrolytic electrode comprises a cathode sheet, an anode sheet and a gas/water separator which is disposed between the cathode sheet and the anode sheet, and the gas/water separator is disposed on the shell above the electrode tank. On the inner wall, the gas/water separator has the characteristics that the water is not ventilated when the electrolysis electrode is electrolyzed and the water is not ventilated when the electrolysis electrode is not electrolyzed; the anode sheet is placed close to the liquid adsorbate, and the bottom of the casing is provided with the electrolysis electrode. The waste water and exhaust gas generated on the anode sheet side are separated and discharged to the outside of the casing Gas-water separation and discharge device.
其中,所述气水分离排出装置包括下气压安全阀和废水塞,下气压安全阀设置在壳体底部一向上凸起的凸部的下通道中,下通道连通壳体内部和壳体外部,下气压安全阀依靠座体自身的重力与放置面的支撑力的相互作用处于打开的状态,废水塞设置在壳体底部一连通壳体内部和壳体外部的废水口上。Wherein, the gas-water separation and discharge device comprises a lower air pressure safety valve and a waste water plug, and the lower air pressure safety valve is disposed in a lower passage of the convex portion at the bottom of the housing, and the lower passage communicates with the inside of the housing and the outside of the housing. The lower air pressure safety valve is in an open state by the interaction of the gravity of the seat body and the supporting force of the placement surface, and the waste water plug is disposed at the bottom of the housing, which is connected to the interior of the housing and the waste water port outside the housing.
其中,所述下气压安全阀包括带下密封头的下密封件,下密封件穿过下通道与设置在壳体外部的下限位件固定连接,下密封头位于壳体内的凸部的上方,下密封件上在壳体底部与下限位件之间套设有下弹性件。Wherein, the lower pneumatic safety valve comprises a lower sealing member with a lower sealing head, and the lower sealing member is fixedly connected to the lower limit member disposed outside the casing through the lower passage, and the lower sealing head is located above the convex portion in the casing, A lower elastic member is sleeved on the lower seal between the bottom of the casing and the lower limit member.
其中,所述液体吸附物为带有蓄水防臭功能的海绵。Wherein, the liquid adsorbent is a sponge with a water storage and deodorization function.
其中,所述壳体内部通过隔离装置分隔成上部的电解腔和下部的废水废气腔,电极槽和电解电极设置在电解腔内,电极槽的底部设置有气水管,气水管上端连接电极槽底部的开口,下端穿过隔离装置连通废水废气腔。The inside of the casing is separated into an upper electrolysis chamber and a lower waste gas exhaust chamber by an isolating device, and the electrode trough and the electrolysis electrode are disposed in the electrolysis chamber, and the bottom of the electrode trough is provided with a gas water pipe, and the upper end of the gas pipe is connected to the bottom of the electrode trough The opening passes through the isolation device to communicate with the waste water chamber.
一种电解装置,具有上述的座体结构,还包括主体和盖体,所述座体、主体和盖体依次连接。An electrolysis device having the above-mentioned seat structure, further comprising a main body and a cover body, wherein the base body, the main body and the cover body are sequentially connected.
其中,所述盖体上设置有使主体内气压始终处于预设值以内的上气压安全阀。Wherein, the cover body is provided with an upper air pressure safety valve for keeping the air pressure in the main body within a preset value.
其中,所述上气压安全阀包括带上密封头的上密封件,上密封件穿过盖体与设置在盖体内部的上限位件固定连接,上密封头位于盖体外部,上密封件上在上限位件与盖体之间设置有上弹性件。Wherein, the upper pneumatic safety valve comprises an upper sealing member with a sealing head, and the upper sealing member is fixedly connected to the upper limit member disposed inside the cover body through the cover body, and the upper sealing head is located outside the cover body and on the upper sealing member An upper elastic member is disposed between the upper limit member and the cover.
一种上述的电解装置的使用方法,包括以下步骤: A method of using the above electrolysis device, comprising the steps of:
往座体的电极槽中加水,液体吸附物吸附加入的水,拧紧座体与主体;Water is added to the electrode slot of the seat body, and the liquid adsorbate adsorbs the added water to tighten the seat body and the body;
往主体内加水,拧紧盖体与主体,将该电解装置放置在平稳处,下气压安全阀受到挤压打开;Add water to the main body, tighten the cover body and the main body, place the electrolyzer on a stable place, and press the lower pneumatic safety valve to be opened;
启动电解电极开始电解,电解电极的阴极片侧生成氢气,氢气一部分溶解在水中形成富氢水,另一部分聚集在装置内;当装置内部的气压达到盖体设定的排气气压值时,上气压安全阀受到挤压上顶打开,气体排出;随后,上气压安全阀复位关闭;Starting the electrolysis electrode to start electrolysis, hydrogen gas is generated on the cathode sheet side of the electrolysis electrode, part of the hydrogen is dissolved in water to form hydrogen-rich water, and the other part is collected in the device; when the internal pressure of the device reaches the exhaust gas pressure value set by the cover body, The pneumatic safety valve is opened by the top of the squeeze and the gas is discharged; then, the upper pneumatic safety valve is reset and closed;
电解电极的阳极片侧利用液体吸附物事先添加的水进行电解产生氧化产物气体;主体内的水从阴极片侧通过气/水隔离膜渗透至阳极片侧,并被液体吸附物吸附供电解电极的阳极片继续电解水时使用;The anode sheet side of the electrolysis electrode is electrolyzed by water added in advance by the liquid adsorbent to generate an oxidation product gas; the water in the main body penetrates from the cathode sheet side through the gas/water separator to the anode sheet side, and is adsorbed by the liquid adsorbate to supply the counter electrode. The anode piece continues to be used when electrolyzing water;
阳极片侧的氧化产物气体和电极槽内的电解废水排入壳体中,氧化产物气体通过下气压安全阀排出,电解废水蓄积在废水废气腔的底部,拔开废水塞排出电解废水。The oxidation product gas on the anode sheet side and the electrolytic waste water in the electrode tank are discharged into the casing, and the oxidation product gas is discharged through the lower gas pressure safety valve, and the electrolytic waste water is accumulated in the bottom of the waste gas exhaust chamber, and the waste water plug is pulled out to discharge the electrolytic waste water.
其中,所述电解电极每隔60s±10s的时间后再次启动开始电解制氢10s±5s。Wherein, the electrolysis electrode starts to start electrolysis hydrogen production for 10 s ± 5 s every 60 s ± 10 s.
本发明具有如下有益效果:The invention has the following beneficial effects:
1、本发明在电解制氢的过程中即能保证气密性,使得液体不外溢,又能确保装置内部气压可控,从而确保了装置的实用性和稳定性。1. The invention can ensure the airtightness in the process of electrolytic hydrogen production, so that the liquid does not overflow, and the internal air pressure of the device can be controlled, thereby ensuring the practicability and stability of the device.
2、本发明在制氢原理上采用氢、氧分离体结构设计,可以有效的防止使用者在饮用还原性的液体时,氧化性的液体被隔离而不会对人体造成危害;并 且,在使用者需制备强氧化性液体时,还原性液体也能被完全隔离,确保氧化性液体的浓度及有效性。2. The invention adopts the hydrogen and oxygen separation structure design in the principle of hydrogen production, and can effectively prevent the user from isolating the oxidizing liquid when drinking the reducing liquid without causing harm to the human body; Moreover, when the user needs to prepare a strong oxidizing liquid, the reducing liquid can also be completely isolated to ensure the concentration and effectiveness of the oxidizing liquid.
3、本发明采用氢、氧分离体制氢结构设计,阳极位于装置底部,在其表面增加了液体吸附物,能有效的锁住阳极在电解时所需的水量,并且能实现气、水分离之目的。3. The invention adopts the hydrogen structure design of hydrogen and oxygen separation system, the anode is located at the bottom of the device, and the liquid adsorbent is added on the surface thereof, which can effectively lock the amount of water required for the anode during electrolysis, and can realize the separation of gas and water. purpose.
4、本发明的盖体在顶部自动气压控制过程中采用新型压力控制机制,使设备在泄压过程中气、水分离,从而确保液体在气体泄压过程中不会外溢;在座体底部自动气压控制过程中利用设备自身所受重力,将底部泄压阀开启,从而保证阳极气体压力与使用环境的大气压保持一致,并且采用气、水分离设计方案,确保在排气过程中不会导致液体外溢。4. The cover body of the invention adopts a novel pressure control mechanism in the top automatic air pressure control process, so that the gas and water are separated during the pressure relief process, thereby ensuring that the liquid does not overflow during the gas pressure release process; the automatic air pressure at the bottom of the seat body During the control process, the bottom pressure relief valve is opened by the gravity of the equipment itself, so as to ensure that the anode gas pressure is consistent with the atmospheric pressure of the use environment, and the gas and water separation design is adopted to ensure that the liquid overflow does not occur during the exhaust process. .
5、本发明的座体结构通过个性化生产,能够装配在不同的杯体、壶体等主体下面来实现制氢获得富氢水,同时将阳极产物实现有效的隔离,用一个座体,就能够实现氢氧分离装置的批量化生产。5. The seat structure of the present invention can be assembled into different cups, pot bodies and the like to realize hydrogen-rich water by individual production, and at the same time, the anode product can be effectively isolated, and a seat body is used. It is possible to realize mass production of a hydrogen-oxygen separation unit.
附图说明DRAWINGS
图1为本发明的整体结构示意图;Figure 1 is a schematic view of the overall structure of the present invention;
图2为本发明的座体的结构示意图;2 is a schematic structural view of a seat body of the present invention;
图3为本发明的下气压安全阀的结构示意图;Figure 3 is a schematic structural view of a lower pneumatic safety valve of the present invention;
图4为本发明的盖体的结构示意图。Fig. 4 is a schematic view showing the structure of a lid body of the present invention.
附图标记说明:Description of the reference signs:
1、座体;10、隔离装置;11、电解腔;111、电极底座;112、电极槽; 113、液体吸附物;114、气水管;12、废水废气腔;121、凸部;1211、下通道;13、下气压安全阀;131、下密封件;1311、下密封头;132、下限位件;133、下弹性件;14、废水塞;2、主体;3、盖体;31、上气压安全阀;311、上密封件;3111、上密封头;312、上限位件;313、上弹性件;32、上通道;33、保护座;4、电解电极;41、电极驱动装置;42、阴极片;43、阳极片;44、气/水隔离膜。1, seat body; 10, isolation device; 11, electrolytic chamber; 111, electrode base; 112, electrode slot; 113, liquid adsorbate; 114, gas water pipe; 12, waste water exhaust chamber; 121, convex portion; 1211, lower passage; 13, lower pneumatic safety valve; 131, lower seal; 1311, lower seal head; 132, lower limit 133, lower elastic member; 14, waste water plug; 2, main body; 3, cover body; 31, upper pneumatic safety valve; 311, upper seal; 3111, upper seal head; 312, upper limit position; Elastic member; 32, upper channel; 33, protective seat; 4, electrolytic electrode; 41, electrode driving device; 42, cathode sheet; 43, anode sheet; 44, gas/water separator.
具体实施方式Detailed ways
以下结合附图和具体实施例对本发明做进一步详细说明:The present invention will be further described in detail below with reference to the accompanying drawings and specific embodiments:
参见图1至图4,一种电解装置,包括依次连接的座体1、主体2和盖体3;具体的,所述座体1设置在主体2的下方且座体1上部与主体2的下部通过螺纹密封连接,所述盖体3设置在主体2上方且盖体3与主体2上部通过螺纹密封连接;所述座体1、主体2和盖体3共同组成一盛水的容器。Referring to FIGS. 1 to 4, an electrolysis device includes a seat body 1, a main body 2 and a cover body 3 which are sequentially connected; specifically, the seat body 1 is disposed below the main body 2 and the upper portion of the seat body 1 and the lower portion of the main body 2 The cover body 3 is disposed above the main body 2 by a threaded sealing connection, and the cover body 3 is connected to the upper portion of the main body 2 by a screw seal; the seat body 1, the main body 2 and the cover body 3 together constitute a container for holding water.
所述座体1包括一壳体,壳体通过设置在座体1内部下部的隔离装置10分隔成上部的电解腔11和下部的废水废气腔12,本实施例中,所述隔离装置10为固定密封连接在座体1内壁上的隔离板。当然,隔离装置10可以根据不同功能的需要进行不同的设置,例如为了实现电解腔11和废水废气腔12的容量可变的功能,所述隔离装置10可设置成带有升降装置的隔离板。The housing 1 includes a housing that is partitioned into an upper electrolytic chamber 11 and a lower wastewater exhaust chamber 12 by an isolating device 10 disposed at a lower portion of the interior of the housing 1. In the present embodiment, the isolation device 10 is fixed. The separator attached to the inner wall of the seat body 1 is sealed. Of course, the isolating device 10 can be arranged differently depending on the needs of the different functions, for example to achieve a variable capacity function of the electrolysis chamber 11 and the waste gas exhaust chamber 12, which can be provided as a separator with a lifting device.
所述电解腔11内设置有电极底座111、电极槽112和电解电极4,所述电极底座111固定安装在隔离装置10上,电极底座111内设置有电极驱动装置41。所述电极槽112固定安装在电极底座111上,电极槽112内容纳有液体吸 附物113,液体吸附物113上吸附有供电解电极4初步电解使用的水。本实施例中,所述液体吸附物113为带有蓄水防臭功能的海绵。电极槽112的底部设置有气水管114,气水管114的上端与电极槽112底部设置的开口连通,气水管114的下端穿过隔离装置10延伸至废水废气腔12中,与废水废气腔12连通,电解电极4阳极产生的废水和废气通过气水管114排入废水废气腔12内。The electrolysis chamber 11 is provided with an electrode base 111, an electrode slot 112 and an electrolysis electrode 4. The electrode base 111 is fixedly mounted on the isolator device 10, and an electrode driving device 41 is disposed in the electrode base 111. The electrode slot 112 is fixedly mounted on the electrode base 111, and the electrode slot 112 is filled with liquid suction. Attachment 113, the liquid adsorbate 113 is adsorbed with water for preliminary electrolysis of the power supply counter electrode 4. In the embodiment, the liquid adsorbate 113 is a sponge with a water storage and deodorization function. The bottom of the electrode slot 112 is provided with a gas pipe 114. The upper end of the gas pipe 114 communicates with an opening provided at the bottom of the electrode groove 112, and the lower end of the gas pipe 114 extends through the isolating device 10 into the waste gas exhaust chamber 12 to communicate with the waste gas exhaust chamber 12. The waste water and exhaust gas generated by the anode of the electrolysis electrode 4 are discharged into the waste gas exhaust chamber 12 through the gas pipe 114.
所述电解电极4固定安装在电极槽112上方,电解电极4包括阴极片42、阳极片43和气/水隔离膜44,所述气/水隔离膜44卡设在电极槽112上方的座体1内壁上。所述气/水隔离膜44在非电解状态即不通电时,通过对装置的高度盛水量等的设置,使得装置内部的气/水隔离膜44在阴极片42侧所受的压力等于气/水隔离膜44在阳极片43侧所受的压力,此时气/水隔离膜44两侧所受的压力相等,因此此时气/水隔离膜44具有不过水且不通气的特性;在电解电极4通电电解时,由于阴极片42侧电解产生氢气的量为阳极片43侧电解产生氧化产物气体的量的两倍,导致装置内部的气/水隔离膜44在阴极片42侧所受的压力大于气/水隔离膜44在阳极片43侧所受的压力,因此此时气/水隔离膜44具有过水不通气的特性水装置内部的水透过气/水隔离膜44渗透至液体吸附物113上为后续阳极电解使用;所述阴极片42设置在气/水隔离膜44的上方且紧贴气/水隔离膜44上表面设置,所述阴极片42通过阴极电极柱421与电极驱动装置41电连接;所述阳极片43设置在气/水隔离膜44的下方,阳极片43的上表面紧贴气/水隔离膜44下表面设置,阳极片43的下表面紧贴液体吸附物 113设置,所述阳极片43通过阳极电极柱431与电极驱动装置41电连接。The electrolysis electrode 4 is fixedly mounted on the electrode slot 112. The electrolysis electrode 4 includes a cathode sheet 42, an anode sheet 43, and a gas/water separator 44. The gas/water separator 44 is seated on the seat body 1 above the electrode slot 112. On the inner wall. When the gas/water separator 44 is in a non-electrolytic state, that is, when the battery is not energized, the gas/water separator 44 inside the device is subjected to a pressure equal to gas/gas on the side of the cathode sheet 42 by setting the height of the device or the like. The pressure of the water separator 44 on the anode sheet 43 side, at this time, the pressures on both sides of the gas/water separator 44 are equal, and thus the gas/water separator 44 has characteristics of being neither water nor ventilating; When the electrode 4 is energized and electrolyzed, the amount of hydrogen gas generated by the electrolysis of the cathode sheet 42 side is twice the amount of the oxidation product gas generated by the electrolysis of the anode sheet 43 side, resulting in the gas/water separator 44 inside the apparatus being subjected to the cathode sheet 42 side. The pressure is greater than the pressure of the gas/water separator 44 on the side of the anode sheet 43, so that the gas/water separator 44 has a water-non-ventilating property at this time, and the water inside the water device permeates the liquid through the gas/water separator 44. The adsorbent 113 is used for subsequent anode electrolysis; the cathode sheet 42 is disposed above the gas/water separator 44 and is disposed close to the upper surface of the gas/water separator 44, and the cathode sheet 42 passes through the cathode electrode column 421 and the electrode. The driving device 41 is electrically connected; the anode piece 43 is disposed at / Water separator below the membrane 44, the upper surface of the anode sheet 43 in close contact with the air / water separator is provided at a film surface 44, the lower surface of the anode sheet 43 in close contact with the liquid sorbate 113, the anode piece 43 is electrically connected to the electrode driving device 41 through the anode electrode post 431.
当电解电极4不通电非电解时,主体2内的水被气/水隔离膜44隔离在主体2内,不能进入气/水隔离膜44下方的座体1中。当电解电极4通电电解时,主体2内的水透过气/水隔离膜44渗入电极槽112中的液体吸附物113中,阴极片42产生氢气混合在水中形成富氢水,阴极片43产生臭氧、高价氯化合物和氯气等废气以及电解剩余的废水通过气水管114流入废水废气腔12中。When the electrolysis electrode 4 is not energized and electrolyzed, the water in the main body 2 is isolated in the main body 2 by the gas/water separator 44, and cannot enter the seat body 1 below the gas/water separator 44. When the electrolysis electrode 4 is energized and electrolyzed, the water in the main body 2 permeates into the liquid adsorbate 113 in the electrode tank 112 through the gas/water separator 44, and the cathode sheet 42 generates hydrogen gas to be mixed in water to form hydrogen-rich water, and the cathode sheet 43 is produced. Exhaust gas such as ozone, high-priced chlorine compounds and chlorine gas, and waste water remaining in the electrolysis flow into the waste gas exhaust chamber 12 through the gas pipe 114.
所述废水废气腔12内设置有气水分离排出装置,用于将电解电极4的阳极片43产生的废水和废气分离后将废水和废气分别排至座体1外部。本实施例中,所述废水废气腔12底部中部位置设置有向上凸起的凸部121,所述凸部121内具有一连通废水废气腔12和座体1外部的下通道1211。所述下通道1211上设置有下气压安全阀13,所述下气压安全阀13依靠装置自身重力处于压制处于常开状态,以便时时排出废水废气腔12内的废气。具体的,所述所述下气压安全阀13包括带下密封头1311的下密封件131,所述下密封件131穿过下通道1211与设置在座体1外部的下限位件132固定连接,所述下密封头1311位于废水废气腔12中,下密封头1311与凸部121的顶端之间设置有密封圈。所述下密封件131外在座体1底部与下限位件132之间设置有下弹性件133,具体的,所述下弹性件133为弹簧。所述废水废气腔12的底部设置有废水口,所述废水口上塞有废水塞14。The waste water exhaust chamber 12 is provided with a gas-water separation and discharge device for separating the waste water and the exhaust gas generated by the anode piece 43 of the electrolytic electrode 4, and discharging the waste water and the exhaust gas to the outside of the seat body 1, respectively. In this embodiment, the bottom portion of the waste gas exhaust chamber 12 is provided with an upwardly convex portion 121 having a lower passage 1211 communicating with the waste water exhaust chamber 12 and the exterior of the base 1. The lower passage 1211 is provided with a lower pneumatic safety valve 13 which is in a normally open state by the gravity of the device itself so as to exhaust the exhaust gas in the waste gas exhaust chamber 12 from time to time. Specifically, the lower air pressure safety valve 13 includes a lower sealing member 131 with a lower sealing head 1311. The lower sealing member 131 is fixedly connected to the lower limit member 132 disposed outside the base body 1 through the lower passage 1211. The sealing head 1311 is located in the waste water exhaust chamber 12, and a seal ring is disposed between the lower seal head 1311 and the top end of the convex portion 121. The lower sealing member 131 is disposed between the bottom of the base body 1 and the lower limit member 132 with a lower elastic member 133. Specifically, the lower elastic member 133 is a spring. A waste water port is disposed at a bottom of the waste gas exhaust chamber 12, and a waste water plug 14 is plugged into the waste water port.
通过在废水废气腔12中设置向上凸起的带下通道1211的凸部121,当该 氢氧分离的电解恒压装置放置在桌面等平面上,利用装置自身的重力即可使得下气压安全阀13处于常开的状态,废气通过下通道1211自然排出,使得座体1内部的气压处于恒定状态,定期拔开废水塞14,即可排出废水。By providing the convex portion 121 of the downwardly convex lower channel 1211 in the waste gas exhaust chamber 12, when The electrolyzed constant pressure device for separating the hydrogen and oxygen is placed on a plane such as a table top, and the gravity of the lower air pressure safety valve 13 is normally opened by the gravity of the device itself, and the exhaust gas is naturally discharged through the lower passage 1211, so that the air pressure inside the seat body 1 is at a position In a constant state, the waste water plug 14 is periodically withdrawn to discharge the waste water.
所述盖体3上设置有使主体2内气压始终处于预设值以内的上气压安全阀31。本实施例中,所述盖体3中部设置有连通盖体3外部和盖体3内部的上通道32,所述上气压安全阀31设置在上通道32上,所述上气压安全阀31包括带上密封头3111的上密封件311,所述上密封件311穿过上通道32与设置在盖体3内部的上限位件312固定连接,所述上密封头3111位于盖体3外部,上密封头3111与盖体3之间设置有密封圈。所述上密封件311外在上限位件312与盖体3之间设置有上弹性件313,具体的,所述上弹性件313为弹簧。优选的,所述盖体3内部在上密封件311的外侧设置有保护座33,所述保护座包裹上密封件311在盖体3内的部分且固定连接在盖体3上,保护座33的底端设置有若干通气孔。The cover body 3 is provided with an upper air pressure safety valve 31 for keeping the air pressure in the main body 2 within a preset value. In the embodiment, the upper portion of the cover body 3 is provided with an upper passage 32 communicating with the outside of the cover body 3 and the inside of the cover body 3. The upper pneumatic safety valve 31 is disposed on the upper passage 32, and the upper pneumatic safety valve 31 includes An upper sealing member 311 is attached to the sealing head 3111. The upper sealing member 311 is fixedly connected to the upper limit member 312 disposed inside the cover body 3 through the upper passage 32. The upper sealing head 3111 is located outside the cover body 3, A seal ring is disposed between the seal head 3111 and the lid body 3. An upper elastic member 313 is disposed between the upper limit member 312 and the cover 3, and the upper elastic member 313 is a spring. Preferably, the inside of the cover body 3 is provided with a protection seat 33 on the outer side of the upper sealing member 311. The protection seat covers a portion of the sealing member 311 in the cover body 3 and is fixedly connected to the cover body 3. The protection seat 33 The bottom end is provided with a plurality of vent holes.
主体2内部的气压超过主体2外部的气压时,上弹性件313被主体2内部的气压向上挤压,密封头1311脱离盖体3上表面,主体2内部的气体排出后,主体2内外气压一致后,弹簧回弹密封件131复位,自动时时保证主体2内部气压安全的同时保证了装置的气密性,防止漏水。When the air pressure inside the main body 2 exceeds the air pressure outside the main body 2, the upper elastic member 313 is pressed upward by the air pressure inside the main body 2, and the sealing head 1311 is separated from the upper surface of the cover body 3. After the gas inside the main body 2 is discharged, the air pressure inside and outside the main body 2 is uniform. After that, the spring rebound seal 131 is reset, and the internal pressure of the main body 2 is ensured at the same time to ensure the airtightness of the device and prevent water leakage.
上述电解装置的使用方法,包括以下步骤:The method of using the above electrolysis device comprises the following steps:
往座体1的电极槽112中加水至电极槽112的顶部下方,液体吸附物113吸附加入的水,将座体1与主体2拧紧; Water is added to the electrode groove 112 of the base body 1 to the lower side of the electrode groove 112, and the liquid adsorbate 113 adsorbs the added water to tighten the seat body 1 and the main body 2;
往主体2内加水至满,将盖体3与主体2拧紧,将该电解装置放置在平稳处,电解装置底部的下气压安全阀13由于电解装置自身的重力与放置面的支撑力作用下,下气压安全阀13由于下弹性件133受到挤压而打开;Adding water to the main body 2 to full, screwing the lid body 3 and the main body 2, placing the electrolysis device in a stable position, and the lower air pressure safety valve 13 at the bottom of the electrolysis device is acted upon by the gravity of the electrolysis device itself and the supporting force of the placement surface. The lower air pressure safety valve 13 is opened due to the pressing of the lower elastic member 133;
启动电解电极4开始电解水,电解电极4的阴极片42侧生成氢气,氢气一部分溶解在水中形成富氢水,另一部分形成气泡上升在盖体3与主体2的液面之间聚集;The electrolysis electrode 4 is started to start electrolyzing water, hydrogen gas is generated on the cathode sheet 42 side of the electrolysis electrode 4, a part of hydrogen gas is dissolved in water to form hydrogen-rich water, and the other part forms a bubble rising and accumulates between the lid body 3 and the liquid surface of the main body 2;
电解电极4持续电解时,阴极片42侧产生的氢气越来越多,电解装置的主体2与盖体3内部的气压持续上升,当气压达到盖体3设定的排气气压值时,上气压安全阀31由于上弹性件313挤压上顶打开,气体从上通道32排出;当内部气压降低后,上气压安全阀31在上弹性件313的弹力作用下关闭,停止排气并防止内部水流出;When the electrolysis electrode 4 continues to electrolyze, more and more hydrogen gas is generated on the cathode sheet 42 side, and the gas pressure inside the main body 2 and the lid body 3 of the electrolysis device continuously rises, and when the gas pressure reaches the exhaust gas pressure value set by the cap body 3, The pneumatic safety valve 31 is opened by the upper elastic member 313, and the gas is discharged from the upper passage 32. When the internal air pressure is lowered, the upper pneumatic safety valve 31 is closed by the elastic force of the upper elastic member 313, stopping the exhaust and preventing the internal portion. Water outflow;
电解电极4的阳极片43侧利用液体吸附物113事先添加的水进行电解产生氧化产物气体;The anode sheet 43 side of the electrolytic electrode 4 is electrolyzed by water previously added by the liquid adsorbate 113 to generate an oxidation product gas;
电解电极4电解时,由于阴极片42侧产生的氢气的量大于阳极片43侧氧化产物气体的量,导致气/水隔离膜44阴极片42侧的压力大于气/水隔离膜44阳极片43侧的压力,主体2内的水从阴极片42侧通过气/水隔离膜44渗透至阳极片43侧,并被液体吸附物113吸附供电解电极4的阳极片43继续电解水时使用;When the electrolytic electrode 4 is electrolyzed, since the amount of hydrogen generated on the side of the cathode sheet 42 is larger than the amount of the oxidation product gas on the side of the anode sheet 43, the pressure on the side of the cathode sheet 42 of the gas/water separator 44 is larger than that of the anode/sheet 43 of the gas/water separator 44. On the side pressure, the water in the main body 2 permeates from the cathode sheet 42 side through the gas/water separator 44 to the anode sheet 43 side, and is adsorbed by the liquid adsorbate 113 when the anode sheet 43 of the supply counter electrode 4 continues to electrolyze water;
电解电极4持续电解时,阳极片43侧的氧化产物气体越来越多,氧化产物气体和电极槽112内的电解废水通过气水管114排入废水废气腔12中,氧 化产物气体通过下气压安全阀13排出,电解废水蓄积在废水废气腔12的底部,拔开废水塞14排出电解废水。When the electrolysis electrode 4 is continuously electrolyzed, the oxidation product gas on the anode sheet 43 side is more and more, and the oxidation product gas and the electrolytic waste water in the electrode tank 112 are discharged into the waste gas exhaust chamber 12 through the gas pipe 114, oxygen The product gas is discharged through the lower air pressure safety valve 13, and the electrolytic waste water is accumulated in the bottom of the waste gas exhaust chamber 12, and the waste water plug 14 is pulled out to discharge the electrolytic waste water.
由于氢分子在低压、常温环境下极难溶于液体,并且使用者少有在极短的时间内将氢水液体喝完,所以为保证氢分子在液体的溶解浓度,就必须持续补充因停止电解后所流失的部分氢气分子。为确保液体中的氢浓度,优选的,电解电极4停止制氢后,每隔60s±10s的时间段后再次启动电解电极4制氢10s±5s,对装置中的液体补充氢气。Since the hydrogen molecules are extremely difficult to dissolve in the liquid under low pressure and normal temperature environment, and the user rarely drinks the hydrogen water liquid in a very short time, in order to ensure the dissolved concentration of the hydrogen molecules in the liquid, it is necessary to continue to replenish due to the stoppage. Part of the hydrogen molecules lost after electrolysis. In order to ensure the concentration of hydrogen in the liquid, it is preferable that after the electrolysis electrode 4 stops hydrogen production, the electrolysis electrode 4 is again activated for 10 s ± 5 s every 60 s ± 10 s, and the liquid in the apparatus is supplemented with hydrogen.
以上所述仅为本发明的具体实施方式,并非因此限制本发明的专利范围,凡是利用本发明说明书及附图内容所作的等效结构变换,或直接或间接运用在其他相关的技术领域,均同理包括在本发明的专利保护范围内。 The above description is only the specific embodiment of the present invention, and is not intended to limit the scope of the patents of the present invention. Any equivalent structural changes made by the description of the present invention and the contents of the drawings may be directly or indirectly applied to other related technical fields. The same is included in the scope of patent protection of the present invention.

Claims (10)

  1. 氢氧分离的电解装置的座体结构,其特征在于:包括壳体,壳体内设置有电极槽(112)和电解电极(4),电极槽(112)内容纳有液体吸附物(113),液体吸附物(113)吸附有供电解电极(4)初步电解使用的水;电极槽(112)的底部设置有排出电解废水的开口,电解电极(4)包括阴极片(42)、阳极片(43)以及紧贴设置在阴极片(42)和阳极片(43)之间的气/水隔离膜(44),气/水隔离膜(44)卡设在电极槽(112)上方的壳体内壁上,气/水隔离膜(44)具有电解电极(4)电解时过水不通气以及电解电极(4)非电解时不过水不通气的特性;阳极片(43)紧贴液体吸附物(113)设置,壳体底部设置有用于将电解电极(4)的阳极片(43)侧产生的废水和废气分离后分别排至壳体外部的气水分离排出装置。The structure of the hydrogen-oxygen separation electrolysis device includes a housing in which an electrode slot (112) and an electrolysis electrode (4) are disposed, and the electrode slot (112) contains a liquid adsorbate (113). The liquid adsorbate (113) adsorbs water for preliminary electrolysis of the power supply counter electrode (4); the bottom of the electrode tank (112) is provided with an opening for discharging electrolytic waste water, and the electrolysis electrode (4) includes a cathode sheet (42) and an anode sheet ( 43) and a gas/water separator (44) disposed between the cathode sheet (42) and the anode sheet (43), the gas/water separator (44) is disposed in the casing above the electrode tank (112) On the wall, the gas/water separator (44) has the characteristics that the electrolysis electrode (4) is not ventilated during electrolysis and the electrolysis electrode (4) is not ventilated when electrolyzed (4) is non-electrolyzed; the anode sheet (43) is in close contact with the liquid adsorbate ( 113) The bottom of the casing is provided with a gas-water separation and discharge device for separating the waste water and the exhaust gas generated on the anode piece (43) side of the electrolysis electrode (4) and discharging them to the outside of the casing, respectively.
  2. 根据权利要求1所述的氢氧分离的电解装置的座体结构,其特征在于:所述气水分离排出装置包括下气压安全阀(13)和废水塞(14),下气压安全阀(13)设置在壳体底部一向上凸起的凸部(121)的下通道(1211)中,下通道(1211)连通壳体内部和壳体外部,下气压安全阀(13)依靠座体自身的重力与放置面的支撑力的相互作用处于打开的状态,废水塞(14)设置在壳体底部一连通壳体内部和壳体外部的废水口上。The seat structure of the hydrogen-oxygen separation electrolysis device according to claim 1, wherein the gas-water separation and discharge device comprises a lower air pressure safety valve (13) and a waste water plug (14), and a lower air pressure safety valve (13). Provided in a lower passage (1211) of an upwardly convex portion (121) at the bottom of the casing, the lower passage (1211) communicates with the inside of the casing and the outside of the casing, and the lower pneumatic safety valve (13) depends on the seat itself The interaction of the gravitational force with the supporting force of the placement surface is in an open state, and the waste water plug (14) is disposed at the bottom of the casing, on the waste water port communicating with the inside of the casing and outside the casing.
  3. 根据权利要求2所述的氢氧分离的电解装置的座体结构,其特征在于:所述下气压安全阀(13)包括带下密封头(1311)的下密封件(131),下密封件(131)穿过下通道(1211)与设置在壳体外部的下限位件(132)固定连接,下密封头(1311)位于壳体内的凸部(121)的上方,下密封件 (131)上在壳体底部与下限位件(132)之间套设有下弹性件(133)。The seat structure of the hydrogen-oxygen separation electrolysis device according to claim 2, wherein the lower gas pressure relief valve (13) comprises a lower seal member (131) with a lower seal head (1311), and a lower seal member (131) is fixedly connected to the lower limit member (132) disposed outside the casing through the lower passage (1211), and the lower seal head (1311) is located above the convex portion (121) in the casing, and the lower seal member A lower elastic member (133) is sleeved between the bottom of the housing and the lower limit member (132).
  4. 根据权利要求1所述的氢氧分离的电解装置的座体结构,其特征在于:所述液体吸附物(113)为带有蓄水防臭功能的海绵。The seat structure of the electro-hydrogen separation electrolysis apparatus according to claim 1, wherein the liquid adsorbate (113) is a sponge having a water storage and deodorization function.
  5. 根据权利要求1所述的氢氧分离的电解装置的座体结构,其特征在于:所述壳体内部通过隔离装置(10)分隔成上部的电解腔(11)和下部的废水废气腔(12),电极槽(112)和电解电极(4)设置在电解腔(11)内,电极槽(112)的底部设置有气水管(114),气水管(114)上端连接电极槽(112)底部的开口,下端穿过隔离装置(10)连通废水废气腔(12)。The seat structure of the hydrogen-oxygen separation electrolysis device according to claim 1, wherein the inside of the casing is partitioned into an upper electrolytic chamber (11) and a lower wastewater exhaust chamber by an isolating device (10) (12). The electrode tank (112) and the electrolysis electrode (4) are disposed in the electrolysis chamber (11), and the bottom of the electrode tank (112) is provided with a gas pipe (114), and the upper end of the gas pipe (114) is connected to the bottom of the electrode groove (112). The opening, the lower end communicates with the waste water chamber (12) through the isolating device (10).
  6. 一种电解装置,具有权利要求2至5任一权利要求所述的座体结构,其特征在于:还包括主体(2)和盖体(3),所述座体(1)、主体(2)和盖体(3)依次连接。An electrolysis device having the base structure according to any one of claims 2 to 5, further comprising a main body (2) and a cover body (3), the base body (1), the main body (2) ) and the cover body (3) are connected in order.
  7. 根据权利要求6所述的电解装置,其特征在于:所述盖体(3)上设置有使主体(2)内气压始终处于预设值以内的上气压安全阀(31)。The electrolysis apparatus according to claim 6, characterized in that the lid body (3) is provided with an upper gas pressure safety valve (31) for keeping the gas pressure in the main body (2) within a preset value.
  8. 根据权利要求7所述的电解装置,其特征在于:所述上气压安全阀(31)包括带上密封头(3111)的上密封件(311),上密封件(311)穿过盖体(3)与设置在盖体(3)内部的上限位件(312)固定连接,上密封头(3111)位于盖体(3)外部,上密封件(311)上在上限位件(312)与盖体(3)之间设置有上弹性件(313)。The electrolysis apparatus according to claim 7, wherein said upper pneumatic safety valve (31) comprises an upper sealing member (311) with an upper sealing head (3111), and an upper sealing member (311) passes through the cover body ( 3) fixedly connected with an upper limit member (312) disposed inside the cover body (3), the upper seal head (3111) is located outside the cover body (3), and the upper seal member (311) is at the upper limit position member (312) An upper elastic member (313) is disposed between the cover bodies (3).
  9. 一种根据权利要求7所述的氢氧分离的电解装置的使用方法,其特征在于,包括以下步骤: A method of using a hydrogen-oxygen separation electrolysis device according to claim 7, comprising the steps of:
    往座体(1)的电极槽(112)中加水,液体吸附物(113)吸附加入的水,拧紧座体(1)与主体(2);Water is added to the electrode slot (112) of the seat body (1), the liquid adsorbate (113) adsorbs the added water, and the seat body (1) and the body (2) are tightened;
    往主体(2)内加水,拧紧盖体(3)与主体(2),将该电解装置放置在平稳处,下气压安全阀(13)受到挤压打开;Add water to the main body (2), tighten the cover body (3) and the main body (2), place the electrolysis device in a stable position, and press the lower pneumatic safety valve (13) to be opened;
    启动电解电极(4)开始电解,电解电极(4)的阴极片(42)侧生成氢气,氢气一部分溶解在水中形成富氢水,另一部分聚集在装置内;当装置内部的气压达到盖体(3)设定的排气气压值时,上气压安全阀(31)受到挤压上顶打开,气体排出;随后,上气压安全阀(31)复位关闭;Starting the electrolysis electrode (4) to start electrolysis, hydrogen gas is generated on the cathode sheet (42) side of the electrolysis electrode (4), a part of hydrogen is dissolved in water to form hydrogen-rich water, and another part is collected in the device; when the internal pressure of the device reaches the cover body ( 3) When the exhaust gas pressure value is set, the upper air pressure safety valve (31) is pressed to open the top and the gas is discharged; then, the upper air pressure safety valve (31) is reset and closed;
    电解电极(4)的阳极片(43)侧利用液体吸附物(113)事先添加的水进行电解产生氧化产物气体;主体(2)内的水从阴极片(42)侧通过气/水隔离膜(44)渗透至阳极片(43)侧,并被液体吸附物(113)吸附供电解电极(4)的阳极片(43)继续电解水时使用;The anode sheet (43) side of the electrolysis electrode (4) is electrolyzed by water previously added by the liquid adsorbate (113) to generate an oxidation product gas; the water in the main body (2) passes through the gas/water separator from the cathode sheet (42) side. (44) penetrating to the anode sheet (43) side, and being adsorbed by the liquid adsorbate (113) to supply the anode sheet (43) of the counter electrode (4) to continue to electrolyze water;
    阳极片(43)侧的氧化产物气体和电极槽(112)内的电解废水排入壳体中,氧化产物气体通过下气压安全阀(13)排出,电解废水蓄积在废水废气腔(12)的底部,拔开废水塞(14)排出电解废水。The oxidation product gas on the anode sheet (43) side and the electrolytic waste water in the electrode tank (112) are discharged into the casing, and the oxidation product gas is discharged through the lower gas pressure safety valve (13), and the electrolytic waste water is accumulated in the waste gas exhaust chamber (12). At the bottom, unplug the waste water plug (14) to discharge the electrolytic wastewater.
  10. 根据权利要求9所述的氢氧分离的电解装置的使用方法,其特征在于:所述电解电极(4)每隔60s±10s的时间后再次启动开始电解制氢10s±5s。 The method of using a hydrogen-oxygen separation electrolysis apparatus according to claim 9, wherein the electrolysis electrode (4) is started again for 60 s ± 10 s after every 60 s ± 10 s.
PCT/CN2017/110099 2017-09-30 2017-11-09 Base structure of hydrogen-oxygen-separated electrolysis device and electrolysis device with base structure WO2019061710A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201710923729.XA CN107540055B (en) 2017-09-30 2017-09-30 The base structure and electrolysis unit with the pedestal of the electrolysis unit of hydrogen-oxygen separation
CN201710923729.X 2017-09-30

Publications (1)

Publication Number Publication Date
WO2019061710A1 true WO2019061710A1 (en) 2019-04-04

Family

ID=60963930

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2017/110099 WO2019061710A1 (en) 2017-09-30 2017-11-09 Base structure of hydrogen-oxygen-separated electrolysis device and electrolysis device with base structure

Country Status (2)

Country Link
CN (1) CN107540055B (en)
WO (1) WO2019061710A1 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111039362A (en) * 2019-12-18 2020-04-21 广州康迈斯科技有限公司 Spiral electrolyzed water generator
CN113856425A (en) * 2021-11-10 2021-12-31 南通理工学院 A electrolytic device for electrolyzing marine water method handles boats and ships tail gas
CN113981463A (en) * 2021-11-10 2022-01-28 广州联动万物科技有限公司 Oxygen production device and oxygen production air conditioner
CN117286542A (en) * 2023-09-21 2023-12-26 三一氢能有限公司 Gas-liquid separation box, bipolar plate, electrolytic tank and hydrogen production system

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108570688A (en) * 2018-04-23 2018-09-25 广州市康亦健医疗设备有限公司 A kind of electrolytic water device
CN109110880A (en) * 2018-08-03 2019-01-01 航天神舟生物科技集团有限公司 Hydrogen molecule water preparation apparatus and method under space microgravity environment
CN109717689B (en) * 2018-12-30 2024-02-27 福州品行科技发展有限公司 Self-heating constant-temperature anti-scalding hydrogen-rich cup

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5037518A (en) * 1989-09-08 1991-08-06 Packard Instrument Company Apparatus and method for generating hydrogen and oxygen by electrolytic dissociation of water
CN104775131A (en) * 2014-01-13 2015-07-15 索尔科生物医疗株式会社 Portable apparatus for producing hydrogen water
CN105220173A (en) * 2015-09-07 2016-01-06 深圳市智慧水科技有限公司 A kind of portable rich hydrogen water generating device
CN205062193U (en) * 2015-09-07 2016-03-02 深圳市智慧水科技有限公司 Portable hydrogen -rich water generating device
CN105543883A (en) * 2016-02-29 2016-05-04 朱上翔 Multifunctional negative hydrogen water generator for industrial production
CN106637280A (en) * 2016-12-12 2017-05-10 吴海荣 Hydrogen-enrich water pressurized electrolytic tank core and generator comprising same

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5037518A (en) * 1989-09-08 1991-08-06 Packard Instrument Company Apparatus and method for generating hydrogen and oxygen by electrolytic dissociation of water
CN104775131A (en) * 2014-01-13 2015-07-15 索尔科生物医疗株式会社 Portable apparatus for producing hydrogen water
CN105220173A (en) * 2015-09-07 2016-01-06 深圳市智慧水科技有限公司 A kind of portable rich hydrogen water generating device
CN205062193U (en) * 2015-09-07 2016-03-02 深圳市智慧水科技有限公司 Portable hydrogen -rich water generating device
CN105543883A (en) * 2016-02-29 2016-05-04 朱上翔 Multifunctional negative hydrogen water generator for industrial production
CN106637280A (en) * 2016-12-12 2017-05-10 吴海荣 Hydrogen-enrich water pressurized electrolytic tank core and generator comprising same

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111039362A (en) * 2019-12-18 2020-04-21 广州康迈斯科技有限公司 Spiral electrolyzed water generator
CN113856425A (en) * 2021-11-10 2021-12-31 南通理工学院 A electrolytic device for electrolyzing marine water method handles boats and ships tail gas
CN113981463A (en) * 2021-11-10 2022-01-28 广州联动万物科技有限公司 Oxygen production device and oxygen production air conditioner
CN113856425B (en) * 2021-11-10 2022-06-03 南通理工学院 A electrolytic device for electrolyzing marine water method handles boats and ships tail gas
CN117286542A (en) * 2023-09-21 2023-12-26 三一氢能有限公司 Gas-liquid separation box, bipolar plate, electrolytic tank and hydrogen production system
CN117286542B (en) * 2023-09-21 2024-05-24 三一氢能有限公司 Gas-liquid separation box, bipolar plate, electrolytic tank and hydrogen production system

Also Published As

Publication number Publication date
CN107540055A (en) 2018-01-05
CN107540055B (en) 2019-04-23

Similar Documents

Publication Publication Date Title
WO2019061710A1 (en) Base structure of hydrogen-oxygen-separated electrolysis device and electrolysis device with base structure
KR200459135Y1 (en) Portable device for producing hydrogen enriched water
KR101604804B1 (en) Hydrogen water generator
KR101718110B1 (en) Desktop Hydrogen Gas Generation Device
CN104876376A (en) Preparation device and preparation method of high-concentration and high-stability hydrogen-rich water
CN107041988B (en) Hydrogen breathing machine
KR101683109B1 (en) Apparatus for manufacturing hydrogen containing water
KR101748789B1 (en) Apparatus for manufacturing hydrogen containing water
CN107261289B (en) Hydrogen breathing machine
KR101748788B1 (en) Apparatus for manufacturing hydrogen containing water
CN106830207A (en) Hydrogeneous aquatic products generating apparatus and hydrogeneous cup
KR20100051046A (en) Sanitizing apparatus for a water purifier
CN208218469U (en) The base structure and electrolysis unit with the pedestal of the electrolysis unit of hydrogen-oxygen separation
KR20060045714A (en) Apparatus for producing oxygen using water
KR101771166B1 (en) Apparatus for manufacturing hydrogen containing water
CN207525020U (en) A kind of portable hydrogen formation apparatus of drinking water
CN214072813U (en) Ozone water cup
CN108826784A (en) The fridge freshness retaining degradation residual sterilizing unit of agriculture
CN212128314U (en) Hydrogen machine
CN208398460U (en) The fridge freshness retaining degradation residual sterilizing unit of agriculture
CN206447614U (en) Hydrogeneous aquatic products generating apparatus and hydrogeneous cup
CN217399008U (en) Hydrogen production machine
CN217565587U (en) Electrolytic safety hydrogen-containing water cup
CN108937471A (en) A kind of hydrogen-rich cup for magnetizing water
CN115536121B (en) Hydrogen-rich water generator

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 17926652

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 17926652

Country of ref document: EP

Kind code of ref document: A1