WO2019059706A1 - Mask pack sheet - Google Patents

Mask pack sheet Download PDF

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Publication number
WO2019059706A1
WO2019059706A1 PCT/KR2018/011232 KR2018011232W WO2019059706A1 WO 2019059706 A1 WO2019059706 A1 WO 2019059706A1 KR 2018011232 W KR2018011232 W KR 2018011232W WO 2019059706 A1 WO2019059706 A1 WO 2019059706A1
Authority
WO
WIPO (PCT)
Prior art keywords
mask pack
nonwoven fabric
lyocell
fiber
aggregate
Prior art date
Application number
PCT/KR2018/011232
Other languages
French (fr)
Korean (ko)
Inventor
정종철
김우철
진상우
이상열
정영한
Original Assignee
코오롱인더스트리 주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020180112855A external-priority patent/KR102356631B1/en
Application filed by 코오롱인더스트리 주식회사 filed Critical 코오롱인더스트리 주식회사
Priority to CN201880046974.XA priority Critical patent/CN110913724A/en
Publication of WO2019059706A1 publication Critical patent/WO2019059706A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D44/00Other cosmetic or toiletry articles, e.g. for hairdressers' rooms
    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D44/00Other cosmetic or toiletry articles, e.g. for hairdressers' rooms
    • A45D44/22Face shaping devices, e.g. chin straps; Wrinkle removers, e.g. stretching the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H13/00Other non-woven fabrics

Definitions

  • the present invention relates to a mask pack sheet, and more particularly, to a mask pack sheet formed from a nonwoven fabric assembly including lyocell fibers.
  • the mask pack refers to a mask pack for impregnating a supporter sheet with an active substance or a cosmetic composition containing ingredients useful for the skin such as a liquid or gel moisturizing agent and a whitening agent for skin health such as moisturizing the skin, removing wastes, whitening, It means a product that is made to contact the face for a long time in order to supply nutrition to the skin.
  • the mask pack sheet used as the support of the mask pack is made of natural fibers such as cotton or cotton, silk, hemp, silk, etc. However, it is difficult to adhere to the face portion having many bends, The nonwoven fabric aggregate prepared by using the mixture of the nonwoven fabric fibers is often used.
  • the main synthetic fibers used for the mask pack sheet are polypropylene fiber (PP fiber), polyester fiber (PET fiber), polyethylene fiber (PE fiber), polyvinyl alcohol fiber (PVA fiber) or polylactic acid Fiber), and a variety of materials using these materials have been studied extensively.
  • the stretchability is weak due to the limitation of physical properties of the material itself constituting the synthetic fiber, and when it is made into a mask pack sheet and applied to the skin, it causes inconvenience in activity, The skin is separated from the skin.
  • thermoplastic resins such as polypropylene fibers (PP fibers), polyester fibers (PET fibers), polyethylene fibers (PE fibers), polyvinyl alcohol fibers (PVA fibers), and polylactic acid
  • PP fibers polypropylene fibers
  • PET fibers polyester fibers
  • PE fibers polyethylene fibers
  • PVA fibers polyvinyl alcohol fibers
  • polylactic acid polylactic acid
  • a mask pack sheet is constituted by using a nonwoven fibrous assembly including lyocell fibers, skin adhesion, essence of the material itself constituting the mask pack sheet, Or the transparency after the water treatment is improved, and the present invention has been completed.
  • an object of the present invention is to provide a mask pack sheet formed of a nonwoven fibrous aggregate containing lyocell, which is improved in skin adhesion and improved in absorbency of essence or moisture, transparency after essence treatment or moisture treatment.
  • Another object of the present invention is to provide a cosmetic mask pack using the mask pack sheet.
  • the present invention provides, as a first preferred embodiment, a mask pack sheet formed from a nonwoven fabric assembly comprising lyocell fibers, wherein the lyocell fiber has a fineness of 1.0 to 1.4 denier to provide.
  • the fiber length of the lyocell fiber according to the first embodiment may be 36 to 40 mm.
  • the number of crimps of the lyocell fiber according to the first embodiment may be 5 to 20 cpi.
  • the lyocell fiber according to the first embodiment may have an emulsion content of 0.1 to 0.4% by weight.
  • the basis weight of the nonwoven fabric aggregate according to the first embodiment may be 30 to 60 g / m 2.
  • the thickness of the nonwoven fabric aggregate according to the first embodiment may be 0.3 to 0.5 mm.
  • the nonwoven fabric aggregate according to the first embodiment may have a water absorption rate of 1000 to 1700 wt%.
  • the nonwoven fabric aggregate according to the first embodiment may have transparency of 80 to 84% after the moisture treatment.
  • the nonwoven fabric aggregate according to the first embodiment may have a transparency of 88 to 94% after the essence treatment.
  • the nonwoven fabric aggregate according to the first embodiment may have a skin adhesion force of 3.6 to 4.2 gf after moisture treatment.
  • the nonwoven fabric aggregate according to the first embodiment may have a skin adhesion of 4.5 to 5.4 gf after the essence treatment.
  • the nonwoven fabric aggregate according to the first embodiment may have an emulsion content of 0.001 wt% or less.
  • the present invention can provide a cosmetic mask pack using the mask pack sheet as another preferred first embodiment.
  • the mask pack sheet of the present invention is formed of a nonwoven fibrous aggregate containing lyocell, its elasticity is improved, so that it is not separated from the skin even when worn for a long time, so that the skin adhesion is improved and the skin absorption power, essence, The transparency can be improved.
  • the mask pack sheet as the support sheet of the mask pack for cosmetics, not only the skin adhesion force and wearing feeling are improved but also the absorbency is excellent, so that nutrition can be effectively supplied to the skin.
  • the color of the mask pack sheet is transparent rather than appearing white when the user's face is viewed from the outside, and is made closer to the color of the user's face, So that the appearance after wearing the mask pack can be enhanced.
  • the present invention relates to a mask pack sheet formed from a nonwoven fabric assembly comprising lyocell fibers, wherein the fineness of the lyocell fibers is 1.0 to 1.4 denier.
  • the Lyocell fiber is produced from natural pulp and amine oxide hydrate, and has fiber characteristics such as excellent tensile property and tactile property as compared with conventional regenerated fiber.
  • the lyocell fiber is a hydrophilic material. As the fineness is lowered, the lyocell fiber has a higher specific surface area and is more excellent in water absorption ability.
  • a liquid composition such as moisture and essence is impregnated into the nonwoven fibrous aggregate containing the lyocell fiber, The absorbency of the nonwoven fabric aggregate is increased and the retention of the liquid composition in the nonwoven fabric aggregate can be increased.
  • the fineness of the lyocell fiber may be 1.0 to 1.4 denier. At this time, if the fineness of the lyocell fiber is less than 1.0 denier, the production of the lyocell fiber becomes difficult. When the lyocell fiber exceeds 1.4 denier, the fineness corresponding to the general fineness applied to the mask pack is lost, The physical properties such as essence absorbency show general level.
  • the lyocell fiber may be staple fiber and the fiber length may be 36 to 40 mm.
  • the lyocell fiber is used as a nonwoven fabric aggregate for a mask pack within the fiber length range, there is an advantage in that the processability during the carding process during the production of the nonwoven fabric aggregate is excellent.
  • the number of crimps of the lyocell fiber may be 5 to 20 cpi.
  • the crimp number may be 5 to 20 cpi, preferably 8 to 12 cpi. If the number of crimps is less than 5 cpi, the entanglement of the fibers in the carding process is low during the manufacturing process of the nonwoven fabric aggregate, resulting in a process problem. If the number of crimps exceeds 20 cpi, the crimp number is too large, A problem arises.
  • the lyocell fiber has a crimp number of 8 to 12 cpi, the absorption rate, transparency and adhesion of the liquid composition can be improved when the lyocell fiber is included in the nonwoven fabric aggregate, do.
  • the lyocell fiber may have an emulsion content of 0.1 to 0.4% by weight.
  • the emulsion When the emulsion satisfies the weight percentage range, it reduces the friction generated during the process of forming the filament to be crimped to be described later, and forms a fiber-to-fiber crimp. Also, the carding property of the nonwoven fabric aggregate is improved.
  • the nonwoven fibrous assembly includes the lyocell fibers and may be used in a mask pack sheet.
  • the basis weight of the nonwoven fibrous aggregate may be 30 to 60 g / m 2 , and the thickness of the nonwoven fibrous aggregate may be 0.3 to 0.5 mm.
  • the thickness of the nonwoven fabric aggregate varies depending on the fineness of the staple fiber and the basis weight of the nonwoven fabric aggregate. The smaller the fineness of the staple fiber and the smaller the nonwoven fabric aggregate basis weight, the thinner the thickness.
  • the basis weight and the thickness range are set to an optimum range for improving the water absorption, transparency, and adhesion of the liquid composition in the nonwoven fabric aggregate comprising the lyocell fibers satisfying the fineness, fiber length, crimp water and emulsion content of the lyocell fiber .
  • the nonwoven fabric aggregate may have a water absorption rate of 1000 to 1700%.
  • the lyocell fiber is hydrophilic and has higher water absorption than other fibers.
  • the water absorption rate of the nonwoven fabric aggregate can be adjusted to the above range.
  • the nonwoven fabric aggregate may have a transparency of 80 to 84% after the moisture treatment, and a transparency after the essence treatment of 88 to 94%.
  • the transparency of the nonwoven fabric aggregate is such that the fineness of the lyocell fiber is in the range of 1.0 to 1.4 denier and the fineness of the nonwoven fabric aggregate including the lyocell fiber is reduced. Therefore, the liquid composition such as moisture, When the nonwoven fabric is supported on the nonwoven fabric aggregate, the nonwoven fabric aggregate can have a soft feeling and transparency within the range of the transparency.
  • the nonwoven fabric aggregate may have a skin adhesion force of 3.6 to 4.2 gf after the water treatment and a skin adhesion force of 4.5 to 5.4 gf after the essence treatment.
  • the skin adhesion of the nonwoven fabric aggregate also satisfies the characteristics of the lyocell fiber, and the above range can be satisfied by the basis weight and thickness of the nonwoven fabric aggregate containing the same.
  • the nonwoven fabric aggregate may have an emulsion content of 0.001 wt% or less.
  • the nonwoven fabric aggregate exhibits the same contents as most of the emulsions contained in the lyocell fibers are washed away when the nonwoven fabric aggregate is subjected to the entrapment of the spun lace process during the manufacturing process of the nonwoven fabric aggregate.
  • nonwoven fabric aggregate containing the lyocell fibers will be described in detail through a method for producing the nonwoven fabric aggregate.
  • the method of producing the nonwoven fibrous aggregate comprises: (S1) spinning a lyocell spinning dope comprising a cellulose pulp and a solvent; (S2) solidifying the lyocell radiation dope radiated in the step (S1) to obtain a lyocell multifilament; (S3) washing the lyocell multifilament obtained in the step (S2); (S4) emulsifying the lyocell multifilament washed in the step (S3); (S5) crimping the tanned lyocell multifilament in a stuffer box to obtain a crimped tow; (S6) drying and cutting the crimped tow obtained in the step (S5) to obtain lyocell staple fibers; And (S7) preparing the lyocell staple fibers obtained in the step (S6) as a nonwoven fabric assembly.
  • (S1) is a step of radiating a lyocell spinning dope comprising cellulose pulp and an NMMO aqueous solution.
  • the lyocell spinning dope comprises 6 to 16% by weight of cellulose pulp; And 84 to 94% by weight of an aqueous solution of N-methylmorpholine-N-oxide, wherein the cellulose pulp has an alpha-cellulose content of 85 to 97% by weight and a degree of polymerization (DPw) of 600 to 1700 have.
  • DPw degree of polymerization
  • the content of the cellulose pulp in the lyocell radial dope is less than 6% by weight, it is difficult to realize the fiber property. If the content is more than 16% by weight, it may be difficult to dissolve in the aqueous liquid.
  • the solubility of the solution is undesirably large, and if it exceeds 94% by weight, It may be difficult to produce a uniform fiber.
  • the weight ratio of N-methylmorpholine-N-oxide and water in the N-methylmorpholine-N-oxide aqueous solution may be 93: 7 to 85:15.
  • the weight ratio of N-methylmorpholine-N-oxide and water is more than 93: 7, the dissolution temperature is high and the cellulose may be decomposed upon dissolving cellulose.
  • the weight ratio is less than 85:15, And the dissolution of cellulose may be difficult.
  • the above-described radiation dope is used to discharge it from the spinneret of the spinneret.
  • the spinneret serves to discharge the spinning dope on the filament as a coagulating solution in the coagulation bath through the air gap section.
  • the step of discharging the spinning dope from the spinneret can be performed at a spinning temperature of 80 to 130 ⁇ .
  • (S2) is a step of solidifying the lyocell radiation dope radiated in the step (S1) to obtain a lyocell multifilament, wherein the solidification in the step (S2) is performed by air quenching (Q / A); And a secondary coagulation step in which the primary coagulated radial dope is immersed in the coagulating liquid to coagulate.
  • step (S1) after the spinning dope is discharged through the spinneret, it can be passed through the air gap section of the space between the spinneret and the coagulation bath.
  • cooling air is supplied from the air cooling part located inside the detachment of the donut type to the outside from the inside of the detent, which can be primary solidified by air quenching which supplies the cooling air to the radiation dope.
  • the factor affecting the physical properties of the lyocell multifilament obtained in the step (S2) is the temperature and the wind speed of the cooling air in the air gap section, and the solidification in the step (S2)
  • the cooling air having a wind speed of 50 m / s may be supplied to the spinning dope to solidify.
  • the temperature of the cooling air during the primary solidification is less than 4 ⁇ , the surface of the spinneret cools, the cross-section of the lyocell multifilament becomes uneven and the spinning processability becomes poor. If the temperature is more than 15 ⁇ , The radiation fairness becomes poor.
  • the air velocity of the cooling air during the first solidification is less than 5 m / s, the primary coagulation due to the cooling air is insufficient and the spinning durability is poor and the spinning dope is generated. If the air velocity exceeds 50 m / s, It is shaken by the air and the radiation fairness becomes poor.
  • the spinning dope After primary coagulation by air quenching, the spinning dope is supplied to the coagulation bath containing the coagulation solution and secondary coagulation can proceed.
  • the temperature of the coagulating solution may be 30 DEG C or less for the progress of proper secondary coagulation. This is so that the secondary solidification temperature is not higher than necessary, so that the solidification rate is properly maintained.
  • the coagulating solution is not particularly limited as it can be manufactured and used in a conventional composition in the technical field to which the present invention belongs.
  • the lyocell multifilament obtained in the step (S2) may be introduced into a traction roller and then introduced into a water bath to be washed with water.
  • a washing solution at a temperature of 0 to 100 ° C may be used in consideration of the ease of recovery and reuse of the solvent after washing with water.
  • Water can be used as the washing solution, May be further included.
  • (S4) is a step of tanning the lyocell multifilament washed in the step (S3), and may be dried after emulsion treatment.
  • the tanning process takes the form that the multifilaments are buried completely in the emulsion and keeps the amount of emulsion adhering to the filaments by the press rollers attached to the exit rolls of the tanning apparatus and the discharge rollers.
  • the emulsions reduce the friction that occurs when filaments contact dry rollers, guides, and crimps, and allow the formation of fiber-to-fiber crimps.
  • (S5) is a step of obtaining a crimped tow by crimping the lyocell multifilament treated by tanning in the step (S4).
  • Crimping is a process of applying a crimp to a multifilament, specifically crimping with a stuffer box to obtain a crimped tow having 8 to 12 crimps per inch.
  • step (S5) steam may be supplied to the lyocell multifilament and crimped by applying pressure.
  • the steam is 0.1 ⁇ 1.0kgf / cm 2 and supplied to raise the temperature, and then 1.5 to pressure by the press roller (Press Roller of 2.0kgf / cm 2 ), Thereby forming a crimp in the stopper box.
  • the crimp can not be smoothly formed. If the supply amount of steam is more than 1.0 kgf / cm 2, the temperature in the stopper box rises to 120 ° C or more, and the filaments stick together and can not pass through the stopper box. If the pressure for pressing the pressing roller is less than 1.5 kgf / cm 2, the desired crimp number is not formed. If the pressing force is more than 2.0 kgf / cm 2, the pressing force is too strong, and the filament may not pass through the stopper box.
  • (S6) is a step of drying and cutting the crimped tow obtained in the step (S5) to obtain a lyocell staple fiber.
  • the crimped tow is dried using a Lattice drier and subjected to a cutting process to form a lyocell staple fiber.
  • (S7) is a step of preparing the lyocell staple fibers obtained in the step (S6) into a nonwoven fabric aggregate.
  • the lyocell staple fibers are received and entangled by carding and spun racing to produce a nonwoven fabric assembly.
  • the present invention can be used as a cosmetic mask pack using the mask pack sheet.
  • the mask pack sheet as a support sheet, the mask pack not only improves the skin adhesion and comfort in the face portion having many bends, but also absorbs liquid compositions such as moisture and essence, .
  • the appearance of the user's face may be made to be close to that of the user's face.
  • a cellulose pulp having a degree of polymerization (DPw) of 820 and an alpha-cellulose content of 93.9% was mixed with an NMMO / H2O mixed solvent (weight ratio 90/10) having a propyl gallate content of 0.01% by weight so that the cellulosic pulp content % (Radiation dope concentration 10%).
  • the spinning dope was spinned while adjusting the discharge amount and spinning speed of the spinning dope so that the filament fineness of the filament was 1.25 denier while maintaining the spinning temperature at 110 ⁇ in the spinning nozzle.
  • the spinning dope on the filament discharged from the spinneret was continuously supplied to the coagulating solution in the coagulation bath through the air gap section.
  • the cooling air in the air gap section is subjected to primary solidification of the spinning dope at a temperature of 8 ⁇ and a wind speed of 5 m / s.
  • the coagulating solution used was one with a temperature of 25 ° C and a concentration of 80% by weight of water and 20% by weight of NMMO.
  • the concentration of the coagulating solution was continuously monitored using a sensor and an refractometer.
  • the filament drawn in the air layer through the pulling roller was washed with a wash water sprayed in a water washing device to remove the remaining NMMO and the filament was allowed to uniformly adhere to the filament, % And dried at 150 ° C on a drying roller.
  • the prepared lyocell multifilament was passed through a steam box (pressure condition: 0.15 kgf / cm 2 ) and preheated to give a temperature to the tow, and the stuffer box compression ruler was used at a pressure of 1.5 kgf / cm 2 To thereby produce a crimped tow in a stuffer box, dry it through a Lattice drier, and finally cut to produce a lyocell staple fiber having a 38 mm fiber length.
  • the lyocell staple fiber was manufactured through a carding and spun raising process which is a process of producing a nonwoven fabric aggregate.
  • the nonwoven fabric aggregate was prepared, the basis weight of the nonwoven fabric aggregate was adjusted to 30 gsm by controlling the feed rate and the process speed, The aggregate weighing deviation was in the range of ⁇ 10%.
  • Nonwoven fabric aggregate A nonwoven fabric aggregate having a fineness of 1.25 denier was prepared in the same manner as in Example 1, except that the basis weight was 40 gsm.
  • a nonwoven fabric aggregate having a fineness of 1.25 denier was prepared in the same manner as in Example 1, except that the basis weight of the nonwoven fabric aggregate was adjusted to be 50 gsm.
  • a nonwoven fabric aggregate having a fineness of 1.25 denier was prepared in the same manner as in Example 1, except that the basis weight of the nonwoven fabric aggregate was adjusted to 60 gsm.
  • a 1.0% denier nonwoven fabric aggregate was prepared in the same manner as in Example 1, except that the single-fineness of the lyocell staple fiber was made 1.0 denier and the basis weight of the nonwoven fabric aggregate was 40 gsm.
  • a 1.0% denier monofilament fiber aggregate was prepared in the same manner as in Example 1, except that the fineness of the lyocell staple fiber was made 1.0 denier and the basis weight of the nonwoven fabric aggregate was 50 gsm.
  • a nonwoven fabric aggregate having a single fineness of 1.3 denier was prepared in the same manner as in Example 1, except that the fineness of the lyocell staple fiber was set to 1.3 denier and the basis weight of the nonwoven fabric aggregate was set to 40 gsm.
  • a nonwoven fabric aggregate having a single fineness of 1.3 denier was prepared in the same manner as in Example 1, except that the fineness of the lyocell staple fiber was set at 1.3 denier and the basis weight of the nonwoven fabric aggregate was set at 50 gsm.
  • a nonwoven fabric aggregate of 5 cpi of crimp number was prepared in the same manner as in Example 1, except that the pressure condition of the steam box and the pressure condition of the Stuber box compression roller were adjusted so that the crimp number of the lyocell staple fiber was 5 cpi.
  • a nonwoven fabric aggregate having a crimp number of 20 cpi was prepared in the same manner as in Example 1, except that the pressure condition of the steam box and the pressure condition of the Stuber box compression roller were adjusted so that the crimp number of the lyocell staple fiber was 20 cpi.
  • a nonwoven fabric aggregate having a single fineness of 1.5 denier was prepared in the same manner as in Example 1, except that the fineness of the lyocell staple fiber was set to 1.5 denier and the basis weight of the nonwoven fabric aggregate was set to 40 gsm.
  • a nonwoven fabric aggregate having a single fineness of 1.5 denier was prepared in the same manner as in Example 1, except that the single fineness of the lyocell staple fiber was set to 1.5 denier and the basis weight of the nonwoven fabric aggregate was set to 50 gsm.
  • a 2.0% denier nonwoven fabric aggregate was prepared in the same manner as in Example 1, except that the fineness of the lyocell staple fiber was adjusted to 2.0 denier and the basis weight of the nonwoven fabric aggregate was set to 40 gsm.
  • the fineness, thickness, transparency, absorbency and skin adhesion of the nonwoven fabric aggregate were measured and calculated for the nonwoven fabric assemblies prepared in the Examples and Comparative Examples as follows, Are shown in Table 1 below.
  • Fineness (De) [monofilament cross-section of the lyocell fibers ( ⁇ m) 2 ⁇ Lioness density (g / cm 3) of the fiber cells ⁇ 9000 (m)] / 1000000
  • the nonwoven fibrous aggregate was sampled at a width of 5 cm and a length of 20 cm and weighed, and the basis weight was calculated by the following formula 2.
  • Basis weight non-woven fiber aggregate sample weight measurement ⁇ 100
  • Sample preparation Immerse the nonwoven fiber aggregate in water or essence for 10 minutes.
  • the haze meter (Nippon Denshoku Industry, NDH-5000), a light transmittance equipment, was used and the transmittance at a wavelength of nm was measured.
  • the weight of the nonwoven fabric aggregate was measured by measuring the before / after weight, and the ability of the nonwoven fabric aggregate to absorb water or essence was calculated by the following formula 3.
  • Absorbency (%) ⁇ (Weight of nonwoven fabric aggregate after immersion - Weight of nonwoven fabric aggregate before immersion) / Weight of nonwoven fabric aggregate before immersion ⁇ ⁇ 100
  • the nonwoven fiber aggregate is cut into a size of 25 mm x 150 mm, and immersed in water or essence for 10 minutes, and then adhered to the human arm. After adhesion, the adhesive force (unit gf) was measured using an Instron (Instron, 3365), while leaving the nonwoven fibrous assembly out of the skin.
  • Instron Instron, 3365
  • Example 1 1.25 10 30 0.33 Water 84 Essence 94 Water 1,000 essence 1,300 Water 3.6 Essence 4.5
  • Example 2 1.25 10 40 0.40 Water 82 Essence 92 Water 1,400 Essence 2,000 Water 4.0 Essence 5.0
  • Example 3 1.25 10 50 0.47 Water 81 Essence 90 Water 1,500 Essence 2,100 Water 4.1 Essence 5.1
  • Example 4 1.25 10 60 0.53 Water 80 Essence 88 Water 1,600 Essence 2,200 Water 4.2 Essence 5.3
  • Example 5 1.0 10 40 0.38 Water 82 Essence 93 Water 1,500 Essence 2,200 Water 4.1 Essence 5.2
  • Example 6 1.0 10 50 0.46 Water 80 Essence 91 Water 1,700 Essence 2,500 Water 4.2 Essence 5.4
  • Example 7 1.3 10 40 0.41 Water 81 Essence 91 Water 1,400 Essence 2,100 Water
  • the lyocell fibers comprising the optimal range of the fineness and the crimp number of the lyocell fiber, and the nonwoven fabric aggregate containing the lyocell
  • the basis weight and the thickness in the respective optimum ranges excellent adhesion, transparency, and absorption power can be ensured.
  • the present invention is applicable to a mask pack for cosmetics using a mask pack sheet.

Abstract

The present invention relates to a mask pack sheet and, more particularly, to a mask pack sheet made of a non-woven fiber aggregate comprising lyocell fiber. The mask pack sheet is made of a non-woven fiber aggregate comprising lyocell fiber, and is characterized in that the fineness of the lyocell fiber is 1.0 to 1.4 denier. The mask pack sheet according to the present invention is made of a non-woven fiber aggregate comprising lyocell fiber and thus has improved flexibility. Accordingly, the mask pack sheet does not detach from the skin even after a long period of wearing, and has improved attachment to skin. The degree of absorption of essence or moisture and the transparency after essence or moisture treatment can be improved. In addition, the mask pack sheet can be used as a mask pack supporter sheet, thereby improving the attachment to skin and the feeling of wearing, and the excellent absorption enables effective supply of nutrients to the skin. Furthermore, the wet transparency is improved such that, when the mask pack sheet is tightly attached to the user's face, the color of the mask pack sheet appears transparent rather than white when the user's face is seen from the outside. Accordingly, the color of the mask pack sheet looks close to the color of the user's face such that less difference in appearance is noticeable, thereby providing an aesthetic appearance after wearing the mask pack.

Description

마스크팩 시트Mask pack sheet
본 발명은 마스크팩 시트에 관한 것으로, 특히 라이오셀 섬유를 포함하는 부직 섬유 집합체로 형성되는 마스크팩 시트에 관한 것이다. The present invention relates to a mask pack sheet, and more particularly, to a mask pack sheet formed from a nonwoven fabric assembly including lyocell fibers.
마스크팩이란 화장품 분야에서 피부의 보습, 노폐물 제거, 미백, 피부 건강 증진 등 피부 건강을 위하여 지지체 시트에 액체 또는 젤 성분의 보습제, 미백제와 같은 피부에 유용한 성분이 함유된 활성 물질이나 화장품 조성물을 함침시킨 것으로, 피부에 영양을 공급하기 위해 얼굴에 장시간 접촉시킬 수 있도록 구성한 제품을 의미한다. The mask pack refers to a mask pack for impregnating a supporter sheet with an active substance or a cosmetic composition containing ingredients useful for the skin such as a liquid or gel moisturizing agent and a whitening agent for skin health such as moisturizing the skin, removing wastes, whitening, It means a product that is made to contact the face for a long time in order to supply nutrition to the skin.
마스크팩의 지지체로 사용되는 마스크팩 시트는 면 또는 코튼, 견, 마, 실크 등의 천연섬유를 이용하였지만, 굴곡이 많은 얼굴 부위에 밀착시키기 어렵고, 흡수력 등의 조절이 쉽지 않아, 합성섬유 또는 이들의 혼합물을 이용하여 제조된 부직 섬유 집합체를 이용하는 경우가 많다. The mask pack sheet used as the support of the mask pack is made of natural fibers such as cotton or cotton, silk, hemp, silk, etc. However, it is difficult to adhere to the face portion having many bends, The nonwoven fabric aggregate prepared by using the mixture of the nonwoven fabric fibers is often used.
마스크팩 시트에 사용되는 소재로서 주요 합성섬유는 폴리 프로필렌 섬유(PP 섬유), 폴리 에스테르 섬유(PET 섬유), 폴리 에틸렌 섬유(PE 섬유), 폴리 비닐알코올 섬유(PVA 섬유) 또는 폴리 락틱에시드(PLA 섬유) 등이 있으며, 이들을 혼용한 다양한 소재에 대한 연구가 많이 진행되고 있다. The main synthetic fibers used for the mask pack sheet are polypropylene fiber (PP fiber), polyester fiber (PET fiber), polyethylene fiber (PE fiber), polyvinyl alcohol fiber (PVA fiber) or polylactic acid Fiber), and a variety of materials using these materials have been studied extensively.
이와 같은 합성섬유를 사용할 때, 초극세사 섬유로 된 멜트브로운 부직 섬유 집합체로 제조하면서, 흡수력을 향상시키기 위하여 친수성 첨가제인 계면활성제를 용융방사전에 부가하여 흡수성을 향상시키고자 한 기술에 관하여 특허 제2011-0060525호(공개)에서 소개하고 있다. In the case of using such a synthetic fiber, it is necessary to prepare a meltblown nonwoven fabric aggregate made of microfine fiber while improving the absorbency by adding a surfactant, which is a hydrophilic additive, 2011-0060525 (public) is introduced.
그러나, 이러한 기술을 사용하더라도 합성섬유를 이루는 소재 자체가 가지는 물성의 한계로 인하여 신축성이 약하여, 마스크팩 시트로 제작하여 피부에 적용할 때, 활동에 불편을 야기시키고, 표정의 변화 또는 오랜 시간 착용시 피부로부터 이격되는 문제를 내재하고 있다. However, even if such a technique is used, the stretchability is weak due to the limitation of physical properties of the material itself constituting the synthetic fiber, and when it is made into a mask pack sheet and applied to the skin, it causes inconvenience in activity, The skin is separated from the skin.
또한, 폴리 프로필렌 섬유(PP 섬유), 폴리 에스테르 섬유(PET 섬유), 폴리 에틸렌 섬유(PE 섬유), 폴리 비닐알코올 섬유(PVA 섬유) 또는 폴리 락틱에시드(PLA 섬유) 등의 열가소성 수지들은 친수성이 없어 화장품 조성물에 대한 젖음성이 떨어져서 화장료를 함침해야 하는 마스크팩 시트으로서의 적용에 제한적일 수 밖에 없다. In addition, thermoplastic resins such as polypropylene fibers (PP fibers), polyester fibers (PET fibers), polyethylene fibers (PE fibers), polyvinyl alcohol fibers (PVA fibers), and polylactic acid The wettability with respect to the cosmetic composition deteriorates so that the application as a mask pack sheet to be impregnated with the cosmetic composition is limited.
이에, 본 발명자들은 상기 문제점을 해결하기 위하여, 라이오셀 섬유를 포함하는 부직 섬유 집합체를 사용하여 마스크팩 시트를 구성할 경우, 피부 밀착력, 마스크팩 시트를 이루는 소재 자체의 에센스 혹은 수분의 흡수력, 에센스 혹은 수분 처리 후의 투명성 등이 개선되는 것을 확인하고, 본 발명을 완성하게 되었다. In order to solve the above problems, the inventors of the present invention have found that when a mask pack sheet is constituted by using a nonwoven fibrous assembly including lyocell fibers, skin adhesion, essence of the material itself constituting the mask pack sheet, Or the transparency after the water treatment is improved, and the present invention has been completed.
이에 본 발명의 목적은 피부 밀착력이 향상되며, 에센스 혹은 수분의 흡수력, 에센스 혹은 수분 처리 후의 투명성이 개선되는, 라이오셀을 포함하는 부직 섬유 집합체로 형성된 마스크팩 시트를 제공하는데 있다.Accordingly, an object of the present invention is to provide a mask pack sheet formed of a nonwoven fibrous aggregate containing lyocell, which is improved in skin adhesion and improved in absorbency of essence or moisture, transparency after essence treatment or moisture treatment.
또한, 본 발명의 목적은 상기 마스크팩 시트를 이용한 화장품용 마스크팩을 제공하는데 있다. Another object of the present invention is to provide a cosmetic mask pack using the mask pack sheet.
이에 본 발명은 바람직한 제 1 구현예로서, 라이오셀 섬유를 포함하는 부직 섬유 집합체로 형성되는 마스크팩 시트에 관한 것으로, 상기 라이오셀 섬유의 섬도는 1.0 내지 1.4 데니어인 것을 특징으로 하는 마스크팩 시트를 제공한다. Accordingly, the present invention provides, as a first preferred embodiment, a mask pack sheet formed from a nonwoven fabric assembly comprising lyocell fibers, wherein the lyocell fiber has a fineness of 1.0 to 1.4 denier to provide.
상기 제 1 구현예에 의한 라이오셀 섬유의 섬유장은 36 내지 40mm 인 것일 수 있다. The fiber length of the lyocell fiber according to the first embodiment may be 36 to 40 mm.
상기 제 1 구현예에 의한 라이오셀 섬유의 크림프 수는 5 내지 20cpi인 것일 수 있다. The number of crimps of the lyocell fiber according to the first embodiment may be 5 to 20 cpi.
상기 제 1 구현예에 의한 라이오셀 섬유는 유제 함유량이 0.1 내지 0.4 중량% 인 것일 수 있다.The lyocell fiber according to the first embodiment may have an emulsion content of 0.1 to 0.4% by weight.
상기 제 1 구현예에 의한 부직 섬유 집합체의 평량은 30 내지 60g/m2 인 것일 수 있다.The basis weight of the nonwoven fabric aggregate according to the first embodiment may be 30 to 60 g / m 2.
상기 제 1 구현예에 의한 부직 섬유 집합체의 두께는 0.3 내지 0.5mm 인 것 일 수 있다.The thickness of the nonwoven fabric aggregate according to the first embodiment may be 0.3 to 0.5 mm.
상기 제 1 구현예에 의한 부직 섬유 집합체는 수분 흡수율이 1000 내지 1700 중량% 인 것일 수 있다. The nonwoven fabric aggregate according to the first embodiment may have a water absorption rate of 1000 to 1700 wt%.
상기 제 1 구현예에 의한 부직 섬유 집합체는 수분 처리 후의 투명도가 80 내지 84%인 것일 수 있다. The nonwoven fabric aggregate according to the first embodiment may have transparency of 80 to 84% after the moisture treatment.
상기 제 1 구현예에 의한 부직 섬유 집합체는 에센스 처리 후의 투명도가 88 내지 94% 인 것일 수 있다.The nonwoven fabric aggregate according to the first embodiment may have a transparency of 88 to 94% after the essence treatment.
상기 제 1 구현예에 의한 부직 섬유 집합체는 수분 처리 후의 피부 밀착력이 3.6 내지 4.2 gf 인 것일 수 있다.The nonwoven fabric aggregate according to the first embodiment may have a skin adhesion force of 3.6 to 4.2 gf after moisture treatment.
상기 제 1 구현예에 의한 부직 섬유 집합체는 에센스 처리 후의 피부 밀착력이 4.5 내지 5.4 gf 인 것일 수 있다.The nonwoven fabric aggregate according to the first embodiment may have a skin adhesion of 4.5 to 5.4 gf after the essence treatment.
상기 제 1 구현예에 의한 부직 섬유 집합체는 유제 함유량이 0.001 중량% 이하인 것일 수 있다.The nonwoven fabric aggregate according to the first embodiment may have an emulsion content of 0.001 wt% or less.
또한, 본 발명은 다른 바람직한 제 1 구현예로서, 상기 마스크팩 시트를 이용한 화장품용 마스크팩을 제공할 수 있다.In addition, the present invention can provide a cosmetic mask pack using the mask pack sheet as another preferred first embodiment.
본 발명의 마스크팩 시트는 라이오셀을 포함하는 부직 섬유 집합체로 형성됨으로써, 신축성이 향상되어 오랜 시간 착용시에도 피부로부터 이격되지 않아 피부 밀착력이 향상되며, 에센스 혹은 수분의 흡수력, 에센스 혹은 수분 처리 후의 투명성이 개선될 수 있다.Since the mask pack sheet of the present invention is formed of a nonwoven fibrous aggregate containing lyocell, its elasticity is improved, so that it is not separated from the skin even when worn for a long time, so that the skin adhesion is improved and the skin absorption power, essence, The transparency can be improved.
또한, 마스크팩 시트를 화장품용 마스크팩의 지지체 시트로 사용함으로써, 피부 밀착력, 착용감이 향상될 뿐만 아니라 흡수성이 우수하여 피부에 효과적으로 영양공급을 할 수 있다.In addition, by using the mask pack sheet as the support sheet of the mask pack for cosmetics, not only the skin adhesion force and wearing feeling are improved but also the absorbency is excellent, so that nutrition can be effectively supplied to the skin.
또한, 습윤 투명성이 개선되어 사용자의 얼굴에 밀착시킨 경우, 외부에서 사용자의 얼굴을 볼 때 마스크팩 시트의 색상이 하얀 색으로 나타나기 보다 투명한 상태가 되어 사용자의 얼굴색과 가깝게 보이게 함으로써, 외관상 이질감을 덜 느끼게 하여 마스크팩 착용 후의 외관이 미려해질 수 있다. In addition, when the wet transparency is improved and brought into close contact with the user's face, the color of the mask pack sheet is transparent rather than appearing white when the user's face is viewed from the outside, and is made closer to the color of the user's face, So that the appearance after wearing the mask pack can be enhanced.
이하, 본 발명을 실시의 형태들에 기초하여 상세히 설명한다. Hereinafter, the present invention will be described in detail based on embodiments.
본 발명은 라이오셀 섬유를 포함하는 부직 섬유 집합체로 형성되는 마스크팩 시트에 관한 것으로, 상기 라이오셀 섬유의 섬도는 1.0 내지 1.4 데니어인 것을 특징으로 하는 마스크팩 시트를 제공할 수 있다. The present invention relates to a mask pack sheet formed from a nonwoven fabric assembly comprising lyocell fibers, wherein the fineness of the lyocell fibers is 1.0 to 1.4 denier.
상기 라이오셀(Lyocell) 섬유는 천연 펄프 및 아민 옥사이드 수화물로부터 제조되는 것으로, 종래의 재생 섬유에 비해 우수한 인장특성과 촉감 등의 섬유 특성을 가진다. 또한, 상기 라이오셀 섬유는 친수성 물질에 해당하여, 단섬도를 낮출수록 비표면적이 높아 수분 흡수력이 우수하여, 라이오셀 섬유를 포함하는 부직 섬유 집합체에 수분 및 에센스 등의 액상 조성물을 함침시켰을 때, 부직 섬유 집합체의 흡수력이 높아지고, 부직 섬유 집합체 내의 액상 조성물 유지력도 높아질 수 있는 것이다. The Lyocell fiber is produced from natural pulp and amine oxide hydrate, and has fiber characteristics such as excellent tensile property and tactile property as compared with conventional regenerated fiber. In addition, the lyocell fiber is a hydrophilic material. As the fineness is lowered, the lyocell fiber has a higher specific surface area and is more excellent in water absorption ability. When a liquid composition such as moisture and essence is impregnated into the nonwoven fibrous aggregate containing the lyocell fiber, The absorbency of the nonwoven fabric aggregate is increased and the retention of the liquid composition in the nonwoven fabric aggregate can be increased.
특히, 상기 라이오셀 섬유의 섬도는 1.0 내지 1.4 데니어일 수 있다. 이 때, 라이오셀 섬유의 섬도가 1.0 데니어 미만이면 라이오셀 섬유의 제조가 난해한 문제가 발생되고, 1.4 데니어를 초과하는 경우에는, 마스크팩에 적용되는 일반적인 섬도에 해당되어 특징이 없어져, 피부 밀착력이나 에센스 흡수력 등 물성이 일반적인 수준을 나타낸다.In particular, the fineness of the lyocell fiber may be 1.0 to 1.4 denier. At this time, if the fineness of the lyocell fiber is less than 1.0 denier, the production of the lyocell fiber becomes difficult. When the lyocell fiber exceeds 1.4 denier, the fineness corresponding to the general fineness applied to the mask pack is lost, The physical properties such as essence absorbency show general level.
또, 상기 라이오셀 섬유는 스테이플 섬유로, 섬유장(纖維長)은 36 내지 40mm일 수 있다. 상기 라이오셀 섬유가 상기 섬유장 범위내에서 마스크팩용 부직 섬유 집합체로 사용되는 경우 부직 섬유 집합체 제조 공정 중 카딩 공정에서의 공정성이 우수한 장점이 있다.In addition, the lyocell fiber may be staple fiber and the fiber length may be 36 to 40 mm. When the lyocell fiber is used as a nonwoven fabric aggregate for a mask pack within the fiber length range, there is an advantage in that the processability during the carding process during the production of the nonwoven fabric aggregate is excellent.
또, 상기 라이오셀 섬유의 크림프 수는 5 내지 20 cpi일 수 있다. 크림프 수는 5 내지 20cpi, 바람직하게는 8 내지 12cpi일 수 있다. 이 때, 크림프 수가 5cpi 미만이면 부직 섬유 집합체 제조공정 중 카딩 공정에서 섬유간의 얽힘이 낮아서 공정 문제가 발생되며, 20cpi 초과이면, 크림프수가 너무 많아서 부직 섬유 집합체 제조 공정 중 카딩 공정에서 개섬이 잘 되지 않는 문제가 발생한다. 상기 라이오셀 섬유의 크림프 수가 8 내지 12cpi인 경우, 부직 섬유 집합체에 라이오셀 섬유가 포함될 때 액상 조성물의 흡수율, 투명도 및 밀착력을 향상시킬 수 있으며, 마스크팩 시트에 사용되는 부직 섬유 집합체의 평량에 부합된다. The number of crimps of the lyocell fiber may be 5 to 20 cpi. The crimp number may be 5 to 20 cpi, preferably 8 to 12 cpi. If the number of crimps is less than 5 cpi, the entanglement of the fibers in the carding process is low during the manufacturing process of the nonwoven fabric aggregate, resulting in a process problem. If the number of crimps exceeds 20 cpi, the crimp number is too large, A problem arises. When the lyocell fiber has a crimp number of 8 to 12 cpi, the absorption rate, transparency and adhesion of the liquid composition can be improved when the lyocell fiber is included in the nonwoven fabric aggregate, do.
또, 상기 라이오셀 섬유는 유제 함유량이 0.1 내지 0.4 중량% 일 수 있다. 상기 유제가 중량% 범위를 만족하는 경우에, 후술할 필라멘트가 크림프 토우로 형성되는 과정에서 발생하는 마찰을 줄여주며, 섬유간 크림프를 잘 형성하도록 한다. 또한 부직 섬유 집합체 제조 시 카딩성을 좋게 하도록 한다.The lyocell fiber may have an emulsion content of 0.1 to 0.4% by weight. When the emulsion satisfies the weight percentage range, it reduces the friction generated during the process of forming the filament to be crimped to be described later, and forms a fiber-to-fiber crimp. Also, the carding property of the nonwoven fabric aggregate is improved.
상기 부직 섬유 집합체는 상기 라이오셀 섬유를 포함하며, 마스크팩 시트에 사용될 수 있다. 상기 부직 섬유 집합체의 평량은 30 내지 60g/m2일 수 있고, 부직 섬유 집합체의 두께는 0.3 내지 0.5mm 일 수 있다. 상기 부직 섬유 집합체의 두께는 스테이플 섬유의 단섬도 및 부직 섬유 집합체의 평량에 따라 달라지는 물성으로, 스테이플 섬유의 단섬도가 낮을수록, 부직 섬유 집합체 평량이 작을수록 두께는 얇아진다. 상기 평량 및 두께 범위는 상기 라이오셀 섬유의 섬도, 섬유장, 크림프 수, 유제 함유량을 만족하는 상기 라이오셀 섬유를 포함하는 부직 섬유 집합체 중에서 액상 조성물의 흡수율, 투명도 및 밀착력을 향상시키기 위한 최적의 범위를 의미한다.The nonwoven fibrous assembly includes the lyocell fibers and may be used in a mask pack sheet. The basis weight of the nonwoven fibrous aggregate may be 30 to 60 g / m 2 , and the thickness of the nonwoven fibrous aggregate may be 0.3 to 0.5 mm. The thickness of the nonwoven fabric aggregate varies depending on the fineness of the staple fiber and the basis weight of the nonwoven fabric aggregate. The smaller the fineness of the staple fiber and the smaller the nonwoven fabric aggregate basis weight, the thinner the thickness. The basis weight and the thickness range are set to an optimum range for improving the water absorption, transparency, and adhesion of the liquid composition in the nonwoven fabric aggregate comprising the lyocell fibers satisfying the fineness, fiber length, crimp water and emulsion content of the lyocell fiber .
또, 상기 부직 섬유 집합체는 수분 흡수율이 1000 내지 1700% 일 수 있다. 상술했듯이, 상기 라이오셀 섬유는 친수성에 해당하여 수분 흡수율이 다른 섬유에 비해 높은 편이지만, 상기 라이오셀 섬유의 특성을 만족시키면서 상기 부직 섬유 집합체의 평량 및 두께 범위를 만족하는 경우에 상기 라이오셀 섬유를 포함하는 부직 섬유 집합체의 수분 흡수율을 상기 범위에 맞춰 흡수시킬 수 있다. The nonwoven fabric aggregate may have a water absorption rate of 1000 to 1700%. As described above, the lyocell fiber is hydrophilic and has higher water absorption than other fibers. However, when the basis weight and thickness range of the nonwoven fabric aggregate are satisfied while satisfying the characteristics of the lyocell fiber, The water absorption rate of the nonwoven fabric aggregate can be adjusted to the above range.
또, 상기 부직 섬유 집합체는 수분 처리 후의 투명도가 80 내지 84% 일 수 있고, 에센스 처리 후의 투명도가 88 내지 94%일 수 있다. 상기 부직 섬유 집합체의 투명도는 상기 라이오셀 섬유의 섬도가 1.0 내지 1.4 데니어로 세섬도에 해당되어, 상기 라이오셀 섬유를 포함하는 부직 섬유 집합체의 두께도 얇아지기 때문에 수분 및 에센스 등의 액상 조성물을 상기 부직 섬유 집합체에 담지하면 부드러운 감촉과 함께 상기 투명도의 범위내의 투명성을 가질 수 있다. The nonwoven fabric aggregate may have a transparency of 80 to 84% after the moisture treatment, and a transparency after the essence treatment of 88 to 94%. The transparency of the nonwoven fabric aggregate is such that the fineness of the lyocell fiber is in the range of 1.0 to 1.4 denier and the fineness of the nonwoven fabric aggregate including the lyocell fiber is reduced. Therefore, the liquid composition such as moisture, When the nonwoven fabric is supported on the nonwoven fabric aggregate, the nonwoven fabric aggregate can have a soft feeling and transparency within the range of the transparency.
또, 상기 부직 섬유 집합체는 수분 처리 후의 피부 밀착력이 3.6 내지 4.2 gf 일 수 있고, 에센스 처리 후의 피부 밀착력이 4.5 내지 5.4 gf 일 수 있다. 상기 부직 섬유 집합체의 피부 밀착력도 상기 라이오셀 섬유의 특성을 만족하며, 이를 포함하는 부직 섬유 집합체의 평량 및 두께에 의해 상기 범위를 만족시킬 수 있다.The nonwoven fabric aggregate may have a skin adhesion force of 3.6 to 4.2 gf after the water treatment and a skin adhesion force of 4.5 to 5.4 gf after the essence treatment. The skin adhesion of the nonwoven fabric aggregate also satisfies the characteristics of the lyocell fiber, and the above range can be satisfied by the basis weight and thickness of the nonwoven fabric aggregate containing the same.
또, 상기 부직 섬유 집합체는 유제 함유량이 0.001 중량% 이하일 수 있다. 상기 부직 섬유 집합체는 부직 섬유 집합체 제조 공정 중 스펀레이스 공정의 수락교락 시 라이오셀 섬유가 함유하고 있는 유제가 대부분 씻겨나가게 되어 상기와 같은 함유율을 나타낸다.The nonwoven fabric aggregate may have an emulsion content of 0.001 wt% or less. The nonwoven fabric aggregate exhibits the same contents as most of the emulsions contained in the lyocell fibers are washed away when the nonwoven fabric aggregate is subjected to the entrapment of the spun lace process during the manufacturing process of the nonwoven fabric aggregate.
이하에서는 상기 부직 섬유 집합체의 제조방법을 통해, 상기 라이오셀 섬유를 포함하고 있는 상기 부직 섬유 집합체를 구체적으로 설명한다. Hereinafter, the nonwoven fabric aggregate containing the lyocell fibers will be described in detail through a method for producing the nonwoven fabric aggregate.
상기 부직 섬유 집합체의 제조방법은 (S1) 셀룰로오스 펄프 및 용매를 포함하는 라이오셀 방사 도프를 방사하는 단계; (S2) 상기 (S1) 단계에서 방사된 라이오셀 방사 도프를 응고시켜 라이오셀 멀티필라멘트를 수득하는 단계; (S3) 상기 (S2) 단계에서 수득된 라이오셀 멀티필라멘트를 수세하는 단계; (S4) 상기 (S3) 단계에서 수세된 라이오셀 멀티필라멘트를 유제 처리하는 단계; (S5) 상기 (S4) 단계에서 유제 처리된 라이오셀 멀티필라멘트를 스터퍼(stuffer box)를 통해 크림핑하여 크림프 토우(crimped tow)를 얻는 단계; (S6) 상기 (S5) 단계에서 수득된 크림프 토우를 건조 및 커팅하여 라이오셀 스테이플 섬유를 얻는 단계; 및 (S7) 상기 (S6) 단계에서 수득된 라이오셀 스테이플 섬유를 부직 섬유 집합체로 제조하는 단계를 포함한다. The method of producing the nonwoven fibrous aggregate comprises: (S1) spinning a lyocell spinning dope comprising a cellulose pulp and a solvent; (S2) solidifying the lyocell radiation dope radiated in the step (S1) to obtain a lyocell multifilament; (S3) washing the lyocell multifilament obtained in the step (S2); (S4) emulsifying the lyocell multifilament washed in the step (S3); (S5) crimping the tanned lyocell multifilament in a stuffer box to obtain a crimped tow; (S6) drying and cutting the crimped tow obtained in the step (S5) to obtain lyocell staple fibers; And (S7) preparing the lyocell staple fibers obtained in the step (S6) as a nonwoven fabric assembly.
[(S1) 단계][Step (S1)] [
(S1) 단계는 셀룰로오스 펄프 및 NMMO 수용액을 포함하는 라이오셀 방사 도프를 방사하는 단계이다.(S1) is a step of radiating a lyocell spinning dope comprising cellulose pulp and an NMMO aqueous solution.
상기 라이오셀 방사 도프는 셀룰로오스 펄프 6 ~ 16 중량%; 및 N-메틸모폴린-N-옥사이드 수용액 84 ~ 94 중량%를 포함하는 것일 수 있으며, 상기 셀룰로오스 펄프는 알파-셀룰로오스 함량이 85 ~ 97중량%이고, 중합도(DPw)가 600~1700인 것일 수 있다.The lyocell spinning dope comprises 6 to 16% by weight of cellulose pulp; And 84 to 94% by weight of an aqueous solution of N-methylmorpholine-N-oxide, wherein the cellulose pulp has an alpha-cellulose content of 85 to 97% by weight and a degree of polymerization (DPw) of 600 to 1700 have.
상기 라이오셀 방사 도프에 있어서 셀룰로오스 펄프의 함량이 6 중량% 미만이면 섬유적 특성을 구현하기 어렵고, 16 중량% 초과이면 수용액상에 용해하기 어려울 수 있다.If the content of the cellulose pulp in the lyocell radial dope is less than 6% by weight, it is difficult to realize the fiber property. If the content is more than 16% by weight, it may be difficult to dissolve in the aqueous liquid.
또한, 라이오셀 방사 도프에 있어서 상기 N-메틸모폴린-N-옥사이드수용액의 함량이 84 중량% 미만이면 용해 점도가 크게 놓아져서 바람직하지 못하며, 94 중량% 초과이면 방사 점도가 크게 낮아져서 방사단계에서 균일한 섬유를 제조하기에 어려울 수 있다.If the content of the aqueous solution of N-methylmorpholine-N-oxide in the lyocell radial dope is less than 84% by weight, the solubility of the solution is undesirably large, and if it exceeds 94% by weight, It may be difficult to produce a uniform fiber.
상기 N-메틸모폴린-N-옥사이드 수용액에서 N-메틸모폴린-N-옥사이드 및 물의 중량비가 93:7 내지 85:15 일 수 있다. 상기 N-메틸모폴린-N-옥사이드 및 물의 중량비가 93:7 초과인 경우에는 용해 온도가 높아져서 셀룰로오스 용해 시 셀룰로오스의 분해가 발생할 수 있으며, 상기 중량비가 85:15 미만인 경우에는 용매의 용해 성능이 저하되어 셀룰로오스의 용해가 어려울 수 있다.The weight ratio of N-methylmorpholine-N-oxide and water in the N-methylmorpholine-N-oxide aqueous solution may be 93: 7 to 85:15. When the weight ratio of N-methylmorpholine-N-oxide and water is more than 93: 7, the dissolution temperature is high and the cellulose may be decomposed upon dissolving cellulose. When the weight ratio is less than 85:15, And the dissolution of cellulose may be difficult.
상술한 방사 도프를 사용하여 이를 방사 구금의 방사 노즐로부터 토출시킨다. 이때, 상기 방사 구금은 필라멘트 상의 방사 도프를 에어 갭 구간을 통해 응고조 내의 응고액으로 토출시키는 역할을 한다. 상기 방사 도프를 방사 구금으로부터 토출시키는 단계는 80~130℃의 방사온도 하에서 이루어질 수 있다.The above-described radiation dope is used to discharge it from the spinneret of the spinneret. At this time, the spinneret serves to discharge the spinning dope on the filament as a coagulating solution in the coagulation bath through the air gap section. The step of discharging the spinning dope from the spinneret can be performed at a spinning temperature of 80 to 130 캜.
[(S2) 단계][Step S2]
(S2) 단계는 상기 (S1) 단계에서 방사된 라이오셀 방사 도프를 응고시켜 라이오셀 멀티필라멘트를 수득하는 단계로서, 상기 (S2) 단계의 응고는 냉각공기를 방사 도프에 공급하여 응고시키는 air quenching(Q/A)에 의한 1차 응고단계; 및 1차 응고된 방사 도프를 응고액에 담그어 응고시키는 2차 응고단계를 포함할 수 있다.(S2) is a step of solidifying the lyocell radiation dope radiated in the step (S1) to obtain a lyocell multifilament, wherein the solidification in the step (S2) is performed by air quenching (Q / A); And a secondary coagulation step in which the primary coagulated radial dope is immersed in the coagulating liquid to coagulate.
상기 (S1) 단계에서, 방사 구금을 통하여 방사 도프를 토출시킨 후에는 이를 상기 방사 구금과, 응고조 사이 공간의 에어 갭 구간으로 통과시킬 수 있다. 이러한 에어 갭 구간에는 도넛 형태의 구금의 안쪽에 위치한 공냉부로부터 구금의 안쪽에서 바깥쪽으로 냉각 공기가 공급되는데, 이러한 냉각 공기를 방사 도프에 공급하는 air quenching에 의해 1차 응고될 수 있다.In the step (S1), after the spinning dope is discharged through the spinneret, it can be passed through the air gap section of the space between the spinneret and the coagulation bath. In such an air gap section, cooling air is supplied from the air cooling part located inside the detachment of the donut type to the outside from the inside of the detent, which can be primary solidified by air quenching which supplies the cooling air to the radiation dope.
이때, (S2) 단계에서 수득되는 라이오셀 멀티필라멘트의 물성에 영향을 미치는 요소는 에어 갭 구간에서의 냉각 공기의 온도 및 풍속이며, (S2) 단계의 응고는 4~15℃의 온도 및 5 ~ 50m/s의 풍속을 갖는 냉각 공기를 방사 도프에 공급하여 응고하는 것일 수 있다.At this time, the factor affecting the physical properties of the lyocell multifilament obtained in the step (S2) is the temperature and the wind speed of the cooling air in the air gap section, and the solidification in the step (S2) The cooling air having a wind speed of 50 m / s may be supplied to the spinning dope to solidify.
상기 1차 응고시 냉각 공기의 온도가 4℃ 미만이면 구금 표면이 식고, 라이오셀 멀티필라멘트의 단면이 불균일하게 되고 방사 공정성도 좋지 않게 되며, 15℃ 초과이면 냉각 공기에 의한 1차 응고가 충분히 되지 않아 방사 공정성이 좋지 않게 된다.If the temperature of the cooling air during the primary solidification is less than 4 캜, the surface of the spinneret cools, the cross-section of the lyocell multifilament becomes uneven and the spinning processability becomes poor. If the temperature is more than 15 캜, The radiation fairness becomes poor.
또한, 1차 응고시 냉각 공기의 풍속이 5m/s 미만이면 냉각 공기에 의한 1차 응고가 충분히 되지 않아서 방사 공정성이 좋지 않게 되어 사절이 발생하고, 50m/s 초과이면 구금에서 토출되는 방사 도프가 공기에 의해 흔들리면서 방사 공정성이 좋지 않게 된다. If the air velocity of the cooling air during the first solidification is less than 5 m / s, the primary coagulation due to the cooling air is insufficient and the spinning durability is poor and the spinning dope is generated. If the air velocity exceeds 50 m / s, It is shaken by the air and the radiation fairness becomes poor.
air quenching에 의한 1차 응고 후, 상기 방사 도프는 응고액이 담겨 있는 응고조에 공급되어 2차 응고가 진행될 수 있다. 한편, 적절한 2차 응고의 진행을 위해, 상기 응고액의 온도는 30℃ 이하일 수 있다. 이는 2차 응고 온도가 필요 이상으로 높지 않아 응고 속도가 적절히 유지되도록 하기 위한 것이다. 여기서 상기 응고액은 본 발명이 속하는 기술분야에서 통상의 조성으로 제조하여 사용할 수 있으므로 특별히 한정되지 않는다.After primary coagulation by air quenching, the spinning dope is supplied to the coagulation bath containing the coagulation solution and secondary coagulation can proceed. On the other hand, the temperature of the coagulating solution may be 30 DEG C or less for the progress of proper secondary coagulation. This is so that the secondary solidification temperature is not higher than necessary, so that the solidification rate is properly maintained. Herein, the coagulating solution is not particularly limited as it can be manufactured and used in a conventional composition in the technical field to which the present invention belongs.
[(S3) 단계][Step (S3)] [
(S3) 단계는 상기 (S2) 단계에서 수득된 라이오셀 멀티필라멘트를 수세하는 단계이다. (S3) is washing the lyocell multifilament obtained in the step (S2).
구체적으로는, 상기 (S2) 단계에서 수득된 라이오셀 멀티필라멘트를 견인롤러에 도입한 후, 수세욕으로 도입하여 수세할 수 있다.Specifically, the lyocell multifilament obtained in the step (S2) may be introduced into a traction roller and then introduced into a water bath to be washed with water.
상기 필라멘트의 수세 단계에서는, 수세 후 용제의 회수 및 재사용의 용이성을 고려하여, 0 내지 100℃ 온도의 수세액을 사용할 수 있으며, 상기 수세액으로는 물을 이용할 수 있고, 필요에 따라 기타의 첨가 성분을 더욱 포함시킬 수도 있다.In the washing step of the filament, a washing solution at a temperature of 0 to 100 ° C may be used in consideration of the ease of recovery and reuse of the solvent after washing with water. Water can be used as the washing solution, May be further included.
[(S4) 단계][Step (S4)] [
(S4) 단계는 상기 (S3) 단계에서 수세된 라이오셀 멀티필라멘트를 유제 처리하는 단계로서, 유제 처리 후 건조할 수 있다.(S4) is a step of tanning the lyocell multifilament washed in the step (S3), and may be dried after emulsion treatment.
유제 처리는 멀티필라멘트가 유제 속에 완전히 잠겨서 묻혀지는 형태를 취하며 유제 처리 장치의 진입롤과 방출롤에 부착된 프레스 롤러에 의해 유제가 필라멘트에 묻는 양을 일정하게 유지한다. 상기 유제는 필라멘트가 건조 롤러 및 가이드, 크림프 단계에서의 접촉 시 발생하는 마찰을 줄여주고 섬유간 크림프가 잘 형성되도록 한다.The tanning process takes the form that the multifilaments are buried completely in the emulsion and keeps the amount of emulsion adhering to the filaments by the press rollers attached to the exit rolls of the tanning apparatus and the discharge rollers. The emulsions reduce the friction that occurs when filaments contact dry rollers, guides, and crimps, and allow the formation of fiber-to-fiber crimps.
[(S5) 단계][Step (S5)] [
(S5) 단계는 상기 (S4) 단계에서 유제 처리된 라이오셀 멀티필라멘트를 크림핑(crimping)하여 크림프 토우(crimped tow)를 얻는 단계이다.(S5) is a step of obtaining a crimped tow by crimping the lyocell multifilament treated by tanning in the step (S4).
크림핑이란 멀티필라멘트에 크림프를 부여하는 공정으로서, 구체적으로 스터퍼 박스(stuffer box)를 이용하여 크림핑하여 인치당 8~12개의 크림프가 부여된 크림프 토우를 얻을 수 있다.Crimping is a process of applying a crimp to a multifilament, specifically crimping with a stuffer box to obtain a crimped tow having 8 to 12 crimps per inch.
상기 (S5) 단계에서는 라이오셀 멀티필라멘트에 스팀을 공급하고 압력을 가하여 크림핑하는 것일 수 있다.In step (S5), steam may be supplied to the lyocell multifilament and crimped by applying pressure.
구체적으로, 상기 라이오셀 멀티필라멘트를 스팀박스(Steam box)에 통과시켜, 스팀은 0.1~1.0kgf/cm2으로 공급하여 온도를 올린 다음 1.5~2.0kgf/cm2의 압력으로 프레스 롤러(Press Roller)를 이용하여 압착함으로써, 스토퍼 박스에서 크림프가 형성된다.Specifically, by passing the lyocell multifilament in a steam box (Steam box), the steam is 0.1 ~ 1.0kgf / cm 2 and supplied to raise the temperature, and then 1.5 to pressure by the press roller (Press Roller of 2.0kgf / cm 2 ), Thereby forming a crimp in the stopper box.
이때, 스팀의 공급량이 0.1 kgf/cm2 미만이면 크림프가 원활하게 형성되지 않으며, 1.0 kgf/cm2 초과이면 스토퍼 박스내의 온도가 120℃ 이상으로 상승하여 필라멘트가 서로 붙어서 스토퍼 박스를 통과하지 못한다. 또한, 압착 롤러를 눌러주는 압력이 1.5 kgf/cm2 미만이면 원하는 크림프 수가 형성되지 않고, 2.0 kgf/cm2 초과이면 눌러주는 힘이 너무 강하여 이 역시 필라멘트가 스토퍼 박스를 통과하지 못할 수가 있다.At this time, if the supply amount of steam is less than 0.1 kgf / cm 2, the crimp can not be smoothly formed. If the supply amount of steam is more than 1.0 kgf / cm 2, the temperature in the stopper box rises to 120 ° C or more, and the filaments stick together and can not pass through the stopper box. If the pressure for pressing the pressing roller is less than 1.5 kgf / cm 2, the desired crimp number is not formed. If the pressing force is more than 2.0 kgf / cm 2, the pressing force is too strong, and the filament may not pass through the stopper box.
[(S6) 단계][Step S6]
(S6) 단계는 상기 (S5) 단계에서 수득된 크림프 토우를 건조 및 커팅하여 라이오셀 스테이플 섬유를 얻는 단계이다. (S6) is a step of drying and cutting the crimped tow obtained in the step (S5) to obtain a lyocell staple fiber.
상기 크림프 토우는 Lattice 건조기를 이용하여 건조하고, 커팅 공정을 거쳐라이오셀 스테이플 섬유를 형성한다. The crimped tow is dried using a Lattice drier and subjected to a cutting process to form a lyocell staple fiber.
[(S7) 단계][Step S7]
(S7) 단계는 상기 (S6) 단계에서 수득된 라이오셀 스테이플 섬유를 부직 섬유 집합체로 제조하는 단계이다. (S7) is a step of preparing the lyocell staple fibers obtained in the step (S6) into a nonwoven fabric aggregate.
상기 라이오셀 스테이플 섬유는 카딩 및 스펀레이싱 방식으로 수락교락하여 부직 섬유 집합체를 제조한다. The lyocell staple fibers are received and entangled by carding and spun racing to produce a nonwoven fabric assembly.
본 발명은 상기 마스크팩 시트를 이용한 화장품용 마스크팩으로 사용할 수 있다. 상기 마스크팩은 상기 마스크팩 시트를 지지체 시트로 사용하여, 굴곡이 많은 얼굴 부위에서도 피부 밀착력, 착용감이 향상될 뿐만 아니라 수분 및 에센스 등의 액상 조성물의 흡수성이 우수하여 얼굴 부위에 효과적으로 영양공급을 할 수 있다. The present invention can be used as a cosmetic mask pack using the mask pack sheet. Using the mask pack sheet as a support sheet, the mask pack not only improves the skin adhesion and comfort in the face portion having many bends, but also absorbs liquid compositions such as moisture and essence, .
또, 습윤 투명성이 개선되어 사용자의 얼굴에 밀착시킬 경우, 사용자의 얼굴색과 가깝게 보이게 함으로써, 외관상 이질감을 덜 느끼게 하여 마스크팩 착용 후의 외관이 미려해질 수 있다. In addition, when the wet transparency is improved and is brought into close contact with the user's face, the appearance of the user's face may be made to be close to that of the user's face.
이하, 실시예를 통하여 본 발명을 더욱 상세히 설명하고자 한다. 이들 실시예는 오로지 본 발명을 보다 구체적으로 설명하기 위한 것으로서, 본 발명의 범위가 이들 실시예에 의해 제한되지 않는다는 것은 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자에게 있어 자명할 것이다. Hereinafter, the present invention will be described in more detail with reference to Examples. It is to be understood by those skilled in the art that these embodiments are only for describing the present invention in more detail and that the scope of the present invention is not limited by these embodiments.
실시예 1Example 1
중합도(DPw) 820, 알파 셀룰로오스 함량 93.9%인 셀룰로오스 펄프를 프로필갈레이트 함량 0.01 중량%인 NMMO/H2O 혼합 용제(중량비 90/10)에 혼합하여, 혼합물 총 중량 대비 셀롤로오스 펄프 함량이 10 중량%(방사도프 농도 10%)인 라이오셀 섬유 제조용 방사도포를 제조하였다. A cellulose pulp having a degree of polymerization (DPw) of 820 and an alpha-cellulose content of 93.9% was mixed with an NMMO / H2O mixed solvent (weight ratio 90/10) having a propyl gallate content of 0.01% by weight so that the cellulosic pulp content % (Radiation dope concentration 10%).
먼저, 상기 방사 도프를 방사노즐에서 방사 온도를 110℃로 유지하면서, 필라멘트의 단섬도가 1.25 데니어가 되도록 방사 도프의 토출량과 방사속도를 조절하여 방사하였다. 상기 방사 노즐로부터 토출된 필라멘트 상의 방사 도프는 연속적으로 에어 갭 구간을 거쳐 응고조 내의 응고액에 공급하였다. 이때 상기 에어 갭 구간에서 냉각 공기는 8℃의 온도 및 5m/s 풍속으로 방사 도프를 1차 응고시킨다. First, the spinning dope was spinned while adjusting the discharge amount and spinning speed of the spinning dope so that the filament fineness of the filament was 1.25 denier while maintaining the spinning temperature at 110 캜 in the spinning nozzle. The spinning dope on the filament discharged from the spinneret was continuously supplied to the coagulating solution in the coagulation bath through the air gap section. At this time, the cooling air in the air gap section is subjected to primary solidification of the spinning dope at a temperature of 8 캜 and a wind speed of 5 m / s.
상기 응고액은 온도 25℃, 농도는 물 80 중량% 및 NMMO 20 중량%인 것을 사용하였으며, 상기 응고액 농도는 센서와 굴절계를 사용하여 지속적으로 모니터링 하였다. The coagulating solution used was one with a temperature of 25 ° C and a concentration of 80% by weight of water and 20% by weight of NMMO. The concentration of the coagulating solution was continuously monitored using a sensor and an refractometer.
견인롤러를 통하여 공기층에서 연신이 된 필라멘트는 수세장치에서 스프레이된 수세액에 의해 수세되어 잔존하는 NMMO를 제거하고, 필라멘트에 유제가 균일하게 묻도록 한 뒤, 다시 압착하여 필라멘트에 대한 유제 함량이 0.2%를 유지하도록 하였으며 건조롤러에서 150℃로 건조하였다. The filament drawn in the air layer through the pulling roller was washed with a wash water sprayed in a water washing device to remove the remaining NMMO and the filament was allowed to uniformly adhere to the filament, % And dried at 150 ° C on a drying roller.
마지막으로, 상기 제조된 라이오셀 멀티필라멘트를 스팀박스(압력 조건 0.15kgf/cm2)에 통과 시키면서 토우에 온도를 부여하는 예열 상태를 거쳐 1.5kgf/cm2의 압력으로 스터퍼 박스 압축 룰러를 이용하여 압착함으로써, 스터퍼 박스에서 크림프 토우를 제조하여 이를 Lattice 건조기를 통하여 건조한 다음 최종적으로 커팅을 함으로써 38mm 섬유장을 갖는 라이오셀 스테이플 섬유를 제조하였다. Finally, the prepared lyocell multifilament was passed through a steam box (pressure condition: 0.15 kgf / cm 2 ) and preheated to give a temperature to the tow, and the stuffer box compression ruler was used at a pressure of 1.5 kgf / cm 2 To thereby produce a crimped tow in a stuffer box, dry it through a Lattice drier, and finally cut to produce a lyocell staple fiber having a 38 mm fiber length.
상기 제조된 라이오셀 스테이플 섬유를 부직 섬유 집합체 제조 공정인 카딩 및 스펀레이싱 공정을 통하여 최종적으로 부직 섬유 집합체를 제조하였으며, 원료 투입 및 공정 속도를 조절하여 부직 섬유 집합체 평량을 30gsm으로 맞추었으며, 부직 섬유 집합체 평량 편차는 ±10% 범위가 되도록 하였다.The lyocell staple fiber was manufactured through a carding and spun raising process which is a process of producing a nonwoven fabric aggregate. Finally, the nonwoven fabric aggregate was prepared, the basis weight of the nonwoven fabric aggregate was adjusted to 30 gsm by controlling the feed rate and the process speed, The aggregate weighing deviation was in the range of ± 10%.
실시예 2Example 2
부직 섬유 집합체 평량을 40gsm이 되도록 한 것을 제외하고, 실시예 1과 동일한 방법으로 단섬도 1.25 데니어의 부직 섬유 집합체를 제조하였다. Nonwoven fabric aggregate A nonwoven fabric aggregate having a fineness of 1.25 denier was prepared in the same manner as in Example 1, except that the basis weight was 40 gsm.
실시예 3Example 3
부직 섬유 집합체 평량을 50gsm이 되도록 한 것을 제외하고, 실시예 1과 동일한 방법으로 단섬도 1.25 데니어의 부직 섬유 집합체를 제조하였다. A nonwoven fabric aggregate having a fineness of 1.25 denier was prepared in the same manner as in Example 1, except that the basis weight of the nonwoven fabric aggregate was adjusted to be 50 gsm.
실시예 4Example 4
부직 섬유 집합체 평량을 60gsm이 되도록 한 것을 제외하고, 실시예 1과 동일한 방법으로 단섬도 1.25 데니어의 부직 섬유 집합체를 제조하였다. A nonwoven fabric aggregate having a fineness of 1.25 denier was prepared in the same manner as in Example 1, except that the basis weight of the nonwoven fabric aggregate was adjusted to 60 gsm.
실시예 5Example 5
라이오셀 스테이플 섬유의 단섬도를 1.0 데니어로 만들고 부직 섬유 집합체 평량을 40gsm이 되도록 한 것을 제외하고, 실시예 1과 동일한 방법으로 단섬도 1.0 데니어의 부직 섬유 집합체를 제조하였다.A 1.0% denier nonwoven fabric aggregate was prepared in the same manner as in Example 1, except that the single-fineness of the lyocell staple fiber was made 1.0 denier and the basis weight of the nonwoven fabric aggregate was 40 gsm.
실시예 6Example 6
라이오셀 스테이플 섬유의 단섬도를 1.0 데니어로 만들고 부직 섬유 집합체 평량을 50gsm이 되도록 한 것을 제외하고, 실시예 1과 동일한 방법으로 단섬도 1.0 데니어의 부직 섬유 집합체를 제조하였다.A 1.0% denier monofilament fiber aggregate was prepared in the same manner as in Example 1, except that the fineness of the lyocell staple fiber was made 1.0 denier and the basis weight of the nonwoven fabric aggregate was 50 gsm.
실시예 7Example 7
라이오셀 스테이플 섬유의 단섬도를 1.3 데니어로 만들고 부직 섬유 집합체 평량을 40gsm이 되도록 한 것을 제외하고, 실시예 1과 동일한 방법으로 단섬도 1.3 데니어의 부직 섬유 집합체를 제조하였다.A nonwoven fabric aggregate having a single fineness of 1.3 denier was prepared in the same manner as in Example 1, except that the fineness of the lyocell staple fiber was set to 1.3 denier and the basis weight of the nonwoven fabric aggregate was set to 40 gsm.
실시예 8Example 8
라이오셀 스테이플 섬유의 단섬도를 1.3 데니어로 만들고 부직 섬유 집합체 평량을 50gsm이 되도록 한 것을 제외하고, 실시예 1과 동일한 방법으로 단섬도 1.3 데니어의 부직 섬유 집합체를 제조하였다.A nonwoven fabric aggregate having a single fineness of 1.3 denier was prepared in the same manner as in Example 1, except that the fineness of the lyocell staple fiber was set at 1.3 denier and the basis weight of the nonwoven fabric aggregate was set at 50 gsm.
실시예 9Example 9
라이오셀 스테이플 섬유의 크림프 수를 5cpi가 되도록 스팀박스의 압력 조건 및 스터버 박스 압축 롤러의 압력 조건을 조정한 것을 제외하고, 실시예 1과 동일한 방법으로 크림프 수 5cpi의 부직 섬유 집합체를 제조하였다. A nonwoven fabric aggregate of 5 cpi of crimp number was prepared in the same manner as in Example 1, except that the pressure condition of the steam box and the pressure condition of the Stuber box compression roller were adjusted so that the crimp number of the lyocell staple fiber was 5 cpi.
실시예 10Example 10
라이오셀 스테이플 섬유의 크림프 수를 20cpi가 되도록 스팀박스의 압력 조건 및 스터버 박스 압축 롤러의 압력 조건을 조정한 것을 제외하고, 실시예 1과 동일한 방법으로 크림프 수 20cpi의 부직 섬유 집합체를 제조하였다. A nonwoven fabric aggregate having a crimp number of 20 cpi was prepared in the same manner as in Example 1, except that the pressure condition of the steam box and the pressure condition of the Stuber box compression roller were adjusted so that the crimp number of the lyocell staple fiber was 20 cpi.
비교예 1Comparative Example 1
라이오셀 스테이플 섬유의 단섬도를 1.5 데니어로 만들고 부직 섬유 집합체 평량을 40gsm이 되도록 한 것을 제외하고는, 실시예 1과 동일한 방법으로 단섬도 1.5 데니어의 부직 섬유 집합체를 제조하였다.A nonwoven fabric aggregate having a single fineness of 1.5 denier was prepared in the same manner as in Example 1, except that the fineness of the lyocell staple fiber was set to 1.5 denier and the basis weight of the nonwoven fabric aggregate was set to 40 gsm.
비교예 2Comparative Example 2
라이오셀 스테이플 섬유의 단섬도를 1.5 데니어로 만들고 부직 섬유 집합체 평량을 50gsm이 되도록 한 것을 제외하고는, 실시예 1과 동일한 방법으로 단섬도 1.5 데니어의 부직 섬유 집합체를 제조하였다.A nonwoven fabric aggregate having a single fineness of 1.5 denier was prepared in the same manner as in Example 1, except that the single fineness of the lyocell staple fiber was set to 1.5 denier and the basis weight of the nonwoven fabric aggregate was set to 50 gsm.
비교예 3Comparative Example 3
라이오셀 스테이플 섬유의 단섬도를 2.0 데니어로 만들고 부직 섬유 집합체 평량을 40gsm이 되도록 한 것을 제외하고는, 실시예 1과 동일한 방법으로 단섬도 2.0 데니어의 부직 섬유 집합체를 제조하였다.A 2.0% denier nonwoven fabric aggregate was prepared in the same manner as in Example 1, except that the fineness of the lyocell staple fiber was adjusted to 2.0 denier and the basis weight of the nonwoven fabric aggregate was set to 40 gsm.
상기 실시예 및 비교예에서 제조된 부직 섬유 집합체에 대하여, 상기 라이오셀의 섬도 및 크림프 수, 상기 부직 섬유 집합체의 평량, 두께, 투명성, 흡수성 및 피부 밀착력를 아래와 같은 방법으로 측정 및 산출하여, 그 결과를 하기 표 1에 나타내었다. The fineness, thickness, transparency, absorbency and skin adhesion of the nonwoven fabric aggregate were measured and calculated for the nonwoven fabric assemblies prepared in the Examples and Comparative Examples as follows, Are shown in Table 1 below.
(1) 섬도(1) Fineness
단면 분석을 통하여 얻은 라이오셀 섬유의 모노필라멘트 단면적과 라이오셀 섬유의 밀도(1.49g/cm3)를 이용하여 하기 식 1로 계산하여 라이오셀 섬유의 섬도를 구하였다. The monofilament cross-sectional area of the lyocell fiber obtained from the cross-sectional analysis and the density of the lyocell fiber (1.49 g / cm 3 ) were calculated to calculate the fineness of the lyocell fiber.
<식 1><Formula 1>
섬도(De) = [라이오셀 섬유의 모노필라멘트 단면적(㎛)2 × 라이오셀 섬유의 밀도(g/cm3) × 9000(m)] / 1000000Fineness (De) = [monofilament cross-section of the lyocell fibers (㎛) 2 × Lioness density (g / cm 3) of the fiber cells × 9000 (m)] / 1000000
(2) 크림프 수(2) Crimp Number
KS K 0326 규격으로 측정하였으며, 크림프가 손상되지 않은 20올의 시료를 취한 후, 미리 준비한 광택 지편(공간 거리 25mm)을 셀룰로이드 4~5%의 아세트산아밀 접착제로 단섬유 1올씩 첨부 길이에 대하여 (25±5)% 늘어지도록 첨부한 후 방치하여 접착제를 건조시킨다. 이 시료에 대하여 크림프 시험기를 사용하여 1올씩 1D당 1.96/1000cN(=2mgf)에 상당하는 초하중을 걸어, 25mm 사이의 크림프 개수를 구한 후. 그 평균값을 소수점 이하 한 자리까지만 하기 표 1에 나타내었다.KS K 0326 standard. After taking a 20-sample sample without any damage to the crimp, prepare a shiny piece (25 mm clearance) prepared beforehand with 1 to 4 glass fibers of amyl acetate with 4-5% celluloid 25 ± 5%). After that, leave the adhesive to dry. The sample was subjected to a crimp test machine to obtain a crimp number of 25 mm between 1 and 100 denier per 1D per 1D (= 2 mgf). Table 1 shows the average value up to one decimal place.
(3) 평량 (gsm = g/m2)(3) Basis weight (gsm = g / m 2 )
부직 섬유 집합체를 가로 5cm, 세로 20cm로 샘플링하고 무게를 측정하여 하기 식 2로 계산하여 평량을 구하였다.The nonwoven fibrous aggregate was sampled at a width of 5 cm and a length of 20 cm and weighed, and the basis weight was calculated by the following formula 2.
<식 2><Formula 2>
평량 = 부직 섬유 집합체 샘플 무게 측정치 × 100 Basis weight = non-woven fiber aggregate sample weight measurement × 100
(4) 두께(4) Thickness
Mitutoyo사의 No. 2046F를 사용하여 측정하였다.Mitutoyo no. 2046F. &Lt; / RTI &gt;
(5) 투명성(5) Transparency
시료 전처리 : 부직 섬유 집합체를 물 혹은 에센스에 10분간 침지 시킨다.Sample preparation: Immerse the nonwoven fiber aggregate in water or essence for 10 minutes.
부직 섬유 집합체의 투명성을 측정하기 위해 광투과율 장비인 Haze Meter(Nippon Denshoku Industry, NDH-5000)를 사용하였으며 nm의 파장의 투과율을 측정하였다.To measure the transparency of the nonwoven fiber aggregate, the haze meter (Nippon Denshoku Industry, NDH-5000), a light transmittance equipment, was used and the transmittance at a wavelength of nm was measured.
(6) 흡수성(6) Absorbency
물 혹은 에센스에 부직 섬유 집합체를 간 침지 시킨 후 전/후의 무게를 측정하여 부직 섬유 집합체가 물 혹은 에센스를 흡수하는 능력을 하기 식 3으로 계산하여 측정하였다.After immersing the nonwoven fabric aggregate in water or essence, the weight of the nonwoven fabric aggregate was measured by measuring the before / after weight, and the ability of the nonwoven fabric aggregate to absorb water or essence was calculated by the following formula 3.
<식 3><Formula 3>
흡수성 (%) = {(침지 후 부직 섬유 집합체 무게 - 침지 전 부직 섬유 집합체 무게)/침지 전 부직 섬유 집합체 무게}×100Absorbency (%) = {(Weight of nonwoven fabric aggregate after immersion - Weight of nonwoven fabric aggregate before immersion) / Weight of nonwoven fabric aggregate before immersion} × 100
(7) 피부 밀착력(7) Skin adhesion
부직 섬유 집합체를 25mm×150mm 크기로 자르고 물 혹은 에센스에 10분간 침지 후 사람 팔 부위에 점착 시킨다. 점착 시킨 후 바로 Instron(Instron, 3365)을 사용하여 부직 섬유 집합체를 피부로부터 때어내면서 점착력(단위 gf)을 측정하였다.The nonwoven fiber aggregate is cut into a size of 25 mm x 150 mm, and immersed in water or essence for 10 minutes, and then adhered to the human arm. After adhesion, the adhesive force (unit gf) was measured using an Instron (Instron, 3365), while leaving the nonwoven fibrous assembly out of the skin.
구분division S/F 조건S / F condition 부직 섬유 집합체조건Nonwoven fibrous aggregate conditions 부직 섬유 집합체 물성Properties of nonwoven fiber aggregate
섬도(De)The island (De) 크림프수(cpi)Crimp Number (cpi) 평량(gsm)Basis weight (gsm) 두께(mm)Thickness (mm) 투명성(%)Transparency (%) 흡수성(%)Absorbency (%) 피부 밀착력(gf)Skin adhesion (gf)
실시예1Example 1 1.251.25 1010 3030 0.330.33 물 84에센스 94Water 84 Essence 94 물 1,000에센스 1,300Water 1,000 essence 1,300 물 3.6에센스 4.5Water 3.6 Essence 4.5
실시예2Example 2 1.251.25 1010 4040 0.400.40 물 82에센스 92Water 82 Essence 92 물 1,400에센스 2,000Water 1,400 Essence 2,000 물 4.0에센스 5.0Water 4.0 Essence 5.0
실시예3Example 3 1.251.25 1010 5050 0.470.47 물 81에센스 90Water 81 Essence 90 물 1,500에센스 2,100Water 1,500 Essence 2,100 물 4.1에센스 5.1Water 4.1 Essence 5.1
실시예4Example 4 1.251.25 1010 6060 0.530.53 물 80에센스 88Water 80 Essence 88 물 1,600에센스 2,200Water 1,600 Essence 2,200 물 4.2에센스 5.3Water 4.2 Essence 5.3
실시예5Example 5 1.01.0 1010 4040 0.380.38 물 82에센스 93Water 82 Essence 93 물 1,500에센스 2,200Water 1,500 Essence 2,200 물 4.1에센스 5.2Water 4.1 Essence 5.2
실시예6Example 6 1.01.0 1010 5050 0.460.46 물 80에센스 91Water 80 Essence 91 물 1,700에센스 2,500Water 1,700 Essence 2,500 물 4.2에센스 5.4Water 4.2 Essence 5.4
실시예7Example 7 1.31.3 1010 4040 0.410.41 물 81에센스 91Water 81 Essence 91 물 1,400에센스 2,100Water 1,400 Essence 2,100 물 4.1에센스 5.1Water 4.1 Essence 5.1
실시예8Example 8 1.31.3 1010 5050 0.480.48 물 79에센스 90Water 79 Essence 90 물 1,500에센스 2,100Water 1,500 Essence 2,100 물 4.2에센스 5.2Water 4.2 Essence 5.2
실시예9Example 9 1.251.25 55 3030 0.330.33 물 76에센스 84Water 76 Essence 84 물 700에센스 800Water 700 Essence 800 물 3.0에센스 4.0Water 3.0 Essence 4.0
실시예10Example 10 1.251.25 2020 3030 0.330.33 물 78에센스 86Water 78 Essence 86 물 800에센스 900Water 800 Essence 900 물 3.1에센스 4.1Water 3.1 Essence 4.1
비교예1Comparative Example 1 1.51.5 1010 4040 0.420.42 물 78에센스 86Water 78 Essence 86 물 980에센스 1,200Water 980 Essence 1,200 물 3.4에센스 4.4Water 3.4 Essence 4.4
비교예2Comparative Example 2 1.51.5 1010 5050 0.500.50 물 77에센스 85Water 77 Essence 85 물 1,000에센스 1,300Water 1,000 essence 1,300 물 3.5에센스 4.5Water 3.5 Essence 4.5
비교예3Comparative Example 3 2.02.0 1010 4040 0.450.45 물 77에센스 86Water 77 Essence 86 물 950에센스 1,000Water 950 Essence 1,000 물 3.3에센스 4.3Water 3.3 Essence 4.3
표 1에 나타난 바와 같이, 본 발명에 따른 실시예 1 내지 실시예8를 통해 라이오셀 섬유의 섬도 및 크림프 수를 최적의 범위로 포함하는 라이오셀 섬유와, 상기 라이오셀을 포함하는 부직 섬유 집합체의 평량 및 두께를 각각 최적의 범위로 포함함으로써, 우수한 밀착력, 투명성, 흡수력을 확보할 수 있다. As shown in Table 1, through the Examples 1 to 8 according to the present invention, the lyocell fibers comprising the optimal range of the fineness and the crimp number of the lyocell fiber, and the nonwoven fabric aggregate containing the lyocell By including the basis weight and the thickness in the respective optimum ranges, excellent adhesion, transparency, and absorption power can be ensured.
반면에, 비교예 1 내지 비교예3에서 확인 가능하듯이 라이오셀 섬유의 섬도가 최적 범위를 벗어나는 경우에는 투명성, 흡수성 및 피부 밀착력이 모두 향상되지 못하고, 일부만 향상됨을 확인 할 수 있다. On the other hand, as can be seen from Comparative Examples 1 to 3, when the fineness of the lyocell fiber is outside the optimum range, the transparency, the absorbency and the skin adhesion are not improved, and only a part of the lyocell fiber is improved.
전술한 본 발명의 설명은 예시를 위한 것이며, 본 발명이 속하는 기술 분야의 통상의 지식을 가진 자는 본 발명의 기술적 사상이나 필수적인 특징을 변경하지 않고서 다른 구체적인 형태로 쉽게 변형이 가능하다는 것을 이해할 수 있을 것이다. 그러므로 이상에서 기술한 실시 예들은 모든 면에서 예시적인 것이며 한정적이 아닌 것으로 이해해야 한다.It will be understood by those skilled in the art that the foregoing description of the present invention is for illustrative purposes only and that those of ordinary skill in the art can readily understand that various changes and modifications may be made without departing from the spirit or essential characteristics of the present invention. will be. It is therefore to be understood that the embodiments described above are in all respects illustrative and not restrictive.
본 발명은 마스크팩 시트를 이용한 화장품용 마스크팩에 적용가능하다. The present invention is applicable to a mask pack for cosmetics using a mask pack sheet.

Claims (13)

  1. 라이오셀 섬유를 포함하는 부직 섬유 집합체로 형성되는 마스크팩 시트에 관한 것으로, The present invention relates to a mask pack sheet formed from a nonwoven fibrous assembly comprising lyocell fibers,
    상기 라이오셀 섬유의 섬도는 1.0 내지 1.4 데니어인 것을 특징으로 하는 마스크팩 시트.Wherein the fineness of the lyocell fiber is 1.0 to 1.4 denier.
  2. 제1항에 있어서,The method according to claim 1,
    상기 라이오셀 섬유의 섬유장은 36 내지 40mm 인 것을 특징으로 하는 마스크팩 시트.Wherein the fiber length of the lyocell fiber is 36 to 40 mm.
  3. 제1항에 있어서,The method according to claim 1,
    상기 라이오셀 섬유의 크림프 수는 5 내지 20cpi인 것을 특징으로 하는 마스크팩 시트.Wherein the number of crimps of the lyocell fiber is 5 to 20 cpi.
  4. 제1항에 있어서,The method according to claim 1,
    상기 라이오셀 섬유는 유제 함유량이 0.1 내지 0.4 중량% 인 것을 특징으로 하는 마스크팩 시트.Wherein the lyocell fiber has an emulsion content of 0.1 to 0.4% by weight.
  5. 제1항에 있어서,The method according to claim 1,
    상기 부직 섬유 집합체의 평량은 30 내지 60g/m2 인 것을 특징으로 하는 마스크팩 시트.Wherein the basis weight of the nonwoven fabric aggregate is 30 to 60 g / m 2 .
  6. 제1항에 있어서,The method according to claim 1,
    상기 부직 섬유 집합체의 두께는 0.3 내지 0.5mm 인 것을 특징으로 하는 마스크팩 시트.Wherein the thickness of the nonwoven fabric aggregate is 0.3 to 0.5 mm.
  7. 제1항에 있어서, The method according to claim 1,
    상기 부직 섬유 집합체는 수분 흡수율이 1000 내지 1700% 인 것을 특징으로 하는 마스크팩 시트.Wherein the nonwoven fibrous aggregate has a water absorption rate of 1000 to 1700%.
  8. 제1항에 있어서, The method according to claim 1,
    상기 부직 섬유 집합체는 수분 처리 후의 투명도가 80 내지 84% 인 것을 특징으로 하는 마스크팩 시트.Wherein the nonwoven fabric aggregate has a transparency of 80 to 84% after the moisture treatment.
  9. 제1항에 있어서, The method according to claim 1,
    상기 부직 섬유 집합체는 에센스 처리 후의 투명도가 88 내지 94% 인 것을 특징으로 하는 마스크팩 시트.Wherein the nonwoven fabric aggregate has a transparency of 88 to 94% after the essence treatment.
  10. 제1항에 있어서, The method according to claim 1,
    상기 부직 섬유 집합체는 수분 처리 후의 피부 밀착력이 3.6 내지 4.2 gf 인 것을 특징으로 하는 마스크팩 시트.Wherein the nonwoven fibrous aggregate has a skin adhesion force of 3.6 to 4.2 gf after moisture treatment.
  11. 제1항에 있어서, The method according to claim 1,
    상기 부직 섬유 집합체는 에센스 처리 후의 피부 밀착력이 4.5 내지 5.4 gf 인 것을 특징으로 하는 마스크팩 시트.Wherein the nonwoven fibrous aggregate has a skin adhesion force after the essence treatment of 4.5 to 5.4 gf.
  12. 제1항에 있어서,The method according to claim 1,
    상기 부직 섬유 집합체는 유제 함유량이 0.001 중량% 이하 인 것을 특징으로 하는 마스크팩 시트.Wherein the nonwoven fabric aggregate has an emulsion content of 0.001 wt% or less.
  13. 제1항 내지 제12항 중 어느 한 항에 의한 마스크팩 시트를 이용한 화장품용 마스크팩.A mask pack for cosmetics using the mask pack sheet according to any one of claims 1 to 12.
PCT/KR2018/011232 2017-09-21 2018-09-21 Mask pack sheet WO2019059706A1 (en)

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Publication number Priority date Publication date Assignee Title
KR20140080655A (en) * 2012-12-13 2014-07-01 한국생산기술연구원 Manufacturing method of carboxymethyl cellulose nonwoven composite and use of using the same
EP2783594A1 (en) * 2011-11-25 2014-10-01 JNC Corporation Cosmetic mask
KR20150030699A (en) * 2012-06-12 2015-03-20 구라레 구라후렛쿠스 가부시키가이샤 Liquid-retaining sheet and face mask
KR101690569B1 (en) * 2016-06-02 2016-12-29 (주)웰크론 Manufacturing method of sheet for cosmetic mask
KR20170079531A (en) * 2015-12-30 2017-07-10 코오롱인더스트리 주식회사 Lyocell Fiber and the method for making it

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Publication number Priority date Publication date Assignee Title
EP2783594A1 (en) * 2011-11-25 2014-10-01 JNC Corporation Cosmetic mask
KR20150030699A (en) * 2012-06-12 2015-03-20 구라레 구라후렛쿠스 가부시키가이샤 Liquid-retaining sheet and face mask
KR20140080655A (en) * 2012-12-13 2014-07-01 한국생산기술연구원 Manufacturing method of carboxymethyl cellulose nonwoven composite and use of using the same
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