WO2019031688A1 - Matériau de gainage pour batterie secondaire et batterie secondaire le comprenant - Google Patents
Matériau de gainage pour batterie secondaire et batterie secondaire le comprenant Download PDFInfo
- Publication number
- WO2019031688A1 WO2019031688A1 PCT/KR2018/005201 KR2018005201W WO2019031688A1 WO 2019031688 A1 WO2019031688 A1 WO 2019031688A1 KR 2018005201 W KR2018005201 W KR 2018005201W WO 2019031688 A1 WO2019031688 A1 WO 2019031688A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- layer
- thin film
- film layer
- secondary battery
- thickness
- Prior art date
Links
- 239000000463 material Substances 0.000 title claims abstract description 30
- 239000010410 layer Substances 0.000 claims abstract description 184
- 239000010409 thin film Substances 0.000 claims abstract description 90
- 229910052751 metal Inorganic materials 0.000 claims abstract description 48
- 239000002184 metal Substances 0.000 claims abstract description 48
- 239000012790 adhesive layer Substances 0.000 claims abstract description 39
- 229920005989 resin Polymers 0.000 claims abstract description 28
- 239000011347 resin Substances 0.000 claims abstract description 28
- 229920000307 polymer substrate Polymers 0.000 claims abstract description 25
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 16
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims description 18
- 229920000642 polymer Polymers 0.000 claims description 14
- 239000011241 protective layer Substances 0.000 claims description 13
- 229910052782 aluminium Inorganic materials 0.000 claims description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 10
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 5
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 3
- 229910001220 stainless steel Inorganic materials 0.000 claims description 2
- 239000010935 stainless steel Substances 0.000 claims description 2
- -1 polyethylene terephthalate Polymers 0.000 description 10
- 230000035699 permeability Effects 0.000 description 9
- 239000003792 electrolyte Substances 0.000 description 6
- 229920000139 polyethylene terephthalate Polymers 0.000 description 6
- 239000005020 polyethylene terephthalate Substances 0.000 description 6
- 230000004888 barrier function Effects 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 4
- 238000000231 atomic layer deposition Methods 0.000 description 4
- 238000005229 chemical vapour deposition Methods 0.000 description 4
- 239000011651 chromium Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 238000004544 sputter deposition Methods 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000008151 electrolyte solution Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000006183 anode active material Substances 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000002346 layers by function Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 229920006284 nylon film Polymers 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920006289 polycarbonate film Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000007774 positive electrode material Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/102—Primary casings; Jackets or wrappings characterised by their shape or physical structure
- H01M50/105—Pouches or flexible bags
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
- H01M50/124—Primary casings; Jackets or wrappings characterised by the material having a layered structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/18—Layered products comprising a layer of metal comprising iron or steel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
- H01M50/117—Inorganic material
- H01M50/119—Metals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
- H01M50/121—Organic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
- H01M50/124—Primary casings; Jackets or wrappings characterised by the material having a layered structure
- H01M50/126—Primary casings; Jackets or wrappings characterised by the material having a layered structure comprising three or more layers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/131—Primary casings; Jackets or wrappings characterised by physical properties, e.g. gas permeability, size or heat resistance
- H01M50/133—Thickness
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/14—Primary casings; Jackets or wrappings for protecting against damage caused by external factors
- H01M50/141—Primary casings; Jackets or wrappings for protecting against damage caused by external factors for protecting against humidity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2457/00—Electrical equipment
- B32B2457/10—Batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Definitions
- the conventional pouch-type case includes a moisture barrier metal layer having a certain thickness or more, And the flexibility of the secondary battery is deteriorated.
- the thickness ratio (metal layer: metal oxide layer) of the metal layer and the metal oxide layer may be in the range of 1: 1 to 5: 1.
- the ratio of the thicknesses of the metal layer and the metal oxide layer satisfies the above-described numerical range, it is very advantageous in securing excellent moisture permeability and securing the flexibility of the outer shell for the secondary battery.
- the ratio of the thickness of the first polymer substrate 31 and the thickness of the first thin film layer 41 is 10: 1 to 500: 1, more specifically, 10: 1 To 50: 1.
- the thickness of the first polymer base material 31 and the thickness of the first thin film layer 41 satisfy the above range, the forming characteristics are excellent.
- the outer casing 131 may further include a functional protective layer 60 disposed between the first thin film layer 41 and the first adhesive layer 51. Referring to FIG.
- the outer sheath 132 may further include an inner metal layer 80 disposed between the first thin film layer 41 and the first adhesive layer 51.
- FIG 5 and 6 are cross-sectional views of a casing for a secondary battery according to an embodiment of the present disclosure.
- the outer casing 135 for a secondary battery includes a second polymer substrate 32, a second thin film layer 42, a third adhesive layer 53, a first polymer substrate 31, a first thin film layer 41,
- the second adhesive layer 52, the inner metal layer 80, the functional protective layer 60, the first adhesive layer 51, and the inner resin layer 70 may be sequentially stacked.
- the energy density of the lithium secondary battery is approximately 1.6% to 3.2% .
- the thin film layer includes a thin film layer having a thickness in the range of 0.01% to 0.001% based on the total thickness of the facing material as in the embodiment of the present invention, wherein the thin film layer is composed of a metal layer and a metal oxide layer 1 to 4, it can be confirmed that the laminate according to Comparative Example 1, which includes the thin film layer made of only the metal layer, is very excellent in the moisture permeability. While the present invention has been described in connection with what is presently considered to be practical exemplary embodiments, it is to be understood that the invention is not limited to the disclosed embodiments, but, on the contrary, And all changes to the scope that are deemed to be valid.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Sealing Battery Cases Or Jackets (AREA)
Abstract
La présente invention concerne un matériau de gainage pour une batterie secondaire et une batterie secondaire le comprenant, le matériau de gainage comprenant : une première couche de film mince ; un premier substrat polymère placé sur une première surface de la première couche de film mince ; une couche de résine interne placée sur une seconde surface de la première couche de film mince ; et une première couche adhésive disposée entre la première couche de film mince et la couche de résine interne de manière à faire adhérer la première couche de film mince à la couche de résine interne, la première couche de film mince ayant une épaisseur allant de 0,001 % à 0,5 % de l'épaisseur totale du matériau de gainage pour une batterie secondaire, et comprenant une couche métallique et une couche d'oxyde métallique.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR10-2017-0101223 | 2017-08-09 | ||
KR1020170101223A KR102504794B1 (ko) | 2017-08-09 | 2017-08-09 | 이차 전지용 외장재 및 이를 포함하는 이차 전지 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2019031688A1 true WO2019031688A1 (fr) | 2019-02-14 |
Family
ID=65271116
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/KR2018/005201 WO2019031688A1 (fr) | 2017-08-09 | 2018-05-04 | Matériau de gainage pour batterie secondaire et batterie secondaire le comprenant |
Country Status (2)
Country | Link |
---|---|
KR (1) | KR102504794B1 (fr) |
WO (1) | WO2019031688A1 (fr) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102382567B1 (ko) * | 2020-04-29 | 2022-04-04 | 충북대학교 산학협력단 | 산소차단성이 증대된 이차전지용 포장재, 이의 표면처리방법, 및 이를 포함하는 파우치형 이차전지 |
KR102608341B1 (ko) * | 2020-12-28 | 2023-12-01 | 주식회사 리베스트 | 외장재 및 외장재를 이용한 배터리 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050112461A1 (en) * | 2001-03-01 | 2005-05-26 | The University Of Chicago | Packaging for primary and secondary batteries |
KR20090056211A (ko) * | 2007-11-30 | 2009-06-03 | 주식회사 엘지화학 | 이차전지용 파우치 외장재 및 파우치형 이차전지 |
KR20090076279A (ko) * | 2008-01-08 | 2009-07-13 | 주식회사 엘지화학 | 이차전지용 파우치 포장재 및 파우치형 이차전지 |
KR20130005886A (ko) * | 2011-07-07 | 2013-01-16 | 주식회사 엘지화학 | 우수한 내구성의 전지케이스 및 이를 포함하는 이차전지 |
KR20130118867A (ko) * | 2010-10-14 | 2013-10-30 | 도판 인사츠 가부시키가이샤 | 리튬 이온 전지용 외장재 |
-
2017
- 2017-08-09 KR KR1020170101223A patent/KR102504794B1/ko active IP Right Grant
-
2018
- 2018-05-04 WO PCT/KR2018/005201 patent/WO2019031688A1/fr active Application Filing
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050112461A1 (en) * | 2001-03-01 | 2005-05-26 | The University Of Chicago | Packaging for primary and secondary batteries |
KR20090056211A (ko) * | 2007-11-30 | 2009-06-03 | 주식회사 엘지화학 | 이차전지용 파우치 외장재 및 파우치형 이차전지 |
KR20090076279A (ko) * | 2008-01-08 | 2009-07-13 | 주식회사 엘지화학 | 이차전지용 파우치 포장재 및 파우치형 이차전지 |
KR20130118867A (ko) * | 2010-10-14 | 2013-10-30 | 도판 인사츠 가부시키가이샤 | 리튬 이온 전지용 외장재 |
KR20130005886A (ko) * | 2011-07-07 | 2013-01-16 | 주식회사 엘지화학 | 우수한 내구성의 전지케이스 및 이를 포함하는 이차전지 |
Also Published As
Publication number | Publication date |
---|---|
KR102504794B1 (ko) | 2023-02-27 |
KR20190016808A (ko) | 2019-02-19 |
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