WO2019026536A1 - Beverage and method for suppressing occurrence of floccing in beverage - Google Patents

Beverage and method for suppressing occurrence of floccing in beverage Download PDF

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Publication number
WO2019026536A1
WO2019026536A1 PCT/JP2018/025588 JP2018025588W WO2019026536A1 WO 2019026536 A1 WO2019026536 A1 WO 2019026536A1 JP 2018025588 W JP2018025588 W JP 2018025588W WO 2019026536 A1 WO2019026536 A1 WO 2019026536A1
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beverage
content
ppm
barley
occurrence
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PCT/JP2018/025588
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French (fr)
Japanese (ja)
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有希子 池上
遼 伊藤
徳子 鈴木
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アサヒグループホールディングス株式会社
アサヒ飲料株式会社
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Publication of WO2019026536A1 publication Critical patent/WO2019026536A1/en

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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/38Other non-alcoholic beverages
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/70Clarifying or fining of non-alcoholic beverages; Removing unwanted matter

Definitions

  • the present invention relates to a packaged cereal tea beverage containing an extract of cereals including roasted and germinated barley, and a method of suppressing the occurrence of flocking in beverages.
  • cereal tea beverages such as barley tea have been widely consumed due to the sweetness and aroma characteristic of barley, and their palatability is enhanced by combining and combining two or more types of grains and tea leaves ( See, for example, Patent Documents 1 to 3).
  • floc which is a suspension or precipitate in the form of a float or turbid, during long-term storage and warming There was a case that occurred.
  • the present inventors set the EBC and turbidity (A720) as an index of the content and color of raffinose, which is one of saccharides, even in a beverage containing an extract of roasted and germinated barley within a predetermined range. By adjusting to, it has been found that the occurrence of floc can be suppressed, and the present invention has been completed. Specifically, the present invention provides the following.
  • the present invention is a container-packed grain tea beverage containing an extract of cereal grains including roasted and germinated barley, wherein the content of raffinose is 1.5 to 9.5 ppm, EBC is 10 or more, and turbid. It is a drink whose degree (A720) is 0.04 or less.
  • the present invention is the beverage according to (1), wherein the turbidity (A720) is 0.035 or less.
  • the present invention is the beverage according to (1) or (2), wherein the content is 2 to 15 ppm fructose, 4 to 30 ppm glucose, 3 to 17 ppm sucrose, or 5 to 40 ppm maltose.
  • the present invention is the beverage according to any one of (1) to (3), wherein the total content of six saccharides of fructose, glucose, sucrose, maltose, raffinose and stachyose is 20 to 110 ppm.
  • the present invention is the beverage according to any one of (1) to (4), wherein starch is contained in an amount of 100 mg / 100 mL or more.
  • the present invention is the beverage according to any one of (1) to (5), wherein the cereals further comprise barley barley or barley.
  • the present invention is a method for suppressing the occurrence of floc in the beverage by adjusting the content of raffinose and the turbidity (A720) in a beverage containing the extract of roasted roasted grain.
  • a beverage which contains an extract of roasted and germinated barley and is capable of suppressing the occurrence of floc. Further, according to the present invention, it is possible to provide a method for suppressing the occurrence of flocking of a beverage.
  • the beverage according to the present embodiment is a containerized cereal tea beverage containing an extract of cereal grains including roasted and germinated barley, and the content of raffinose is 1.5 to 9.5 ppm, and the EBC is 10 or more.
  • the turbidity (A720) is 0.04 or less.
  • the content of raffinose, EBC, and turbidity (A720) are adjusted within a predetermined range while the sweetness and aroma unique to roasted and germinated barley are imparted to improve the palatability. By doing so, the occurrence of floc is suppressed.
  • EBC is called boiling color, and the higher the value, the darker the color.
  • the EBC is measured by the Analytica-EBC standard method of EBC (European Brewery Convention) or a method according thereto.
  • EBC is a value measured under the condition of wavelength 430 nm. Specifically, a sample is placed in a cell of 10 mm (optical path length), absorbance is measured with monochromatic light of 430 nm, and calculation is made according to the formula shown in the following formula (1). When the absorbance at a wavelength of 430 nm is 0.8 or more, the sample is diluted with distilled water and then measured.
  • EBC 25 ⁇ f ⁇ A 430 (1) (In the formula (1), “25” is a factor for converting EBC, “f” is a dilution ratio, and “A430” is absorbance at a wavelength of 430 nm.)
  • the EBC of the beverage according to the present embodiment is 10 or more, preferably 12 or more, from the viewpoint of excellent palatability. If the EBC is too small, the taste such as the concentration of taste tends to decrease.
  • the upper limit of EBC is not particularly limited, but is preferably 28 or less, more preferably 25 or less, and particularly preferably 20 or less. If the EBC is too large, the taste may be too strong or the white flock may be noticeable.
  • the turbidity (A720) is the absorbance at a wavelength of 720 nm in a cell of 10 mm (optical path length), and the smaller the value, the higher the transparency.
  • the turbidity A720 is, for example, a value measured at a wavelength of 720 nm using a spectrophotometer U-5100 (manufactured by Hitachi High-Technologies Corporation).
  • the turbidity (A 720) of the beverage according to the present embodiment is 0.04 or less, preferably 0.035 or less, more preferably 0.030 or less, from the viewpoint of suppressing the occurrence of floc. If the turbidity A720 is too large, floc is likely to occur.
  • the lower limit value of the turbidity (A720) is not particularly limited, but may be 0.
  • turbidity A720 becomes an important index in controlling the occurrence of floc. It has been conventionally thought that there is a correlation between haze and flock occurrence, but it is difficult to accurately predict flock occurrence probability from haze, as is apparent from the examples described later. There is. By using turbidity A720 as an index, it is possible to predict the likelihood of occurrence of floc, and it has become clear that the occurrence of floc can be suppressed by adjusting the turbidity A720 within a predetermined range.
  • the drink which concerns on this embodiment contains raffinose which is 1 type of saccharides within the predetermined
  • the content of raffinose correlates with the palatability of the beverage such as the intensity of the taste, the intensity of the scent, the intensity of sweetness, the fragrantness, etc. Differently, it became clear that there was a strong correlation with the occurrence of floc.
  • the content of raffinose is 1.5 to 9.5 ppm, preferably 2.0 to 8.0 ppm, more preferably 2.5 from the viewpoint of suppressing floc generation and / or excellent palatability. It is ⁇ 7.5 ppm. If the content of raffinose is too low, the taste tends to be reduced. When the content of raffinose is too large, flocking tends to occur and the taste tends to decrease.
  • the content of fructose is preferably 1 to 25 ppm, more preferably 2 to 20 ppm, and particularly preferably 4 to 15 ppm, from the viewpoint of suppressing flocculation and / or excellent palatability. If the content of fructose is too low, the taste tends to decrease. When the content of fructose is excessive, flocking tends to occur and the taste tends to decrease.
  • the content of glucose is preferably 2 to 40 ppm, more preferably 4 to 35 ppm, and particularly preferably 6 to 30 ppm, from the viewpoint of suppressing flocculation and / or excellent palatability. If the content of glucose is too low, the taste tends to decrease. When the content of glucose is too high, flocking tends to occur and the taste tends to decrease.
  • sucrose The content of sucrose is preferably 2 to 25 ppm, more preferably 3 to 20 ppm, particularly preferably 4 to 17 ppm, from the viewpoint of suppressing the occurrence of floc and / or excellent palatability. If the content of sucrose is too low, the preference tends to be reduced. When the content of glucose is too high, flocking tends to occur and the taste tends to decrease.
  • the maltose content is preferably 2 to 60 ppm, more preferably 5 to 50 ppm, and particularly preferably 10 to 40 ppm, from the viewpoint of suppressing the occurrence of floc and / or excellent palatability. If the maltose content is too low, the taste tends to be reduced. When the content of maltose is too large, flocking tends to occur and the taste tends to decrease.
  • the content of stachyose is preferably 0.8 to 10 ppm, more preferably 1 to 5 ppm, and particularly preferably 1.5 to 4 ppm, from the viewpoint of suppressing flocculation and / or excellent palatability. If the content of stachyose is too low, the preference tends to be reduced. When the content of stachyose is too large, flocking tends to occur and the taste tends to decrease.
  • the total content of these six saccharides of raffinose, fructose, glucose, sucrose, maltose and stachyose is preferably 10 to 180 ppm, more preferably 15 to 140 ppm, and particularly preferably 20 to 110 ppm.
  • the concentration of taste, the intensity of aroma, the intensity of sweetness, the fragrantness, etc. are imparted while suppressing the floc to give palatability It can be an excellent beverage.
  • starch means, in addition to the above-described six types of sugars, oligosaccharides other than these sugars, starch which is a mixture of amylose and amylopectin, and dextrin which is a hydrolyzate of starch. And other sugars.
  • the content of starch is measured by an enzymatic method quantification using an F-kit starch (product number: 207748; manufactured by Roche Diagnostics) by a method described later.
  • the content of starch is not particularly limited, but the lower limit thereof is preferably 90 mg / 100 ml or more, more preferably 100 mg / 100 ml or more, from the viewpoint of imparting sweetness and body feeling (drinkiness).
  • the upper limit of the content of starch is not particularly limited, and is, for example, 180 mg / 100 ml or less and 160 mg / 100 ml or less. Conventionally, it has been considered to reduce the starch content to suppress the occurrence of floc, but in the present embodiment, the content of raffinose, EBC, and turbidity (A720) are adjusted within a predetermined range. Because of this, relatively large amounts of starch can be imparted to the beverage to impart sweetness and body feeling, and the advantage is great in terms of palatability.
  • the six types of saccharides and starch which were mentioned above may be produced
  • at least 1 or more types may be selected and used from several types of grains so that adjustment of content of six types of saccharides and starch which were mentioned above may satisfy the said content, those The mixing ratio of the extract may be changed appropriately.
  • the use amount of roasted and germinated barley may be increased, the use amount of grains having a high content of raffinose may be increased, or the roasting conditions of the grain may have a high L value. It may be prepared to be When it is desired to reduce the content of raffinose, it is necessary to reduce the use of roasted and germinated barley, to reduce the use of grains having a low content of raffinose, or to treat with an adsorbent having an ability to adsorb saccharides. do it.
  • the use amount of grains having a high starch content may be increased, the roasting conditions of the grains may be adjusted to increase the L value, or the roasted barley extraction may be performed. It may be sufficient to lengthen the time.
  • the soluble solid content is a value obtained by measuring the concentration of the total soluble solid content in the beverage with a sugar refractometer, and refers to "Brix".
  • the soluble solid content is a value measured at 30 ° C. using, for example, a digital differential densitometer DD-7 (manufactured by Atago Co., Ltd.).
  • the soluble solid content of the beverage according to the present embodiment is not particularly limited, but the lower limit of the soluble solid content is preferably 0.30 mass% or more, and more preferably, from the viewpoint of imparting sweetness and body feeling (drinkiness). It is 0.30 mass% or more.
  • the upper limit of the soluble solid content is preferably 0.45% by mass or less from the viewpoint of suppressing the occurrence of floc.
  • the soluble solid content may be adjusted as appropriate by changing the roasting conditions of grains and the extraction conditions of grains, and may be adjusted by adding soluble solids. For example, when it is desired to increase the soluble solid content, extraction time of roasted barley may be extended, or an appropriate amount of carbonate (sodium hydrogen carbonate etc.) may be added at the time of extraction. For example, in the case of adding sodium hydrogen carbonate, an appropriate amount such that the soluble solid content becomes a desired value may be selected from the range of 0.25 g to 6 g per 1 L of the extraction solvent. By adjusting the pH of the extraction solvent by the addition of a carbonate (such as sodium hydrogen carbonate), it becomes easy to obtain a large amount of soluble solids.
  • a carbonate such as sodium hydrogen carbonate
  • the method for producing a beverage according to the present embodiment can adopt a general method, and if necessary, a roasting step of roasting grains, an extraction step of extracting roasted grains to obtain an extract, extraction It includes a blending step of blending water and various additives into a liquid, a heating and sterilization step of heating and sterilizing the blended beverage, and a container filling step of filling the blended beverage into a container.
  • roasting process A common roasting method can be adopted, and a suitable roasting method (roasting time, roasting temperature, etc.) is selected to obtain the desired content of sugars and starch, EBC, turbidity (A 720), etc. It should be done.
  • a suitable roasting method for example, hot air roasting, direct fire roasting, sand roasting, far infrared roasting and the like can be mentioned.
  • the roasted grain may be transferred to the extraction step as it is in the hole or may be crushed and transferred to the extraction step.
  • the L value of roasted and germinated barley is preferably 20 to 40, more preferably 24 to 34, and still more preferably 27 to 31.
  • the L value is measured using a color difference meter ZE-2000 (manufactured by Nippon Denshoku Kogyo Co., Ltd.).
  • grains other than roasted and germinated barley may be used, and as grains other than germinated barley, for example, barley such as barley, barley, wheat, etc.
  • Brown rice, rice such as sprouted brown rice, beans such as black beans, bubbles, millet and the like can be used. These may be used alone or in combination of two or more.
  • wheat and barley are preferable from the viewpoint of obtaining a beverage with high palatability, and barley and barley are particularly preferably used from the viewpoint of palatability.
  • barley and barley have high nutritional value of carbohydrate and contain more protein than rice and other barley, they are known to activate metabolism in the body and are preferably used.
  • the stalk-worm contains a koikusenolide as an anti-ulcer component and a coixol as a component which suppresses attraction.
  • Antioxidant action, skin-refining action, wart action, and the like are known as the effects of moth barley, and it is preferably used.
  • Cereals are harvested at desired times and subjected to appropriate treatments such as drying, threshing, roasting, grinding and the like. By roasting, the Maillard reaction between sugar contained in cereals and proteins is likely to occur, and aroma and brown color are enhanced.
  • Camellia sinensis species are fermented tea (black tea), semi-fermented tea (such as oolong tea), non-fermented tea (such as green tea), post-fermented tea (such as puar tea), and tea leaves with different flavor qualities depending on the fermentation conditions. It is known to be.
  • plants other than Camellia sinensis species include, for example, tomorrow leaves, guava, persimmons, persimmons, wolfberry, wormwood, amachan, persimmon, persimmon leaf, persimmon, persimmon, young barley, senso, dokudami, plantain, honeysuckle, persimmon, There may be mentioned oyster oysters, kawara-ketsumei, gymnema sylvesta, yellow tea (walnut family), green tea (rose family), gymnema, rooibos, ruffuma, dandelion, peppermint, moth earth, ginkgo, pine needles, lotus, olive and the like. These may be used alone or in combination of two or more.
  • the raw material of the extract it is preferable to select and use at least one or more kinds from a plurality of kinds of grains in addition to the germinated barley so that the content of the six kinds of sugars and starch satisfies the above mentioned range.
  • the amount of roasted and germinated barley used is preferably 0.5 to 5.5, and more preferably 1 per liter of beverage, in order to suppress the occurrence of floc while improving the preference such as sweetness and aroma.
  • the content is from 0 to 4.5 g, more preferably from 1.5 to 3.5 g.
  • a general extraction method can be adopted, and if an appropriate extraction method (extraction magnification, extraction temperature, extraction time, etc.) is selected in order to obtain desired sugar content, EBC, and turbidity (A 720) Good.
  • an appropriate extraction method extraction magnification, extraction temperature, extraction time, etc.
  • conventionally known extraction methods such as steam distillation, liquefied carbon dioxide gas extraction, alcohol extraction, hot water extraction and the like can be used.
  • the type of extraction solvent used for the extraction is not particularly limited, but it is preferable to use one which has been purified by deionized exchange treatment or distilled water. These are inexpensive, easy and safe to prepare and provide for extraction equipment.
  • ethanol and other hydrophilic organic solvents are mentioned as extraction solvents other than water.
  • the extraction ratio (the ratio of the extraction solvent to the raw material) is not particularly limited. The less the amount of raw material (grain) used with respect to the water used for extraction, the smaller the intensity of taste, the intensity of aroma and the intensity of sweetness of the resulting extract. As the amount of the raw material (grain) used increases, the resulting extract has a greater flavor, flavor and sweetness. For this reason, the extraction ratio is generally adjusted to an optimal amount in order to extract it from the roasted raw material (cereal).
  • the extraction temperature is not particularly limited, but is preferably, for example, 80 ° C. or more and 100 ° C. or less. If extraction is performed in the above temperature range, the extraction efficiency is high.
  • the extraction time is also not particularly limited, but is preferably in the range of 5 minutes to 1 hour. If an extract is obtained at the above-mentioned extraction time, it tends to be easy to extract each ingredient of sweetness and fragrantness, suppressing the flavor change and dissipation of an aroma component by heat. This makes it easy to obtain a tea beverage excellent in palatability.
  • the obtained extract can be provided as it is as the beverage of the present invention, but adjustment and / or dilution or the like of pH and soluble solid may be appropriately performed on the obtained extract.
  • antioxidants, perfumes, various esters, organic acids, organic acid salts, inorganic acids, inorganic acid salts, inorganic salts, inorganic salts, dyes, emulsifiers, preservatives, seasonings, quality stabilizers And the like may be included.
  • the obtained extract may be appropriately heat-sterilized, etc., and filled in a container for storage.
  • the container include a molded container mainly made of polyethylene terephthalate (so-called plastic bottle), a paper container combined with a metal foil or a plastic film, a metal can, a bottle and the like.
  • the method for suppressing flock generation of a beverage suppresses flock generation of a beverage by adjusting the content of raffinose and the turbidity (A720) in a beverage containing the extract of roasted grain which has been germinated. It is a method.
  • the grain as described above, barley such as barley, buckwheat, wheat etc., rice such as brown rice, sprouted brown rice etc., beans such as black beans, rubble, millet etc. are preferably mentioned.
  • the occurrence of flocs can be suppressed by adjusting the content and the turbidity of raffinose, and visual superiority can be secured. .
  • Extracts 1 to 8 Using a column-type extractor, add crude water to the roasted grains and roasted germinated barley (L value: 29.74) in the amounts shown in Table 1 to obtain a crude solution, Sodium ascorbate and sodium hydrogen carbonate (sodium bicarbonate) were added to obtain extracts 1 to 8. The unit of the numbers in Table 1 is [g / L]. Extracts 1 and 8 do not contain the extract of roasted and germinated barley.
  • Comparative Example 1 and Reference Example Extract 1 shown in Table 1 was used as the beverage of Comparative Example 1, and Extract 8 was used as the beverage of the reference example.
  • the contents of each saccharide and starch in the beverages of Comparative Example 1 and Reference Example, Brix, turbidity (A 720), EBC, and haze are as shown in Table 2.
  • Extracts 2 to 7 shown in Table 1 were appropriately formulated to obtain the beverages of Examples 1 to 5 and Comparative Example 2.
  • the contents of each saccharide and starch, Brix, turbidity (A 720), EBC and haze in the beverages of Examples 1 to 5 and Comparative Example 2 are as shown in Table 2.
  • content of a starch was measured by the enzyme method quantification using F kit starch, as shown below.
  • haze is a value when a sample is put in a cell (10 mm ⁇ 40 mm) and measured at 20 ° C. using a haze meter NDH2000 (manufactured by Nippon Denshoku Co., Ltd.).
  • Solution I A solution of “F-kit starch” bottle 1 (approximately 100 mg lyophilized product: citric acid buffer, pH approximately 4.6; approximately 84 U of enzyme amyloglucosidase (AGS)) in 6 ml of distilled water.
  • Solution II "F-kit” bottle 2 (about 5 g powder; triethanolamine buffer, pH about 7.6; nicotinamide adenine dinucleotide phosphate (NADP) about 75 mg: adenosine triphosphate (ATP) about 190 mg
  • Solution III Bin 3 of "F-kit starch” (0.7 ml suspension: about 200 U of hexokinase (HK); about 100 U of glucose-6-phosphate dehydrogenase (G6P-DH)).
  • Table 3 shows the sensory evaluation immediately after the preparation of each beverage and the evaluation of the occurrence of floc two weeks after heating. For each evaluation, ten panelists who received specialized training conducted seven-level evaluations of 1 to 7 according to the following evaluation criteria, and made the average score of the evaluation points of each panel.
  • the beverages of Examples 1 to 5 having a raffinose content of 1.5 to 9.5 ppm, an EBC of 10 or more, and a turbidity (A720) of 0.04 or less were roasted and germinated barley. Containing the extract of cereals contained, the taste intensity, smell, sweetness, flavor is increased, while the taste (total taste) is increased, while the occurrence of floc is suppressed I understand.
  • the beverages of Examples 1 to 3 in which the fructose content is 2 to 15 ppm, the glucose content is 4 to 30 ppm, the sucrose content is 3 to 17 ppm, and the maltose content is 5 to 40 ppm are It can be seen that the occurrence of is more reliably suppressed.
  • the beverage of Comparative Example 2 in which the content of raffinose was excessive and the turbidity (A720) was excessive the occurrence of floc was noticeable.

Abstract

The present invention addresses the problem of providing: a beverage which contains an extract of roasted, germinated barley and in which it is possible to suppress the occurrence of floccing; and a method for suppressing the occurrence of floccing in a beverage. The present invention is a container-packed grain tea beverage containing an extract of grains including roasted, germinated barley, wherein the raffinose content of the beverage is 1.5-9.5 ppm, the EBC is 10 or higher, and the turbidity (A720) is 0.04 or lower. The present invention is also a method for suppressing the occurrence of floccing in the beverage by adjusting the raffinose content and turbidity (A720) in a tea beverage containing an extract of germinated, roasted grain.

Description

飲料及び飲料のフロック発生を抑制する方法Method for suppressing the occurrence of flocks in beverages and beverages
 本発明は、焙煎発芽大麦を含む穀物の抽出物を含有する容器詰穀物茶飲料、及び飲料のフロック発生を抑制する方法に関する。 The present invention relates to a packaged cereal tea beverage containing an extract of cereals including roasted and germinated barley, and a method of suppressing the occurrence of flocking in beverages.
 従来より、麦茶をはじめとする穀物茶飲料は、麦特有の甘味やその香ばしさから広く愛飲されており、複数種の穀物や茶葉を組み合わせて配合することで、嗜好性が高められている(例えば、特許文献1~3参照)。 In the past, cereal tea beverages such as barley tea have been widely consumed due to the sweetness and aroma characteristic of barley, and their palatability is enhanced by combining and combining two or more types of grains and tea leaves ( See, for example, Patent Documents 1 to 3).
特開2008-237066号公報JP 2008-237066 A 特開2012-170374号公報JP 2012-170374 A 特開2015-8704号公報JP, 2015-8704, A
 しかしながら、穀物茶飲料においては、焙煎発芽大麦を配合すると嗜好性が上がる一方で、長期間の保管や加温時に、浮遊物状又は白濁状の懸濁又は沈殿物であるフロック(オリ)が発生する場合があった。 However, in cereal tea beverages, while adding roasted and germinated barley improves palatability, floc (oly), which is a suspension or precipitate in the form of a float or turbid, during long-term storage and warming There was a case that occurred.
 これまで、フロックの発生要因はスターチであると考えられてきた。しかし、本発明者らが鋭意検討を重ねた結果、必ずしもスターチ量を調節するだけではフロックの発生を抑制できるとは限られないことがわかった。 So far, the cause of floc has been considered to be the starch. However, as a result of intensive studies by the present inventors, it was found that merely adjusting the amount of starch can not necessarily suppress the occurrence of floc.
 本発明は、焙煎発芽大麦の抽出物を含み、かつフロックの発生を抑制可能な飲料を提供することを目的とする。また、本発明は、飲料のフロック発生を抑制する方法を提供することを目的とする。 An object of the present invention is to provide a beverage comprising an extract of roasted and germinated barley and capable of suppressing the occurrence of floc. Another object of the present invention is to provide a method for suppressing the occurrence of flocks in beverages.
 本発明者らは、焙煎発芽大麦の抽出物を含む飲料であっても、糖類の1種であるラフィノースの含有量や色度の指標となるEBCや濁度(A720)を所定の範囲内に調節することにより、フロックの発生を抑制できることを見出し、本発明を完成するに至った。具体的に、本発明は以下のものを提供する。 The present inventors set the EBC and turbidity (A720) as an index of the content and color of raffinose, which is one of saccharides, even in a beverage containing an extract of roasted and germinated barley within a predetermined range. By adjusting to, it has been found that the occurrence of floc can be suppressed, and the present invention has been completed. Specifically, the present invention provides the following.
 (1)本発明は、焙煎発芽大麦を含む穀物の抽出物を含有する容器詰穀物茶飲料であって、ラフィノースの含有量が1.5~9.5ppmであり、EBCが10以上、濁度(A720)が0.04以下である飲料である。 (1) The present invention is a container-packed grain tea beverage containing an extract of cereal grains including roasted and germinated barley, wherein the content of raffinose is 1.5 to 9.5 ppm, EBC is 10 or more, and turbid. It is a drink whose degree (A720) is 0.04 or less.
 (2)本発明は、濁度(A720)が0.035以下である(1)記載の飲料である。 (2) The present invention is the beverage according to (1), wherein the turbidity (A720) is 0.035 or less.
 (3)本発明は、含有量が、フルクトース2~15ppm、グルコース4~30ppm、スクロース3~17ppm、又はマルトース5~40ppmである(1)又は(2)記載の飲料である。 (3) The present invention is the beverage according to (1) or (2), wherein the content is 2 to 15 ppm fructose, 4 to 30 ppm glucose, 3 to 17 ppm sucrose, or 5 to 40 ppm maltose.
 (4)本発明は、フルクトース、グルコース、スクロース、マルトース、ラフィノース及びスタキオースの6種の糖類の合計含有量が、20~110ppmである(1)から(3)いずれか記載の飲料である。 (4) The present invention is the beverage according to any one of (1) to (3), wherein the total content of six saccharides of fructose, glucose, sucrose, maltose, raffinose and stachyose is 20 to 110 ppm.
 (5)本発明は、スターチが、100mg/100mL以上の量で含まれる(1)から(4)いずれか記載の飲料である。 (5) The present invention is the beverage according to any one of (1) to (4), wherein starch is contained in an amount of 100 mg / 100 mL or more.
 (6)本発明は、前記穀物は、さらにハトムギ又は大麦を含む(1)から(5)いずれか記載の飲料である。
 (7)本発明は、発芽処理された焙煎穀物の抽出物を含有する飲料におけるラフィノース含有量及び濁度(A720)を調節することで、前記飲料のフロック発生を抑制する方法である。
(6) The present invention is the beverage according to any one of (1) to (5), wherein the cereals further comprise barley barley or barley.
(7) The present invention is a method for suppressing the occurrence of floc in the beverage by adjusting the content of raffinose and the turbidity (A720) in a beverage containing the extract of roasted roasted grain.
 本発明によれば、焙煎発芽大麦の抽出物を含み、かつフロックの発生を抑制可能な飲料を提供することができる。また、本発明によれば、飲料のフロック発生を抑制する方法を提供することができる。 According to the present invention, it is possible to provide a beverage which contains an extract of roasted and germinated barley and is capable of suppressing the occurrence of floc. Further, according to the present invention, it is possible to provide a method for suppressing the occurrence of flocking of a beverage.
 以下、本発明の具体的な実施形態について詳細に説明するが、本発明は以下の実施形態に何ら限定されるものではなく、本発明の目的の範囲内において、適宜変更を加えて実施することができる。なお、本明細書にて、「X~Y」(X、Yは任意の数値)との表記は、「X以上Y以下」の意味である。 Hereinafter, although specific embodiments of the present invention will be described in detail, the present invention is not limited to the following embodiments in any way, and may be appropriately modified and implemented within the scope of the object of the present invention. Can. In the present specification, the notation “X to Y” (X and Y are arbitrary numerical values) means “more than X and less than Y”.
 <飲料>
 本実施形態に係る飲料は、焙煎発芽大麦を含む穀物の抽出物を含有する容器詰穀物茶飲料であって、ラフィノースの含有量が1.5~9.5ppmであり、EBCが10以上 、濁度(A720)が0.04以下である。本実施形態に係る飲料は、焙煎発芽大麦がもつ特有の甘みや香ばしさが付与され嗜好性が向上しながらも、ラフィノースの含有量、EBC、及び濁度(A720)が所定の範囲に調節されていることによりフロックの発生が抑制される。
<Beverage>
The beverage according to the present embodiment is a containerized cereal tea beverage containing an extract of cereal grains including roasted and germinated barley, and the content of raffinose is 1.5 to 9.5 ppm, and the EBC is 10 or more. The turbidity (A720) is 0.04 or less. In the beverage according to the present embodiment, the content of raffinose, EBC, and turbidity (A720) are adjusted within a predetermined range while the sweetness and aroma unique to roasted and germinated barley are imparted to improve the palatability. By doing so, the occurrence of floc is suppressed.
 以下、EBC、濁度(A720)、及び穀物の抽出物に含まれる成分について具体的に説明する。 Hereinafter, the components contained in EBC, turbidity (A 720), and extracts of cereals will be specifically described.
 [EBC]
 EBCは、煮出し色度と称されるものであり、値が高いほど色が濃いことを示す。EBCは、EBC(European Brewery Convention)のAnalytica-EBC標準法、又はこれに準じた方法により測定する。本明細書において、EBCは、波長430nmの条件で測定した値である。具体的には、試料を10mm(光路長)のセルに入れ、430nmの単色光で吸光度を測定し、下式(1)に示す算出式により算出する。波長430nmにおける吸光度が0.8以上の場合には、試料を蒸留水で希釈してから測定する。
 EBC=25×f×A430  ・・・(1)
(式(1)中、「25」は、EBCを換算するためのファクター、「f」は希釈率、「A430」は、波長430nmにおける吸光度である。)
[EBC]
EBC is called boiling color, and the higher the value, the darker the color. The EBC is measured by the Analytica-EBC standard method of EBC (European Brewery Convention) or a method according thereto. In the present specification, EBC is a value measured under the condition of wavelength 430 nm. Specifically, a sample is placed in a cell of 10 mm (optical path length), absorbance is measured with monochromatic light of 430 nm, and calculation is made according to the formula shown in the following formula (1). When the absorbance at a wavelength of 430 nm is 0.8 or more, the sample is diluted with distilled water and then measured.
EBC = 25 × f × A 430 (1)
(In the formula (1), “25” is a factor for converting EBC, “f” is a dilution ratio, and “A430” is absorbance at a wavelength of 430 nm.)
 本実施形態に係る飲料のEBCは、嗜好性に優れる点から、10以上、好ましくは12以上である。EBCが過小であると、味の濃さ等の嗜好性が低下する傾向がある。EBCの上限値は、特に限定されないが、好ましくは28以下、より好ましくは25以下、特に好ましくは20以下である。EBCが過大であると、味が濃すぎたり、白色のフロックが目立ちやすくなったりする。 The EBC of the beverage according to the present embodiment is 10 or more, preferably 12 or more, from the viewpoint of excellent palatability. If the EBC is too small, the taste such as the concentration of taste tends to decrease. The upper limit of EBC is not particularly limited, but is preferably 28 or less, more preferably 25 or less, and particularly preferably 20 or less. If the EBC is too large, the taste may be too strong or the white flock may be noticeable.
 [濁度(A720)]
 濁度(A720)は、10mm(光路長)のセル中、波長720nmにおける吸光度であり、数値が小さいほど透明性が高いことを示す。本明細書において、濁度A720は、例えば、分光光度計U-5100(日立ハイテクノロジーズ社製)を用いて波長720nm条件で測定した値である。
[Purpose (A 720)]
The turbidity (A720) is the absorbance at a wavelength of 720 nm in a cell of 10 mm (optical path length), and the smaller the value, the higher the transparency. In the present specification, the turbidity A720 is, for example, a value measured at a wavelength of 720 nm using a spectrophotometer U-5100 (manufactured by Hitachi High-Technologies Corporation).
 本実施形態に係る飲料の濁度(A720)は、フロックの発生を抑制する点から、0.04以下であり、好ましくは0.035以下、より好ましくは0.030以下である。濁度A720が過大であると、フロックが発生しやすくなる。濁度(A720)の下限値は、特に限定されないが、0であってもよい。 The turbidity (A 720) of the beverage according to the present embodiment is 0.04 or less, preferably 0.035 or less, more preferably 0.030 or less, from the viewpoint of suppressing the occurrence of floc. If the turbidity A720 is too large, floc is likely to occur. The lower limit value of the turbidity (A720) is not particularly limited, but may be 0.
 ここで、濁度A720は、フロックの発生を抑制する上で重要な指標となることが明らかになった。ヘイズとフロック発生との間には相関関係があると従来考えられていたが、後述する実施例からも明らかなように、ヘイズからはフロックの発生しやすさを正確に予測することが難しい場合がある。濁度A720を指標とすることにより、フロックの発生しやすさを予測することができ、濁度A720を所定の範囲内に調節することにより、フロックの発生を抑制できることが明らかになった。 Here, it became clear that turbidity A720 becomes an important index in controlling the occurrence of floc. It has been conventionally thought that there is a correlation between haze and flock occurrence, but it is difficult to accurately predict flock occurrence probability from haze, as is apparent from the examples described later. There is. By using turbidity A720 as an index, it is possible to predict the likelihood of occurrence of floc, and it has become clear that the occurrence of floc can be suppressed by adjusting the turbidity A720 within a predetermined range.
 [穀物の抽出物に含まれる成分について]
 本実施形態に係る飲料は、以下に説明するように、糖類の1種であるラフィノースを所定の範囲内で含有する。また、本実施形態に係る飲料は、ラフィノース以外に糖類の1種である、フルクトース、グルコース、スクロース、又はマルトースを所定の範囲内で含有することが好ましい。さらに、本実施形態に係る飲料は、スターチを所定の範囲内で含有することが好ましい。
[About the ingredients contained in the extract of cereals]
The drink which concerns on this embodiment contains raffinose which is 1 type of saccharides within the predetermined | prescribed range, as demonstrated below. Moreover, it is preferable that the drink which concerns on this embodiment contains fructose, glucose, sucrose, or maltose which is 1 type of saccharides other than raffinose within the predetermined | prescribed range. Furthermore, the beverage according to the present embodiment preferably contains starch in a predetermined range.
 [ラフィノース]
 ラフィノースの含有量は、後述する他の糖類と同様に、味の濃さ、香りの強さ、甘味の強さ、香ばしさ等の飲料の嗜好性と相関関係があるが、他の糖類とは異なり、フロックの発生と強い相関関係があることが明らかになった。ラフィノースの含有量は、フロック発生を抑制し、及び/又は嗜好性に優れる点から、1.5~9.5ppmであり、好ましくは2.0~8.0ppmであり、より好ましくは2.5~7.5ppmである。ラフィノースの含有量が過小であると、嗜好性が低下する傾向がある。ラフィノースの含有量が過大であると、フロックが発生しやすくなると共に、嗜好性が低下する傾向がある。
[Raffinose]
The content of raffinose, like the other saccharides described later, correlates with the palatability of the beverage such as the intensity of the taste, the intensity of the scent, the intensity of sweetness, the fragrantness, etc. Differently, it became clear that there was a strong correlation with the occurrence of floc. The content of raffinose is 1.5 to 9.5 ppm, preferably 2.0 to 8.0 ppm, more preferably 2.5 from the viewpoint of suppressing floc generation and / or excellent palatability. It is ̃7.5 ppm. If the content of raffinose is too low, the taste tends to be reduced. When the content of raffinose is too large, flocking tends to occur and the taste tends to decrease.
 [フルクトース]
 フルクトースの含有量は、フロック発生を抑制し、及び/又は嗜好性に優れる点から、好ましくは1~25ppm、より好ましくは2~20ppmであり、特に好ましくは4~15ppmである。フルクトースの含有量が過小であると、嗜好性が低下する傾向がある。フルクトースの含有量が過大であると、フロックが発生しやすくなると共に、嗜好性が低下する傾向がある。
[Fructose]
The content of fructose is preferably 1 to 25 ppm, more preferably 2 to 20 ppm, and particularly preferably 4 to 15 ppm, from the viewpoint of suppressing flocculation and / or excellent palatability. If the content of fructose is too low, the taste tends to decrease. When the content of fructose is excessive, flocking tends to occur and the taste tends to decrease.
 [グルコース]
 グルコースの含有量は、フロック発生を抑制し、及び/又は嗜好性に優れる点から、好ましくは2~40ppm、より好ましくは4~35ppmであり、特に好ましくは6~30ppmである。グルコースの含有量が過小であると、嗜好性が低下する傾向がある。グルコースの含有量が過大であると、フロックが発生しやすくなると共に、嗜好性が低下する傾向がある。
[glucose]
The content of glucose is preferably 2 to 40 ppm, more preferably 4 to 35 ppm, and particularly preferably 6 to 30 ppm, from the viewpoint of suppressing flocculation and / or excellent palatability. If the content of glucose is too low, the taste tends to decrease. When the content of glucose is too high, flocking tends to occur and the taste tends to decrease.
 [スクロース]
 スクロースの含有量は、フロック発生を抑制し、及び/又は嗜好性に優れる点から、好ましくは2~25ppm、より好ましくは3~20ppmであり、特に好ましくは4~17ppmである。スクロースの含有量が過小であると、嗜好性が低下する傾向がある。グルコースの含有量が過大であると、フロックが発生しやすくなると共に、嗜好性が低下する傾向がある。
[sucrose]
The content of sucrose is preferably 2 to 25 ppm, more preferably 3 to 20 ppm, particularly preferably 4 to 17 ppm, from the viewpoint of suppressing the occurrence of floc and / or excellent palatability. If the content of sucrose is too low, the preference tends to be reduced. When the content of glucose is too high, flocking tends to occur and the taste tends to decrease.
 [マルトース]
 マルトースの含有量は、フロック発生を抑制し、及び/又は嗜好性に優れる点から、好ましくは2~60ppm、より好ましくは5~50ppmであり、特に好ましくは10~40ppmである。マルトースの含有量が過小であると、嗜好性が低下する傾向がある。マルトースの含有量が過大であると、フロックが発生しやすくなると共に、嗜好性が低下する傾向がある。
[Martose]
The maltose content is preferably 2 to 60 ppm, more preferably 5 to 50 ppm, and particularly preferably 10 to 40 ppm, from the viewpoint of suppressing the occurrence of floc and / or excellent palatability. If the maltose content is too low, the taste tends to be reduced. When the content of maltose is too large, flocking tends to occur and the taste tends to decrease.
 [スタキオース]
 スタキオースの含有量は、フロック発生を抑制し、及び/又は嗜好性に優れる点から、好ましくは0.8~10ppm、より好ましくは1~5ppmであり、特に好ましくは1.5~4ppmである。スタキオースの含有量が過小であると、嗜好性が低下する傾向がある。スタキオースの含有量が過大であると、フロックが発生しやすくなると共に、嗜好性が低下する傾向がある。
[Stakiose]
The content of stachyose is preferably 0.8 to 10 ppm, more preferably 1 to 5 ppm, and particularly preferably 1.5 to 4 ppm, from the viewpoint of suppressing flocculation and / or excellent palatability. If the content of stachyose is too low, the preference tends to be reduced. When the content of stachyose is too large, flocking tends to occur and the taste tends to decrease.
 これらラフィノース、フルクトース、グルコース、スクロース、マルトース、及びスタキオースの6種の糖類の合計含有量は、好ましくは10~180ppm、より好ましくは15~140ppm、特に好ましくは20~110ppmである。これら6種の糖類の合計含有量が上記範囲であることにより、フロックを抑制しながら、適度な味の濃さ、香りの強さ、甘味の強さ、香ばしさ等を付与して嗜好性に優れた飲料とすることができる。 The total content of these six saccharides of raffinose, fructose, glucose, sucrose, maltose and stachyose is preferably 10 to 180 ppm, more preferably 15 to 140 ppm, and particularly preferably 20 to 110 ppm. When the total content of these six types of saccharides is in the above-mentioned range, the concentration of taste, the intensity of aroma, the intensity of sweetness, the fragrantness, etc. are imparted while suppressing the floc to give palatability It can be an excellent beverage.
 なお、これらの糖類の含有量は、液体クロマトグラフ質量分析計により測定する。 In addition, content of these saccharides is measured by a liquid chromatograph mass spectrometer.
 (スターチ)
 本明細書中、「スターチ」とは、上述した6種の糖に加えて、これら以外の糖であるオリゴ糖や、アミロースとアミロペクチンとの混合物であるデンプンや、デンプンの加水分解物であるデキストリン等の糖を含む。本明細書中において、スターチの含有量は、F-キットスターチ(製品番号;207748;ロッシュ・ダイアグノスティックス社製)を用いた酵素法定量によって、後述する方法で測定する。
(starch)
In the present specification, “starch” means, in addition to the above-described six types of sugars, oligosaccharides other than these sugars, starch which is a mixture of amylose and amylopectin, and dextrin which is a hydrolyzate of starch. And other sugars. In the present specification, the content of starch is measured by an enzymatic method quantification using an F-kit starch (product number: 207748; manufactured by Roche Diagnostics) by a method described later.
 スターチの含有量は、特に制限されないが、甘味やボディー感(飲みごたえ)を付与する点から、その下限は、好ましくは90mg/100ml以上、より好ましくは100mg/100ml以上である。一方、スターチの含有量の上限は、特に制限されないが、例えば、180mg/100ml以下、160mg/100ml以下である。従来より、フロック発生を抑制するためにスターチの含有量を下げることが検討されていたが、本実施形態においては、ラフィノースの含有量、EBC、濁度(A720)が所定の範囲内に調節されていることから、飲料に甘味やボディー感を付与するスターチを比較的多めに付与することができ、嗜好性の点でメリットが大きい。 The content of starch is not particularly limited, but the lower limit thereof is preferably 90 mg / 100 ml or more, more preferably 100 mg / 100 ml or more, from the viewpoint of imparting sweetness and body feeling (drinkiness). On the other hand, the upper limit of the content of starch is not particularly limited, and is, for example, 180 mg / 100 ml or less and 160 mg / 100 ml or less. Conventionally, it has been considered to reduce the starch content to suppress the occurrence of floc, but in the present embodiment, the content of raffinose, EBC, and turbidity (A720) are adjusted within a predetermined range. Because of this, relatively large amounts of starch can be imparted to the beverage to impart sweetness and body feeling, and the advantage is great in terms of palatability.
 なお、上述した6種の糖類やスターチは、穀物の焙煎により生成されるものであってもよいし、従来公知の方法で精製されたものであってもよい。また、上述した6種の糖類やスターチの含有量の調整は、上記含有量を満たすように、発芽大麦に加えて複数種の穀物から少なくとも1種以上を選定して用いてもよいし、それらの抽出液の混合割合を変更して適宜調整してもよい。また、上記含有量を満たすために従来公知の方法で精製された成分単体や副原料を追加してもよい。例えば、ラフィノースの含有量を多くしたい場合には、焙煎発芽大麦の使用量を多くしたり、ラフィノースの含有量が多い穀物の使用量を多くしたり、穀物の焙煎条件をL値が高くなるように調製したりすればよい。ラフィノースの含有量を少なくしたい場合には、焙煎発芽大麦の使用量を少なくしたり、ラフィノースの含有量が少ない穀物の使用量を少なくしたり、糖類の吸着能を有する吸着剤で処理したりすればよい。また、スターチの含有量を多くしたい場合には、スターチの含有量が多い穀物の使用量を多くしたり、穀物の焙煎条件をL値が高くなるように調整したり、焙煎麦の抽出時間を長くしたりすればよい。 In addition, the six types of saccharides and starch which were mentioned above may be produced | generated by roasting of a grain, and may be refine | purified by the conventionally well-known method. Moreover, in addition to sprouted barley, at least 1 or more types may be selected and used from several types of grains so that adjustment of content of six types of saccharides and starch which were mentioned above may satisfy the said content, those The mixing ratio of the extract may be changed appropriately. Moreover, in order to satisfy | fill said content, you may add the component simple substance and auxiliary material which were refine | purified by the conventionally well-known method. For example, when it is desired to increase the content of raffinose, the use amount of roasted and germinated barley may be increased, the use amount of grains having a high content of raffinose may be increased, or the roasting conditions of the grain may have a high L value. It may be prepared to be When it is desired to reduce the content of raffinose, it is necessary to reduce the use of roasted and germinated barley, to reduce the use of grains having a low content of raffinose, or to treat with an adsorbent having an ability to adsorb saccharides. do it. In addition, when it is desired to increase the starch content, the use amount of grains having a high starch content may be increased, the roasting conditions of the grains may be adjusted to increase the L value, or the roasted barley extraction may be performed. It may be sufficient to lengthen the time.
 [可溶性固形分]
 可溶性固形分は、飲料中の可溶性固形分全体の濃度を糖用屈折計で測定した値であり、「Brix」を指す。本明細書において、可溶性固形分は、例えばデジタル示差濃度計DD-7(株式会社アタゴ製)を使用して30℃で測定したときの値をいう。
[Soluble solid content]
The soluble solid content is a value obtained by measuring the concentration of the total soluble solid content in the beverage with a sugar refractometer, and refers to "Brix". In the present specification, the soluble solid content is a value measured at 30 ° C. using, for example, a digital differential densitometer DD-7 (manufactured by Atago Co., Ltd.).
 本実施形態に係る飲料の可溶性固形分は、特に制限されないが、甘味やボディー感(飲みごたえ)を付与する点から、可溶性固形分の下限は、好ましくは0.30質量%以上、より好ましくは0.30質量%以上である。一方、可溶性固形分の上限は、フロックの発生を抑制する点から、好ましくは0.45質量%以下である。 The soluble solid content of the beverage according to the present embodiment is not particularly limited, but the lower limit of the soluble solid content is preferably 0.30 mass% or more, and more preferably, from the viewpoint of imparting sweetness and body feeling (drinkiness). It is 0.30 mass% or more. On the other hand, the upper limit of the soluble solid content is preferably 0.45% by mass or less from the viewpoint of suppressing the occurrence of floc.
 可溶性固形分は、穀物の焙煎条件や、穀物の抽出条件を変更して適宜調整してもよく、可溶性固形分を添加して調整してもよい。例えば、可溶性固形分を多くしたい場合には、焙煎麦の抽出時間を長くしたり、抽出時に適量の炭酸塩(炭酸水素ナトリウム等)を添加したりすればよい。例えば、炭酸水素ナトリウムを添加する場合には、抽出溶媒1Lに対して0.25g以上6g以下の範囲から可溶性固形分が所望の値となる適量を選択すればよい。炭酸塩(炭酸水素ナトリウム等)の添加によって抽出溶媒のpHを調整することで、可溶性固形分を多く取りやすくなる。 The soluble solid content may be adjusted as appropriate by changing the roasting conditions of grains and the extraction conditions of grains, and may be adjusted by adding soluble solids. For example, when it is desired to increase the soluble solid content, extraction time of roasted barley may be extended, or an appropriate amount of carbonate (sodium hydrogen carbonate etc.) may be added at the time of extraction. For example, in the case of adding sodium hydrogen carbonate, an appropriate amount such that the soluble solid content becomes a desired value may be selected from the range of 0.25 g to 6 g per 1 L of the extraction solvent. By adjusting the pH of the extraction solvent by the addition of a carbonate (such as sodium hydrogen carbonate), it becomes easy to obtain a large amount of soluble solids.
<飲料の製造方法>
 本実施形態に係る飲料の製造方法は、一般的な方法を採用可能であり、必要に応じて、穀物を焙煎する焙煎工程、焙煎穀物を抽出して抽出液を得る抽出工程、抽出液に水や各種添加物を調合する調合工程、調合された飲料を加熱殺菌する加熱殺菌工程、調合された飲料を容器に充填する容器充填工程等を含む。
<Method of producing beverage>
The method for producing a beverage according to the present embodiment can adopt a general method, and if necessary, a roasting step of roasting grains, an extraction step of extracting roasted grains to obtain an extract, extraction It includes a blending step of blending water and various additives into a liquid, a heating and sterilization step of heating and sterilizing the blended beverage, and a container filling step of filling the blended beverage into a container.
 [焙煎工程]
 一般的な焙煎方法を採用可能であり、所望の糖類及びスターチの含有量、EBC、濁度(A720)等を得るために適正な焙煎方法(焙煎時間、焙煎温度等)が選択されればよい。一般的な方法としては、熱風焙煎、直火焙煎、砂炒焙煎、遠赤外焙煎等が挙げられる。焙煎穀物は、ホールのまま抽出工程に移行してもよく、粉砕して抽出工程に移行してもよい。
[Roasting process]
A common roasting method can be adopted, and a suitable roasting method (roasting time, roasting temperature, etc.) is selected to obtain the desired content of sugars and starch, EBC, turbidity (A 720), etc. It should be done. As a general method, hot air roasting, direct fire roasting, sand roasting, far infrared roasting and the like can be mentioned. The roasted grain may be transferred to the extraction step as it is in the hole or may be crushed and transferred to the extraction step.
 例えば、焙煎発芽大麦のL値は、好ましくは20~40、より好ましくは24~34、さらに好ましくは27~31である。L値が上記範囲内であることで、飲料に好ましい味の濃さ、香ばしさを付与できる焙煎強度を選択しやすくなる。本明細書において、L値は、色差計ZE-2000(日本電色工業株式会社製)を用いて測定する。 For example, the L value of roasted and germinated barley is preferably 20 to 40, more preferably 24 to 34, and still more preferably 27 to 31. When the L value is in the above range, it becomes easy to select the roasting strength that can impart a preferable taste and flavor to the beverage. In the present specification, the L value is measured using a color difference meter ZE-2000 (manufactured by Nippon Denshoku Kogyo Co., Ltd.).
 なお、本実施形態に係る飲料(抽出物)の原料としては、焙煎発芽大麦以外の穀物も用いてもよく、発芽大麦以外の穀物としては、例えば、大麦、ハトムギ、小麦等の麦類、玄米、発芽玄米等の米類、黒豆等の豆類、あわ、キビ等を用いることができる。これらは単独でも用いてもよく、2種類以上を併用してもよい。嗜好性の高い飲料を得る観点から、これら穀物の中でも、麦類が好ましく、嗜好性の点から、特に大麦やハトムギが好ましく用いられる。また、大麦やハトムギは、炭水化物栄養価が高く、米や他の麦に比べタンパク質を多く含むため、体内の新陳代謝を活発化させることが知られており、好ましく用いられる。また、ハトムギは、抗潰瘍性成分としてのコイクセノライドと、ひきつけを抑制する成分としてのコイクソールとを含有する。ハトムギの効用としては、抗酸化作用、美肌作用、イボとり作用等が知られており、好ましく用いられる。 In addition, as a raw material of the drink (extract) which concerns on this embodiment, grains other than roasted and germinated barley may be used, and as grains other than germinated barley, for example, barley such as barley, barley, wheat, etc. Brown rice, rice such as sprouted brown rice, beans such as black beans, bubbles, millet and the like can be used. These may be used alone or in combination of two or more. Among these cereals, wheat and barley are preferable from the viewpoint of obtaining a beverage with high palatability, and barley and barley are particularly preferably used from the viewpoint of palatability. In addition, since barley and barley have high nutritional value of carbohydrate and contain more protein than rice and other barley, they are known to activate metabolism in the body and are preferably used. In addition, the stalk-worm contains a koikusenolide as an anti-ulcer component and a coixol as a component which suppresses attraction. Antioxidant action, skin-refining action, wart action, and the like are known as the effects of moth barley, and it is preferably used.
 穀物は、それぞれ所望の時期に収穫後、乾燥、脱穀、焙煎、粉砕等の適切な処理が施される。焙煎することにより、穀物に含まれる糖とタンパク質とのメイラード反応が生じやすくなり、香ばしさや褐色が増強される。 Cereals are harvested at desired times and subjected to appropriate treatments such as drying, threshing, roasting, grinding and the like. By roasting, the Maillard reaction between sugar contained in cereals and proteins is likely to occur, and aroma and brown color are enhanced.
 また、飲料(抽出物)の原料としては、上述した穀物以外に、カメリア・シネンシス種の茎葉や、カメリア・シネンシス種以外の植物の茎葉を用いてもよい。 Moreover, as a raw material of a drink (extract), you may use the foliage of a Camellia sinensis species other than the grain mentioned above, and the foliage of plants other than a Camellia sinensis species.
 カメリア・シネンシス種の茎葉は、発酵条件の違いによって、発酵茶(紅茶)、半発酵茶(ウーロン茶等)、不発酵茶(緑茶等)、後発酵茶(プアール茶等)、香味品質の異なる茶葉となることが知られている。 The stems and leaves of Camellia sinensis species are fermented tea (black tea), semi-fermented tea (such as oolong tea), non-fermented tea (such as green tea), post-fermented tea (such as puar tea), and tea leaves with different flavor qualities depending on the fermentation conditions. It is known to be.
 カメリア・シネンシス種以外の植物としては、例えば、明日葉、グァバ、柿、笹、クコ、よもぎ、アマチャヅル、桑、杜仲葉、シソ、びわ、大麦若葉、仙草、ドクダミ、オオバコ、スイカズラ、ツキミソウ、カキドオシ、カワラケツメイ、ギムネマ・シルベスタ、黄杞茶(クルミ科)、甜茶(バラ科)、ギムネマ、ルイボス、ラフマ、タンポポ、ペパーミント、モロヘイヤ、イチョウ、松葉、蓮、及びオリーブ等が挙げられる。これらは単独で用いてもよく、2種類以上を併用してもよい。 Examples of plants other than Camellia sinensis species include, for example, tomorrow leaves, guava, persimmons, persimmons, wolfberry, wormwood, amachan, persimmon, persimmon leaf, persimmon, persimmon, young barley, senso, dokudami, plantain, honeysuckle, persimmon, There may be mentioned oyster oysters, kawara-ketsumei, gymnema sylvesta, yellow tea (walnut family), green tea (rose family), gymnema, rooibos, ruffuma, dandelion, peppermint, moth earth, ginkgo, pine needles, lotus, olive and the like. These may be used alone or in combination of two or more.
 抽出物の原料は、上述したように、6種の糖類やスターチの含有量が上述した範囲を満たすように、発芽大麦に加えて複数種の穀物から少なくとも1種以上を選定して用いるとよい。甘味や香ばしさ等の嗜好性の向上を図りながら、フロック発生を抑制する点から、焙煎発芽大麦の使用量は、好ましくは飲料1Lに対して0.5~5.5、より好ましくは1.0~4.5g、より好ましくは1.5~3.5gである。 As the raw material of the extract, as described above, it is preferable to select and use at least one or more kinds from a plurality of kinds of grains in addition to the germinated barley so that the content of the six kinds of sugars and starch satisfies the above mentioned range. . The amount of roasted and germinated barley used is preferably 0.5 to 5.5, and more preferably 1 per liter of beverage, in order to suppress the occurrence of floc while improving the preference such as sweetness and aroma. The content is from 0 to 4.5 g, more preferably from 1.5 to 3.5 g.
 [抽出工程]
 一般的な抽出方法を採用可能であり、所望の糖類の含有量、EBC、及び濁度(A720)を得るために適正な抽出方法(抽出倍率、抽出温度、抽出時間等)が選択されればよい。一般的な方法としては、水蒸気蒸留、液化炭酸ガス抽出、アルコール抽出、熱水抽出等の従来公知の抽出方法を用いることができる。また、抽出に用いる抽出溶媒の種類は、特に限定されるものではないが、脱イオン交換処理精製したもの又は蒸留水を用いることが好ましい。これらは、安価、手軽であり、かつ安全に調製し抽出設備に供することができる。なお、水以外の抽出溶媒としては、エタノールやその他の親水性有機溶媒が挙げられる。また、抽出溶媒に対して、抽出効率化の目的で、食品添加物のいわゆる炭酸塩(炭酸水素ナトリウム(重曹)等)、リン酸塩、アスコルビン酸塩、アスコルビン酸等を適宜添加してもよい。
[Extraction process]
A general extraction method can be adopted, and if an appropriate extraction method (extraction magnification, extraction temperature, extraction time, etc.) is selected in order to obtain desired sugar content, EBC, and turbidity (A 720) Good. As a general method, conventionally known extraction methods such as steam distillation, liquefied carbon dioxide gas extraction, alcohol extraction, hot water extraction and the like can be used. Further, the type of extraction solvent used for the extraction is not particularly limited, but it is preferable to use one which has been purified by deionized exchange treatment or distilled water. These are inexpensive, easy and safe to prepare and provide for extraction equipment. In addition, ethanol and other hydrophilic organic solvents are mentioned as extraction solvents other than water. In addition, so-called carbonates (sodium hydrogen carbonate (sodium bicarbonate), etc.), phosphates, ascorbates, ascorbic acid, etc. of food additives may be appropriately added to the extraction solvent for the purpose of enhancing extraction efficiency. .
 抽出倍率(原料に対する抽出溶媒の倍率)は、特に限定されない。抽出に用いる水に対して原料(穀物)の使用量が少なくなるほど、得られる抽出液は、味の濃さ、香りの強さ、甘味の強さが小さくなる。原料(穀物)の使用量が多くなるほど、得られる抽出液は、味の濃さ、香りの強さ、甘味の強さが大きくなる。このため、抽出倍率は、焙煎された原料(穀物)からこれを引き出すために、最適な量に調整されることが一般的である。 The extraction ratio (the ratio of the extraction solvent to the raw material) is not particularly limited. The less the amount of raw material (grain) used with respect to the water used for extraction, the smaller the intensity of taste, the intensity of aroma and the intensity of sweetness of the resulting extract. As the amount of the raw material (grain) used increases, the resulting extract has a greater flavor, flavor and sweetness. For this reason, the extraction ratio is generally adjusted to an optimal amount in order to extract it from the roasted raw material (cereal).
 抽出温度は、特に限定されないが、例えば、80℃以上100℃以下であることが好ましい。上記温度範囲で抽出を行えば、抽出効率が高い。抽出時間も特に限定されないが、5分以上1時間以下の範囲内で行うことが好ましい。上記抽出時間で抽出液を得れば、熱による風味変化や香気成分の散逸を抑えつつ、甘味、香ばしさの各成分を抽出しやすい傾向にある。これにより、嗜好性に優れた茶飲料を得やすくなる。 The extraction temperature is not particularly limited, but is preferably, for example, 80 ° C. or more and 100 ° C. or less. If extraction is performed in the above temperature range, the extraction efficiency is high. The extraction time is also not particularly limited, but is preferably in the range of 5 minutes to 1 hour. If an extract is obtained at the above-mentioned extraction time, it tends to be easy to extract each ingredient of sweetness and fragrantness, suppressing the flavor change and dissipation of an aroma component by heat. This makes it easy to obtain a tea beverage excellent in palatability.
 [調合工程]
 得られた抽出液は、そのまま本発明の飲料として提供することができるが、得られた抽出液に対して、pHや可溶性固形分の調整及び/又は希釈等を適宜行ってもよい。また、必要に応じて、例えば、酸化防止剤、香料、各種エステル類、有機酸類、有機酸塩類、無機酸類、無機酸塩類、無機塩類、色素類、乳化剤、保存料、調味料、品質安定剤等の各種添加剤を含んでいてもよい。
[Blending process]
The obtained extract can be provided as it is as the beverage of the present invention, but adjustment and / or dilution or the like of pH and soluble solid may be appropriately performed on the obtained extract. In addition, if necessary, for example, antioxidants, perfumes, various esters, organic acids, organic acid salts, inorganic acids, inorganic acid salts, inorganic salts, inorganic salts, dyes, emulsifiers, preservatives, seasonings, quality stabilizers And the like may be included.
 [殺菌工程・容器詰め工程]
 得られた抽出液は、適宜加熱殺菌等を行ってもよく、容器に充填して保存する。容器としては、ポリエチレンテレフタレートを主成分とする成形容器(いわゆるペットボトル)、金属箔やプラスチックフィルムと複合された紙容器、金属缶、瓶等が挙げられる。金属缶や瓶のように容器に充填後、加熱殺菌できる場合は、レトルト殺菌(110~140℃、1~数十分間)により製造されるが、ペットボトルや紙容器のようにレトルト殺菌できないものについては、あらかじめレトルト殺菌と同等の殺菌条件、例えばプレート式熱交換機等で高温短時間殺菌(UHT殺菌:110~150℃、1~数十秒間)し、一定の温度まで冷却後、容器に充填する等の方法が選択できる。
[Sterilization process, container packing process]
The obtained extract may be appropriately heat-sterilized, etc., and filled in a container for storage. Examples of the container include a molded container mainly made of polyethylene terephthalate (so-called plastic bottle), a paper container combined with a metal foil or a plastic film, a metal can, a bottle and the like. If it can be heat-sterilized after filling it in a container like metal cans and bottles, it is manufactured by retort sterilization (110-140 ° C, for 1 to several tens of minutes), but retort sterilization can not be done like plastic bottles and paper containers About thing, the high temperature short time sterilization (UHT sterilization: 110-150 ° C, 1-dozen seconds) with the sterilization conditions equivalent to retort sterilization beforehand, for example with a plate type heat exchanger etc. A method such as filling can be selected.
<飲料のフロック発生を抑制する方法>
 本実施形態に係る飲料のフロック発生抑制方法は、発芽処理された焙煎穀物の抽出物を含有する飲料におけるラフィノース含有量及び濁度(A720)を調節することで、飲料のフロック発生を抑制する方法である。ここで、穀物としては、上述したように、大麦、ハトムギ、小麦等の麦類、玄米、発芽玄米等の米類、黒豆等の豆類、あわ、キビ等が好ましく挙げられる。
<Method to suppress the occurrence of flock of beverage>
The method for suppressing flock generation of a beverage according to the present embodiment suppresses flock generation of a beverage by adjusting the content of raffinose and the turbidity (A720) in a beverage containing the extract of roasted grain which has been germinated. It is a method. Here, as the grain, as described above, barley such as barley, buckwheat, wheat etc., rice such as brown rice, sprouted brown rice etc., beans such as black beans, rubble, millet etc. are preferably mentioned.
 本実施形態に係る飲料のフロック発生抑制方法によれば、上述したように、ラフィノースの含有量及び濁度を調節することでフロックの発生を抑制することができ、視覚的な優位性を確保できる。 According to the method for suppressing the occurrence of flocs in a beverage according to the present embodiment, as described above, the occurrence of flocs can be suppressed by adjusting the content and the turbidity of raffinose, and visual superiority can be secured. .
 本実施形態に係る方法を単独で行っても十分なフロック発生抑制効果が得られるが、必要に応じてフロックの発生を抑制する公知の技術を併用してもよい。公知の技術としては、酵素処理により高分子多糖類を分解する製造方法、限外ろ過やケイ藻土等の精密ろ過を行う製造方法、沈殿物の発生を促した後にこれを除去する方法等が挙げられる。 Even when the method according to the present embodiment is performed alone, a sufficient flocculation suppression effect can be obtained, but if necessary, known techniques for suppressing the flocculation may be used in combination. As known techniques, there are a production method for decomposing high molecular weight polysaccharides by enzyme treatment, a production method for performing ultrafiltration or microfiltration such as kieselguhr, a method for promoting generation of a precipitate and removing it, etc. It can be mentioned.
 以下、本発明を実施例に基づいて説明するが、本発明はこれら実施例に限定されるものではない。 Hereinafter, the present invention will be described based on examples, but the present invention is not limited to these examples.
 [抽出液1~8の調製]
 カラム型抽出器を用いて、表1に示される量の焙煎穀物類と焙煎発芽大麦(L値:29.74)とに水温90度以上の水を加えて粗液を得て、さらにアスコルビン酸ナトリウムと炭酸水素ナトリウム(重曹)とを加えて、抽出液1~8を得た。表1中の数字の単位は、[g/L]である。なお、抽出液1、8は、焙煎発芽大麦の抽出液を含まない。
[Preparation of Extracts 1 to 8]
Using a column-type extractor, add crude water to the roasted grains and roasted germinated barley (L value: 29.74) in the amounts shown in Table 1 to obtain a crude solution, Sodium ascorbate and sodium hydrogen carbonate (sodium bicarbonate) were added to obtain extracts 1 to 8. The unit of the numbers in Table 1 is [g / L]. Extracts 1 and 8 do not contain the extract of roasted and germinated barley.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
 [比較例1及び参照例]
 表1に示される抽出液1を比較例1の飲料とし、抽出液8を参照例の飲料とした。比較例1及び参照例の飲料中の各糖類及びスターチの含有量、Brix、濁度(A720)、EBC、ヘイズは、表2に示される通りである。
Comparative Example 1 and Reference Example
Extract 1 shown in Table 1 was used as the beverage of Comparative Example 1, and Extract 8 was used as the beverage of the reference example. The contents of each saccharide and starch in the beverages of Comparative Example 1 and Reference Example, Brix, turbidity (A 720), EBC, and haze are as shown in Table 2.
 [実施例1~5及び比較例2]
 表1に示される抽出液2~7を適宜調合し、実施例1~5及び比較例2の飲料とした。実施例1~5及び比較例2の飲料中の、各糖類及びスターチの含有量、Brix、濁度(A720)、EBC、ヘイズは、表2に示される通りである。なお、スターチの含有量は、以下に示すように、Fキットスターチを用いた酵素法定量によって測定した。また、ヘイズは、ヘイズメーターNDH2000(日本電色株式会社製)を用い、セル(10mm×40mm)に試料を入れ20℃で測定したとき値である。
[Examples 1 to 5 and Comparative Example 2]
Extracts 2 to 7 shown in Table 1 were appropriately formulated to obtain the beverages of Examples 1 to 5 and Comparative Example 2. The contents of each saccharide and starch, Brix, turbidity (A 720), EBC and haze in the beverages of Examples 1 to 5 and Comparative Example 2 are as shown in Table 2. In addition, content of a starch was measured by the enzyme method quantification using F kit starch, as shown below. Moreover, haze is a value when a sample is put in a cell (10 mm × 40 mm) and measured at 20 ° C. using a haze meter NDH2000 (manufactured by Nippon Denshoku Co., Ltd.).
 (スターチの含有量の測定方法)
 (A)試料を2~10倍に希釈した後、試料溶液0.10mlに対し、溶液Iを0.20ml混和し、55~60℃(温浴中)で15分間インキュベーションした。その後、試料を温浴から取り出し、室温に戻してから、蒸留水を1.00ml、溶液IIを1.00ml秤取、混和し、約3分後に波長340nmにおける吸光度E1を測定した。さらに、溶液IIIを0.02ml混和し、約15分後に波長340nmにおける吸光度E2を測定した。そして、吸光度ΔE(=吸光度E2-吸光度E1)を算出した。
(Method of measuring starch content)
(A) After the sample was diluted 2 to 10 times, 0.20 ml of solution I was mixed with 0.10 ml of the sample solution, and incubated at 55 to 60 ° C. (in a warm bath) for 15 minutes. Thereafter, the sample was removed from the bath, after returning to room temperature, distilled water 1.00 ml, 1.00 ml weighed solution II, mixed, and the absorbance was measured E A 1 at the wavelength of 340nm after about 3 minutes. Furthermore, 0.02 ml of solution III was mixed, and after about 15 minutes, absorbance E A 2 at a wavelength of 340 nm was measured. Then, the absorbance ΔE A (= absorbance E A 2-absorbance E A 1) was calculated.
 (B)試料を2~10倍に希釈した後、試料溶液0.10mlを55~60℃(温浴中)で15分間インキュベーションした。その後、温浴から取り出し、室温に戻してから、蒸留水を1.20ml、溶液IIを1.00ml秤取、混和し、約3分後に波長340nmにおける吸光度E1を測定した。さらに、溶液IIIを0.02ml混和し、約15分後に波長340nmにおける吸光度E2を測定した。そして、吸光度ΔE(=吸光度E2-吸光度E1)を算出した。 (B) After diluting the sample 2 to 10 times, 0.10 ml of the sample solution was incubated at 55 to 60 ° C. (in a warm bath) for 15 minutes. Then, it was removed from the warm bath, returned to room temperature, 1.20 ml of distilled water and 1.00 ml of solution II were weighed and mixed, and after about 3 minutes, the absorbance E B 1 at a wavelength of 340 nm was measured. Furthermore, 0.02 ml of solution III was mixed, and after about 15 minutes, the absorbance E B 2 at a wavelength of 340 nm was measured. Then, the absorbance ΔE B (= absorbance E B 2-absorbance E B 1) was calculated.
 上記(A)(B)において使用した溶液は、下記の通りである。
 溶液I:「F-キット スターチ」のビン1(約100mg凍結乾燥品:クエン酸バッファー、pH約4.6;酵素アミログルコシダーゼ(AGS)約84U)を蒸留水6mlで溶解した溶液。
 溶液II:「F-キット スターチ」のビン2(約5g粉末;トリエタノールアミンバッファー、pH約7.6;ニコチンアミドアデニンジヌクレオチドリン酸(NADP)約75mg:アデノシン三リン酸(ATP)約190mg;MgSO)を蒸留水27mlで溶解した溶液。
 溶液III:「F-キット スターチ」のビン3(0.7ml懸濁液:ヘキソキナーゼ(HK)約200U;グルコース‐6‐リン酸デヒドロゲナーゼ(G6P-DH)約100U)。
The solutions used in the above (A) and (B) are as follows.
Solution I: A solution of “F-kit starch” bottle 1 (approximately 100 mg lyophilized product: citric acid buffer, pH approximately 4.6; approximately 84 U of enzyme amyloglucosidase (AGS)) in 6 ml of distilled water.
Solution II: "F-kit" bottle 2 (about 5 g powder; triethanolamine buffer, pH about 7.6; nicotinamide adenine dinucleotide phosphate (NADP) about 75 mg: adenosine triphosphate (ATP) about 190 mg A solution of Mg 2 SO 4 dissolved in 27 ml of distilled water.
Solution III: Bin 3 of "F-kit starch" (0.7 ml suspension: about 200 U of hexokinase (HK); about 100 U of glucose-6-phosphate dehydrogenase (G6P-DH)).
 そして、ΔE=ΔE-ΔEを算出し、次式によりスターチの含有量を算出した。
 スターチの含有量(mg/100ml)=0.597×ΔE×100×希釈倍率
Then, ΔE = ΔE A −ΔE B was calculated, and the starch content was calculated by the following equation.
Starch content (mg / 100 ml) = 0.597 × ΔE × 100 × dilution ratio
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
 [評価]
 表3に、各飲料の製造直後における官能性評価と、加温2週間後のフロック発生の評価を合わせて示す。なお、各評価は、専門的な訓練を受けたパネル10名により、以下の評価基準に従って1~7点の7段階評価を実施し、各パネルによる評価点の平均点とした。
[Evaluation]
Table 3 shows the sensory evaluation immediately after the preparation of each beverage and the evaluation of the occurrence of floc two weeks after heating. For each evaluation, ten panelists who received specialized training conducted seven-level evaluations of 1 to 7 according to the following evaluation criteria, and made the average score of the evaluation points of each panel.
 (官能性評価)
 7点:とても良い
 6点:良い
 5点:やや良い
 4点:どちらともいえない
 3点:やや悪い
 2点:悪い
 1点:とても悪い
(Sensory evaluation)
7 points: very good 6 points: good 5 points: somewhat good 4 points: neither good 3 points: somewhat bad 2 points: bad 1 point: very bad
 (フロック発生の評価)
 7点:全く認められない
 6点:僅かに認められる
 5点:少し認められる
 4点:比較的認められる
 3点:とても認められる
 2点:かなり認められる
 1点:非常に認められる
(Evaluation of occurrence of floc)
7 points: not recognized at all 6 points: slightly recognized 5 points: slightly recognized 4 points: relatively recognized 3 points: very recognized 2 points: considerably recognized 1 point: very recognized
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000003
 [結果]
 表2及び表3に示されるように、比較例1の飲料は、焙煎発芽大麦の抽出液を含有していないため、フロックの発生が認められないものの、味の濃さ、香り、甘味、香ばしさが不足し、嗜好性(総合的なおいしさ)に不足感があった。なお、参照例の飲料は、焙煎発芽大麦を配合せず、穀物の配合量を多くしてスターチの含有量を増大させているが、フロックの発生が認められなかった。このことから、これまで、焙煎発芽大麦の抽出液を含有させると、スターチの含有量が多くなりフロックが発生すると考えられていたが、スターチの含有量がフロックの発生の直接の要因ではないことが確認できた。
[result]
As shown in Tables 2 and 3, since the beverage of Comparative Example 1 does not contain the extract of roasted and germinated barley, occurrence of flock is not recognized, but the taste intensity, smell, sweetness, There was a lack of flavor and there was a sense of lack of preference (overall taste). In addition, although the drink of the reference example is not mix | blending roasted germinated barley, the compounding quantity of grains is increased and the content of starch is increased, but generation | occurrence | production of a floc was not recognized. From this fact, it was thought that when the extract of roasted and germinated barley was contained, the starch content increased and flocking occurred until now, but the starch content is not a direct factor of flocking occurrence That was confirmed.
 これに対し、ラフィノースの含有量が1.5~9.5ppmであり、EBCが10以上、濁度(A720)が0.04以下である実施例1~5の飲料は、焙煎発芽大麦を含む穀物の抽出物を含有することにより、味の濃さ、香り、甘味、香ばしさが増大し、嗜好性(総合的なおいしさ)が増大しながらも、フロックの発生が抑制されていることがわかる。特に、フルクトースの含有量が2~15ppm、グルコースの含有量が4~30ppm、スクロースの含有量が3~17ppm、及びマルトースの含有量が5~40ppmである実施例1~3の飲料は、フロックの発生がより確実に抑制されていることがわかる。一方、ラフィノースの含有量が過大であり、濁度(A720)が過大である比較例2の飲料は、フロックの発生が目立った。 On the other hand, the beverages of Examples 1 to 5 having a raffinose content of 1.5 to 9.5 ppm, an EBC of 10 or more, and a turbidity (A720) of 0.04 or less were roasted and germinated barley. Containing the extract of cereals contained, the taste intensity, smell, sweetness, flavor is increased, while the taste (total taste) is increased, while the occurrence of floc is suppressed I understand. In particular, the beverages of Examples 1 to 3 in which the fructose content is 2 to 15 ppm, the glucose content is 4 to 30 ppm, the sucrose content is 3 to 17 ppm, and the maltose content is 5 to 40 ppm are It can be seen that the occurrence of is more reliably suppressed. On the other hand, in the beverage of Comparative Example 2 in which the content of raffinose was excessive and the turbidity (A720) was excessive, the occurrence of floc was noticeable.

Claims (7)

  1.  焙煎発芽大麦を含む穀物の抽出物を含有する容器詰穀物茶飲料であって、
     ラフィノースの含有量が1.5~9.5ppmであり、
     EBCが10以上、濁度(A720)が0.04以下である飲料。
    A containerized cereal tea beverage comprising an extract of cereal grains including roasted and germinated barley,
    Raffinose content is 1.5 to 9.5 ppm,
    A beverage having an EBC of 10 or more and a turbidity (A720) of 0.04 or less.
  2.  濁度(A720)が0.035以下である請求項1記載の飲料。 The beverage according to claim 1, wherein the turbidity (A720) is 0.035 or less.
  3.  含有量が、
     フルクトース2~15ppm、
     グルコース4~30ppm、
     スクロース3~17ppm、又は
     マルトース5~40ppmである請求項1又は2記載の飲料。
    The content is
    Fructose 2 to 15 ppm,
    4 to 30 ppm of glucose
    The beverage according to claim 1 or 2, which contains 3 to 17 ppm sucrose or 5 to 40 ppm maltose.
  4.  フルクトース、グルコース、スクロース、マルトース、ラフィノース及びスタキオースの6種の糖類の合計含有量が、20~110ppmである請求項1から3いずれか記載の飲料。 The beverage according to any one of claims 1 to 3, wherein the total content of six saccharides of fructose, glucose, sucrose, maltose, raffinose and stachyose is 20 to 110 ppm.
  5.  スターチが、100mg/100mL以上の量で含まれる請求項1から4いずれか記載の飲料。 The beverage according to any one of claims 1 to 4, wherein the starch is contained in an amount of 100 mg / 100 mL or more.
  6.  前記穀物は、さらにハトムギ又は大麦を含む請求項1から5いずれか記載の飲料。 The beverage according to any one of claims 1 to 5, wherein the grain further comprises barley barley or barley.
  7.  発芽処理された焙煎穀物の抽出物を含有する飲料におけるラフィノース含有量及び濁度(A720)を調節することで、前記飲料のフロック発生を抑制する方法。 A method for suppressing the occurrence of floc in the beverage by adjusting the content of raffinose and the turbidity (A720) in the beverage containing the extract of the roasted roasted grain.
PCT/JP2018/025588 2017-08-04 2018-07-05 Beverage and method for suppressing occurrence of floccing in beverage WO2019026536A1 (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007330190A (en) * 2006-06-16 2007-12-27 Asahi Soft Drinks Co Ltd Tea beverage producing method, and tea beverage
WO2008123214A1 (en) * 2007-03-26 2008-10-16 Suntory Holdings Limited Blended tea beverage packed in container
JP2012170375A (en) * 2011-02-18 2012-09-10 Ito En Ltd Packaged barley tea beverage
JP2017000020A (en) * 2015-06-05 2017-01-05 アサヒ飲料株式会社 Packaged tea beverage and method for suppressing floc generation

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007330190A (en) * 2006-06-16 2007-12-27 Asahi Soft Drinks Co Ltd Tea beverage producing method, and tea beverage
WO2008123214A1 (en) * 2007-03-26 2008-10-16 Suntory Holdings Limited Blended tea beverage packed in container
JP2012170375A (en) * 2011-02-18 2012-09-10 Ito En Ltd Packaged barley tea beverage
JP2017000020A (en) * 2015-06-05 2017-01-05 アサヒ飲料株式会社 Packaged tea beverage and method for suppressing floc generation

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