WO2019023058A1 - Traitement de déblais de forage - Google Patents
Traitement de déblais de forage Download PDFInfo
- Publication number
- WO2019023058A1 WO2019023058A1 PCT/US2018/043087 US2018043087W WO2019023058A1 WO 2019023058 A1 WO2019023058 A1 WO 2019023058A1 US 2018043087 W US2018043087 W US 2018043087W WO 2019023058 A1 WO2019023058 A1 WO 2019023058A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- cuttings
- drill cuttings
- drilling fluid
- water soluble
- consolidated material
- Prior art date
Links
- 238000005520 cutting process Methods 0.000 title claims abstract description 139
- 150000003839 salts Chemical class 0.000 claims abstract description 106
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 89
- 238000000034 method Methods 0.000 claims abstract description 75
- 230000008569 process Effects 0.000 claims abstract description 71
- 238000005553 drilling Methods 0.000 claims abstract description 63
- 239000007787 solid Substances 0.000 claims abstract description 52
- 239000012530 fluid Substances 0.000 claims abstract description 44
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 25
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 25
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 15
- 239000003085 diluting agent Substances 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 42
- 229920000642 polymer Polymers 0.000 claims description 32
- 239000004576 sand Substances 0.000 claims description 12
- 230000003301 hydrolyzing effect Effects 0.000 claims description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 9
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical group [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 8
- 239000011362 coarse particle Substances 0.000 claims description 7
- 150000001768 cations Chemical class 0.000 claims description 6
- 229920002401 polyacrylamide Polymers 0.000 claims description 5
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 4
- 239000001099 ammonium carbonate Substances 0.000 claims description 4
- 235000019270 ammonium chloride Nutrition 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 3
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims description 3
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 3
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 3
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 3
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 claims description 2
- 239000004254 Ammonium phosphate Substances 0.000 claims description 2
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims description 2
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 claims description 2
- 235000012501 ammonium carbonate Nutrition 0.000 claims description 2
- 235000019289 ammonium phosphates Nutrition 0.000 claims description 2
- 238000004064 recycling Methods 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 abstract description 13
- 238000002156 mixing Methods 0.000 abstract description 7
- 239000003921 oil Substances 0.000 description 39
- -1 e.g. Substances 0.000 description 19
- 239000002245 particle Substances 0.000 description 15
- 239000000243 solution Substances 0.000 description 13
- 230000015572 biosynthetic process Effects 0.000 description 12
- 238000005755 formation reaction Methods 0.000 description 12
- 238000004220 aggregation Methods 0.000 description 7
- 230000002776 aggregation Effects 0.000 description 7
- 239000012267 brine Substances 0.000 description 6
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 5
- 238000001914 filtration Methods 0.000 description 5
- 230000003311 flocculating effect Effects 0.000 description 5
- 230000005484 gravity Effects 0.000 description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 description 5
- 235000010755 mineral Nutrition 0.000 description 5
- 239000011707 mineral Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000013535 sea water Substances 0.000 description 5
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 238000007596 consolidation process Methods 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 4
- 239000007791 liquid phase Substances 0.000 description 4
- 239000000314 lubricant Substances 0.000 description 4
- 239000012266 salt solution Substances 0.000 description 4
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- 238000005189 flocculation Methods 0.000 description 3
- 230000016615 flocculation Effects 0.000 description 3
- 150000004676 glycans Chemical class 0.000 description 3
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 description 3
- 229910000360 iron(III) sulfate Inorganic materials 0.000 description 3
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 229920001282 polysaccharide Polymers 0.000 description 3
- 239000005017 polysaccharide Substances 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 229920003169 water-soluble polymer Polymers 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 238000005119 centrifugation Methods 0.000 description 2
- 239000000701 coagulant Substances 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- 230000015271 coagulation Effects 0.000 description 2
- 238000010924 continuous production Methods 0.000 description 2
- 238000011043 electrofiltration Methods 0.000 description 2
- 239000003337 fertilizer Substances 0.000 description 2
- 239000008394 flocculating agent Substances 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- WMFOQBRAJBCJND-UHFFFAOYSA-M lithium hydroxide Inorganic materials [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 2
- 229910000000 metal hydroxide Inorganic materials 0.000 description 2
- 150000004692 metal hydroxides Chemical class 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000003209 petroleum derivative Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 229920000768 polyamine Polymers 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K potassium phosphate Substances [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000005067 remediation Methods 0.000 description 2
- 239000011435 rock Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 1
- WWILHZQYNPQALT-UHFFFAOYSA-N 2-methyl-2-morpholin-4-ylpropanal Chemical compound O=CC(C)(C)N1CCOCC1 WWILHZQYNPQALT-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 1
- 239000005695 Ammonium acetate Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical class [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical class [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 235000019257 ammonium acetate Nutrition 0.000 description 1
- 229940043376 ammonium acetate Drugs 0.000 description 1
- BIGPRXCJEDHCLP-UHFFFAOYSA-N ammonium bisulfate Chemical compound [NH4+].OS([O-])(=O)=O BIGPRXCJEDHCLP-UHFFFAOYSA-N 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- WGEFECGEFUFIQW-UHFFFAOYSA-L calcium dibromide Chemical compound [Ca+2].[Br-].[Br-] WGEFECGEFUFIQW-UHFFFAOYSA-L 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 239000013256 coordination polymer Substances 0.000 description 1
- 238000009295 crossflow filtration Methods 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 230000001687 destabilization Effects 0.000 description 1
- 230000000368 destabilizing effect Effects 0.000 description 1
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- OTCKOJUMXQWKQG-UHFFFAOYSA-L magnesium bromide Chemical compound [Mg+2].[Br-].[Br-] OTCKOJUMXQWKQG-UHFFFAOYSA-L 0.000 description 1
- 229910001623 magnesium bromide Inorganic materials 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 235000011009 potassium phosphates Nutrition 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical class [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 1
- 229910052683 pyrite Inorganic materials 0.000 description 1
- 239000011028 pyrite Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000001223 reverse osmosis Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 235000011008 sodium phosphates Nutrition 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000002364 soil amendment Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000002207 thermal evaporation Methods 0.000 description 1
- FZGFBJMPSHGTRQ-UHFFFAOYSA-M trimethyl(2-prop-2-enoyloxyethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCOC(=O)C=C FZGFBJMPSHGTRQ-UHFFFAOYSA-M 0.000 description 1
- RRHXZLALVWBDKH-UHFFFAOYSA-M trimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)OCC[N+](C)(C)C RRHXZLALVWBDKH-UHFFFAOYSA-M 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B21/00—Methods or apparatus for flushing boreholes, e.g. by use of exhaust air from motor
- E21B21/06—Arrangements for treating drilling fluids outside the borehole
- E21B21/068—Arrangements for treating drilling fluids outside the borehole using chemical treatment
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B21/00—Methods or apparatus for flushing boreholes, e.g. by use of exhaust air from motor
- E21B21/06—Arrangements for treating drilling fluids outside the borehole
- E21B21/063—Arrangements for treating drilling fluids outside the borehole by separating components
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B21/00—Methods or apparatus for flushing boreholes, e.g. by use of exhaust air from motor
- E21B21/06—Arrangements for treating drilling fluids outside the borehole
- E21B21/063—Arrangements for treating drilling fluids outside the borehole by separating components
- E21B21/065—Separating solids from drilling fluids
- E21B21/066—Separating solids from drilling fluids with further treatment of the solids, e.g. for disposal
Definitions
- the present disclosure relates to dewatering and consolidation of drill cuttings, which are a by-product of drilling subterraneous formations for the recovery of hydrocarbons therefrom. Hydrocarbons that may be present in the drill cuttings can also be separated and recovered.
- Drilling into these formations usually involves the use of drilling fluids, also referred to as drilling muds.
- drilling muds can be oil based or water based and serve to provide hydrostatic pressure, cool the drill bit and flush out drill cuttings.
- Drill cuttings are the rock, soil, sand, shale or other minerals bought to the surface during drilling.
- Oil based muds can withstand greater heat than water based muds and are based on petroleum products such as diesel. There are also synthetic muds, which use synthetic oils that are environmentally safer (although these are also usually based on petroleum products). Oil based muds are an invert-emulsion system, with oil or synthetic oil forming the continuous phase and water or brine as the internal phase. Chemical agents are used to stabilize the emulsion, making subsequent recover ⁇ ' of the oil difficult. Oil and synthetic based muds are preferred when drilling into shale formations, because they do not swell clays, which would lead to shale instability.
- Advantages of the present disclosure include processes to treat drill cuttings, which include solids and drilling fluid, to consolidate the drill cuttings to produce high solids content materials.
- the drill cuttings can include an oil-based drilling fluid or a water-based drilling fluid. Additional advantageous can include separating the drilling fluid from the drill cuttings.
- the process comprises treating the drill cuttings, which includes solids, some or all of which can be sized as fines, and drill fluid.
- the process can include treating the drill cuttings with the at least one highly water soluble salt or solution thereof to form a treated drill cuttings.
- the process can further include treating the drill cuttings with either or both of at least one polymer flocculant or solution thereof and/or coarse particles, e.g., sand, to form a treated cuttings.
- the treated cuttings can include a consolidated material in the drilling fluid. The drilling fluid then be advantageously separated from the consolidated material.
- drill cuttings that include hydrocarbon, such as from an oil based drilling fluid, including hydrocarbon lubricants, synthetic oils, petroleum oils or lubricants such as diesel, or oil or hydrocarbons from the subterranean formation made with the drilling mud, or combinations thereof, can be separated and recovered.
- the process can further comprise treating the drill cuttings with a diluent to dilute hydrocarbons therein and recovering the diluted hydrocarbon.
- the hydrocarbon directly separated from the drill cuttings can contain a low amount of fines or has low minerals content, e.g., less than about 1 wt% or no more than about 0.5 wt% or no more than about 0.1 wt%.
- Implementations of the process of the present disclosure include, for example, (i) treating the drill cuttings with at least one highly water soluble salt to form a treated cuttings including a consolidated material in the drilling fluid, (ii) treating the drill cuttings with at least one highly water soluble salt and at least one polymer flocculant to form a treated cuttings including a consolidated material in the drilling fluid, (iii) treating the drill cuttings with at least one highly water soluble salt thereof, and coarse particles to form a treated cuttings including a consolidated material in the drilling fluid, and (iv) treating the drill cuttings with at least one highly water soluble salt, at least one polymer flocculant and coarse particles to form a treated cuttings including a consolidated material in the drilling fluid.
- Each of these implementations can include aqueous solutions of the salt and/or polymer flocculant to treat the cuttings and each of these implementations can include separating the aqueous solution from the treated cuttings. Each of these implementations can also include separating the drilling fluid from the consolidated material. [0012] In practicing aspects of the processes of the present disclosure and the various embodiments thereof, the process includes treating the drill cuttings with one or more aqueous solutions of the sait(s) and/or polymer flocculant(s).
- the process can further comprise one or more of: (i) recovering at least a portion of the separated aqueous solution including the salt(s) and/or polymer floccuiant(s); (ii) recycling at least a portion of recovered, separated aqueous solution to treat additional drill cuttings; (iii) purifying at least a portion of recovered aqueous solution and/or (iv) concentrating the at least one highly water soluble salt in recovered aqueous solution to form a brine and using the brine to treat additional drill cuttings.
- concentration can be carried out by reverse osmosis, for example.
- Yet another aspect of the present disclosure includes recovering the consolidated materials from the drill cuttings,
- the at least one highly water soluble salt can have a solubility in water (a salt/water solubility) of at least about 5 g/100 g at 20 °C, e.g., at least about 10 g/ 100 g at 20 °C.
- the at least one highly water soluble salt is a non- hydrolyzing salt.
- the at least one highly water soluble salt can have a monovalent cation and can include an ammonium based salt, a phosphate based salt, or a sulfate based salt.
- treating drill cuttings include using a solution of one or more highly soluble salts sourced from a natural or existing source such as seawater or a body of hypersaiine water.
- the at least one polymer flocculant is a polyacryl amide or co-polymer thereof.
- the cuttings also can be treated with coarse particles, e.g., sand.
- treating the drill cuttings can be carried out at ambient temperature, e.g., no more than about 2 °C to about 5 °C above ambient.
- treating the aqueous coal waste composition can be carried out at a temperature of no more than about 50 °C, e.g., no more than about 40 °C or 30 °C.
- the drilling fluid can be separated from the consolidated material by any one or more of decanting, filtering, vacuuming, gravity draining, etc. or combinations thereof.
- separating the drilling fluid from the consolidated material can include mechanically dewatering the consolidated material, e.g.. mechanically dewatering the consolidated material by a dewatering screw. Once separated, the consolidated material can be transferred for further dewatering or disposal.
- drill cuttings are a waste by-product of drilling subterraneous formations for the purpose of recovering hydrocarbons from such formations.
- the drill cuttings typically contain drilling fluid, which can be either water or oil-based, and various solid particles such as rocks, soil, shale, mineral matter, clays, fines, etc.
- the drill cuttings can contain up to 5, wt%, 10 wt%, 15 wt%, 30 wt%, 50 wt% or more of solids, e.g., between about 10 wt% to about 50 wt% solids.
- the solid particles are contaminated with oil from the drilling fluid which are oil- based and any oil in the formation being drilled.
- the proportion of solids and oil in the cuttings varies with the formation being drilled, the operator and the nature of the drilling mud being used.
- the drill cuttings also typically include a certain amount of water apart from the drilling fluid.
- the process of the present disclosure can consolidate the solids of the cuttings to produce solids content initially in excess of about 50% by weight, e.g., solids content of greater than about 60 wt% or 70 wt%, or higher.
- treating the drill cuttings can separate hydrocarbons associated with the drill cuttings.
- hydrocarbons include hydrocarbons from an oil based drilling fluid such as hydrocarbon lubricants, synthetic oils, petroleum oils or lubricants such as diesel, hydrocarbons from the subteiranean formation as a result of the drilling operation with the drilling mud, or combinations thereof.
- the hydrocarbon directly separated from the drill cuttings can contain a low amount of fines or has low minerals content, e.g., less than about 1 wt% or no more than about 0.5 wt% or no more than about 0.1 wt%.
- the solids of drill cuttings are classified herein according to particle sizes.
- the term fines as used herein is consistent with the Canadian oil sands classification system and means solid particles with sizes equal to or less than 44 microns ( ⁇ ). Sand is considered solid particles with sizes greater than 44 ⁇ .
- the cuttings from oils sands extraction can also include a significant amount of fines by weight (>5 wt%) as their solids content.
- coagulation and flocculation are often used interchangeably in the literature.
- coagulation means particle aggregation brought about by the addition of hydrolyzing salts
- flocculation means particle aggregation induced by flocculating polymers.
- Hydrolyzing salts undergo hydrolysis when added to water to form metal hydroxides, which precipitate from the solution, trapping fines and other minerals in the coagulating mass, Hydrolyzing salts typically have low solubility in water and are used as coagulants.
- Aggregation induced by flocculation is believed to be the result of the polymer binding to the particles thereby tying the particles together into a so called floe causing aggregation of the particles.
- drill cuttings e.g., a composition of solids and drilling fluid, which can include hydrocarbon and water
- drill cuttings can be consolidated by treating the drill cuttings with one or more highly water soluble sait(s) or an aqueous solution thereof to destabilize and consolidate solids in the cuttings, e.g., to destabilize and consolidate fines in the cuttings.
- Aggregation induced by the addition of salts is believed to be the result of destabilizing the particles suspended in the fluid by an alteration or a shielding of the surface electrical charge of the particles to reduce the inter-particle repulsive forces that prevent aggregation.
- the drilling fluid can then be separated from the consolidated material.
- the consolidated material has a solids content of at least 45% by weight, e.g., a soli ds content of greater than about 50% by weight.
- Salts that are useful in practicing the present disclosure include salts that are highly soluble in water, A highly water soluble salt as used herein is one that has a solubility in water of greater than 2 g of salt per 100 g of water (i.e., a salt/water solubility of 2g/100g) at 20 °C.
- the highly water soluble salt has a water solubility of at least about 5 g/100 g at 20 °C, e.g., at least about 10 g/100 g of salt/water at 20 °C.
- the highly water soluble salts used in the processes of the present disclosure are preferably non-hydrolyzing.
- Hydrolyzing salts undergo hydrolysis when added to water to form metal hydroxides, which precipitate from the solution. Such hydrolyzing salts are believed to form open floes with inferior solids content and cannot be readily recycled for use with additional cuttings in continuous or semi-continuous processes.
- hydrolyzing salts typically have low solubility in water and are used at elevated temperatures to ensure sufficient solubility for aggregation, which is an energy intensive process. See US 4,225,433 which discloses the use of lime as a coagulating agent at a temperature of 75 °C.
- the highly water soluble salts are preferably not carboxylate salts since such organic acid salts tend to be more expensive than inorganic salts and can be deleterious to plant and/or animal life.
- Highly water soluble salts that are not hydrolyzing and useful in practicing processes of the present disclosure include salts having a monovalent cation, e.g., alkali halide salts such as sodium chloride, potassium chloride; also salts with monovalent cations such as sodium nitrate, potassium nitrate, sodium and potassium phosphates, sodium and potassium sulfates, etc. are useful in practicing processes of the present disclosure.
- alkali halide salts such as sodium chloride, potassium chloride
- salts with monovalent cations such as sodium nitrate, potassium nitrate, sodium and potassium phosphates, sodium and potassium sulfates, etc. are useful in practicing processes of the present disclosure.
- ammonium based salts such as ammonium acetate (NH 4 C 2 H 3 0 2 ), ammonium chloride (NH 4 C1), ammonium bromide (NH 4 .Br), ammonium carbonate ((NFL ⁇ COs), ammonium bicarbonate (NH 4 HCQ 3 ), ammonium nitrate (NH 4 NO 3 ), ammonium sulfate ( ⁇ M i. .
- Ammonium based salts are useful for practicing the present disclosure since residual ammonium based salts on the consolidated material after combining the salt with the drill cuttings are not harmful to plant life.
- many of the ammonium based salts are useful as fertilizers and are in fact beneficial to plant life, e.g., ammonium chloride, ammonium nitrate, ammonium sulfate, etc.
- Many of the monovalent sulfate and phosphate salts are also useful as fertilizers.
- the highly water soluble salt or salts used in the processes of the present disclosure can preferably be non-toxic and beneficial to plant life to aid in environmental remediation and the restoration of mine sites.
- treating drill cuttings with a highly water soluble salt destabilizes and consolidates solids in the cuttings.
- Such a process can include mixing the drill cuttings, which includes solids, some or all of which are sized as fines, and drilling fluid, with a highly water soluble salt to consolidate the solids, and separating the drilling fluid from the consolidated fines to produce a high solids content, e.g., at least 45% by weight.
- the highly water soluble salt is an ammonium based salt.
- Highly water soluble salts that can be used in practicing the present process can also include salts having multivalent cations.
- Such salts include, for example, divalent cation salts such as calcium and magnesium cation salts, such as calcium chloride (CaCl 2 ), calcium bromide (CaBr 2 ), calcium nitrate (CaiNO:);).
- the highly water soluble salts used in the processes of the present disclosure are preferably non-hydroiyzing. Many of the multivalent cation salts are hydrolyzing and thus less preferred for the reasons stated above. Moreover, experimentation with multivalent salts showed increased fouling of containers and formation of less cohesive consolidated materials as compared to highly water soluble salts having monovalent cations.
- some multivalent salts such as FeCl 3 and Fe 2 (S0 4 ) 3 , are particularly corrosive and Fe 2 (S0 4 ) is formed from oxidizing pyrite and results in acid mine runoff, which make such salts less preferable for use in processes of the present disclosure.
- the highly water soluble salt(s) can be used to treat drill cuttings as a solid, e.g., combining the salt as a solid in the form of a powder with the cuttings.
- the salt can be used to treat drill cuttings as a solution, e.g., combining an aqueous salt solution with the cuttings.
- an aqueous solution of the highly water soluble salt can be used having a concentration of no less than about 1 wt%, e.g., greater than about 2 wt%, 3 wt%, 5 wt%, 7 wt%, 10 wt%, 20 wt%, 30 wt% and even as great as a 40 wt% or as an aqueous salt slurry.
- a natural source of a highly soluble salt or salts such as in a natural body of water including such salts in sufficiently high concentration such as at least about 2 wt% and even at least about 3 wt% or greater.
- ocean or seawater can be used as a source of highly soluble salts, which can significantly improve the economics of the process under certain conditions.
- the vast majority of seawater has a salinity of between 31 g/kg and 38 g/kg, that is, 3, 1 -3.8%.
- seawater in the world's oceans has a salinity of about 3.5% (35 g/L, 599 mM).
- Seawater includes a mixture of salts, containing not only sodium cations and chlorine anions (together totaling about 85% of the dissolved salts present), but also sulfate anions and calcium, potassium and magnesium cations. There are other ions present (such as bicarbonate), but these are the main components.
- Another natural source of highly soluble salts that can be used as a source of highly soluble salts includes a hypersaline body of water, e.g., a hypersaline lake, pond, or reservoir.
- a hypersaline body of water is a body of water that has a high concentration of sodium chloride and other highly soluble salts with saline levels surpassing ocean water, e.g., greater than 3.8 wt% and typically greater than about 10 wt%.
- Such hypersaline bodies of water are located on the surface of the earth and also subsurface, which can be brought to the surface as a result of mining operations.
- the drill cuttings and aqueous salt solution or slurry should be mixed at a ratio suffi cient to destabilize the cuttings and/or cause consolidation of the solids therein,
- the liquid phase e.g., drill fluid together with liquid hydrocarbon and/or water from the drilling operation, etc.
- the consolidated solids can be separated from the liquid phase by gravity, such as in a settling tank, or more or less immediately such as by thermal or evaporative technics, or by physical technics, such as by centrifugation, filtration, electro-filtration, cross-flow filtration, dewatering screws and screens, etc. Once separated, the consolidated material can be transferred for further dewatering or disposal.
- the process of the present disclosure allows for large-scale treatment of drill cuttings in a continuous or semi-continuous process.
- the liquid phase separated from an initial cuttings treatment can advantageously include the highly water soluble salt, water or brine from the drilling mud, and oil from the mud or formation being drilled.
- the water or brine in oil emulsions in the original drilling mud are destabilized by the highly water soluble salt and the oil can be separated from the aqueous salt phase using techniques known to the art, such as settling tanks, stack centrifuges, etc. Brine solutions can be recycled for use in formulating drilling muds.
- mixing the drill cuttings with the highly water soluble salt comprises in-line mixing, where a stream of the highly water soluble salt is fed into a stream of drill cuttings.
- consolidating drill cuttings is implemented by mixing the cuttings with a highly water soluble salt and a water- soluble polymer flocculant to form a consolidated material.
- the consolidated material and the liquid phase can be separated from each other by gravity such as sedimentation or more or less immediately such as by physical technics, such as by centrifugation, filtration, electro-filtration, dewatering screws and screens, etc.
- the separated consolidated material then can be disposed or deposited in a containment stmcture which allows removal of released water from the consolidated material.
- Polymers that are useful in practicing the present disclosure include water soluble flocculating polymers such as a nomomc polyacrylamide, an anionic polyacryl amide (APAM) such as a polyacrylamide-co-acrylic acid, and a cationic polyacrylamide (CP AM), which can contain co-monomers such as acryloxyethyltrimethyl ammonium chloride. methacryloxyethyltrimethyl ammonium chloride, dimethyldiallyammonium chloride (DMDAAC), etc.
- APAM anionic polyacryl amide
- CP AM cationic polyacrylamide
- water soluble flocculating polymers useful for practicing the present disclosure include a polyamine, such as a polyamine or quaternized form thereof, e.g., polyacrylamide-co-dimethylaminoethylacrylate in quaternized form, a polyethyleneimine, a polydialiyldimethyl ammonium chloride, a polydicyandiamide, or their copolymers, a polyamide-co-amine, polyelectrolytes such as a sulfonated polystyrenes can also be used.
- Other water soluble polymers such as polyethylene oxide and its copolymers can also be used.
- the polymer flocculants can be synthesized in the form of a variety of molecular weights (MW), electric charge types and charge density to suit specific requirements.
- the flocculating polymer used in practicing processes of the present disclosure do not include use of activated polysaccharides or activated starches, i.e., polysaccharides and starches that have been heat treated, in sufficient amounts to lower the density of the floe to below the density of the process water from which they are separated.
- Such activated polysaccharides and activated starches when used in sufficiently high dosages tend to form low density floes which rise to the surface of an aqueous composition complicating removal of hydrocarbon and can hinder removal of solids in large scale operations involving high solids content and can also hinder dewatering of consolidated material.
- the amount of polymer(s) used to treat cuttings should preferably be sufficient to flocculate the solids in the cuttings and any added sand.
- the amount of polymer(s) used to treat cuttings can be characterized as a concentration based on the total weight of the cuttings or as a dosage based on the weight percent of the solids in the cuttings.
- the concentration of the one or more polymer floeculant(s) in the treated cuttings has dosage (weight of the flocculant(s) to weight of the solids in the cuttings) of no less than zero and up to about 0,005 wt%, e.g., up to about 0.01 wt% and in some implementations, up to about 0.015 wt%, 0.020 wt%, 0.025 wt%, 0.03 wt%, or 0.04 wt%.
- the processes of the present disclosure can also include treating drill cuttings with coarse particles, e.g., particles with sizes greater than 44 ⁇ , such as sand, to increase the solids content. 1 ⁇
- Treating drill cuttings with at least one highly water soluble salt and optionally with either or both of at least one polymer flocculant and/or sand can be carried out in a number of ways.
- treating the drill cuttings includes combining and/or mixing the various components.
- the at least one salt can be added directly to the cuttings either as an undiluted powder or as a solution;
- the at least one polymer flocculant can be added directly to the cuttings either as an undiluted material or as a solution, and the sand can be added to the cuttings directly or with the salt and/or polymer or solutions thereof.
- the salt and polymer can be combined in a single solution, with or without sand, and combined with the cuttings.
- the order of combining the salt, polymer and sand to the cuttings can give equivalent results and optimization of the process will depend on the scale and equipment used in the process.
- an aqueous solution of one or more highly water soluble salt(s) can be used in the processes of the present disclosure having a concentration of no less than about 0.5 wt% or 1 wt%, e.g., at least about 2 wt%, 3 wt%, 4 wt%, 5 wt , 6 wt%, 7 wt%, 10 wt%, 20 wt%, 30 wt% and even as great as a 40 wt% or as an aqueous salt slurry for use in treating the cuttings.
- the one or more polymer fiocculant(s) can also be included in the aqueous solution of the salt(s) and can have a concentration of up to about 0.001 wt%, e.g., up to about 0.003 wt%, 0.005 wt%, 0.01 wt%, 0.04 wt%, 0.05 wt %, 0.1 wt3 ⁇ 4, 0.2 wt3 ⁇ 4, 0.4 wt%, for example,
- treating the drill cuttings need not be elevated above ambient temperature to practice the process.
- treating the drill cuttings can be carried out at ambient temperature, e.g., no more than about 2 °C to about 5 °C above ambient.
- treating drill cuttings can be carried out at a temperature of no more than about 50 °C, e.g., no more than about 40 °C or 30 °C.
- the processes of the present disclosure can be practiced without addition of a significant amount of an alkali metal hydroxide salt(s), such as lithium, sodium or potassium hydroxide, e.g., less than 0.05 wt% or without any addition of such salts.
- an alkali metal hydroxide salt(s) such as lithium, sodium or potassium hydroxide, e.g., less than 0.05 wt% or without any addition of such salts.
- Such strongly alkali salts tend to require elevated temperatures to be effective.
- solids in drill cuttings can be consolidated by treating the drill cuttings with at least one highly water soluble salt or aqueous solutions thereof which can optionally include at least one polymer flocculant. Treating cuttings in this manner can cause destabilization and consolidation of the solids to form a consolidated material, which can settle under gravity relatively quickly in the drilling fluid. The drilling fluid can then be readily separated from the consolidated material.
- the treated cuttings and/or consolidated material can be further dewatered to further separate the water from the consolidated material and, in some instances, further consolidate the solids.
- the consolidated material formed in the treated cuttings can be separated from the drilling fluid by any one or more of decanting, filtering, e.g., eleetrofiltering, cross-flow filtering, gravity draining, vacuuming and other evaporating techniques, etc.
- a mechanical dewatering i .e., applying an external force to the consolidated material
- a device for dewatering consolidated material such as by applying a centrifuge, decanting centrifuge, dewatering screw, hydrocyclone, filter press, pressing device, etc. or combinations thereof.
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Abstract
Processus de traitement de déblais de forage qui comprennent des solides et un fluide de forage pour consolider les solides et/ou séparer le fluide de forage et/ou des hydrocarbures. Les processus consistent à mélanger des déblais de forage avec un sel hautement soluble dans l'eau ou une solution aqueuse de celui-ci pour déstabiliser et consolider les solides dans les déblais. Le processus peut également consister à traiter les déblais de forage avec un diluant pour séparer et récupérer les hydrocarbures associés aux déblais de forage.
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US20100186767A1 (en) * | 2007-08-01 | 2010-07-29 | Seimtec Limited | Method for removing oil from oil-contaminated material |
CN102030435A (zh) * | 2009-09-30 | 2011-04-27 | 北京中科国益环保工程有限公司 | 一种油田钻井废水处理方法 |
CN105084614A (zh) * | 2015-08-12 | 2015-11-25 | 中国石油化工股份有限公司 | 一种钻井废液处理方法 |
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US20100186767A1 (en) * | 2007-08-01 | 2010-07-29 | Seimtec Limited | Method for removing oil from oil-contaminated material |
CN101318748A (zh) * | 2008-07-15 | 2008-12-10 | 濮阳市天地人环保工程技术有限公司 | 一种用于油气田钻采废液集中处理的工艺技术 |
CN102030435A (zh) * | 2009-09-30 | 2011-04-27 | 北京中科国益环保工程有限公司 | 一种油田钻井废水处理方法 |
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