WO2019012176A1 - Appareil d'arrosage - Google Patents

Appareil d'arrosage Download PDF

Info

Publication number
WO2019012176A1
WO2019012176A1 PCT/FI2017/050533 FI2017050533W WO2019012176A1 WO 2019012176 A1 WO2019012176 A1 WO 2019012176A1 FI 2017050533 W FI2017050533 W FI 2017050533W WO 2019012176 A1 WO2019012176 A1 WO 2019012176A1
Authority
WO
WIPO (PCT)
Prior art keywords
flow space
straight duct
sparger
duct flow
wing elements
Prior art date
Application number
PCT/FI2017/050533
Other languages
English (en)
Inventor
Janne Kauppi
Original Assignee
Outotec (Finland) Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Outotec (Finland) Oy filed Critical Outotec (Finland) Oy
Priority to PCT/FI2017/050533 priority Critical patent/WO2019012176A1/fr
Priority to EP18740263.1A priority patent/EP3651890A1/fr
Priority to CA3069101A priority patent/CA3069101A1/fr
Priority to PCT/FI2018/050482 priority patent/WO2019012179A1/fr
Priority to EA202090156A priority patent/EA039537B1/ru
Priority to BR112020000206-2A priority patent/BR112020000206B1/pt
Priority to PE2020000041A priority patent/PE20200371A1/es
Publication of WO2019012176A1 publication Critical patent/WO2019012176A1/fr
Priority to CL2020000052A priority patent/CL2020000052A1/es

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/232Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles
    • B01F23/2326Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles adding the flowing main component by suction means, e.g. using an ejector
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/232Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J4/00Feed or outlet devices; Feed or outlet control devices
    • B01J4/001Feed or outlet devices as such, e.g. feeding tubes
    • B01J4/004Sparger-type elements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/30Injector mixers
    • B01F25/31Injector mixers in conduits or tubes through which the main component flows
    • B01F25/313Injector mixers in conduits or tubes through which the main component flows wherein additional components are introduced in the centre of the conduit
    • B01F25/3133Injector mixers in conduits or tubes through which the main component flows wherein additional components are introduced in the centre of the conduit characterised by the specific design of the injector
    • B01F25/31331Perforated, multi-opening, with a plurality of holes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J4/00Feed or outlet devices; Feed or outlet control devices
    • B01J4/001Feed or outlet devices as such, e.g. feeding tubes
    • B01J4/002Nozzle-type elements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J4/00Feed or outlet devices; Feed or outlet control devices
    • B01J4/001Feed or outlet devices as such, e.g. feeding tubes
    • B01J4/005Feed or outlet devices as such, e.g. feeding tubes provided with baffles

Definitions

  • the invention relates to a sparger apparatus as defined in the preamble of independent claim 1.
  • a sparger is used to feed a first fluid such as gas into a second flowing liquid such as into a flowing liquid media. It is known in the prior art to use venture systems, and spargers comprising porous material such as ceramic, sintered or laser cut holing systems.
  • a known problem with spargers is the control of the bubble size of the first fluid that is fed into the second flowing fluid and to control the distribution of the bubbles of the first fluid in the second flowing fluid. Lack of control results in that tiny bubbles of first fluid merge together to create larger bubbles of first fluid or in that large bubbles of first fluid are divided to create smaller bubbles of first fluid that possible merge again.
  • the object of the invention is sparger apparatus that provides for a controlled feed of a first fluid such as gas into a second flowing liquid such as a flowing liquid media.
  • the sparger apparatus is characterized by the definitions of independent claim 1.
  • Figure 1 shows one embodiment of the sparger apparatus
  • Figure 2 shows the sparger apparatus shown in figure 1 in partly cut state
  • Figure 3 shows the sparger apparatus shown in figure 1 in partly cut state
  • Figure 4 shows the sparger apparatus shown in figure 1 as cut along plane B-B in figure 1,
  • Figure 5 shows the sparger apparatus shown in figure 1 as seen from one side
  • Figure 6 shows the sparger apparatus shown in figure 1 as seen from another side
  • Figure 7 shows the sparger apparatus shown in figure 1 as cut along plane A- A in figure 5
  • Figure 8 shows the sparger apparatus shown in figure 1 as seen from the downstream end
  • Figure 9 shows the sparger apparatus shown in figure 1 as seen from yet another side
  • Figure 10 shows the sparger apparatus shown in figure 1 as cut along plane C-C in figure
  • Figure 11 shows the sparger apparatus shown in figure 1 as cut along plane D-D in figure
  • Figure 13 shows a pattern in which the opening of the nozzles can be arranged
  • Figure 14 is a section view of another embodiment of the sparger apparatus.
  • Figure 15 is a section view of still another embodiment of the sparger apparatus.
  • the figures shows examples of a sparger apparatus 1 for feeding a first fluid (not shown in the figures) into a second flowing fluid (not shown in the figures).
  • the first fluid can be gas such as air, oxygen, nitrogen, ozone, or carbon dioxide.
  • the second flowing fluid can be a flowing liquid media such as effluent, industrial process fluid, fresh water, raw water, mine water, process water, water that contains substances that requires biological oxygen demand, water that contains substances that requires chemical oxygen demand, or water that contains substances often called total organic carbons.
  • a flowing liquid media such as effluent, industrial process fluid, fresh water, raw water, mine water, process water, water that contains substances that requires biological oxygen demand, water that contains substances that requires chemical oxygen demand, or water that contains substances often called total organic carbons.
  • the sparger apparatus comprises a hollow tube member 2 defining a straight duct flow space 3 having an upstream inlet end 4 and a downstream outlet end 5.
  • the sparger apparatus comprises nozzles 6 in the straight duct flow space 3.
  • the nozzles 6 are configured to feed first fluid into second flowing fluid that is configured to flow in a direction of flow B in the straight duct flow space 3 from the upstream inlet end 4 to the downstream outlet end 5.
  • the nozzles 6 are provided in a sparger 7 arranged in the straight duct flow space 3.
  • the sparger 7 comprises wing elements 8; 9.
  • the nozzles 6 are provided at the wing elements 8; 9.
  • the wing elements 8;9 can configured to, for a moment, divide the flow of second flowing fluid in the straight duct flow space 3 for example into a laminar flow or into a transitional flow.
  • the openings 10 of the nozzles 6 are distributed at several positions along the direction of flow B so that the openings 10 forms upstream openings and downstream openings and so that each upstream opening is unfollowed by a downstream opening in the direction of flow B.
  • An advantage of the sparger apparatus is that the wing elements 8; 9 will protect the bubbles of first fluid that is fed from the openings 10 of the nozzle 6 into the second flowing fluid.
  • the straight duct flow space 3 does not have to be as long in comparison to the sparger 7 as shown in the figures. It is enough that the straight duct flow space is provided at the nozzles and at a short section downstream of the nozzles.
  • the relative number of openings 10 increases preferably, but not necessarily, in a direction along the direction of flow B towards the middle of the straight duct flow space 3 such as towards a longitudinal central axis A of the straight duct flow space 3.
  • This is advantageous, because the flow rate is higher at the middle of the straight duct flow space, because of the friction between the second flowing fluid and the walls of the straight duct flow space at the walls of the straight duct flow space. Therefore shall more first fluid preferably be fed at the middle of the straight duct flow space than at the walls of the straight duct flow space to achieve an even distribution of first fluid in the second flowing fluid.
  • the straight duct flow space 3 has preferably, but not necessarily, a longitudinal central axis A, and the straight duct flow space 3 is preferably, but not necessarily, symmetrical around the longitudinal central axis A of the straight duct flow space 3.
  • the straight duct flow space 3 has a longitudinal central axis A, and if the straight duct flow space 3 is symmetrical around the longitudinal central axis A of the straight duct flow space 3, the openings 10 of the nozzles 6 are preferably, but not necessarily, arranged symmetrically about the longitudinal central axis A of the straight duct flow space 3. An advantage of this is more even concentration of first fluid in the second flowing fluid.
  • the wing elements 8; 9 are preferably, but not necessarily, arranged symmetrically about the longitudinal central axis A of the straight duct flow space 3.
  • the openings 10 of the nozzles 6 are preferably, but not necessarily, as shown in figure 13, provided in a pattern 14 defined by several rings 15 having the center at the longitudinal central axis A of the straight duct flow space 3, wherein each ring 15 is provided at a location along the longitudinal central axis A of the straight duct flow space 3 that is different from the location of the other rings 15 and wherein each ring 15 has a diameter that is different from the diameter of the other rings 15.
  • the sparger apparatus comprises preferably, but not necessarily, a fluid distribution ring 11 surrounding the straight duct flow space 3, and the wing elements of the sparger 7 comprises preferably, but not necessarily, first wing elements 8 and second wing elements 9, so that the first wing elements 8 are in fluid connection with the fluid distribution ring 11, so that by the second wing elements 9 are in fluid connection with the first wing elements 8, and so that by the nozzles 6 are provided at the second wing elements 9.
  • the sparger apparatus comprises a fluid distribution ring 11 as presented, the sparger apparatus comprises preferably, but not necessarily, a fluid inlet 12 in fluid connection with the fluid distribution ring 11.
  • each first wing element 8 extend preferably, but not necessarily, from the fluid distribution ring 11 to the middle of the straight duct flow space 3 inclined in relation to the direction of flow B, towards the downstream outlet end 5 of the hollow tube member 2.
  • the first wing elements 8 are preferably, but not necessarily, in fluid connection with each other in the middle of the straight duct flow space 3 such as at a longitudinal central axis A of the straight duct flow space 3.
  • Each first wing element 8 extend preferably, but not necessarily, in an angle between 15 and 75, preferably between 30 and 60°, such as about 45°, in relation to the direction of flow B or in relation to a longitudinal central axis A of the straight duct flow space 3.
  • the second wing elements 9 extend preferably, but not necessarily, between adjacent first wing elements 8.
  • the second wing elements 9 extend preferably, but not necessarily, between adjacent first wing elements 8 in an inclined and/or curved configuration towards the downstream outlet end 5 of the straight duct flow space 3 between adjacent first wing elements 8. It is for example possible that the second wing elements 9 are in side profile of arc shape or of pointed gothic arch shape.
  • the second wing elements 9 can form in the direction transverse to the direction of flow B, at least two, preferably three or four circular concentric formations in the straight duct flow space 3 so that arc shaped intermediate flow spaces 13 or intermediate flow spaces having the form of a part of a segment are formed between the first wing elements 8 and second wing elements 8 of the sparger 7.
  • the sparger 7 of the sparger apparatus comprises first wing elements 8 and second wing elements 8 as presented
  • the cross-section of the first wing elements 8 have preferably, but not necessarily, the shape of an ellipse, a droplet or a vesica piscis.
  • the cross-section of the second wing elements 9 have preferably, but not necessarily, the shape of an ellipse, a droplet a vesica piscis, a parallelogram, a kite, an isosceles trapezoid and similar shapes that are irregular.
  • An advantage of this is that the second wing element causes less turbulence in the flow of second lowing fluid.
  • the openings 10 of the nozzles 6 have preferably, but not necessarily, the shape of a convex polygon such as the shape of a quadrilateral, a rhombus or a square.
  • An advantage of this is that the sharp edges of the openings 10 will make the bubbles of first fluid smaller and will facilitate detaching of a bubble of first fluid from the opening 10.
  • the openings 10 of the nozzles 6 have preferably, but not necessarily, an area between 3 ⁇ 2 and 750 ⁇ 2 in order to create bubbles of first fluid of small size.
  • the nozzles 6 extend preferably, but not necessarily, from the wing elements 8; 9, at least partly in a direction transversal to the direction of flow B.
  • An advantage of this is that the nozzles 10 will locally cause turbulence and/or vacuum in the second flowing fluid at the nozzle 10, which facilitates sucking of first fluid from the opening 10 in the nozzle 6 into the second flowing fluid flowing in the direction of flow B in the straight tubular flow space 3.
  • the nozzles 6 extend preferably, but not necessarily, from the second wing elements 9, provided that the wing elements comprises such second wing elements 9, at least partly in a direction transversal to the direction of flow B.
  • the height of the nozzles 6 can for example be between 100 and 500 ⁇ .
  • Figures 1 to 12 shows a sparger apparatus having a hollow tube member 2 having straight duct flow space 3 having the same cross-section form and dimensions between the upstream inlet end 4 and the downstream outlet end 5 of the straight duct flow space 3.
  • the hollow tube member 2 as shown in figure 14, comprises a throat section 16 between the upstream inlet end 4 and the downstream outlet end 5 of the straight duct flow space 3, and that the sparger 7 is arranged in the throat section 16.
  • the diameter of the throat section 16 is preferably, but not necessarily, between 99 and 80 % of the diameter of the straight duct flow space 3 between the upstream inlet end 4 of the straight duct flow space 3 and the throat section 16 and between the downstream outlet end 5 of the straight duct flow space 3 and the throat section 16.
  • Figures 1 to 12 shows a sparger apparatus having a hollow tube member 2 having straight duct flow space 3 having the same cross-section form and dimensions between the upstream inlet end 4 and the downstream outlet end 5 of the straight duct flow space 3. It is however possible that the hollow tube member 2, as shown in figure 15, comprises an enlarged section 17 between the upstream inlet end 4 and the downstream outlet end 5 of the straight duct flow space 3, and that the sparger 7 is arranged in the enlarged section 17.
  • the diameter of the enlarged section 17 is preferably, but not necessarily, between 101 and 120 % of the diameter of the straight duct flow space 3 between the upstream inlet end 4 of the straight duct flow space 3 and the enlarged section 17 and between the downstream outlet end 5 of the straight duct flow space 3 and the enlarged section 17.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Apparatus Associated With Microorganisms And Enzymes (AREA)
  • Nozzles (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Sampling And Sample Adjustment (AREA)
  • Extraction Or Liquid Replacement (AREA)

Abstract

L'invention concerne un appareil d'arrosage (1) pour introduire un premier fluide dans un second fluide en écoulement. L'appareil d'arrosage comprend un élément de tube creux (2) définissant un espace d'écoulement de conduit droit (3) ayant une extrémité d'entrée amont (4) et une extrémité de sortie aval (5), et des buses (6) dans l'espace d'écoulement de conduit droit (3). Les buses (6) sont conçues pour acheminer un premier fluide dans un second fluide d'écoulement configuré pour s'écouler dans une direction d'écoulement B dans l'espace d'écoulement de conduit droit de l'extrémité d'entrée amont (4) à l'extrémité de sortie aval (5). Les ouvertures (10) des buses (6) sont réparties à plusieurs positions le long de la direction d'écoulement B de sorte que les ouvertures (10) forment des ouvertures amont et des ouvertures aval et de sorte que chaque ouverture amont est non suivie d'une ouverture aval dans la direction d'écoulement B.
PCT/FI2017/050533 2017-07-11 2017-07-11 Appareil d'arrosage WO2019012176A1 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
PCT/FI2017/050533 WO2019012176A1 (fr) 2017-07-11 2017-07-11 Appareil d'arrosage
EP18740263.1A EP3651890A1 (fr) 2017-07-11 2018-06-20 Appareil d'arrosage et procédé d'extraction de particules
CA3069101A CA3069101A1 (fr) 2017-07-11 2018-06-20 Appareil d'arrosage et procede d'extraction de particules
PCT/FI2018/050482 WO2019012179A1 (fr) 2017-07-11 2018-06-20 Appareil d'arrosage et procédé d'extraction de particules
EA202090156A EA039537B1 (ru) 2017-07-11 2018-06-20 Барботирующее устройство и способ извлечения частиц
BR112020000206-2A BR112020000206B1 (pt) 2017-07-11 2018-06-20 Aparelho de aspersão e método para extração de partículas
PE2020000041A PE20200371A1 (es) 2017-07-11 2018-06-20 Aparato burbujeador y metodo para la extraccion de particulas
CL2020000052A CL2020000052A1 (es) 2017-07-11 2020-01-08 Aparato burbujeador y método para la extracción de partículas.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/FI2017/050533 WO2019012176A1 (fr) 2017-07-11 2017-07-11 Appareil d'arrosage

Publications (1)

Publication Number Publication Date
WO2019012176A1 true WO2019012176A1 (fr) 2019-01-17

Family

ID=62904504

Family Applications (2)

Application Number Title Priority Date Filing Date
PCT/FI2017/050533 WO2019012176A1 (fr) 2017-07-11 2017-07-11 Appareil d'arrosage
PCT/FI2018/050482 WO2019012179A1 (fr) 2017-07-11 2018-06-20 Appareil d'arrosage et procédé d'extraction de particules

Family Applications After (1)

Application Number Title Priority Date Filing Date
PCT/FI2018/050482 WO2019012179A1 (fr) 2017-07-11 2018-06-20 Appareil d'arrosage et procédé d'extraction de particules

Country Status (6)

Country Link
EP (1) EP3651890A1 (fr)
CA (1) CA3069101A1 (fr)
CL (1) CL2020000052A1 (fr)
EA (1) EA039537B1 (fr)
PE (1) PE20200371A1 (fr)
WO (2) WO2019012176A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11518787B2 (en) 2018-07-11 2022-12-06 The Brigham And Women's Hospital, Inc. Methods and compositions for delivery of agents across the blood-brain barrier
US11981705B2 (en) 2021-01-08 2024-05-14 The Brigham And Women's Hospital, Inc. Methods and compositions for delivery of immunotherapy agents across the blood-brain barrier to treat brain cancer

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4082975A1 (fr) 2021-04-26 2022-11-02 Metso Outotec Finland Oy Oxydation d'espèces soufrées
ES2932676B2 (es) * 2021-07-07 2024-03-20 Acciona Agua S A Procedimiento de generacion de microburbujas

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3734111A (en) * 1971-12-20 1973-05-22 Phillips Petroleum Co Apparatus for in-line mixing of fluids
US5935490A (en) * 1996-07-26 1999-08-10 Boc Gases Australia Limited Oxygen dissolver for pipelines or pipe outlets
US20040000789A1 (en) * 2002-06-27 2004-01-01 Nanya Technology Corporation Piping apparatus
WO2004035187A2 (fr) * 2002-10-15 2004-04-29 Vast Power Systems, Inc. Methode et appareil pour melanger des fluides
US20070253281A1 (en) * 2006-04-17 2007-11-01 Radford Philip T Manifold and system suitable for introducing one or more additives into a fluid stream
WO2011032253A1 (fr) * 2009-09-15 2011-03-24 Suncor Energy Inc. Procédé de séchage de résidus fins mûrs de sables pétrolifères
EP3051113A1 (fr) * 2015-01-29 2016-08-03 Caterpillar Energy Solutions GmbH Mélangeur de gaz pour moteur à combustion interne

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Publication number Priority date Publication date Assignee Title
ES2192505T3 (es) * 2000-06-19 2003-10-16 Balcke Duerr Energietech Gmbh Mezclador para mezclar por lo menos dos corrientes de gas o de otros fluidos newtonianos.
US20070248510A1 (en) * 2006-04-25 2007-10-25 Dean Anne M Dual gas-liquid spargers for catalytic processing units
US9643146B2 (en) * 2013-11-29 2017-05-09 Uop Llc Unit for processing a liquid/gas phase mixture, mercaptan oxidation system including the same, and method of processing a liquid/gas phase mixture
WO2018102284A1 (fr) * 2016-11-30 2018-06-07 Dresser-Rand Company Système de distribution de fluide pour un réservoir de réacteur

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3734111A (en) * 1971-12-20 1973-05-22 Phillips Petroleum Co Apparatus for in-line mixing of fluids
US5935490A (en) * 1996-07-26 1999-08-10 Boc Gases Australia Limited Oxygen dissolver for pipelines or pipe outlets
US20040000789A1 (en) * 2002-06-27 2004-01-01 Nanya Technology Corporation Piping apparatus
WO2004035187A2 (fr) * 2002-10-15 2004-04-29 Vast Power Systems, Inc. Methode et appareil pour melanger des fluides
US20070253281A1 (en) * 2006-04-17 2007-11-01 Radford Philip T Manifold and system suitable for introducing one or more additives into a fluid stream
WO2011032253A1 (fr) * 2009-09-15 2011-03-24 Suncor Energy Inc. Procédé de séchage de résidus fins mûrs de sables pétrolifères
EP3051113A1 (fr) * 2015-01-29 2016-08-03 Caterpillar Energy Solutions GmbH Mélangeur de gaz pour moteur à combustion interne

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11518787B2 (en) 2018-07-11 2022-12-06 The Brigham And Women's Hospital, Inc. Methods and compositions for delivery of agents across the blood-brain barrier
US11981705B2 (en) 2021-01-08 2024-05-14 The Brigham And Women's Hospital, Inc. Methods and compositions for delivery of immunotherapy agents across the blood-brain barrier to treat brain cancer

Also Published As

Publication number Publication date
CA3069101A1 (fr) 2019-01-17
EA202090156A1 (ru) 2020-05-22
EP3651890A1 (fr) 2020-05-20
PE20200371A1 (es) 2020-02-24
BR112020000206A2 (pt) 2020-07-07
CL2020000052A1 (es) 2020-08-07
WO2019012179A1 (fr) 2019-01-17
EA039537B1 (ru) 2022-02-08

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