WO2019004698A1 - Élément décoratif et son procédé de préparation - Google Patents

Élément décoratif et son procédé de préparation Download PDF

Info

Publication number
WO2019004698A1
WO2019004698A1 PCT/KR2018/007225 KR2018007225W WO2019004698A1 WO 2019004698 A1 WO2019004698 A1 WO 2019004698A1 KR 2018007225 W KR2018007225 W KR 2018007225W WO 2019004698 A1 WO2019004698 A1 WO 2019004698A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
light
absorbing layer
light absorbing
decorative member
Prior art date
Application number
PCT/KR2018/007225
Other languages
English (en)
Korean (ko)
Inventor
김용찬
손정우
조필성
김기환
Original Assignee
주식회사 엘지화학
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020170136808A external-priority patent/KR102201549B1/ko
Application filed by 주식회사 엘지화학 filed Critical 주식회사 엘지화학
Priority to JP2019564026A priority Critical patent/JP6884969B2/ja
Priority to US16/615,735 priority patent/US11225045B2/en
Priority to CN201880034790.1A priority patent/CN110678809B/zh
Priority to EP18823948.7A priority patent/EP3647053B1/fr
Publication of WO2019004698A1 publication Critical patent/WO2019004698A1/fr

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/30—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B23/00—Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose
    • B32B23/04—Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose comprising such cellulosic plastic substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B23/08—Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose comprising such cellulosic plastic substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/38—Layered products comprising a layer of synthetic resin comprising epoxy resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/263—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer having non-uniform thickness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K9/00—Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • G02F1/153—Constructional details
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/20—Inorganic coating
    • B32B2255/205—Metallic coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/402—Coloured
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/416—Reflective
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2451/00—Decorative or ornamental articles

Definitions

  • the present invention relates to a decorative member and a manufacturing method thereof. Specifically, the present invention relates to a decorative member suitable for use in a mobile device or an electronic product, and a manufacturing method thereof.
  • Mobile phones, various mobile devices, and home appliances have a major role in designing products, such as color, shape, pattern, etc., of products other than the functions of products, to give value to customers. Depending on the design, the preference and price of the product are also influenced.
  • the conventional deco film color development was attempted through printing, deposition, and the like. If different colors are expressed on a single plane, they must be printed more than twice, and it is difficult to implement them when various colors are to be applied to a three-dimensional pattern.
  • the conventional deco film has a fixed color depending on viewing angles, and even if there is a slight change, it is limited to the degree of color difference.
  • the color developing layer is formed on the opposite side of the light reflecting layer opposite to the light absorbing layer, between the light reflecting layer and the light absorbing layer, or opposite to the light reflecting layer of the light absorbing layer And a color film provided on the opposite side of the surface.
  • the color film when the color film is present, the color film has L * a * a * b * on the chromaticity coordinates CIE L * a * b * of the color developing layer when compared with the case where the color film is not provided the color difference DELTA E * ab, which is the distance in the space of * b *, exceeds 1.
  • a substrate is provided on the opposite surface of the light reflecting layer opposite to the light absorbing layer, or on the opposite surface of the light absorbing layer facing the light reflecting layer.
  • the substrate is provided on the opposite surface of the light reflecting layer opposite to the light absorbing layer, and the color film is provided between the substrate and the light reflecting layer or on the opposite surface of the substrate facing the light reflecting layer .
  • the base material is provided on the opposite surface of the light absorbing layer opposite to the light reflection layer, and the color film is provided on the opposite side of the base material and the light absorbing layer, or on the surface of the base material opposite to the light absorbing layer .
  • the light absorbing layer includes two or more points having different thicknesses.
  • the light absorbing layer includes two or more regions having different thicknesses.
  • the light absorbing layer includes at least one region having an inclined surface whose upper surface has an inclination angle of more than 0 degrees and not more than 90 degrees, and the light absorbing layer has a thickness And at least one region having a thickness different from the thickness.
  • the light absorbing layer includes at least one region whose thickness gradually changes.
  • the light absorbing layer includes at least one region having an inclined surface whose top surface has an inclination angle of more than 0 degrees and not more than 90 degrees, and a region having at least one inclined surface, . ≪ / RTI >
  • the light absorption layer has an extinction coefficient (k) value of more than 0 and 4 or less, preferably 0.01 to 4 at 4000 nm.
  • the decorative member is a household article requiring a decorative film, a case of a mobile device, or an appliance case or color decoration.
  • external light is absorbed in each of the incident path and reflection mirror upon reflection through the color-developing layer, and external light is reflected by the surface of the light-absorbing layer and the surface of the light-
  • a constructive interference and a destructive interference phenomenon occur between the reflected light on the surface of the light absorption layer and the reflected light on the surface of the light reflection layer.
  • a specific color can be expressed through the above-described incidence path and the phenomenon of light absorption, constructive interference, and destructive interference in the reflector path. Therefore, a specific color can be realized according to the reflectance spectrum and the composition of the light absorbing layer depending on the material of the light reflecting layer.
  • the color to be expressed has thickness dependency, the color can be changed according to the thickness even when the same material composition is used.
  • the electrochromic device By providing the electrochromic device on one side of the color developing layer as described above, it is possible to provide an active decorative member, thereby providing a decorative member having an aesthetic point of view different from that of a conventional passive decorative member Can be provided. As a result, various colors can be implemented in decorating members of mobile phones, various mobile devices and home appliances.
  • the width of color that can be realized can be further increased even when the material and thickness of the light reflection layer and the light absorption layer are determined.
  • the color change width due to the addition of the color filter can be defined as a color difference (DELTA E * ab) which is a difference between L * a * b * before and after application of the color filter.
  • the light absorbing layer has two or more points or areas having different thicknesses on the same surface, so that a plurality of hues can be expressed.
  • the light absorbing layer when the upper surface of the light absorbing layer has at least one inclined surface, it is possible to realize a change in color developed according to the viewing angle, and in addition, the light absorbing layer can be manufactured to have two or more regions having different thicknesses by a simple process.
  • FIG. 1 illustrates a laminated structure of decorative members according to an embodiment of the present invention.
  • Fig. 2 is a schematic diagram for explaining the principle of color development in a light reflection layer and a light absorption layer structure.
  • 3 to 6 illustrate a laminated structure of decorative members according to embodiments of the present invention.
  • Figs. 7 to 10 illustrate the top surface structure of the light absorbing layer of the decorative member according to the embodiments of the present application.
  • 11 to 14 illustrate a laminated structure of decorative members according to embodiments of the present invention.
  • Figs. 15 to 17 are diagrams showing that hue appears different depending on the thickness of the light absorbing layer. Fig.
  • FIG 18 illustrates the structure of the cathode side electrochromic layer and the anode side electrochromic layer.
  • FIG. 19 is a photograph showing the color of the decorative member manufactured in the embodiment.
  • Fig. 20 shows a simulation result of colors of the decorative member manufactured in Examples 1 to 3 and Comparative Example 1.
  • Fig. 21 shows a laminated structure including the prism patter structure of the fourth embodiment.
  • FIG. 23 is a diagram showing a method of distinguishing between a light absorbing layer and a light reflecting layer.
  • &quot point " means one position that does not have an area.
  • the above expression is used to indicate that there are two or more points where the thicknesses of the light absorbing layers are different from each other.
  • " region " represents a portion having a certain area.
  • the decorating member is placed on the ground so that the light reflecting layer is on the bottom and the light absorbing layer is on the top, and both ends of the inclined surface or both ends having the same thickness are vertically divided with respect to the ground, Refers to an area divided by both ends, and an area having the same thickness means an area divided by both ends having the same thickness.
  • " face " or " region &quot may be plane, but not limited thereto, all or part may be curved.
  • shape of the vertical cross section may include a structure of a circle, a part of an arc of an ellipse, a wave structure, and a zigzag structure.
  • &quot inclined surface " means a surface having an angle formed by the upper surface with respect to the ground when the decorative member is placed on the ground such that the light reflection layer is on the lower side and the light absorption layer is on the upper side. do.
  • the "thickness" of any layer means the shortest distance from the lower surface to the upper surface of the layer.
  • a decorative member includes a color reproduction layer including a light reflection layer and a light absorption layer provided on the light reflection layer; And an electrochromic device provided on one side of the color developing layer.
  • the resistance or sheet resistance It can be measured using a known surface resistor according to a 4-point probe method.
  • the surface resistance (V / I) is measured by measuring the current (I) and the voltage (V) with four probes and the area (cross-sectional area, W) of the sample and the distance between the electrodes L (V / I x W / L), and multiplied by the resistance correction factor (RCF) to calculate ohm / square as the sheet resistance unit.
  • the resistance correction coefficient can be calculated using the size of the sample, the thickness of the sample, and the temperature at the time of measurement, which can be calculated by the Poisson equation.
  • the sheet resistance of the whole laminate can be measured and calculated in the laminate itself and the sheet resistance of each layer can be measured before forming a layer made of the remaining material excluding the target layer to be measured in the whole laminate, Or after analyzing the material of the target layer and forming a layer on the same condition as the target layer.
  • Electrochemical coloration is a phenomenon in which the optical properties of an electrochromic active material are changed by an electrochemical oxidation or reduction reaction.
  • an external voltage is applied to the electrochromic material, the electrons move or oxidize or reduce the electron, The inherent color and transmission of the material change reversibly.
  • the electrochromic device using such an electrochromic phenomenon includes an anode, a cathode, and an electrolyte layer largely in the same structure as a battery.
  • an electrochromic layer is formed between the anode and the electrolyte or between the cathode and the electrolyte, ions such as H +, Li + or Na + move in the electrolyte when a specific potential is applied,
  • the electron density of the electrochromic material changes and the optical property changes. That is, when electrons and ions are inserted and removed by an electrochemical oxidation-reduction reaction, coloration or discoloration occurs on the surface of the metal oxide.
  • the electrochromic device includes an anode, an anode side electrochromic layer, an electrolyte layer, a cathode side electrochromic layer, and a cathode. They may be laminated in the above order.
  • a substrate may be additionally provided on the opposite surface of the anode that is in contact with the anode-side electrochromic layer or on the surface of the cathode that is in contact with the cathode-side electrochromic layer.
  • the substrate may be made of materials known in the art. Specifically, glass, plastic, or the like can be used as the substrate, but the present invention is not limited thereto.
  • the substrate may be a transparent substrate. In one embodiment, the substrate may have a transmittance of 60% or more in the visible light region. In another embodiment, the substrate may have a transmittance of 80% or more in the visible light region.
  • the substrate may be glass having a transmittance of 80% or more.
  • the thickness of the substrate may be selected as desired, and may range, for example, from 50 to 200 micrometers.
  • the anode and the cathode are not particularly limited as long as they are well known in the art.
  • the anode and the cathode each independently comprise indium doped tin oxide (ITO), antimony doped tin oxide (ATO), fluorine doped tin oxide (FTO), indium doped zinc oxide (IZO) But is not limited thereto.
  • the anode and the cathode may each be a transparent electrode.
  • ITO having a transmittance of 80% or more can be used.
  • the thicknesses of the anode and the cathode are each independently 10 to 500 nm, for example 100 nm.
  • the anode-side electrochromic layer may be a Prussia Blue film.
  • Prussian blue film contains blue MFeFe (CN) 6 or colorless M2FeFe (CN 6 ).
  • M is a monovalent alkali ion such as H + , Li + , Na + , K + . It appears blue when tinted, and colorless when decolorized.
  • the thickness of the anode-side electrochromic layer is 20 nm or more and 700 nm or less, for example, 300-400 nm.
  • the refractive index of the anode side electrochromic layer at a wavelength of 550 nm is 1.8 to 2.9.
  • the production of the electrolyte layer may utilize materials and methods known in the art. Specifically, pentaerythritol triacrylate (PETA) monomer, 1M or more LiClO 4 , polycarbonate (PC), or the like can be used, but is not limited thereto.
  • PETA pentaerythritol triacrylate
  • 1M or more LiClO 4 polycarbonate
  • PC polycarbonate
  • the electrolyte layer may include a lithium salt, a plasticizer, an oligomer, a monomer, an additive, a radical initiator, and the like. Oligomers used in the present invention should be compatible with plasticizers.
  • the electrolyte layer may be formed by, for example, coating an electrolyte solution on a first release film, then attaching a second release film and UV curing the electrolyte film to form an electrolyte film .
  • the first release film and the second release film may be removed from the electrolyte film, and the first release film and the second release film may be bonded to the anode side electrochromic layer and the cathode side electrochromic layer.
  • the first release film and the second release film may be made of materials known in the art.
  • the viscosity of the electrolyte solution may be 10 to 100,000 cps based on 25 ° C, and may be 1,000 to 5,000 cps.
  • the coating processability is excellent, and the coating process is facilitated by preventing defective mixing process and defoaming process.
  • the thickness of the electrolyte layer is independently from 10 [mu] m to 500 [mu] m, e.g., 50-100 [mu] m.
  • the cathode-side electrochromic layer includes an oxide containing tungsten (W).
  • the cathode-side electrochromic layer includes an oxide including tungsten (W), and may further include chromium (Cr), manganese (Mn), or niobium (Nb) .
  • the cathode-side electrochromic layer may include a thin film containing an oxide containing tungsten (W).
  • W oxide containing tungsten
  • the density of the thin film may be 1 to 4 g / cm < 3 >.
  • the oxide containing tungsten (W) can be represented by the formula WO z , and z is a real number of 1 or more and 3 or less.
  • the oxide comprising tungsten (W) is tungsten trioxide (WO 3 ).
  • the thickness of the cathode-side electrochromic layer is 10 nm or more and 1 ⁇ ⁇ or less, for example, 300-400 nm.
  • the cathode-side electrochromic layer may be formed using a method known in the art.
  • Each of the anode side electrochromic layer and the cathode side emitting color discoloring layer may further include a metal bus bar at an edge portion thereof.
  • the material of the metal bus bar may be made of a metal having high conductivity, and silver, copper, aluminum, or the like may be used.
  • the thickness of the metal bus bar may be set equal to the thickness of the electrochromic layer, and the width of the metal bus bar may be 1 mm to 10 mm, but is not limited thereto.
  • 1 illustrates a laminated structure of decorative members according to an embodiment of the present application.
  • 1 shows a decorating member including a color developing layer 100 and an electrochromic device 200.
  • the color developing layer 100 includes a substrate 101, a light reflecting layer 201, and a light absorbing layer 301.
  • the electrochromic device 200 includes a cathode 501, a cathode side electrochromic layer 601, an electrolyte layer 701, an anode side electrochromic layer 801, an anode 901 and a substrate 1001. 1 shows the structure in which the base material 101 is provided on the side of the light reflection layer 201 of the color developing layer 100.
  • the base material 101 may be omitted or the light absorption layer 201 of the light reflection layer 301, Or may be provided on the opposite side of the surface.
  • 1 shows a structure in which the base material 1001 is provided on the anode 901 side of the electrochromic device 200 but a further base material may be provided on the cathode 501 side, May be omitted.
  • 1 shows a structure in which a cathode 501, a cathode side electrochromic layer 601, an electrolyte layer 701, an anode side electrochromic layer 801, and an anode 901 are sequentially stacked on a color developing layer
  • the present invention is not limited thereto.
  • the structure in which the anode 901, the anode side electrochromic layer 801, the electrolyte layer 701, the cathode side electrochromic layer 601, and the cathode 501 are sequentially stacked on the color developing layer is also within the scope of the present invention .
  • each layer is laminated in the order of L i-1 layer, L i layer and L i + 1 layer in the direction in which light enters, and between the L i-1 layer and the L i layer
  • the interface I i is located, and the interface I i + 1 is located between the L i layer and the L i + 1 layer.
  • the reflectance at the interface Ii can be expressed by the following equation (1).
  • K i ( ⁇ ) is an extinction coefficient according to the wavelength ⁇ of the i-th layer
  • n i ( ⁇ ) denotes a refractive index according to the wavelength ⁇ of the i-th layer, .
  • the extinction coefficient is a measure to define how strongly an object absorbs light at a specific wavelength, and the definition is as described above.
  • Equation (2) When the sum of the reflectances of the respective wavelengths at the interface I i calculated at each wavelength is defined as R i by applying Equation (1), R i is represented by Equation (2) below.
  • the layer located in contact with the interface Ii and facing the interface Ii in the direction in which the light enters is referred to as a light reflecting layer, and the remaining layer is defined as a light absorbing layer.
  • the remaining layer is defined as a light absorbing layer.
  • FIG. 18 illustrates a structure in which a metal bus bar is provided on the edge portions of the anode-side electrochromic layer and the cathode-side electrochromic layer.
  • the length of the electrochromic layer is 100 mm and the length of the electrochromic layer is 70 mm.
  • the width and length of the electrochromic layer may be determined according to the size of the decorative member that is ultimately required. For example, when the decorative member is intended to be used as a case applied to a cellular phone, it may be determined as the size of the cellular phone case.
  • FIG. 2 shows a schematic diagram of such a working principle. 2 illustrates a structure in which the substrate 101 is provided on the side of the light reflection layer 201. However, the structure is not limited to this structure, and the positions of the substrate 101 may be arranged at different positions as described above .
  • the pattern when the light absorbing layer includes a pattern, the pattern may be a symmetric structure, an asymmetric structure, or a combination thereof.
  • the light absorbing layer may include a pattern of a symmetric structure.
  • the symmetric structure includes a prism structure, a lenticular lens structure, and the like.
  • the light absorbing layer may include a pattern of an asymmetric structure.
  • an asymmetric structure means that it has an asymmetric structure on at least one surface when viewed from the top, side or cross section.
  • the decorative member can exhibit dichroism. Dichroism means that different colors are observed depending on the viewing angle.
  • Dichroism is related to the above-mentioned color difference , And it can be defined that dichroism exists when the color difference according to viewing angle is ⁇ E * ab> 1.
  • the light absorbing layer may have a dichroic property of DELTA E * ab >
  • the light absorbing layer includes a pattern whose upper surface has a protruding portion or a groove portion in the form of a cone.
  • the cone shape includes the shape of a cone, a cone, or a polygonal cone.
  • the shape of the bottom surface of a polygonal horn is triangular, square, and star shape with five or more protruding points.
  • the cone shape may be in the form of a protrusion formed on the upper surface of the light absorbing layer or in the form of a groove formed on the upper surface of the light absorbing layer.
  • the projecting portion is triangular in cross section, and the groove has an inverted triangular cross section.
  • the lower surface of the light absorbing layer may have the same shape as the upper surface of the light absorbing layer.
  • the cone-shaped pattern may have an asymmetric structure.
  • the cone-shaped pattern when the cone-shaped pattern is observed on the upper surface, when three or more identical shapes exist when the cone is rotated 360 degrees with respect to the vertex of the cone, dichroism is hardly expressed from the pattern. However, when the cone-shaped pattern is observed on the upper surface, dichroism can be expressed when there are two or less of the same shapes when the cone is rotated 360 degrees from the vertex of the cone.
  • Fig. 7 shows a top view of a cone shape.
  • Fig. 7 (a) shows a cone shape of a symmetric structure
  • Fig. 7 (b) shows a cone shape of an asymmetric structure.
  • the cone shape of symmetrical structure is a structure in which the bottom face of the cone shape is a circle or regular polygon having the same length on each side and the vertex of the cone is on the vertical line of the center of gravity of the bottom face.
  • the position of the vertex of the cone is located on the vertical line of the point other than the center of gravity of the floor surface, or the polygonal or elliptical structure to be.
  • the bottom surface is a polygon having an asymmetric structure, at least one of the sides or angles of the polygon can be designed differently from the rest.
  • the position of the vertex of the cone can be changed. Specifically, when the vertex of the cone is located on the vertical line of the center of gravity (O1) of the bottom surface when observing from the top, as shown in the first figure of FIG. 8, (4 fold symmetry). However, the symmetry structure is broken by designing the vertex of the cone at the position O2 instead of the center of gravity O1 of the floor surface.
  • the length of one side of the bottom surface is x
  • the moving distance of the vertex of the cone is a and b
  • the height of the cone shape which is the length of the line vertically connecting the vertex (O1 or O2)
  • a coincidence value can be obtained with respect to the plane 1, plane 2, plane 3 and plane 4 in Fig. 8 as follows.
  • the light absorbing layer includes a pattern in which the peak has a line-shaped protrusion or a bottom point has a line-shaped groove.
  • the line shape may be a linear shape, a curved shape, or both a curve and a straight line.
  • FIG. 9 is a top view of a pattern having a line-shaped protrusion, wherein (a) illustrates a pattern having a line-shaped protrusion that does not exhibit dichroism, (b) As shown in Fig. 9A is an isosceles triangle or an equilateral triangle, and the Y-Y 'cross section of FIG. 9B is a triangle having side lengths different from each other.
  • the light absorbing layer includes a pattern having a protruding portion or a groove portion whose upper surface is a cone-shaped upper surface cut-out structure.
  • the cross-section of such a pattern may be trapezoidal or inverted trapezoidal.
  • dichroism can be expressed by designing the top surface, the side surface, or the cross section to have an asymmetric structure.
  • FIG. 10 Various protrusions or groove patterns as shown in FIG. 10 may be implemented in addition to the structures exemplified above.
  • the light absorbing layer may include two or more regions having different thicknesses.
  • Fig. 3 and 4 illustrate a structure in which the light reflection layer 201 and the light absorption layer 301 are laminated.
  • the decorative member of Figs. 3 and 4 may include a substrate, the substrate 101 may be provided on the light reflection layer 201 side, and the substrate 101 may be provided on the light absorption layer 301 side.
  • the light absorbing layer 301 has two or more points having different thicknesses from each other. According to Fig. 3, the thickness of the light absorbing layer 301 at the point A and the point B is different. According to Fig. 4, the thickness of the light absorbing layer 301 in the C region and the D region is different.
  • the light absorbing layer includes at least one region having an inclined surface whose upper surface has an inclination angle of more than 0 degrees and not more than 90 degrees, and the light absorbing layer has a thickness And at least one region having a thickness different from the thickness.
  • the surface characteristics such as the inclination of the upper surface of the light reflecting layer may be the same as the upper surface of the light absorbing layer.
  • the upper surface of the light absorbing layer may have the same inclination as the upper surface of the light reflecting layer by using the vapor deposition method when forming the light absorbing layer.
  • Fig. 5 illustrates the structure of a decorative member having a light absorbing layer whose top surface has an inclined surface.
  • the thickness t1 of the light absorbing layer 301 in the E region and the thickness t2 in the F region are different from each other in the structure in which the substrate 101, the light reflecting layer 201 and the light absorbing layer 301 are laminated.
  • Fig. 5 relates to a light absorbing layer having a sloped surface facing each other, that is, a triangular section.
  • the thickness of the light absorbing layer may be different on two surfaces of the triangular structure even if the deposition proceeds under the same conditions in the structure of the pattern having the inclined surfaces facing each other.
  • a light absorbing layer having two or more regions having different thicknesses can be formed by only one step.
  • the color hue differs depending on the thickness of the light absorbing layer.
  • the thickness of the light reflecting layer is more than a predetermined value, the color change is not affected.
  • 5 shows a structure in which the substrate 101 is disposed on the side of the light reflection layer 201.
  • the structure is not limited to this structure, and the positions of the substrate 101 may be arranged at different positions as described above.
  • 5 has a flat surface in contact with the light reflecting layer 201 and a surface of the base 101 in contact with the light reflecting layer 201 is a pattern having the same slope as the top surface of the light reflecting layer 201 Lt; / RTI >
  • the difference in the thickness of the light absorbing layer may also be caused by the difference in the inclination of the pattern of the base material.
  • the present invention is not limited thereto, and the thickness of the light absorbing layer may be different on both sides of the pattern, so that the above-described dichroism can be exhibited even if the substrate and the light absorbing layer have different inclination using another vapor deposition method.
  • the light absorbing layer includes at least one region whose thickness gradually changes. According to Fig. 3, the structure in which the thickness of the light absorbing layer gradually changes is illustrated.
  • the light absorbing layer includes at least one region having an inclined surface whose top surface has an inclination angle of more than 0 degrees and not more than 90 degrees, and a region having at least one inclined surface, . ≪ / RTI > Fig. 6 illustrates the structure of the light absorbing layer including a region having a sloped upper surface. Both the G region and the H region of Fig. 6 have a structure in which the upper surface of the light absorbing layer has an inclined surface and the thickness of the light absorbing layer gradually changes.
  • the light absorbing layer may include a first region having a first inclined plane whose inclination angle is within a range of 1 to 90 degrees, and an upper face may be inclined differently from the first inclined plane, Or a second area whose top surface is horizontal. At this time, the thickness of the light absorbing layer in the first region and the second region may be different from each other.
  • the light absorbing layer may include a first region having a first inclined face whose inclination angle is within a range of 1 to 90 degrees, and the upper face may be different from the first inclined face in inclination direction, And may further include two or more regions having an inclined plane or a top plane. At this time, the thicknesses of the light absorbing layers in the first region and the two or more regions may be different from each other.
  • the color developing layer is formed on the opposite side of the light reflecting layer opposite to the light absorbing layer, between the light reflecting layer and the light absorbing layer, or opposite to the light reflecting layer of the light absorbing layer And a color film provided on the opposite side of the surface.
  • the color film has a color difference DELTA a * b * in a space of L * a * b * on the chromaticity coordinates CIE L * a * b * of the color reproduction layer in the presence of the color film, E * ab is greater than 1.
  • the color representation can be expressed as CIE L * a * b *, and the color difference can be defined using the distance ( ⁇ E * ab) in the L * a * b * space. Specifically, , And observers can not induce a color difference within the range of 0 ⁇ DELTA E * ab ⁇ 1 (Reference: Machine Graphics and Vision 20 (4): 383-411). Therefore, in this specification, the color difference due to the addition of the color film can be defined as DELTA E * ab > 1.
  • Fig. 11 shows a color conversion layer including a color film.
  • Fig. 11 shows a structure in which a light reflection layer 201, a light absorption layer 301 and a color film 401 are sequentially laminated in Fig. 11 (a) a structure in which the light reflection layer 201, the color film 401 and the light absorption layer 301 are sequentially stacked on the light reflection film 201, the light reflection film 201, And the absorbing layer 301 are sequentially laminated.
  • the color film may serve as a substrate.
  • it can be used as a color film by adding a dye or pigment to what can be used as a substrate.
  • the opposite surface of the light reflection layer opposite to the light absorption layer (Fig. 12 (a)); Or the substrate may be provided on the opposite surface (FIG. 12 (b)) of the surface of the light absorbing layer opposed to the light reflection layer.
  • the substrate when the substrate is provided on the opposite surface of the light reflecting layer opposite to the light absorbing layer, and the color film is located on the opposite surface of the light reflecting layer opposite to the light absorbing layer, Between the substrate and the light reflective layer; Or on the opposite surface of the substrate facing the light reflection layer.
  • the substrate when the substrate is provided on the opposite surface of the light absorbing layer opposite to the light reflecting layer, and the color film is located on the opposite side of the light absorbing layer to the light reflecting layer, The color film being disposed between the substrate and the light absorbing layer; Or on the opposite surface of the substrate facing the light absorption layer.
  • a substrate is provided on the opposite surface of the light reflecting layer opposite to the light absorbing layer, and a color film is additionally provided.
  • 13A shows a structure in which the color film 401 is provided on the opposite surface of the light absorbing layer 301 on the side of the light reflection layer 201.
  • the color film 401 has a structure in which the light absorbing layer 301 A structure in which a color film 401 is provided between the light reflection layer 201 and the base material 101 and a structure in which a color film 401 is provided between the light reflection layer 201 and the base material 101 is shown in Figure 13 (c) And a film 401 is provided on the opposite surface of the substrate 101 on the light reflection layer 201 side.
  • the color films 401a, 401b, 401c and 401d are respectively disposed on opposite sides of the light absorbing layer 301 on the light reflecting layer 201 side, between the light absorbing layer 301 and the light reflecting layer 201, but the present invention is not limited thereto and the color films 401a, 401b, 401c, and 401c may be formed on the opposite surfaces of the reflective layer 201 and the substrate 101, 401d may be omitted.
  • a substrate is provided on the opposite surface of the light absorbing layer to the light reflecting layer, and a color film is additionally provided.
  • 14A shows a structure in which the color film 401 is provided on the opposite surface of the substrate 101 on the side of the light absorbing layer 301.
  • FIG. 14B shows a structure in which the color film 401 is provided on the substrate 101 A structure in which the color film 401 is provided between the light absorbing layer 301 and the light reflecting layer 201 is shown in Fig. 14C, a structure in which the color film 401 is provided between the light absorbing layer 301 and the light reflecting layer 201, (401) is provided on the opposite surface of the light reflection layer (201) on the side of the light absorption layer (301).
  • color films 401a, 401b, 401c and 401d are disposed on the opposite side of the substrate 101 on the side of the light absorbing layer 301, between the substrate 101 and the light absorbing layer 301,
  • the present invention is not limited thereto and the color films 401a, 401b, and 401c (not shown in the drawings) may be used as the light reflection layer 201 , And 401d may be omitted.
  • the transmittance is 1% or more, preferably 3% or more, and more preferably 5% or more. This is because the transmitted light can be mixed with the color of the color film in the visible light transmittance range.
  • the color film may be provided in a state in which one sheet or two or more sheets of the same kind or different types are laminated.
  • the color film may be combined with the color developed from the above-described laminated structure of the light reflection layer and the light absorption layer to exhibit a desired color.
  • a color film may be used in which one or more of pigments and dyes are dispersed in the matrix resin to exhibit color.
  • the color film may be formed by coating a composition for forming a color film directly at a position where the color film may be formed, or may be formed by coating a composition for forming a color film on a separate substrate, Method is used to manufacture a color film, and then a color film is placed or adhered to a position where the color film can be provided.
  • the coating method may be a wet coating or a dry coating.
  • the pigments and dyes that can be included in the color film may be selected from those known in the art as those capable of achieving a desired color from the final decorating material, and may be selected from red, yellow, And pigments and dyes such as pigments, pigments, pigments, pigments, etc. Specific examples thereof include perinone red dyes, anthraquinone dyes, anthraquinone dyes, methine dyes, anthraquinone dyes, anthraquinone dyes, phthalocyanine dyes, thioindigo dyes, isoindigo dyes, Dyes such as isoxindigo-based pink dyes may be used alone or in combination.
  • Carbon black, copper phthalocyanine (CI Pigment Blue 15: 3), C.I. Pigment Red 112, Pigment blue, and Isoindoline yellow may be used alone or in combination.
  • Commercially available materials such as dyes or pigments may be used.
  • materials such as Ciba ORACET Co., Ltd. or Chohwa Paint Co., Ltd. can be used.
  • the types of the dyes or pigments and their hue are merely examples, and known dyes or pigments can be used in various ways, thereby realizing more various colors.
  • the matrix resin included in the color film materials known as materials such as a transparent film, a primer layer, an adhesive layer, and a coating layer can be used, and the material is not particularly limited thereto.
  • materials such as an acrylic resin, a polyethylene terephthalate resin, a urethane resin, a linear olefin resin, a cycloolefin resin, an epoxy resin, and a triacetylcellulose resin may be selected. Mixtures may also be used.
  • the color film has a light transmittance of not less than 1%, preferably not less than 3%, more preferably not less than 5%, which is expressed from the light reflection layer, the light absorption layer or the laminated structure of the light reflection layer and the light absorption layer desirable.
  • hues expressed from the color film and the light reflected from the light reflecting layer, the light absorbing layer, or the laminated structure thereof can be combined together to achieve a desired color.
  • the thickness of the color film is not particularly limited and can be selected by a person having ordinary knowledge in the art as long as it can exhibit a desired color.
  • the thickness of the color film may be 500 nm to 1 mm.
  • the light absorption layer can be implemented in various colors according to the refractive index (n), the extinction coefficient (k), and the thickness (t).
  • FIG. 15 shows the reflectance according to the wavelength depending on the thickness of the light absorbing layer
  • FIG. 16 shows the hue realized according to the thickness of the light absorbing layer.
  • FIG. 15 is a graph of a reflectance simulation graph of CuO / Cu with respect to the CuO deposition thickness, which is prepared by changing the thickness of CuO by 10 to 60 nm under the same deposition conditions.
  • 17 is a simulation result showing that a different color is observed according to the viewing angle.
  • 17 shows a simulation result of CuON / Al.
  • the thickness of the light absorbing layer is increased from 10 nm to 100 nm by 10 nm, and the incident angle is adjusted from 15 degrees to 0 degrees from 60 degrees. From the simulation results, it can be seen that various colors can be realized by adjusting the thickness of the light absorbing layer and the inclination angle of the upper surface in the structure according to the embodiment of the present application. In addition, by providing a color film, more various colors can be realized.
  • the L * a * b * coordinate values of a1 to a5 in FIG. 17 are (91,3,5), and the L * a * b * coordinate values of b1 to b5 are (74,14,8) , 14,8), (72,15,10), (69,15,11), (66,16,13), and the L * a * b * coordinate values of c1 through c5 are (46,22, -11), (45,22, -10), (43,25, -9), (40,28, -4), (42,30,6)
  • the coordinate values are (36, -12, -22), (35, -11, -23), (30, -7, -24) ),
  • L * a * b * coordinate values of e1 to e5 are (49, -20, -7), (48, -20, -7) -18,39) and (18,7, -10), and the L * a * b * coordinate values of f1 to f5 are (60,
  • the light reflecting layer is not particularly limited as long as it is a material capable of reflecting light, but the light reflectance can be determined depending on the material, and for example, the color can be easily realized at 50% or more.
  • the light reflectance can be measured using an ellipsometer.
  • the light absorption layer preferably has a refractive index (n) of 0 to 8 at 400 nm, may be 0 to 7, may be 0.01 to 3, and may be 2 to 2.5.
  • the refractive index n can be calculated as sin? 1 / sin? 2 (? 1 is the angle of light incident from the surface of the light absorption layer, and? 2 is the refraction angle of light within the light absorption layer).
  • the light absorption layer preferably has a refractive index (n) of 0 to 8 at 380 to 780 nm, may be 0 to 7, may be 0.01 to 3, and may be 2 to 2.5.
  • the light absorption layer preferably has an extinction coefficient (k) of more than 0 and less than 4 at 400 nm, preferably 0.01 to 4, may be 0.01 to 3.5, may be 0.01 to 3, and may be 0.1 to 1.
  • the extinction coefficient k is a value obtained by multiplying the reduction ratio dI / I of the intensity of light per unit length (dx), e.g., 1 m, in the light absorbing layer by? / 4? , Where lambda is the wavelength of light.
  • the light absorption layer preferably has an extinction coefficient (k) of more than 0 and less than 4, preferably 0.01 to 4, more preferably 0.01 to 3.5, more preferably 0.01 to 3, and more preferably 0.1 to 1 at 380 to 780 nm.
  • the extinction coefficient (k) in the entire visible wavelength range of 400 nm, preferably 380 to 780 nm is in the above range, it can act as a light absorbing layer within the visible light range.
  • the spectrum that absorbs light differs.
  • the absorption wavelength band is fixed and only the absorption amount changes depending on the change in coating thickness.
  • a thickness variation of at least several micrometers is necessary in order to adjust the light absorption amount.
  • the wavelength range of light to be absorbed varies even if the thickness changes to several tens or nanometers scale.
  • the light reflecting layer may be a metal layer, a metal oxide layer, a metal nitride layer, a metal oxynitride layer, or an inorganic layer.
  • the light reflection layer may be formed of a single layer, or may be composed of two or more layers.
  • the light reflecting layer may include at least one of indium (In), titanium (Ti), tin (Sn), silicon (Si), germanium (Ge), aluminum (Al), copper (Cu), nickel (Ni) V, tungsten, tantalum, molybdenum, neodymium, iron, chromium, cobalt, gold and silver. May be a single layer or multiple layers including one or more materials selected from the group consisting of one or more materials, oxides, nitrides or oxynitrides thereof, and carbon and carbon composites.
  • the light reflecting layer may comprise two or more alloys selected from the above materials, oxides, nitrides or oxynitrides thereof.
  • the light reflection layer may be manufactured using an ink including a carbon or carbon composite, thereby realizing a high-resistance reflection layer.
  • the carbon or carbon composite include carbon black and CNT.
  • the ink containing the carbon or carbon composite material may include the above-described materials or oxides, nitrides or oxynitrides thereof, and examples thereof include indium (In), titanium (Ti), tin (Sn), silicon (Si) Ge).
  • Aluminum, aluminum, copper, nickel, vanadium, tungsten, tantalum, molybdenum, neodymium, iron, chromium, One or more oxides selected from cobalt (Co), gold (Au), and silver (Ag) may be included.
  • the light reflection layer includes two or more kinds of materials
  • two or more kinds of materials may be formed by one process, for example, a deposition or printing method.
  • a method of forming a layer thereon with one or more kinds of materials may be used.
  • an ink containing carbon may be printed and cured to form a light reflection layer.
  • the ink may further include an oxide such as titanium oxide or silicon oxide.
  • the light absorbing layer may be a single layer, or may be a multilayer of two or more layers.
  • the light absorbing layer may be made of a material having an extinction coefficient (k) at 400 nm, preferably 380 to 780 nm, that is, a material having an extinction coefficient of more than 0 and 4 or less, preferably 0.01 to 4.
  • the light absorbing layer may include one or two or more selected from the group consisting of metals, metalloids, and oxides, nitrides, oxynitrides and carbides of metals or metalloids.
  • the oxide, nitride, oxynitride or carbide of the metal or metalloid can be formed by deposition conditions set by a person skilled in the art.
  • the light absorbing layer may contain the same metal, semi-metal, two or more alloys or oxynitrides as the light reflecting layer.
  • the light absorption layer may be formed of indium (In), titanium (Ti), tin (Sn), silicon (Si), germanium (Ge), aluminum (Al), copper (Cu), nickel (Ni) ,
  • tungsten (W) tantalum (Ta), molybdenum (Mo), neodymium (Nb), iron (Fe), chromium (Cr), cobalt (Co), gold (Au)
  • a single layer or multiple layers comprising two or more materials or oxides, nitrides or oxynitrides thereof.
  • the light absorbing layer includes one or two or more selected from among copper oxide, copper nitride, copper oxynitride, aluminum oxide, aluminum nitride, aluminum oxynitride and molybdenum titanium oxynitride.
  • the light absorbing layer comprises silicon (Si) or germanium (Ge).
  • the light absorbing layer made of silicon (Si) or germanium (Ge) has a refractive index (n) of 0 to 8 at a wavelength of 400 nm and can be 0 to 7 and an extinction coefficient (k) 4, 0.01 to 3, or 0.01 to 1.
  • the light absorbing layer includes one or two or more selected from among copper oxide, copper nitride, copper oxynitride, aluminum oxide, aluminum nitride, aluminum oxynitride and molybdenum titanium oxynitride.
  • the light absorption layer may have a refractive index (n) of 1 to 3, for example, 2 to 2.5 at 400 nm, and an extinction coefficient k of more than 0 and 4 or less, preferably 0.01 to 2.5, preferably 0.2 to 2.5, More preferably, it may be 0.2 to 0.6.
  • the light absorbing layer is AlOxNy (x> 0, y> 0).
  • the light absorbing layer may be AlOxNy (0? X? 1.5, 0? Y? 1).
  • the light absorbing layer is made of AlOxNy (x> 0, y> 0), and the number of each atom satisfies the following formula with respect to 100% of the total number of atoms.
  • the light absorbing layer may be made of a material having an extinction coefficient k at 400 nm, preferably 380 to 780 nm.
  • the light absorbing layer / light reflecting layer may be made of CuO / Cu, CuON / / Al, AlON / Al, AlN / AL / AlON / Cu, and AlN / Cu.
  • the thickness of the light reflection layer can be determined according to a desired color in the final structure, and is, for example, 1 nm or more, preferably 25 nm or more, such as 50 nm or more, preferably 70 nm or more.
  • the thickness of the light absorbing layer may be 5 to 500 nm, for example 30 to 500 nm.
  • the thickness difference of the light absorbing layer in each region is 2 to 200 nm and can be determined according to a desired color difference.
  • the light reflection layer may further include a substrate provided on a lower surface of the light reflecting layer or on an upper surface of the light absorbing layer.
  • the surface characteristics such as the inclination of the upper surface of the substrate may be the same as the upper surface of the light reflection layer and the light absorption layer.
  • the light reflecting layer and the light absorbing layer are formed by the vapor deposition method, so that the substrate, light reflecting layer and light absorbing layer can have inclined surfaces at the same angle.
  • such a structure can be realized by forming an inclined surface or a three-dimensional structure on an upper surface of a substrate, depositing a light reflecting layer and a light absorbing layer on the substrate sequentially, or sequentially depositing a light absorbing layer and a light reflecting layer.
  • forming a sloped surface or a three-dimensional structure on the surface of the substrate can be carried out by forming a pattern on the ultraviolet curable resin and curing it by using ultraviolet rays, or by laser processing.
  • the decorative member may be a case of a deco film or a mobile device.
  • the decorative member may further include an adhesive layer as needed.
  • the material of the substrate is not particularly limited, and when forming a sloped surface or a steric structure in the above-described manner, a UV-curable resin known in the art can be used.
  • a protective layer may be further provided on the light absorption layer.
  • the adhesive layer may be further provided on the opposite surface of the substrate having the light absorbing layer or the light reflecting layer.
  • This adhesive layer may be an optically clear adhesive (OCA) layer.
  • OCA optically clear adhesive
  • a release liner may be additionally provided for protection if necessary.
  • a deposition such as a sputtering method as an example of a method of forming a light reflecting layer and a light absorbing layer
  • vapor deposition chemical vapor deposition (CVD), wet coating, or the like can be used.
  • An 80 nm thick ITO layer and a 250 nm thick WO 3 layer were sequentially laminated on one surface of a PET substrate.
  • a light reflecting layer (Al, thickness: 100 nm) and a light absorbing layer (aluminum oxynitride, thickness: 40 nm) were deposited on the opposite surface of the PET substrate to provide a basic color of gold upon decolorization.
  • the thus-prepared half cell was placed in a bath containing an electrolytic solution (LiClO 4 (1M) + propylene carbonate (PC)), and a potentiostat apparatus was prepared. It is 50 seconds and was colored WO 3.
  • ITO / WO 3 / GPE / ITO layer by cementing a Prussian blue (PB) / ITO laminate with a film containing ITO layer and WO 3 layer of the half cell via a gel polymer electrolyte (GPE) A film having a laminated structure of PB / ITO was prepared.
  • PB Prussian blue
  • GPE gel polymer electrolyte
  • the discoloration rate was measured while repeatedly applying a bleaching voltage and a coloration voltage to the produced film at regular intervals.
  • the decoloring voltage and the coloring voltage per one cycle were applied for 50 seconds with a magnitude of ( ⁇ ) 1.2 V, respectively.
  • An 80 nm thick ITO layer and a 250 nm thick WO 3 layer were sequentially laminated on one surface of a PET substrate.
  • a light reflecting layer (Al, thickness: 100 nm) and a light absorbing layer (aluminum oxynitride, thickness: 60 nm) were deposited on the opposite surface of the PET substrate to provide a basic color of gold upon decolorization.
  • the thus-prepared half cell was placed in a bath containing an electrolytic solution (LiClO 4 (1M) + propylene carbonate (PC)), and a potentiostat apparatus was prepared. It is 50 seconds and was colored WO 3.
  • ITO / WO 3 / GPE / ITO layer by cementing a Prussian blue (PB) / ITO laminate with a film containing ITO layer and WO 3 layer of the half cell via a gel polymer electrolyte (GPE) A film having a laminated structure of PB / ITO was prepared.
  • PB Prussian blue
  • GPE gel polymer electrolyte
  • the discoloration rate was measured while repeatedly applying a bleaching voltage and a coloration voltage to the produced film at regular intervals.
  • the decoloring voltage and the coloring voltage per one cycle were applied for 50 seconds with a magnitude of ( ⁇ ) 1.2 V, respectively.
  • An 80 nm thick ITO layer and a 250 nm thick WO 3 layer were sequentially laminated on one surface of a PET substrate.
  • a light reflecting layer (Al, thickness: 100 nm) and a light absorbing layer (aluminum oxynitride, thickness: 80 nm) were deposited on the opposite surface of the PET substrate to provide a basic color of gold upon decolorization.
  • the thus prepared half cell was placed in a bath containing an electrolytic solution (LiClO4 (1M) + propylene carbonate (PC)), and a potentiostat apparatus was prepared. seconds applied to, was colored WO 3.
  • ITO / WO 3 / GPE / ITO layer by cementing a Prussian blue (PB) / ITO laminate with a film containing ITO layer and WO 3 layer of the half cell via a gel polymer electrolyte (GPE) A film having a laminated structure of PB / ITO was prepared.
  • PB Prussian blue
  • GPE gel polymer electrolyte
  • the discoloration rate was measured while repeatedly applying a bleaching voltage and a coloration voltage to the produced film at regular intervals.
  • the decoloring voltage and the coloring voltage per one cycle were applied for 50 seconds with a magnitude of ( ⁇ ) 1.2 V, respectively.
  • ITO having a thickness of 210 nm and WO 3 having a thickness of 250 nm were sequentially laminated on a PET substrate without forming the light reflecting layer and the light absorbing layer of Example 1. Then, a transmission type electrochromic film (ITO / WO 3 / GPE / PB / ITO) was produced through the same laminating process as in Example 1. The film thus prepared was measured for discoloration rate in the same manner as in Example 1.
  • the ITO resistance used in Examples 1, 2 and 3 was all the same as 30 ohm / sq]
  • the color change according to the time when the coloring voltage was applied to the film prepared in Example 1 and the time when the coloring voltage was applied The color change is shown in Fig. According to FIG. 19, it can be seen that various colors can be displayed according to the voltage application and the elapse of time after the voltage application.
  • Each numeral in FIG. 19 represents the CIE L * ab coordinate value of the corresponding color.
  • Example 21 except that a PET film having a prism pattern formed on the opposite side to the surface contacting the electrochromic device was used as the PET substrate and a light reflection layer and a light absorption layer were formed on the surface of the PET film on which the prism pattern was provided The procedure of Example 1 was repeated. Further, after the ITO layer was formed as an anode, a PET film was further laminated. The size of one side of the manufactured decorative member was 70 mm x 100 mm as shown in Fig.
  • Example 2 In the case of the electrochromic rate, the same result as in Example 1 was obtained because it was influenced by the coloring material and the resistance of ITO.
  • the results of simulating the colors observed on the side of the light reflecting layer and the light absorbing layer provided on the prism pattern of the PET film in the decolorized state are shown in Fig. Right, Down, Left, and Up in FIG. 22 represent implementation colors when viewed from the right side, from below, from the left, and from above, respectively, in FIG.
  • the sheet resistance of the films prepared in Examples and Production Examples was measured using a known surface resistor according to the 4-point probe method.
  • the sheet resistance in Table 1 was measured for the light reflecting layer before forming the light absorbing layer of the example, and for the ITO in the comparative example.
  • the sheet resistance of the entire laminate is determined by the resistance of the reflective layer having a low sheet resistance since it is a parallel connection.
  • the sheet resistance was measured with Hiresta's MCP-HT450, ASP PROVE.
  • Color Change Time was measured as the time taken to reach the 20% level of the final coloring state transmittance observed after the time (50s) for applying the electric potential for coloring had elapsed.
  • the decolorization time was measured as the time taken for reaching the 80% level of the final decolored state transmittance observed after elapse of the time (50s) for applying the potential for decolorization.

Landscapes

  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Nonlinear Science (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Devices For Indicating Variable Information By Combining Individual Elements (AREA)

Abstract

La présente invention concerne un élément décoratif comprenant : une couche d'expression de couleur comprenant une couche de réflexion de lumière et une couche d'absorption de lumière disposée sur la couche de réflexion de lumière ; et un élément électrochrome disposé sur une surface de la couche d'expression de lumière.
PCT/KR2018/007225 2017-06-27 2018-06-26 Élément décoratif et son procédé de préparation WO2019004698A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2019564026A JP6884969B2 (ja) 2017-06-27 2018-06-26 装飾部材およびその製造方法
US16/615,735 US11225045B2 (en) 2017-06-27 2018-06-26 Decorative member and method for preparing same
CN201880034790.1A CN110678809B (zh) 2017-06-27 2018-06-26 装饰构件及其制备方法
EP18823948.7A EP3647053B1 (fr) 2017-06-27 2018-06-26 Élément décoratif

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR10-2017-0081401 2017-06-27
KR20170081401 2017-06-27
KR10-2017-0136808 2017-10-20
KR1020170136808A KR102201549B1 (ko) 2017-06-27 2017-10-20 장식 부재 및 이의 제조방법

Publications (1)

Publication Number Publication Date
WO2019004698A1 true WO2019004698A1 (fr) 2019-01-03

Family

ID=64742905

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2018/007225 WO2019004698A1 (fr) 2017-06-27 2018-06-26 Élément décoratif et son procédé de préparation

Country Status (1)

Country Link
WO (1) WO2019004698A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3731011A4 (fr) * 2019-02-27 2021-06-30 Suzhou Institute of Nano-Tech and Nano-Bionics (Sinano), Chinese Academy of Scie Structure électrochromique polychrome, son procédé de préparation et son application

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005519462A (ja) * 2002-02-28 2005-06-30 モトローラ・インコーポレイテッド 多様な外観のハウジングを備える携帯通信ハンドセットおよびその方法
KR100563419B1 (ko) * 1998-02-24 2006-03-22 아사히 가라스 가부시키가이샤 광 흡수성 반사방지체 및 그 제조 방법
JP2010173273A (ja) * 2009-01-30 2010-08-12 Toyoda Gosei Co Ltd 機器用筐体、機器用装飾体及び変色の抑制方法
JP2010197798A (ja) * 2009-02-26 2010-09-09 Toppan Printing Co Ltd 偽造防止機能を有する光学素子及びそれを具備する偽造防止表示体
JP5016722B2 (ja) * 2009-12-25 2012-09-05 パナソニック株式会社 装飾部材
KR20140111813A (ko) * 2013-03-12 2014-09-22 (주)엘지하우시스 전기변색기능이 있는 인테리어 장식필름 및 그의 제조방법
KR20170081401A (ko) 2016-01-04 2017-07-12 삼성전자주식회사 전자 장치 및 그의 동작 방법
KR20170136808A (ko) 2016-06-02 2017-12-12 강성욱 모서리에 자석이 부착되어 있는 이불

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100563419B1 (ko) * 1998-02-24 2006-03-22 아사히 가라스 가부시키가이샤 광 흡수성 반사방지체 및 그 제조 방법
JP2005519462A (ja) * 2002-02-28 2005-06-30 モトローラ・インコーポレイテッド 多様な外観のハウジングを備える携帯通信ハンドセットおよびその方法
JP2010173273A (ja) * 2009-01-30 2010-08-12 Toyoda Gosei Co Ltd 機器用筐体、機器用装飾体及び変色の抑制方法
JP2010197798A (ja) * 2009-02-26 2010-09-09 Toppan Printing Co Ltd 偽造防止機能を有する光学素子及びそれを具備する偽造防止表示体
JP5016722B2 (ja) * 2009-12-25 2012-09-05 パナソニック株式会社 装飾部材
KR20140111813A (ko) * 2013-03-12 2014-09-22 (주)엘지하우시스 전기변색기능이 있는 인테리어 장식필름 및 그의 제조방법
KR20170081401A (ko) 2016-01-04 2017-07-12 삼성전자주식회사 전자 장치 및 그의 동작 방법
KR20170136808A (ko) 2016-06-02 2017-12-12 강성욱 모서리에 자석이 부착되어 있는 이불

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
MACHINE GRAPHICS AND VISION, vol. 20, no. 4, pages 383 - 411

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3731011A4 (fr) * 2019-02-27 2021-06-30 Suzhou Institute of Nano-Tech and Nano-Bionics (Sinano), Chinese Academy of Scie Structure électrochromique polychrome, son procédé de préparation et son application

Similar Documents

Publication Publication Date Title
WO2019117626A1 (fr) Élément de décoration et son procédé de production
WO2019117413A1 (fr) Élément décoratif et procédé de fabrication s'y rapportant
KR20190001486A (ko) 장식 부재 및 이의 제조방법
WO2019198939A1 (fr) Élément décoratif destiné à un contenant de produit cosmétique, et son procédé de production
WO2014084697A1 (fr) Ecran tactile et son procédé de fabrication
WO2012121519A2 (fr) Structure conductrice et procédé de fabrication correspondant
WO2019240558A1 (fr) Élément de décoration et procédé de fabrication d'élément de décoration
WO2019004724A1 (fr) Élément décoratif et son procédé de production
WO2019004722A1 (fr) Élément décoratif et son procédé de préparation
WO2015088295A1 (fr) Capteur tactile et son procédé de fabrication
WO2016204488A1 (fr) Capteur tactile et son procédé de fabrication
WO2021167377A1 (fr) Film multicouche et stratifié le comprenant
WO2019004721A1 (fr) Élément décoratif et son procédé de préparation
WO2019004723A1 (fr) Élément décoratif et son procédé de préparation
WO2019199036A1 (fr) Élément de décoration et son procédé de fabrication
WO2019004698A1 (fr) Élément décoratif et son procédé de préparation
WO2019199037A1 (fr) Élément de décoration et son procédé de fabrication
WO2016204487A1 (fr) Capteur tactile et son procédé de fabrication
WO2021167378A1 (fr) Film multicouche et stratifié le comprenant
WO2019117638A1 (fr) Élément de décoration et son procédé de production
WO2018164464A1 (fr) Élément décoratif et procédé de fabrication associé
WO2012169864A2 (fr) Capteur tactile
WO2022014754A1 (fr) Structure de couleur variable, et dispositif électronique
WO2020071646A1 (fr) Plaque polarisante et dispositif d'affichage optique la comprenant
WO2019004725A1 (fr) Élément décoratif et procédé de fabrication associé

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 18823948

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 2019564026

Country of ref document: JP

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE

ENP Entry into the national phase

Ref document number: 2018823948

Country of ref document: EP

Effective date: 20200127