WO2018228846A1 - Composition de nettoyage des cheveux contenant un extrait de fleur de cymbidium grandiflorum - Google Patents

Composition de nettoyage des cheveux contenant un extrait de fleur de cymbidium grandiflorum Download PDF

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Publication number
WO2018228846A1
WO2018228846A1 PCT/EP2018/064653 EP2018064653W WO2018228846A1 WO 2018228846 A1 WO2018228846 A1 WO 2018228846A1 EP 2018064653 W EP2018064653 W EP 2018064653W WO 2018228846 A1 WO2018228846 A1 WO 2018228846A1
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composition
composition according
weight
hair
amount
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PCT/EP2018/064653
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English (en)
Inventor
Lei Jiang
Chaochun Dong
Yabin Wang
Tan WANG
Zhaoxia Bao
Xiaopeng Hong
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Beiersdorf Ag
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Publication of WO2018228846A1 publication Critical patent/WO2018228846A1/fr

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783—Angiosperms [Magnoliophyta]
    • A61K8/9794—Liliopsida [monocotyledons]
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners

Definitions

  • the present invention belongs to the cosmetic field, and relates to a cosmetic composition, especially a hair cleansing composition comprising Cymbidium Grandiflorum flower extract, at least one anionic surfactant and at least one amphoteric surfactant, and at least one cationic polymer.
  • the cosmetic composition leads to an improvement in the physical-optical properties of hair, especially causing a moisturizing effect of hair, thus preventing dryness and roughness of hair.
  • the composition is easy to wash out after application on hair.
  • the invention relates also to the use of the cosmetic composition.
  • Hair consists of a hair shaft and a hair root.
  • the hair shaft protrudes freely from the skin, and is a keratinized (dead) section of the hair.
  • the hair shaft represents the actual visible part of the hair, which is continually renewed.
  • the hair root sticks in the skin and is the living part of the hair.
  • the hair shaft is composed of three layers: the central part, which is called hair marrow (medulla), is regressed in humans, often completely missing; then there is the marrow, also called cortex; and cuticle as the outermost layer, comprising up to ten horny layers.
  • the horny layer being the external sheath of the hair, and also the inner region below the cuticle are subjected to particular stress by environmental influences.
  • Cymbidium Grandiflorum is also called Cymbidium hookerianum belonging to the botanical family of Orchidaceae. Orchids are well known for their moisturizing properties in relation to skin, as well as having activities of scavenging free radicals and influencing skin immunity. Some species, like the pink orchid, are rich in minerals, especially those which are important for the skin. In addition, polysaccharides and sugars are present, helping in regulating the moisture of the skin. Flower extracts can be obtained from the Cymbidium hookerianum Rchb.f. species. After an extraction and separation process the resulting extract is rich in saponins. These saponins can inhibit hyaluronidase activity, thus increasing the content of hyaluronic acid in the skin. The increase in hyaluronic acid leads to a moisturizing effect, too.
  • Moisturizing hair is connected with the idea of delivering water and/or natural oils to hair.
  • the outmost structure of hair is the cuticula, which is arranged in form of shingles. If the cuticula is intact and compact, for example water and natural moisturizing factors cannot escape from the cortex of hair. The hair looks healthy and resembles hair in a freshly grown condition. If the cuticula is not intact for various reasons, water and natural moisturizing factors can escape from the cortex causing a dry condition of hair. In order to moisturize hair water binding components and natural oils can be delivered to hair helping to restore the cuticula and provide the cortex with water binding components. If the cuticula is restored, water and natural moisturizing factors can be inclosed again.
  • WO 2009/1 17626 A2 describes color cosmetics using naturally derived materials.
  • a finishing powder contains a Cymbidium Grandiflorum flower extract.
  • the document is silent on specific effects related to the extract. No detailed effects of the extract are disclosed.
  • FR 3016126 A1 describes the use of an extract of Artemia Salina to protect the skin against the influence and damage of cold temperatures.
  • a creme composition for men contains Cymbidium Grandiflorum flower extract. No effects of the Cymbidium Grandiflorum flower extract are disclosed.
  • WO 2006/044193 A2 describes the synthesis of rheology modifiers/hair styling resins for hair care compositions.
  • An example of a conditioning shampoo discloses the use of a Cymbidium Grandiflorum flower extract.
  • WO 2006/044193 A2 is directed to polymers, no effect of the Cymbidium Grandiflorum flower extract is mentioned.
  • one aim of hair care is to retain the natural state of freshly grown hair over a prolonged period of time and, in the case of loss of the natural state, to restore it.
  • natural healthy hair has a silky shine, low porosity and a pleasant, smooth feel.
  • the aim of the present invention is to make available hair cleansing compositions, which at the same time also provide a caring effect to hair.
  • the components contributing to the caring of hair should be of natural origin or nature based ingredients.
  • Said compositions should cleanse hair thoroughly and carefully. Further, said compositions should help to restore the natural condition of hair thus providing healthy looking hair which is no longer dry or rough.
  • compositions comprising a Cymbidium Grandiflorum flower extract should help to improve the nourishing of the scalp thereby influencing the condition of the scalp but also the condition of the freshly grown hair in positive manner.
  • Inventors of the present invention found out that a hair cleansing composition containing Cymbidium Grandiflorum flower extract in a concentration of 0.01 to 10.0% by weight, calculated to the total weight of the composition, is able to improve the physical-optical properties of hair and scalp.
  • the present invention provides a hair cleansing composition, comprising
  • the composition comprises preferably 0.05 to 7.5 % by weight, more preferably 0.1 to 5.0 % by weight, calculated to the total weight of the composition, of Cymbidium Grandiflorum flower extract.
  • the composition can optionally comprise the auxiliary components as listed in the part of "detailed description of the invention", such as thickening agent, nonionic surfactant, cationic surfactant, silicone, anti- dandruff agent, preservative, pearlescent agent, and colorant.
  • the composition comprises a balance amount of water, so that all the components amount to 100% by weight.
  • composition of the present invention is free from specific fatty acid dialkylamides and fatty dialkanolamides, namely cocamide mea and cocamide dea, free from specific alkanolamines, namely mea, dea and tea, and free from monoalkylamines and trialkylamines and salts thereof.
  • These substances might be regarded as substances leading to nitrosamines.
  • Nitrosamines are known to be involved in causing cancer.
  • "free from” means less than 0.1 %, preferably less than 0.01 %, and more preferably 0% by weight of the total composition.
  • the present invention relates to use of the composition of the present invention for cleansing hair thereby performing a conditioning and moisturizing effect of hair.
  • the conditioning and moisturizing effect of hair results in an improved gliding, softness and combability of hair in the wet and dry condition.
  • Another aspect of the present invention is the use of the composition of the present invention for providing shiny hair.
  • the present invention relates to use of Cymbidium Grandiflorum flower extract in preparation of a hair cleansing composition.
  • composition of the present invention By using the composition of the present invention, the possible damages of hair treatments as intense combing or brushing, colorations, bleaching and permanent waving, and also hair shaping using a hair dryer or other tools are reduced.
  • Cymbidium Grandiflorum flower extracts are obtained from the flowers of orchids by extraction and separation processes. Cymbidium Grandiflorum flower extracts are also commercially available. Cymbidium Grandiflorum flower extract can, for example, be purchased from Kunming Chin-herb Bio-tec.
  • Cymbidium Grandiflorum flower extract is essential for the present invention.
  • Anionic surfactants suitable for the present invention comprise, but are not limited to sulfate, sulfonate, sarcosinate and sarcosine derivatives.
  • Preferred anionic surfactants are alkali- and/or ammonium salts of alkylsulfate and/or alkylethersulfate. It is preferred that the alkylsulfates and/or alkylethersulfates have alkyl substituents containing 8 to 16 carbon atoms, more preferred are alkylsulfates and/or alkylethersulfates with alkyl substituents containing 10 to 14 carbon atoms. Even more preferred are alkylsulfates and/or alkylethersulfates where the alkyl substituent essentially contains a lauryl group. Furthermore it is preferred that the alkylsulfates and/or alkylethersulfates are in the form of ammonium or sodium salts. Advantageously sodium laureth sulfate is used.
  • the anionic surfactants are preferably used in an amount of 1 to 30 % by weight, more preferably 5 to 25 % by weight, still more preferably 10 to 20 % by weight, relative to the total weight of the composition.
  • the values are referring to the active content of the anionic surfactants.
  • the amphoteric surfactants suitable for the present invention are the substances commonly known in the art to be used in hair care or personal care cleansing composition, such as those described in CN 101 164520A and DE 202015002188U1 . According to the invention, the amphoteric surfactants are preferably alkyl- and/or alkylamidopropylbetaines.
  • alkyl- and/or alkylamidopropylbetaines have alkyl substituents containing 8 to 16 carbon atoms. Even more preferred are alkyl- and/or alkylamidopropylbetaines with alkyl substituents containing 10 to 14 carbon atoms. Most preferred are alkyl- and/or alkylamidopropylbetaines where the alkyl substituent is a lauryl group. Advantageously lauramidopropyl betaine is used.
  • amphoteric surfactants are preferably contained in an amount of 0.5 to 15 % by weight, more preferably 1 .0 to 15 % by weight, still more preferably 1.0 to 12.5 % by weight, most preferably 1 .5 to 10 % by weight, relative to the total weight of the composition.
  • the values are referring to the active content of the amphoteric surfactants.
  • composition of the present invention contains at least one cationic polymer, which contributes to the conditioning effect of hair.
  • cationic polymers of natural origin or synthetic origin may be used.
  • the cationic polymers are chosen from the group cationic polysaccharides, vinyl monomer containing copolymers, vinylpyrrolidone containing copolymers and cationic proteins.
  • cationic polymers of natural origin are guar molecules modified in such a way that the cationic substituents are introduced or substituents are introduced which are cationic at specific pH values, specifically at those pH values of the hair conditioning compositions. It is preferred if the modified guar molecule is guar hydroxypropyltrimonium chloride.
  • Another class of cationic polymers which can also be used in the present invention are cationic cellulose polymers. Similar to the guar polymer, the substituents introduced into cellulose molecules lead to cellulose molecules having cationic qualities.
  • a typical example is polyquaternium 10 (e.g. JR 30M® obtained from Amerchol company), which is also called cellulose 2-(2-hydroxy- 3-(trimethylammonio)propoxy)ethyl ether chloride.
  • One or more cationic polymers of natural origin can be used according to the present invention. However, it is preferred to use a combination of cationic polymers of natural origin. Even more preferable is a combination of guar hydroxypropyltrimonium chloride and polyquaternium-10.
  • polyquaternium 74 is an acrylic / methacrylamide propyldimethylammonium chloride / hydroxypropyltrimethylammonium copolymer.
  • the total content of one or more cationic polymer(s) ranges from 0.01 to 1.5 % by weight, preferably 0.05% to 1 % by weight, relative to the total weight of the composition.
  • the values are referring to the active content of the cationic polymers.
  • the cleansing compositions contain components influencing the consistency of the composition. By the addition of these components the viscosity of the composition can be adjusted. These components will be called thickening agents. They function by enlarging the micelles of the surfactants or by swelling the aqueous phase.
  • the thickening agents belong to chemically very different substances, for example electrolytes or ethers, ester or diesters with high ethoxylation, as well as polymeric thickening agents.
  • the thickening of the compositions is achieved by electrolytes, especially sodium chloride.
  • the compositions may be further thickened by the addition of diesters, which are highly ethoxylated.
  • highly ethoxylated means 50 to 300 ethoxy units (EO), preferably 100 to 200 EO units.
  • EO ethoxy units
  • An example which can be advantageously used is PEG-150 distearate.
  • the electrolyte(s) with thickening function is/are used in an amount of 0.01 to 2.0 % by weight, more preferably 0.1 to 1 .0 % by weight, still more preferably 0.3 to 0.8 % by weight, relative to the total weight of the composition.
  • the one or more diester(s) with high ethoxylation is/are used in an amount of 0.01 to 1 .0 % by weight, more preferably 0.05 to 0.8 % by weight, still more preferably 0.08 to 0.5 % by weight, relative to the total weight of the composition.
  • Polymeric thickening agents may also be used according to the present invention.
  • these polymeric thickeners are those which contain monomers selected from acrylic acid, methacrylic acid and derivatives of acrylic acid or methacrylic acid.
  • the polymeric thickeners are in form of Carbopols, like those of the Lubrizol company, for instance Carbopol 980, 981 , 1382, 5984, ETD 2001 , ETD 2020, ETD 2050, Ultrez-10, Pemulen TR1 & TR2, Acrylates Copolymer (trade name Carbopol Aqua SF-1 ) or Acrylates Crosspolymer-4 (trade name Carbopol Aqua SF-2).
  • composition of the present invention may contain cationic surfactants.
  • the cationic surfactants are preferably those which provide the hair with an additional conditioning effect. More preferably, the cationic surfactants are quaternary ammonium salts. Still more preferably, the cationic surfactants are of the fatty acid aminopropyl PG-dimonium chloride phosphate type.
  • cationic surfactants are contained, they are preferably present in an amount of 0.001 to 1 .0 % by weight, more preferably 0.01 to 0.5 % by weight, relative to the total weight of the composition. The values are referring to the active content of the cationic surfactants.
  • nonionic surfactants can also be contained in the compositions of the invention. If nonionic surfactants are used, said surfactants are advantageously alkylglycosides.
  • the nonionic surfactants are preferably used in an amount of 0.05 to 3.0 % by weight, more preferably 0.1 to 2.0 % by weight, relative to the total weight of the composition.
  • the values are referring to the active content of the nonionic surfactants.
  • Silicones especially dimethicones and/or amodimethicones can be used according to the present invention. Dimethicones and/or amodimethicones are especially useful in contributing to a conditioning effect of hair.
  • Silicone fluids can be characterized by their viscosity. Commercial products have a viscosity of between 1 centistokes (est) and 1 ,000,000 est. The lower viscosity products are miscible for example with mineral oil and isopropyl myristate and are useful for aerosol applications. The products having 100 - 500 est are the traditional silicones used as additives in skin care formulations and products characterized by higher viscosities used in barrier products or in hair products.
  • the silicones are preferably dimethicones available as Baysilone M Dimethicone (5,000 - 2,000,000 est) or CB-50M (- 500,000 est at 25°C), both supplied by Momentive; further preferred are Dimethyl Silicone Fluids supplied by Dow Corning like PMX-200 Silicone Fluid (60,000 - 500,000 est) or CB 6634 Fluid (250,000 -650,000 est); further preferred amodimethicones are 8500 Conditioning Agent, 2-8566 Amino Fluid or AP-8087 Fluid supplied by Guangzhou Dongxiong.
  • the total content of one or more dimethicone(s) and/or amodimethicone(s) preferably ranges from 0.1 to 5 % by weight, more preferably 0.5% to 3 % by weight, relative to the total weight of the composition.
  • the values are referring to the active content of the silicones.
  • the hair cleansing composition of the present invention can optionally contain anti-dandruff agents.
  • the anti-dandruff agents suitable for the present invention comprise any anti-dandruff agents known by one skilled in the art for treatment and prevention of dandruff formation.
  • antifungal components are known from prior art that can be used as anti-dandruff agents in cosmetic compositions. Examples of anti-dandruff agents are climbazole, ketoconazole, ciclopirox, piroctone olamine, zinc pyrithione, and selen disulfide.
  • Zinc pyrithione is preferred in the present invention.
  • Anti-dandruff agents are preferably used in an amount of 0.1 to 2.0 % by weight, more preferably 0.2 to 1.0 % by weight, relative to the total weight of the composition. The values are referring to the active content of the antidandruff.
  • the hair cleansing composition of the present invention can comprise preservatives, which are allowed and suitable for cosmetic preparations. However, it is preferred to use of Benzyl Alcohol, Methylisothiazolinone, Methylchloroisothiazolinone, Ethylparaben, Methylparaben, Phenoxyethanol, and mixtures thereof.
  • the preferred preservatives can be used alone or in combination.
  • the total amount of preservative, referring as well to one single preservative as to a combination of preservatives, is from 0.0001 to 5.0 % by weight, preferably 0.0005 to 2.5 % by weight, relative to the total weight of the composition.
  • the values are referring to the active content of the preservatives.
  • the hair cleansing compositions of the present invention can optionally comprise pearlescent agents.
  • pearlescent agents are ethylene glycol mono-stearate, ethylene glycol distearate, polyethylene glycol distearate and mixtures thereof.
  • compositions of the present invention comprise glycol distearate and/or PEG-3 distearate as pearlescent agents.
  • Pearlescent agents are used preferably in an amount of 0.1 to 3 % by weight, more preferably 0.2 to 2 % by weight, relative to the total weight of the composition.
  • the hair cleansing compositions of the present invention can comprise colorants which have to be water soluble.
  • suitable water soluble colorants are CI 19140, CI 42090, CI 14700.
  • a preferred colorant for the present invention is CI 19140.
  • composition of the present invention can be prepared by any technique known or effective to prepare a hair cleansing composition.
  • the process to prepare the composition of the present invention comprises conventional formulating and mixing techniques. For example, the methods as disclosed in DE 202015002188U 1 and CN 101 164520A can be used.
  • compositions of the present invention and a comparative composition are preferably produced with the following procedure (Table 1 shows the detailed composition of the Examples, and Table 3 shows the corresponding trade name and INCI of the compounds):
  • an IKA RW20 digital or IKA Eurostar stir equipment and a stirrer e.g. a paddle stirrer is used.
  • phase B to phase A while slowly stirring, stir at 150 - 250rpm until 40 - 45°C.
  • phase E Finally add phase E while slowly stirring, stir until the composition is cooled down to room temperature.
  • compositions comprising Cymbidium Grandiflorum flower extract at different concentrations ranging from 0.1 to 5.0 % by weight (Examples 1 to 6) are prepared as samples of the present invention, and a blank shampoo is used as the comparative sample, which does not comprise Cymbidium Grandiflorum flower extract at all. Respective test samples are filled in syringes, not revealing any details of the composition therein. Depending on the length of the hair, the amount of sample will be 3-5 ml.
  • a trained hairdresser starts with an initial assessment of the subject's hair to be treated by evaluating and recording the condition of the subject's hair.
  • Comb the hair with wide tooth comb, assess the dry detangling properties. After this, comb the hair with fine tooth comb, and assess the dry combability.
  • the evaluation is based on a 10-point system, "1 point” corresponds to "bad", and "10 points” corresponds to "good”.
  • a value of 5 points is a medium value, corresponding to sufficient qualities.
  • the values of 9 to 6 points give descending values, making it possible to differentiate stepwise between good and sufficient.
  • the values of 4 to 2 points give descending values, making it possible to differentiate stepwise between sufficient and bad.
  • Table 3 wherein the average score based on the 8 evaluation scores is recorded for each sample.
  • an amount of 0.5 % by weight of Cymbidium Grandiflorum flower extract in the respective composition leads to good results regarding gliding of wet hair and an amount of 1.0 % by weight of Cymbidium Grandiflorum flower extract in the respective composition leads to good results regarding softness in wet hair. Combability of wet hair is evaluated best after treatment with compositions containing 2.5 % Cymbidium Grandiflorum flower extract.
  • Cymbidium Grandiflorum flower extract 0.5 % by weight of Cymbidium Grandiflorum flower extract in the respective composition leads to best results concerning combability, gliding, and flowing of hair.
  • Combability in dry hair is evaluated best after the application of a composition containing 1 .0 % by weight of Cymbidium Grandiflorum flower extract.
  • Softness in dry hair is evaluated best after the application of a composition containing 5.0 % by weight of Cymbidium Grandiflorum flower extract, but the application of compositions containing 0.5 to 1 .0 % by weight of Cymbidium Grandiflorum flower extract already lead to good evaluations.
  • compositions containing 5.0 % by weight Cymbidium Grandiflorum flower extract lead to best result concerning moisture of hair, but already compositions with 1 .0 to 2.5 % by weight of Cymbidium Grandiflorum flower extract lead to very good evaluations concerning the moisture of hair.
  • Compositions containing 1 .0 % by weight of Cymbidium Grandiflorum flower extract lead to very good evaluations concerning shine of hair.
  • compositions of the present invention manage to cause a conditioning and moisturizing effect of hair, thus improving combability, gliding and softness in wet and dry hair. Also after application of compositions of the present invention hair does not feel rough or heavy, but instead free flowing. Furthermore, compositions of the present invention improve the shine of hair.

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Abstract

L'invention appartient au domaine cosmétique et concerne une composition de nettoyage des cheveux et son utilisation, la composition comprenant au moins un tensioactif anionique, au moins un tensioactif amphotère, au moins un polymère cationique, et un extrait de fleur de Cymbidium Grandiflorum. La composition permet d'améliorer les propriétés physico-optiques des cheveux, et est facile à rincer après son application sur les cheveux. La composition de la présente invention permet d'hydrater significativement les cheveux qui sont également améliorés en termes de propriétés de glisse, de démêlage et d'anti-rugosité.
PCT/EP2018/064653 2017-06-16 2018-06-04 Composition de nettoyage des cheveux contenant un extrait de fleur de cymbidium grandiflorum WO2018228846A1 (fr)

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PCT/CN2017/088549 WO2018227516A1 (fr) 2017-06-16 2017-06-16 Composition nettoyante pour cheveux contenant un extrait de fleur de cymbidium grandiflorum
CNPCT/CN2017/088549 2017-06-16

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WO2009117626A2 (fr) 2008-03-20 2009-09-24 Abbott Laboratories Procédés de préparation d'agents destinés au système nerveux central qui sont des antagonistes des trpv1
WO2009117625A2 (fr) * 2008-03-21 2009-09-24 Kaya Mcintosh Produits cosmétiques de couleur utilisant des matières naturelles
DE202015002188U1 (de) 2015-03-19 2015-05-06 Beiersdorf Ag Haarshampoo mit verbesserter Pflegeleistung enthaltend Silikone
FR3016126A1 (fr) 2014-01-08 2015-07-10 Isp Investments Inc Utilisation cosmetique d'un extrait d'artemia salina pour proteger la peau des stress thermiques

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Publication number Priority date Publication date Assignee Title
WO2017035766A1 (fr) * 2015-09-01 2017-03-09 Beiersdorf Daily Chemical (Wuhan) Co. Ltd. Composition nettoyante pour cheveux contenant de l'huile de fleur de lotus et son utilisation

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US20060024254A1 (en) * 2004-08-02 2006-02-02 Isp Investments Inc. Personal care compositions
WO2006044193A2 (fr) 2004-10-14 2006-04-27 Isp Investments Inc. Resine de coiffure/modificatrice de rheologie
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