WO2018221381A1 - Mask - Google Patents
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- Publication number
- WO2018221381A1 WO2018221381A1 PCT/JP2018/020040 JP2018020040W WO2018221381A1 WO 2018221381 A1 WO2018221381 A1 WO 2018221381A1 JP 2018020040 W JP2018020040 W JP 2018020040W WO 2018221381 A1 WO2018221381 A1 WO 2018221381A1
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- WO
- WIPO (PCT)
- Prior art keywords
- mask
- side sheet
- exhalation
- sheet
- fiber
- Prior art date
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/14—Other self-supporting filtering material ; Other filtering material
- B01D39/16—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
- B01D39/1607—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous
- B01D39/1623—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous of synthetic origin
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- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62B—DEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
- A62B18/00—Breathing masks or helmets, e.g. affording protection against chemical agents or for use at high altitudes or incorporating a pump or compressor for reducing the inhalation effort
- A62B18/02—Masks
- A62B18/025—Halfmasks
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D13/00—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
- A41D13/05—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches protecting only a particular body part
- A41D13/11—Protective face masks, e.g. for surgical use, or for use in foul atmospheres
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62B—DEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
- A62B18/00—Breathing masks or helmets, e.g. affording protection against chemical agents or for use at high altitudes or incorporating a pump or compressor for reducing the inhalation effort
- A62B18/02—Masks
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62B—DEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
- A62B19/00—Cartridges with absorbing substances for respiratory apparatus
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62B—DEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
- A62B23/00—Filters for breathing-protection purposes
- A62B23/02—Filters for breathing-protection purposes for respirators
- A62B23/025—Filters for breathing-protection purposes for respirators the filter having substantially the shape of a mask
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62B—DEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
- A62B9/00—Component parts for respiratory or breathing apparatus
- A62B9/003—Means for influencing the temperature or humidity of the breathing gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/14—Other self-supporting filtering material ; Other filtering material
- B01D39/16—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
- B01D39/18—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being cellulose or derivatives thereof
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D2500/00—Materials for garments
- A41D2500/30—Non-woven
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/02—Types of fibres, filaments or particles, self-supporting or supported materials
- B01D2239/0216—Bicomponent or multicomponent fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/04—Additives and treatments of the filtering material
- B01D2239/0414—Surface modifiers, e.g. comprising ion exchange groups
- B01D2239/0421—Rendering the filter material hydrophilic
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/04—Additives and treatments of the filtering material
- B01D2239/0435—Electret
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/06—Filter cloth, e.g. knitted, woven non-woven; self-supported material
- B01D2239/0604—Arrangement of the fibres in the filtering material
- B01D2239/0622—Melt-blown
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/06—Filter cloth, e.g. knitted, woven non-woven; self-supported material
- B01D2239/065—More than one layer present in the filtering material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/10—Filtering material manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/12—Special parameters characterising the filtering material
- B01D2239/1291—Other parameters
Definitions
- the present invention relates to a mask that covers at least the mouth and / or nose of a human body. More specifically, the present invention relates to a mask that absorbs and diffuses water vapor and water droplets from exhaled air to prevent wetting and stickiness and can give a cool feeling to the wearer.
- Patent Document 1 Japanese Patent Application Laid-Open No. 2004-357871
- Patent Document 1 Japanese Patent Application Laid-Open No. 2004-357871
- a face mask is disclosed.
- Patent Document 2 Japanese Patent Application Laid-Open No. 2006-325688
- Patent Document 2 Japanese Patent Application Laid-Open No. 2006-325688
- a mask comprising a hydrophobic fabric on at least a surface that touches the face is disclosed.
- Patent Document 1 since the gauze is folded so as to have a plurality of layers, heat tends to be accumulated depending on the thickness. As a result, the moisture inside the mask becomes excessively high due to moist exhalation from the mouth and nose when used for a long time, and as a result, the surface that is in contact with the face of the mask gets wet and sticks, making it uncomfortable. . In patent document 2, since the cloth which has hydrophobicity is provided in the surface which touches a face, there exists a problem that the water
- an object of the present invention is to provide a mask that efficiently absorbs water vapor or water droplets from exhaled breath, prevents wetting and stickiness at the contact portion of the wearer, and does not impair comfort even when used for a long time. There is.
- a mesh-like non-woven fabric containing hydrophilic fibers is used as an exhalation side as a layer on the human body side of the covering part at the mouth and / or nose of the human body.
- a mesh-like non-woven fabric containing hydrophilic fibers is used as an exhalation side as a layer on the human body side of the covering part at the mouth and / or nose of the human body.
- a mask including a covering portion that covers at least the mouth and / or nose of a human body, wherein the covering portion includes at least an expiration side sheet including hydrophilic fibers as a human body layer, and the expiration side sheet includes a wire
- the mask which is a mesh-like nonwoven fabric comprised by the shape part.
- the average line width of the linear portion of the exhalation-side sheet is 0.1 to 3.0 mm (preferably 0.2 to 2.5 mm, more preferably 0.3 to 2. 0 mm, more preferably 0.5 to 2.0 mm).
- an exhalation-side sheet containing hydrophilic fibers is provided as a human-side layer of the mouth and / or nose cover of the human body, and the exhalation-side sheet is made into a mesh-like nonwoven fabric.
- the mask of the present invention not only absorbs moisture derived from sweat generated on the face in contact with the mask, and can reduce the feeling of stickiness and sweating caused by sweat, but also reduces moisture content.
- a refreshing sensation can be provided by utilizing the heat of vaporization generated during diffusion and drying.
- the mask of the present invention since the mask of the present invention has high drying properties, it is possible to suppress the growth of bacteria inside the mask due to sweat and saliva, and to reduce the odor caused by the propagation of bacteria. is there.
- the mask of the present invention is useful as a summer mask because it gives a refreshing feeling to the wearer and can reduce the wearer's discomfort even in summer.
- FIG. 1 is a schematic plan view showing a mask according to a first embodiment of the present invention. It is a schematic sectional drawing which shows an example of the lamination sheet used by 1st Embodiment. It is an enlarged photograph for demonstrating the arrangement
- FIG. 6 is a schematic development view of the mask of FIG. 5.
- the mask refers to a mask that covers at least one of the mouth and / or nose (particularly the nostril) of the human body, and it does not matter whether there is a fixing part such as a band for fixing to the face. Furthermore, the mask may cover portions other than the mouth and nose of the human body.
- FIG. 1 is a schematic plan view showing a mask according to the first embodiment of the present invention.
- FIG. 2 is a schematic cross-sectional view showing an example of a laminated sheet used in the mask according to the first embodiment.
- FIG. 3 is an enlarged photograph for explaining the arrangement of the fibers of the mesh nonwoven fabric of the breath side sheet used in the first embodiment, and
- FIG. 4 is an outline for explaining the mesh nonwoven fabric of FIG. It is an enlarged plan view.
- a pleated mask 100 has a horizontally long covering portion 110 having a size capable of covering the mouth and nose, and both end portions in the lateral direction of the covering portion. And a fixed portion 150 provided. At least one pleat 130 can be formed on the covering portion 110 by a fold extending in the lateral direction. Since the covering portion 110 extends in the vertical direction by the pleats 130, the covering portion 110 can be adapted to various face sizes.
- the fixing portion 150 can be made of, for example, a string-like stretchable material, and is attached by ultrasonic waves or the like at both ends of the covering portion 110.
- the covering part 110 can incorporate a wire 140, for example, along its upper side.
- a wire 140 for example, along its upper side.
- an elastic reinforcing portion 160 can be incorporated in the covering portion 110 in parallel with the pleats at a substantially central portion of the covering portion.
- the elastic reinforcing portion may be, for example, a longitudinal elastic member having a width of 1 to 6 mm and a length of about 70 to 155 mm.
- the elastic member include various resins (thermoplastic resin, thermosetting resin).
- polyester resins such as polyethylene terephthalate (PET) and polybutylene terephthalate (PBT); polyolefin resins such as polyethylene, polypropylene and polybutylene; polyamide resins; polycarbonate (PC) resins; polystyrene resins; SEP, SEPS, SEBS, A thermoplastic elastomer such as SEEPS; a polyurethane resin; an epoxy resin; or a mixture of these resins as appropriate.
- PET polyethylene terephthalate
- PBT polybutylene terephthalate
- polyolefin resins such as polyethylene, polypropylene and polybutylene
- polyamide resins polycarbonate (PC) resins
- polystyrene resins SEP, SEPS, SEBS
- SEEPS thermoplastic elastomer
- SEEPS polyurethane resin
- epoxy resin an epoxy resin
- mixture of these resins as appropriate.
- the covering portion of the mask By providing the elastic reinforcing portion 160, it becomes possible for the covering portion of the mask to have a radial shape in the outward direction, the water vapor from the exhalation spreads radially, and the water vapor can be more evenly adsorbed to the mask covering portion. Moreover, the hollow space in a mouth can be expanded and a mask wearer's comfort level can be improved.
- the covering portion 110 includes a laminated sheet 120.
- the laminated sheet 120 is composed of a plurality of sheet layers.
- the laminated sheet 120 includes an exhalation-side sheet 121 that covers the mouth and nose, a filter sheet 122 that forms an intermediate layer, It is preferable to include a top sheet 123 that forms an outer layer opposite to the exhalation side.
- Each of these layers may be provided with two or more sheets in each layer.
- the exhalation side sheet is composed of a mesh-like nonwoven fabric.
- the vertical direction corresponds to the vertical direction of the face
- the horizontal direction corresponds to the horizontal direction of the face.
- the mesh nonwoven fabric has a three-dimensional three-dimensional structure formed by a linear portion formed of discontinuous fibers, and has a thin portion (fiber sparse portion) and a thick portion (fiber Are densely arranged at predetermined intervals.
- the linear portion means a fiber assembly in which fibers are formed substantially uniformly by a continuous thick portion.
- FIG. 3 there are a vertical line portion in which the thick portions are arranged in the vertical direction and a horizontal line portion in which the thick portions are arranged in the horizontal direction, and the vertical line portions and the horizontal line portions intersect each other, and the mesh A non-woven fabric is formed. Further, in the mesh nonwoven fabric, there are gaps between the vertical line parts and between the horizontal line parts, respectively, and the overlap between the vertical line parts and the gap between the horizontal line parts is a thin part. Become.
- discontinuous fibers having a predetermined length are gently oriented in the longitudinal direction or the lateral direction.
- the vertical linear portion and the horizontal linear portion may have the same or different orientation.
- the fibers are more uniformly oriented in the horizontal linear portion than in the vertical linear portion of the mesh nonwoven fabric.
- FIG. 4 conceptually illustrates the mesh nonwoven fabric of FIG.
- the vertical direction corresponds to the vertical direction of the face
- the horizontal direction corresponds to the horizontal direction of the face
- the exhalation-side sheet 121 is a mesh-like fiber assembly, and includes a thin portion 124 and a thick portion 125 composed of a vertical line portion 126 and a horizontal line portion 127.
- the vertical linear portions 126 are arranged in the vertical direction of the face
- the horizontal linear portions are arranged in the horizontal direction of the face.
- the exhalation-side sheet has the following mechanism.
- water vapor having a relative humidity of 100% at about 32 ° C. is present in the mouth portion due to the body temperature of the human body.
- the water vapor that cannot be present at a relative humidity exceeding 100% according to the temperature of the outside air for example, 25 ° C.
- the temperature of the outside air for example, 25 ° C.
- seat 121 is excellent in water absorption, a diffusivity, and quick-drying, generation
- the horizontal linear portion (the horizontal direction of the face) has a higher fiber orientation than the vertical linear portion (the vertical direction of the face)
- water vapor and liquid droplets are generated in the vertical direction of the sheet (the vertical direction of the face).
- Examples of the mesh nonwoven fabric forming the exhalation-side sheet 121 include nonwoven fabrics formed by combining linear portions (for example, linear portions, curved portions) such as vertical, horizontal, and diagonal, and these nonwoven fabrics are According to the overlap of the linear portions, the thin portion (or the opening portion) and the thick portion are provided.
- a gentle fiber flow is formed along the longitudinal direction of the line.
- the gentle fiber flow is, for example, a fiber in which each of more than half of the discontinuous fibers is oriented within a range of, for example, about ⁇ 30 ° with respect to the longitudinal direction of the linear portion. It may be a flow.
- the mesh-like nonwoven fabric may have a substantially polygonal thin portion by combining linear portions.
- the substantially polygonal thin portion include thin portions such as a substantially triangular shape, a substantially quadrangular shape, and a substantially pentagonal shape.
- the exhalation side sheet may have a lattice shape having a substantially rectangular thin portion as shown in FIG.
- the exhalation-side sheet can appropriately set the width of the linear portion according to the shape, but from the viewpoint of achieving both moisture absorption and diffusion and air permeability, the average line width of the linear portion is Any of the linear portions in the direction may preferably be in the range of 0.1 to 3.0 mm, more preferably in the range of 0.2 to 2.5 mm, and still more preferably in the range of 0.3 to 2.0 mm. More preferably, it may be in the range of 0.5 to 2.0 mm.
- the average line width of the linear portion means the width of the linear fiber portion excluding the thin portion, and shows, for example, the widths of the vertical linear portion 126 and the horizontal linear portion 127 shown in FIG.
- the line width is preferably measured for each direction of the linear portion, and the line width of the linear portion may be an average value in all directions.
- the value measured by the method described in the Example mentioned later may be sufficient as the line
- the line widths are substantially equal in each direction (for example, the vertical direction and the horizontal direction).
- the thickness of the exhalation-side sheet is, for example, 0.25 to 1.00 mm, preferably 0.30 to 0.80 mm, from the viewpoint of achieving both moisture absorption and diffusivity, breathability and moisture release to the outside. More preferably, it may be 0.35 to 0.60 mm.
- the thickness of the exhalation side sheet is related to the thickness of the linear part of the mesh nonwoven fabric. The thicker the film, the better the water absorption, but the air permeability and the water release to the outside are suppressed. In addition, thickness is a value measured by the method described in the below-mentioned Example.
- the product of the average line width (mm) and the thickness (mm) of the exhalation side sheet that is, the average
- the line width ⁇ thickness (mm ⁇ mm) may be 0.025 to 1.8, preferably 0.1 to 1.5, more preferably 0.15 to 1.2, and still more preferably 0.00. It may be 2 to 1.0.
- the average line width ⁇ thickness (mm ⁇ mm) preferably satisfies the above range in any average line width of the linear portion in each direction.
- the basis weight of the breath side sheet is, for example, 30 to 100 g / m 2 , preferably 32 to 90 g / m 2 , and more preferably May be from 35 to 80 g / m 2 .
- the basis weight is a value measured by the method described in Examples described later.
- the air permeability of the exhalation side sheet may be, for example, 150 to 300 cm 3 / cm 2 / s, preferably 160 to 280 cm 3 / cm 2 / s, more preferably, from the viewpoint of ensuring ease of breathing. May be 170 to 250 cm 3 / cm 2 / s.
- the air permeability is a value measured by the method described in Examples described later.
- the water absorption rate may be within 5.0 seconds, preferably within 3.0 seconds, more preferably It may be within 1.0 seconds.
- a water absorption rate is a value measured by the method described in the below-mentioned Example.
- the diffusibility of water after water absorption (after 5 seconds of dropping of water droplets) in the exhalation side sheet can be increased by rapidly diffusing water in the exhalation side sheet.
- the area represented by the product of the diffusion length in the left-right direction (mm) and the diffusion length in the vertical direction (mm) as the diffusibility in the mask may be preferably 400 mm 2 or more, more preferably It may be 430 mm 2 or more, more preferably 450 mm 2 or more.
- the upper limit of diffusibility is not specifically limited, For example, about 900 mm ⁇ 2 > may be sufficient.
- the diffusivity is a value measured by the method described in the examples described later.
- the shorter diffusion length in the up and down direction of the mask and the longer diffusion length in the left and right direction the upward water rise is suppressed. It is possible to more effectively suppress the occurrence of fogging.
- the evaporation rate of water after water absorption of the exhalation-side sheet is preferably larger from the viewpoint of achieving a decrease in heat due to heat of vaporization, and may be, for example, 51% or more, preferably 55% or more, more preferably It may be 60% or more.
- the upper limit of the evaporation rate is 100%, but may be about 90%, for example.
- an evaporation rate is a value measured by the method described in the below-mentioned Example.
- the water retention of the exhalation side sheet can be appropriately set according to the water absorption rate and the evaporation rate of the exhalation side sheet, but the water retention amount per 100 cm 2 of the exhalation side sheet is, for example, about 1.6 to 7.2 g, Preferably, it may be about 2.4 to 6.4 g, more preferably about 3.2 to 5.6 g. Further, the water retention rate of the exhalation side sheet (percentage of the weight of the exhalation side sheet 100 cm 2 ) may be, for example, about 500 to 1400%, preferably about 600 to 1200%, more preferably about 700 to 1000%. .
- the manufacture of the mask 100 is not particularly limited, but it is preferable to carry out the continuous production in terms of productivity, manufacturing cost, and the like.
- the exhalation-side sheet 121, the filter sheet 122, and the top sheet 123 are each unwound by a roll and laminated in this order, and thereafter, pleating with a folded plate, ultrasonic sealing or heat sealing at the top, bottom, left and right ends,
- the mask 100 may be manufactured by continuously attaching the fixing portion 150 by ultrasonic sealing or heat sealing.
- the mesh nonwoven fabric forming the breath side sheet 121 is manufactured so that the left-right direction of the mask is the MD direction of the nonwoven fabric.
- MD direction is a flow direction of the nonwoven fabric at the time of manufacture, and MD direction can be judged with the orientation direction of a fiber.
- FIG. 5 is a view showing a mask according to the second embodiment of the present invention
- FIG. 6 is a development view of the mask according to the second embodiment.
- the three-dimensional mask 200 is a three-dimensional mask worn so as to cover the mouth and the nose, and includes a covering portion 210 and a covering portion. 210 and a fixing part 250 formed of a stretchable nonwoven fabric or the like.
- the mask 200 is formed by joining the joining portions 261 and 262 at the tips of a pair of mask pieces 201 and 202 by heat sealing or the like as shown in FIG. Can be formed.
- a pair of mask pieces 201 and 202 shown in FIG. 6 is obtained by cutting the joint portion 210 and the fixing portion 250 into the shape shown in FIG.
- reference numeral 251 denotes a cut (hole for passing an ear) provided to form the fixing portion 250.
- the covering portion 210 can include a laminated sheet similar to the laminated sheet 120 used in the first embodiment. That is, the top sheet 123 is provided as the outermost layer, the filter sheet 122 is provided as the intermediate layer, and the expiration side sheet 121 is provided as the innermost layer. Also in the mask according to the second embodiment, moisture derived from exhalation can be quickly absorbed by the mesh-like nonwoven fabric of the exhalation side sheet, and the moisture is diffused inside the exhalation side sheet and then evaporated. It is possible to obtain a refreshing feeling by utilizing the heat of vaporization.
- the mask of the present invention can be formed by various embodiments in addition to the above-described two embodiments.
- the mask should just be equipped with the exhalation side sheet
- the mask of the present invention is a therapeutic mask for sleep apnea syndrome (for example, a nasal mask) used for CPAP therapy suitable for treatment of sleep apnea syndrome, NIPPV therapy suitable for ventilation failure, and the like. , Full face mask, etc.).
- a mask for treating sleep apnea syndrome includes, for example, a mask body, a fixing means for fixing the mask body to the wearer, and a tube attachment port for introducing a humid air flow into the mask body (for example, a plastic member).
- an exhalation-side sheet is detachably attached to the inner surface of the mask body using a hook-and-loop fastener or the like as a layer on the human body side.
- the exhalation side sheet has an opening corresponding to the tube attachment port.
- the thin exhalation side sheet may protrude outside the mask. Even when the mask and the wearer's wearing part are in contact with each other through the exhalation side sheet, the thin exhalation side sheet can maintain the airtightness of the mask and the wearer and protrudes outside the mask of the exhalation side sheet It is possible to release moisture from the part to the outside.
- the mesh nonwoven fabric used in the exhalation-side sheet is a dry nonwoven fabric from the viewpoint of ensuring handleability (for example, breakage resistance at the time of wearing) and water absorption and flexibility, and can be obtained by the following method, for example. .
- the fiber length of the constituent fibers may be about 20 to 70 mm, preferably about 25 to 65 mm, more preferably about 30 to 60 mm, and further preferably about 35 to 55 mm. . It is possible to distinguish it from a wet non-woven fabric (usually the fiber length is 10 mm or less) in which fiber entanglement works disadvantageously in the production process.
- a web is formed from a predetermined fiber assembly by a card method or an airlaid method.
- the fiber assembly includes at least hydrophilic fibers, and may include other fibers (such as heat-fusible fibers and functional fibers) as necessary.
- the web shape include a random web, a semi-random web, and a parallel web. Among these, a semi-random web is preferable from the viewpoint of improving the fiber orientation of the linear portion forming the mesh.
- the obtained web is then bonded to each other in order to give practical strength.
- a bonding method chemical bonding (for example, chemical bonding method), thermal bonding (for example, thermal bonding method), or mechanical bonding (for example, hydroentanglement method, needle punching method) can be used.
- thermal bonding for example, thermal bonding method
- mechanical bonding for example, hydroentanglement method, needle punching method
- hydroentanglement method needle punching method
- a high-pressure water stream is jetted from a nozzle with fine holes on a porous support on which a web is placed. Are entangled and combined.
- a plurality of porous supports may be used, for example, the first porous support is passed through to entangle the fibers having a three-dimensional shape, the second porous support is passed through, and the nonwoven fabric is passed through.
- a desired mesh shape may be given.
- the second porous support has a pattern shape corresponding to a desired mesh shape.
- the obtained mesh nonwoven fabric may be further thermally bonded as necessary to increase the strength of the nonwoven fabric.
- the fiber diameter of the fibers forming the mesh nonwoven fabric is, for example, about 0.5 to 30.0 ⁇ m, preferably 2.0 to 25.0 ⁇ m, from the viewpoint of improving water absorption between fibers as well as the fiber surface. May be about 5.0 to 20.0 ⁇ m.
- the fiber diameter of a fiber is a value measured by the method described in the Example mentioned later.
- the hydrophilic fiber contained in the exhalation-side sheet is not particularly limited as long as the liquid can be retained, and natural fiber, regenerated fiber, semi-synthetic fiber, and synthetic fiber can be used.
- the hydrophilic fiber may be a fiber imparted with hydrophilicity by post-processing. As the hydrophilic fiber, only one kind may be used alone, or two or more kinds may be used in combination. Examples of hydrophilic natural fibers include natural cellulose fibers such as cotton, hemp, wool, and pulp. Examples of hydrophilic regenerated fibers include regenerated cellulose fibers such as rayon, polynosic, and cupra. Examples of hydrophilic semisynthetic fibers include semisynthetic cellulose fibers such as acetate and triacetate.
- hydrophilic synthetic fibers include synthetic fibers composed of a thermoplastic resin having hydrophilic functional groups such as hydroxyl groups, carboxyl groups, and sulfonic acid groups, and / or hydrophilic bonds such as amide bonds. Is a suitable example.
- the hydrophilic fiber may preferably be a cellulose-based fiber such as natural cellulose fiber, regenerated cellulose fiber, or semi-synthetic cellulose fiber. More preferably, it may be rayon (for example, viscose rayon) of regenerated cellulose fibers.
- the hydrophilic fiber may preferably be a polyamide-based resin of synthetic fibers.
- the polyamide resin include aliphatic polyamides such as polyamide 6, polyamide 66, polyamide 11, polyamide 12, polyamide 610, polyamide 612, polyamide 92, polyamide 9C (polyamide comprising nonanediamine and cyclohexanedicarboxylic acid) and
- the copolymer is a semi-aromatic polyamide synthesized from an aromatic dicarboxylic acid and an aliphatic diamine such as polyamide 9T (polyamide composed of nonanediamine and terephthalic acid) and a copolymer thereof.
- the ratio of hydrophilic fibers may be, for example, 50% by weight or more, preferably 60% by weight or more, and more preferably May be 70% by weight or more.
- the upper limit is not particularly limited, and may be composed entirely of hydrophilic fibers, but may be, for example, 95% by weight or less, preferably 90% by weight or less, and more preferably 85% by weight. % Or less.
- the fiber aggregate preferably contains, for example, heat-fusible fibers as other fibers from the viewpoint of improving the strength of the nonwoven fabric without being binder-free.
- the heat-fusible fiber only needs to have a melting point or heat distortion temperature that can be melted at the treatment temperature in thermal bonding, for example, a low-melting resin non-composite fiber having a melting point or heat distortion temperature lower than the treatment temperature. It may be a composite resin of the low melting point resin and a high melting point resin having a higher melting point than the low melting point resin.
- a composite fiber having a core-sheath structure in which a low melting point resin is a sheath component and a high melting point resin is a core component is preferable.
- the low-melting point resin and the high-melting point resin can be appropriately selected from polyolefin fibers such as polyethylene and polypropylene, polyester fibers such as polyethylene terephthalate, polybutylene terephthalate, and polylactic acid, depending on the treatment temperature in thermal bonding. .
- the fineness of the heat-fusible fiber may be, for example, about 1.0 to 3.5 dtex, preferably about 1.3 to 3 dtex, more preferably about 1.5 to 2.5 dtex.
- the fiber length of the heat-fusible fiber may be, for example, about 30 to 80 mm, preferably about 35 to 60 mm, from the viewpoint of satisfactorily arranging the fibers in the linear portion.
- the weight ratio of the hydrophilic fiber to the heat-fusible fiber may be, for example, 50/50 to 95/5 from the viewpoint of ensuring strength while ensuring sufficient water absorption. It may be 60/40 to 90/10, more preferably 70/30 to 85/15.
- the intermediate layer may be provided as necessary, and when provided, various functions can be imparted according to the purpose of the mask.
- the mask preferably includes a filter sheet as an intermediate layer.
- the filter sheet is not particularly limited as long as it has the ability to filter pollen and dust.
- Porous membranes for example, PTFE (polytetrafluoroethylene) porous membranes
- non-woven fabrics manufactured by the various methods described above may be used. Can be mentioned.
- a filter sheet that has been charged (or electreted) is preferred.
- the charging treatment of the filter sheet can be performed by a known or common method. Since the exhalation-side sheet of the present invention has high water absorption, even if moisture derived from exhalation is present, it is possible to suppress a decrease in chargeability of the filter sheet.
- the nonwoven fabric is preferably a nonwoven fabric by a spunbond method, a thermal bond method, a spunlace method or a needle punch method, a nonwoven fabric (preferably a nanofiber nonwoven fabric) by a melt blow method or an electrospinning method, or a nonwoven fabric made of sea-island type fibers.
- a non-woven fabric (preferably nanofiber non-woven fabric) obtained by dissolving and removing sea components from can be used. More preferably, the non-woven fabric may be a melt-blown non-woven fabric that has been charged or a needle punched non-woven fabric that has been frictionally charged. Good.
- the fiber constituting the filter sheet can be appropriately selected according to the purpose of use of the mask.
- polyolefin fibers such as polyethylene and polypropylene
- polyester fibers such as polyethylene terephthalate, polybutylene terephthalate, polylactic acid, and acrylic fibers.
- the fibers constituting the melt-blown nonwoven fabric subjected to the charge treatment include polypropylene fibers, polylactic acid fibers, polybutylene terephthalate fibers, and the like, and polypropylene fibers are more preferable.
- the fibers constituting the frictionally charged needle punched nonwoven fabric include acrylic fibers, polypropylene fibers, and polyethylene terephthalate fibers.
- the pressure loss of the filter sheet may be, for example, about 0 to 30 Pa, preferably about 1 to 25 Pa, more preferably 2 to 20 Pa. It may be a degree.
- the pressure loss of a filter sheet is a value measured by the method described in the Example mentioned later.
- the collection efficiency of the filter sheet is, for example, 80% or more (for example, 80% to 99.99%). It may be 85% or more, more preferably 90% or more.
- the collection efficiency of a filter sheet is a value measured by the method described in the Example mentioned later.
- the top sheet is used as a reinforcing layer or a support layer of the breath side sheet having a mesh shape.
- a known or conventional nonwoven fabric or the like can be used depending on the purpose or configuration.
- a nonwoven fabric by a spun bond method, a melt blow method, a thermal bond method, a spun lace method or a chemical bond method can be used.
- the nonwoven fiber structure was observed using a scanning electron microscope. The diameter of 100 fibers selected at random from an electron micrograph was measured, the number average fiber diameter was determined, and the average fiber diameter was determined.
- the exhalation-side sheet thickness was measured according to 6.1 of JIS L 1913 “General nonwoven fabric test method”. Specifically, a razor ("Feather Razor S single blade", manufactured by Feather Safety Razor Co., Ltd.) is parallel to the thickness direction of the exhalation side sheet and perpendicular to the machine direction (MD) direction. ) Are used to cut any 10 locations on the exhalation-side sheet, each cross-section is observed with a digital microscope, the thickness of each cross-section is measured, and the average value is calculated to obtain the thickness (mm )
- the water retention rate of the breath side sheet was measured according to 6.9.2 of JIS L 1913 “General nonwoven fabric test method”. Specifically, three test pieces having a size of 100 mm ⁇ 100 mm square were collected, and the mass (mass before immersion) was measured. Next, the test piece was immersed in water for 15 minutes, then pulled up, suspended for 1 minute in air with one corner up, and the surface water was cut off, and then the mass (mass after immersion) was measured. did.
- the water absorption rate of the exhalation-side sheet was measured according to the dropping method defined in 7.1.1 of JIS L 1907 “Fabricity water absorption test method”. Specifically, 0.05 g / drop of water droplet is dropped on the obtained exhalation-side sheet with a burette from a height of 10 mm, and the time (seconds) until the specular reflection disappears when the water droplet is absorbed. ) was measured.
- a sheet obtained by cutting the exhalation-side sheet into 10 cm ⁇ 10 cm was prepared, and this was left on a horizontal table.
- colored water was prepared by adding 1 g of ink ("PILOT ink RED (INK-350-R)", manufactured by Pilot Corporation) to 100 g of ion-exchanged water.
- 1 drop (0.05 g) of colored water was dropped with a dropper from 1 cm above (over the sky) of the sheet left still to the center of the sheet. Five seconds after the dropping, the length of the color water diffused in the plane, that is, the vertical diffusion length (mm) and the horizontal diffusion length (mm) in the mask was determined.
- the product of the diffusion length in the vertical direction (mm) and the diffusion length in the left-right direction (mm) was defined as the diffusivity value.
- a larger diffusivity value means that the liquid is diffused over a wider area.
- the longer / shorter diffusion length was calculated as the value of diffusion anisotropy in the horizontal direction and vertical direction of the mask.
- Air permeability (cm 3 / cm 2 / s) was measured by the Frazier method according to JIS L 1096 “Fabric and knitted fabric test method” 8.26.
- a fine differential pressure gauge was placed between the upstream side and the downstream side of the measurement cell in the filter medium evaluation apparatus, and the differential pressure (pressure loss (Pa)) at a flow rate of 30 liters / minute was measured.
- Example 1 (1) Production of breath side sheet First, a rayon fiber (“Hope”, manufactured by Ohmi Kenshi Co., Ltd.) 80% by weight with a fineness of 1.7 dtex, an average fiber diameter of 12.0 ⁇ m, and a fiber length of 40 mm, and a fineness of 1.7 dtex, average fiber 20% by weight of a heat-fusible fiber having a diameter of 15.3 ⁇ m and a fiber length of 51 mm (core-sheath composite fiber with a core of polypropylene and a sheath of polyethylene, “HR-NTW”, manufactured by Ube Eximo Co., Ltd.) is semi-cured using a card method. A random web was made.
- a rayon fiber (“Hope”, manufactured by Ohmi Kenshi Co., Ltd.) 80% by weight with a fineness of 1.7 dtex, an average fiber diameter of 12.0 ⁇ m, and a fiber length of 40 mm, and a fineness of 1.7 dtex, average fiber 20% by weight of
- the produced semi-random web was placed on a punching drum support having a hole area ratio of 25% and a hole diameter of 0.3 mm, and continuously transferred in the longitudinal direction at a speed of 5 m / min.
- the confounding process was performed by jetting water flow.
- two nozzles having orifices with a hole diameter of 0.10 mm provided at intervals of 0.6 mm along the width direction of the web are used (distance 20 cm between adjacent nozzles).
- the water pressure of the high-pressure water stream injected from the nozzle was set to 3.0 MPa, and the water pressure of the high-pressure water stream injected from the nozzles in the second row was set to 5.0 MPa (Table WJ).
- the fiber diameter is 0.90 mm, 10 mesh / inch, and the flat weave is placed on the flat net support from the surface opposite to the surface on which the surface WJ is applied.
- the entanglement process was performed to transfer the unevenness of the net onto the surface of the nonwoven fabric.
- This entanglement process uses three nozzles provided with orifices having a hole diameter of 0.10 mm at intervals of 0.6 mm along the width direction of the web, all under the condition of a high pressure water flow of 4.0 MPa. (Back WJ).
- Example 1 shows various evaluation results of the exhalation side sheet.
- Example 2 Except for changing the basis weight and thickness of the semi-random web in the production of the exhalation-side sheet to the values shown in Table 1, the exhalation-side sheet produced by the same method as in Example 1 was used, and otherwise the same as in Example 1 A mask was prepared by the method. The evaluation results are shown in Table 1.
- Example 3 As a net support used for the back WJ, an exhalation-side sheet produced by the same method as in Example 1 except that a fiber diameter of 0.90 mm, 13 meshes / inch, and plain weave was used. A mask was produced by the same method.
- Example 4 As the net support used for the back WJ, an exhalation-side sheet produced by the same method as in Example 2 was used except that a fiber diameter of 0.90 mm, 13 meshes / inch, and plain weave was used. A mask was produced by the same method.
- Example 5 As the net support used for the back WJ, an exhalation-side sheet produced by the same method as in Example 1 except that a fiber diameter of 1.20 mm, 12 meshes / inch, and plain weave was used. A mask was produced by the same method.
- Example 6 As a net support used for the back WJ, an exhalation-side sheet produced by the same method as in Example 2 was used except that a fiber diameter of 1.20 mm, 12 meshes / inch, and plain weave was used. A mask was produced by the same method.
- Example 7 As a net support used for the back WJ, an exhalation-side sheet produced by the same method as in Example 1 except that a fiber diameter of 0.65 mm, 25 meshes / inch, and plain weave was used. A mask was produced by the same method.
- Example 8 As the net support used for the back WJ, an exhalation-side sheet produced by the same method as in Example 2 was used except that a fiber diameter of 0.65 mm, 25 meshes / inch, and plain weave was used. A mask was produced by the same method.
- Example 9 As the net support used for the back WJ, an exhalation-side sheet produced by the same method as in Example 1 except that a fiber diameter of 0.90 mm, 6 meshes / inch, and plain weave was used. A mask was produced by the same method.
- Example 1 A mask was prepared in the same manner as in Example 1 except that a polypropylene thermal bond nonwoven fabric (“NRIP (HYCOMFORT)”, manufactured by Rengo Non-Woven Products Co., Ltd.) was used as the breath side sheet.
- NRIP HYCOMFORT
- Comparative Example 1 since the hydrophobic polypropylene thermal bond nonwoven fabric is used as the breath side sheet, the feeling of wearing the mask is clearly felt even though the intermediate layer and the surface sheet are the same. It is evaluated that there is no further cool feeling. Moreover, when the gauze mask is used in Comparative Example 2, the basis weight of the mask is large and the thickness is large, so that the water retention rate is lower than that of the example and the air permeability is lower than that of the example. For this reason, even though the amount of water retention is high, it is evaluated that a sticky feeling can be clearly felt when wearing a mask.
- Comparative Example 3 Although the nonwoven fabric composed of the same material as that of Example 1 was used for the breath side sheet, the nonwoven fabric was clogged and formed with a linear portion because there was no thin portion. Not applicable to mesh-like nonwoven fabrics. For this reason, both the diffusibility and the evaporation rate of the mask are low values as compared with the example. For this reason, the feeling of wearing the mask is evaluated as having no cool feeling.
- the mask of the present invention can be used as, for example, a flat mask other than the pleated mask and the three-dimensional mask as described above.
- a mask can be used, for example, for pollen countermeasure, cold / virus countermeasure, PM2 .5 can be used as household masks for countermeasures, medical masks such as surgical masks, and industrial masks such as dust masks such as N95 masks certified by the US NISHH.
- the mask of the present invention can be used as a treatment mask for sleep apnea syndrome.
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Abstract
Description
〔態様1〕
人体の少なくとも口元および/または鼻元を被覆する被覆部を備えるマスクであって、前記被覆部は、人体側の層として親水性繊維を含む呼気側シートを少なくとも備え、前記呼気側シートが、線状部で構成されたメッシュ状不織布であるマスク。 That is, the present invention can be configured in the following manner.
[Aspect 1]
A mask including a covering portion that covers at least the mouth and / or nose of a human body, wherein the covering portion includes at least an expiration side sheet including hydrophilic fibers as a human body layer, and the expiration side sheet includes a wire The mask which is a mesh-like nonwoven fabric comprised by the shape part.
態様1に記載のマスクであって、前記呼気側シートの線状部の平均線幅が0.1~3.0mm(好ましくは0.2~2.5mm、より好ましくは0.3~2.0mm、さらに好ましくは0.5~2.0mm)であるマスク。 [Aspect 2]
In the mask according to
態様1または2に記載のマスクであって、前記親水性繊維がセルロース系繊維(好ましくはレーヨン)であるマスク。 [Aspect 3]
The mask according to
態様1~3のいずれか一態様に記載のマスクであって、前記呼気側シートの親水性繊維の含有率が50重量%以上(好ましくは60重量%以上、より好ましくは70重量%以上)であり、熱融着性繊維をさらに含むマスク。 [Aspect 4]
The mask according to any one of
態様1~4のいずれか一態様に記載のマスクであって、前記呼気側シートの厚さが0.25~1.00mm(好ましくは0.30~0.80mm、より好ましくは0.35~0.60mm)であるマスク。 [Aspect 5]
The mask according to any one of
態様1~5のいずれか一態様に記載のマスクであって、前記呼気側シートの平均線幅(mm)×厚さ(mm)が0.025~1.8(好ましくは0.1~1.5、より好ましくは0.2~1.0、さらに好ましくは0.2~1.0)であるマスク。 [Aspect 6]
The mask according to any one of
態様1~6のいずれか一態様に記載のマスクであって、前記呼気側シートの目付が30~100g/m2(好ましくは32~90g/m2、より好ましくは35~80g/m2)であるマスク。 [Aspect 7]
The mask according to any one of
態様1~7のいずれか一態様に記載のマスクであって、前記被覆部が、さらにフィルターシートを前記呼気側シートの外層に備えるマスク。 [Aspect 8]
The mask according to any one of
態様8に記載のマスクであって、前記フィルターシートが帯電処理したメルトブローン不織布であるマスク。 [Aspect 9]
9. The mask according to aspect 8, wherein the filter sheet is a melt-blown non-woven fabric subjected to electrification treatment.
態様8に記載のマスクであって、前記フィルターシートが摩擦帯電したニードルパンチ不織布であるマスク。 [Aspect 10]
The mask according to aspect 8, wherein the filter sheet is a needle punched nonwoven fabric that is frictionally charged.
さらにまた、本発明のマスクでは、乾燥性が高いため、汗や唾液に由来してマスク内部で細菌が繁殖するのを抑制し、細菌の繁殖に由来して生じる臭いを低減することも可能である。 Furthermore, the mask of the present invention not only absorbs moisture derived from sweat generated on the face in contact with the mask, and can reduce the feeling of stickiness and sweating caused by sweat, but also reduces moisture content. A refreshing sensation can be provided by utilizing the heat of vaporization generated during diffusion and drying.
Furthermore, since the mask of the present invention has high drying properties, it is possible to suppress the growth of bacteria inside the mask due to sweat and saliva, and to reduce the odor caused by the propagation of bacteria. is there.
呼気側シートで用いられるメッシュ状不織布は、取扱い性(例えば、装着時における耐破損性)や、吸水性および柔軟性を確保する観点から乾式不織布であり、例えば、以下の方法により得ることができる。なお、乾式不織布は、例えば、構成繊維の繊維長が20~70mm程度、好ましくは25~65mm程度であってもよく、より好ましくは30~60mm程度であり、さらに好ましくは35~55mm程度である。繊維の絡み合いが製法上不利に働く湿式不織布(通常、繊維長は10mm以下)と区別することが可能である。 (Exhalation side seat)
The mesh nonwoven fabric used in the exhalation-side sheet is a dry nonwoven fabric from the viewpoint of ensuring handleability (for example, breakage resistance at the time of wearing) and water absorption and flexibility, and can be obtained by the following method, for example. . In the dry nonwoven fabric, for example, the fiber length of the constituent fibers may be about 20 to 70 mm, preferably about 25 to 65 mm, more preferably about 30 to 60 mm, and further preferably about 35 to 55 mm. . It is possible to distinguish it from a wet non-woven fabric (usually the fiber length is 10 mm or less) in which fiber entanglement works disadvantageously in the production process.
中間層は、必要に応じて設ければよく、設ける場合、マスクの目的に従ってさまざまな機能を付与することができる。例えば、防塵性を高める観点からは、マスクは中間層としてフィルターシートを備えているのが好ましい。 (Middle layer)
The intermediate layer may be provided as necessary, and when provided, various functions can be imparted according to the purpose of the mask. For example, from the viewpoint of enhancing dust resistance, the mask preferably includes a filter sheet as an intermediate layer.
表面シートは、メッシュ形状である呼気側シートの補強層や支持層などとして用いられる。表面シートは、目的や構成に応じて、公知又は慣用の不織布などを利用することが可能である。
好ましくは、スパンボンド法、メルトブロー法、サーマルボンド法、スパンレース法又はケミカルボンド法による不織布を用いることができる。 (Surface sheet)
The top sheet is used as a reinforcing layer or a support layer of the breath side sheet having a mesh shape. As the surface sheet, a known or conventional nonwoven fabric or the like can be used depending on the purpose or configuration.
Preferably, a nonwoven fabric by a spun bond method, a melt blow method, a thermal bond method, a spun lace method or a chemical bond method can be used.
走査型電子顕微鏡を用いて不織繊維構造を観察した。電子顕微鏡写真より無作為に選択した100本の繊維径を測定し、数平均繊維径を求め、繊維の平均繊維径とした。 [Average fiber diameter]
The nonwoven fiber structure was observed using a scanning electron microscope. The diameter of 100 fibers selected at random from an electron micrograph was measured, the number average fiber diameter was determined, and the average fiber diameter was determined.
JIS L 1015「化学繊維ステープル試験方法」に準じて、呼気側シートを構成する繊維の繊度を測定した。 [Fineness]
In accordance with JIS L 1015 “Chemical fiber staple test method”, the fineness of the fibers constituting the breath side sheet was measured.
JIS L 1913「一般不織布試験方法」の6.2に準じて、呼気側シートの目付(g/m2)を測定した。 [Unit weight]
The basis weight (g / m 2 ) of the breath side sheet was measured according to 6.2 of JIS L 1913 “General Nonwoven Test Method”.
JIS L 1913「一般不織布試験方法」の6.1に準じて、呼気側シートの厚さを測定した。具体的には、呼気側シートの厚み方向に対して平行に、かつ機械方向(MD)方向に対して垂直となるように、剃刀(「フェザー剃刀S片刃」、フェザー安全剃刀(株)社製)を用いて呼気側シートの任意の10カ所を切断し、デジタル顕微鏡にてそれぞれの断面を観察して各断面の厚さを測定し、これらの平均値を算出することにより、厚さ(mm)を求めた。 [thickness]
The exhalation-side sheet thickness was measured according to 6.1 of JIS L 1913 “General nonwoven fabric test method”. Specifically, a razor ("Feather Razor S single blade", manufactured by Feather Safety Razor Co., Ltd.) is parallel to the thickness direction of the exhalation side sheet and perpendicular to the machine direction (MD) direction. ) Are used to cut any 10 locations on the exhalation-side sheet, each cross-section is observed with a digital microscope, the thickness of each cross-section is measured, and the average value is calculated to obtain the thickness (mm )
シート表面を、デジタル顕微鏡(「VHX-900 DIGITAL MICROSCOPE」、(株)KEYENCE製)を用いて観察し、肉薄部を除く繊維部分を線状部として、その幅を線状部の線幅とした。線状部の線幅は線状部の方向毎に測定し、それぞれの方向について、ランダムに選択した10個の線幅について平均値を算出し、それぞれの方向における線幅とした。 [Average line width of linear part]
The surface of the sheet was observed using a digital microscope (“VHX-900 DIGITAL MICROSCOPE”, manufactured by KEYENCE Inc.), and the fiber part excluding the thin part was defined as a linear part, and the width was defined as the line width of the linear part. . The line width of the linear portion was measured for each direction of the linear portion, and an average value was calculated for 10 line widths selected at random for each direction, and the line width in each direction was obtained.
JIS L 1913「一般不織布試験方法」の6.9.2に準じて、呼気側シートの保水率を測定した。具体的には、100mm×100mm角サイズの試験片を3枚採取し、その質量(浸漬前質量)を測定した。次いで、この試験片を水中に15分間浸漬し、その後引き上げて、空気中に1つの角を上にした状態で1分間吊して表面の水を切った後、質量(浸漬後質量)を測定した。3枚の試験片について下記式:
保水率(質量%)=100×(浸漬後質量-浸漬前質量)/浸漬前質量
に基づいて保水率を算出し、これらの平均値をもって呼気側シートの保水率とした。また、浸漬後質量-浸漬前質量の質量を保水量(g)とした。 [Water retention rate, water retention amount]
The water retention rate of the breath side sheet was measured according to 6.9.2 of JIS L 1913 “General nonwoven fabric test method”. Specifically, three test pieces having a size of 100 mm × 100 mm square were collected, and the mass (mass before immersion) was measured. Next, the test piece was immersed in water for 15 minutes, then pulled up, suspended for 1 minute in air with one corner up, and the surface water was cut off, and then the mass (mass after immersion) was measured. did. For the three specimens the following formula:
The water retention rate was calculated based on the water retention rate (mass%) = 100 × (mass after immersion−mass before immersion) / mass before immersion, and the average value thereof was used as the water retention rate of the exhalation side sheet. Moreover, the mass of the mass after immersion−the mass before immersion was defined as the water retention amount (g).
JIS L 1907「繊維製品の吸水性試験法」の7.1.1に規定される滴下法に準じて、呼気側シートの吸水速度を測定した。具体的には、得られた呼気側シートに、0.05g/滴の水滴を10mmの高さからビュレットで1滴滴下し、その水滴が吸収されることにより鏡面反射が消えるまでの時間(秒)を測定した。 [Water absorption speed]
The water absorption rate of the exhalation-side sheet was measured according to the dropping method defined in 7.1.1 of JIS L 1907 “Fabricity water absorption test method”. Specifically, 0.05 g / drop of water droplet is dropped on the obtained exhalation-side sheet with a burette from a height of 10 mm, and the time (seconds) until the specular reflection disappears when the water droplet is absorbed. ) Was measured.
呼気側シートを10cm×10cmにカットしたシートを作製し、これを水平な台に静置した。次にイオン交換水100gに対し、インキ(「PILOTインキRED(INK-350-R)」、(株)パイロットコーポレーション製)を1g添加した色水を作製した。次に、静置したシートの1cm上方(上空)からシートの中央に対し、スポイトを用いて色水を1滴(0.05g)滴下した。滴下から5秒後、色水が面内において拡散した長さ、すなわち、マスク中の上下方向の拡散長さ(mm)、および左右方向の拡散長さ(mm)を求めた。また、上下方向の拡散長さ(mm)と左右方向の拡散長さ(mm)の積を拡散性の値とした。拡散性の値が大きいほど、液体が広範囲に拡散されることを意味する。また、マスクの左右方向および上下方向について、拡散長さの長い方/短い方を拡散異方性の値として算出した。 [Diffusion and diffusion anisotropy]
A sheet obtained by cutting the exhalation-side sheet into 10 cm × 10 cm was prepared, and this was left on a horizontal table. Next, colored water was prepared by adding 1 g of ink ("PILOT ink RED (INK-350-R)", manufactured by Pilot Corporation) to 100 g of ion-exchanged water. Next, 1 drop (0.05 g) of colored water was dropped with a dropper from 1 cm above (over the sky) of the sheet left still to the center of the sheet. Five seconds after the dropping, the length of the color water diffused in the plane, that is, the vertical diffusion length (mm) and the horizontal diffusion length (mm) in the mask was determined. The product of the diffusion length in the vertical direction (mm) and the diffusion length in the left-right direction (mm) was defined as the diffusivity value. A larger diffusivity value means that the liquid is diffused over a wider area. Further, the longer / shorter diffusion length was calculated as the value of diffusion anisotropy in the horizontal direction and vertical direction of the mask.
JIS L 1096「織物及び編物の生地試験方法」の8.26に準じて、フラジール形法により通気度(cm3/cm2/s)を測定した。 [Air permeability]
The air permeability (cm 3 / cm 2 / s) was measured by the Frazier method according to JIS L 1096 “Fabric and knitted fabric test method” 8.26.
呼気側シートを100mm×100mmにカットしたシートに0.10gの水滴を垂らし、30分間静置し、蒸発によって減少した水分の割合を示す。 [Evaporation rate]
The ratio of the water | moisture content reduced by evaporation is shown by dripping a 0.10-g water drop on the sheet | seat which cut the exhalation side sheet | seat into 100 mm x 100 mm, and leaving still for 30 minutes.
濾材評価装置(「AP-6310FP」、柴田科学(株)製)を用いて、フィルターシートの濾材特性を評価した。まず、試験サンプルを濾過面の直径が86mmの測定セルに装着した。この状態で最大径が2μm以下で、かつ数平均径が0.5μmのシリカダストを試験粉塵に用いて、粉塵濃度30g±5mg/m3となるように調製した粉塵含有空気を、濾材をセットした測定セルに30リットル/分の流量で1分間流し、上流側の粉塵濃度D1、下流側(濾過後)の粉塵濃度D2を光散乱質量濃度計を用いて測定し、下記の式から捕集効率を求めた。
捕集効率(%)=[(D1-D2)/D1]×100 [Collection efficiency]
The filter medium characteristics of the filter sheet were evaluated using a filter medium evaluation apparatus (“AP-6310FP”, manufactured by Shibata Kagaku Co., Ltd.). First, the test sample was attached to a measurement cell having a filtration surface diameter of 86 mm. In this state, using silica dust with a maximum diameter of 2 μm or less and a number average diameter of 0.5 μm as test dust, set the filter medium with dust-containing air prepared to a dust concentration of 30 g ± 5 mg / m 3. Measure the upstream dust concentration D1 and downstream (after filtration) dust concentration D2 using a light scattering mass densitometer, and collect from the following formula. We asked for efficiency.
Collection efficiency (%) = [(D1-D2) / D1] × 100
濾材評価装置における測定セルの上流側、下流側間に微差圧計を配置し、流量30リットル/分における差圧(圧力損失(Pa))を測定した。 [Pressure loss]
A fine differential pressure gauge was placed between the upstream side and the downstream side of the measurement cell in the filter medium evaluation apparatus, and the differential pressure (pressure loss (Pa)) at a flow rate of 30 liters / minute was measured.
実際にマスクを着用し、気温25度、湿度60%の部屋で3時間着用したときの使用感について10人の被験者に、以下の3つの判定基準で官能評価を行い、その平均値を算出した。
[ひんやり感]
+++(3ポイント):ひんやりした感じがする。
++(2ポイント):ややひんやりした感じがする。
+(1ポイント):ひんやりした感じがない。
[べとつき感]
+++(3ポイント):べとつきを感じない。
++(2ポイント):ほとんどべとつきを感じない。
+(1ポイント):はっきりべとつきを感じる。 [Sensory evaluation (cool feeling, stickiness)]
Ten subjects were subjected to sensory evaluation on the feeling of use when wearing a mask for 3 hours in a room with an air temperature of 25 degrees and a humidity of 60%, and the average value was calculated. .
[Cool feeling]
++++ (3 points): I feel cool.
++ (2 points): I feel a little cool.
+ (1 point): There is no cool feeling.
[A feeling of stickiness]
++++ (3 points): Does not feel sticky.
++ (2 points): almost no stickiness.
+ (1 point): I feel the stickiness clearly.
(1)呼気側シートの製造
まず、繊度1.7dtex、平均繊維径12.0μm、繊維長40mmのレーヨン繊維(「ホープ」、オーミケンシ株式会社製)80重量%、および繊度1.7dtex、平均繊維径15.3μm、繊維長51mmの熱融着性繊維(芯がポリプロピレン、鞘がポリエチレンの芯鞘複合繊維、「HR-NTW」、宇部エクシモ社製)20重量%を、カード法を用いてセミランダムウェブを作製した。 [Example 1]
(1) Production of breath side sheet First, a rayon fiber (“Hope”, manufactured by Ohmi Kenshi Co., Ltd.) 80% by weight with a fineness of 1.7 dtex, an average fiber diameter of 12.0 μm, and a fiber length of 40 mm, and a fineness of 1.7 dtex, average fiber 20% by weight of a heat-fusible fiber having a diameter of 15.3 μm and a fiber length of 51 mm (core-sheath composite fiber with a core of polypropylene and a sheath of polyethylene, “HR-NTW”, manufactured by Ube Eximo Co., Ltd.) is semi-cured using a card method. A random web was made.
呼気側シートの各種評価結果を表1に示す。 Next, the nonwoven fabric after the back WJ treatment was dried at 135 ° C. using a cylinder dryer. As a result, the exhalation-side sheet used in Example 1 was produced.
Table 1 shows various evaluation results of the exhalation side sheet.
上記(1)の呼気側シート、フィルターシートとしてポリプロピレン繊維を素材とした帯電処理したメルトブローン不織布、及び表面シートとしてレーヨンを素材としたケミカルボンド不織布をこの順にそれぞれロールで巻き出すことによって、連続的に3層を積層した。その後、折板で機械方向にプリーツ加工を施し、マスクの上下両端に超音波シールを行い、マスクの横を規定長さにカットし、マスクの左右両端に超音波シールを行い、ゴム紐を超音波シールで取り付け、実施例1のマスクを製造した。 (2) Manufacture of mask The exhalation side sheet of (1), the melt-blown non-woven fabric made of polypropylene fiber as the filter sheet, and the chemical bond non-woven fabric made of rayon as the top sheet are unwound in this order. Thus, three layers were continuously laminated. After that, pleating is performed in the machine direction with a folded plate, ultrasonic sealing is performed on the upper and lower ends of the mask, the side of the mask is cut to a specified length, ultrasonic sealing is performed on the left and right ends of the mask, and the rubber cord is The mask of Example 1 was manufactured by attaching with a sonic seal.
呼気側シートの製造におけるセミランダムウェブの目付および厚さを表1に示す値に変更した以外は実施例1と同様の方法により作製した呼気側シートを用い、それ以外は実施例1と同様の方法によりマスクを作製した。評価結果を表1に示す。 [Example 2]
Except for changing the basis weight and thickness of the semi-random web in the production of the exhalation-side sheet to the values shown in Table 1, the exhalation-side sheet produced by the same method as in Example 1 was used, and otherwise the same as in Example 1 A mask was prepared by the method. The evaluation results are shown in Table 1.
裏WJに用いるネット支持体として、繊維径0.90mm、メッシュ13本/inch、平織を用いた以外は実施例1と同様の方法により作製した呼気側シートを用い、それ以外は実施例1と同様の方法によりマスクを作製した。 [Example 3]
As a net support used for the back WJ, an exhalation-side sheet produced by the same method as in Example 1 except that a fiber diameter of 0.90 mm, 13 meshes / inch, and plain weave was used. A mask was produced by the same method.
裏WJに用いるネット支持体として、繊維径0.90mm、メッシュ13本/inch、平織を用いた以外は実施例2と同様の方法により作製した呼気側シートを用い、それ以外は実施例2と同様の方法によりマスクを作製した。 [Example 4]
As the net support used for the back WJ, an exhalation-side sheet produced by the same method as in Example 2 was used except that a fiber diameter of 0.90 mm, 13 meshes / inch, and plain weave was used. A mask was produced by the same method.
裏WJに用いるネット支持体として、繊維径1.20mm、メッシュ12本/inch、平織を用いた以外は実施例1と同様の方法により作製した呼気側シートを用い、それ以外は実施例1と同様の方法によりマスクを作製した。 [Example 5]
As the net support used for the back WJ, an exhalation-side sheet produced by the same method as in Example 1 except that a fiber diameter of 1.20 mm, 12 meshes / inch, and plain weave was used. A mask was produced by the same method.
裏WJに用いるネット支持体として、繊維径1.20mm、メッシュ12本/inch、平織を用いた以外は実施例2と同様の方法により作製した呼気側シートを用い、それ以外は実施例2と同様の方法によりマスクを作製した。 [Example 6]
As a net support used for the back WJ, an exhalation-side sheet produced by the same method as in Example 2 was used except that a fiber diameter of 1.20 mm, 12 meshes / inch, and plain weave was used. A mask was produced by the same method.
裏WJに用いるネット支持体として、繊維径0.65mm、メッシュ25本/inch、平織を用いた以外は実施例1と同様の方法により作製した呼気側シートを用い、それ以外は実施例1と同様の方法によりマスクを作製した。 [Example 7]
As a net support used for the back WJ, an exhalation-side sheet produced by the same method as in Example 1 except that a fiber diameter of 0.65 mm, 25 meshes / inch, and plain weave was used. A mask was produced by the same method.
裏WJに用いるネット支持体として、繊維径0.65mm、メッシュ25本/inch、平織を用いた以外は実施例2と同様の方法により作製した呼気側シートを用い、それ以外は実施例2と同様の方法によりマスクを作製した。 [Example 8]
As the net support used for the back WJ, an exhalation-side sheet produced by the same method as in Example 2 was used except that a fiber diameter of 0.65 mm, 25 meshes / inch, and plain weave was used. A mask was produced by the same method.
裏WJに用いるネット支持体として、繊維径0.90mm、メッシュ6本/inch、平織を用いた以外は実施例1と同様の方法により作製した呼気側シートを用い、それ以外は実施例1と同様の方法によりマスクを作製した。 [Example 9]
As the net support used for the back WJ, an exhalation-side sheet produced by the same method as in Example 1 except that a fiber diameter of 0.90 mm, 6 meshes / inch, and plain weave was used. A mask was produced by the same method.
呼気側シートとしてポリプロピレンサーマルボンド不織布(「NRIP(HYCOMFORT)」、レンゴー・ノンウーブン・プロダクツ株式会社製)を用いた以外は、実施例1と同様の方法によりマスクを作製した。 [Comparative Example 1]
A mask was prepared in the same manner as in Example 1 except that a polypropylene thermal bond nonwoven fabric (“NRIP (HYCOMFORT)”, manufactured by Rengo Non-Woven Products Co., Ltd.) was used as the breath side sheet.
市販品のガーゼマスク(綿100%、18枚ガーゼ合わせ)(日進医療器株式会社製)を用いた。 [Comparative Example 2]
A commercially available gauze mask (100% cotton, 18 sheets gauze together) (manufactured by Nisshin Medical Instrument Co., Ltd.) was used.
裏WJに用いるネット支持体として、繊維径0.20mm、メッシュ76本/inch、平織を用いた以外は実施例1と同様の方法により作製した呼気側シートを用い、それ以外は実施例1と同様の方法によりマスクを作製した。 [Comparative Example 3]
As the net support used for the back WJ, an exhalation-side sheet produced by the same method as in Example 1 except that a fiber diameter of 0.20 mm, 76 meshes / inch, and plain weave was used. A mask was produced by the same method.
また、比較例2で、ガーゼマスクを用いた場合、マスクの目付が大きく、分厚いため、保水率は実施例と比べて低く、通気度が実施例と比較して低い値である。そのためか、保水量が高いにもかかわらず、マスクの着用した際に、べとつき感がはっきりと感じられると評価されている。
比較例3では、呼気側シートに実施例1と同様の材料で構成される不織布を用いているにもかかわらず、当該不織布は目が詰まり肉薄部が存在しないため、線状部で構成されたメッシュ状不織布には該当しない。そのため、マスクの拡散性および蒸発率のいずれも実施例と比較して低い値である。そのためか、マスクの着用感は、ひんやりとした感じは全くないと評価されている。 On the other hand, in Comparative Example 1, since the hydrophobic polypropylene thermal bond nonwoven fabric is used as the breath side sheet, the feeling of wearing the mask is clearly felt even though the intermediate layer and the surface sheet are the same. It is evaluated that there is no further cool feeling.
Moreover, when the gauze mask is used in Comparative Example 2, the basis weight of the mask is large and the thickness is large, so that the water retention rate is lower than that of the example and the air permeability is lower than that of the example. For this reason, even though the amount of water retention is high, it is evaluated that a sticky feeling can be clearly felt when wearing a mask.
In Comparative Example 3, although the nonwoven fabric composed of the same material as that of Example 1 was used for the breath side sheet, the nonwoven fabric was clogged and formed with a linear portion because there was no thin portion. Not applicable to mesh-like nonwoven fabrics. For this reason, both the diffusibility and the evaporation rate of the mask are low values as compared with the example. For this reason, the feeling of wearing the mask is evaluated as having no cool feeling.
201,202・・・マスク用片
110,210・・・被覆部
120・・・積層シート
121・・・呼気側シート
122・・・フィルターシート
123・・・表面シート
130・・・プリーツ
140・・・ワイヤー
150,250・・・固定部
251・・・耳掛け用の切れ目
160・・・弾性補強部
260,261,262・・・接合部 DESCRIPTION OF SYMBOLS 100,200 ... Mask 201,202 ... Mask piece 110,210 ... Cover
Claims (10)
- 人体の少なくとも口元、鼻元、または双方を被覆する被覆部を備えるマスクであって、前記被覆部は、人体側の層として親水性繊維を含む呼気側シートを少なくとも備え、前記呼気側シートが、線状部で構成されたメッシュ状不織布であるマスク。 A mask comprising a covering portion that covers at least the mouth, nose, or both of the human body, wherein the covering portion includes at least an expiration side sheet containing hydrophilic fibers as a human body side layer, and the expiration side sheet includes: A mask which is a mesh-like non-woven fabric composed of linear portions.
- 請求項1に記載のマスクであって、前記呼気側シートの線状部の平均線幅が0.1~3.0mmの範囲にあるマスク。 The mask according to claim 1, wherein an average line width of the linear portion of the exhalation side sheet is in a range of 0.1 to 3.0 mm.
- 請求項1または2に記載のマスクであって、前記親水性繊維がセルロース系繊維であるマスク。 The mask according to claim 1 or 2, wherein the hydrophilic fibers are cellulosic fibers.
- 請求項1~3のいずれか1項に記載のマスクであって、前記呼気側シートの親水性繊維の含有率が50重量%以上であり、熱融着性繊維をさらに含むマスク。 The mask according to any one of claims 1 to 3, wherein the exhalation-side sheet has a hydrophilic fiber content of 50% by weight or more and further includes a heat-fusible fiber.
- 請求項1~4のいずれか1項に記載のマスクであって、前記呼気側シートの厚さが0.25~1.00mmであるマスク。 The mask according to any one of claims 1 to 4, wherein the breathing side sheet has a thickness of 0.25 to 1.00 mm.
- 請求項1~5のいずれか1項に記載のマスクであって、前記呼気側シートの平均線幅(mm)×厚さ(mm)が0.025~1.8であるマスク。 The mask according to any one of claims 1 to 5, wherein an average line width (mm) x thickness (mm) of the exhalation side sheet is 0.025 to 1.8.
- 請求項1~6のいずれか1項に記載のマスクであって、前記呼気側シートの目付が30~100g/m2であるマスク。 The mask according to any one of claims 1 to 6, wherein the basis weight of the exhalation side sheet is 30 to 100 g / m 2 .
- 請求項1~7のいずれか1項に記載のマスクであって、前記被覆部が、さらにフィルターシートを前記呼気側シートの外層に備えるマスク。 The mask according to any one of claims 1 to 7, wherein the covering portion further includes a filter sheet on an outer layer of the expiration side sheet.
- 請求項8に記載のマスクであって、前記フィルターシートが帯電処理したメルトブローン不織布であるマスク。 9. The mask according to claim 8, wherein the filter sheet is a melt-blown non-woven fabric subjected to electrification treatment.
- 請求項8に記載のマスクであって、前記フィルターシートが摩擦帯電したニードルパンチ不織布であるマスク。 9. The mask according to claim 8, wherein the filter sheet is a needle punched nonwoven fabric frictionally charged.
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP18809944.4A EP3632247A4 (en) | 2017-06-02 | 2018-05-24 | Mask |
AU2018277892A AU2018277892A1 (en) | 2017-06-02 | 2018-05-24 | Mask |
JP2019522174A JP7142632B2 (en) | 2017-06-02 | 2018-05-24 | mask |
KR1020197035722A KR20200014308A (en) | 2017-06-02 | 2018-05-24 | Mask |
CN201880035486.9A CN110691526B (en) | 2017-06-02 | 2018-05-24 | Gauze mask |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2017109843 | 2017-06-02 | ||
JP2017-109843 | 2017-06-02 |
Publications (1)
Publication Number | Publication Date |
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WO2018221381A1 true WO2018221381A1 (en) | 2018-12-06 |
Family
ID=64454711
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2018/020040 WO2018221381A1 (en) | 2017-06-02 | 2018-05-24 | Mask |
Country Status (7)
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EP (1) | EP3632247A4 (en) |
JP (1) | JP7142632B2 (en) |
KR (1) | KR20200014308A (en) |
CN (1) | CN110691526B (en) |
AU (1) | AU2018277892A1 (en) |
TW (1) | TWI821187B (en) |
WO (1) | WO2018221381A1 (en) |
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WO2021192490A1 (en) * | 2020-03-27 | 2021-09-30 | ユニ・チャーム株式会社 | Mask |
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JP2022124963A (en) * | 2021-02-16 | 2022-08-26 | ユニ・チャーム株式会社 | mask |
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2018
- 2018-05-24 KR KR1020197035722A patent/KR20200014308A/en not_active IP Right Cessation
- 2018-05-24 JP JP2019522174A patent/JP7142632B2/en active Active
- 2018-05-24 EP EP18809944.4A patent/EP3632247A4/en active Pending
- 2018-05-24 WO PCT/JP2018/020040 patent/WO2018221381A1/en unknown
- 2018-05-24 AU AU2018277892A patent/AU2018277892A1/en active Pending
- 2018-05-24 CN CN201880035486.9A patent/CN110691526B/en active Active
- 2018-05-31 TW TW107118602A patent/TWI821187B/en active
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WO2021131800A1 (en) * | 2019-12-24 | 2021-07-01 | ユニ・チャーム株式会社 | Mask sheet and mask |
JP2021101048A (en) * | 2019-12-24 | 2021-07-08 | ユニ・チャーム株式会社 | Mask sheet and mask |
JP7301731B2 (en) | 2019-12-24 | 2023-07-03 | ユニ・チャーム株式会社 | Mask sheets and masks |
WO2021192490A1 (en) * | 2020-03-27 | 2021-09-30 | ユニ・チャーム株式会社 | Mask |
JP2021155895A (en) * | 2020-03-27 | 2021-10-07 | ユニ・チャーム株式会社 | mask |
JP7113863B2 (en) | 2020-03-27 | 2022-08-05 | ユニ・チャーム株式会社 | mask |
CN115697500A (en) * | 2020-05-28 | 2023-02-03 | 欧罗菲利特斯控股公司 | Breathing protective cover |
JP7473957B2 (en) | 2020-06-18 | 2024-04-24 | フレックスジャパン株式会社 | mask |
JP2022124963A (en) * | 2021-02-16 | 2022-08-26 | ユニ・チャーム株式会社 | mask |
TWI753831B (en) * | 2021-05-20 | 2022-01-21 | 中國衛生材料生產中心股份有限公司 | Mask |
Also Published As
Publication number | Publication date |
---|---|
EP3632247A4 (en) | 2021-03-10 |
JPWO2018221381A1 (en) | 2020-04-02 |
TWI821187B (en) | 2023-11-11 |
TW201902537A (en) | 2019-01-16 |
AU2018277892A1 (en) | 2020-01-02 |
CN110691526A (en) | 2020-01-14 |
JP7142632B2 (en) | 2022-09-27 |
KR20200014308A (en) | 2020-02-10 |
CN110691526B (en) | 2022-09-13 |
EP3632247A1 (en) | 2020-04-08 |
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