WO2018205430A1 - Magnetron sputtering cavity for through-silicon-via filling and semiconductor processing device - Google Patents

Magnetron sputtering cavity for through-silicon-via filling and semiconductor processing device Download PDF

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Publication number
WO2018205430A1
WO2018205430A1 PCT/CN2017/095587 CN2017095587W WO2018205430A1 WO 2018205430 A1 WO2018205430 A1 WO 2018205430A1 CN 2017095587 W CN2017095587 W CN 2017095587W WO 2018205430 A1 WO2018205430 A1 WO 2018205430A1
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Prior art keywords
target
magnetron
rotating arm
magnetron sputtering
sputtering chamber
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PCT/CN2017/095587
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French (fr)
Chinese (zh)
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侯珏
王厚工
丁培军
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北京北方华创微电子装备有限公司
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Publication of WO2018205430A1 publication Critical patent/WO2018205430A1/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/67005Apparatus not specifically provided for elsewhere
    • H01L21/67011Apparatus for manufacture or treatment
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14Metallic material, boron or silicon
    • C23C14/16Metallic material, boron or silicon on metallic substrates or on substrates of boron or silicon
    • C23C14/165Metallic material, boron or silicon on metallic substrates or on substrates of boron or silicon by cathodic sputtering
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34Sputtering
    • C23C14/35Sputtering by application of a magnetic field, e.g. magnetron sputtering

Definitions

  • the invention belongs to the field of semiconductor devices, and in particular to a magnetron sputtering chamber and a semiconductor processing device for through-silicon via filling.
  • PVD Physical Vapor Deposition
  • TSV Through Silicon Via
  • the application of PVD in TSV is mainly to deposit a barrier layer and a copper seed layer inside the through-silicon via.
  • the function of the barrier layer is to prevent copper from diffusing into silicon or silicon dioxide.
  • the role of the copper seed layer is for the subsequent electroplating process.
  • a layer of conductive layer, so the deposition of a barrier layer and a copper seed layer in the through-silicon via has high requirements for physical vapor deposition film coverage.
  • the poor coverage of the barrier film will affect the reliability of the TSV device; the poor coverage of the copper seed layer may result in the inability to perform electroplating, or the TSV device after plating may have voids or gaps, which seriously affects device performance.
  • FIGS. 1 and 2 A typical DC magnetron sputtering apparatus is shown in FIGS. 1 and 2, the apparatus includes a susceptor 3 for carrying a wafer 4, and the susceptor 3 and the wafer 4 carried thereon are disposed opposite the target 2;
  • the uniformity of the film and the area of the magnetron are designed.
  • the projected area of the magnetron on the target 2 accounts for more than one-half of the area of the target 2; in order to increase the deposition rate of the film, the target
  • the distance (distance between the target 2 and the wafer 4) is usually set to be less than 70 mm.
  • the main corrosion region of the target 2 is close to the edge position of the target 2, and since the target base distance is too small, the angle at which the ions and atoms are incident on the through-silicon via 41 at the center of the wafer 4 is larger than the incident to The angle of the through silicon via 41 at the central portion of the wafer 4 causes a large difference in coverage between the center position of the wafer 4 and the edge position of the wafer 4, and the filling of the through silicon via is uneven.
  • the present invention provides a magnetron sputtering chamber and a semiconductor processing apparatus for through-silicon via filling, which at least solves the problem of low deposition rate in the prior art for filling silicon vias.
  • a magnetron sputtering chamber for through-silicon via filling comprising: a cavity, a target disposed on a top of the cavity, and a device disposed above the target a magnetron, and a susceptor disposed inside the cavity and below the target, the projected area of the magnetron on the plane of the target being less than or equal to one-fifth of the target The area of the material.
  • the projected area of the magnetron on the plane of the target is less than one-fifth of the area of the target.
  • the magnetron comprises an outer magnetic pole and an inner magnetic pole opposite in magnetic polarity, and the inner magnetic pole is surrounded by the outer magnetic pole.
  • the outer magnetic pole has a long diameter and a short diameter, and the short diameter is less than or equal to one-half of a difference between a diameter of the inner chamber and a diameter of a wafer to be carried by the susceptor.
  • the magnetron sputtering chamber further includes a rotating mechanism, the rotating mechanism includes a rotating shaft, a first rotating arm and a second rotating arm; one end of the first rotating arm is fixedly connected with the rotating shaft, and One end is connected to one end of the second rotating arm, and the other end of the second rotating arm is fixedly connected to the magnetron; the first rotating arm and the second rotating arm have an angle;
  • the rotating shaft drives the first rotating arm and the second rotating arm to rotate, thereby driving the magnetron to rotate.
  • the angle between the first rotating arm and the second rotating arm is adjustable, and the angle is a circumference of 0-180 degrees; when the included angle is 0 degrees, a projection of the magnetron on a plane of the target falls in a central area of the target; when the angle is 180 degrees The projection of the magnetron on the plane of the target falls on the edge region of the target.
  • the magnetron sputtering chamber further includes a biasing unit that generates a negative bias on the base to attract positive ions to move vertically toward the base.
  • the biasing unit includes a radio frequency power source and a matching device, wherein the radio frequency power source is connected to the base through the matching device; the power of the radio frequency power source ranges from 800 to 1400 W.
  • the vertical distance between the target and the base is 100-150 mm.
  • the present invention also provides a semiconductor processing apparatus comprising the magnetron sputtering chamber for through silicon via filling described in any of the above aspects.
  • the present invention provides a magnetron sputtering chamber for through-silicon via filling.
  • the projected area of the magnetron on the target is less than or equal to one-fifth of the target area, which is relative to the prior art magnetron.
  • the present invention can increase the ionization rate of the dielectric gas (such as argon) in the case where the loaded power is the same. Thereby, the filling rate of the through silicon vias is effectively increased, and the film coverage is further improved.
  • the magnetron sputtering chamber for through-silicon via filling of the present invention is employed, and the filling rate of the through-silicon via holes can be increased, and the film coverage can be further improved.
  • FIG. 1 is a schematic structural view of a magnetron sputtering chamber for through-silicon via filling in the prior art
  • FIG. 2 is a schematic view showing an incident angle of a plasma when a through-silicon via is filled in a magnetron sputtering chamber for through-silicon via filling in the prior art
  • FIG. 3 is a schematic diagram of a magnetron sputtering chamber for through silicon via filling in accordance with an embodiment of the present invention
  • FIG. 4 is a schematic diagram of a magnetron sputtering chamber for through silicon via filling in accordance with an embodiment of the present invention
  • FIG. 5 is a schematic diagram of a magnetron sputtering chamber for through silicon via filling in accordance with an embodiment of the present invention
  • FIG. 6 is a schematic view showing an incident angle of positive ions when filling a through silicon via according to the embodiment shown in FIG. 5;
  • the present embodiment provides a magnetron sputtering chamber for through-silicon via filling, comprising: a cavity, a target disposed on the top of the cavity, a magnetron disposed above the target, and a cavity Internal and located below the target, the projected area of the magnetron on the target is less than or equal to one-fifth of the target area to increase the ionization rate of the dielectric gas, thereby increasing the filling of the through-silicon via. rate.
  • the projected area of the magnetron on the plane of the target is generally one-half of the area of the target, and the magnetron sputtering chamber provided by the present invention uses a magnetron in the plane of the target.
  • the area of the projection above is less than or equal to one-fifth of the area of the target.
  • the magnetron sputtering chamber provided by the invention can increase the power density per unit area, thereby greatly increasing the ionization rate of the medium gas, that is, generating more Ions, which can improve the through silicon via The fill rate.
  • the projected area of the magnetron on the plane of the target is preferably less than one-fifth of the area of the target, and the projected area of the magnetron on the plane of the target is less than fifteenth of the area of the target.
  • the power density per unit area is higher, and the ionization rate of the dielectric gas is correspondingly higher, so the filling rate of the through silicon vias is also higher.
  • the magnetron in this embodiment includes an outer magnetic pole and an inner magnetic pole which are opposite in magnetic polarity, and the inner magnetic pole is surrounded by the outer magnetic pole.
  • the other settings in this embodiment are the same as those in the first embodiment, and are not described herein.
  • the magnetron 1 in the magnetron sputtering chamber of the present embodiment includes magnetically opposite outer and inner magnetic poles, the inner magnetic pole is surrounded by the outer magnetic pole, and the magnetron 1 is kidney-shaped. It can provide a higher ionization rate of the medium gas.
  • the outer magnetic pole of the magnetron 1 may be circular, rectangular or elliptical.
  • the outer magnetic pole has a long diameter L and a short diameter D, and the short diameter D is preferably less than or equal to one-half of the difference between the inner diameter of the chamber and the diameter of the wafer 4 to be carried by the susceptor 3, that is, the short diameter during the process.
  • the projection of the magnetron 1 on the plane of the wafer 4 is between the projection of the wafer 4 and the chamber wall on the plane, That is, for the plane in which the wafer 4 is located, the projection of the magnetron 1 is located in the outer region of the wafer 4 (hereinafter referred to as the magnetron 1 in the outer region of the wafer 4), by which the magnetron 1 is disposed, and
  • the projection of the movement trajectory of the magnetron 1 on the plane of the wafer 4 falls on the outer region of the wafer 4, so that a part of the escaped target atoms and ions are deposited on the edge region of the wafer 4, and a part is floated to the center of the wafer 4.
  • the region is deposited in the central region of the wafer 4, thereby adjusting the uniformity of de
  • the minimum value of the short diameter D and the long diameter L of the magnetron is conditioned on the condition that the medium gas can be stably maintained in the plasma state. If the size is too small, the magnetic field may be weakened, and the medium gas may not be maintained in the plasma state.
  • the magnetron sputtering chamber in this embodiment further includes the rotating mechanism shown in FIG.
  • the other settings in this embodiment are the same as those in the second embodiment, and are not described herein.
  • the rotating mechanism 5 in this embodiment includes a rotating shaft 51, a first rotating arm 52, and a second rotating arm 53.
  • One end of the first rotating arm 52 is fixedly connected to the rotating shaft 51, and the other end is second.
  • One end of the rotating arm 53 is connected, the other end of the second rotating arm 53 is fixedly connected with the magnetron 1;
  • the first rotating arm 52 has an angle with the second rotating arm 53;
  • the rotating shaft 51 drives the first rotating arm 52 and
  • the second rotating arm 53 rotates to drive the magnetron 1 to rotate.
  • the connection between the first rotating arm 52 and the second rotating arm 53 may be a fixed connection or an active connection.
  • the angle between the first rotating arm 52 and the second rotating arm 53 is not adjustable; when the movable connection is employed, the angle between the first rotating arm 52 and the second rotating arm 53 is adjustable, that is, The angle can be adjusted according to the process requirements, and after the first rotating arm 52 and the second rotating arm 53 are fixed, the rotating shaft 51 is rotated, so that the first rotating arm 52 and the second rotating arm 53 drive the magnetron. 1 rotation.
  • the angle between the first rotating arm 52 and the second rotating arm 53 ranges from 0 to 180 degrees.
  • the angle is 0 degree
  • the magnetron 1 is projected in the central area of the target 2, that is, the projection of the magnetron 1 on the plane of the target 2 falls in the central area of the target 2; when the angle is 180 At the time, the magnetron 1 is projected on the edge region of the target 2, that is, the projection of the magnetron 1 on the plane of the target 2 falls on the edge region of the target 2.
  • the selection of the angle between the first rotating arm 52 and the second rotating arm 53 and the through hole of the wafer 4 The main fill position corresponds. That is, the angle between the first rotating arm 52 and the second rotating arm 53 is set in accordance with the main filling position of the wafer 4.
  • the projection of the magnetron 1 on the plane of the target 2 falls on the central region of the target 2, at which time the through-silicon vias of the central region of the wafer 4 are mainly filled;
  • the projection of the magnetron 1 on the plane of the target 2 falls on the edge region of the target 2, at which time the edge region of the wafer 4 is mainly filled; according to the filling condition, the first rotating arm can be adjusted in time.
  • An angle between 52 and the second rotating arm 53, thereby adjusting the magnetron 1 at the target The projection position on 2, thereby changing the main filling position of the wafer 4, makes the filling of the through-silicon vias more uniform.
  • the so-called main filling position refers to the position where most of the ions and atoms are deposited when the through silicon via is filled.
  • the magnetron sputtering chamber in this embodiment further includes a biasing unit.
  • a biasing unit As for other settings, the same as the setting of Embodiment 3, and details are not described herein.
  • the magnetron sputtering chamber of the present embodiment includes a biasing unit 6 that generates a negative bias on the susceptor 2 to attract positively charged ions into the silicon pass of the wafer 4 vertically. The bottom of the hole, so that the uniformity of the through-silicon via filling can be improved.
  • the biasing unit 6 since the biasing unit 6 is disposed in the magnetron sputtering chamber of the embodiment, the positive ions generated by the process gas ionization will be close to zero under the action of the biasing unit 6.
  • the angle of incidence is perpendicular to the through silicon via, as indicated by the arrows in FIG.
  • the positive ions are vertically filled into the through silicon vias, which not only improves the filling rate, but also improves the uniformity of filling.
  • the area of the magnetron 1 is reduced by making the volume of the magnetron 1 projected on the plane of the target 2 less than or equal to one fifth of the area of the target 2, thereby increasing the ionization of the medium gas. Rate, increasing the amount of positive ions in the plasma.
  • the positive ions can be vertically filled to the through-silicon vias at an incident angle close to zero, thereby improving the uniformity of filling, and effectively solving the problems existing in the prior art, that is, positive
  • the incident angle of ions at the edge portion of the wafer is close to 0 degrees, and the incident angle at the central portion is large, causing a problem of uneven filling of the through-silicon via holes in the central portion of the wafer and the through-hole filling of the edge portions.
  • the biasing unit preferably includes a radio frequency power source and a matching device, and the radio frequency power source is connected to the base through the matching device.
  • the power range of the radio frequency power source is preferably 800-1400 W, further preferably 1000-1300 W, and still more preferably 1100 W, 1200 W, and 1250 W.
  • the reason why the power range of the RF power source is preferably set to 800-1400 W is that when the RF power range is less than 800 W, the bias generated on the susceptor is difficult to attract positive ions into the through silicon vias of the wafer; when the RF power is greater than 1400 W At this time, the bias generated on the pedestal is too large, so that the positive ions move too fast and deposit to silicon.
  • the energy at the bottom of the through hole 41 is strong, which causes excessive bombardment, that is, the original deposited layer at the bottom of the thin through silicon via 41 is thinned, and even the deposited layer at the bottom is completely sputtered onto the sidewall, reducing deposition. Uniformity.
  • the power range of the RF power source When the power range of the RF power source is maintained between 800 and 1400 W, on the one hand, it generates an appropriate negative bias on the pedestal 3, increasing the kinetic energy of the positive ions to some extent, and accelerating the positive ions to the wafer 4. The acceleration of the movement increases the filling rate; on the other hand, the ions maintain proper kinetic energy, and when the bottom surface of the through silicon via 41 is bombarded, a part of the film previously deposited on the bottom of the through silicon via 41 is sputtered out to the through silicon via 41.
  • the position of the corner of the side wall increases the coverage of the bottom of the through-silicon via and the corner of the sidewall, so that the thickness of the bottom of the through-silicon via 41 and the corner of the sidewall are relatively uniform.
  • the vertical distance between the target 2 and the susceptor 3 is 100-150 mm.
  • the other settings in this embodiment are the same as those in the embodiment 4, and are not described herein.
  • the target is projected on the basis of the area where the projection of the magnetron on the plane of the target is less than or equal to one-fifth of the area of the target and the bias unit is disposed.
  • the vertical distance between the material and the base is set to 100-150 mm.
  • the vertical distance between the target and the pedestal is set to 100-150 mm, which is larger than 70 mm in the prior art, that is, the target base distance is increased, which makes the positive filling into the through-silicon via at a small incident angle.
  • the increase in ions, especially the positive ions that are vertically filled into the through-silicon vias increases the film coverage and the utilization of the target.
  • the magnetron sputtering chambers for silicon via filling provided by Embodiments 1 to 5 of the present invention all increase the filling rate of the through silicon vias, and can even further improve the filling uniformity of the through silicon vias.
  • the present embodiment provides a semiconductor processing apparatus.
  • the semiconductor processing apparatus in this embodiment may include any one of Embodiments 1-5 for a magnetron sputtering chamber for through-silicon via filling.
  • the semiconductor processing apparatus in this embodiment adopts the magnetron sputtering chamber of the present invention, can improve the filling rate of the through silicon via filling, and can even further improve the filling uniformity of the through silicon via.
  • the projected area of the magnetron on the plane of the target is set to be smaller than or equal to the target area.
  • One-fifth of the set, the biasing unit connected to the base, and/or the target base distance is between 100mm and 150mm.
  • the magnetron sputtering chamber of the present invention has an effect of increasing the filling rate and the filling uniformity when filling the through silicon via, the following description will be made by way of comparative examples and comparative examples.
  • the magnetron sputtering chamber used had a cavity radius of 222.5 mm and a pedestal radius of 150 mm.
  • the wafer is a 12-inch wafer (300 mm in diameter) and the target diameter is 450 mm (target area is 158962.5 mm 2 ).
  • the magnetron is selected in three sizes, which can be respectively labeled as magnetron a (for comparative example), magnetron b (for embodiment), and magnetron c (for embodiment).
  • the projected area of the magnetron a on the plane of the target is 1/2 of the target area, that is, 79481.25 mm 2 ;
  • the projected area of the magnetron b on the plane of the target is 1 of the target area /5, ie 31792.5 mm 2 ;
  • the projected area of the magnetron c on the plane of the target is 1/15 of the target area, ie 10597.5 mm 2 , preferably, the magnetron c is on the plane of the target
  • the area of the projection is less than 1/15 of the area of the target.
  • the magnetron c has a kidney-shaped structure, and the short diameter D is less than or equal to 75 mm, and the long diameter L is less than or equal to 140 mm.
  • test results of the present invention are characterized by three parameters of film coverage, film uniformity, and productivity.
  • the film coverage is calculated as 100%*T b /T f , T b is the thickness of the bottom film of the through silicon via, and T f is the thickness of the surface film of the wafer. The larger the value of the film coverage, the thicker the film deposited on the bottom of the through silicon via.
  • the production capacity is defined as the number of wafers produced by the equipment per unit time, which is generally the number of wafers produced by the equipment per hour. In this test, the number of wafers produced by the equipment per hour is also used. it is good.
  • Example 1 Comparing the data of Example 1, Example 2 and Comparative Example 1 in Table 1, it can be seen that when the area of the projection of the magnetron on the plane of the target is less than or equal to one-fifth of the area of the target. At the same time, the film coverage is relatively highest, which indicates that in these three examples, when the area of the projection of the magnetron on the plane of the target is less than or equal to one-fifth of the area of the target, the filling rate of the through-silicon via is relatively highest. .
  • Example 3 in Table 1 Comparing Example 3 in Table 1 with Example 1, it can be seen that in the case where the area of the projection of the magnetron on the plane of the target is kept to be less than or equal to one-fifth of the area of the target, After the bias unit is provided, the coverage of the film and the uniformity of the film can be further improved.
  • the biasing unit can further increase the filling rate and filling uniformity of the through silicon via.
  • Example 4 Comparing Example 4 and Example 2 in Table 1, it can be seen that in the case where the area of the projection of the magnetron on the plane of the target is kept to be less than or equal to one-fifth of the area of the target.
  • the coverage of the film and the uniformity of the film are further improved, which means that the setting of the biasing unit can further improve the filling rate and filling uniformity of the through-silicon via.
  • the bias unit is further disposed, so that the generated positive ions are close to vertical. The angle is incident into the through silicon vias, thereby increasing the fill rate of the through silicon vias and improving fill uniformity.

Abstract

A magnetron sputtering cavity for through-silicon-via filling and a semiconductor processing device. The magnetron sputtering cavity comprises a cavity, a target (2) provided at the top of the cavity, a magnetron (1) provided above the target (2), and a base (3) provided inside the cavity and located below the target (2); the area of a projection of the magnetron (1) on a plane where the target (2) is located is less than or equal to one fifth of the area of the target to improve the ionization rate of a dielectric gas so as to improve the filling rate for the through-silicon-via (41). The semiconductor processing device comprises the magnetron sputtering cavity. The magnetron sputtering cavity and the semiconductor processing device improve the filling rate of the through-silicon-via.

Description

用于硅通孔填充的磁控溅射腔室和半导体处理设备Magnetron sputtering chamber and semiconductor processing equipment for through-silicon via filling 技术领域Technical field
本发明属于半导体设备领域,具体地,涉及一种用于硅通孔填充的磁控溅射腔室和半导体处理设备。The invention belongs to the field of semiconductor devices, and in particular to a magnetron sputtering chamber and a semiconductor processing device for through-silicon via filling.
背景技术Background technique
物理气相沉积(Physical Vapor Deposition,PVD)是集成电路制造过程中沉积金属层和相关材料广泛采用的方法。目前硅通孔(Through Silicon Via,TSV)技术的应用越来越广泛,该技术大大降低了芯片之间的互连延迟,并且是三维集成实现的关键技术。PVD在TSV中的应用主要是在硅通孔内部沉积阻挡层和铜籽晶层,阻挡层的作用是防止铜向硅或者二氧化硅中扩散,铜籽晶层的作用是为后续电镀工艺做一层导电层,因此在硅通孔内沉积阻挡层和铜籽晶层对物理气相沉积的薄膜覆盖率有很高的要求。阻挡层的薄膜覆盖率不佳,会影响TSV器件的可靠性;铜籽晶层的覆盖率不佳,可能会导致电镀无法进行,或者电镀后的TSV器件有空洞或缝隙,严重影响器件性能。Physical Vapor Deposition (PVD) is a widely used method for depositing metal layers and related materials in integrated circuit manufacturing processes. At present, the application of Through Silicon Via (TSV) technology is more and more widely used. This technology greatly reduces the interconnection delay between chips and is a key technology for 3D integration implementation. The application of PVD in TSV is mainly to deposit a barrier layer and a copper seed layer inside the through-silicon via. The function of the barrier layer is to prevent copper from diffusing into silicon or silicon dioxide. The role of the copper seed layer is for the subsequent electroplating process. A layer of conductive layer, so the deposition of a barrier layer and a copper seed layer in the through-silicon via has high requirements for physical vapor deposition film coverage. The poor coverage of the barrier film will affect the reliability of the TSV device; the poor coverage of the copper seed layer may result in the inability to perform electroplating, or the TSV device after plating may have voids or gaps, which seriously affects device performance.
典型的直流磁控溅射设备如图1以及图2所示,该设备包括用于承载晶片4的基座3,基座3及其所承载的晶片4与靶材2正对设置;为了保证薄膜的均匀性,磁控管面积设计的都较大,一般磁控管在靶材2上的投影的面积占靶材2的面积的二分之一以上;为了提高薄膜的沉积速率,靶基距(靶材2与晶片4之间的距离)通常设置为小于70mm。A typical DC magnetron sputtering apparatus is shown in FIGS. 1 and 2, the apparatus includes a susceptor 3 for carrying a wafer 4, and the susceptor 3 and the wafer 4 carried thereon are disposed opposite the target 2; The uniformity of the film and the area of the magnetron are designed. Generally, the projected area of the magnetron on the target 2 accounts for more than one-half of the area of the target 2; in order to increase the deposition rate of the film, the target The distance (distance between the target 2 and the wafer 4) is usually set to be less than 70 mm.
但在现有技术中,存在以下问题:However, in the prior art, the following problems exist:
(1)由于磁控管面积太大导致了介质气体的离化率较低,从而使硅通孔的填充速率较慢; (1) Since the area of the magnetron is too large, the ionization rate of the dielectric gas is low, so that the filling rate of the through silicon via is slow;
(2)如图2所示,靶材2的主要腐蚀区域靠近靶材2的边缘位置,由于靶基距太小,离子和原子入射至晶片4中心部位的硅通孔41的角度大于入射至晶片4中心部位的硅通孔41的角度,导致了晶片4的中心位置和晶片4的边缘位置处的覆盖率差异较大,对硅通孔的填充不均匀。(2) As shown in FIG. 2, the main corrosion region of the target 2 is close to the edge position of the target 2, and since the target base distance is too small, the angle at which the ions and atoms are incident on the through-silicon via 41 at the center of the wafer 4 is larger than the incident to The angle of the through silicon via 41 at the central portion of the wafer 4 causes a large difference in coverage between the center position of the wafer 4 and the edge position of the wafer 4, and the filling of the through silicon via is uneven.
鉴于此,需要提供一种提高硅通孔填充速率和提高硅通孔填充均匀度的磁控溅射腔室和半导体处理设备。In view of this, it is desirable to provide a magnetron sputtering chamber and a semiconductor processing apparatus that increase the through-silicon via fill rate and increase the uniformity of through-silicon via fill.
发明内容Summary of the invention
本发明提供了一种用于硅通孔填充的磁控溅射腔室和半导体处理设备,至少解决了现有技术中存在的对硅通孔填充时沉积速率低的问题。The present invention provides a magnetron sputtering chamber and a semiconductor processing apparatus for through-silicon via filling, which at least solves the problem of low deposition rate in the prior art for filling silicon vias.
根据本发明的一方面,提供了一种用于硅通孔填充的磁控溅射腔室,其包括:腔体、设置于所述腔体顶部的靶材、设置于所述靶材上方的磁控管、以及设置于所述腔体内部且位于所述靶材下方的基座,所述磁控管在所述靶材所在平面上的投影的面积小于等于五分之一的所述靶材的面积。According to an aspect of the present invention, a magnetron sputtering chamber for through-silicon via filling is provided, comprising: a cavity, a target disposed on a top of the cavity, and a device disposed above the target a magnetron, and a susceptor disposed inside the cavity and below the target, the projected area of the magnetron on the plane of the target being less than or equal to one-fifth of the target The area of the material.
其中,所述磁控管在所述靶材所在平面上的投影的面积小于十五分之一的所述靶材的面积。Wherein the projected area of the magnetron on the plane of the target is less than one-fifth of the area of the target.
其中,所述磁控管包括磁性相反的外磁极和内磁极,所述内磁极被所述外磁极包围。Wherein, the magnetron comprises an outer magnetic pole and an inner magnetic pole opposite in magnetic polarity, and the inner magnetic pole is surrounded by the outer magnetic pole.
其中,所述外磁极具有长径和短径,所述短径小于或等于所述腔室内径与所述基座欲承载的晶片的直径的差的二分之一。Wherein, the outer magnetic pole has a long diameter and a short diameter, and the short diameter is less than or equal to one-half of a difference between a diameter of the inner chamber and a diameter of a wafer to be carried by the susceptor.
其中,所述磁控溅射腔室还包括旋转机构,所述旋转机构包括旋转轴、第一旋转臂和第二旋转臂;所述第一旋转臂的一端与所述旋转轴固定连接,另一端与所述第二旋转臂的一端连接,所述第二旋转臂的另一端与所述磁控管固定连接;所述第一旋转臂与所述第二旋转臂之间具有夹角;所述旋转轴带动所述第一旋转臂和所述第二旋转臂旋转,从而带动所述磁控管旋转。Wherein the magnetron sputtering chamber further includes a rotating mechanism, the rotating mechanism includes a rotating shaft, a first rotating arm and a second rotating arm; one end of the first rotating arm is fixedly connected with the rotating shaft, and One end is connected to one end of the second rotating arm, and the other end of the second rotating arm is fixedly connected to the magnetron; the first rotating arm and the second rotating arm have an angle; The rotating shaft drives the first rotating arm and the second rotating arm to rotate, thereby driving the magnetron to rotate.
其中,所述第一旋转臂与所述第二旋转臂之间的夹角可调,所述夹角范 围为0-180度;当所述夹角为0度时,所述磁控管在所述靶材所在平面上的投影落在所述靶材的中心区域;当所述夹角为180度时,所述磁控管在所述靶材所在平面上的投影落在所述靶材的边缘区域。Wherein the angle between the first rotating arm and the second rotating arm is adjustable, and the angle is a circumference of 0-180 degrees; when the included angle is 0 degrees, a projection of the magnetron on a plane of the target falls in a central area of the target; when the angle is 180 degrees The projection of the magnetron on the plane of the target falls on the edge region of the target.
其中,所述磁控溅射腔室还包括偏压单元,所述偏压单元在所述基座上产生负偏压,以吸引正离子向所述基座方向垂直运动。Wherein, the magnetron sputtering chamber further includes a biasing unit that generates a negative bias on the base to attract positive ions to move vertically toward the base.
其中,所述偏压单元包括射频电源和匹配器,其中,所述射频电源通过所述匹配器与所述基座相连;所述射频电源的功率范围为800-1400W。The biasing unit includes a radio frequency power source and a matching device, wherein the radio frequency power source is connected to the base through the matching device; the power of the radio frequency power source ranges from 800 to 1400 W.
其中,所述靶材与所述基座之间的竖直距离为100-150mm。Wherein, the vertical distance between the target and the base is 100-150 mm.
作为另一个方面,本发明还提供一种半导体处理设备,其包括上述任一种方案所述的用于硅通孔填充的磁控溅射腔室。In another aspect, the present invention also provides a semiconductor processing apparatus comprising the magnetron sputtering chamber for through silicon via filling described in any of the above aspects.
有益效果:Beneficial effects:
本发明提供的用于硅通孔填充的磁控溅射腔室,磁控管在靶材上的投影的面积小于等于五分之一的靶材面积,这相对于现有技术中磁控管在靶材上的投影的面积一般大于等于二分之一的靶材面积的情况相比,在所加载的功率相同的情况下,本发明可以提高介质气体(如氩气)的离化率,从而有效提高对硅通孔的填充速率,甚至进一步提高薄膜覆盖率。The present invention provides a magnetron sputtering chamber for through-silicon via filling. The projected area of the magnetron on the target is less than or equal to one-fifth of the target area, which is relative to the prior art magnetron. Compared with the case where the projected area on the target is generally greater than or equal to one-half of the target area, the present invention can increase the ionization rate of the dielectric gas (such as argon) in the case where the loaded power is the same. Thereby, the filling rate of the through silicon vias is effectively increased, and the film coverage is further improved.
根据本发明的半导体设备,采用了本发明的用于硅通孔填充的磁控溅射腔室,同样能够提高对硅通孔的填充速率,甚至进一步提高薄膜覆盖率。According to the semiconductor device of the present invention, the magnetron sputtering chamber for through-silicon via filling of the present invention is employed, and the filling rate of the through-silicon via holes can be increased, and the film coverage can be further improved.
附图说明DRAWINGS
图1为现有技术中用于硅通孔填充的磁控溅射腔室的结构示意图;1 is a schematic structural view of a magnetron sputtering chamber for through-silicon via filling in the prior art;
图2为现有技术中用于硅通孔填充的磁控溅射腔室对硅通孔进行填充时等离子体的入射角度示意图;2 is a schematic view showing an incident angle of a plasma when a through-silicon via is filled in a magnetron sputtering chamber for through-silicon via filling in the prior art;
图3为根据本发明一种实施例的用于硅通孔填充的磁控溅射腔室的示意图; 3 is a schematic diagram of a magnetron sputtering chamber for through silicon via filling in accordance with an embodiment of the present invention;
图4为根据本发明一种实施例的用于硅通孔填充的磁控溅射腔室的示意图;4 is a schematic diagram of a magnetron sputtering chamber for through silicon via filling in accordance with an embodiment of the present invention;
图5为根据本发明一种实施例的用于硅通孔填充的磁控溅射腔室的示意图;5 is a schematic diagram of a magnetron sputtering chamber for through silicon via filling in accordance with an embodiment of the present invention;
图6为根据图5所示实施例中对硅通孔填充时正离子的入射角度示意图;6 is a schematic view showing an incident angle of positive ions when filling a through silicon via according to the embodiment shown in FIG. 5;
附图标记:Reference mark:
1-磁控管;2-靶材;3-基座;4-晶片;41-硅通孔;5-旋转机构;51-旋转轴;52-第一旋转臂;53-第二旋转臂;6-偏压单元。1-magnetron; 2-target; 3-base; 4-wafer; 41-silicon via; 5-rotating mechanism; 51-rotating shaft; 52-first rotating arm; 53-second rotating arm; 6-bias unit.
具体实施方式detailed description
现在将结合附图和实施例来对本发明进行详细的描述。值得注意的是下述实施例仅用于对本发明进行说明,而不对本发明的范围进行限制。The invention will now be described in detail in conjunction with the drawings and embodiments. It is to be noted that the following examples are merely illustrative of the invention and are not intended to limit the scope of the invention.
值得注意的是,相似的标号和字母在下面的附图中表示类似项,因此,一旦某一项在一个附图中被定义,则在随后的附图中不需要对其进行进一步讨论。It is noted that like numerals and letters indicate similar items in the following figures, and therefore, once an item is defined in a drawing, it is not required to be further discussed in the subsequent figures.
实施例1Example 1
本实施例提供了一种用于硅通孔填充的磁控溅射腔室,包括:腔体、设置于腔体顶部的靶材、设置于靶材上方的磁控管、以及设置于腔体内部且位于靶材下方的基座,磁控管在靶材上的投影的面积小于或等于靶材面积的五分之一,以提高介质气体的离化率,从而提高对硅通孔的填充速率。The present embodiment provides a magnetron sputtering chamber for through-silicon via filling, comprising: a cavity, a target disposed on the top of the cavity, a magnetron disposed above the target, and a cavity Internal and located below the target, the projected area of the magnetron on the target is less than or equal to one-fifth of the target area to increase the ionization rate of the dielectric gas, thereby increasing the filling of the through-silicon via. rate.
现有技术中,磁控管在靶材所在平面上的投影的面积一般为靶材面积的二分之一,而本发明提供的磁控溅射腔室采用的磁控管在靶材所在平面上的投影的面积小于或等于靶材面积的五分之一。相较于现有技术,在相同功率条件下,本发明提供的磁控溅射腔室能够提高单位面积的功率密度,以此大幅度提高对介质气体的离化率,即,产生更多的离子,从而可提高对硅通孔 的填充速率。In the prior art, the projected area of the magnetron on the plane of the target is generally one-half of the area of the target, and the magnetron sputtering chamber provided by the present invention uses a magnetron in the plane of the target. The area of the projection above is less than or equal to one-fifth of the area of the target. Compared with the prior art, under the same power conditions, the magnetron sputtering chamber provided by the invention can increase the power density per unit area, thereby greatly increasing the ionization rate of the medium gas, that is, generating more Ions, which can improve the through silicon via The fill rate.
其中,磁控管在靶材所在平面上的投影的面积优选小于靶材面积的十五分之一,当磁控管在靶材所在平面上的投影的面积小于靶材面积的十五分之一时,在相同功率条件下,单位面积的功率密度更高,介质气体的离化率也相应地更高,因此对硅通孔的填充速率也会更高。Wherein, the projected area of the magnetron on the plane of the target is preferably less than one-fifth of the area of the target, and the projected area of the magnetron on the plane of the target is less than fifteenth of the area of the target. At one time, under the same power conditions, the power density per unit area is higher, and the ionization rate of the dielectric gas is correspondingly higher, so the filling rate of the through silicon vias is also higher.
实施例2Example 2
本实施例中的磁控管包括磁性相反的外磁极和内磁极,内磁极被外磁极包围。至于本实施例中的其它设置,与实施例1的设置相同,在此不予赘述。The magnetron in this embodiment includes an outer magnetic pole and an inner magnetic pole which are opposite in magnetic polarity, and the inner magnetic pole is surrounded by the outer magnetic pole. The other settings in this embodiment are the same as those in the first embodiment, and are not described herein.
优选地,如图3所示,本实施例的磁控溅射腔室中的磁控管1包括磁性相反的外磁极和内磁极,内磁极被外磁极包围,且磁控管1呈肾型,其能提供更高的介质气体的离化率。另外,磁控管1的外磁极可以为圆形、矩形或者椭圆形。其中,外磁极具有长径L和短径D,短径D优选小于或等于腔室内径与基座3欲承载的晶片4的直径的差的二分之一,即在工艺过程中,短径D小于或等于腔室内径的半径与晶片4的半径的差。当磁控管1的短径D小于或等于腔室与晶片4的半径差时,磁控管1在晶片4所在平面上的投影位于晶片4和腔室壁在该平面上的投影之间,也就是说,对于在晶片4所在平面而言,磁控管1的投影位于晶片4的外侧区域(以下简称为磁控管1位于晶片4的外侧区域),通过这样设置磁控管1,并使磁控管1的移动轨迹在晶片4所在平面上的投影落在晶片4的外侧区域,可以使逸出的靶材原子和离子一部分沉积在晶片4的边缘区域,一部分飘至晶片4的中心区域而沉积在晶片4的中心区域,从而调节晶片4的边缘区域与其中心区域的沉积的均匀性。Preferably, as shown in FIG. 3, the magnetron 1 in the magnetron sputtering chamber of the present embodiment includes magnetically opposite outer and inner magnetic poles, the inner magnetic pole is surrounded by the outer magnetic pole, and the magnetron 1 is kidney-shaped. It can provide a higher ionization rate of the medium gas. In addition, the outer magnetic pole of the magnetron 1 may be circular, rectangular or elliptical. Wherein, the outer magnetic pole has a long diameter L and a short diameter D, and the short diameter D is preferably less than or equal to one-half of the difference between the inner diameter of the chamber and the diameter of the wafer 4 to be carried by the susceptor 3, that is, the short diameter during the process. D is less than or equal to the difference between the radius of the inner diameter of the chamber and the radius of the wafer 4. When the short diameter D of the magnetron 1 is less than or equal to the difference between the chamber and the radius of the wafer 4, the projection of the magnetron 1 on the plane of the wafer 4 is between the projection of the wafer 4 and the chamber wall on the plane, That is, for the plane in which the wafer 4 is located, the projection of the magnetron 1 is located in the outer region of the wafer 4 (hereinafter referred to as the magnetron 1 in the outer region of the wafer 4), by which the magnetron 1 is disposed, and The projection of the movement trajectory of the magnetron 1 on the plane of the wafer 4 falls on the outer region of the wafer 4, so that a part of the escaped target atoms and ions are deposited on the edge region of the wafer 4, and a part is floated to the center of the wafer 4. The region is deposited in the central region of the wafer 4, thereby adjusting the uniformity of deposition of the edge region of the wafer 4 and its central region.
磁控管的短径D和长径L的最小值以能够将介质气体稳定维持在等离子体状态为条件,尺寸太小有可能会造成磁场减弱,无法使介质气体维持在等离子体状态。The minimum value of the short diameter D and the long diameter L of the magnetron is conditioned on the condition that the medium gas can be stably maintained in the plasma state. If the size is too small, the magnetic field may be weakened, and the medium gas may not be maintained in the plasma state.
实施例3 Example 3
本实施例中的磁控溅射腔室还包括图4所示的旋转机构。至于本实施例中的其它设置,与实施例2的设置相同,在此不予赘述。The magnetron sputtering chamber in this embodiment further includes the rotating mechanism shown in FIG. The other settings in this embodiment are the same as those in the second embodiment, and are not described herein.
如图4所示,本实施例中的旋转机构5包括旋转轴51、第一旋转臂52和第二旋转臂53;第一旋转臂52的一端与旋转轴51固定连接,另一端与第二旋转臂53的一端连接,第二旋转臂53的另一端与磁控管1固定连接;第一旋转臂52与第二旋转臂53之间具有夹角;旋转轴51带动第一旋转臂52和第二旋转臂53旋转,从而带动磁控管1旋转。As shown in FIG. 4, the rotating mechanism 5 in this embodiment includes a rotating shaft 51, a first rotating arm 52, and a second rotating arm 53. One end of the first rotating arm 52 is fixedly connected to the rotating shaft 51, and the other end is second. One end of the rotating arm 53 is connected, the other end of the second rotating arm 53 is fixedly connected with the magnetron 1; the first rotating arm 52 has an angle with the second rotating arm 53; the rotating shaft 51 drives the first rotating arm 52 and The second rotating arm 53 rotates to drive the magnetron 1 to rotate.
其中,第一旋转臂52和第二旋转臂53之间的连接方式,可以为固定连接,也可以为活动连接。当采用固定连接时,第一旋转臂52和第二旋转臂53之间的角度不可调;当采用活动连接时,第一旋转臂52和第二旋转臂53之间的角度可调,即,可根据工艺要求而对该角度进行调节,并在对第一旋转臂52和第二旋转臂53进行固定后再旋转旋转轴51,使第一旋转臂52和第二旋转臂53带动磁控管1旋转。The connection between the first rotating arm 52 and the second rotating arm 53 may be a fixed connection or an active connection. When a fixed connection is employed, the angle between the first rotating arm 52 and the second rotating arm 53 is not adjustable; when the movable connection is employed, the angle between the first rotating arm 52 and the second rotating arm 53 is adjustable, that is, The angle can be adjusted according to the process requirements, and after the first rotating arm 52 and the second rotating arm 53 are fixed, the rotating shaft 51 is rotated, so that the first rotating arm 52 and the second rotating arm 53 drive the magnetron. 1 rotation.
其中,在第一旋转臂52与第二旋转臂53之间的夹角可调的情况下,该夹角的范围为0-180度。当夹角为0度时,磁控管1投影在靶材2的中心区域,即,磁控管1在靶材2所在平面上的投影落在靶材2的中心区域;当夹角为180度时,磁控管1投影在靶材2的边缘区域,即,磁控管1在靶材2所在平面上的投影落在靶材2的边缘区域。Wherein, in the case where the angle between the first rotating arm 52 and the second rotating arm 53 is adjustable, the angle ranges from 0 to 180 degrees. When the angle is 0 degree, the magnetron 1 is projected in the central area of the target 2, that is, the projection of the magnetron 1 on the plane of the target 2 falls in the central area of the target 2; when the angle is 180 At the time, the magnetron 1 is projected on the edge region of the target 2, that is, the projection of the magnetron 1 on the plane of the target 2 falls on the edge region of the target 2.
其中,在第一旋转臂52与第二旋转臂53之间的夹角可调的情况下,第一旋转臂52与第二旋转臂53之间的夹角的选择与晶片4的硅通孔的主要填充位置对应。即,根据晶片4主要填充位置,设定第一旋转臂52和第二旋转臂53之间的夹角。当夹角为0度时,磁控管1在靶材2所在平面上的投影落在靶材2的中心区域,此时主要对晶片4的中心区域的硅通孔进行填充;当夹角为180度时,磁控管1在靶材2所在平面上的投影落在靶材2的边缘区域,此时主要对晶片4的边缘区域进行填充;根据填充情况,可以及时的调节第一旋转臂52和第二旋转臂53之间的夹角,从而调整磁控管1在靶材 2上的投影位置,从而改变晶片4的主要填充位置,使对硅通孔的填充更加均匀。所谓主要填充位置,指的是在硅通孔填充时,大部分的离子和原子所沉积的位置。Wherein, in the case where the angle between the first rotating arm 52 and the second rotating arm 53 is adjustable, the selection of the angle between the first rotating arm 52 and the second rotating arm 53 and the through hole of the wafer 4 The main fill position corresponds. That is, the angle between the first rotating arm 52 and the second rotating arm 53 is set in accordance with the main filling position of the wafer 4. When the angle is 0 degree, the projection of the magnetron 1 on the plane of the target 2 falls on the central region of the target 2, at which time the through-silicon vias of the central region of the wafer 4 are mainly filled; At 180 degrees, the projection of the magnetron 1 on the plane of the target 2 falls on the edge region of the target 2, at which time the edge region of the wafer 4 is mainly filled; according to the filling condition, the first rotating arm can be adjusted in time. An angle between 52 and the second rotating arm 53, thereby adjusting the magnetron 1 at the target The projection position on 2, thereby changing the main filling position of the wafer 4, makes the filling of the through-silicon vias more uniform. The so-called main filling position refers to the position where most of the ions and atoms are deposited when the through silicon via is filled.
实施例4Example 4
本实施例中的磁控溅射腔室还包括偏压单元。至于其它设置,与实施例3的设置相同,在此不予赘述。The magnetron sputtering chamber in this embodiment further includes a biasing unit. As for other settings, the same as the setting of Embodiment 3, and details are not described herein.
如图5所示,本实施例的磁控溅射腔室包括偏压单元6,偏压单元6在基座2上产生负偏压,以吸引带正电荷的离子垂直进入晶片4的硅通孔底部,从而可以提高对硅通孔填充的均匀性。As shown in FIG. 5, the magnetron sputtering chamber of the present embodiment includes a biasing unit 6 that generates a negative bias on the susceptor 2 to attract positively charged ions into the silicon pass of the wafer 4 vertically. The bottom of the hole, so that the uniformity of the through-silicon via filling can be improved.
如图6所示,由于本实施例的磁控溅射腔室中设置有偏压单元6,在该偏压单元6的作用下,工艺气体离化后产生的正离子会以接近于零的入射角垂直向硅通孔运动,如图6中的箭头所示。正离子垂直填充至硅通孔,不仅可以提高填充速率,而且可以提高填充的均匀性。As shown in FIG. 6, since the biasing unit 6 is disposed in the magnetron sputtering chamber of the embodiment, the positive ions generated by the process gas ionization will be close to zero under the action of the biasing unit 6. The angle of incidence is perpendicular to the through silicon via, as indicated by the arrows in FIG. The positive ions are vertically filled into the through silicon vias, which not only improves the filling rate, but also improves the uniformity of filling.
本实施例中,通过减小磁控管1的体积而使其在靶材2所在平面上的投影的面积小于或者等于靶材2的面积的五分之一,以此提高介质气体的离化率,增加等离子体中的正离子的数量。进一步地,通过设置偏压单元6,可以使正离子以接近于零的入射角垂直填充至硅通孔,从而提高填充的均匀性,有效解决了现有技术中所存在的问题,即,正离子在晶片的边缘部分入射角度接近0度,而在中心部分的入射角度较大,造成对晶片的中心部分的硅通孔填充和边缘部分的硅通孔填充不均匀问题。In the present embodiment, the area of the magnetron 1 is reduced by making the volume of the magnetron 1 projected on the plane of the target 2 less than or equal to one fifth of the area of the target 2, thereby increasing the ionization of the medium gas. Rate, increasing the amount of positive ions in the plasma. Further, by providing the biasing unit 6, the positive ions can be vertically filled to the through-silicon vias at an incident angle close to zero, thereby improving the uniformity of filling, and effectively solving the problems existing in the prior art, that is, positive The incident angle of ions at the edge portion of the wafer is close to 0 degrees, and the incident angle at the central portion is large, causing a problem of uneven filling of the through-silicon via holes in the central portion of the wafer and the through-hole filling of the edge portions.
其中,偏压单元优选包括射频电源和匹配器,射频电源通过匹配器与基座相连。射频电源的功率范围优选为800-1400W,进一步地优选为1000-1300W,更进一步地优选为1100W、1200W和1250W。优选将射频电源的功率范围设置为800-1400W的原因在于:当射频功率范围小于800W时,在基座上产生的偏压难以将正离子吸引至晶片的硅通孔中;当射频功率大于1400W时,在基座上产生的偏压过大,使正离子运动的速度过快,沉积至硅 通孔41底部时的能量较强,会造成过度轰击,即,会减薄薄硅通孔41底部的原有的沉积层,甚至使底部的沉积层完全被溅射到侧壁上,降低沉积的均匀度。Wherein, the biasing unit preferably includes a radio frequency power source and a matching device, and the radio frequency power source is connected to the base through the matching device. The power range of the radio frequency power source is preferably 800-1400 W, further preferably 1000-1300 W, and still more preferably 1100 W, 1200 W, and 1250 W. The reason why the power range of the RF power source is preferably set to 800-1400 W is that when the RF power range is less than 800 W, the bias generated on the susceptor is difficult to attract positive ions into the through silicon vias of the wafer; when the RF power is greater than 1400 W At this time, the bias generated on the pedestal is too large, so that the positive ions move too fast and deposit to silicon. The energy at the bottom of the through hole 41 is strong, which causes excessive bombardment, that is, the original deposited layer at the bottom of the thin through silicon via 41 is thinned, and even the deposited layer at the bottom is completely sputtered onto the sidewall, reducing deposition. Uniformity.
当射频电源的功率范围保持在800-1400W之间时,一方面,其在基座3上产生了适当的负偏压,在一定程度上增加正离子的动能,加快了正离子向晶片4的移动加速,提高了填充速率;另一方面又使离子保持适当的动能,在轰击硅通孔41的底面时,会使一部分之前沉积在硅通孔41底部的薄膜脱离溅射至硅通孔41的侧壁拐角的位置,从而提高了硅通孔底部和侧壁拐角位置的覆盖率,使硅通孔41的底部和侧壁拐角位置的沉积厚度较为均匀。When the power range of the RF power source is maintained between 800 and 1400 W, on the one hand, it generates an appropriate negative bias on the pedestal 3, increasing the kinetic energy of the positive ions to some extent, and accelerating the positive ions to the wafer 4. The acceleration of the movement increases the filling rate; on the other hand, the ions maintain proper kinetic energy, and when the bottom surface of the through silicon via 41 is bombarded, a part of the film previously deposited on the bottom of the through silicon via 41 is sputtered out to the through silicon via 41. The position of the corner of the side wall increases the coverage of the bottom of the through-silicon via and the corner of the sidewall, so that the thickness of the bottom of the through-silicon via 41 and the corner of the sidewall are relatively uniform.
实施例5Example 5
在本实施例的磁控溅射腔室中,靶材2与基座3之间的竖直距离为100-150mm。至于本实施例中的其它设置,与实施例4的设置相同,在此不予赘述。In the magnetron sputtering chamber of the present embodiment, the vertical distance between the target 2 and the susceptor 3 is 100-150 mm. The other settings in this embodiment are the same as those in the embodiment 4, and are not described herein.
根据本实施例的磁控溅射腔室,在使磁控管在靶材所在平面上的投影的面积小于或等于靶材面积的五分之一、且设置偏压单元的基础上,将靶材与基座之间的竖直距离设置为100-150mm。将靶材与基座之间的竖直距离设置为100-150mm,大于现有技术中的70mm,即增大了靶基距,这使得以较小的入射角填充至硅通孔中的正离子增多,特别是垂直填充至硅通孔中的正离子增多,从而提高了薄膜覆盖率以及靶材的利用率。According to the magnetron sputtering chamber of the present embodiment, the target is projected on the basis of the area where the projection of the magnetron on the plane of the target is less than or equal to one-fifth of the area of the target and the bias unit is disposed. The vertical distance between the material and the base is set to 100-150 mm. The vertical distance between the target and the pedestal is set to 100-150 mm, which is larger than 70 mm in the prior art, that is, the target base distance is increased, which makes the positive filling into the through-silicon via at a small incident angle. The increase in ions, especially the positive ions that are vertically filled into the through-silicon vias, increases the film coverage and the utilization of the target.
本发明实施例1至实施例5提供的用于硅通孔填充的磁控溅射腔室,均提高了硅通孔的填充速率,甚至能够进一步提高硅通孔的填充均匀性。The magnetron sputtering chambers for silicon via filling provided by Embodiments 1 to 5 of the present invention all increase the filling rate of the through silicon vias, and can even further improve the filling uniformity of the through silicon vias.
实施例6Example 6
本实施例提供了一种半导体处理设备,本实施例中的半导体处理设备可以包括实施例1-5中的任意一种用于硅通孔填充的磁控溅射腔室。The present embodiment provides a semiconductor processing apparatus. The semiconductor processing apparatus in this embodiment may include any one of Embodiments 1-5 for a magnetron sputtering chamber for through-silicon via filling.
当然,在本发明的半导体设备中,可以包括权利要求中进行任何排列组合形成的其它磁控溅射腔室。 Of course, in the semiconductor device of the present invention, other magnetron sputtering chambers formed by any arrangement and combination in the claims may be included.
本实施例中的半导体处理设备,采用本发明的磁控溅射腔室,能够提高硅通孔填充的填充速率,甚至能够进一步提高硅通孔的填充均匀性。The semiconductor processing apparatus in this embodiment adopts the magnetron sputtering chamber of the present invention, can improve the filling rate of the through silicon via filling, and can even further improve the filling uniformity of the through silicon via.
综上可以看出,在本发明的用于硅通孔填充的磁控溅射腔室及半导体设备中,将磁控管在靶材所在平面上的投影的面积设置为小于或等于靶材面积的五分之一、设置和基座连接的偏压单元、和/或将靶基距设置在100mm-150mm之间,在对硅通孔进行填充时,这个三个方面的因素可以相互结合、相辅相成,可以更大程度上提高对硅通孔的填充速率,甚至进一步提高硅通孔的填充均匀性。In summary, in the magnetron sputtering chamber and the semiconductor device for through-silicon via filling of the present invention, the projected area of the magnetron on the plane of the target is set to be smaller than or equal to the target area. One-fifth of the set, the biasing unit connected to the base, and/or the target base distance is between 100mm and 150mm. When filling the through-silicon via, these three factors can be combined with each other. Complementing each other, the filling rate of the through silicon vias can be increased to a greater extent, and the filling uniformity of the through silicon vias can be further improved.
申请人为了证明本发明的磁控溅射腔室对硅通孔进行填充时具有提高填充速率和填充均匀性的效果,以下采用实施例和比较例进行对比说明。In order to prove that the magnetron sputtering chamber of the present invention has an effect of increasing the filling rate and the filling uniformity when filling the through silicon via, the following description will be made by way of comparative examples and comparative examples.
在下述比较例和实施例中,采用的磁控溅射腔室的腔体半径为222.5mm,基座的半径为150mm。晶片为12寸晶片(直径300mm),靶材直径选用450mm(靶材面积为158962.5mm2)。In the comparative examples and examples described below, the magnetron sputtering chamber used had a cavity radius of 222.5 mm and a pedestal radius of 150 mm. The wafer is a 12-inch wafer (300 mm in diameter) and the target diameter is 450 mm (target area is 158962.5 mm 2 ).
同时为了对比,磁控管选用了三种规格,可以分别标记为磁控管a(用于比较例)、磁控管b(用于实施例)和磁控管c(用于实施例)。其中,磁控管a在靶材所在平面上的投影的面积为靶材面积的1/2,即79481.25mm2;磁控管b在靶材所在平面上的投影的面积为靶材面积的1/5,即31792.5mm2;磁控管c在靶材所在平面上的投影的面积为靶材面积的1/15,即10597.5mm2,优选地,磁控管c在靶材所在平面上的投影的面积小于靶材面积的1/15,例如,磁控管c采用肾形结构,且其短径长度D小于等于75mm,长径长度L小于等于140mm。At the same time, for comparison, the magnetron is selected in three sizes, which can be respectively labeled as magnetron a (for comparative example), magnetron b (for embodiment), and magnetron c (for embodiment). Wherein, the projected area of the magnetron a on the plane of the target is 1/2 of the target area, that is, 79481.25 mm 2 ; the projected area of the magnetron b on the plane of the target is 1 of the target area /5, ie 31792.5 mm 2 ; the projected area of the magnetron c on the plane of the target is 1/15 of the target area, ie 10597.5 mm 2 , preferably, the magnetron c is on the plane of the target The area of the projection is less than 1/15 of the area of the target. For example, the magnetron c has a kidney-shaped structure, and the short diameter D is less than or equal to 75 mm, and the long diameter L is less than or equal to 140 mm.
本发明的测试结果用薄膜覆盖率、薄膜均匀性、产能这三个参数来表征。The test results of the present invention are characterized by three parameters of film coverage, film uniformity, and productivity.
其中,薄膜覆盖率的计算公式为100%*Tb/Tf,Tb为硅通孔的底部薄膜的厚度,Tf为晶片的表面薄膜的厚度。薄膜覆盖率的数值越大,则表示沉积在硅通孔底部上的薄膜越厚。Wherein, the film coverage is calculated as 100%*T b /T f , T b is the thickness of the bottom film of the through silicon via, and T f is the thickness of the surface film of the wafer. The larger the value of the film coverage, the thicker the film deposited on the bottom of the through silicon via.
薄膜均匀性定义为晶片的表面薄膜厚度分布均匀程度,采用专业的金属 薄膜厚度测量设备进行检测,常用的如Rudolph公司的MetaPULSE。薄膜厚度均匀性的检测方式通常为:在晶片上选取均匀分布的一定数量(通常为49个)的点,测量这些点处的薄膜厚度,这些点的薄膜厚度平均值记为AVG,方差记为STDEV,那么薄膜均匀性U的计算公式为U=100%*STDEV/AVG,U的数值越小,则说明薄膜分布越均匀。Film uniformity is defined as the uniformity of the thickness distribution of the surface film of the wafer, using professional metal Film thickness measuring equipment is used for testing, commonly used by Rudolph's MetaPULSE. Film thickness uniformity is usually measured by selecting a uniform number of (usually 49) points uniformly distributed on the wafer and measuring the film thickness at these points. The average film thickness at these points is recorded as AVG, and the variance is recorded as STDEV, then the calculation formula of the film uniformity U is U=100%*STDEV/AVG, and the smaller the value of U, the more uniform the film distribution.
产能定义为单位时间内设备所生产的晶片的数量,一般为每小时内设备所生产的晶片的数量,在本检测中也采用每小时内设备所生产的晶片的数量,该值越大效果越好。The production capacity is defined as the number of wafers produced by the equipment per unit time, which is generally the number of wafers produced by the equipment per hour. In this test, the number of wafers produced by the equipment per hour is also used. it is good.
申请人对晶片的性能进行了测试,具体的测试条件和测试结果如表1所示:The applicant tested the performance of the wafer. The specific test conditions and test results are shown in Table 1:
表1Table 1
Figure PCTCN2017095587-appb-000001
Figure PCTCN2017095587-appb-000001
将表1中的实施例1、实施例2和比较例1的数据进行比较,可以看出:当磁控管在靶材所在平面上的投影的面积小于等于靶材面积的十五分之一时,薄膜覆盖率相对最高,这说明在这三个例子中当磁控管在靶材所在平面上的投影的面积小于等于靶材面积的十五分之一时硅通孔的填充速率相对最高。Comparing the data of Example 1, Example 2 and Comparative Example 1 in Table 1, it can be seen that when the area of the projection of the magnetron on the plane of the target is less than or equal to one-fifth of the area of the target. At the same time, the film coverage is relatively highest, which indicates that in these three examples, when the area of the projection of the magnetron on the plane of the target is less than or equal to one-fifth of the area of the target, the filling rate of the through-silicon via is relatively highest. .
将表1中的实施例3与实施例1进行对比,可以看出:在保持磁控管在靶材所在平面上的投影的面积小于等于靶材面积的五分之一不变的情况下,设置偏压单元后,可以进一步提高薄膜的覆盖率和薄膜的均匀性,这说明设 置偏压单元可以进一步提高对硅通孔的填充速率和填充均匀性。Comparing Example 3 in Table 1 with Example 1, it can be seen that in the case where the area of the projection of the magnetron on the plane of the target is kept to be less than or equal to one-fifth of the area of the target, After the bias unit is provided, the coverage of the film and the uniformity of the film can be further improved. The biasing unit can further increase the filling rate and filling uniformity of the through silicon via.
将表1中的实施例4和实施例2进行对比,可以看出:在保持磁控管在靶材所在平面上的投影的面积小于等于靶材面积的十五分之一不变的情况下,设置偏压单元后,进一步提高了薄膜的覆盖率和薄膜的均匀性,这说明设置偏压单元可以进一步提高对硅通孔的填充速率和填充均匀性。Comparing Example 4 and Example 2 in Table 1, it can be seen that in the case where the area of the projection of the magnetron on the plane of the target is kept to be less than or equal to one-fifth of the area of the target. After the bias unit is disposed, the coverage of the film and the uniformity of the film are further improved, which means that the setting of the biasing unit can further improve the filling rate and filling uniformity of the through-silicon via.
根据对表1中的数据的分析也可以看出,在比较例以及各个实施例中,在产能以及其他条件不变的前提下,磁控管在靶材所在平面上的投影的面积越小,越能够提高介质气体的离化率,增加磁控溅射后正离子的数量,进而提高填充速率。进一步地,在保持磁控管在靶材所在平面上的投影的面积小于等于靶材面积的十五分之一不变的情况下,再设置偏压单元,会使产生的正离子以接近垂直的角度入射至硅通孔中,从而提高硅通孔的填充速率,以及提高填充均匀性。According to the analysis of the data in Table 1, it can be seen that in the comparative example and the respective embodiments, the smaller the area of projection of the magnetron on the plane of the target, the smaller the capacity and other conditions, The more the ionization rate of the dielectric gas can be increased, the number of positive ions after magnetron sputtering is increased, and the filling rate is increased. Further, in the case where the area of the projection of the magnetron on the plane of the target is kept to be less than or equal to one-fifth of the area of the target, the bias unit is further disposed, so that the generated positive ions are close to vertical. The angle is incident into the through silicon vias, thereby increasing the fill rate of the through silicon vias and improving fill uniformity.
虽然已经通过实施例对本发明进行了详细说明,但本领域的技术人员应该理解,以上实施例仅为了进行说明,而不为了限制本发明的范围。本领域的技术人员应该理解,可在不脱离本发明的范围和精神的情况下,对以上实施例进行修改。本发明的范围由所附权利要求来限定。 While the invention has been described in detail, the preferred embodiments of the invention It will be appreciated by those skilled in the art that the above embodiments may be modified without departing from the scope and spirit of the invention. The scope of the invention is defined by the appended claims.

Claims (10)

  1. 一种用于硅通孔填充的磁控溅射腔室,包括:腔体、设置于所述腔体顶部的靶材、设置于所述靶材上方的磁控管、以及设置于所述腔体内部且位于所述靶材下方的基座,其特征在于,A magnetron sputtering chamber for through-silicon via filling, comprising: a cavity, a target disposed on a top of the cavity, a magnetron disposed above the target, and a cavity disposed in the cavity a pedestal inside the body and below the target, characterized in that
    所述磁控管在所述靶材所在平面上的投影的面积小于等于五分之一的所述靶材的面积。The projected area of the magnetron on the plane of the target is less than or equal to one-fifth of the area of the target.
  2. 根据权利要求1所述的磁控溅射腔室,其特征在于,所述磁控管在所述靶材所在平面上的投影的面积小于十五分之一的所述靶材的面积。The magnetron sputtering chamber of claim 1 wherein the projected area of the magnetron on the plane of the target is less than one-fifth of the area of the target.
  3. 根据权利要求1所述的磁控溅射腔室,其特征在于,所述磁控管包括磁性相反的外磁极和内磁极,所述内磁极被所述外磁极包围。The magnetron sputtering chamber of claim 1 wherein said magnetron comprises an outer magnetic pole and an inner magnetic pole that are opposite in magnetic polarity, said inner magnetic pole being surrounded by said outer magnetic pole.
  4. 根据权利要求3所述的磁控溅射腔室,其特征在于,所述外磁极具有长径和短径,所述短径小于或等于所述腔室内径与所述基座欲承载的晶片的直径的差的二分之一。The magnetron sputtering chamber according to claim 3, wherein said outer magnetic pole has a long diameter and a short diameter, said short diameter being less than or equal to said inner diameter of said chamber and said wafer to be carried by said susceptor The difference in diameter is one-half.
  5. 根据权利要求1-4任一所述的磁控溅射腔室,还包括旋转机构,其特征在于,所述旋转机构包括旋转轴、第一旋转臂和第二旋转臂;A magnetron sputtering chamber according to any one of claims 1 to 4, further comprising a rotating mechanism, wherein said rotating mechanism comprises a rotating shaft, a first rotating arm and a second rotating arm;
    所述第一旋转臂的一端与所述旋转轴固定连接,另一端与所述第二旋转臂的一端连接,所述第二旋转臂的另一端与所述磁控管固定连接;One end of the first rotating arm is fixedly connected to the rotating shaft, the other end is connected to one end of the second rotating arm, and the other end of the second rotating arm is fixedly connected to the magnetron;
    所述第一旋转臂与所述第二旋转臂之间具有夹角;An angle between the first rotating arm and the second rotating arm;
    所述旋转轴带动所述第一旋转臂和所述第二旋转臂旋转,从而带动所述磁控管旋转。The rotating shaft drives the first rotating arm and the second rotating arm to rotate, thereby driving the magnetron to rotate.
  6. 根据权利要求5所述的磁控溅射腔室,其特征在于,所述第一旋转臂 与所述第二旋转臂之间的夹角可调,所述夹角范围为0-180度;The magnetron sputtering chamber of claim 5 wherein said first rotating arm An angle between the second rotating arm and the second rotating arm is adjustable, the angle is in the range of 0-180 degrees;
    当所述夹角为0度时,所述磁控管在所述靶材所在平面上的投影落在所述靶材的中心区域;When the angle is 0 degrees, a projection of the magnetron on a plane of the target falls in a central region of the target;
    当所述夹角为180度时,所述磁控管在所述靶材所在平面上的投影落在所述靶材的边缘区域。When the included angle is 180 degrees, the projection of the magnetron on the plane of the target falls on the edge region of the target.
  7. 根据权利要求1所述的磁控溅射腔室,其特征在于,所述磁控溅射腔室还包括偏压单元,所述偏压单元在所述基座上产生负偏压,以吸引正离子向所述基座方向垂直运动。A magnetron sputtering chamber according to claim 1 wherein said magnetron sputtering chamber further comprises a biasing unit that produces a negative bias on said base to attract Positive ions move vertically in the direction of the susceptor.
  8. 根据权利要求7所述的磁控溅射腔室,其特征在于,所述偏压单元包括射频电源和匹配器,其中,所述射频电源通过所述匹配器与所述基座相连;所述射频电源的功率范围为800-1400W。A magnetron sputtering chamber according to claim 7 wherein said biasing unit comprises a radio frequency power source and a matcher, wherein said radio frequency power source is coupled to said base via said matcher; The power range of the RF power supply is 800-1400W.
  9. 根据权利要求1所述的磁控溅射腔室,其特征在于,所述靶材与所述基座之间的竖直距离为100-150mm。The magnetron sputtering chamber of claim 1 wherein the vertical distance between the target and the base is between 100 and 150 mm.
  10. 一种半导体处理设备,其特征在于,包括权利要求1-9任一项所述的用于硅通孔填充的磁控溅射腔室。 A semiconductor processing apparatus comprising the magnetron sputtering chamber for through silicon via filling according to any one of claims 1-9.
PCT/CN2017/095587 2017-05-10 2017-08-02 Magnetron sputtering cavity for through-silicon-via filling and semiconductor processing device WO2018205430A1 (en)

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