WO2018196891A1 - Method of manufacturing a primary cell of a heat exchange surface of a heat exchanger or a filtering surface of a separation module based on hollow polymerous fibres and a production line for implementing the method - Google Patents

Method of manufacturing a primary cell of a heat exchange surface of a heat exchanger or a filtering surface of a separation module based on hollow polymerous fibres and a production line for implementing the method Download PDF

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Publication number
WO2018196891A1
WO2018196891A1 PCT/CZ2018/050019 CZ2018050019W WO2018196891A1 WO 2018196891 A1 WO2018196891 A1 WO 2018196891A1 CZ 2018050019 W CZ2018050019 W CZ 2018050019W WO 2018196891 A1 WO2018196891 A1 WO 2018196891A1
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WO
WIPO (PCT)
Prior art keywords
fibres
hollow
mould
edge
hollow polymer
Prior art date
Application number
PCT/CZ2018/050019
Other languages
French (fr)
Inventor
Jaroslav BORUTA
Jan INDERKA
Hynek DEDEK
Miroslav Kadlec
Original Assignee
Promens a.s.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Promens a.s. filed Critical Promens a.s.
Publication of WO2018196891A1 publication Critical patent/WO2018196891A1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • B29C45/14008Inserting articles into the mould
    • B29C45/14016Intermittently feeding endless articles, e.g. transfer films, to the mould
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/02Hollow fibre modules
    • B01D63/021Manufacturing thereof
    • B01D63/022Encapsulating hollow fibres
    • B01D63/0221Encapsulating hollow fibres using a mould
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/02Hollow fibre modules
    • B01D63/021Manufacturing thereof
    • B01D63/0232Manufacturing thereof using hollow fibers mats as precursor, e.g. wound or pleated mats
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • B29C45/14336Coating a portion of the article, e.g. the edge of the article
    • B29C45/14385Coating a portion of a bundle of inserts, e.g. making brushes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06Fibrous reinforcements only
    • B29C70/10Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/42Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
    • B29C70/46Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs
    • B29C70/48Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs and impregnating the reinforcements in the closed mould, e.g. resin transfer moulding [RTM], e.g. by vacuum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/54Component parts, details or accessories; Auxiliary operations, e.g. feeding or storage of prepregs or SMC after impregnation or during ageing
    • B29C70/56Tensioning reinforcements before or during shaping
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/68Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts by incorporating or moulding on preformed parts, e.g. inserts or layers, e.g. foam blocks
    • B29C70/84Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts by incorporating or moulding on preformed parts, e.g. inserts or layers, e.g. foam blocks by moulding material on preformed parts to be joined
    • B29C70/845Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts by incorporating or moulding on preformed parts, e.g. inserts or layers, e.g. foam blocks by moulding material on preformed parts to be joined by moulding material on a relative small portion of the preformed parts
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F21/00Constructions of heat-exchange apparatus characterised by the selection of particular materials
    • F28F21/06Constructions of heat-exchange apparatus characterised by the selection of particular materials of plastics material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2315/00Details relating to the membrane module operation
    • B01D2315/22Membrane contactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2323/00Details relating to membrane preparation
    • B01D2323/42Details of membrane preparation apparatus
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2793/00Shaping techniques involving a cutting or machining operation
    • B29C2793/009Shaping techniques involving a cutting or machining operation after shaping
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/0003Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor of successively moulded portions rigidly joined to each other
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • B29C45/14549Coating rod-like, wire-like or belt-like articles
    • B29C45/14565Coating rod-like, wire-like or belt-like articles at spaced locations, e.g. coaxial-cable wires
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/14Filters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/755Membranes, diaphragms
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F2255/00Heat exchanger elements made of materials having special features or resulting from particular manufacturing processes
    • F28F2255/06Heat exchanger elements made of materials having special features or resulting from particular manufacturing processes composite, e.g. polymers with fillers or fibres
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F2255/00Heat exchanger elements made of materials having special features or resulting from particular manufacturing processes
    • F28F2255/14Heat exchanger elements made of materials having special features or resulting from particular manufacturing processes molded
    • F28F2255/146Heat exchanger elements made of materials having special features or resulting from particular manufacturing processes molded overmolded
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F2260/00Heat exchangers or heat exchange elements having special size, e.g. microstructures
    • F28F2260/02Heat exchangers or heat exchange elements having special size, e.g. microstructures having microchannels

Definitions

  • the invention relates to a method for producing a primary element of a heat exchanger heat-transfer surface area or of a filtration surface area of a separation module on the basis of hollow polymer fibres having compact or porous walls, the method of production consisting in fixing the system of hollow polymer fibres in a polymer edge. Further, the invention relates to a production line for carrying out the production method.
  • Ordered or disordered systems of hollow polymer fibres are used as efficient heat-transferring (heat exchaning) or separation (filtration) surface areas in heat- exchangers and separation (filtration) modules in a wide application area.
  • a general problem of design and production of the heat-exchangers and separation modules based on hollow polymer fibres is inlet (entry) and fixation of the hollow polymer fibres so that the system of capillary fibre cavities could be connected tightly to the circulation loop of the liquid or gas medium.
  • fixation of the positions of the pre-cut separate hollow polymer fibre ends can be obtained by applying, for instance, hot melt thermoplastic adhesive in such a way that a sealed space is created for subsequent injection, for instance of reactive components, thus forming a flange, as described the USA patent U.S. 8864990.
  • the desired arrangement of the fibres at the end of the fibre bundle can also be achieved by enclosing the fibre bundle with an elastic collar and by mutual turning of the bundle and the collar, as described in the Czech patent CZ 304270.
  • Winding of the hollow polymer fibres on a firm frame followed by their potting with a polymer material in areas of thinned shoulders is the subject of the British patent GB 1472227.
  • An arrangement of the hollow fibres in a vertical position followed by potting thereof with epoxy resin is described in the Czech patent CZ 304191 .
  • the tubular arrangement of the hollow polymer fibres in the heat-transfer surface area and creation of the flanges are achieved by drawing the separate fibres through distance circular plates placed in a cylindrical mould and by subsequent potting thereof with a reactive mixture, the reactive mixture being injected into the mould through a central gating system according to the Japanese patent application JP 201 1 167580.
  • the regular arrangement of the hollow fibres is achieved by drawing the fibres through a perforated plate and subsequent imbedding thereof in a horizontal position according to the international patent application WO 9533548.
  • the nature of the invention is that the ordered system of the hollow polymer fibres is created and the fibres are fixed in the polymer edge by performing directly interconnected steps as follows:
  • the hollow polymer fibres are wound off either from separate creel reels or from a package of woven hollow fibres and the entire system of the hollow fibres is parallelly fed in an ordered state directly into an open injection mould;
  • the reactive low viscosity mixture is injected into the mould to create at least one polymer edge for fixing the position of the hollow polymer fibres; c) when the mould cavity containing the hollow polymer fibres has been filled with the reactive mixture and the polymerisation process has been completed, the polymer edge oriented in the crosswise direction to the led-in hollow fibre system or the edge about the whole circumference of the led-in system of the hollow polymer fibres is formed. The edge fixes the position of the freely led-in ordered hollow polymer fibres in such a way that the space between separate hollow polymer fibres is sealed and simultaneously regular surface areas defining the shape of the polymer edge are created;
  • the entire system of the hollow fibres including the polymer edge thus created is drawn into the stabilization zone outside the shape mould cavity without interrupting feeding of the system of hollow polymer fibres from the reels; f) in the stabilization zone the edge position is fixed while the lengths of the hollow fibres of the primary element produced can be controlled by setting the distance between the position of the edge fixation and the shape mould cavity;
  • the system of ordered hollow polymer fibres with polymer edges is wound off from the mould in continuous bands, thereupon the entrance into the inside of the hollow polymer fibres is uncovered without limiting the pass-through ability thereof by separating a part of the edges in the direction crosswise to the direction of the system of hollow polymer fibres by cutting or by a combination of cutting and breaking.
  • a separate primary element of the heat-exchanger heat-transfer surface area or a primary element of the filtration surface area of the separation module based on hollow polymer fibres is created;
  • hollow polymer fibres for the production of the primary element for the heat- exchanger heat-transfer surface area hollow fibres with compact walls will be used, as hollow polymer fibres for the production of the primary element filtration surface area for the separation module hollow fibres with microporous walls will be used.
  • These hollow polymer fibres are made of a polymer material selected advantageously from a group comprising polypropylene (PP) including polypropylene copolymers, polycarbonate (PC), PC/ABS copolymer, polyamide (PA) and PA/ABS copolymer.
  • DCPD dicyclopentadiene
  • the production line for carrying out the method according to the invention contains an unwinding facility comprising a creel with a reel system or an unwinding reel for wind-up of woven hollow fibres followed by an injection module comprising a tensioning mechanism, an injection mould with stabilization zones including positioning pins for fixing the edge position, a mould carrier and a clamping plate for fixing the mixing head of the reactive mixture dosing unit.
  • the injection mould can have one of the following designs:
  • a tensioning mechanism is advantageously combined into one set, a part of which is also a fibre guiding comb, anchor comb of the injection mould stabilization zones and the injection mould shape part including the gating system.
  • Auxiliary openings in the injection mould cavity and in the edges can be advantageously created for positioning the edge with the hollow fibres on the pins of the injection mould stabilization zone.
  • the method of manufacture and design of the manufacturing line enable a great processing variability with respect to choice of materials for production of hollow polymer fibres and polymer edges of the primary elements.
  • the method of manufacture and design of the manufacturing line permit a great processing variability with respect to choice of performance of the heat- transfer or separation surface areas of the primary element (variability in the number, length and diameter of the hollow polymer fibres);
  • Fig. 1 Diagram of the overall arrangement of the manufacturing line.
  • FIG. 2 Detail of an open mould with a moulding.
  • FIG. 3 Depicted separation of a couple of the adjacent polymer edges by cutting.
  • Fig. 4 Detail of ending of the hollow polymer fibres in the polymer edge of the primary element of the heat-transfer or filtration surface area.
  • Fig. 5 Detail of the cavity die (matrix) of the injection mould for production of the edge about the circumference of the primary element.
  • the manufacturing line for carrying out the method according to the invention in the exemplary embodiment contains an unwinding unit comprising a creel 1 with a system of reels 2 followed by an injection module 12.
  • the injection module 12 comprises tensioning mechanism 7, injection mould 3 with stabilization zones 8 complete with positioning pins 10 for fixing the position of the edges, carrier 6 of the mould 3 and clamping plate H for fixing the mixing head of the dosing unit intended for dosage of the reactive mixture.
  • the injection mould 3 In order to seal the hollow polymer fibres against flow of the reactive mixture outside the shape cavity 5a of the mould 3 and against an undesirable deformation of the hollow polymer fibres during injection moulding the injection mould 3 is provided with a replaceable elastic profiled sealing 5b (see Fig. 5).
  • the feed-in anchor 9 (see Fig. 6) comprises an anchor frame 13, anchor comb 14 and tensioning frame 15 with a guiding comb 16.
  • Creel 1 was fitted with 133 reels 2 containing windings of PA hollow fibres having compact walls (with an outer diemater of 0.8 mm) - see Fig. 1.
  • Example 5 Primary element of the heat-exchanger heat-transfer surface area on the basis of 125 hollow polymer woven fibres with a polymer edge 275 mm in width about the circumference of the heat-transfer surface area and the hollow fibres operating length of 225 mm was produced employing the procedure described in Example 3 with differences as follows:
  • Creel 1 was fitted with a woven winding of hollow PP fibres with compact walls (having an outer diamater of 0.8 mm) - see Fig. 1 .
  • Creel 1 was fitted with 133 reels 2 containing windings of PC hollow fibres with compact walls (having an outer diemater of 0.8 mm) - see Fig. 1.
  • Creel 1 was fitted with 133 reels 2 containing windings of PC/ABS hollow fibres with compact walls (having an outer diemater of 0.8 mm) - see Fig. 1 .
  • Example 8 Primary element of the heat-exchanger heat-transfer surface area on the basis of 133 hollow polymer fibres with polymer edges 220 mm in width and a hollow fibres active length of 190 mm was produced in the following variant of the method according to the invention using the production line according to Fig. 1 given in Example 3 with the deviations as follows:
  • Creel 1 was fitted with 133 reels 2 containing windings of PA/ABS hollow fibres with compact walls (having an outer diemater of 0.8 mm) - see Fig. 1 .

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Composite Materials (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

Creation of a spacially ordered system of hollow polymer fibres and fixation thereof in polymer edges (selvedges) made of a polymer are carried out in a combined device employing immediately successive steps in such a way that the hollow polymer fibres are wound off from separate creel reels and the entire hollow fibre system is parallelly fed in an ordered state directly into an open mould located in an injection module. After closing the mould, a reactive mixture is injected into the mould to form the polymer edges, which fix the position of the hollow polymer fibres. The production of the primary element of the heat-transfer surface area for a heat-exchanger or the primary element for the separation module is finished by separating a part of the edges in the direction crosswise to the direction of the hollow polymer fibres by cutting or by a combination of cutting and breaking.

Description

A METHOD OF MANUFACTURING A PRIMARY CELL OF A HEAT EXCHANGE SURFACE OF A HEAT EXCHANGER OR A FILTERING SURFACE OF A SEPARATION MODULE BASED ON HOLLOW POLYMEROUS FIBRES AND A PRODUCTION LINE FOR IMPLEMENTING THE METHOD
Field of invention
The invention relates to a method for producing a primary element of a heat exchanger heat-transfer surface area or of a filtration surface area of a separation module on the basis of hollow polymer fibres having compact or porous walls, the method of production consisting in fixing the system of hollow polymer fibres in a polymer edge. Further, the invention relates to a production line for carrying out the production method.
Description of the prior art
Ordered or disordered systems of hollow polymer fibres are used as efficient heat-transferring (heat exchaning) or separation (filtration) surface areas in heat- exchangers and separation (filtration) modules in a wide application area. A general problem of design and production of the heat-exchangers and separation modules based on hollow polymer fibres is inlet (entry) and fixation of the hollow polymer fibres so that the system of capillary fibre cavities could be connected tightly to the circulation loop of the liquid or gas medium.
For fixation of the hollow polymer fibre ends and creation of flanges, procedures based on filling thereof with solidifying (hardening) polymers are used. By cutting the flange the inlet of the hollow polymer fibres opens, thus enabling a connection to the circuit of the appropriate medium. This process is described, for instance, in the Japanese patent JPH 62160108 or the Swedish patent SE 397638. The regular arrangement of the system of hollow polymer fibres during their potting (embedding) can be achieved by weaving thereof and by creating defined positions of the separate fibres, as described in the USA patent U.S. 5922201. The fixation of the positions of the pre-cut separate hollow polymer fibre ends can be obtained by applying, for instance, hot melt thermoplastic adhesive in such a way that a sealed space is created for subsequent injection, for instance of reactive components, thus forming a flange, as described the USA patent U.S. 8864990.
The desired arrangement of the fibres at the end of the fibre bundle can also be achieved by enclosing the fibre bundle with an elastic collar and by mutual turning of the bundle and the collar, as described in the Czech patent CZ 304270. Winding of the hollow polymer fibres on a firm frame followed by their potting with a polymer material in areas of thinned shoulders is the subject of the British patent GB 1472227. An arrangement of the hollow fibres in a vertical position followed by potting thereof with epoxy resin is described in the Czech patent CZ 304191 .
An auxiliary fixation of the ends of the hollow polymer fibre bundle with wax followed by potting thereof with a polymer material is described in the U.S. Patent No. 5639373.
Fixing the ends of the hollow polymer fibre bundle by centrifugal casting of cyclo- olefin is described in the Japanese patent JPH 06170177.
The tubular arrangement of the hollow polymer fibres in the heat-transfer surface area and creation of the flanges are achieved by drawing the separate fibres through distance circular plates placed in a cylindrical mould and by subsequent potting thereof with a reactive mixture, the reactive mixture being injected into the mould through a central gating system according to the Japanese patent application JP 201 1 167580. The regular arrangement of the hollow fibres is achieved by drawing the fibres through a perforated plate and subsequent imbedding thereof in a horizontal position according to the international patent application WO 9533548.
However, the above mentioned procedures are complicated for use in mass production conditions, particularly when a regular arrangement of hollow polymer fibres in heat-transfer surface areas of heat-exchangers or in filtration surface areas of separation modules is needed.
Nature of the invention
The shortcoming of the above prior art can be eliminated to a great extent by using a method for production of the primary element of the heat-exchanger heat- transfer surface area or filtration surface area of the separation module on the basis of hollow polymer fibres having compact walls or walls having porous structure according to the invention, the method of manufacture being, in a similar way as known methods, based in principle on fixation of the hollow polymer fibre system in the polymer edge.
The nature of the invention is that the ordered system of the hollow polymer fibres is created and the fibres are fixed in the polymer edge by performing directly interconnected steps as follows:
a) the hollow polymer fibres are wound off either from separate creel reels or from a package of woven hollow fibres and the entire system of the hollow fibres is parallelly fed in an ordered state directly into an open injection mould;
b) after closing the mould, the reactive low viscosity mixture is injected into the mould to create at least one polymer edge for fixing the position of the hollow polymer fibres; c) when the mould cavity containing the hollow polymer fibres has been filled with the reactive mixture and the polymerisation process has been completed, the polymer edge oriented in the crosswise direction to the led-in hollow fibre system or the edge about the whole circumference of the led-in system of the hollow polymer fibres is formed. The edge fixes the position of the freely led-in ordered hollow polymer fibres in such a way that the space between separate hollow polymer fibres is sealed and simultaneously regular surface areas defining the shape of the polymer edge are created;
d) after opening the mould, flashes of the mould gating and venting systems are removed;
e) the entire system of the hollow fibres including the polymer edge thus created is drawn into the stabilization zone outside the shape mould cavity without interrupting feeding of the system of hollow polymer fibres from the reels; f) in the stabilization zone the edge position is fixed while the lengths of the hollow fibres of the primary element produced can be controlled by setting the distance between the position of the edge fixation and the shape mould cavity;
g) subsequently, in the distance from the first edge defined in this manner, further edge is created on the system of parallel hollow polymer fibres using the same procedure and the steps according to a) to d), also in the crosswise direction, or another edge about the entire circumference of the led-in system of the hollow polymer fibres;
h) the system of ordered hollow polymer fibres with polymer edges is wound off from the mould in continuous bands, thereupon the entrance into the inside of the hollow polymer fibres is uncovered without limiting the pass-through ability thereof by separating a part of the edges in the direction crosswise to the direction of the system of hollow polymer fibres by cutting or by a combination of cutting and breaking. Thus a separate primary element of the heat-exchanger heat-transfer surface area or a primary element of the filtration surface area of the separation module based on hollow polymer fibres is created;
i) in conclusion the primary elements are bonded into blocks and the blocks are fitted with flenges.
Thus the process of production of the basic heat exchanger module (zakladni modul) or the basic separation module is completed.
As hollow polymer fibres for the production of the primary element for the heat- exchanger heat-transfer surface area hollow fibres with compact walls will be used, as hollow polymer fibres for the production of the primary element filtration surface area for the separation module hollow fibres with microporous walls will be used. These hollow polymer fibres are made of a polymer material selected advantageously from a group comprising polypropylene (PP) including polypropylene copolymers, polycarbonate (PC), PC/ABS copolymer, polyamide (PA) and PA/ABS copolymer.
In order to create edges a compound from a group including dicyclopentadiene (DCPD) with a catalytic system based on molybdenum compounds, a catalytic system based on wolfram compounds or a catalytic system based on ruthenium compounds, further two-component epoxy casting substances, two-component acrylate casting substances and two-component polyurethane mixtures will be used as a reactive low- viscosity mixture for injection under low pressure of 1 to 10 bars.
The production line for carrying out the method according to the invention contains an unwinding facility comprising a creel with a reel system or an unwinding reel for wind-up of woven hollow fibres followed by an injection module comprising a tensioning mechanism, an injection mould with stabilization zones including positioning pins for fixing the edge position, a mould carrier and a clamping plate for fixing the mixing head of the reactive mixture dosing unit.
The injection mould can have one of the following designs:
- injection mould for creating one edge perpendicular to the direction of the hollow fibres,
- injection mould for creating one edge about the circumference of the heat-transfer or filtration surface areas using one injection of the reactive mixture,
- injection mould for creating n couples of edges perpendicular to the direction of the hollow fibres by injecting reactive mixture from one or more mixing heads, the distance between the edge couples defining the operation length of the heat-transfer or filtration surface areas with the separate edges in the edge couples being close to each other,
- injection mould for creating n couples of edges about the circumference of the heat- transfer or filtration surface areas with an injection of the reactive mixture from one or more mixing heads.
In order to achieve an ordered state of the hollow polymer fibres in the injection mould a tensioning mechanism is advantageously combined into one set, a part of which is also a fibre guiding comb, anchor comb of the injection mould stabilization zones and the injection mould shape part including the gating system. Auxiliary openings in the injection mould cavity and in the edges can be advantageously created for positioning the edge with the hollow fibres on the pins of the injection mould stabilization zone.
In order to seal the hollow polymer fibres against flow of the reactive mixture outside the mould shape cavity and against an undesirable deformation of the hollow polymer fibres during injection moulding it is advantageous to fit the injection mould with a replaceable elastic profiled sealing.
The solution according to the invention brings a number of advantages, of which those shown below can be given as the most significant:
j) by way of an efficient arrangement and an incorporation of the separate technological steps into the line, conditions for automation of the whole manufacturing process have been created;
k) the design of the manufacturing line and the method of preparation makes possible to process individual hollow polymer fibres wound off the creel reels as well as hollow fibres in the form of woven materials;
I) the possibility of processing individual hollow polymer fibres brings a significant economic advantage over processing of woven hollow fibres. Weaving of hollow fibres is a slow, technically problematic (a damage of the fibres can occur) and expensive process;
m) the method of manufacture and design of the manufacturing line enable a great processing variability with respect to choice of materials for production of hollow polymer fibres and polymer edges of the primary elements. n) the method of manufacture and design of the manufacturing line permit a great processing variability with respect to choice of performance of the heat- transfer or separation surface areas of the primary element (variability in the number, length and diameter of the hollow polymer fibres);
o) the method of manufacture and design of the manufacturing line enable a great processing variability with respect to choice of shape of the primary element polymer edges (crosswise edges or edges about the circumference, as well as number of the edges in the mould can be chosen). Brief description of the drawings
In order to clarify the nature of the invention in a greater detail drawings are enclosed showing:
Fig. 1 - Diagram of the overall arrangement of the manufacturing line.
Fig. 2 - Detail of an open mould with a moulding.
Fig. 3 - Depicted separation of a couple of the adjacent polymer edges by cutting. Fig. 4 - Detail of ending of the hollow polymer fibres in the polymer edge of the primary element of the heat-transfer or filtration surface area.
Fig. 5 - Detail of the cavity die (matrix) of the injection mould for production of the edge about the circumference of the primary element.
Fig. 6 - Detail of the feed-in anchor.
Embodiments of the invention Example 1
Primary element of the heat-exchanger heat-transfer surface area on the basis of 133 hollow polymer fibres with polymer edges 220 mm in width and a hollow fibres active length of 190 mm was made in the following variant of the method according to the invention on the manufacturing line according to Fig. 1 : a) Creel 1 was fitted with 133 reels 2 containing PP hollow fibres having compact walls (0.8 mm in outer diameter) - see Fig. 1 . b) Injection mould 3 (see Fig. 1 ) containing two shape cavities comprising a punch 4 and a cavity die (matrix) 5 for making two edges lying next to each other and perpendicular to the direction of feeding of the hollow fibres was heated to the temperature of 75 °C. c) The separate hollow PP fibres were fed through tensioning mechanism 7 and injection mould 3 into the feed-in anchor 9 (see Fig. 1 ) with a pull handle 13 (see the detail in Fig. 6). d) By means of the tensioning mechanism 7 the hollow PP fibre system was tensioned over stabilization zones 8 and shape cavities 5 of the injection mould 3 in such a way that spacings between the fibres were 1 .6 mm. e) After closing the injection mould, reactive mixture of dicyclopentadiene (with a molybdenum based catalyst) was injected into the mould shape cavity comprising a punch 4 and a cavity die (matrix) 5 under the following conditions:
temperature of the reactive components A/B = 22 23 °C,
injection time: 1 second,
mixing pressures of the separate reactive components A/B: 80/ 80 bar. f) After elapsing of the polymerization time (1 .5 minutes), the injection mould was opened and the feed 3b and venting 3a systems were separated (see Fig. 2). g) The couple of the edges formed 7 was moved into the stabilization zone to the position given by the positioning pins 10 (see Fig. 2). Simultaneously, the required length of the hollow PP fibres was unwound and the fibres were tensioned with the tensioning mechanism 7 (see Fig. 1 ). h) After the injection mould 3 was closed, additional edge couples 17 in the form of a continuous band (see Fig. 2) were made according to points e) to g) by injecting the reactive mixture into the mould shape cavity comprising punch 4 and a cavity die (matrix) 5 - see Fig. 2. i) Polymer edges V7 were separated in the direction perpendicular to the direction of the hollow fibres by a combination of cutting and breaking (indicated in Fig. 3). Thus opening of the hollow polymer fibre ends in edges 17 (see Fig. 4) and separation of individual primary elements from the continuous band (see Fig. 3) were achieved. With respect to the construction arrangement, the manufacturing line for carrying out the method according to the invention in the exemplary embodiment (see Fig. 1 ) contains an unwinding unit comprising a creel 1 with a system of reels 2 followed by an injection module 12. The injection module 12 comprises tensioning mechanism 7, injection mould 3 with stabilization zones 8 complete with positioning pins 10 for fixing the position of the edges, carrier 6 of the mould 3 and clamping plate H for fixing the mixing head of the dosing unit intended for dosage of the reactive mixture.
In order to seal the hollow polymer fibres against flow of the reactive mixture outside the shape cavity 5a of the mould 3 and against an undesirable deformation of the hollow polymer fibres during injection moulding the injection mould 3 is provided with a replaceable elastic profiled sealing 5b (see Fig. 5).
The feed-in anchor 9 (see Fig. 6) comprises an anchor frame 13, anchor comb 14 and tensioning frame 15 with a guiding comb 16.
Example 2
Primary element of the separation (filtration) module based on 133 hollow polymer fibres with polymer edges 220 mm in width and the hollow fibres active length of 190 mm was made by a method entirely identical with that described in Example 1 with one deviation consisting in the fact that the creel 1 was fitted with 133 reels containing windings of PP hollow fibres having microporous walls (with an outer diameter of 0.8 mm) - see Fig. 1 . Further procedure corresponded to that described in Example 1 , points a) to j).
Example 3
Primary element of the heat-exchanger heat-transfer surface area based on 125 hollow polymer fibres having a polymer edge 275 mm in width located about the circumference of the heat-transfer surface area and the hollow fibres operating length of 225 mm was produced employing the following procedure: a) Creel 1 was fitted with 125 reels 2 containing windings of PP hollow fibres having compact walls (0.8 mm in outer diameter) - see Fig. 1 . b) The mould containing a shape cavity for making polymer edge 2 about the circumference of the heat-transfer surface area (see Fig. 5) was heated to the temperature of 72 °C. c) The separate hollow PP fibres were fed through tensioning mechanism 7 and the mould into feed-in anchor 9 - see Fig. 1 . d) Employing the tensioning mechanism 7 the system of hollow PP fibres was tensioned over stabilization zones 8 (see Fig. 1 ) and shape part 2 of the injection mould (see Fig. 5) in such a way that spacings between the fibres constituted 1 .6 mm. e) After the mould was closed, reactive mixture of dicyclopentadine (with a molebdenum based catalyst) was injected into the shape part of the mould 2 under the conditions as follows:
temperature of the reactive components A/B = 23 24 °C,
injection time: 1 second,
mixing pressures of the separate reactive components A/B: 85/ 85 bar - see Fig. 1 . f) After elapsing of the polymerization time (1 .5 minutes), the injection mould was opened and the feed 4 and venting 1 systems were separated (see Fig. 5). g) The edge created about the circumference of the heat-transfer surface area was moved into the stabilization zone 8 to the position given by the positioning pins. Simultaneously, the required length of the hollow PP fibres was unwound and the fibres were tensioned with the tensioning mechanism 7 (see Fig. 1 ). h) After the injection mould 3 was closed, further edge in the form of a continuous band was produced about the circumference of the heat-exchaning surface area by injecting the reactive mixture into the shape part of the mould according to points e) to g) (see Fig. 1 ). i) The polymer edges were separated using a procedure identical with that described in point i) of Example 1 .
Example 4
Primary element of the heat-exchanger heat-transfer surface area on the basis of 133 hollow polymer fibres with polymer edges 220 mm in width and an active length of the hollow fibres of 190 mm was produced in the following variant of the method according to the invention employing the production line according to Fig. 1 in compliance with Example 1 with the deviations as follows:
In point a) Creel 1 was fitted with 133 reels 2 containing windings of PA hollow fibres having compact walls (with an outer diemater of 0.8 mm) - see Fig. 1.
In point b) The injection mould 3 containing 2 shape cavities comprising punch 4 and cavity die (matrix) 5 for making two edges lying next to each other and perpendicular to the direction of hollow fibre feeding was heated to the temperature of 65 °C - see Fig. 1 .
In point e) When the injection mould was closed, a reactive mixture of polyol and isocyanate was injected into the shape cavity formed by punch 4 and cavity die (matrix)
5 under the conditions as follows:
temperature of the reactive components A/B = 24 25 °C,
injection time: 1 .3 second,
mixing pressures of the reactive components A/B: 95/ 95 bar.
In point f) When the polymerization time (4 minutes) elapsed, the injection mould was opened and the feed 3 and venting 2 systems were separated (see Fig. 2).
Example 5 Primary element of the heat-exchanger heat-transfer surface area on the basis of 125 hollow polymer woven fibres with a polymer edge 275 mm in width about the circumference of the heat-transfer surface area and the hollow fibres operating length of 225 mm was produced employing the procedure described in Example 3 with differences as follows:
In point a) Creel 1 was fitted with a woven winding of hollow PP fibres with compact walls (having an outer diamater of 0.8 mm) - see Fig. 1 .
In point b) The injection mould containing a shape cavity for making polymer edge 2 about the circumference of the heat-transfer surface area (see Fig. 5) was heated to the temperature of 72 °C.
In point c) The separate hollow PP fibres were fed through tensioning mechanism 7 and the mould into feed-in anchor 9 - see Fig. 1 .
In point d) Employing the tensioning mechanism 7 the system of hollow PP fibres was tensioned over stabilization zones 8 (see Figure 1 ) and shape part 2 of the injection mould (see Fig. 5) in such a way that spacings between the fibres were 1 .6 mm.
In point e) After the mould was closed, a reactive mixture of dicyclopentadine (with a molebdenum based catalyst) was injected into the shape part of the mould 2 under the conditions as follows:
temperature of the reactive components A/B = 23 24 °C,
injection time: 1 second,
mixing pressures of the reactive components A/B: 85/ 85 bar - see Fig. 1 .
In point f) After elapsing of the polymerization time (1 .5 minutes), the injection mould was opened and the feed 4 and venting 1 systems were separated (see Fig. 5). In point g) The edge created about the circumference of the heat-transfer surface area was moved into the stabilization zone 8 to the position given by the positioning pins. Simultaneously, the required length of the hollow PP fibres was unwound and the fibres were tensioned with the tensioning mechanism 7 (see Fig. 1 ).
In point h) After the injection mould 3 was closed, further edge in the form of a continuous band was made about the circumference of the heat-exchaning surface area by injecting the reactive mixture into the shape part of the mould according to points e) to g) (see Fig. 1 ).
Example 6
Primary element of the heat-exchanger heat-transfer surface area on the basis of 133 hollow polymer fibres with polymer edges 220 mm in width and an active length of the hollow fibres of 190 mm was produced in the following variant of the method according to the invention using the production line according to Fig. 1 given in Example 3 with the deviations as follows:
In point a) Creel 1 was fitted with 133 reels 2 containing windings of PC hollow fibres with compact walls (having an outer diemater of 0.8 mm) - see Fig. 1.
In point b) The injection mould 3 containing 2 shape cavities comprising punch 4 and cavity die (matrix) 5 for making two edges lying next to each other and perpendicular to the direction of hollow fibres feeding was heated to the temperature of 100 °C - see Fig. 1 .
In point e) After the injection mould was closed, a reactive mixture of epoxy prepolymer based on bisphenol A and diamine was injected into the shape cavity under the conditions as follows:
temperature of the reactive components A/B = 45 45 °C,
injection time: 5 seconds,
mixing pressures of the reactive components A/B: 75/ 75 bar - see Fig. 1 . In point f) After the polymerization time (5 minutes) elapsed, the injection mould was opened and the feed 3 and venting 2 systems were separated (see Fig. 2).
Example 7
Primary element of the heat-exchanger heat-transfer surface area on the basis of 133 hollow polymer fibres with polymer edges 220 mm in width and a hollow fibres active length of 190 mm was produced in the following variant of the method according to the invention utilising the production line according to Fig. 1 given in Example 3 with the deviations as follows:
In point a) Creel 1 was fitted with 133 reels 2 containing windings of PC/ABS hollow fibres with compact walls (having an outer diemater of 0.8 mm) - see Fig. 1 .
In point b) The injection mould 3 containing 2 shape cavities comprising punch 4 and cavity die (matrix) 5 for making two edges lying next to each other and perpendicular to the direction of hollow fibres feeding was heated to the temperature of 100 °C - see Fig. 1 .
In point e) After the injection mould was closed, a reactive mixture of epoxy prepolymer based on bisphenol A and diamine was injected into the shape cavity under the conditions as follows:
temperature of the reactive components A/B = 52 50 °C
injection time: 5 seconds,
mixing pressures of the reactive components A/B: 75/ 75 bar - see Fig. 1 .
In point f) After elapsing of the polymerization time (5 minutes), the injection mould was opened and the feed 3 and venting 2 systems were separated (see Fig. 2).
Example 8 Primary element of the heat-exchanger heat-transfer surface area on the basis of 133 hollow polymer fibres with polymer edges 220 mm in width and a hollow fibres active length of 190 mm was produced in the following variant of the method according to the invention using the production line according to Fig. 1 given in Example 3 with the deviations as follows:
In point a) Creel 1 was fitted with 133 reels 2 containing windings of PA/ABS hollow fibres with compact walls (having an outer diemater of 0.8 mm) - see Fig. 1 .
In point b) The injection mould 3 containing 2 shape cavities comprising punch 4 and cavity die (matrix) 5 for making two edges lying next to each other and perpendicular to the direction of feeding of the hollow fibres was heated to the temperature of 65 °C - see Fig. 1 .
In point e) After the injection mould was closed, a reactive mixture of polyol and isocyanate was injected into the shape cavity under the conditions as follows:
temperature of the reactive components A/B = 24 25 °C,
injection time: 1 .3 seconds,
mixing pressures of the reactive components A/B: 95/ 95 bar - see Fig. 1 .
In point f) When the polymerization time (4 minutes) elapsed, the injection mould was opened and the feed 3 and venting 2 systems were separated (see Fig. 2).
Example 9
Primary element of the heat-exchanger heat-transfer surface area on the basis of 133 hollow polymer fibres with polymer edges 220 mm in width and a hollow fibres active length of 190 mm was produced in the following variant of the method according to the invention employing the production line according to Fig. 1 given in Example 1 with the deviations as follows: In point a) Creel 1 was fitted with 133 reels 2 containing windings of PA hollow fibres with compact walls (having an outer diemater of 0.8 mm) - see Fig. 1.
In point b) The injection mould 3 containing 2 shape cavities comprising punch 4 and cavity die (matrix) 5 for making two edges lying next to each other and perpendicular to the direction of feeding of the hollow fibres was heated to the temperature of 65 °C - see Fig. 1 .
In point e) After the injection mould was closed, a reactive mixture of acrylates was injected into the shape cavity under the conditions as follows:
temperature of the reactive components A/B = 70 75 °C,
injection time: 3 seconds,
mixing pressures of the reactive components A/B: 100/ 95 bar - see Fig. 1 .
In point f) When the polymerization time (8 minutes) elapsed, the injection mould was opened and the feed 3 and venting 2 systems were separated (see Fig. 2).

Claims

P A T E N T C L A I M S WHAT IS CLAIMED IS:
1 . A method of manufacture of a primary element of heat-exchanger heat-transfer surface
or the filtration surface of a separation module based on hollow polymer fibres with compact walls or with walls having porous structure consisting in fixing the system of hollow polymer fibres in the polymer edge characterized in that creation of an ordered system of hollow polymer fibres and fixation thereof in the polymer edge are carried out by using directly interconnected steps as follows: a) hollow polymer fibres are wound off either from separate creel reels or from a winding of woven hollow fibres and the entire system of the hollow fibres is fed parallelly in an ordered state directly into an open injection mould. b) after closing the mould, a reactive low viscosity mixture is injected into the mould to create at least one polymer edge aimed at fixing the position of the hollow polymer fibres; c) by filling the mould cavity containing hollow polymer fibres with the reactive mixture and after completing the polymerisation process, the polymer edge oriented in the crosswise direction to the fed-in system of the hollow fibres or an edge on the whole circumference of the fed-in hollow fibres system is formed. The edge fixes the position of the freely fed-in ordered hollow polymer fibres in such a way that the space between separate hollow polymer fibres is sealed and simultaneously regular surface areas defining spatially the polymer edge are created; d) after opening the mould, flashes of the mould gating and venting systems are removed; e) the entire system of the hollow fibres including the polymer edge created is drawn into the stabilisation zone outside the mould shape cavity without interrupting feeding of the hollow polymer fibres system from the reels; f) in the stabilisation zone the edge position is fixed while the lengths of the hollow fibres of the primary element produced can be controlled by setting the distance between the edge fixation position and the mould shape cavity; g) subsequently, in the distance from the first edge defined in this manner, further edge is created on the system of parallel hollow polymer fibres using the same procedure and the steps according to a) to d) also in the crosswise direction or further edge about the entire circumference of the fed-in system of the hollow polymer fibres; h) the system of ordered hollow polymer fibres with polymer edges is wound off from the mould in the form of continuous bands, thereupon the entrance of the hollow polymer fibres is uncovered without limiting the pass-through ability thereof by separating a part of the edges in the direction crosswise to the direction of the hollow polymer fibre system by cutting or by a combination of cutting and breaking. Thus a separate primary element of the heat-exchanger or a primary element of the filtration surface of the separation module based on hollow polymer fibres is created; i) in conclusion the primary elements are joined with an adhesive into blocks and the blocks are fitted with flanges.
2. The method according to Claim 1 , in which hollow fibres with compact walls are used as hollow polymer fibres for manufacture of the primary element of heat-exchanger heat- transfer surface.
3) The method as claimed in Claim 1 , wherein hollow fibres with microporous walls are used as hollow polymer fibres for manufacture of the primary element of the separation module filtration surface.
4. The method according to Claim 2 or 3, characterized in that the hollow polymer fibres are produced from a polymer material selected from a group comprising polypropylene (PP) including PP copolymers, polycarbonate (PC), PC/ABS copolymer, polyamide (PA) and PA/ABS copolymer.
5. The method according to Claims 1 to 10, wherein as a reactive low-viscosity mixture for injection under low pressure of 1 to 10 bars for creation of edges a compound including dicyclopentadiene (DCPD) with a catalytic system based on molybdenum compounds, a catalytic system based on wolfram compounds or a catalytic system based on ruthenium compounds, further two-component epoxy casting substances, two- component acrylic casting substances and two-component polyurethane compounds are used.
6. The production line for carrying out the method according to Claim 1 characterized in that the said production line contains an unwinding facility comprising a creel (1 ) with a reel system (2) followed by an injection module (12) comprising a tensioning mechanism (7), injection mould (3) with stabilisation zones (8) including positioning pins (10) for fixing edge position, mould carrier (6) and clamping plate (1 1 ) for fixing the mixing head of the reactive mixture dosing unit.
7. The production line according to Claim 6, characterized in that the injection mould (3) is in one design from a group comprising an injection mould for creation of one edge perpendicular to the direction of the hollow fibres, an injection mould for creation of one edge about the circumference of heat-transfer or filtration surfaces by way of injection of the reactive mixture, an injection mould for creation of n couples of edges perpendicular to the direction of the hollow fibres by way of injection of the reactive mixture from one or more mixing heads, the distance between the edge couples defining the operation length of the heat-transfer or filtration surface and the separate edges in the edge couples being close to each other, and an injection mould for creation of n couples of edges about the circumference of heat-transfer or filtration surfaces by way of injection of the reactive mixture from one or more mixing heads.
8. The production line according to Claim 6, characterized in that a tensioning mechanism (7) is combined functionally into one set, a part of which is also a fibre guiding comb (16), anchor comb of the stabilisation zones (14) of the injection mould (3) and of the shape part of the injection mould (3) including the gating system in order to achieve an ordered state of the hollow polymer fibres in the injection mould (3).
9. The production line according to Claim 6, characterized in that in the cavity of the injection mould (3) and in the edges auxiliary openings for positioning the edge with the hollow fibres on the pins (10) of the stabilization zone (8) of the injection mould (3) are created.
10. The production line according to Claim 6, characterized in that the injection mould (3) is fitted with a replaceable elastic profiled sealing in order to seal the hollow polymer fibres during injection moulding against flow of the reactive mixture outside the shape cavity (5a) of the mould (3) and against an undesirable deformation of the hollow polymer fibres.
PCT/CZ2018/050019 2017-04-26 2018-04-23 Method of manufacturing a primary cell of a heat exchange surface of a heat exchanger or a filtering surface of a separation module based on hollow polymerous fibres and a production line for implementing the method WO2018196891A1 (en)

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