WO2018190417A1 - 硬化性樹脂組成物、それを用いた燃料電池およびシール方法 - Google Patents
硬化性樹脂組成物、それを用いた燃料電池およびシール方法 Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08L23/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/14—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated containing elements other than carbon and hydrogen
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
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- C08K5/54—Silicon-containing compounds
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- C08L101/00—Compositions of unspecified macromolecular compounds
- C08L101/02—Compositions of unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J147/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Adhesives based on derivatives of such polymers
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
- C09J5/06—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving heating of the applied adhesive
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/10—Materials in mouldable or extrudable form for sealing or packing joints or covers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0271—Sealing or supporting means around electrodes, matrices or membranes
- H01M8/0273—Sealing or supporting means around electrodes, matrices or membranes with sealing or supporting means in the form of a frame
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0271—Sealing or supporting means around electrodes, matrices or membranes
- H01M8/028—Sealing means characterised by their material
- H01M8/0284—Organic resins; Organic polymers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/48—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/416—Additional features of adhesives in the form of films or foils characterized by the presence of essential components use of irradiation
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2409/00—Presence of diene rubber
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M2008/1095—Fuel cells with polymeric electrolytes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0082—Organic polymers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Definitions
- the present invention relates to a curable resin composition having properties such as high extensibility, high tensile strength, and hydrogen gas barrier properties while having low viscosity.
- a fuel cell is a power generator that extracts electricity by chemically reacting hydrogen and oxygen.
- a fuel cell is a clean next-generation power generation device because it has high energy efficiency during power generation and water is generated by the reaction of hydrogen and oxygen.
- fuel cells There are four types of fuel cells: solid polymer fuel cells, phosphoric acid fuel cells, molten carbonate fuel cells, and solid oxide fuel cells.
- solid polymer fuel cells have an operating temperature. Since it has a relatively low temperature (around 80 ° C.) and high power generation efficiency, it is expected to be used in applications such as a power source for automobiles, a household power generator, a small power source for electronic devices such as a mobile phone, and an emergency power source.
- the cell 1 of the polymer electrolyte fuel cell is an electrolyte membrane electrode assembly 5 (MEA) having a structure in which a polymer electrolyte membrane 4 is sandwiched between an air electrode 3a and a fuel electrode 3b. ), A frame 6 that supports the MEA, and a separator 2 in which a gas flow path is formed.
- MEA electrolyte membrane electrode assembly 5
- hydrosilylation using polyisobutylene polymer is a rubber elastic body with excellent hydrogen gas barrier properties, low moisture permeability, heat resistance, acid resistance, and flexibility.
- Heat curable resin composition (see Patent Document 1) that undergoes a hydration reaction, heat curable resin composition that undergoes a hydrosilylation reaction using a fluoropolyether compound (see Patent Document 2), heating that undergoes a hydrosilylation reaction using a fluoropolymer A curable resin composition (see Patent Document 3) and a heat-curable resin composition using an ethylene-propylene-diene rubber (see Patent Document 4) have been studied.
- thermosetting resin compositions of Patent Documents 1 to 4 use a polymer having a high molecular weight in order to improve the sealing property, there is a problem that the viscosity increases and the coating workability decreases. . Further, generally, a method of adding a plasticizer is used to lower the viscosity in the curable resin composition, but this time there is a problem that the extensibility, tensile strength, and hydrogen gas barrier properties are lowered. .
- an object of the present invention is to provide a curable resin composition having characteristics such as high extensibility, high tensile strength, and hydrogen gas barrier properties while having low viscosity.
- a curable resin composition comprising the following components (A) to (D): Component (A): Vinyl polymer having one or more alkenyl groups in the molecule (B) Component: Compound having one or more hydrosilyl groups in the molecule (C) Component: Hydrosilylation catalyst (D) Component: Multifunctional vinyl ether Compound [2]
- the component (D) is at least one selected from the group consisting of a vinyl ether compound having a cycloalkane structure, a vinyl ether compound having an ether structure, and a vinyl ether compound having an alkylene structure.
- the component (A) is polyisobutylene having one or more alkenyl groups or an acrylic polymer having one or more alkenyl groups, [1] or [2] Curable resin composition.
- a curable sealant for a fuel cell comprising the curable resin composition according to any one of [1] to [3].
- the fuel cell for peripheral fuel of any member of the group consisting of a separator, a frame, an electrolyte, a fuel electrode, an air electrode, and an electrolyte membrane electrode assembly, wherein the curable sealant for a fuel cell is a member in the fuel cell
- the curable sealant for a fuel cell is a sealant between adjacent separators in a fuel cell, or a sealant between a fuel cell frame and an electrolyte membrane or an electrolyte membrane electrode assembly.
- the sealing agent according to [4].
- a fuel cell comprising any one of a group consisting of a seal between adjacent separators in a fuel cell and a seal between a fuel cell frame and an electrolyte membrane or an electrolyte membrane electrode assembly, A fuel cell in which any one of the seals includes the cured product according to [8].
- a method for sealing at least a part between at least two flanges of a part to be sealed having at least two flanges, wherein at least one of the flanges is capable of transmitting heat or active energy rays A step of applying the curable resin composition according to any one of [1] to [3] to at least one surface of the flange; one flange applied with the curable resin composition; and the other flange; Bonding through the curable resin composition, and heating or irradiating active energy rays through the light transmissive flange to cure the curable resin composition, Sealing at least a portion of the sealing method.
- a method for sealing at least a part between at least two flanges of a part to be sealed having at least two flanges the step of disposing a gasket forming mold on at least one of the flanges Injecting the curable resin composition according to any one of [1] to [3] into at least a part of a gap between the gasket forming mold and the flange on which the mold is disposed; Heating the curable resin composition or irradiating active energy rays to cure the curable resin composition, and forming a gasket made of a cured product of the curable resin composition; Removing from one flange, placing the other flange on the gasket, and pressing the one flange and the other flange through the gasket; And sealing method characterized by comprising the step, of sealing at least a portion between the at least two flanges.
- the present invention provides a curable resin composition having properties such as high extensibility, high tensile strength, and hydrogen gas barrier properties while having low viscosity.
- the present invention relates to a curable resin composition containing the following components (A) to (D).
- Component Component: Compound having one or more hydrosilyl groups in the molecule
- Component Hydrosilylation catalyst
- Component Multifunctional vinyl ether Compound.
- the components (A) to (D) and optional components of the curable resin composition of the present invention those satisfying any of the following conditions can be used in any combination.
- the components (A) to (D) are different from each other.
- the component (A) used in the present invention is not particularly limited as long as it is a vinyl polymer that is liquid at 25 ° C. (normal temperature) having one or more alkenyl groups in one molecule.
- the viscosity at 25 ° C. of the component (A) in the present invention is not particularly limited, but is preferably 5 to 5000 Pa ⁇ s, more preferably 50 to 3000 Pa ⁇ s, particularly preferably from the viewpoint of workability. 100 to 2000 Pa ⁇ s. Unless otherwise specified, the viscosity was measured at 25 ° C. using a cone plate viscometer.
- the alkenyl group is at the end of the main chain of the vinyl polymer, it is preferable from the viewpoint that it is easy to obtain a rubber elastic body having low strength but high strength and low compression set.
- the alkenyl group is, for example, suitably an alkenyl group having 1 to 10 carbon atoms, preferably 2 to 8 carbon atoms, more preferably 3 to 5 carbon atoms.
- an allyl group, a propenyl group, and a butenyl group are suitable.
- the component (A) preferably has 1 to 6 alkenyl groups, more preferably 2 to 4, more preferably 2 to 3, particularly preferably 2 (especially at both ends of the polymer). Is appropriate.
- the alkenyl group may be present at either the side chain or the terminal of the molecule, but is preferably present at the terminal of the molecule from the viewpoint of rubber elasticity.
- the molecular weight of the component (A) in the present invention is not particularly limited, but the number average molecular weight is preferably 500 to 500,000, more preferably 1,000 to 100 in terms of fluidity and physical properties after curing. 3,000, particularly preferably 3,000 to 50,000.
- the number average molecular weight was calculated by a standard polystyrene conversion method using size exclusion chromatography (SEC) unless otherwise specified.
- component (A) vinyl polymer examples include polyisobutylene, polyisoprene, polybutadiene, and (meth) acrylic polymers. Among them, from the viewpoint of sealing properties, polyisobutylene and acrylic polymers. Polyisobutylene is particularly preferred from the viewpoint of excellent gas barrier properties.
- component (A) polyisobutylene, - [CH 2 C (CH 3 ) 2] - may be you have the unit "- [CH 2 C (CH 3 ) 2] - other structural unit other than the unit May be included.
- the — [CH 2 C (CH 3 ) 2 ] — unit is contained, for example, at least 50% by mass, preferably 70% by mass or more, more preferably 75% by mass or more, based on the total amount of the structural units. Preferably it contains 80 mass% or more.
- the component (A) includes — [CH 2 C (CH 3 ) 2 ] — units, for example, 100% by mass or less, in another aspect, 95% by mass or less, and in another aspect, 90% by mass or less.
- the term “poly” or “polymer” is not limited by theory, but for example, a structure having a repeating unit of a monomer in the main chain of the polymer, for example, 100 or more, preferably 300 or more, more preferably 500 or more. It can be defined to refer to a compound consisting of units. Although it does not specifically limit as a commercial item of the polyisobutylene of the said (A) component, For example, EPION (Epion) (trademark) 200A, 400A, 600A (made by Kaneka Corporation) etc. are mentioned.
- Examples of the (meth) acrylic polymer of the component (A) include polypropyl acrylate, polybutyl acrylate, polypentyl acrylate, polyhexyl acrylate, and the like. Although it does not specifically limit as a commercial item of the (meth) acrylic-type polymer of the said (A) component, For example, SA100A, OR100A, OR200A (made by Kaneka Corporation) etc. are mentioned.
- the hydrosilyl group-containing compound of the component (B) of the present invention is not particularly limited as long as it can be cured by the hydrosilylation reaction with the component (A).
- the hydrosilyl group represents a group having a SiH bond.
- the component (B) is not particularly limited, but preferably includes an organohydrogenpolysiloxane. More specifically, a hydrosilyl group is formed in a molecule composed of a linear, branched, cyclic or network molecule. Examples thereof include silicone. In addition, a compound having, for example, 2 or more, preferably 3 or more hydrosilyl groups is preferable.
- the commercial product of the component (B) is not particularly limited, but CR-300, CR-500 (manufactured by Kaneka Corporation), HMS-013, HMS-151, HMS-301 (manufactured by Azmax Co., Ltd.), SH1107 fluid ( Toray Dow Corning Co., Ltd.).
- the blending amount of the component (B) is not particularly limited, but is preferably 0.1 to 50 parts by weight, more preferably 1 to 40 parts by weight with respect to 100 parts by weight of the component (A).
- the amount is more preferably 5 to 30 parts by mass, and particularly preferably 8 to 20 parts by mass.
- the amount (equivalent) of the component (B) is usually 0.5 to 2.5 equivalents per 1 mol in total of the alkenyl group contained in the component (A) and the vinyl ether group contained in the component (D).
- the amount is preferably 1.0 to 2.0 equivalents. If it is 0.5 equivalent or more, the gas permeability and low moisture permeability of the cured product can be sufficiently ensured without lowering the crosslinking density, and if it is 2.5 equivalent or less, hydrogen gas is generated by the hydrosilylation reaction. This is preferable because it does not cause a problem of foaming of the cured product and does not affect the heat resistance.
- the hydrosilylation catalyst as component (C) of the present invention is not particularly limited as long as it can catalyze a hydrosilylation reaction, and any catalyst can be used.
- a carrier such as chloroplatinic acid, platinum alone, alumina, silica, and carbon black. those was supported; chlor
- chloroplatinic acid platinum-olefin complexes, platinum-vinylsiloxane complexes and the like are preferable from the viewpoint of excellent activity.
- the component (C) is cured by using a catalyst that can be cured by heating, rather than a catalyst that can be cured by irradiation with an active energy ray such as ultraviolet rays, as described later. From the viewpoint of excellent durability and reliability.
- the present curable resin composition is cured by irradiating active energy rays such as ultraviolet rays
- active energy rays such as ultraviolet rays
- a platinum complex having a ⁇ -diketonate compound as a ligand or a platinum complex having a cyclic diene compound as a ligand can be used.
- the active energy ray is a broad sense such as radiation such as ⁇ ray or ⁇ ray, electromagnetic wave such as ⁇ ray or X ray, electron beam (EB), ultraviolet ray of about 100 to 400 nm, visible ray of about 400 to 800 nm, or the like. It contains all light, preferably ultraviolet light.
- platinum complex having the ⁇ -diketonate compound as a ligand examples include, for example, trimethyl (acetylacetonato) platinum, trimethyl (3,5-heptanedionate) platinum, trimethyl (methylacetoacetate) platinum, bis (2 , 4-pentanedionato) platinum, bis (2,4-hexandionato) platinum, bis (2,4-heptaneedionato) platinum, bis (3,5-heptaneedionato) platinum, bis (1-phenyl-1,3 -Butanedionato) platinum, bis (1,3-diphenyl-1,3-propanedionato) platinum, etc.
- bis (2,4-pentanedionato) platinum is particularly preferred from the viewpoint of high activity by ultraviolet rays. Is preferred.
- platinum complex having the cyclic diene compound as a ligand examples include (1,5-cyclooctadienyl) dimethylplatinum complex, (1,5-cyclooctadienyl) diphenylplatinum complex, (1,5 -Cyclooctadienyl) dipropylplatinum complex, (2,5-norboradiene) dimethylplatinum complex, (2,5-norboradiene) diphenylplatinum complex, (cyclopentadienyl) dimethylplatinum complex, (methylcyclopentadienyl) diethyl Platinum complex, (trimethylsilylcyclopentadienyl) diphenylplatinum complex, (methylcycloocta-1,5-dienyl) diethylplatinum complex, (cyclopentadienyl) trimethylplatinum complex, (cyclopentadienyl) ethyldimethylplatinum complex
- platinum complex examples include an isopropyl alcohol solution of platinum divinyltetramethyldisiloxane complex (Pt-VTS-3.0IPA, manufactured by Umicore Precious Metals Japan Co., Ltd.).
- catalysts other than platinum compounds include RhCl (PPh 3 ) 3 , RhCl 3 , RuCl 3 , IrCl 3 , FeCl 3 , AlCl 3 , PdCl 3 .2H 2 O, NiCl 2 , TiCl 4 and the like. . These catalysts may be used alone or in combination of two or more.
- the amount of catalyst is not particularly limited, but it is preferably used in the range of 1 ⁇ 10 ⁇ 1 to 1 ⁇ 10 ⁇ 8 mol as a compound with respect to 1 mol of alkenyl group in component (A). Preferably, it is used in the range of 1 ⁇ 10 ⁇ 2 to 1 ⁇ 10 ⁇ 6 mol. Further, it is preferable that the hydrosilyl group-forming catalyst is less than 1 ⁇ 10 ⁇ 1 mol because it does not become too expensive and does not generate hydrogen gas to cause foaming in the cured product.
- the absolute amount of component (C) in the curable resin composition is, for example, 10 to 1000 ⁇ l, preferably 50 to 700 ⁇ l, more preferably 100 to 500 ⁇ l, and still more preferably 200 to 400 ⁇ l.
- the form of component (C) may be either solid or liquid.
- it is used in the form of an alcohol solution, preferably in the form of a solution such as methanol, ethanol or propanol, more preferably in the form of an isopropanol solution. It is appropriate to do.
- the polyfunctional vinyl ether compound which is the component (D) of the present invention is a cured product which can satisfy characteristics such as high extensibility, high tensile strength, hydrogen gas barrier property while having low viscosity by combining with the other components of the present invention.
- the remarkable effect that is obtained can be obtained.
- the polyfunctional vinyl ether compound means a compound having two or more vinyl ether groups.
- it does not specifically limit as said (D) component The polyfunctional vinyl ether compound containing a cycloalkane structure, the polyfunctional vinyl ether compound containing an ether structure, the polyfunctional vinyl ether compound containing an alkylene structure, etc. are mention
- polyfunctional vinyl ether compound containing the said cycloalkane structure For example, cyclohexane dimethanol divinyl ether etc. are mention
- the polyfunctional vinyl ether compound containing the ether structure is not particularly limited, and examples thereof include triethylene glycol divinyl ether, diethylene glycol divinyl ether, and tetraethylene glycol divinyl ether.
- the polyfunctional vinyl ether compound containing an alkylene structure is not particularly limited, and examples thereof include 1,4-butanediol divinyl ether and 1,6-hexanediol divinyl ether.
- the commercial product of the component (D) is not particularly limited, but 1,4-butylene divinyl ether (BDVE), cyclohexane divinyl ether (CHDVE), diethylene glycol divinyl ether (DEGDVE), triethylene glycol civinyl ether (TEGDVE, Japan) Carbide Industries Co., Ltd.).
- BDVE 1,4-butylene divinyl ether
- CHDVE cyclohexane divinyl ether
- DEGDVE diethylene glycol divinyl ether
- TEGDVE triethylene glycol civinyl ether
- the blending amount of the component (D) is not particularly limited, but is preferably 0.05 to 30 parts by mass, more preferably 0.1 to 20 parts by mass with respect to 100 parts by mass of the component (A). Particularly preferred is 0.5 to 10 parts by mass. It is preferable because a cured product excellent in high extensibility and high tensile strength can be obtained while being low viscosity by being 0.1 part by mass or more, and excellent in hydrogen gas barrier properties by being 30 parts by mass or less. It is preferable because a cured product can be obtained.
- composition of the present invention various elastomers such as a crosslinking agent, a silane coupling agent, a reaction rate regulator, a styrene copolymer, a filler, a storage stabilizer, and an antioxidant, as long as the object of the present invention is not impaired.
- Additives such as additives, light stabilizers, plasticizers such as polyalphaolefins, pigments, flame retardants, and surfactants can be used.
- a crosslinking agent may be added to the present invention.
- the crosslinking agent include 2,4,6-tris (allyloxy) -1,3,5-triazine, 1,2-polybutadiene, 1,2-polybutadiene derivative, trimethylolpropane diallyl ether, pentaerythritol triallyl ether.
- 1,2,4-trivinylcyclohexane, triallyl isocyanurate, 2,4,6-tris (allyloxy) -1,3,5-triazine 1,2-polybutadiene is preferred.
- silane coupling agent examples include vinyltrimethoxysilane, vinyltriethoxysilane, 3-methacryloxypropylmethyldimethoxysilane, 3-methacryloxypropyltrimethoxysilane, 3-acryloxypropyltrimethoxysilane, and 3-methacryloxypropyl.
- examples thereof include methyldiethoxysilane, 3-methacryloxypropyltriethoxysilane, p-styryltrimethoxysilane, and allyltrimethoxysilane.
- the commercial product of the silane coupling agent is not particularly limited, but KBM-1003, KBE-1003, KBM-502, KBE-502, KBM-503, KBE-503, KBM-5103, KBM-1403 ( Shin-Etsu Chemical Co., Ltd.), Z-6825 (Toray Dow Corning Co., Ltd.), and the like.
- reaction rate modifier may be added to the present invention.
- reaction rate modifier include alkyne compounds, maleic esters, organic phosphorus compounds, organic sulfur compounds, nitrogen-containing compounds, and the like. These may be used alone or in combination of two or more.
- alkyne compound examples include 3-hydroxy-3-methyl-1-butyne, 3-hydroxy-3-phenyl-1-butyne, 3,5-dimethyl-1-hexyn-3-ol, -Ethynyl-1-cyclohexanol and the like.
- maleic esters include maleic anhydride, dimethyl maleate, diethyl maleate and the like.
- organic phosphorus compound examples include triorganophosphine, diorganophosphine, organophosphon, and triorganophosphite.
- organic sulfur compound examples include organomercaptans, diorganosulfides, hydrogen sulfide, benzothiazole, thiazole, benzothiazole disulfide, and the like.
- nitrogen-containing compounds include N, N, N ′, N′-tetramethylethylenediamine, N, N-dimethylethylenediamine, N, N-diethylethylenediamine, N, N-dibutylethylenediamine, and N, N.
- the compounding amount of the alkyne compound is suitably about 0.01 to 10 parts by mass, preferably about 0.1 to 1 part by mass with respect to 100 parts by mass of component (A).
- elastomers such as a styrene copolymer may be added to the present invention.
- elastomers such as styrene copolymers include styrene-butadiene-styrene block copolymers, styrene-isoprene-styrene block copolymers, and styrene-ethylenebutylene-styrene block copolymers obtained by hydrogenation thereof. And styrene-ethylenepropylene-styrene block copolymer. These may be used alone or in combination of two or more.
- a filler that does not impair storage stability may be added to the present invention.
- the shape of the filler is not particularly limited, but a spherical shape is preferable because the mechanical strength of the cured product of the curable resin composition can be improved and an increase in viscosity can be suppressed.
- the average particle size of the filler is not particularly limited, but is preferably in the range of 0.001 to 100 ⁇ m, more preferably in the range of 0.01 to 50 ⁇ m.
- Specific examples of the filler include organic powders, inorganic powders, metallic powders, and the like.
- the inorganic powder filler examples include glass, silica, alumina, mica, ceramics, silicone rubber powder, calcium carbonate, aluminum nitride, carbon powder, kaolin clay, dry clay mineral, and dry diatomaceous earth.
- the blending amount of the inorganic powder is suitably about 0.1 to 300 parts by weight, preferably 1 to 100 parts by weight, more preferably about 10 to 50 parts by weight with respect to 100 parts by weight of component (A). If it is larger than 0.1 parts by mass, the effect is not reduced, and if it is 300 parts by mass or less, sufficient fluidity of the curable resin composition is obtained, and good workability is obtained.
- Silica can be blended for the purpose of adjusting the viscosity of the curable resin composition or improving the mechanical strength of the cured product.
- those hydrophobized with organochlorosilanes, polyorganosiloxane, hexamethyldisilazane and the like can be used.
- Specific examples of the silica include granular silica, spherical silica, and fumed silica.
- Specific examples of fumed silica include commercially available products such as trade names Aerosil R974, R972, R972V, R972CF, R805, R812, R812S, R816, R8200, RY200, RX200, RY200S, and R202 manufactured by Nippon Aerosil. .
- organic powder filler examples include polyethylene, polypropylene, nylon, crosslinked acrylic, crosslinked polystyrene, polyester, polyvinyl alcohol, polyvinyl butyral, and polycarbonate.
- the blending amount of the organic powder is preferably about 0.1 to 100 parts by mass with respect to 100 parts by mass of the component (A). If it is 0.1 mass part or more, sufficient effect will be acquired, and if it is 100 mass parts or less, the fluidity
- a storage stabilizer may be added to the present invention.
- the storage stabilizer include 2-benzothiazolyl sulfide, benzothiazole, thiazole, dimethylacetylene dicarboxylate, diethylacetylene dicarboxylate, 2,6-di-t-butyl-4-methylphenol, butylhydroxy Anisole, 2- (4-morphodinyldithio) benzothiazole, 3-methyl-1-buten-3-ol, acetylenically unsaturated group-containing organosiloxane, acetylene alcohol, 3-methyl-1-butyl-3-ol Diallyl fumarate, diallyl maleate, diethyl fumarate, diethyl maleate, dimethyl maleate, 2-pentenenitrile, 2,3-dichloropropene male and the like. These may be used alone or in combination of two or more.
- An antioxidant may be added to the present invention.
- the antioxidant include ⁇ -naphthoquinone, 2-methoxy-1,4-naphthoquinone, methyl hydroquinone, hydroquinone, hydroquinone monomethyl ether, mono-tert-butyl hydroquinone, 2,5-di-tert-butyl hydroquinone, p Quinone compounds such as benzoquinone, 2,5-diphenyl-p-benzoquinone, 2,5-di-tert-butyl-p-benzoquinone; phenothiazine, 2,2-methylene-bis (4-methyl-6-tert- Butylphenol), catechol, tert-butylcatechol, 2-butyl-4-hydroxyanisole, 2,6-di-tert-butyl-p-cresol, 2-tert-butyl-6- (3-tert-butyl-2- Hydroxy-5-methylbenzyl) -4-methyl Phenyl acrylate
- a light stabilizer may be added to the present invention.
- the light stabilizer include bis (2,2,6,6-tetramethyl-4-piperidyl) sebacate, bis (1,2,2,6,6-pentamethyl-4-piperidyl) sebacate, and 4-benzoyl.
- Plasticizers, pigments, flame retardants and surfactants may be added to the present invention.
- the plasticizer include petroleum-based process oils such as raffinic process oil, naphthenic process oil, and aromatic process oil, acrylic plasticizers, dibasic acids such as diethyl phthalate, dioctyl phthalate, and dibutyl adipate. And low molecular weight liquid polymers such as dialkyl, liquid polybutene, and liquid polyisoprene.
- Preferred plasticizers include polyalphaolefin plasticizers and acrylic plasticizers.
- the blending amount of the plasticizer is, for example, 0.1 to 100 parts by mass, preferably 1 to 50 parts by mass, and more preferably 10 to 40 parts by mass with respect to 100 parts by mass of the component (A).
- the pigment include carbon.
- the flame retardant include a hydrated metal compound system, a phosphorus system, a silicone system, and a nitrogen compound system.
- the surfactant include an anionic surfactant, a nonionic surfactant, and a nonionic surfactant. These may be used alone or in combination of two or more.
- the curable resin composition of the present invention can be produced by a conventionally known method. For example, a predetermined amount of components (A) to (D) and other optional components are blended and mixed using a mixing means such as a planetary mixer, preferably at a temperature of 10 to 70 ° C., more preferably It can be produced by mixing at 20 to 50 ° C., particularly preferably at room temperature (25 ° C.), preferably 0.1 to 5 hours, more preferably 30 minutes to 3 hours, particularly preferably around 60 minutes.
- a mixing means such as a planetary mixer, preferably at a temperature of 10 to 70 ° C., more preferably It can be produced by mixing at 20 to 50 ° C., particularly preferably at room temperature (25 ° C.), preferably 0.1 to 5 hours, more preferably 30 minutes to 3 hours, particularly preferably around 60 minutes.
- ⁇ Application method> As a method for applying the curable resin composition of the present invention to an adherend, known sealing agents and adhesive methods are used. For example, methods such as dispensing, spraying, inkjet, screen printing, gravure printing, dipping, spin coating using an automatic coater can be used.
- the curable resin composition of the present invention is preferably liquid at 25 ° C. from the viewpoint of applicability.
- the curable resin composition of the present invention can be cured by heating or irradiation with an active energy ray such as ultraviolet light or visible light to obtain a cured product.
- an active energy ray such as ultraviolet light or visible light
- a cured product obtained by heating is preferable because of excellent durability and reliability.
- the temperature and time at the time of heating are not particularly limited as long as they can be sufficiently cured.
- the temperature and time are 40 to 300 ° C, preferably 60 to 200 ° C, more preferably 80 to 150 ° C, and particularly preferably 130 ° C.
- the light source for curing by irradiating active energy rays such as ultraviolet rays and visible light is not particularly limited.
- a low pressure mercury lamp, a medium pressure mercury lamp, a high pressure mercury lamp, an ultrahigh pressure mercury lamp, a black light lamp, a microwave Examples include an excited mercury lamp, a metal halide lamp, a sodium lamp, a halogen lamp, a xenon lamp, an LED, a fluorescent lamp, sunlight, and an electron beam irradiation device.
- the irradiation amount of light irradiation is preferably 10 kJ / m 2 or more, more preferably 15 kJ / m 2 or more.
- the curable resin composition of the present invention to a two-component composition (kit)
- a two-component composition (kit) it is preferable to include the component (A) in one liquid and the component (B) in the other liquid.
- the two liquids can be mixed or applied separately and then contacted and cured.
- the curable resin composition of the present invention or a cured product thereof is preferably used as a thermosetting or photocurable sealing agent.
- the sealing agent includes uses such as an adhesive, a coating agent, a casting agent, and a potting agent.
- the curable resin composition of this invention is a liquid at 25 degreeC.
- the curable resin composition of the present invention or the cured product thereof is a rubber elastic body excellent in low gas permeability, low moisture permeability, heat resistance, acid resistance, and flexibility.
- the curable resin composition of the present invention or the cured product thereof is a rubber elastic body excellent in low gas permeability, low moisture permeability, heat resistance, acid resistance, and flexibility.
- fuel cells solar cells, dye-sensitized solar cells, lithium ion batteries, electrolytic capacitors, liquid crystal displays, organic EL displays, electronic paper, LEDs, hard disk devices, photodiodes, optical communication / circuits, electric wires / cables / optical fibers Laminates such as optical isolators and IC cards, sensors, substrates, pharmaceutical / medical instruments and devices, and the like.
- the curable resin composition of the present invention is rapidly cured by irradiation with active energy rays such as ultraviolet rays, and has excellent adhesion to an electrolyte membrane that is a difficult-to-adhere material. Use is particularly preferred.
- a fuel cell is a power generator that extracts electricity by chemically reacting hydrogen and oxygen.
- fuel cells there are four types of fuel cells: solid polymer fuel cells, phosphoric acid fuel cells, molten carbonate fuel cells, and solid oxide fuel cells. Since the operating temperature is relatively low (around 80 ° C.) and high power generation efficiency, it is used for applications such as automobile power sources, household power generators, small power supplies for electronic devices such as mobile phones, and emergency power supplies.
- a cell 1 of a typical polymer electrolyte fuel cell is an electrolyte membrane electrode assembly having a structure in which a polymer electrolyte membrane 4 is sandwiched between an air electrode 3a and a fuel electrode 3b. 5 (MEA), a frame 6 that supports the MEA, and a separator 2 in which a gas flow path is formed.
- fuel gas hydrogen gas
- oxidizing gas oxygen gas
- a package in which several hundreds of cells are stacked is called a cell stack 10 as shown in FIG.
- a sealing agent is frequently used for the purpose of preventing leakage of fuel gas, oxygen gas and the like. Specifically, a sealant is used between adjacent separators, between the separator and the frame, between the frame and the electrolyte membrane or MEA, and the like.
- the polymer electrolyte membrane examples include a cation exchange membrane having ion conductivity, preferably a chemically stable and strong operation at a high temperature, and examples thereof include a fluorine polymer having a sulfonic acid group. It is done.
- examples of commercially available products include Nafion (registered trademark) manufactured by DuPont, Flemion (registered trademark) manufactured by Asahi Kasei Corporation, and Aciplex (registered trademark) manufactured by Asahi Glass Co., Ltd.
- the polymer electrolyte membrane is a material that hardly adheres, but can be adhered by using the curable resin composition of the present invention.
- the fuel electrode is called a hydrogen electrode or an anode, and a known one is used.
- carbon in which a catalyst such as platinum, nickel, ruthenium or the like is supported is used.
- the air electrode is called an oxygen electrode or a cathode, and a known one is used.
- carbon in which a catalyst such as platinum or an alloy is supported is used.
- the surface of each electrode may be provided with a gas diffusion layer that functions to diffuse gas and keep the electrolyte membrane moisturized.
- a known gas diffusion layer is used, and examples thereof include carbon paper, carbon cloth, and carbon fiber.
- the separator 2 has a fine flow path with irregularities, through which fuel gas and oxidizing gas pass and are supplied to the electrodes.
- the separator is made of aluminum, stainless steel, titanium, graphite, carbon, or the like.
- the frame is used to support and reinforce a thin electrolyte membrane or MEA so as not to be broken.
- the material of the frame include thermoplastic resins such as polyvinyl chloride, polyethylene naphthalate (PEN), polyethylene terephthalate (PET), polypropylene (PP), and polycarbonate.
- thermoplastic resins such as polyvinyl chloride, polyethylene naphthalate (PEN), polyethylene terephthalate (PET), polypropylene (PP), and polycarbonate.
- the fuel cell of the present invention is a fuel cell characterized by being sealed with the curable resin composition of the present invention or a cured product thereof.
- the member that needs to be sealed in the fuel cell include a separator, a frame, an electrolyte membrane, a fuel electrode, an air electrode, and an MEA. More specific seal locations include between adjacent separators, between separators and frames, between frames and electrolyte membranes or MEAs, and the like.
- the purpose of the main seal “between the separator and the frame” or “between the polymer electrolyte membrane or MEA and the frame” is to prevent gas mixing and leakage, and between the adjacent separators.
- the purpose of the seal is to prevent gas leakage and to prevent cooling water from leaking from the cooling water flow path to the outside.
- the sealing method using the curable resin composition of the present invention is not particularly limited.
- FIPG form in place gasket
- CIPG cure in place gasket
- MIPG mold in place gasket
- Examples include liquid injection molding.
- FIPG means that the curable resin composition of the present invention is applied to a flange of a part to be sealed by an automatic application device or the like, and is bonded to the other flange and irradiated with heating or active energy rays to be cured.
- the resin composition is cured and adhesively sealed. More specifically, a method of sealing at least a part between at least two flanges of a sealed part having at least two flanges, wherein at least one of the flanges is capable of conducting heat or active energy rays.
- the step of applying the curable resin composition described above to at least one surface of the flange, the one flange and the other flange coated with the curable resin composition being the curable resin composition.
- a step of laminating the curable resin composition by heating or irradiating an active energy ray through the flange capable of transmitting the active energy ray to cure the curable resin composition, and at least a part between the at least two flanges And a sealing method.
- CIPG is a bead coating of the curable resin composition of the present invention on the flange of a part to be sealed with an automatic coating apparatus, etc., and heating or irradiating active energy rays to cure the curable resin composition to form a gasket. To do. And it is the technique of pasting together and compressing and sealing with the other flange. More specifically, a method for sealing at least a part between at least two flanges of a part to be sealed having at least two flanges, wherein at least one of the flanges has the curable resin composition described above.
- a step of sealing at least a part of the sealing method.
- a mold is pressed against a flange of a part to be sealed in advance, a curable resin composition is injected into a cavity formed between the mold of the light transmissive material and the flange, and heated or irradiated with active energy rays. Then, a gasket is formed. And it is the technique of pasting together and compressing and sealing with the other flange.
- a release agent such as a fluorine type or a silicone type in advance to the mold in order to facilitate removal from the mold after the gasket is formed.
- a step of irradiating the active energy ray to cure the curable resin composition forming a gasket made of a cured product of the curable resin composition, a step of removing the mold from the one flange, The other flange is disposed on the gasket, the one flange and the other flange are pressure-bonded via the gasket, and the Both a sealing method which comprises a step, to seal at least a portion between the two flanges.
- the curable resin composition of the present invention is poured into a mold at a specific pressure, and heated or irradiated with active energy rays to form a gasket. And it is the technique of pasting together and compressing and sealing with the other flange.
- a release agent such as a fluorine type or a silicone type in advance to the mold in order to facilitate removal from the mold after the gasket is formed.
- test methods implemented in the examples and comparative examples in Table 1 are as follows.
- ⁇ Viscosity measurement method The viscosity (Pa ⁇ s) of the curable resin composition was measured with a cone plate viscometer (manufactured by Brookfield) based on the following measurement conditions. Evaluation is based on the following criteria, and the results are shown in Table 1.
- the viscosity is preferably 800 Pa ⁇ s or less, and particularly preferably 700 Pa ⁇ s or less.
- [Measurement condition] Cone type CPE-52, rotation speed 0.5 rpm, shear rate 1.0 1 / s, temperature 25 ° C.
- the thickness of the curable resin composition is set to 2 mm, and is heated and cured by heating at 130 ° C. for 1 hour to produce a sheet-like cured product. While holding the pressure surface of the A-type durometer (hardness meter) parallel to the test piece (three sheets of cured product stacked and set to a thickness of 6 mm), press and apply with a force of 10 N The pressing surface and the sample are brought into close contact with each other. The maximum value is read during measurement, and the maximum value is defined as “hardness” (Shore A hardness). Details follow JIS K 6253 (2012).
- the hardness (Shore A hardness) is preferably 30 or more, and more preferably 35 or more.
- ⁇ Tensile strength measurement> The thickness of the curable resin composition is set to 2 mm, and is heated and cured by heating at 130 ° C. for 1 hour to create a sheet-like cured product.
- a test piece is produced by punching with a No. 3 dumbbell. Fix both ends of the test piece to the chuck so that the long axis of the test piece and the center of the chuck are aligned. The test piece is pulled at a pulling speed of 50 mm / min, and the maximum load is measured. The strength at the maximum load is defined as “tensile strength (MPa)”. Details follow JIS K 6251 (2010).
- the tensile strength is preferably 2.0 MPa or more, more preferably 2.5 MPa or more.
- ⁇ Measurement method of elongation percentage of cured product The thickness of the curable resin composition is set to 2 mm, and is heated and cured by heating at 130 ° C. for 1 hour to create a sheet-like cured product.
- a test piece is produced by punching with a No. 3 type dumbbell, and marked lines at intervals of 20 mm are written on the test piece. The sample is fixed to the chuck in the same manner as the measurement of the tensile strength, and pulled until the test piece is cut at a tensile speed of 500 mm / min. Since the test piece extends during measurement and the interval between the marked lines increases, the interval between the marked lines is measured with a caliper until the test piece is cut.
- the elongation ratio is defined as “elongation rate (%)”. Evaluation is based on the following criteria, and the results are shown in Table 1.
- the elongation is preferably 200% or more, and more preferably 230% or more.
- the present invention has characteristics such as high extensibility and high tensile strength while having low viscosity.
- Comparative Example 1 was obtained by removing the component (D) of the present invention, but had a high viscosity and poor tensile strength.
- Comparative Examples 2 and 3 were compositions using d'1 and d'2 which were not the component (D) of the present invention, but the results were soft and inferior in tensile strength.
- ⁇ Hydrogen gas barrier test> The thickness of the curable resin composition of Example 1 is set to 2 mm, and is heated and cured by heating at 130 ° C. for 1 hour to create a sheet-like cured product.
- the cured product was measured in accordance with JIS K7126-1: 2006 (Plastics—Films and Sheets—Gas Permeability Test Method—Part 1: Differential Pressure Method).
- the type of test was the pressure sensor method, the conditions were 23 ° C., the test gas (hydrogen gas) on the high pressure side was measured with a sheet of 100 kPa and a thickness of 1 mm, and evaluated based on the following evaluation criteria. The result was less than 1 ⁇ 10 ⁇ 14 mol ⁇ m / m 2 ⁇ s ⁇ Pa, and it was confirmed that it could be used as a fuel cell sealant.
- the curable composition changed from a1 (polyisobutylene having alkenyl groups at both ends) to a2 (acrylic polymer having alkenyl groups at both ends) of component (A) was examined. (See Table 2)
- Example 5 preparation was carried out in the same manner as in Example 1, except that a1 of component (A) was changed to a2 and plasticizer 1 was changed to plasticizer 2.
- Example 5 was obtained. (See Table 2)
- Comparative Example 4 was prepared in the same manner as Comparative Example 1, except that a1 of component (A) was changed to a2 and plasticizer 1 was changed to plasticizer 2. Got. (See Table 2)
- Example 5 and Comparative Example 4 in Table 2 are the same as the test methods performed in Examples 1 to 4 above.
- the hardness (Shore A hardness) is preferably 10 or more, more preferably 12 or more, and the tensile strength is preferably 1.0 MPa or more, more preferably 1.2 MPa or more.
- Example 5 in Table 2 when a1 of component (A) is changed to a2, it has properties such as high extensibility and high tensile strength while having low viscosity as in Examples 1 to 4. I found out. On the other hand, although the comparative example 4 remove
- the curable resin composition of the present invention has properties such as high extensibility, high tensile strength, hydrogen gas barrier property, etc. while having low viscosity, and therefore, sealant, adhesive, coating agent, casting agent, potting. It can be used in various applications such as an agent and is industrially useful.
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Abstract
Description
[1]下記の(A)~(D)成分を含有することを特徴とする硬化性樹脂組成物。
(A)成分:1分子中にアルケニル基を1以上有するビニル重合体
(B)成分:1分子中にヒドロシリル基を1以上有する化合物
(C)成分:ヒドロシリル化触媒
(D)成分:多官能ビニルエーテル化合物
[2] 前記(D)成分が、シクロアルカン構造を含むビニルエーテル化合物、エーテル構造を含むビニルエーテル化合物、及びアルキレン構造を含むビニルエーテル化合物からなる群から選択される少なくとも1以上であることを特徴とする[1]に記載の硬化性樹脂組成物。
[3]前記(A)成分が、アルケニル基を1以上有するポリイソブチレンまたはアルケニル基を1以上有するアクリル系重合体であることを特徴とする[1]または[2]のいずれか1項に記載の硬化性樹脂組成物。
[4][1]~[3]のいずれか1項に記載の硬化性樹脂組成物を含む、燃料電池用硬化性シール剤。
[5]前記燃料電池用硬化性シール剤が、燃料電池における部材であるセパレーター、フレーム、電解質、燃料極、空気極、及び電解質膜電極接合体からなる群のいずれかの部材周辺用燃料電池用硬化性シール剤である、[4]に記載のシール剤。
[6]前記燃料電池用硬化性シール剤が、燃料電池における隣り合うセパレーター同士との間のシール剤、若しくは燃料電池のフレームと電解質膜または電解質膜電極接合体との間のシール剤である、[4]に記載のシール剤。
[7]前記燃料電池が、固体高分子形燃料電池である、[4]~[6]のいずれか1項に記載のシール剤。
[8][1]~[3]のいずれか1項に記載の硬化性樹脂組成物または[4]~[6]のいずれか1項に記載のシール剤を光硬化してなる硬化物。
[9]燃料電池における隣り合うセパレーター同士との間のシール、及び燃料電池のフレームと電解質膜または電解質膜電極接合体との間のシールからなる群のいずれかを含む燃料電池であって、前記いずれかのシールが、[8]に記載の硬化物を含む、燃料電池。
[10]前記燃料電池が、固体高分子形燃料電池である、[9]に記載の燃料電池。
[11]少なくとも2つのフランジを有する被シール部品の当該少なくとも2つのフランジの間の少なくとも一部をシールする方法であって、前記フランジの少なくとも一方が熱または活性エネルギー線を透過可能であり、前記フランジの少なくとも一方の表面に、[1]~[3]のいずれか1項に記載の硬化性樹脂組成物を塗布する工程、前記硬化性樹脂組成物を塗布した一方のフランジと他方のフランジとを前記硬化性樹脂組成物を介して貼り合わせる工程、及び、加熱してまたは活性エネルギー線を前記光透過可能なフランジを通して照射して前記硬化性樹脂組成物を硬化させ、前記少なくとも2つのフランジの間の少なくとも一部をシールする工程、を含むことを特徴とする前記シール方法。
[12]少なくとも2つのフランジを有する被シール部品の当該少なくとも2つのフランジの間の少なくとも一部をシールする方法であって、前記フランジの少なくとも一方のフランジに、[1]~[3]のいずれか1項に記載の硬化性樹脂組成物を塗布する工程、前記塗布した硬化性樹脂組成物に加熱してまたは活性エネルギー線を照射して前記硬化性樹脂組成物を硬化させ、前記硬化性樹脂組成物の硬化物からなるガスケットを形成する工程、他方のフランジを前記ガスケット上に配置して、硬化性樹脂組成物を塗布した一方のフランジと前記他方のフランジとを前記ガスケットを介して圧着し、前記少なくとも2つのフランジの間の少なくとも一部をシールする工程、を含むことを特徴とする前記シール方法。
[13]少なくとも2つのフランジを有する被シール部品の当該少なくとも2つのフランジの間の少なくとも一部をシールする方法であって、前記フランジの少なくとも一方のフランジ上にガスケット形成用金型を配置する工程、前記ガスケット形成用金型と該金型を配置したフランジとの間の空隙の少なくとも一部に[1]~[3]のいずれか1項に記載の硬化性樹脂組成物を注入する工程、前記硬化性樹脂組成物に加熱してまたは活性エネルギー線を照射して前記硬化性樹脂組成物を硬化させ、前記硬化性樹脂組成物の硬化物からなるガスケットを形成する工程、前記金型を前記一方のフランジから取り外す工程、他方のフランジを前記ガスケット上に配置して、前記一方のフランジと前記他方のフランジとを前記ガスケットを介して圧着し、前記少なくとも2つのフランジの間の少なくとも一部をシールする工程、を含むことを特徴とするシール方法。
<硬化性樹脂組成物>
本発明は、下記の(A)~(D)成分を含有することを特徴とする硬化性樹脂組成物に関する。
(A)成分:1分子中にアルケニル基を1以上有するビニル重合体
(B)成分:1分子中にヒドロシリル基を1以上有する化合物
(C)成分:ヒドロシリル化触媒
(D)成分:多官能ビニルエーテル化合物。
本発明の硬化性樹脂組成物の各(A)~(D)成分、並びに任意成分は、下記のいずれかの条件を満たすものを任意に組み合わせて使用することができる。なお、各(A)~(D)成分は相互に異なる成分である。
本発明に用いられる(A)成分とは、1分子中にアルケニル基を1以上有する25℃(常温)で液状であるビニル系重合体であれば特に限定されるものではない。本発明における(A)成分の25℃での粘度は、特に制限は無いが、作業性などの面から5~5000Pa・sが好ましく、より好ましくは、50~3000Pa・sであり、特に好ましくは、100~2000Pa・sである。なお、特に断りがない限り、粘度の測定はコーンプレート型粘度計を用いて25℃での粘度を測定した。また、アルケニル基がビニル系重合体の主鎖末端にあるとき、低硬度ながら高強度、低圧縮永久ひずみのゴム弾性体が得られやすくなるなどの点から好ましい。ここでアルケニル基は、例えば、炭素数1~10、好ましくは炭素数2~8、より好ましくは炭素数3~5のアルケニル基であることが適当である。好ましいアルケニル基としては、例えば、アリル基、プロペニル基、ブテニル基が適当である。また、(A)成分は、アルケニル基を、好ましくは1~6個、より好ましくは2~4個、さらに好ましくは2~3個、特に好ましくは2個(特にポリマーの両末端に)有することが適当である。また、アルケニル基は分子の側鎖、または、末端のいずれに存在していてもかまわないが、ゴム弾性の点から、分子の末端に存在することが好ましい。
本発明の(B)成分のヒドロシリル基含有化合物としては、(A)成分とヒドロシリル化反応により硬化できるものであれば特に制限はない。ヒドロシリル基とは、SiH結合を有する基を表す。(B)成分としては、特に限定されないが、好ましくはオルガノハイドロジェンポリシロキサンなどが挙げられ、より具体的には、直鎖状、分岐状、環状または網状の分子からなる分子中にヒドロシリル基を含有するシリコーンなどが挙げられる。また、ヒドロシリル基を、例えば2以上、好ましくは3以上有する化合物が好ましい。
本発明の(C)成分であるヒドロシリル化触媒については、ヒドロシリル化反応を触媒できるものであれば特に制限はなく、任意のものが使用できる。
本発明の(D)成分である多官能ビニルエーテル化合物は、本発明のその他成分と組み合わせることによって、低粘度でありながら、高伸張性、高引張強度、水素ガスバリア性等の特性を満足できる硬化物が得られるという顕著な効果を得ることができる。前記多官能ビニルエーテル化合物は、ビニルエーテル基を2以上有する化合物を意味する。前記(D)成分としては、特に限定されないが、シクロアルカン構造を含む多官能ビニルエーテル化合物、エーテル構造を含む多官能ビニルエーテル化合物、アルキレン構造を含む多官能ビニルエーテル化合物などがあげられる。(D)成分の代わりに単官能ビニルエーテル化合物を用いた場合は、このような効果は発揮されない。
本発明の組成物に対し、本発明の目的を損なわない範囲で、架橋剤、シランカップリング剤、反応速度調節剤、スチレン系共重合体等の各種エラストマー、充填材、保存安定剤、酸化防止剤、光安定剤、ポリアルファオレフィン等の可塑剤、顔料、難燃剤、及び界面活性剤等の添加剤を使用することができる。
本発明の硬化性樹脂組成物を被着体への塗布する方法としては、公知のシール剤や接着剤の方法が用いられる。例えば、自動塗布機を用いたディスペンシング、スプレー、インクジェット、スクリーン印刷、グラビア印刷、ディッピング、スピンコートなどの方法を用いることができる。なお、本発明の硬化性樹脂組成物は、塗布性の観点から25℃で液状であることが好ましい。
本発明の硬化性樹脂組成物は、加熱することにより、もしくは、活性エネルギー線、例えば紫外線、可視光等の光を照射することにより硬化して硬化物を得ることができる。特に、耐久性、信頼性に優れることから加熱することによる硬化物が好ましい。
<硬化方法>
加熱に際しての温度及び時間は、十分に硬化できる条件であればよいが、例えば、40~300℃、好ましくは60~200℃、より好ましくは80~150℃、特に好ましくは130℃の温度で、例えば、10秒~10時間、好ましくは1分~5時間、より好ましくは30分~3時間、更に好ましくは1時間程度の条件で加熱することが適当である。低温硬化性の観点から、好ましくは、80~150℃で30分~2時間の条件が適切である。活性エネルギー線、例えば紫外線、可視光等の光を照射することにより硬化させるに際しての光源は特に限定されず、例えば、低圧水銀灯、中圧水銀灯、高圧水銀灯、超高圧水銀灯、ブラックライトランプ、マイクロウェーブ励起水銀灯、メタルハライドランプ、ナトリウムランプ、ハロゲンランプ、キセノンランプ、LED、蛍光灯、太陽光、電子線照射装置等が挙げられる。光照射の照射量は硬化物の特性の観点から積算光量10kJ/m2以上であることが好ましく、より好ましくは積算光量15kJ/m2以上である。
本発明の硬化性樹脂組成物またはその硬化物が好適に用いられる用途としては、熱硬化性又は光硬化性シール剤である。本発明においてシール剤とは、接着剤、コーティング剤、注型剤、ポッティング剤等の用途も含まれるものである。なお、このような用途で使用するにあたり、本発明の硬化性樹脂組成物は25℃で液状であることが好ましい。
燃料電池とは、水素と酸素を化学的に反応させることにより電気を取り出す発電装置である。また、燃料電池には、固体高分子形燃料電池、りん酸形燃料電池、溶融炭酸塩形燃料電池、固体酸化物形燃料電池の4つの方式があるが、中でも固体高分子形燃料電池は、運転温度が比較的低温(80℃前後)でありながら高発電効率であるので、自動車用動力源、家庭用発電装置、携帯電話などの電子機器用小型電源、非常電源等の用途に用いられる。
燃料極(アノード電極):H2→2H++2e-
酸素極(カソード電極):1/2O2+2H++2e-→H2O
ナフィオン(登録商標)
本発明の硬化性樹脂組成物を用いたシール手法としては、特に限定されないが、代表的には、FIPG(フォームインプレイスガスケット)、CIPG(キュアーインプレイスガスケット)、MIPG(モールドインプレイスガスケット)、液体射出成形などが挙げられる。
各成分を表1及び2に示す質量部で採取し、常温(25℃)にてプラネタリーミキサーで60分混合し、硬化性樹脂組成物を調製し、各種物性に関して次のようにして測定した。尚詳細な調製量は表1及び2に従い、数値は質量部で表記する。但し、(C)成分のみμl表記である。なお、(B)成分の添加量は、1.6当量比(ヒドロシリル基/炭素-炭素二重結合)に相当するものである。前記炭素-炭素二重結合とは、(A)成分に含まれるアルケニル基と(D)成分に含まれるビニルエーテル基の合計量を意味する。
a1:25℃で1700Pa・sである両末端にアルケニル基を有するポリイソブチレン(EPION 400A、株式会社カネカ製)
a2:25℃で、660Pa・sである両末端にアルケニル基を有するアクリル系重合体(OR-100A、株式会社カネカ製)
<(B)成分>
b1:ヒドロシリル基含有化合物(CR-300、株式会社カネカ製)
<(C)成分>
c1:白金ジビニルテトラメチルジシロキサン錯体のイソプロピルアルコール溶液(Pt-VTS-3.0IPA、ユミコアプレシャスメタルズジャパン株式会社製)
<(D)成分>
d1:シクロヘキサンジビニルエーテル(CHDVE、日本カーバイド工業株式会社製)
d2:トリエチレングリコールシビニルエーテル(TEGDVE、日本カーバイド工業株式会社製)
d3:ジエチレングリコールジビニルエーテル(DEGDVE、日本カーバイド工業株式会社製)
d4:1,4-ブチレンジビニルエーテル (BDVE、日本カーバイド工業株式会社製)
<(D)成分の比較成分>
d’1:シクロヘキサンモノビニルエーテル (CHVE、日本カーバイド工業株式会社製)
d’2:トリビニルシクロヘキサン(試薬)
<可塑剤>
可塑剤1:ポリアルファオレフィン系可塑剤(SpectraSyn10 ExxonMobil製)
可塑剤2:アクリル系可塑剤(UP-1000 東亜合成株式会社製)
<その他>
・マレイン酸ジメチル(試薬)
・球状シリカ(平均粒径3μm)
コーンプレート型粘度計(ブルックフィールド社製)により下記の測定条件に基づき硬化性樹脂組成物の粘度(Pa・s)を測定した。下記の基準に基づき評価し、結果を表1に示す。粘度は、800Pa・s以下が好ましく、特に好ましくは700Pa・s以下である。
[測定条件]
コーン型CPE-52、回転数 0.5rpm、せん断速度 1.0 1/s、温度 25℃
硬化性樹脂組成物の厚さを2mmに設定し、130℃にて1時間加熱することにより加熱硬化させてシート状の硬化物を作製する。A型デュロメータ(硬度計)の加圧面を試験片(シート状の硬化物を3枚重ねて、厚さ6mmに設定した状態のもの)に対して平行に保ちながら、10Nの力で押しつけ、加圧面と試料とを密着させる。測定時に最大値を読み取り、最大値を「硬さ」(ショアA硬さ)とする。詳細はJIS K 6253(2012)に従う。なお、硬さ(ショアA硬さ)は30以上が好ましく、35以上がより好ましい。
硬化性樹脂組成物の厚さを2mmに設定し、130℃にて1時間加熱することにより加熱硬化させてシート状の硬化物を作成する。3号形ダンベルで打ち抜いてテストピースを作製する。テストピースの長軸とチャックの中心が一直線になる様に、テストピースの両端をチャックに固定する。引張速度50mm/minでテストピースを引張り、最大荷重を測定する。当該最大荷重時の強度を「引張強さ(MPa)」とする。詳細はJIS K 6251(2010)に従う。なお、引張強さは2.0MPa以上が好ましく、2.5MPa以上がより好ましい。
硬化性樹脂組成物の厚さを2mmに設定し、130℃にて1時間加熱することにより加熱硬化させてシート状の硬化物を作成する。3号形ダンベルで打ち抜いてテストピースを作製し、20mm間隔の標線をテストピースに記入する。
引張強さの測定と同じ要領でチャックに固定して、引張速度500mm/minで試験片の切断に至るまで引っ張る。測定時にテストピースが伸びて標線の間隔の広がるため、テストピースが切断されるまでノギスにより標線の間隔を計測する。初期の標線間隔を基準として、伸びた割合を「伸び率(%)」とする。下記の基準に基づき評価し、結果を表1に示す。なお、伸び率は200%以上が好ましく、230%以上がより好ましい。
実施例1の硬化性樹脂組成物の厚さを2mmに設定し、130℃にて1時間加熱することにより加熱硬化させてシート状の硬化物を作成する。その硬化物を用いてJIS K7126-1:2006(プラスチック-フィルム及びシート-ガス透過度試験方法-第1部:差圧法)に準拠し測定した。尚、試験の種類は圧力センサ法であり、条件は23℃、高圧側の試験ガス(水素ガス)は100kPa、厚さ1mmシートにて測定し、下記評価基準に基づき評価した。結果は、1×10-14mol・m/m2・s・Pa未満であり、燃料電池用シール剤として使用可能なことが確認できた。
さらに、実施例1において(A)成分のa1をa2に変更し、かつ、可塑剤1を可塑剤2に変更した以外は、実施例1と同様にして調製して実施例5を得た。(表2参照)
比較例1において(A)成分のa1をa2に変更し、かつ、可塑剤1を可塑剤2に変更した以外は、比較例1と同様にして調製して比較例4を得た。(表2参照)
一方で比較例4は、本発明の(D)成分を除いたものであるが、粘度が高く、引張強度も劣る結果であった。
2 セパレーター
3a 空気極(カソード)
3b 燃料極(アノード)
4 高分子電解質膜
5 電解質膜電極接合体(MEA)
6 フレーム
7 接着剤またはシール剤
8a 酸化ガス流路
8b 燃料ガス流路
9 冷却水の流路
10 セルスタック
11 固体高分子形燃料電池
Claims (13)
- 下記の(A)~(D)成分を含有することを特徴とする硬化性樹脂組成物。
(A)成分:1分子中にアルケニル基を1以上有するビニル重合体
(B)成分:1分子中にヒドロシリル基を1以上有する化合物
(C)成分:ヒドロシリル化触媒
(D)成分:多官能ビニルエーテル化合物 - 前記(D)成分が、シクロアルカン構造を含む多官能ビニルエーテル化合物、エーテル構造を含む多官能ビニルエーテル化合物、及びアルキレン構造を含む多官能ビニルエーテル化合物からなる群から選択される少なくとも1以上である、請求項1に記載の硬化性樹脂組成物。
- 前記(A)成分が、アルケニル基を1以上有するポリイソブチレンまたはアルケニル基を1以上有するアクリル系重合体である、請求項1または2に記載の硬化性樹脂組成物。
- 請求項1~3のいずれか1項に記載の硬化性樹脂組成物を含む、燃料電池用硬化性シール剤。
- 前記燃料電池用硬化性シール剤が、燃料電池における部材であるセパレーター、フレーム、電解質、燃料極、空気極、及び電解質膜電極接合体からなる群のいずれかの部材周辺用燃料電池用硬化性シール剤である、請求項4に記載の燃料電池用硬化性シール剤。
- 前記燃料電池用硬化性シール剤が、燃料電池における隣り合うセパレーター同士との間のシール剤、若しくは燃料電池のフレームと電解質膜または電解質膜電極接合体との間のシール剤である、請求項4に記載の燃料電池用硬化性シール剤。
- 前記燃料電池が、固体高分子形燃料電池である、請求項4~6のいずれか1項に記載の燃料電池用硬化性シール剤。
- 請求項1~3のいずれか1項に記載の硬化性樹脂組成物または請求項4~6のいずれか1項に記載の燃料電池用硬化性シール剤を硬化してなる硬化物。
- 燃料電池における隣り合うセパレーター同士との間のシール、及び燃料電池のフレームと電解質膜または電解質膜電極接合体との間のシールからなる群のいずれかを含む燃料電池であって、前記いずれかのシールが、請求項8に記載の硬化物を含む、燃料電池。
- 前記燃料電池が、固体高分子形燃料電池である、請求項9に記載の燃料電池。
- 少なくとも2つのフランジを有する被シール部品の当該少なくとも2つのフランジの間の少なくとも一部をシールする方法であって、前記フランジの少なくとも一方が熱または活性エネルギー線を透過可能であり、前記フランジの少なくとも一方の表面に、請求項1~3のいずれか1項に記載の硬化性樹脂組成物を塗布する工程、前記硬化性樹脂組成物を塗布した一方のフランジと他方のフランジとを前記硬化性樹脂組成物を介して貼り合わせる工程、及び、加熱してまたは活性エネルギー線を前記光透過可能なフランジを通して照射して前記硬化性樹脂組成物を硬化させ、前記少なくとも2つのフランジの間の少なくとも一部をシールする工程、を含むことを特徴とする前記シール方法。
- 少なくとも2つのフランジを有する被シール部品の当該少なくとも2つのフランジの間の少なくとも一部をシールする方法であって、前記フランジの少なくとも一方のフランジに、請求項1~3のいずれか1項に記載の硬化性樹脂組成物を塗布する工程、前記塗布した硬化性樹脂組成物に加熱してまたは活性エネルギー線を照射して前記硬化性樹脂組成物を硬化させ、前記硬化性樹脂組成物の硬化物からなるガスケットを形成する工程、他方のフランジを前記ガスケット上に配置して、硬化性樹脂組成物を塗布した一方のフランジと前記他方のフランジとを前記ガスケットを介して圧着し、前記少なくとも2つのフランジの間の少なくとも一部をシールする工程、を含むことを特徴とする前記シール方法。
- 少なくとも2つのフランジを有する被シール部品の当該少なくとも2つのフランジの間の少なくとも一部をシールする方法であって、前記フランジの少なくとも一方のフランジ上にガスケット形成用金型を配置する工程、前記ガスケット形成用金型と該金型を配置したフランジとの間の空隙の少なくとも一部に請求項1~3のいずれか1項に記載の硬化性樹脂組成物を注入する工程、前記硬化性樹脂組成物に加熱してまたは活性エネルギー線を照射して前記硬化性樹脂組成物を硬化させ、前記硬化性樹脂組成物の硬化物からなるガスケットを形成する工程、前記金型を前記一方のフランジから取り外す工程、他方のフランジを前記ガスケット上に配置して、前記一方のフランジと前記他方のフランジとを前記ガスケットを介して圧着し、前記少なくとも2つのフランジの間の少なくとも一部をシールする工程、を含むことを特徴とするシール方法。
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US16/497,252 US11114679B2 (en) | 2017-04-14 | 2018-04-13 | Curable resin composition, and fuel cell and sealing method using the same |
CN201880024567.9A CN110494500B (zh) | 2017-04-14 | 2018-04-13 | 固化性树脂组合物、使用该固化性树脂组合物的燃料电池和密封方法 |
CA3057824A CA3057824A1 (en) | 2017-04-14 | 2018-04-13 | Curable resin composition, and fuel cell and sealing method using the same |
JP2019512576A JP7125651B2 (ja) | 2017-04-14 | 2018-04-13 | 硬化性樹脂組成物、それを用いた燃料電池およびシール方法 |
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EP3611227B1 (en) | 2022-12-21 |
EP3611227A1 (en) | 2020-02-19 |
CN110494500B (zh) | 2022-02-08 |
US20200321634A1 (en) | 2020-10-08 |
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