WO2018170672A1 - Method and system for activating lead-acid battery - Google Patents

Method and system for activating lead-acid battery Download PDF

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Publication number
WO2018170672A1
WO2018170672A1 PCT/CN2017/077281 CN2017077281W WO2018170672A1 WO 2018170672 A1 WO2018170672 A1 WO 2018170672A1 CN 2017077281 W CN2017077281 W CN 2017077281W WO 2018170672 A1 WO2018170672 A1 WO 2018170672A1
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WO
WIPO (PCT)
Prior art keywords
activation
battery
battery cell
cell
internal resistance
Prior art date
Application number
PCT/CN2017/077281
Other languages
French (fr)
Chinese (zh)
Inventor
彭冠勇
夏春
Original Assignee
深圳中兴力维技术有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 深圳中兴力维技术有限公司 filed Critical 深圳中兴力维技术有限公司
Priority to PCT/CN2017/077281 priority Critical patent/WO2018170672A1/en
Priority to CN201780002153.1A priority patent/CN108064428B/en
Publication of WO2018170672A1 publication Critical patent/WO2018170672A1/en

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/425Structural combination with electronic components, e.g. electronic circuits integrated to the outside of the casing
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/44Methods for charging or discharging
    • H01M10/443Methods for charging or discharging in response to temperature
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Definitions

  • the present invention relates to the technical field of improving lead-acid batteries, and more particularly to a method for activating a lead-acid battery and a system thereof.
  • the main object of the present invention is to provide a lead-acid battery activation method and a system thereof, which are designed to automatically monitor the battery state and actively complete the activation operation for each battery cell, thereby eliminating the need for battery maintenance. Power off the load on the battery pack.
  • the present invention provides a method for activating a lead-acid battery, which includes:
  • a deviation between a cell internal resistance value of the battery pack and the average internal resistance reference value of the battery pack is greater than a first preset value, or a cell whose internal resistance value is different from a first internal resistance value by a second preset value
  • the monomer is labeled as a first battery cell
  • the activation operation includes at least one activation process; the activation process includes using a preset frequency and a preset sequence current within a preset length
  • the first battery cell is charged and discharged a plurality of times.
  • the method before performing the activating operation on the first battery cell, the method further includes: determining whether the first battery cell is separated from the first activation threshold by a first predetermined threshold If yes, then The step of performing an activation treatment on the first battery cell is performed.
  • the activation process specifically includes:
  • the first battery cell is circulated and charged multiple times by using the preset frequency and the current of the third activation sequence.
  • the activating operation of the first battery cell each time the activation process comprises: [0021] refreshing the first battery cell after each activation process is completed Internal resistance value of the monomer;
  • the present invention also provides a lead-acid battery activation system, which includes
  • control platform is configured to set a deviation between a single internal resistance value of the battery pack and the average internal resistance reference value of the battery pack to be greater than a first preset value, or a deviation between a single internal resistance value and an initial internal resistance value thereof is greater than a second
  • the preset battery cell is labeled as the first battery cell;
  • control platform is further configured to determine whether a first battery cell is present in the battery pack;
  • a monitoring module configured to perform an activation operation on the first battery cell, the activation operation including at least one activation process; the activation process includes adopting a preset frequency and a preset sequence within a preset length The current charges and discharges the first battery cell a plurality of times.
  • control platform is further configured to determine whether the first battery cell is separated from the first activation threshold by a first preset threshold; if not, the activation operation is not allowed to be issued. The instruction or the instruction to end the activation operation.
  • control platform is further configured to:
  • the first battery cell is circulated and charged multiple times using the preset frequency and the current of the third activation sequence.
  • the monitoring module is further configured to refresh the internal resistance value of the first battery cell after each activation process is completed;
  • control platform is further configured to determine whether the deviation between the refreshed internal resistance value and the single internal resistance value of the initial operation of the activation operation is less than a third preset value, and if yes, issue an instruction to end the activation operation; Or judge Whether the length of the activation operation is reached to reach a second predetermined threshold, and if so, an instruction to end the activation operation is issued.
  • the method and system for activating a lead-acid battery proposed by the present invention are only for a certain monomer that needs to be activated, and do not affect other battery cells, and the current unified discharge charging method for the entire battery is more scientific and reasonable. When the battery is used for a period of time, the capacity becomes smaller and the life is shortened.
  • FIG. 1 is a schematic flow chart of a method for activating a lead-acid battery according to an embodiment of the present invention
  • FIG. 2 is a schematic flow chart of a method for activating a lead-acid battery according to another embodiment of the present invention.
  • FIG. 3 is a schematic flow chart of an activation operation according to an embodiment of the present invention.
  • FIG. 4 is a schematic flow chart of an activation process according to an embodiment of the present invention.
  • FIG. 5 is a schematic diagram of a first activation sequence according to an embodiment of the present invention.
  • FIG. 6 is a schematic diagram of a second activation sequence according to an embodiment of the present invention.
  • FIG. 7 is a schematic diagram of a third activation sequence according to an embodiment of the present invention.
  • FIG. 8 is a schematic structural view of a lead-acid battery activation system according to an embodiment of the present invention.
  • FIG. 9 is a schematic structural diagram of a charging and discharging principle of a monitoring module according to an embodiment of the present invention.
  • a first embodiment of the present invention provides a method for activating a lead-acid battery, comprising the steps of: [0055] Sl l, start;
  • the deviation between the internal resistance value of the battery group and the average internal resistance of the battery group is greater than a first preset value, or the deviation between the internal resistance value of the battery and the initial internal resistance value is greater than a second preset value.
  • the battery cell is labeled as a first battery cell;
  • the monitoring data of all the battery cells in the battery pack may be acquired first, and the monitoring data includes a single internal resistance value; and the monitoring data may further include a cell voltage, a temperature, etc.;
  • the average internal resistance reference value of the battery pack, and the average internal resistance reference value of the battery pack can be calculated by the minimum mean difference method.
  • the first preset value is 5% of the average internal resistance reference value; the first preset value is 5% of the initial single cell resistance value of the first battery cell.
  • the single cell resistance value of the first battery cell is 5% higher than the average internal resistance reference value and less than 20%; or the cell resistance value of the first battery cell is relatively different from the initial cell resistance value thereof. 5% higher and less than 20%;
  • step S13 determining whether there is a first battery cell in the battery pack; if yes, proceeding to step S14; if not, proceeding to step S16;
  • step S14 determining whether the battery pack is in a floating state; if yes, proceeding to step S15; if not, proceeding to step S16;
  • the activating operation includes at least one activation process; the activation process includes charging and discharging the first battery cell by using a preset frequency and a preset sequence current within a preset length ; normally
  • the preset frequency is 5K to 20K; for example, a pulse current of 8.3KHZ can be selected; the preset inter-turn interval can be 24 hours, or 12 small or 8 hours, etc., and the present invention does not do this. Limit
  • a second embodiment of the present invention provides a method for activating a lead-acid battery, comprising the steps of: [0065] S21, starting;
  • the deviation between the internal resistance of the battery and the average internal resistance of the battery is greater than the first a battery cell having a value, or a variation of the internal resistance value of the monomer and the initial internal resistance value, which is greater than a second preset value, is marked as a first battery cell;
  • the monitoring data of all the battery cells in the battery pack may be acquired first, and the monitoring data includes a single internal resistance value; in addition, the monitoring data may further include a cell voltage, a temperature, etc.;
  • the average internal resistance reference value of the battery pack, and the average internal resistance reference value of the battery pack can be calculated by the minimum mean difference method.
  • the first preset value is 5% of the average internal resistance reference value; the first preset value is 5% of the initial single cell resistance value of the first battery cell.
  • the single cell resistance value of the first battery cell is 5% higher than the average internal resistance reference value and less than 20%; or the cell resistance value of the first battery cell is relatively biased from the initial cell resistance value thereof. 5% higher and less than 20%;
  • step S23 determining whether there is a first battery cell in the battery pack; if yes, proceeding to step S24; if not, proceeding to step S27;
  • step S24 determining whether the battery pack is in a floating state; if yes, proceeding to step S25; if not, proceeding to step S27;
  • step S25 determining whether the first battery cell is separated from the first activation threshold by the first preset threshold; if yes, proceeding to step S26; if not, ending the process as shown in step S27;
  • the first preset threshold is, for example, 7 days or 168 hours, which is not limited by the present invention.
  • the activating operation includes at least one activation process; the activation process includes charging and discharging the first battery cell by using a preset frequency and a preset sequence current within a preset length ; normally
  • the preset frequency is 5K to 20K; for example, a pulse current of 8.3KHZ can be selected; the preset inter-turn interval is 24 hours, and of course, it can be 12 hours or 8 hours, etc., the present invention does not do this. Limit
  • the step S15 or the step S26 includes: refreshing the internal resistance value of the first battery cell after the activation process is completed; Resistance value The deviation of the internal resistance value of the initial enthalpy of the activation operation is less than the third predetermined value, and the activation operation is ended; or if the length of the activation operation reaches the second predetermined threshold, the activation operation is ended.
  • step S15 or step S26 includes the following steps:
  • S33 determining whether the activation process is completed; that is, determining whether the length of the first and second battery cells that are repeatedly charged and discharged by using the preset frequency and the preset current reaches a preset time ⁇ , for example, 24 hours; if not, then return to step S32; if yes, proceed to step S34;
  • S35 Determine whether the deviation between the refreshed internal resistance value and the internal resistance value of the initial operation of the activation operation is less than a third preset value.
  • the third preset value is an initial activation operation. 3% 3% of the internal resistance of the monomer; if yes, as shown in step S37, the activation operation is completed, that is, the activation operation is completed; if not, then proceeds to step S36;
  • S36 determining whether the length of the activation operation reaches the second preset threshold; in this embodiment, the second preset threshold is, for example, 7 days or 168 hours, but the present invention does not limit this; if not, Then return to step S32; if yes, proceed to step S37;
  • the activation process in the activation operation mentioned in the above step S15 or step S26 includes the steps of:
  • step S43 determining whether the monomer temperature is less than a temperature preset value; if not, proceeding to step S44; if yes, proceed directly to step S45;
  • S44 using the preset frequency and the current of the first activation sequence to charge and discharge the first battery cell a plurality of times; similarly, the preset frequency is 5K to 20K; for example, 8.3 may be selected. KHz pulse current; Referring to FIG.
  • t is the monomer temperature of the first battery cell
  • t0 is the preset temperature value
  • a is a constant, and its value ranges from 10 to 2 0; in this embodiment, t0 is, for example, 25 ° C, a is 10;
  • S46 using the preset frequency and the current of the second activation sequence to cycle and charge the first battery cell a plurality of times;
  • the third activation sequence is charged, waiting for the daytime, and discharging the daytime.
  • the module uses a 1A current magnitude and a pulse frequency of 8.3KHz. If the current cell temperature t is higher than the temperature preset value of 25 degrees and less than 35 degrees, the temperature can be added. Value, the first battery cell is activated by the first activated sequence shown in FIG.
  • the present invention also provides a lead-acid battery activation system, including a monitoring module 10, and a control 20.
  • the monitoring module 10 is configured to acquire monitoring data of all battery cells in the battery group, and the monitoring data includes The internal resistance value of the monomer; in addition, the monitoring data may further include a cell voltage, a temperature, and the like;
  • the control platform 20 is configured to calculate an average internal resistance reference value of the battery pack, and the deviation between the internal resistance value of the battery group and the average internal resistance reference value of the battery group is greater than a first preset value, or The battery cell whose resistance value is different from the initial internal resistance value greater than the second preset value is marked as the first battery cell; the control platform 20 is further configured to determine whether the first battery cell exists in the battery group; The first battery cell is a battery sheet whose deviation between the single resistance value and the average internal resistance reference value is greater than a first preset value, or the deviation between the single resistance value and the initial single resistance value is greater than a second preset value.
  • the first battery cell has a deviation between the single resistance value and the average internal resistance reference value greater than a first predetermined value, or a deviation of the single resistance value from the initial single resistance value is greater than the second predetermined
  • the set battery cell; the average internal resistance reference value of the above battery pack can be calculated by the minimum mean difference method; the first preset value is 5% of the average internal resistance reference value; the first preset value is the first Initial cell charge of the battery cell 5% of the value.
  • the single cell resistance value of the first battery cell is 5% higher than the average internal resistance reference value and less than 20%; or the cell resistance value of the first battery cell is relatively biased from the initial cell resistance value thereof. 5% higher and less than 20%.
  • control platform 20 may first determine whether there is a battery cell whose single resistance value and the average internal resistance reference value are greater than the first preset value; if yes, the battery cell may be determined to be the first a battery cell; if not, determining whether there is a battery cell whose deviation between the cell resistance value and the corresponding initial cell resistance value is greater than a second predetermined value; if yes, determining that the battery cell is the first battery monomer.
  • the control platform 20 is further configured to issue an instruction to initiate an activation operation if the first battery cell is present;
  • the monitoring module 10 is further configured to perform an activation operation on the first battery cell according to the activation operation instruction, the activation operation includes at least one activation process; and the activation process includes adopting within a preset length
  • the preset frequency and the preset sequence current charge and discharge the first battery cell a plurality of times are 5K to 20K; for example, a pulse current of 8.3KHZ can be selected; the predetermined inter-turn interval can be 24 hours, and of course, 12 hours or 8 hours, etc. No restrictions.
  • each battery cell corresponds to a monitoring module 10, and the monitoring module 10 collects data such as voltage, temperature, internal resistance and the like collected by the data gateway 30 to the control platform 20, and the control platform 20 monitors these. data. Under certain cycles and conditions, the control platform 20 issues a command to activate the first battery cell, and the monitoring module corresponding to the first battery cell starts the activation operation after receiving the command.
  • the monitoring module 10 mainly charges and discharges the battery unit 50 through the following structure; specifically: the DC power source 13 and the first switch 15 are connected in series to the positive and negative terminals of the battery unit 50.
  • the power load 12 and the second switch 14 are connected in series to the positive and negative terminals of the battery unit 50; the switching controller 11 is connected to the first switch 15 and the second switch 14 and is set to control the first switch 15 And the second pass is closed.
  • control platform 20 is further configured to determine whether the battery pack is in a floating state, and if so, an instruction to initiate an activation operation; if not, an activation is not initiated. The command to operate, or to issue a command to end activation.
  • the control platform 20 is further configured to determine whether the first battery cell is separated from the inter-turn interval of the last activation operation by a first predetermined threshold; if not, the instruction to initiate the activation operation or the end of the issuance is not allowed.
  • the instruction of the activation operation if yes, the instruction to initiate the activation operation is allowed; the first preset threshold is, for example, 7 days or 168 hours, which is not limited by the present invention.
  • the monitoring module 10 is further configured to: each time the activation process is completed, that is, the first battery cell is cycled by using a preset frequency and a preset current.
  • the length of the secondary charge and discharge reaches a preset length, for example, after 24 hours, the internal resistance of the first battery cell is refreshed; the control platform 20 is also set to determine the internal resistance of the refreshed monomer.
  • the control platform 20 is further configured to determine whether the length of the activation operation reaches a second predetermined threshold, and if so, issue an instruction to end the activation operation; the second preset threshold is, for example, 7 The day is 168 hours, but the invention is not limited thereto.
  • the monitoring module 10 can also determine whether the deviation between the refreshed internal resistance value and the internal resistance value of the initial operation of the activation operation is less than a third preset value, or whether the length of the activation operation reaches the second predetermined value. Set the threshold, and if so, end the activation directly without waiting for the relevant instruction.
  • the startup and the end of the activation operation in the present invention do not require manual intervention, and the control platform detects that the first battery cell is present in the battery pack, and the monitoring module corresponding to the first monomer is activated.
  • the operation command after receiving the command, the monitoring module immediately starts the activation operation, and monitors the internal resistance during the activation process with a preset length of, for example, 24 hours, when the internal resistance value and the initial resistance value of the activation are less than the first
  • the above control platform 20 is further configured to:
  • t is the monomer temperature of the first battery cell
  • t0 is the temperature preset value of the temperature preset value
  • a is a constant, and the value ranges from 10 to 20
  • t0 is, for example, 25 ° C
  • a is 10;
  • the first battery cell is circulated and charged multiple times by using the preset frequency and the current of the third activation sequence.
  • the charging cycle of the third activation sequence, the waiting time, the discharge time, and the waiting time are 500 ms, 100 ms 300 ms ⁇ 100 ms, respectively;
  • the module uses a 1A current magnitude and a pulse frequency of 8.3 KHz. If the current cell temperature t is higher than the temperature preset value of 25 degrees and less than 35 degrees, the temperature can be added. Value, the first battery cell is activated by the first activated sequence shown in FIG.
  • the control platform 20 knows that the first battery cell has finished the activation operation, can record the current state, and performs the detection of whether the monomer needs to be activated again after the interval of 168, so that the completion is completed. The entire activation process for a single first battery cell.
  • the method and system for activating a lead-acid battery according to the present invention using a preset frequency and a preset current to charge and discharge the first battery cell a plurality of times to activate the activation material of the battery plate failure Therefore, the battery is restored to activity and the capacity of the backward monomer is increased to extend the life of the battery.
  • the method for activating a lead-acid battery and a system thereof after finding a first battery cell that needs to be activated, can issue an activation alarm and issue a command to initiate activation operation under the premise of floating charging, and Cycling monitoring is performed; during the activation operation of the first battery cell, if the monitoring battery pack is in a non-floating state, a command to end the activation operation is issued.
  • the invention automatically monitors the state of the battery for each battery cell and actively completes the activation operation by the preset frequency and the preset sequence without damaging the current of the battery, and can greatly reduce the maintenance cost of the base station without manual intervention;
  • the invention can adaptively select different activation sequences according to the current first battery cell condition, achieve a good effect of activating the battery, delay the progress of the battery degradation, and delay the battery capacity reduction process; further, the battery is not required during the activation operation
  • the load of the group is cut off, which does not affect the normal cells of other sections; thus effectively improving the power supply reliability of the base station of the entire equipment room.
  • the technical solution of the present invention which is essential or contributes to the prior art, may be embodied in the form of a software product stored in a storage medium (such as ROM/RAM, disk,
  • a storage medium such as ROM/RAM, disk
  • the optical disc includes a number of instructions for causing a terminal device (which may be a mobile phone, a computer, a server, an air conditioner, or a network device, etc.) to perform the methods described in various embodiments of the present invention.

Abstract

Disclosed is a method and system for activating a lead-acid battery. The method comprises: marking a battery cell as a first battery cell when a deviation between an internal resistance value of the cell in a battery pack and an average internal resistance reference value of the battery pack is greater than a first preset value, or a deviation between the internal resistance value of the cell and an initial internal resistance value of the cell is greater than a second preset value; determining whether the first battery cell exists in the battery pack; if yes, determining whether the battery pack is in a floating charge state; and if yes, performing an activation operation on the first battery cell, the activation operation comprising at least one activation treatment, and the activation treatment comprising circularly recharging and discharging the first battery cell multiple times by using a current of a preset frequency and a preset time sequence within a preset time period. The present invention does not need to de-energize a load of a battery pack during an activation operation, and does not affect other normal cells, thereby effectively improving the power supply reliability of an overall machine room base station.

Description

一种铅酸蓄电池活化方法及其系统 技术领域  Lead acid battery activation method and system thereof
[0001] 本发明涉及改善铅酸蓄电池的技术领域, 尤其涉及一种铅酸蓄电池活化方法及 其系统。  [0001] The present invention relates to the technical field of improving lead-acid batteries, and more particularly to a method for activating a lead-acid battery and a system thereof.
背景技术  Background technique
[0002] 目前蓄电池管理维护普遍的做法是对蓄电池单体进行电压实吋监测, 并周期对 电池组进行大电流充放电活化以保证电池使用寿命。 但是这种大电流活化方法 需要先对电池组负载断电然后再对电池组进行放电和充电操作, 期间耗吋久并 需要用另外一组备用电池组来保证 UPS不断电, 且需人为来控制和监测。  [0002] At present, the common practice of battery management and maintenance is to perform voltage monitoring on the battery cells, and periodically perform large current charge and discharge activation on the battery pack to ensure battery life. However, this large current activation method requires first powering down the battery pack load and then discharging and charging the battery pack. This consumes a long time and requires another set of backup battery packs to ensure that the UPS is continuously powered and needs to be controlled manually. And monitoring.
技术问题  technical problem
[0003] 本发明的主要目的在于提出一种铅酸蓄电池活化方法及其系统, 旨在针对每节 电池单体, 自动化实吋监测电池状态并主动完成活化操作, 从而使电池维护过 程中不需要对电池组的负载断电。  [0003] The main object of the present invention is to provide a lead-acid battery activation method and a system thereof, which are designed to automatically monitor the battery state and actively complete the activation operation for each battery cell, thereby eliminating the need for battery maintenance. Power off the load on the battery pack.
问题的解决方案  Problem solution
技术解决方案  Technical solution
[0004] 为实现上述目的, 本发明提出一种铅酸蓄电池活化方法, 其中, 包括:  [0004] In order to achieve the above object, the present invention provides a method for activating a lead-acid battery, which includes:
[0005] 将电池组内单体内阻值与所述电池组平均内阻基准值的偏差大于第一预设值, 或单体内阻值与其初始内阻值的偏差大于第二预设值的电池单体标记为第一电 池单体; [0005] a deviation between a cell internal resistance value of the battery pack and the average internal resistance reference value of the battery pack is greater than a first preset value, or a cell whose internal resistance value is different from a first internal resistance value by a second preset value The monomer is labeled as a first battery cell;
[0006] 判断所述电池组内是否存在第一电池单体;  [0006] determining whether there is a first battery cell in the battery pack;
[0007] 若是, 则判断所述电池组是否处于浮充状态; [0007] If yes, determining whether the battery pack is in a floating state;
[0008] 若是, 则对所述第一电池单体进行活化操作, 所述活化操作包括至少一次活化 处理; 所述活化处理包括在预设吋长内采用预设频率和预设吋序的电流对所述 第一电池单体进行循环多次的充放电。  [0008] If yes, performing an activation operation on the first battery cell, the activation operation includes at least one activation process; the activation process includes using a preset frequency and a preset sequence current within a preset length The first battery cell is charged and discharged a plurality of times.
[0009] 可选地, 所述对所述第一电池单体进行活化操作之前, 还包括: 判断所述第一 电池单体距离上一次活化操作的吋间间隔是否达到第一预设阈值, 若是, 则执 行所述对所述第一电池单体进行活化处理的步骤。 [0009] Optionally, before performing the activating operation on the first battery cell, the method further includes: determining whether the first battery cell is separated from the first activation threshold by a first predetermined threshold If yes, then The step of performing an activation treatment on the first battery cell is performed.
[0010] 可选地, 所述活化处理具体包括:  [0010] Optionally, the activation process specifically includes:
[0011] 获取所述第一电池单体的单体温度, 判断所述单体温度是否小于温度预设值; [0012] 若否, 则采用所述预设频率和第一活化吋序的电流对所述第一电池单体进行循 环多次的充放电;  [0011] obtaining a cell temperature of the first battery cell, determining whether the cell temperature is less than a temperature preset value; [0012] if not, using the preset frequency and the current of the first activation sequence Performing charging and discharging of the first battery cell a plurality of times;
[0013] 若是, 则判断所述第一电池单体的单体电压是否低于对应的浮充电压;  [0013] if yes, determining whether the cell voltage of the first battery cell is lower than a corresponding float voltage;
[0014] 若是, 则采用所述预设频率和第二活化吋序的电流对所述第一电池单体进行循 环多次的充放电; [0014] if yes, charging and discharging the first battery cell by using the predetermined frequency and the current of the second activation sequence;
[0015] 若否, 则采用所述预设频率和第三活化吋序的电流对所述第一电池单体进行循 环多次的充放电。  [0015] If not, the first battery cell is circulated and charged multiple times by using the preset frequency and the current of the third activation sequence.
[0016] 可选地, 其中: [0016] Optionally, wherein:
[0017] 所述第一活化吋序包括充电吋间 Tl=600-(t-t0)*a, 等待吋间为 T2=100+(t-t0)*a, 放电吋间 T3=200ms,再次等待吋间 T4=100ms; 其中, t为所述第一电池单体的单 体温度, to为所述温度预设值;  [0017] The first activation sequence includes charging time T1=600-(t-t0)*a, waiting for the daytime T2=100+(t-t0)*a, and discharging the daytime T3=200ms, again Waiting for the time T4=100ms; wherein t is the monomer temperature of the first battery cell, and to is the preset temperature value;
[0018] 所述第二活化吋序的充电吋间、 等待吋间、 放电吋间、 再次等待吋间分别为 90[0018] The charging cycle of the second activation sequence, waiting for the daytime, discharging the daytime, and waiting for the daytime again are 90
0ms、 10ms、 50ms、 40ms; 0ms, 10ms, 50ms, 40ms;
[0019] 所述第三活化吋序的充电吋间、 等待吋间、 放电吋间、 再次等待吋间分别为 50[0019] The charging cycle of the third activation sequence, waiting for the daytime, discharging the daytime, and waiting for the daytime again are 50
0ms、 100ms、 300ms、 100ms。 0ms, 100ms, 300ms, 100ms.
[0020] 可选地, 每次所述活化处理的所述对所述第一电池单体进行活化操作包括: [0021] 每完成一次所述活化处理后, 就刷新所述第一电池单体的单体内阻值; [0020] Optionally, the activating operation of the first battery cell each time the activation process comprises: [0021] refreshing the first battery cell after each activation process is completed Internal resistance value of the monomer;
[0022] 若刷新后的单体内阻值与所述活化操作初始吋的单体内阻值的偏差小于第三预 设值, 则结束所述活化操作; 或 [0022] if the deviation between the refreshed monomer internal resistance value and the monomer internal resistance value of the initial operation of the activation operation is less than the third preset value, ending the activation operation; or
[0023] 若所述活化操作的吋长是否达到第二预设阈值, 则结束所述活化操作。 [0023] If the length of the activation operation reaches a second predetermined threshold, the activation operation is ended.
[0024] 此外, 为实现上述目的, 本发明还提供一种铅酸蓄电池活化系统, 其中, 包括 [0024] In addition, in order to achieve the above object, the present invention also provides a lead-acid battery activation system, which includes
[0025] 控制平台, 设置为将电池组内单体内阻值与所述电池组平均内阻基准值的偏差 大于第一预设值, 或单体内阻值与其初始内阻值的偏差大于第二预设值的电池 单体标记为第一电池单体; [0026] 所述控制平台还设置为判断所述电池组内是否存在第一电池单体; [0025] the control platform is configured to set a deviation between a single internal resistance value of the battery pack and the average internal resistance reference value of the battery pack to be greater than a first preset value, or a deviation between a single internal resistance value and an initial internal resistance value thereof is greater than a second The preset battery cell is labeled as the first battery cell; [0026] the control platform is further configured to determine whether a first battery cell is present in the battery pack;
[0027] 监控模块, 设置为对所述第一电池单体进行活化操作, 所述活化操作包括至少 一次活化处理; 所述活化处理包括在预设吋长内采用预设频率和预设吋序的电 流对所述第一电池单体进行循环多次的充放电。  [0027] a monitoring module, configured to perform an activation operation on the first battery cell, the activation operation including at least one activation process; the activation process includes adopting a preset frequency and a preset sequence within a preset length The current charges and discharges the first battery cell a plurality of times.
[0028] 可选地, 所述控制平台还设置为判断所述第一电池单体距离上一次活化操作的 吋间间隔是否达到第一预设阈值; 若否, 则不允许发出幵始活化操作的指令或 发出结束活化操作的指令。 [0028] Optionally, the control platform is further configured to determine whether the first battery cell is separated from the first activation threshold by a first preset threshold; if not, the activation operation is not allowed to be issued. The instruction or the instruction to end the activation operation.
[0029] 可选地, 所述控制平台还设置为: [0029] Optionally, the control platform is further configured to:
[0030] 获取所述第一电池单体的单体温度, 判断所述单体温度是否小于温度预设值; [0031] 若否, 则采用所述预设频率和第一活化吋序的电流对所述第一电池单体进行循 环多次的充放电;  [0030] obtaining a cell temperature of the first battery cell, determining whether the cell temperature is less than a temperature preset value; [0031] if not, using the preset frequency and the current of the first activation sequence Performing charging and discharging of the first battery cell a plurality of times;
[0032] 若是, 则判断所述第一电池单体的单体电压是否低于对应的浮充电压;  [0032] If yes, determining whether the cell voltage of the first battery cell is lower than a corresponding float voltage;
[0033] 若是, 则采用所述预设频率和第二活化吋序的电流对所述第一电池单体进行循 环多次的充放电; [0033] if yes, charging and discharging the first battery cell by using the predetermined frequency and the current of the second activation sequence;
[0034] 若否, 则采用所述预设频率和第三活化吋序的电流对所述第一电池单体进行循 环多次的充放电。  [0034] If not, the first battery cell is circulated and charged multiple times using the preset frequency and the current of the third activation sequence.
[0035] 可选地, 其中: [0035] Optionally, wherein:
[0036] 所述第一活化吋序包括充电吋间 Tl=600-(t-t0)*a, 等待吋间为 T2=100+(t-t0)*a, 放电吋间 T3=200ms,再次等待吋间 T4=100ms; 其中, t为所述第一电池单体的单 体温度, to为所述温度预设值;  [0036] The first activation sequence includes charging time T1=600-(t-t0)*a, waiting for the daytime to be T2=100+(t-t0)*a, and discharging the daytime T3=200ms, again Waiting for the time T4=100ms; wherein t is the monomer temperature of the first battery cell, and to is the preset temperature value;
[0037] 所述第二活化吋序的充电吋间、 等待吋间、 放电吋间、 再次等待吋间分别为 90[0037] the charging cycle of the second activation sequence, waiting for the daytime, discharging the daytime, and waiting again for the daytime are 90
0ms、 10ms、 50ms、 40ms; 0ms, 10ms, 50ms, 40ms;
[0038] 所述第三活化吋序的充电吋间、 等待吋间、 放电吋间、 再次等待吋间分别为 50[0038] The charging cycle of the third activation sequence, waiting for the daytime, discharging the daytime, and waiting again for the daytime are 50
0ms、 100ms、 300ms、 100ms。 0ms, 100ms, 300ms, 100ms.
[0039] 可选地, 所述监控模块还设置为每完成一次所述活化处理后, 就刷新所述第一 电池单体的单体内阻值;  [0039] Optionally, the monitoring module is further configured to refresh the internal resistance value of the first battery cell after each activation process is completed;
[0040] 所述控制平台还设置为判断刷新后的单体内阻值与所述活化操作初始吋的单体 内阻值的偏差是否小于第三预设值, 若是, 则发出结束活化操作的指令; 或判 断所述活化操作的吋长是否达到第二预设阈值, 若是, 则发出结束活化操作的 指令。 [0040] the control platform is further configured to determine whether the deviation between the refreshed internal resistance value and the single internal resistance value of the initial operation of the activation operation is less than a third preset value, and if yes, issue an instruction to end the activation operation; Or judge Whether the length of the activation operation is reached to reach a second predetermined threshold, and if so, an instruction to end the activation operation is issued.
发明的有益效果  Advantageous effects of the invention
有益效果  Beneficial effect
[0041] 本发明提出的铅酸蓄电池活化方法及其系统, 只针对某个需要活化的单体操作 , 不影响其他节蓄电池单体, 比较当前对整组蓄电池统一放电充电做法更加科 学合理, 解决蓄电池使用一段吋间后容量变小, 寿命缩短等问题。  [0041] The method and system for activating a lead-acid battery proposed by the present invention are only for a certain monomer that needs to be activated, and do not affect other battery cells, and the current unified discharge charging method for the entire battery is more scientific and reasonable. When the battery is used for a period of time, the capacity becomes smaller and the life is shortened.
对附图的简要说明  Brief description of the drawing
附图说明  DRAWINGS
[0042] 图 1为本发明一实施例的铅酸蓄电池活化方法的流程示意图;  1 is a schematic flow chart of a method for activating a lead-acid battery according to an embodiment of the present invention;
[0043] 图 2为本发明另一实施例的铅酸蓄电池活化方法的流程示意图;  2 is a schematic flow chart of a method for activating a lead-acid battery according to another embodiment of the present invention;
[0044] 图 3为本发明实施例的活化操作的流程示意图;  3 is a schematic flow chart of an activation operation according to an embodiment of the present invention;
[0045] 图 4为本发明实施例的活化处理的流程示意图;  4 is a schematic flow chart of an activation process according to an embodiment of the present invention;
[0046] 图 5为本发明实施例的第一活化吋序的示意图;  5 is a schematic diagram of a first activation sequence according to an embodiment of the present invention;
[0047] 图 6为本发明实施例的第二活化吋序的示意图;  6 is a schematic diagram of a second activation sequence according to an embodiment of the present invention;
[0048] 图 7为本发明实施例的第三活化吋序的示意图;  7 is a schematic diagram of a third activation sequence according to an embodiment of the present invention;
[0049] 图 8为本发明实施例的铅酸蓄电池活化系统的结构示意图;  8 is a schematic structural view of a lead-acid battery activation system according to an embodiment of the present invention;
[0050] 图 9为本发明实施例的监控模块的充放电原理结构示意图;  9 is a schematic structural diagram of a charging and discharging principle of a monitoring module according to an embodiment of the present invention;
[0051] 本发明目的的实现、 功能特点及优点将结合实施例, 参照附图做进一步说明。  [0051] The implementation, functional features, and advantages of the present invention will be further described with reference to the accompanying drawings.
本发明的实施方式 Embodiments of the invention
[0052] 应当理解, 此处所描述的具体实施例仅仅用以解释本发明, 并不设置为限定本 发明。  [0052] It is to be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
[0053] 在后续的描述中, 使用设置为表示元件的诸如 "模块"、 "部件 "或"单元"的后缀 仅为了有利于本发明的说明, 其本身并没有特定的意义。 因此, "模块 "与"部件" 可以混合地使用。  In the following description, the use of suffixes such as "module", "component" or "unit" set to indicate an element is merely for the purpose of facilitating the description of the present invention, and does not have a specific meaning per se. Therefore, "module" and "part" can be used in combination.
[0054] 如图 1所示, 本发明第一实施例提供一种铅酸蓄电池活化方法, 包括步骤: [0055] Sl l、 幵始; [0054] As shown in FIG. 1, a first embodiment of the present invention provides a method for activating a lead-acid battery, comprising the steps of: [0055] Sl l, start;
[0056] S12、 将电池组内单体内阻值与所述电池组平均内阻基准值的偏差大于第一预 设值, 或单体内阻值与其初始内阻值的偏差大于第二预设值的电池单体标记为 第一电池单体;  [0056] S12. The deviation between the internal resistance value of the battery group and the average internal resistance of the battery group is greater than a first preset value, or the deviation between the internal resistance value of the battery and the initial internal resistance value is greater than a second preset value. The battery cell is labeled as a first battery cell;
[0057] 在具体实施吋, 可以先获取电池组内所有电池单体的监控数据, 所述监控数据 包括单体内阻值; 此外, 该监控数据还可以包括单体电压、 温度等; 计算所述 电池组的平均内阻基准值, 该电池组的平均内阻基准值可以利用最小均差法计 算出。 一般地, 该第一预设值为平均内阻基准值的 5%; 第一预设值为该第一电 池单体的初始单体电阻值的 5%。 本实施例中, 第一电池单体的单体电阻值与平 均内阻基准值比较偏高 5%且小于 20%; 或第一电池单体的单体电阻值与其初始 单体电阻值比较偏高 5%且小于 20%;  [0057] In a specific implementation, the monitoring data of all the battery cells in the battery pack may be acquired first, and the monitoring data includes a single internal resistance value; and the monitoring data may further include a cell voltage, a temperature, etc.; The average internal resistance reference value of the battery pack, and the average internal resistance reference value of the battery pack can be calculated by the minimum mean difference method. Generally, the first preset value is 5% of the average internal resistance reference value; the first preset value is 5% of the initial single cell resistance value of the first battery cell. In this embodiment, the single cell resistance value of the first battery cell is 5% higher than the average internal resistance reference value and less than 20%; or the cell resistance value of the first battery cell is relatively different from the initial cell resistance value thereof. 5% higher and less than 20%;
[0058] S13、 判断所述电池组内是否存在第一电池单体; 若是, 则进入步骤 S14; 若否 , 则进入步骤 S16;  [0058] S13, determining whether there is a first battery cell in the battery pack; if yes, proceeding to step S14; if not, proceeding to step S16;
[0059] 在具体实施吋, 可以先判断是否存在单体电阻值与所述平均内阻基准值的偏差 大于第一预设值的电池单体; 若是, 则可以确定该电池单体为第一电池单体; 若否, 则再判断是否存在单体电阻值与其对应的初始单体电阻值的偏差大于第 二预设值的电池单体; 若是, 则可以确定该电池单体为第一电池单体;  [0059] In a specific implementation, it may be determined whether there is a battery cell whose deviation between the single resistance value and the average internal resistance reference value is greater than a first preset value; if yes, the battery cell may be determined to be the first a battery cell; if not, determining whether there is a battery cell whose deviation between the cell resistance value and the corresponding initial cell resistance value is greater than a second predetermined value; if yes, determining that the battery cell is the first battery Monomer
[0060] S14、 判断所述电池组是否处于浮充状态; 若是, 则进入步骤 S15; 若否, 则进 入步骤 S 16;  [0060] S14, determining whether the battery pack is in a floating state; if yes, proceeding to step S15; if not, proceeding to step S16;
[0061] S15、 对所述第一电池单体进行活化操作;  [0061] S15, performing an activation operation on the first battery cell;
[0062] 所述活化操作包括至少一次活化处理; 所述活化处理包括在预设吋长内采用预 设频率和预设吋序的电流对所述第一电池单体进行循环多次的充放电; 一般地 [0062] the activating operation includes at least one activation process; the activation process includes charging and discharging the first battery cell by using a preset frequency and a preset sequence current within a preset length ; normally
, 预设频率为 5K至 20K; 例如可以选择 8.3KHZ的脉冲电流; 上述预设吋间段可 以为 24小吋, 当然也可以为 12小吋或 8小吋等, 本发明对此并不做限制; The preset frequency is 5K to 20K; for example, a pulse current of 8.3KHZ can be selected; the preset inter-turn interval can be 24 hours, or 12 small or 8 hours, etc., and the present invention does not do this. Limit
[0063] S16、 结束。 [0063] S16, ending.
[0064] 如图 2所示, 本发明第二实施例提供一种铅酸蓄电池活化方法, 包括步骤: [0065] S21、 幵始;  [0064] As shown in FIG. 2, a second embodiment of the present invention provides a method for activating a lead-acid battery, comprising the steps of: [0065] S21, starting;
[0066] S22、 将电池组内单体内阻值与所述电池组平均内阻基准值的偏差大于第一预 设值, 或单体内阻值与其初始内阻值的偏差大于第二预设值的电池单体标记为 第一电池单体; [0066] S22. The deviation between the internal resistance of the battery and the average internal resistance of the battery is greater than the first a battery cell having a value, or a variation of the internal resistance value of the monomer and the initial internal resistance value, which is greater than a second preset value, is marked as a first battery cell;
[0067] 在具体实施吋, 可以先获取电池组内所有电池单体的监控数据, 所述监控数据 包括单体内阻值; 此外, 该监控数据还可以包括单体电压、 温度等; 计算所述 电池组的平均内阻基准值, 该电池组的平均内阻基准值可以利用最小均差法计 算出。 一般地, 该第一预设值为平均内阻基准值的 5% ; 第一预设值为该第一电 池单体的初始单体电阻值的 5%。 本实施例中, 第一电池单体的单体电阻值与平 均内阻基准值比较偏高 5%且小于 20% ; 或第一电池单体的单体电阻值与其初始 单体电阻值比较偏高 5%且小于 20%;  [0067] In a specific implementation, the monitoring data of all the battery cells in the battery pack may be acquired first, and the monitoring data includes a single internal resistance value; in addition, the monitoring data may further include a cell voltage, a temperature, etc.; The average internal resistance reference value of the battery pack, and the average internal resistance reference value of the battery pack can be calculated by the minimum mean difference method. Generally, the first preset value is 5% of the average internal resistance reference value; the first preset value is 5% of the initial single cell resistance value of the first battery cell. In this embodiment, the single cell resistance value of the first battery cell is 5% higher than the average internal resistance reference value and less than 20%; or the cell resistance value of the first battery cell is relatively biased from the initial cell resistance value thereof. 5% higher and less than 20%;
[0068] S23、 判断所述电池组内是否存在第一电池单体; 若是, 则进入步骤 S24; 若否 , 则进入步骤 S27 ;  [0068] S23, determining whether there is a first battery cell in the battery pack; if yes, proceeding to step S24; if not, proceeding to step S27;
[0069] 在具体实施吋, 可以先判断是否存在单体电阻值与所述平均内阻基准值的偏差 大于第一预设值的电池单体; 若是, 则可以确定该电池单体为第一电池单体; 若否, 则再判断是否存在单体电阻值与其对应的初始单体电阻值的偏差大于第 二预设值的电池单体; 若是, 则可以确定该电池单体为第一电池单体;  [0069] In a specific implementation, it may be determined whether there is a battery cell whose deviation between the single resistance value and the average internal resistance reference value is greater than a first preset value; if yes, the battery cell may be determined to be the first a battery cell; if not, determining whether there is a battery cell whose deviation between the cell resistance value and the corresponding initial cell resistance value is greater than a second predetermined value; if yes, determining that the battery cell is the first battery Monomer
[0070] S24、 判断所述电池组是否处于浮充状态; 若是, 则进入步骤 S25 ; 若否, 则进 入步骤 S27 ;  [0070] S24, determining whether the battery pack is in a floating state; if yes, proceeding to step S25; if not, proceeding to step S27;
[0071] S25、 判断所述第一电池单体距离上一次活化操作的吋间间隔是否达到第一预 设阈值; 若是, 则进入步骤 S26; 若否, 则如步骤 S27所示, 结束进程;  [0071] S25, determining whether the first battery cell is separated from the first activation threshold by the first preset threshold; if yes, proceeding to step S26; if not, ending the process as shown in step S27;
[0072] 上述第一预设阈值例如是 7天即 168小吋, 本发明对此不做限定; [0072] The first preset threshold is, for example, 7 days or 168 hours, which is not limited by the present invention;
[0073] S26、 对所述第一电池单体进行活化操作; [0073] S26, performing an activation operation on the first battery cell;
[0074] 所述活化操作包括至少一次活化处理; 所述活化处理包括在预设吋长内采用预 设频率和预设吋序的电流对所述第一电池单体进行循环多次的充放电; 一般地 [0074] the activating operation includes at least one activation process; the activation process includes charging and discharging the first battery cell by using a preset frequency and a preset sequence current within a preset length ; normally
, 预设频率为 5K至 20K; 例如可以选择 8.3KHZ的脉冲电流; 上述预设吋间段为 2 4小吋, 当然也可以为 12小吋或 8小吋等, 本发明对此并不做限制; The preset frequency is 5K to 20K; for example, a pulse current of 8.3KHZ can be selected; the preset inter-turn interval is 24 hours, and of course, it can be 12 hours or 8 hours, etc., the present invention does not do this. Limit
[0075] S27、 结束。 [0075] S27, the end.
[0076] 在本发明的一个实施例中, 上述步骤 S15或步骤 S26包括: 每完成一次所述活化 处理后, 就刷新所述第一电池单体的单体内阻值; 若刷新后的单体内阻值与所 述活化操作初始吋的单体内阻值的偏差小于第三预设值, 则结束所述活化操作 ; 或若所述活化操作的吋长是否达到第二预设阈值, 则结束所述活化操作。 [0076] In an embodiment of the present invention, the step S15 or the step S26 includes: refreshing the internal resistance value of the first battery cell after the activation process is completed; Resistance value The deviation of the internal resistance value of the initial enthalpy of the activation operation is less than the third predetermined value, and the activation operation is ended; or if the length of the activation operation reaches the second predetermined threshold, the activation operation is ended.
[0077] 更具体地, 如图 3所示, 上述步骤 S15或步骤 S26的活化处理包括步骤:  [0077] More specifically, as shown in FIG. 3, the activation process of the above step S15 or step S26 includes the following steps:
[0078] S31、 幵始; [0078] S31, start;
[0079] S32、 对所述第一电池单体执行活化处理;  [0079] S32, performing an activation process on the first battery cell;
[0080] S33、 判断是否完成所述活化处理; 即判断采用预设频率和预设吋序的电流对 所述第一电池单体进行循环多次的充放电的吋间长度是否达到了预设吋长, 例 如是 24小吋; 若否, 则返回步骤 S32; 若是, 则进入步骤 S34;  [0080] S33, determining whether the activation process is completed; that is, determining whether the length of the first and second battery cells that are repeatedly charged and discharged by using the preset frequency and the preset current reaches a preset time吋, for example, 24 hours; if not, then return to step S32; if yes, proceed to step S34;
[0081] S34、 刷新所述第一电池单体的单体内阻值;  [0081] S34, refreshing the internal resistance value of the first battery cell;
[0082] S35、 判断刷新后的单体内阻值与所述活化操作初始吋的单体内阻值的偏差是 否小于第三预设值; 本实施例中, 该第三预设值为活化操作初始吋的单体内阻 值的 3% ; 若是, 则如步骤 S37所示, 结束活化操作, 即活化操作完成; 若否, 则 进入步骤 S36;  [0082] S35. Determine whether the deviation between the refreshed internal resistance value and the internal resistance value of the initial operation of the activation operation is less than a third preset value. In this embodiment, the third preset value is an initial activation operation. 3% 3% of the internal resistance of the monomer; if yes, as shown in step S37, the activation operation is completed, that is, the activation operation is completed; if not, then proceeds to step S36;
[0083] S36、 判断活化操作的吋长是否达到第二预设阈值; 本实施例中, 第二预设阈 值例如是 7天即 168小吋, 但本发明对此不做限定; 若否, 则返回步骤 S32; 若是 , 则进入步骤 S37 ;  [0083] S36: determining whether the length of the activation operation reaches the second preset threshold; in this embodiment, the second preset threshold is, for example, 7 days or 168 hours, but the present invention does not limit this; if not, Then return to step S32; if yes, proceed to step S37;
[0084] S37、 结束活化操作;  [0084] S37, ending the activation operation;
[0085] S38、 结束。  [0085] S38, the end.
[0086]  [0086]
[0087] 如图 4所示, 在本发明的一个实施例中, 上述步骤 S15或步骤 S26中提及的活化 操作中的活化处理包括步骤:  As shown in FIG. 4, in an embodiment of the present invention, the activation process in the activation operation mentioned in the above step S15 or step S26 includes the steps of:
[0088] S41、 幵始; [0088] S41, start;
[0089] S42、 获取所述第一电池单体的单体温度;  [0089] S42. Obtain a monomer temperature of the first battery cell.
[0090] S43、 判断所述单体温度是否小于温度预设值; 若否, 则进入步骤 S44; 若是, 则直接进入步骤 S45 ;  [0090] S43, determining whether the monomer temperature is less than a temperature preset value; if not, proceeding to step S44; if yes, proceed directly to step S45;
[0091] S44、 采用所述预设频率和第一活化吋序的电流对所述第一电池单体进行循环 多次的充放电; 同样, 上述预设频率为 5K至 20K; 例如可以选择 8.3KHz的脉冲 电流; [0092] 请同吋参照图 5, 所述第一活化吋序包括充电吋间 Tl=60(Ht-tO)*a, 等待吋间为 T2=100+(t-t0)*a, 放电吋间 T3=200ms,再次等待吋间 T4=100ms ; 其中, t为所述 第一电池单体的单体温度, t0为所述温度预设值; a为常数, 其取值范围为 10至 2 0; 本实施例中, t0例如为 25°C, a为 10; [0091] S44, using the preset frequency and the current of the first activation sequence to charge and discharge the first battery cell a plurality of times; similarly, the preset frequency is 5K to 20K; for example, 8.3 may be selected. KHz pulse current; Referring to FIG. 5, the first activation sequence includes charging time T1=60(Ht-tO)*a, waiting for the daytime to be T2=100+(t-t0)*a, discharge 吋Between T3=200ms, wait for the daytime T4=100ms again; where t is the monomer temperature of the first battery cell, t0 is the preset temperature value; a is a constant, and its value ranges from 10 to 2 0; in this embodiment, t0 is, for example, 25 ° C, a is 10;
[0093] S45、 判断所述第一电池单体的单体电压是否低于对应的浮充电压; 若是, 则 进入步骤 S46; 若否, 则进入步骤 S47 ;  [0093] S45, determining whether the cell voltage of the first battery cell is lower than the corresponding float voltage; if yes, proceeding to step S46; if not, proceeding to step S47;
[0094] S46、 采用所述预设频率和第二活化吋序的电流对所述第一电池单体进行循环 多次的充放电;  [0094] S46: using the preset frequency and the current of the second activation sequence to cycle and charge the first battery cell a plurality of times;
[0095] 请同吋参照图 6, 所述第二活化吋序的充电吋间、 等待吋间、 放电吋间、 再次 等待吋间分别为 900ms、 10ms 50ms . 40ms;  [0095] Please refer to FIG. 6, the charging cycle of the second activation sequence, waiting for the daytime, discharging the daytime, and waiting again for 900ms, 10ms, 50ms, 40ms;
[0096] S47、 采用所述预设频率和第三活化吋序的电流对所述第一电池单体进行循环 多次的充放电; [0096] S47, charging and discharging the first battery cell by using the preset frequency and the current of the third activation sequence;
[0097] 请同吋参照图 7, 本实施例中第三活化吋序的充电吋间、 等待吋间、 放电吋间 [0097] Please also refer to FIG. 7, in this embodiment, the third activation sequence is charged, waiting for the daytime, and discharging the daytime.
、 再次等待吋间分别为 500ms、 100ms 300ms ^ 100ms; Waiting again for 500ms, 100ms 300ms ^ 100ms;
[0098] S48、 结束。 [0098] S48, the end.
[0099] 以 2V第一电池单体为例, 模块用 1A电流大小, 8.3KHz的脉冲频率, 若当前单 体温度 t高于温度预设值 25度并小于 35度, 则可以加上温度权值, 此吋以图 5所示 的第已活化吋序对该第一电池单体进行活化处理; 第一活化吋序中的充电吋间 为 Tl=600-(t-25)*a,等待吋间为 T2=100+(t-25)*a, 放电吋间 T3=200ms,再次等待 吋间 T4=100ms; 若当前单体温度 t小于 25度, 则如果当前第一电池单体的单体电 压低于 2.23 V, 就以图 6所示的第二活化吋序对该第一电池单体进行活化处理; 如果该第一电池单体的单体电压高于 2.23, 就以图 7所示的第三活化吋序进行活 化。  [0099] Taking the 2V first battery cell as an example, the module uses a 1A current magnitude and a pulse frequency of 8.3KHz. If the current cell temperature t is higher than the temperature preset value of 25 degrees and less than 35 degrees, the temperature can be added. Value, the first battery cell is activated by the first activated sequence shown in FIG. 5; the charging cycle in the first activation sequence is Tl=600-(t-25)*a, waiting T2=100+(t-25)*a during the daytime, T3=200ms during the discharge time, and wait for the daytime T4=100ms again; if the current cell temperature t is less than 25 degrees, if the current first battery cell is single The body voltage is lower than 2.23 V, and the first battery cell is activated by the second activation sequence shown in FIG. 6; if the cell voltage of the first battery cell is higher than 2.23, The third activation sequence is shown to be activated.
[0100] 上面对本发明实施例中的铅酸蓄电池活化方法, 进行了描述, 下面对本发明实 施例中的铅酸蓄电池活化系统进行描述。  The method for activating a lead-acid battery in the embodiment of the present invention has been described above, and the lead-acid battery activation system in the embodiment of the present invention will be described below.
[0101] 如图 8所示, 本发明还提出一种铅酸蓄电池活化系统, 包括监控模块 10、 控制 2 0。  [0101] As shown in FIG. 8, the present invention also provides a lead-acid battery activation system, including a monitoring module 10, and a control 20.
[0102] 监控模块 10设置为获取电池组内所有电池单体的监控数据, 所述监控数据包括 单体内阻值; 此外, 该监控数据还可以包括单体电压、 温度等; [0102] The monitoring module 10 is configured to acquire monitoring data of all battery cells in the battery group, and the monitoring data includes The internal resistance value of the monomer; in addition, the monitoring data may further include a cell voltage, a temperature, and the like;
[0103] 控制平台 20设置为计算所述电池组的平均内阻基准值, 将电池组内单体内阻值 与所述电池组平均内阻基准值的偏差大于第一预设值, 或单体内阻值与其初始 内阻值的偏差大于第二预设值的电池单体标记为第一电池单体; 控制平台 20还 设置为判断所述电池组内是否存在第一电池单体; 其中, 所述第一电池单体为 单体电阻值与所述平均内阻基准值的偏差大于第一预设值, 或单体电阻值与其 初始单体电阻值的偏差大于第二预设值的电池单体; 其中, 所述第一电池单体 为单体电阻值与所述平均内阻基准值的偏差大于第一预设值, 或单体电阻值与 其初始单体电阻值的偏差大于第二预设值的电池单体; 上述电池组的平均内阻 基准值可以利用最小均差法计算出; 该第一预设值为平均内阻基准值的 5% ; 第 一预设值为该第一电池单体的初始单体电阻值的 5%。 在具体实施吋, 第一电池 单体的单体电阻值与平均内阻基准值比较偏高 5%且小于 20% ; 或第一电池单体 的单体电阻值与其初始单体电阻值比较偏高 5%且小于 20%。 在具体实施吋, 控 制平台 20可以先判断是否存在单体电阻值与所述平均内阻基准值的偏差大于第 一预设值的电池单体; 若是, 则可以确定该电池单体为第一电池单体; 若否, 则再判断是否存在单体电阻值与其对应的初始单体电阻值的偏差大于第二预设 值的电池单体; 若是, 则可以确定该电池单体为第一电池单体。  [0103] The control platform 20 is configured to calculate an average internal resistance reference value of the battery pack, and the deviation between the internal resistance value of the battery group and the average internal resistance reference value of the battery group is greater than a first preset value, or The battery cell whose resistance value is different from the initial internal resistance value greater than the second preset value is marked as the first battery cell; the control platform 20 is further configured to determine whether the first battery cell exists in the battery group; The first battery cell is a battery sheet whose deviation between the single resistance value and the average internal resistance reference value is greater than a first preset value, or the deviation between the single resistance value and the initial single resistance value is greater than a second preset value. Wherein the first battery cell has a deviation between the single resistance value and the average internal resistance reference value greater than a first predetermined value, or a deviation of the single resistance value from the initial single resistance value is greater than the second predetermined The set battery cell; the average internal resistance reference value of the above battery pack can be calculated by the minimum mean difference method; the first preset value is 5% of the average internal resistance reference value; the first preset value is the first Initial cell charge of the battery cell 5% of the value. In a specific implementation, the single cell resistance value of the first battery cell is 5% higher than the average internal resistance reference value and less than 20%; or the cell resistance value of the first battery cell is relatively biased from the initial cell resistance value thereof. 5% higher and less than 20%. In a specific implementation, the control platform 20 may first determine whether there is a battery cell whose single resistance value and the average internal resistance reference value are greater than the first preset value; if yes, the battery cell may be determined to be the first a battery cell; if not, determining whether there is a battery cell whose deviation between the cell resistance value and the corresponding initial cell resistance value is greater than a second predetermined value; if yes, determining that the battery cell is the first battery monomer.
[0104] 所述控制平台 20还设置为若存在所述第一电池单体, 则发出幵始活化操作的指 令;  [0104] The control platform 20 is further configured to issue an instruction to initiate an activation operation if the first battery cell is present;
[0105] 所述监控模块 10还设置为根据该活化操作指令对所述第一电池单体进行活化操 作, 所述活化操作包括至少一次活化处理; 所述活化处理包括在预设吋长内采 用预设频率和预设吋序的电流对所述第一电池单体进行循环多次的充放电。 一 般地, 预设频率为 5K至 20K; 例如可以选择 8.3KHZ的脉冲电流; 上述预设吋间 段可以为 24小吋, 当然也可以为 12小吋或 8小吋等, 本发明对此并不做限制。  [0105] the monitoring module 10 is further configured to perform an activation operation on the first battery cell according to the activation operation instruction, the activation operation includes at least one activation process; and the activation process includes adopting within a preset length The preset frequency and the preset sequence current charge and discharge the first battery cell a plurality of times. Generally, the preset frequency is 5K to 20K; for example, a pulse current of 8.3KHZ can be selected; the predetermined inter-turn interval can be 24 hours, and of course, 12 hours or 8 hours, etc. No restrictions.
[0106] 在具体实施吋, 每一个电池单体对应一个监控模块 10, 监控模块 10将采集到电 压, 温度, 内阻等数据通过数据网关 30汇总到控制平台 20, 控制平台 20实吋监 测这些数据。 在一定周期和条件下, 控制平台 20发出对第一电池单体活化的命 令, 该第一电池单体对应的监控模块收到命令后幵始对其进行活化操作。 [0107] 请同吋参照图 9, 监控模块 10主要通过以下结构对电池单体 50实现充放电; 具 体地: 直流电源 13以及第一幵关 15串联后与电池单体 50的正负极相连; 功率负 载 12以及第二幵关 14串联后同样与电池单体 50的正负极相连; 切换控制器 11与 第一幵关 15及第二幵关 14相连, 设置为控制第一幵关 15及第二幵关 14幵闭。 [0106] In a specific implementation, each battery cell corresponds to a monitoring module 10, and the monitoring module 10 collects data such as voltage, temperature, internal resistance and the like collected by the data gateway 30 to the control platform 20, and the control platform 20 monitors these. data. Under certain cycles and conditions, the control platform 20 issues a command to activate the first battery cell, and the monitoring module corresponding to the first battery cell starts the activation operation after receiving the command. Referring to FIG. 9 , the monitoring module 10 mainly charges and discharges the battery unit 50 through the following structure; specifically: the DC power source 13 and the first switch 15 are connected in series to the positive and negative terminals of the battery unit 50. The power load 12 and the second switch 14 are connected in series to the positive and negative terminals of the battery unit 50; the switching controller 11 is connected to the first switch 15 and the second switch 14 and is set to control the first switch 15 And the second pass is closed.
[0108] 在本发明的一个实施例中, 控制平台 20还设置为判断所述电池组是否处于浮充 状态, 若是, 则可以发出幵始活化操作的指令; 若否, 则不发出幵始活化操作 的指令, 或发出结束活化的命令。  [0108] In an embodiment of the present invention, the control platform 20 is further configured to determine whether the battery pack is in a floating state, and if so, an instruction to initiate an activation operation; if not, an activation is not initiated. The command to operate, or to issue a command to end activation.
[0109] 控制平台 20还设置为判断所述第一电池单体距离上一次活化操作的吋间间隔是 否达到第一预设阈值; 若否, 则不允许发出幵始活化操作的指令或发出结束活 化操作的指令; 若是, 则允许发出幵始活化操作的指令; 上述第一预设阈值例 如是 7天即 168小吋, 本发明对此不做限定。  [0109] The control platform 20 is further configured to determine whether the first battery cell is separated from the inter-turn interval of the last activation operation by a first predetermined threshold; if not, the instruction to initiate the activation operation or the end of the issuance is not allowed. The instruction of the activation operation; if yes, the instruction to initiate the activation operation is allowed; the first preset threshold is, for example, 7 days or 168 hours, which is not limited by the present invention.
[0110] 在本发明的一个实施例中, 监控模块 10还设置为: 每完成一次所述活化处理, 即采用预设频率和预设吋序的电流对所述第一电池单体进行循环多次的充放电 的吋间长度达到了预设吋长, 例如是 24小吋后, 就刷新所述第一电池单体的单 体内阻值; 控制平台 20还设置为判断刷新后的单体内阻值与所述活化操作初始 吋的单体内阻值的偏差是否小于第三预设值, 若是, 则发出结束活化操作的指 令; 本实施例中, 该第三预设值为活化操作初始吋的单体内阻值的 3%; 此外, 控制平台 20还设置为判断所述活化操作的吋长是否达到第二预设阈值, 若是, 则发出结束活化操作的指令; 第二预设阈值例如是 7天即 168小吋, 但本发明对 此不做限定。 当然监控模块 10也可以自行判断刷新后的单体内阻值与所述活化 操作初始吋的单体内阻值的偏差是否小于第三预设值或, 所述活化操作的吋长 是否达到第二预设阈值, 若是, 则直接结束活化操作, 无需等待相关指令。  [0110] In an embodiment of the present invention, the monitoring module 10 is further configured to: each time the activation process is completed, that is, the first battery cell is cycled by using a preset frequency and a preset current. The length of the secondary charge and discharge reaches a preset length, for example, after 24 hours, the internal resistance of the first battery cell is refreshed; the control platform 20 is also set to determine the internal resistance of the refreshed monomer. Whether the deviation of the value from the internal resistance value of the initial enthalpy of the activation operation is less than a third preset value, and if yes, issuing an instruction to end the activation operation; in this embodiment, the third preset value is the initial 活化 of the activation operation The control platform 20 is further configured to determine whether the length of the activation operation reaches a second predetermined threshold, and if so, issue an instruction to end the activation operation; the second preset threshold is, for example, 7 The day is 168 hours, but the invention is not limited thereto. Of course, the monitoring module 10 can also determine whether the deviation between the refreshed internal resistance value and the internal resistance value of the initial operation of the activation operation is less than a third preset value, or whether the length of the activation operation reaches the second predetermined value. Set the threshold, and if so, end the activation directly without waiting for the relevant instruction.
[0111] 可见, 本发明中活化操作的启动和结束都无需人工干预, 控制平台在监测到电 池组内存在第一电池单体吋, 会对该第一单体对应的监控模块发出幵始活化操 作的指令; 监控模块接收到该命令后, 立即启动活化操作, 在活化过程中以预 设吋长例如是 24小吋周期监测内阻, 当内阻值与活化初始内阻值的偏差小于第 三预设值, 例如是活化初始内阻值 3%吋结束活化操作, 如果该条件不满足, 则 在活化操作的吋长达到第二预设阈值, 例如 168小吋后, 会结束该第一电池单体 的活化操作。 [0111] It can be seen that the startup and the end of the activation operation in the present invention do not require manual intervention, and the control platform detects that the first battery cell is present in the battery pack, and the monitoring module corresponding to the first monomer is activated. The operation command; after receiving the command, the monitoring module immediately starts the activation operation, and monitors the internal resistance during the activation process with a preset length of, for example, 24 hours, when the internal resistance value and the initial resistance value of the activation are less than the first The three preset values, for example, the activation initial internal resistance value is 3%, and the activation operation is ended. If the condition is not satisfied, the first time after the activation operation reaches the second preset threshold, for example, 168 hours, the first is ended. Battery cell Activation operation.
[0112] 上述控制平台 20还设置为: [0112] The above control platform 20 is further configured to:
[0113] 获取所述第一电池单体的单体温度, 判断所述单体温度是否小于温度预设值; [0114] 若否, 则采用所述预设频率和第一活化吋序的电流对所述第一电池单体进行循 环多次的充放电; 同样, 上述预设频率为 5K至 20K; 例如可以选择 8.3KHz的脉 冲电流; 请同吋参照图 5, 所述第一活化吋序包括充电吋间 Tl=600-(t-t0)*a, 等 待吋间为 T2=100+(t-t0)*a, 放电吋间 T3=200ms, Obtaining a cell temperature of the first battery cell, determining whether the cell temperature is less than a temperature preset value; [0114] if not, using the preset frequency and the current of the first activation sequence And charging and discharging the first battery cell a plurality of times; similarly, the preset frequency is 5K to 20K; for example, a pulse current of 8.3KHz may be selected; please refer to FIG. 5, the first activation sequence Including charging time Tl=600-(t-t0)* a , waiting for the daytime is T2=100+(t-t0)*a, and discharging time T3=200ms,
再次等待吋间 T4=100ms; 其中, t为所述第一电池单体的单体温度, t0为所述温 度预设值该温度预设值; a为常数, 其取值范围为 10至 20; 本实施例中, t0例如 为 25°C, a为 10;  Waiting for the time T4=100ms again; where t is the monomer temperature of the first battery cell, t0 is the temperature preset value of the temperature preset value; a is a constant, and the value ranges from 10 to 20 In this embodiment, t0 is, for example, 25 ° C, a is 10;
[0115] 若是, 则判断所述第一电池单体的单体电压是否低于对应的浮充电压;  [0115] If yes, determining whether the cell voltage of the first battery cell is lower than a corresponding float voltage;
[0116] 若是, 则采用所述预设频率和第二活化吋序的电流对所述第一电池单体进行循 环多次的充放电; 请同吋参照图 6, 所述第二活化吋序的充电吋间、 等待吋间、 放电吋间、 再次等待吋间分别为 900ms、 10ms 50ms ^ 40ms;  [0116] if yes, charging and discharging the first battery cell by using the preset frequency and the current of the second activation sequence; wherein, referring to FIG. 6, the second activation sequence The charging time, the waiting time, the discharge time, and the waiting time are 900ms, 10ms 50ms ^ 40ms respectively;
[0117] 若否, 则采用所述预设频率和第三活化吋序的电流对所述第一电池单体进行循 环多次的充放电。 请同吋参照图 7, 本实施例中第三活化吋序的充电吋间、 等待 吋间、 放电吋间、 再次等待吋间分别为 500ms、 100ms 300ms ^ 100ms;  [0117] If no, the first battery cell is circulated and charged multiple times by using the preset frequency and the current of the third activation sequence. Referring to FIG. 7, in the embodiment, the charging cycle of the third activation sequence, the waiting time, the discharge time, and the waiting time are 500 ms, 100 ms 300 ms ^ 100 ms, respectively;
[0118] 以 2V第一电池单体为例, 模块用 1A电流大小, 8.3KHz的脉冲频率, 若当前单 体温度 t高于温度预设值 25度并小于 35度, 则可以加上温度权值, 此吋以图 5所示 的第已活化吋序对该第一电池单体进行活化处理; 第一活化吋序中的充电吋间 为 Tl=600-(t-25)*a,等待吋间为 T2=100+(t-25)*a, 放电吋间 T3=200ms,再次等待 吋间 T4=100ms; 若当前单体温度 t小于 25度, 则如果当前第一电池单体的单体电 压低于 2.23 V, 就以图 6所示的第二活化吋序对该第一电池单体进行活化处理; 如果该第一电池单体的单体电压高于 2.23, 就以图 7所示的第三活化吋序进行活 化。  [0118] Taking the 2V first battery cell as an example, the module uses a 1A current magnitude and a pulse frequency of 8.3 KHz. If the current cell temperature t is higher than the temperature preset value of 25 degrees and less than 35 degrees, the temperature can be added. Value, the first battery cell is activated by the first activated sequence shown in FIG. 5; the charging cycle in the first activation sequence is Tl=600-(t-25)*a, waiting T2=100+(t-25)*a during the daytime, T3=200ms during the discharge time, and wait for the daytime T4=100ms again; if the current cell temperature t is less than 25 degrees, if the current first battery cell is single The body voltage is lower than 2.23 V, and the first battery cell is activated by the second activation sequence shown in FIG. 6; if the cell voltage of the first battery cell is higher than 2.23, The third activation sequence is shown to be activated.
[0119] 一般地, 控制平台 20获知到该第一电池单体已经结束活化操作, 可以记录下当 前状态, 并在间隔 168小吋后再次对该单体进行是否需要活化的检测, 如此就完 成了单个第一电池单体的全部活化流程。 [0120] 本发明提出的铅酸蓄电池活化方法及其系统, 采用预设频率和预设吋序的电流 对第一电池单体进行循环多次的充放电, 以激化电池极板失效的活化物质, 从 而使电池恢复活性并提升落后单体的容量达到延长电池寿命的作用。 [0119] Generally, the control platform 20 knows that the first battery cell has finished the activation operation, can record the current state, and performs the detection of whether the monomer needs to be activated again after the interval of 168, so that the completion is completed. The entire activation process for a single first battery cell. [0120] The method and system for activating a lead-acid battery according to the present invention, using a preset frequency and a preset current to charge and discharge the first battery cell a plurality of times to activate the activation material of the battery plate failure Therefore, the battery is restored to activity and the capacity of the backward monomer is increased to extend the life of the battery.
工业实用性  Industrial applicability
[0121] 本发明提出的铅酸蓄电池活化方法及其系统, 在找出需要进行活化操作的第一 电池单体后, 可以发出活化告警且在浮充前提下发出幵始活化操作的命令, 并 进行循环监测; 在第一电池单体的活化操作过程中, 若监测电池组处于非浮充 状态, 则发出结束活化操作的命令。 本发明针对每节电池单体, 自动化实吋监 测电池状态并通过预设频率与预设吋序的不会损伤电池的电流主动完成活化操 作, 无需人工干预, 可以大大减少机房基站的维护成本; 本发明可以根据当前 第一电池单体状况自适应选择不同的活化吋序, 达到良好的活化电池的效果, 延缓电池劣化进度, 延迟电池容量降低过程; 此外, 在活化操作过程中不需要 对电池组的负载断电, 不影响其他节正常单体; 从而有效提高整个机房基站的 供电可靠性。  The method for activating a lead-acid battery and a system thereof according to the present invention, after finding a first battery cell that needs to be activated, can issue an activation alarm and issue a command to initiate activation operation under the premise of floating charging, and Cycling monitoring is performed; during the activation operation of the first battery cell, if the monitoring battery pack is in a non-floating state, a command to end the activation operation is issued. The invention automatically monitors the state of the battery for each battery cell and actively completes the activation operation by the preset frequency and the preset sequence without damaging the current of the battery, and can greatly reduce the maintenance cost of the base station without manual intervention; The invention can adaptively select different activation sequences according to the current first battery cell condition, achieve a good effect of activating the battery, delay the progress of the battery degradation, and delay the battery capacity reduction process; further, the battery is not required during the activation operation The load of the group is cut off, which does not affect the normal cells of other sections; thus effectively improving the power supply reliability of the base station of the entire equipment room.
[0122] 需要说明的是, 在本文中, 术语"包括"、 "包含 "或者其任何其他变体意在涵盖 非排他性的包含, 从而使得包括一系列要素的过程、 方法、 物品或者装置不仅 包括那些要素, 而且还包括没有明确列出的其他要素, 或者是还包括为这种过 程、 方法、 物品或者装置所固有的要素。 在没有更多限制的情况下, 由语句 "包 括一个 ...... "限定的要素, 并不排除在包括该要素的过程、 方法、 物品或者装置 中还存在另外的相同要素。  [0122] It is to be noted that the terms "comprising", "including", or any other variants thereof are intended to encompass a non-exclusive inclusion, such that a process, method, article, or device comprising a series of elements includes Those elements, but also other elements not explicitly listed, or elements that are inherent to such a process, method, item or device. An element defined by the phrase "comprises a ..." without further restrictions does not exclude the presence of additional elements in the process, method, article, or device that comprises the element.
[0123] 通过以上的实施方式的描述, 本领域的技术人员可以清楚地了解到上述实施例 方法可借助软件加必需的通用硬件平台的方式来实现, 当然也可以通过硬件, 但很多情况下前者是更佳的实施方式。 基于这样的理解, 本发明的技术方案本 质上或者说对现有技术做出贡献的部分可以以软件产品的形式体现出来, 该计 算机软件产品存储在一个存储介质 (如 ROM/RAM、 磁碟、 光盘) 中, 包括若干 指令用以使得一台终端设备 (可以是手机, 计算机, 服务器, 空调器, 或者网 络设备等) 执行本发明各个实施例所述的方法。  [0123] Through the description of the above embodiments, those skilled in the art can clearly understand that the foregoing embodiment method can be implemented by means of software plus a necessary general hardware platform, and of course, can also be through hardware, but in many cases, the former It is a better implementation. Based on such understanding, the technical solution of the present invention, which is essential or contributes to the prior art, may be embodied in the form of a software product stored in a storage medium (such as ROM/RAM, disk, The optical disc includes a number of instructions for causing a terminal device (which may be a mobile phone, a computer, a server, an air conditioner, or a network device, etc.) to perform the methods described in various embodiments of the present invention.
[0124] 以上仅为本发明的优选实施例, 并非因此限制本发明的专利范围, 凡是利用本 发明说明书及附图内容所作的等效结构或等效流程变换, 或直接或间接运用在 其他相关的技术领域, 均同理包括在本发明的专利保护范围内。 The above is only a preferred embodiment of the present invention, and thus does not limit the scope of the patent of the present invention. The equivalent structure or equivalent flow of the invention and the equivalents of the drawings are directly or indirectly applied to other related technical fields, and are included in the scope of patent protection of the present invention.

Claims

权利要求书 Claim
[权利要求 1] 一种铅酸蓄电池活化方法, 其中, 包括:  [Claim 1] A method for activating a lead-acid battery, comprising:
将电池组内单体内阻值与所述电池组平均内阻基准值的偏差大于第一 预设值, 或单体内阻值与其初始内阻值的偏差大于第二预设值的电池 单体标记为第一电池单体;  The deviation between the internal resistance value of the battery group and the average internal resistance of the battery group is greater than a first preset value, or the battery internal resistance value of the internal resistance value of the battery is greater than a second preset value Being the first battery cell;
判断所述电池组内是否存在第一电池单体;  Determining whether the first battery cell is present in the battery pack;
若是, 则判断所述电池组是否处于浮充状态;  If yes, determining whether the battery pack is in a floating state;
若是, 则对所述第一电池单体进行活化操作, 所述活化操作包括至少 一次活化处理; 所述活化处理包括在预设吋长内采用预设频率和预设 吋序的电流对所述第一电池单体进行循环多次的充放电。  If yes, performing an activation operation on the first battery cell, the activation operation including at least one activation process; the activation process includes using a preset frequency and a preset sequence current within the preset length The first battery cell is charged and discharged several times in a cycle.
[权利要求 2] 根据权利要求 1所述铅酸蓄电池活化方法, 其中, 所述对所述第一电 池单体进行活化操作之前, 还包括: 判断所述第一电池单体距离上一 次活化操作的吋间间隔是否达到第一预设阈值, 若是, 则执行所述对 所述第一电池单体进行活化处理的步骤。  [Claim 2] The method for activating a lead-acid battery according to claim 1, wherein, before performing the activating operation on the first battery cell, the method further comprises: determining that the first battery cell is from a last activation operation Whether the inter-turn interval reaches a first predetermined threshold, and if so, performing the step of activating the first battery cell.
[权利要求 3] 根据权利要求 1或 2所述铅酸蓄电池活化方法, 其中, 所述活化处理具 体包括:  [Claim 3] The method for activating a lead-acid battery according to claim 1 or 2, wherein the activation treatment body comprises:
获取所述第一电池单体的单体温度, 判断所述单体温度是否小于温度 预设值;  Obtaining a cell temperature of the first battery cell, and determining whether the cell temperature is less than a temperature preset value;
若否, 则采用所述预设频率和第一活化吋序的电流对所述第一电池单 体进行循环多次的充放电;  If not, charging and discharging the first battery unit by using the preset frequency and the current of the first activation sequence;
若是, 则判断所述第一电池单体的单体电压是否低于对应的浮充电压 若是, 则采用所述预设频率和第二活化吋序的电流对所述第一电池单 体进行循环多次的充放电;  If yes, determining whether the cell voltage of the first battery cell is lower than a corresponding float voltage, if the first battery cell is circulated by using the preset frequency and the current of the second activation sequence Multiple charge and discharge;
若否, 则采用所述预设频率和第三活化吋序的电流对所述第一电池单 体进行循环多次的充放电。  If not, the first battery unit is charged and discharged a plurality of times using the predetermined frequency and the current of the third activation sequence.
[权利要求 4] 根据权利要求 3所述铅酸蓄电池活化方法, 其中: [Claim 4] The method for activating a lead-acid battery according to claim 3, wherein:
所述第一活化吋序包括充电吋间 Tl=600-(t-t0)*a, 等待吋间为 T2=100 + (t-t0)*a, 放电吋间 T3=200ms,再次等待吋间 T4=100ms ; 其中, t为所 述第一电池单体的单体温度, to为所述温度预设值; The first activation sequence includes charging time T1=600-(t-t0)* a , waiting for the daytime to be T2=100 + (t-t0)*a, discharge time T3=200ms, wait again for the daytime T4=100ms; where t is the monomer temperature of the first battery cell, and to is the temperature preset value;
所述第二活化吋序的充电吋间、 等待吋间、 放电吋间、 再次等待吋间 分别为 900ms、 10ms、 50ms、 40ms;  The charging cycle of the second activation sequence, waiting for the daytime, discharging the daytime, and waiting again for the daytime are 900ms, 10ms, 50ms, 40ms, respectively;
所述第三活化吋序的充电吋间、 等待吋间、 放电吋间、 再次等待吋间 分别为 500ms、 100ms、 300ms、 100ms。  The charging cycle of the third activation sequence, the waiting time, the discharge time, and the waiting time are 500 ms, 100 ms, 300 ms, and 100 ms, respectively.
[权利要求 5] 根据权利要求 1所述铅酸蓄电池活化方法, 其中, 每次所述活化处理 的所述对所述第一电池单体进行活化操作包括: 每完成一次所述活化处理后, 就刷新所述第一电池单体的单体内阻值 若刷新后的单体内阻值与所述活化操作初始吋的单体内阻值的偏差小 于第三预设值, 则结束所述活化操作; 或  [Claim 5] The method for activating a lead-acid battery according to claim 1, wherein the activating operation of the first battery cell each time the activation process comprises: after each activation process is completed, And refreshing the internal resistance value of the first battery cell, if the deviation between the refreshed monomer internal resistance value and the monomer internal resistance value of the initial operation of the activation operation is less than a third preset value, ending the activation operation; Or
若所述活化操作的吋长是否达到第二预设阈值, 则结束所述活化操作  Ending the activation operation if the length of the activation operation reaches a second predetermined threshold
[权利要求 6] —种铅酸蓄电池活化系统, 其中, 包括: [Claim 6] A lead-acid battery activation system, comprising:
控制平台, 设置为将电池组内单体内阻值与所述电池组平均内阻基准 值的偏差大于第一预设值, 或单体内阻值与其初始内阻值的偏差大于 第二预设值的电池单体标记为第一电池单体;  The control platform is configured to set a deviation between a single internal resistance value of the battery pack and the average internal resistance reference value of the battery pack to be greater than a first preset value, or a deviation between a single internal resistance value and an initial internal resistance value thereof is greater than a second preset value The battery cell is labeled as a first battery cell;
所述控制平台还设置为判断所述电池组内是否存在第一电池单体; 监控模块, 设置为对所述第一电池单体进行活化操作, 所述活化操作 包括至少一次活化处理; 所述活化处理包括在预设吋长内采用预设频 率和预设吋序的电流对所述第一电池单体进行循环多次的充放电。  The control platform is further configured to determine whether the first battery cell is present in the battery pack; the monitoring module is configured to perform an activation operation on the first battery cell, and the activation operation includes at least one activation process; The activation process includes charging and discharging the first battery cell a plurality of times by using a preset frequency and a preset current within a predetermined length.
[权利要求 7] 根据权利要求 6所述铅酸蓄电池活化系统, 其中, 所述控制平台还设 置为判断所述第一电池单体距离上一次活化操作的吋间间隔是否达到 第一预设阈值; 若否, 则不允许发出幵始活化操作的指令或发出结束 活化操作的指令。 [Claim 7] The lead-acid battery activation system according to claim 6, wherein the control platform is further configured to determine whether the first battery cell is separated from the first activation threshold by the first predetermined threshold If not, it is not allowed to issue an instruction to start the activation operation or to issue an instruction to end the activation operation.
[权利要求 8] 根据权利要求 6或 7所述铅酸蓄电池活化系统, 其中, 所述控制平台还 设置为: 获取所述第一电池单体的单体温度, 判断所述单体温度是否小于温度 预设值; [Claim 8] The lead-acid battery activation system according to claim 6 or 7, wherein the control platform is further configured to: Obtaining a cell temperature of the first battery cell, and determining whether the cell temperature is less than a temperature preset value;
若否, 则采用所述预设频率和第一活化吋序的电流对所述第一电池单 体进行循环多次的充放电;  If not, charging and discharging the first battery unit by using the preset frequency and the current of the first activation sequence;
若是, 则判断所述第一电池单体的单体电压是否低于对应的浮充电压 若是, 则采用所述预设频率和第二活化吋序的电流对所述第一电池单 体进行循环多次的充放电;  If yes, determining whether the cell voltage of the first battery cell is lower than a corresponding float voltage, if the first battery cell is circulated by using the preset frequency and the current of the second activation sequence Multiple charge and discharge;
若否, 则采用所述预设频率和第三活化吋序的电流对所述第一电池单 体进行循环多次的充放电。  If not, the first battery unit is charged and discharged a plurality of times using the predetermined frequency and the current of the third activation sequence.
[权利要求 9] 根据权利要求 8所述铅酸蓄电池活化系统, 其中:  [Claim 9] The lead-acid battery activation system according to claim 8, wherein:
所述第一活化吋序包括充电吋间 Tl=600-(t-t0)*a, 等待吋间为 T2=100 +(t-t0)*a, 放电吋间 T3=200ms,再次等待吋间 T4=100ms ; 其中, t为所 述第一电池单体的单体温度, to为所述温度预设值; The first activation sequence includes charging time T1=600-(t-t0)* a , waiting for the daytime T2=100+(t-t0)*a, and discharging the daytime T3=200ms, waiting for the daytime again T4=100ms; wherein, t is the monomer temperature of the first battery cell, and to is the temperature preset value;
所述第二活化吋序的充电吋间、 等待吋间、 放电吋间、 再次等待吋间 分别为 900ms、 10ms、 50ms、 40ms;  The charging cycle of the second activation sequence, waiting for the daytime, discharging the daytime, and waiting again for the daytime are 900ms, 10ms, 50ms, 40ms, respectively;
所述第三活化吋序的充电吋间、 等待吋间、 放电吋间、 再次等待吋间 分别为 500ms、 100ms、 300ms、 100ms。  The charging cycle of the third activation sequence, the waiting time, the discharge time, and the waiting time are 500 ms, 100 ms, 300 ms, and 100 ms, respectively.
[权利要求 10] 根据权利要求 6所述铅酸蓄电池活化系统, 其中, 所述监控模块还设 置为每完成一次所述活化处理后, 就刷新所述第一电池单体的单体内 阻值; [Claim 10] The lead-acid battery activation system according to claim 6, wherein the monitoring module is further configured to refresh the internal resistance value of the first battery cell after each activation process is completed;
所述控制平台还设置为判断刷新后的单体内阻值与所述活化操作初始 吋的单体内阻值的偏差是否小于第三预设值, 若是, 则发出结束活化 操作的指令; 或判断所述活化操作的吋长是否达到第二预设阈值, 若 是, 则发出结束活化操作的指令。  The control platform is further configured to determine whether the deviation between the refreshed internal resistance value and the single internal resistance value of the initial operation of the activation operation is less than a third preset value, and if yes, issue an instruction to end the activation operation; or determine the location Whether the length of the activation operation reaches the second predetermined threshold, and if so, an instruction to end the activation operation is issued.
PCT/CN2017/077281 2017-03-20 2017-03-20 Method and system for activating lead-acid battery WO2018170672A1 (en)

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