WO2018105133A1 - Hydrogen fluid closed cycle device - Google Patents

Hydrogen fluid closed cycle device Download PDF

Info

Publication number
WO2018105133A1
WO2018105133A1 PCT/JP2017/004574 JP2017004574W WO2018105133A1 WO 2018105133 A1 WO2018105133 A1 WO 2018105133A1 JP 2017004574 W JP2017004574 W JP 2017004574W WO 2018105133 A1 WO2018105133 A1 WO 2018105133A1
Authority
WO
WIPO (PCT)
Prior art keywords
hydrogen gas
food
hydrogen
drying
closed cycle
Prior art date
Application number
PCT/JP2017/004574
Other languages
French (fr)
Japanese (ja)
Inventor
杉山　修
Original Assignee
杉山　修
水口 果南
水口 侑香
水口 小春
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2016238102A external-priority patent/JP2018093740A/en
Priority claimed from JP2016006115U external-priority patent/JP3209283U/en
Priority claimed from JP2017000033U external-priority patent/JP3209521U/en
Application filed by 杉山　修, 水口 果南, 水口 侑香, 水口 小春 filed Critical 杉山　修
Publication of WO2018105133A1 publication Critical patent/WO2018105133A1/en

Links

Images

Classifications

    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B4/00—General methods for preserving meat, sausages, fish or fish products
    • A23B4/03—Drying; Subsequent reconstitution
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B7/00—Preservation or chemical ripening of fruit or vegetables
    • A23B7/02—Dehydrating; Subsequent reconstitution
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
    • A23L3/40—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by drying or kilning; Subsequent reconstitution
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
    • A61M15/00—Inhalators
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/08—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents with metals
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
    • F02C1/00—Gas-turbine plants characterised by the use of hot gases or unheated pressurised gases, as the working fluid
    • F02C1/04—Gas-turbine plants characterised by the use of hot gases or unheated pressurised gases, as the working fluid the working fluid being heated indirectly
    • F02C1/10—Closed cycles
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
    • F02C6/00—Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas- turbine plants for special use
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
    • F02C6/00—Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas- turbine plants for special use
    • F02C6/20—Adaptations of gas-turbine plants for driving vehicles
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Definitions

  • the present invention relates to a hydrogen fluid closed cycle apparatus such as a food drying apparatus, an antioxidant action imparting apparatus, a drive / power generation apparatus, and a power engine using a hydrogen fluid, and a method using the apparatus.
  • Patent Documents 1 to 8 Food, food waste, and other foodstuffs must be dried for storage, to be tasty, to reduce volume, to have the desired shape, to concentrate nutrients, and to regenerate as other forms of foodstuffs, etc.
  • Patent Documents 1 to 4 describe a method of drying food with air.
  • Patent Document 1 describes a method of drying food waste such as food processing residues with hot air
  • Patent Document 2 discloses a method of drying with hot air while crushing food raw materials in a sealed container.
  • Patent Document 3 describes a method for drying food that causes dehumidified cold air to collide with food on a conveyor having a large number of ventilation holes.
  • Patent Document 4 describes the direction of drying air produced by a refrigerator. A cold air drying device that blows air in a changed manner is described.
  • Patent Documents 5 to 8 describe a method of drying a food material with a gas other than air.
  • Patent Document 5 describes an apparatus for processing foodstuffs, and a drying apparatus having a passage for guiding a gaseous medium such as superheated steam from a horizontal direction and a vertical direction of a spiral conveyor belt
  • Patent Document 6 describes a method of drying a food material with superheated steam at a low temperature (100 ° C. or less) under reduced pressure.
  • Patent Document 7 describes a method for producing edible particles by contacting a supercritical medium made of carbon dioxide or nitrous oxide
  • Patent Document 8 describes a method for drying food by circulating gas.
  • As the gas a method using a gas having an oxygen concentration of 10% or less and nitrogen having a purity of 90% or more is described.
  • Patent Document 9 describes a method of generating hydrogen gas from “water in which hydrogen is dissolved” and inhaling the hydrogen gas from the nose.
  • Patent Documents 10, 11, and 12 describe a method for inhaling hydrogen gas generated by electrolysis of water from the nose or mouth, and an inhalation mask.
  • Patent Document 13 describes a method and sheet for preventing or suppressing cancer by bringing a water retaining layer holding “water in which hydrogen is dissolved” into contact with the skin.
  • the apparatus used in the above technique does not have a hydrogen gas generator inside, but obtains hydrogen from water in which hydrogen is dissolved (so-called “hydrogen water”). It was a wasteful stage to produce hydrogen gas from it.
  • electricity is used for electrolysis of water, and the equipment used there consumes electricity, uses industrial energy such as a steam reforming method, and heats hydrogen gas. I don't think that I will show the effect.
  • Patent Documents 14, 15, and 16 describe a hydrogen gas generator that brings alkaline water into contact with aluminum, silicon, or the like.
  • Patent Document 17 describes a direct-cycle engine that uses liquid hydrogen and liquid oxygen and uses volume expansion due to combustion.
  • Patent Document 18 describes a hydrogen engine characterized by a throttle using hydrogen gas as a fuel. However, all of these are those that burn hydrogen to gain energy.
  • Patent Document 19 describes an electric vehicle that uses hydrogen obtained by electrolyzing water as fuel for a fuel cell.
  • Patent Document 20 describes hydrogen obtained by catalytic reaction of methanol as fuel for a fuel cell. Is used as a power device. However, they all use hydrogen as fuel for the fuel cell to obtain electric power and consume hydrogen gas.
  • hydrogen gas has a low critical point and high thermal conductivity, and it is safe if oxygen is not present, there are technologies to obtain energy by burning and fuel cell fuel technologies. There are few techniques for obtaining kinetic energy (propulsion, rotational drive, etc.) or electrical energy (power generation by rotating a rotor blade with a fluid that does not depend on combustion) by using it as a fluid.
  • the present invention has been made in view of the above-described background art, and its problem is to provide a novel apparatus using a specific gas.
  • a novel food drying method a food drying apparatus, Providing a novel dry food production method; Providing a novel antioxidant device and antioxidant method; “Non-atmospheric energy closed cycle” that does not use the atmosphere and does not emit exhaust gas
  • the present inventor has used the above-mentioned problems by using hydrogen gas having features such as a low critical point, high thermal conductivity, and safety without oxygen. It was found that can be solved. Specifically, the present inventors have found an excellent effect that drying can be efficiently performed by using hydrogen gas as a medium used for drying food materials. In addition, the body can be effectively protected by using a combination of a hydrogen gas generator that generates only hydrogen gas through a chemical reaction and a member that allows the human to ingest the heated hydrogen from the temperature rising device. I found out that I can.
  • the present invention provides a hydrogen fluid closed cycle device characterized by comprising at least the following (1), (2) and (R).
  • (1) Hydrogen gas generator for generating hydrogen gas (2)
  • Hydrogen gas heating device and hydrogen gas utilization device that uses hydrogen gas from the temporary storage tank
  • the present invention includes the following aspect 1, aspect 2 or aspect 3 as a preferable aspect.
  • aspect 1 of the present invention is a food drying apparatus comprising the above hydrogen fluid closed cycle apparatus
  • the present invention provides a food drying apparatus that is used in a food drying method for removing water contained in the food by bringing hydrogen gas into contact with and passing through the food.
  • the present invention is a food drying method using the above-described food drying apparatus, wherein hydrogen is brought into contact with and permeated through the food to remove moisture contained in the food. A method is provided.
  • drying using the above-described food drying apparatus or the above-described food drying method allows hydrogen gas to contact and permeate the food to remove moisture contained in the food.
  • the manufacturing method of a foodstuff is provided.
  • Aspect 2 of the present invention is an antioxidant effect imparting device comprising the above hydrogen fluid closed cycle device,
  • the present invention provides an antioxidant effect imparting device characterized by comprising at least the following (a), (b) and (R2).
  • (A) Hydrogen gas generator for generating hydrogen gas by chemical reaction (b) Hydrogen gas temperature rise control device (R2) for raising the temperature of the hydrogen gas generated by the above (a) hydrogen gas generator (R2)
  • R2 Hydrogen gas temperature rise control device
  • the hydrogen gas Hydrogen gas inhalation mask that allows a human to inhale, or a hydrogen gas discharge filling container that makes the hydrogen gas contact a human or a part of the human
  • the second aspect of the present invention is to use the above-mentioned antioxidant action imparting device and raise the hydrogen gas stepwise while controlling the temperature of the hydrogen gas to bring the hydrogen gas into contact with a human or a part of the human.
  • the present invention provides a method for imparting an anti-oxidant action.
  • Aspect 3 of the present invention is a hydrogen fluid closed cycle drive / power generation device comprising the above hydrogen fluid closed cycle device,
  • the present invention provides a supercritical hydrogen fluid closed cycle drive / power generation device characterized by comprising at least all of the following (R3) and (R4).
  • (R3) Drive unit including a turbine that rotates when hydrogen gas is injected from the temporary storage tank (R4)
  • Fluid generator that generates power by rotating the rotor blades when hydrogen gas is injected from the temporary storage tank
  • Aspect 3 of the present invention provides a power engine equipped with the above hydrogen fluid closed cycle drive / power generation apparatus.
  • Aspect 3 of the present invention provides a driving / power generation method using the above-described hydrogen fluid closed cycle driving / power generation apparatus.
  • the food drying apparatus which is one form of the hydrogen fluid closed cycle apparatus according to the present invention and the invention related to the apparatus will be abbreviated as “Aspect 1”, and similarly, the antioxidant action imparting apparatus which is another form and the invention related thereto. Is abbreviated as “Aspect 2”, and similarly, another embodiment of the hydrogen fluid closed cycle drive / power generation apparatus and the invention related thereto are abbreviated as “Aspect 3”.
  • hydrogen gas having characteristics such as a low critical point and extremely high thermal conductivity; safe without oxygen; has an antioxidant effect; It is possible to provide an apparatus and a method that are easy, physically and chemically safe, have no toxicity, and are safe for living organisms. Further, it is an “closed cycle of energy” that does not burn and does not use the atmosphere, and can provide an apparatus that does not emit exhaust gas, pollutes the atmosphere, does not load the environment, and has low risk.
  • the effects of the aspect 1 of the present invention are as follows. Even if the food is not heated to a high temperature, it can be dried in a very short time.
  • the thermal conductivity of hydrogen gas is much higher than that of air, nitrogen gas, water vapor, methane gas, fluorine gas, or the like.
  • the thermal conductivity of hydrogen gas is higher than that of helium gas, which is known for its extremely high thermal conductivity.
  • hydrogen gas since hydrogen gas has a low critical point and high thermal conductivity, heat is easily transferred to the food, high-pressure fluid is easily generated, and the food can be dried in a short time.
  • hydrogen gas has high permeability and permeability to objects. For this reason, it penetrates and permeates the inside of an object (foodstuff) with high gas barrier properties and quickly dries the foodstuff. Therefore, for example, potatoes such as potatoes and sweet potatoes (skins); fruits such as apples, strawberries and oranges (skins); mushrooms such as jellyfishes; marine products such as fish, abalone and sea cucumbers; etc. It is also suitable for drying, roasting in an intermediate temperature range, non-flying heating and the like.
  • the nutrient value can be concentrated and dried while maintaining the shape of the food, increasing the commercial value.
  • the food drying method of aspect 1 of the present invention is applicable to (part of) eatable organisms themselves, non-standard vegetables, fruits and seafood, as well as secondary products generated during food processing. It can also be applied to food waste. Therefore, there is no waste of ingredients, and it is possible to provide ingredients with higher nutritional value.
  • the effect of the aspect 2 of this invention is the following.
  • the apparatus can be configured as a simple device, and the human body can be suitably protected on a daily basis. Specifically, without burdening the body against active substances, oxygen radicals, hydroxy (anion) radicals and other cells (species) that easily oxidize cells, intracellular tissues (organelles), and body substances It is possible to counter effectively.
  • the hydrogen fluid closed cycle drive / power generation device can be said to be a non-atmospheric hydrogen supercritical fluid closed cycle drive / power generation device, and basically does not require oxygen or air, and the drive / power generation energy is reduced to a low temperature. Created at (around 50-400 ° C). Since it does not depend on the atmosphere, it can be applied to non-atmosphere-dependent propulsion (AIP) submarines.
  • AIP non-atmosphere-dependent propulsion
  • the hydrogen used has a critical point of ⁇ 240 ° C. and 1.3 MPa, the highest thermal conductivity in the gas, and 0.1919 W / (m ⁇ K) under the condition of 50 ° C.
  • the air is 0.0272 W / (m ⁇ K) under the condition of 40 ° C. Compared to air, it has a thermal conductivity about 7 times that of a supercritical fluid even at low temperatures.
  • the hydrogen becomes supercritical in about 1 to 2 minutes.
  • the pressure is from 80 to 350 atm
  • the temperature is from 50 ° C to 400 ° C
  • the power generation capacity can be designed freely by setting the temperature and temporary storage time.
  • Temperature and pressure are in a proportional relationship, and the supercritical discharge state can be controlled by easily adjusting the temperature and pressure with a pressure control valve. If the impeller is directly rotated at a high speed as a supercritical fluid and the fluid power generator is directly rotated via the drive shaft, highly efficient electric power can be obtained.
  • a closed cycle operation can be performed by injecting and circulating a high-density active hydrogen gas fluid compressed and pressurized with power. Therefore, sunlight (electromagnetic waves), geothermal heat, other heat sources, “thermal expansion / waste heat by compressors, blanker pumps, etc.” can be used (recovered), and the hydrogen gas fluid can be driven at high pressure even at low temperatures. It is also possible to perform efficient rotation, drive and power generation.
  • an existing reciprocating engine diesel engine / rotary engine
  • a compression scroll engine or a single-shaft turbine
  • a single-shaft turbine is suitable because it can be operated in a closed cycle by thermal expansion.
  • an ignition spark plug, fuel, and air as in the existing engine are not required.
  • the hydrogen fluid closed cycle drive / power generation apparatus of the present invention uses a system that can be used as a power engine to achieve both driving and power generation.
  • FIG. 12 shows an example applied to a single-shaft turbine drive, but a supercritical pressure drive can supply a propulsive force and electric power, and a simultaneous output of at least 3 MW or more is possible.
  • FIG. 13 shows an example applied to a single-shaft turbine drive, but a supercritical pressure drive can supply a propulsive force and electric power, and a simultaneous output of at least 3 MW or more is possible.
  • the supercritical hydrogen fluid closed cycle drive / power generation device is effective in the maintenance of limited resources because no exhaust gas is produced and no fuel is consumed in gasoline. When applied to an automobile, it becomes a private power generation vehicle, and there is no exhaust emission of NOX during traveling.
  • the vehicle body can be lightened, and rare metals that are catalysts for fuel cells and the like are unnecessary. Moreover, the manufacturing cost is low, and it can be realized only by a combination of existing technologies. Since hydrogen gas is generated each time and is a continuous compression, heating system, or temporary storage system, a hydrogen compression storage tank is unnecessary. Hydrogen having a critical point of ⁇ 240 ° C. is less affected by the temperature, and if heated even below freezing, the hydrogen expands and becomes high pressure and becomes supercritical, so there is no decrease in output. It is a closed cycle system that does not consume fuel, and is highly energy efficient.
  • the hydrogen fluid closed cycle drive / power generation device of aspect 3 of the present invention is safe.
  • hydrogen gas has an ignition point of 570 ° C. in air and 450 ° C. in oxygen, and both are temperatures when oxygen is present.
  • hydrogen gas or “inactive with hydrogen” The “gas mixture” does not cause combustion or explosion. Only a hydrogen gas generator (alkaline ion water) is loaded, and even if there is a traffic accident, it does not explode because there is no high-pressure tank. There is no explosive fire because no fuel is loaded.
  • the hydrogen fluid closed cycle drive / power generation apparatus of aspect 3 of the present invention is optimal not only for the above-mentioned drive / power generation for consumer use, but also for the engine drive / power generation of ships and vehicles (see FIG. 13).
  • non-atmospheric propulsion for example, in the case of a submarine, an internal combustion diesel engine is usually used, and electric drive propulsion that floats, generates electric power, stores electricity, and dives.
  • the alkaline ion battery cannot store a large amount of electric power, and therefore cannot perform long-term stealth diving. Therefore, AIP (non-atmosphere-dependent propulsion) assists with a Stirling engine or the like, but the power generation capacity is as low as about 75 kW.
  • the closed cycle steam turbine engine used in the submarine burns a mixed gas of “oxygen obtained by vaporizing liquid oxygen as a supply source” and ethanol, and uses the combustion gas obtained at about 700 ° C.
  • a steam generator operates a steam turbine at 500 ° C. to generate electricity. There you need fuel.
  • the hydrogen fluid closed cycle drive / power generation device is a non-atmospheric supercritical closed cycle drive / power generation device (system). That is, it is a system that does not burn fuel, and the use of air in the ship is zero, which is extremely preferable for the ship environment. Since air and oxygen are not used and there is no exhaust gas, a large amount of power can be supplied from time to time within the ship, making it possible to covert underwater as long as a nuclear submarine. Submarine snorkeling is not required, and hydrogen gas production for leak replenishment can also be created in the ship (seawater fuel (hydrogen)) from drawn-in seawater.
  • system non-atmospheric supercritical closed cycle drive / power generation device
  • the hydrogen gas used as the heat medium is continuously generated by the method described later. Therefore, when a metal such as aluminum is separated from the alkaline water, the generation of the hydrogen gas stops immediately in only about 1 to 3 seconds. Therefore, there is no need for an adiabatic high-pressure tank such as liquefied hydrogen or a heavy hydrogen storage alloy, liquefied oxygen is unnecessary, and there is no explosion and it is extremely safe.
  • the supercritical hydrogen fluid having a high pressure is sequentially supplied from a plurality of temporary storage tanks, the rotating blades are rotated at a high speed, the drive shaft is rotated, and the power is driven.
  • This is a closed cycle system in which the fluid power generator is operated from the rotation of the shaft. Since air is not required, the internal combustion engine is not required (non-atmospheric energy), and the most technical point of the present invention is that hydrogen can be used as a supercritical fluid medium without burning.
  • the hydrogen gas is warmed and can be used in, for example, 1 to 2 minutes in a state of being temporarily confined in a plurality of sealed spaces (sealed containers).
  • FIG. 1 It is a conceptual diagram which shows an example of the aspect 1 of this invention. It is a schematic whole view showing an example of composition of a foodstuffs drying device of mode 1 of the present invention, and is a schematic diagram showing an example which has a foodstuff drying container and a foodstuff shelf. It is the schematic which shows an example of the structure of "the long and spiral food drying container" of the food drying apparatus of aspect 1 of this invention. It is a figure which shows the example of the photograph of the dry foodstuff from which the water
  • a photo of the ingredients are fish and the dried ingredients are fish meal
  • a photograph of the ingredients are fruits and the dried ingredients are dried fruits It is the schematic which shows an example of the antioxidant action provision apparatus of aspect 2 of this invention.
  • A) Cross-sectional view of antioxidant device (b) Photograph showing usage It is the schematic which shows an example of the antioxidant action provision apparatus of aspect 2 of this invention.
  • the drive device in aspect 3 of this invention is a rotary engine
  • the schematic which shows an example of the aspect of this rotary engine When the drive device in aspect 3 of this invention is a single shaft turbine engine, it is the schematic which shows an example of the aspect of this single shaft turbine engine. It is the schematic which shows an example of the aspect of this motor vehicle, when the hydrogen fluid closed cycle drive and electric power generating apparatus of aspect 3 of this invention is utilized for a motor vehicle.
  • the present invention is a hydrogen fluid closed cycle device comprising at least the following (1), (2) and (R).
  • (1) Hydrogen gas generator for generating hydrogen gas (2)
  • Hydrogen gas heating device and hydrogen gas utilization device that uses hydrogen gas from the temporary storage tank
  • the foodstuff dry container is the aspect 1
  • the (R) hydrogen gas utilization device of the present invention is a hydrogen gas suction mask or a hydrogen gas discharge full container, which is aspect 2.
  • the aspect (3) is that the (R) hydrogen gas utilization device of the present invention is a drive device including a turbine and a fluid power generator that rotates to generate electric power.
  • FIGS. 1 to 4 An example of the aspect 1 is shown in FIGS. 1 to 4, and “the reference numerals used in FIGS. 1 to 4” and “the reference numerals in the description of the aspect 1 below” are applied only to the aspect 1. To do. That is, “the reference numerals in the description of the aspect 1 described below” correspond to “the reference numerals used in FIGS. 1 to 4”, and the same reference numerals are used for the other elements in the description of other aspects and other drawings. Have been.
  • Aspect 1 of the present invention is a food drying apparatus comprising the above hydrogen fluid closed cycle apparatus, A food drying apparatus characterized by being used in a food drying method for removing water contained in the food by bringing hydrogen gas into contact with and passing through the food. Further, the present invention is a food drying method characterized by removing hydrogen contained in the food by contacting / permeating the gas with the hydrogen gas.
  • contact / transmission means “contact and / or transmission”. In the case of thick foods and the like, the case where it does not penetrate is also included.
  • the hydrogen gas to be used is not particularly limited, and may be generated by a chemical reaction or obtained by electrolysis of water or the like in a hydrogen gas generator attached to a food drying apparatus. It is preferable to use the hydrogen gas obtained by the above. Further, the reflux hydrogen gas from which the water vapor has been removed from the “hydrogen gas containing water vapor” once used as a drying medium may be heated and circulated again (closed cycle).
  • the temperature of the hydrogen gas immediately before contacting / permeating the food and the temperature of the hydrogen gas when contacting / permeating the food are not particularly limited, but are preferably 0 ° C. or higher and 100 ° C. or lower, more preferably 10 ° C. It is 60 ° C. or lower, particularly preferably 20 ° C. or higher and 40 ° C. or lower. Further, the temperature of the food during drying is not particularly limited, but it is preferable to dry the food so as to be in the above temperature range.
  • the temperature is equal to or higher than the above lower limit, it is not necessary to cool the hydrogen gas and a cooler is unnecessary, so that the water in the food does not freeze and it is difficult to remove the water.
  • the partial pressure (relative humidity) of water vapor contained in the hydrogen gas can be sufficiently reduced.
  • the hydrogen gas is preferably heated by the hydrogen gas heating device 28 before being introduced into the food drying container (see FIGS. 1 to 3). Heating facilitates drying, and heating in a sealed environment is particularly preferable because the pressure increases.
  • the temperature when the temperature is not more than the above upper limit, it becomes easy to dry without altering “various substances derived from living organisms” contained in food.
  • enzymes and vitamins should be 40 ° C. or lower, and preferably 38 ° C. or lower, so that decomposition and inactivation can be suppressed and drying can be facilitated.
  • the starch should be kept at 55 ° C. or lower, preferably 50 ° C. or lower, so that it does not change to ⁇ starch in the presence of water remaining in the drying ingredients, and is dried as ⁇ starch. Becomes easier.
  • the hydrogen gas to be introduced can be higher than the temperature while keeping the temperature of the food in the above range.
  • the pressure of hydrogen gas immediately before contacting / permeating the food material and the pressure of hydrogen gas contacting / permeating the food material are not particularly limited, but the hydrogen gas pressure is sealed before being introduced into the food drying container. It is also achieved by heating in the state. If the temperature of the hydrogen gas is raised, the pressure will increase, and the flow rate of hydrogen with an increased temperature will inevitably become faster, thus promoting drying. Moreover, hydrogen gas circulates and refluxes quickly.
  • the hydrogen gas may be introduced into the food material drying container through the inside of the hydrogen gas introduction pipe, or may be injected from the hydrogen gas introduction nozzle into the food material drying container.
  • the food drying apparatus 10 used in the food drying method of the present invention includes at least a hydrogen gas generator 20 that generates hydrogen gas, a food drying container 30 that stores the food F and allows hydrogen gas to pass, and a food drying container 30. It is preferable to include a dehumidifying device 40 that removes the water vapor from the “hydrogen gas containing water vapor” that has passed through the inside of the water.
  • FIG.1 and FIG.2 shows an example of a structure of the foodstuff drying apparatus 10 used for this invention.
  • Hydrogen gas generation (device)
  • the hydrogen gas used for drying may be separately brought into a cylinder or the like at a location away from the food drying apparatus 10, but in the hydrogen gas generator 20 associated with the food drying apparatus 10 of the present invention, a chemical reaction ( Or the amount of hydrogen required for drying is sufficient; there is no cost for cylinder charges, electricity charges, etc .; residual water exhausted by hydrogen gas is obtained as a useful byproduct; From the point of view, it is preferable.
  • the generation of hydrogen in the hydrogen gas generator 20 is preferably performed by bringing the alkaline water 22 into contact with the metal 21. That is, the hydrogen gas generator 20 in the present invention is preferably one that generates hydrogen gas by bringing the alkaline water 22 into contact with a metal.
  • the metal element is preferably a metal such as aluminum (Al), zinc (Zn), titanium (Ti), tin (Sn), etc., from the viewpoints of safety, cost (inexpensive), and useful products.
  • Aluminum is particularly preferred. Particularly in the case of aluminum, the reaction product is particularly preferable because it can be used as a purification material after filtration.
  • the metal 21 is preferably a metal 21 having a high ionization tendency.
  • the pH of the alkaline water is not particularly limited, but is preferably 12 or more, more preferably 13 or more, and particularly preferably 13.5 or more.
  • aluminum hydroxide (Al (OH) 3 ) produced on the surface of the aluminum is insoluble in water, so that the reaction is less likely to occur inside the metal.
  • Al (OH) 3 aluminum hydroxide
  • (strong) alkaline water having the above pH aluminum hydroxide is converted to aluminate ions and dissolved in water, the hydroxide film on the metal surface is dissolved, and the chemical reaction of the hydrogen gas activity is caused by the metal 21 Progress to the inside.
  • the produced aluminate (salt) should preferably be filtered off periodically.
  • a method of not precipitating aluminate (salt) by a simple technical operation has already been established, so that aluminate (salt) is not precipitated. You can also.
  • a stoichiometric amount of hydrogen gas of at least 1130 L or more can be obtained at high speed from 1 L of alkaline water in a standard state, so that the amount of hydrogen gas introduced into the food drying container 30 is sufficient.
  • the water after the reaction hydrogen generation is also clean transparent water.
  • the alkaline water 22 is obtained from natural products 27 such as natural stones (limestone, etc.), shells, meteorites, and the like because it is environmentally friendly.
  • FIG. 3 shows an apparatus for obtaining hydrogen from the alkaline water 22 by adding water to the natural product 27. Further, after the alkaline water is brought into contact with a metal 21 such as aluminum (Al) to generate hydrogen gas, it is not necessary to filter it by the above-mentioned technical operation. It is possible and environmentally friendly. Even when aluminate (salt) is precipitated by the reaction, the “filtered water obtained by filtering it” approaches neutrality.
  • the hydrogen gas to be introduced into the food drying container 30 passes through the inside of the food drying container 30 having the generated hydrogen gas generated by the hydrogen gas generator 20 and / or the food F, and “water vapor in the food
  • the reflux hydrogen gas obtained by removing the water vapor from the “hydrogen gas containing” can be used. It is preferable to supplement the recirculated hydrogen gas in a shortage due to leakage with the generated hydrogen gas.
  • the critical temperature of hydrogen is 33K ( ⁇ 240 ° C.), so it becomes supercritical by definition.
  • FIGS. 2 and 3 are schematic views of the hydrogen gas generator 20.
  • the metal 21 is moored and charged into the hydrogen gas generator 20 having the alkaline water 22 in the alkaline water tank 23, hydrogen gas is generated.
  • the generated hydrogen gas generated by the hydrogen gas generator 20 is introduced into the food drying container 30 through the hydrogen gas heating device 28, the temporary storage tank 26, and, if necessary, the dehumidifying filter 41.
  • the hydrogen gas is heated and pressurized by the hydrogen gas generator 20, the hydrogen gas heating device 28 and the temporary storage tank 26 while being introduced into the food drying container 30 (before).
  • the food drying apparatus 10 of the present invention has good drying efficiency because the hydrogen gas before being introduced into the food drying container 30 is heated and pressurized in the hydrogen gas heating device 28 and the temporary storage tank 26. It is essential from the point that the pressure can be raised.
  • the introduction of the hydrogen gas into the food material drying container 30 may be injected using a nozzle, or may be introduced or injected from below, but is more preferably introduced or injected from below.
  • the remaining water 24 can be orally used and can be effectively used for other purposes such as aquaculture water.
  • FIG. 2 shows an example of the food drying container 30.
  • the food drying container 30 in FIG. 2 has a “food material shelf 31 that is net-like and holds the food material from below” inside, and allows hydrogen gas to pass through the food material shelf 31, so that the food material F on the food material shelf 31 passes through the food material F on the food material shelf 31.
  • water contained in the food material F is removed by contacting and permeating hydrogen gas.
  • the food drying container 30 provided with the food shelf 31 is used for a relatively large dry food material as shown in FIG.
  • the food shelf 31 has a net-like shape so that the food F placed thereon does not fall down and allows hydrogen gas to pass from the bottom to the top.
  • the mesh size is not particularly limited as long as the above conditions are satisfied, but is preferably 0.1 mm or more and 100 mm or less, more preferably 0.5 mm or more and 50 mm or less, and particularly preferably 1 mm or more and 20 mm or less.
  • the “net-like” is also preferably “porous mesh-like”.
  • the form which put the basket on this net-like foodstuff shelf 31 may be sufficient. However, if the obtained dried food is in the form of powder as shown in FIG. 4B (for example, if it is expected to become powder), the mesh is further refined or the basket is placed on the food shelf 31. It is also preferable to place it.
  • the material of the net-like food shelf 31 is not particularly limited, and may be a net, a woven fabric, a perforated plate, or the like.
  • the material shelf 31 is not limited to any particular material, but may be any of metals, polymers such as synthetic resins, natural products such as wood, and the like. This is particularly preferable because it does not easily occur and does not cause a problem of metal embrittlement.
  • the number of the food shelves 31 in one food drying container 30 is not particularly limited, but is preferably 1 or more and 20 or less, more preferably 2 or more and 15 or less, and 3 or more and 10 or less. Particularly preferred.
  • a plurality of food drying containers 30 may be connected in parallel or in series (not shown). The connection may be vertical or horizontal, but it is preferable to arrange them horizontally because they are easy to work.
  • the food material F is appropriately cut as necessary, and is loaded into the food material drying container 30 from the food material charging hopper 37.
  • the generated hydrogen gas generated from the hydrogen gas generator 20 is heated to an appropriate temperature, and then introduced into the food drying container 30 using the hydrogen gas introduction pipe 32.
  • the injection position of the generated hydrogen gas to the food material drying container 30 may be anywhere, but as shown in FIG. 2, holes are made in the hydrogen gas introduction pipes 32 to hit the food material F, or particularly from below. It is particularly preferable from the viewpoint of drying efficiency.
  • the gas composed of “water vapor and hydrogen gas” from which moisture has been removed from the food material F is taken out from the “primary outlet 36 for water vapor and reflux hydrogen gas”, dehumidified in the pipe, and refluxed hydrogen gas transfer pipe 35 by the reflux hydrogen gas transfer pump 35. 33, and is introduced or injected into the food drying container 30 from the reflux hydrogen gas introduction nozzle 34 (FIG. 2).
  • the position where the reflux hydrogen gas is injected into the food drying container 30 may be from any location, and in the same manner as in the case of the generated hydrogen gas, holes may be made in places in the introduction pipe and applied to the food F from the side (not shown). 2), as shown in FIG. 2, it may be injected from below toward the food F by the reflux hydrogen gas introduction nozzle 34 from below.
  • the food drying container 30 has an elongated spiral shape, and the food F is placed on a hydrogen gas fluid to pass through the inside thereof, so that the moisture contained in the food F is contained. Those which are designed to be removed are also preferred.
  • the food drying container 30 that is elongated and spiral is preferably used in a form in which the dry food becomes powdery.
  • the food F is appropriately cut as necessary, and is loaded into the food drying container 30 from the food charging hopper 37.
  • the generated hydrogen gas generated from the hydrogen gas generator 20 is introduced into the food material drying container 30 from the vicinity of the starting point of the spiral food material drying container 30 using the hydrogen gas introduction pipe 32.
  • a gas composed of “water vapor and hydrogen gas” from which moisture has been removed from the food material F is taken out from the “primary outlet 36 of water vapor and reflux hydrogen gas” existing near the end point of the spiral food drying container 30, and is then refluxed hydrogen.
  • the gas is transferred through the reflux hydrogen gas transfer pipe 33 by the gas transfer pump 35 and introduced into the food drying container 30 from the vicinity of the starting point of the spiral food drying container 30 (FIG. 3).
  • reflux hydrogen gas transfer pipe 33 In the middle of the reflux hydrogen gas transfer pipe 33, it is preferable to provide a dehumidifier 40, where water vapor is removed, and the obtained dry hydrogen gas is introduced again into the food drying container 30 as reflux hydrogen gas.
  • Protrusions, baffles (buffers), etc. are provided on the inner wall of the elongated and spiral food drying container 30 to create a turbulent flow of hydrogen gas and move the food F in a zigzag manner.
  • water drainage pipes 42 (drain) (not shown) for collecting and extracting water droplets condensed on the inner wall of the food drying container 30 may be provided at places on the lower surface of the spiral food drying container 30. preferable.
  • Dehumidification (Device) The “gas consisting of water vapor and hydrogen gas” taken out from the “primary outlet 36 of water vapor and refluxing hydrogen gas” removes the water vapor by passing through the dehumidifying device 40, and the resulting dry hydrogen gas is refluxed. It is preferable to introduce or inject into the food drying container 30 as hydrogen gas.
  • the configuration of the dehumidifying device 40 is not particularly limited, it is preferable that the dehumidifying device 40 has a tank shape as shown in FIG. 2, and water droplets condensed in the tank are collected and extracted from the water drain pipe 42 (drain). Furthermore, it is preferable to provide a drain trap so that moisture is not entrained in the refluxing hydrogen gas.
  • the dehumidifying filter 41 is not particularly limited, and a known filter is used.
  • the dehumidifying device 40 is preferably a pipe having a built-in dehumidifying filter 41 because the dehumidifying effect is high.
  • the ingredients F may be pre-dried before being dried using the ingredients drying apparatus 10 of the present invention (before using the ingredients drying method of the present invention). It is also preferable to use the food F which has been pre-dried and which has been transported and stored.
  • the preliminary drying may be performed by a normal food drying method or the food drying method of the present invention. If the water content is 50% by mass or less by preliminary drying, practical storage is possible.
  • This invention is also a manufacturing method of the dried foodstuff characterized by using said foodstuff drying method. Moreover, it is also a manufacturing method of the dry foodstuff characterized by removing the water
  • the dried food obtained using the food drying method and the food drying apparatus 10 of the present invention include fish powder, meat powder, starch powder, dried fruit, and vegetable powder.
  • the obtained dried foods are supplements, dry powders, nutritional foods and health foods such as tablets; medical drugs such as powders (tablets); general foods such as sprinkles, dried fish and preserved foods; spices; It is useful as tea such as green tea and black tea; flour such as starch, rice flour, buckwheat flour and bread crumbs;
  • increasing the temperature is useful for roasting, non-fry cooking, and the like. Since hydrogen gas is highly permeable to objects and has high thermal conductivity, the dried food has a large volume of sea cucumber, abalone, fish, etc. It is mentioned as a particularly preferable one that has been utilized.
  • the thermal conductivity of hydrogen gas at 1 atm 0 ° C. is 168 mW / (m ⁇ K), whereas the thermal conductivity of air is 24 mW / (m ⁇ K).
  • the thermal conductivity of hydrogen gas at 1 atm. 25 ° C. is 185 mW / (m ⁇ K), whereas the thermal conductivity of air is 26 mW / (m ⁇ K).
  • the thermal conductivity of hydrogen gas at 1 atmosphere and 50 ° C. is 192 mW / (m ⁇ K), whereas the thermal conductivity of air is 28 mW / (m ⁇ K).
  • the thermal conductivity of hydrogen gas at 1 atm is about 7 times at any temperature relative to the thermal conductivity of air at 1 atm.
  • hydrogen gas has higher thermal conductivity at any temperature.
  • helium gas is much more expensive than hydrogen gas.
  • Embodiment 1 of the present invention is shown in FIGS. 1 to 3, but Embodiment 1 of the present invention is not limited to the specific embodiments shown in these.
  • the description of FIG. 1 will be described below.
  • Alkaline water 1 is injected in an appropriate amount leaving a space in the hydrogen gas generator 2.
  • the injected alkaline water 1 reacts with the metal 15 to continuously generate hydrogen gas.
  • the generated hydrogen enters the spiral heating tube in the microwave heating apparatus through the introduction tube and is heated to an appropriate temperature suitable for the nuclear food material.
  • the water vapor 6 is also generated from the microwave excitation heating device, the water vapor is also heated from the outer peripheral portion of the storage tank 7.
  • Example 1 The food material F was dried using the food material drying apparatus 10 schematically shown in FIG.
  • hydrogen gas generation apparatus (apparatus) (see FIG. 3)
  • alkaline water 22 obtained by adding water to natural product 27 including natural stones and shells was used, and aluminum was used as metal 21.
  • the temperature was set to 35 ° C. and introduced into the food drying container 30.
  • Hydrogen gas was blown onto the food material F placed on the food material shelf 31 made of polypropylene having an opening of 1 cm ⁇ 1 cm provided in the food material drying container 30.
  • the food drying container 30 was formed by connecting five food storage shelves 31 in parallel to each other.
  • Ingredients F are all non-standard in size and shape, and are carrots, grated burdock, burdock, and potato cut in advance to about 3 cm x about 1 cm x about 1 cm. It was predried by the drying method. A total of 5 kg was placed on the above-described 15-stage (three-stage ⁇ 5) food shelves 31, and heated hydrogen gas was injected from below.
  • a food drying container 30 having a “primary outlet 36 for water vapor and reflux hydrogen gas” and a “reflux hydrogen gas introduction nozzle 34” as shown in FIG. 2 is used.
  • the reflux hydrogen gas once used for drying was also used.
  • the refluxed hydrogen gas was dehumidified by passing through a dehumidifying device 40 provided with a dehumidifying filter 41 therein, and was made 35 ° C. and jetted upward from the bottom of the food drying container 30.
  • the time required from the start of drying to the end of drying was 10 minutes.
  • vitamins and enzymes were not decomposed (denatured) or inactivated and remained as they were.
  • the starch remained as beta starch.
  • the obtained vegetable chip was useful as a preserved food and a nutritional food.
  • Example 2 The foodstuff F was dried using the foodstuff drying apparatus 10 schematically shown in FIG. 3, and the same procedure as in Example 1 was used except that the fish preliminarily dried by a normal drying method was used until the water content reached 15% by mass. And dried.
  • Ingredient F is put in from the charging hopper, and hydrogen gas at 35 ° C. obtained in the same manner as in Example 1 is introduced into an “elongated and spirally shaped ingredient drying container 30” having an elliptical protrusion inside. Circulated.
  • the time required from the start of drying to the end of drying was 10 minutes.
  • the obtained fish meal was not decomposed (denatured) or inactivated, and remained as it was, and was useful as a preserved food, nutritional food, cooking additive, sprinkles and the like.
  • Example 1 drying was performed in the same manner as in Example 1 except that air was used instead of hydrogen gas, but 1 hour which was about 7 times as long as Example 1 from the start of drying to the end of drying. It took 10 minutes.
  • FIG. 5 to FIG. 7 An example of Aspect 2 is shown in FIG. 5 to FIG. 7, but “the reference numerals used in FIG. 5 to FIG. 7” and “the reference numerals in the description of Aspect 2 below” are applied only to Aspect 2. To do. That is, “the reference numerals in the description of the aspect 2 described below” correspond to “the reference numerals used in FIGS. 5 to 7”, and the same reference numerals are used in other aspects and other drawings. There may be.
  • Aspect 2 of the present invention is an antioxidant effect imparting device comprising the above hydrogen fluid closed cycle device, An antioxidant action imparting device characterized by comprising at least the following (a), (b) and (R2).
  • (A) Hydrogen gas generator for generating hydrogen gas by chemical reaction (b) Hydrogen gas temperature rise control device (R2) for raising the temperature of the hydrogen gas generated by the above (a) hydrogen gas generator (R2)
  • R2 Hydrogen gas temperature rise control device
  • the hydrogen gas Hydrogen gas inhalation mask that allows a human to inhale, or a hydrogen gas discharge filling container that makes the hydrogen gas contact a human or a part of the human
  • the hydrogen gas generator 2 used in the embodiment 2 of the present invention generates hydrogen gas by a chemical reaction. That is, “(1) a hydrogen gas generator for generating hydrogen gas” of the present invention is “(a) a hydrogen gas generator for generating hydrogen gas by a chemical reaction”. By generating hydrogen gas through a chemical reaction in the device provided in the antioxidant device 1, no intermediate product such as hydrogen water is required, and the hydrogen gas generator 2 does not consume electricity. Compactness can be achieved.
  • the one that can generate hydrogen gas by bringing the alkaline water 11 into contact with the metal 12 is the hydrogen necessary for the antioxidant effect imparting device of the present invention.
  • the amount is sufficient; since hydrogen gas of at least 1130 L can be obtained from 1 L of alkaline water, it can be made more compact, and costs such as cylinder charges and electricity charges are not required; See FIGS.
  • alkaline water before hydrogen gas generation obtained from natural products such as natural stone (limestone, etc.), shells, and meteorites has a very high calcium ion concentration. Containing water is obtained as a by-product.
  • FIG. 5A shows an outline of the hydrogen gas generator 2.
  • the generation of hydrogen in the hydrogen gas generator 2 is preferably caused by bringing the alkaline water 11 into contact with the metal 12.
  • the metal 12 includes alloys, and includes those processed into metal-containing materials.
  • the metal element is preferably a metal such as aluminum (Al), zinc (Zn), titanium (Ti), tin (Sn), etc., from the viewpoints of safety, cost (inexpensive), and useful products.
  • Aluminum (Al) is particularly preferable.
  • the metal 12 is also preferably a metal having a high ionization tendency.
  • the pH of the alkaline water is not particularly limited, but is preferably 12 or more, more preferably 12.5 or more, and particularly preferably 13 or more.
  • a stoichiometric amount of hydrogen gas of at least 1130 L can be obtained from 1 L of alkaline water in a standard state.
  • the amount of hydrogen gas used in the apparatus of the invention is sufficient.
  • the alkaline water 11 is not particularly limited, but it is particularly preferable to obtain the alkaline water 11 from natural products such as natural stones (limestone, etc.), shells, meteorites and the like because they are environmentally friendly. Further, even after the alkaline water 11 is brought into contact with a metal 12 such as aluminum (Al) to generate hydrogen gas, it can be taken orally without filtration by a technical operation method in which no aluminate is deposited. From that point, it is also environmentally friendly.
  • a metal 12 such as aluminum (Al) to generate hydrogen gas
  • Hydrogen gas generated by the hydrogen gas generator 2 is sent to the hydrogen gas suction mask 17 or the hydrogen gas discharge full container 27 through the hydrogen gas introduction pipes 15 and 23. In the meantime, it is preferable to pass through a dehumidifying filter 18 (not shown in FIG. 6) as shown in FIG.
  • a hydrogen gas temperature rise control device 3 for raising the temperature of the hydrogen gas is provided on the way.
  • the pressure is increased and the hydrogen gas is discharged or injected into the hydrogen gas discharge container 27 by using a nozzle, and the following effects are also achieved.
  • it is essential to provide a hydrogen gas heating device and a temporary storage tank (not shown in FIGS. 6A and 6B and FIG. 7).
  • the hydrogen gas heating device and the temporary storage tank may be installed before or after the hydrogen gas temperature increase control device 3, and the temperature rising portion or the like may be installed in the hydrogen gas temperature increase control device 3. It may be combined with the control device 3.
  • the appropriate temperature of hydrogen gas makes you feel better, increases the temperature of the human body, part of the human body, or the whole body, improves the basal body temperature, and improves blood circulation (blood flow Immunity is increased, and leukocytes are also increased and activated. It may also increase metabolic capacity and promote insulin secretion.
  • blood flow Immunity is increased, and leukocytes are also increased and activated. It may also increase metabolic capacity and promote insulin secretion.
  • the cancer cells exceed about 42 ° C., the proliferation is suppressed and apoptosis (self-destruction) is promoted, and as a result, the cancer cells may be reduced.
  • the antioxidant effect imparting device 1 is such that the hydrogen gas temperature raising control device 3 can be raised stepwise while controlling the temperature of the hydrogen gas at least in the range from 15 ° C. to 45 ° C. It is preferable that it is what is.
  • the preferred rate of temperature rise is gradually from the body temperature (about 36 ° C), preferably gradually over 2 minutes to 5 minutes, and raised to a maximum of 45 ° C ⁇ 1 ° C. This is preferable because there is little shock to heat, and hydrogen gas penetrates from the skin tissue into the blood and deep parts of the body (for example, cell walls, cell membranes, cell nuclei, bone marrow, etc.).
  • the time taken from 36 ° C. to 45 ° C. varies depending on the individual, but is more preferably 5 minutes to 20 minutes, and particularly preferably 10 minutes to 15 minutes, but is not limited thereto. Thereafter, keeping for 20 minutes or more is preferable in order to obtain the effect of the present invention.
  • Hot hydrogen gas inhalation mask Based on FIG. 5, an antioxidant action imparting device 1 having a hydrogen gas inhalation mask 17 for allowing a human to inhale the generated hydrogen gas will be described.
  • the aspect 2 of the present invention is limited to the specific aspect of FIG. 5. Is not to be done.
  • FIG. 5 is connected to a bottle main body containing alkaline water 11 (alkaline ion warm water) and metal 12, a connecting bottle 14, and a hydrogen gas introduction pipe 15 through which hydrogen gas passes, so that a medical condition, etc.
  • a hydrogen gas suction mask 17 having an appropriate shape corresponding to the application is connected (FIG. 5A).
  • FIG. 5B shows a state in which a human is sucking hydrogen gas from the hydrogen gas suction mask 17.
  • the metal 12 may be moored to the lid 13 so that it can be taken in and out as the lid 13 is opened and closed (may be detachable).
  • the bottle body preferably contains a medicinal component, an aroma component, and the like together with the alkaline water 11. It is also preferable to provide a dehumidifying filter 18 between the hydrogen gas introduction pipe 15 and the hydrogen gas suction mask 17.
  • the hydrogen gas suction mask 17 When the hydrogen gas suction mask 17 is used, it may not be provided to make the apparatus compact, but it is also preferable to provide the hydrogen gas temperature rise control device 3 to raise the temperature of the hydrogen gas.
  • the blood circulation In the case of warmed hydrogen gas, the blood circulation is increased, so that a more preferable result can be obtained quickly and the effect of the above-mentioned “warmed hydrogen gas” can be obtained.
  • Air is also inhaled at the same time, but air is only carried from the alveoli into the body, but hydrogen also penetrates into the obstructed brain.
  • the antioxidant effect imparting device 1 in FIG. 6A includes a hydrogen gas discharge filling container 27 that is brought into contact with the “whole body or body below the human neck”, and the antioxidant effect in FIG. 6B.
  • the applying device 1 includes a hydrogen gas discharge filling container 27 that is brought into contact with “a part of a person”.
  • FIG. 6B shows an example of a breast, but “part of a human” is not limited, and examples thereof include a breast, a torso, a back, a chest, a waist, and a limb.
  • the “part of human” is preferably an affected area, and a lymph gland is also preferable.
  • the normal temperature hydrogen gas generated from the hydrogen gas generator 2 enters the hydrogen gas temperature rise control device 3 through the hydrogen gas introduction pipe 23.
  • the configuration of the hydrogen gas temperature increase control device 3 is not particularly limited, but hydrogen gas enters the “spiral tube tube immersed in the thermostatic bath” and gradually increases in temperature while being controlled within the above temperature range. It is preferable that it is such.
  • the hydrogen gas heated to an appropriate temperature is guided to the hydrogen gas discharge full container 27 at the upper part of the mat 24 and comes into contact with a human.
  • the hydrogen gas discharge filling container 27 for bringing the hydrogen gas into contact with the human is, for example, one that contacts (contacts) the hydrogen gas toward the human (the whole) from a porous film vent pipe. Is preferred.
  • the hydrogen gas filling the hydrogen gas discharge filling container 27 contacts the human body, a part of the hydrogen gas penetrates and penetrates deep into the body, and then, for example, is installed in the upper part or the like.
  • the hydrogen gas discharge port 25 passes through the hydrogen gas return pipe 26 and circulates to the hydrogen gas temperature raising control device 3.
  • a drain trap 28 containing a dehumidifying material 31 is preferably provided in the middle, preferably in a vertical part, and moisture in the hydrogen gas is preferably removed by the drain trap 28 (FIG. 6A). .
  • the hydrogen gas from which moisture has been removed again enters the hydrogen gas temperature increase control device 3 and is circulated after being heated.
  • a hydrogen gas inhalation mask 17 as shown in FIG. 5 (a) is used in combination with a hydrogen gas discharge / filling container 27 for "the whole human body or the body below the human neck” as shown in FIG. 6 (a). May be. Warm hydrogen gas aspirated (with air) from the oral cavity, nasal cavity, etc. through the hydrogen gas inhalation mask 17 is taken into the body and brain tissue.
  • the antioxidant effect imparting device 1 of FIG. 6B includes a hydrogen gas discharge filling container 27 that is brought into contact with a breast that is “a part of a human being”. 6A, the hydrogen gas that has passed through the hydrogen gas introduction pipe 23 from the hydrogen gas generator 2 is heated through the thermostatic bath, and passes through the hydrogen gas introduction pipe 23. The hydrogen gas discharge filling container 27 is discharged or filled therein. Hydrogen gas is radiated to the affected area under the control of the temperature range and the rate of temperature increase, and the temperature is gradually raised from about 36 ° C. and heated to a maximum of about 45 ° C. At this time, a flexible cloth may be applied between the body and the body.
  • the thermal conductivity of hydrogen gas is much higher than that of air, nitrogen gas, water vapor, methane gas, fluorine gas, or the like.
  • the thermal conductivity of hydrogen gas is higher than that of helium gas, which is known for its extremely high thermal conductivity.
  • hydrogen gas has high permeability and permeability to objects. Due to its high permeability, when it comes into contact with humans, it easily penetrates into the inside (for example, cells and organs).
  • a particularly preferred embodiment of the invention will be described as part of a human being, for example but not limited to the breast.
  • the hydrogen gas generated from the hydrogen gas generator 2 is subjected to precise temperature control in a thermostatic chamber in the heating tube of the hydrogen gas temperature rise control device 3, and is gradually heated from room temperature, and then the radiant cup ( Radiated from the hydrogen gas-filled container 27) to the affected area (breast), gradually heated from 36 ° C and heated to 45 ° C. Since the temperature rises gradually, there is no shock to the heat. Since hydrogen is light, the radiation cup (hydrogen gas discharge full container 27) needs to be directed from the bottom to the top. At this time, you may apply a flexible cloth between affected part positions. Hydrogen penetrates and permeates with heat from skin tissue to blood and deep cells and organs. In particular, cancer cells are vulnerable to heat and self-destruct at around 42 ° C.
  • FIG. 7 Using FIG. 7 as an example, a particularly preferred embodiment of Embodiment 2 of the present invention will be described.
  • the concave portion of the mat 24 formed with irregularities there are several rows of vent pipes 29 and dozens of vent holes 30, and the vent holes 30 are heated and heated to an appropriate temperature by the hydrogen gas temperature rise control device 3 such as a thermostatic bath. Hydrogen gas is injected and emitted into the body (FIGS. 7A and 7D).
  • the convex portion of the rug such as the mat 24 functions as a cushion for humans.
  • a cloth that absorbs sweat The cloth may be the clothes of the human body.
  • the upper portion of the mat 24 is covered with an aluminum laminated sheet to protect the hydrogen gas from leaking.
  • An example of a preferable material for the hydrogen gas container 27 and the mat 24 is shown in FIG.
  • the material is preferably a laminate of aluminum foil.
  • a hydrogen gas return pipe 26 that collects and recirculates the hydrogen gas that has contacted (penetrated) the body is connected to a substantially central portion of the sheet.
  • the hydrogen gas return pipe 26 is made of an aluminum foil laminated pipe material 32, and it is preferable that a dehumidifying material 31 for adsorbing moisture in hydrogen gas containing moisture evaporated and sweated by heat is inserted in the inner diameter of the pipe ( FIG. 7B).
  • a drain trap 28 for discharging these moisture is installed below the hydrogen gas return pipe 26.
  • An appropriate amount of hydrogen gas discharged from the hydrogen gas generator 2 through a valve is released from the vent hole 30 via a hydrogen gas heating device and a temporary storage tank. Specifically, it enters a heating tube set inside a thermostatic chamber which is the hydrogen gas temperature raising control device 3, is heated to an appropriate temperature and gradually heated, and the hot hydrogen gas is a number inside the mat 24. It is discharged from the lower side of the human body toward the human body through the vent holes 30 of the dozens of vent pipes 29 in a strip. Since hydrogen gas is light, it diffuses immediately to the upper side, so it is preferable to discharge from the lower side (FIG. 7A).
  • FIGS. 8 to 13 An example of the aspect 3 is shown in FIGS. 8 to 13, but “the reference numerals used in FIGS. 8 to 13” and “the reference numerals in the description of the aspect 3 below” are applied only to the aspect 3. To do. That is, “the reference numerals in the description of the aspect 3 described below” correspond to “the reference numerals used in FIGS. 8 to 13”, and the same reference numerals are used in other aspects and other drawings. There may be.
  • Aspect 3 of the present invention is a hydrogen fluid closed cycle drive / power generation device including the above hydrogen fluid closed cycle device, A hydrogen fluid closed cycle drive / power generation device comprising at least all of the following (R3) and (R4): (R3) Drive unit including a turbine that rotates when hydrogen gas is injected from the temporary storage tank (R4) Fluid generator that generates power by rotating the rotor blades when hydrogen gas is injected from the temporary storage tank
  • the present invention comprises (1) a hydrogen gas generator, (2) a hydrogen gas heating device and a plurality of temporary storage tanks, and (R) a hydrogen gas utilization device, and (R) a hydrogen gas utilization device.
  • the apparatus has the (R3) driving device and (R4) fluid power generator.
  • the hydrogen fluid closed cycle drive / power generation apparatus 01 of the present invention includes (1) a hydrogen gas generator 11.
  • Generation of hydrogen in the hydrogen gas generator 11 is not particularly limited, but is caused by bringing alkaline water into contact with a metal. That is, it is preferable that the hydrogen gas generator 11 in the present invention is configured to generate hydrogen gas by bringing alkaline water into contact with a metal.
  • the metal element is preferably a metal such as aluminum (Al), zinc (Zn), titanium (Ti), tin (Sn), etc., from the viewpoints of safety, cost (inexpensive), and useful products.
  • Aluminum is particularly preferred. Particularly in the case of aluminum, the reaction product is particularly preferable because it can be used as a purification material after filtration. Further, as the metal, a metal having a high ionization tendency is also preferable.
  • the pH of the alkaline water is not particularly limited, but is preferably 12 or more, more preferably 13 or more, and particularly preferably 13.5 or more.
  • a stoichiometric amount of hydrogen gas of at least 1130 L can be obtained from 1 L of alkaline water in a standard state, which is sufficient as the amount of hydrogen gas.
  • alumina does not precipitate due to the reaction between the metal and the alkaline ionized water, filtration is not necessary, and the residual water is very effective as a clear and useful oral water. This technical operation has already been found.
  • the alkaline water is not limited, it is particularly preferable to obtain it from natural products such as natural stones (limestone, etc.), shells, meteorites and the like because they are environmentally friendly.
  • natural products such as natural stones (limestone, etc.), shells, meteorites and the like because they are environmentally friendly.
  • ionized alkaline water is obtained.
  • the alkaline water is brought into contact with a metal such as aluminum (Al) to generate hydrogen gas.
  • the generated hydrogen gas generated by the hydrogen gas generator 11 can be used. It is preferable to supplement the recirculated hydrogen gas in a shortage due to leakage with the generated hydrogen gas.
  • the critical temperature of hydrogen is 33K (-240 ° C).
  • the hydrogen gas heating apparatus is used by heating the hydrogen gas in a sealed container (sealed container) such as the temporary storage tank 13 to preferably 400 ° C. or lower. . See FIGS.
  • residual water after hydrogen gas generation can be extracted and substances such as generated aluminate can be removed.
  • the filtered water of the residual water can be taken orally and can be used effectively for other purposes such as aquaculture water.
  • Aluminic acid (salt) can also be effectively used as a purifier.
  • the hydrogen gas generator 11 is created by creating water with a high hydrogen ion concentration by a special method from natural resources with excellent environmental characteristics.
  • the hydrogen gas generator 11 is submerged in water with an inexpensive catalyst moored in the high ion concentration water. Since hydrogen gas is continuously generated, pure metal gas is produced by adding the metal in a timely manner when necessary. Therefore, a pressure-resistant container is not necessary, and a simple alkali-resistant resin container (for example, polyethylene, polypropylene, etc.) is sufficient.
  • the water used as the source of hydrogen gas generation used in the present invention is preferably used for medical purposes or foods.
  • seawater or terrestrial water is used as the water to produce alkaline water. Ionic water may be used.
  • seawater there are many mineral components, and more hydrogen gas is produced (already tested).
  • Hydrogen gas may be hydrogen alone (pure), but other gases can be mixed and used as a mixed gas.
  • the mixed gas has an effect of preventing “hydrogen embrittlement inherent to hydrogen gas” to the furnace body and the like.
  • hydrogen gas and “another inert gas such as carbon dioxide, nitrogen, argon, helium” are particularly preferable.
  • nitrogen, carbon dioxide and the like are more preferable.
  • carbon dioxide (CO 2 ) critical point: 31.1 ° C., 7.4 MPa) having a good cost performance is particularly preferable.
  • a mixed gas in which 95 to 98 parts by volume of hydrogen gas and 2 to 5 parts by volume of carbon dioxide gas are mixed is preferable.
  • the mixing ratio for example, “95% by volume of hydrogen, 5% by volume of carbon dioxide (CO 2 )”, “98% by volume of hydrogen, 2% by volume of helium” and the like are particularly preferable.
  • Hydrogen gas is a supercritical fluid even at a low temperature (for example, around 100 ° C.), the entire apparatus is light, no weight design is required, and the cost is low.
  • the engine apparatus can be manufactured by a 3D printer.
  • the hydrogen fluid closed cycle drive / power generation device 01 includes (2) a hydrogen gas heating device 12 that temporarily raises the pressure of the hydrogen gas by raising the temperature of the hydrogen gas generated by the hydrogen gas generator 11, and a temporary A mechanical storage tank 13 is provided.
  • the hydrogen gas heating device 12 and the temporary storage tank 13 are configured so that the hydrogen gas in the sealed temporary storage tank 13 is 400 ° C. or less. It is preferable to heat and use.
  • the heated hydrogen gas sequentially enters the temporary storage tank 13 (preferably 2 to 4 units), and after the sealed state has passed for about 1 to 2 minutes, the hydrogen gas is increased in pressure even in a low temperature region (50 ° C.). At this time, it becomes a supercritical fluid, and its pressure becomes about 20 MPa or more. Although the pressure of the hydrogen is increased, the storage time in the temporary storage tank 13 is only a few minutes, and an advanced pressure-resistant tank is not required, and the discharge is sequentially performed after 1 to 2 minutes, which is safe.
  • This high-pressure supercritical hydrogen sequentially flows into the pipe through the pressure control valve and the injection device, and is heated and temporarily stored in the fluid power generator 14 without burning the hydrogen gas.
  • the rotating blades are rotated at high speed by the hydrogen gas fluid generated to generate power from the drive shaft. It is preferable to evacuate the piping of each piece of equipment and the inside of the power engine in advance and then inject after filling with a mixed gas such as heated hydrogen gas or “hydrogen gas and carbon dioxide”. This is a common matter of the apparatus of the present invention (applied to plants, automobiles, etc.).
  • Hydrogen gas pressurized by heating with the heated steam 16 or the like enters a compression device such as a compression scroll engine, a rotary engine, or a single-shaft turbine, which is a power engine, and is driven and compressed through an exhaust port. Circulate and reflux again. Thus, it is non-atmosphere and low temperature, and it is possible to create driving force and electric power in various environments such as outer space, deep underground space, and highland.
  • a compression device such as a compression scroll engine, a rotary engine, or a single-shaft turbine, which is a power engine, and is driven and compressed through an exhaust port. Circulate and reflux again.
  • it is non-atmosphere and low temperature, and it is possible to create driving force and electric power in various environments such as outer space, deep underground space, and highland.
  • Hydrogen gas exiting from the hydrogen gas generator 11 enters a spiral heating tube or the like from the introduction pipe, is heated by the hydrogen gas heating device 12, enters the temporary storage tank 13, and is pressurized.
  • the hydrogen gas heating device 12 is used by heating the hydrogen gas in the temporary storage tank 13 to 400 ° C. or less.
  • the pressurized hydrogen gas is injected toward the intake port of the fluid power generator 14 to drive the rotor blades.
  • the pressurized hydrogen gas from the exhaust port merges with the fluid ejected from the temporary residual heat storage tank on the lower side, and returns to the temporary storage tank 13 again while driving the next rotor blade via the aspirator. It is heated and circulated with heated steam 16 (for example, about 300 ° C.).
  • the hydrogen fluid closed cycle drive / power generation device 01 includes (3) a drive device including a turbine that rotates when hydrogen gas is injected.
  • the hydrogen fluid closed cycle drive / power generation device 01 of the present invention includes (4) a fluid power generator that generates power by rotating the rotor blades when hydrogen gas is injected.
  • An alternator linked to the operating shaft of the rotor blade of the fluid power generator 14 generates power in a closed cycle manner, and drives or partially charges the storage battery 19.
  • a catch pan 17 is set at the lowermost part, and is discharged and collected from the drain trap 17. Excess process steam may be refluxed. Since this device (system) is basic, it can be used for, for example, those described later, and can be widely applied to disasters, private power generation, cars, ships, trains, submarines, space navigation, and the like.
  • Microwave excited water plasma heating device 12 is heated using microwaves or the like as non-atmosphere.
  • the mode and characteristics of the microwave-excited underwater plasma heating device 12a, which is a particularly preferable mode of the hydrogen gas heating device 12, will be described below with reference to FIG.
  • the microwave is initially driven by electricity from the storage battery 19.
  • 1 The configuration is such that the rotor blades are rotated at high speed with supercritical hydrogen gas, the structure is simple without using an internal combustion engine or a compression device, and maintenance is easy and quiet.
  • 2 Hydrogen is not combusted, is used in a closed cycle, and is not fuel. A high-pressure tank is unnecessary and safe, and hydrogen gas is generated when a metal that chemically reacts when necessary and moored together with a weight, and generation stops when removed.
  • 3 The catalyst of underwater plasma is a permanent catalyst. 4: Exhaust gas is zero and power can be generated indoors. Further, air (oxygen) is not necessary and can be used in a non-atmospheric space.
  • I POWER inorganic heating board that generates heat by microwaves can also be used semi-permanently. 6: Since the power generation stops when the start of the microwave is stopped, it may be started when power is required. A microwave output of 100 to 200 W is sufficient.
  • FIG. 10 shows a compression scroll type engine drive / power generation device 02 as an application example of the hydrogen fluid closed cycle drive / power generation device 01 of the present invention.
  • the compression scroll type engine drive / power generation device 02 is a device that drives and / or generates power with the scroll type engine 32, and uses compression (expansion) scroll type engine drive / power generation, and is applied to private power generation, automobiles, and the like.
  • Hydrogen gas sequentially generated from the hydrogen gas generator 11 reaches a critical point at room temperature.
  • this hydrogen gas or hydrogen mixed gas When this hydrogen gas or hydrogen mixed gas is injected from the sealed temporary storage tank 13 and flows as the scroll engine 32 through the suction port 34 near the center of the fixed blade, it is compressed between the movable blades and is pressurized. And expand, and the rotation shaft at the center can be rotated and driven.
  • the expanded hydrogen gas moves to the exhaust port 35, returns to the original temperature, and returns to the circulation pipe 36 from the discharge port.
  • the hydrogen gas returns to the center of the scroll type engine 32 again, is compressed and pressurized, and repeatedly performs a closed cycle operation.
  • the pressure is preferably 8 MPa or more. It is a closed-cycle operation and basically does not require fuel. Drive and power generation are possible from this rotating shaft.
  • the speed can be controlled by adjusting the flow rate of hydrogen gas with an accelerator pedal, and the engine brake is applied when the accelerator is released. Since the power is generated by the compression scroll engine 32, it can be said to be a “self-generated power vehicle”. Hydrogen gas is generated by the above-described chemical reaction from the loaded water and is driven by a continuous compression process, so it is extremely safe without the need for loading compressed liquefied hydrogen gas.
  • FIG. 11 shows a rotary engine drive / power generation device 03 as an application example of the hydrogen fluid closed cycle drive / power generation device 01 of the present invention.
  • the normal temperature hydrogen gas reaching the critical point is sucked into the suction port 34, and the pressure is increased in the sealed temporary storage tank 13, and is injected into the rotary engine 41 from the pressure regulating valve.
  • the rotary engine 41 is driven in the step (3) in which the pressure is further increased and the pressure becomes higher and higher in (4), and the body is rotated by the body expansion pressure.
  • the compression ratio of a normal rotary engine is 7-8, and hydrogen gas is 10 atmospheres or more in a supercritical fluid state.
  • the hydrogen in the step (3) in which the expansion is completed decreases in temperature, exits from the exhaust port 35, circulates, returns to the intake port 34 from the circulation pipe 36, and repeatedly performs closed cycle driving and power generation.
  • This rotary type engine drive / power generation device uses an engine drive system that is completely different from the combustion of ordinary fossil fuels, and is the most suitable environmental technology for global warming countermeasures, air pollution countermeasures, and resource reduction. Even with a normal diesel engine or reciprocating engine, the present invention can be carried out with a slight improvement. However, since there is metal embrittlement inherent to hydrogen gas, it is preferable to use a mixed gas of 95% by volume of hydrogen gas and 5% by volume of carbon dioxide, or the equipment is manufactured by ceramic spraying.
  • FIG. 12 shows a (non-atmosphere) single-shaft closed cycle turbine 53 and a single-shaft turbine engine drive / power generation device 04 as an application example of the hydrogen fluid closed cycle drive / power generation device 01 of the present invention.
  • the sealed temporary storage tank 13 is filled with hydrogen gas (mixed gas) for preheating.
  • the hydrogen gas (mixed gas) heated by the hydrogen gas heating device 12 is temporarily stored to increase the pressure.
  • the microwave-excited underwater plasma heating device 12a is provided with a gas heating tube, and the sunlight / waste heat / steam heating device 12b is provided with a hydrogen gas heating two-layer tank.
  • Compressed return gas is injected to the main turbine side and driving force is improved.
  • the gas exhausted from the single-shaft (closed cycle) turbine 53 returns to the microwave-excited underwater plasma heating device 12a again through the heat exchanger 55, is again heated and stored, returns to the compressor in a high-pressure state, and is driven. It becomes a cycle to repeat.
  • the fluid generator 54 and the drive motor 56 (generator possible) interlocked with the single-shaft turbine shaft are driven.
  • the temperature is about 100 ° C. and the pressure is about 20 MPa to about 35 MPa.
  • closed cycle power generation can be performed even at low temperatures.
  • Various waste heat, natural energy such as sunlight and geothermal ocean temperature difference can be recovered.
  • the hydrogen fluid closed cycle drive / power generation device 01 of the present invention can be used (mounted) in a power engine such as an automobile or a ship.
  • FIG. 13 shows a case where the hydrogen fluid closed cycle drive / power generation apparatus 01 of the present invention is applied to an automobile (for example, a new hybrid car) 05 as an application example.
  • the new hybrid vehicle 05 using the hydrogen fluid closed cycle drive / power generation device 01 of the present invention achieves both a driving motor propulsion force and a power generation function.
  • 1 Driven by motor 65 only when starting.
  • the motor 65 is an AC synchronous motor and preferably has a three-phase AC.
  • 2 During low-speed traveling with closed-cycle main power, the closed-cycle engines 02 and 03 are divided into two systems by the power split mechanism 64. One drives the motor through a path for generating electricity by driving the generator, and the other directly rotates the wheels via the gear transmission 66.
  • 3 When accelerating, it accelerates with two powers. By adding “engine driving force and power from the storage battery 19” and “high-power motor driving force”, smooth power performance with good response is exhibited and acceleration performance is improved.
  • the wheels and drive shaft 67 act on the motor 65 to operate the high-output motor (power control unit 63) as a generator to convert the braking energy of the car into more power. It acts as a highly efficient regenerative brake, and the collected electric power charges the storage battery 19.
  • the power control unit (PU) 63 has a function of converting a direct current and an alternating current to adjust a power supply voltage, and preferably includes an inverter, a variable voltage system, and a DC / DC converter.
  • the power split mechanism 64 is preferably linked to the drive train and the generator by various gears in the planetary gear mechanism.
  • the regenerative brake refers to a motor that rotates when electricity is applied, but generates electric power as a generator when rotated by an external driving force.
  • the hydrogen gas in the present invention has characteristics such as a critical point at low temperature, extremely high thermal conductivity, safety without oxygen, and an antioxidant effect, and is easy to raise and pressurize. Because it is physically and chemically safe, non-toxic and safe for the living body, it is a closed cycle that does not use the atmosphere, exhaust gas is not emitted, the atmosphere is not polluted, and the environment is not burdened. It can be used in various fields.
  • the food drying method and the food drying apparatus using the hydrogen gas of aspect 1 of the present invention as a drying medium are particularly excellent in drying efficiency and the like, and the raw material is also targeted for non-standard products, waste products, etc. Ingredients that are difficult to handle, large ingredients, etc. are also targeted, and the resulting dried ingredients are used in various applications, so they are widely used in food processing industries, household food industries, agriculture, fisheries, waste disposal industries, etc. It is what is used.
  • the antioxidation-effect imparting device is an anti-oxidation effect imparting device that has a hydrogen gas inhaled by a human inhalation or is brought into contact with the whole human or “part of an affected area”. Since the disease can be cured or relaxed by oxidizing and preferably raising the immunity by raising the temperature, it is widely used in the field of health equipment, the medical field, and the like.
  • the hydrogen fluid closed cycle drive / power generation device is a closed cycle, does not put a load on the environment, and has low risk. It is widely used in all fields.
  • FIG. 1 Alkaline water 2: Hydrogen gas generator 3: Microwave excitation: Heating part 4: Hydrogen gas introduction heating tube 5: Water 6: Water vapor 7: Temporary storage tank 8: Preliminary drain 9: Heated hydrogen gas injection hole DESCRIPTION OF SYMBOLS 10: Drying furnace 11: Shelf sliding mesh drying net 12: Recirculating hydrogen gas 13: Drain trap 14: Drain water 15: Metal 16: Filtration device 17: Filtration water 18: Catalyst mooring lid 19: Microwave unit 20: Vertical Dehumidifying material 21 in piping: Piping 22: Process steam

Abstract

Provided is a hydrogen fluid closed cycle device that includes (1) a hydrogen gas generator which generates hydrogen gas, (2) a hydrogen gas heating device and a temporary storage tank which raise the pressure of the hydrogen gas by raising the temperature of the hydrogen gas emitted from (1) the hydrogen gas generator, and (R) a hydrogen gas utilization device which utilizes the hydrogen gas emitted from (2) the hydrogen gas heating device and the temporary storage tank. Also provided are a foodstuff drying device, an antioxidative effect imparting device, and a hydrogen fluid closed cycle driving and power generating device provided with the hydrogen fluid closed cycle device.

Description

水素流体閉サイクル装置Hydrogen fluid closed cycle equipment
　本発明は、水素流体を用いる、食材乾燥装置、抗酸化作用付与装置、駆動・発電装置、動力機関等の水素流体閉サイクル装置、及び、該装置を用いた方法に関するものである。 The present invention relates to a hydrogen fluid closed cycle apparatus such as a food drying apparatus, an antioxidant action imparting apparatus, a drive / power generation apparatus, and a power engine using a hydrogen fluid, and a method using the apparatus.
　食品、食品廃棄物等の食材は、保存するため、美味しくさせるため、体積を減少させるため、所望の形状にするため、栄養分を濃縮させるため、別形態の食材として再生させるため等に乾燥することが知られている（特許文献１～８）。 Food, food waste, and other foodstuffs must be dried for storage, to be tasty, to reduce volume, to have the desired shape, to concentrate nutrients, and to regenerate as other forms of foodstuffs, etc. Are known (Patent Documents 1 to 8).
　例えば、特許文献１～４には、空気で食材を乾燥する方法が記載されている。
　特許文献１には、食品加工残渣等の食品廃棄物を、温風で乾燥する方法が記載されており、特許文献２には、密閉容器内で食品原料を粉砕しながら熱風で乾燥する方法が記載されている。
　特許文献３には、多数の通気孔を有するコンベア上の食品に、除湿冷気を衝突させる食品の乾燥方法が記載されており、特許文献４には、冷凍機で作った乾燥空気を、向きを変えて送風する冷風乾燥装置が記載されている。 For example, Patent Documents 1 to 4 describe a method of drying food with air.
Patent Document 1 describes a method of drying food waste such as food processing residues with hot air, and Patent Document 2 discloses a method of drying with hot air while crushing food raw materials in a sealed container. Are listed.
Patent Document 3 describes a method for drying food that causes dehumidified cold air to collide with food on a conveyor having a large number of ventilation holes. Patent Document 4 describes the direction of drying air produced by a refrigerator. A cold air drying device that blows air in a changed manner is described.
　特許文献５～８には、空気以外の気体で食材を乾燥する方法が記載されている。
　特許文献５には、食材を処理する装置であって、過熱水蒸気等のガス状媒体を「螺旋形状のコンベアベルトの水平方法と垂直方向から案内する」通路を有する乾燥装置が記載されており、特許文献６には、減圧下で低温（１００℃以下）の過熱水蒸気で食品材料を乾燥する方法が記載されている。 Patent Documents 5 to 8 describe a method of drying a food material with a gas other than air.
Patent Document 5 describes an apparatus for processing foodstuffs, and a drying apparatus having a passage for guiding a gaseous medium such as superheated steam from a horizontal direction and a vertical direction of a spiral conveyor belt, Patent Document 6 describes a method of drying a food material with superheated steam at a low temperature (100 ° C. or less) under reduced pressure.
　特許文献７には、二酸化炭素又は亜酸化窒素からなる超臨界媒体を接触させて食用粒子を生成する方法が記載されており、特許文献８には、ガスを循環させて食材を乾燥させる方法において、該ガスとして、酸素濃度１０％以下のガス、純度９０％以上の窒素を用いる方法が記載されている。 Patent Document 7 describes a method for producing edible particles by contacting a supercritical medium made of carbon dioxide or nitrous oxide, and Patent Document 8 describes a method for drying food by circulating gas. As the gas, a method using a gas having an oxygen concentration of 10% or less and nitrogen having a purity of 90% or more is described.
　このように、食材の乾燥に用いる気体の種類は極めて限られており、乾燥のためのガスの種類に着目し、乾燥効率の極めて優れた乾燥方法については殆ど知られていなかった。 As described above, the types of gases used for drying foods are extremely limited, and attention has been paid to the types of gases for drying, and there has been little known about drying methods with extremely excellent drying efficiency.
　また、水素ガスには還元性があり、体内において抗酸化作用を有するため、活性酸素等の酸化性物質が引き起こす体内の種々の悪影響を除去することが知られており、水素ガスを体内に摂取する方法や、該方法に使用される装置も種々知られている（例えば、特許文献９～１３）。 In addition, since hydrogen gas is reducible and has an antioxidant effect in the body, it is known to eliminate various adverse effects caused by oxidizing substances such as active oxygen, and ingesting hydrogen gas into the body Various methods and methods used in the method are also known (for example, Patent Documents 9 to 13).
　特許文献９には、水素ガスを「水素を溶解させた水」から発生させ、その水素ガスを鼻から吸入する方法が記載されている。
　特許文献１０、１１、１２には、水の電気分解で発生する水素ガスを鼻又は口から吸入する方法や、吸入マスクについて記載されている。
　特許文献１３には、「水素を溶解させた水」を保持する保水層を皮膚に接触させて、がんを予防・転移抑制する方法やシートが記載されている。 Patent Document 9 describes a method of generating hydrogen gas from “water in which hydrogen is dissolved” and inhaling the hydrogen gas from the nose.
Patent Documents 10, 11, and 12 describe a method for inhaling hydrogen gas generated by electrolysis of water from the nose or mouth, and an inhalation mask.
Patent Document 13 describes a method and sheet for preventing or suppressing cancer by bringing a water retaining layer holding “water in which hydrogen is dissolved” into contact with the skin.
　しかしながら、上記技術で使用する装置は、その内部に、水素ガス発生器を具備するものではなく、水素を溶解させた水（所謂「水素水」）から水素を得ており、一旦「水素水」を製造して、そこから水素ガスを得ると言う無駄な段階をふむものであった。
　また、水の電気分解に電気を使用するものであり、そこで使用する装置は電気を消費するものであり、水蒸気改質法等の工業的エネルギーを使用するものであり、水素ガスを加温してその効果を発揮させることは考えてはいない。 However, the apparatus used in the above technique does not have a hydrogen gas generator inside, but obtains hydrogen from water in which hydrogen is dissolved (so-called “hydrogen water”). It was a wasteful stage to produce hydrogen gas from it.
In addition, electricity is used for electrolysis of water, and the equipment used there consumes electricity, uses industrial energy such as a steam reforming method, and heats hydrogen gas. I don't think that I will show the effect.
　一方、水素を発生させる方法には、水の電気分解以外にも多くが知られており、例えば、アルカリ水と両性金属を接触させる方法、酸性水とイオン化傾向が大きい金属を接触させる方法等が知られている。
　例えば、特許文献１４、１５、１６には、アルカリ水を、アルミニウム、シリコン等に接触させる水素ガスの発生器が記載されている。 On the other hand, many methods other than electrolysis of water are known as methods for generating hydrogen, such as a method of contacting alkaline water with an amphoteric metal, a method of contacting acidic water and a metal having a large ionization tendency, and the like. Are known.
For example, Patent Documents 14, 15, and 16 describe a hydrogen gas generator that brings alkaline water into contact with aluminum, silicon, or the like.
　しかしながら、「水素ボンベも水素水も使用しない特定の水素ガス発生器」と、「特定のヒトに摂取又は接触させる装置」とを、極めてマッチング性良く組み合わせた装置は殆ど知られていなかった。
　また、ヒトに摂取又は接触させる際の水素ガスの温度にまで検討の範囲を広げた技術は存在しなかった。更に、装置全体としてコンパクトにまとめられた装置も殆ど知られていなかった。 However, few devices have been known in which a “specific hydrogen gas generator that does not use hydrogen cylinders or hydrogen water” and a “device that is ingested or brought into contact with a specific human being” are combined very well.
In addition, there has been no technology that extends the scope of the study to the temperature of hydrogen gas when ingested or brought into contact with humans. Furthermore, few devices have been known that are compact as a whole device.
　水素ガスには抗酸化作用があり、ヒトに摂取させることが有望視されてはいるが、上記したように、ヒトに対する水素ガスの接触方法、人に対する摂取装置・方法は極めて限られており、それらに特化した優れた方法に基づく装置の開発が望まれていた。 Although hydrogen gas has an antioxidant effect and is expected to be ingested by humans, as mentioned above, the method of contacting hydrogen gas with humans and the ingestion device / method for humans are extremely limited. Development of an apparatus based on an excellent method specialized for them has been desired.
　また、水素は酸素と反応して熱エネルギーを発生させるので、空気中で燃焼させてタービンを回して電力を得たり、該燃焼による体積膨張を利用して推進力を得たりしている。
　酸素を含有する大気を利用しない閉サイクルのエンジンとして、例えば、特許文献１７には、液体水素と液体酸素を用い、燃焼による体積膨張を利用した直接サイクルエンジンが記載されている。
　特許文献１８には、水素ガスを燃料として、スロットルに特徴のある水素エンジンが記載されている。
　しかしながら、これらは全て、水素を燃焼させてエネルギーを得るものである。 Further, since hydrogen reacts with oxygen to generate thermal energy, it is burned in air and rotated to obtain electric power, or a propulsive force is obtained using volume expansion caused by the combustion.
As a closed-cycle engine that does not use oxygen-containing air, for example, Patent Document 17 describes a direct-cycle engine that uses liquid hydrogen and liquid oxygen and uses volume expansion due to combustion.
Patent Document 18 describes a hydrogen engine characterized by a throttle using hydrogen gas as a fuel.
However, all of these are those that burn hydrogen to gain energy.
　一方、水素は、燃料電池の燃料としても利用され、水素を燃焼させずに電気エネルギーを得るためにも使用されている。
　特許文献１９には、水を電気分解して得た水素を燃料電池の燃料として使用する電気自動車が記載されており、特許文献２０には、メタノールの触媒反応により得た水素を燃料電池の燃料として使用する動力装置が記載されている。
　しかしながら、これらは全て、水素を燃料電池の燃料として用いて電力を得るものであり水素ガスを消耗するものである。 On the other hand, hydrogen is also used as a fuel for fuel cells, and is used to obtain electrical energy without burning hydrogen.
Patent Document 19 describes an electric vehicle that uses hydrogen obtained by electrolyzing water as fuel for a fuel cell. Patent Document 20 describes hydrogen obtained by catalytic reaction of methanol as fuel for a fuel cell. Is used as a power device.
However, they all use hydrogen as fuel for the fuel cell to obtain electric power and consume hydrogen gas.
　水素ガスは、臨界点が低く熱伝導率が高く、酸素が存在しなければ安全であるにも関わらず、燃焼させてエネルギーを得る技術や、燃料電池の燃料とする技術が存在するくらいで、流体として利用して運動エネルギー（推進力、回転駆動等）や電気エネルギー（燃焼によらない流体で回転翼を回転させて発電）を得る技術は殆どない。 Although hydrogen gas has a low critical point and high thermal conductivity, and it is safe if oxygen is not present, there are technologies to obtain energy by burning and fuel cell fuel technologies. There are few techniques for obtaining kinetic energy (propulsion, rotational drive, etc.) or electrical energy (power generation by rotating a rotor blade with a fluid that does not depend on combustion) by using it as a fluid.
特開２００３－２８４５０９号公報JP 2003-284509 A 特開２００６－３１４２３２号公報JP 2006-314232 A 特開２００９－２１３３５７号公報JP 2009-213357 A 特開２０１２－２４１９５６号公報JP 2012-241956 A 特開２００７－５０２６１３号公報JP 2007-502613 A 特開２０１１－１４４９５４号公報JP 2011-144554 A 特表２００９－５３６０２０号公報Special table 2009-536020 gazette 特開２０１６－０３６３０７号公報JP 2016-036307 A 特開２０１６－１８２１５３号公報JP 2016-182153 A 特開２００５－０８７２５７号公報JP 2005-087257 A 特開２０１５－２１７１１６号公報JP 2015-217116 A 特開２０１６－１７２８８３号公報JP 2016-172883 A 特開２００７－２５４４３５号公報JP 2007-254435 A 特開２００４－２１０５９１号公報JP 2004-210591 A 特開２００５－２０６４５９号公報Japanese Patent Laying-Open No. 2005-204559 特開２００７－３２０７９２号公報JP 2007-320792 A 特開平０５－１８７２５２号公報JP 05-187252 A 特開平０８－１３５４８８号公報Japanese Patent Laid-Open No. 08-135488 特開平１１－１１３１０５号公報JP-A-11-113105 特開平１１－３３６５１１号公報JP-A-11-336511
　本発明は上記背景技術に鑑みてなされたものであり、その課題は、特定の気体を用いた新規な装置を提供することにあり、具体的には、新規な食材乾燥方法、食材乾燥装置、新規な乾燥食材の製造方法を提供すること；新規な抗酸化作用付与装置、抗酸化作用付与方法を提供すること；大気を利用しない「非大気エネルギーの閉サイクル」であり、排気ガスが出ず大気を汚染せず環境に負荷をかけず、危険性も低い、駆動力（運動エネルギー）と電力（電気エネルギー）を得る新規な装置、駆動・発電方法を提供することにある。 The present invention has been made in view of the above-described background art, and its problem is to provide a novel apparatus using a specific gas. Specifically, a novel food drying method, a food drying apparatus, Providing a novel dry food production method; Providing a novel antioxidant device and antioxidant method; “Non-atmospheric energy closed cycle” that does not use the atmosphere and does not emit exhaust gas It is an object of the present invention to provide a novel apparatus and driving / power generation method for obtaining driving force (kinetic energy) and electric power (electric energy) that do not pollute the atmosphere, do not impose a load on the environment, and have a low risk.
　本発明者は、上記の課題を解決すべく鋭意検討を重ねた結果、臨界点が低く熱伝導率が高く、酸素がなければ安全である等の特徴を有する水素ガスを用いることで、上記課題を解決できることを見出した。
　具体的には、食材の乾燥に用いる媒体として水素ガスを用いることによって、効率よく乾燥ができると言った優れた効果を見出した。
　また、化学反応で水素ガスのみを発生させる水素ガス発生器と、昇温装置による加温水素を、ヒトに摂取させる部材とを装置内で組み合わせて用いることによって、効果的に体を保護することができることを見出した。
　また、水素ガス発生器と水素ガス加熱装置と一時的貯留タンクとを具備し、水素ガスを燃焼させずに水素ガスの超臨界高圧流体を用いれば、閉サイクルで安全な駆動及び発電ができることを見出した。
　そして、それらによって上記課題が解決でき、本発明を完成するに至った。 As a result of intensive studies to solve the above-mentioned problems, the present inventor has used the above-mentioned problems by using hydrogen gas having features such as a low critical point, high thermal conductivity, and safety without oxygen. It was found that can be solved.
Specifically, the present inventors have found an excellent effect that drying can be efficiently performed by using hydrogen gas as a medium used for drying food materials.
In addition, the body can be effectively protected by using a combination of a hydrogen gas generator that generates only hydrogen gas through a chemical reaction and a member that allows the human to ingest the heated hydrogen from the temperature rising device. I found out that I can.
In addition, if a hydrogen gas generator, a hydrogen gas heating device, and a temporary storage tank are provided and a hydrogen gas supercritical high pressure fluid is used without burning the hydrogen gas, it is possible to safely drive and generate power in a closed cycle. I found it.
And the said subject could be solved by them and came to complete this invention.
　すなわち、本発明は、少なくとも、以下の（１）、（２）及び（Ｒ）を具備するものであることを特徴とする水素流体閉サイクル装置を提供するものである。
（１）水素ガスを発生させる水素ガス発生器
（２）上記（１）水素ガス発生器から出る水素ガスの温度を上げることによって水素ガスの圧力を上げる水素ガス加熱装置と一時的貯留タンク
（Ｒ）上記（２）水素ガス加熱装置と一時的貯留タンクから出る水素ガスを利用する水素ガス利用装置 That is, the present invention provides a hydrogen fluid closed cycle device characterized by comprising at least the following (1), (2) and (R).
(1) Hydrogen gas generator for generating hydrogen gas (2) (1) Hydrogen gas heating device and temporary storage tank (R) for raising the pressure of hydrogen gas by raising the temperature of hydrogen gas exiting from the above (1) hydrogen gas generator ) (2) Hydrogen gas heating device and hydrogen gas utilization device that uses hydrogen gas from the temporary storage tank
　本発明は、好ましい態様として、以下の態様１、態様２又は態様３を包含する。 The present invention includes the following aspect 1, aspect 2 or aspect 3 as a preferable aspect.
　すなわち、本発明の態様１は、上記の水素流体閉サイクル装置を具備する食材乾燥装置であって、
　水素ガスを食材に接触・透過させて、該食材に含有されている水分を除去する食材乾燥方法に用いるものであることを特徴とする食材乾燥装置を提供するものである。
　また、本発明は、上記の食材乾燥装置を使用した食材乾燥方法であって、水素ガスを食材に接触・透過させて、該食材に含有されている水分を除去することを特徴とする食材乾燥方法を提供するものである。
　また、本発明の態様１は、上記食材乾燥装置又は上記食材乾燥方法を用いて、水素ガスを食材に接触・透過させて、該食材に含有されている水分を除去することを特徴とする乾燥食材の製造方法を提供するものである。 That is, aspect 1 of the present invention is a food drying apparatus comprising the above hydrogen fluid closed cycle apparatus,
The present invention provides a food drying apparatus that is used in a food drying method for removing water contained in the food by bringing hydrogen gas into contact with and passing through the food.
Moreover, the present invention is a food drying method using the above-described food drying apparatus, wherein hydrogen is brought into contact with and permeated through the food to remove moisture contained in the food. A method is provided.
Further, according to aspect 1 of the present invention, drying using the above-described food drying apparatus or the above-described food drying method allows hydrogen gas to contact and permeate the food to remove moisture contained in the food. The manufacturing method of a foodstuff is provided.
　また、本発明の態様２は、上記の水素流体閉サイクル装置を具備する抗酸化作用付与装置であって、
　少なくとも、以下の（ａ）、（ｂ）及び（Ｒ２）を具備するものであることを特徴とする抗酸化作用付与装置を提供するものである。
（ａ）化学反応で水素ガスを発生させる水素ガス発生器
（ｂ）上記（ａ）水素ガス発生器で発生した水素ガスの温度を昇温制御する水素ガス昇温制御装置
（Ｒ２）該水素ガスをヒトに吸入させる水素ガス吸入マスク、又は、該水素ガスをヒト若しくはヒトの一部に接触させる水素ガス吐出充満容器 Aspect 2 of the present invention is an antioxidant effect imparting device comprising the above hydrogen fluid closed cycle device,
The present invention provides an antioxidant effect imparting device characterized by comprising at least the following (a), (b) and (R2).
(A) Hydrogen gas generator for generating hydrogen gas by chemical reaction (b) Hydrogen gas temperature rise control device (R2) for raising the temperature of the hydrogen gas generated by the above (a) hydrogen gas generator (R2) The hydrogen gas Hydrogen gas inhalation mask that allows a human to inhale, or a hydrogen gas discharge filling container that makes the hydrogen gas contact a human or a part of the human
　また、本発明の態様２は、上記の抗酸化作用付与装置を使用し、水素ガスの温度を制御しつつ段階的に上昇させて、該水素ガスをヒト若しくはヒトの一部に接触させることを特徴とする抗酸化作用付与方法を提供するものである。 In addition, the second aspect of the present invention is to use the above-mentioned antioxidant action imparting device and raise the hydrogen gas stepwise while controlling the temperature of the hydrogen gas to bring the hydrogen gas into contact with a human or a part of the human. The present invention provides a method for imparting an anti-oxidant action.
　また、本発明の態様３は、上記の水素流体閉サイクル装置を具備する水素流体閉サイクル駆動・発電装置であって、
　少なくとも、以下の（Ｒ３）及び（Ｒ４）の全てを具備するものであることを特徴とする超臨界水素流体閉サイクル駆動・発電装置を提供するものである。
（Ｒ３）一時的貯留タンクから水素ガスが噴射されることで回転するタービンを備える駆動装置
（Ｒ４）一時的貯留タンクから水素ガスが噴射されることで回転翼が回転して発電する流体発電器 Aspect 3 of the present invention is a hydrogen fluid closed cycle drive / power generation device comprising the above hydrogen fluid closed cycle device,
The present invention provides a supercritical hydrogen fluid closed cycle drive / power generation device characterized by comprising at least all of the following (R3) and (R4).
(R3) Drive unit including a turbine that rotates when hydrogen gas is injected from the temporary storage tank (R4) Fluid generator that generates power by rotating the rotor blades when hydrogen gas is injected from the temporary storage tank
　また、本発明の態様３は、上記の水素流体閉サイクル駆動・発電装置を搭載した動力機関を提供するものである。
　また、本発明の態様３は、上記の水素流体閉サイクル駆動・発電装置を使用することを特徴とする駆動・発電方法を提供するものである。 Aspect 3 of the present invention provides a power engine equipped with the above hydrogen fluid closed cycle drive / power generation apparatus.
Aspect 3 of the present invention provides a driving / power generation method using the above-described hydrogen fluid closed cycle driving / power generation apparatus.
　以下、本発明である水素流体閉サイクル装置の一形態である食材乾燥装置及び該装置に関する発明を「態様１」と略記し、同様に他の一形態である抗酸化作用付与装置及びそれに関する発明を「態様２」と略記し、同様に他の一形態である水素流体閉サイクル駆動・発電装置及びそれに関する発明を「態様３」と略記する。 Hereinafter, the food drying apparatus which is one form of the hydrogen fluid closed cycle apparatus according to the present invention and the invention related to the apparatus will be abbreviated as “Aspect 1”, and similarly, the antioxidant action imparting apparatus which is another form and the invention related thereto. Is abbreviated as “Aspect 2”, and similarly, another embodiment of the hydrogen fluid closed cycle drive / power generation apparatus and the invention related thereto are abbreviated as “Aspect 3”.
　本発明によれば、臨界点が低く熱伝導率が極めて高い；酸素がなければ安全である；抗酸化作用がある；等の特徴を有する水素ガスを用いているので、昇温・加圧が容易であり、物理的・化学的に安全性も高く、毒性もないため生体に対して安全である等の特徴を有する装置及び方法が提供できる。
　また、燃焼させず大気を利用しない「エネルギーの閉サイクル」であり、排気ガスが出ず大気を汚染せず環境に負荷をかけず、危険性も低い装置を提供することができる。 According to the present invention, hydrogen gas having characteristics such as a low critical point and extremely high thermal conductivity; safe without oxygen; has an antioxidant effect; It is possible to provide an apparatus and a method that are easy, physically and chemically safe, have no toxicity, and are safe for living organisms.
Further, it is an “closed cycle of energy” that does not burn and does not use the atmosphere, and can provide an apparatus that does not emit exhaust gas, pollutes the atmosphere, does not load the environment, and has low risk.
＜態様１の発明の効果＞
　更に、本発明の態様１の効果は以下である。
　食材を高温に加熱しなくても、極めて短時間で乾燥可能である。
　水素ガスの熱伝導率は、空気、窒素ガス、水蒸気、メタンガス、フッ素ガス等に比較して格段に高い。また、熱伝導率が極めて高いことで知られるヘリウムガスと比較しても、水素ガスの熱伝導率はそれよりも高い。
　このように、水素ガスは臨界点が低く熱伝導率が高いために、熱が食材に伝わり易く、高圧流体も生じ易く、食材を短時間で乾燥させることが可能である。 <Effect of Invention of Aspect 1>
Furthermore, the effects of the aspect 1 of the present invention are as follows.
Even if the food is not heated to a high temperature, it can be dried in a very short time.
The thermal conductivity of hydrogen gas is much higher than that of air, nitrogen gas, water vapor, methane gas, fluorine gas, or the like. In addition, the thermal conductivity of hydrogen gas is higher than that of helium gas, which is known for its extremely high thermal conductivity.
Thus, since hydrogen gas has a low critical point and high thermal conductivity, heat is easily transferred to the food, high-pressure fluid is easily generated, and the food can be dried in a short time.
　また、水素ガスは、物体に対しての浸透性・透過性が高い。そのため、ガスバリヤー性の高い物体（食材）の内部にも浸透・透過し、素早く食材を乾燥する。
　従って、例えば、ジャガイモ、サツマイモ等のイモ類（の皮）；リンゴ、柿、オレンジ等の果物（の皮）；キクラゲ等のキノコ；魚、アワビ、ナマコ等の海産物；等、乾燥させ難い食材の乾燥や、中温領域の焙煎、ノンフライ加熱等にも好適である。 In addition, hydrogen gas has high permeability and permeability to objects. For this reason, it penetrates and permeates the inside of an object (foodstuff) with high gas barrier properties and quickly dries the foodstuff.
Therefore, for example, potatoes such as potatoes and sweet potatoes (skins); fruits such as apples, strawberries and oranges (skins); mushrooms such as jellyfishes; marine products such as fish, abalone and sea cucumbers; etc. It is also suitable for drying, roasting in an intermediate temperature range, non-flying heating and the like.
　また、その高い透過性のために、海産物等の比較的大きな食材を切らずにそのままの形で、効率よく無酸素状態で、短時間で乾燥させることが可能である。食材の形状を保ったまま養分濃縮乾燥が可能であるため、商品価値が上げられる。 Also, due to its high permeability, it can be dried in a short period of time in an oxygen-free state efficiently without cutting off relatively large foodstuffs such as marine products. The nutrient value can be concentrated and dried while maintaining the shape of the food, increasing the commercial value.
　本発明は、乾燥媒体として水素ガスを用いるので、実質的に酸素ガスや空気がない状態で、乾燥中に食材に付着している好気性菌を殺す（又は増殖を抑える）ことができる。従って、乾燥後の食材においては好気性菌の繁殖がなく、乾燥（水分不存在）との相乗効果で、食材が腐ることを更に防止できる。また、抗酸化性雰囲気の中で乾燥ができるので食品の酸化が防止できる（防腐剤、保存料不使用が可能）。
　また、乾燥後にそのまま空気に触れずに密閉することによって、保存中も酸素に触れさせないで、酸化せず変質せず乾燥食材の保存が可能となる。 Since hydrogen gas is used as a drying medium in the present invention, aerobic bacteria adhering to a food material during drying can be killed (or suppressed in growth) in a state substantially free of oxygen gas and air. Therefore, there is no growth of aerobic bacteria in the dried food material, and it is possible to further prevent the food material from rotting due to a synergistic effect with drying (the absence of moisture). Moreover, since it can be dried in an antioxidative atmosphere, the food can be prevented from being oxidized (preservatives and preservatives can be used).
In addition, by sealing without drying the air as it is after drying, it is possible to store the dried food without oxidation and alteration without being exposed to oxygen during storage.
　また、水素ガスは熱伝導率が高く乾燥効率が良いために、比較的低温で食材を乾燥することが可能となるため、生物由来の酵素の失活を抑制しつつ乾燥することが容易になり、野菜・果物等の食材に主に含まれるビタミン類を分解させずに乾燥することが容易になり、デンプンはαデンプンに変化させずにβデンプンのまま乾燥することが容易になる。
　すなわち、食材に含有される生物由来物を、そのまま変質させずに、栄養価が濃縮された乾燥食材を製造することが容易となる。
　また、食材の持つ自由水のみならず、たんぱく質等と水素結合をしている結合水も、（加温した）水素ガスが浸透透過することで、食材中の内部水分も連行し素早く乾燥ができる。 In addition, since hydrogen gas has high thermal conductivity and good drying efficiency, it becomes possible to dry foods at a relatively low temperature, which makes it easy to dry while suppressing inactivation of biological enzymes. It becomes easy to dry without decomposing vitamins mainly contained in foodstuffs such as vegetables and fruits, and starch can be easily dried as β starch without changing to α starch.
That is, it becomes easy to produce a dry food material having a concentrated nutritional value without altering the biological material contained in the food material as it is.
In addition to the free water of the ingredients, the water that is hydrogen-bonded to proteins, etc., can penetrate and permeate the (warmed) hydrogen gas, so that the internal moisture in the ingredients can be taken and dried quickly. .
　本発明の態様１の食材乾燥方法は、食べられる生物（の一部）自体に対しても、規格外の野菜・果物・海産物に対しても、食品加工に際して発生する二次産物に対しても、食品廃棄物に対しても適用可能である。
　そのため、食材の無駄がないと共に、更に栄養価の高い食材をも提供できる。 The food drying method of aspect 1 of the present invention is applicable to (part of) eatable organisms themselves, non-standard vegetables, fruits and seafood, as well as secondary products generated during food processing. It can also be applied to food waste.
Therefore, there is no waste of ingredients, and it is possible to provide ingredients with higher nutritional value.
＜態様２の発明の効果＞
　更に、本発明の態様２の効果は以下である。
　本発明の態様２によれば、上記問題点や課題を解決し、化学反応で水素ガスを発生させる水素ガス発生器と、ヒトに摂取させる部材とを装置内で組み合わせて用いることによって、効率的で簡易な装置に構成することができ、日頃からヒトの体を好適に保護することができる。
　具体的には、活性酸素、酸素ラジカル、ヒドロキシ（アニオン）ラジカル等の、細胞、細胞内組織（小器官）、体内物質を酸化させ易い物質（種）に対して、体に負担をかけることなく、効果的に対抗することが可能である。 <Effect of Invention of Aspect 2>
Furthermore, the effect of the aspect 2 of this invention is the following.
According to the second aspect of the present invention, the above-described problems and problems are solved, and a hydrogen gas generator that generates hydrogen gas through a chemical reaction and a member that is ingested by a human are used in combination in the apparatus, thereby efficiently. In this way, the apparatus can be configured as a simple device, and the human body can be suitably protected on a daily basis.
Specifically, without burdening the body against active substances, oxygen radicals, hydroxy (anion) radicals and other cells (species) that easily oxidize cells, intracellular tissues (organelles), and body substances It is possible to counter effectively.
　上記（１）水素ガス発生器として、アルミニウム等の金属にアルカリ水を接触させることによって水素ガスを発生させられるような装置を用いることによって、水の電気分解と言った電気を用いることが避けられ、水素ガス発生に用いた後の「アルミニウム等の金属」の化合物を、有用物として再利用することもできる。 (1) By using an apparatus capable of generating hydrogen gas by bringing alkaline water into contact with a metal such as aluminum as the hydrogen gas generator, it is possible to avoid using electricity such as electrolysis of water. The compound of “metal such as aluminum” after being used for generating hydrogen gas can be reused as a useful product.
　また、発生させた水素ガスを、１５℃から４５℃までの範囲で温度制御して段階的に上昇させつつヒトの皮膚等に接触させることによって、正常な細胞組織は４５℃を超えなければ組織破壊は起きず、特定の癌細胞の増殖を抑えたり、体内に転移した可能性がある全ての癌細胞も同時に不活性化させたりすることが可能である。
　また、加温された水素ガスの接触によって体温を上昇させることで、免疫力がアップすると同時に、水素ガス固有の抗酸化作用で、体内の酸化を防止し、若い健康体を維持できる可能性がある。 In addition, when the generated hydrogen gas is brought into contact with human skin or the like while gradually increasing the temperature in a range from 15 ° C. to 45 ° C., normal cellular tissue is tissue that does not exceed 45 ° C. No destruction occurs, it is possible to suppress the growth of specific cancer cells, or to inactivate all cancer cells that may have metastasized into the body.
In addition, by raising body temperature through contact with warmed hydrogen gas, immunity improves, and at the same time, there is a possibility of preventing oxidation in the body and maintaining a young healthy body with the antioxidant action unique to hydrogen gas. is there.
＜態様３の発明の効果＞
　更に、本発明の態様３の効果は以下である。
　本発明によれば、上記問題点や課題を解決し、水素を用いることによって、大気に依存せずに駆動と発電が可能である。
　本発明の態様３の水素流体閉サイクル駆動・発電装置は、非大気水素超臨界流体閉サイクル駆動・発電装置とも言えるもので、基本的に酸素や空気を必要とせず、駆動・発電エネルギーを低温（５０～４００℃近傍）で創出する。大気に依存しないので、非大気依存推進（ＡＩＰ）潜水艦等にも応用され得る技術である。 <Effect of Invention of Aspect 3>
Furthermore, the effect of the aspect 3 of this invention is the following.
According to the present invention, by solving the above problems and problems and using hydrogen, driving and power generation are possible without depending on the atmosphere.
The hydrogen fluid closed cycle drive / power generation device according to aspect 3 of the present invention can be said to be a non-atmospheric hydrogen supercritical fluid closed cycle drive / power generation device, and basically does not require oxygen or air, and the drive / power generation energy is reduced to a low temperature. Created at (around 50-400 ° C). Since it does not depend on the atmosphere, it can be applied to non-atmosphere-dependent propulsion (AIP) submarines.
　使用する水素は、臨界点が、－２４０℃、１．３ＭＰａであり、更に、熱伝導率が気体中最も高く、５０℃条件下において、０．１９１９Ｗ／（ｍ・Ｋ）である。なお、空気は、４０℃条件下において、０．０２７２Ｗ／（ｍ・Ｋ）である。空気と比較しても約７倍の熱伝導率で、低温でも超臨界流体となる特性がある。 The hydrogen used has a critical point of −240 ° C. and 1.3 MPa, the highest thermal conductivity in the gas, and 0.1919 W / (m · K) under the condition of 50 ° C. The air is 0.0272 W / (m · K) under the condition of 40 ° C. Compared to air, it has a thermal conductivity about 7 times that of a supercritical fluid even at low temperatures.
　この水素を昇温して、密閉容器（密閉空間）に一時的に貯留させると、１～２分間程度で水素は超臨界状態となる。その圧力は８０気圧から３５０気圧であり、温度は５０℃～４００℃であり、温度と一時貯留時間設定によって発電能力は自在に設計ができる。
　温度と圧力は比例関係であり、温度圧力を圧力調整弁で容易に調整し、超臨界吐出状態をコントロール可能である。
　超臨界流体として羽根車をダイレクトに高速回転させて駆動軸を介して直接流体発電器を回転させれば、能率の高い電力が得られる。 When this hydrogen is heated and temporarily stored in a sealed container (sealed space), the hydrogen becomes supercritical in about 1 to 2 minutes. The pressure is from 80 to 350 atm, the temperature is from 50 ° C to 400 ° C, and the power generation capacity can be designed freely by setting the temperature and temporary storage time.
Temperature and pressure are in a proportional relationship, and the supercritical discharge state can be controlled by easily adjusting the temperature and pressure with a pressure control valve.
If the impeller is directly rotated at a high speed as a supercritical fluid and the fluid power generator is directly rotated via the drive shaft, highly efficient electric power can be obtained.
　従来の内燃機関と異なり、極めてコンパクトで且つシンプルな構成である。
　即ち、化石燃料、液体酸素、液体水素等を燃焼させず、水素ガス単独又は水素混合気体に熱伝導させて、前記のように一時貯留させて超高圧の超臨界流体として、（回転）駆動・発電を閉サイクル低温環境で行なうことができる。
　僅か数分の貯留で、（複数の）一時的貯留タンクから、順次、連続的に吐出することで目的を達成できる。 Unlike the conventional internal combustion engine, it has a very compact and simple configuration.
In other words, fossil fuel, liquid oxygen, liquid hydrogen, etc. are not burned, but are made to conduct heat to hydrogen gas alone or a hydrogen mixed gas, and temporarily stored as described above as an ultra-high pressure supercritical fluid (rotation) drive. Power generation can be performed in a closed cycle low temperature environment.
With only a few minutes of storage, the objective can be achieved by sequentially and continuously discharging from a plurality of temporary storage tanks.
　既存機関を改良する時は、動力で圧縮高圧化した密度の高いアクティブな水素ガス流体を噴射循環させて閉サイクル運転を行うこともできる。
　従って、太陽光（電磁波）、地熱、他の熱源、「圧縮機、ブランジャーポンプ等による熱膨張・廃棄熱」等の（回収）利用も可能であり、低温でも水素ガス流体の高圧駆動力で、効率的な回転・駆動・発電を行なうことも可能となる。 When an existing engine is improved, a closed cycle operation can be performed by injecting and circulating a high-density active hydrogen gas fluid compressed and pressurized with power.
Therefore, sunlight (electromagnetic waves), geothermal heat, other heat sources, “thermal expansion / waste heat by compressors, blanker pumps, etc.” can be used (recovered), and the hydrogen gas fluid can be driven at high pressure even at low temperatures. It is also possible to perform efficient rotation, drive and power generation.
　動力機関としては、既存のレシプロエンジン（ディーゼルエンジン・ロータリーエンジン）、圧縮スクロールエンジンや、１軸タービンで、熱膨張駆動による閉サイクル運転が可能であり好適である。しかも、本発明の場合、燃焼させないので、既存のエンジンのような点火スパークプラグ、燃料、空気は必要としない。 As a power engine, an existing reciprocating engine (diesel engine / rotary engine), a compression scroll engine, or a single-shaft turbine is suitable because it can be operated in a closed cycle by thermal expansion. Moreover, in the case of the present invention, since it is not burned, an ignition spark plug, fuel, and air as in the existing engine are not required.
　本発明の水素流体閉サイクル駆動・発電装置は、動力機関として使用して、駆動と発電を両立させることができるシステムを利用している。
　図１２に１軸タービン駆動に応用した例を示したが、超臨界圧力駆動で、推進力や電力を供給でき、最低でも３ＭＷ以上の同時出力が可能である。
　図１３に本発明を自動車に応用した例を示したが、発電規模によって、熱源やプラント動力機関を任意選定すればよい。 The hydrogen fluid closed cycle drive / power generation apparatus of the present invention uses a system that can be used as a power engine to achieve both driving and power generation.
FIG. 12 shows an example applied to a single-shaft turbine drive, but a supercritical pressure drive can supply a propulsive force and electric power, and a simultaneous output of at least 3 MW or more is possible.
Although the example which applied this invention to the motor vehicle was shown in FIG. 13, what is necessary is just to select a heat source and a plant motive power engine arbitrarily according to a power generation scale.
　本発明の態様３の超臨界水素流体閉サイクル駆動・発電装置は、排気ガスが出ない、ガソリンの燃料消費がないので、限りある資源の保全に有効である。自動車に応用すると、自家発電車となり、走行時のＮＯＸの排気排出がない。車体を軽くすることができ、燃料電池等の触媒であるレアメタルが不要である。また、製造コストが安く、既存技術の組み合わせだけで実現できる。
　水素ガスはその都度生成させ、連続圧縮や加熱方式、一時的貯留方式であるので、水素圧縮貯蔵タンクが不要である。臨界点－２４０℃である水素は気温による影響が小さく、氷点下でも加熱すれば、水素は膨張し高圧化して超臨界となるので出力低下はない。燃料を消費せず閉サイクル方式であり、エネルギー効率が高い。 The supercritical hydrogen fluid closed cycle drive / power generation device according to the third aspect of the present invention is effective in the maintenance of limited resources because no exhaust gas is produced and no fuel is consumed in gasoline. When applied to an automobile, it becomes a private power generation vehicle, and there is no exhaust emission of NOX during traveling. The vehicle body can be lightened, and rare metals that are catalysts for fuel cells and the like are unnecessary. Moreover, the manufacturing cost is low, and it can be realized only by a combination of existing technologies.
Since hydrogen gas is generated each time and is a continuous compression, heating system, or temporary storage system, a hydrogen compression storage tank is unnecessary. Hydrogen having a critical point of −240 ° C. is less affected by the temperature, and if heated even below freezing, the hydrogen expands and becomes high pressure and becomes supercritical, so there is no decrease in output. It is a closed cycle system that does not consume fuel, and is highly energy efficient.
　また、本発明の態様３の水素流体閉サイクル駆動・発電装置は安全である。すなわち、水素ガスは、空気中で発火点５７０℃、酸素中で４５０℃であるが、何れも酸素が介在しているときの温度であり、閉サイクル方式では、水素ガス又は「水素と不活性ガスの混合気体」は、燃焼や爆発現象を生じない。
　水素ガス発生器（アルカリイオン水）を積載するのみであり、交通事故があっても高圧タンクがないため爆発しない。燃料も積載しないため爆発的な火災が起きない。 In addition, the hydrogen fluid closed cycle drive / power generation device of aspect 3 of the present invention is safe. In other words, hydrogen gas has an ignition point of 570 ° C. in air and 450 ° C. in oxygen, and both are temperatures when oxygen is present. In the closed cycle system, hydrogen gas or “inactive with hydrogen” The “gas mixture” does not cause combustion or explosion.
Only a hydrogen gas generator (alkaline ion water) is loaded, and even if there is a traffic accident, it does not explode because there is no high-pressure tank. There is no explosive fire because no fuel is loaded.
　また、本発明の態様３の水素流体閉サイクル駆動・発電装置は、民生用としての前記の駆動・発電のみならず、船舶・車両のエンジン駆動・発電にも最適である（図１３参照）。
　非大気推進の従来技術例として、例えば潜水艦の場合、通常、内燃式ディーゼル機関が用いられ、浮上して発電し蓄電させて潜航する電気駆動推進が用いられている。
　また、アルカリイオン電池は、大きな電力を貯められず、従って長期のステルス潜航航続は出来ない。そのため、ＡＩＰ（非大気依存推進）では、スターリングエンジン等で補助しているが、発電能力は約７５ｋＷ程度と低い。 Further, the hydrogen fluid closed cycle drive / power generation apparatus of aspect 3 of the present invention is optimal not only for the above-mentioned drive / power generation for consumer use, but also for the engine drive / power generation of ships and vehicles (see FIG. 13).
As a prior art example of non-atmospheric propulsion, for example, in the case of a submarine, an internal combustion diesel engine is usually used, and electric drive propulsion that floats, generates electric power, stores electricity, and dives.
In addition, the alkaline ion battery cannot store a large amount of electric power, and therefore cannot perform long-term stealth diving. Therefore, AIP (non-atmosphere-dependent propulsion) assists with a Stirling engine or the like, but the power generation capacity is as low as about 75 kW.
　従来、閉サイクルディーゼル機関においては、潜航時には燃料と液体酸素で駆動している。しかし、使用される純粋酸素による燃焼では過度の損耗があるため、不活性ガスを混入し自然大気と同様な分圧にしなければならない。
　また、内燃機関であるので、作動時の振動・騒音でソナーに探知され易く、排気ガスの冷却液化等の処理問題があり、そのために多くのスペースが必要である。
　燃料電池作動電気推進についても、圧縮された液体水素と液体酸素の高圧タンクの搭載による危険性が指摘されている。
　また、その起電力も極めて小さく、１モジュール出力３４ｋＷ×９基でも、最大３００ｋＷである。 Conventionally, in a closed cycle diesel engine, it is driven by fuel and liquid oxygen at the time of diving. However, since combustion with pure oxygen used causes excessive wear, an inert gas must be mixed to make the partial pressure similar to that of natural air.
Further, since it is an internal combustion engine, it is easily detected by sonar due to vibration and noise during operation, and there are processing problems such as exhaust gas cooling and liquefaction, which requires a lot of space.
Fuel cell-operated electric propulsion has also been pointed out to be dangerous due to the installation of compressed liquid hydrogen and liquid oxygen high-pressure tanks.
In addition, the electromotive force is extremely small, and even if one module output is 34 kW × 9 units, the maximum is 300 kW.
　潜水艦に使用されている閉サイクル蒸気タービン機関は、「液体酸素を供給源として気化して得られた酸素」とエタノールとの混合気体を燃焼させ、それで得た約７００℃の燃焼ガスを利用する蒸気発生装置で、５００℃の蒸気タービンを作動して発電している。そこでは、燃料を必要としている。
　最近ではＣＯ２閉サイクルタービン方式もあるが、加熱部位は通常の燃焼方法であり、そこでも燃料と空気や酸素を必要としている。 The closed cycle steam turbine engine used in the submarine burns a mixed gas of “oxygen obtained by vaporizing liquid oxygen as a supply source” and ethanol, and uses the combustion gas obtained at about 700 ° C. A steam generator operates a steam turbine at 500 ° C. to generate electricity. There you need fuel.
Recently, there is also a CO 2 closed cycle turbine system, but the heating part is a normal combustion method, which also requires fuel, air and oxygen.
　本発明の態様３の水素流体閉サイクル駆動・発電装置は、非大気の超臨界閉サイクルの駆動・発電装置（システム）である。
　すなわち、燃料を燃焼させない方式であり、艦内の空気使用はゼロであるので、艦内環境にとって極めて好ましい。空気や酸素を使用せず排気ガスも無く、大きな電力が艦内で随時供給できるので、原子力潜水艦並みに長期に隠密潜航が可能となる。
　潜水艦のシュノーケル航行は不要であり、更に、漏えい補充用の水素ガス生産も、引き込み海水から艦内創出（海水燃料化（水素））することもできる。 The hydrogen fluid closed cycle drive / power generation device according to aspect 3 of the present invention is a non-atmospheric supercritical closed cycle drive / power generation device (system).
That is, it is a system that does not burn fuel, and the use of air in the ship is zero, which is extremely preferable for the ship environment. Since air and oxygen are not used and there is no exhaust gas, a large amount of power can be supplied from time to time within the ship, making it possible to covert underwater as long as a nuclear submarine.
Submarine snorkeling is not required, and hydrogen gas production for leak replenishment can also be created in the ship (seawater fuel (hydrogen)) from drawn-in seawater.
　また、インフラ未整備区域の地産地消発電や災害用自家発電装置として、規模を拡大すれば大規模な発電所としても極めて有効である。
　環境に負荷をかけず、限りある地下資源の節約ができ、排気ガスゼロで大気を汚染しないため、温暖化防止（気候変動抑制）、赤道付近や砂漠化が進行しているような乾燥地帯等の電力インフラ未整備区域にも、太陽熱を加熱装置の補助熱源とすれば電力供給ができる。
　電力供給ができれば、砂漠地下水の汲み上げによる塩分除去の上、水道水供給も可能となり、乾燥地の緑化、農業振興にも寄与可能となる。 In addition, it is extremely effective as a large-scale power plant if the scale is expanded as a local production for local consumption power generation in an undeveloped infrastructure area or a disaster private power generation system.
Because it does not burden the environment, it can save limited underground resources, and it does not pollute the atmosphere with zero exhaust gas, so it can prevent global warming (climate change suppression), dry areas where equator and desertification are progressing, etc. Electricity can be supplied even in areas where power infrastructure has not been established, using solar heat as an auxiliary heat source for the heating device.
If power can be supplied, it will be possible to supply tap water after removing salt by pumping up groundwater in the desert, contributing to greening of dry land and promotion of agriculture.
　本発明では、熱媒体として使用する水素ガスは、後述する方法で連続発生させるので、アルミニウム等の金属をアルカリ水から離せば、水素ガスの発生は僅か１～３秒程度で即座に停止する。
　従って、液化水素等の断熱高圧タンクや重い水素吸蔵合金も必要なく、液化酸素も不要であり、爆発もなく極めて安全である。 In the present invention, the hydrogen gas used as the heat medium is continuously generated by the method described later. Therefore, when a metal such as aluminum is separated from the alkaline water, the generation of the hydrogen gas stops immediately in only about 1 to 3 seconds.
Therefore, there is no need for an adiabatic high-pressure tank such as liquefied hydrogen or a heavy hydrogen storage alloy, liquefied oxygen is unnecessary, and there is no explosion and it is extremely safe.
　外洋航路の大型船舶や艦隊では、海水と廃棄物質から創出する技術手段も既に実験済みである。長期航海においても、燃料補給のための寄港は不要であり、洋上給油も不要である。
　島国においては、無限大ともいえる豊富な海水と廃棄物質をベースとした水素生産資源基地として最適な経済振興となるばかりでなく、他国からの燃料の輸入も大幅に削減し国家収支も改善する。また、内陸部では、沼や湖や河川水を利用した水素ガス生成技術も確立している。
　また、従来のように、水素ガス生成に要する燃料改質技術操作や、電気分解や貯蔵のための液化に要するエネルギーや耐圧貯蔵施設も不要である。 Large-scale vessels and fleets on the open ocean route have already experimented with technical means to create from seawater and waste materials. Even on long-term voyages, there is no need to call for refueling and no offshore refueling.
In the island countries, it will not only be an optimal economic promotion as a hydrogen production resource base based on abundant seawater and waste materials that can be said to be infinite, but it will also greatly reduce the import of fuel from other countries and improve the national balance. Inland areas, hydrogen gas generation technology using swamps, lakes, and river water has also been established.
Further, as in the prior art, there is no need for fuel reforming technology operation required for hydrogen gas generation, and energy and pressure resistant storage facilities required for liquefaction for electrolysis and storage.
　本発明の態様３は、複数基の一時的貯留タンクから、順次、高圧となった超臨界水素流体を供給し、回転翼を高速回転させて、駆動軸を回転させて動力とする共に、駆動軸の回転から流体発電器を稼働させる閉サイクル方式である。空気を必要としないため、内燃機関も必要とせず（非大気エネルギーであり）、水素を燃やさず超臨界流体媒体として利用できることが、本発明の最大の技術ポイントである。水素ガスを温め、複数基の密閉空間（密閉容器）内で一時的に閉じ込められた状態で、例えば１～２分間で使用できる。 According to the third aspect of the present invention, the supercritical hydrogen fluid having a high pressure is sequentially supplied from a plurality of temporary storage tanks, the rotating blades are rotated at a high speed, the drive shaft is rotated, and the power is driven. This is a closed cycle system in which the fluid power generator is operated from the rotation of the shaft. Since air is not required, the internal combustion engine is not required (non-atmospheric energy), and the most technical point of the present invention is that hydrogen can be used as a supercritical fluid medium without burning. The hydrogen gas is warmed and can be used in, for example, 1 to 2 minutes in a state of being temporarily confined in a plurality of sealed spaces (sealed containers).
本発明の態様１の一例を示す概念図である。It is a conceptual diagram which shows an example of the aspect 1 of this invention. 本発明の態様１の食材乾燥装置の構成の一例を示す概略全体図であって、食材乾燥容器、食材棚を有するものである一例を示す概略図である。It is a schematic whole view showing an example of composition of a foodstuffs drying device of mode 1 of the present invention, and is a schematic diagram showing an example which has a foodstuff drying container and a foodstuff shelf. 本発明の態様１の食材乾燥装置の「細長く螺旋状になっている食材乾燥容器」の構造の一例を示す概略図である。It is the schematic which shows an example of the structure of "the long and spiral food drying container" of the food drying apparatus of aspect 1 of this invention. 本発明の態様１の食材乾燥方法で水分を除去された乾燥食材の写真の例を示す図である。　（ａ）食材が魚で乾燥食材が魚粉の写真　（ｂ）食材が果物で乾燥食材がドライフルーツの写真It is a figure which shows the example of the photograph of the dry foodstuff from which the water | moisture content was removed by the foodstuff drying method of aspect 1 of this invention. (A) A photo of the ingredients are fish and the dried ingredients are fish meal (b) A photograph of the ingredients are fruits and the dried ingredients are dried fruits 本発明の態様２の抗酸化作用付与装置の一例を示す概略図である。　（ａ）抗酸化作用付与装置の横断面図　（ｂ）使用態様を示す写真It is the schematic which shows an example of the antioxidant action provision apparatus of aspect 2 of this invention. (A) Cross-sectional view of antioxidant device (b) Photograph showing usage 本発明の態様２の抗酸化作用付与装置の一例を示す概略図である。　（ａ）ヒトの首から下に接触させる抗酸化作用付与装置の縦断面図　（ｂ）ヒトの乳房に接触させる抗酸化作用付与装置の概略図（四角枠内は水素ガス吐出充満容器の拡大図）It is the schematic which shows an example of the antioxidant action provision apparatus of aspect 2 of this invention. (A) Longitudinal cross-sectional view of an antioxidant effect imparting device to be brought into contact with the human neck from below (b) Schematic diagram of the antioxidant effect imparting device to be brought into contact with a human breast (the inside of the square frame is an enlarged view of a hydrogen gas discharge container) ) 本発明の態様２の、ヒトの首から下に接触させる抗酸化作用付与装置の一例の図である。　（ａ）抗酸化作用付与装置の水素ガスの流れを示す横から見た断面図　（ｂ）水素ガス導入管の一例の横断面図　（ｃ）水素ガス吐出充満容器の材質を示す断面図　（ｄ）抗酸化作用付与装置の水素ガスの流れを示す上から見た断面図It is a figure of an example of the antioxidant effect | action provision apparatus made to contact below from a human neck of aspect 2 of this invention. (A) Cross-sectional view from the side showing the flow of hydrogen gas in the antioxidant action imparting device (b) Cross-sectional view of an example of the hydrogen gas introduction pipe (c) Cross-sectional view showing the material of the hydrogen gas discharge full container (d ) Cross section viewed from above showing the flow of hydrogen gas in the antioxidant device 本発明の態様３の水素流体閉サイクル駆動・発電装置の基本構成を示す概略図である。It is the schematic which shows the basic composition of the hydrogen fluid closed cycle drive and electric power generating apparatus of aspect 3 of this invention. 本発明の態様３における水素ガス加熱装置が、マイクロ波等を利用して加熱する装置である場合に、該装置の態様の一例を示す概略図である。When the hydrogen gas heating apparatus in aspect 3 of this invention is an apparatus heated using a microwave etc., it is the schematic which shows an example of the aspect of this apparatus. 本発明の態様３における駆動装置が圧縮スクロール型エンジンである場合に、該圧縮スクロール型エンジンの態様の一例を示す概略図である。When the drive device in aspect 3 of this invention is a compression scroll type engine, it is the schematic which shows an example of the aspect of this compression scroll type engine. 本発明の態様３における駆動装置がロータリー型エンジンである場合に、該ロータリー型エンジンの態様の一例を示す概略図である。When the drive device in aspect 3 of this invention is a rotary engine, it is the schematic which shows an example of the aspect of this rotary engine. 本発明の態様３における駆動装置が１軸タービンエンジンである場合に、該１軸タービンエンジンの態様の一例を示す概略図である。When the drive device in aspect 3 of this invention is a single shaft turbine engine, it is the schematic which shows an example of the aspect of this single shaft turbine engine. 本発明の態様３の水素流体閉サイクル駆動・発電装置を自動車に利用した場合に、該自動車の態様の一例を示す概略図である。It is the schematic which shows an example of the aspect of this motor vehicle, when the hydrogen fluid closed cycle drive and electric power generating apparatus of aspect 3 of this invention is utilized for a motor vehicle.
　以下、本発明について説明するが、本発明は、以下の具体的形態に限定されるものではなく、技術的思想の範囲内で任意に変形することができる。
　本発明は、少なくとも、以下の（１）、（２）及び（Ｒ）を具備するものであることを特徴とする水素流体閉サイクル装置である。
（１）水素ガスを発生させる水素ガス発生器
（２）上記（１）水素ガス発生器から出る水素ガスの温度を上げることによって水素ガスの圧力を上げる水素ガス加熱装置と一時的貯留タンク
（Ｒ）上記（２）水素ガス加熱装置と一時的貯留タンクから出る水素ガスを利用する水素ガス利用装置 Hereinafter, the present invention will be described, but the present invention is not limited to the following specific embodiments, and can be arbitrarily modified within the scope of the technical idea.
The present invention is a hydrogen fluid closed cycle device comprising at least the following (1), (2) and (R).
(1) Hydrogen gas generator for generating hydrogen gas (2) (1) Hydrogen gas heating device and temporary storage tank (R) for raising the pressure of hydrogen gas by raising the temperature of hydrogen gas exiting from the above (1) hydrogen gas generator ) (2) Hydrogen gas heating device and hydrogen gas utilization device that uses hydrogen gas from the temporary storage tank
　以下、本発明を態様１、態様２及び態様３に分けて説明するが、水素ガス発生器、水素ガス加熱装置、及び、一時的貯留タンクの構造、仕様、性能等については、共通したものが使用可能であるので、態様１、態様２及び態様３の間で相互に読み替えて適用させることができる。
　本発明の上記（Ｒ）水素ガス利用装置を、食材乾燥容器としたものが態様１であり、
　本発明の上記（Ｒ）水素ガス利用装置を、水素ガス吸入マスク又は水素ガス吐出充満容器としたものが態様２であり、
　本発明の上記（Ｒ）水素ガス利用装置を、タービンを備える駆動装置及び回転して発電する流体発電器としたものが態様３である。 Hereinafter, although this invention is divided and demonstrated to aspect 1, aspect 2 and aspect 3, about the structure, specification, performance, etc. of a hydrogen gas generator, a hydrogen gas heating device, and a temporary storage tank, there are common things. Since it can be used, it can be applied to the first, second, and third aspects by reading each other.
What made the said (R) hydrogen gas utilization apparatus of this invention the foodstuff dry container is the aspect 1,
The (R) hydrogen gas utilization device of the present invention is a hydrogen gas suction mask or a hydrogen gas discharge full container, which is aspect 2.
The aspect (3) is that the (R) hydrogen gas utilization device of the present invention is a drive device including a turbine and a fluid power generator that rotates to generate electric power.
＜態様１＞
　以下、態様１について記載する。態様１の一例を図１ないし図４に示すが、「図１ないし図４に使用されている符号」及び「下記する態様１の記載中の符号」は、態様１にのみ適用されるものとする。すなわち、「下記する態様１の記載中の符号」は、「図１ないし図４に使用されている符号」に対応し、他の態様の説明や他の図では同じ符号が他のものに使用されていることがある。 <Aspect 1>
Hereinafter, Embodiment 1 will be described. An example of the aspect 1 is shown in FIGS. 1 to 4, and “the reference numerals used in FIGS. 1 to 4” and “the reference numerals in the description of the aspect 1 below” are applied only to the aspect 1. To do. That is, “the reference numerals in the description of the aspect 1 described below” correspond to “the reference numerals used in FIGS. 1 to 4”, and the same reference numerals are used for the other elements in the description of other aspects and other drawings. Have been.
　本発明の態様１は、上記の水素流体閉サイクル装置を具備する食材乾燥装置であって、
　水素ガスを食材に接触・透過させて、該食材に含有されている水分を除去する食材乾燥方法に用いるものであることを特徴とする食材乾燥装置である。また、水素ガスを食材に接触・透過させて、該食材に含有されている水分を除去することを特徴とする食材乾燥方法である。
　ここで「接触・透過」とは、「接触及び／又は透過」のことを言う。厚い食材等の場合で、透過しない場合も含まれる。 Aspect 1 of the present invention is a food drying apparatus comprising the above hydrogen fluid closed cycle apparatus,
A food drying apparatus characterized by being used in a food drying method for removing water contained in the food by bringing hydrogen gas into contact with and passing through the food. Further, the present invention is a food drying method characterized by removing hydrogen contained in the food by contacting / permeating the gas with the hydrogen gas.
Here, “contact / transmission” means “contact and / or transmission”. In the case of thick foods and the like, the case where it does not penetrate is also included.
＜＜水素ガス＞＞
　使用される水素ガスは、特に限定はされず、食材乾燥装置に付随した水素ガス発生器において、化学反応によって生成されたものでも、水等の電気分解で得られたものでもよいが、化学反応によって得られた水素ガスを用いることが好ましい。
　また、一旦乾燥の媒体として使用された「水蒸気を含有する水素ガス」から、該水蒸気を除去した還流水素ガスを、加温し再度循環使用してもよい（閉サイクル）。 << Hydrogen gas >>
The hydrogen gas to be used is not particularly limited, and may be generated by a chemical reaction or obtained by electrolysis of water or the like in a hydrogen gas generator attached to a food drying apparatus. It is preferable to use the hydrogen gas obtained by the above.
Further, the reflux hydrogen gas from which the water vapor has been removed from the “hydrogen gas containing water vapor” once used as a drying medium may be heated and circulated again (closed cycle).
　食材に接触・透過させる直前の水素ガスの温度や、食材に接触・透過させているときの水素ガスの温度は、特に限定はないが、好ましくは０℃以上１００℃以下、より好ましくは１０℃以上６０℃以下、特に好ましくは２０℃以上４０℃以下である。
　また、乾燥中の食材の温度も、特に限定はないが、上記温度範囲になるように乾燥することが好ましい。 The temperature of the hydrogen gas immediately before contacting / permeating the food and the temperature of the hydrogen gas when contacting / permeating the food are not particularly limited, but are preferably 0 ° C. or higher and 100 ° C. or lower, more preferably 10 ° C. It is 60 ° C. or lower, particularly preferably 20 ° C. or higher and 40 ° C. or lower.
Further, the temperature of the food during drying is not particularly limited, but it is preferable to dry the food so as to be in the above temperature range.
　該温度が上記下限以上であると、水素ガスを冷却する必要がなく冷却器が不要であり、食材中の水が凍って水分を除去し難くなることがない。また、水素ガス中に含有される水蒸気の分圧（相対湿度）を十分に下げることができる。
　該水素ガスは、水素ガス加熱装置２８で、食材乾燥容器に導入前に加熱することが好ましい（図１～３参照）。加熱することで乾燥が容易になると共に、密閉環境で加熱すると圧力が上昇するので特に好ましい。 If the temperature is equal to or higher than the above lower limit, it is not necessary to cool the hydrogen gas and a cooler is unnecessary, so that the water in the food does not freeze and it is difficult to remove the water. In addition, the partial pressure (relative humidity) of water vapor contained in the hydrogen gas can be sufficiently reduced.
The hydrogen gas is preferably heated by the hydrogen gas heating device 28 before being introduced into the food drying container (see FIGS. 1 to 3). Heating facilitates drying, and heating in a sealed environment is particularly preferable because the pressure increases.
　一方、該温度が上記上限以下であると、食材に含有されている「生物（生命）由来の種々の物質」を変質させずに乾燥することが容易となる。例えば、酵素やビタミンは４０℃以下にすることで、好ましくは３８℃以下にすることで、分解や失活を抑制して乾燥することが容易になる。また、デンプンは５５℃以下にすることで、好ましくは５０℃以下にすることで、乾燥中の食材中に残存する水の存在下でαデンプンに変化せずに、βデンプンのまま乾燥することが容易になる。 On the other hand, when the temperature is not more than the above upper limit, it becomes easy to dry without altering “various substances derived from living organisms” contained in food. For example, enzymes and vitamins should be 40 ° C. or lower, and preferably 38 ° C. or lower, so that decomposition and inactivation can be suppressed and drying can be facilitated. In addition, the starch should be kept at 55 ° C. or lower, preferably 50 ° C. or lower, so that it does not change to α starch in the presence of water remaining in the drying ingredients, and is dried as β starch. Becomes easier.
　食材からの水の蒸発熱で該食材は冷却されるので、該食材の温度を上記範囲に保ちつつ、導入する水素ガスは、上記温度より高くすることも可能である。 Since the food is cooled by the heat of evaporation of water from the food, the hydrogen gas to be introduced can be higher than the temperature while keeping the temperature of the food in the above range.
　食材に接触・透過させる直前の水素ガスの圧力や、食材に接触・透過させているときの水素ガスの圧力は、特に限定はないが、水素ガスの圧力は、食材乾燥容器に導入前に密閉状態で加熱することによっても達成される。水素ガスを昇温すれば圧力が大きくなり、温度の高まった水素の流速が必然的に速くなり乾燥を促進する。また、速やかに水素ガスが循環還流する。
　水素ガスは、水素ガス導入管の内部を通過させて食材乾燥容器の中に導入してもよいし、水素ガス導入ノズルから食材乾燥容器の中に噴射してもよい。 The pressure of hydrogen gas immediately before contacting / permeating the food material and the pressure of hydrogen gas contacting / permeating the food material are not particularly limited, but the hydrogen gas pressure is sealed before being introduced into the food drying container. It is also achieved by heating in the state. If the temperature of the hydrogen gas is raised, the pressure will increase, and the flow rate of hydrogen with an increased temperature will inevitably become faster, thus promoting drying. Moreover, hydrogen gas circulates and refluxes quickly.
The hydrogen gas may be introduced into the food material drying container through the inside of the hydrogen gas introduction pipe, or may be injected from the hydrogen gas introduction nozzle into the food material drying container.
　水素ガスの純度は高いほど好ましい。他の元素の気体（ガス）を混合させてもよいが、実質的に水素ガスのみであることが、熱伝導率の高さ、食材への浸透性の高さ等、前記した水素ガスの物性を生かし易いために好ましい。 The higher the purity of hydrogen gas, the better. Other element gases (gases) may be mixed, but the fact that only hydrogen gas is present is that the physical properties of the hydrogen gas described above, such as high thermal conductivity and high permeability to foodstuffs. It is preferable because it is easy to make the best use of.
＜＜食材乾燥装置＞＞
　本発明の食材乾燥方法に使用される食材乾燥装置１０は、少なくとも、水素ガスを発生させる水素ガス発生器２０、食材Ｆを収納し水素ガスを通過させる食材乾燥容器３０、及び、食材乾燥容器３０の内部を通過した「水蒸気を含む水素ガス」から該水蒸気を除去する除湿装置４０を具備するものであることが好ましい。
　図１及び図２に、本発明に用いられる食材乾燥装置１０の構成の一例を示す。 << Food drying equipment >>
The food drying apparatus 10 used in the food drying method of the present invention includes at least a hydrogen gas generator 20 that generates hydrogen gas, a food drying container 30 that stores the food F and allows hydrogen gas to pass, and a food drying container 30. It is preferable to include a dehumidifying device 40 that removes the water vapor from the “hydrogen gas containing water vapor” that has passed through the inside of the water.
FIG.1 and FIG.2 shows an example of a structure of the foodstuff drying apparatus 10 used for this invention.
＜＜水素ガス発生（装置）＞＞
　乾燥に用いる水素ガスは、食材乾燥装置１０から離れた場所で別途ボンベ等に入れて持ち込まれたものでもよいが、本発明の食材乾燥装置１０に付随した水素ガス発生器２０において、化学反応（又は化学触媒反応）よって生成されたものが、乾燥に必要な水素の量としては十分である；ボンベ代・電気代等のコストがかからない；水素ガスが出尽くした残水が有用副産物として得られる；等の点から好ましい。 << Hydrogen gas generation (device) >>
The hydrogen gas used for drying may be separately brought into a cylinder or the like at a location away from the food drying apparatus 10, but in the hydrogen gas generator 20 associated with the food drying apparatus 10 of the present invention, a chemical reaction ( Or the amount of hydrogen required for drying is sufficient; there is no cost for cylinder charges, electricity charges, etc .; residual water exhausted by hydrogen gas is obtained as a useful byproduct; From the point of view, it is preferable.
　水素ガス発生器２０における水素の発生は、金属２１に、アルカリ水２２を接触させることによることが好ましい。すなわち、本発明における水素ガス発生器２０は、金属にアルカリ水２２を接触させることによって水素ガスを発生させるようになっているものであることが好ましい。
　該金属元素としては、アルミニウム（Ａｌ）、亜鉛（Ｚｎ）、チタン（Ｔｉ）、スズ（Ｓｎ）等の金属が好ましく、安全性、コスト（安価）、生成物が有用物である等の観点から、アルミニウムが特に好ましい。特にアルミニウムの場合、反応生成物は濾過後に浄化材料として使用可能である点からも特に好ましい。また、該金属２１としては、イオン化傾向の高い金属２１が好ましい。 The generation of hydrogen in the hydrogen gas generator 20 is preferably performed by bringing the alkaline water 22 into contact with the metal 21. That is, the hydrogen gas generator 20 in the present invention is preferably one that generates hydrogen gas by bringing the alkaline water 22 into contact with a metal.
The metal element is preferably a metal such as aluminum (Al), zinc (Zn), titanium (Ti), tin (Sn), etc., from the viewpoints of safety, cost (inexpensive), and useful products. Aluminum is particularly preferred. Particularly in the case of aluminum, the reaction product is particularly preferable because it can be used as a purification material after filtration. The metal 21 is preferably a metal 21 having a high ionization tendency.
　該アルカリ水のｐＨとしては、特に限定はないが、１２以上が好ましく、１３以上がより好ましく、１３．５以上１４が特に好ましい。
　例えば、水酸化ナトリウム水溶液とアルミニウムの場合、アルミニウムの表面に生成される水酸化アルミニウム（Ａｌ（ＯＨ）３）は水に不溶であり、そのため反応が金属内部では起こり難くなる。しかし、上記ｐＨの（強）アルカリ水であると、水酸化アルミニウムがアルミン酸イオンとなって水中に溶解し、金属表面の水酸化物被膜が溶解し、水素ガス活性の化学反応が金属２１の内部にまで進行する。 The pH of the alkaline water is not particularly limited, but is preferably 12 or more, more preferably 13 or more, and particularly preferably 13.5 or more.
For example, in the case of an aqueous sodium hydroxide solution and aluminum, aluminum hydroxide (Al (OH) 3 ) produced on the surface of the aluminum is insoluble in water, so that the reaction is less likely to occur inside the metal. However, in the case of (strong) alkaline water having the above pH, aluminum hydroxide is converted to aluminate ions and dissolved in water, the hydroxide film on the metal surface is dissolved, and the chemical reaction of the hydrogen gas activity is caused by the metal 21 Progress to the inside.
　金属元素としてアルミニウムを用いたときの最終的な化学反応は、示性式の記載方法は種々あるが、例えば以下の反応式（１）のようになる。
　２Ａｌ＋６ＯＨ－ → ２（ＡｌＯ３）３－＋３Ｈ２　・・・・・（１） The final chemical reaction when aluminum is used as the metal element can be expressed in various ways, for example, as shown in the following reaction formula (1).
2Al + 6OH − → 2 (AlO 3 ) 3 − + 3H 2 (1)
　通常は、生成したアルミン酸（塩）は、好ましくは定期的に濾過除去する必要がある。本発明に用いる水素ガス発生器２０のアルカリイオン水では、技術的な簡易な操作によって、アルミン酸（塩）を析出させない方法も既に技術確立しているために、アルミン酸（塩）を析出させないこともできる。
　このような方法で、化学量論的に、１Ｌのアルカリ水から、標準状態で最低１１３０Ｌ以上の水素ガスを高速で得ることができるので、食材乾燥容器３０に導入する水素ガスの量としては十分であり反応水素生成後の水も綺麗な透明水である。 Usually, the produced aluminate (salt) should preferably be filtered off periodically. In the alkaline ionized water of the hydrogen gas generator 20 used in the present invention, a method of not precipitating aluminate (salt) by a simple technical operation has already been established, so that aluminate (salt) is not precipitated. You can also.
In this way, a stoichiometric amount of hydrogen gas of at least 1130 L or more can be obtained at high speed from 1 L of alkaline water in a standard state, so that the amount of hydrogen gas introduced into the food drying container 30 is sufficient. The water after the reaction hydrogen generation is also clean transparent water.
　上記アルカリ水２２は、自然石（石灰石等）、貝殻、珊瑚石等の天然物２７から得ることが、環境に優しいために特に好ましい。図３には、天然物２７に水を加えることによって、アルカリ水２２から水素を得る装置が示されている。
　また、該アルカリ水を、アルミニウム（Ａｌ）等の金属２１に接触させて水素ガスを発生させた後に、前記技術的な操作をすれば濾過する必要はなく、透明な水でありそのまま経口摂取が可能で、その点からも環境に優しい。また、反応によってアルミン酸（塩）が析出する場合でも、「それを濾過した濾過水」は中性に近づく。 It is particularly preferable that the alkaline water 22 is obtained from natural products 27 such as natural stones (limestone, etc.), shells, meteorites, and the like because it is environmentally friendly. FIG. 3 shows an apparatus for obtaining hydrogen from the alkaline water 22 by adding water to the natural product 27.
Further, after the alkaline water is brought into contact with a metal 21 such as aluminum (Al) to generate hydrogen gas, it is not necessary to filter it by the above-mentioned technical operation. It is possible and environmentally friendly. Even when aluminate (salt) is precipitated by the reaction, the “filtered water obtained by filtering it” approaches neutrality.
　食材乾燥容器３０に導入する水素ガスとしては、上記水素ガス発生器２０で生成させた発生水素ガス、及び／又は、食材Ｆを有する食材乾燥容器３０の内部を通過して「該食材中の水蒸気を含有した水素ガス」から該水蒸気を除いた還流水素ガスが使用できる。漏洩で不足した分の還流水素ガスを発生水素ガスで補うことが好ましい。
　発生水素ガスや還流水素ガスは、密閉容器中で加熱して１３．２気圧以上にすると、水素の臨界温度は３３Ｋ（－２４０℃）なので、定義上は超臨界になる。 The hydrogen gas to be introduced into the food drying container 30 passes through the inside of the food drying container 30 having the generated hydrogen gas generated by the hydrogen gas generator 20 and / or the food F, and “water vapor in the food The reflux hydrogen gas obtained by removing the water vapor from the “hydrogen gas containing” can be used. It is preferable to supplement the recirculated hydrogen gas in a shortage due to leakage with the generated hydrogen gas.
When the generated hydrogen gas or refluxing hydrogen gas is heated to 13.2 atm or higher in a closed container, the critical temperature of hydrogen is 33K (−240 ° C.), so it becomes supercritical by definition.
　図２と図３に水素ガス発生器２０の概略図を示す。アルカリ水タンク２３内のアルカリ水２２を有する水素ガス発生器２０の中内部に金属２１を係留し投入すると水素ガスが発生する。水素ガス発生器２０で生成させた発生水素ガスは、水素ガス加熱装置２８、一時的貯留タンク２６、及び、要すれば除湿フィルター４１を介して、食材乾燥容器３０の中に導入される。生成水素移送ポンプ（図示せず）を用いて、食材乾燥容器３０の中に導入してもよい。
　水素ガスは、食材乾燥容器３０の中に導入する途中で（前に）、水素ガス発生器２０及び水素ガス加熱装置２８と一時的貯留タンク２６で加温し加圧される。
　本発明の食材乾燥装置１０は、食材乾燥容器３０に導入前の水素ガスを、水素ガス加熱装置２８と一時的貯留タンク２６において、加熱・加圧するようになっていることが、乾燥効率が良い点、圧力を上げられる点等から必須である。
　水素ガスの食材乾燥容器３０の中への導入は、ノズルを用いて噴射させもよいし、下方から導入又は噴射させてもよいが、下方から導入又は噴射させることが更に好ましい。 2 and 3 are schematic views of the hydrogen gas generator 20. When the metal 21 is moored and charged into the hydrogen gas generator 20 having the alkaline water 22 in the alkaline water tank 23, hydrogen gas is generated. The generated hydrogen gas generated by the hydrogen gas generator 20 is introduced into the food drying container 30 through the hydrogen gas heating device 28, the temporary storage tank 26, and, if necessary, the dehumidifying filter 41. You may introduce | transduce into the foodstuff drying container 30 using a production | generation hydrogen transfer pump (not shown).
The hydrogen gas is heated and pressurized by the hydrogen gas generator 20, the hydrogen gas heating device 28 and the temporary storage tank 26 while being introduced into the food drying container 30 (before).
The food drying apparatus 10 of the present invention has good drying efficiency because the hydrogen gas before being introduced into the food drying container 30 is heated and pressurized in the hydrogen gas heating device 28 and the temporary storage tank 26. It is essential from the point that the pressure can be raised.
The introduction of the hydrogen gas into the food material drying container 30 may be injected using a nozzle, or may be introduced or injected from below, but is more preferably introduced or injected from below.
　抜き取り管２５からは、残水２４の水は経口可能であり、養殖水等の別用途に有効に使用することもできる。反応によってアルミン酸（塩）が析出しない残水濾過不要の新規技術が更に好ましい。 From the extraction tube 25, the remaining water 24 can be orally used and can be effectively used for other purposes such as aquaculture water. A novel technique that does not require residual water filtration, in which aluminate (salt) is not precipitated by the reaction, is more preferable.
＜＜食材棚を具備した食材乾燥容器＞＞
　図２に食材乾燥容器３０の一例を示す。図２の食材乾燥容器３０は、内部に「網状であって食材を下から保持する食材棚３１」を有し、該食材棚３１に水素ガスを通過させ、該食材棚３１上の食材Ｆに対して水素ガスを接触・透過させることによって、該食材Ｆに含有されている水分を除去するようになっている。
　限定はされないが、食材棚３１を具備した食材乾燥容器３０は、図４（ｂ）に示したように、乾燥食材が粉末状にならず、比較的大きなものに使用されることが好ましい。 << Ingredient drying container with ingredient shelf >>
FIG. 2 shows an example of the food drying container 30. The food drying container 30 in FIG. 2 has a “food material shelf 31 that is net-like and holds the food material from below” inside, and allows hydrogen gas to pass through the food material shelf 31, so that the food material F on the food material shelf 31 passes through the food material F on the food material shelf 31. On the other hand, water contained in the food material F is removed by contacting and permeating hydrogen gas.
Although not limited, it is preferable that the food drying container 30 provided with the food shelf 31 is used for a relatively large dry food material as shown in FIG.
　該食材棚３１は網状になっており、その上に乗せた食材Ｆが下に落ちないようになっていると共に、水素ガスが下から上に通過できるようになっている。網状の目の大きさは、上記条件を満たせば特に限定はないが、０．１ｍｍ以上１００ｍｍ以下が好ましく、０．５ｍｍ以上５０ｍｍ以下がより好ましく、１ｍｍ以上２０ｍｍ以下が特に好ましい。また、上記「網状」は「多孔質メッシュ状」であることも好ましい。
　また、該網状の食材棚３１の上に、かごを乗せた形態でもよい。ただし、得られた乾燥食材が、例えば図４（ｂ）のような粉状であれば（粉状となることが予想されたら）、網目を更に細かくするか、食材棚３１の上にかごを乗せることも好ましい。 The food shelf 31 has a net-like shape so that the food F placed thereon does not fall down and allows hydrogen gas to pass from the bottom to the top. The mesh size is not particularly limited as long as the above conditions are satisfied, but is preferably 0.1 mm or more and 100 mm or less, more preferably 0.5 mm or more and 50 mm or less, and particularly preferably 1 mm or more and 20 mm or less. The “net-like” is also preferably “porous mesh-like”.
Moreover, the form which put the basket on this net-like foodstuff shelf 31 may be sufficient. However, if the obtained dried food is in the form of powder as shown in FIG. 4B (for example, if it is expected to become powder), the mesh is further refined or the basket is placed on the food shelf 31. It is also preferable to place it.
　網状の食材棚３１の素材は、特に限定はなく、網、織布、穿孔板等、何れでもよい。また、食材棚３１の材質も、特に限定はないが、金属；合成樹脂等の高分子；木材等の天然物；等、何れでもよいが、高分子又は木材であることが、水素による劣化が起き難い点、金属脆化問題が発生しない点等から特に好ましい。 The material of the net-like food shelf 31 is not particularly limited, and may be a net, a woven fabric, a perforated plate, or the like. The material shelf 31 is not limited to any particular material, but may be any of metals, polymers such as synthetic resins, natural products such as wood, and the like. This is particularly preferable because it does not easily occur and does not cause a problem of metal embrittlement.
　１個の食材乾燥容器３０の中にある食材棚３１の数は、特に限定はないが、１個以上２０個以下が好ましく、２個以上１５個以下がより好ましく、３個以上１０個以下が特に好ましい。
　また、食材乾燥容器３０は、並列に又は直列に複数個を連結させてもよい（図示せず）。連結は縦でも横でもよいが、横に並べることが、作業がし易いために好ましい。 The number of the food shelves 31 in one food drying container 30 is not particularly limited, but is preferably 1 or more and 20 or less, more preferably 2 or more and 15 or less, and 3 or more and 10 or less. Particularly preferred.
A plurality of food drying containers 30 may be connected in parallel or in series (not shown). The connection may be vertical or horizontal, but it is preferable to arrange them horizontally because they are easy to work.
　まず、食材Ｆを必要に応じて適宜切断し、食材投入ホッパー３７から食材乾燥容器３０に投入する。次いで、水素ガス発生器２０から発生する発生水素ガスを、適温に加熱後、水素ガス導入管３２を用いて食材乾燥容器３０の中に導入する。発生水素ガスの食材乾燥容器３０への噴射位置は、どこからでもよいが、図２に示したように、水素ガス導入管３２の所々に穴を開けて食材Ｆに当てること、又は特に下方から噴射することが、乾燥効率の点から特に好ましい。
　また、水素ガス導入前に、食材乾燥容器３０の中を真空引きし、その後に水素ガス導入を開始することが無酸素状態にできる点、乾燥効率向上、抗菌性向上、酸化防止等の点から好ましい。 First, the food material F is appropriately cut as necessary, and is loaded into the food material drying container 30 from the food material charging hopper 37. Next, the generated hydrogen gas generated from the hydrogen gas generator 20 is heated to an appropriate temperature, and then introduced into the food drying container 30 using the hydrogen gas introduction pipe 32. The injection position of the generated hydrogen gas to the food material drying container 30 may be anywhere, but as shown in FIG. 2, holes are made in the hydrogen gas introduction pipes 32 to hit the food material F, or particularly from below. It is particularly preferable from the viewpoint of drying efficiency.
In addition, it is possible to evacuate the food drying container 30 before introducing hydrogen gas, and then start introducing hydrogen gas in an oxygen-free state, from the viewpoints of improving drying efficiency, improving antibacterial properties, preventing oxidation, etc. preferable.
　食材Ｆから水分を除去した「水蒸気と水素ガス」からなる気体は、「水蒸気と還流水素ガスの１次出口３６」から取出され管内で除湿され、還流水素ガス移送ポンプ３５によって還流水素ガス移送管３３の中を移送され、還流水素ガス導入ノズル３４から、食材乾燥容器３０の中に導入又は噴射される（図２）。
　還流水素ガスの食材乾燥容器３０への噴射位置は、どこからでもよく、発生水素ガスの場合と同様に、導入管の所々に穴を開けて、食材Ｆに横から当ててもよいし（図示せず）、図２に示したように、下から還流水素ガス導入ノズル３４によって、食材Ｆに向けて下から噴射させてもよい。 The gas composed of “water vapor and hydrogen gas” from which moisture has been removed from the food material F is taken out from the “primary outlet 36 for water vapor and reflux hydrogen gas”, dehumidified in the pipe, and refluxed hydrogen gas transfer pipe 35 by the reflux hydrogen gas transfer pump 35. 33, and is introduced or injected into the food drying container 30 from the reflux hydrogen gas introduction nozzle 34 (FIG. 2).
The position where the reflux hydrogen gas is injected into the food drying container 30 may be from any location, and in the same manner as in the case of the generated hydrogen gas, holes may be made in places in the introduction pipe and applied to the food F from the side (not shown). 2), as shown in FIG. 2, it may be injected from below toward the food F by the reflux hydrogen gas introduction nozzle 34 from below.
＜＜細長く螺旋状になっている食材乾燥容器＞＞
　上記食材乾燥容器３０は、図３に示したように、細長い螺旋状になっており、食材Ｆを水素ガスの流体に乗せて内部を通過させることによって、該食材Ｆに含有されている水分を除去するようになっているものも好ましい。
　限定はされないが、細長く螺旋状になっている食材乾燥容器３０は、図４（ａ）に示したように、乾燥食材が粉末状になるものに使用されることが好ましい。 << Elongated and spiral food drying container >>
As shown in FIG. 3, the food drying container 30 has an elongated spiral shape, and the food F is placed on a hydrogen gas fluid to pass through the inside thereof, so that the moisture contained in the food F is contained. Those which are designed to be removed are also preferred.
Although not limited, as shown in FIG. 4 (a), the food drying container 30 that is elongated and spiral is preferably used in a form in which the dry food becomes powdery.
　この場合も、上記と同様に、食材Ｆを必要に応じて適宜切断し、食材投入ホッパー３７から食材乾燥容器３０に投入する。
　次いで、水素ガス発生器２０から発生する発生水素ガスを、水素ガス導入管３２を用いて食材乾燥容器３０の中に、螺旋状の食材乾燥容器３０の始点付近から導入する。
　また、食材Ｆから水分を除去した「水蒸気と水素ガス」からなる気体を、螺旋状の食材乾燥容器３０の終点付近に存在する「水蒸気と還流水素ガスの１次出口３６」から取出し、還流水素ガス移送ポンプ３５によって還流水素ガス移送管３３の中を移送し、食材乾燥容器３０の中に、螺旋状の食材乾燥容器３０の始点付近から導入する（図３）。 Also in this case, similarly to the above, the food F is appropriately cut as necessary, and is loaded into the food drying container 30 from the food charging hopper 37.
Next, the generated hydrogen gas generated from the hydrogen gas generator 20 is introduced into the food material drying container 30 from the vicinity of the starting point of the spiral food material drying container 30 using the hydrogen gas introduction pipe 32.
In addition, a gas composed of “water vapor and hydrogen gas” from which moisture has been removed from the food material F is taken out from the “primary outlet 36 of water vapor and reflux hydrogen gas” existing near the end point of the spiral food drying container 30, and is then refluxed hydrogen. The gas is transferred through the reflux hydrogen gas transfer pipe 33 by the gas transfer pump 35 and introduced into the food drying container 30 from the vicinity of the starting point of the spiral food drying container 30 (FIG. 3).
　還流水素ガス移送管３３の途中には、除湿装置４０を設け、そこで水蒸気を除去し、得られた乾燥水素ガスを還流水素ガスとして、食材乾燥容器３０の中に再度導入することが好ましい。 In the middle of the reflux hydrogen gas transfer pipe 33, it is preferable to provide a dehumidifier 40, where water vapor is removed, and the obtained dry hydrogen gas is introduced again into the food drying container 30 as reflux hydrogen gas.
　細長く螺旋状になっている食材乾燥容器３０の内壁には、所々に、突起、邪魔板（バッファ）等を設けて（図示せず）、水素ガスの乱流を作り、食材Ｆをジグザグに移動させると共に、水素ガスの乱流によって食材Ｆ中の水分を効率よく除去することが好ましい。
　また、食材乾燥容器３０の内に、所々に除湿フィルター４１を設けて、水素ガス中の水分を除去することが好ましい。 Protrusions, baffles (buffers), etc. (not shown) are provided on the inner wall of the elongated and spiral food drying container 30 to create a turbulent flow of hydrogen gas and move the food F in a zigzag manner. In addition, it is preferable to efficiently remove moisture in the food material F by the turbulent flow of hydrogen gas.
Moreover, it is preferable to provide the dehumidification filter 41 in some places in the foodstuff drying container 30, and to remove the water | moisture content in hydrogen gas.
　また、螺旋状の食材乾燥容器３０の下面の所々には、食材乾燥容器３０の内壁に結露した水滴を集めて抜き取るための水抜き取り管４２（ドレン）（図示せず）が設けてあることが好ましい。 Further, water drainage pipes 42 (drain) (not shown) for collecting and extracting water droplets condensed on the inner wall of the food drying container 30 may be provided at places on the lower surface of the spiral food drying container 30. preferable.
＜＜除湿（装置）＞＞
　「水蒸気と還流水素ガスの１次出口３６」から取出された、「水蒸気と水素ガスからなる気体」は、除湿装置４０を通過させることによって水蒸気を除去し、得られた乾燥水素ガスを、還流水素ガスとして食材乾燥容器３０の中に導入又は噴射することが好ましい。
　除湿装置４０の構成は、特に限定はないが、図２に示したように、タンク状になっていて、タンク内に結露した水滴を集めて水抜き取り管４２（ドレン）から抜き取ることが好ましい。更に、還流水素ガスに水分を連行させないために、ドレントラップを設けることが好ましい。 << Dehumidification (Device) >>
The “gas consisting of water vapor and hydrogen gas” taken out from the “primary outlet 36 of water vapor and refluxing hydrogen gas” removes the water vapor by passing through the dehumidifying device 40, and the resulting dry hydrogen gas is refluxed. It is preferable to introduce or inject into the food drying container 30 as hydrogen gas.
Although the configuration of the dehumidifying device 40 is not particularly limited, it is preferable that the dehumidifying device 40 has a tank shape as shown in FIG. 2, and water droplets condensed in the tank are collected and extracted from the water drain pipe 42 (drain). Furthermore, it is preferable to provide a drain trap so that moisture is not entrained in the refluxing hydrogen gas.
　また、除湿装置４０の内部には、除湿フィルター４１を設置して、水蒸気を更に除去することが好ましい。該除湿フィルター４１は、特に限定はなく公知のものが使用される。
　上記除湿装置４０は、除湿フィルター４１を内蔵したパイプ状のものであることも、除湿効果が高いために好ましい。 Further, it is preferable to install a dehumidifying filter 41 inside the dehumidifying device 40 to further remove water vapor. The dehumidifying filter 41 is not particularly limited, and a known filter is used.
The dehumidifying device 40 is preferably a pipe having a built-in dehumidifying filter 41 because the dehumidifying effect is high.
＜＜食材＞＞
　水素ガスは、物体に対しての浸透性が高いため、ガスバリヤー性の高い物質・物体にも浸透・透過する。従って、硬い食材の乾燥に好適である。
　例えば、ジャガイモ、サツマイモ、長芋、ヤマトイモ、サトイモ等のイモ類（の皮）；ニンジン、ゴボウ、レンコン等の根菜（の皮）；リンゴ、柿、オレンジ等の果物（の皮）；きくらげ、シイタケ等のキノコ；魚、アワビ、ナマコ等の海産物；等、水分の多い食材、乾燥させ難い食材、硬い食材、原形を留めておいて乾燥させるために大きな食材等の乾燥に特に好適である。 << Ingredients >>
Since hydrogen gas has high permeability to an object, it penetrates and permeates a substance / object having a high gas barrier property. Therefore, it is suitable for drying hard food.
For example, potatoes (skins) such as potatoes, sweet potatoes, Nagatoro, Yamatoimo, taro, etc .; root vegetables (skins) such as carrots, burdock, lotus roots; fruits (skins) such as apples, strawberries, oranges; jellyfish, shiitake, etc. Mushrooms such as fish, abalone, sea cucumber, etc .; especially suitable for drying foods with high moisture content, hard-to-dry foods, hard foods, large foods to keep the original shape and dry.
　食材Ｆは、本発明の食材乾燥装置１０を用いて乾燥する前に（本発明の食材乾燥方法を使用する前に）、予備乾燥をしておいてもよい。該予備乾燥をしておき、移送や保存をしておいた食材Ｆを使用することも好ましい。該予備乾燥は、通常の食材乾燥方法で行っても、本発明の食材乾燥方法で行ってもよい。予備乾燥で水分量を５０質量％以下にしておけば、実用的な保存が可能である。 The ingredients F may be pre-dried before being dried using the ingredients drying apparatus 10 of the present invention (before using the ingredients drying method of the present invention). It is also preferable to use the food F which has been pre-dried and which has been transported and stored. The preliminary drying may be performed by a normal food drying method or the food drying method of the present invention. If the water content is 50% by mass or less by preliminary drying, practical storage is possible.
＜＜乾燥食材及びその製造方法＞＞
　本発明は、上記の食材乾燥方法を使用することを特徴とする乾燥食材の製造方法でもある。
　また、上記の食材乾燥装置１０を用いて、水素ガスを食材Ｆに接触・透過させて、該食材Ｆに含有されている水分を除去することを特徴とする乾燥食材の製造方法でもある。 << Dry foodstuff and manufacturing method thereof >>
This invention is also a manufacturing method of the dried foodstuff characterized by using said foodstuff drying method.
Moreover, it is also a manufacturing method of the dry foodstuff characterized by removing the water | moisture content contained in this foodstuff F by making hydrogen gas contact and permeate | transmit the foodstuff F using said foodstuff drying apparatus 10. FIG.
＜＜乾燥食材＞＞
　本発明の食材乾燥方法や食材乾燥装置１０を用いて得られる乾燥食材としては、魚粉、肉粉、デンプン粉、ドライフルーツ、野菜パウダー等が好ましいものとして挙げられる。また、得られた乾燥食材は、サプリメント、乾燥粉体、タブレット等の栄養食品・健康食品；粉体（タブレット）等の医療薬剤；ふりかけ、干物、保存食等の一般食品；香辛料；漢方薬剤；緑茶、紅茶等の茶；小麦粉、片栗粉、米粉、そば粉、パン粉等の粉；等として有用である。また、温度を上げれば、焙煎やノンフライ調理等としても有用である。
　水素ガスは物体に対する浸透性、熱伝導性が高いので、該乾燥食材としては、ナマコ、アワビ、魚等の体積の大きい「海産物そのままの姿の乾燥品（乾物）」が、本発明の特長を生かしたものとして、特に好ましいものとして挙げられる。 << Dry ingredients >>
Preferable examples of the dried food obtained using the food drying method and the food drying apparatus 10 of the present invention include fish powder, meat powder, starch powder, dried fruit, and vegetable powder. In addition, the obtained dried foods are supplements, dry powders, nutritional foods and health foods such as tablets; medical drugs such as powders (tablets); general foods such as sprinkles, dried fish and preserved foods; spices; It is useful as tea such as green tea and black tea; flour such as starch, rice flour, buckwheat flour and bread crumbs; In addition, increasing the temperature is useful for roasting, non-fry cooking, and the like.
Since hydrogen gas is highly permeable to objects and has high thermal conductivity, the dried food has a large volume of sea cucumber, abalone, fish, etc. It is mentioned as a particularly preferable one that has been utilized.
　本発明の食材乾燥方法が優れた乾燥効果（水分の除去効果）を示す作用・原理としては、以下のことが考えられる。ただし本発明は、以下の作用・原理の及ぶ範囲に限定されるわけではない。 The following can be considered as the action / principle showing the excellent drying effect (moisture removal effect) of the food drying method of the present invention. However, the present invention is not limited to the scope of the following actions and principles.
　１気圧０℃の水素ガスの熱伝導率は、１６８ｍＷ／（ｍ・Ｋ）であり、それに対して空気の熱伝導率は、２４ｍＷ／（ｍ・Ｋ）である。
　また、１気圧２５℃の水素ガスの熱伝導率は、１８５ｍＷ／（ｍ・Ｋ）であり、それに対して空気の熱伝導率は、２６ｍＷ／（ｍ・Ｋ）である。
　また、１気圧５０℃の水素ガスの熱伝導率は、１９２ｍＷ／（ｍ・Ｋ）であり、それに対して空気の熱伝導率は、２８ｍＷ／（ｍ・Ｋ）である。
　このように、１気圧における水素ガスの熱伝導率は、同じく１気圧における空気の熱伝導率に対して、何れの温度においても約７倍である。
　熱伝導率が高いことで知られるヘリウムガスと比較しても、何れの温度においても、水素ガスの方が、熱伝導率が高い。更に、ヘリウムガスは、水素ガスに比べてはるかに高価である。 The thermal conductivity of hydrogen gas at 1 atm 0 ° C. is 168 mW / (m · K), whereas the thermal conductivity of air is 24 mW / (m · K).
In addition, the thermal conductivity of hydrogen gas at 1 atm. 25 ° C. is 185 mW / (m · K), whereas the thermal conductivity of air is 26 mW / (m · K).
In addition, the thermal conductivity of hydrogen gas at 1 atmosphere and 50 ° C. is 192 mW / (m · K), whereas the thermal conductivity of air is 28 mW / (m · K).
Thus, the thermal conductivity of hydrogen gas at 1 atm is about 7 times at any temperature relative to the thermal conductivity of air at 1 atm.
Compared to helium gas, which is known for its high thermal conductivity, hydrogen gas has higher thermal conductivity at any temperature. Furthermore, helium gas is much more expensive than hydrogen gas.
　また、水素分子は極性が低いため、あらゆる固体物質に対する透過性・浸透性が高い。
　上記のような理由により、緩和な条件（温度、圧力等）で、短時間でも水分の除去が可能になったと考えられる。 In addition, since hydrogen molecules have low polarity, they are highly permeable and permeable to all solid substances.
For the reasons described above, it is considered that moisture can be removed in a short time under mild conditions (temperature, pressure, etc.).
　本発明の態様１の一例を図１ないし図３に示すが、本発明の態様１はこれらに示した具体的態様には限定されない。以下に、図１の説明を記載する。
　アルカリ水１は、水素ガス発生器２に空間を残し適量注入する。注入されたアルカリ水１は金属１５と反応し水素ガスを連続的に発生する。発生した水素は、導入管を通してマイクロ波加熱装置内の渦巻き式加熱チューブ内に入り核食材に適合する適温に加熱される。更に、マイクロ波励起加熱装置からも水蒸気６が発生するが、その水蒸気は７の貯留タンク外周部からも加熱される。 An example of Embodiment 1 of the present invention is shown in FIGS. 1 to 3, but Embodiment 1 of the present invention is not limited to the specific embodiments shown in these. The description of FIG. 1 will be described below.
Alkaline water 1 is injected in an appropriate amount leaving a space in the hydrogen gas generator 2. The injected alkaline water 1 reacts with the metal 15 to continuously generate hydrogen gas. The generated hydrogen enters the spiral heating tube in the microwave heating apparatus through the introduction tube and is heated to an appropriate temperature suitable for the nuclear food material. Furthermore, although the water vapor 6 is also generated from the microwave excitation heating device, the water vapor is also heated from the outer peripheral portion of the storage tank 7.
　その加熱された水素は、一時的貯留タンク７に入り、噴射孔９から噴射され、乾燥炉内の乾燥棚上の食材に浸透透過し素材の深部外部を循環しながら乾燥する。
　食材中の自由水及び結合水は徐々に水素ガスと共に蒸発するが、乾燥炉上部から還流する水素ガス１２は、垂直部位配管内にセットされている除湿素材２０にその水分のみは吸着し、内外温度差の温度低下と共にその水分は落水し、ドレントラップ１３に導かれるため、水素ガス気体は、乾燥状態になり循環パイプから再び３の加熱チューブ４に入り加熱され循環し、食材を繰り返し乾燥させる。（閉サイクル方式） The heated hydrogen enters the temporary storage tank 7, is injected from the injection hole 9, permeates and permeates the food on the drying shelf in the drying furnace, and dries while circulating through the deep part of the material.
Free water and combined water in the food material gradually evaporate together with hydrogen gas, but the hydrogen gas 12 refluxed from the upper part of the drying furnace adsorbs only its moisture to the dehumidifying material 20 set in the vertical part piping, and inside and outside As the temperature drops due to the temperature difference, the water drops and is guided to the drain trap 13, so that the hydrogen gas gas becomes dry and enters the heating tube 4 again through the circulation pipe and circulates to repeatedly dry the food. . (Closed cycle method)
　以下に、実施例及び比較例を挙げて本発明の態様１を更に具体的に説明するが、本発明は、その要旨を超えない限りこれらの実施例に限定されるものではない。 Hereinafter, the embodiment 1 of the present invention will be described more specifically with reference to examples and comparative examples, but the present invention is not limited to these examples as long as the gist thereof is not exceeded.
実施例１
　図２に概略を示した食材乾燥装置１０を用いて食材Ｆを乾燥させた。
　水素ガス発生（装置）（図３参照）において、自然石と貝殻を含む天然物２７に水を加えて得られるアルカリ水２２を用い、金属２１としてアルミニウムを用い、両者が接触することによって発生した水素ガスを水素ガス加熱装置２８で加熱した後、３５℃にして食材乾燥容器３０に導入した。 Example 1
The food material F was dried using the food material drying apparatus 10 schematically shown in FIG.
In hydrogen gas generation (apparatus) (see FIG. 3), alkaline water 22 obtained by adding water to natural product 27 including natural stones and shells was used, and aluminum was used as metal 21. After heating the hydrogen gas with the hydrogen gas heating device 28, the temperature was set to 35 ° C. and introduced into the food drying container 30.
　食材乾燥容器３０に設けられた、目開き１ｃｍ×１ｃｍのポリプロピレンでできた食材棚３１の上に乗せた食材Ｆに水素ガスを吹き付けた。
　食材乾燥容器３０は、１個に３段の食材棚３１があるものを５個並列に連結したものであった。 Hydrogen gas was blown onto the food material F placed on the food material shelf 31 made of polypropylene having an opening of 1 cm × 1 cm provided in the food material drying container 30.
The food drying container 30 was formed by connecting five food storage shelves 31 in parallel to each other.
　食材Ｆは何れも大きさや形が規格外のものであり、約３ｃｍ×約１ｃｍ×約１ｃｍに前もって切断したニンジン、長芋、ゴボウ、及び、ジャガイモであり、水分量５０質量％になるまで、通常の乾燥方法で予備乾燥したものであった。
　それら合計５ｋｇを、上記した全部で１５段（３段×５個）の食材棚３１の上に乗せ、それらに加温した水素ガスを下方から噴射した。 Ingredients F are all non-standard in size and shape, and are carrots, grated burdock, burdock, and potato cut in advance to about 3 cm x about 1 cm x about 1 cm. It was predried by the drying method.
A total of 5 kg was placed on the above-described 15-stage (three-stage × 5) food shelves 31, and heated hydrogen gas was injected from below.
　水素ガスは、上記した発生水素ガスの他に、図２に示したような、「水蒸気と還流水素ガスの１次出口３６」と「還流水素ガス導入ノズル３４」を有する食材乾燥容器３０を用い、一度乾燥に用いた還流水素ガスも用いた。
　還流水素ガスは、内部に除湿フィルター４１を具備した除湿装置４０を通過させて除湿し、３５℃にして、食材乾燥容器３０の下部から上に向けて噴射した。 As the hydrogen gas, in addition to the generated hydrogen gas, a food drying container 30 having a “primary outlet 36 for water vapor and reflux hydrogen gas” and a “reflux hydrogen gas introduction nozzle 34” as shown in FIG. 2 is used. The reflux hydrogen gas once used for drying was also used.
The refluxed hydrogen gas was dehumidified by passing through a dehumidifying device 40 provided with a dehumidifying filter 41 therein, and was made 35 ° C. and jetted upward from the bottom of the food drying container 30.
　乾燥開始から乾燥終了までに要した時間は１０分であった。
　乾燥された野菜チップは、ビタミンや酵素が分解（変性）も失活もせず、そのまま残存していた。また、デンプンは、βデンプンのままであった。
　得られた野菜チップは、保存食、栄養食として有用であった。 The time required from the start of drying to the end of drying was 10 minutes.
In the dried vegetable chips, vitamins and enzymes were not decomposed (denatured) or inactivated and remained as they were. Also, the starch remained as beta starch.
The obtained vegetable chip was useful as a preserved food and a nutritional food.
実施例２
　図３に概略を示した食材乾燥装置１０を用いて食材Ｆを乾燥させ、水分量１５質量％になるまで、通常の乾燥方法で予備乾燥した魚を用いた以外は、実施例１と同様にして乾燥をした。
　投入ホッパーから食材Ｆを入れ、実施例１と同様にして得られた３５℃の水素ガスを、内部に楕円形の突起を有する「細長く螺旋状になった食材乾燥容器３０」の中に導入し回流させた。 Example 2
The foodstuff F was dried using the foodstuff drying apparatus 10 schematically shown in FIG. 3, and the same procedure as in Example 1 was used except that the fish preliminarily dried by a normal drying method was used until the water content reached 15% by mass. And dried.
Ingredient F is put in from the charging hopper, and hydrogen gas at 35 ° C. obtained in the same manner as in Example 1 is introduced into an “elongated and spirally shaped ingredient drying container 30” having an elliptical protrusion inside. Circulated.
　乾燥開始から乾燥終了までに要した時間は１０分であった。
　得られた魚粉は、ビタミンや酵素が分解（変性）も失活もせず、そのまま残存しており、保存食、栄養食、料理添加材、ふりかけ等として有用であった。 The time required from the start of drying to the end of drying was 10 minutes.
The obtained fish meal was not decomposed (denatured) or inactivated, and remained as it was, and was useful as a preserved food, nutritional food, cooking additive, sprinkles and the like.
比較例１
　実施例１において、水素ガスに代えて空気を用いた以外は、実施例１と同様にして乾燥をしたが、乾燥開始から乾燥終了までに、実施例１の約７倍の時間である１時間１０分を要した。 Comparative Example 1
In Example 1, drying was performed in the same manner as in Example 1 except that air was used instead of hydrogen gas, but 1 hour which was about 7 times as long as Example 1 from the start of drying to the end of drying. It took 10 minutes.
＜態様２＞
　以下、態様２について記載する。態様２の一例を図５ないし図７に示すが、「図５ないし図７に使用されている符号」及び「下記する態様２の記載中の符号」は、態様２にのみ適用されるものとする。すなわち、「下記する態様２の記載中の符号」は、「図５ないし図７に使用されている符号」に対応し、他の態様や他の図では同じ符号が他のものに使用されていることがある。 <Aspect 2>
Hereinafter, Embodiment 2 will be described. An example of Aspect 2 is shown in FIG. 5 to FIG. 7, but “the reference numerals used in FIG. 5 to FIG. 7” and “the reference numerals in the description of Aspect 2 below” are applied only to Aspect 2. To do. That is, “the reference numerals in the description of the aspect 2 described below” correspond to “the reference numerals used in FIGS. 5 to 7”, and the same reference numerals are used in other aspects and other drawings. There may be.
　本発明の態様２は、上記の水素流体閉サイクル装置を具備する抗酸化作用付与装置であって、
　少なくとも、以下の（ａ）、（ｂ）及び（Ｒ２）を具備するものであることを特徴とする抗酸化作用付与装置である。
（ａ）化学反応で水素ガスを発生させる水素ガス発生器
（ｂ）上記（ａ）水素ガス発生器で発生した水素ガスの温度を昇温制御する水素ガス昇温制御装置
（Ｒ２）該水素ガスをヒトに吸入させる水素ガス吸入マスク、又は、該水素ガスをヒト若しくはヒトの一部に接触させる水素ガス吐出充満容器 Aspect 2 of the present invention is an antioxidant effect imparting device comprising the above hydrogen fluid closed cycle device,
An antioxidant action imparting device characterized by comprising at least the following (a), (b) and (R2).
(A) Hydrogen gas generator for generating hydrogen gas by chemical reaction (b) Hydrogen gas temperature rise control device (R2) for raising the temperature of the hydrogen gas generated by the above (a) hydrogen gas generator (R2) The hydrogen gas Hydrogen gas inhalation mask that allows a human to inhale, or a hydrogen gas discharge filling container that makes the hydrogen gas contact a human or a part of the human
＜＜水素ガス発生器＞＞
　本発明の態様２に使用される水素ガス発生器２は、化学反応で水素ガスを発生させるようになっている。すなわち、本発明の「（１）水素ガスを発生させる水素ガス発生器」が「（ａ）化学反応で水素ガスを発生させる水素ガス発生器」である。
　抗酸化作用付与装置１に具備された装置内で、化学反応で水素ガスを発生させることで、水素水等の途中段階の製品を必要としない、水素ガス発生器２としては電気を消費しない、コンパクトにできる等が達成できる。 << Hydrogen gas generator >>
The hydrogen gas generator 2 used in the embodiment 2 of the present invention generates hydrogen gas by a chemical reaction. That is, “(1) a hydrogen gas generator for generating hydrogen gas” of the present invention is “(a) a hydrogen gas generator for generating hydrogen gas by a chemical reaction”.
By generating hydrogen gas through a chemical reaction in the device provided in the antioxidant device 1, no intermediate product such as hydrogen water is required, and the hydrogen gas generator 2 does not consume electricity. Compactness can be achieved.
　化学反応で水素ガスを発生させる装置の中でも、金属１２にアルカリ水１１を接触させることによって水素ガスを発生させられるようになっているものが、本発明の抗酸化作用付与装置に必要な水素の量としては十分である；アルカリ水１Ｌから最低１１３０Ｌの水素ガスが得られるので、よりコンパクトにできる、ボンベ代・電気代等のコストがかからない；等の点から好ましい。図５ないし図７参照。
　また、例えば、自然石（石灰石等）、貝殻、珊瑚石等の天然物から得られた水素ガス発生前のアルカリ水は、カルシウムイオンの濃度が極めて高いため、水素ガス発生後には、カルシウムイオンを含有する水が副産物として得られる。 Among the devices that generate hydrogen gas by chemical reaction, the one that can generate hydrogen gas by bringing the alkaline water 11 into contact with the metal 12 is the hydrogen necessary for the antioxidant effect imparting device of the present invention. The amount is sufficient; since hydrogen gas of at least 1130 L can be obtained from 1 L of alkaline water, it can be made more compact, and costs such as cylinder charges and electricity charges are not required; See FIGS.
In addition, alkaline water before hydrogen gas generation obtained from natural products such as natural stone (limestone, etc.), shells, and meteorites has a very high calcium ion concentration. Containing water is obtained as a by-product.
　図５（ａ）に、水素ガス発生器２の概要を示す。水素ガス発生器２における水素の発生は、金属１２にアルカリ水１１を接触させることによることが好ましい。該金属１２には、合金も含まれ、金属含有物に加工したものも含まれる。
　該金属元素としては、アルミニウム（Ａｌ）、亜鉛（Ｚｎ）、チタン（Ｔｉ）、スズ（Ｓｎ）等の金属が好ましく、安全性、コスト（安価）、生成物が有用物である等の観点から、アルミニウム（Ａｌ）が特に好ましい。また、該金属１２としては、イオン化傾向の高い金属も好ましい。 FIG. 5A shows an outline of the hydrogen gas generator 2. The generation of hydrogen in the hydrogen gas generator 2 is preferably caused by bringing the alkaline water 11 into contact with the metal 12. The metal 12 includes alloys, and includes those processed into metal-containing materials.
The metal element is preferably a metal such as aluminum (Al), zinc (Zn), titanium (Ti), tin (Sn), etc., from the viewpoints of safety, cost (inexpensive), and useful products. Aluminum (Al) is particularly preferable. The metal 12 is also preferably a metal having a high ionization tendency.
　該アルカリ水のｐＨとしては、特に限定はないが、１２以上が好ましく、１２．５以上がより好ましく、１３以上１４が特に好ましい。 The pH of the alkaline water is not particularly limited, but is preferably 12 or more, more preferably 12.5 or more, and particularly preferably 13 or more.
　金属元素としてアルミニウムを用いたときの最終的な化学反応について、示性式の記載方法は種々あるが、例えば以下の反応式（１）のようになる。
　２Ａｌ＋６ＯＨ－ → ２（ＡｌＯ３）３－＋３Ｈ２　・・・・・（１） Regarding the final chemical reaction when aluminum is used as the metal element, there are various methods for describing the characteristic formula. For example, the following reaction formula (1) is obtained.
2Al + 6OH - → 2 (AlO 3) 3- + 3H 2 ····· (1)
　（好ましくは、反応によってアルミン酸（塩）が析出しない特殊な技術操作で）、化学量論的に、１Ｌのアルカリ水から、標準状態で最低１１３０Ｌ以上の水素ガスを得ることができるので、本発明の装置に用いる水素ガスの量としては十分である。 (Preferably, with a special technical operation in which aluminate (salt) is not precipitated by the reaction), a stoichiometric amount of hydrogen gas of at least 1130 L can be obtained from 1 L of alkaline water in a standard state. The amount of hydrogen gas used in the apparatus of the invention is sufficient.
　上記アルカリ水１１は、特に限定はないが、自然石（石灰石等）、貝殻、珊瑚石等の天然物から得ることが、環境に優しいために特に好ましい。
　また、該アルカリ水１１を、アルミニウム（Ａｌ）等の金属１２に接触させて水素ガスを発生させた後においてもアルミン酸の析出がない技術的な操作方法では濾過を必要せず経口摂取可能で、その点からも環境に優しい。 The alkaline water 11 is not particularly limited, but it is particularly preferable to obtain the alkaline water 11 from natural products such as natural stones (limestone, etc.), shells, meteorites and the like because they are environmentally friendly.
Further, even after the alkaline water 11 is brought into contact with a metal 12 such as aluminum (Al) to generate hydrogen gas, it can be taken orally without filtration by a technical operation method in which no aluminate is deposited. From that point, it is also environmentally friendly.
　水素ガス発生器２で発生させた水素ガスは、水素ガス導入管１５、２３を通って、水素ガス吸入マスク１７、又は、水素ガス吐出充満容器２７に送られる。その間に、図５のように除湿フィルター１８（図６では図示せず）を介することが好ましい。 Hydrogen gas generated by the hydrogen gas generator 2 is sent to the hydrogen gas suction mask 17 or the hydrogen gas discharge full container 27 through the hydrogen gas introduction pipes 15 and 23. In the meantime, it is preferable to pass through a dehumidifying filter 18 (not shown in FIG. 6) as shown in FIG.
＜＜水素ガス昇温制御装置＞＞
　また、発生した水素ガスを水素ガス吐出充満容器２７に送るときは、途中に、水素ガスの温度を昇温制御する水素ガス昇温制御装置３を設ける。
　水素ガスの温度を昇温制御することは、圧力を高くして、水素ガス吐出充満容器２７の中に導入又はノズルを利用して噴射させるために好ましいことに加え、以下の効果も奏する。圧力を高くするために、水素ガス加熱装置と一時的貯留タンクを設けることが必須である（図６（ａ）、（ｂ）、図７では図示せず）。
　該水素ガス加熱装置と該一時的貯留タンクは、水素ガス昇温制御装置３の前に設置されていてもよいし、後に設置されていてもよいし、その昇温部分等が水素ガス昇温制御装置３と兼ね合わされていてもよい。 << Hydrogen Gas Temperature Control Device >>
In addition, when the generated hydrogen gas is sent to the hydrogen gas discharge full container 27, a hydrogen gas temperature rise control device 3 for raising the temperature of the hydrogen gas is provided on the way.
In addition to being preferable for controlling the temperature of the hydrogen gas to increase the pressure, the pressure is increased and the hydrogen gas is discharged or injected into the hydrogen gas discharge container 27 by using a nozzle, and the following effects are also achieved. In order to increase the pressure, it is essential to provide a hydrogen gas heating device and a temporary storage tank (not shown in FIGS. 6A and 6B and FIG. 7).
The hydrogen gas heating device and the temporary storage tank may be installed before or after the hydrogen gas temperature increase control device 3, and the temperature rising portion or the like may be installed in the hydrogen gas temperature increase control device 3. It may be combined with the control device 3.
　適温の水素ガスによって、気持ちが良くなったりすると共に、ヒト（の体）やヒトの（体の）一部又は全身の温度が上昇し、基礎体温も向上したり、血液循環の向上（血流促進）等で免疫力が上昇したり、白血球も増し活性化したりする。また、新陳代謝力が上がり、インシュリン分泌も促進される可能性がある。
　また、癌細胞も約４２℃を超えると、増殖が抑制され、アポトーシス（自滅）を促進させ、その結果、癌細胞を縮小させる可能性がある。 The appropriate temperature of hydrogen gas makes you feel better, increases the temperature of the human body, part of the human body, or the whole body, improves the basal body temperature, and improves blood circulation (blood flow Immunity is increased, and leukocytes are also increased and activated. It may also increase metabolic capacity and promote insulin secretion.
In addition, when the cancer cells exceed about 42 ° C., the proliferation is suppressed and apoptosis (self-destruction) is promoted, and as a result, the cancer cells may be reduced.
　本発明の態様２の抗酸化作用付与装置１は、水素ガス昇温制御装置３が、少なくとも、１５℃から４５℃までの範囲で、水素ガスの温度を制御しつつ段階的に上昇させられるようになっているものであることが好ましい。
　好ましい昇温速度は、体温（の３６℃位）から徐々に昇温し、好ましくは２分以上５分程度の時間をかけて徐々に昇温し、最高４５℃±１℃にまで昇温することが、熱さに対するショックが少なく、水素ガスが皮膚組織から血液や体の深部（例えば、細胞壁、細胞膜、細胞核、骨髄等）に浸透するために好ましい。
　３６℃から４５℃までにかける時間は、個人差があり様々であるが、より好ましくは５分～２０分であり、特に好ましくは１０分～１５分であるが、限定されるものではない。
　その後、２０分以上キープすることが、本発明の効果を得るために好ましい。 The antioxidant effect imparting device 1 according to the second aspect of the present invention is such that the hydrogen gas temperature raising control device 3 can be raised stepwise while controlling the temperature of the hydrogen gas at least in the range from 15 ° C. to 45 ° C. It is preferable that it is what is.
The preferred rate of temperature rise is gradually from the body temperature (about 36 ° C), preferably gradually over 2 minutes to 5 minutes, and raised to a maximum of 45 ° C ± 1 ° C. This is preferable because there is little shock to heat, and hydrogen gas penetrates from the skin tissue into the blood and deep parts of the body (for example, cell walls, cell membranes, cell nuclei, bone marrow, etc.).
The time taken from 36 ° C. to 45 ° C. varies depending on the individual, but is more preferably 5 minutes to 20 minutes, and particularly preferably 10 minutes to 15 minutes, but is not limited thereto.
Thereafter, keeping for 20 minutes or more is preferable in order to obtain the effect of the present invention.
＜＜温水素ガス吸入マスク＞＞
　図５を基に、発生した該水素ガスをヒトに吸入させる水素ガス吸入マスク１７を具備する抗酸化作用付与装置１について説明するが、本発明の態様２は図５の具体的な態様に限定されるものではない。 << Hot hydrogen gas inhalation mask >>
Based on FIG. 5, an antioxidant action imparting device 1 having a hydrogen gas inhalation mask 17 for allowing a human to inhale the generated hydrogen gas will be described. The aspect 2 of the present invention is limited to the specific aspect of FIG. 5. Is not to be done.
　図５の抗酸化作用付与装置１は、アルカリ水１１（アルカリイオン温水）と金属１２が入っているボトル本体、連結ボトル１４、及び、水素ガスを通す水素ガス導入管１５が接続され、病状等の用途に対応して適宜形状を好適化した水素ガス吸入マスク１７が接続されている（図５（ａ））。図５（ｂ）にヒトが水素ガス吸入マスク１７から水素ガスを吸引している様子を示す。 5 is connected to a bottle main body containing alkaline water 11 (alkaline ion warm water) and metal 12, a connecting bottle 14, and a hydrogen gas introduction pipe 15 through which hydrogen gas passes, so that a medical condition, etc. A hydrogen gas suction mask 17 having an appropriate shape corresponding to the application is connected (FIG. 5A). FIG. 5B shows a state in which a human is sucking hydrogen gas from the hydrogen gas suction mask 17.
　金属１２は蓋１３に係留されていて、蓋１３の開け閉めに合わせて、取り入れと取り出しが可能のようになっていてもよい（着脱式になっていてもよい）。
　ボトル本体には、アルカリ水１１と共に、薬効成分、香気成分等を含有させることも好ましい。また、水素ガス導入管１５と水素ガス吸入マスク１７の間には、除湿フィルター１８を設けることも好ましい。 The metal 12 may be moored to the lid 13 so that it can be taken in and out as the lid 13 is opened and closed (may be detachable).
The bottle body preferably contains a medicinal component, an aroma component, and the like together with the alkaline water 11. It is also preferable to provide a dehumidifying filter 18 between the hydrogen gas introduction pipe 15 and the hydrogen gas suction mask 17.
　水素ガス吸入マスク１７を使用する場合には、装置をコンパクトにするために具備しなくてもよいが、水素ガス昇温制御装置３を具備して、水素ガスを昇温することも好ましい。温めた水素ガスの場合には、血液循環が高まるために更に好ましい結果が早く得られると共に前記した「加温した水素ガス」の効果が得られる。空気も同時に吸入するが、空気は肺胞から体内に運ばれるのみであるが、水素は閉塞した脳内にも浸透する。 When the hydrogen gas suction mask 17 is used, it may not be provided to make the apparatus compact, but it is also preferable to provide the hydrogen gas temperature rise control device 3 to raise the temperature of the hydrogen gas. In the case of warmed hydrogen gas, the blood circulation is increased, so that a more preferable result can be obtained quickly and the effect of the above-mentioned “warmed hydrogen gas” can be obtained. Air is also inhaled at the same time, but air is only carried from the alveoli into the body, but hydrogen also penetrates into the obstructed brain.
＜＜水素ガス吐出充満容器＞＞
　図６を基に、発生した水素ガスＨ２を「ヒト若しくはヒトの一部」Ａに接触させる水素ガス吐出充満容器２７を具備する抗酸化作用付与装置１について説明するが、本発明の態様２は図６の具体的な態様に限定されるものではない。 << Hydrogen gas discharge filling container >>
Based on FIG. 6, the antioxidant effect imparting device 1 including the hydrogen gas discharge filling container 27 for bringing the generated hydrogen gas H2 into contact with “a person or a part of the person” A will be described. It is not limited to the specific mode of FIG.
　図６（ａ）の抗酸化作用付与装置１は、「ヒト全体又はヒトの首以下の体」に接触させる水素ガス吐出充満容器２７を具備するものであり、図６（ｂ）の抗酸化作用付与装置１は、「ヒトの一部」に接触させる水素ガス吐出充満容器２７を具備するものである。
　図６（ｂ）は乳房の例であるが、「ヒトの一部」としては、限定はないが、例えば、乳房、胴体、背中、胸、腰、手足等が挙げられる。「ヒトの一部」は、患部であることが好ましく、リンパ腺も好ましい。 The antioxidant effect imparting device 1 in FIG. 6A includes a hydrogen gas discharge filling container 27 that is brought into contact with the “whole body or body below the human neck”, and the antioxidant effect in FIG. 6B. The applying device 1 includes a hydrogen gas discharge filling container 27 that is brought into contact with “a part of a person”.
FIG. 6B shows an example of a breast, but “part of a human” is not limited, and examples thereof include a breast, a torso, a back, a chest, a waist, and a limb. The “part of human” is preferably an affected area, and a lymph gland is also preferable.
　図６（ａ）に示したように、水素ガス発生器２から発生した常温の水素ガスは、水素ガス導入管２３を通って水素ガス昇温制御装置３に入る。水素ガス昇温制御装置３の構成は特に限定はないが、水素ガスが「恒温槽の中に浸漬されている渦巻き状のチューブ管」に入り、上記温度範囲にコントロールされて徐々に昇温するようになっていることが好ましい。 As shown in FIG. 6A, the normal temperature hydrogen gas generated from the hydrogen gas generator 2 enters the hydrogen gas temperature rise control device 3 through the hydrogen gas introduction pipe 23. The configuration of the hydrogen gas temperature increase control device 3 is not particularly limited, but hydrogen gas enters the “spiral tube tube immersed in the thermostatic bath” and gradually increases in temperature while being controlled within the above temperature range. It is preferable that it is such.
　適温に加温された水素ガスは、マット２４の上部にある水素ガス吐出充満容器２７に導かれ、ヒトに接触する。ヒトに水素ガスを接触させるための水素ガス吐出充満容器２７は、例えば、多孔性フィルムの通気管から、水素ガスをヒト（の全体）に向けて、当てる（接触させる）ようになっているものが好ましい。このとき、体との間に柔軟な布をあてがうことが、初期のサーマルショックの緩和や、加温によって発汗する水を吸着せしめるためにも好ましい。 The hydrogen gas heated to an appropriate temperature is guided to the hydrogen gas discharge full container 27 at the upper part of the mat 24 and comes into contact with a human. The hydrogen gas discharge filling container 27 for bringing the hydrogen gas into contact with the human is, for example, one that contacts (contacts) the hydrogen gas toward the human (the whole) from a porous film vent pipe. Is preferred. At this time, it is preferable to apply a flexible cloth between the body and the body in order to alleviate the initial thermal shock and to adsorb water that sweats by heating.
　図６（ａ）に示したように、水素ガス吐出充満容器２７を満たした水素ガスは、ヒトの体に接触し、一部は体内深部に浸透透過し、その後、例えば上部等に設置されている水素ガス排出口２５から、水素ガス戻り管２６を通り、水素ガス昇温制御装置３に循環する。 As shown in FIG. 6 (a), the hydrogen gas filling the hydrogen gas discharge filling container 27 contacts the human body, a part of the hydrogen gas penetrates and penetrates deep into the body, and then, for example, is installed in the upper part or the like. The hydrogen gas discharge port 25 passes through the hydrogen gas return pipe 26 and circulates to the hydrogen gas temperature raising control device 3.
　途中、好ましくは垂直部位には、除湿材３１を内蔵したドレントラップ２８を設け、水素ガス中の水分は、該ドレントラップ２８で除かれるようになっていることが好ましい（図６（ａ））。
　水分が除去された水素ガスは、再び、水素ガス昇温制御装置３に入り昇温されて循環する。 A drain trap 28 containing a dehumidifying material 31 is preferably provided in the middle, preferably in a vertical part, and moisture in the hydrogen gas is preferably removed by the drain trap 28 (FIG. 6A). .
The hydrogen gas from which moisture has been removed again enters the hydrogen gas temperature increase control device 3 and is circulated after being heated.
　図６（ａ）のような、「ヒト全体又はヒトの首以下の体」用の水素ガス吐出充満容器２７には、図５（ａ）に示したような水素ガス吸入マスク１７が併用されていてもよい。水素ガス吸入マスク１７をかけて、口腔、鼻腔等から、（空気と共に）吸引された暖かい水素ガスは、体内、脳内組織に取り込まれる。 A hydrogen gas inhalation mask 17 as shown in FIG. 5 (a) is used in combination with a hydrogen gas discharge / filling container 27 for "the whole human body or the body below the human neck" as shown in FIG. 6 (a). May be. Warm hydrogen gas aspirated (with air) from the oral cavity, nasal cavity, etc. through the hydrogen gas inhalation mask 17 is taken into the body and brain tissue.
　ヒトの体に接触したり吸引されたりした水素は、一部は体内に浸透し、水素ガスの持つ抗酸化性と昇温による血流促進や免疫力の上昇で、多様な体内疾患を解消できる。 Part of the hydrogen that comes into contact with or inhaled into the human body penetrates into the body, and can solve various body diseases by promoting the blood flow and increasing immunity by the antioxidant properties of hydrogen gas and the temperature rise. .
　図６（ｂ）の抗酸化作用付与装置１は、「ヒトの一部」である乳房に接触させる水素ガス吐出充満容器２７を具備するものである。図６（ａ）の抗酸化作用付与装置１と同様に、水素ガス発生器２から水素ガス導入管２３を通った水素ガスは、恒温槽を通って昇温され、水素ガス導入管２３を通って、水素ガス吐出充満容器２７に放出又はその内部に充満される。
　水素ガスは、前記温度範囲と昇温速度にコントロールされて、患部に放射され、約３６℃から徐々に昇温し最高約４５℃に加温される。このとき、体との間に柔軟な布をあてがってもよい。 The antioxidant effect imparting device 1 of FIG. 6B includes a hydrogen gas discharge filling container 27 that is brought into contact with a breast that is “a part of a human being”. 6A, the hydrogen gas that has passed through the hydrogen gas introduction pipe 23 from the hydrogen gas generator 2 is heated through the thermostatic bath, and passes through the hydrogen gas introduction pipe 23. The hydrogen gas discharge filling container 27 is discharged or filled therein.
Hydrogen gas is radiated to the affected area under the control of the temperature range and the rate of temperature increase, and the temperature is gradually raised from about 36 ° C. and heated to a maximum of about 45 ° C. At this time, a flexible cloth may be applied between the body and the body.
　ヒトの「患部等の一部」に接触した水素は、体内に浸透し、水素ガスの持つ抗酸化性と昇温による血流促進、免疫力、新陳代謝、白血球等の上昇で、該部分の疾患を解消できる可能性がある。 Hydrogen that has come into contact with the “part of the affected area” of humans penetrates into the body and increases the antioxidant properties of hydrogen gas, blood flow promotion by elevated temperature, immunity, metabolism, leukocytes, etc. There is a possibility that can be resolved.
＜＜水素ガスの物性＞＞
　水素ガスの熱伝導率は、空気、窒素ガス、水蒸気、メタンガス、フッ素ガス等に比較して格段に高い。また、熱伝導率が極めて高いことで知られるヘリウムガスと比較しても、水素ガスの熱伝導率はそれよりも高い。
　また、水素ガスは、物体に対しての浸透性・透過性が高い。その高い浸透性のために、ヒトに接触すると、その内部（例えば、細胞・臓器内）に浸透し易い。 << Physical properties of hydrogen gas >>
The thermal conductivity of hydrogen gas is much higher than that of air, nitrogen gas, water vapor, methane gas, fluorine gas, or the like. In addition, the thermal conductivity of hydrogen gas is higher than that of helium gas, which is known for its extremely high thermal conductivity.
In addition, hydrogen gas has high permeability and permeability to objects. Due to its high permeability, when it comes into contact with humans, it easily penetrates into the inside (for example, cells and organs).
　ヒトの一部として、限定はされないが例えば乳房を例にとって、本発明の特に好ましい態様を説明する。水素ガス発生器２から発生した水素ガスは、水素ガス昇温制御装置３の加熱チューブ内の恒温槽で綿密な温度コントロールがされて、常温から徐々に加温されて、通気チューブから放射カップ（水素ガス充満容器２７）から患部（乳房）に放射され、３６℃から徐々に昇温され４５℃に加温される。徐々に昇温するため、熱さに対するショックはない。
　水素は軽いので、放射カップ（水素ガス吐出充満容器２７）は下から上に向ける必要がある。このとき、患部位置との間に柔軟な布をあてがってもよい。
　水素は、皮膚組織から血液や深部細胞や臓器まで温熱を伴って浸透透過する。特に、癌細胞は熱に弱く４２℃前後で自滅する。 A particularly preferred embodiment of the invention will be described as part of a human being, for example but not limited to the breast. The hydrogen gas generated from the hydrogen gas generator 2 is subjected to precise temperature control in a thermostatic chamber in the heating tube of the hydrogen gas temperature rise control device 3, and is gradually heated from room temperature, and then the radiant cup ( Radiated from the hydrogen gas-filled container 27) to the affected area (breast), gradually heated from 36 ° C and heated to 45 ° C. Since the temperature rises gradually, there is no shock to the heat.
Since hydrogen is light, the radiation cup (hydrogen gas discharge full container 27) needs to be directed from the bottom to the top. At this time, you may apply a flexible cloth between affected part positions.
Hydrogen penetrates and permeates with heat from skin tissue to blood and deep cells and organs. In particular, cancer cells are vulnerable to heat and self-destruct at around 42 ° C.
　図７を例にとって、本発明の態様２の特に好ましい態様を説明する。
　凹凸を形成したマット２４の凹部には、通気管２９が数列、通気孔３０が数十個あり、通気孔３０からは、恒温槽等の水素ガス昇温制御装置３で適温に加熱温熱された水素ガスが体内に向けて噴射放射される（図７（ａ）（ｄ））。
　図７（ａ）に示したように、マット２４等の敷物の凸部はヒトに対するクッション機能を果たす。その上には、発汗を吸収する布を用いることも好ましい。該布は人体の着衣そのままでもよい。 Using FIG. 7 as an example, a particularly preferred embodiment of Embodiment 2 of the present invention will be described.
In the concave portion of the mat 24 formed with irregularities, there are several rows of vent pipes 29 and dozens of vent holes 30, and the vent holes 30 are heated and heated to an appropriate temperature by the hydrogen gas temperature rise control device 3 such as a thermostatic bath. Hydrogen gas is injected and emitted into the body (FIGS. 7A and 7D).
As shown in FIG. 7A, the convex portion of the rug such as the mat 24 functions as a cushion for humans. It is also preferable to use a cloth that absorbs sweat. The cloth may be the clothes of the human body.
　マット２４の上部は、アルミ積層シートで覆われていて、水素ガスが漏えいすることを保護する。水素ガス充満容器２７やマット２４の好ましい材質の一例を、図７（ｃ）に示す。該材質はアルミ箔が積層されているものが好ましい。
　このシートのほぼ中央部位には、体に接触（浸透）した水素ガスを集めて還流する水素ガス戻り管２６が接続されている。水素ガス戻り管２６は、アルミ箔積層管材３２でできていて、温熱によって発汗蒸発した水分を含む水素ガス中の水分を吸着するための除湿材３１が管内径に挿入してあることが好ましい（図７（ｂ））。なお、水素ガス戻り管２６の下方にはこれらの水分を排出するためのドレントラップ２８が設置してある。 The upper portion of the mat 24 is covered with an aluminum laminated sheet to protect the hydrogen gas from leaking. An example of a preferable material for the hydrogen gas container 27 and the mat 24 is shown in FIG. The material is preferably a laminate of aluminum foil.
A hydrogen gas return pipe 26 that collects and recirculates the hydrogen gas that has contacted (penetrated) the body is connected to a substantially central portion of the sheet. The hydrogen gas return pipe 26 is made of an aluminum foil laminated pipe material 32, and it is preferable that a dehumidifying material 31 for adsorbing moisture in hydrogen gas containing moisture evaporated and sweated by heat is inserted in the inner diameter of the pipe ( FIG. 7B). A drain trap 28 for discharging these moisture is installed below the hydrogen gas return pipe 26.
　水素ガス発生器２からバルブを介して適量出た水素ガスは、水素ガス加熱装置と一時的貯留タンクを経由して通気孔３０から放出される。具体的には、水素ガス昇温制御装置３である恒温槽内部にセットしてある加温チューブ内に入り、適温に加熱され徐々に昇温し、該温熱水素ガスは、マット２４内部の数条で数十個の通気管２９の通気孔３０から人体に向けて人体の下部側から放出される。水素ガスは軽いので、直ぐに上部側に拡散するため、下部側から出すことが好ましい（図７（ａ））。 An appropriate amount of hydrogen gas discharged from the hydrogen gas generator 2 through a valve is released from the vent hole 30 via a hydrogen gas heating device and a temporary storage tank. Specifically, it enters a heating tube set inside a thermostatic chamber which is the hydrogen gas temperature raising control device 3, is heated to an appropriate temperature and gradually heated, and the hot hydrogen gas is a number inside the mat 24. It is discharged from the lower side of the human body toward the human body through the vent holes 30 of the dozens of vent pipes 29 in a strip. Since hydrogen gas is light, it diffuses immediately to the upper side, so it is preferable to discharge from the lower side (FIG. 7A).
＜態様３＞
　以下、態様３について記載する。態様３の一例を図８ないし図１３に示すが、「図８ないし図１３に使用されている符号」及び「下記する態様３の記載中の符号」は、態様３にのみ適用されるものとする。すなわち、「下記する態様３の記載中の符号」は、「図８ないし図１３に使用されている符号」に対応し、他の態様や他の図では同じ符号が他のものに使用されていることがある。 <Aspect 3>
Hereinafter, Embodiment 3 will be described. An example of the aspect 3 is shown in FIGS. 8 to 13, but “the reference numerals used in FIGS. 8 to 13” and “the reference numerals in the description of the aspect 3 below” are applied only to the aspect 3. To do. That is, “the reference numerals in the description of the aspect 3 described below” correspond to “the reference numerals used in FIGS. 8 to 13”, and the same reference numerals are used in other aspects and other drawings. There may be.
　本発明の態様３は、前記の水素流体閉サイクル装置を具備する水素流体閉サイクル駆動・発電装置であって、
　少なくとも、以下の（Ｒ３）及び（Ｒ４）の全てを具備するものであることを特徴とする水素流体閉サイクル駆動・発電装置である。
（Ｒ３）一時的貯留タンクから水素ガスが噴射されることで回転するタービンを備える駆動装置
（Ｒ４）一時的貯留タンクから水素ガスが噴射されることで回転翼が回転して発電する流体発電器 Aspect 3 of the present invention is a hydrogen fluid closed cycle drive / power generation device including the above hydrogen fluid closed cycle device,
A hydrogen fluid closed cycle drive / power generation device comprising at least all of the following (R3) and (R4):
(R3) Drive unit including a turbine that rotates when hydrogen gas is injected from the temporary storage tank (R4) Fluid generator that generates power by rotating the rotor blades when hydrogen gas is injected from the temporary storage tank
　すなわち、本発明の（１）水素ガス発生器、（２）水素ガス加熱装置と複数基の一時的貯留タンク、及び、（Ｒ）水素ガス利用装置を具備した上で、（Ｒ）水素ガス利用装置が、上記（Ｒ３）駆動装置と（Ｒ４）流体発電器を有している。 That is, the present invention comprises (1) a hydrogen gas generator, (2) a hydrogen gas heating device and a plurality of temporary storage tanks, and (R) a hydrogen gas utilization device, and (R) a hydrogen gas utilization device. The apparatus has the (R3) driving device and (R4) fluid power generator.
＜＜水素ガス発生（装置）＞＞
　本発明の水素流体閉サイクル駆動・発電装置０１は、（１）水素ガス発生器１１を具備する。
　該水素ガス発生器１１における水素の発生は、特に限定はないが、金属にアルカリ水を接触させることによる。すなわち、本発明における水素ガス発生器１１は、金属にアルカリ水を接触させることによって水素ガスを発生させるようになっているものであることが好ましい。
　該金属元素としては、アルミニウム（Ａｌ）、亜鉛（Ｚｎ）、チタン（Ｔｉ）、スズ（Ｓｎ）等の金属が好ましく、安全性、コスト（安価）、生成物が有用物である等の観点から、アルミニウムが特に好ましい。特にアルミニウムの場合、反応生成物は濾過後に浄化材料として使用可能である点からも特に好ましい。また、該金属としては、イオン化傾向の高い金属も好ましい。 << Hydrogen gas generation (device) >>
The hydrogen fluid closed cycle drive / power generation apparatus 01 of the present invention includes (1) a hydrogen gas generator 11.
Generation of hydrogen in the hydrogen gas generator 11 is not particularly limited, but is caused by bringing alkaline water into contact with a metal. That is, it is preferable that the hydrogen gas generator 11 in the present invention is configured to generate hydrogen gas by bringing alkaline water into contact with a metal.
The metal element is preferably a metal such as aluminum (Al), zinc (Zn), titanium (Ti), tin (Sn), etc., from the viewpoints of safety, cost (inexpensive), and useful products. Aluminum is particularly preferred. Particularly in the case of aluminum, the reaction product is particularly preferable because it can be used as a purification material after filtration. Further, as the metal, a metal having a high ionization tendency is also preferable.
　該アルカリ水のｐＨとしては、特に限定はないが、１２以上が好ましく、１３以上がより好ましく、１３．５以上１４が特に好ましい。 The pH of the alkaline water is not particularly limited, but is preferably 12 or more, more preferably 13 or more, and particularly preferably 13.5 or more.
　金属元素としてアルミニウムを用いたときの最終的な化学反応は、示性式の記載方法は種々あるが、例えば以下の反応式（１）のようになる。
　２Ａｌ＋６ＯＨ－ → ２（ＡｌＯ３）３－＋３Ｈ２　・・・・・（１） The final chemical reaction when aluminum is used as the metal element can be expressed in various ways, for example, as shown in the following reaction formula (1).
2Al + 6OH − → 2 (AlO 3 ) 3 − + 3H 2 (1)
　このような方法で、化学量論的に、１Ｌのアルカリ水から、標準状態で最低１１３０Ｌ以上の水素ガスを得ることができ、水素ガスの量としてはそれで十分である。なお、金属とアルカリイオン水の反応によってアルミン酸が析出しない技術操作においては、濾過も不要であり残水は透明で有用な経口水として極めて有効である。この技術操作も既に見出している。 In such a method, a stoichiometric amount of hydrogen gas of at least 1130 L can be obtained from 1 L of alkaline water in a standard state, which is sufficient as the amount of hydrogen gas. In the technical operation in which alumina does not precipitate due to the reaction between the metal and the alkaline ionized water, filtration is not necessary, and the residual water is very effective as a clear and useful oral water. This technical operation has already been found.
　上記アルカリ水は、限定はされないが、自然石（石灰石等）、貝殻、珊瑚石等の天然物から得ることが、環境に優しいために特に好ましい。天然物に水を加えることによって、イオン化したアルカリ水を得る。
　該アルカリ水を、アルミニウム（Ａｌ）等の金属に接触させて水素ガスを発生させる。 Although the alkaline water is not limited, it is particularly preferable to obtain it from natural products such as natural stones (limestone, etc.), shells, meteorites and the like because they are environmentally friendly. By adding water to the natural product, ionized alkaline water is obtained.
The alkaline water is brought into contact with a metal such as aluminum (Al) to generate hydrogen gas.
　使用する水素ガスとしては、上記水素ガス発生器１１で生成させた発生水素ガスが使用できる。漏洩で不足した分の還流水素ガスを発生水素ガスで補うことが好ましい。
　発生水素ガスや還流水素ガスを加熱して、密閉容器である一時的貯留タンク１３中で１３．２気圧以上にすると、水素の臨界温度は３３Ｋ（－２４０℃）なので、定義上は超臨界になる。 As the hydrogen gas to be used, the generated hydrogen gas generated by the hydrogen gas generator 11 can be used. It is preferable to supplement the recirculated hydrogen gas in a shortage due to leakage with the generated hydrogen gas.
When the generated hydrogen gas or the reflux hydrogen gas is heated to 13.2 atm or more in the temporary storage tank 13 which is a sealed container, the critical temperature of hydrogen is 33K (-240 ° C). Become.
　アルカリ水タンク内のアルカリ水を、内部に金属を有する水素ガス発生器１１の中に投入すると水素ガスが発生する。水素ガス発生器１１で生成させた発生水素ガスは、水素ガス加熱装置１２を介して、生成水素移送ポンプを用いて機関内に導入される。水素ガスは、機関内に導入する途中で（前に）、一時的貯留タンク１３で加温させることによって加圧される。本発明では、機関内に導入前の水素ガスを、水素ガス加熱装置１２で加熱するようになっており、一時的貯留タンク１３で圧力を上げられるようになっている。
　すなわち、上記（２）水素ガス加熱装置は、一時的貯留タンク１３のような密閉された容器（密閉容器）内の水素ガスを、好ましくは４００℃以下に加熱して使用するようになっている。図８ないし図１１参照。 When the alkaline water in the alkaline water tank is put into the hydrogen gas generator 11 having a metal inside, hydrogen gas is generated. The generated hydrogen gas generated by the hydrogen gas generator 11 is introduced into the engine through the hydrogen gas heating device 12 using a generated hydrogen transfer pump. The hydrogen gas is pressurized by being heated in the temporary storage tank 13 during (before) introduction into the engine. In the present invention, the hydrogen gas before being introduced into the engine is heated by the hydrogen gas heating device 12 so that the pressure can be increased by the temporary storage tank 13.
That is, the (2) hydrogen gas heating apparatus is used by heating the hydrogen gas in a sealed container (sealed container) such as the temporary storage tank 13 to preferably 400 ° C. or lower. . See FIGS.
　抜き取り管からは、水素ガス生成後の残水を抜き取ったり、生成したアルミン酸塩等の物質を取り除いたりすることができる。残水の濾過水は経口摂取も可能であり、養殖水等の別用途に有効に使用することもできる。また、アルミン酸（塩）も浄化剤として有効利用できる。 From the extraction pipe, residual water after hydrogen gas generation can be extracted and substances such as generated aluminate can be removed. The filtered water of the residual water can be taken orally and can be used effectively for other purposes such as aquaculture water. Aluminic acid (salt) can also be effectively used as a purifier.
　水素ガス発生器１１は、環境特性に優れた自然資源から特殊な方法で水素イオン濃度の高い水を創造したものであり、そのイオン濃度の高い水に安価な触媒を係留させた状態で水中に入れて水素ガスを連続発生させるので、必要な時にタイムリーに前記金属入れて純粋な水素ガスを産出する。
　従って、耐圧容器も不要であり、単なる耐アルカリ性樹脂容器（例えば、ポリエチレン、ポリプロピレン等）で十分である。 The hydrogen gas generator 11 is created by creating water with a high hydrogen ion concentration by a special method from natural resources with excellent environmental characteristics. The hydrogen gas generator 11 is submerged in water with an inexpensive catalyst moored in the high ion concentration water. Since hydrogen gas is continuously generated, pure metal gas is produced by adding the metal in a timely manner when necessary.
Therefore, a pressure-resistant container is not necessary, and a simple alkali-resistant resin container (for example, polyethylene, polypropylene, etc.) is sufficient.
　更に、本発明に使用するこの水素ガス生成の源となる水は、医療用途や食品用途であることが好ましいが、時として工業系用途の場合は、該水として海水や陸水を用いてアルカリイオン水としてもよい。海水の場合は、特にミネラル成分が多く、より多くの水素ガスの生成がある（実証実験済み）。 Furthermore, the water used as the source of hydrogen gas generation used in the present invention is preferably used for medical purposes or foods. However, sometimes in the case of industrial uses, seawater or terrestrial water is used as the water to produce alkaline water. Ionic water may be used. In the case of seawater, there are many mineral components, and more hydrogen gas is produced (already tested).
　水素ガスは、水素単独（純粋なもの）でもよいが、他の気体を混合させ混合気体として使用することもできる。該混合気体は、炉体等に対する「水素ガス固有の水素脆化」を防ぐ効果がある。 Hydrogen gas may be hydrogen alone (pure), but other gases can be mixed and used as a mixed gas. The mixed gas has an effect of preventing “hydrogen embrittlement inherent to hydrogen gas” to the furnace body and the like.
　本発明の態様３においては、水素ガスと、「他の不活性ガスである二酸化炭素、窒素、アルゴン、ヘリウム等のガス」を選択し、混合気体として使用することも好ましい。具体的には、窒素、炭酸ガス等がより好ましいものとして挙げられる。
　混合するガスとして、コストパフォーマンスが良い二酸化炭素（ＣＯ２）（臨界点３１．１℃、７．４ＭＰａ）が特に好ましい。
　具体的には、水素ガス９５～９８容量部に、炭酸ガス２～５容量部を混合させた混合気体が好ましい。混合比として、例えば、「水素９５容量％、二酸化炭素（ＣＯ２）５容量％」、「水素９８容量％、ヘリウム２容量％」等が特に好ましい。 In aspect 3 of the present invention, it is also preferable to select hydrogen gas and “another inert gas such as carbon dioxide, nitrogen, argon, helium” and use them as a mixed gas. Specifically, nitrogen, carbon dioxide and the like are more preferable.
As a gas to be mixed, carbon dioxide (CO 2 ) (critical point: 31.1 ° C., 7.4 MPa) having a good cost performance is particularly preferable.
Specifically, a mixed gas in which 95 to 98 parts by volume of hydrogen gas and 2 to 5 parts by volume of carbon dioxide gas are mixed is preferable. As the mixing ratio, for example, “95% by volume of hydrogen, 5% by volume of carbon dioxide (CO 2 )”, “98% by volume of hydrogen, 2% by volume of helium” and the like are particularly preferable.
　本発明の態様３においては、水素ガスの金属脆化問題があるために、金属系の使用を少なくし、配管やエンジンを含む部材を繊維強化耐熱樹脂アルミ積層類とすることも好ましい。
　ただし、本発明のように低温高圧駆動型である場合（例えば１００℃前後の低温）、金属系以外の材質でも十分である。本発明では、更に混合ガスを使用することで、水素固有の金属脆化問題をクリヤーできる。 In aspect 3 of the present invention, since there is a problem of metal embrittlement of hydrogen gas, it is also preferable to reduce the use of metal-based materials and to use members including pipes and engines as fiber reinforced heat-resistant resin aluminum laminates.
However, in the case of a low-temperature and high-pressure drive type as in the present invention (for example, a low temperature of around 100 ° C.), a material other than metal is sufficient. In the present invention, the problem of metal embrittlement inherent to hydrogen can be cleared by using a mixed gas.
　水素ガスは、低温（例えば１００℃前後）でも超臨界流体であり、装置全体も軽く重量設計は不要であり、且つコストも低く、機関の装置は、３Ｄプリンターでも製作可能である。 Hydrogen gas is a supercritical fluid even at a low temperature (for example, around 100 ° C.), the entire apparatus is light, no weight design is required, and the cost is low. The engine apparatus can be manufactured by a 3D printer.
＜＜超臨界水素流体閉サイクル駆動・発電装置＞＞
　本発明の態様３の具体的な態様を、基本図である図８に従って以下に示す。
　水素ガス発生器１１から発生する水素ガスは、この時点で常温であるため、既に臨界温度に達している（水素臨界点－２４０℃、１．３ＭＰａ）。
　その水素ガスは、水素ガス加熱装置１２で加温され、熱伝導性が高いので僅か数秒で昇温する。
　本発明の態様３の水素流体閉サイクル駆動・発電装置０１は、（２）上記水素ガス発生器１１で発生した水素ガスの温度を上げることによって水素ガスの圧力を上げる水素ガス加熱装置１２及び一時的貯留タンク１３を具備する。 << Supercritical hydrogen fluid closed cycle drive / power generation system >>
A specific aspect of aspect 3 of the present invention will be described below in accordance with FIG.
Since the hydrogen gas generated from the hydrogen gas generator 11 is normal temperature at this time, it has already reached the critical temperature (hydrogen critical point -240 ° C., 1.3 MPa).
The hydrogen gas is heated by the hydrogen gas heating device 12 and has a high thermal conductivity, so that the temperature rises in just a few seconds.
The hydrogen fluid closed cycle drive / power generation device 01 according to the third aspect of the present invention includes (2) a hydrogen gas heating device 12 that temporarily raises the pressure of the hydrogen gas by raising the temperature of the hydrogen gas generated by the hydrogen gas generator 11, and a temporary A mechanical storage tank 13 is provided.
　本発明の態様３の水素流体閉サイクル駆動・発電装置０１において、上記（２）水素ガス加熱装置１２と一時的貯留タンク１３は、密閉された一時的貯留タンク１３内の水素ガスを４００℃以下に加熱して使用するようになっていることが好ましい。 In the hydrogen fluid closed cycle drive / power generation device 01 according to the third aspect of the present invention, (2) the hydrogen gas heating device 12 and the temporary storage tank 13 are configured so that the hydrogen gas in the sealed temporary storage tank 13 is 400 ° C. or less. It is preferable to heat and use.
　昇温した水素ガスは、順次、一時的貯留タンク１３（好ましくは２～４基）内に入り、密閉状態が約１～２分を経ると、水素ガスは低温領域（５０℃）でも高圧化し、この時点で超臨界流体となり、その圧力は約２０ＭＰａ以上となる。
　高圧化した水素であるが、一時的貯留タンク１３内の貯留時間は僅か数分であり、高度な耐圧タンクは必要とせず、１～２分間を経て順次吐出するので安全である。 The heated hydrogen gas sequentially enters the temporary storage tank 13 (preferably 2 to 4 units), and after the sealed state has passed for about 1 to 2 minutes, the hydrogen gas is increased in pressure even in a low temperature region (50 ° C.). At this time, it becomes a supercritical fluid, and its pressure becomes about 20 MPa or more.
Although the pressure of the hydrogen is increased, the storage time in the temporary storage tank 13 is only a few minutes, and an advanced pressure-resistant tank is not required, and the discharge is sequentially performed after 1 to 2 minutes, which is safe.
　この高圧化した超臨界水素は、圧力調整弁を経て噴射装置を経由して、配管内に順次高速流入し、流体発電器１４において、水素ガスを燃焼させずに、加熱して一時的に貯留した水素ガスの流体によって回転翼を高速回転し駆動軸から発電する。
　予め各機材の配管や動力機関内部を真空引きした上で、加温した水素ガス、「水素ガスと炭酸ガス」等の混合気体を充填後、噴射することが好ましい。これは、本発明の装置（プラント、自動車等に応用される）の共通事項である。 This high-pressure supercritical hydrogen sequentially flows into the pipe through the pressure control valve and the injection device, and is heated and temporarily stored in the fluid power generator 14 without burning the hydrogen gas. The rotating blades are rotated at high speed by the hydrogen gas fluid generated to generate power from the drive shaft.
It is preferable to evacuate the piping of each piece of equipment and the inside of the power engine in advance and then inject after filling with a mixed gas such as heated hydrogen gas or “hydrogen gas and carbon dioxide”. This is a common matter of the apparatus of the present invention (applied to plants, automobiles, etc.).
　加温蒸気１６等で加温されることで加圧された水素ガスは、動力機関である圧縮スクロールエンジン、ロータリーエンジン、１軸タービン等の圧縮装置に入り、駆動と圧縮工程を経て排気ポートから循環し再び還流する。
　このように、非大気であり低温であり、宇宙空間・深地下空間・高地等、様々な環境下において駆動力や電力を創出することが可能である。 Hydrogen gas pressurized by heating with the heated steam 16 or the like enters a compression device such as a compression scroll engine, a rotary engine, or a single-shaft turbine, which is a power engine, and is driven and compressed through an exhaust port. Circulate and reflux again.
Thus, it is non-atmosphere and low temperature, and it is possible to create driving force and electric power in various environments such as outer space, deep underground space, and highland.
　水素ガス発生器１１から出る水素ガスは、導入管から渦巻き式等の加熱チューブに入り、水素ガス加熱装置１２で加温されて、一時的貯留タンク１３に入り、加圧された状態となる。
　本発明の態様３の水素流体閉サイクル駆動・発電装置０１は、水素ガス加熱装置１２が、一時的貯留タンク１３内の水素ガスを４００℃以下に加熱して使用するようになっている。
　該昇圧された水素ガスは、流体発電器１４の吸気ポートに向けて噴射されて回転翼を駆動する。 Hydrogen gas exiting from the hydrogen gas generator 11 enters a spiral heating tube or the like from the introduction pipe, is heated by the hydrogen gas heating device 12, enters the temporary storage tank 13, and is pressurized.
In the hydrogen fluid closed cycle drive / power generation device 01 of the aspect 3 of the present invention, the hydrogen gas heating device 12 is used by heating the hydrogen gas in the temporary storage tank 13 to 400 ° C. or less.
The pressurized hydrogen gas is injected toward the intake port of the fluid power generator 14 to drive the rotor blades.
　排気ポートからでる加圧された水素ガスは、下部側の一時的余熱貯留タンクから噴出する流体と合流し、アスピレーターを介して次の回転翼を駆動しながら再び一時的貯留タンク１３に戻り、再び加温蒸気１６（例えば約３００℃）で加熱されて循環する。
　本発明の水素流体閉サイクル駆動・発電装置０１は、（３）水素ガスが噴射されることで回転するタービンを備える駆動装置を具備する。 The pressurized hydrogen gas from the exhaust port merges with the fluid ejected from the temporary residual heat storage tank on the lower side, and returns to the temporary storage tank 13 again while driving the next rotor blade via the aspirator. It is heated and circulated with heated steam 16 (for example, about 300 ° C.).
The hydrogen fluid closed cycle drive / power generation device 01 according to the present invention includes (3) a drive device including a turbine that rotates when hydrogen gas is injected.
　また、本発明の水素流体閉サイクル駆動・発電装置０１は、（４）水素ガスが噴射されることで回転翼が回転して発電する流体発電器を具備する。流体発電器１４の回転翼の稼働軸に連動したオルタネーターが、閉サイクル方式で発電して、駆動また一部は蓄電池１９を充電する。 Further, the hydrogen fluid closed cycle drive / power generation device 01 of the present invention includes (4) a fluid power generator that generates power by rotating the rotor blades when hydrogen gas is injected. An alternator linked to the operating shaft of the rotor blade of the fluid power generator 14 generates power in a closed cycle manner, and drives or partially charges the storage battery 19.
　加温蒸気１６は、結露するので最下部にキャッチパン１７をセットし、ドレントラップ１７から排出回収する。余剰プロセス蒸気は還流してもよい。
　この装置（システム）は、基本的なものなので、例えば、後記するようなものに利用できる他、災害用・自家発電・車・船舶・電車・潜水艦・宇宙航行等にも広く応用できる。 Since the heated steam 16 is condensed, a catch pan 17 is set at the lowermost part, and is discharged and collected from the drain trap 17. Excess process steam may be refluxed.
Since this device (system) is basic, it can be used for, for example, those described later, and can be widely applied to disasters, private power generation, cars, ships, trains, submarines, space navigation, and the like.
＜＜マイクロ波励起水中プラズマ加熱装置＞＞
　本発明の態様３の水素流体閉サイクル駆動・発電装置０１では、上記水素ガス加熱装置１２が、非大気としてマイクロ波等を利用して加熱するものであることが好ましい。
　図９に従って、水素ガス加熱装置１２の特に好ましい態様である、マイクロ波励起水中プラズマ加熱装置１２ａの態様と特徴について以下に説明する。 << Microwave excited water plasma heating device >>
In the hydrogen fluid closed cycle drive / power generation device 01 according to the third aspect of the present invention, it is preferable that the hydrogen gas heating device 12 is heated using microwaves or the like as non-atmosphere.
The mode and characteristics of the microwave-excited underwater plasma heating device 12a, which is a particularly preferable mode of the hydrogen gas heating device 12, will be described below with reference to FIG.
０：マイクロ波は、蓄電池１９からの電気で初期駆動する。
１：超臨界の水素ガスで回転翼を高速で回転する構成であり、内燃機関や圧縮装置を使用せず構造がシンプルであり、メンテナンスが容易であり静粛である。
２：水素は燃焼させず、閉サイクル方式で循環使用であり燃料ではない。高圧タンクは不要で安全であり、水素ガスは必要時に化学反応する金属を重りと共に係留投入すれば発生し、外せば発生は止まる。
３：水中プラズマの触媒は永久使用の触媒である。
４：排気ガスはゼロであり室内で発電ができる。また、空気（酸素）は不要であり非大気空間で使用できる。
５：マイクロ波で発熱するＩ　ＰＯＷＥＲ無機発熱ボードも半永久使用可能である。
６：マイクロ波の起動を停止すれば発電は止まるので、電力必要時に起動すればよい。マイクロ波出力は１００～２００Ｗで十分である。 0: The microwave is initially driven by electricity from the storage battery 19.
1: The configuration is such that the rotor blades are rotated at high speed with supercritical hydrogen gas, the structure is simple without using an internal combustion engine or a compression device, and maintenance is easy and quiet.
2: Hydrogen is not combusted, is used in a closed cycle, and is not fuel. A high-pressure tank is unnecessary and safe, and hydrogen gas is generated when a metal that chemically reacts when necessary and moored together with a weight, and generation stops when removed.
3: The catalyst of underwater plasma is a permanent catalyst.
4: Exhaust gas is zero and power can be generated indoors. Further, air (oxygen) is not necessary and can be used in a non-atmospheric space.
5: I POWER inorganic heating board that generates heat by microwaves can also be used semi-permanently.
6: Since the power generation stops when the start of the microwave is stopped, it may be started when power is required. A microwave output of 100 to 200 W is sufficient.
＜＜スクロール型エンジン駆動・発電装置＞＞
　図１０に、本発明の水素流体閉サイクル駆動・発電装置０１の応用例として、圧縮スクロール型エンジン駆動・発電装置０２について示す。該圧縮スクロール型エンジン駆動・発電装置０２は、スクロール型エンジン３２で駆動及び／又は発電する装置であり、圧縮（膨張）スクロール型エンジン駆動・発電を利用し、自家発電、自動車等に適用される。
　水素ガス発生器１１から順次発生する水素ガスは、常温で臨界点に達している。この水素ガス又は水素混合気体を、密閉された一時的貯留タンク１３から噴射し、スクロール型エンジン３２として、固定翼の中心部近傍の吸入ポート３４から流入させると、可動翼間で圧縮されて高圧となり膨張し、中心部の回転軸を回転させ駆動させることができる。 << Scroll type engine drive / power generation system >>
FIG. 10 shows a compression scroll type engine drive / power generation device 02 as an application example of the hydrogen fluid closed cycle drive / power generation device 01 of the present invention. The compression scroll type engine drive / power generation device 02 is a device that drives and / or generates power with the scroll type engine 32, and uses compression (expansion) scroll type engine drive / power generation, and is applied to private power generation, automobiles, and the like. .
Hydrogen gas sequentially generated from the hydrogen gas generator 11 reaches a critical point at room temperature. When this hydrogen gas or hydrogen mixed gas is injected from the sealed temporary storage tank 13 and flows as the scroll engine 32 through the suction port 34 near the center of the fixed blade, it is compressed between the movable blades and is pressurized. And expand, and the rotation shaft at the center can be rotated and driven.
　膨張した水素ガスは、排気ポート３５へ移動し元の温度に戻り、排出口から循環パイプ３６へ還流する。該水素ガスは、再びスクロール型エンジン３２の中心部に戻り、圧縮高圧化し、繰り返し閉サイクル運転をする。圧力は８ＭＰａ以上が好ましい。
　閉サイクル運転であり、基本的に燃料が不要である。この回転軸から駆動と発電が可能である。 The expanded hydrogen gas moves to the exhaust port 35, returns to the original temperature, and returns to the circulation pipe 36 from the discharge port. The hydrogen gas returns to the center of the scroll type engine 32 again, is compressed and pressurized, and repeatedly performs a closed cycle operation. The pressure is preferably 8 MPa or more.
It is a closed-cycle operation and basically does not require fuel. Drive and power generation are possible from this rotating shaft.
　自動車の場合は、アクセルペダルによる水素ガスの流量調整で、スピードを制御でき、アクセルを離すとエンジンブレーキがかかる。
　圧縮スクロール型エンジン３２で発電するため、「自家発電自動車」と言える。
　水素ガスは、搭載した水から前述した化学反応で生成させて、連続した圧縮工程で駆動するので、圧縮液化水素ガスを搭載する必要なく極めて安全である。 In the case of an automobile, the speed can be controlled by adjusting the flow rate of hydrogen gas with an accelerator pedal, and the engine brake is applied when the accelerator is released.
Since the power is generated by the compression scroll engine 32, it can be said to be a “self-generated power vehicle”.
Hydrogen gas is generated by the above-described chemical reaction from the loaded water and is driven by a continuous compression process, so it is extremely safe without the need for loading compressed liquefied hydrogen gas.
＜＜ロータリー型エンジン駆動・発電装置＞＞
　図１１に、本発明の水素流体閉サイクル駆動・発電装置０１の応用例として、ロータリー型エンジン駆動・発電装置０３について示す。
　吸入ポート３４に、臨界点に達している常温水素ガスが吸入され、密閉された一時的貯留タンク１３で高圧化し、圧力調整弁からロータリー型エンジン４１の内部に噴射され、図１１の（３）で圧縮されて、（４）で更に高圧高温となり、体膨張圧で回転し、排気ポート３５から排気される工程（３）で、ロータリー型エンジン４１が駆動する。 << Rotary type engine drive and power generator >>
FIG. 11 shows a rotary engine drive / power generation device 03 as an application example of the hydrogen fluid closed cycle drive / power generation device 01 of the present invention.
The normal temperature hydrogen gas reaching the critical point is sucked into the suction port 34, and the pressure is increased in the sealed temporary storage tank 13, and is injected into the rotary engine 41 from the pressure regulating valve. In step (3), the rotary engine 41 is driven in the step (3) in which the pressure is further increased and the pressure becomes higher and higher in (4), and the body is rotated by the body expansion pressure.
　通常のロータリーエンジンの圧縮比は７～８であり、水素ガスは超臨界流体状態の１０気圧以上である。膨張が完了した工程（３）の水素は、温度が低下し排気ポート３５から出て、循環して循環パイプ３６から再び吸入ポート３４に戻り、繰り返し閉サイクル駆動・発電をする。 The compression ratio of a normal rotary engine is 7-8, and hydrogen gas is 10 atmospheres or more in a supercritical fluid state. The hydrogen in the step (3) in which the expansion is completed decreases in temperature, exits from the exhaust port 35, circulates, returns to the intake port 34 from the circulation pipe 36, and repeatedly performs closed cycle driving and power generation.
　このロータリー型エンジン駆動・発電装置は、通常の化石燃料の燃焼とは全く異なるエンジン駆動方式を用いており、温暖化対策・大気汚染対策・資源の削減に最適な環境技術である。通常のディーゼルエンジンやレシプロエンジンでも、少しの改良を加えれば本発明を行うことができる。しかし、水素ガス固有の金属脆化があるために、水素ガス９５容量％：炭酸ガス５容量％の混合気体とするか、又は、機器類はセラミック溶射で製造することが好ましい。 This rotary type engine drive / power generation device uses an engine drive system that is completely different from the combustion of ordinary fossil fuels, and is the most suitable environmental technology for global warming countermeasures, air pollution countermeasures, and resource reduction. Even with a normal diesel engine or reciprocating engine, the present invention can be carried out with a slight improvement. However, since there is metal embrittlement inherent to hydrogen gas, it is preferable to use a mixed gas of 95% by volume of hydrogen gas and 5% by volume of carbon dioxide, or the equipment is manufactured by ceramic spraying.
＜＜１軸タービンエンジン駆動・発電装置＞＞
　図１２に、本発明の水素流体閉サイクル駆動・発電装置０１の応用例として、（非大気）１軸閉サイクルタービン５３、１軸タービンエンジン駆動・発電装置０４について示す。
　水素ガス発生器１１から、密閉された一時的貯留タンク１３内部に、余熱用の水素ガス（の混合気体）を充填する。水素ガス加熱装置１２（太陽光・廃棄熱・蒸気利用加熱装置１２ｂ及びマイクロ波励起水中プラズマ加熱装置１２ａ）で加温された水素ガス（の混合気体）は、一時的に貯留することで圧力が増し、圧力調整弁３１でコントロールされて、超臨界流体として噴射孔から１軸閉サイクルタービンの圧縮側に噴射される。
　マイクロ波励起水中プラズマ加熱装置１２ａには、気体加熱チューブが具備されており、太陽光・廃棄熱・蒸気利用加熱装置１２ｂには、水素ガス加温２層タンクが具備されている。 << Single-shaft turbine engine drive / power generation system >>
FIG. 12 shows a (non-atmosphere) single-shaft closed cycle turbine 53 and a single-shaft turbine engine drive / power generation device 04 as an application example of the hydrogen fluid closed cycle drive / power generation device 01 of the present invention.
From the hydrogen gas generator 11, the sealed temporary storage tank 13 is filled with hydrogen gas (mixed gas) for preheating. The hydrogen gas (mixed gas) heated by the hydrogen gas heating device 12 (sunlight / waste heat / steam-utilizing heating device 12b and microwave-excited underwater plasma heating device 12a) is temporarily stored to increase the pressure. Further, the pressure is controlled by the pressure regulating valve 31 and is injected as a supercritical fluid from the injection hole to the compression side of the single-shaft closed cycle turbine.
The microwave-excited underwater plasma heating device 12a is provided with a gas heating tube, and the sunlight / waste heat / steam heating device 12b is provided with a hydrogen gas heating two-layer tank.
　噴射圧縮された戻りガスは、主タービン側に噴射され、駆動力が向上する。１軸（閉サイクル）タービン５３から排気されるガスは、熱交換器５５を経て再びマイクロ波励起水中プラズマ加熱装置１２ａに戻り、再び加温され貯留し、高圧状態で圧縮機に戻り、駆動させ繰り返すサイクルとなる。 Compressed return gas is injected to the main turbine side and driving force is improved. The gas exhausted from the single-shaft (closed cycle) turbine 53 returns to the microwave-excited underwater plasma heating device 12a again through the heat exchanger 55, is again heated and stored, returns to the compressor in a high-pressure state, and is driven. It becomes a cycle to repeat.
　１軸タービン軸に連動する流体発電器５４、駆動モーター５６（発電機可）を駆動する。温度は約１００℃、圧力は約２０ＭＰａ～約３５ＭＰａである。
　熱媒体として水素単独又は水素ガス／炭酸ガスの混合ガスの特性を最大限に活かすと、低温でも閉サイクル発電が行える。
　様々な廃棄熱や自然エネルギーである太陽光、地熱海洋温度差等無駄に捨てられている排熱を回収できる。 The fluid generator 54 and the drive motor 56 (generator possible) interlocked with the single-shaft turbine shaft are driven. The temperature is about 100 ° C. and the pressure is about 20 MPa to about 35 MPa.
When the characteristics of hydrogen alone or a mixed gas of hydrogen gas / carbon dioxide are utilized to the maximum as a heat medium, closed cycle power generation can be performed even at low temperatures.
Various waste heat, natural energy such as sunlight and geothermal ocean temperature difference can be recovered.
＜＜動力機関（自動車（新ハイブリッド車））＞＞
　本発明の水素流体閉サイクル駆動・発電装置０１は、自動車、船舶等の動力機関に利用（搭載）できる。
　図１３に、本発明の水素流体閉サイクル駆動・発電装置０１の応用例として、自動車（例えば、新ハイブリッド車）０５に適用した場合を示す。 << Power engine (automobile (new hybrid car)) >>
The hydrogen fluid closed cycle drive / power generation device 01 of the present invention can be used (mounted) in a power engine such as an automobile or a ship.
FIG. 13 shows a case where the hydrogen fluid closed cycle drive / power generation apparatus 01 of the present invention is applied to an automobile (for example, a new hybrid car) 05 as an application example.
　本発明の水素流体閉サイクル駆動・発電装置０１を利用した新ハイブリッド車０５は、駆動モーター推進力と発電機能の両立が図られている。
１：発進時はモーター６５のみで駆動する。モーター６５は、交流同期モーターで３相交流が好ましい。
２：閉サイクル主動力とした低速走行時は、閉サイクルエンジン０２、０３は、動力分割機構６４で２系統に分割する。一方は、発電機を駆動させて発電する経路でモーターを駆動し、もう一方は、車輪を、ギア変速機６６を介して直接駆動回転させる。
３：加速時は、２つのパワーで加速する。「エンジンの駆動力と蓄電池１９からのパワー」と「高出力のモーターの駆動力」を加えることで、レスポンスの良い滑らかな動力性能を発揮し、加速性能を向上させる。
４：減速時や制動時は、車輪と駆動軸６７がモーター６５に作用して、高出力モーター（パワーコントロールユット６３）を発電機として作動させ、車の制動エネルギーをより多くの電力に変換し、高効率の回生ブレーキとして作用し、その回収した電力は蓄電池１９を充電する。 The new hybrid vehicle 05 using the hydrogen fluid closed cycle drive / power generation device 01 of the present invention achieves both a driving motor propulsion force and a power generation function.
1: Driven by motor 65 only when starting. The motor 65 is an AC synchronous motor and preferably has a three-phase AC.
2: During low-speed traveling with closed-cycle main power, the closed- cycle engines 02 and 03 are divided into two systems by the power split mechanism 64. One drives the motor through a path for generating electricity by driving the generator, and the other directly rotates the wheels via the gear transmission 66.
3: When accelerating, it accelerates with two powers. By adding “engine driving force and power from the storage battery 19” and “high-power motor driving force”, smooth power performance with good response is exhibited and acceleration performance is improved.
4: During deceleration and braking, the wheels and drive shaft 67 act on the motor 65 to operate the high-output motor (power control unit 63) as a generator to convert the braking energy of the car into more power. It acts as a highly efficient regenerative brake, and the collected electric power charges the storage battery 19.
　発電出力：８０ＫＷ以上、最大トルク：３０．５ｋｇｆ／ｍが可能である。
　上記パワーコントロールユニット（ＰＵ）６３は、直流・交流を変換し電源電圧を調整機能があり、インバータ・可変電圧システム・ＤＣ／ＤＣコンバーター内蔵されているものが好ましい。
　上記動力分割機構６４は、エンジンの動力を遊星歯車機構において、多種の歯車によってドライブトレーンと発電機に連動していることが好ましい。
　上記回生ブレーキとは、モーターは電気を流すことで回転するが、逆に外部からの駆動力で回転させると発電機として電力を発生するものを言う。 Power generation output: 80 KW or more, maximum torque: 30.5 kgf / m is possible.
The power control unit (PU) 63 has a function of converting a direct current and an alternating current to adjust a power supply voltage, and preferably includes an inverter, a variable voltage system, and a DC / DC converter.
In the planetary gear mechanism, the power split mechanism 64 is preferably linked to the drive train and the generator by various gears in the planetary gear mechanism.
The regenerative brake refers to a motor that rotates when electricity is applied, but generates electric power as a generator when rotated by an external driving force.
　本発明における水素ガスは、低温が臨界点であり、熱伝導率が極めて高く、酸素がなければ安全であり、抗酸化作用がある等の特徴を有し、昇温・加圧が容易であり、物理的・化学的に安全性も高く、毒性もなく生体に対して安全であり、大気を利用しない閉サイクルであり、排気ガスが出ず大気を汚染せず環境に負荷をかけないので、種々の分野に利用可能である。 The hydrogen gas in the present invention has characteristics such as a critical point at low temperature, extremely high thermal conductivity, safety without oxygen, and an antioxidant effect, and is easy to raise and pressurize. Because it is physically and chemically safe, non-toxic and safe for the living body, it is a closed cycle that does not use the atmosphere, exhaust gas is not emitted, the atmosphere is not polluted, and the environment is not burdened. It can be used in various fields.
　本発明の態様１の水素ガスを乾燥媒体として用いた食材乾燥方法や食材乾燥装置は、特に乾燥効率等に優れており、原料となる食材は、規格外品、廃棄品等も対象となり、乾燥させ難い食材、大きな食材等も対象となり、得られる乾燥食材は、種々の用途に用いられるので、食品加工業、家庭向け食品業等を始め、農業、漁業、廃棄物処理業等にも、広く利用されるものである。 The food drying method and the food drying apparatus using the hydrogen gas of aspect 1 of the present invention as a drying medium are particularly excellent in drying efficiency and the like, and the raw material is also targeted for non-standard products, waste products, etc. Ingredients that are difficult to handle, large ingredients, etc. are also targeted, and the resulting dried ingredients are used in various applications, so they are widely used in food processing industries, household food industries, agriculture, fisheries, waste disposal industries, etc. It is what is used.
　本発明の態様２の抗酸化作用付与装置は、水素ガスをヒトが吸入したり、ヒトの全体又は「患部等の一部」に接触したりして、体内に取り込まれ、水素ガスの持つ抗酸化性と、好ましくは昇温による免疫力の上昇で、疾患を治癒できたりリラックスさせたりできるので、健康器具分野、医療分野等に広く利用されるものである。 The antioxidation-effect imparting device according to aspect 2 of the present invention is an anti-oxidation effect imparting device that has a hydrogen gas inhaled by a human inhalation or is brought into contact with the whole human or “part of an affected area”. Since the disease can be cured or relaxed by oxidizing and preferably raising the immunity by raising the temperature, it is widely used in the field of health equipment, the medical field, and the like.
　本発明の態様３の水素流体閉サイクル駆動・発電装置は、閉サイクルであり、環境に負荷をかけず、危険性も低いため、駆動力を必要とするあらゆる分野、及び、電気を必要とするあらゆる分野に広く利用されるものである。 The hydrogen fluid closed cycle drive / power generation device according to the third aspect of the present invention is a closed cycle, does not put a load on the environment, and has low risk. It is widely used in all fields.
　本願は、２０１６年１２月８日に出願した日本の特許出願である特願２０１６－２３８１０２、２０１６年１２月２１日に出願した日本の実用新案登録出願である実願２０１６－００６１１５、及び、２０１７年１月１０日に出願した日本の実用新案登録出願である実願２０１７－００００３３に基づくものであり、それらの出願の全ての内容はここに引用し、本願発明の明細書の開示として取り込まれるものである。 The present application is Japanese Patent Application No. 2016-238102 filed on Dec. 8, 2016, Japanese Utility Model Registration Application No. 2016-006115 filed on Dec. 21, 2016, and 2017. This is based on Japanese Utility Model Registration Application No. 2017-000033 filed on January 10, 2010, the entire contents of which are hereby incorporated by reference as the disclosure of the specification of the present invention. Is.
＜態様１の符号＞
　態様１の図１以外における符号、すなわち、図２ないし図４、及び、明細書の態様１についての記載中の符号は以下である。
１０　：食材乾燥装置
２０　：水素ガス発生器
２１　：金属
２２　：アルカリイオン水
２３　：アルカリ水タンク
２４　：残水
２５　：抜き取り管
２６　：生成水素移送ポンプ
２７　：天然物（自然石、貝殻、珊瑚等）
２８　：水素ガス加熱装置
３０　：食材乾燥容器
３１　：食材棚
３２　：水素ガス導入管
３３　：還流水素ガス移送管
３４　：還流水素ガス導入ノズル
３５　：還流水素ガス移送ポンプ
３６　：水蒸気と還流水素ガスの１次出口
３７　：食材投入ホッパー
４０　：除湿装置
４１　：除湿フィルター
４２　：水抜き取り管
Ｈ２ 　：水素ガス
　Ｆ　：食材 <Symbol of aspect 1>
Reference numerals other than FIG. 1 of the aspect 1, that is, reference numerals in FIGS. 2 to 4 and the description of the aspect 1 of the specification are as follows.
DESCRIPTION OF SYMBOLS 10: Food drying apparatus 20: Hydrogen gas generator 21: Metal 22: Alkaline ion water 23: Alkaline water tank 24: Residual water 25: Extraction pipe 26: Generated hydrogen transfer pump 27: Natural products (natural stone, shell, shell, etc.) )
28: Hydrogen gas heating device 30: Food drying container 31: Food shelf 32: Hydrogen gas introduction pipe 33: Recirculation hydrogen gas transfer pipe 34: Recirculation hydrogen gas introduction nozzle 35: Recirculation hydrogen gas transfer pump 36: Steam and recirculation hydrogen gas primary port 37: ingredients input hopper 40: dehumidifier 41: dehumidification filter 42: water extraction tube H 2: hydrogen gas F: ingredients
　図１における符号は以下である。
　１　：アルカリ水
　２　：水素ガス発生器
　３　：マイクロ波励起：加熱部位
　４　：水素ガス導入加熱チューブ
　５　：水
　６　：水蒸気
　７　：一時的貯留タンク
　８　：予備ドレン
　９　：加熱された水素ガス噴射孔
１０　：乾燥炉
１１　：棚スライド式メッシュ乾燥網
１２　：還流する水素ガス
１３　：ドレントラップ
１４　：ドレン水
１５　：金属
１６　：濾過装置
１７　：濾過水
１８　：触媒係留蓋
１９　：マイクロ波ユニット
２０　：垂直配管内の除湿材
２１　：配管
２２　：プロセス蒸気 Reference numerals in FIG. 1 are as follows.
1: Alkaline water 2: Hydrogen gas generator 3: Microwave excitation: Heating part 4: Hydrogen gas introduction heating tube 5: Water 6: Water vapor 7: Temporary storage tank 8: Preliminary drain 9: Heated hydrogen gas injection hole DESCRIPTION OF SYMBOLS 10: Drying furnace 11: Shelf sliding mesh drying net 12: Recirculating hydrogen gas 13: Drain trap 14: Drain water 15: Metal 16: Filtration device 17: Filtration water 18: Catalyst mooring lid 19: Microwave unit 20: Vertical Dehumidifying material 21 in piping: Piping 22: Process steam
＜態様２＞
　態様１における符号、すなわち、図５ないし図７、及び、明細書の態様２についての記載中の符号は以下である。
　１　：抗酸化作用付与装置
　２　：水素ガス発生器
　３　：水素ガス昇温制御装置
１１　：アルカリイオン水
１２　：金属
１３　：蓋
１４　：連結ボトル
１５　：水素ガス導入管
１６　：水素ガス吸入マスクと除湿フィルターの設置範囲
１７　：水素ガス吸入マスク
１８　：除湿フィルター
２３　：水素ガス導入管
２４　：マット
２５　：水素ガス排出口
２６　：水素ガス戻り管
２７　：水素ガス吐出充満容器
２８　：ドレントラップ
２９　：通気管
３０　：通気孔
３１　：除湿材
３２　：アルミ箔積層管材
Ｈ２　：水素ガス
　Ａ　：ヒト若しくはヒトの一部 <Aspect 2>
The code | symbol in aspect 1, ie, the description in the description about aspect 2 of FIG. 5 thru | or FIG. 7, and a specification is as follows.
1: Antioxidation imparting device 2: Hydrogen gas generator 3: Hydrogen gas temperature rise control device 11: Alkaline ion water 12: Metal 13: Lid 14: Connection bottle 15: Hydrogen gas introduction pipe 16: Hydrogen gas suction mask and dehumidification Filter installation range 17: Hydrogen gas suction mask 18: Dehumidification filter 23: Hydrogen gas introduction pipe 24: Mat 25: Hydrogen gas outlet 26: Hydrogen gas return pipe 27: Hydrogen gas discharge full container 28: Drain trap 29: Vent pipe 30: Ventilation hole 31: Dehumidifying material 32: Aluminum foil laminated tube material H2: Hydrogen gas A: Human or part of human
＜態様３＞
　態様３における符号、すなわち、図８ないし図１３、及び、明細書の態様３についての記載中の符号は以下である。 <Aspect 3>
The code | symbol in aspect 3, ie, the description in the description about aspect 3 of FIG. 8 thru | or 13, and a specification is as follows.
＜＜主に図８とその説明に使用されている符号＞＞
０１　：水素流体閉サイクル駆動・発電装置
１１　：水素ガス発生器
１２　：水素ガス加熱装置
１２ａ：マイクロ波励起水中プラズマ加熱装置
１２ｂ：太陽光・廃棄熱・蒸気利用加熱装置
１３　：一時的貯留タンク（密閉容器）
１４　：流体発電器
１５　：給水タンク
１６　：加温蒸気
１７　：キャッチパン・ドレントラップ
１８　：プロセス蒸気
１９　：蓄電池 << Primarily used in FIG. 8 and the description thereof >>
01: Hydrogen fluid closed cycle drive / power generation device 11: Hydrogen gas generator 12: Hydrogen gas heating device 12a: Microwave excited underwater plasma heating device 12b: Solar power / waste heat / steam heating device 13: Temporary storage tank ( Airtight container)
14: Fluid generator 15: Water supply tank 16: Heated steam 17: Catch pan / drain trap 18: Process steam 19: Storage battery
＜＜主に図１０と図１１とそれらの説明に使用されている符号＞＞
０２　：圧縮スクロール型エンジン駆動・発電装置
０３　：ロータリー型エンジン駆動・発電装置
１１　：水素ガス発生器
１３　：一時的貯留タンク（密閉容器）
１４　：流体発電器
３１　：水素ガス（又はその混合ガス）圧力調整弁
３２　：圧縮スクロール型エンジン
３３　：エンジン軸
３４　：吸入ポート
３５　：排気ポート
３６　：循環パイプ
３７　：流体発電器
４１　：ロータリー型エンジン << Primarily used in FIGS. 10 and 11 and their description >>
02: Compression scroll type engine drive / power generation device 03: Rotary type engine drive / power generation device 11: Hydrogen gas generator 13: Temporary storage tank (sealed container)
14: Fluid generator 31: Hydrogen gas (or mixed gas) pressure regulating valve 32: Compression scroll engine 33: Engine shaft 34: Suction port 35: Exhaust port 36: Circulation pipe 37: Fluid generator 41: Rotary engine
＜＜主に図１２とその説明に使用されている符号＞＞
０４　：１軸タービンエンジン駆動・発電装置
１２ａ：マイクロ波励起水中プラズマ加熱装置
１２ｂ：太陽光・廃棄熱・蒸気利用加熱装置
１４　：流体発電器
３６　：循環パイプ
５１　：炭酸ガス
５３　：１軸圧縮機・タービン
５５　：１次排気
５６　：予備熱交換器
５７　：駆動モーター
５８　：水・定量ポンプ
５９　：蒸気 << Primarily used in FIG. 12 and the explanation thereof >>
04: 1-shaft turbine engine drive / power generation device 12a: microwave-excited underwater plasma heating device 12b: sunlight / waste heat / steam-utilizing heating device 14: fluid power generator 36: circulation pipe 51: carbon dioxide 53: 1-axis compressor Turbine 55: Primary exhaust 56: Preliminary heat exchanger 57: Drive motor 58: Water / metering pump 59: Steam
＜＜主に図１３とその説明に使用されている符号＞＞
０１　：水素流体閉サイクル駆動・発電装置
０２　：圧縮スクロール型エンジン駆動・発電装置
０３　：ロータリー型エンジン
０５　：自動車（ハイブリッド車）
１４　：流体発電器
１９　：蓄電池
５７　：駆動モーター（交流同期モーター３相交流）
６３　：パワーコントロールユット
６４　：動力分割機構
６６　：ギア変速機
６７　：車輪と駆動軸 << Reference Signs Used mainly in FIG. 13 and the Description >>
01: Hydrogen fluid closed cycle drive / power generation device 02: Compression scroll type engine drive / power generation device 03: Rotary type engine 05: Automobile (hybrid vehicle)
14: Fluid power generator 19: Storage battery 57: Drive motor (AC synchronous motor 3-phase AC)
63: Power control unit 64: Power split mechanism 66: Gear transmission 67: Wheel and drive shaft

Claims (22)

  1. 　少なくとも、以下の（１）、（２）及び（Ｒ）を具備するものであることを特徴とする水素流体閉サイクル装置。
    （１）水素ガスを発生させる水素ガス発生器
    （２）上記（１）水素ガス発生器から出る水素ガスの温度を上げることによって水素ガスの圧力を上げる水素ガス加熱装置と一時的貯留タンク
    （Ｒ）上記（２）水素ガス加熱装置と一時的貯留タンクから出る水素ガスを利用する水素ガス利用装置     A hydrogen fluid closed cycle device comprising at least the following (1), (2) and (R):
    (1) Hydrogen gas generator for generating hydrogen gas (2) (1) Hydrogen gas heating device and temporary storage tank (R) for raising the pressure of hydrogen gas by raising the temperature of hydrogen gas exiting from the above (1) hydrogen gas generator ) (2) Hydrogen gas heating device and hydrogen gas utilization device that uses hydrogen gas from the temporary storage tank
  2. 　請求項１に記載の水素流体閉サイクル装置を具備する食材乾燥装置であって、
    　水素ガスを食材に接触・透過させて、該食材に含有されている水分を除去する食材乾燥方法に用いるものであることを特徴とする食材乾燥装置。     A food drying device comprising the hydrogen fluid closed cycle device according to claim 1,
    A food material drying apparatus characterized by being used in a food material drying method that removes moisture contained in the food material by bringing hydrogen gas into contact with and permeating the food material.
  3. 　上記食材を収納し水素ガスを通過させる食材乾燥容器、及び、食材乾燥容器の内部を通過した「水蒸気を含む水素ガス」から該水蒸気を除去する除湿装置を具備するものである請求項２に記載の食材乾燥装置。 The food drying container which accommodates the said foodstuffs and allows hydrogen gas to pass through, and the dehumidification apparatus which removes this water vapor from "the hydrogen gas containing water vapor" which passed the inside of a foodstuff drying container are comprised. Food drying equipment.
  4. 　上記食材乾燥容器が、内部に、網状であって食材を下から保持する食材棚を有し、該食材棚と該食材棚上の食材に対して水素ガスを接触・透過させることによって、該食材に含有されている水分を除去するようになっている請求項３に記載の食材乾燥装置。 The food drying container has a food shelf that is net-like and holds the food from below, and allows the hydrogen gas to contact and permeate the food shelf and the food on the food shelf. 4. The food drying apparatus according to claim 3, wherein moisture contained in the food is removed.
  5. 　上記食材乾燥容器が、細長く螺旋状になっており、食材を水素ガスの流体に乗せて、内部を通過させることによって、該食材に含有されている水分を除去するようになっている請求項３に記載の食材乾燥装置。 4. The food drying container is elongated and spiral, and the food is placed on a hydrogen gas fluid and passed through the interior to remove moisture contained in the food. The food drying apparatus according to 1.
  6. 　上記水素ガス発生器が、金属にアルカリ水を接触させることによって水素ガスを発生させるようになっている請求項２ないし請求項５の何れかの請求項に記載の食材乾燥装置。 The food drying apparatus according to any one of claims 2 to 5, wherein the hydrogen gas generator generates hydrogen gas by bringing alkaline water into contact with a metal.
  7. 　上記除湿装置が除湿フィルターを内蔵したパイプ状のものである請求項３ないし請求項６の何れかの請求項に記載の食材乾燥装置。 The food drying device according to any one of claims 3 to 6, wherein the dehumidifying device is a pipe-shaped device incorporating a dehumidifying filter.
  8. 　請求項２ないし請求項７の何れかの請求項に記載の食材乾燥装置を使用した食材乾燥方法であって、水素ガスを食材に接触・透過させて、該食材に含有されている水分を除去することを特徴とする食材乾燥方法。 A food drying method using the food drying apparatus according to any one of claims 2 to 7, wherein hydrogen gas is brought into contact with and permeated through the food to remove moisture contained in the food. A method for drying ingredients, characterized by:
  9. 　請求項８に記載の食材乾燥方法を使用することを特徴とする乾燥食材の製造方法。 A method for producing a dried food material, wherein the method for drying a food material according to claim 8 is used.
  10. 　請求項２ないし請求項７の何れかの請求項に記載の食材乾燥装置を用いて、水素ガスを食材に接触・透過させて、該食材に含有されている水分を除去することを特徴とする乾燥食材の製造方法。 Using the food drying apparatus according to any one of claims 2 to 7, hydrogen gas is brought into contact with and permeated through the food to remove moisture contained in the food. A method for producing dry ingredients.
  11. 　請求項１に記載の水素流体閉サイクル装置を具備する抗酸化作用付与装置であって、
    　少なくとも、以下の（ａ）、（ｂ）及び（Ｒ２）を具備するものであることを特徴とする抗酸化作用付与装置。
    （ａ）化学反応で水素ガスを発生させる水素ガス発生器
    （ｂ）上記（ａ）水素ガス発生器で発生した水素ガスの温度を昇温制御する水素ガス昇温制御装置
    （Ｒ２）該水素ガスをヒトに吸入させる水素ガス吸入マスク、又は、該水素ガスをヒト若しくはヒトの一部に接触させる水素ガス吐出充満容器     An antioxidant effect imparting device comprising the hydrogen fluid closed cycle device according to claim 1,
    An antioxidant effect imparting device comprising at least the following (a), (b) and (R2).
    (A) Hydrogen gas generator for generating hydrogen gas by chemical reaction (b) Hydrogen gas temperature rise control device (R2) for raising the temperature of the hydrogen gas generated by the above (a) hydrogen gas generator (R2) The hydrogen gas Hydrogen gas inhalation mask that allows a human to inhale, or a hydrogen gas discharge filling container that makes the hydrogen gas contact a human or a part of the human
  12. 　上記（ｂ）水素ガス昇温制御装置が、少なくとも、１５℃から４５℃までの範囲で、水素ガスの温度を制御しつつ段階的に上昇させられるようになっているものである請求項１１に記載の抗酸化作用付与装置。 12. The hydrogen gas temperature increase control device (b) is capable of being raised stepwise while controlling the temperature of hydrogen gas at least in the range from 15 ° C. to 45 ° C. The antioxidant action imparting device described.
  13. 　上記（ａ）水素ガス発生器が、金属にアルカリ水を接触させることによって水素ガスを発生させられるようになっているものである請求項１１又は請求項１２に記載の抗酸化作用付与装置。 13. The antioxidant effect imparting device according to claim 11 or 12, wherein the (a) hydrogen gas generator is adapted to generate hydrogen gas by bringing alkaline water into contact with a metal.
  14. 　請求項１１ないし請求項１３の何れかの請求項に記載の抗酸化作用付与装置を使用し、水素ガスの温度を制御しつつ段階的に上昇させて、該水素ガスをヒト若しくはヒトの一部に接触させることを特徴とする抗酸化作用付与方法。 The antioxidant effect imparting device according to any one of claims 11 to 13 is used, and the hydrogen gas is increased stepwise while controlling the temperature of the hydrogen gas, so that the hydrogen gas is human or part of human. A method of imparting an antioxidant effect, characterized by contacting with water.
  15. 　請求項１に記載の水素流体閉サイクル装置を具備する水素流体閉サイクル駆動・発電装置であって、
    　少なくとも、以下の（Ｒ３）及び（Ｒ４）の全てを具備するものであることを特徴とする水素流体閉サイクル駆動・発電装置。
    （Ｒ３）一時的貯留タンクから水素ガスが噴射されることで回転するタービンを備える駆動装置
    （Ｒ４）一時的貯留タンクから水素ガスが噴射されることで回転翼が回転して発電する流体発電器     A hydrogen fluid closed cycle drive / power generation device comprising the hydrogen fluid closed cycle device according to claim 1,
    A hydrogen fluid closed cycle drive / power generation apparatus characterized by comprising at least all of the following (R3) and (R4).
    (R3) Drive unit including a turbine that rotates when hydrogen gas is injected from the temporary storage tank (R4) Fluid generator that generates power by rotating the rotor blades when hydrogen gas is injected from the temporary storage tank
  16. 　上記（１）水素ガス発生器が、金属にアルカリ水を接触させることによって水素ガスを生成させるようになっている請求項１５に記載の水素流体閉サイクル駆動・発電装置。 The hydrogen fluid closed cycle drive / power generation device according to claim 15, wherein the hydrogen gas generator (1) generates hydrogen gas by bringing alkaline water into contact with a metal.
  17. 　上記（２）水素ガス加熱装置が、密閉された容器内の水素ガスを４００℃以下に加熱して使用するようになっている請求項１５又は請求項１６に記載の水素流体閉サイクル駆動・発電装置。 The hydrogen fluid closed cycle drive / power generation according to claim 15 or 16, wherein the (2) hydrogen gas heating device is configured to use hydrogen gas in a sealed container heated to 400 ° C or lower. apparatus.
  18. 　上記（２）水素ガス加熱装置が、マイクロ波を利用して加熱するものである請求項１５ないし請求項１７の何れかの請求項に記載の水素流体閉サイクル駆動・発電装置。 The hydrogen fluid closed cycle drive / power generation device according to any one of claims 15 to 17, wherein the (2) hydrogen gas heating device heats using a microwave.
  19. 　上記（Ｒ３）駆動装置が、圧縮スクロール型エンジン、ロータリー型エンジン、又は、１軸タービンエンジンである請求項１５ないし請求項１８の何れかの請求項に記載の水素流体閉サイクル駆動・発電装置。 The hydrogen fluid closed cycle drive / power generation device according to any one of claims 15 to 18, wherein the (R3) drive device is a compression scroll type engine, a rotary type engine, or a single-shaft turbine engine.
  20. 　上記（Ｒ４）流体発電器が、水素ガスを燃焼させずに、加熱して一時的に貯留した超臨界水素ガスの流体によって回転翼を回転させて発電するものである請求項１５ないし請求項１９の何れかの請求項に記載の水素流体閉サイクル駆動・発電装置。 The fluid generator (R4) generates power by rotating a rotor blade with a fluid of supercritical hydrogen gas that is heated and temporarily stored without burning hydrogen gas. The hydrogen fluid closed cycle drive / power generation device according to claim 1.
  21. 　請求項１５ないし請求項２０の何れかの請求項に記載の水素流体閉サイクル駆動・発電装置を搭載した動力機関。 A power engine equipped with the hydrogen fluid closed cycle drive / power generation device according to any one of claims 15 to 20.
  22. 　請求項１５ないし請求項２０の何れかの請求項に記載の水素流体閉サイクル駆動・発電装置を使用することを特徴とする駆動・発電方法。 21. A drive / power generation method using the hydrogen fluid closed cycle drive / power generation apparatus according to any one of claims 15 to 20.
PCT/JP2017/004574 2016-12-08 2017-02-08 Hydrogen fluid closed cycle device WO2018105133A1 (en)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP2016238102A JP2018093740A (en) 2016-12-08 2016-12-08 Food material drying method and food material drying device used therefor
JP2016-238102 2016-12-08
JP2016-006115U 2016-12-21
JP2016006115U JP3209283U (en) 2016-12-21 2016-12-21 Antioxidant device
JP2017000033U JP3209521U (en) 2017-01-10 2017-01-10 Hydrogen fluid closed cycle drive / power generation equipment
JP2017-000033U 2017-01-10

Publications (1)

Publication Number Publication Date
WO2018105133A1 true WO2018105133A1 (en) 2018-06-14

Family

ID=62490973

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2017/004574 WO2018105133A1 (en) 2016-12-08 2017-02-08 Hydrogen fluid closed cycle device

Country Status (1)

Country Link
WO (1) WO2018105133A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6492235B1 (en) * 2019-01-18 2019-03-27 株式会社エヌティシィー Method of processing processed food, processing system of processed food, and method of preserving fresh food and processed food in the same sealed environmental device
CN111766191A (en) * 2020-08-10 2020-10-13 盐城新海川机电科技有限公司 Environment-friendly material cylinder penetration testing machine and working method thereof

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05316944A (en) * 1990-03-05 1993-12-03 Blaizat Claude Antoine Method and device for complete or partial dehydration of vegetable product and dehydrated product obtained
JPH06241055A (en) * 1993-02-12 1994-08-30 Mazda Motor Corp Gas fuel engine
JP2002156102A (en) * 2000-11-17 2002-05-31 Toyota Central Res & Dev Lab Inc Method for injecting liquid fuel
JP2004210591A (en) * 2002-12-27 2004-07-29 Itec Co Ltd Apparatus and method of producing gaseous hydrogen
JP2007064169A (en) * 2005-09-02 2007-03-15 Mazda Motor Corp Fuel injection device for hydrogen rotary engine
JP2008166248A (en) * 2006-12-26 2008-07-17 Samsung Electro-Mechanics Co Ltd Fuel cell having hydrogen storage tank
JP2011178609A (en) * 2010-03-02 2011-09-15 Kawasaki Heavy Ind Ltd Method for producing hydrogen gas
JP2014095115A (en) * 2012-11-08 2014-05-22 Suntec Inc Gas generation device
JP6029044B1 (en) * 2016-03-01 2016-11-24 株式会社グレイトチレン Wet high concentration hydrogen mixed gas breathing system
JP3209283U (en) * 2016-12-21 2017-03-09 杉山　修 Antioxidant device
JP3209521U (en) * 2017-01-10 2017-03-23 杉山　修 Hydrogen fluid closed cycle drive / power generation equipment

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05316944A (en) * 1990-03-05 1993-12-03 Blaizat Claude Antoine Method and device for complete or partial dehydration of vegetable product and dehydrated product obtained
JPH06241055A (en) * 1993-02-12 1994-08-30 Mazda Motor Corp Gas fuel engine
JP2002156102A (en) * 2000-11-17 2002-05-31 Toyota Central Res & Dev Lab Inc Method for injecting liquid fuel
JP2004210591A (en) * 2002-12-27 2004-07-29 Itec Co Ltd Apparatus and method of producing gaseous hydrogen
JP2007064169A (en) * 2005-09-02 2007-03-15 Mazda Motor Corp Fuel injection device for hydrogen rotary engine
JP2008166248A (en) * 2006-12-26 2008-07-17 Samsung Electro-Mechanics Co Ltd Fuel cell having hydrogen storage tank
JP2011178609A (en) * 2010-03-02 2011-09-15 Kawasaki Heavy Ind Ltd Method for producing hydrogen gas
JP2014095115A (en) * 2012-11-08 2014-05-22 Suntec Inc Gas generation device
JP6029044B1 (en) * 2016-03-01 2016-11-24 株式会社グレイトチレン Wet high concentration hydrogen mixed gas breathing system
JP3209283U (en) * 2016-12-21 2017-03-09 杉山　修 Antioxidant device
JP3209521U (en) * 2017-01-10 2017-03-23 杉山　修 Hydrogen fluid closed cycle drive / power generation equipment

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6492235B1 (en) * 2019-01-18 2019-03-27 株式会社エヌティシィー Method of processing processed food, processing system of processed food, and method of preserving fresh food and processed food in the same sealed environmental device
JP2020114187A (en) * 2019-01-18 2020-07-30 株式会社エヌティシィー Processing method and processing system of processed food, and method of preserving fresh food and processed food in same sealed atmosphere apparatus
CN111766191A (en) * 2020-08-10 2020-10-13 盐城新海川机电科技有限公司 Environment-friendly material cylinder penetration testing machine and working method thereof
CN111766191B (en) * 2020-08-10 2023-11-24 江苏钦宇建设工程有限公司 Environment-friendly material cylinder penetration testing machine and working method thereof

Similar Documents

Publication Publication Date Title
RU2264854C2 (en) Activating structure, substance activation apparatus, and substance activation process
WO2018105133A1 (en) Hydrogen fluid closed cycle device
EP2572592A1 (en) Method and appliances for low temperature pasteurisation of liquid foods and removal of oxygen from liquid foods by decompression and/or high linear or rotary acceleration
CN204105676U (en) Deoxidation juice extractor
US20090302613A1 (en) Power generation methods and systems
KR20150084058A (en) Systems and methods for utilizing alcohol fuels
JP2009197778A (en) Various energy conservation cycle combined engine
JPH03207936A (en) Oxygen generator and air-conditioning system
CN102793009A (en) Grain and plant food preservation method and device
CN202979916U (en) Alive-keeping box for aquatic products
JP3184538U (en) Simple hydrogen gas generator
CN109527452A (en) The preparation method and application of high calcium low sodium seawood meal
JP3209521U (en) Hydrogen fluid closed cycle drive / power generation equipment
Fenno Man's milieu in space
CN113907034A (en) Logistics system that seafood transportation was used
CN211091639U (en) Fresh-keeping processing system reaches fresh-keeping freezer including it
JP2009174313A (en) Various energy conservation cycle combined engine
CN202551918U (en) Package for transport of live fish
JP2018093740A (en) Food material drying method and food material drying device used therefor
CN215044770U (en) Inflatable ozone sterilization heat preservation box
KR100672477B1 (en) Refrigerator
US20220074382A1 (en) Apparatus and method
CN211607902U (en) Mobile double-loop water ecological circulating and filtering device
CN202630558U (en) Ozone sterilizing pressure return device for vacuum pre-cooler
TW201121437A (en) Systems and methods for maintaining perishable foods

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 17877394

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

32PN Ep: public notification in the ep bulletin as address of the adressee cannot be established

Free format text: NOTING OF LOSS OF RIGHTS PURSUANT TO RULE 112(1) EPC (EPO FORM 1205N DATED 14.08.2019)

122 Ep: pct application non-entry in european phase

Ref document number: 17877394

Country of ref document: EP

Kind code of ref document: A1