WO2018077127A1 - Gas-gas mixed aspirator - Google Patents

Gas-gas mixed aspirator Download PDF

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Publication number
WO2018077127A1
WO2018077127A1 PCT/CN2017/107227 CN2017107227W WO2018077127A1 WO 2018077127 A1 WO2018077127 A1 WO 2018077127A1 CN 2017107227 W CN2017107227 W CN 2017107227W WO 2018077127 A1 WO2018077127 A1 WO 2018077127A1
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WO
WIPO (PCT)
Prior art keywords
gas
pipe
flow
seamless
exhaust
Prior art date
Application number
PCT/CN2017/107227
Other languages
French (fr)
Chinese (zh)
Inventor
斯科特·韦恩 小福特
郎建峰
Original Assignee
山西北极熊环境科技有限公司
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Publication of WO2018077127A1 publication Critical patent/WO2018077127A1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
    • B01D53/56Nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/76Gas phase processes, e.g. by using aerosols
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/40Nitrogen compounds
    • B01D2257/404Nitrogen oxides other than dinitrogen oxide

Definitions

  • the present invention relates to the field of industrial waste gas treatment, and relates to a gas mixing aspirator, and more particularly to a device for mixing a gas such as ozone or chlorine with a gas in a boiler exhaust gas stream.
  • Boiler exhaust streams from large industrial and power plants usually contain pollutants such as NO and/or SO 2 . In order to reduce the content of pollutants such as NO and/or SO 2 in the exhaust gas, they can be mixed by gas and gas.
  • the aspirator introduces a feed gas that can react with the boiler exhaust stream.
  • Figure 1 is a schematic view showing the structure of a classic gas-gas mixing aspirator in the prior art. Four incisions are selected as the intake ports at different positions of the flue (0100), and the raw material gas (0104) passes through the four intakes. The tube structure at the mouth enters and is mixed with the boiler exhaust stream (0101). The raw material gas (0104) such as 0 3 is mixed with the exhaust gas stream (0101) to make 0 3
  • NO: 0 3 is 1: 11 ⁇ 2 (molar ratio) to convert all NO to NO 2; in addition, another problem that needs attention is to convert NO to NO 2 Excessive 0 3 may cause ozone escaping and discharge into the atmosphere, while there are strict regulations for 0 3 (ozone), and any ozone escaping may violate the relevant regulations.
  • the raw material gas pipe at a constant pressure (0107) can be prevented from being blown back (0105) (the exhaust gas enters the raw material gas pipe (0104) and flows into the ozone device. ) influences.
  • the present invention discloses a gas-gas mixing aspirator which is designed in the form of a flow nozzle conduit due to the converging section/tube and diverging section of the gas-gas mixing aspirator/
  • the designed structure of the tube can eliminate cavitation and delamination; the elimination of cavitation and stratification, so that the 0 3 introduced into the exhaust gas stream can fully contact the NO in the exhaust gas stream, and then all the NO in the exhaust gas stream Converted to NO 2 ; no need to gas Additional gas is introduced into the gas mixing aspirator, and all NO can be converted to NO 2 by using NO: 0 3 in a molar ratio ;
  • the direction of the pitot tube is The flow of the exhaust stream is consistent, and the flow rate of the exhaust stream provides a constant suction to the pitot tube feed line to introduce the feed gas into the exhaust stream without the need to maintain the feed gas line at a constant pressure like a classical gas-mixed as
  • An air-gas mixing aspirator comprising: a flow nozzle pipe for exhaust gas flow, a carrier gas pipe and a seamless pipe for conveying a reaction gas to the exhaust gas flow, and being installed on the flow nozzle pipe
  • the hole structure for passing the carrier gas pipe the carrier gas pipe extends from the outside of the flow nozzle pipe to the inside of the flow nozzle pipe through the hole structure
  • the seamless pipe is axially mounted, connected to the end of the carrier gas pipe, and flows to the exhaust gas stream A direction extension for delivering the pumped gas into the exhaust stream.
  • the flow nozzle pipe is composed of an intake pipe, a shrink pipe, a gas flow intermediate pipe, a diverging pipe and an air outlet pipe, wherein a radius of the gas flow intermediate pipe is smaller than that of the intake pipe and the gas outlet pipe.
  • the radius, the radius of the intake pipe and the outlet pipe are equal, the seamless pipe is located on the intake pipe, and the air outlet of the seamless pipe extends toward the downstream of the intake pipe.
  • the gas-gas mixing aspirator may include: a flow nozzle pipe for passing the exhaust gas flow, a carrier gas pipe and a seamless pipe for conveying the reaction gas into the exhaust gas flow, and uniform An eyelet structure distributed on the same section of the flow nozzle pipe for passing the carrier gas pipe; the carrier gas pipe extends from the outside of the flow nozzle pipe to the inside of the flow nozzle pipe through an equidistantly distributed orifice structure; The seamless pipe inside the nozzle pipe is axially mounted, connected to the end of the carrier pipe, and extends in the flow direction of the exhaust gas flow.
  • a bent portion is provided at the end of the seamless pipe, a partition is provided near the inlet end of the seamless pipe, and a seamless pipe is disposed between the partition and the bent portion.
  • the angle between the side wall of the shrink tube and the horizontal direction is 20-70°.
  • the angle between the curved portion of the seamless tube and the horizontal direction is 45°.
  • the seamless tube is a pitot tube.
  • the NO-containing exhaust gas stream delivered to the gas-gas mixing aspirator is contacted with the 0 3 transported by the carrier gas pipe to convert NO into NO 2 to form NO 2 and unconverted NO. Exhaust gas flow.
  • the carrier gas tube is in communication with the ozone generator, and the ozone generator converts 0 2 to 0.
  • the present invention discloses an apparatus and method for mixing large amounts of ozone, chlorine, and/or other gases with large industrial and power plant boiler exhaust streams.
  • the apparatus and method include a flow nozzle pipe, a pitot tube disposed at different positions and depths inside the flow nozzle pipe, for guiding a gas (eg, ozone) into the boiler exhaust gas flow and a target such as NO (nitrogen oxide)
  • a gas eg, ozone
  • NO nitrogen oxide
  • the exhaust gas stream of the contaminants is contacted and mixed, and NO is brought into contact with ozone 0 3 to react, thereby converting NO into NO 2 .
  • the flow of gas or liquid through the flow nozzle conduit is described as a motion that flows through the narrow jaw without causing an increase or decrease in entropy.
  • the gas molecules Whenever gas is forced into a pipe or flue, the gas molecules will deflect in the direction of motion due to the presence of the pipe wall. If the velocity of the gas is much less than the speed of sound, the density of the gas will remain the same and the velocity of the fluid will increase. However, when the fluid velocity is close to the speed of sound, the effect of gas compressibility should be considered, and the density of the gas will be related to its location. At the same time, in consideration of the state in which the fluid flows through the pipe or the flue enthalpy, when the flow rate of the fluid slowly decreases and slowly increases, the fluid can return to the previous normal flow state ⁇ , which is a reversible process.
  • a flow meter is further included, and the gas can be gased by a gas-gas mixing aspirator under a micro-positive pressure condition of (0.03 ps inverted 0.5 psi). 3 ) Guide into the exhaust gas flow to ensure that the gas (0 3 ) uniformly enters the exhaust gas flow and complete the mixing of the two gases.
  • the gas-gas mixing aspirator is installed in the boiler exhaust gas flow after the electrostatic precipitator or the bag filter (bag filter), and the temperature of the boiler exhaust gas is 150 ° C - 270 ° C. Mixing a gas such as ozone (0 3 ) that participates in the reaction requires a certain stagnation time (about 3 seconds).
  • the installation of the gas-gas mixing aspirator should consider the factor of stagnation.
  • the gas flows through a pipe whose cross-sectional area is reduced and then enlarged, thereby generating a change in the volume of the flow.
  • the pressure of the gas inside the pipe will decrease.
  • the flow rate of the fluid in this narrow flow area must be increased to maintain its continuity. Due to the Venturi effect, the interior of the pitot tube is drawn to a vacuum.
  • FIG. 1 shows a schematic view of a device of a prior art classical gas-mixed aspirator.
  • FIG. 2 is a schematic view showing the apparatus of the gas-gas mixing aspirator of the present invention.
  • FIG. 3 is a schematic diagram of a one-dimensional forward shock wave.
  • FIG. 4 is a schematic diagram of a suction control panel.
  • FIG. 5 is a schematic illustration of the application of a suction device to a boiler exhaust stream.
  • the gas-gas mixing aspirator shown in one or more embodiments of the present invention is fabricated from 304/316L stainless steel (0208), in addition, the suction end of one or more embodiments of the present invention
  • the size to the adjacent constricted section/tube (0209) is reduced or reduced by about 4 feet.
  • the distance between the constricted section/tube (0209) of the gas-mixed aspirator to the diverging section/tube (0210) is 8 feet.
  • the surface area of the diverging section/tube (0210) increases back to the original size of the initial end of the aspirator.
  • the movement of the fluid of the present invention through a flow nozzle is referred to as "Technology of Thermodynamics" which is a technique for passing a one-dimensional fluid through a flow nozzle in thermodynamics.
  • the momentum equations of the control volume are derived and applied to solve such same problems.
  • the speed of sound is defined by thermodynamic properties and mentions the importance of Mach numbers for such variable incompressible fluids.
  • Also disclosed in one or more embodiments of the invention are 0°, 45°, 90°, 135°, 180 at the aspirator.
  • the pitot tubes were installed at 225°, 270° and 315°, respectively, with 4 long pitots (0211) extending into the aspirator and 4 short pitots (0212) extending into the aspirator. These 8 pitot tubes are installed at different angles of the aspirator and are staggered in length.
  • the disclosed pitot tube in one or more embodiments of the invention is used to measure the local flow rate at a given point in the flowing fluid, rather than the average flow rate in the conduit or conduit.
  • "Tubes” are generally applied to tubular structures in boilers, heat exchangers, and instrumentation, unlike pipes, pressure pipes, and mechanical pipes (piterons), which are usually classified according to their manufacturing method and processing accuracy (slurry).
  • the pitot tube is mounted on the gas-gas mixing aspirator, and the separator fitting is mounted at the end of the pitot tube 1.5 inches from the outer surface of the aspirator ( 0213) The height.
  • the 316 stainless steel washer (0214) is welded to the pitot under the bulkhead to prevent slippage of the pits/holes prepared for the pitot tube on the suction.
  • the distance from the beginning of the baffle to the 45° bend is 3 inches (0215), while the distance from the pitot 45° bend (0216) to the end is 2 inches (0217).
  • the pipe arrangement is a short pitot tube (0212) mounted to the aspirator, which is distributed in sequence and inserted into the aspirator at intervals.
  • the pitot tube is mounted in a 45° bend inside the suction tube toward the exhaust gas flow so that the ozone can flow along with the exhaust gas flow.
  • the long pitot tube and the short pitot tube are installed in a similar manner, and the baffle fitting is mounted at the end of the pitot tube 1.5 inches from the outer surface of the aspirator.
  • the 316 stainless steel washer (0219) is welded to the pitot under the bulkhead to prevent the pitot tube from slipping on the suction tube/hole for the pitot tube.
  • the distance from the beginning of the bulkhead to the 45° bend is 1 foot to 4 inches (0220), while the distance from the pitot 45° bend (0221) to the end is 2 inches (0223).
  • the pipe is arranged as a long pitot tube (0211) mounted on the aspirator, and the pitot tubes are distributed in order, with the suction device inserted at intervals.
  • the pitot tube is installed in a 45° bend in the direction of the exhaust gas flow inside the aspirator so that the ozone can flow along with the exhaust gas stream.
  • the exhaust gas stream (0224) and the secondary gas sucked into the exhaust gas stream flow through the gas-gas mixture suction device.
  • the isentropic stagnation state is the state that a substance will decelerate to zero during the reversible adiabatic process.
  • a nozzle is a device that allows the kinetic energy of a substance to increase in an adiabatic state. The increase in kinetic energy is passed The reduction in pressure and the appropriate change in the flow area are achieved.
  • a diffuser is a device that has the opposite function, that is, increases the pressure by reducing the velocity of the substance. In order to maximize the terminology of the term, the nozzle and the diffuser are referred to as nozzles in the future.
  • a shock wave is a wave in which a state undergoes an extremely rapid and abrupt change. In a positive shock wave, this change often occurs at a cross section perpendicular to the flow direction.
  • Figure 3 shows the normal control surface (0325) containing the positive shock (0326).
  • an apparatus and method for mixing one gas with another is disclosed by way of embodiments of the present invention. More specifically, it is disclosed by one or more embodiments of the present invention that a gas such as 03 is mixed with a boiler exhaust stream to achieve the purpose of contacting 03 with NO in the boiler exhaust stream.
  • the present invention also discloses the conversion of NO in the exhaust stream to NO 2 and the introduction of H 2 0 to condense the product to form nitric acid.
  • the gas and gas mixing device includes a flow nozzle pipe, which can be made of, but not limited to, a metal such as stainless steel, a divergent type and a contracted type. device.
  • a flow nozzle pipe which can be made of, but not limited to, a metal such as stainless steel, a divergent type and a contracted type. device.
  • the pitot tubes are distributed in eight different directions of the flow nozzle tubes.
  • the flow meter directs the gas (0 3 ) into the aspirator and is evenly distributed into the boiler exhaust stream.
  • the gas-gas mixing aspirator in one or more embodiments of the present invention is capable of converting pollutants (such as nitrogen oxides) produced in industrial plant exhaust gas, where the industrial plant involves multiple market segments.
  • pollutants such as nitrogen oxides
  • Processing and manufacturing including but not limited to food processing and packaging, pulp and paper, printing, chemicals and related products, rubber, plastics, hospitals, universities, metal industry, pharmaceutical production, wastewater and sewage treatment, beverages, utilities, incineration , steel, cosmetics, textiles, electronics and petroleum refining.
  • NO x is nitric oxide (NO) and nitrogen dioxide (NO 2) in general. Both NO and NO 2 are formed by the reaction of nitrogen and oxygen in the air during combustion. NO 2 can form wastewater by contacting NO 2 with steam in water, steam or flue gas stream, and then collect the wastewater and flow it to the wastewater treatment plant for neutralization. . Since NO cannot be removed by contact with water, it is necessary to convert NO into a NO 2 by a chemical reaction which can be reacted by introducing ozone (0 3 ) into the exhaust gas as follows:
  • FIG. 4 shows a control panel of a gas-mixing aspirator, wherein the control panel (0431) is made of stainless steel or painted steel to prevent dust, light, and Indirect splashing, making it weatherproof, dustproof, and explosion proof.
  • each flow meter is manually adjusted to each of the lines (0436)
  • a micro-positive pressure gas (0 3 ) is supplied and the gas is introduced into the aspirator to allow the gas to be thoroughly mixed.
  • a manual shut-off valve (0433) is mounted on the bottom or bottom of the flow meter for facilitating replacement of the damaged flow meter.
  • a control valve (0435) in the control panel is mounted below the flow meter for supplying the main gas to the flow meter.
  • the control valve (0435) is a normally closed valve that only slams when a gas supply is required.
  • the control valve (0435) is not a regulating valve and can only be used for the opening or closing of the device, while the flow meter controls the flow of gas into the aspirator.
  • the present invention also features a pressure relief valve (0434) for removing residual gases from the line as the primary gas enters the control panel.
  • FIG. 5 is a gas-gas mixing aspirator suitable for use in a boiler exhaust stream, and a typical coal-fired boiler that produces an exhaust gas stream is shown.
  • the combustor within the boiler (0538) receives a quantity of preheated combustion air and fuel to effect a combustion process to produce an exhaust stream. From the beginning of the boiler (0538), the exhaust stream is directed from the boiler through a metal flue (0539), which in turn flows through the air heater (0540) and the electrostatic precipitator ESP (0541).
  • the exhaust stream is sent to the gas-gas mixing aspirator (0542) .
  • the gas-gas mixing device (0542) mixes the ozone (0 3 ) with the exhaust gas stream to convert NO to NO 2 .
  • the oxidation reaction in the redox reaction (Reference: Basic Chemistry, Chemical Concept Method, Fourth Edition)
  • the initial refers to the reaction of the substance with the oxidation
  • the "reduction reaction” refers to the reaction of removing the oxygen in the oxygenate.
  • the oxidation reaction is a process in which the atomic oxidation value is increased
  • the reduction reaction refers to a process in which the atomic oxidation value is lowered. It can be clearly seen from the principle of distribution of oxidation values that neither the oxidation reaction nor the reduction reaction occurs separately.
  • the total increase in the oxidation value is always equal to the total reduction in the oxidation value. Since one substance cannot be reduced, unless the other substance is oxidized, the reduced substance undergoes an oxidation reaction, which is called an oxidizing agent. Since the two processes of oxidation and reduction are interdependent, the opposite is true, that is, the substance to be oxidized is called a reducing agent.
  • the equations for oxidation-reduction reactions are generally more difficult to trim than those that do not involve oxidation-reduction reactions.
  • the oxidation-reduction equation is usually balanced by the oxidation method and the ion/electron method.
  • the ozone in Figure 5 is provided by an ozone generator (05 43) that produces ozone.
  • the outlet of the oxygen supply unit (0544) is connected to the ozone generator via a series of pipes, fittings and control valves (0545).
  • the control valve (0545) controls the flow of oxygen to the ozone generator (0543) and adjusts the boiler system so that the oxygen supply unit (0544) supplies the ozone generator (0543) with an appropriate amount of oxygen.
  • oxygen (0 2 ) enters the ozone generator (0543), and under the action of high-pressure charge bombardment, a portion of 0 2 is converted to 0 3 (ozone). Due to the continuous high-pressure charge bombardment in the ozone generator (0543) vessel, a large amount of heat dissipation will be required to cool, so that the temperature of the ozone in the vessel is maintained near ambient temperature. Most ozone generators are internally provided with a cooling system for maintaining the required temperature. The cooling system sends cooling water through the cooling water supply unit (0546), and drains the cooling water to the cooling tower (0547). The cooling water is in the cooling tower. After the internal temperature is lowered, it is returned to the cooling system of the ozone generator (0543) through the return pipe (0548) as cooling cooling water, and the cooled cooling water is used to assist the normal operation of the cooling system cooling work.
  • the generated ozone (0 3 ) enters the gas-mixing suction control panel (0549) through a series of pipes and fittings. Before the air-mixing suction control device (0551) is snoring, Ozone (O 3 ) is removed to remove all gases from the system. Once the gas-mixed aspirator control valve (0551) is snoring, ozone (0 3 ) will enter the gas-gas mixing aspirator through a series of flow meters (0552).
  • the flow meter (0552) delivers a micro-positive pressure of 0.03-0.05 psi to each of the lines in a manually adjusted configuration.
  • the ozone output from the flow meter (0552) is sent to the gas-mixing suction bow I (0542) through a series of lines (0553) to treat the ozone (0 3
  • the kinetic region is a period in which the concentration of the reaction component is constantly changing
  • the equilibrium region is a period in which the concentration of the reaction component does not change further, and the reaction appears to be stopped.
  • the gas is mixed with the boiler exhaust stream and then drained to other equipment (0554) to remove the converted N in the exhaust gas.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
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  • Treating Waste Gases (AREA)

Abstract

Provided is a gas-gas mixed aspirator, comprising a flow nozzle pipe used for passage of a waste gas flow (0224), a gas-carrying tube and pitot tube (0211, 0212) used for transporting a reagent gas into the waste gas flow (0224), and a hole structure mounted on a flow nozzle pipe and used for enabling passage of the gas-carrying tube; by means of the hole structure, the gas-carrying tube extends from the exterior of the flow nozzle pipe to the interior of the flow nozzle pipe; the pitot tube (0211, 0212) is arranged in the axial direction and is connected to the end of the gas-carrying tube, extends in the direction of the flow of the waste gas (0224), and is used for transporting sucked gas into the waste gas flow (0224).

Description

一种气气混合吸引器  Air-gas mixing aspirator
技术领域  Technical field
[0001] 本发明属于工业废气治理技术领域, 涉及一种气体混合吸引器, 特别是涉及一 种用于臭氧或氯气这类气体与锅炉废气流中气体混合的装置。  [0001] The present invention relates to the field of industrial waste gas treatment, and relates to a gas mixing aspirator, and more particularly to a device for mixing a gas such as ozone or chlorine with a gas in a boiler exhaust gas stream.
背景技术  Background technique
[0002] 大型工业和发电厂产生的锅炉废气流中通常会含有 NO和 /或 SO 2这类污染物, 为了降低废气中 NO和 /或 SO 2这类污染物的含量, 可通过气气混合吸引器向锅炉 废气流中引入能与其发生反应的原料气体。 图 1所示的是现有技术中经典的气气 混合吸引器结构示意图, 在烟道 (0100)的不同位置选择 4个切入点作为进气口, 原料气体 (0104)通过这 4个进气口处的管结构进入, 并与锅炉废气流 (0101)混合。 如 0 3这类原料气体 (0104)与废气流 (0101)混合, 使 0 3 [0002] Boiler exhaust streams from large industrial and power plants usually contain pollutants such as NO and/or SO 2 . In order to reduce the content of pollutants such as NO and/or SO 2 in the exhaust gas, they can be mixed by gas and gas. The aspirator introduces a feed gas that can react with the boiler exhaust stream. Figure 1 is a schematic view showing the structure of a classic gas-gas mixing aspirator in the prior art. Four incisions are selected as the intake ports at different positions of the flue (0100), and the raw material gas (0104) passes through the four intakes. The tube structure at the mouth enters and is mixed with the boiler exhaust stream (0101). The raw material gas (0104) such as 0 3 is mixed with the exhaust gas stream (0101) to make 0 3
与废气流中的目标污染物 NO混合, 从而使废气流中的 NO转化成 NO 2。 但是, 一 方面, 由于摩擦造成的压强差通常会在烟道内产生汽蚀和分层现象, 使得该应 用并不能将 NO100%的转化成 N0 2; 另一方面, 在经典气气混合吸引器的应用中 , 需要额外的气体, NO: 0 3为1: 1½ (摩尔比) 以将所有的 NO转化成 NO 2; 此 夕卜, 还需要关注的另一个问题是用于将 NO转化成 NO 2的多余的 0 3可能会发生臭 氧逃逸, 排放到大气中, 而对于 0 3 (臭氧) 有其严格的规定, 任何臭氧逃逸都 有可能违反相关规定。 Mixing with the target contaminant NO in the exhaust stream to convert NO in the exhaust stream to NO 2 . However, on the one hand, the pressure difference caused by friction usually causes cavitation and delamination in the flue, so that the application cannot convert NO100% into N0 2; on the other hand, in the classic gas-mixing aspirator In the application, additional gas is required, NO: 0 3 is 1: 11⁄2 (molar ratio) to convert all NO to NO 2; in addition, another problem that needs attention is to convert NO to NO 2 Excessive 0 3 may cause ozone escaping and discharge into the atmosphere, while there are strict regulations for 0 3 (ozone), and any ozone escaping may violate the relevant regulations.
[0003] 此外, 在经典气气混合吸引器的应用中, 保持恒定压力 (0107)下的原料气体管 可以避免废气流的回吹 (0105) (废气进入原料气体管 (0104)进而流入臭氧设备) 影响。  [0003] In addition, in the application of the classic gas-mixed suction device, the raw material gas pipe at a constant pressure (0107) can be prevented from being blown back (0105) (the exhaust gas enters the raw material gas pipe (0104) and flows into the ozone device. ) influences.
技术问题  technical problem
[0004] 为了克服现有技术中的缺陷, 本发明公幵了一种气气混合吸引器, 将其设计成 流量喷咀管道的形式, 由于气气混合吸引器收缩段 /管和发散段 /管的设计结构, 可以消除汽蚀和分层现象; 汽蚀和分层现象的消除, 使被引入废气流中的 0 3可 以与废气流中的 NO充分接触, 进而将废气流中全部的 NO转化成 NO 2 ; 无需向气 气混合吸引器中引入额外的气体, 将 NO: 0 3按1: 1½ (摩尔比) 就可以将所有 的 NO转化成 NO 2 ; 此外, 在本发明气气混合器中由于皮托管的方向与废气流的 流动相一致, 废气流的流速可对皮托管进料管线造成恒定的吸力, 以将原料气 体引入废气流中, 而无需像经典气气混合吸引器那样使原料气体管保持恒定压 力下。 In order to overcome the deficiencies in the prior art, the present invention discloses a gas-gas mixing aspirator which is designed in the form of a flow nozzle conduit due to the converging section/tube and diverging section of the gas-gas mixing aspirator/ The designed structure of the tube can eliminate cavitation and delamination; the elimination of cavitation and stratification, so that the 0 3 introduced into the exhaust gas stream can fully contact the NO in the exhaust gas stream, and then all the NO in the exhaust gas stream Converted to NO 2 ; no need to gas Additional gas is introduced into the gas mixing aspirator, and all NO can be converted to NO 2 by using NO: 0 3 in a molar ratio ; in addition, in the gas-gas mixer of the present invention, the direction of the pitot tube is The flow of the exhaust stream is consistent, and the flow rate of the exhaust stream provides a constant suction to the pitot tube feed line to introduce the feed gas into the exhaust stream without the need to maintain the feed gas line at a constant pressure like a classical gas-mixed aspirator .
问题的解决方案  Problem solution
技术解决方案  Technical solution
[0005] 本发明是通过如下技术方案实现的: [0005] The present invention is achieved by the following technical solutions:
[0006] 一种气气混合吸引器, 包括: 用于废气流通过的流量喷咀管道, 用于向废气流 中输送反应气体的载气管和无缝管, 及安装在流量喷咀管道上用于使载气管通 过的孔眼结构; 载气管通过孔眼结构从流量喷咀管道的外部延伸到流量喷咀管 道的内部; 无缝管轴向安装, 与载气管的末端连接, 并向废气流的流动方向延 伸, 用于将抽吸的气体输送到废气流中。  [0006] An air-gas mixing aspirator comprising: a flow nozzle pipe for exhaust gas flow, a carrier gas pipe and a seamless pipe for conveying a reaction gas to the exhaust gas flow, and being installed on the flow nozzle pipe The hole structure for passing the carrier gas pipe; the carrier gas pipe extends from the outside of the flow nozzle pipe to the inside of the flow nozzle pipe through the hole structure; the seamless pipe is axially mounted, connected to the end of the carrier gas pipe, and flows to the exhaust gas stream A direction extension for delivering the pumped gas into the exhaust stream.
[0007] 作为一种优选实施方式, 所述流量喷咀管道是由进气管、 收缩管、 气流中间管 、 发散管和出气管组成的, 其中, 气流中间管的半径小于进气管和出气管的半 径, 进气管和出气管的半径相等, 无缝管位于进气管上, 且无缝管的出气口向 进气管下游方向延伸。  [0007] As a preferred embodiment, the flow nozzle pipe is composed of an intake pipe, a shrink pipe, a gas flow intermediate pipe, a diverging pipe and an air outlet pipe, wherein a radius of the gas flow intermediate pipe is smaller than that of the intake pipe and the gas outlet pipe The radius, the radius of the intake pipe and the outlet pipe are equal, the seamless pipe is located on the intake pipe, and the air outlet of the seamless pipe extends toward the downstream of the intake pipe.
[0008] 作为一种优选实施方式, 该气气混合吸引器, 可以包括: 用于废气流通过的流 量喷咀管道, 用于向废气流中输送反应气体的载气管和无缝管, 及均匀分布在 流量喷咀管道同一截面上用于使载气管通过的孔眼结构; 载气管通过等距离分 布的孔眼结构从流量喷咀管道的外部延伸到流量喷咀管道的内部; 长短交错均 匀分布在流量喷咀管道内部的无缝管轴向安装, 与载气管的末端连接, 并向废 气流的流动方向延伸。  [0008] As a preferred embodiment, the gas-gas mixing aspirator may include: a flow nozzle pipe for passing the exhaust gas flow, a carrier gas pipe and a seamless pipe for conveying the reaction gas into the exhaust gas flow, and uniform An eyelet structure distributed on the same section of the flow nozzle pipe for passing the carrier gas pipe; the carrier gas pipe extends from the outside of the flow nozzle pipe to the inside of the flow nozzle pipe through an equidistantly distributed orifice structure; The seamless pipe inside the nozzle pipe is axially mounted, connected to the end of the carrier pipe, and extends in the flow direction of the exhaust gas flow.
[0009] 作为一种优选实施方式, 在无缝管的末端设有一个弯部, 在无缝管进气端附近 设有隔板, 并在隔板和弯部之间的无缝管上设有用于防止无缝管在气气混合吸 引器内滑动的垫圈。  [0009] As a preferred embodiment, a bent portion is provided at the end of the seamless pipe, a partition is provided near the inlet end of the seamless pipe, and a seamless pipe is disposed between the partition and the bent portion. There are washers for preventing the seamless tube from sliding inside the air-mixing aspirator.
[0010] 作为一种优选实施方式, 收缩管侧壁与水平方向所成的夹角范围为 20-70°。  [0010] As a preferred embodiment, the angle between the side wall of the shrink tube and the horizontal direction is 20-70°.
[0011] 作为一种优选实施方式, 无缝管弯部与水平方向所成的夹角为 45°。 [0012] 作为一种优选实施方式, 所述无缝管为皮托管。 [0011] As a preferred embodiment, the angle between the curved portion of the seamless tube and the horizontal direction is 45°. [0012] As a preferred embodiment, the seamless tube is a pitot tube.
[0013] 作为一种优选实施方式, 输送至气气混合吸引器中的包含 NO的废气流与载气 管输送来的 0 3接触, 将 NO转化成 NO 2, 形成包含 NO 2和未转化的 NO的废气流 。 当然, 还可以输送至气气混合吸引器中的包含 SO 2的废气流与 Cl 2接触, 将 SO 2转化成 SCI 2[0013] As a preferred embodiment, the NO-containing exhaust gas stream delivered to the gas-gas mixing aspirator is contacted with the 0 3 transported by the carrier gas pipe to convert NO into NO 2 to form NO 2 and unconverted NO. Exhaust gas flow. Of course, it is also possible to contact the exhaust stream containing SO 2 in the gas-gas mixing aspirator with Cl 2 to convert SO 2 into SCI 2 .
[0014] 作为一种优选实施方式, 载气管与臭氧发生器连通, 臭氧发生器将 0 2转化为 0 [0014] As a preferred embodiment, the carrier gas tube is in communication with the ozone generator, and the ozone generator converts 0 2 to 0.
3。 一方面, 本发明公幵了一种用于将大量臭氧、 氯气和 /或其它气体与大型工业 和发电厂锅炉废气流混合的装置和方法。 该装置和方法包括流量喷咀管道, 设 置在流量喷咀管道内部不同位置和深度的皮托管, 用于引导气体 (如: 臭氧) 进入锅炉废气流来与如 NO (—氧化氮) 这类目标污染物的废气流接触混合, 使 NO与臭氧 0 3接触并发生反应, 从而使 NO转化成 NO 2。 气体或液体流经流量喷 咀管道被描述为一种在不引起熵的增减的情况下流过狭窄幵口的运动。 每当气 体被迫进入管道或烟道吋, 气体分子会因管壁的存在而发生运动方向的偏转。 如果气体的速度远小于声速, 气体的密度将会保持不变, 而流体速度将会增加 。 然而, 当流体速度与声速相近吋, 需考虑气体可压缩性的影响, 气体的密度 将与其所在的位置有关。 同吋, 在考虑流体流经管道或烟道吋的状态的情况吋 , 当流体的流速缓慢降低又缓慢增加后, 流体可恢复至之前的正常的流速状态 吋, 这是一个可逆过程。 3. In one aspect, the present invention discloses an apparatus and method for mixing large amounts of ozone, chlorine, and/or other gases with large industrial and power plant boiler exhaust streams. The apparatus and method include a flow nozzle pipe, a pitot tube disposed at different positions and depths inside the flow nozzle pipe, for guiding a gas (eg, ozone) into the boiler exhaust gas flow and a target such as NO (nitrogen oxide) The exhaust gas stream of the contaminants is contacted and mixed, and NO is brought into contact with ozone 0 3 to react, thereby converting NO into NO 2 . The flow of gas or liquid through the flow nozzle conduit is described as a motion that flows through the narrow jaw without causing an increase or decrease in entropy. Whenever gas is forced into a pipe or flue, the gas molecules will deflect in the direction of motion due to the presence of the pipe wall. If the velocity of the gas is much less than the speed of sound, the density of the gas will remain the same and the velocity of the fluid will increase. However, when the fluid velocity is close to the speed of sound, the effect of gas compressibility should be considered, and the density of the gas will be related to its location. At the same time, in consideration of the state in which the fluid flows through the pipe or the flue enthalpy, when the flow rate of the fluid slowly decreases and slowly increases, the fluid can return to the previous normal flow state 吋, which is a reversible process.
[0015] 另一方面, 在本发明的一个或多个实施例中, 还包括流量计, 可以通过气气混 合吸引器在(0.03ps倒 0.5psi)的微正压条件下, 将气体 (0 3)引导进入废气流, 以 确保气体 (0 3)均匀进入废气流, 并完成这两种气体的混合。 气气混合吸引器安装 在静电除尘器或袋滤捕尘室 (袋式除尘器) 之后的锅炉废气流中, 锅炉废气流 的温度为 150°C-270°C。 混合如臭氧 (0 3)这类参与反应的气体需要一定的停滞吋 间 (约 3秒) , 因此, 气气混合吸引器的安装要考虑停滞吋间这一因素。 在吸引 器中, 气体流经横截面积缩小再扩大的管道, 从而产生流量体积的变化。 当管 道变窄吋, 管内气体的压力将减小。 在这个狭窄流通区域中流体的流速必将提 高, 以保持其连续性。 由于文丘里效应, 皮托管内部会被抽至真空。 [0015] In another aspect, in one or more embodiments of the present invention, a flow meter is further included, and the gas can be gased by a gas-gas mixing aspirator under a micro-positive pressure condition of (0.03 ps inverted 0.5 psi). 3 ) Guide into the exhaust gas flow to ensure that the gas (0 3 ) uniformly enters the exhaust gas flow and complete the mixing of the two gases. The gas-gas mixing aspirator is installed in the boiler exhaust gas flow after the electrostatic precipitator or the bag filter (bag filter), and the temperature of the boiler exhaust gas is 150 ° C - 270 ° C. Mixing a gas such as ozone (0 3 ) that participates in the reaction requires a certain stagnation time (about 3 seconds). Therefore, the installation of the gas-gas mixing aspirator should consider the factor of stagnation. In the aspirator, the gas flows through a pipe whose cross-sectional area is reduced and then enlarged, thereby generating a change in the volume of the flow. As the pipe narrows, the pressure of the gas inside the pipe will decrease. The flow rate of the fluid in this narrow flow area must be increased to maintain its continuity. Due to the Venturi effect, the interior of the pitot tube is drawn to a vacuum.
发明的有益效果 对附图的简要说明 Advantageous effects of the invention Brief description of the drawing
附图说明  DRAWINGS
[0016] 为了更清楚地说明本发明实施例和现有技术中的技术方案, 下面将对实施例或 现有技术描述中所需要使用的附图作简单地介绍, 显而易见地, 下面描述中的 附图仅仅是本发明的一些实施例, 对于本领域普通技术人员来讲, 在不付出创 造性劳动性的前提下, 还可以根据这些附图获得其他的附图。  [0016] In order to more clearly illustrate the embodiments of the present invention and the technical solutions in the prior art, the drawings to be used in the embodiments or the prior art description will be briefly described below, and obviously, in the following description The drawings are only some of the embodiments of the present invention, and other drawings may be obtained from those skilled in the art without departing from the drawings.
[0017] 图 1显示了现有技术中经典气气混合吸引器的装置示意图。  [0017] FIG. 1 shows a schematic view of a device of a prior art classical gas-mixed aspirator.
[0018] 图 2显示了本发明中气气混合吸引器的装置示意图。  2 is a schematic view showing the apparatus of the gas-gas mixing aspirator of the present invention.
[0019] 图 3为一维正激波的示意图。  3 is a schematic diagram of a one-dimensional forward shock wave.
[0020] 图 4为吸引器控制面板示意图。  4 is a schematic diagram of a suction control panel.
[0021] 图 5为吸引器应用到锅炉废气流的示意图。  [0021] FIG. 5 is a schematic illustration of the application of a suction device to a boiler exhaust stream.
本发明的实施方式 Embodiments of the invention
[0022] 为对本发明有更透彻的理解, 下面将结合说明书附图对本发明的具体实施方式 进行详细说明, 并在以下实施例的详细说明中对许多细节进行阐述。 然而, 对 于本领域技术人员而言, 即使没有这些细节描述, 本发明也可以实施。 除此之 夕卜, 本发明并没有对公知常识进行详细的介绍, 以避免因不必要的描述而冗长  [0022] In the following detailed description of the embodiments of the invention, reference to the claims However, it will be apparent to those skilled in the art that the present invention may be practiced without these details. In addition, the present invention does not introduce common knowledge in detail to avoid lengthy descriptions due to unnecessary description.
[0023] 图 2展示了本发明一个或多个实施例中典型气气混合吸引器的侧视图和后视图 。 此外, 本发明的一个或多个实施例中展示的气气混合吸引器是由 304/316L不锈 钢 (0208)制造而成的, 另外, 本发明的一个或多个实施例中的吸引器端部到相邻 收缩段 /管 (0209)的尺寸减少或缩小了约 4英尺。 本发明一个或多个实施例中气气 混合吸引器的收缩段 /管 (0209)到发散段 /管 (0210)之间的距离为 8英尺。 发散段 /管 (0210)的表面积增加恢复到吸引器初始端原来的大小。 本发明流体通过流量喷咀 的运动, 参考 《热力学基础》 是一种关于热力学中一维流体通过流量喷咀的技 术。 此外, 控制体积的动量方程被导出并应用于解决这类相同问题。 声速通过 热力学性质定义, 并提到马赫数对于这种可变的不可压缩流体的重要性。 2 shows a side view and a rear view of a typical gas-mixing aspirator in one or more embodiments of the present invention. Moreover, the gas-gas mixing aspirator shown in one or more embodiments of the present invention is fabricated from 304/316L stainless steel (0208), in addition, the suction end of one or more embodiments of the present invention The size to the adjacent constricted section/tube (0209) is reduced or reduced by about 4 feet. In one or more embodiments of the invention, the distance between the constricted section/tube (0209) of the gas-mixed aspirator to the diverging section/tube (0210) is 8 feet. The surface area of the diverging section/tube (0210) increases back to the original size of the initial end of the aspirator. The movement of the fluid of the present invention through a flow nozzle is referred to as "Technology of Thermodynamics" which is a technique for passing a one-dimensional fluid through a flow nozzle in thermodynamics. In addition, the momentum equations of the control volume are derived and applied to solve such same problems. The speed of sound is defined by thermodynamic properties and mentions the importance of Mach numbers for such variable incompressible fluids.
[0024] 本发明的一个或多个实施例中还公幵了将在吸引器的 0°、 45°、 90°、 135°、 180 。、 225°、 270°和 315°上分别安装皮托管, 其中, 有 4根伸向吸引器中的长皮托管 ( 0211), 其余为 4根伸向吸引器中的短皮托管 (0212)。 这 8根皮托管安装在吸引器 的不同角度, 并长短交错分布。 [0024] Also disclosed in one or more embodiments of the invention are 0°, 45°, 90°, 135°, 180 at the aspirator. . The pitot tubes were installed at 225°, 270° and 315°, respectively, with 4 long pitots (0211) extending into the aspirator and 4 short pitots (0212) extending into the aspirator. These 8 pitot tubes are installed at different angles of the aspirator and are staggered in length.
[0025] 本发明一个或多个实施例中公幵的皮托管是用来测量流动流体中给定点处的局 部流速, 而不是管道或导管中的平均流速。 "管"通常适用于锅炉、 热交换器和仪 器仪表中的管状结构, 而不像管道、 压力管、 机械管 (皮托管) 通常是根据其 制造方法和加工精度 (光洁度) 而划分的。  [0025] The disclosed pitot tube in one or more embodiments of the invention is used to measure the local flow rate at a given point in the flowing fluid, rather than the average flow rate in the conduit or conduit. "Tubes" are generally applied to tubular structures in boilers, heat exchangers, and instrumentation, unlike pipes, pressure pipes, and mechanical pipes (piterons), which are usually classified according to their manufacturing method and processing accuracy (slurry).
[0026] 此外, 由图 2可知在本发明的一个或多个实施例中, 皮托管安装在气气混合吸 引器上, 而隔板配件安装在皮托管的末端自吸引器外表面 1.5英寸(0213)的高度 。 316不锈钢垫圈 (0214)焊接在隔板下的皮托管上, 用于防止皮托管在吸引器上 为皮托管准备的管孔 /孔眼中发生滑动。 隔板始端到 45°弯部的距离为 3英寸 (0215) , 而皮托管 45°弯部 (0216)到末端的距离为 2英寸 (0217)。 管道排布方式为安装到 吸引器上的短皮托管 (0212), 皮托管按顺序分布, 间隔插入吸引器。 当在吸引器 上安装带配件的皮托管吋, 将皮托管安装在吸弓 I器内部朝向废气流方向的 45°弯 部, 使臭氧能跟随废气流一同流动。  In addition, as can be seen from FIG. 2, in one or more embodiments of the present invention, the pitot tube is mounted on the gas-gas mixing aspirator, and the separator fitting is mounted at the end of the pitot tube 1.5 inches from the outer surface of the aspirator ( 0213) The height. The 316 stainless steel washer (0214) is welded to the pitot under the bulkhead to prevent slippage of the pits/holes prepared for the pitot tube on the suction. The distance from the beginning of the baffle to the 45° bend is 3 inches (0215), while the distance from the pitot 45° bend (0216) to the end is 2 inches (0217). The pipe arrangement is a short pitot tube (0212) mounted to the aspirator, which is distributed in sequence and inserted into the aspirator at intervals. When a pitot tube with fittings is installed on the aspirator, the pitot tube is mounted in a 45° bend inside the suction tube toward the exhaust gas flow so that the ozone can flow along with the exhaust gas flow.
[0027] 此外, 由图 2可知在本发明的一个或多个实施例中, 长皮托管和短皮托管的安 装方式相似, 而隔板配件安装在皮托管的末端自吸引器外表面 1.5英寸(0218)的 高度。 316不锈钢垫圈 (0219)焊接在隔板下的皮托管上, 用于防止皮托管在吸引 器上为皮托管准备的管孔 /孔眼而发生滑动。 隔板始端到 45°弯部的距离为 1英尺 零 4英寸 (0220), 而皮托管 45°弯部 (0221)到末端的距离为 2英寸 (0223)。 管道排布 方式为安装到吸引器上的长皮托管 (0211), 皮托管按顺序分布, 间隔插入吸引器 。 当在吸引器上安装带配件的皮托管吋, 将皮托管安装在吸引器内部朝向废气 流方向的 45°弯部, 使臭氧能跟随废气流一同流动。  [0027] Furthermore, it can be seen from FIG. 2 that in one or more embodiments of the present invention, the long pitot tube and the short pitot tube are installed in a similar manner, and the baffle fitting is mounted at the end of the pitot tube 1.5 inches from the outer surface of the aspirator. The height of (0218). The 316 stainless steel washer (0219) is welded to the pitot under the bulkhead to prevent the pitot tube from slipping on the suction tube/hole for the pitot tube. The distance from the beginning of the bulkhead to the 45° bend is 1 foot to 4 inches (0220), while the distance from the pitot 45° bend (0221) to the end is 2 inches (0223). The pipe is arranged as a long pitot tube (0211) mounted on the aspirator, and the pitot tubes are distributed in order, with the suction device inserted at intervals. When a pitot tube with fittings is installed on the aspirator, the pitot tube is installed in a 45° bend in the direction of the exhaust gas flow inside the aspirator so that the ozone can flow along with the exhaust gas stream.
[0028] 此外, 如图 2所示在本发明的一个或多个实施例中, 废气流 (0224)和被吸入到废 气流中的次要气体流经气气混合吸弓 I器。 可通过弓 I入等熵滞止状态概念以及与 此相关的性质, 来简化很多关于流体问题的论证和方程式。 等熵滞止状态是一 种物质在可逆绝热过程中减速为零吋, 将会达到的状态。  Further, as shown in FIG. 2, in one or more embodiments of the present invention, the exhaust gas stream (0224) and the secondary gas sucked into the exhaust gas stream flow through the gas-gas mixture suction device. Many of the arguments and equations for fluid problems can be simplified by incorporating the concept of isentropic stagnation states and the properties associated with them. The isentropic stagnation state is the state that a substance will decelerate to zero during the reversible adiabatic process.
[0029] 喷咀是一种可使其中物质的动能在绝热状态下增加的装置。 动能的增加是通过 压力的降低和流通面积的适当改变实现的。 扩散器是一个具有相反功能的设备 , 即, 通过降低物质的速度来增加压力。 为了最大限度的使术语简单统一化, 以后部分将喷咀和扩散器都称之为喷咀。 [0029] A nozzle is a device that allows the kinetic energy of a substance to increase in an adiabatic state. The increase in kinetic energy is passed The reduction in pressure and the appropriate change in the flow area are achieved. A diffuser is a device that has the opposite function, that is, increases the pressure by reducing the velocity of the substance. In order to maximize the terminology of the term, the nozzle and the diffuser are referred to as nozzles in the future.
[0030] 在本发明的一个或多个实施例中, 将讨论冲击波是一种状态会发生极其迅速且 突然的变化的一种波。 在正激波中, 这种变化常发生在与流动方向垂直的横截 面处。 图 3显示的为包含正激波 (0326)的正常操纵面 (0325)。 我们现在可以确定掌 管流体流动的关系式。 假定这是一个稳态、 稳流过程, 可以写出如下关系式, 式中的下标 X(0327)和 Y(0328)分别表示上游 (0329)和下游冲击波。  [0030] In one or more embodiments of the invention, a shock wave is a wave in which a state undergoes an extremely rapid and abrupt change. In a positive shock wave, this change often occurs at a cross section perpendicular to the flow direction. Figure 3 shows the normal control surface (0325) containing the positive shock (0326). We can now determine the relationship governing fluid flow. Assuming that this is a steady-state, steady-state process, the following relationship can be written, where the subscripts X(0327) and Y(0328) represent the upstream (0329) and downstream shockwaves, respectively.
[0031] 第一定律:
Figure imgf000008_0001
[0031] The first law:
Figure imgf000008_0001
[0032] 连续性方程:
Figure imgf000008_0002
[0032] continuity equation:
Figure imgf000008_0002
[0033] 动量方程:
Figure imgf000008_0003
[0033] Momentum equation:
Figure imgf000008_0003
[0034] 值得注意的是, 该关系式是在操纵面 (0330)上没有热量传递和做功的条件下成 立的。  [0034] It is worth noting that the relationship is established on the control surface (0330) without heat transfer and work.
[0035] 总之, 需要指出的是, 前面所考虑的正激波, 都是在忽略了粘度和导热系数影 响的情况下进行的。 而实际的正激波具有一定的厚度。 然而, 这里给出了正激 波一个很好的性质说明给出了一个相当准确的量化结果。  [0035] In summary, it should be noted that the forward shocks considered above were all carried out with the influence of viscosity and thermal conductivity being neglected. The actual positive shock has a certain thickness. However, a good property description of the positive shock is given here to give a fairly accurate quantitative result.
[0036] 现在我们要考虑的蒸汽是作为一种以气相存在但有一定程度上的过热的物质。  [0036] The steam we are considering now is a substance that exists in the gas phase but has some degree of superheat.
因此, 蒸汽很可能与理想气体之间存在很大的偏差, 蒸汽易发生冷凝这一性质 一定要考虑到。 如: 通过锅炉烟道喷咀的热烟气。  Therefore, steam is likely to have a large deviation from the ideal gas, and the nature of steam condensing must be considered. Such as: Passing hot flue gas from the boiler flue nozzle.
[0037] 为了对本发明有更透彻的理解, 在以下本发明实施例的详细说明中, 将会对许 多细节进行阐述。 然而, 对于本领域技术人员来讲, 即使没有这些细节的阐述 , 本发明也可以实施。 除此之外, 本发明并没有对公知常识进行详细的介绍, 以避免因不必要描述而复杂化。 [0037] In the following detailed description of the embodiments of the invention, in the claims However, it will be apparent to those skilled in the art that the present invention may be practiced without these details. In addition, the present invention does not provide a detailed introduction to common knowledge. To avoid complications due to unnecessary description.
[0038] 在一般情况下, 通过本发明的实施例公幵了一种用于将一种气体与另一种气体 混合的设备和方法。 更具体地说, 通过本发明的一个或多个实施例公幵了一种 将如 0 3这类气体与锅炉废气流混合来达到使 0 3与锅炉废气流中 NO接触的目的 。 本发明还公幵了将废气流中的 NO转化成 NO 2, 并引入 H 20将生成物冷凝形成 硝酸。 [0038] In general, an apparatus and method for mixing one gas with another is disclosed by way of embodiments of the present invention. More specifically, it is disclosed by one or more embodiments of the present invention that a gas such as 03 is mixed with a boiler exhaust stream to achieve the purpose of contacting 03 with NO in the boiler exhaust stream. The present invention also discloses the conversion of NO in the exhaust stream to NO 2 and the introduction of H 2 0 to condense the product to form nitric acid.
[0039] 根据本发明的一个或多个实施例可以看出, 气体与气体混合设备 (吸引器) 包 括流量喷咀管道, 可以由但并不仅限于金属, 如不锈钢制成的发散型和收缩型 设备。 为了使气体充分混合, 将皮托管分布在流量喷咀管道的 8个不同方向上。 此外, 在本发明的一个或多个实施例中, 流量计直接引导气体 (0 3)进入吸引器, 并均匀分布到锅炉废气流中。 尽管本发明所公幵的实施例中的指明了流量计的 数量和按特定顺序组合的气气混合吸引器, 但流量计的顺序或数量并不仅限于 本发明所公幵的这些布局排列形式。 本领域的技术人员应该了解, 在不脱离本 发明公幵范围的情况下, 流量计数量和顺序的任何改变都是允许的。 例如: 在 设备中使用任何数量的皮托管、 流量计、 控制阀都不脱离本发明所公幵的范围 。 因此, 本发明一个或多个实施例中所公幵的灵活性强、 模块化的装置, 可适 用于从不同类型的工业废气流的气体混合应用。 [0039] According to one or more embodiments of the present invention, it can be seen that the gas and gas mixing device (sucker) includes a flow nozzle pipe, which can be made of, but not limited to, a metal such as stainless steel, a divergent type and a contracted type. device. In order to mix the gases thoroughly, the pitot tubes are distributed in eight different directions of the flow nozzle tubes. Moreover, in one or more embodiments of the invention, the flow meter directs the gas (0 3 ) into the aspirator and is evenly distributed into the boiler exhaust stream. Although the number of flow meters and the gas-gas mixing aspirator combined in a particular order are indicated in the embodiments of the present invention, the order or number of flow meters is not limited to these layout arrangements as disclosed in the present invention. Those skilled in the art will appreciate that any change in the number and sequence of flow meters is permissible without departing from the scope of the present disclosure. For example: The use of any number of pitot tubes, flow meters, control valves in the apparatus does not depart from the scope of the present disclosure. Thus, the flexible, modular device disclosed in one or more embodiments of the present invention is applicable to gas mixing applications from different types of industrial exhaust streams.
[0040] 本发明一个或多个实施例中的气气混合吸引器能够将产自于工业厂房废气中的 污染物 (如氮氧化物) 进行转化, 这里的工业厂房涉及到多个市场领域的加工 和制造业, 包括但不限于食品加工和包装、 纸浆和造纸、 印刷、 化工及相关产 品、 橡胶、 塑料、 医院、 大学、 金属工业、 药品生产、 废水和污水处理、 饮料 、 公用事业、 焚烧、 钢铁、 化妆品、 纺织品、 电子产品和石油精炼。  [0040] The gas-gas mixing aspirator in one or more embodiments of the present invention is capable of converting pollutants (such as nitrogen oxides) produced in industrial plant exhaust gas, where the industrial plant involves multiple market segments. Processing and manufacturing, including but not limited to food processing and packaging, pulp and paper, printing, chemicals and related products, rubber, plastics, hospitals, universities, metal industry, pharmaceutical production, wastewater and sewage treatment, beverages, utilities, incineration , steel, cosmetics, textiles, electronics and petroleum refining.
[0041] 为了除去不需要的和 /或目标污染物, 如 NO和 SO 2, 需要借助某些反应才能实 现。 下面介绍了一些用于除去废气中这些污染物的反应和方法。 [0041] In order to remove unwanted and/or target contaminants such as NO and SO 2 , some reaction is required to achieve this. Some reactions and methods for removing these contaminants from the exhaust gases are described below.
[0042] NO+0 3  [0042] NO+0 3
[0043] NO x是一氧化氮 (NO)和二氧化氮 (NO 2)的总称。 NO和 NO 2都是由燃烧过程中空 气中的氮和氧发生反应而形成的。 NO 2可以通过将 NO 2与水、 水蒸汽或烟气流 中的蒸汽接触生成废水, 然后再将废水收集并弓 I流至废水处理厂进行中和处理 。 由于 NO不能通过与水接触的方式除去, 因此, 需要将 NO通过化学反应转化成 NO 2, 这种转化可以通过在废气中通入臭氧 (0 3)而发生如下反应: [0043] NO x is nitric oxide (NO) and nitrogen dioxide (NO 2) in general. Both NO and NO 2 are formed by the reaction of nitrogen and oxygen in the air during combustion. NO 2 can form wastewater by contacting NO 2 with steam in water, steam or flue gas stream, and then collect the wastewater and flow it to the wastewater treatment plant for neutralization. . Since NO cannot be removed by contact with water, it is necessary to convert NO into a NO 2 by a chemical reaction which can be reacted by introducing ozone (0 3 ) into the exhaust gas as follows:
[0044] NO + 0 3→ NO 2 + 0 2 NO + 0 3→ NO 2 + 0 2
Figure imgf000010_0001
Figure imgf000010_0001
[0046] 二氧化硫 (SO 2)和氯气 (CI 2)是两种广泛用于各行各业的气体, 由于这两种气体 反应生成的主要产物为磺酰氯, 这是一种有毒的发烟液体, 因此, 这两种气体 很少一起加入作为反应物。 然而, 在适当的条件下, 这两种气体混合也可以生 成硫酸。 在本发明的一个或多个实施例中, 图 4展示的是气气混合吸引器的控制 面板, 其中, 控制面板 (0431)是由不锈钢或喷漆钢制成的, 用于防止灰尘、 光和 间接飞溅, 从而使其具有耐候、 防尘、 防爆作用。 此外, 在本发明的一个或多 个实施例中, 气气混合吸引器内设有 8个手动流量计 (0432), 而每个流量计以手 动调节的形式向每个管路 (0436)中供应微正压气体 (0 3), 并将气体引入吸引器以 使气体充分混合。 此外, 在本发明的一个或多个实施例中, 在流量计上边或下 边安装有手动截止阀 (0433), 用于方便更换损坏的流量计。 控制面板中的控制阀 (0435)安装在流量计的下方, 用于向流量计供应主气体。 控制阀 (0435)是常闭阀 , 只有当需要气体供应吋才打幵。 控制阀 (0435)不是调节阀, 只能用于装置的幵 启或关闭, 而流量计可控制进入吸引器气体的流量。 本发明还设有泄压阀 (0434) , 当主气体进入控制面板吋, 用于清除管线中所残余的气体。 [0046] Sulfur dioxide (SO 2 ) and chlorine (CI 2 ) are two gases widely used in various industries. The main product produced by the reaction of these two gases is sulfonyl chloride, which is a toxic fuming liquid. Therefore, these two gases are rarely added together as a reactant. However, under appropriate conditions, the mixing of the two gases can also produce sulfuric acid. In one or more embodiments of the present invention, FIG. 4 shows a control panel of a gas-mixing aspirator, wherein the control panel (0431) is made of stainless steel or painted steel to prevent dust, light, and Indirect splashing, making it weatherproof, dustproof, and explosion proof. Moreover, in one or more embodiments of the present invention, eight manual flow meters (0432) are provided in the gas-gas mixing aspirator, and each flow meter is manually adjusted to each of the lines (0436) A micro-positive pressure gas (0 3 ) is supplied and the gas is introduced into the aspirator to allow the gas to be thoroughly mixed. Further, in one or more embodiments of the present invention, a manual shut-off valve (0433) is mounted on the bottom or bottom of the flow meter for facilitating replacement of the damaged flow meter. A control valve (0435) in the control panel is mounted below the flow meter for supplying the main gas to the flow meter. The control valve (0435) is a normally closed valve that only slams when a gas supply is required. The control valve (0435) is not a regulating valve and can only be used for the opening or closing of the device, while the flow meter controls the flow of gas into the aspirator. The present invention also features a pressure relief valve (0434) for removing residual gases from the line as the primary gas enters the control panel.
[0047] 在本发明的一个或多个实施例中, 图 5为适用于锅炉废气流的气气混合吸引器 , 图中显示了产生废气流的典型燃煤锅炉。 此外, 根据本发明的一个或多个实 施例可知, 锅炉 (0538)内的燃烧器接收定量的经预热燃烧空气和燃料, 从而实现 燃烧过程, 产生废气流。 从锅炉 (0538)幵始, 废气流通过金属材质的烟道 (0539) 从锅炉中引导出来, 依次流经空气加热器 (0540)和静电除尘器 ESP(0541)。 此外 , 在本发明的一个或多个实施例中, 在静电除尘器 ESP(0541)将废气流中所有大 颗粒的飞灰和颗粒物除去后, 废气流被送至气气混合吸引器 (0542)。  In one or more embodiments of the invention, FIG. 5 is a gas-gas mixing aspirator suitable for use in a boiler exhaust stream, and a typical coal-fired boiler that produces an exhaust gas stream is shown. Moreover, in accordance with one or more embodiments of the present invention, the combustor within the boiler (0538) receives a quantity of preheated combustion air and fuel to effect a combustion process to produce an exhaust stream. From the beginning of the boiler (0538), the exhaust stream is directed from the boiler through a metal flue (0539), which in turn flows through the air heater (0540) and the electrostatic precipitator ESP (0541). Further, in one or more embodiments of the present invention, after the electrostatic precipitator ESP (0541) removes all of the large particles of fly ash and particulate matter in the exhaust stream, the exhaust stream is sent to the gas-gas mixing aspirator (0542) .
[0048] 在本发明的一个或多个实施例中, 气气混合吸弓 I器 (0542)将臭氧 (0 3)和废气流 进行混合, 从而使 NO转化成 NO 2[0048] In one or more embodiments of the invention, the gas-gas mixing device (0542) mixes the ozone (0 3 ) with the exhaust gas stream to convert NO to NO 2 .
[0049] 氧化还原反应 (参考: 基础化学, 化学概念方法, 第四版) 中的"氧化反应"最 初指的是物质与氧化合的反应, 而"还原反应"是指去除含氧化合物中氧的反应。 随着认识的不断加深, 关于"氧化反应"和"还原反应"的含义也在逐渐扩大。 氧化 反应是原子氧化值升高的过程, 而还原反应指的是原子氧化值降低的过程。 从 氧化值的分配原则可以很明显的看出, 氧化反应与还原反应均不会单独发生。 [0049] The oxidation reaction in the redox reaction (Reference: Basic Chemistry, Chemical Concept Method, Fourth Edition) The initial refers to the reaction of the substance with the oxidation, and the "reduction reaction" refers to the reaction of removing the oxygen in the oxygenate. As the understanding continues to deepen, the meaning of "oxidation reaction" and "reduction reaction" is gradually expanding. The oxidation reaction is a process in which the atomic oxidation value is increased, and the reduction reaction refers to a process in which the atomic oxidation value is lowered. It can be clearly seen from the principle of distribution of oxidation values that neither the oxidation reaction nor the reduction reaction occurs separately.
[0050] 此外, 氧化值的总增加量始终等于氧化值的总减少量。 由于一种物质不可能被 还原, 除非另一种物质同吋被氧化, 被还原的物质发生氧化反应, 被称之为氧 化剂。 由于氧化和还原这两个过程是相互依存的, 相反也是如此, 即被氧化的 物质被称之为还原剂。  [0050] Furthermore, the total increase in the oxidation value is always equal to the total reduction in the oxidation value. Since one substance cannot be reduced, unless the other substance is oxidized, the reduced substance undergoes an oxidation reaction, which is called an oxidizing agent. Since the two processes of oxidation and reduction are interdependent, the opposite is true, that is, the substance to be oxidized is called a reducing agent.
[0051] 氧化-还原反应的方程通常比那些不涉及氧化-还原反应的方程更难配平。 通常 采用氧化值法和离子 /电子法这两种方法来配平氧化 -还原方程。  [0051] The equations for oxidation-reduction reactions are generally more difficult to trim than those that do not involve oxidation-reduction reactions. The oxidation-reduction equation is usually balanced by the oxidation method and the ion/electron method.
[0052] 即使在 3000°C下, NO的产率也仅为 4%左右。 一个好的 NO制备方法, 须将反应 生成的热气体快速冷却以阻止 NO分解成 Ν ^Π0 2。 通过该反应, 大气中的 N 2在 闪电的作用下进行固定, 该反应还可以通过电弧工艺来为 Ν 2和0 2结合提供所必 需高温环境, 进而达到固氮的目的。 [0052] Even at 3000 ° C, the yield of NO is only about 4%. A good NO preparation method, the hot gas generated by the reaction must be rapidly cooled to prevent the decomposition of NO into Ν^Π0 2 . Through this reaction, N 2 in the atmosphere is fixed by the action of lightning, and the reaction can also provide the necessary high temperature environment for the combination of Ν 2 and 0 2 by the arc process, thereby achieving the purpose of nitrogen fixation.
[0053] 在本发明的一个或多个实施例中, 图 5中的臭氧是由生产臭氧的臭氧发生器 (05 43)提供的。 氧气供应单元 (0544)的出口通过一系列管道、 配件和控制阀 (0545)连 通至臭氧发生器上。 控制阀 (0545)控制供给臭氧发生器 (0543)的氧气流量, 并调 节锅炉系统, 以使氧气供应单元 (0544)供给臭氧发生器 (0543)适量的氧气。  [0053] In one or more embodiments of the invention, the ozone in Figure 5 is provided by an ozone generator (05 43) that produces ozone. The outlet of the oxygen supply unit (0544) is connected to the ozone generator via a series of pipes, fittings and control valves (0545). The control valve (0545) controls the flow of oxygen to the ozone generator (0543) and adjusts the boiler system so that the oxygen supply unit (0544) supplies the ozone generator (0543) with an appropriate amount of oxygen.
[0054] 在本发明的一个或多个实施例中, 氧气 (0 2)进入臭氧发生器 (0543), 在高压电 荷的轰击作用下, 部分 0 2转化成 0 3 (臭氧) 。 由于臭氧发生器 (0543)容器内连 续高压电荷的轰击, 将会产生大量热量耗散需要冷却, 以使容器内的臭氧的温 度维持在环境温度附近。 大多数臭氧发生器内部都设有用于维持所需温度的冷 却系统, 冷却系统通过冷却水供应单元 (0546)将冷却水送出, 并将冷却水引流至 冷却塔 (0547), 冷却水在冷却塔内降温后又作为冷却回水通过回水管 (0548)回流 至臭氧发生器 (0543)的冷却系统, 冷却后的冷却回水用于协助冷却系统冷却工作 的正常进行。 [0054] In one or more embodiments of the invention, oxygen (0 2 ) enters the ozone generator (0543), and under the action of high-pressure charge bombardment, a portion of 0 2 is converted to 0 3 (ozone). Due to the continuous high-pressure charge bombardment in the ozone generator (0543) vessel, a large amount of heat dissipation will be required to cool, so that the temperature of the ozone in the vessel is maintained near ambient temperature. Most ozone generators are internally provided with a cooling system for maintaining the required temperature. The cooling system sends cooling water through the cooling water supply unit (0546), and drains the cooling water to the cooling tower (0547). The cooling water is in the cooling tower. After the internal temperature is lowered, it is returned to the cooling system of the ozone generator (0543) through the return pipe (0548) as cooling cooling water, and the cooled cooling water is used to assist the normal operation of the cooling system cooling work.
[0055] 在本发明的一个或多个实施例中, 产生的臭氧 (0 3)通过一系列的管道和配件进 入气气混合吸弓 I器控制面板 (0549)。 在气气混合吸弓 I器控制阀 (0551)打幵之前, 将臭氧 (O 3)清除以消除系统中所有的气体。 一旦将气气混合吸引器控制阀 (0551) 打幵, 臭氧 (0 3)将通过一系列的流量计 (0552)进入气气混合吸引器。 [0055] In one or more embodiments of the invention, the generated ozone (0 3 ) enters the gas-mixing suction control panel (0549) through a series of pipes and fittings. Before the air-mixing suction control device (0551) is snoring, Ozone (O 3 ) is removed to remove all gases from the system. Once the gas-mixed aspirator control valve (0551) is snoring, ozone (0 3 ) will enter the gas-gas mixing aspirator through a series of flow meters (0552).
[0056] 在本发明的一个或多个实施例中, 流量计 (0552)以手动调整的形式向每个管路 中输送 0.03-0.05psi的微正压。 从流量计 (0552)输出的臭氧通过一系列管路 (0553) 送至气气混合吸弓 I器 (0542), 将臭氧 (0 3 [0056] In one or more embodiments of the invention, the flow meter (0552) delivers a micro-positive pressure of 0.03-0.05 psi to each of the lines in a manually adjusted configuration. The ozone output from the flow meter (0552) is sent to the gas-mixing suction bow I (0542) through a series of lines (0553) to treat the ozone (0 3
)和废气流进行混合, 从而使 NO转化成 NO 2And mixing with the exhaust stream to convert NO to NO 2 .
[0057] 根据定义, 动力学区域 (the kinetic region) 是反应组份浓度不断发生变化的期 间, 平衡区域是指在此之后, 反应组分的浓度不发生进一步的变化, 反应看似 停止的期间。 [0057] By definition, the kinetic region is a period in which the concentration of the reaction component is constantly changing, and the equilibrium region is a period in which the concentration of the reaction component does not change further, and the reaction appears to be stopped. .
[0058] 气体与锅炉废气流混合后引流至其他设备 (0554) 来去除废气中已转化完成的 N [0058] The gas is mixed with the boiler exhaust stream and then drained to other equipment (0554) to remove the converted N in the exhaust gas.
0 2。 对于本领域的技术人员来讲, 技术在没有这些细节的情况下, 本发明也是 可以实施的。 在其他实施例中, 并没有对一些公知常识进行再介绍, 以避免不 必要的复杂描述。 0 2 . It will be apparent to those skilled in the art that the present invention may be practiced without these details. In other embodiments, some common general knowledge has not been re-introduced to avoid unnecessary complicated descriptions.
[0059] 以上显示和描述了本发明的基本原理、 主要特征和本发明的优点。 本行业的技 术人员应该了解, 本发明不受上述实施例的限制, 上述实施例和说明书中描述 的只是本发明的原理, 在不脱离本发明精神和范围的前提下本发明还会有各种 变化和改进, 这些变化和改进都落入要求保护的本发明的范围内。 本发明要求 的保护范围由所附的权利要求书及其等同物界定。  The basic principles, main features, and advantages of the present invention are shown and described above. It should be understood by those skilled in the art that the present invention is not limited by the foregoing embodiments, and that the present invention is described in the foregoing embodiments and the description of the present invention. Variations and modifications are intended to fall within the scope of the invention as claimed. The scope of the invention is defined by the appended claims and their equivalents.

Claims

权利要求书 Claim
[权利要求 1] 一种气气混合吸引器, 其特征包括: 用于废气流通过的流量喷咀管道 [Claim 1] An air-gas mixing aspirator characterized by: a flow nozzle pipe for exhaust gas flow
, 用于向废气流中输送反应气体的载气管和无缝管, 及安装在流量喷 咀管道上用于使载气管通过的孔眼结构; 载气管通过孔眼结构从流量 喷咀管道的外部延伸到流量喷咀管道的内部; 无缝管轴向安装, 与载 气管的末端连接, 并向废气流的流动方向延伸, 用于将抽吸的气体输 送到废气流中。 a carrier gas pipe and a seamless pipe for conveying the reaction gas into the exhaust gas stream, and an orifice structure installed on the flow nozzle pipe for passing the carrier gas pipe; the carrier gas pipe extending from the outside of the flow nozzle pipe through the hole structure to The inside of the flow nozzle pipe; the seamless pipe is axially mounted, connected to the end of the carrier gas pipe, and extends in the flow direction of the exhaust gas flow for conveying the sucked gas into the exhaust gas stream.
[权利要求 2] 如权利要求 1所述的气气混合吸引器, 其特征在于: 所述流量喷咀管 道是由进气管、 收缩管、 气流中间管、 发散管和出气管组成的, 其中 , 气流中间管的半径小于进气管和出气管的半径, 进气管和出气管的 半径相等, 无缝管位于进气管上, 且无缝管的出气口向进气管下游方 向延伸。  [Claim 2] The gas-gas mixing aspirator according to claim 1, wherein: the flow nozzle pipe is composed of an intake pipe, a shrink pipe, a gas flow intermediate pipe, a diverging pipe, and an air outlet pipe, wherein The radius of the middle pipe of the air flow is smaller than the radius of the intake pipe and the air outlet pipe, the radius of the intake pipe and the air outlet pipe are equal, the seamless pipe is located on the intake pipe, and the air outlet of the seamless pipe extends to the downstream direction of the intake pipe.
[权利要求 3] 如权利要求 1所述的气气混合吸引器, 其特征在于包括: 用于废气流 通过的流量喷咀管道, 用于向废气流中输送反应气体的载气管和无缝 管, 及均匀分布在流量喷咀管道同一截面上用于使载气管通过的孔眼 结构; 载气管通过等距离分布的孔眼结构从流量喷咀管道的外部延伸 到流量喷咀管道的内部; 长短交错均匀分布在流量喷咀管道内部的无 缝管轴向安装, 与载气管的末端连接, 并向废气流的流动方向延伸。  [Claim 3] The gas-gas mixing aspirator according to claim 1, comprising: a flow nozzle pipe for passing the exhaust gas flow, a carrier gas pipe and a seamless pipe for conveying the reaction gas to the exhaust gas flow And an eyelet structure uniformly distributed on the same section of the flow nozzle pipe for passing the carrier gas pipe; the carrier gas pipe extends from the outside of the flow nozzle pipe to the inside of the flow nozzle pipe through an equidistantly distributed orifice structure; The seamless pipe distributed inside the flow nozzle pipe is axially mounted, connected to the end of the carrier gas pipe, and extends in the flow direction of the exhaust gas flow.
[权利要求 4] 如权利要求 3所述的气气混合吸引器, 其特征在于: 在无缝管的末端 设有一个弯部, 在无缝管进气端附近设有隔板, 并在隔板和弯部之间 的无缝管上设有用于防止无缝管在气气混合吸弓 I器内滑动的垫圈。  [Claim 4] The gas-gas mixing aspirator according to claim 3, wherein: a bent portion is provided at an end of the seamless pipe, and a partition is provided near the inlet end of the seamless pipe, and is separated A gasket for preventing the seamless tube from sliding in the gas-mixing suction device is provided on the seamless tube between the plate and the bent portion.
[权利要求 5] 如权利要求 3所述的气气混合吸引器, 其特征在于: 收缩管侧壁与水 平方向所成的夹角范围为 20-70°。  [Claim 5] The gas-gas mixing aspirator according to claim 3, wherein the angle between the side wall of the shrink tube and the horizontal direction is 20-70.
[权利要求 6] 如权利要求 3所述的气气混合吸引器, 其特征在于: 无缝管弯部与水 平方向所成的夹角为 45°。  [Claim 6] The gas-air mixing aspirator according to claim 3, wherein the angle between the curved portion of the seamless tube and the horizontal direction is 45°.
[权利要求 7] 如权利要求 1-6中任一所述的气气混合吸引器, 其特征在于: 所述无 缝管为皮托管。  [Claim 7] The gas-gas mixing aspirator according to any one of claims 1 to 6, wherein the seamless tube is a pitot tube.
[权利要求 8] 如权利要求 1-3中任一所述的气气混合吸引器, 其特征在于: 输送至 气气混合吸引器中的包含 NO的废气流与载气管输送来的 O 3 [Claim 8] The gas-gas mixing aspirator according to any one of claims 1 to 3, wherein: The exhaust gas stream containing NO in the gas-gas mixing aspirator and the O 3 conveyed by the carrier gas pipe
接触, 将 NO转化成 NO 2, 形成包含 NO 2和未转化的 NO的废气流。 In contact, NO is converted to NO 2 to form an exhaust stream comprising NO 2 and unconverted NO.
[权利要求 9] 如权利要求 1-3中任一所述的气气混合吸引器, 其特征在于: 输送至 气气混合吸引器中的包含 SO 2的废气流与 C1 2接触, 将 SO 2转化成 SCI [Claim 9] The gas-gas mixing aspirator according to any one of claims 1 to 3, wherein: the exhaust gas stream containing SO 2 delivered to the gas-gas mixing aspirator is in contact with C1 2 to form SO 2 Converted to SCI
[权利要求 10] 如权利要求 8所述的气气混合吸引器, 其特征在于: 载气管与臭氧发 生器连通, 臭氧发生器将 0 2转化为 0 3[Claim 10] The gas-gas mixing aspirator according to claim 8, wherein: the carrier gas pipe is in communication with the ozone generator, and the ozone generator converts 0 2 into 0 3 .
PCT/CN2017/107227 2016-10-28 2017-10-23 Gas-gas mixed aspirator WO2018077127A1 (en)

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