WO2018036294A1 - Composition pesticide - Google Patents

Composition pesticide Download PDF

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Publication number
WO2018036294A1
WO2018036294A1 PCT/CN2017/092640 CN2017092640W WO2018036294A1 WO 2018036294 A1 WO2018036294 A1 WO 2018036294A1 CN 2017092640 W CN2017092640 W CN 2017092640W WO 2018036294 A1 WO2018036294 A1 WO 2018036294A1
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WO
WIPO (PCT)
Prior art keywords
composition
thiabendazole
azoxystrobin
active component
active ingredient
Prior art date
Application number
PCT/CN2017/092640
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English (en)
Chinese (zh)
Inventor
仲汉根
季自华
季红进
季定根
Original Assignee
江苏辉丰农化股份有限公司
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Publication of WO2018036294A1 publication Critical patent/WO2018036294A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof

Definitions

  • the invention is mainly applied to the field of agricultural plant protection, and is a composition of a plant growth regulator and a bactericide, comprising an active ingredient thifenone and a methoxy acrylate pesticide.
  • Pyraclostrobin is a new type of high-efficiency plant growth regulator. When thidiazepine is absorbed by plants, it can promote the separation of the petioles and stems, thus promoting the shedding of mature leaves. At higher concentrations, it can stimulate the formation of ethylene. Promotes the activity of pectin and cellulase. Under low concentration conditions, it has an cytokines effect and can induce plant callus differentiation and bud emergence.
  • the structure is as follows:
  • the methoxy acrylate fungicide belongs to Qols (Qonespirationinhibi.tons) and is a biomimetic synthetic analogue of natural fungal metabolites. It is a kind of low toxicity, high activity, broad spectrum, systemic fungicide with protection. The role of treatment, eradication. They have good activity against Ascomycetes, Basidiomycetes, Deuteromycetes and Oomycetes, and can control diseases such as powdery mildew, rust, downy mildew and rice blast of various crops.
  • This kind of compound mainly inhibits the mitochondrial respiration by inhibiting the electron transfer between the cytochrome b and c1 of the pathogenic fungus, interferes with the energy supply of the cell, and exerts a bactericidal action, and can be sprayed on the leaf surface or seeded.
  • Azoxystrobin is a highly effective, broad-spectrum fungicide for almost all fungal communities (Ascomycota, Basidiomycotina, Flagellate, and Deuteromyces) diseases such as powdery mildew, rust, and sclerotium. Net spot disease, downy mildew, rice blast, etc. have good activity. It can be used for stem and leaf spray, seed treatment, and soil treatment. It is mainly used for cereals, rice, peanuts, grapes, potatoes, fruit trees, vegetables, coffee, lawns, etc.
  • the azoxystrobin structure is as follows:
  • Pyridoxal is a systemic fungicide with a broad spectrum of control targets, mainly used to control foliar diseases such as leaf blight of wheat. Leaf rust, wing blight, brown spot, powdery mildew, etc. Pyridoxine is a mitochondrial respiratory inhibitor that inhibits mitochondrial respiration by electron transfer between cytochrome b and C1. It is effective to control strains which are resistant to 14-demethylase inhibitors, benzamides, tricarboxamides and benzimidazoles.
  • the picoxystrobin moves in the xylem and flows with the water flow in the transport system; it also flows in the gas phase of the surface of the blade and flows into the xylem as it is absorbed into the blade from the gas phase.
  • the crops treated with oxystrobin [250g(ai)/hm2] under no rain conditions and the crops treated for 2 hours after the same spray treatment were exposed to rainfall of 10 mm for up to 1 h, and the results showed that the two were on barley leaves.
  • the control effect of blight is consistent. It is because of the systemic activity and fumigation activity of picoxystrobin that the active ingredient can be effectively redistributed and fully delivered after application. Therefore, oxystrobin is better than commercial azoxystrobin and trifloxystrobin.
  • Therapeutic activity Suitable for crops and safe wheat such as wheat, barley, oats and rye; safe and non-toxic to crops at the recommended dosage.
  • picoxystrobin The structure of picoxystrobin is:
  • Pyraclostrobin is a new broad-spectrum fungicide.
  • the mechanism of action is mitochondrial respiratory inhibitors, which are protective, therapeutic, and leaf osmotic conduction effects by preventing electron transfer in cytochrome synthesis.
  • the results of field efficacy test of pyraclostrobin emulsion showed good control effect on cucumber powdery mildew, downy mildew and banana scab, leaf spot and sclerotinia.
  • the structural formula of pyraclostrobin is:
  • the object of the present invention is to provide a pesticide composition capable of regulating crop growth and preventing crop diseases, promoting crop growth, controlling crop diseases, rapidly controlling the spread of crop diseases, increasing crop yield, and achieving disease resistance and yield increase. It has been found through experiments that thifibrone and methoxy acrylate fungicides have significant effects in regulating crop growth, controlling crop diseases and increasing single-sided machine yield.
  • Another object of the present invention is to provide a preparation method comprising a combination of two active ingredients A and B agricultural compounds and an application for regulating and promoting crop growth in the agricultural field.
  • the object of the invention can be achieved by the following measures:
  • the invention relates to a pesticide composition, in particular to a synergistic plant growth regulator and a bactericide composition, the composition comprising two active components A and B, wherein the active component A is thiabenzene Long, the active component B is one of the methoxy acrylate fungicides azoxystrobin, picoxystrobin or pyraclostrobin, and the weight ratio between the two components is the active component A and the active group.
  • the weight ratio of the sub-B is 1: (240 to 5).
  • the weight ratio of active ingredient A to active ingredient B is 1: (204 to 10) or 1: (204 to 10).
  • the weight ratio of azoxystrobin and azoxystrobin is 1:204-10
  • the weight ratio of azoxystrobin to picoxystrobin is 1:204-10
  • azoxystrobin and pyraclostrobin The weight ratio of the ester is 1:204 to 10.
  • the weight ratio between the two components of A and B can be arbitrarily adjusted within the range of the following ratios: 1:5, 1:6, 1:7, 1:8, 1:9 , 1:10, 1:11, 1:12, 1:13, 1:14, 1:15, 1:16, 1:17, 1:18, 1:19, 1:20, 1:21, 1 :22, 1:23, 1:24, 1:25, 1:26, 1:27, 1:28, 1:29, 1:30, 1:32, 1:33, 1:34, 1:35 1, 1:36, 1:37, 1:38, 1:39, 1:40, 1:41, 1:42, 1:43, 1:44, 1:45, 1:46, 1:47, 1 : 48, 1:49, 1:50, 1:51, 1:52, 1:53, 1:54, 1:55, 1:56, 1:57, 1:58, 159:, 1:60, 1:61, 1:62, 1:63, 1:64, 1:65, 1:66, 1:67, 1:68, 1
  • the invention finds through experiments that the composition is used for better control of crop diseases.
  • the treatment with the compound can better control the spread of the disease and promote the health effect of the crop. Enhance the disease resistance of crops and improve the quality of crop products.
  • the present invention provides a combination comprising component A (thiabendazole) and component B (methoxy acrylate fungicide selected from the group consisting of azoxystrobin, picoxystrobin or pyraclostrobin)
  • component A thiabendazole
  • component B methoxy acrylate fungicide selected from the group consisting of azoxystrobin, picoxystrobin or pyraclostrobin
  • composition of the present invention can also be used in combination with other pesticides (such as fungicides, insecticides, herbicides, plant growth regulators), fertilizers, etc., and these are mixed with existing ones.
  • pesticides such as fungicides, insecticides, herbicides, plant growth regulators
  • fertilizers etc.
  • composition of the present invention can be made into a pesticide-acceptable dosage form from the active ingredient and the pesticide adjuvant.
  • the active ingredient in the composition has a mass content of from 5 to 85%, preferably from 5 to 60%.
  • composition may specifically comprise an agrochemical auxiliary, such as one or more of a carrier, a solvent, a dispersing agent, a wetting agent, an adhesive, a thickener, a binder, a surfactant, etc., during the application process.
  • an agrochemical auxiliary such as one or more of a carrier, a solvent, a dispersing agent, a wetting agent, an adhesive, a thickener, a binder, a surfactant, etc.
  • an agrochemical auxiliary such as one or more of a carrier, a solvent, a dispersing agent, a wetting agent, an adhesive, a thickener, a binder, a surfactant, etc.
  • Suitable auxiliaries may be solid or liquid, they are usually materials commonly used in the processing of dosage forms, such as natural or regenerated minerals, solvents, dispersants, wetting agents, adhesives, thickeners, binders or fertilizers. .
  • the method of application of the compositions of the invention comprises the use of the compositions of the invention for aerial parts of plants, in particular leaves or foliage. You can choose to soak or apply to the surface of the control object.
  • the frequency of administration and the amount administered will depend on the biological and climatic conditions of the pathogen.
  • the plant growth site such as rice fields, may be wetted with a liquid formulation of the composition, or the composition may be applied to the soil in solid form, such as in the form of granules (soil application), the composition may be passed from the soil to the plant through the roots of the plant. In vivo (systemic action).
  • compositions may be applied only with the active ingredient or may be mixed with an additive (agrochemical adjuvant).
  • compositions of the present invention may be prepared in a pesticide acceptable dosage form such as a liquid, suspension, soluble liquid, oil suspension, microcapsule, microemulsion, suspension, and the like.
  • a pesticide acceptable dosage form such as a liquid, suspension, soluble liquid, oil suspension, microcapsule, microemulsion, suspension, and the like.
  • the compositions may be applied by spraying, misting, dusting, spreading or pouring, and the like.
  • Microcapsule dosage forms suitable for the present invention include: microcapsule suspension, microcapsule suspension-suspension, microcapsule suspension-water emulsion, etc., characterized in that the inner wall of the capsule (ie, the capsule core) contains the active ingredient thiabendone and methoxy
  • the acrylate bactericide is mixed into a microcapsule in a mixture of a certain ratio.
  • the microcapsules are stably dispersed and suspended in a certain concentration to form a microcapsule suspending agent in water as a continuous phase.
  • one of the active ingredients is prepared as a microcapsule suspension, another active ingredient is prepared into an emulsion, and the prepared two components are mixed, stirred, and shaken to obtain a microcapsule suspension-suspension or microcapsule suspension.
  • Agent-water emulsion is a microcapsule suspension.
  • composition of the present invention can be prepared into various dosage forms by a known method, and the active ingredient and the auxiliary agent, such as a solvent, a solid carrier, and, if necessary, can be uniformly mixed and ground together with the surfactant to prepare a desired preparation. Dosage form.
  • the above solvent may be selected from aromatic hydrocarbons, preferably containing from 8 to 12 carbon atoms, such as a mixture of xylenes or substituted benzenes, phthalates such as dibutyl phthalate or dicaprylic acid, aliphatic hydrocarbons such as rings.
  • aromatic hydrocarbons preferably containing from 8 to 12 carbon atoms, such as a mixture of xylenes or substituted benzenes, phthalates such as dibutyl phthalate or dicaprylic acid, aliphatic hydrocarbons such as rings.
  • Alkenes or paraffins, alcohols and glycols and their ethers and esters such as ethanol, ethylene glycol, ethylene glycol monomethyl
  • ketones such as cyclohexanone
  • highly polar solvents such as N-methyl-2 Pyrrolidone, dimethyl sulfoxide or dimethylformamide
  • vegetable or vegetable oils such as soybean oil.
  • the above solid carriers are usually natural mineral fillers such as talc, kaolin, montmorillonite or activated clay.
  • a highly dispersible silicic acid or a highly dispersible adsorbent polymer carrier such as a particulate adsorbent carrier or a non-adsorbing carrier, and a suitable particulate adsorbent carrier is porous.
  • a suitable particulate adsorbent carrier is porous.
  • suitable non-adsorbing carriers such as calcite or sand.
  • a large amount of pre-granulated materials of inorganic or organic nature can be used as a carrier, in particular dolomite.
  • Suitable surfactants are lignosulfonic acid, naphthalenesulfonic acid, phenolsulfonic acid, alkaline earth metal or amine salts, alkylarylsulfonates, alkyl groups Sulfates, alkyl sulfonates, fatty alcohol sulphates, fatty acids and sulfated fatty alcohol glycol ethers, as well as condensates of sulfonated naphthalene and naphthalene derivatives with formaldehyde, naphthalene or naphthalene sulfonic acid with phenol and formaldehyde Condensate, polyoxyethylene octyl phenyl ether, ethoxylated isooctyl phenol, octyl phenol, nonyl phenol, alkyl aryl polyglycol ether, tributyl benzene poly
  • composition of the present invention can be applied in the agricultural field to regulate crop growth and control crop diseases.
  • Plants in the present invention include, but are not limited to, crops such as rice, cucumber or banana.
  • the two active ingredients in the composition of the present invention exhibit mutual promotion, the activity of the composition is higher than the expected activity of using a single compound, and the planting agent in the present invention can promote plant growth regulation, and the fungicide component can effectively kill Disease killer.
  • the treatment of the crop with the composition can effectively prevent the spread and spread of the pathogen, and can better and better control the crop disease and reduce the impact of the medicine on the crop.
  • the other characteristics exhibited by the composition of the present invention are mainly as follows: 1.
  • the composition of the present invention has a synergistic additive effect and can promote each other; 2 due to the difference in chemical composition of the two single agents of the composition Large, the mechanism of action is completely different, there is no cross-resistance, the crop is safe, and the disease-preventing effect can be greatly improved; 3 the composition reduces the adverse effects caused by the application of the drug to the crop; 4 the composition can be improved Crop yield, quality improvement, and high economic value.
  • the active ingredient and the auxiliary agent are mixed according to a certain ratio, and then finely ground to prepare a thiabendazole azoxystrobin suspension agent, a thiabendazole pyridoxal ester suspension agent, and a thiabendazole pyriazole Ester suspension.
  • Example 1 48% thiabendazole azoxystrobin suspension
  • Example 2 19% thiabendazole azoxystrobin suspension
  • Example 8 19% thiabendazole pyraclostrobin suspension
  • the active ingredients thiablon and azoxystrobin, oxypoxystrobin and pyraclostrobin are mixed in proportion with solvent, emulsifier and flow, and after fine sanding and high-speed shearing, semi-finished products are obtained. Processed into finished products.
  • Example 10 41% thiabendazole azoxystrobin water emulsion
  • Example 11 16% thiabendazole azoxystrobin water emulsion
  • Example 12 15% thiabendazole azoxystrobin water emulsion
  • Example 14 16% thiabendazole ⁇ hyperoxylate aqueous emulsion
  • the effective component thiablon and one of a mixture of azoxystrobin, oxypide and pyraclostrobin are mixed with various auxiliaries and fillers in proportion, and pulverized by an ultrafine pulverizer. Wettable powder.
  • Example 19 35% thiabendazole azoxystrobin wettable powder
  • Example 20 29% thiabendazole azoxystrobin wettable powder
  • Example 22 35% thiabendazole ⁇ picoxybacteride wettable powder
  • Example 23 29% thiabendazole ⁇ picoxystrobin wettable powder
  • Example 24 18% thiabendazole picoxystrobin wettable powder
  • Example 25 35% thiabendazole picoxystrobin wettable powder
  • Example 26 29% thiabendazole pyraclostrobin wettable powder
  • Example 27 18% thiabendazole pyraclostrobin wettable powder
  • Thiabendron 3% Thiabendron 3%, pyraclostrobin 15%, sodium lignin sulfonate 3%, alkyl sulfonate 5%, white carbon black 10%, kaolin to 100%.
  • Example 28 11% thiabendazole azoxystrobin soluble solution
  • Example 30 11% thiabendazole pyraclostrobin soluble liquid agent
  • the thiazole and methoxy acrylate fungicides were diluted with acetone at a certain concentration, and the crops were sprayed to determine the effects of various concentrations on crop growth in the field, including plant height, sheath blight control rate, and rice. Comprehensive evaluation of the prevention and treatment rate of rickets.
  • Plant height increase rate (clear water control plant height - treated plant height) / clear water control plant height * 100%
  • Thousand-grain weight increase rate (1000-grain weight of treated - 1000-grain weight of clear water control) / 1000-grain weight of clear water control *100%
  • Mu yield increase rate (mu yield after treatment - yield per mu of clear water control) / mu yield of clear water control * 100%
  • Table 1 Summary of thiabendazole and methoxy acrylate fungicides in rice growth regulation and disease prevention
  • the inventors found that there is a good synergistic effect between thiabendone and methoxy acrylate fungicide.
  • the thidiazepine and methoxy acrylate fungicide are mixed at different ratios, and the thiobenzene is relatively Long, methoxy acrylate fungicide single agent, and clear water control, the rice growth regulation effect is obvious, mainly in: control rice plant height, increase rice 1000-grain weight, increase rice yield per mu; spray the composition of the invention The incidence rate is greatly reduced, and the disease prevention effect is improved.
  • the thiazole and methoxy acrylate fungicides were diluted with acetone at a certain concentration, and the crops were sprayed to determine the effects of various concentrations on the growth of the crops, including the stem diameter, downy mildew and powdery mildew of the crops. Comprehensive evaluation of the rate and production situation.
  • Stem thickening rate (clear water stem diameter - treated stem diameter) / clear water control stem thick * 100%
  • Rate of fruit growth per plant (single plant fruit of the treated plant - fruit water control group) / fruit setting rate of clear water control * 100%
  • Moisture content increase rate (water content after treatment - moisture content of clean water control) / moisture content of clear water control * 100%
  • the experimental data from Table 2 shows that the product of the present invention is applied in the early stage of cucumber downy mildew and powdery mildew, and can effectively reduce the disease index and improve the control effect when cucumber downy mildew and powdery mildew occur; Thickening; increase the fruit setting rate of cucumber per plant, increase the moisture content of cucumber, and improve the quality of cucumber.

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

L'invention concerne une composition pesticide, et en particulier une composition d'un régulateur de croissance végétale et d'un fongicide qui ont un effet synergique. La composition comprend deux principes actifs A et B, le principe actif A étant de la thidiazurone, le principe actif B étant un parmi des fongicides à base de strobilurine, tels que l'azoxystrobine, la picoxystrobine, ou la pyraclostrobine, le rapport pondéral du principe actif A au principe actif B étant de 1:240 à 5. La composition de pesticide peut faciliter la croissance de cultures, empêcher des maladies des cultures, réguler rapidement la propagation des maladies des cultures et améliorer les rendements des récoltes, ce qui permet d'obtenir une prévention des maladies et une augmentation du rendement. On a trouvé sur la base d'expériences que le fongicide composé de thidiazurone et strobilurine a des effets significatifs dans la régulation de la croissance de cultures, la prévention et le traitement de maladies des cultures, et l'amélioration des rendements par unité de surface.
PCT/CN2017/092640 2016-08-22 2017-07-12 Composition pesticide WO2018036294A1 (fr)

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CN201610705870.8 2016-08-22
CN201610705870.8A CN106359430A (zh) 2016-08-22 2016-08-22 一种农药组合物

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CN106359430A (zh) * 2016-08-22 2017-02-01 江苏辉丰农化股份有限公司 一种农药组合物
CN106922683A (zh) * 2017-03-21 2017-07-07 江苏辉丰农化股份有限公司 含有苯并异噻唑啉酮和噻苯隆的农药组合物
CN112514909A (zh) * 2020-12-17 2021-03-19 多农多收技术研究(江苏)有限公司 一种增产组合物、增产药剂及其应用

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CN105475315A (zh) * 2015-12-18 2016-04-13 广东中迅农科股份有限公司 含有吡唑醚菌酯和萘乙酸的农药组合物
CN105594720A (zh) * 2015-12-18 2016-05-25 广东中迅农科股份有限公司 含有吡唑醚菌酯和芸苔素内酯的农药组合物
CN106359430A (zh) * 2016-08-22 2017-02-01 江苏辉丰农化股份有限公司 一种农药组合物

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