WO2018003798A1 - Method for manufacturing three-dimensionally shaped molding - Google Patents

Method for manufacturing three-dimensionally shaped molding Download PDF

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Publication number
WO2018003798A1
WO2018003798A1 PCT/JP2017/023580 JP2017023580W WO2018003798A1 WO 2018003798 A1 WO2018003798 A1 WO 2018003798A1 JP 2017023580 W JP2017023580 W JP 2017023580W WO 2018003798 A1 WO2018003798 A1 WO 2018003798A1
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WIPO (PCT)
Prior art keywords
pores
solidified layer
layer
powder
light beam
Prior art date
Application number
PCT/JP2017/023580
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French (fr)
Japanese (ja)
Inventor
吉田 徳雄
暁史 中村
阿部 諭
雅憲 森本
内野々 良幸
Original Assignee
パナソニックIpマネジメント株式会社
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Publication of WO2018003798A1 publication Critical patent/WO2018003798A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/10Sintering only
    • B22F3/105Sintering only by using electric current other than for infrared radiant energy, laser radiation or plasma ; by ultrasonic bonding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/12Both compacting and sintering
    • B22F3/16Both compacting and sintering in successive or repeated steps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/24After-treatment of workpieces or articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y10/00Processes of additive manufacturing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency

Definitions

  • the present invention relates to a method for manufacturing a three-dimensional shaped object.
  • this invention relates to the manufacturing method of the three-dimensional shaped molded article which forms a solidified layer by light beam irradiation to a powder layer.
  • a method for producing a three-dimensional shaped object by irradiating a powder material with a light beam has been conventionally known.
  • a three-dimensional shaped object is manufactured by alternately repeating powder layer formation and solidified layer formation based on the following steps (i) and (ii).
  • the obtained three-dimensional shaped object can be used as a mold.
  • organic resin powder is used as the powder material, the obtained three-dimensional shaped object can be used as various models.
  • a metal powder is used as a powder material and a three-dimensional shaped object obtained thereby is used as a mold.
  • the squeezing blade 23 is moved to form a powder layer 22 having a predetermined thickness on the modeling plate 21 (see FIG. 10A).
  • the solidified layer 24 is formed from the powder layer 22 by irradiating a predetermined portion of the powder layer 22 with the light beam L (see FIG. 10B).
  • a new powder layer 22 is formed on the obtained solidified layer 24, and a light beam is irradiated again to form a new solidified layer 24.
  • the solidified layer 24 is laminated (see FIG.
  • a three-dimensional structure composed of the laminated solidified layer 24 is formed.
  • a shaped object can be obtained. Since the solidified layer 24 formed as the lowermost layer is coupled to the modeling plate 21, the three-dimensional modeled object and the modeling plate 21 form an integrated object, and the integrated object can be used as a mold.
  • the present inventors have found the following phenomenon in the solidified layer formation stage. Specifically, the inventors of the present application have found that when forming a solidified layer by irradiating a metal powder with a light beam, pores can locally exist in the solidified layer. When the pores are locally present in the solidified layer, the structural strength of the region where the pores are present is relatively weak due to the pores forming voids. There may be a possibility that a crack may occur as a starting point. For this reason, there is a possibility that the structural strength of the finally obtained three-dimensional shaped object is lowered due to this. That is, there is a possibility that a highly accurate three-dimensional shaped object cannot be obtained.
  • the object of the present invention is to provide a method for manufacturing a three-dimensional shaped object that can obtain a highly accurate three-dimensional shaped object.
  • a method for producing a three-dimensional shaped object by sequentially forming a plurality of solidified layers by irradiation with a light beam there is provided a method for producing a three-dimensional shaped object comprising reducing pores caused by residual gas in a solidified layer.
  • a highly accurate three-dimensional shaped object can be obtained.
  • FIG. 1 (a) Sectional drawing schematically showing a mode of reducing the pores in the solidified layer
  • FIG. 1 (b) Cross-sectional view schematically showing the phenomenon of pore formation Sectional drawing which showed the aspect which pinpoints the generation
  • FIG. 4 (a) identification of occurrence of pores
  • FIG. 5A is a cross-sectional view schematically illustrating a mode of adjusting the light beam irradiation conditions (FIG. 5A: light beam output adjustment, FIG. 5B: light beam scanning speed adjustment, FIG. 5C: light) Beam spot diameter adjustment)
  • Sectional drawing which showed typically the aspect which presses the predetermined part of the solidification layer containing a pore from the outside Sectional drawing which showed typically the other aspect which presses the predetermined part of the solidification layer containing a pore from the outside Sectional drawing schematically showing a mode in which a predetermined portion of the solidified layer including pores is subjected to cutting (FIG. 8A: start of cutting, FIG. 8B: after completion of cutting, FIG. c): powder filling, FIG.
  • FIG. 9A is a cross-sectional view schematically showing a mode of adjusting the thickness of a layer made of powder
  • FIG. 9A thickness adjustment by a squeegee blade
  • FIG. 9B thickness adjustment by a powder supply nozzle
  • FIG. 9 (c) Thickness adjustment by powder suction nozzle
  • Cross-sectional views schematically showing a process aspect of stereolithography combined processing in which the powder bed fusion bonding method is performed (FIG. 10A: at the time of forming the powder layer
  • FIG. 10B at the time of forming the solidified layer
  • FIG. c During lamination
  • the perspective view which showed the composition of the optical modeling compound processing machine typically Flow chart showing general operation of stereolithography combined processing machine
  • powder layer means, for example, “a metal powder layer made of metal powder” or “a resin powder layer made of resin powder”.
  • the “predetermined portion of the powder layer” substantially refers to the region of the three-dimensional shaped object to be manufactured. Therefore, by irradiating the powder existing at the predetermined location with a light beam, the powder is sintered or melted and solidified to form a three-dimensional shaped object.
  • solidified layer means “sintered layer or melt-solidified layer” when the powder layer is a metal powder layer, and “cured layer or melt-bonded layer” when the powder layer is a resin powder layer. "Means.
  • the “up and down” direction described directly or indirectly in the present specification is a direction based on the positional relationship between the modeling plate and the three-dimensional shaped object, for example, and is based on the modeling plate.
  • the side on which the shaped object is manufactured is “upward”, and the opposite side is “downward”.
  • FIG. 10 schematically shows a process aspect of stereolithographic composite processing
  • FIGS. 11 and 12 are flowcharts of the main configuration and operation of the stereolithographic composite processing machine capable of performing the powder bed fusion bonding method and the cutting process. Respectively.
  • the stereolithography combined processing machine 1 includes a powder layer forming means 2, a light beam irradiation means 3, and a cutting means 4, as shown in FIG.
  • the powder layer forming means 2 is means for forming a powder layer by spreading a powder such as a metal powder or a resin powder with a predetermined thickness.
  • the light beam irradiation means 3 is a means for irradiating a predetermined portion of the powder layer with the light beam L.
  • the cutting means 4 is means for cutting the surface of the laminated solidified layer, that is, the surface of the three-dimensional shaped object.
  • the powder layer forming means 2 mainly comprises a powder table 25, a squeezing blade 23, a modeling table 20, and a modeling plate 21, as shown in FIG.
  • the powder table 25 is a table that can be moved up and down in a powder material tank 28 whose outer periphery is surrounded by a wall 26.
  • the squeezing blade 23 is a blade that can move in the horizontal direction to obtain the powder layer 22 by supplying the powder 19 on the powder table 25 onto the modeling table 20.
  • the modeling table 20 is a table that can be moved up and down in a modeling tank 29 whose outer periphery is surrounded by a wall 27.
  • the modeling plate 21 is a plate that is arranged on the modeling table 20 and serves as a base for a three-dimensional modeled object.
  • the light beam irradiation means 3 mainly has a light beam oscillator 30 and a galvanometer mirror 31 as shown in FIG.
  • the light beam oscillator 30 is a device that emits a light beam L.
  • the galvanometer mirror 31 is means for scanning the emitted light beam L into the powder layer 22, that is, scanning means for the light beam L.
  • the cutting means 4 mainly includes an end mill 40 and a drive mechanism 41 as shown in FIG.
  • the end mill 40 is a cutting tool for cutting the surface of the laminated solidified layer, that is, the surface of the three-dimensional shaped object.
  • the drive mechanism 41 is means for moving the end mill 40 to a desired location to be cut.
  • the operation of the stereolithography combined processing machine 1 includes a powder layer forming step (S1), a solidified layer forming step (S2), and a cutting step (S3), as shown in the flowchart of FIG.
  • the powder layer forming step (S1) is a step for forming the powder layer 22.
  • the modeling table 20 is lowered by ⁇ t (S11) so that the level difference between the upper surface of the modeling plate 21 and the upper end surface of the modeling tank 29 becomes ⁇ t.
  • the squeezing blade 23 is moved in the horizontal direction from the powder material tank 28 toward the modeling tank 29 as shown in FIG.
  • the powder 19 arranged on the powder table 25 can be transferred onto the modeling plate 21 (S12), and the powder layer 22 is formed (S13).
  • the powder material for forming the powder layer 22 include “metal powder having an average particle diameter of about 5 ⁇ m to 100 ⁇ m” and “resin powder such as nylon, polypropylene, or ABS having an average particle diameter of about 30 ⁇ m to 100 ⁇ m”. it can.
  • the solidified layer forming step (S2) is a step of forming the solidified layer 24 by light beam irradiation.
  • the light beam L is emitted from the light beam oscillator 30 (S21), and the light beam L is scanned to a predetermined location on the powder layer 22 by the galvano mirror 31 (S22).
  • the powder at a predetermined location of the powder layer 22 is sintered or melted and solidified to form the solidified layer 24 as shown in FIG. 10B (S23).
  • a carbon dioxide laser, an Nd: YAG laser, a fiber laser, an ultraviolet ray, or the like may be used.
  • the powder layer forming step (S1) and the solidified layer forming step (S2) are alternately repeated. As a result, a plurality of solidified layers 24 are laminated as shown in FIG.
  • the cutting step (S3) is a step for cutting the surface of the laminated solidified layer 24, that is, the surface of the three-dimensional shaped object.
  • a cutting step is started by driving the end mill 40 (see FIG. 10C and FIG. 11) (S31). For example, when the end mill 40 has an effective blade length of 3 mm, a cutting process of 3 mm can be performed along the height direction of the three-dimensional shaped object.
  • the end mill 40 is driven. Specifically, a cutting process is performed on the surface of the laminated solidified layer 24 while moving the end mill 40 by the drive mechanism 41 (S32).
  • the present invention is characterized in the solidified layer forming stage.
  • the manufacturing method of the present invention includes reducing pores 10 generated in the solidified layer 24 in the formation stage of the solidified layer 24 as shown in FIGS. 1 (a) and 1 (b). Become. More specifically, in the production method of the present invention, as shown in FIGS. 1 (a) and 1 (b), pores generated due to residual gas in the solidified layer 24 in the formation stage of the solidified layer 24. Comprising subtracting ten.
  • pore 10 refers to a void formed in the solidified layer 24 as shown in the upper right enlarged view of FIG. 1A, and is not particularly limited in cross-sectional view, but is 20 to 100 ⁇ m. Which can have the following dimensions: More specifically, the “pores 10” referred to here indicate voids generated in a high density region where the solidification density in the solidified layer 24 is, for example, 80 to 100%. In other words, the “pores 10” here refers to those that do not occur in the low / medium density region where the solidification density in the solidified layer 24 is less than 80%, for example.
  • the pores 10 may exist in the density region where the solidification density is relatively high as described above. From the above, it is confirmed that the “pore 10” in the present invention is essentially different from the “porous region” formed in the density region where the solidification density in the solidified layer is relatively low. I will add to.
  • the “pore 10” in the present invention can be caused by the following phenomenon. Specifically, as shown in FIG. 2, when a new solidified layer 24B is formed by irradiation with the light beam L, the irradiation heat of the light beam L is transmitted to the solidified layer 24A located in the already formed lower layer. obtain. When the irradiation heat of the light beam L is transmitted to the solidified layer 24A located in the already formed lower layer, the residual gas 5 that can locally remain in the solidified layer 24A can be expanded by the irradiation heat of the light beam L. Due to the expansion of the residual gas 5, pores 10 may be locally generated in the solidified layer 24 ⁇ / b> A located in the already formed lower layer.
  • the “residual gas 5” here is not particularly limited. For example, the gas remaining when the light beam is applied to a predetermined portion of the powder layer remains in the solidified layer. Can occur.
  • reducing pores substantially refers to reducing the number of pores and / or the size of the pores.
  • reduce as used herein includes those that are completely removed.
  • region where the pore 10 exists) where the structural strength in a solidified layer is relatively weak can be suppressed.
  • the structural strength of the finally obtained three-dimensional shaped article 100 can be maintained due to the suppression of the occurrence of cracks.
  • a highly accurate three-dimensional shaped object 100 can be obtained.
  • this invention may take the following aspect.
  • the generation location of the pore 10 may be specified in advance based on the temperature difference between the pore 10 in the solidified layer 24 and the peripheral portion of the pore 10.
  • the uppermost surface 24a of the solidified layer 24 is irradiated with the light beam L at the formation stage of the solidified layer 24, and the light beam L is irradiated using the infrared camera 50, particularly infrared thermography.
  • the temperature distribution in the region below the predetermined portion of the uppermost surface 24a is measured.
  • the pores 10 are formed in the solidified layer 24, the light beam applied to the uppermost surface 24a of the solidified layer 24 due to the pores 10 forming voids.
  • the irradiation heat of L can be transferred into the pores 10 through the solidified layer 24.
  • the irradiation heat of the light beam L can be caused to remain in the void due to this, that is, it can be in a “muffled” state. Therefore, when the temperature distribution in the lower region of the predetermined portion of the uppermost surface 24a irradiated with the infrared camera 50 is measured, as shown in the upper right view of FIG.
  • the temperature distribution with the temperature region 70 at the peripheral portion of the hole 10 generation portion may be different. Specifically, as shown in the upper right view of FIG.
  • the temperature range 60 of the pore 10 generation portion can be relatively higher than the temperature range 70 of the peripheral portion of the pore 10 generation portion in plan view ( Part where the pores 10 are generated: black part in the upper right diagram in FIG. 3). By utilizing such a difference in temperature distribution, it can be specified where the pores 10 are generated.
  • pores in the solidified layer already formed may be reduced according to the following mode.
  • the location where the pores 10 are generated is specified, and then the predetermined portion 24 ′ of the solidified layer 24 including the pores 10 is irradiated with the light beam L so as to It may be melted to reduce the pores 10.
  • the location where the pores 10 are generated is specified in advance using the infrared camera 50 described above.
  • a predetermined portion 24 ′ of the solidified layer 24 including the pores 10 is irradiated with the light beam L as shown in FIG.
  • the “light beam L” may be used when forming a new solidified layer (corresponding to the uppermost solidified layer in FIG. 4B).
  • the predetermined portion 24 ′ of the solidified layer 24 including the pores 10 can be in a molten state. Thereafter, as shown in FIG.
  • the predetermined portion 24 ′ of the solidified layer 24 including the pores 10 in a molten state can be in a solidified state when the temperature of the portion 24 ′ decreases. As described above, the pores 10 that may exist in the solidified layer 24 can be reduced.
  • the irradiation conditions of the light beam L may be adjusted to reduce the pores 10 in the solidified layer 24 that has already been formed.
  • the output of L when the number of occurrence locations of the pores 10 specified using the above-described infrared camera exceeds a predetermined standard, for example, as shown in FIG. You may change the output of L suitably. Specifically, when the number of occurrence locations of the pores 10 exceeds a predetermined standard, it is determined that there is a large amount of residual gas that can cause the pores 10 in the solidified layer 24, and light is accordingly emitted. The output of the beam L may be increased. When the output of the light beam L is increased, a relatively large irradiation heat of the light beam L is provided to a predetermined portion of the already formed solidified layer 24 including the pores 10 located in the lower layer. Can be.
  • the predetermined part of the already formed solidified layer 24 including the pores 10 can be suitably brought into a molten state. Thereafter, as the temperature decreases, a predetermined portion of the already formed solidified layer 24 including the pores 10 in a suitable molten state can be suitably solidified. Thereby, the pores 10 already formed in the solidified layer 24 can be suitably reduced.
  • the light beam L is compared with that in the normal solidified layer formation, depending on the degree of occurrence of the identified pores 10 that exceeds the predetermined reference. It may be determined how much to increase the output of.
  • the degree of output of the light beam L that is increased as compared with the normal solidified layer formation. May be relatively small.
  • the degree of output of the light beam L to be increased is relatively large as compared with the normal solidified layer formation. It's okay.
  • the scanning speed of L may be changed as appropriate. Specifically, when the number of occurrence locations of the pores 10 exceeds a predetermined standard, it is determined that there is a large amount of residual gas that can cause the pores 10 in the solidified layer 24, and light is accordingly emitted. The scanning speed of the beam L may be reduced. When the scanning speed of the light beam L is reduced, the irradiation heat of the light beam L is provided relatively sufficiently to a predetermined portion of the already formed solidified layer 24 including the pores 10 located in the lower layer. Can be.
  • the predetermined part of the already formed solidified layer 24 including the pores 10 can be suitably brought into a molten state. Thereafter, as the temperature decreases, a predetermined portion of the already formed solidified layer 24 including the pores 10 in a suitable molten state can be suitably solidified. Thereby, the pores 10 already formed in the solidified layer 24 can be suitably reduced.
  • the light beam L is compared with that at the time of normal solidified layer formation, depending on the degree of occurrence of the identified pores 10 that exceeds the predetermined reference. It may be determined how much the scanning speed is reduced.
  • the degree may be relatively small.
  • the degree of scanning speed of the light beam L that is reduced compared to the normal solidified layer formation is relatively large. It can be big.
  • the spot diameter of L may be changed as appropriate. Specifically, when the number of occurrence locations of the pores 10 exceeds a predetermined standard, it is determined that there is a large amount of residual gas that can cause the pores 10 in the solidified layer 24, and light is accordingly emitted.
  • the spot diameter of the beam L may be made smaller than that during normal solidified layer formation. When the spot diameter of the light beam L is reduced, a relatively large irradiation heat of the light beam L is provided to a predetermined portion of the already formed solidified layer 24 including the pores 10 located in the lower layer.
  • the predetermined part of the already formed solidified layer 24 including the pores 10 can be suitably brought into a molten state. Thereafter, as the temperature decreases, a predetermined portion of the already formed solidified layer 24 including the pores 10 in a suitable molten state can be suitably solidified. Thereby, the pores 10 already formed in the solidified layer 24 can be suitably reduced.
  • the light beam L is compared with that in the normal solidified layer formation, depending on the degree of occurrence of the identified pores 10 that exceeds the predetermined reference. It may be determined how much the spot diameter is to be reduced.
  • the spot diameter of the light beam L that is smaller than that at the time of normal solidified layer formation when the number of occurrence locations of the specified pores 10 that exceed the predetermined standard is relatively small, the spot diameter of the light beam L that is smaller than that at the time of normal solidified layer formation.
  • the degree may be relatively small.
  • the degree of the spot diameter of the light beam L to be made smaller than that at the time of normal solidified layer formation is relatively large. It can be big.
  • a predetermined portion of the solidified layer 24 including the pores 10 may be pressed from the outside to reduce the pores 10 in the already formed solidified layer 24.
  • the location where the pores 10 are generated is specified, and the predetermined portion 24 ′ of the solidified layer 24 including the pores 10 is, for example, the cutting means 4 (however, a cutting blade is installed). May be pressed from the outside.
  • the pressing direction may be a direction facing the stacking direction as shown in FIG.
  • the pores 10 may not be properly crushed only by pressing the predetermined portion 24 'of the solidified layer 24 including the pores 10 from the outside. Therefore, as shown in FIG. 7, the cutting means 4 is rotated by rotating the cutting means 4 while applying a pressing force to the predetermined portion 24 ′ of the solidified layer 24 including the pores 10 using the cutting means 4. A rotational force may be further applied to the predetermined portion 24 ′ of the solidified layer 24. Thereby, the pore 10 can be crushed more suitably. As a result, the pores 10 already formed in the solidified layer 24 can be more suitably reduced.
  • the predetermined portion 24 ′ of the solidified layer 24 including the pores 10 may be subjected to cutting to reduce the pores 10.
  • a predetermined portion 24 ′ of the solidified layer 24 including the pores 10 as shown in FIG. 4 is used for cutting.
  • the predetermined portion 24 ′ of the solidified layer 24 including the pores 10 cannot exist in the solidified layer 24.
  • the powder 19 is applied to a place where the predetermined portion 24 ′ does not exist as shown in FIG. Fill.
  • the portion filled with the powder 19 is irradiated with the light beam L to melt and solidify the filled powder 19.
  • the pores 10 can be reduced from the already formed solidified layer 24.
  • the supply conditions of the powder used for forming the solidified layer may be adjusted to reduce the pores in the already formed solidified layer.
  • the following aspect may be taken. Specifically, it is determined that there is a large amount of residual gas that can cause the pores 10 in the solidified layer 24, and the squeezing blade 23 is formed accordingly, for example, as shown in FIG.
  • the thickness of the powder layer 22 may be adjusted as appropriate. For example, as shown in FIG. 9A, the thickness of the layer is set to L 1 , L 2 (> L) according to the degree of the number of occurrence locations of the specified pore 10 that exceeds the predetermined standard. 1 ), or L 3 (> L 2 ).
  • the powder layer 22 When the thickness of the powder layer 22 becomes relatively small, when a new solidified layer is formed by irradiating a predetermined portion of the powder layer 22 with a light beam, the powder layer 22 already includes the pores 10 located in the lower layer.
  • the irradiation heat of the light beam can be suitably provided to a predetermined portion in the formed solidified layer 24.
  • the predetermined part in the already formed solidified layer 24 including the pores 10 located in the lower layer can be suitably brought into a molten state.
  • a predetermined portion in the already formed solidified layer 24 including the pores 10 located in the lower layer in a suitable molten state can be suitably solidified.
  • the pores 10 already formed in the solidified layer 24 can be suitably reduced.
  • the solidified layer may be formed by a method.
  • the “powder spray method” is a method of forming a solidified layer by performing powder supply and light beam irradiation substantially simultaneously.
  • the powder spray method has a feature that no powder layer is formed when a solidified layer is obtained. That is, in the powder spray method, a light beam is irradiated to a powder supply location, and a solidified layer is formed from the supplied powder by supplying powder or the like directly to the powder supply location.
  • the following aspect may be taken. Specifically, it is determined that there is a large amount of residual gas that can cause the pores 10 in the solidified layer 24, and the powder 19 is supplied from the powder supply nozzle 80 accordingly, for example, as shown in FIG.
  • the thickness of the layer formed of the powder 19 may be adjusted as appropriate. For example, as shown in FIG. 9B, the thickness of the layer is set to L 1 , L 2 (> L) according to the degree of the number of occurrence locations of the specified pore 10 that exceeds the predetermined standard. 1 ), or L 3 (> L 2 ).
  • the pores 10 located in the lower layer are included.
  • the irradiation heat of the light beam can be suitably supplied to a predetermined portion in the already formed solidified layer 24.
  • the predetermined part in the already formed solidified layer 24 including the pores 10 located in the lower layer can be suitably brought into a molten state.
  • a predetermined portion in the already formed solidified layer 24 including the pores 10 located in the lower layer in a suitable molten state can be suitably solidified.
  • the pores 10 already formed in the solidified layer 24 can be suitably reduced.
  • the following aspect may be taken. Specifically, it is determined that there is a large amount of residual gas that can cause the pores 10 in the solidified layer 24, and the powder 19 is sucked from the powder suction nozzle 90 accordingly, for example, as shown in FIG.
  • the thickness of the layer formed of the powder 19 may be adjusted as appropriate. For example, as shown in FIG. 9C, the thickness of the layer is set to L 1 , L 2 (> L) according to the degree of the number of occurrence locations of the identified pore 10 that exceeds the predetermined standard. 1 ), or L 3 (> L 2 ).
  • the powder 19 when the thickness of the layer made of the powder 19 becomes relatively small, when the powder 19 is irradiated with a light beam to form a new solidified layer, the powder 19 is already formed including the pores 10 located in the lower layer.
  • the irradiation heat of the light beam can be suitably provided to a predetermined portion in the solidified layer 24.
  • the predetermined part in the already formed solidified layer 24 including the pores 10 located in the lower layer can be suitably brought into a molten state.
  • a predetermined portion in the already formed solidified layer 24 including the pores 10 located in the lower layer in a suitable molten state can be suitably solidified.
  • the pores 10 already formed in the solidified layer 24 can be suitably reduced.
  • pores that may be generated in the newly formed solidified layer may be reduced according to the following embodiment.
  • the residual gas 5 that can locally remain in the solidified layer 24A is expanded by the irradiation heat of the light beam L. Then, the expansion of the residual gas 5 may locally generate pores 10 in the solidified layer 24A (see FIG. 2).
  • it can be considered that such residual gas 5 is particularly likely to be generated as the temperature of the solidified layer at the time of formation increases. Therefore, in view of this point, when forming a new solidified layer, in order to suppress in advance the generation of the residual gas 5 that may cause the pores 10, the light beam L is compared with that during normal solidified layer formation.
  • the irradiation conditions of the light beam L are adjusted such that the irradiation energy of the light beam L is relatively reduced, the scanning speed of the light beam L is relatively increased, and / or the spot diameter of the light beam L is relatively increased. Is good. Further, the present invention is not limited to this, and when a new solidified layer is formed, in order to suppress in advance the generation of the residual gas 5 that may cause the pores 10, a solidified layer (modeling that has already been formed as a base material) is formed. The temperature of the new powder layer by lowering the temperature of the object) and / or the modeling plate.
  • First aspect A method for producing a three-dimensional shaped object by sequentially forming a plurality of solidified layers by irradiation with a light beam, A method for producing a three-dimensional shaped object comprising reducing pores generated due to residual gas in the solidified layer.
  • Second aspect In the first aspect described above, the method for producing a three-dimensional shaped article, wherein the pores generated in a high density region having a solidification density of 80 to 100% in the solidified layer is reduced.
  • Third aspect In the said 1st aspect or the 2nd aspect, the manufacturing method of the three-dimensional shape molded article which pinpoints the generation
  • Fourth aspect In the third aspect, a method for producing a three-dimensional shaped article, wherein a predetermined portion of the solidified layer including the pores is irradiated with the light beam to melt and solidify the portion to reduce the pores.
  • Fifth aspect In the said 3rd aspect or the 4th aspect, the said predetermined part of the said solidification layer containing the said pore is pressed from the outside, The manufacturing method of the three-dimensional shaped molded article which reduces the said pore.
  • Sixth aspect The method for producing a three-dimensional shaped structure according to any one of the third to fifth aspects, wherein the predetermined portion of the solidified layer including the pores is subjected to a cutting process to reduce the pores.
  • the solidified layer is formed by a powder bed melt bonding method.
  • Various articles can be manufactured by carrying out the manufacturing method of a three-dimensional shaped object according to an embodiment of the present invention.
  • the powder layer is an inorganic metal powder layer and the solidified layer is a sintered layer
  • the resulting three-dimensional shaped article is a plastic injection mold, a press mold, a die-cast mold, It can be used as a mold such as a casting mold or a forging mold.
  • the powder layer is an organic resin powder layer and the solidified layer is a hardened layer
  • the obtained three-dimensional shaped article can be used as a resin molded product.

Abstract

In order to provide a method for manufacturing a three-dimensionally shaped molding, whereby a high-precision three-dimensionally shaped molding can be obtained, an embodiment of the present invention provides a method for manufacturing a three-dimensionally shaped molding, said method comprising successively forming a plurality of solidified layers by light beam irradiation, wherein the method includes reducing pores produced by residual gas in the solidified layers.

Description

三次元形状造形物の製造方法Manufacturing method of three-dimensional shaped object
 本発明は、三次元形状造形物の製造方法に関する。より詳細には、本発明は、粉末層への光ビーム照射によって固化層を形成する三次元形状造形物の製造方法に関する。 The present invention relates to a method for manufacturing a three-dimensional shaped object. In more detail, this invention relates to the manufacturing method of the three-dimensional shaped molded article which forms a solidified layer by light beam irradiation to a powder layer.
 光ビームを粉末材料に照射することを通じて三次元形状造形物を製造する方法(一般的には「粉末床溶融結合法」と称される)は、従来より知られている。かかる方法は、以下の工程(i)および(ii)に基づいて粉末層形成と固化層形成とを交互に繰り返し実施して三次元形状造形物を製造する。
 (i)粉末層の所定箇所に光ビームを照射し、かかる所定箇所の粉末を焼結又は溶融固化させて固化層を形成する工程。
 (ii)得られた固化層の上に新たな粉末層を形成し、同様に光ビームを照射して更なる固化層を形成する工程。
A method for producing a three-dimensional shaped object by irradiating a powder material with a light beam (generally referred to as “powder bed fusion bonding method”) has been conventionally known. In this method, a three-dimensional shaped object is manufactured by alternately repeating powder layer formation and solidified layer formation based on the following steps (i) and (ii).
(I) A step of irradiating a predetermined portion of the powder layer with a light beam and sintering or melting and solidifying the powder at the predetermined portion to form a solidified layer.
(Ii) A step of forming a new powder layer on the obtained solidified layer and similarly irradiating a light beam to form a further solidified layer.
 このような製造技術に従えば、複雑な三次元形状造形物を短時間で製造することが可能となる。粉末材料として無機質の金属粉末を用いる場合、得られる三次元形状造形物を金型として使用することができる。一方、粉末材料として有機質の樹脂粉末を用いる場合、得られる三次元形状造形物を各種モデルとして使用することができる。 According to such a manufacturing technique, it becomes possible to manufacture a complicated three-dimensional shaped object in a short time. When an inorganic metal powder is used as the powder material, the obtained three-dimensional shaped object can be used as a mold. On the other hand, when organic resin powder is used as the powder material, the obtained three-dimensional shaped object can be used as various models.
 粉末材料として金属粉末を用い、それによって得られる三次元形状造形物を金型として使用する場合を例にとる。図10に示すように、まず、スキージング・ブレード23を動かして造形プレート21上に所定厚みの粉末層22を形成する(図10(a)参照)。次いで、粉末層22の所定箇所に光ビームLを照射して粉末層22から固化層24を形成する(図10(b)参照)。引き続いて、得られた固化層24の上に新たな粉末層22を形成して再度光ビームを照射して新たな固化層24を形成する。このようにして粉末層形成と固化層形成とを交互に繰り返し実施すると固化層24が積層することになり(図10(c)参照)、最終的には積層化した固化層24から成る三次元形状造形物を得ることができる。最下層として形成される固化層24は造形プレート21と結合した状態になるので、三次元形状造形物と造形プレート21とは一体化物を成すことになり、その一体化物を金型として使用できる。 Suppose that a metal powder is used as a powder material and a three-dimensional shaped object obtained thereby is used as a mold. As shown in FIG. 10, first, the squeezing blade 23 is moved to form a powder layer 22 having a predetermined thickness on the modeling plate 21 (see FIG. 10A). Next, the solidified layer 24 is formed from the powder layer 22 by irradiating a predetermined portion of the powder layer 22 with the light beam L (see FIG. 10B). Subsequently, a new powder layer 22 is formed on the obtained solidified layer 24, and a light beam is irradiated again to form a new solidified layer 24. When the powder layer formation and the solidified layer formation are alternately performed in this manner, the solidified layer 24 is laminated (see FIG. 10C), and finally, a three-dimensional structure composed of the laminated solidified layer 24 is formed. A shaped object can be obtained. Since the solidified layer 24 formed as the lowermost layer is coupled to the modeling plate 21, the three-dimensional modeled object and the modeling plate 21 form an integrated object, and the integrated object can be used as a mold.
特開2010-065259号公報JP 2010-065259 A
 ここで、本願発明者らは、固化層形成段階において以下の事象を見出した。具体的には、本願発明者らは、金属粉末に光ビームを照射して固化層を形成する際において、当該固化層内に細孔が局所的に存在し得ることを見出した。細孔が固化層内に局所的に存在する場合、細孔が空隙を成していることに起因して、細孔が存在する領域の構造強度は相対的に弱くなっており、かかる領域を起点としてクラックが生じ得る虞があり得る。そのため、これに起因して最終的に得られる三次元形状造形物の構造強度が低下する虞があり得る。つまり、高精度な三次元形状造形物が得られない虞があり得る。 Here, the present inventors have found the following phenomenon in the solidified layer formation stage. Specifically, the inventors of the present application have found that when forming a solidified layer by irradiating a metal powder with a light beam, pores can locally exist in the solidified layer. When the pores are locally present in the solidified layer, the structural strength of the region where the pores are present is relatively weak due to the pores forming voids. There may be a possibility that a crack may occur as a starting point. For this reason, there is a possibility that the structural strength of the finally obtained three-dimensional shaped object is lowered due to this. That is, there is a possibility that a highly accurate three-dimensional shaped object cannot be obtained.
 本発明は、かかる事情に鑑みて為されたものである。すなわち、本発明の目的は、高精度な三次元形状造形物を得ることが可能な三次元形状造形物の製造方法を提供することである。 The present invention has been made in view of such circumstances. That is, the object of the present invention is to provide a method for manufacturing a three-dimensional shaped object that can obtain a highly accurate three-dimensional shaped object.
 上記目的を達成するために、本発明の一実施形態では、
 光ビームの照射によって複数の固化層を逐次形成して三次元形状造形物を製造する方法であって、
 固化層内の残存ガスに起因して生じる細孔を減じることを含んで成る、三次元形状造形物の製造方法が提供される。
In order to achieve the above object, in one embodiment of the present invention,
A method for producing a three-dimensional shaped object by sequentially forming a plurality of solidified layers by irradiation with a light beam,
There is provided a method for producing a three-dimensional shaped object comprising reducing pores caused by residual gas in a solidified layer.
 本発明の一実施形態では、高精度な三次元形状造形物を得ることができる。 In one embodiment of the present invention, a highly accurate three-dimensional shaped object can be obtained.
固化層内の細孔を減じる態様を模式的に示した断面図(図1(a):細孔を減じる前、図1(b):細孔を減じた後)Sectional drawing schematically showing a mode of reducing the pores in the solidified layer (FIG. 1 (a): before reducing the pores, FIG. 1 (b): after reducing the pores) 細孔の発生現象を模式的に示した断面図Cross-sectional view schematically showing the phenomenon of pore formation 細孔の発生箇所を特定する態様を模式的に示した断面図Sectional drawing which showed the aspect which pinpoints the generation | occurrence | production location of a pore typically 細孔を含んで成る固化層の所定部分に光ビームを照射する態様を模式的に示した断面図(図4(a):細孔の発生箇所特定、図4(b):光ビーム照射開始、図4(c):光ビーム照射終了後)Sectional drawing schematically showing a mode in which a light beam is irradiated onto a predetermined portion of a solidified layer including pores (FIG. 4 (a): identification of occurrence of pores, FIG. 4 (b): light beam irradiation start FIG. 4 (c): after the end of light beam irradiation) 光ビームの照射条件を調整する態様を模式的に示した断面図(図5(a):光ビームの出力調整、図5(b):光ビームの走査速度調整、図5(c):光ビームのスポット径調整)FIG. 5A is a cross-sectional view schematically illustrating a mode of adjusting the light beam irradiation conditions (FIG. 5A: light beam output adjustment, FIG. 5B: light beam scanning speed adjustment, FIG. 5C: light) Beam spot diameter adjustment) 細孔を含んで成る固化層の所定部分を外部から押圧する態様を模式的に示した断面図Sectional drawing which showed typically the aspect which presses the predetermined part of the solidification layer containing a pore from the outside 細孔を含んで成る固化層の所定部分を外部から押圧する別態様を模式的に示した断面図Sectional drawing which showed typically the other aspect which presses the predetermined part of the solidification layer containing a pore from the outside 細孔を含んで成る固化層の所定部分を切削加工に付す態様を模式的に示した断面図(図8(a):切削加工開始、図8(b):切削加工終了後、図8(c):粉末充填、図8(d):光ビーム照射)Sectional drawing schematically showing a mode in which a predetermined portion of the solidified layer including pores is subjected to cutting (FIG. 8A: start of cutting, FIG. 8B: after completion of cutting, FIG. c): powder filling, FIG. 8 (d): light beam irradiation) 粉末から成る層の厚さを調整する態様を模式的に示した断面図(図9(a):スキージング・ブレードによる厚さ調整、図9(b):粉末供給ノズルによる厚さ調整、図9(c):粉末吸引ノズルによる厚さ調整)FIG. 9A is a cross-sectional view schematically showing a mode of adjusting the thickness of a layer made of powder (FIG. 9A: thickness adjustment by a squeegee blade, FIG. 9B: thickness adjustment by a powder supply nozzle, FIG. 9 (c): Thickness adjustment by powder suction nozzle) 粉末床溶融結合法が実施される光造形複合加工のプロセス態様を模式的に示した断面図(図10(a):粉末層形成時、図10(b):固化層形成時、図10(c):積層途中)Cross-sectional views schematically showing a process aspect of stereolithography combined processing in which the powder bed fusion bonding method is performed (FIG. 10A: at the time of forming the powder layer, FIG. 10B: at the time of forming the solidified layer, FIG. c): During lamination 光造形複合加工機の構成を模式的に示した斜視図The perspective view which showed the composition of the optical modeling compound processing machine typically 光造形複合加工機の一般的な動作を示すフローチャートFlow chart showing general operation of stereolithography combined processing machine
 以下では、図面を参照して本発明の一実施形態をより詳細に説明する。図面における各種要素の形態および寸法は、あくまでも例示にすぎず、実際の形態および寸法を反映するものではない。 Hereinafter, an embodiment of the present invention will be described in more detail with reference to the drawings. The forms and dimensions of the various elements in the drawings are merely examples, and do not reflect actual forms and dimensions.
 本明細書において「粉末層」とは、例えば「金属粉末から成る金属粉末層」または「樹脂粉末から成る樹脂粉末層」を意味している。また「粉末層の所定箇所」とは、製造される三次元形状造形物の領域を実質的に指している。従って、かかる所定箇所に存在する粉末に対して光ビームを照射することによって、その粉末が焼結又は溶融固化して三次元形状造形物を構成することになる。更に「固化層」とは、粉末層が金属粉末層である場合には「焼結層又は溶融固化層」を意味し、粉末層が樹脂粉末層である場合には「硬化層又は溶融結合層」を意味している。 In this specification, “powder layer” means, for example, “a metal powder layer made of metal powder” or “a resin powder layer made of resin powder”. The “predetermined portion of the powder layer” substantially refers to the region of the three-dimensional shaped object to be manufactured. Therefore, by irradiating the powder existing at the predetermined location with a light beam, the powder is sintered or melted and solidified to form a three-dimensional shaped object. Further, “solidified layer” means “sintered layer or melt-solidified layer” when the powder layer is a metal powder layer, and “cured layer or melt-bonded layer” when the powder layer is a resin powder layer. "Means.
 また、本明細書で直接的または間接的に説明される“上下”の方向は、例えば造形プレートと三次元形状造形物との位置関係に基づく方向であって、造形プレートを基準にして三次元形状造形物が製造される側を「上方向」とし、その反対側を「下方向」とする。 Further, the “up and down” direction described directly or indirectly in the present specification is a direction based on the positional relationship between the modeling plate and the three-dimensional shaped object, for example, and is based on the modeling plate. The side on which the shaped object is manufactured is “upward”, and the opposite side is “downward”.
[粉末床溶融結合法]
 まず、本発明の製造方法の前提となる粉末床溶融結合法(いわゆるパウダーベッド方式)について説明する。特に粉末床溶融結合法において三次元形状造形物の切削処理を付加的に行う光造形複合加工を例として挙げる。図10は、光造形複合加工のプロセス態様を模式的に示しており、図11および図12は、粉末床溶融結合法と切削処理とを実施できる光造形複合加工機の主たる構成および動作のフローチャートをそれぞれ示している。
[Powder bed fusion bonding method]
First, the powder bed fusion bonding method (so-called powder bed method) which is a premise of the production method of the present invention will be described. In particular, an optical modeling combined processing that additionally performs a cutting process of a three-dimensional shaped object in the powder bed fusion bonding method will be given as an example. FIG. 10 schematically shows a process aspect of stereolithographic composite processing, and FIGS. 11 and 12 are flowcharts of the main configuration and operation of the stereolithographic composite processing machine capable of performing the powder bed fusion bonding method and the cutting process. Respectively.
 光造形複合加工機1は、図11に示すように、粉末層形成手段2、光ビーム照射手段3および切削手段4を備えている。 The stereolithography combined processing machine 1 includes a powder layer forming means 2, a light beam irradiation means 3, and a cutting means 4, as shown in FIG.
 粉末層形成手段2は、金属粉末または樹脂粉末などの粉末を所定厚みで敷くことによって粉末層を形成するための手段である。光ビーム照射手段3は、粉末層の所定箇所に光ビームLを照射するための手段である。切削手段4は、積層化した固化層の表面、すなわち、三次元形状造形物の表面を削るための手段である。 The powder layer forming means 2 is means for forming a powder layer by spreading a powder such as a metal powder or a resin powder with a predetermined thickness. The light beam irradiation means 3 is a means for irradiating a predetermined portion of the powder layer with the light beam L. The cutting means 4 is means for cutting the surface of the laminated solidified layer, that is, the surface of the three-dimensional shaped object.
 粉末層形成手段2は、図10に示すように、粉末テーブル25、スキージング・ブレード23、造形テーブル20および造形プレート21を主に有して成る。粉末テーブル25は、外周が壁26で囲まれた粉末材料タンク28内にて上下に昇降できるテーブルである。スキージング・ブレード23は、粉末テーブル25上の粉末19を造形テーブル20上へと供して粉末層22を得るべく水平方向に移動できるブレードである。造形テーブル20は、外周が壁27で囲まれた造形タンク29内にて上下に昇降できるテーブルである。そして、造形プレート21は、造形テーブル20上に配され、三次元形状造形物の土台となるプレートである。 The powder layer forming means 2 mainly comprises a powder table 25, a squeezing blade 23, a modeling table 20, and a modeling plate 21, as shown in FIG. The powder table 25 is a table that can be moved up and down in a powder material tank 28 whose outer periphery is surrounded by a wall 26. The squeezing blade 23 is a blade that can move in the horizontal direction to obtain the powder layer 22 by supplying the powder 19 on the powder table 25 onto the modeling table 20. The modeling table 20 is a table that can be moved up and down in a modeling tank 29 whose outer periphery is surrounded by a wall 27. The modeling plate 21 is a plate that is arranged on the modeling table 20 and serves as a base for a three-dimensional modeled object.
 光ビーム照射手段3は、図11に示すように、光ビーム発振器30およびガルバノミラー31を主に有して成る。光ビーム発振器30は、光ビームLを発する機器である。ガルバノミラー31は、発せられた光ビームLを粉末層22にスキャニングする手段、すなわち、光ビームLの走査手段である。 The light beam irradiation means 3 mainly has a light beam oscillator 30 and a galvanometer mirror 31 as shown in FIG. The light beam oscillator 30 is a device that emits a light beam L. The galvanometer mirror 31 is means for scanning the emitted light beam L into the powder layer 22, that is, scanning means for the light beam L.
 切削手段4は、図11に示すように、エンドミル40および駆動機構41を主に有して成る。エンドミル40は、積層化した固化層の表面、すなわち、三次元形状造形物の表面を削るための切削工具である。駆動機構41は、エンドミル40を所望の切削すべき箇所へと移動させる手段である。 The cutting means 4 mainly includes an end mill 40 and a drive mechanism 41 as shown in FIG. The end mill 40 is a cutting tool for cutting the surface of the laminated solidified layer, that is, the surface of the three-dimensional shaped object. The drive mechanism 41 is means for moving the end mill 40 to a desired location to be cut.
 光造形複合加工機1の動作について詳述する。光造形複合加工機1の動作は、図12のフローチャートに示すように、粉末層形成ステップ(S1)、固化層形成ステップ(S2)および切削ステップ(S3)から構成されている。粉末層形成ステップ(S1)は、粉末層22を形成するためのステップである。かかる粉末層形成ステップ(S1)では、まず造形テーブル20をΔt下げ(S11)、造形プレート21の上面と造形タンク29の上端面とのレベル差がΔtとなるようにする。次いで、粉末テーブル25をΔt上げた後、図10(a)に示すようにスキージング・ブレード23を粉末材料タンク28から造形タンク29に向かって水平方向に移動させる。これによって、粉末テーブル25に配されていた粉末19を造形プレート21上へと移送させることができ(S12)、粉末層22の形成が行われる(S13)。粉末層22を形成するための粉末材料としては、例えば「平均粒径5μm~100μm程度の金属粉末」および「平均粒径30μm~100μm程度のナイロン、ポリプロピレンまたはABS等の樹脂粉末」を挙げることができる。粉末層22が形成されたら、固化層形成ステップ(S2)へと移行する。固化層形成ステップ(S2)は、光ビーム照射によって固化層24を形成するステップである。かかる固化層形成ステップ(S2)においては、光ビーム発振器30から光ビームLを発し(S21)、ガルバノミラー31によって粉末層22上の所定箇所へと光ビームLをスキャニングする(S22)。これによって、粉末層22の所定箇所の粉末を焼結又は溶融固化させ、図10(b)に示すように固化層24を形成する(S23)。光ビームLとしては、炭酸ガスレーザ、Nd:YAGレーザ、ファイバレーザまたは紫外線などを用いてよい。 The operation of the stereolithography combined processing machine 1 will be described in detail. The operation of the optical modeling complex machine 1 includes a powder layer forming step (S1), a solidified layer forming step (S2), and a cutting step (S3), as shown in the flowchart of FIG. The powder layer forming step (S1) is a step for forming the powder layer 22. In the powder layer forming step (S1), first, the modeling table 20 is lowered by Δt (S11) so that the level difference between the upper surface of the modeling plate 21 and the upper end surface of the modeling tank 29 becomes Δt. Next, after raising the powder table 25 by Δt, the squeezing blade 23 is moved in the horizontal direction from the powder material tank 28 toward the modeling tank 29 as shown in FIG. Thereby, the powder 19 arranged on the powder table 25 can be transferred onto the modeling plate 21 (S12), and the powder layer 22 is formed (S13). Examples of the powder material for forming the powder layer 22 include “metal powder having an average particle diameter of about 5 μm to 100 μm” and “resin powder such as nylon, polypropylene, or ABS having an average particle diameter of about 30 μm to 100 μm”. it can. When the powder layer 22 is formed, the process proceeds to a solidified layer forming step (S2). The solidified layer forming step (S2) is a step of forming the solidified layer 24 by light beam irradiation. In the solidified layer forming step (S2), the light beam L is emitted from the light beam oscillator 30 (S21), and the light beam L is scanned to a predetermined location on the powder layer 22 by the galvano mirror 31 (S22). As a result, the powder at a predetermined location of the powder layer 22 is sintered or melted and solidified to form the solidified layer 24 as shown in FIG. 10B (S23). As the light beam L, a carbon dioxide laser, an Nd: YAG laser, a fiber laser, an ultraviolet ray, or the like may be used.
 粉末層形成ステップ(S1)および固化層形成ステップ(S2)は、交互に繰り返して実施する。これにより、図10(c)に示すように複数の固化層24が積層化する。 The powder layer forming step (S1) and the solidified layer forming step (S2) are alternately repeated. As a result, a plurality of solidified layers 24 are laminated as shown in FIG.
 積層化した固化層24が所定厚みに達すると(S24)、切削ステップ(S3)へと移行する。切削ステップ(S3)は、積層化した固化層24の表面、すなわち、三次元形状造形物の表面を削るためのステップである。エンドミル40(図10(c)および図11参照)を駆動させることによって切削ステップが開始される(S31)。例えば、エンドミル40が3mmの有効刃長さを有する場合、三次元形状造形物の高さ方向に沿って3mmの切削処理を行うことができるので、Δtが0.05mmであれば60層分の固化層24が積層した時点でエンドミル40を駆動させる。具体的には駆動機構41によってエンドミル40を移動させながら、積層化した固化層24の表面に対して切削処理を施すことになる(S32)。このような切削ステップ(S3)の最終では、所望の三次元形状造形物が得られているか否かを判断する(S33)。所望の三次元形状造形物が依然得られていない場合では、粉末層形成ステップ(S1)へと戻る。以降、粉末層形成ステップ(S1)~切削ステップ(S3)を繰り返し実施して更なる固化層の積層化および切削処理を実施することによって、最終的に所望の三次元形状造形物が得られる。 When the laminated solidified layer 24 reaches a predetermined thickness (S24), the process proceeds to the cutting step (S3). The cutting step (S3) is a step for cutting the surface of the laminated solidified layer 24, that is, the surface of the three-dimensional shaped object. A cutting step is started by driving the end mill 40 (see FIG. 10C and FIG. 11) (S31). For example, when the end mill 40 has an effective blade length of 3 mm, a cutting process of 3 mm can be performed along the height direction of the three-dimensional shaped object. When the solidified layer 24 is laminated, the end mill 40 is driven. Specifically, a cutting process is performed on the surface of the laminated solidified layer 24 while moving the end mill 40 by the drive mechanism 41 (S32). At the end of such a cutting step (S3), it is determined whether or not a desired three-dimensional shaped object has been obtained (S33). When the desired three-dimensional shaped object is not yet obtained, the process returns to the powder layer forming step (S1). Thereafter, the powder layer forming step (S1) to the cutting step (S3) are repeatedly performed to further laminate the solidified layer and perform a cutting process, whereby a desired three-dimensional shaped object is finally obtained.
[本発明の製造方法]
 本発明は、固化層形成段階において特徴を有している。
[Production method of the present invention]
The present invention is characterized in the solidified layer forming stage.
 具体的には、本発明の製造方法は、図1(a)および図1(b)に示すように固化層24の形成段階において、固化層24内に生じる細孔10を減じることを含んで成る。より具体的には、本発明の製造方法は、図1(a)および図1(b)に示すように固化層24の形成段階において、固化層24内の残存ガスに起因して生じる細孔10を減じることを含んで成る。 Specifically, the manufacturing method of the present invention includes reducing pores 10 generated in the solidified layer 24 in the formation stage of the solidified layer 24 as shown in FIGS. 1 (a) and 1 (b). Become. More specifically, in the production method of the present invention, as shown in FIGS. 1 (a) and 1 (b), pores generated due to residual gas in the solidified layer 24 in the formation stage of the solidified layer 24. Comprising subtracting ten.
 ここでいう「細孔10」とは、図1(a)の右上拡大図に示すように固化層24内に形成される空隙を指し、断面視において特に限定されるものではないが20~100μmの寸法を有し得るものを指す。より具体的には、ここでいう「細孔10」とは、固化層24における固化密度が例えば80~100%の高密度領域に生じる空隙を指す。換言すれば、ここでいう「細孔10」とは、固化層24における固化密度が例えば80%未満の低/中密度領域には生じないものを指す。なお、固化層における固化密度が相対的に低い密度領域では、固化密度が相対的に低いことに起因していわゆるポーラス領域が内部に形成され得る。一方、本発明の一実施形態では、上述のように固化密度が相対的に高い密度領域内に細孔10が存在し得る。以上の事からも、本発明における「細孔10」は、固化層における固化密度が相対的に低い密度領域内に形成される「ポーラス領域」とは本質的に異なるものであることを確認的に付言しておく。 As used herein, “pore 10” refers to a void formed in the solidified layer 24 as shown in the upper right enlarged view of FIG. 1A, and is not particularly limited in cross-sectional view, but is 20 to 100 μm. Which can have the following dimensions: More specifically, the “pores 10” referred to here indicate voids generated in a high density region where the solidification density in the solidified layer 24 is, for example, 80 to 100%. In other words, the “pores 10” here refers to those that do not occur in the low / medium density region where the solidification density in the solidified layer 24 is less than 80%, for example. In the density region where the solidification density in the solidified layer is relatively low, a so-called porous region can be formed inside due to the relatively low solidification density. On the other hand, in one embodiment of the present invention, the pores 10 may exist in the density region where the solidification density is relatively high as described above. From the above, it is confirmed that the “pore 10” in the present invention is essentially different from the “porous region” formed in the density region where the solidification density in the solidified layer is relatively low. I will add to.
 特定の理論に拘束されるものではないが、本発明における「細孔10」は以下の現象により生じ得ると考えられる。具体的には、図2に示すように、光ビームLを照射して新たな固化層24Bを形成する際においては、光ビームLの照射熱が既に形成した下層に位置する固化層24Aに伝わり得る。光ビームLの照射熱が既に形成した下層に位置する固化層24Aに伝わると、当該固化層24A内に局所的に残存し得る残存ガス5が当該光ビームLの照射熱により膨張し得る。かかる残存ガス5の膨張により、既に形成した下層に位置する固化層24A内に局所的に細孔10が生じ得る。なお、ここでいう「残存ガス5」とは、特に限定されるものではないが、例えば、粉末層の所定箇所に光ビームを照射した際に生じるガスが固化層内に残存することに起因して生じるものであり得る。 Although not bound by a specific theory, it is considered that the “pore 10” in the present invention can be caused by the following phenomenon. Specifically, as shown in FIG. 2, when a new solidified layer 24B is formed by irradiation with the light beam L, the irradiation heat of the light beam L is transmitted to the solidified layer 24A located in the already formed lower layer. obtain. When the irradiation heat of the light beam L is transmitted to the solidified layer 24A located in the already formed lower layer, the residual gas 5 that can locally remain in the solidified layer 24A can be expanded by the irradiation heat of the light beam L. Due to the expansion of the residual gas 5, pores 10 may be locally generated in the solidified layer 24 </ b> A located in the already formed lower layer. The “residual gas 5” here is not particularly limited. For example, the gas remaining when the light beam is applied to a predetermined portion of the powder layer remains in the solidified layer. Can occur.
 図1(b)に示すように、固化層24内の残存ガスに起因して内部に局所的に生じ得る細孔10を減じると、固化層24の内部は空隙が減じられた状態となり得る。ここでいう「細孔を減じる」とは、細孔の数および/又は細孔の寸法を減じることを実質的に指す。また、ここでいう「減じる」とは、完全に除去したものも含む。空隙が減じられると、細孔10が空隙を成していることに起因して細孔10が存在する領域の構造強度が相対的に弱くなるといった問題を抑制することができ得る。これにより、固化層内の構造強度が相対的に弱い部分(すなわち、細孔10が存在する領域)を起点としたクラックの発生を抑制することができ得る。これにより、クラックの発生抑制に起因して、最終的に得られる三次元形状造形物100の構造強度を維持し得る。その結果として、本発明の一実施形態では、高精度な三次元形状造形物100を得ることができ得る。 As shown in FIG. 1B, when the pores 10 that can be locally generated due to the residual gas in the solidified layer 24 are reduced, the inside of the solidified layer 24 can be in a state in which voids are reduced. As used herein, “reducing pores” substantially refers to reducing the number of pores and / or the size of the pores. The term “reduce” as used herein includes those that are completely removed. When the voids are reduced, it is possible to suppress the problem that the structural strength of the region where the pores 10 are present is relatively weak due to the pores 10 forming voids. Thereby, generation | occurrence | production of the crack starting from the part (namely, area | region where the pore 10 exists) where the structural strength in a solidified layer is relatively weak can be suppressed. Thereby, the structural strength of the finally obtained three-dimensional shaped article 100 can be maintained due to the suppression of the occurrence of cracks. As a result, in one embodiment of the present invention, a highly accurate three-dimensional shaped object 100 can be obtained.
 なお、本発明は、下記態様を採ってよい。 In addition, this invention may take the following aspect.
<細孔の特定態様>
 一態様では、図3に示すように固化層24内の細孔10と当該細孔10の周縁部分の温度差に基づき、細孔10の発生箇所を予め特定してよい。
<Specific embodiment of pore>
In one embodiment, as shown in FIG. 3, the generation location of the pore 10 may be specified in advance based on the temperature difference between the pore 10 in the solidified layer 24 and the peripheral portion of the pore 10.
 具体的には、図3に示すように、固化層24の形成段階で固化層24の最上面24aに光ビームLを照射し、赤外線カメラ50、特に赤外線サーモグラフィを用いて、光ビームLを照射した最上面24aの所定部分の下方領域の温度分布を測定する。特定の理論に拘束されるものではないが、固化層24内に細孔10が生じている場合、細孔10が空隙を成すことに起因して固化層24の最上面24aに照射した光ビームLの照射熱が固化層24を介して細孔10内へ伝わり得る。この時、細孔10は空隙を成すため、これに起因して光ビームLの照射熱が当該空隙に留まる状態、すなわち“こもる”状態となり得る。そのため、赤外線カメラ50を用いて照射した最上面24aの所定部分の下方領域の温度分布を測定した場合、平面視において図3の右上図に示すように細孔10発生部分の温度域60と細孔10発生部分の周縁部分の温度域70との温度分布が異なり得る。具体的には、平面視において図3の右上図に示すように細孔10発生部分の温度域60が細孔10発生部分の周縁部分の温度域70よりも温度が相対的に高くなり得る(細孔部10の発生部分:図3右上図の黒色部分)。かかる温度分布の違いを利用することで、細孔10がいずれの箇所に生じているかを特定でき得る。 Specifically, as shown in FIG. 3, the uppermost surface 24a of the solidified layer 24 is irradiated with the light beam L at the formation stage of the solidified layer 24, and the light beam L is irradiated using the infrared camera 50, particularly infrared thermography. The temperature distribution in the region below the predetermined portion of the uppermost surface 24a is measured. Although not limited to a specific theory, when the pores 10 are formed in the solidified layer 24, the light beam applied to the uppermost surface 24a of the solidified layer 24 due to the pores 10 forming voids. The irradiation heat of L can be transferred into the pores 10 through the solidified layer 24. At this time, since the pore 10 forms a void, the irradiation heat of the light beam L can be caused to remain in the void due to this, that is, it can be in a “muffled” state. Therefore, when the temperature distribution in the lower region of the predetermined portion of the uppermost surface 24a irradiated with the infrared camera 50 is measured, as shown in the upper right view of FIG. The temperature distribution with the temperature region 70 at the peripheral portion of the hole 10 generation portion may be different. Specifically, as shown in the upper right view of FIG. 3, the temperature range 60 of the pore 10 generation portion can be relatively higher than the temperature range 70 of the peripheral portion of the pore 10 generation portion in plan view ( Part where the pores 10 are generated: black part in the upper right diagram in FIG. 3). By utilizing such a difference in temperature distribution, it can be specified where the pores 10 are generated.
<既に形成した固化層内に生じた細孔を減じるための態様>
 具体的には、本発明の一実施形態では下記態様により既に形成した固化層内の細孔を減じてよい。
<Mode for reducing pores generated in already formed solidified layer>
Specifically, in one embodiment of the present invention, pores in the solidified layer already formed may be reduced according to the following mode.
 一態様では、図4に示すように細孔10の発生箇所を特定した上で、細孔10を含んで成る固化層24の所定部分24’に光ビームLを照射して当該部分24’を溶融させて、細孔10を減じてよい。 In one embodiment, as shown in FIG. 4, the location where the pores 10 are generated is specified, and then the predetermined portion 24 ′ of the solidified layer 24 including the pores 10 is irradiated with the light beam L so as to It may be melted to reduce the pores 10.
 具体的には、図4(a)に示すように、上述の赤外線カメラ50を用いて細孔10の発生箇所を予め特定する。細孔10の発生箇所を特定した後、図4(b)に示すように細孔10を含んで成る固化層24の所定部分24’に対して光ビームLを照射する。なお、ここでいう「光ビームL」とは、新たな固化層(図4(b)内の最上層の固化層に相当)の形成に用いる際のものであってよい。光ビームLを照射すると、細孔10を含んで成る固化層24の所定部分24’が溶融状態となり得る。その後、図4(c)に示すように溶融状態となった細孔10を含んで成る固化層24の所定部分24’は、かかる部分24’の温度が低下することで固化状態となり得る。以上により、固化層24内に存在し得る細孔10を減じることができ得る。 Specifically, as shown in FIG. 4A, the location where the pores 10 are generated is specified in advance using the infrared camera 50 described above. After specifying the location where the pores 10 are generated, a predetermined portion 24 ′ of the solidified layer 24 including the pores 10 is irradiated with the light beam L as shown in FIG. Here, the “light beam L” may be used when forming a new solidified layer (corresponding to the uppermost solidified layer in FIG. 4B). When the light beam L is irradiated, the predetermined portion 24 ′ of the solidified layer 24 including the pores 10 can be in a molten state. Thereafter, as shown in FIG. 4C, the predetermined portion 24 ′ of the solidified layer 24 including the pores 10 in a molten state can be in a solidified state when the temperature of the portion 24 ′ decreases. As described above, the pores 10 that may exist in the solidified layer 24 can be reduced.
 なお、図5に示すように光ビームLの照射条件を調節して、既に形成した固化層24内の細孔10を減じてよい。 In addition, as shown in FIG. 5, the irradiation conditions of the light beam L may be adjusted to reduce the pores 10 in the solidified layer 24 that has already been formed.
 一態様では、固化層形成段階において、上述の赤外線カメラを用いて特定する細孔10の発生箇所の数が所定基準を超えている場合には、例えば図5(a)に示すように光ビームLの出力を適宜変更してよい。具体的には、細孔10の発生箇所の数が所定基準を超えている場合には、固化層24内に細孔10を生じさせる原因となり得る残存ガスが多いと判断し、それに応じて光ビームLの出力を増大させてよい。光ビームLの出力を増大させると、それに起因して下層に位置する細孔10を含んで成る既に形成した固化層24の所定部分に対して相対的に大きな光ビームLの照射熱を供することができ得る。これにより、細孔10を含んで成る既に形成した固化層24の所定部分を好適に溶融状態にすることができ得る。その後、温度低下に伴い、好適な溶融状態である細孔10を含んで成る既に形成した固化層24の所定部分を好適に固化状態とすることができ得る。これにより、既に形成した固化層24内の細孔10を好適に減じることができ得る。なお、例えば、図5(a)に示すように、所定基準と比べて超過する当該特定した細孔10の発生箇所の数の程度に応じて、通常の固化層形成時と比べて光ビームLの出力をどの程度増大させるか決定してよい。一例を挙げると、所定基準と比べて超過する当該特定した細孔10の発生箇所の数の程度が相対的に小さい場合、通常の固化層形成時と比べて増大させる光ビームLの出力の程度は相対的に小さくてよい。所定基準と比べて超過する当該特定した細孔10の発生箇所の数の程度が相対的に大きい場合、通常の固化層形成時と比べて増大させる光ビームLの出力の程度は相対的に大きくてよい。 In one embodiment, in the solidified layer forming stage, when the number of occurrence locations of the pores 10 specified using the above-described infrared camera exceeds a predetermined standard, for example, as shown in FIG. You may change the output of L suitably. Specifically, when the number of occurrence locations of the pores 10 exceeds a predetermined standard, it is determined that there is a large amount of residual gas that can cause the pores 10 in the solidified layer 24, and light is accordingly emitted. The output of the beam L may be increased. When the output of the light beam L is increased, a relatively large irradiation heat of the light beam L is provided to a predetermined portion of the already formed solidified layer 24 including the pores 10 located in the lower layer. Can be. Thereby, the predetermined part of the already formed solidified layer 24 including the pores 10 can be suitably brought into a molten state. Thereafter, as the temperature decreases, a predetermined portion of the already formed solidified layer 24 including the pores 10 in a suitable molten state can be suitably solidified. Thereby, the pores 10 already formed in the solidified layer 24 can be suitably reduced. For example, as shown in FIG. 5A, the light beam L is compared with that in the normal solidified layer formation, depending on the degree of occurrence of the identified pores 10 that exceeds the predetermined reference. It may be determined how much to increase the output of. As an example, when the number of occurrence locations of the specified pore 10 that exceeds the predetermined standard is relatively small, the degree of output of the light beam L that is increased as compared with the normal solidified layer formation. May be relatively small. When the number of occurrence locations of the specified pores 10 that exceed the predetermined standard is relatively large, the degree of output of the light beam L to be increased is relatively large as compared with the normal solidified layer formation. It's okay.
 一態様では、固化層形成段階において、上述の赤外線カメラを用いて特定する細孔10の発生箇所の数が所定基準を超えている場合には、例えば図5(b)に示すように光ビームLの走査速度を適宜変更してよい。具体的には、細孔10の発生箇所の数が所定基準を超えている場合には、固化層24内に細孔10を生じさせる原因となり得る残存ガスが多いと判断し、それに応じて光ビームLの走査速度を小さくしてよい。光ビームLの走査速度を小さくすると、それに起因して下層に位置する細孔10を含んで成る既に形成した固化層24の所定部分に対して相対的に十分に光ビームLの照射熱を供することができ得る。これにより、細孔10を含んで成る既に形成した固化層24の所定部分を好適に溶融状態にすることができ得る。その後、温度低下に伴い、好適な溶融状態である細孔10を含んで成る既に形成した固化層24の所定部分を好適に固化状態とすることができ得る。これにより、既に形成した固化層24内の細孔10を好適に減じることができ得る。なお、例えば、図5(b)に示すように、所定基準と比べて超過する当該特定した細孔10の発生箇所の数の程度に応じて、通常の固化層形成時と比べて光ビームLの走査速度をどの程度小さくするか決定してよい。一例を挙げると、所定基準と比べて超過する当該特定した細孔10の発生箇所の数の程度が相対的に小さい場合、通常の固化層形成時と比べて小さくする光ビームLの走査速度の程度は相対的に小さくてよい。所定基準と比べて超過する当該特定した細孔10の発生箇所の数の程度が相対的に大きい場合、通常の固化層形成時と比べて小さくする光ビームLの走査速度の程度は相対的に大きくてよい。 In one aspect, in the solidified layer forming stage, when the number of occurrence locations of the pores 10 specified using the above-described infrared camera exceeds a predetermined reference, for example, as shown in FIG. The scanning speed of L may be changed as appropriate. Specifically, when the number of occurrence locations of the pores 10 exceeds a predetermined standard, it is determined that there is a large amount of residual gas that can cause the pores 10 in the solidified layer 24, and light is accordingly emitted. The scanning speed of the beam L may be reduced. When the scanning speed of the light beam L is reduced, the irradiation heat of the light beam L is provided relatively sufficiently to a predetermined portion of the already formed solidified layer 24 including the pores 10 located in the lower layer. Can be. Thereby, the predetermined part of the already formed solidified layer 24 including the pores 10 can be suitably brought into a molten state. Thereafter, as the temperature decreases, a predetermined portion of the already formed solidified layer 24 including the pores 10 in a suitable molten state can be suitably solidified. Thereby, the pores 10 already formed in the solidified layer 24 can be suitably reduced. Note that, for example, as shown in FIG. 5B, the light beam L is compared with that at the time of normal solidified layer formation, depending on the degree of occurrence of the identified pores 10 that exceeds the predetermined reference. It may be determined how much the scanning speed is reduced. As an example, when the number of occurrence locations of the specified pores 10 that exceed the predetermined standard is relatively small, the scanning speed of the light beam L that is smaller than that at the time of normal solidified layer formation. The degree may be relatively small. When the degree of the number of occurrences of the specified pores 10 that exceed the predetermined standard is relatively large, the degree of scanning speed of the light beam L that is reduced compared to the normal solidified layer formation is relatively large. It can be big.
 一態様では、固化層形成段階において、上述の赤外線カメラを用いて特定する細孔10の発生箇所の数が所定基準を超えている場合には、例えば図5(c)に示すように光ビームLのスポット径を適宜変更してよい。具体的には、細孔10の発生箇所の数が所定基準を超えている場合には、固化層24内に細孔10を生じさせる原因となり得る残存ガスが多いと判断し、それに応じて光ビームLのスポット径を通常の固化層形成時よりも小さくしてよい。光ビームLのスポット径が小さくなると、それに起因して下層に位置する細孔10を含んで成る既に形成した固化層24の所定部分に対して相対的に大きな光ビームLの照射熱を供することができ得る。これにより、細孔10を含んで成る既に形成した固化層24の所定部分を好適に溶融状態にすることができ得る。その後、温度低下に伴い、好適な溶融状態である細孔10を含んで成る既に形成した固化層24の所定部分を好適に固化状態とすることができ得る。これにより、既に形成した固化層24内の細孔10を好適に減じることができ得る。なお、例えば、図5(c)に示すように、所定基準と比べて超過する当該特定した細孔10の発生箇所の数の程度に応じて、通常の固化層形成時と比べて光ビームLのスポット径をどの程度小さくさせるか決定してよい。一例を挙げると、所定基準と比べて超過する当該特定した細孔10の発生箇所の数の程度が相対的に小さい場合、通常の固化層形成時と比べて小さくする光ビームLのスポット径の程度は相対的に小さくてよい。所定基準と比べて超過する当該特定した細孔10の発生箇所の数の程度が相対的に大きい場合、通常の固化層形成時と比べて小さくする光ビームLのスポット径の程度は相対的に大きくてよい。 In one aspect, in the solidified layer forming stage, when the number of occurrence locations of the pores 10 specified using the above-described infrared camera exceeds a predetermined standard, for example, as shown in FIG. The spot diameter of L may be changed as appropriate. Specifically, when the number of occurrence locations of the pores 10 exceeds a predetermined standard, it is determined that there is a large amount of residual gas that can cause the pores 10 in the solidified layer 24, and light is accordingly emitted. The spot diameter of the beam L may be made smaller than that during normal solidified layer formation. When the spot diameter of the light beam L is reduced, a relatively large irradiation heat of the light beam L is provided to a predetermined portion of the already formed solidified layer 24 including the pores 10 located in the lower layer. Can be. Thereby, the predetermined part of the already formed solidified layer 24 including the pores 10 can be suitably brought into a molten state. Thereafter, as the temperature decreases, a predetermined portion of the already formed solidified layer 24 including the pores 10 in a suitable molten state can be suitably solidified. Thereby, the pores 10 already formed in the solidified layer 24 can be suitably reduced. For example, as shown in FIG. 5C, the light beam L is compared with that in the normal solidified layer formation, depending on the degree of occurrence of the identified pores 10 that exceeds the predetermined reference. It may be determined how much the spot diameter is to be reduced. As an example, when the number of occurrence locations of the specified pores 10 that exceed the predetermined standard is relatively small, the spot diameter of the light beam L that is smaller than that at the time of normal solidified layer formation. The degree may be relatively small. When the degree of the number of occurrences of the specified pores 10 that exceed the predetermined standard is relatively large, the degree of the spot diameter of the light beam L to be made smaller than that at the time of normal solidified layer formation is relatively large. It can be big.
 一態様では、図6に示すように細孔10を含んで成る固化層24の所定部分を外部から押圧して、既に形成した固化層24内の細孔10を減じてよい。 In one embodiment, as shown in FIG. 6, a predetermined portion of the solidified layer 24 including the pores 10 may be pressed from the outside to reduce the pores 10 in the already formed solidified layer 24.
 具体的には、図6に示すように細孔10の発生箇所を特定した上で細孔10を含んで成る固化層24の所定部分24’を例えば切削手段4(但し、切削刃が設置されていないもの)で外部から押圧してよい。押圧方向としては、図6に示すように積層方向に対向する方向であってよい。細孔10を含んで成る固化層24の所定部分24’を外部から押圧することで、細孔10を押しつぶすことができ得る。これにより、固化層24内の細孔10を減じることができ得る。なお、細孔10を含んで成る固化層24の所定部分24’の押圧前後の固化層の最上面24aの高さを比べると、その差は約10μmであり得る(図6内の拡大図参照)。そのため、固化層24の最上面24aの平坦性は確保されていると言える。 Specifically, as shown in FIG. 6, the location where the pores 10 are generated is specified, and the predetermined portion 24 ′ of the solidified layer 24 including the pores 10 is, for example, the cutting means 4 (however, a cutting blade is installed). May be pressed from the outside. The pressing direction may be a direction facing the stacking direction as shown in FIG. By pressing the predetermined portion 24 ′ of the solidified layer 24 including the pores 10 from the outside, the pores 10 can be crushed. Thereby, the pores 10 in the solidified layer 24 can be reduced. When the height of the uppermost surface 24a of the solidified layer before and after pressing the predetermined portion 24 ′ of the solidified layer 24 including the pores 10 is compared, the difference can be about 10 μm (see the enlarged view in FIG. 6). ). Therefore, it can be said that the flatness of the uppermost surface 24a of the solidified layer 24 is ensured.
 なお、細孔10の大きさおよび形状によっては、細孔10を含んで成る固化層24の所定部分24’を外部から押圧するのみでは好適に細孔10を押しつぶすことができない場合があり得る。そこで、図7に示すように切削手段4を用いて細孔10を含んで成る固化層24の所定部分24’に外部から押圧力を加えつつ、切削手段4を回転させて細孔10を含んで成る固化層24の所定部分24’に回転力を更に加えてよい。これにより、細孔10をより好適に押しつぶすことができ得る。その結果、既に形成した固化層24内の細孔10をより好適に減じることができ得る。 Depending on the size and shape of the pores 10, the pores 10 may not be properly crushed only by pressing the predetermined portion 24 'of the solidified layer 24 including the pores 10 from the outside. Therefore, as shown in FIG. 7, the cutting means 4 is rotated by rotating the cutting means 4 while applying a pressing force to the predetermined portion 24 ′ of the solidified layer 24 including the pores 10 using the cutting means 4. A rotational force may be further applied to the predetermined portion 24 ′ of the solidified layer 24. Thereby, the pore 10 can be crushed more suitably. As a result, the pores 10 already formed in the solidified layer 24 can be more suitably reduced.
 一態様では、図8に示すように細孔10を含む固化層24の所定部分24’を切削加工に付して、細孔10を減じてよい。 In one embodiment, as shown in FIG. 8, the predetermined portion 24 ′ of the solidified layer 24 including the pores 10 may be subjected to cutting to reduce the pores 10.
 具体的には、赤外線カメラを用いて細孔10の発生箇所を特定した上で、図8(a)に示すように細孔10を含んで成る固化層24の所定部分24’を、切削手段4を用いて切削加工に付す。切削加工に付すと、図8(b)に示すように固化層24内に細孔10を含んで成る固化層24の所定部分24’が存在し得ない状態になる。固化層24内に細孔10を含んで成る固化層24の所定部分24’が存在しない状態にした後、図8(c)に示すように当該所定部分24’が存在しない箇所に粉末19を充填する。粉末19を充填した後、図8(d)に示すように、当該粉末19を充填した部分に光ビームLを照射して、充填した粉末19を溶融固化させる。以上により、既に形成した固化層24内から細孔10を減じることができ得る。 Specifically, after specifying the location where the pores 10 are generated using an infrared camera, a predetermined portion 24 ′ of the solidified layer 24 including the pores 10 as shown in FIG. 4 is used for cutting. When subjected to the cutting process, as shown in FIG. 8B, the predetermined portion 24 ′ of the solidified layer 24 including the pores 10 cannot exist in the solidified layer 24. After the predetermined portion 24 ′ of the solidified layer 24 including the pores 10 does not exist in the solidified layer 24, the powder 19 is applied to a place where the predetermined portion 24 ′ does not exist as shown in FIG. Fill. After filling the powder 19, as shown in FIG. 8D, the portion filled with the powder 19 is irradiated with the light beam L to melt and solidify the filled powder 19. As described above, the pores 10 can be reduced from the already formed solidified layer 24.
 一態様では、図9に示すように固化層の形成に用いる粉末の供給条件を調節して、既に形成した固化層内の細孔を減じてよい。 In one embodiment, as shown in FIG. 9, the supply conditions of the powder used for forming the solidified layer may be adjusted to reduce the pores in the already formed solidified layer.
 一態様では、上述の赤外線カメラを用いて特定する細孔10の発生箇所の数が所定基準を超えている場合には、以下の態様をとってよい。具体的には、固化層24内に細孔10を生じさせる原因となり得る残存ガスが多いと判断し、それに応じて例えば図9(a)に示すようにスキージング・ブレード23を用いて形成される粉末層22の厚さを適宜調整してよい。例えば、図9(a)に示すように、所定基準と比べて超過する当該特定した細孔10の発生箇所の数の程度に応じて、かかる層の厚さをL、L(>L)、又はL(>L)としてよい。なお、粉末層22の厚さが相対的に小さくなると、粉末層22の所定箇所に光ビームを照射して新たな固化層を形成する際に、下層に位置する細孔10を含んで成る既に形成した固化層24内の所定部分に対して光ビームの照射熱を好適に供することができ得る。これにより、下層に位置する細孔10を含んで成る既に形成した固化層24内の所定部分を好適に溶融状態にすることができ得る。その後、温度低下に伴い、好適な溶融状態である下層に位置する細孔10を含んで成る既に形成した固化層24内の所定部分を好適に固化状態とすることができ得る。これにより、既に形成した固化層24内の細孔10を好適に減じることができ得る。 In one aspect, when the number of occurrence locations of the pores 10 specified using the above-described infrared camera exceeds a predetermined reference, the following aspect may be taken. Specifically, it is determined that there is a large amount of residual gas that can cause the pores 10 in the solidified layer 24, and the squeezing blade 23 is formed accordingly, for example, as shown in FIG. The thickness of the powder layer 22 may be adjusted as appropriate. For example, as shown in FIG. 9A, the thickness of the layer is set to L 1 , L 2 (> L) according to the degree of the number of occurrence locations of the specified pore 10 that exceeds the predetermined standard. 1 ), or L 3 (> L 2 ). When the thickness of the powder layer 22 becomes relatively small, when a new solidified layer is formed by irradiating a predetermined portion of the powder layer 22 with a light beam, the powder layer 22 already includes the pores 10 located in the lower layer. The irradiation heat of the light beam can be suitably provided to a predetermined portion in the formed solidified layer 24. Thereby, the predetermined part in the already formed solidified layer 24 including the pores 10 located in the lower layer can be suitably brought into a molten state. Thereafter, as the temperature decreases, a predetermined portion in the already formed solidified layer 24 including the pores 10 located in the lower layer in a suitable molten state can be suitably solidified. Thereby, the pores 10 already formed in the solidified layer 24 can be suitably reduced.
 なお、これまで主として粉末床溶融結合法(いわゆるパウダーベッド方式)で固化層を形成する態様に基づき説明してきたが、これに限定されることなく、例えば図8(b)に示すようにパウダースプレー方式で固化層を形成してよい。ここでいう「パウダースプレー方式」とは、粉末供給と光ビーム照射とを実質的に同時に行って固化層を形成する方式である。粉末床溶融結合法(いわゆるパウダーベッド方式)との対比でいうと、パウダースプレー方式は、固化層を得るに際して粉末層形成を行わないといった特徴を有する。つまり、パウダースプレー方式では、粉末供給箇所に光ビームが照射されると共に、その粉末供給箇所に対して粉末等が直接的に供給されることを通じて、その供給される粉末から固化層を形成する。 In addition, although it demonstrated based on the aspect which forms the solidified layer mainly by the powder bed fusion | bonding method (so-called powder bed system) until now, it is not limited to this, For example, as shown in FIG.8 (b), it is a powder spray. The solidified layer may be formed by a method. Here, the “powder spray method” is a method of forming a solidified layer by performing powder supply and light beam irradiation substantially simultaneously. In contrast to the powder bed fusion bonding method (so-called powder bed method), the powder spray method has a feature that no powder layer is formed when a solidified layer is obtained. That is, in the powder spray method, a light beam is irradiated to a powder supply location, and a solidified layer is formed from the supplied powder by supplying powder or the like directly to the powder supply location.
 一態様では、上述の赤外線カメラを用いて特定する細孔10の発生箇所の数が所定基準を超えている場合には、以下の態様をとってよい。具体的には、固化層24内に細孔10を生じさせる原因となり得る残存ガスが多いと判断し、それに応じて例えば図9(b)に示すように粉末供給ノズル80から粉末19を供給して形成される粉末19から成る層の厚さを適宜調整してよい。例えば、図9(b)に示すように、所定基準と比べて超過する当該特定した細孔10の発生箇所の数の程度に応じて、かかる層の厚さをL、L(>L)、又はL(>L)としてよい。なお、粉末19から成る層の厚さが相対的に小さくなると、新たに供給した粉末19に光ビームを照射して新たな固化層を形成する際に、下層に位置する細孔10を含んで成る既に形成した固化層24内の所定部分に対して光ビームの照射熱を好適に供することができ得る。これにより、下層に位置する細孔10を含んで成る既に形成した固化層24内の所定部分を好適に溶融状態にすることができ得る。その後、温度低下に伴い、好適な溶融状態である下層に位置する細孔10を含んで成る既に形成した固化層24内の所定部分を好適に固化状態とすることができ得る。これにより、既に形成した固化層24内の細孔10を好適に減じることができ得る。 In one aspect, when the number of occurrence locations of the pores 10 specified using the above-described infrared camera exceeds a predetermined reference, the following aspect may be taken. Specifically, it is determined that there is a large amount of residual gas that can cause the pores 10 in the solidified layer 24, and the powder 19 is supplied from the powder supply nozzle 80 accordingly, for example, as shown in FIG. The thickness of the layer formed of the powder 19 may be adjusted as appropriate. For example, as shown in FIG. 9B, the thickness of the layer is set to L 1 , L 2 (> L) according to the degree of the number of occurrence locations of the specified pore 10 that exceeds the predetermined standard. 1 ), or L 3 (> L 2 ). When the thickness of the layer made of the powder 19 is relatively small, when the newly supplied powder 19 is irradiated with a light beam to form a new solidified layer, the pores 10 located in the lower layer are included. The irradiation heat of the light beam can be suitably supplied to a predetermined portion in the already formed solidified layer 24. Thereby, the predetermined part in the already formed solidified layer 24 including the pores 10 located in the lower layer can be suitably brought into a molten state. Thereafter, as the temperature decreases, a predetermined portion in the already formed solidified layer 24 including the pores 10 located in the lower layer in a suitable molten state can be suitably solidified. Thereby, the pores 10 already formed in the solidified layer 24 can be suitably reduced.
 一態様では、上述の赤外線カメラを用いて特定する細孔10の発生箇所の数が所定基準を超えている場合には、以下の態様をとってよい。具体的には、固化層24内に細孔10を生じさせる原因となり得る残存ガスが多いと判断し、それに応じて例えば図9(c)に示すように粉末吸引ノズル90から粉末19を吸引して形成される粉末19から成る層の厚さを適宜調整してよい。例えば、図9(c)に示すように、所定基準と比べて超過する当該特定した細孔10の発生箇所の数の程度に応じて、かかる層の厚さをL、L(>L)、又はL(>L)としてよい。なお、粉末19から成る層の厚さが相対的に小さくなると、粉末19に光ビームを照射して新たな固化層を形成する際に、下層に位置する細孔10を含んで成る既に形成した固化層24内の所定部分に対して光ビームの照射熱を好適に供することができ得る。これにより、下層に位置する細孔10を含んで成る既に形成した固化層24内の所定部分を好適に溶融状態にすることができ得る。その後、温度低下に伴い、好適な溶融状態である下層に位置する細孔10を含んで成る既に形成した固化層24内の所定部分を好適に固化状態とすることができ得る。これにより、既に形成した固化層24内の細孔10を好適に減じることができ得る。 In one aspect, when the number of occurrence locations of the pores 10 specified using the above-described infrared camera exceeds a predetermined reference, the following aspect may be taken. Specifically, it is determined that there is a large amount of residual gas that can cause the pores 10 in the solidified layer 24, and the powder 19 is sucked from the powder suction nozzle 90 accordingly, for example, as shown in FIG. The thickness of the layer formed of the powder 19 may be adjusted as appropriate. For example, as shown in FIG. 9C, the thickness of the layer is set to L 1 , L 2 (> L) according to the degree of the number of occurrence locations of the identified pore 10 that exceeds the predetermined standard. 1 ), or L 3 (> L 2 ). In addition, when the thickness of the layer made of the powder 19 becomes relatively small, when the powder 19 is irradiated with a light beam to form a new solidified layer, the powder 19 is already formed including the pores 10 located in the lower layer. The irradiation heat of the light beam can be suitably provided to a predetermined portion in the solidified layer 24. Thereby, the predetermined part in the already formed solidified layer 24 including the pores 10 located in the lower layer can be suitably brought into a molten state. Thereafter, as the temperature decreases, a predetermined portion in the already formed solidified layer 24 including the pores 10 located in the lower layer in a suitable molten state can be suitably solidified. Thereby, the pores 10 already formed in the solidified layer 24 can be suitably reduced.
<新たに形成する固化層内に生じ得る細孔を減じるための態様>
 上記では、既に形成した固化層内に生じた細孔を減じるための態様について主として説明してきたが、新たに形成する固化層内に生じ得る細孔を減じるためには下記の態様をとってよい。
<Mode for reducing pores that may be generated in a newly formed solidified layer>
In the above, the embodiment for reducing the pores generated in the already formed solidified layer has been mainly described. However, in order to reduce the pores that can be generated in the newly formed solidified layer, the following embodiment may be adopted. .
 具体的には、下記態様により新たに形成する固化層内に生じ得る細孔を減じてよい。 Specifically, pores that may be generated in the newly formed solidified layer may be reduced according to the following embodiment.
 上述のとおり、光ビームLの照射熱が既に形成した下層に位置する固化層24Aに伝わると、当該固化層24A内に局所的に残存し得る残存ガス5が当該光ビームLの照射熱により膨張し、かかる残存ガス5の膨張により、固化層24A内に局所的に細孔10が生じ得る(図2参照)。特定の理論に拘束されるものではないが、特に、かかる残存ガス5は、形成時の固化層の温度が高い程発生し易いと考えられ得る。そこで、この点を鑑み、新たな固化層を形成する際には、細孔10が生じる原因となり得る残存ガス5の発生を事前抑制するために、通常の固化層形成時と比べて光ビームLの照射エネルギーを相対的に小さくする、光ビームLの走査速度を相対的に大きくする、および/または光ビームLのスポット径を相対的に大きくするといった光ビームLの照射条件の調節を行うことがよい。また、これに限定されず、新たな固化層を形成する際には、細孔10が生じる原因となり得る残存ガス5の発生を事前抑制するために、母材となる既に形成した固化層(造形物)および/または造形プレートの温度を低くして新たな粉末層表面の温度を低くするといった温度調節を行うことがよい。 As described above, when the irradiation heat of the light beam L is transmitted to the solidified layer 24A located in the already formed lower layer, the residual gas 5 that can locally remain in the solidified layer 24A is expanded by the irradiation heat of the light beam L. Then, the expansion of the residual gas 5 may locally generate pores 10 in the solidified layer 24A (see FIG. 2). Although not bound by any particular theory, it can be considered that such residual gas 5 is particularly likely to be generated as the temperature of the solidified layer at the time of formation increases. Therefore, in view of this point, when forming a new solidified layer, in order to suppress in advance the generation of the residual gas 5 that may cause the pores 10, the light beam L is compared with that during normal solidified layer formation. The irradiation conditions of the light beam L are adjusted such that the irradiation energy of the light beam L is relatively reduced, the scanning speed of the light beam L is relatively increased, and / or the spot diameter of the light beam L is relatively increased. Is good. Further, the present invention is not limited to this, and when a new solidified layer is formed, in order to suppress in advance the generation of the residual gas 5 that may cause the pores 10, a solidified layer (modeling that has already been formed as a base material) is formed. The temperature of the new powder layer by lowering the temperature of the object) and / or the modeling plate.
 以上、本発明の一実施形態について説明してきたが、本発明の適用範囲のうちの典型例を例示したに過ぎない。従って、本発明はこれに限定されず、種々の改変がなされ得ることを当業者は容易に理解されよう。 As mentioned above, although one Embodiment of this invention has been demonstrated, it has only illustrated the typical example of the application scope of this invention. Therefore, those skilled in the art will readily understand that the present invention is not limited thereto and various modifications can be made.
 なお、上述のような本発明の一実施形態は、次の好適な態様を包含している。
第1態様
 光ビームの照射によって複数の固化層を逐次形成して三次元形状造形物を製造する方法であって、
 前記固化層内の残存ガスに起因して生じる細孔を減じることを含んで成る、三次元形状造形物の製造方法。
第2態様
 上記第1態様において、 前記固化層における固化密度が80~100%の高密度領域に生じる前記細孔を減じる、三次元形状造形物の製造方法。
第3態様
 上記第1態様又は第2態様において、前記細孔と該細孔の周縁部分との温度差に基づき、該細孔の発生箇所を特定する、三次元形状造形物の製造方法。
第4態様
 上記第3態様において、前記細孔を含んで成る前記固化層の所定部分に前記光ビームを照射して該部分を溶融固化させ、前記細孔を減じる、三次元形状造形物の製造方法。
第5態様
 上記第3態様又は第4態様において、前記細孔を含んで成る前記固化層の前記所定部分を外部から押圧して、前記細孔を減じる、三次元形状造形物の製造方法。
第6態様
 上記第3態様~第5態様のいずれかにおいて、前記細孔を含んで成る前記固化層の前記所定部分を切削加工に付して、前記細孔を減じる、三次元形状造形物の製造方法。
第7態様
 上記第1態様~第6態様のいずれかにおいて、前記固化層を粉末床溶融結合法で形成す
One embodiment of the present invention as described above includes the following preferred modes.
First aspect :
A method for producing a three-dimensional shaped object by sequentially forming a plurality of solidified layers by irradiation with a light beam,
A method for producing a three-dimensional shaped object comprising reducing pores generated due to residual gas in the solidified layer.
Second aspect :
In the first aspect described above, the method for producing a three-dimensional shaped article, wherein the pores generated in a high density region having a solidification density of 80 to 100% in the solidified layer is reduced.
Third aspect :
In the said 1st aspect or the 2nd aspect, the manufacturing method of the three-dimensional shape molded article which pinpoints the generation | occurrence | production location of this pore based on the temperature difference of the said pore and the peripheral part of this pore.
Fourth aspect :
In the third aspect, a method for producing a three-dimensional shaped article, wherein a predetermined portion of the solidified layer including the pores is irradiated with the light beam to melt and solidify the portion to reduce the pores.
Fifth aspect :
In the said 3rd aspect or the 4th aspect, the said predetermined part of the said solidification layer containing the said pore is pressed from the outside, The manufacturing method of the three-dimensional shaped molded article which reduces the said pore.
Sixth aspect :
The method for producing a three-dimensional shaped structure according to any one of the third to fifth aspects, wherein the predetermined portion of the solidified layer including the pores is subjected to a cutting process to reduce the pores.
Seventh aspect :
In any one of the first to sixth aspects, the solidified layer is formed by a powder bed melt bonding method.
 本発明の一実施形態に係る三次元形状造形物の製造方法を実施することによって、種々の物品を製造することができる。例えば、『粉末層が無機質の金属粉末層であって、固化層が焼結層となる場合』では、得られる三次元形状造形物をプラスチック射出成形用金型、プレス金型、ダイカスト金型、鋳造金型、鍛造金型などの金型として用いることができる。一方、『粉末層が有機質の樹脂粉末層であって、固化層が硬化層となる場合』では、得られる三次元形状造形物を樹脂成形品として用いることができる。 Various articles can be manufactured by carrying out the manufacturing method of a three-dimensional shaped object according to an embodiment of the present invention. For example, in “when the powder layer is an inorganic metal powder layer and the solidified layer is a sintered layer”, the resulting three-dimensional shaped article is a plastic injection mold, a press mold, a die-cast mold, It can be used as a mold such as a casting mold or a forging mold. On the other hand, in “when the powder layer is an organic resin powder layer and the solidified layer is a hardened layer”, the obtained three-dimensional shaped article can be used as a resin molded product.
関連出願の相互参照Cross-reference of related applications
 本出願は、日本国特許出願第2016-130009号(出願日:2016年6月30日、発明の名称:「三次元形状造形物の製造方法」)に基づくパリ条約上の優先権を主張する。当該出願に開示された内容は全て、この引用により、本明細書に含まれるものとする。 This application claims priority under the Paris Convention based on Japanese Patent Application No. 2016-130009 (filing date: June 30, 2016, title of invention: “Method for producing three-dimensional shaped object”) . All the contents disclosed in the application are incorporated herein by this reference.
 5    残存ガス
 10   細孔
 19   粉末
 24   固化層
 24’  固化層の所定部分
 60   細孔発生部分の温度域
 70   細孔発生部分の周縁部分の温度域
 100  三次元形状造形物
 L    光ビーム
5 Residual gas 10 Pore 19 Powder 24 Solidified layer 24 ′ Predetermined portion of solidified layer 60 Temperature range of pore generating portion 70 Temperature range of peripheral portion of pore generating portion 100 Three-dimensional shaped object L Light beam

Claims (7)

  1.  光ビームの照射によって複数の固化層を逐次形成して三次元形状造形物を製造する方法であって、
     前記固化層内の残存ガスに起因して生じる細孔を減じることを含んで成る、三次元形状造形物の製造方法。
    A method for producing a three-dimensional shaped object by sequentially forming a plurality of solidified layers by irradiation with a light beam,
    A method for producing a three-dimensional shaped object comprising reducing pores generated due to residual gas in the solidified layer.
  2.  前記固化層における固化密度が80~100%の高密度領域に生じる前記細孔を減じる、請求項1に記載の三次元形状造形物の製造方法。 The method for producing a three-dimensional shaped article according to claim 1, wherein the pores generated in a high density region having a solidification density of 80 to 100% in the solidified layer is reduced.
  3.  前記細孔と該細孔の周縁部分との温度差に基づき、該細孔の発生箇所を特定する、請求項1に記載の三次元形状造形物の製造方法。 The method for producing a three-dimensional shaped article according to claim 1, wherein a location where the pores are generated is specified based on a temperature difference between the pores and a peripheral portion of the pores.
  4.  前記細孔を含んで成る前記固化層の所定部分に前記光ビームを照射して該部分を溶融固化させ、前記細孔を減じる、請求項3に記載の三次元形状造形物の製造方法。 The method for producing a three-dimensional shaped article according to claim 3, wherein a predetermined portion of the solidified layer including the pores is irradiated with the light beam to melt and solidify the portion to reduce the pores.
  5.  前記細孔を含んで成る前記固化層の前記所定部分を外部から押圧して、前記細孔を減じる、請求項3に記載の三次元形状造形物の製造方法。 The method for producing a three-dimensional shaped object according to claim 3, wherein the predetermined portion of the solidified layer including the pores is pressed from outside to reduce the pores.
  6.  前記細孔を含んで成る前記固化層の前記所定部分を切削加工に付して、前記細孔を減じる、請求項3に記載の三次元形状造形物の製造方法。 The method for producing a three-dimensional shaped object according to claim 3, wherein the predetermined portion of the solidified layer including the pores is subjected to a cutting process to reduce the pores.
  7.  前記固化層を粉末床溶融結合法で形成する、請求項1に記載の三次元形状造形物の製造方法。
     
    The manufacturing method of the three-dimensional shape molded article according to claim 1, wherein the solidified layer is formed by a powder bed fusion bonding method.
PCT/JP2017/023580 2016-06-30 2017-06-27 Method for manufacturing three-dimensionally shaped molding WO2018003798A1 (en)

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JP2010065259A (en) * 2008-09-09 2010-03-25 Panasonic Electric Works Co Ltd Method for producing three-dimensionally shaped object
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