WO2017212381A1 - Procédé et système d'épuration de dioxyde de carbone à partir d'émissions de véhicule - Google Patents
Procédé et système d'épuration de dioxyde de carbone à partir d'émissions de véhicule Download PDFInfo
- Publication number
- WO2017212381A1 WO2017212381A1 PCT/IB2017/053272 IB2017053272W WO2017212381A1 WO 2017212381 A1 WO2017212381 A1 WO 2017212381A1 IB 2017053272 W IB2017053272 W IB 2017053272W WO 2017212381 A1 WO2017212381 A1 WO 2017212381A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- cartridges
- granules
- scrubbing
- carbon dioxide
- pipe
- Prior art date
Links
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims abstract description 93
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims abstract description 93
- 239000001569 carbon dioxide Substances 0.000 title claims abstract description 49
- 238000005201 scrubbing Methods 0.000 title claims abstract description 38
- 238000000034 method Methods 0.000 title claims abstract description 25
- 239000008187 granular material Substances 0.000 claims abstract description 34
- 239000000126 substance Substances 0.000 claims abstract description 18
- 239000007789 gas Substances 0.000 claims description 33
- HUAUNKAZQWMVFY-UHFFFAOYSA-M sodium;oxocalcium;hydroxide Chemical compound [OH-].[Na+].[Ca]=O HUAUNKAZQWMVFY-UHFFFAOYSA-M 0.000 claims description 30
- 230000007246 mechanism Effects 0.000 claims description 13
- 238000010521 absorption reaction Methods 0.000 claims description 9
- 238000005203 dry scrubbing Methods 0.000 abstract description 3
- 239000000523 sample Substances 0.000 description 16
- 238000002474 experimental method Methods 0.000 description 14
- 238000013461 design Methods 0.000 description 7
- 238000005259 measurement Methods 0.000 description 7
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 6
- 238000002485 combustion reaction Methods 0.000 description 6
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 5
- 239000003546 flue gas Substances 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 238000003915 air pollution Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 239000002803 fossil fuel Substances 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000013618 particulate matter Substances 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000002594 sorbent Substances 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- 238000012935 Averaging Methods 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 239000003225 biodiesel Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002906 medical waste Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- -1 petrol Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000011172 small scale experimental method Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
- F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
- F01N3/022—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous
- F01N3/0224—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous the structure being granular
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
- F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
- F01N3/022—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous
- F01N3/0226—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous the structure being fibrous
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
- F01N3/0828—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents characterised by the absorbed or adsorbed substances
- F01N3/0857—Carbon oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/30—Alkali metal compounds
- B01D2251/304—Alkali metal compounds of sodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/30—Alkali metal compounds
- B01D2251/306—Alkali metal compounds of potassium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/40—Alkaline earth metal or magnesium compounds
- B01D2251/404—Alkaline earth metal or magnesium compounds of calcium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/01—Engine exhaust gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/12—Methods and means for introducing reactants
- B01D2259/128—Solid reactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/45—Gas separation or purification devices adapted for specific applications
- B01D2259/4566—Gas separation or purification devices adapted for specific applications for use in transportation means
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2570/00—Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
- F01N2570/10—Carbon or carbon oxides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
Definitions
- the invention relates to the field of pollution control of vehicle exhausts. More particularly, the invention relates to method or system to separate or remove carbon dioxide from vehicle exhausts. More particularly, the invention relates to a system using a carbon dioxide absorbent to capture or extract the carbon dioxide gas and then removing the absorbed carbon dioxide.
- Scrubber is usually referred to pollution control devices that use liquid to wash unwanted pollutants from a gas stream. It also describes systems that inject a dry reagent or slurry into a dirty exhaust stream to "wash out” acid gases. Scrubbers are one of the primary devices that control gaseous emissions, especially acid gases.
- Scrubber systems are a diverse group of air pollution control devices that are used to remove some particulates and/or gases from industrial exhaust streams for example the scrubber to remove carbon dioxide from the air of submarines. Scrubbers can also be used for heat recovery from hot gases by flue-gas condensation.
- the scrubbing systems can be wet or dry based on the manner they treat the flue gas. Dry scrubbing systems are used to remove acid gases (such as S0 2 and HC1) primarily from combustion sources and for the removal of odorous and corrosive gases from wastewater treatment plant operations, medical waste incinerators, industrial and utility boilers and a few municipal waste combustors. There are a number of dry type scrubbing system designs which consist of two main parts: a device to introduce the acid gas sorbent material into the gas stream and a particulate matter control device to remove reaction products, excess sorbent material as well as any particulate matter already in the flue gas.
- a device to introduce the acid gas sorbent material into the gas stream and a particulate matter control device to remove reaction products, excess sorbent material as well as any particulate matter already in the flue gas.
- the present invention discloses a carbon scrubbing method is to capture carbon dioxide from vehicular emissions so as to prevent it from entering the atmosphere. Furthermore, with increasing global concerns about climate change there is a continuous need to develop devices such as those disclosed in this application in order to reduce C0 2 emissions.
- the present invention has been made in view of the above-described issue and provides for a method to remove carbon dioxide from vehicular emissions.
- the purpose of the invention is to provide a scrubbing system for a vehicle, comprising of a scrubbing device designed to remove the emitted C0 2 by the vehicle.
- Said scrubbing device follows a dry scrubbing method using granules of chemicals that absorb carbon dioxide, for example soda lime.
- Within the said scrubbing system is a device which holds said granules in place as both the exhaust moves through them and the vehicle moves. These granules are preferably held in removable cartridges wherein the granules are sandwiched between wire meshes.
- the scrubbing device cartridges are places in coiled or twisted pipe.
- the coiled or twisted pipe serves the following purposes: 1 ) to slow down the gases, so that the reaction between C0 2 and the chemical has more time to occur before the gases leave the vehicle. 2) a large length of piping can be fitted into a relatively small volume, making it easily to attach to the underside of a car.
- Another preferred embodiment of the invention is to have a locking mechanism for the cartridges in the pipe so as to ensure that the cartridges stay in place and to allow accessibility of the cartridges for replacement as desired.
- the scrubber system is preferred to be fitted within the exhaust system of the vehicle such as to receive the exhaust of vehicles.
- the unique features of the invention are the removable cartridges which are easily extracted and replaced and the coiled or twisted pipe that it gives the gases a larger distance over which to react with chemicals while restricting the size of the device.
- the invention can be used in any vehicle running on the combustion of fossil fuels.
- the invention results in reduction of vehicular C0 2 emissions. .
- the C0 2 is stored in the actual chemical form and can be released into a container when the cartridges are removed and replaced.
- the invention therefore provides for a method and system to remove carbon dioxide from vehicular emissions.
- the scrubbing system used in the method is designed to remove the emitted C0 2 of the vehicle by fixing a scrubbing system in the vehicle exhaust system so as to receive the vehicular emissions or exhaust prior to disposal from the vehicle, said system comprising of one or more scrubbing device fitted within the pipe through a locking mechanism.
- the scrubbing device is a cartridge comprising granules of chemicals that absorb carbon dioxide, preferably soda lime. Once the exhaust gases to flow through the scrubbing device, the C0 2 is absorbed by the scrubbing device before release of the exhaust gases.
- the scrubbing device is removable and/or reusable.
- Figure 1 A-C Depict the soda lime cartridge of the invention
- Figure ID Gives a few examples of coiled and twisted pipes
- Figure 2 Depicts the positioning of the cartridge in the pipe
- Figure 3 Depicts the locking mechanism of the cartridges in the pipe
- Figure 4a-d Shows the photograph of one of the embodiment of the locking mechanism of the cartridge in the pipe.
- Figure 5 Depicts cross section of a cartridge comprising multiple pairs of wire meshes
- Figure 6 Depicts top view of various pairs of wire meshes having granules of the C02 absorbing chemicals in different positions.
- Figure 7 Depicts a cartridge assembly in the exhaust pipe wherein the edges of the wire mesh at both the ends of the cartridge is visible.
- Figure 8 Depicts the variation in C0 2 concentration with time measured by each of the probes in Example 5.
- Figure 9 Depicts the difference between the measurements of the Pre and Post probes, i.e the amount of C0 2 absorbed vs time in Example 5.
- Figure 10 Depicts the graph of difference between pre and post amount of C0 2 absorbed vs time for Example 6
- the method to remove carbon dioxide from vehicular emissions uses: ⁇ Granules of chemicals that absorb carbon dioxide. Examples include soda lime.
- Removable Cartridges that consist of wire meshes that hold the granules in place as both the exhaust moves through them and the vehicle moves
- the entire system is then fitted to the exhausts of vehicles.
- the chemical granules contained in the series of wire-meshes within the coiling pipe reacts with the Carbon dioxide as the exhaust gases pass through the pipe.
- the air coming out of the disclosed system has a reduced concentration of carbon dioxide.
- the removable cartridges can then be extracted and replaced.
- the invention can be used in any vehicle running on the combustion of fossil fuels.
- the invention reduces CO 2 emissions.
- soda lime is feasible for use in vehicles.
- the experiment showed that soda lime is able to function efficiently and react with carbon dioxide at the high temperatures and in the presence of the pollutants present in vehicle exhausts. It also showed that, at these temperatures, soda lime does not decompose or change form. While other chemicals may be used in the cartridges other than soda lime, the experiment showed soda lime to be practical for such an application.
- Soda lime cartridges in pipe The wire mesh cartridges containing soda lime granules arranged in various manners, such as parallel pipes, inter-twined pipes, flexible pipes, pipes in series etc. are the various embodiments for the C0 2 scrubbing.
- Figures 1A-D show the construction of a removable cartridge, and the coiled pipes in which the cartridges are to be placed.
- the cartridge itself is a cylinder containing granules of carbon dioxide absorbing chemicals.
- the tops and bottoms of the cylinder are made of wire meshes, fine enough to hold the granules in place, the construction of the cartridge is shown in Figure 1 A
- Figure IB and 1C show what the cartridge will look like.
- Figure ID gives a few examples of suitable coiled pipes for use in the device.
- Figures 1A depict the blown up description of the cartridge wherein the solid ring of the cartridge (also shown in Figure 1C side view) is filled with granules and then both sides are covered with the wire mesh.
- FIG. IB The top view of the cartridge with the soda lime granules being visible through the wire mesh is depicted in Figure IB.
- Figure ID Some examples of coiled pipes the cartridges are to be fitted into are shown in Figure ID.
- the cartridges can also be placed in the pipe in various manners. Alone or in a series as depicted in Figure 2.
- Figure 2 shows the placement of the cartridges into a section of the coiled pipes. The cross sectional area of the cartridges must be flush with the cross sectional area of the pipe.
- Locking mechanism for cartridges The pipes containing cartridges have various locking mechanism including the one disclosed in figure two.
- the locks are so arranged so as to allow replacement of one or two or more or all cartridges at one time.
- Figure 3 shows a preferred embodiment of the locking mechanism to attach the cartridge to the pipe. Screw-like arms are attached to the cartridge, along with caps on either end which can be screwed onto adjoining sections of the pipe.
- the pipe itself must have a helical groove at the ends where the cartridges are to be placed so that they can be screwed on.
- Figure 4a shows a cartridge locking mechanism to implement the invention.
- the central hollow part is where the scrubber is housed and the on either side the exhaust pipe is present which can be curved or coiled as desired.
- Figure 4b shows the grooves on the outside of the pipe and
- Figure 4c shows the grooves on the inside of the scrubbing device.
- the grooves on the exhaust pipe are screwed into the grooves on the inside of the scrubbing chamber, holding it in place as depicted in Figure 4d.
- the invention was tested in a motor plant for its working and efficiency and for one of the experiments a cartridge using a 15 cm long section of an 80 dia pipe (88.9 mm in diameter).
- the cartridge secured to the pipe was to secure to the test bed with triangular flanges.
- the wire mesh space was 2X2mm.
- Granules or pieces of soda lime which would be held together within mesh and not pass through the mesh was used to fill the cartridge and then it attached to the exhaust.
- the Figure 7 shows a cartridge assembly design used in the example. The following measurements were recorded
- Amount of carbon dioxide absorbed by the cartridge- Horiba CO 2 probes were used for this measurement. One probe was placed before the cartridge and directly after the engine (pre- probe) and the second probe was placed after the cartridge (post-probe). The difference in the readings recorded by the two probes was used to calculate the amount of carbon dioxide absorbed by the cartridge.
- the rate in change of absorption of carbon dioxide- the C0 2 probes were set to take readings at a frequency of l OHz at frequent time intervals.
- the engine was started at idling (700 rpm) and the C0 2 and pressure were recorded through the probe.
- the temperature was increased at regular intervals of 5 minutes by increasing the rpms of the engine.
- the experiment was run as shown in the table above. The experiment was thus for testing for a total of 20 minutes with the probes making measurements every 0.1 seconds. The experiment was run continuously with no stoppage or pauses. Observations
- Back pressure which is the pressure felt by the system and measured immediately after the turbocharger was measured to be 60 millibars at idling without the cartridge.
- Figure 8 graph shows the variation in C0 2 concentration with time measured by each of the probes.
- the blue line is the C0 2 concentration before the cartridge (Pre) and the red line represents the C0 2 concentration after the concentration (Post).
- Concentration is measured on the y axis in ppm (parts per million) and time is measured on the x axis in seconds. The spikes and drops in C0 2 concentration occur at points when the throttle was changed, increasing the temperature and flow rate of exhaust gases.
- Figure 9 shows the difference between the measurements of the Pre and Post probes, i.e the amount of C0 2 absorbed, vs time.
- the sudden spikes in the said figure correlate with the engine's rpms and hence the temperature of the exhaust gases have been increased.
- the first spike appears when temperature is increased from 85 degrees Celsius to 155 degrees Celsius.
- the second spike appears at an increase from 155 to 185. Because this reversed the process and resulted in C0 2 being emitted rather than released, the temperature was reduced once more to 155 degrees Celsius.
- the cartridge can successfully reduce C0 2 emissions from vehicles.
- a coiled pipe which alternates in diameter with some lengths of it being narrow and others being wide can be used for better efficiency.
- the wider stretches of pipe will further slow down the exhaust gases and allow the device to become more efficient if the cartridges are placed in these sections.
- the narrow sections of the pipe will speed up the exhaust gases during the time that they are travelling between cartridges and help counteract the increase in back pressure.
- Figure 10 shows the results on a graph of the experiment conducted in Example 6.
- the amount of C0 2 absorbed is shown in the y axis in hundreds of parts per million.
- the graph of Figure 10 depicts the difference between pre and post cartridge amount of CO 2 absorbed vs time. The fluctuations are accounted for by the fact that the flow rate and temperature in the exhaust fluctuated a little with time.
- the frequency of the readings and the frequency of the cycle of the engine also collude to form the waveform- like graph as seen in Figure 10.
- Back pressure At idling, back pressure is 60 bars and once the engine is started, back pressure escalated to about 83 bars. This is only a 23% increase in back pressure as compared to a 66.67% increase with the single mesh cartridge design of Example 5. This is the most significant difference in result that the new design does reduce back pressure. Using more meshes would further reduce the back pressure generated by the scrubber and allow the coiled pipe to be used in such a way as not to significantly affect the vehicles fuel efficiency.
- the cartridge configuration of the invention does not hinder the absorption of C0 2 and is at least 2-3% more efficient. The efficiency can therefore be further enhanced though other embodiments of the invention by changing several other factors:
- the number of meshes can be increased feasibly, depending on granule size. For example 1 mesh per cm of pipe, resulting in 10 meshes in 10 centimeters of pipe.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Biomedical Technology (AREA)
- Health & Medical Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
Abstract
La présente invention concerne un dispositif de purification d'air pour véhicules qui utilise une nouvelle structure d'épuration de CO2 et un procédé. Ledit dispositif d'épuration applique un procédé d'épuration à sec utilisant des granules de substances chimiques qui absorbent le dioxyde de carbone dans ledit dispositif d'épuration qui maintient lesdits granules en place lorsque l'échappement se déplace à travers ceux-ci et le véhicule se déplace. Ces granules sont de préférence maintenus dans des cartouches amovibles dans lesquelles ils sont pris en sandwich entre des mailles métalliques.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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IN201621019435 | 2016-06-06 | ||
IN201621019435 | 2016-06-06 |
Publications (1)
Publication Number | Publication Date |
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WO2017212381A1 true WO2017212381A1 (fr) | 2017-12-14 |
Family
ID=59153231
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/IB2017/053272 WO2017212381A1 (fr) | 2016-06-06 | 2017-06-02 | Procédé et système d'épuration de dioxyde de carbone à partir d'émissions de véhicule |
Country Status (1)
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WO (1) | WO2017212381A1 (fr) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110758764A (zh) * | 2019-10-21 | 2020-02-07 | 江苏卡途航空科技有限公司 | 一种具有尾气处理的食品车 |
DE102020215686A1 (de) | 2020-12-11 | 2022-06-15 | Thyssenkrupp Ag | CO2-Absorber |
DE102020215687A1 (de) | 2020-12-11 | 2022-06-15 | Thyssenkrupp Ag | CO2-Absorber |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
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US3593820A (en) * | 1970-04-30 | 1971-07-20 | William H Doub | Pipelike muffler with zigzag shape |
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CN110758764A (zh) * | 2019-10-21 | 2020-02-07 | 江苏卡途航空科技有限公司 | 一种具有尾气处理的食品车 |
DE102020215686A1 (de) | 2020-12-11 | 2022-06-15 | Thyssenkrupp Ag | CO2-Absorber |
DE102020215687A1 (de) | 2020-12-11 | 2022-06-15 | Thyssenkrupp Ag | CO2-Absorber |
WO2022122473A1 (fr) | 2020-12-11 | 2022-06-16 | Thyssenkrupp Marine Systems Gmbh | Électrolyseur à co2 |
WO2022122472A1 (fr) | 2020-12-11 | 2022-06-16 | Thyssenkrupp Marine Systems Gmbh | Sous-marin ayant un absorbeur de co2 |
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