WO2017185858A1 - Serial flash furnace and smelting method thereof - Google Patents

Serial flash furnace and smelting method thereof Download PDF

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Publication number
WO2017185858A1
WO2017185858A1 PCT/CN2017/074026 CN2017074026W WO2017185858A1 WO 2017185858 A1 WO2017185858 A1 WO 2017185858A1 CN 2017074026 W CN2017074026 W CN 2017074026W WO 2017185858 A1 WO2017185858 A1 WO 2017185858A1
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Prior art keywords
reaction body
flash furnace
tandem
molten
molten pool
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PCT/CN2017/074026
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French (fr)
Chinese (zh)
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李效东
邱江波
夏明�
黄小兵
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天津闪速炼铁技术有限公司
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Publication of WO2017185858A1 publication Critical patent/WO2017185858A1/en

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/001Dry processes
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B13/00Making spongy iron or liquid steel, by direct processes
    • C21B13/14Multi-stage processes processes carried out in different vessels or furnaces
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B13/00Obtaining lead
    • C22B13/02Obtaining lead by dry processes
    • C22B13/025Recovery from waste materials
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B19/00Obtaining zinc or zinc oxide
    • C22B19/30Obtaining zinc or zinc oxide from metallic residues or scraps
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B30/00Obtaining antimony, arsenic or bismuth
    • C22B30/06Obtaining bismuth
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B58/00Obtaining gallium or indium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/02Working-up flue dust
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B17/00Furnaces of a kind not covered by any preceding group
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D7/00Forming, maintaining, or circulating atmospheres in heating chambers
    • F27D7/06Forming or maintaining special atmospheres or vacuum within heating chambers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D7/00Forming, maintaining, or circulating atmospheres in heating chambers
    • F27D7/06Forming or maintaining special atmospheres or vacuum within heating chambers
    • F27D2007/063Special atmospheres, e.g. high pressure atmospheres
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27MINDEXING SCHEME RELATING TO ASPECTS OF THE CHARGES OR FURNACES, KILNS, OVENS OR RETORTS
    • F27M2003/00Type of treatment of the charge
    • F27M2003/16Treatment involving a chemical reaction
    • F27M2003/165Reduction
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Definitions

  • the invention belongs to the field of metallurgy, and in particular relates to a tandem flash furnace and a smelting method.
  • Flash metallurgy has been used only for the smelting of metal sulfide ore from the invention to the present.
  • the main reason is that the existing flash furnace only has one reaction space and is a micro-negative pressure environment in which gas-solid or gas-liquid can be carried out.
  • a single reaction space using a micro-negative pressure of a flash furnace cannot produce an effective reducing gas (CO + H 2 ) volume ratio exceeding 73% of the reducing gas, so there is no guarantee that the metal oxide will substantially complete the reduction in the suspended state.
  • the present invention aims to provide a tandem flash furnace to solve the problems of low efficiency of direct production of reducing gas in the existing flash furnace space, low concentration of active components, and high cost and high risk of introducing reducing gas from the outside.
  • a tandem flash furnace comprising an upper reaction body 5, a lower reaction body 1 and a connecting passage 7 communicating the two, the upper reaction body 5 being located at an upper portion of the lower reaction body 1, forming a tandem structure, the lower At least one molten pool 2 is disposed at a lower portion of the reaction body 1; the flash furnace further includes a rising flue 3 for discharging flue gas, and the rising flue 3 is connected to the lower reaction body 1 through the molten pool 2 Each of the molten pools 2 is provided with a slag discharge port.
  • the reaction body under the flash furnace 1 A reducing gas (CO + H 2 ) is produced while supplying heat to the lower reactant 1.
  • the gas pressure in the upper reaction body 5 may be greater than or equal to the pressure of the lower reaction body 1, preferably a high pressure condition, by constructing an independent high temperature and high pressure gasification space, so that the gasifying agent can be well vaporized, thereby improving the effective reducing gas ( Concentration of CO + H 2 ).
  • the pressure of the upper reaction body 5 can be controlled by adjusting the inner width of the connecting passage 7 and the amount of the oxygen-containing gas and the gasifying agent to be injected per unit time.
  • the tandem flash furnace of the invention has the advantages of compact structure, and can directly supply the heat and reducing atmosphere required for smelting to the reaction body 1 through the upper reaction body 5, and is returned to the smelting after being compared with some existing ones.
  • the gas smelting process avoids the heat loss of the high-temperature gas during the long-distance transportation process and the loss of the transmission pipeline (the high-temperature exhaust gas above 1000 °C has higher requirements on the pipeline material, the pipeline cost is high, and the service life is short); At the same time, since no auxiliary equipment (such as tail gas cracking conversion equipment, gas pressure conveying equipment, etc.) is required, the one-time investment is greatly reduced, and the failure rate of the whole equipment is greatly reduced, thereby reducing equipment cost and maintenance cost;
  • the upper reaction body 5 of the present invention has a simple gas-making principle, and can be realized by a simple chemical reaction using a gasifying agent (such as coal powder) and oxygen, without using other complicated and expensive methods (such as plasma ionization, etc.).
  • the upper reaction body 5 is located at the upper part of the lower reaction body 1, and is directly connected in series by a connecting passage 7 of not more than 2 m, so that the reducing gas stream produced by the upper reaction body 5 can enter from the top of the lower reaction body 1, thereby making the connection
  • the mineral powder added to the channel 7 and the reducing atmosphere have a longer contact time and increase the reduction rate of the metal oxide to be smelted.
  • the inner width of the connecting passage 7 is not more than 2/3 of the inner diameter of the lower reaction body 1, and the length is not more than 2 m.
  • the inner width of the connecting passage 7 is adjustable, and by controlling the inner width of the connecting passage 7, the pressure inside the upper reaction body 5 can be controlled, thereby affecting the gas generating efficiency, and at the same time, the upper reaction body 5 can be changed to the inner reaction body 1 to be transported.
  • the length of the connecting channel 7 is not more than 2 m, so as not to affect the efficiency of the upper reaction body 5 transferring heat to the reaction body 1 downward.
  • the connecting channel 7 is provided with a feeding device.
  • the ore powder to be smelted is added to the flash furnace through a feeding device disposed on the connecting passage 7, so that the ore powder and the reducing gas can be contacted and fully mixed before entering the lower reaction body 1, and the disintegration extends the ore to be smelted.
  • the smelting time of the powder in the lower reaction body 1 increases the reduction rate of the metal oxide to be smelted in the mineral powder.
  • the feeding device is one or more of a nozzle, a spray gun, and a sealing feed port; or a combination of one or more of a nozzle, a spray gun, and a sealing feed port and a burner.
  • the raw materials, fuel and auxiliary materials necessary for smelting are added to the flash furnace by setting a nozzle or a spray gun or a sealed feed port; if necessary, heat can be added to the lower reaction body 1 through the burner.
  • the feeding device can also be disposed on the top of the lower reaction body 1 or on the side wall of the lower reaction body 1 according to actual needs.
  • the upper reaction body 5 is provided with a spray gun or a nozzle for spraying an oxygen-containing gas and a gasifying agent into the upper reaction body 5.
  • a spray gun or a nozzle is disposed on the upper reaction body 5, penetrates the inner wall of the upper reaction body 5, and projects into the upper reaction body 5.
  • the spray gun or nozzle can be single or multi-channel, which can spray only one raw material, and the multi-channel spray gun or nozzle can simultaneously spray a variety of raw materials.
  • the spray gun or the nozzle sprays an oxygen-containing gas and a gasifying agent into the upper reaction body 5, such as a combination of one or more of coal powder, coal water slurry, water vapor, natural gas, fuel oil, methane and acetylene, to be used for producing a reduction.
  • the gas supplies heat to the lower reactant 1.
  • the gasification agent is pulverized coal, and the coal gasification technology is relatively mature, and at the same time, coal is also the most economical gas-making raw material in China at present.
  • an upper portion of the space in which the melt is contained in the molten pool 2 is provided with a space of a pyrophoric layer through which the molten charge falls.
  • the upper portion of the molten pool 2 is formed with a pyrophoric layer 6 that passes through the molten charge.
  • One implementation is to add coke to the lower reaction body 1 through a charging device disposed at the top of the connecting passage 7 or the lower reaction body 1, coke.
  • the particle size ranges from 1 to 11 mm, and is rapidly heated in the lower reaction body 1.
  • the heated coke particles fall on the surface of the molten pool 2 to form a porous carbon material-coke filter layer 6; if the coke has a particle size of less than 1 mm, Coke is depleted faster at high temperatures, but the particle size exceeds 11mm.
  • the center of the coke cannot be heated to a sufficient temperature, and the excessive particle size causes the gap between the coke particles to become large, which causes a loss of the metal oxide melt recovery rate through the pyrophoric layer 6.
  • the coke filter layer 6 can also be realized by adding a pulverized coal suitable for coking, and after the pulverized coal is burned off at a high temperature, coke particles can be formed.
  • the focal filter layer 6 has a space of 50-250 mm.
  • the space of the pyrophoric layer is 50-250 mm, preferably 100-200 mm. If the coke filter layer 6 is too thick, it will cause coke waste, increase energy consumption, and too thin to achieve the required reduction effect.
  • the thickness of the pyrophoric layer can be appropriately adjusted by adjusting the rate at which coke or pulverized coal suitable for coking is added to the lower reactant 1.
  • each of the molten pools 2 is provided with a side blowing arrangement for injecting fuel and oxygen-containing gas into the molten pool 2.
  • Fuel and gas are injected into the molten pool by side blowing to provide heat to the molten pool to maintain the molten pool at a certain high temperature.
  • the fuel is one of heavy oil, natural gas, liquefied petroleum gas, coal, coke, and hydrocarbon;
  • the oxygen-containing gas is air, an oxygen-air mixture, or process oxygen.
  • the position of the side blowing arrangement corresponds to a lower middle portion of the slag layer in the molten pool.
  • the side blowing is arranged in the lower part of the slag layer, so that the slag can be convected or tumbling, which facilitates the exchange of heat and substance between the upper and lower layers, thereby reducing the viscosity of the melt and improving the recovery rate of the metal to be smelted.
  • the side blowing arrangement includes side blowing holes symmetrically disposed on opposite side walls of the molten pool 2 and side blowing nozzles 4 disposed in the side blowing holes.
  • the number of the molten pools 2 is 1-4.
  • the setting of 1-4 molten pools 2 in the flash furnace can meet the needs of different smelting production.
  • the present invention also provides a method of smelting using the above-described tandem flash furnace.
  • the invention also protects the use of the flash furnace described above in smelting.
  • tandem flash furnace of the present invention has the following advantages:
  • the tandem flash furnace of the present invention is capable of producing a high-temperature, high-pressure, high-concentration reducing gas in the upper reaction body 5, and providing the lower reactant 1 with a reducing atmosphere and heat required for smelting, as opposed to being directly under the existing flash furnace.
  • Coal gasification in the reaction body 1 has higher quality of gasification on the one hand, and can provide a higher concentration of effective reducing gas for the smelting process, thereby making the reduction speed of the mineral powder in the lower reaction body 1 faster, and also making some
  • the space needs a high concentration reducing atmosphere to realize the reduction of the metal oxide by flash furnace smelting; on the other hand, the gas-making efficiency is higher, and it is not necessary for the lower reaction body 1 to undertake the task of gas-making again.
  • the smelting time of the powder in the flash furnace space increases the reduction rate of the metal to be smelted, reduces energy consumption, and improves economic efficiency.
  • the tandem flash furnace of the present invention connects the reaction body and the lower reaction body in series through a connecting channel of not more than 2 m, so that the reducing atmosphere and heat generated by the upper reaction body can be efficiently and quickly supplied to the lower reaction body, compared with the existing one.
  • FIG. 1 is a schematic structural view of a tandem flash furnace according to an embodiment of the present invention.
  • FIG. 2 is a schematic view showing a second structure of a tandem flash furnace according to an embodiment of the present invention
  • FIG. 3 is a schematic view showing a third structure of a tandem flash furnace according to an embodiment of the present invention.
  • FIG. 4 is a fourth structural schematic view of a tandem flash furnace according to an embodiment of the present invention.
  • FIG. 5 is a fifth structural schematic view of a tandem flash furnace according to an embodiment of the present invention.
  • FIG. 6 is a sixth structural schematic view of a tandem flash furnace according to an embodiment of the present invention.
  • FIG. 7 is a seventh structural schematic view of a tandem flash furnace according to an embodiment of the present invention.
  • FIG. 8 is a schematic structural view of an eighth type of a tandem flash furnace according to an embodiment of the present invention.
  • FIG. 9 is a schematic view showing a ninth structure of a tandem flash furnace according to an embodiment of the present invention.
  • FIG. 10 is a schematic structural view of a tenth type of a tandem flash furnace according to an embodiment of the present invention.
  • FIG. 11 is a schematic view showing a tenth structure of a tandem flash furnace according to an embodiment of the present invention.
  • first”, “second”, and the like are used for the purpose of description only, and are not to be construed as indicating or implying a relative importance or implicitly indicating the number of technical features indicated.
  • features defining “first”, “second”, etc. may include one or more of the features, either explicitly or implicitly.
  • connection In the description of the present invention, it should be noted that the terms “installation”, “connected”, and “connected” are to be understood broadly, and may be fixed or detachable, for example, unless otherwise explicitly defined and defined. Connected, or integrally connected; can be mechanical or electrical; can be directly connected, or indirectly connected through an intermediate medium, can be the internal communication of the two components.
  • Connected, or integrally connected can be mechanical or electrical; can be directly connected, or indirectly connected through an intermediate medium, can be the internal communication of the two components.
  • the specific meaning of the above terms in the present invention can be understood by a person of ordinary skill in the art.
  • a tandem flash furnace as shown in FIGS. 1-11, includes an upper reaction body 5, a lower reaction body 1 and a connecting passage 7 communicating the two, and the upper reaction body 5 is located at an upper portion of the lower reaction body 1 to form a tandem structure.
  • the lower part of the lower reaction body 1 is provided with at least one molten pool 2; the flash furnace further comprises a rising flue 3 for discharging flue gas, and the rising flue 3 is connected to the lower reaction body 1 through the molten pool 2, each molten pool 2
  • the gas-generating fuel and the oxygen-containing gas are sprayed into the upper reaction body 5 to generate a high concentration of reducing gas and release heat, and the dry metal oxide ore powder, the flux and the molten material are sprayed into the reaction body 1 downward.
  • the dispersed oxide melt formed in the droplet falls into the molten pool and enters the pyrophoric layer 6.
  • the melt penetrates the pyrophoric layer 6, the metal oxide to be smelted which is not completely reduced is reduced by carbothermal .
  • the gangue and the flux in the ore powder undergo a slagging reaction to form a slag having a low melting point.
  • a side blowing arrangement may be provided in the molten pool 2, and the fuel and the oxygen-containing gas are respectively injected into the melt by the side blowing.
  • the coal powder and the oxygen are respectively injected into the melt to be melted.
  • the pool 2 provides heat and achieves the tumbling of the melt, while maintaining the molten pool 2 in a strong reducing environment, and the remaining metal oxide to be smelted is completely reduced in the molten pool 2, thereby improving the recovery rate of the metal to be smelted.
  • the reduced low-boiling metal into the flue gas exits the furnace through the ascending flue 3, and can be collected by condensation or fuming, and the remaining molten metal is precipitated and layered in the molten pool 2 to form a layer.
  • Metal layer and slag layer, metal The melt is discharged from the molten pool 2 to obtain a crude metal, and the molten slag is discharged from the slag discharge port.
  • tandem flash furnace provided by the invention is applied to the smelting of soot in a steel plant:
  • soot contains oxides of valuable metals such as zinc, lead, antimony, indium and iron, of which the content of indium and antimony is relatively low.
  • Table 1 The following is a table of the main metal components obtained from the weighted average of zinc-containing soot components in a domestic steel plant, as shown in Table 1:
  • the outer wall of the upper reaction body 5 and the connecting passage 7 is double-layer steel plate, the cooling water is passed in the middle, and the refractory brick is built on the inner wall.
  • the cooling water forms a chilled wall, which is favorable for the ash in the coal to form a slag on the inner wall to protect the furnace wall.
  • the upper reaction body 5 is provided with four spray guns on the side wall, and pulverized coal and oxygen gas (which can be added with water vapor) are sprayed from the spray gun 2 into the upper reaction body 5, and the pulverized coal in the upper reaction body 5 is rapidly burned and vaporized to form a temperature of A reducing gas stream having a volume ratio of effective reducing gas (CO + H 2 ) of 90% at 1380 ° C is ejected from the outlet of the upper reactant 5 .
  • pulverized coal and oxygen gas which can be added with water vapor
  • the connecting passage 7 has a length of 0.8 m and an inner width of about 2/5 of the inner diameter of the lower reaction body 1.
  • the feeding passage 7 is provided with a feeding device.
  • the feeding device is a sealed feeding port having a three-layer channel structure. Through the sealed feeding port of the three-layer channel structure, the compressed air is used to send the steel plant soot, flux and coke into the flash furnace.
  • the general dust particle size of the steel plant is below 100 mesh, no need to carry out grinding treatment. Drying to a water content of %0.3%; flux is limestone, containing more than 90% CaCO 3 , particle size less than 1mm, drying to less than 1% water; coke particle size in the range of 1-11mm.
  • the soot particles are thoroughly mixed with the reducing gas ejected from the upper reaction body 5 at the moment of being sprayed into the flash furnace, and are floated into the lower reaction body 1 at a high temperature of about 1100 ° C to 1450 ° C, and the metal oxide in the soot. It is mass-extended in a very high specific surface area in the lower reaction body 1 filled with reducing gas, and rapidly completes zinc, lead, iron and antimony in the powder by rapid heat transfer, mass transfer and gas-solid and gas-liquid reaction.
  • the metal oxide such as indium is reduced and melted, and falls in the molten pool in the lower portion of the lower reaction body 1.
  • the reduced Zn is rapidly vaporized and enters the ascending flue 3, and can be recovered by means of lead rain/zinc rain condensation or fuming.
  • the metal oxide melt such as iron and zinc which is not completely reduced in the lower reactant 1 enters the 150 mm thick coke filter layer 6 in the form of droplets, and is reduced by carbon when the melt penetrates the pyrophoric layer 6 downward. Therefore, the metal oxides such as ZnO and FeO which are relatively difficult to reduce are also substantially reduced.
  • the gangue in the ore powder and the added flux slag are sprayed with oxygen and pulverized coal into the molten pool 2 through the side blowing nozzle 4 (process oxygen concentration is 99.6%, and pulverized coal particle size is 5 mm-8 mm)
  • the molten pool 2 is supplemented with heat, and the molten pool 2 is formed into a high-temperature reducing environment of 1300 ° C to 1650 ° C.
  • the position of the side blowing is located at the lower part of the slag layer, and the melt can be tumbling, so that a small amount of unreduced zinc oxide, lead bismuth, indium and the like in the slag layer is sufficiently contacted with the carbon reducing agent to completely complete the reduction.
  • the molten pool 2 Most of the reduced Zn will rapidly vaporize away from the melt into the ascending flue 3, and the remaining metal droplets will be concentrated down through the less dense slag layer, and the Fe and Pb will melt.
  • the body is completely immiscible, and the metal layer is divided into a molten iron layer and a crude lead alloy layer.
  • the molten pool 1 Due to the difference in density, the molten pool 1 forms a three-layer structure of a slag layer, a molten iron layer and a crude lead alloy layer from top to bottom. A small amount of Bi, In and a small amount of unvaporized Zn are easily dissolved in the lead liquid, and are trapped by the lead liquid and then enter the crude lead alloy layer. After the crude lead alloy is discharged, the Pb can be purified by refining or the like. metal.
  • the process for treating steel soot by using the tandem flash furnace provided by the invention is shorter than the existing rotary kiln process or wet process, and can comprehensively recover a plurality of valuable metals, and the comprehensive energy consumption is reduced by more than 40%. Pollution is reduced by 90%.
  • the main chemical reactions occurring in the lower reactant 1 are:
  • the inner width of the connecting passage 7 is not more than 2/3 of the inner diameter of the lower reaction body 1, while the length is not more than 2 m.
  • the inner width of the connecting passage 7 affects the pressure inside the upper reaction body 5, thereby affecting the gas generating efficiency.
  • the length of the connecting passage 7 is not more than 2 m, so as not to affect the efficiency of the upper reaction body 5 transferring heat to the reaction body 1 downward.
  • the connecting channel 7 is provided with a feeding device, as shown in FIG. 1, through which the ore powder to be smelted can be fed, the mineral powder and the reducing gas are contacted in advance, and the mineral powder is increased.
  • the feeding device is one or more of a nozzle, a spray gun, and a sealing feed port; or a combination of one or more of a nozzle, a spray gun, and a sealing feed port and a burner. Add the raw materials, fuel and auxiliary materials necessary for smelting to the flash furnace by setting a nozzle or a spray gun or a sealed feed port.
  • the feeding device may also be disposed at the top end of the lower reaction body 1, as shown in Fig. 2, and two sets of burners are disposed at the top of the lower reaction body 1 to supplement the heat of the lower reaction body 1. Further, the feeding means may be provided on the side wall of the lower reaction body 1 as needed.
  • the upper reaction body 5 is provided with a spray gun or a nozzle for blowing an oxygen-containing gas and a gasifying agent into the upper reaction body 5.
  • the spray gun or nozzle is disposed on the upper reaction body 5, penetrates the inner wall of the upper reaction body 5, and extends into the upper reaction body 5, as shown in FIGS. 1 and 2.
  • the lance or the nozzle sprays an oxygen-containing gas and a gasifying agent into the reaction body 5.
  • the dual-channel spray gun injects oxygen and pulverized coal into the reaction body 5 to generate a reducing gas (CO + H 2 ) and provide heat to the lower reaction body 1.
  • a space above the space in which the melt is contained in the molten pool 2 is provided with a space for the filter layer.
  • the upper portion of the melt of the molten pool 2 is formed with a pyrophoric layer 6 which passes through the molten charge.
  • an embodiment is to add coke to the lower reaction body 1 through a nozzle disposed at the top of the lower reaction body 1, coke.
  • the particle size ranges from 1 to 11 mm, and is rapidly heated in the lower reaction body 1, and the heated coke particles fall on the surface of the molten pool 2 to form a porous carbon material-coke filter layer 6.
  • the coke filter layer 6 can also be realized by spraying a pulverized coal suitable for coking, and after the pulverized coal is burned off at a high temperature, coke particles can be formed.
  • the focal filter layer space is 50-250 mm high, preferably 100-200 mm, as shown in FIG.
  • the thickness of the pyrophoric layer is appropriately adjusted by adjusting the speed at which coke or pulverized coal is added to the lower reaction body 1.
  • each of the molten pools 2 is provided with a side blowing arrangement for injecting a carbonaceous fuel and an oxygen containing gas into the molten pool 2, as shown in Figures 3-4 and 6-11.
  • the position of the side blowing arrangement corresponds to the lower middle portion of the slag layer in the molten pool, and the side blowing is provided.
  • the slag Placed in the lower part of the slag layer, the slag can be convected or tumbling, which facilitates the exchange of heat and substances between the upper and lower layers, thereby reducing the viscosity of the melt and improving the metal recovery rate.
  • the number of ascending flues 3 coincides with the number of molten pools 2, as shown in Figures 10 and 11.
  • the number of molten pools 2 is 1-4.
  • the setting of 1-4 molten pools 2 in the flash furnace can meet the needs of different smelting production.

Abstract

A serial flash furnace, comprising an upper reaction body (5) and a lower reaction body (1), and a connecting channel (7) connecting the upper reaction body (5) and the lower reaction body (1). The upper reaction body (5) is located above the lower reaction body (1) to form a serial structure. At least one melting pool (2) is provided at a lower portion of the lower reaction body (1). The flash furnace further comprises a rising flue (3) for discharging flue gases. The rising flue (3) is in communication with the lower reaction body (1) by means of the melting pool (2). Each melting pool (2) is provided with a slag discharge port.

Description

串联闪速炉及冶炼方法Tandem flash furnace and smelting method 技术领域Technical field
本发明属于冶金领域,尤其是涉及一种串联闪速炉及冶炼方法。The invention belongs to the field of metallurgy, and in particular relates to a tandem flash furnace and a smelting method.
背景技术Background technique
闪速冶金从发明到现在,只用于金属硫化矿的冶炼,主要原因是现有的闪速炉只拥有一个反应空间,且为微负压环境,在该空间内可进行气固或气液间的氧化反应或弱还原反应,但无法制造强还原气氛进行快速有效的还原反应,例如,利用闪速炉微负压的单反应空间无法制造出有效还原气(CO+H2)体积比超过73%的还原气体,因而无法保证金属氧化物在悬浮态下基本完成还原。Flash metallurgy has been used only for the smelting of metal sulfide ore from the invention to the present. The main reason is that the existing flash furnace only has one reaction space and is a micro-negative pressure environment in which gas-solid or gas-liquid can be carried out. An oxidation reaction or a weak reduction reaction, but a strong reducing atmosphere cannot be produced to carry out a rapid and effective reduction reaction. For example, a single reaction space using a micro-negative pressure of a flash furnace cannot produce an effective reducing gas (CO + H 2 ) volume ratio exceeding 73% of the reducing gas, so there is no guarantee that the metal oxide will substantially complete the reduction in the suspended state.
发明内容Summary of the invention
有鉴于此,本发明旨在提出一种串联闪速炉,以解决现有闪速炉空间直接制造还原气体效率低、有效成分浓度低,而从外部引入还原气体成本高、危险大等问题。In view of this, the present invention aims to provide a tandem flash furnace to solve the problems of low efficiency of direct production of reducing gas in the existing flash furnace space, low concentration of active components, and high cost and high risk of introducing reducing gas from the outside.
为达到上述目的,本发明的技术方案是这样实现的:In order to achieve the above object, the technical solution of the present invention is achieved as follows:
一种串联闪速炉,包括上反应体5、下反应体1及连通两者的连接通道7,所述上反应体5位于所述下反应体1的上部,形成串联式结构,所述下反应体1下部设有至少一个熔池2;所述闪速炉还包括用于排出烟气的上升烟道3,所述上升烟道3通过所述熔池2与所述下反应体1相连通,各所述熔池2上均设有排渣口。通过向上反应体5喷入含氧气体(空气,氧气-空气混合物或者工艺氧)及气化剂如:煤粉、水煤浆、水蒸气、天然气、燃油、甲烷,为闪速炉下反应体1制造还原气体(CO+H2),同时为下反应体1提供热量。上反应体5内的气压可以大于或等于下反应体1的压强,优选高压条件,通过构建一个独立的高温高压气化空间,使气化剂能够很好的气化,从而提高有效还原气(CO+H2)的浓度。上反应体5的压强可以通过调节连接通道7的内宽及单位时间喷入含氧气体及气化剂的量来进行控制。本发明所述的串联闪速炉结构紧凑,可直接通过上反应体5向下反应体1提供冶炼所需要的热量和还原气氛,相对于目前现有的一些将尾气重整后再返回作为冶炼气体的冶炼工艺,避免了高温气体在长距离输运过程中的热量损失及对传输管道的损耗(1000℃以上的高温尾气的输送对管道材料的要求较高,管道成本高、寿命短);同时,由于不需要附属设备(如尾气 裂化转化设备、气体加压输送设备等),大大降低了一次性投资,也使整套设备的故障率大大的降低,从而降低了设备成本与维修成本;此外,本发明所述上反应体5造气原理简单,使用气化剂(如煤粉)和氧气进行简单的化学反应即可实现,而不需要通过其他复杂昂贵的方式(如等离子电离等)实现造气或气体转化,大大降低了生产和使用成本。所述上反应体5位于下反应体1的上部,且通过不大于2m的连接通道7直接串接,使上反应体5生产的还原气流可以从下反应体1最顶部进入,进而使从连接通道7加入的矿粉和还原气氛有更长的接触时间,提高待冶炼金属氧化物的还原率。A tandem flash furnace comprising an upper reaction body 5, a lower reaction body 1 and a connecting passage 7 communicating the two, the upper reaction body 5 being located at an upper portion of the lower reaction body 1, forming a tandem structure, the lower At least one molten pool 2 is disposed at a lower portion of the reaction body 1; the flash furnace further includes a rising flue 3 for discharging flue gas, and the rising flue 3 is connected to the lower reaction body 1 through the molten pool 2 Each of the molten pools 2 is provided with a slag discharge port. By spraying the oxygen-containing gas (air, oxygen-air mixture or process oxygen) and gasifying agent such as coal powder, coal water slurry, water vapor, natural gas, fuel oil and methane into the upper reaction body 5, the reaction body under the flash furnace 1 A reducing gas (CO + H 2 ) is produced while supplying heat to the lower reactant 1. The gas pressure in the upper reaction body 5 may be greater than or equal to the pressure of the lower reaction body 1, preferably a high pressure condition, by constructing an independent high temperature and high pressure gasification space, so that the gasifying agent can be well vaporized, thereby improving the effective reducing gas ( Concentration of CO + H 2 ). The pressure of the upper reaction body 5 can be controlled by adjusting the inner width of the connecting passage 7 and the amount of the oxygen-containing gas and the gasifying agent to be injected per unit time. The tandem flash furnace of the invention has the advantages of compact structure, and can directly supply the heat and reducing atmosphere required for smelting to the reaction body 1 through the upper reaction body 5, and is returned to the smelting after being compared with some existing ones. The gas smelting process avoids the heat loss of the high-temperature gas during the long-distance transportation process and the loss of the transmission pipeline (the high-temperature exhaust gas above 1000 °C has higher requirements on the pipeline material, the pipeline cost is high, and the service life is short); At the same time, since no auxiliary equipment (such as tail gas cracking conversion equipment, gas pressure conveying equipment, etc.) is required, the one-time investment is greatly reduced, and the failure rate of the whole equipment is greatly reduced, thereby reducing equipment cost and maintenance cost; The upper reaction body 5 of the present invention has a simple gas-making principle, and can be realized by a simple chemical reaction using a gasifying agent (such as coal powder) and oxygen, without using other complicated and expensive methods (such as plasma ionization, etc.). Gasification or gas conversion greatly reduces production and use costs. The upper reaction body 5 is located at the upper part of the lower reaction body 1, and is directly connected in series by a connecting passage 7 of not more than 2 m, so that the reducing gas stream produced by the upper reaction body 5 can enter from the top of the lower reaction body 1, thereby making the connection The mineral powder added to the channel 7 and the reducing atmosphere have a longer contact time and increase the reduction rate of the metal oxide to be smelted.
进一步的,所述连接通道7的内宽不大于下反应体1内径的2/3,同时长度不大于2m。连接通道7的内宽可调,通过控制连接通道7的内宽,可以控制上反应体5内部的压强,进而影响造气效率,同时,也可改变上反应体5向下反应体1内输送气流的速度。接通道7的长度不大于2m,以免过长影响上反应体5向下反应体1传递热量的效率。Further, the inner width of the connecting passage 7 is not more than 2/3 of the inner diameter of the lower reaction body 1, and the length is not more than 2 m. The inner width of the connecting passage 7 is adjustable, and by controlling the inner width of the connecting passage 7, the pressure inside the upper reaction body 5 can be controlled, thereby affecting the gas generating efficiency, and at the same time, the upper reaction body 5 can be changed to the inner reaction body 1 to be transported. The speed of the airflow. The length of the connecting channel 7 is not more than 2 m, so as not to affect the efficiency of the upper reaction body 5 transferring heat to the reaction body 1 downward.
进一步的,所述连接通道7上设有给料装置。待冶炼的矿粉通过设置在连接通道7上的给料装置加入闪速炉内,可以使矿粉和还原气体在进入下反应体1前即开始提前接触并充分混合,变相延长了待冶炼矿粉在下反应体1的冶炼时间,提高了矿粉中待冶炼金属氧化物的还原率。所述给料装置为喷嘴、喷枪、密封加料口中的一种或多种;或者为喷嘴、喷枪、密封加料口中的一种或多种与烧嘴的组合。通过设置喷嘴或喷枪或密封加料口向闪速炉加入冶炼所必需的原料、燃料和辅助材料;必要时,可通过烧嘴为下反应体1内补充热量。当然,根据实际需要,给料装置也可设置在下反应体1顶部,或设置于下反应体1侧壁上。Further, the connecting channel 7 is provided with a feeding device. The ore powder to be smelted is added to the flash furnace through a feeding device disposed on the connecting passage 7, so that the ore powder and the reducing gas can be contacted and fully mixed before entering the lower reaction body 1, and the disintegration extends the ore to be smelted. The smelting time of the powder in the lower reaction body 1 increases the reduction rate of the metal oxide to be smelted in the mineral powder. The feeding device is one or more of a nozzle, a spray gun, and a sealing feed port; or a combination of one or more of a nozzle, a spray gun, and a sealing feed port and a burner. The raw materials, fuel and auxiliary materials necessary for smelting are added to the flash furnace by setting a nozzle or a spray gun or a sealed feed port; if necessary, heat can be added to the lower reaction body 1 through the burner. Of course, the feeding device can also be disposed on the top of the lower reaction body 1 or on the side wall of the lower reaction body 1 according to actual needs.
进一步的,所述上反应体5上设有向上反应体5内喷吹含氧气体及气化剂的喷枪或喷管。喷枪或喷管设置于上反应体5上,并穿透上反应体5内壁,伸入上反应体5内。喷枪或喷管可为单通道或多通道,可只喷吹一种原料,多通道喷枪或喷管可同时喷吹多种原料。喷枪或喷管向上反应体5内喷入含氧气体及气化剂如:煤粉、水煤浆、水蒸气、天然气、燃油、甲烷、乙炔中一种或多种的组合,用来产生还原性气体并为下反应体1提供热量。优选的,气化剂为煤粉,煤气化技术比较成熟,同时煤也是目前国内最经济的造气原料。Further, the upper reaction body 5 is provided with a spray gun or a nozzle for spraying an oxygen-containing gas and a gasifying agent into the upper reaction body 5. A spray gun or a nozzle is disposed on the upper reaction body 5, penetrates the inner wall of the upper reaction body 5, and projects into the upper reaction body 5. The spray gun or nozzle can be single or multi-channel, which can spray only one raw material, and the multi-channel spray gun or nozzle can simultaneously spray a variety of raw materials. The spray gun or the nozzle sprays an oxygen-containing gas and a gasifying agent into the upper reaction body 5, such as a combination of one or more of coal powder, coal water slurry, water vapor, natural gas, fuel oil, methane and acetylene, to be used for producing a reduction. The gas supplies heat to the lower reactant 1. Preferably, the gasification agent is pulverized coal, and the coal gasification technology is relatively mature, and at the same time, coal is also the most economical gas-making raw material in China at present.
进一步的,所述熔池2内盛纳熔体的空间上部设有熔融炉料下落时通过的焦滤层空间。所述熔池2熔体上部形成有熔融炉料下落时通过的焦滤层6,一种实现方式是通过设置在连接通道7或下反应体1顶部的加料装置把焦炭加入下反应体1,焦炭粒径范围为1-11mm,在下反应体1内迅速被加热,加热后的焦炭颗粒落到熔池2熔体表面形成一层多孔的碳物料-焦滤层6;如果焦炭的粒度小于1mm,焦炭在高温下损耗较快,但粒度超过11mm又会 使焦炭的中心不能够被加热到足够的温度,且粒度过大会使焦炭颗粒间的间隙变大,这会导致通过焦滤层6的金属氧化物熔体回收率的损失。焦滤层6也可通过加入适合炼焦的粉煤的方式实现,粉煤在高温下烧掉其中的挥发分后,即可形成焦炭颗粒。Further, an upper portion of the space in which the melt is contained in the molten pool 2 is provided with a space of a pyrophoric layer through which the molten charge falls. The upper portion of the molten pool 2 is formed with a pyrophoric layer 6 that passes through the molten charge. One implementation is to add coke to the lower reaction body 1 through a charging device disposed at the top of the connecting passage 7 or the lower reaction body 1, coke. The particle size ranges from 1 to 11 mm, and is rapidly heated in the lower reaction body 1. The heated coke particles fall on the surface of the molten pool 2 to form a porous carbon material-coke filter layer 6; if the coke has a particle size of less than 1 mm, Coke is depleted faster at high temperatures, but the particle size exceeds 11mm. The center of the coke cannot be heated to a sufficient temperature, and the excessive particle size causes the gap between the coke particles to become large, which causes a loss of the metal oxide melt recovery rate through the pyrophoric layer 6. The coke filter layer 6 can also be realized by adding a pulverized coal suitable for coking, and after the pulverized coal is burned off at a high temperature, coke particles can be formed.
进一步的,所述焦滤层6空间高50-250mm。焦滤层空间高50-250mm,优选为100-200mm,焦滤层6过厚会造成焦炭浪费、能耗升高,过薄又起不到所需要的还原效果。根据待冶炼金属氧化物被碳还原的难易程度,可适当调节焦滤层的厚度,调节的方法是调节向下反应体1内加入焦炭或适合炼焦的粉煤的速度。Further, the focal filter layer 6 has a space of 50-250 mm. The space of the pyrophoric layer is 50-250 mm, preferably 100-200 mm. If the coke filter layer 6 is too thick, it will cause coke waste, increase energy consumption, and too thin to achieve the required reduction effect. Depending on the ease with which the metal oxide to be smelted is reduced by carbon, the thickness of the pyrophoric layer can be appropriately adjusted by adjusting the rate at which coke or pulverized coal suitable for coking is added to the lower reactant 1.
进一步的,各所述熔池2均设有向所述熔池2内喷入燃料和含氧气体的侧吹布置。通过侧吹向熔池喷入燃料和气体,为熔池提供热量,使熔池维持在一定的高温段。所述燃料为重油、天然气、液化石油气、煤、焦丁、碳氢化合物中的一种;所述含氧气体为空气、氧气-空气混合物或者工艺氧。Further, each of the molten pools 2 is provided with a side blowing arrangement for injecting fuel and oxygen-containing gas into the molten pool 2. Fuel and gas are injected into the molten pool by side blowing to provide heat to the molten pool to maintain the molten pool at a certain high temperature. The fuel is one of heavy oil, natural gas, liquefied petroleum gas, coal, coke, and hydrocarbon; the oxygen-containing gas is air, an oxygen-air mixture, or process oxygen.
进一步的,所述侧吹布置所在位置与所述熔池中熔渣层中下部对应。侧吹设置在熔渣层中下部,可以使熔渣形成对流或翻滚,方便上下层间的热量和物质交换,从而减小熔体的粘度,提高待冶炼金属的回收率。Further, the position of the side blowing arrangement corresponds to a lower middle portion of the slag layer in the molten pool. The side blowing is arranged in the lower part of the slag layer, so that the slag can be convected or tumbling, which facilitates the exchange of heat and substance between the upper and lower layers, thereby reducing the viscosity of the melt and improving the recovery rate of the metal to be smelted.
进一步的,所述侧吹布置包括对称设置在所述熔池2相对侧壁上的侧吹孔及设置在侧吹孔内的侧吹喷管4。Further, the side blowing arrangement includes side blowing holes symmetrically disposed on opposite side walls of the molten pool 2 and side blowing nozzles 4 disposed in the side blowing holes.
进一步的,所述熔池2的数目为1-4个。闪速炉中1-4个熔池2的设置能够满足不同冶炼产量需求。Further, the number of the molten pools 2 is 1-4. The setting of 1-4 molten pools 2 in the flash furnace can meet the needs of different smelting production.
本发明还提供一种利用上述串联闪速炉进行冶炼的方法。The present invention also provides a method of smelting using the above-described tandem flash furnace.
本发明还保护利用上述闪速炉在冶炼中的应用。The invention also protects the use of the flash furnace described above in smelting.
相对于现有技术,本发明所述的串联闪速炉具有以下优势:Compared with the prior art, the tandem flash furnace of the present invention has the following advantages:
本发明所述的串联闪速炉能够在上反应体5中制造高温高压高浓度的还原气体,为下反应体1提供冶炼所需要的还原气氛和热量,相对于直接在现有闪速炉下反应体1内进行煤气化,一方面造气的质量更高,可为熔炼过程提供更高浓度的有效还原气,从而使矿粉在下反应体1的还原速度更快,同时也使某些在空间需要高浓度还原气氛才能实现还原的金属氧化物采用闪速炉进行冶炼成为可能;另一方面造气的效率更高,不需要让下反应体1再另行承担造气的任务,矿粉一进入闪速炉内即可与还原气体充分接触并发生反应,变相的延长了矿 粉在闪速炉空间的冶炼时间,从而提高了待冶炼金属的还原率,降低了能耗,提高了经济效益。The tandem flash furnace of the present invention is capable of producing a high-temperature, high-pressure, high-concentration reducing gas in the upper reaction body 5, and providing the lower reactant 1 with a reducing atmosphere and heat required for smelting, as opposed to being directly under the existing flash furnace. Coal gasification in the reaction body 1 has higher quality of gasification on the one hand, and can provide a higher concentration of effective reducing gas for the smelting process, thereby making the reduction speed of the mineral powder in the lower reaction body 1 faster, and also making some The space needs a high concentration reducing atmosphere to realize the reduction of the metal oxide by flash furnace smelting; on the other hand, the gas-making efficiency is higher, and it is not necessary for the lower reaction body 1 to undertake the task of gas-making again. Entering the flash furnace, it can fully contact with the reducing gas and react, and the phase change extends the mine. The smelting time of the powder in the flash furnace space increases the reduction rate of the metal to be smelted, reduces energy consumption, and improves economic efficiency.
本发明所述的串联闪速炉通过一个不大于2m的连接通道串接上反应体和下反应体,使上反应体制造的还原气氛和热量能有效快速的供给下反应体,相对于现有冶金行业一些将尾气重整后再返回作为冶炼气体的工艺,工艺流程简单,一次性投资小,能耗低,生产和维护成本低。The tandem flash furnace of the present invention connects the reaction body and the lower reaction body in series through a connecting channel of not more than 2 m, so that the reducing atmosphere and heat generated by the upper reaction body can be efficiently and quickly supplied to the lower reaction body, compared with the existing one. Some processes in the metallurgical industry that return the tail gas and then return it as a smelting gas, the process is simple, the one-time investment is small, the energy consumption is low, and the production and maintenance costs are low.
附图说明DRAWINGS
构成本发明的一部分的附图用来提供对本发明的进一步理解,本发明的示意性实施例及其说明用于解释本发明,并不构成对本发明的不当限定。在附图中:The accompanying drawings, which are incorporated in the claims In the drawing:
图1为本发明实施例所述的串联闪速炉的一种结构示意图;1 is a schematic structural view of a tandem flash furnace according to an embodiment of the present invention;
图2为本发明实施例所述的串联闪速炉的第二种结构示意图;2 is a schematic view showing a second structure of a tandem flash furnace according to an embodiment of the present invention;
图3为本发明实施例所述的串联闪速炉的第三种结构示意图;3 is a schematic view showing a third structure of a tandem flash furnace according to an embodiment of the present invention;
图4为本发明实施例所述的串联闪速炉的第四种结构示意图;4 is a fourth structural schematic view of a tandem flash furnace according to an embodiment of the present invention;
图5为本发明实施例所述的串联闪速炉的第五种结构示意图;5 is a fifth structural schematic view of a tandem flash furnace according to an embodiment of the present invention;
图6为本发明实施例所述的串联闪速炉的第六种结构示意图;6 is a sixth structural schematic view of a tandem flash furnace according to an embodiment of the present invention;
图7为本发明实施例所述的串联闪速炉的第七种结构示意图;7 is a seventh structural schematic view of a tandem flash furnace according to an embodiment of the present invention;
图8为本发明实施例所述的串联闪速炉的第八种结构示意图;8 is a schematic structural view of an eighth type of a tandem flash furnace according to an embodiment of the present invention;
图9为本发明实施例所述的串联闪速炉的第九种结构示意图;9 is a schematic view showing a ninth structure of a tandem flash furnace according to an embodiment of the present invention;
图10为本发明实施例所述的串联闪速炉的第十种结构示意图;10 is a schematic structural view of a tenth type of a tandem flash furnace according to an embodiment of the present invention;
图11为本发明实施例所述的串联闪速炉的第十种结构示意图。FIG. 11 is a schematic view showing a tenth structure of a tandem flash furnace according to an embodiment of the present invention.
附图标记说明:Description of the reference signs:
1-下反应体,2-熔池,3-上升烟道,4-侧吹喷管,5-上反应体,6-焦滤层,7-连接通道。1- lower reaction body, 2-melt pool, 3-rise flue, 4-side blow nozzle, 5-upper reaction body, 6-pyro filter layer, 7-connected channel.
具体实施方式detailed description
需要说明的是,在不冲突的情况下,本发明中的实施例及实施例中的特征可以相互组合。 It should be noted that the embodiments in the present invention and the features in the embodiments may be combined with each other without conflict.
在本发明的描述中,需要理解的是,术语“中心”、“纵向”、“横向”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”、“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。此外,术语“第一”、“第二”等仅用于描述目的,而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量。由此,限定有“第一”、“第二”等的特征可以明示或者隐含地包括一个或者更多个该特征。In the description of the present invention, it is to be understood that the terms "center", "longitudinal", "lateral", "upper", "lower", "front", "back", "left", "right", " The orientation or positional relationship of the indications of "upright", "horizontal", "top", "bottom", "inside", "outside", etc. is based on the orientation or positional relationship shown in the drawings, only for the convenience of describing the present invention and The simplification of the description is not intended to limit or imply that the device or component that is referred to has a particular orientation, is constructed and operated in a particular orientation, and thus is not to be construed as limiting. Moreover, the terms "first", "second", and the like are used for the purpose of description only, and are not to be construed as indicating or implying a relative importance or implicitly indicating the number of technical features indicated. Thus, features defining "first", "second", etc. may include one or more of the features, either explicitly or implicitly.
在本发明的描述中,需要说明的是,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体地连接;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以通过具体情况理解上述术语在本发明中的具体含义。In the description of the present invention, it should be noted that the terms "installation", "connected", and "connected" are to be understood broadly, and may be fixed or detachable, for example, unless otherwise explicitly defined and defined. Connected, or integrally connected; can be mechanical or electrical; can be directly connected, or indirectly connected through an intermediate medium, can be the internal communication of the two components. The specific meaning of the above terms in the present invention can be understood by a person of ordinary skill in the art.
下面将参考附图并结合实施例来详细说明本发明。The invention will be described in detail below with reference to the drawings in conjunction with the embodiments.
一种串联闪速炉,如图1-11所示,包括上反应体5、下反应体1及连通两者的连接通道7,上反应体5位于下反应体1的上部,形成串联式结构,下反应体1下部设有至少一个熔池2;闪速炉还包括用于排出烟气的上升烟道3,上升烟道3通过熔池2与下反应体1相连通,各熔池2上均设有排渣口,排渣口未在图1-11中标出。A tandem flash furnace, as shown in FIGS. 1-11, includes an upper reaction body 5, a lower reaction body 1 and a connecting passage 7 communicating the two, and the upper reaction body 5 is located at an upper portion of the lower reaction body 1 to form a tandem structure. The lower part of the lower reaction body 1 is provided with at least one molten pool 2; the flash furnace further comprises a rising flue 3 for discharging flue gas, and the rising flue 3 is connected to the lower reaction body 1 through the molten pool 2, each molten pool 2 There are slag discharge ports on the top, and the slag discharge ports are not marked in Figure 1-11.
本实例的工作过程:将造气燃料和含氧气体喷入上反应体5中,产生高浓度的还原气体并放出热量,向下反应体1内喷入干燥的金属氧化矿粉料、熔剂和焦炭,在高温炽热、充满还原气氛的下反应体1中,通过传热、传质和气-固、气-液反应,迅速完成粉料中待冶炼金属氧化物的还原和熔化;在下反应体1中形成的弥散的氧化物熔体以小滴状落入熔池并进入焦滤层6,当熔体穿透焦滤层6时,其中未被完全还原的待冶炼金属氧化物被碳热还原。The working process of the present example: the gas-generating fuel and the oxygen-containing gas are sprayed into the upper reaction body 5 to generate a high concentration of reducing gas and release heat, and the dry metal oxide ore powder, the flux and the molten material are sprayed into the reaction body 1 downward. Coke, in the lower reaction body 1 with high temperature and high temperature and full of reducing atmosphere, through the heat transfer, mass transfer and gas-solid, gas-liquid reaction, the reduction and melting of the metal oxide to be smelted in the powder are rapidly completed; The dispersed oxide melt formed in the droplet falls into the molten pool and enters the pyrophoric layer 6. When the melt penetrates the pyrophoric layer 6, the metal oxide to be smelted which is not completely reduced is reduced by carbothermal .
在熔池2中,矿粉中的脉石和熔剂发生造渣反应,生成熔点低的渣。根据需要,也可同时在熔池2中设置侧吹布置,通过侧吹向熔体中分别喷吹燃料和含氧气体,本实施例中向熔体中分别喷吹煤粉和氧气,为熔池2提供热量并实现熔体的翻滚,同时使熔池2保持强还原环境,剩余的待冶炼金属氧化物彻底在熔池2中完成还原,从而提高待冶炼金属的回收率。被还原出来的低沸点金属进入烟气通过上升烟道3排出炉外,后续可通过冷凝或烟化进行收集,其余被还原出的熔融的金属在熔池2内与液态渣沉淀分层,形成金属层和渣层,将金属 熔体从熔池2内排出,得到粗金属,熔渣从排渣口排出炉外。In the molten pool 2, the gangue and the flux in the ore powder undergo a slagging reaction to form a slag having a low melting point. If necessary, a side blowing arrangement may be provided in the molten pool 2, and the fuel and the oxygen-containing gas are respectively injected into the melt by the side blowing. In this embodiment, the coal powder and the oxygen are respectively injected into the melt to be melted. The pool 2 provides heat and achieves the tumbling of the melt, while maintaining the molten pool 2 in a strong reducing environment, and the remaining metal oxide to be smelted is completely reduced in the molten pool 2, thereby improving the recovery rate of the metal to be smelted. The reduced low-boiling metal into the flue gas exits the furnace through the ascending flue 3, and can be collected by condensation or fuming, and the remaining molten metal is precipitated and layered in the molten pool 2 to form a layer. Metal layer and slag layer, metal The melt is discharged from the molten pool 2 to obtain a crude metal, and the molten slag is discharged from the slag discharge port.
将本发明提供的串联闪速炉应用在钢铁厂烟尘的冶炼:The tandem flash furnace provided by the invention is applied to the smelting of soot in a steel plant:
钢铁企业在高炉、电炉、转炉、烧结等工段都有大量的烟尘产生,烟尘中含有锌、铅、铋、铟和铁等有价金属的氧化物,其中铟和铋的含量相对较低。下面是国内一钢铁厂含锌烟尘成分加权平均后得出的主要金属成分表,如表1所示:Iron and steel enterprises produce a large amount of soot in the blast furnace, electric furnace, converter, sintering and other sections. The soot contains oxides of valuable metals such as zinc, lead, antimony, indium and iron, of which the content of indium and antimony is relatively low. The following is a table of the main metal components obtained from the weighted average of zinc-containing soot components in a domestic steel plant, as shown in Table 1:
表1:Table 1:
FeFe PbPb ZnZn BiBi InIn
30.2%30.2% 3.5%3.5% 7.5%7.5% 0.3%0.3% 0.010%0.010%
上反应体5及连接通道7的外壁选用双层钢板,中间通冷却水,内壁砌耐火砖。冷却水形成激冷壁,有利于煤中的灰分在内壁形成挂渣,保护炉壁。上反应体5在侧壁上设有四只喷枪,粉煤、氧气(可加水蒸气)从喷枪2喷入上反应体5,在上反应体5内粉煤迅速燃烧并气化,生成温度为1380℃、有效还原气(CO+H2)成分体积比达90%的还原气流,从上反应体5出口喷出。The outer wall of the upper reaction body 5 and the connecting passage 7 is double-layer steel plate, the cooling water is passed in the middle, and the refractory brick is built on the inner wall. The cooling water forms a chilled wall, which is favorable for the ash in the coal to form a slag on the inner wall to protect the furnace wall. The upper reaction body 5 is provided with four spray guns on the side wall, and pulverized coal and oxygen gas (which can be added with water vapor) are sprayed from the spray gun 2 into the upper reaction body 5, and the pulverized coal in the upper reaction body 5 is rapidly burned and vaporized to form a temperature of A reducing gas stream having a volume ratio of effective reducing gas (CO + H 2 ) of 90% at 1380 ° C is ejected from the outlet of the upper reactant 5 .
连接通道7长0.8m,内宽约为下反应体1内径的2/5,在连接通道7上设有给料装置,本实施例中给料装置为具有三层通道结构的密封加料口,通过三层通道结构的密封加料口,分别用压缩空气向闪速炉内送入钢铁厂烟尘、熔剂和焦炭,钢铁厂烟尘一般粒度都在100目以下,不需要再进行磨矿处理,只需烘干至水量≦0.3%;熔剂为石灰石,含CaCO3在90%以上,粒度小于1mm,干燥至含水小于1%;焦炭的粒径在1-11mm范围内。The connecting passage 7 has a length of 0.8 m and an inner width of about 2/5 of the inner diameter of the lower reaction body 1. The feeding passage 7 is provided with a feeding device. In this embodiment, the feeding device is a sealed feeding port having a three-layer channel structure. Through the sealed feeding port of the three-layer channel structure, the compressed air is used to send the steel plant soot, flux and coke into the flash furnace. The general dust particle size of the steel plant is below 100 mesh, no need to carry out grinding treatment. Drying to a water content of %0.3%; flux is limestone, containing more than 90% CaCO 3 , particle size less than 1mm, drying to less than 1% water; coke particle size in the range of 1-11mm.
烟尘颗粒在喷入闪速炉的瞬间,即与上反应体5喷出的还原气体充分混合,并呈飘浮状态进入约1100℃-1450℃高温的下反应体1中,烟尘中的金属氧化物以极大的比表面积状态弥撒于炽热、充满还原气分的下反应体1中,通过快速传热、传质和气-固、气-液反应,迅速完成粉料中锌、铅、铁、铋和铟等金属氧化物的还原和熔化,并飘落在下反应体1下部的熔池中。被还原出来的Zn迅速气化并进入上升烟道3,后续可采用铅雨/锌雨冷凝或烟化的方式进行回收。The soot particles are thoroughly mixed with the reducing gas ejected from the upper reaction body 5 at the moment of being sprayed into the flash furnace, and are floated into the lower reaction body 1 at a high temperature of about 1100 ° C to 1450 ° C, and the metal oxide in the soot. It is mass-extended in a very high specific surface area in the lower reaction body 1 filled with reducing gas, and rapidly completes zinc, lead, iron and antimony in the powder by rapid heat transfer, mass transfer and gas-solid and gas-liquid reaction. The metal oxide such as indium is reduced and melted, and falls in the molten pool in the lower portion of the lower reaction body 1. The reduced Zn is rapidly vaporized and enters the ascending flue 3, and can be recovered by means of lead rain/zinc rain condensation or fuming.
在下反应体1中未被完全还原的铁和锌等金属氧化物熔体以小滴状进入150mm厚的焦滤层6,在熔体穿透焦滤层6向下流动时,被碳还原,从而使ZnO和FeO等比较难还原的金属氧化物也基本完成还原。The metal oxide melt such as iron and zinc which is not completely reduced in the lower reactant 1 enters the 150 mm thick coke filter layer 6 in the form of droplets, and is reduced by carbon when the melt penetrates the pyrophoric layer 6 downward. Therefore, the metal oxides such as ZnO and FeO which are relatively difficult to reduce are also substantially reduced.
在熔池2中,矿粉中的脉石和加入的熔剂造渣,通过侧吹喷管4向熔池2喷入氧气和粉煤(工艺氧浓度为99.6%,粉煤粒度为5mm-8mm),为熔池2补充热量,并使熔池2形成1300℃-1650℃的高温还原环境。侧吹的位置位于渣层的下部,可使熔体翻滚,使渣层中的少量未还原的锌铁铅铋铟等金属氧化物与碳还原剂充分接触,彻底完成还原。在熔池2中, 还原出来的Zn绝大部分会迅速气化离开熔体进入上升烟道3,其余被还原出来的金属液滴除了极少量挥发外,穿过密度较小的渣层向下聚集,Fe和Pb熔体完全不互溶,金属层分为铁水层和粗铅合金层,由于密度的差异,熔池1从上到下形成渣层、铁水层、粗铅合金层三层结构。少量的Bi、In及少量未蒸发的Zn易溶于铅液中,被铅液捕集后进入粗铅合金层,粗铅合金排出后,后续可以采用精炼等方式提纯Pb并分离合金中的其它金属。In the molten pool 2, the gangue in the ore powder and the added flux slag are sprayed with oxygen and pulverized coal into the molten pool 2 through the side blowing nozzle 4 (process oxygen concentration is 99.6%, and pulverized coal particle size is 5 mm-8 mm) The molten pool 2 is supplemented with heat, and the molten pool 2 is formed into a high-temperature reducing environment of 1300 ° C to 1650 ° C. The position of the side blowing is located at the lower part of the slag layer, and the melt can be tumbling, so that a small amount of unreduced zinc oxide, lead bismuth, indium and the like in the slag layer is sufficiently contacted with the carbon reducing agent to completely complete the reduction. In the molten pool 2, Most of the reduced Zn will rapidly vaporize away from the melt into the ascending flue 3, and the remaining metal droplets will be concentrated down through the less dense slag layer, and the Fe and Pb will melt. The body is completely immiscible, and the metal layer is divided into a molten iron layer and a crude lead alloy layer. Due to the difference in density, the molten pool 1 forms a three-layer structure of a slag layer, a molten iron layer and a crude lead alloy layer from top to bottom. A small amount of Bi, In and a small amount of unvaporized Zn are easily dissolved in the lead liquid, and are trapped by the lead liquid and then enter the crude lead alloy layer. After the crude lead alloy is discharged, the Pb can be purified by refining or the like. metal.
采用本发明提供的串联闪速炉对钢铁烟尘进行处理的工艺,相比现有的回转窑工艺或湿法工艺,流程短,可综合回收多种有价金属,综合能耗降低40%以上,污染减少90%。The process for treating steel soot by using the tandem flash furnace provided by the invention is shorter than the existing rotary kiln process or wet process, and can comprehensively recover a plurality of valuable metals, and the comprehensive energy consumption is reduced by more than 40%. Pollution is reduced by 90%.
在下反应体1内发生的主要化学反应有:The main chemical reactions occurring in the lower reactant 1 are:
CaCO3=CaO+CO2 CaCO 3 =CaO+CO 2
ZnO+CO=Zn(g)+CO2 ZnO+CO=Zn(g)+CO 2
PbO+CO=Pb+CO2 PbO+CO=Pb+CO 2
Bi2O3+3CO=2Bi+3CO2 Bi 2 O 3 +3CO=2Bi+3CO 2
In2O3+3CO=2In+3CO2 In 2 O 3 +3CO=2In+3CO 2
3Fe2O3+CO=2Fe3O4+CO2 3Fe 2 O 3 +CO=2Fe 3 O 4 +CO 2
Fe3O4+CO=3FeO+CO2 Fe 3 O 4 +CO=3FeO+CO 2
FeO+CO=Fe+CO2 FeO+CO=Fe+CO 2
在熔池2中发生的主要化学反应如下:The main chemical reactions occurring in the molten pool 2 are as follows:
(PbO)+C=Pb(l)+CO(PbO) slag + C = Pb (l) + CO
(ZnO)+C=Zn(g)+CO(ZnO) slag + C = Zn (g) + CO
(ZnO)+Fe(l)=Zn(g)+(FeO) (ZnO) slag + Fe(l) = Zn(g) + (FeO) slag
(PbO)+Fe(l)=Pb(g)+(FeO) (PbO) slag + Fe(l) = Pb(g) + (FeO) slag
(FeO)+C=Fe(l)+CO(FeO) slag + C = Fe(l) + CO
(Bi2O3)+3C=2Bi(l)+3CO(Bi 2 O 3 ) slag +3C=2Bi(l)+3CO
(In2O3)+3C=2In(l)+3CO (In 2 O 3 ) slag +3C=2In(l)+3CO
根据本发明的一个实施例,连接通道7的内宽不大于下反应体1内径的2/3,同时长度不大于2m。连接通道7的内宽过大会影响上反应体5内部的压强,进而影响造气效率。连接通道7的长度不大于2m,以免过长影响上反应体5向下反应体1传递热量的效率。According to an embodiment of the invention, the inner width of the connecting passage 7 is not more than 2/3 of the inner diameter of the lower reaction body 1, while the length is not more than 2 m. The inner width of the connecting passage 7 affects the pressure inside the upper reaction body 5, thereby affecting the gas generating efficiency. The length of the connecting passage 7 is not more than 2 m, so as not to affect the efficiency of the upper reaction body 5 transferring heat to the reaction body 1 downward.
根据本发明的一个实施例,连接通道7上设有给料装置,如图1所示,通过该给料装置可以给入待冶炼的矿粉,使矿粉和还原气体提前接触,提高矿粉中待冶炼金属氧化物的还原率。给料装置为喷嘴、喷枪、密封加料口中的一种或多种;或者为喷嘴、喷枪、密封加料口中的一种或多种与烧嘴的组合。通过设置喷嘴或喷枪或密封加料口向闪速炉加入冶炼所必需的原料、燃料和辅助材料。给料装置也可设置在下反应体1顶端,如图2所示,2组烧嘴设置在下反应体1的顶部为下反应体1补充热量。另外,根据需要,给料装置也可设置下反应体1的侧壁上。According to an embodiment of the present invention, the connecting channel 7 is provided with a feeding device, as shown in FIG. 1, through which the ore powder to be smelted can be fed, the mineral powder and the reducing gas are contacted in advance, and the mineral powder is increased. The reduction rate of metal oxides to be smelted. The feeding device is one or more of a nozzle, a spray gun, and a sealing feed port; or a combination of one or more of a nozzle, a spray gun, and a sealing feed port and a burner. Add the raw materials, fuel and auxiliary materials necessary for smelting to the flash furnace by setting a nozzle or a spray gun or a sealed feed port. The feeding device may also be disposed at the top end of the lower reaction body 1, as shown in Fig. 2, and two sets of burners are disposed at the top of the lower reaction body 1 to supplement the heat of the lower reaction body 1. Further, the feeding means may be provided on the side wall of the lower reaction body 1 as needed.
根据本发明的一个实施例,上反应体5上设有向上反应体5内喷吹含氧气体及气化剂的喷枪或喷管。喷枪或喷管设置于上反应体5上,并穿透上反应体5内壁,伸入上反应体5内,如图1及图2所示。喷枪或喷管向上反应体5中喷入含氧气体及气化剂。双通道的喷枪向上反应体5内喷入氧气和煤粉,用来产生还原气体(CO+H2)并为下反应体1提供热量。According to an embodiment of the present invention, the upper reaction body 5 is provided with a spray gun or a nozzle for blowing an oxygen-containing gas and a gasifying agent into the upper reaction body 5. The spray gun or nozzle is disposed on the upper reaction body 5, penetrates the inner wall of the upper reaction body 5, and extends into the upper reaction body 5, as shown in FIGS. 1 and 2. The lance or the nozzle sprays an oxygen-containing gas and a gasifying agent into the reaction body 5. The dual-channel spray gun injects oxygen and pulverized coal into the reaction body 5 to generate a reducing gas (CO + H 2 ) and provide heat to the lower reaction body 1.
根据本发明的一个实施例,所述熔池2内盛纳熔体的空间上部设有焦滤层空间。所述熔池2熔体上部形成有熔融炉料下落时通过的焦滤层6,如图2所示,一种实现方式是通过设置在下反应体1顶部的喷嘴把焦炭加入下反应体1,焦炭粒径范围为1-11mm,在下反应体1内迅速被加热,加热后的焦炭颗粒落到熔池2熔体表面形成一层多孔的碳物料-焦滤层6。如果块度小于1mm,焦炭在高温下损耗较快,但粒度超过11mm又会使焦炭的中心不能够被加热到足够的温度,且粒度过大会使焦炭颗粒间的间隙变大,这会导致通过焦滤层6的待冶炼金属氧化物熔体回收率的损失。焦滤层6也可通过喷吹适合炼焦的粉煤的方式实现,粉煤在高温下烧掉其中的挥发分后,即可形成焦炭颗粒。According to an embodiment of the invention, a space above the space in which the melt is contained in the molten pool 2 is provided with a space for the filter layer. The upper portion of the melt of the molten pool 2 is formed with a pyrophoric layer 6 which passes through the molten charge. As shown in FIG. 2, an embodiment is to add coke to the lower reaction body 1 through a nozzle disposed at the top of the lower reaction body 1, coke. The particle size ranges from 1 to 11 mm, and is rapidly heated in the lower reaction body 1, and the heated coke particles fall on the surface of the molten pool 2 to form a porous carbon material-coke filter layer 6. If the blockiness is less than 1mm, the coke will lose faster at high temperature, but the particle size of more than 11mm will make the center of the coke not be heated to a sufficient temperature, and the excessive particle size will make the gap between the coke particles larger, which will lead to the passage. Loss of the recovery of the metal oxide melt to be smelted by the pyrophoric layer 6. The coke filter layer 6 can also be realized by spraying a pulverized coal suitable for coking, and after the pulverized coal is burned off at a high temperature, coke particles can be formed.
根据本发明的一个实施例,焦滤层空间高50-250mm,优选为100-200mm,如图2所示。根据待冶炼金属被碳还原的难易程度,适当调节焦滤层的厚度,调节的方法是调节向下反应体1内加入焦炭或粉煤的速度。According to one embodiment of the invention, the focal filter layer space is 50-250 mm high, preferably 100-200 mm, as shown in FIG. According to the difficulty of carbon reduction of the metal to be smelted, the thickness of the pyrophoric layer is appropriately adjusted by adjusting the speed at which coke or pulverized coal is added to the lower reaction body 1.
根据本发明的一个实施例,各熔池2均设有向熔池2内喷入含碳燃料和含氧气体的侧吹布置,如图3-4及6-11所示。In accordance with an embodiment of the present invention, each of the molten pools 2 is provided with a side blowing arrangement for injecting a carbonaceous fuel and an oxygen containing gas into the molten pool 2, as shown in Figures 3-4 and 6-11.
根据本发明的一个实施例,侧吹布置所在位置与所述熔池中熔渣层中下部对应,侧吹设 置在熔渣层中下部,可以使熔渣形成对流或翻滚,方便上下层间热量和物质的交换,从而减小熔体的粘度,提高金属回收率。According to an embodiment of the present invention, the position of the side blowing arrangement corresponds to the lower middle portion of the slag layer in the molten pool, and the side blowing is provided. Placed in the lower part of the slag layer, the slag can be convected or tumbling, which facilitates the exchange of heat and substances between the upper and lower layers, thereby reducing the viscosity of the melt and improving the metal recovery rate.
根据本发明的一个实施例,上升烟道3数目与熔池2数目一致,如图10及图11所示。According to one embodiment of the invention, the number of ascending flues 3 coincides with the number of molten pools 2, as shown in Figures 10 and 11.
根据本发明的一个实施例,熔池2的数目为1-4个。闪速炉中1-4个熔池2的设置能够满足不同冶炼产量需求。According to an embodiment of the invention, the number of molten pools 2 is 1-4. The setting of 1-4 molten pools 2 in the flash furnace can meet the needs of different smelting production.
以上所述仅为本发明的较佳实施例而已,并不用以限制本发明,凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。 The above is only the preferred embodiment of the present invention, and is not intended to limit the present invention. Any modifications, equivalent substitutions, improvements, etc., which are included in the spirit and scope of the present invention, should be included in the present invention. Within the scope of protection.

Claims (10)

  1. 一种串联闪速炉,其特征在于:包括上反应体(5)、下反应体(1)及连通两者的连接通道(7),所述上反应体(5)位于所述下反应体(1)的上部,形成串联式结构,所述下反应体(1)下部设有至少一个熔池(2);所述闪速炉还包括用于排出烟气的上升烟道(3),所述上升烟道(3)通过所述熔池(2)与所述下反应体(1)相连通,各所述熔池(2)上均设有排渣口。A tandem flash furnace characterized by comprising an upper reaction body (5), a lower reaction body (1) and a connecting passage (7) communicating the two, the upper reaction body (5) being located in the lower reaction body The upper part of (1) forms a tandem structure, and the lower part of the lower reaction body (1) is provided with at least one molten pool (2); the flash furnace further includes a rising flue (3) for discharging flue gas, The rising flue (3) is in communication with the lower reaction body (1) through the molten pool (2), and each of the molten pools (2) is provided with a slag discharge port.
  2. 根据权利要求1所述的串联闪速炉,其特征在于:所述连接通道(7)的内宽不大于下反应体(1)内径的2/3,长度不大于2m。The tandem flash furnace according to claim 1, characterized in that the inner width of the connecting passage (7) is not more than 2/3 of the inner diameter of the lower reaction body (1) and the length is not more than 2 m.
  3. 根据权利要求1-2任一项所述的串联闪速炉,其特征在于:所述连接通道(7)上设有给料装置。The tandem flash furnace according to any one of claims 1-2, characterized in that the connecting channel (7) is provided with a feeding device.
  4. 根据权利要求3所述的串联闪速炉,其特征在于:所述上反应体(5)上设有向上反应体(5)内喷吹含氧气体及气化剂的喷枪或喷管。The tandem flash furnace according to claim 3, characterized in that the upper reaction body (5) is provided with a spray gun or a nozzle for blowing an oxygen-containing gas and a gasifying agent into the upper reaction body (5).
  5. 根据权利要求1所述的串联闪速炉,其特征在于:所述熔池(2)内盛纳熔体的空间上部设有熔融炉料下落时通过的焦滤层空间。The tandem flash furnace according to claim 1, characterized in that the upper portion of the space in the molten pool (2) containing the melt is provided with a space of the pyrophoric layer through which the molten charge falls.
  6. 根据权利要求5所述的串联闪速炉,其特征在于:所述焦滤层空间高50-250mm。A tandem flash furnace according to claim 5, wherein said pyrophoric layer has a space of 50-250 mm.
  7. 根据权利要求1所述的串联闪速炉,其特征在于:各所述熔池(2)均设有向所述熔池(2)内喷入燃料和含氧气体的侧吹布置。A tandem flash furnace according to claim 1, characterized in that each of said molten pools (2) is provided with a side blowing arrangement for injecting fuel and oxygen-containing gas into said molten pool (2).
  8. 根据权利要求7所述的串联闪速炉,其特征在于:所述侧吹布置所在位置与所述熔池中熔渣层中下部对应。The tandem flash furnace according to claim 7, wherein the position of the side blowing arrangement corresponds to a lower middle portion of the slag layer in the molten pool.
  9. 根据权利要求1所述的串联闪速炉,其特征在于:所述熔池(2)的数目为1-4个。The tandem flash furnace according to claim 1, characterized in that the number of the molten pools (2) is 1-4.
  10. 一种利用权利要求1-9所述的闪速炉进行冶炼的方法。 A method of smelting using the flash furnace of claims 1-9.
PCT/CN2017/074026 2016-04-28 2017-02-19 Serial flash furnace and smelting method thereof WO2017185858A1 (en)

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