WO2017185857A1 - Flash furnace having side-blown molten pool sections - Google Patents

Flash furnace having side-blown molten pool sections Download PDF

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Publication number
WO2017185857A1
WO2017185857A1 PCT/CN2017/074025 CN2017074025W WO2017185857A1 WO 2017185857 A1 WO2017185857 A1 WO 2017185857A1 CN 2017074025 W CN2017074025 W CN 2017074025W WO 2017185857 A1 WO2017185857 A1 WO 2017185857A1
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Prior art keywords
molten pool
pool
flash furnace
blown
pool section
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PCT/CN2017/074025
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French (fr)
Chinese (zh)
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李效东
夏明�
邱江波
黄小兵
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天津闪速炼铁技术有限公司
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Publication of WO2017185857A1 publication Critical patent/WO2017185857A1/en

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B15/00Obtaining copper
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B3/00Hearth-type furnaces, e.g. of reverberatory type; Tank furnaces
    • F27B3/10Details, accessories, or equipment peculiar to hearth-type furnaces
    • F27B3/20Arrangements of heating devices
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B3/00Hearth-type furnaces, e.g. of reverberatory type; Tank furnaces
    • F27B3/10Details, accessories, or equipment peculiar to hearth-type furnaces

Definitions

  • the invention belongs to the field of metallurgy, and in particular relates to a flash furnace with a side blowing pool section.
  • Flash metallurgy has only been used in the smelting of sulfide ore from invention to the present, and has not been applied to the smelting of oxidized ore.
  • flash copper smelting is a powdery copper sulphide concentrate after drying. After the concentrate nozzle is fully mixed with the oxygen-enriched air, it is sprayed into the flash furnace, and the thermal dissociation and oxidation reaction are carried out in the high-temperature reaction tower to partially oxidize and slag the copper in the copper concentrate to produce ice with higher copper content. copper. Since the reaction of sulfide and oxygen releases a large amount of heat, there is no need to additionally add heat to the molten pool.
  • the inner width of the molten pool is determined according to the inner diameter of the reaction tower, generally 1-2 meters of the inner diameter of the reaction tower, and its top view is shown in Fig. 2.
  • the principle of oxidized ore flash metallurgy is that the mineral powder is in the process of floating and falling in the hot flash furnace reaction tower filled with reducing atmosphere.
  • the special surface area of the contact between the mineral powder and the high-temperature reducing gas is large, and the reaction speed is fast.
  • the reduction of the metal oxide to be smelted in the mineral powder, the metal oxide which is not completely reduced falls into the molten pool and continues to be reduced.
  • the molten pool of the oxidized ore flash furnace needs to carry out the slagging reaction and complete the separation and discharge of the liquid metal and slag. Therefore, it is necessary to maintain a high-temperature reducing environment.
  • the heat and reducing agent delivered by the reaction tower are still far from enough to accomplish the above work. Therefore, it is a necessary means to replenish the molten pool and provide a reducing agent by means of side blowing.
  • the side blowing of the molten pool is achieved by arranging side blowing nozzles on the side of the molten pool. In China, blowing coal and oxygen through the side of the nozzle is one of the most economical solutions. According to a large number of tests, we can conclude that the inner width of the side-blown molten pool cannot be more than 3 meters, otherwise the center of the molten pool is difficult to be blown through.
  • the inner width of the molten pool is 1-2 meters larger than the diameter of the reaction tower. At present, there is no flash furnace with a width smaller than the diameter of the reaction tower. There is a case where a flash furnace has multiple molten pools. Due to the limitation of space smelting principle, all practical flash furnaces have a diameter of more than 3 meters, that is, the width of the molten pool is more than 4 meters. If the side is blown, the molten pool is supplemented with heat and reaction materials.
  • the inner diameter of the molten pool is more than 3 meters, if the spray gun is too shallow, the center of the molten pool cannot be affected, resulting in low temperature, high viscosity in the middle part of the molten pool, and high content of metal oxide to be smelted in the molten slag. If the spray gun is deep into the molten pool, although the center can be blown through, but melted The edge of the pool cannot be directly affected, and the edge area of the pool is low in temperature, high in viscosity, and the content of metal oxide to be smelted in the slag is high. This means that the traditional Alto Kampus sulphide flash furnace cannot effectively use the side blowing method to replenish the molten pool and provide reaction materials.
  • the present invention aims to propose a flash furnace with a side blow pool segment to solve the problem that the existing flash furnace bath cannot be smelted by metal oxidizing ore by side blowing.
  • a flash furnace with a side-blown molten pool section comprising a reaction tower 1 having a feeding device on the reaction tower 1 and at least one molten pool 2 in the lower portion of the reaction tower 1, each of the molten pools 2, each of which is provided with a side blowing pool section having an inner width of less than 3 meters, and a side blowing arrangement is arranged on a side of the side blowing pool section, and the molten pool 2 is provided with a slag discharging port 5, and the side is blown a pool section is located between the slag discharge port 5 and the molten pool 2;
  • the flash furnace further includes a rising flue 3, and the rising flue 3 is connected to the reaction tower 1 through the molten pool 2 The rising flue 3 is used to discharge the flue gas generated during the reaction.
  • the side blowing arrangement is used for injecting fuel and oxygen-containing gas into the furnace body of the side blowing pool to provide heat and reducing agent for the molten pool 2,
  • the fuel is heavy oil, natural gas, liquefied petroleum gas, coal, One of a char, a hydrocarbon gas;
  • the oxygen-containing gas is one of air, an oxygen-air mixture, or process oxygen.
  • the side-blown molten pool section is located between the slag discharge port and the molten pool 2, so that the melt is smelted through the side blow smelting of the side-blown smelting pool section, and further precipitated and stratified, thereby reducing the content of the metal to be smelted in the slag layer and improving The recovery rate of metals to be smelted.
  • the number of the rising flue 3 is the same as the number of the molten pool 2.
  • the side blow pool section has a length of 8-20 meters.
  • the side blow pool segment is a rectangular parallelepiped.
  • the inner width of the side-blowing molten pool section is 1.5-2.5 m. Within the width range, the spray guns on both sides of the side-blowing molten pool section can jointly affect the central area of the molten pool, and at the same time, both sides of the molten pool can be considered. The melt exerts an effective influence. If the width of the side-blown molten pool section is too narrow, which will affect the bearing capacity of the molten pool, it is necessary to increase the number of molten pools and increase the investment.
  • the inner width of the molten pool 2 is gradually reduced from the end of the reaction column 1 to a distance of less than 3 meters and not less than 1 meter.
  • the melt and flue gas flow rate can be gently changed to reduce the impact on the smelting process.
  • the number of the molten pools 2 is 1-4.
  • the side blowing arrangement includes a side blowing hole symmetrically disposed in the side blowing pool section and a side blowing nozzle 4 disposed in the side blowing hole.
  • the position of the side blowing arrangement corresponds to the slag layer in the side blowing pool section, so that the side blowing arrangement sprays oxygen-containing gas and fuel into the slag layer of the side blowing pool section.
  • the slag is tumbling or convected, the heat transfer in the melt and the chemical reaction in the slag layer are promoted, and the recovery rate of the metal to be smelted is improved.
  • Oxygen-containing gas air, oxygen-air mixture or process oxygen
  • CO, H 2 reducing gas
  • the combustion of the oxygen-containing gas and the reducing gas in the flue gas is carried out through the tuyere provided on the side wall of the flue 3, and on the one hand, the soot adhesion due to the temperature drop of the flue gas during the flow process can be avoided, and the flue is blocked. It is possible to burn off the CO in the exhaust gas and reduce the subsequent flue gas treatment process.
  • the feeding device is a combination of a nozzle or a nozzle, a burner or a burner, and a nozzle and a spray gun.
  • the raw material, fuel and auxiliary materials necessary for smelting are added to the flash furnace by setting the feeding device, and if necessary, heat can be added to the space of the reaction tower 1 through a feeding device such as a burner.
  • the ascending flue 3 is disposed at an upper portion of the molten pool 2 near the inlet of the side blown pool section.
  • the flue gas does not directly enter the flue through the side-blown molten pool section, thereby avoiding fluctuations in the flue gas flow rate due to the change in the width of the molten pool in the side-blown molten pool section.
  • reaction tower 1 is connected with a gas transport pipeline so that the reaction gas introduced from the outside of the flash furnace and the heat it carries can be directly delivered into the furnace.
  • the reaction gas is one or more of CO, H 2 or hydrocarbon gas; preferably, it is industrially produced exhaust gas containing a reducing atmosphere or gas produced by a coal gas generating device; more preferably, It is one or more of blast furnace gas, converter gas, coke oven gas, electric furnace tail gas, rotary kiln tail gas, and rotary bottom furnace exhaust gas.
  • the flash furnace with side blowing pool segments of the present invention has the following advantages:
  • the flash furnace of the present invention can directly affect various parts of the molten pool by side blowing by providing a side blowing pool section having an inner width of less than 3 meters, in particular, the central part can be blown through, and the side blowing is on the one hand
  • the molten pool replenishes the heat, so that the molten pool forms a liquid melt environment with good fluidity, thereby realizing the functions of slag formation, slag and metal precipitation stratification, slag and metal discharge, and the side blowing setting can also provide the molten pool.
  • the reducing agent completes the reduction of the remaining metal oxides to be smelted in the slag layer, and improves the recovery rate of the metal to be smelted.
  • Figure 1-2 is a schematic structural view of a conventional flash furnace
  • FIG. 3 is a schematic structural view of a flash furnace with a side blow pool section according to an embodiment of the present invention
  • FIG. 4 is another schematic structural view of a flash furnace with a side blow pool section according to an embodiment of the present invention.
  • FIG. 5 is a schematic view showing a third structure of a flash furnace with a side blow pool section according to an embodiment of the present invention
  • FIG. 6 is a fourth structural schematic view of a flash furnace with a side blow pool section according to an embodiment of the present invention.
  • FIG. 7 is a fifth structural schematic view of a flash furnace with a side blow pool section according to an embodiment of the invention.
  • FIG. 8 is a sixth structural schematic view of a flash furnace with a side blow pool segment according to an embodiment of the invention.
  • FIG. 9 is a seventh structural schematic view of a flash furnace with a side blow pool section according to an embodiment of the present invention.
  • FIG. 10 is a schematic view showing an eighth structure of a flash furnace with a side blow pool section according to an embodiment of the present invention.
  • FIG. 11 is a ninth structural schematic view of a flash furnace with a side blow pool section according to an embodiment of the present invention.
  • Figure 12 is a tenth structural schematic view of a flash furnace with a side blown pool section according to an embodiment of the present invention.
  • first”, “second”, and the like are used for the purpose of description only, and are not to be construed as indicating or implying a relative importance or implicitly indicating the number of technical features indicated.
  • features defining “first”, “second”, etc. may include one or more of the features, either explicitly or implicitly.
  • connection In the description of the present invention, it should be noted that the terms “installation”, “connected”, and “connected” are to be understood broadly, and may be fixed or detachable, for example, unless otherwise explicitly defined and defined. Connected, or integrally connected; can be mechanical or electrical; can be directly connected, or indirectly connected through an intermediate medium, can be the internal communication of the two components.
  • Connected, or integrally connected can be mechanical or electrical; can be directly connected, or indirectly connected through an intermediate medium, can be the internal communication of the two components.
  • the specific meaning of the above terms in the present invention can be understood by a person of ordinary skill in the art.
  • a flash furnace with a side blowing pool section comprises a reaction tower 1, a reaction device is arranged on the reaction tower 1, and at least one molten pool 2 is arranged in the lower part of the reaction tower 1, each The molten pool 2 is provided with a side blowing pool section having an inner width of less than 3 meters, and the side of the side blowing pool section is provided with a side blowing arrangement, the molten pool 2 is provided with a slag discharging port 5, and the side blowing molten pool section is located at the row Between the slag port and the molten pool 2; the flash furnace further includes an ascending flue 3 for discharging flue gas generated during the reaction, and the ascending flue 3 communicates with the reaction tower 1 through the molten pool 2.
  • the melt which completes the chemical reaction in the reaction tower 1 falls into the molten pool 2 in the lower part of the flash furnace, and the side of the molten pool 2 is provided with a side blowing arrangement, and the molten pool is supplemented with heat by the side blowing fuel and oxygen, so that the molten pool 2 is maintained constant. High temperature environment.
  • a side blowing pool section having an inner width of less than 3 meters is specially provided.
  • the fuel and the oxygen-containing gas are injected into the melt through the side blowing
  • Pulverized coal and oxygen are respectively injected into the slag layer to provide heat for the side-blown molten pool section and maintain the reducing environment of the molten pool, while tumbling or convecting the slag layer, accelerating the exchange of heat and substances between the upper and lower layers, and promoting chemical reaction.
  • the rapid progress is made such that the metal oxide which is not completely reduced in the reaction column 1 is reduced in the side blow pool section.
  • the design of the side blown pool section of less than 3 meters enables the various positions of the side blown pool section to be directly affected by the side blow even at the center, thereby eliminating the dead angle and improving the reduction rate and recovery rate of the metal to be smelted.
  • the overall viscosity of the melt in the molten pool 2 is lowered.
  • the gangue component and the flux slag in the ore powder after the reduction smelting and clarification through the side-blown molten pool section, the reduced metal and the slag are precipitated and layered, and the slag layer is formed due to the difference in density. And a layer of coarse metal, the slag is discharged from the end of the molten pool The mouth is discharged.
  • the reduced low-boiling metal is vaporized and then enters the flue gas and flows out of the furnace from the rising flue 3, and can be recovered by condensation.
  • the flash furnace with side blowing pool section provided by the invention is applied to the smelting of manganese oxide ore. This is the first time that the flash furnace is newly applied to the production of manganese alloy, and the specific smelting process is as follows:
  • the reaction tower has a diameter of 4 meters and a height of 7 meters.
  • the total length of the molten pool is 20 meters.
  • the length of the side-blown molten pool with an inner width of less than 3 meters is 12 meters, and the width of the end of the side-blown molten pool is 1.2.
  • the manganese dioxide ore (soft manganese ore and hard manganese ore, manganese content greater than 25%) after enrichment in ore dressing, drying to moisture ⁇ 0.3%, grinding 80% granules less than 200 mesh; pulverized coal is divided into two types, A kind of flash furnace is sprayed from the top of the reaction tower for gas production, and the pulverized coal is subjected to coal grinding and drying treatment, so that the water content is less than 1%, the particle size is less than 200 mesh, 85%, and the other is used for the side. For blowing and blowing, it does not need to be specially dried, the particle size is 5mm-8mm; the flux is quicklime, the particle size is less than 1mm, and the water content is less than 1%.
  • Manganese dioxide powder ore, pulverized coal, oxygen-enriched, flux CaO is sprayed into the reaction tower from the top nozzle of the flash furnace reaction tower.
  • the pulverized coal reacts with oxygen to produce CO and a small amount of H 2 and provides heat to the reaction tower space. 1200-1450 ° C, in the hot space of reducing atmosphere, manganese dioxide in the mineral powder and CO reduction reaction, the formation of MnO, iron oxide in the ore powder is also reduced to low-cost FeO and part of the metal Fe .
  • the main reactions in the reaction column space are as follows:
  • the gangue component and the flux slag in the ore powder due to the difference in density, the reduced liquid metal flows to the bottom of the molten pool, and after the slag is precipitated and layered, a slag layer is formed from top to bottom.
  • the carbon-manganese-iron alloy layer the slag is smelted through the side-blown molten pool section, and is discharged from the slag discharge port 5 at the end of the molten pool, and the metal alloy is discharged from the molten pool to obtain high-carbon ferromanganese, and the recovery rate of manganese is 95%.
  • the comprehensive energy consumption per unit of product is less than 850kgce/t, compared to the current manganese oxide ore furnace or electric furnace (electric furnace) smelting process less than 90% manganese recovery rate, higher than 1000kgce / t of comprehensive energy consumption, in recycling
  • the efficiency and energy consumption indicators have been greatly improved.
  • the manganese-rich slag with low phosphorus content can be produced through the above process, and the manganese-rich slag can be used for subsequent production of silicon-manganese alloy or manganese metal.
  • the silicon-manganese alloy can be directly produced by the flash furnace, and the reaction is as follows:
  • the number of ascending flue 3 is the same as the number of molten pool 2, as shown in Figure 9-12.
  • the length of the side blown pool section is 8-20 meters.
  • the side blown pool section is a rectangular parallelepiped, as shown in Figure 3-5 and Figure 9-10.
  • the inner width of the side-blown molten pool section is 1.5-2.5 m.
  • the spray guns on both sides of the side-blown molten pool section can be 0.3-1.1 meters deep into the furnace as needed, and affect the area of the center of the molten pool. At the same time, avoiding the deep penetration of the spray gun can not effectively exert an effective influence on the melt on both side walls of the molten pool. If the width of the side blown pool section is too narrow, which will affect the bearing capacity of the melt, the number of molten pools needs to be increased. increase investment.
  • the inner width of the molten pool 2 is gradually reduced from the end of the reaction tower 1 to the distal end to 1 m, as shown in Fig. 6-8, so that the melt and the flue gas flow rate can be gently changed to reduce the influence on the smelting process.
  • the number of molten pools 2 is 1-4.
  • the side blowing arrangement includes a side blowing hole symmetrically disposed in the side blowing pool section and a side blowing nozzle 4 disposed in the side blowing hole.
  • the position of the side blowing arrangement corresponds to the slag layer in the side blowing pool section, so that the side blowing arrangement sprays oxygen-containing gas and fuel into the slag layer of the side blowing pool section, so that the slag is tumbling or convective It promotes the exchange of heat in the melt and the chemical reaction in the slag layer to improve the recovery rate of the metal.
  • Each of the molten pools 2 is provided with a side blowing arrangement for injecting fuel and oxygen-containing gas into the molten pool 2.
  • the fuel may be one of heavy oil, natural gas, liquefied petroleum gas, coal, coke or hydrocarbon gas;
  • the oxygen-containing gas is one of air, oxygen-air mixture or process oxygen.
  • a tuyere is provided on the molten pool 2 or on the side wall of the ascending flue 3.
  • Oxygen-containing gas air, oxygen-air mixture or process oxygen
  • CO, H 2 reducing gas
  • the combustion of the oxygen-containing gas and the reducing gas in the flue gas is carried out through the tuyere provided on the side wall of the flue 3, and on the one hand, the soot adhesion due to the temperature drop of the flue gas during the flow process can be avoided, and the flue is blocked. It is possible to burn off the CO in the exhaust gas and reduce the subsequent flue gas treatment process.
  • the feeding device is a combination of a nozzle or a nozzle, a burner or a burner, and a nozzle and a spray gun.
  • the ascending flue 3 is disposed near the upper portion of the molten pool 2 at the inlet of the side-blown molten pool section, and the flue gas does not directly enter the flue through the side-blown molten pool section, thereby avoiding the flue gas flow rate due to the variation of the molten pool width of the side-blown molten pool section.
  • the fluctuations are shown in Figure 11.
  • the reaction tower 1 is connected to a gas transport pipe so that the reaction gas introduced from the outside of the flash furnace and the heat it carries can be directly delivered to the furnace.
  • the reaction gas is one or more of CO, H 2 or hydrocarbon gas; preferably, it is industrially produced exhaust gas containing a reducing atmosphere or gas produced by a coal gas generating device; more preferably, It is one or more of blast furnace gas, converter gas, coke oven gas, electric furnace tail gas, rotary kiln tail gas, and rotary bottom furnace exhaust gas.

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Abstract

A flash furnace having side-blown molten pool sections, comprising a reaction tower (1). At least one molten pool (2) is provided below the reaction tower (1); each molten pool (2) is provided with a side-blown molten pool section having an inner width of less than 3 m; a side-blown arrangement is provided on a side surface of the side-blown molten pool section; a slag discharge port is provided at a tail end of the side-blown molten pool section; the side-blown molten pool section is located between the slag discharge port and the reaction tower (1). The flash furnace further comprises an uptake flue (3) that is in communication with the reaction tower (1) by means of the molten pool (2). By providing a side-blown molten pool section having an inner width of less than 3 m, all portions of a molten pool (2) can be directly affected by side blowing, and a liquid melt environment with good flowability is formed by the molten pool (2), thereby implementing functions such as slag formation, and the settling, stratification, and discharging of slag and metal. In addition, the arrangement of side blowing can also provide a reducing agent for the molten pool (2) to complete the reduction of the remaining metal oxides to be smelted in a slag layer so as to improve the recovery of metal.

Description

一种带有侧吹熔池段的闪速炉Flash furnace with side blowing pool section 技术领域Technical field
本发明属于冶金领域,尤其是涉及一种带有侧吹熔池段的闪速炉。The invention belongs to the field of metallurgy, and in particular relates to a flash furnace with a side blowing pool section.
背景技术Background technique
闪速冶金从发明到现在,只用于硫化矿的冶炼,还没有应用于氧化矿的冶炼,以闪速炼铜为例,闪速炼铜工艺是将干燥后的粉状铜硫化物精矿经精矿喷嘴与富氧空气充分混合后喷入闪速炉,在高温反应塔内进行热离解和氧化反应,使铜精矿中部分铁氧化并造渣除去,产出含铜较高的冰铜。由于硫化物和氧气反应会放出大量的热量,所以无须再额外为熔池补充热量。Flash metallurgy has only been used in the smelting of sulfide ore from invention to the present, and has not been applied to the smelting of oxidized ore. For example, flash copper smelting is a powdery copper sulphide concentrate after drying. After the concentrate nozzle is fully mixed with the oxygen-enriched air, it is sprayed into the flash furnace, and the thermal dissociation and oxidation reaction are carried out in the high-temperature reaction tower to partially oxidize and slag the copper in the copper concentrate to produce ice with higher copper content. copper. Since the reaction of sulfide and oxygen releases a large amount of heat, there is no need to additionally add heat to the molten pool.
传统硫化矿闪速炉结构示意图如图1所示。The schematic diagram of the structure of the traditional sulfide mine flash furnace is shown in Figure 1.
传统奥托昆普硫化矿闪速炉在设计时,熔池的内宽是根据反应塔的内径确定的,一般为反应塔内径加上1-2米,其俯视示意图如图2所示。In the design of the traditional Outokumpu sulfide mine flash furnace, the inner width of the molten pool is determined according to the inner diameter of the reaction tower, generally 1-2 meters of the inner diameter of the reaction tower, and its top view is shown in Fig. 2.
氧化矿闪速冶金原理是矿粉在炽热的充满还原气氛的闪速炉反应塔空间悬浮下落的过程中,利用矿粉与高温还原气体接触的比表面积较大,反应速度快的特点,实现对矿粉中的待冶炼金属氧化物的还原,未完全还原的金属氧化物落入熔池后继续完成还原。The principle of oxidized ore flash metallurgy is that the mineral powder is in the process of floating and falling in the hot flash furnace reaction tower filled with reducing atmosphere. The special surface area of the contact between the mineral powder and the high-temperature reducing gas is large, and the reaction speed is fast. The reduction of the metal oxide to be smelted in the mineral powder, the metal oxide which is not completely reduced falls into the molten pool and continues to be reduced.
氧化矿闪速炉的熔池除了要完成剩余待冶炼金属氧化物的还原外,还要进行造渣反应及完成液态金属和熔渣的分离和排放,因而需要维持一个高温的还原环境,仅靠反应塔传递来的热量和还原剂还远远不足以完成上述工作。因而,通过侧吹的方式为熔池补充热量和提供还原剂就成为一种必要的手段。熔池侧吹是通过在熔池侧面布置侧吹喷管实现的,在中国,通过喷管侧吹煤和氧是其中一种最经济的方案。我们根据大量试验得出:侧吹熔池的内宽不能大于3米,否则熔池的中心部位难以被吹透。In addition to the reduction of the remaining metal oxides to be smelted, the molten pool of the oxidized ore flash furnace needs to carry out the slagging reaction and complete the separation and discharge of the liquid metal and slag. Therefore, it is necessary to maintain a high-temperature reducing environment. The heat and reducing agent delivered by the reaction tower are still far from enough to accomplish the above work. Therefore, it is a necessary means to replenish the molten pool and provide a reducing agent by means of side blowing. The side blowing of the molten pool is achieved by arranging side blowing nozzles on the side of the molten pool. In China, blowing coal and oxygen through the side of the nozzle is one of the most economical solutions. According to a large number of tests, we can conclude that the inner width of the side-blown molten pool cannot be more than 3 meters, otherwise the center of the molten pool is difficult to be blown through.
但根据传统的奥拓昆普闪速炉的设计原则,熔池的内宽要比反应塔直径大1-2米,,目前还未出现过熔池内宽小于反应塔直径的闪速炉,也未出现一台闪速炉拥有多个熔池的情况。受空间冶炼原理的限制,迄今为止所有实际应用的闪速炉的直径都在3米以上,也即熔池内宽都大于4米,若采用侧吹的方式为熔池补充热量和反应物料,对于内宽大于3米以上的熔池,若喷枪深入熔池过浅,则熔池中心无法被影响到,造成熔池中部区域温度低、粘度高、熔渣中待冶炼的金属氧化物含量高,若喷枪深入熔池过深,虽然中心部位可以被吹透,但熔 池的边缘部位无法被直接影响到,又会造成熔池边缘区域温度低、粘度高、熔渣中待冶炼的金属氧化物含量高。这就意味着传统奥拓昆普硫化矿闪速炉无法有效的应用侧吹的方式为熔池补充热量及提供反应物料。However, according to the design principle of the traditional Alto Kunpu flash furnace, the inner width of the molten pool is 1-2 meters larger than the diameter of the reaction tower. At present, there is no flash furnace with a width smaller than the diameter of the reaction tower. There is a case where a flash furnace has multiple molten pools. Due to the limitation of space smelting principle, all practical flash furnaces have a diameter of more than 3 meters, that is, the width of the molten pool is more than 4 meters. If the side is blown, the molten pool is supplemented with heat and reaction materials. If the inner diameter of the molten pool is more than 3 meters, if the spray gun is too shallow, the center of the molten pool cannot be affected, resulting in low temperature, high viscosity in the middle part of the molten pool, and high content of metal oxide to be smelted in the molten slag. If the spray gun is deep into the molten pool, although the center can be blown through, but melted The edge of the pool cannot be directly affected, and the edge area of the pool is low in temperature, high in viscosity, and the content of metal oxide to be smelted in the slag is high. This means that the traditional Alto Kampus sulphide flash furnace cannot effectively use the side blowing method to replenish the molten pool and provide reaction materials.
发明内容Summary of the invention
有鉴于此,本发明旨在提出一种带有侧吹熔池段的闪速炉,以解决现有的闪速炉熔池无法通过侧吹对金属氧化矿进行熔炼的问题。In view of this, the present invention aims to propose a flash furnace with a side blow pool segment to solve the problem that the existing flash furnace bath cannot be smelted by metal oxidizing ore by side blowing.
为达到上述目的,本发明的技术方案是这样实现的:In order to achieve the above object, the technical solution of the present invention is achieved as follows:
一种带有侧吹熔池段的闪速炉,包括反应塔1,所述反应塔1上设有给料装置,所述反应塔1下部设有至少一个熔池2,各所述熔池2上均设有内宽小于3米的侧吹熔池段,所述侧吹熔池段的侧面设有侧吹布置,所述熔池2上设置有排渣口5,所述侧吹熔池段位于所述排渣口5和所述熔池2之间;所述闪速炉还包括上升烟道3,所述上升烟道3通过所述熔池2与所述反应塔1相连通,上升烟道3用于排出反应过程中所产生的烟气。A flash furnace with a side-blown molten pool section, comprising a reaction tower 1 having a feeding device on the reaction tower 1 and at least one molten pool 2 in the lower portion of the reaction tower 1, each of the molten pools 2, each of which is provided with a side blowing pool section having an inner width of less than 3 meters, and a side blowing arrangement is arranged on a side of the side blowing pool section, and the molten pool 2 is provided with a slag discharging port 5, and the side is blown a pool section is located between the slag discharge port 5 and the molten pool 2; the flash furnace further includes a rising flue 3, and the rising flue 3 is connected to the reaction tower 1 through the molten pool 2 The rising flue 3 is used to discharge the flue gas generated during the reaction.
所述侧吹布置用来向所述侧吹熔池段炉体内喷入燃料及含氧气体,为熔池2内提供热量及还原剂,所述燃料为重油、天然气、液化石油气、煤、焦丁、碳氢化合物气体中的一种;所述含氧气体为空气,氧气-空气混合物或者工艺氧中的一种。小于3米的侧吹熔池段的设置能够使熔池2的各个部位都可以被侧吹直接影响,进而为熔池2内补充热量和提供还原剂。侧吹熔池段位于排渣口和熔池2之间,以便使熔体经过侧吹熔池段的侧吹熔炼,进一步沉淀分层后排放,从而降低渣层中待冶炼金属的含量,提高待冶炼金属的回收率。The side blowing arrangement is used for injecting fuel and oxygen-containing gas into the furnace body of the side blowing pool to provide heat and reducing agent for the molten pool 2, the fuel is heavy oil, natural gas, liquefied petroleum gas, coal, One of a char, a hydrocarbon gas; the oxygen-containing gas is one of air, an oxygen-air mixture, or process oxygen. The arrangement of the side-blown molten pool sections of less than 3 meters enables the various parts of the molten pool 2 to be directly affected by the side blows, thereby supplementing the molten pool 2 with heat and providing a reducing agent. The side-blown molten pool section is located between the slag discharge port and the molten pool 2, so that the melt is smelted through the side blow smelting of the side-blown smelting pool section, and further precipitated and stratified, thereby reducing the content of the metal to be smelted in the slag layer and improving The recovery rate of metals to be smelted.
优选的,所述上升烟道3数目与所述熔池2数目一致。Preferably, the number of the rising flue 3 is the same as the number of the molten pool 2.
优选的,所述侧吹熔池段的长度为8-20米。Preferably, the side blow pool section has a length of 8-20 meters.
优选的,所述侧吹熔池段为长方体。优选的,侧吹熔池段的内宽为1.5-2.5米,在该宽度范围内,侧吹熔池段两侧喷枪可以共同影响到熔池中心区域,同时又能兼顾对熔池两侧壁的熔体施加有效的影响,若侧吹熔池段宽度过窄,会影响熔池对熔体的承载量,则需增加熔池的数目,增加投资。Preferably, the side blow pool segment is a rectangular parallelepiped. Preferably, the inner width of the side-blowing molten pool section is 1.5-2.5 m. Within the width range, the spray guns on both sides of the side-blowing molten pool section can jointly affect the central area of the molten pool, and at the same time, both sides of the molten pool can be considered. The melt exerts an effective influence. If the width of the side-blown molten pool section is too narrow, which will affect the bearing capacity of the molten pool, it is necessary to increase the number of molten pools and increase the investment.
优选的,所述熔池2的内宽由所述反应塔1端向远端逐渐减小至小于3米且不小于1米。从而使熔体和烟气流速能够平缓的变化,减小对冶炼过程的影响。Preferably, the inner width of the molten pool 2 is gradually reduced from the end of the reaction column 1 to a distance of less than 3 meters and not less than 1 meter. Thereby, the melt and flue gas flow rate can be gently changed to reduce the impact on the smelting process.
进一步的,所述熔池2的数目为1-4个。 Further, the number of the molten pools 2 is 1-4.
进一步的,所述侧吹布置包括对称设置在所述侧吹熔池段的侧吹孔及设置在侧吹孔内的侧吹喷管4。Further, the side blowing arrangement includes a side blowing hole symmetrically disposed in the side blowing pool section and a side blowing nozzle 4 disposed in the side blowing hole.
进一步的,所述侧吹布置所在位置与所述侧吹熔池段中熔渣层对应,以便使所述侧吹布置向所述侧吹熔池段熔渣层内喷吹含氧气体和燃料,使熔渣翻滚或对流,促进熔体内热量的交流传递及熔渣层中的化学反应,提高待冶炼金属的回收率。Further, the position of the side blowing arrangement corresponds to the slag layer in the side blowing pool section, so that the side blowing arrangement sprays oxygen-containing gas and fuel into the slag layer of the side blowing pool section. The slag is tumbling or convected, the heat transfer in the melt and the chemical reaction in the slag layer are promoted, and the recovery rate of the metal to be smelted is improved.
进一步的,所述熔池2上或上升烟道3侧壁上设有风口。含氧气体(空气、氧-空气混合物或者工艺氧)通过风口喷入熔池液面上部的连通烟道使还原气体(CO、H2)二次燃烧,一方面为熔池补充热量,另一方面降低尾气中CO的含量。通过烟道3侧壁上设置的风口喷入含氧气体和烟气中的还原气体进行燃烧,一方面可以避免由于烟气在流动过程中温度下降造成的烟尘粘结堵塞烟道,另一个作用是可以烧掉尾气中的CO,减少后续的烟气处理工序。Further, a tuyeres are arranged on the molten pool 2 or on the sidewalls of the ascending flue 3. Oxygen-containing gas (air, oxygen-air mixture or process oxygen) is injected into the communicating flue above the surface of the molten pool through the tuyere to cause secondary combustion of the reducing gas (CO, H 2 ), on the one hand to replenish the molten pool, and on the other hand In terms of reducing the CO content in the exhaust gas. The combustion of the oxygen-containing gas and the reducing gas in the flue gas is carried out through the tuyere provided on the side wall of the flue 3, and on the one hand, the soot adhesion due to the temperature drop of the flue gas during the flow process can be avoided, and the flue is blocked. It is possible to burn off the CO in the exhaust gas and reduce the subsequent flue gas treatment process.
进一步的,所述给料装置为喷嘴或喷嘴、烧嘴或烧嘴与喷嘴、喷枪的结合。通过设置给料装置向闪速炉加入冶炼所必需的原料、燃料和辅助材料,必要时,也可通过给料装置如烧嘴为反应塔1空间内补充热量。Further, the feeding device is a combination of a nozzle or a nozzle, a burner or a burner, and a nozzle and a spray gun. The raw material, fuel and auxiliary materials necessary for smelting are added to the flash furnace by setting the feeding device, and if necessary, heat can be added to the space of the reaction tower 1 through a feeding device such as a burner.
进一步的,所述上升烟道3设置在靠近所述侧吹熔池段入口处的熔池2上部。烟气不经过侧吹熔池段直接进入烟道,从而避免由于侧吹熔池段熔池宽度的变化引起出炉烟气流速的波动。Further, the ascending flue 3 is disposed at an upper portion of the molten pool 2 near the inlet of the side blown pool section. The flue gas does not directly enter the flue through the side-blown molten pool section, thereby avoiding fluctuations in the flue gas flow rate due to the change in the width of the molten pool in the side-blown molten pool section.
进一步的,所述反应塔1连接有气体输运管道,以便从闪速炉外部引入的反应气体及其所带的热量可以直接输送至炉内。所述反应气体为含CO、H2或碳氢化合物气体中的一种或多种;优选的,为工业生产排放的含还原气氛的废气或煤制气装置所生产的煤气;更优选的,为高炉煤气、转炉煤气、焦炉煤气、电炉尾气、回转窑尾气、转底炉尾气中的一种或多种。Further, the reaction tower 1 is connected with a gas transport pipeline so that the reaction gas introduced from the outside of the flash furnace and the heat it carries can be directly delivered into the furnace. The reaction gas is one or more of CO, H 2 or hydrocarbon gas; preferably, it is industrially produced exhaust gas containing a reducing atmosphere or gas produced by a coal gas generating device; more preferably, It is one or more of blast furnace gas, converter gas, coke oven gas, electric furnace tail gas, rotary kiln tail gas, and rotary bottom furnace exhaust gas.
相对于现有技术,本发明所述的带有侧吹熔池段的闪速炉具有以下优势:Compared with the prior art, the flash furnace with side blowing pool segments of the present invention has the following advantages:
本发明所述的闪速炉通过设置内宽小于3米的侧吹熔池段,使熔池的各个部位都可以被侧吹直接影响,特别是中心部位可以被吹透,侧吹一方面为熔池补充热量,使熔池形成流动性良好的液态熔体环境,从而实现造渣、渣和金属的沉淀分层、渣和金属的排放等功能,同时,侧吹设置也可为熔池提供还原剂,完成渣层中剩余待冶炼金属氧化物的还原,提高待冶炼金属的回收率。The flash furnace of the present invention can directly affect various parts of the molten pool by side blowing by providing a side blowing pool section having an inner width of less than 3 meters, in particular, the central part can be blown through, and the side blowing is on the one hand The molten pool replenishes the heat, so that the molten pool forms a liquid melt environment with good fluidity, thereby realizing the functions of slag formation, slag and metal precipitation stratification, slag and metal discharge, and the side blowing setting can also provide the molten pool. The reducing agent completes the reduction of the remaining metal oxides to be smelted in the slag layer, and improves the recovery rate of the metal to be smelted.
附图说明 DRAWINGS
构成本发明的一部分的附图用来提供对本发明的进一步理解,本发明的示意性实施例及其说明用于解释本发明,并不构成对本发明的不当限定。在附图中:The accompanying drawings, which are incorporated in the claims In the drawing:
图1-2为现有的闪速炉的结构示意图;Figure 1-2 is a schematic structural view of a conventional flash furnace;
图3为本发明实施例所述的带有侧吹熔池段的闪速炉的一种结构示意图;3 is a schematic structural view of a flash furnace with a side blow pool section according to an embodiment of the present invention;
图4为本发明实施例所述的带有侧吹熔池段的闪速炉的另一种结构示意图;4 is another schematic structural view of a flash furnace with a side blow pool section according to an embodiment of the present invention;
图5为本发明实施例所述的带有侧吹熔池段的闪速炉的第三种结构示意图;5 is a schematic view showing a third structure of a flash furnace with a side blow pool section according to an embodiment of the present invention;
图6为本发明实施例所述的带有侧吹熔池段的闪速炉的第四种结构示意图;6 is a fourth structural schematic view of a flash furnace with a side blow pool section according to an embodiment of the present invention;
图7为本发明实施例所述的带有侧吹熔池段的闪速炉的第五种结构示意图;7 is a fifth structural schematic view of a flash furnace with a side blow pool section according to an embodiment of the invention;
图8为本发明实施例所述的带有侧吹熔池段的闪速炉的第六种结构示意图;8 is a sixth structural schematic view of a flash furnace with a side blow pool segment according to an embodiment of the invention;
图9为本发明实施例所述的带有侧吹熔池段的闪速炉的第七种结构示意图;9 is a seventh structural schematic view of a flash furnace with a side blow pool section according to an embodiment of the present invention;
图10为本发明实施例所述带有侧吹熔池段的闪速炉的第八种结构示意图;10 is a schematic view showing an eighth structure of a flash furnace with a side blow pool section according to an embodiment of the present invention;
图11为本发明实施例所述带有侧吹熔池段的闪速炉的第九种结构示意图;11 is a ninth structural schematic view of a flash furnace with a side blow pool section according to an embodiment of the present invention;
图12为本发明实施例所述带有侧吹熔池段的闪速炉的第十种结构示意图。Figure 12 is a tenth structural schematic view of a flash furnace with a side blown pool section according to an embodiment of the present invention.
附图标记说明:Description of the reference signs:
1-反应塔,2-熔池,3-上升烟道,4-侧吹喷管,5-排渣口。1-reaction tower, 2-melt pool, 3-rise flue, 4-side blow nozzle, 5-slag drain.
具体实施方式detailed description
需要说明的是,在不冲突的情况下,本发明中的实施例及实施例中的特征可以相互组合。It should be noted that the embodiments in the present invention and the features in the embodiments may be combined with each other without conflict.
在本发明的描述中,需要理解的是,术语“中心”、“纵向”、“横向”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”、“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。此外,术语“第一”、“第二”等仅用于描述目的,而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量。由此,限定有“第一”、“第二”等的特征可以明示或者隐含地包括一个或者更多个该特征。 In the description of the present invention, it is to be understood that the terms "center", "longitudinal", "lateral", "upper", "lower", "front", "back", "left", "right", " The orientation or positional relationship of the indications of "upright", "horizontal", "top", "bottom", "inside", "outside", etc. is based on the orientation or positional relationship shown in the drawings, only for the convenience of describing the present invention and The simplification of the description is not intended to limit or imply that the device or component that is referred to has a particular orientation, is constructed and operated in a particular orientation, and thus is not to be construed as limiting. Moreover, the terms "first", "second", and the like are used for the purpose of description only, and are not to be construed as indicating or implying a relative importance or implicitly indicating the number of technical features indicated. Thus, features defining "first", "second", etc. may include one or more of the features, either explicitly or implicitly.
在本发明的描述中,需要说明的是,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体地连接;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以通过具体情况理解上述术语在本发明中的具体含义。In the description of the present invention, it should be noted that the terms "installation", "connected", and "connected" are to be understood broadly, and may be fixed or detachable, for example, unless otherwise explicitly defined and defined. Connected, or integrally connected; can be mechanical or electrical; can be directly connected, or indirectly connected through an intermediate medium, can be the internal communication of the two components. The specific meaning of the above terms in the present invention can be understood by a person of ordinary skill in the art.
下面将参考附图并结合实施例来详细说明本发明。The invention will be described in detail below with reference to the drawings in conjunction with the embodiments.
一种带有侧吹熔池段的闪速炉,如图3-12所示,包括反应塔1,反应塔1上设有给料装置,反应塔1下部设有至少一个熔池2,各熔池2上均设有内宽小于3米的侧吹熔池段,侧吹熔池段的侧面设有侧吹布置,熔池2上设置有排渣口5,侧吹熔池段位于排渣口和熔池2之间;闪速炉还包括用于排出反应过程中所产生烟气的上升烟道3,上升烟道3通过熔池2与所述反应塔1相连通。A flash furnace with a side blowing pool section, as shown in FIG. 3-12, comprises a reaction tower 1, a reaction device is arranged on the reaction tower 1, and at least one molten pool 2 is arranged in the lower part of the reaction tower 1, each The molten pool 2 is provided with a side blowing pool section having an inner width of less than 3 meters, and the side of the side blowing pool section is provided with a side blowing arrangement, the molten pool 2 is provided with a slag discharging port 5, and the side blowing molten pool section is located at the row Between the slag port and the molten pool 2; the flash furnace further includes an ascending flue 3 for discharging flue gas generated during the reaction, and the ascending flue 3 communicates with the reaction tower 1 through the molten pool 2.
本实例的工作过程:The working process of this example:
向反应塔1中喷入待冶炼的金属氧化矿矿粉、还原气体(如CO或H2)或可造还原气体的反应物(如氧气和粉煤)及熔剂(参与造渣),矿粉在高温炽热的、充满还原气氛的反应塔1中,通过快速的传热、传质和气-固、气-液反应,迅速完成其中待冶炼金属氧化物的还原和熔化。Spraying the metal oxide ore powder to be smelted into the reaction tower 1, a reducing gas (such as CO or H 2 ) or a reactant (such as oxygen and pulverized coal) capable of producing a reducing gas, and a flux (participating in slagging), mineral powder In the high temperature hot, reductive atmosphere-containing reaction column 1, the reduction and melting of the metal oxide to be smelted therein are rapidly completed by rapid heat transfer, mass transfer, and gas-solid, gas-liquid reaction.
在反应塔1中完成化学反应的熔体落入闪速炉下部的熔池2,熔池2侧面设有侧吹布置,通过侧吹燃料和氧气为熔池补充热量,使熔池2维持一定的高温环境。The melt which completes the chemical reaction in the reaction tower 1 falls into the molten pool 2 in the lower part of the flash furnace, and the side of the molten pool 2 is provided with a side blowing arrangement, and the molten pool is supplemented with heat by the side blowing fuel and oxygen, so that the molten pool 2 is maintained constant. High temperature environment.
在熔池中特别设有内宽小于3米侧吹熔池段,当熔体流经侧吹熔池段时,通过侧吹向熔体中喷吹燃料和含氧气体,本实施例中向熔渣层中分别喷吹煤粉和氧气,为侧吹熔池段提供热量并维持熔池的还原环境,同时使熔渣层翻滚或对流,加快上下层间热量和物质的交换,促进化学反应的快速进行,从而使在反应塔1中未被完全还原的金属氧化物在侧吹熔池段中完成还原。小于3米的侧吹熔池段的设计,使侧吹熔池段的各个位置即便是中心部位也可以被侧吹直接影响到,从而消除了死角,提高了待冶炼金属的还原率和回收率,降低了熔池2中熔体的整体粘度。In the molten pool, a side blowing pool section having an inner width of less than 3 meters is specially provided. When the melt flows through the side blowing pool section, the fuel and the oxygen-containing gas are injected into the melt through the side blowing, in this embodiment, Pulverized coal and oxygen are respectively injected into the slag layer to provide heat for the side-blown molten pool section and maintain the reducing environment of the molten pool, while tumbling or convecting the slag layer, accelerating the exchange of heat and substances between the upper and lower layers, and promoting chemical reaction. The rapid progress is made such that the metal oxide which is not completely reduced in the reaction column 1 is reduced in the side blow pool section. The design of the side blown pool section of less than 3 meters enables the various positions of the side blown pool section to be directly affected by the side blow even at the center, thereby eliminating the dead angle and improving the reduction rate and recovery rate of the metal to be smelted. The overall viscosity of the melt in the molten pool 2 is lowered.
在熔池2中,矿粉中的脉石成分与熔剂造渣,在经过侧吹熔池段的还原熔炼和澄清后,被还原出的金属与熔渣沉淀分层,由于密度差异形成渣层和粗金属层,渣从熔池末端的排渣 口排出。被还原出来的低沸点金属气化后进入烟气从上升烟道3流出炉外,后续可通过冷凝的方式进行回收。In the molten pool 2, the gangue component and the flux slag in the ore powder, after the reduction smelting and clarification through the side-blown molten pool section, the reduced metal and the slag are precipitated and layered, and the slag layer is formed due to the difference in density. And a layer of coarse metal, the slag is discharged from the end of the molten pool The mouth is discharged. The reduced low-boiling metal is vaporized and then enters the flue gas and flows out of the furnace from the rising flue 3, and can be recovered by condensation.
将本发明提供的带有侧吹熔池段的闪速炉应用于氧化锰矿的冶炼,这是首次把闪速炉创新应用于生产锰合金,具体冶炼工艺如下:The flash furnace with side blowing pool section provided by the invention is applied to the smelting of manganese oxide ore. This is the first time that the flash furnace is newly applied to the production of manganese alloy, and the specific smelting process is as follows:
1)闪速炉设计:1) Flash furnace design:
反应塔直径为4米,高7米,熔池总长20米,如图11所示,其中内宽小于3米的侧吹熔池段长为12米,侧吹熔池段末端内宽为1.2米,年处理矿量120万吨。The reaction tower has a diameter of 4 meters and a height of 7 meters. The total length of the molten pool is 20 meters. As shown in Fig. 11, the length of the side-blown molten pool with an inner width of less than 3 meters is 12 meters, and the width of the end of the side-blown molten pool is 1.2. Rice, with an annual processing capacity of 1.2 million tons.
2)原料准备:2) Raw material preparation:
经选矿富集后的二氧化锰矿(软锰矿或硬锰矿,含锰量大于25%),烘干至水份≦0.3%,磨矿使80%颗粒小于200目;粉煤分为两种,一种从反应塔顶部喷入闪速炉用于造气,该粉煤须进行磨煤及干燥处理,使其含水量低于1%、粒度小于200目占85%,另一种用于侧吹喷吹用,不需要经过特别干燥,粒度为5mm-8mm;熔剂为生石灰,粒度小于1mm,含水量低于1%。The manganese dioxide ore (soft manganese ore and hard manganese ore, manganese content greater than 25%) after enrichment in ore dressing, drying to moisture ≦ 0.3%, grinding 80% granules less than 200 mesh; pulverized coal is divided into two types, A kind of flash furnace is sprayed from the top of the reaction tower for gas production, and the pulverized coal is subjected to coal grinding and drying treatment, so that the water content is less than 1%, the particle size is less than 200 mesh, 85%, and the other is used for the side. For blowing and blowing, it does not need to be specially dried, the particle size is 5mm-8mm; the flux is quicklime, the particle size is less than 1mm, and the water content is less than 1%.
3)熔炼过程:3) Smelting process:
二氧化锰粉矿、粉煤、富氧、熔剂CaO从闪速炉反应塔顶部喷嘴喷入反应塔,粉煤与氧气反应生产CO及少量H2并为反应塔空间提供热量,反应塔的温度为1200-1450℃,在炽热的呈还原气氛的空间中,矿粉中的二氧化锰与CO发生还原反应,生成MnO,矿粉中的氧化铁也被还原成低价的FeO及部分金属Fe。Manganese dioxide powder ore, pulverized coal, oxygen-enriched, flux CaO is sprayed into the reaction tower from the top nozzle of the flash furnace reaction tower. The pulverized coal reacts with oxygen to produce CO and a small amount of H 2 and provides heat to the reaction tower space. 1200-1450 ° C, in the hot space of reducing atmosphere, manganese dioxide in the mineral powder and CO reduction reaction, the formation of MnO, iron oxide in the ore powder is also reduced to low-cost FeO and part of the metal Fe .
反应塔空间主要的反应如下:The main reactions in the reaction column space are as follows:
2C+O2=2CO2C+O 2 =2CO
4MnO2+2CO=2Mn2O3+2CO2 4MnO 2 + 2CO = 2Mn 2 O 3 + 2CO 2
3Mn2O3+CO=2Mn3O4+CO2 3Mn 2 O 3 +CO=2Mn 3 O 4 +CO 2
Mn3O4+CO=3MnO+CO2 Mn 3 O 4 +CO=3MnO+CO 2
3Fe2O3+CO=2Fe3O4+CO2 3Fe 2 O 3 +CO=2Fe 3 O 4 +CO 2
Fe3O4+CO=3FeO+CO2 Fe 3 O 4 +CO=3FeO+CO 2
FeO+CO=Fe+CO2 FeO+CO=Fe+CO 2
在空间反应后的熔体落入熔池,由于MnO比较难还原,只能在熔池中由固碳进行还原, 在熔体流经侧吹熔池段时,通过侧吹喷管向熔体喷入氧气和煤粉(工艺氧浓度为99.6%,煤粉过量),一方面为熔池补充热量,使熔池维持1450℃-1650℃的高温,同时使熔池2形成强还原环境;另一方面,通过向渣层下部喷吹煤氧的侧吹布置,可使渣层翻滚,加快熔体上下层间的热量交换,同时使锰和铁氧化物与碳还原剂能充分接触,即便在熔池中心部位热量和还原剂也充足,从而使MnO和FeO彻底的被C还原。The melt after the space reaction falls into the molten pool. Since MnO is relatively difficult to reduce, it can only be reduced by carbon fixation in the molten pool. When the melt flows through the side blowing pool section, oxygen and pulverized coal are injected into the melt through the side blowing nozzle (process oxygen concentration is 99.6%, excessive coal powder), on the one hand, the molten pool is supplemented with heat, so that the molten pool Maintaining a high temperature of 1450 ° C - 1650 ° C, while making the molten pool 2 form a strong reducing environment; on the other hand, by spraying the side blowing arrangement of coal oxygen to the lower part of the slag layer, the slag layer can be tumbled and the upper and lower layers of the melt can be accelerated. Heat exchange, at the same time, make manganese and iron oxides in full contact with the carbon reducing agent, even if the heat and reducing agent are sufficient in the center of the molten pool, so that MnO and FeO are completely reduced by C.
在熔池中,矿粉中的脉石成分和熔剂造渣,由于密度的差异,还原后的液态的金属流到熔池底部,和熔渣沉淀分层后,从上至下分别形成渣层和碳锰铁合金层,熔渣经过侧吹熔池段熔炼后,从熔池的末端排渣口5排出炉外,金属合金从熔池排出后得到高碳锰铁,锰的回收率达95%以上,单位产品的综合能耗低于850kgce/t,相对于目前氧化锰矿高炉或矿热炉(电炉)冶炼工艺不到90%的锰回收率、高于1000kgce/t的综合能耗,在回收效率和能耗指标方面得到了较大的提升。In the molten pool, the gangue component and the flux slag in the ore powder, due to the difference in density, the reduced liquid metal flows to the bottom of the molten pool, and after the slag is precipitated and layered, a slag layer is formed from top to bottom. And the carbon-manganese-iron alloy layer, the slag is smelted through the side-blown molten pool section, and is discharged from the slag discharge port 5 at the end of the molten pool, and the metal alloy is discharged from the molten pool to obtain high-carbon ferromanganese, and the recovery rate of manganese is 95%. Above, the comprehensive energy consumption per unit of product is less than 850kgce/t, compared to the current manganese oxide ore furnace or electric furnace (electric furnace) smelting process less than 90% manganese recovery rate, higher than 1000kgce / t of comprehensive energy consumption, in recycling The efficiency and energy consumption indicators have been greatly improved.
熔池发生的主要化学反应如下:The main chemical reactions taking place in the molten pool are as follows:
C+O2=CO2 C+O 2 =CO 2
CO2+C=2COCO 2 +C=2CO
MnO·SiO2+CaO=CaO·SiO2+MnOMnO·SiO 2 +CaO=CaO·SiO 2 +MnO
FeO+C=Fe+COFeO+C=Fe+CO
3MnO+4C=Mn3C+3CO3MnO+4C=Mn 3 C+3CO
4)在氧化锰矿的闪速熔炼工艺中,若不加熔剂或少加熔剂,通过上述流程则可生产含磷低的富锰渣,富锰渣可用于后续生产硅锰合金或金属锰。4) In the flash smelting process of manganese oxide ore, if no flux or less flux is added, the manganese-rich slag with low phosphorus content can be produced through the above process, and the manganese-rich slag can be used for subsequent production of silicon-manganese alloy or manganese metal.
若在原料中添加硅石,同时提高熔池的温度至1665℃以上(SiO2在该温度开始被C还原成Si),则可用该闪速炉直接生产硅锰合金,反应如下:If silica is added to the raw material and the temperature of the molten pool is raised to above 1665 ° C (SiO 2 is reduced to Si by C at this temperature), the silicon-manganese alloy can be directly produced by the flash furnace, and the reaction is as follows:
SiO2+2C=Si+2COSiO 2 +2C=Si+2CO
Mn3C+3Si=3MnSi+CMn 3 C+3Si=3MnSi+C
上升烟道3数目与熔池2数目一致,如图9-12所示。The number of ascending flue 3 is the same as the number of molten pool 2, as shown in Figure 9-12.
侧吹熔池段的长度为8-20米。The length of the side blown pool section is 8-20 meters.
侧吹熔池段为长方体,如图3-5及图9-10所示。优选的,侧吹熔池段的内宽为1.5-2.5米,在该范围内,侧吹熔池段两侧喷枪根据需要可以深入炉内0.3-1.1米,共同影响到熔池中心的区域,同时又避免喷枪深入过深无法对熔池两侧壁边的熔体施加有效的影响,若侧吹熔池段宽度过窄,会影响对熔体的承载量,则需增加熔池的数目,增加投资。The side blown pool section is a rectangular parallelepiped, as shown in Figure 3-5 and Figure 9-10. Preferably, the inner width of the side-blown molten pool section is 1.5-2.5 m. Within this range, the spray guns on both sides of the side-blown molten pool section can be 0.3-1.1 meters deep into the furnace as needed, and affect the area of the center of the molten pool. At the same time, avoiding the deep penetration of the spray gun can not effectively exert an effective influence on the melt on both side walls of the molten pool. If the width of the side blown pool section is too narrow, which will affect the bearing capacity of the melt, the number of molten pools needs to be increased. increase investment.
熔池2的内宽由反应塔1端向远端逐渐减小至1米,如图6-8所示,从而使熔体和烟气流速能够平缓的变化,减小对冶炼过程的影响。 The inner width of the molten pool 2 is gradually reduced from the end of the reaction tower 1 to the distal end to 1 m, as shown in Fig. 6-8, so that the melt and the flue gas flow rate can be gently changed to reduce the influence on the smelting process.
熔池2的数目为1-4个。The number of molten pools 2 is 1-4.
侧吹布置包括对称设置在侧吹熔池段的侧吹孔及设置在侧吹孔内的侧吹喷管4。The side blowing arrangement includes a side blowing hole symmetrically disposed in the side blowing pool section and a side blowing nozzle 4 disposed in the side blowing hole.
侧吹布置所在位置与侧吹熔池段中熔渣层对应,以便使所述侧吹布置向所述侧吹熔池段熔渣层内喷吹含氧气体和燃料,使熔渣翻滚或对流,促进熔体内热量的交流传递及熔渣层中的化学反应,提高金属的回收率。The position of the side blowing arrangement corresponds to the slag layer in the side blowing pool section, so that the side blowing arrangement sprays oxygen-containing gas and fuel into the slag layer of the side blowing pool section, so that the slag is tumbling or convective It promotes the exchange of heat in the melt and the chemical reaction in the slag layer to improve the recovery rate of the metal.
各熔池2均设有向熔池2内喷入燃料和含氧气体的侧吹布置。燃料可以为重油、天然气、液化石油气、煤、焦丁或碳氢化合物气体中的一种;含氧气体为空气、氧气-空气混合物或者工艺氧中的一种。Each of the molten pools 2 is provided with a side blowing arrangement for injecting fuel and oxygen-containing gas into the molten pool 2. The fuel may be one of heavy oil, natural gas, liquefied petroleum gas, coal, coke or hydrocarbon gas; the oxygen-containing gas is one of air, oxygen-air mixture or process oxygen.
熔池2上或上升烟道3侧壁上设有风口。含氧气体(空气、氧-空气混合物或者工艺氧)通过风口喷入熔池液面上部的连通烟道使还原气体(CO、H2)二次燃烧,一方面为熔池补充热量,另一方面降低尾气中CO的含量。通过烟道3侧壁上设置的风口喷入含氧气体和烟气中的还原气体进行燃烧,一方面可以避免由于烟气在流动过程中温度下降造成的烟尘粘结堵塞烟道,另一个作用是可以烧掉尾气中的CO,减少后续的烟气处理工序。A tuyere is provided on the molten pool 2 or on the side wall of the ascending flue 3. Oxygen-containing gas (air, oxygen-air mixture or process oxygen) is injected into the communicating flue above the surface of the molten pool through the tuyere to cause secondary combustion of the reducing gas (CO, H 2 ), on the one hand to replenish the molten pool, and on the other hand In terms of reducing the CO content in the exhaust gas. The combustion of the oxygen-containing gas and the reducing gas in the flue gas is carried out through the tuyere provided on the side wall of the flue 3, and on the one hand, the soot adhesion due to the temperature drop of the flue gas during the flow process can be avoided, and the flue is blocked. It is possible to burn off the CO in the exhaust gas and reduce the subsequent flue gas treatment process.
给料装置为喷嘴或喷嘴、烧嘴或烧嘴与喷嘴、喷枪的结合。通过设置在反应塔顶部的喷嘴和/或喷枪向闪速炉加入冶炼所必需的原料、燃料和辅助材料,也可同时在反应塔上设置烧嘴,当闪速炉内热量不足时,通过烧嘴为反应塔1空间内补充热量。The feeding device is a combination of a nozzle or a nozzle, a burner or a burner, and a nozzle and a spray gun. By adding the raw materials, fuel and auxiliary materials necessary for smelting to the flash furnace through nozzles and/or spray guns provided at the top of the reaction tower, it is also possible to set a burner on the reaction tower at the same time, and when the heat in the flash furnace is insufficient, the fire is burned. The mouth is supplemented with heat in the space of the reaction tower 1.
上升烟道3设置在靠近侧吹熔池段入口处的熔池2上部,烟气不经过侧吹熔池段直接进入烟道,从而避免由于侧吹熔池段熔池宽度的变化引起出炉烟气流速的波动,如图11所示。The ascending flue 3 is disposed near the upper portion of the molten pool 2 at the inlet of the side-blown molten pool section, and the flue gas does not directly enter the flue through the side-blown molten pool section, thereby avoiding the flue gas flow rate due to the variation of the molten pool width of the side-blown molten pool section. The fluctuations are shown in Figure 11.
反应塔1连接有气体输运管道,以便从闪速炉外部引入的反应气体及其所带的热量可以直接输送至炉内。所述反应气体为含CO、H2或碳氢化合物气体中的一种或多种;优选的,为工业生产排放的含还原气氛的废气或煤制气装置所生产的煤气;更优选的,为高炉煤气、转炉煤气、焦炉煤气、电炉尾气、回转窑尾气、转底炉尾气中的一种或多种。The reaction tower 1 is connected to a gas transport pipe so that the reaction gas introduced from the outside of the flash furnace and the heat it carries can be directly delivered to the furnace. The reaction gas is one or more of CO, H 2 or hydrocarbon gas; preferably, it is industrially produced exhaust gas containing a reducing atmosphere or gas produced by a coal gas generating device; more preferably, It is one or more of blast furnace gas, converter gas, coke oven gas, electric furnace tail gas, rotary kiln tail gas, and rotary bottom furnace exhaust gas.
以上所述仅为本发明的较佳实施例而已,并不用以限制本发明,凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。 The above is only the preferred embodiment of the present invention, and is not intended to limit the present invention. Any modifications, equivalent substitutions, improvements, etc., which are included in the spirit and scope of the present invention, should be included in the present invention. Within the scope of protection.

Claims (10)

  1. 一种带有侧吹熔池段的闪速炉,其特征在于:包括反应塔(1),所述反应塔(1)上设有给料装置,所述反应塔(1)下部设有至少一个熔池(2),各所述熔池(2)上均设有内宽小于3米的侧吹熔池段,所述侧吹熔池段的侧面设有侧吹布置,所述熔池(2)上设置有排渣口(5),所述侧吹熔池段位于所述排渣口(5)和所述反应塔(2)之间;所述闪速炉还包括上升烟道(3),所述上升烟道(3)通过所述熔池(2)与所述反应塔(1)相连通。A flash furnace with a side blow pool segment, characterized in that it comprises a reaction tower (1), the reaction tower (1) is provided with a feeding device, and the lower portion of the reaction tower (1) is provided with at least a molten pool (2), each of the molten pools (2) is provided with a side blowing pool section having an inner width of less than 3 meters, and a side blowing arrangement is provided on a side of the side blowing pool section, the molten pool (2) provided with a slag discharge port (5), the side blown smelting pool section is located between the slag discharge port (5) and the reaction tower (2); the flash furnace further includes a rising flue (3) The rising flue (3) is in communication with the reaction column (1) through the molten pool (2).
  2. 根据权利要求1所述的带有侧吹熔池段的闪速炉,其特征在于:所述侧吹熔池段为长方体,优选的,侧吹熔池段的内宽为1.5-2.5米。The flash furnace with a side blow pool segment according to claim 1, wherein the side blow pool segment is a rectangular parallelepiped, and preferably, the side blow pool segment has an inner width of 1.5-2.5 meters.
  3. 根据权利要求1所述的带有侧吹熔池段的闪速炉,其特征在于:所述熔池(2)的内宽由所述反应塔(1)端向远端逐渐减小至小于3米且不小于1米。The flash furnace with a side blow pool section according to claim 1, characterized in that the inner width of the molten pool (2) is gradually reduced from the end of the reaction tower (1) to the distal end to less than 3 meters and not less than 1 meter.
  4. 根据权利要求1-3任一项所述的带有侧吹熔池段的闪速炉,其特征在于:所述熔池(2)的数目为1-4个。A flash furnace with a side blow pool section according to any one of claims 1 to 3, characterized in that the number of the molten pools (2) is 1-4.
  5. 根据权利要求4所述的带有侧吹熔池段的闪速炉,其特征在于:所述侧吹布置包括对称设置在所述侧吹熔池段的侧吹孔及设置在侧吹孔内的侧吹喷管(4)。The flash furnace with a side blow pool section according to claim 4, wherein the side blowing arrangement comprises a side blowing hole symmetrically disposed in the side blowing pool section and disposed in the side blowing hole Side blow nozzle (4).
  6. 根据权利要求1所述的带有侧吹熔池段的闪速炉,其特征在于:所述侧吹布置所在位置与所述侧吹熔池段中熔渣层对应。The flash furnace with a side blowing pool section according to claim 1, wherein the side blowing arrangement is located at a position corresponding to the slag layer in the side blowing pool section.
  7. 根据权利要求1所述的带有侧吹熔池段的闪速炉,其特征在于:所述熔池(2)上或上升烟道(3)侧壁上设有风口。The flash furnace with a side blown pool section according to claim 1, characterized in that a tuyeres are arranged on the molten pool (2) or on the side walls of the ascending flue (3).
  8. 根据权利要求1所述的带有侧吹熔池段的闪速炉,其特征在于:其特征在于:所述给料装置为喷嘴或喷嘴、烧嘴或烧嘴与喷嘴、喷枪的结合。The flash furnace with a side blow pool section according to claim 1, characterized in that the feeding device is a combination of a nozzle or a nozzle, a burner or a burner and a nozzle, and a spray gun.
  9. 根据权利要求1所述的带有侧吹熔池段的闪速炉,其特征在于:所述上升烟道(3)设置在靠近所述侧吹熔池段入口处的熔池(2)上部。A flash furnace with a side blow pool section according to claim 1, wherein said ascending flue (3) is disposed at an upper portion of the molten pool (2) near the inlet of said side blown pool section .
  10. 根据权利要求1所述的带有侧吹熔池段的闪速炉,其特征在于:所述反应塔(1)上连接有气体输运管道。 The flash furnace with a side blow pool section according to claim 1, characterized in that a gas transport pipe is connected to the reaction tower (1).
PCT/CN2017/074025 2016-04-28 2017-02-19 Flash furnace having side-blown molten pool sections WO2017185857A1 (en)

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CN105716423B (en) * 2016-04-28 2017-12-26 天津闪速炼铁技术有限公司 A kind of Flash Smelting Furnace with side-blowing bath section
CN110629054B (en) * 2019-10-30 2024-03-22 中国恩菲工程技术有限公司 Preparation device of manganese-rich slag
CN113074558A (en) * 2020-01-03 2021-07-06 江西华赣瑞林稀贵金属科技有限公司 Side-blown smelting furnace
CN113913578B (en) * 2021-08-16 2022-08-23 北京科技大学 Method for increasing temperature of molten iron in molten pool by using high-temperature exhaust flue gas
CN114053970B (en) * 2021-11-22 2023-09-26 天津闪速炼铁技术有限公司 Methane cracking furnace

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