WO2017177726A1 - Solar cell module and method for manufacturing same, assembly, and system - Google Patents

Solar cell module and method for manufacturing same, assembly, and system Download PDF

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Publication number
WO2017177726A1
WO2017177726A1 PCT/CN2017/000123 CN2017000123W WO2017177726A1 WO 2017177726 A1 WO2017177726 A1 WO 2017177726A1 CN 2017000123 W CN2017000123 W CN 2017000123W WO 2017177726 A1 WO2017177726 A1 WO 2017177726A1
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WIPO (PCT)
Prior art keywords
solar cell
cell module
metal conductive
front surface
type solar
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PCT/CN2017/000123
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French (fr)
Chinese (zh)
Inventor
林建伟
季根华
刘志锋
孙玉海
张育政
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泰州中来光电科技有限公司
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Priority to JP2019600014U priority Critical patent/JP3220955U/en
Publication of WO2017177726A1 publication Critical patent/WO2017177726A1/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0224Electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/05Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0224Electrodes
    • H01L31/022408Electrodes for devices characterised by at least one potential jump barrier or surface barrier
    • H01L31/022425Electrodes for devices characterised by at least one potential jump barrier or surface barrier for solar cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/048Encapsulation of modules
    • H01L31/049Protective back sheets
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/547Monocrystalline silicon PV cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Definitions

  • the present invention relates to the field of solar cell technologies, and in particular, to a solar cell module, a preparation method thereof, a component, and a system.
  • a solar cell is a semiconductor device that converts solar energy into electrical energy.
  • metallization is a key step in the production process of solar cells, and photogenerated carriers must be efficiently collected by the conductive electrodes formed by metallization.
  • the most common metallization method for mass production of solar cells is the screen printing metal paste method, which is formed by printing silver paste or aluminum-doped silver paste through high-temperature sintering process to form functions such as electrical contact, electrical conduction, and solder interconnection. Metalization.
  • the front surface of the solar cell is generally printed with silver paste or aluminum-doped silver paste, but the price of silver paste or aluminum-doped silver paste is generally expensive, resulting in silver-containing paste in the solar cell.
  • the proportion of manufacturing costs remains high. Therefore, it is a key task to reduce the production cost of solar cells by finding a front metallization method that can reduce the amount of silver-containing slurry used while satisfying ohmic contact.
  • a large-area back aluminum electrode is provided on the back surface of a conventional P-type solar cell, but in order to meet the solderability requirements, a silver-containing back main gate electrode must be disposed therein, and the cost of the silver-containing paste is much higher than that of the aluminum paste. . If the back of the battery does not need to be soldered, the silver-backed main gate electrode can be eliminated, and the all-aluminum back electrode can be used, which not only reduces the cost but also increases the open circuit voltage of the battery.
  • a single-cell solar cell cannot be directly used as an energy source, and a plurality of single-cell batteries must be connected in series and tightly sealed to form a component to stably output electric energy.
  • the method of connecting the cells in series is to use a solder ribbon to solder the electrodes on the front and back sides of the adjacent cells, and performing two soldering operations on the cell not only reduces the yield but also causes a high fragmentation rate.
  • the purpose of the present invention is to provide a solar cell module and a system thereof for the deficiencies of the prior art.
  • the method and the component and the system, the solar cell module of the invention can significantly reduce the use amount of the silver-containing slurry, reduce the production cost of the solar cell, increase the open circuit voltage of the solar cell, and simultaneously, in the process of connecting the cell sheets in series,
  • the positive and negative electrodes of the cell have no soldering operation, which not only simplifies the production operation, increases the yield, but also reduces the fragmentation rate.
  • a solar cell module comprising a solar cell module and a back plate, the metal plate is embedded in the back plate, and the solar cell module comprises a P-type solar cell substrate and an N-type solar cell substrate alternately arranged, and the P-type solar cell substrate is in front of the substrate.
  • the negative electrode of the surface is connected to the positive electrode of the front surface of the N-type solar cell substrate; the solar cell module is disposed on the metal conductive plate.
  • the metal conductive plate is an aluminum plate or a copper plate.
  • the interval between the P-type solar cell substrate and the N-type solar cell substrate is no more than 5 mm.
  • the positioning device is arranged on the back plate.
  • the N-type solar cell substrate includes a front surface positive electrode, a front surface passivation anti-reflection film, a p+ doped region, an N-type crystalline silicon substrate, an n+ doped region, a back surface passivation film, and a back surface, in order from top to bottom.
  • the negative electrode; the P-type solar cell substrate includes a front surface negative electrode, a front surface passivation anti-reflection film, an n+ doped region, a P-type crystalline silicon substrate, and a back surface all-aluminum back from top to bottom.
  • the negative electrode of the front surface of the P-type solar cell substrate and the positive electrode of the front surface of the N-type solar cell substrate are connected by a wire
  • the negative electrode of the front surface of the P-type solar cell substrate comprises a segmented sub-gate and is disposed at a thermally conductive layer on the segmented sub-gate, the segmented sub-gate electrically connected to a doped region of a front surface of the P-type solar cell substrate;
  • the wire is electrically connected to the heat-sensitive conductive layer;
  • the positive electrode of the front surface of the solar cell substrate includes a segmented sub-gate and a heat-sensitive conductive layer disposed on the segmented sub-gate, the segmented sub-gate electrically connected to the doped region of the front surface of the N-type solar cell substrate;
  • a wire is electrically connected to the heat sensitive conductive layer.
  • the wire is provided with 60-120 wires, and the wire is tin-coated copper wire, tin-coated aluminum wire or tin-coated steel wire.
  • the wire has a diameter of 40-80 microns.
  • the solar cell module includes at least two solar cell modules and a first metal conductive plate, a second metal conductive plate, a third metal conductive plate, and a fourth metal conductive plate disposed in sequence on the back plate, first The metal conductive plate and the second metal conductive plate are insulated from each other, the third metal conductive plate and the fourth metal conductive plate are insulated from each other, and the second metal conductive plate and the third metal conductive plate are electrically connected to each other; the solar battery module
  • the utility model comprises a P-type solar cell substrate and an N-type solar cell substrate, wherein the negative electrode of the front surface of the P-type solar cell substrate and the positive electrode of the front surface of the N-type solar cell substrate are connected by a wire; wherein the front surface of one of the solar cell modules is upward
  • the first metal conductive plate and the second metal conductive plate are disposed, and the front surface of the other solar cell module is placed upward on the third metal conductive plate and the fourth metal conductive plate.
  • the invention also provides a preparation method of a solar cell module, comprising the following steps:
  • the wire connects the front surface negative electrode of the P-type solar cell substrate and the positive electrode of the front surface of the N-type solar cell substrate through the heat-sensitive conductive layer on the surface of the cell sheet.
  • the temperature of the heat treatment is 183 to 250 °C.
  • the invention also provides a solar cell module comprising a front layer material, a packaging material and a solar cell module which are sequentially connected from top to bottom, and the solar cell module is the above-mentioned solar cell module.
  • the present invention also provides a solar cell system comprising more than one solar cell module, the solar cell module being a solar cell module as described above.
  • Each battery module is composed of a P-type solar cell and an N-type solar cell, wherein a negative electrode of the P-type solar cell and a positive electrode of the N-type solar cell pass Wire connection.
  • the use of wire has the following two advantages: 1) no need to use the ribbon connection, saving the cost of materials and equipment; 2) the wire can replace the silver main grid and the secondary grid used in the prior art, which reduces the front shading loss and reduces the
  • the use cost of the silver-containing slurry can save about 50% of the silver-containing slurry consumption compared to the existing front metallization process.
  • the P-type solar cell replaces the existing silver back electrode and the back aluminum electrode structure with an all-aluminum back electrode, which not only reduces the use cost of the silver-containing paste but also increases the open circuit voltage of the battery.
  • the existing backplane is replaced by a backplane embedded with a metal conductive plate, and the battery module is placed on the metal conductive plate, and the metal conductive plates of the adjacent battery modules are connected to each other to complete the series connection between the battery modules. Repeat this step to get the solar cell module.
  • the positive and negative electrodes of the battery sheet are not welded, which not only simplifies the production operation, improves the production efficiency, but also reduces the fragmentation rate.
  • FIG. 1 is a schematic front view of a battery module in a solar cell module according to an embodiment of the invention.
  • FIG. 2 is a schematic cross-sectional view of a battery module in a solar cell module according to an embodiment of the present invention.
  • FIG 3 is a partial schematic view of a back plate embedded with a metal conductive plate in a solar cell module according to an embodiment of the invention.
  • FIG. 4 is a partial schematic view of a solar cell module according to an embodiment of the invention.
  • FIG. 5 is a partial cross-sectional view showing a solar cell module according to an embodiment of the present invention.
  • FIG. 6 is a schematic diagram of a regularly arranged non-continuous dot-shaped segmented sub-gate in a solar cell module according to an embodiment of the invention.
  • FIG. 7 is a schematic diagram of a non-continuous dot-shaped segmented sub-gate arranged in a misaligned manner in a solar cell module according to an embodiment of the present invention.
  • FIG. 8 is a schematic diagram of a laterally arranged non-continuous line segmented sub-gate in a solar cell module according to an embodiment of the invention.
  • FIG. 9 is a schematic diagram of a non-continuous line segmentation pair arranged vertically in a solar cell module according to an embodiment of the present invention. Schematic diagram of the grid.
  • N-type solar cell substrate 2. P-type solar cell substrate; 3. Metal wire; 31, N-segment sub-gate; 32, P-segment sub-gate; 33, heat-sensitive conductive layer; 41, first metal conductive a plate; 42, a second metal conductive plate; 43, a third metal conductive plate; 44, a fourth metal conductive plate; 5, a back plate.
  • the solar cell module in this embodiment refers to a back sheet including a metal conductive plate embedded therein and a solar cell sheet connected thereto.
  • a solar cell module of the present embodiment includes a solar cell module and a back plate 5, and a metal conductive plate is embedded on the back plate 5, and the metal conductive plate may be an aluminum plate or a copper plate.
  • the solar cell module includes a P-type solar cell substrate 2 and an N-type solar cell substrate 1 which are alternately arranged, and a negative electrode of a front surface of the P-type solar cell substrate 2 is connected with a positive electrode of a front surface of the N-type solar cell substrate 1; Set on a metal conductive plate.
  • the back plate 5 embedded with the metal conductive plate is provided with a positioning device for placing the battery module, so as to facilitate the installation of the positioning battery module.
  • the interval between the P-type solar cell substrate 2 and the N-type solar cell substrate 1 is not more than 5 mm.
  • a back plate embedded with a metal conductive plate is used to replace the existing back plate, and the battery module is placed on the metal conductive plate, and the metal conductive plates of the adjacent battery modules are connected to each other to complete the battery module. In tandem, repeat this step to get the solar cell module.
  • the positive and negative electrodes of the cell have no soldering operation, which not only simplifies the production operation, but also improves the production efficiency and reduces the fragmentation rate.
  • the negative electrode on the front surface of the P-type solar cell substrate 2 and the positive electrode on the front surface of the N-type solar cell substrate 1 are connected by a wire 3, and the negative electrode on the front surface of the P-type solar cell substrate 2 includes a P-segmented sub-gate 32 and a thermally conductive layer 33 disposed on the P-segmented sub-gate 32, the P-segmented sub-gate 32 being electrically connected to the doped region of the front surface of the P-type solar cell substrate 2; the wire 3 and the heat The sensitive conductive layer 33 is electrically connected; the positive electrode of the front surface of the N-type solar cell substrate includes an N-segment sub-gate 31 and a heat-sensitive conductive layer 33 disposed on the N-segment sub-gate 31, and the N-segment sub-gate 31 and the N-type Solar power The doped regions of the front surface of the cell substrate are electrically connected; the wires 3 are electrically connected to the heat-sensitive
  • the heat-sensitive conductive layer 33 is a solder paste conductive layer
  • the metal wire 3 is a metal wire coated with a heat-sensitive conductive material
  • the wire coated with the heat-sensitive conductive material may be selected from a tin-coated copper wire, a silver-coated copper wire, or a tin-coated aluminum wire.
  • the solder paste containing any one of tin, tin-lead alloy, tin-bismuth alloy or tin-lead-silver alloy.
  • a total of 60-120 wires 3 are provided, and the wire 3 has a diameter of 40-80 ⁇ m.
  • the use of wire has the following two advantages: 1) no need to use the ribbon connection, saving the cost of materials and equipment; 2) the wire can replace the silver main grid and the secondary grid used in the prior art, which reduces the front shading loss and reduces the
  • the use cost of the silver-containing slurry can save about 50% of the silver-containing slurry consumption compared to the existing front metallization process.
  • any two adjacent solar cell substrates one of which is a P-type solar cell substrate 2, the other is an N-type solar cell substrate 1, and the front surface of the N-type solar cell substrate 1 is a positive electrode
  • the back surface is a negative electrode; the front surface of the P-type solar cell substrate 2 is a negative electrode, and the back surface is a positive electrode; the positive electrode of the N-type solar cell substrate 1 and the negative electrode of the P-type solar cell substrate 2 are connected by a wire 3 .
  • the solar cell module includes at least two solar cell modules and a first metal conductive plate 41, a second metal conductive plate 42, and a third metal conductive plate disposed in sequence on the back plate 5.
  • 43 and the fourth metal conductive plate 44, the first metal conductive plate 41 and the second metal conductive plate 42 are insulated from each other, and the third metal conductive plate 43 and the fourth metal conductive plate 44 are insulated from each other, and the second metal conductive plate is insulated from each other.
  • the solar cell module comprises a P-type solar cell substrate 2 and an N-type solar cell substrate 1, a negative electrode of the front surface of the P-type solar cell substrate 2, and an N-type solar cell
  • the positive electrode of the front surface of the substrate 1 is connected by the wire 3; one of the front surfaces of the solar cell module is placed upward on the first metal conductive plate 41 and the second metal conductive plate 42, and the front surface of the other solar cell module is placed upward.
  • the three metal conductive plates 43 and the fourth metal conductive plate 44 are on.
  • the N-type solar cell substrate 1 includes, in order from top to bottom, a front surface passivation anti-reflection film, a p+ doped region, an N-type crystalline silicon substrate, an n+ doped region, a back surface passivation film, and a back surface silver.
  • the P-type solar cell substrate 2 includes, in order from top to bottom, a front surface passivation anti-reflection film, an n+ doped region, a P-type crystalline silicon substrate, and a back surface all-aluminum back electrode.
  • P-type solar cells use all aluminum
  • the back electrode replaces the existing silver back electrode and the back aluminum electrode structure, which not only reduces the use cost of the silver-containing paste but also increases the open circuit voltage of the battery.
  • a method for preparing a solar cell module of the embodiment includes the following steps:
  • an N-type solar cell substrate 1 and a P-type solar cell substrate 2 are prepared.
  • the N-type solar cell substrate 1 and the P-type solar cell substrate 2 may be a whole piece or a non-whole piece.
  • the N-type solar cell substrate 1 includes, in order from top to bottom, a front surface passivation anti-reflection film, a p+ doped region, an N-type crystalline silicon substrate, an n+ doped region, a back surface passivation film, and a back surface silver electrode.
  • the P-type solar cell substrate 2 includes a front surface passivation anti-reflection film, an n+ doped region, a P-type crystalline silicon substrate and a back surface aluminum electrode in order from top to bottom, and the back surface aluminum electrode covers the entire back surface (all-aluminum back electrode) ).
  • Both the back silver electrode of the N-type solar cell substrate 1 and the back aluminum electrode of the P-type solar cell substrate 2 were printed and dried, and no sintering treatment was performed. Then, the N-segment sub-gate 31 is printed on the front surface of the N-type solar cell substrate 1 using an aluminum-doped silver paste, and the P-segmented sub-gate 32 is printed on the front surface of the P-type solar cell substrate 2 using a silver paste.
  • the shape of the N-segment sub-gate 31 and the P-segment sub-gate 32 in this embodiment may be discontinuous dots or discontinuous lines.
  • the discontinuous dots in the adjacent segmented sub-gates may be a regular array, or as shown in FIG. 7, the discontinuous dots in the adjacent segmented sub-gates are misaligned.
  • the discontinuous lines in adjacent segmented sub-gates can be horizontally regular arrays.
  • the discontinuous lines in the adjacent segmented sub-gates are longitudinally regular arrays; the discontinuous lines in adjacent segmented sub-gates may also be misaligned.
  • the temperature-sensitive conductive layer 33 is printed on the N-segment sub-gate 31 and the P-segment sub-gate 32.
  • the heat conductive layer 33 is a solder paste.
  • the solder paste contains any one of tin, tin-lead alloy, tin-bismuth alloy or tin-lead-silver alloy.
  • the wire 3 is any one of a tin-clad copper wire, a tin-clad aluminum wire, or a tin-clad steel wire.
  • the wires 3 are parallel to each other, and a total of 60-120 strips are provided, and the cross section is circular, and the diameter thereof is 40-80 ⁇ m.
  • the N-type solar cell substrate 1 and the P-type solar cell substrate 2 connected by the wire 3 are heat-treated.
  • the heat treatment is infrared heating, and the peak temperature of the reflux is 183-250 degrees Celsius.
  • an ohmic contact is formed between the p+ doped region of the front surface of the N-type solar cell substrate 1, the N-segment sub-gate 31, the heat-sensitive conductive layer 33, and the wire 3, and the front surface of the P-type solar cell substrate 2
  • An ohmic contact is formed between the n+ doped region, the P segmented sub-gate 32, the thermistive conductive layer 33, and the wire 3, that is, the fabrication of the battery module of the present invention is completed.
  • the completed battery module is shown in Figure 1, and its cross-sectional view is shown in Figure 2.
  • the first metal conductive plate 41, the second metal conductive plate 42, the third metal conductive plate 43, and the fourth metal conductive plate 44 are sequentially disposed on the back plate 5.
  • the first metal conductive plate 41 and the second metal conductive plate 42 are insulated from each other, and the third metal conductive plate 43 and the fourth metal conductive plate 44 are insulated from each other, and the second metal conductive plate 42 and the third metal conductive plate are insulated from each other.
  • 43 is conductive to each other.
  • the front surface of the first battery module is placed upward on the first metal conductive plate 41 and the second metal conductive plate 42, and the front surface of the second battery module is placed upward on the third metal conductive plate 43 and the fourth metal conductive plate 44. Upper (as shown in Figures 4 and 5). In this way, the interconnection between the two battery modules is realized, and the solar battery module in which a plurality of battery modules are connected in series is obtained by repeating this step.
  • the backplane embedded with the metal conductive plate and the battery module connected thereto form the solar battery module described in this embodiment.
  • the embodiment further provides a solar cell module, which comprises a front layer material, a packaging material and a solar cell module which are sequentially connected from top to bottom, and the solar cell module is the above-mentioned solar cell module.
  • the structure and working principle of the solar cell module of the present embodiment use techniques well known in the art, and the improvement of the solar cell module provided by the present invention relates only to the above-mentioned solar cell module, and no other parts are modified. Therefore, this specification only details the solar cell module and its preparation method. Other components and working principles of the solar cell module will not be described herein.
  • the solar cell module of the present invention can be realized by those skilled in the art based on the contents described in the present specification.
  • the embodiment further provides a solar cell system comprising more than one solar cell module connected in series, and the solar cell module is a solar cell module as described above.
  • the structure and working principle of the solar cell system of the present embodiment use techniques well known in the art, and the solar cell system provided by the present invention The improvement is only related to the above solar cell module, and no other parts are modified. Therefore, this specification only details the solar cell module and its preparation method. Other components and working principles of the solar cell system will not be described here.
  • the solar cell system of the present invention can be realized by those skilled in the art based on the contents described in the present specification.

Abstract

A solar cell module and a method for manufacturing same, an assembly, and a system. The solar cell module comprises solar cell pieces and a back plate (5); metal conductive plates (41, 42, 43, 44) are embedded on the back plate; the solar cell pieces comprise P type solar cell substrates (2) and N type solar cell substrates (1) which are alternately arranged; a negative electrode on the front surface of each P type solar cell substrate is connected to a positive electrode on the front surface of each N type solar cell substrate by means of a metal wire (3); the solar cell pieces are disposed on the metal conductive plates. Also disclosed are a method for manufacturing the solar cell module, a solar cell assembly comprising the solar cell module, and a solar cell system. According to the solar cell module, solder strips are not needed for connection, such that material and device costs are reduced; silver busbars and fingers used in the prior art can be replaced with metal wires, such that shading losses on the front surfaces are decreased, costs of using silver containing paste are reduced, and the consumption of silver containing paste may be reduced by about 50%. No welding operation is used for the positive electrodes and negative electrodes of the cell pieces, such that the production operation is simplified, the production efficiency is improved, and the breakage rate is reduced.

Description

一种太阳能电池模组及其制备方法和组件、系统Solar battery module and preparation method, component and system thereof 技术领域Technical field
本发明涉及太阳能电池技术领域,具体涉及一种太阳能电池模组及其制备方法和组件、系统。The present invention relates to the field of solar cell technologies, and in particular, to a solar cell module, a preparation method thereof, a component, and a system.
背景技术Background technique
太阳能电池是一种能将太阳能转化为电能的半导体器件。其中金属化是太阳能电池生产工序中的一个关键步骤,光生载流子必须通过金属化形成的导电电极才能获得有效收集。目前,量产太阳能电池中最常用的金属化方法是丝网印刷金属浆料法,通过印刷银浆或掺铝银浆,经过高温烧结过程,形成具备电学接触、电学传导、焊接互联等功能的金属化。为了形成良好的欧姆接触以及兼顾可焊性,太阳能电池的前表面一般印刷银浆或掺铝银浆,但银浆或掺铝银浆的价格一般都较为昂贵,导致含银浆料在太阳能电池制造成本中的占比居高不下。因而寻找一种可以降低含银浆料使用量、同时又能满足欧姆接触的正面金属化方法成为减少太阳能电池生产成本的一个关键工作。A solar cell is a semiconductor device that converts solar energy into electrical energy. Among them, metallization is a key step in the production process of solar cells, and photogenerated carriers must be efficiently collected by the conductive electrodes formed by metallization. At present, the most common metallization method for mass production of solar cells is the screen printing metal paste method, which is formed by printing silver paste or aluminum-doped silver paste through high-temperature sintering process to form functions such as electrical contact, electrical conduction, and solder interconnection. Metalization. In order to form good ohmic contact and balance weldability, the front surface of the solar cell is generally printed with silver paste or aluminum-doped silver paste, but the price of silver paste or aluminum-doped silver paste is generally expensive, resulting in silver-containing paste in the solar cell. The proportion of manufacturing costs remains high. Therefore, it is a key task to reduce the production cost of solar cells by finding a front metallization method that can reduce the amount of silver-containing slurry used while satisfying ohmic contact.
另外,常规P型太阳能电池的背表面会设置大面积的背面铝电极,但为了满足可焊性的要求,必须在其中设置含银背面主栅电极,含银浆料的成本远高于铝浆。如果电池背面无需焊接,则可以取消含银背面主栅电极,使用全铝背电极,不仅会降低成本还能提高电池的开路电压。In addition, a large-area back aluminum electrode is provided on the back surface of a conventional P-type solar cell, but in order to meet the solderability requirements, a silver-containing back main gate electrode must be disposed therein, and the cost of the silver-containing paste is much higher than that of the aluminum paste. . If the back of the battery does not need to be soldered, the silver-backed main gate electrode can be eliminated, and the all-aluminum back electrode can be used, which not only reduces the cost but also increases the open circuit voltage of the battery.
单体太阳能电池并不能作为能源直接使用,必须将若干单体电池串并联连接和严密封装成组件后才能稳定输出电能。目前串接电池片的方法是使用焊带焊接连接相邻电池片正面和背面的电极,在电池片上进行两次焊接操作不仅降低了产量还会带来较高的碎片率。A single-cell solar cell cannot be directly used as an energy source, and a plurality of single-cell batteries must be connected in series and tightly sealed to form a component to stably output electric energy. At present, the method of connecting the cells in series is to use a solder ribbon to solder the electrodes on the front and back sides of the adjacent cells, and performing two soldering operations on the cell not only reduces the yield but also causes a high fragmentation rate.
发明内容Summary of the invention
本发明的目的在于针对现有技术的不足,提供一种太阳能电池模组及其制 备方法和组件、系统,本发明的太阳能电池模组可以显著地降低含银浆料的使用量,降低太阳能电池的生产成本,提高太阳能电池的开路电压,同时在串接电池片的过程中,电池片的正极和负极均没有焊接操作,不仅简化了生产操作、提高了产量,还可降低碎片率。The purpose of the present invention is to provide a solar cell module and a system thereof for the deficiencies of the prior art. The method and the component and the system, the solar cell module of the invention can significantly reduce the use amount of the silver-containing slurry, reduce the production cost of the solar cell, increase the open circuit voltage of the solar cell, and simultaneously, in the process of connecting the cell sheets in series, The positive and negative electrodes of the cell have no soldering operation, which not only simplifies the production operation, increases the yield, but also reduces the fragmentation rate.
本发明提供的一种太阳能电池模组,其技术方案是:The solar cell module provided by the invention has the technical solutions of:
一种太阳能电池模组,包括太阳能电池模块和背板,背板上嵌有金属导电板,太阳能电池模块包括互相交替排列的P型太阳能电池基体和N型太阳能电池基体,P型太阳能电池基体前表面的负电极与N型太阳能电池基体前表面的正电极连接;太阳能电池模块设置在金属导电板上。A solar cell module comprising a solar cell module and a back plate, the metal plate is embedded in the back plate, and the solar cell module comprises a P-type solar cell substrate and an N-type solar cell substrate alternately arranged, and the P-type solar cell substrate is in front of the substrate. The negative electrode of the surface is connected to the positive electrode of the front surface of the N-type solar cell substrate; the solar cell module is disposed on the metal conductive plate.
其中,金属导电板是铝板或者铜板。Wherein, the metal conductive plate is an aluminum plate or a copper plate.
其中,P型太阳能电池基体和N型太阳能电池基体之间的间隔为不大于5mm。Wherein, the interval between the P-type solar cell substrate and the N-type solar cell substrate is no more than 5 mm.
其中,背板上设置有定位装置。Wherein, the positioning device is arranged on the back plate.
其中,N型太阳能电池基体从上至下依次包括前表面正电极、前表面钝化减反膜、p+掺杂区域、N型晶体硅基体、n+掺杂区域、背表面钝化膜和背表面负电极;P型太阳能电池基体从上至下依次包括前表面负电极、前表面钝化减反膜、n+掺杂区域、P型晶体硅基体和背表面全铝背The N-type solar cell substrate includes a front surface positive electrode, a front surface passivation anti-reflection film, a p+ doped region, an N-type crystalline silicon substrate, an n+ doped region, a back surface passivation film, and a back surface, in order from top to bottom. The negative electrode; the P-type solar cell substrate includes a front surface negative electrode, a front surface passivation anti-reflection film, an n+ doped region, a P-type crystalline silicon substrate, and a back surface all-aluminum back from top to bottom.
电极。electrode.
其中,P型太阳能电池基体前表面的负电极与所述N型太阳能电池基体前表面的正电极通过金属丝连接,所述P型太阳能电池基体前表面的负电极包括分段副栅和设置在分段副栅上的热敏导电层,所述分段副栅与P型太阳能电池基体前表面的掺杂区域电连接;所述金属丝与所述热敏导电层电连接;所述N型太阳能电池基体前表面的正电极包括分段副栅和设置在分段副栅上的热敏导电层,所述分段副栅与N型太阳能电池基体前表面的掺杂区域电连接;所述金属丝与所述热敏导电层电连接。Wherein the negative electrode of the front surface of the P-type solar cell substrate and the positive electrode of the front surface of the N-type solar cell substrate are connected by a wire, and the negative electrode of the front surface of the P-type solar cell substrate comprises a segmented sub-gate and is disposed at a thermally conductive layer on the segmented sub-gate, the segmented sub-gate electrically connected to a doped region of a front surface of the P-type solar cell substrate; the wire is electrically connected to the heat-sensitive conductive layer; The positive electrode of the front surface of the solar cell substrate includes a segmented sub-gate and a heat-sensitive conductive layer disposed on the segmented sub-gate, the segmented sub-gate electrically connected to the doped region of the front surface of the N-type solar cell substrate; A wire is electrically connected to the heat sensitive conductive layer.
其中,金属丝共设置60-120条,金属丝为锡包铜丝、锡包铝丝或锡包钢丝 中的任一种,所述金属丝的直径为40-80微米。Among them, the wire is provided with 60-120 wires, and the wire is tin-coated copper wire, tin-coated aluminum wire or tin-coated steel wire. In any of the above, the wire has a diameter of 40-80 microns.
其中,所述太阳能电池模组包括至少两个太阳能电池模块和所述背板上依次设置的第一金属导电板、第二金属导电板、第三金属导电板和第四金属导电板,第一金属导电板与第二金属导电板之间互相绝缘,第三金属导电板与第四金属导电板之间互相绝缘,第二金属导电板与第三金属导电板之间互相电连接;太阳能电池模块包括一块P型太阳能电池基体和一块N型太阳能电池基体,P型太阳能电池基体前表面的负电极和N型太阳能电池基体前表面的正电极通过金属丝连接;其中的一个太阳能电池模块前表面向上置于第一金属导电板和第二金属导电板上,另外一个太阳能电池模块前表面向上置于第三金属导电板和第四金属导电板上。The solar cell module includes at least two solar cell modules and a first metal conductive plate, a second metal conductive plate, a third metal conductive plate, and a fourth metal conductive plate disposed in sequence on the back plate, first The metal conductive plate and the second metal conductive plate are insulated from each other, the third metal conductive plate and the fourth metal conductive plate are insulated from each other, and the second metal conductive plate and the third metal conductive plate are electrically connected to each other; the solar battery module The utility model comprises a P-type solar cell substrate and an N-type solar cell substrate, wherein the negative electrode of the front surface of the P-type solar cell substrate and the positive electrode of the front surface of the N-type solar cell substrate are connected by a wire; wherein the front surface of one of the solar cell modules is upward The first metal conductive plate and the second metal conductive plate are disposed, and the front surface of the other solar cell module is placed upward on the third metal conductive plate and the fourth metal conductive plate.
本发明还提供了一种太阳能电池模组的制备方法,包括以下步骤:The invention also provides a preparation method of a solar cell module, comprising the following steps:
(1)、将N型太阳能电池基体和P型太阳能电池基体并排放置,然后铺设金属丝,热处理后得到太阳能电池模块;(1) placing an N-type solar cell substrate and a P-type solar cell substrate side by side, then laying a wire, and obtaining a solar cell module after heat treatment;
(2)、选择嵌有金属导电板的背板,背板上嵌有多块金属导电板,根据太阳能电池模块的结构将多块金属导电板作绝缘或者电导通处理,然后将太阳能电池模块放置于嵌有金属导电板的背板上得到太阳能电池模组。(2) Selecting a back plate embedded with a metal conductive plate, a plurality of metal conductive plates embedded in the back plate, and insulating or electrically conducting the plurality of metal conductive plates according to the structure of the solar battery module, and then placing the solar battery module A solar cell module is obtained on a back plate in which a metal conductive plate is embedded.
其中,步骤(1)中,金属丝通过电池片表面的热敏导电层将P型太阳能电池基体前表面负电极与N型太阳能电池基体前表面的正电极相连接。Wherein, in the step (1), the wire connects the front surface negative electrode of the P-type solar cell substrate and the positive electrode of the front surface of the N-type solar cell substrate through the heat-sensitive conductive layer on the surface of the cell sheet.
其中,步骤(1)中,热处理的温度为183-250℃。Wherein, in the step (1), the temperature of the heat treatment is 183 to 250 °C.
本发明还提供了一种太阳能电池组件,包括由上至下依次连接的前层材料、封装材料、太阳能电池模组,太阳能电池模组是上述的一种太阳能电池模组。The invention also provides a solar cell module comprising a front layer material, a packaging material and a solar cell module which are sequentially connected from top to bottom, and the solar cell module is the above-mentioned solar cell module.
本发明还提供给了一种太阳能电池系统,包括一个以上太阳能电池组件,太阳能电池组件是上述的一种太阳能电池组件。The present invention also provides a solar cell system comprising more than one solar cell module, the solar cell module being a solar cell module as described above.
本发明的实施包括以下技术效果:Implementations of the invention include the following technical effects:
本发明的技术效果主要体现在:1、每个电池模块由P型太阳能电池和N型太阳能电池构成,其中P型太阳能电池的负极和N型太阳能电池的正极通过 金属丝连接。采用金属丝有如下两个优点:1)无需使用焊带连接,节约了材料设备成本;2)金属丝可代替现有技术使用的银主栅及副栅,既降低了正面遮光损失又减少了含银浆料的使用成本,相比现有的正面金属化工艺,本发明可以节约大概50%的含银浆料消耗量。同时,P型太阳能电池使用全铝背电极取代现有的银背电极和背面铝电极结构,不仅降低了含银浆料的使用成本还能提高电池的开路电压。2、使用嵌有金属导电板的背板取代现有背板,将电池模块置于该金属导电板上,相邻电池模块的金属导电板互相连接,即可完成电池模块之间的串接,重复这一步骤就可得到太阳能电池模组。使用本发明中的串接方法,电池片的正极和负极均没有焊接操作,不仅简化了生产操作,提高了生产效率,还可降低碎片率。The technical effects of the present invention are mainly embodied in: 1. Each battery module is composed of a P-type solar cell and an N-type solar cell, wherein a negative electrode of the P-type solar cell and a positive electrode of the N-type solar cell pass Wire connection. The use of wire has the following two advantages: 1) no need to use the ribbon connection, saving the cost of materials and equipment; 2) the wire can replace the silver main grid and the secondary grid used in the prior art, which reduces the front shading loss and reduces the The use cost of the silver-containing slurry can save about 50% of the silver-containing slurry consumption compared to the existing front metallization process. At the same time, the P-type solar cell replaces the existing silver back electrode and the back aluminum electrode structure with an all-aluminum back electrode, which not only reduces the use cost of the silver-containing paste but also increases the open circuit voltage of the battery. 2. The existing backplane is replaced by a backplane embedded with a metal conductive plate, and the battery module is placed on the metal conductive plate, and the metal conductive plates of the adjacent battery modules are connected to each other to complete the series connection between the battery modules. Repeat this step to get the solar cell module. By using the tandem method of the present invention, the positive and negative electrodes of the battery sheet are not welded, which not only simplifies the production operation, improves the production efficiency, but also reduces the fragmentation rate.
附图说明DRAWINGS
图1为本发明实施例的一种太阳能电池模组中的电池模块的前表面示意图。1 is a schematic front view of a battery module in a solar cell module according to an embodiment of the invention.
图2为本发明实施例的一种太阳能电池模组中的电池模块的截面示意图。2 is a schematic cross-sectional view of a battery module in a solar cell module according to an embodiment of the present invention.
图3为本发明实施例的一种太阳能电池模组中的嵌有金属导电板的背板的局部示意图。3 is a partial schematic view of a back plate embedded with a metal conductive plate in a solar cell module according to an embodiment of the invention.
图4为本发明实施例的一种太阳能电池模组的局部示意图。4 is a partial schematic view of a solar cell module according to an embodiment of the invention.
图5为本发明实施例的一种太阳能电池模组的局部截面示意图。FIG. 5 is a partial cross-sectional view showing a solar cell module according to an embodiment of the present invention.
图6为本发明实施例的一种太阳能电池模组中规则排列的非连续圆点状分段副栅的示意图。FIG. 6 is a schematic diagram of a regularly arranged non-continuous dot-shaped segmented sub-gate in a solar cell module according to an embodiment of the invention.
图7为本发明实施例的一种太阳能电池模组中错位排列的非连续圆点状分段副栅的示意图。FIG. 7 is a schematic diagram of a non-continuous dot-shaped segmented sub-gate arranged in a misaligned manner in a solar cell module according to an embodiment of the present invention.
图8为本发明实施例的一种太阳能电池模组中横向排列的非连续线条状分段副栅的示意图。FIG. 8 is a schematic diagram of a laterally arranged non-continuous line segmented sub-gate in a solar cell module according to an embodiment of the invention.
图9为本发明实施例的一种太阳能电池模组中竖向排列的非连续线条状分段副 栅的示意图。FIG. 9 is a schematic diagram of a non-continuous line segmentation pair arranged vertically in a solar cell module according to an embodiment of the present invention; Schematic diagram of the grid.
1、N型太阳能电池基体;2、P型太阳能电池基体;3、金属丝;31、N分段副栅;32、P分段副栅;33、热敏导电层;41、第一金属导电板;42、第二金属导电板;43、第三金属导电板;44、第四金属导电板;5、背板。1. N-type solar cell substrate; 2. P-type solar cell substrate; 3. Metal wire; 31, N-segment sub-gate; 32, P-segment sub-gate; 33, heat-sensitive conductive layer; 41, first metal conductive a plate; 42, a second metal conductive plate; 43, a third metal conductive plate; 44, a fourth metal conductive plate; 5, a back plate.
具体实施方式detailed description
下面将结合实施例以及附图对本发明加以详细说明,需要指出的是,所描述的实施例仅旨在便于对本发明的理解,而对其不起任何限定作用。The invention will be described in detail below with reference to the embodiments and the accompanying drawings, which are to be understood that the described embodiments are only intended to facilitate the understanding of the invention.
本实施例中的太阳能电池模组指的是包含嵌有金属导电板的背板及与之相连的太阳能电池片。The solar cell module in this embodiment refers to a back sheet including a metal conductive plate embedded therein and a solar cell sheet connected thereto.
参见图1至图5所示,本实施例的一种太阳能电池模组,包括太阳能电池模块和背板5,背板5上嵌有金属导电板,金属导电板可以是铝板或者铜板。太阳能电池模块包括相互交替排列的P型太阳能电池基体2和N型太阳能电池基体1,P型太阳能电池基体2前表面的负电极与N型太阳能电池基体1前表面的正电极连接;太阳能电池模块设置在金属导电板上。作为优选,嵌有金属导电板的背板5上设置有放置电池模块的定位装置,方便安装定位电池模块。P型太阳能电池基体2和N型太阳能电池基体1之间的间隔为不大于5mm。上述的太阳能电池模组,使用嵌有金属导电板的背板取代现有背板,将电池模块置于该金属导电板上,相邻电池模块的金属导电板互相连接,即可完成电池模块之间的串接,重复这一步骤就可得到太阳能电池模组。电池片的正极和负极均没有焊接操作,不仅简化了生产操作,提高了生产效率,还可降低碎片率。As shown in FIG. 1 to FIG. 5, a solar cell module of the present embodiment includes a solar cell module and a back plate 5, and a metal conductive plate is embedded on the back plate 5, and the metal conductive plate may be an aluminum plate or a copper plate. The solar cell module includes a P-type solar cell substrate 2 and an N-type solar cell substrate 1 which are alternately arranged, and a negative electrode of a front surface of the P-type solar cell substrate 2 is connected with a positive electrode of a front surface of the N-type solar cell substrate 1; Set on a metal conductive plate. Preferably, the back plate 5 embedded with the metal conductive plate is provided with a positioning device for placing the battery module, so as to facilitate the installation of the positioning battery module. The interval between the P-type solar cell substrate 2 and the N-type solar cell substrate 1 is not more than 5 mm. In the above solar cell module, a back plate embedded with a metal conductive plate is used to replace the existing back plate, and the battery module is placed on the metal conductive plate, and the metal conductive plates of the adjacent battery modules are connected to each other to complete the battery module. In tandem, repeat this step to get the solar cell module. The positive and negative electrodes of the cell have no soldering operation, which not only simplifies the production operation, but also improves the production efficiency and reduces the fragmentation rate.
参见图1和图5所示,P型太阳能电池基体2前表面的负电极与N型太阳能电池基体1前表面的正电极通过金属丝3连接,P型太阳能电池基体2前表面的负电极包括P分段副栅32和设置在P分段副栅32上的热敏导电层33,P分段副栅32与P型太阳能电池基体2前表面的掺杂区域电连接;金属丝3与热敏导电层33电连接;N型太阳能电池基体前表面的正电极包括N分段副栅31和设置在N分段副栅31上的热敏导电层33,N分段副栅31与N型太阳能电 池基体前表面的掺杂区域电连接;金属丝3与热敏导电层33电连接。热敏导电层33是锡膏导电层,金属丝3是镀有热敏导电材料的金属丝,镀有热敏导电材料的金属丝可以选择锡包铜丝、银包铜丝、锡包铝丝或锡包钢丝中的任一种,锡膏含有锡、锡铅合金、锡铋合金或锡铅银合金中的任一种。Referring to FIGS. 1 and 5, the negative electrode on the front surface of the P-type solar cell substrate 2 and the positive electrode on the front surface of the N-type solar cell substrate 1 are connected by a wire 3, and the negative electrode on the front surface of the P-type solar cell substrate 2 includes a P-segmented sub-gate 32 and a thermally conductive layer 33 disposed on the P-segmented sub-gate 32, the P-segmented sub-gate 32 being electrically connected to the doped region of the front surface of the P-type solar cell substrate 2; the wire 3 and the heat The sensitive conductive layer 33 is electrically connected; the positive electrode of the front surface of the N-type solar cell substrate includes an N-segment sub-gate 31 and a heat-sensitive conductive layer 33 disposed on the N-segment sub-gate 31, and the N-segment sub-gate 31 and the N-type Solar power The doped regions of the front surface of the cell substrate are electrically connected; the wires 3 are electrically connected to the heat-sensitive conductive layer 33. The heat-sensitive conductive layer 33 is a solder paste conductive layer, the metal wire 3 is a metal wire coated with a heat-sensitive conductive material, and the wire coated with the heat-sensitive conductive material may be selected from a tin-coated copper wire, a silver-coated copper wire, or a tin-coated aluminum wire. Or any one of tin-coated steel wires, the solder paste containing any one of tin, tin-lead alloy, tin-bismuth alloy or tin-lead-silver alloy.
本实施例的太阳能电池模块中,金属丝3共设置60-120条,金属丝3的直径为40-80微米。采用金属丝有如下两个优点:1)无需使用焊带连接,节约了材料设备成本;2)金属丝可代替现有技术使用的银主栅及副栅,既降低了正面遮光损失又减少了含银浆料的使用成本,相比现有的正面金属化工艺,本发明可以节约大概50%的含银浆料消耗量。本实施例的太阳能电池模块,任意相邻的两块太阳能电池基体,其中一块为P型太阳能电池基体2,另一块为N型太阳能电池基体1,N型太阳能电池基体1的前表面为正电极,背表面为负电极;P型太阳能电池基体2的前表面为负电极,背表面为正电极;N型太阳能电池基体1的正电极与P型太阳能电池基体2的负电极通过金属丝3连接。In the solar cell module of the present embodiment, a total of 60-120 wires 3 are provided, and the wire 3 has a diameter of 40-80 μm. The use of wire has the following two advantages: 1) no need to use the ribbon connection, saving the cost of materials and equipment; 2) the wire can replace the silver main grid and the secondary grid used in the prior art, which reduces the front shading loss and reduces the The use cost of the silver-containing slurry can save about 50% of the silver-containing slurry consumption compared to the existing front metallization process. The solar cell module of the present embodiment, any two adjacent solar cell substrates, one of which is a P-type solar cell substrate 2, the other is an N-type solar cell substrate 1, and the front surface of the N-type solar cell substrate 1 is a positive electrode The back surface is a negative electrode; the front surface of the P-type solar cell substrate 2 is a negative electrode, and the back surface is a positive electrode; the positive electrode of the N-type solar cell substrate 1 and the negative electrode of the P-type solar cell substrate 2 are connected by a wire 3 .
参见图4和图5所示,优选地,太阳能电池模组包括至少两个太阳能电池模块和背板5上依次设置的第一金属导电板41、第二金属导电板42、第三金属导电板43和第四金属导电板44,第一金属导电板41与第二金属导电板42之间互相绝缘,第三金属导电板43与第四金属导电板44之间互相绝缘,第二金属导电板42与第三金属导电板43之间互相电连接;太阳能电池模块包括一块P型太阳能电池基体2和一块N型太阳能电池基体1,P型太阳能电池基体2前表面的负电极和N型太阳能电池基体1前表面的正电极通过金属丝3连接;其中的一个太阳能电池模块前表面向上置于第一金属导电板41和第二金属导电板42上,另外一个太阳能电池模块前表面向上置于第三金属导电板43和第四金属导电板44上。本实施例中,N型太阳能电池基体1从上至下依次包括前表面钝化减反膜、p+掺杂区域、N型晶体硅基体、n+掺杂区域、背表面钝化膜和背表面银电极;P型太阳能电池基体2从上至下依次包括前表面钝化减反膜、n+掺杂区域、P型晶体硅基体和背表面全铝背电极。P型太阳能电池使用全铝 背电极取代现有的银背电极和背面铝电极结构,不仅降低了含银浆料的使用成本还能提高电池的开路电压。Referring to FIG. 4 and FIG. 5, preferably, the solar cell module includes at least two solar cell modules and a first metal conductive plate 41, a second metal conductive plate 42, and a third metal conductive plate disposed in sequence on the back plate 5. 43 and the fourth metal conductive plate 44, the first metal conductive plate 41 and the second metal conductive plate 42 are insulated from each other, and the third metal conductive plate 43 and the fourth metal conductive plate 44 are insulated from each other, and the second metal conductive plate is insulated from each other. 42 is electrically connected to the third metal conductive plate 43; the solar cell module comprises a P-type solar cell substrate 2 and an N-type solar cell substrate 1, a negative electrode of the front surface of the P-type solar cell substrate 2, and an N-type solar cell The positive electrode of the front surface of the substrate 1 is connected by the wire 3; one of the front surfaces of the solar cell module is placed upward on the first metal conductive plate 41 and the second metal conductive plate 42, and the front surface of the other solar cell module is placed upward. The three metal conductive plates 43 and the fourth metal conductive plate 44 are on. In this embodiment, the N-type solar cell substrate 1 includes, in order from top to bottom, a front surface passivation anti-reflection film, a p+ doped region, an N-type crystalline silicon substrate, an n+ doped region, a back surface passivation film, and a back surface silver. The P-type solar cell substrate 2 includes, in order from top to bottom, a front surface passivation anti-reflection film, an n+ doped region, a P-type crystalline silicon substrate, and a back surface all-aluminum back electrode. P-type solar cells use all aluminum The back electrode replaces the existing silver back electrode and the back aluminum electrode structure, which not only reduces the use cost of the silver-containing paste but also increases the open circuit voltage of the battery.
参见图1至图9所示,本实施例的太阳能电池模组的制备方法,包括以下步骤:Referring to FIG. 1 to FIG. 9 , a method for preparing a solar cell module of the embodiment includes the following steps:
(1)、制备太阳能电池模块。首先,制备N型太阳能电池基体1和P型太阳能电池基体2。所述N型太阳能电池基体1和P型太阳能电池基体2可以为整片,也可以为非整片。其中N型太阳能电池基体1从上至下依次包括前表面钝化减反膜、p+掺杂区域、N型晶体硅基体、n+掺杂区域、背表面钝化膜和背表面银电极。P型太阳能电池基体2从上至下依次包括前表面钝化减反膜、n+掺杂区域、P型晶体硅基体和背表面铝电极,背表面铝电极覆盖了整个背表面(全铝背电极)。N型太阳能电池基体1的背面银电极和P型太阳能电池基体2的背面铝电极均为印刷烘干,没有进行烧结处理。然后,在N型太阳能电池基体1的前表面使用掺铝银浆印刷N分段副栅31,在P型太阳能电池基体2的前表面使用银浆印刷P分段副栅32。本实施例中N分段副栅31及P分段副栅32的形状可以是非连续的圆点或者是非连续的线条。如图6所示,相邻分段副栅中的非连续的圆点可以是有规则的阵列,也可以如图7所示,相邻分段副栅中的非连续的圆点错位排列。如图8所示,相邻分段副栅中的非连续的线条可以是横向的有规则的阵列。如图9所示,相邻分段副栅中的非连续的线条是纵向的有规则的阵列;相邻分段副栅中的非连续的线条还可以错位排列。印刷完成后进行烧结,烧结峰值温度为850-950℃。烧结完成后,在N分段副栅31和P分段副栅32上印刷热敏导电层33。热敏导电层33是锡膏。锡膏含有锡、锡铅合金、锡铋合金或锡铅银合金中的任一种。然后,将N型太阳能电池基体1和P型太阳能电池基体2并排置于工作台上,在前表面的热敏导电层33上铺设金属丝3。金属丝3为锡包铜线、锡包铝线或锡包钢线中的任一种。金属丝3互相平行,共设置60-120条,截面为圆形,其直径为40-80微米。最后,对通过金属丝3相连接的N型太阳能电池基体1和P型太阳能电池基体2进行热处 理,本实施例中热处理为红外加热,回流峰值温度为183-250摄氏度。热处理后,N型太阳能电池基体1的前表面的p+掺杂区域、N分段副栅31、热敏导电层33和金属丝3之间形成欧姆接触,P型太阳能电池基体2的前表面的n+掺杂区域、P分段副栅32、热敏导电层33和金属丝3之间形成欧姆接触,,即完成本发明电池模块的制作。完成后的电池模块如图1所示,其截面图如图2所示。(1) Preparing a solar cell module. First, an N-type solar cell substrate 1 and a P-type solar cell substrate 2 are prepared. The N-type solar cell substrate 1 and the P-type solar cell substrate 2 may be a whole piece or a non-whole piece. The N-type solar cell substrate 1 includes, in order from top to bottom, a front surface passivation anti-reflection film, a p+ doped region, an N-type crystalline silicon substrate, an n+ doped region, a back surface passivation film, and a back surface silver electrode. The P-type solar cell substrate 2 includes a front surface passivation anti-reflection film, an n+ doped region, a P-type crystalline silicon substrate and a back surface aluminum electrode in order from top to bottom, and the back surface aluminum electrode covers the entire back surface (all-aluminum back electrode) ). Both the back silver electrode of the N-type solar cell substrate 1 and the back aluminum electrode of the P-type solar cell substrate 2 were printed and dried, and no sintering treatment was performed. Then, the N-segment sub-gate 31 is printed on the front surface of the N-type solar cell substrate 1 using an aluminum-doped silver paste, and the P-segmented sub-gate 32 is printed on the front surface of the P-type solar cell substrate 2 using a silver paste. The shape of the N-segment sub-gate 31 and the P-segment sub-gate 32 in this embodiment may be discontinuous dots or discontinuous lines. As shown in FIG. 6, the discontinuous dots in the adjacent segmented sub-gates may be a regular array, or as shown in FIG. 7, the discontinuous dots in the adjacent segmented sub-gates are misaligned. As shown in Figure 8, the discontinuous lines in adjacent segmented sub-gates can be horizontally regular arrays. As shown in FIG. 9, the discontinuous lines in the adjacent segmented sub-gates are longitudinally regular arrays; the discontinuous lines in adjacent segmented sub-gates may also be misaligned. Sintering is carried out after the printing is completed, and the sintering peak temperature is 850-950 °C. After the sintering is completed, the temperature-sensitive conductive layer 33 is printed on the N-segment sub-gate 31 and the P-segment sub-gate 32. The heat conductive layer 33 is a solder paste. The solder paste contains any one of tin, tin-lead alloy, tin-bismuth alloy or tin-lead-silver alloy. Then, the N-type solar cell substrate 1 and the P-type solar cell substrate 2 are placed side by side on a table, and the wire 3 is laid on the heat-sensitive conductive layer 33 on the front surface. The wire 3 is any one of a tin-clad copper wire, a tin-clad aluminum wire, or a tin-clad steel wire. The wires 3 are parallel to each other, and a total of 60-120 strips are provided, and the cross section is circular, and the diameter thereof is 40-80 μm. Finally, the N-type solar cell substrate 1 and the P-type solar cell substrate 2 connected by the wire 3 are heat-treated. In this embodiment, the heat treatment is infrared heating, and the peak temperature of the reflux is 183-250 degrees Celsius. After the heat treatment, an ohmic contact is formed between the p+ doped region of the front surface of the N-type solar cell substrate 1, the N-segment sub-gate 31, the heat-sensitive conductive layer 33, and the wire 3, and the front surface of the P-type solar cell substrate 2 An ohmic contact is formed between the n+ doped region, the P segmented sub-gate 32, the thermistive conductive layer 33, and the wire 3, that is, the fabrication of the battery module of the present invention is completed. The completed battery module is shown in Figure 1, and its cross-sectional view is shown in Figure 2.
(2)、选择嵌有金属导电板的背板5。如图3所示,背板5上依次设置有第一金属导电板41、第二金属导电板42、第三金属导电板43和第四金属导电板44。其中第一金属导电板41与第二金属导电板42之间互相绝缘,第三金属导电板43与第四金属导电板44之间互相绝缘,而第二金属导电板42与第三金属导电板43之间互相导通。将第一个电池模块前表面向上置于第一金属导电板41和第二金属导电板42上,将第二个电池模块前表面向上置于第三金属导电板43和第四金属导电板44上(如图4及图5所示)。这样就实现了两个电池模块之间的互连,重复这一步骤即得到多个电池模块串接的太阳能电池模组。嵌有金属导电板的背板及与之相连的电池模块共同组成了本实施例所述的太阳能电池模组。(2) Select the backing plate 5 in which the metal conductive plate is embedded. As shown in FIG. 3, the first metal conductive plate 41, the second metal conductive plate 42, the third metal conductive plate 43, and the fourth metal conductive plate 44 are sequentially disposed on the back plate 5. The first metal conductive plate 41 and the second metal conductive plate 42 are insulated from each other, and the third metal conductive plate 43 and the fourth metal conductive plate 44 are insulated from each other, and the second metal conductive plate 42 and the third metal conductive plate are insulated from each other. 43 is conductive to each other. The front surface of the first battery module is placed upward on the first metal conductive plate 41 and the second metal conductive plate 42, and the front surface of the second battery module is placed upward on the third metal conductive plate 43 and the fourth metal conductive plate 44. Upper (as shown in Figures 4 and 5). In this way, the interconnection between the two battery modules is realized, and the solar battery module in which a plurality of battery modules are connected in series is obtained by repeating this step. The backplane embedded with the metal conductive plate and the battery module connected thereto form the solar battery module described in this embodiment.
本实施例还提供了一种太阳能电池组件,包括由上至下依次连接的前层材料、封装材料、太阳能电池模组,太阳能电池模组是上述的一种太阳能电池模组。本实施例的太阳能电池组件的结构及工作原理使用本领域公知的技术,且本发明提供的太阳能电池组件的改进仅涉及上述的太阳能电池模组,不对其他部分进行改动。故本说明书仅对太阳能电池模组及其制备方法进行详述,对太阳能电池组件的其他部件及工作原理这里不再赘述。本领域技术人员在本说明书描述的内容基础上,即可实现本发明的太阳能电池组件。The embodiment further provides a solar cell module, which comprises a front layer material, a packaging material and a solar cell module which are sequentially connected from top to bottom, and the solar cell module is the above-mentioned solar cell module. The structure and working principle of the solar cell module of the present embodiment use techniques well known in the art, and the improvement of the solar cell module provided by the present invention relates only to the above-mentioned solar cell module, and no other parts are modified. Therefore, this specification only details the solar cell module and its preparation method. Other components and working principles of the solar cell module will not be described herein. The solar cell module of the present invention can be realized by those skilled in the art based on the contents described in the present specification.
本实施例还提供了一种太阳能电池系统,包括一个以上串联的太阳能电池组件,太阳能电池组件是上述的一种太阳能电池组件。本实施例的太阳能电池系统的结构及工作原理使用本领域公知的技术,且本发明提供的太阳能电池系 统的改进仅涉及上述的太阳能电池模组,不对其他部分进行改动。故本说明书仅对太阳能电池模组及其制备方法进行详述,对太阳能电池系统的其他部件及工作原理这里不再赘述。本领域技术人员在本说明书描述的内容基础上,即可实现本发明的太阳能电池系统。The embodiment further provides a solar cell system comprising more than one solar cell module connected in series, and the solar cell module is a solar cell module as described above. The structure and working principle of the solar cell system of the present embodiment use techniques well known in the art, and the solar cell system provided by the present invention The improvement is only related to the above solar cell module, and no other parts are modified. Therefore, this specification only details the solar cell module and its preparation method. Other components and working principles of the solar cell system will not be described here. The solar cell system of the present invention can be realized by those skilled in the art based on the contents described in the present specification.
最后应当说明的是,以上实施例仅用以说明本发明的技术方案,而非对本发明保护范围的限制,尽管参照较佳实施例对本发明作了详细地说明,本领域的普通技术人员应当理解,可以对本发明的技术方案进行修改或者等同替换,而不脱离本发明技术方案的实质和保护范围。 It should be noted that the above embodiments are only intended to illustrate the technical solutions of the present invention, and are not intended to limit the scope of the present invention. Although the present invention is described in detail with reference to the preferred embodiments, those skilled in the art should understand The technical solutions of the present invention may be modified or equivalently substituted without departing from the spirit and scope of the technical solutions of the present invention.

Claims (13)

  1. 一种太阳能电池模组,包括太阳能电池模块和背板,所述背板上嵌有金属导电板,其特征在于:所述太阳能电池模块包括互相交替排列的P型太阳能电池基体和N型太阳能电池基体,所述P型太阳能电池基体前表面的负电极与所述N型太阳能电池基体前表面的正电极连接;所述太阳能电池模块设置在所述金属导电板上。A solar cell module comprising a solar cell module and a back plate, wherein the back plate is embedded with a metal conductive plate, wherein the solar cell module comprises a P-type solar cell substrate and an N-type solar cell which are alternately arranged with each other. a substrate, a negative electrode of a front surface of the P-type solar cell substrate is connected to a positive electrode of a front surface of the N-type solar cell substrate; and the solar cell module is disposed on the metal conductive plate.
  2. 根据权利要求1所述的一种太阳能电池模组,其特征在于:所述金属导电板是铝板或者铜板。A solar cell module according to claim 1, wherein the metal conductive plate is an aluminum plate or a copper plate.
  3. 根据权利要求1所述的一种太阳能电池模组,其特征在于:所述P型太阳能电池基体和所述N型太阳能电池基体之间的间隔为不大于5mm。The solar cell module according to claim 1, wherein an interval between the P-type solar cell substrate and the N-type solar cell substrate is no more than 5 mm.
  4. 根据权利要求1所述的一种太阳能电池模组,其特征在于:所述背板上设置有定位装置。A solar cell module according to claim 1, wherein the backing plate is provided with positioning means.
  5. 根据权利要求1所述的一种太阳能电池模组,其特征在于:所述N型太阳能电池基体从上至下依次包括前表面正电极、前表面钝化减反膜、p+掺杂区域、N型晶体硅基体、n+掺杂区域、背表面钝化膜和背表面负电极;所述P型太阳能电池基体从上至下依次包括前表面负电极、前表面钝化减反膜、n+掺杂区域、P型晶体硅基体和背表面全铝背电极。The solar cell module according to claim 1, wherein the N-type solar cell substrate comprises a front surface positive electrode, a front surface passivation anti-reflection film, a p+ doped region, and a N from top to bottom. a crystalline silicon substrate, an n+ doped region, a back surface passivation film, and a back surface negative electrode; the P-type solar cell substrate includes a front surface negative electrode, a front surface passivation anti-reflection film, and n+ doping from top to bottom The region, the P-type crystalline silicon substrate and the back surface all aluminum back electrode.
  6. 根据权利要求1-5任一所述的一种太阳能电池模组,其特征在于:所述P型太阳能电池基体前表面的负电极与所述N型太阳能电池基体前表面的正电极通过金属丝连接,所述P型太阳能电池基体前表面的负电极包括分段副栅和设置在分段副栅上的热敏导电层,所述分段副栅与P型太阳能电池基体前表面的掺杂区域电连接,所述金属丝与所述热敏导电层电连接;所述N型太阳能电池基体前表面的正电极包括分段副栅和设置在分段副栅上的热敏导电层,所述分段副栅与N型太阳能电池基体前表面的掺杂区域电连接,所述金属丝与所述热敏导电层电连接。The solar cell module according to any one of claims 1 to 5, wherein the negative electrode of the front surface of the P-type solar cell substrate and the positive electrode of the front surface of the N-type solar cell substrate pass through the wire Connecting, the negative electrode of the front surface of the P-type solar cell substrate comprises a segmented sub-gate and a heat-sensitive conductive layer disposed on the segmented sub-gate, the doped sub-gate and the doping of the front surface of the P-type solar cell substrate Electrically connecting, the wire is electrically connected to the heat-sensitive conductive layer; the positive electrode of the front surface of the N-type solar cell substrate comprises a segmented sub-gate and a heat-sensitive conductive layer disposed on the segmented sub-gate The segmented sub-gate is electrically connected to a doped region of a front surface of the N-type solar cell substrate, and the wire is electrically connected to the heat-sensitive conductive layer.
  7. 根据权利要求6所述的一种太阳能电池模组,其特征在于:所述金属丝 共设置60-120条,所述金属丝为锡包铜丝、锡包铝丝或锡包钢丝中的任一种,所述金属丝的直径为40-80微米。A solar cell module according to claim 6, wherein said metal wire A total of 60-120 strips are provided, and the wire is any one of tin-coated copper wire, tin-coated aluminum wire or tin-coated steel wire, and the wire has a diameter of 40-80 micrometers.
  8. 根据权利要求1-5任一所述的一种太阳能电池模组,其特征在于:所述太阳能电池模组包括至少两个太阳能电池模块和所述背板上依次设置的第一金属导电板、第二金属导电板、第三金属导电板和第四金属导电板,所述第一金属导电板与所述第二金属导电板之间互相绝缘,所述第三金属导电板与所述第四金属导电板之间互相绝缘,所述第二金属导电板与所述第三金属导电板之间互相电连接;所述太阳能电池模块包括一块P型太阳能电池基体和一块N型太阳能电池基体,所述P型太阳能电池基体前表面的负电极和所述N型太阳能电池基体前表面的正电极通过金属丝连接;其中的一个太阳能电池模块前表面向上置于所述第一金属导电板和所述第二金属导电板上,另外一个太阳能电池模块前表面向上置于所述第三金属导电板和所述第四金属导电板上。The solar cell module according to any one of claims 1 to 5, wherein the solar cell module comprises at least two solar cell modules and a first metal conductive plate disposed in sequence on the back plate, a second metal conductive plate, a third metal conductive plate and a fourth metal conductive plate, wherein the first metal conductive plate and the second metal conductive plate are insulated from each other, the third metal conductive plate and the fourth The metal conductive plates are insulated from each other, and the second metal conductive plate and the third metal conductive plate are electrically connected to each other; the solar cell module comprises a P-type solar cell substrate and an N-type solar cell substrate. a negative electrode of a front surface of the P-type solar cell substrate and a positive electrode of a front surface of the N-type solar cell substrate are connected by a wire; a front surface of one of the solar cell modules is placed upward on the first metal conductive plate and On the second metal conductive plate, another front surface of the solar cell module is placed upward on the third metal conductive plate and the fourth metal conductive plate.
  9. 一种太阳能电池模组的制备方法,其特征在于:包括以下步骤:A method for preparing a solar cell module, comprising: the following steps:
    (1)、将N型太阳能电池基体和P型太阳能电池基体并排放置,然后铺设金属丝,热处理后得到太阳能电池模块;(1) placing an N-type solar cell substrate and a P-type solar cell substrate side by side, then laying a wire, and obtaining a solar cell module after heat treatment;
    (2)、选择嵌有金属导电板的背板,所述背板上嵌有多块金属导电板,根据太阳能电池模块的结构将多块金属导电板作绝缘或者电导通处理,然后将太阳能电池模块放置于嵌有金属导电板的背板上得到太阳能电池模组。(2) selecting a back plate embedded with a metal conductive plate, wherein the plurality of metal conductive plates are embedded in the back plate, and the plurality of metal conductive plates are insulated or electrically connected according to the structure of the solar battery module, and then the solar battery is The module is placed on a back plate embedded with a metal conductive plate to obtain a solar cell module.
  10. 根据权利要求9所述的一种太阳能电池模组的制备方法,其特征在于:步骤(1)中,金属丝通过电池片表面的热敏导电层将P型太阳能电池基体前表面的负电极与N型太阳能电池基体前表面的正电极相连接。The method for fabricating a solar cell module according to claim 9, wherein in the step (1), the wire passes the negative electrode of the front surface of the P-type solar cell substrate through the heat-sensitive conductive layer on the surface of the cell sheet. The positive electrodes of the front surface of the N-type solar cell substrate are connected.
  11. 根据权利要求9所述的一种太阳能电池模组的制备方法,其特征在于:步骤(1)中,热处理的温度为183-250℃。The method of manufacturing a solar cell module according to claim 9, wherein in the step (1), the temperature of the heat treatment is 183 to 250 °C.
  12. 一种太阳能电池组件,包括由上至下依次连接的前层材料、封装材料、太阳能电池模组,其特征在于:所述太阳能电池模组是权利要求1-8任一所述的一种太阳能电池模组。 A solar cell module comprising a front layer material, a packaging material, and a solar cell module connected in sequence from top to bottom, wherein the solar cell module is a solar energy according to any one of claims 1-8 Battery module.
  13. 一种太阳能电池系统,包括一个以上太阳能电池组件,其特征在于:所述太阳能电池组件是权利要求12所述的一种太阳能电池组件。 A solar cell system comprising more than one solar cell module, characterized in that the solar cell module is a solar cell module according to claim 12.
PCT/CN2017/000123 2016-04-14 2017-01-19 Solar cell module and method for manufacturing same, assembly, and system WO2017177726A1 (en)

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