WO2017121751A1 - Procédé et installation de liquéfaction de gaz naturel prétraité - Google Patents
Procédé et installation de liquéfaction de gaz naturel prétraité Download PDFInfo
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- WO2017121751A1 WO2017121751A1 PCT/EP2017/050463 EP2017050463W WO2017121751A1 WO 2017121751 A1 WO2017121751 A1 WO 2017121751A1 EP 2017050463 W EP2017050463 W EP 2017050463W WO 2017121751 A1 WO2017121751 A1 WO 2017121751A1
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- Prior art keywords
- gas
- cooling
- conduit
- liquefaction
- pressure
- Prior art date
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 158
- 239000003345 natural gas Substances 0.000 title claims abstract description 65
- 238000000034 method Methods 0.000 title claims abstract description 46
- 239000007789 gas Substances 0.000 claims abstract description 265
- 238000001816 cooling Methods 0.000 claims abstract description 110
- 239000007788 liquid Substances 0.000 claims abstract description 28
- 239000002826 coolant Substances 0.000 claims abstract description 15
- 239000007791 liquid phase Substances 0.000 claims abstract description 13
- 239000012071 phase Substances 0.000 claims abstract description 10
- 239000007792 gaseous phase Substances 0.000 claims abstract description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 103
- 239000003949 liquefied natural gas Substances 0.000 claims description 58
- 229910052757 nitrogen Inorganic materials 0.000 claims description 51
- 238000000926 separation method Methods 0.000 claims description 11
- 238000007906 compression Methods 0.000 claims description 7
- 230000006835 compression Effects 0.000 claims description 6
- 238000003860 storage Methods 0.000 claims description 6
- 239000012809 cooling fluid Substances 0.000 claims description 4
- 239000000112 cooling gas Substances 0.000 claims description 3
- 230000008569 process Effects 0.000 description 30
- 239000003507 refrigerant Substances 0.000 description 25
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 14
- 229930195733 hydrocarbon Natural products 0.000 description 14
- 150000002430 hydrocarbons Chemical class 0.000 description 14
- 239000012530 fluid Substances 0.000 description 12
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 10
- 239000000047 product Substances 0.000 description 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 8
- 238000005057 refrigeration Methods 0.000 description 8
- 239000004215 Carbon black (E152) Substances 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 7
- 239000001294 propane Substances 0.000 description 7
- 235000013844 butane Nutrition 0.000 description 6
- 238000007781 pre-processing Methods 0.000 description 6
- 239000002131 composite material Substances 0.000 description 5
- 239000001273 butane Substances 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 239000003915 liquefied petroleum gas Substances 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 239000003245 coal Substances 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 238000002203 pretreatment Methods 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000005755 formation reaction Methods 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910000497 Amalgam Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- -1 i.e. Substances 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- DBSMLQTUDJVICQ-CJODITQLSA-N onametostat Chemical compound NC1=C2C=CN([C@@H]3C[C@H](CCC4=CC=C5C=C(Br)C(N)=NC5=C4)[C@@H](O)[C@H]3O)C2=NC=N1 DBSMLQTUDJVICQ-CJODITQLSA-N 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
- F25J1/0022—Hydrocarbons, e.g. natural gas
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
- F25J1/0035—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work
- F25J1/0037—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work of a return stream
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
- F25J1/004—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by flash gas recovery
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
- F25J1/0042—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by liquid expansion with extraction of work
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
- F25J1/0045—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by vaporising a liquid return stream
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0047—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle
- F25J1/005—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by expansion of a gaseous refrigerant stream with extraction of work
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/006—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the refrigerant fluid used
- F25J1/007—Primary atmospheric gases, mixtures thereof
- F25J1/0072—Nitrogen
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0203—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a single-component refrigerant [SCR] fluid in a closed vapor compression cycle
- F25J1/0208—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a single-component refrigerant [SCR] fluid in a closed vapor compression cycle in combination with an internal quasi-closed refrigeration loop, e.g. with deep flash recycle loop
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0257—Construction and layout of liquefaction equipments, e.g. valves, machines
- F25J1/0262—Details of the cold heat exchange system
- F25J1/0264—Arrangement of heat exchanger cores in parallel with different functions, e.g. different cooling streams
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0257—Construction and layout of liquefaction equipments, e.g. valves, machines
- F25J1/0262—Details of the cold heat exchange system
- F25J1/0264—Arrangement of heat exchanger cores in parallel with different functions, e.g. different cooling streams
- F25J1/0265—Arrangement of heat exchanger cores in parallel with different functions, e.g. different cooling streams comprising cores associated exclusively with the cooling of a refrigerant stream, e.g. for auto-refrigeration or economizer
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0279—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc.
- F25J1/0285—Combination of different types of drivers mechanically coupled to the same refrigerant compressor, possibly split on multiple compressor casings
- F25J1/0288—Combination of different types of drivers mechanically coupled to the same refrigerant compressor, possibly split on multiple compressor casings using work extraction by mechanical coupling of compression and expansion of the refrigerant, so-called companders
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2210/00—Processes characterised by the type or other details of the feed stream
- F25J2210/06—Splitting of the feed stream, e.g. for treating or cooling in different ways
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2220/00—Processes or apparatus involving steps for the removal of impurities
- F25J2220/60—Separating impurities from natural gas, e.g. mercury, cyclic hydrocarbons
- F25J2220/62—Separating low boiling components, e.g. He, H2, N2, Air
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
- F25J2230/20—Integrated compressor and process expander; Gear box arrangement; Multiple compressors on a common shaft
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
- F25J2230/30—Compression of the feed stream
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2245/00—Processes or apparatus involving steps for recycling of process streams
- F25J2245/02—Recycle of a stream in general, e.g. a by-pass stream
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2270/00—Refrigeration techniques used
- F25J2270/04—Internal refrigeration with work-producing gas expansion loop
- F25J2270/06—Internal refrigeration with work-producing gas expansion loop with multiple gas expansion loops
Definitions
- the present invention relates to improvements in methods and plants for liquefaction of natural gas to provide Liquefied Natural Gas (LNG) with enhanced efficiency and production rate, while at the same time providing improved economics, improved personnel safety and a reduction of the environmental impact. More specifically, the present invention relates to a method and plant for small scale LNG production environmentally suited to locations onshore, which can satisfy the requirements set with regard to increased safety and environmental protection with increased liquefaction efficiency and production rate.
- LNG Liquefied Natural Gas
- SSLNG is used in areas which have no gas pipeline infrastructure or grid, and there is natural gas available from for example local gas reservoirs or local oil production where gas is separated from the oil in oil stabilization processes. In many areas, gas from oil / gas separators is flared. SSLNG reduces such undesirable flaring. SSLNG enables the transport of gas by truck or small LNG carriers to end users. End use includes domestic heating and fuel for power plants, industries or transport such as trucking or marine vessels. Depending on application, the liquefied gas may be sold as such, or vaporized before delivery. In this way, SSLNG serves a wide range of end users.
- SSLNG One of the main challenges with SSLNG is to provide technical solutions.
- the excellent safety record of the LNG industry needs to be maintained, while at the same time keeping costs low.
- SSLNG lacks economics of scale, and smaller plants usually do not have the same experienced personnel as larger units.
- WO 01/44735 A1 describes a process for liquefaction of natural gas where compressed gas flow at a pressure above 1 1 ,000 kPa (approx. 735 bara) is split in two flows, a first flow that is expanded and used for cooling the second, and still compressed, gas flow. The thus cooled gas flow is then expanded to give a
- Figure 2 shows composite curves for the first stage gas pre-cooling
- Figure 4 shows composite curves for the nitrogen refrigerant pre-cooling
- SSLNG is used as an abbreviation for Small Scale Liquefied Natural Gas.
- natural gas or “gas” is used for a gas comprising low molecular weight hydrocarbons, , which during cooling to produce LNG might be under sufficient pressure to provide supercritical state, where it remains a single phase, or at lower pressures where, depending on temperature, there may be gas only, mixtures of gas and liquid, or liquid only.
- the cooling process may include pre-cooling, which may be any degree of cooling down to about -100°C, main cooling which may be any degree of cooling in the temperature range from precooled temperature to about - 140°C, and sub-cooling which is cooling from main cooling temperature to LNG temperature, where the LNG is stable, or gives only very small amounts of gas, such as 1 to 2% on mass basis, when expanded to
- pre-cooling which may be any degree of cooling down to about -100°C
- main cooling which may be any degree of cooling in the temperature range from precooled temperature to about - 140°C
- sub-cooling which is cooling from main cooling temperature to LNG temperature, where the LNG is stable, or gives only very small amounts of gas, such as 1 to 2% on mass basis, when expanded to
- cooling is used for both pre-cooling, main cooling and sub-cooling.
- a re-cycle gas is introduced into the compressed gas conduit 104 from a discharge conduit 103, before the gas is introduced into the cooler 1 10.
- the gas cooler 1 10 is preferably an air cooler and is provided for cooling the gas that has been heated due to compression.
- the gas cooler 1 10, which conveniently comprises several gas coolers, comprises the first part of the pre-cooling part 1.
- the gas from conduit 104 is, after cooling in the gas cooler 1 10, led in conduit 1 1 1 to a pre-cooling gas / gas heat exchanger 135.
- the gas / gas exchanger 135 cools the gas from near ambient temperature, such as 30°C, typically to about - 30 to -45°C. Downstream of gas / gas exchanger 135, the cooled gas flows in conduit 134 to a second gas / gas heat exchanger 133, where it is further cooled to about -75 to -95°C. This completes the pre-cooling of the gas, which is then led in a conduit 132 to the main cooling or liquefaction part 2.
- a side draw from conduit 1 1 1 is led in conduit 126 via valve 121 to a turbo expander 1 15.
- Some additional gas, a recycle gas part from the liquefaction part 2 is led in a conduit 136, and is mixed with the gas in conduit 126.
- the added recycle gas introduced via conduit 136 typically about 2.0 to 2.5% of the gas flow in conduit 1 1 1.
- a valve 121 is provided in line 126 for reducing the pressure therein to the pressure in conduit 136 to allow the gas from conduit 136 to flow freely into line 126.
- the reduction of pressure over valve 121 is 1 to 3 bar.
- conduit 129 As an example, if desired temperature in conduit 134 is -39°C, then, if the pressure is reduced from about 83 bara to a pressure of about 23 bara in turbo expander 1 15, the expansion cools the gas to a temperature of about -42°C, being about 3°C lower than the desired temperature in conduit 134.
- This cooled gas is led in a conduit 1 16 to a conduit 129 and mixed with gas in conduit 129.
- This mixed gas in conduit 129 may, depending on gas composition, contain small amounts of liquid, such as for example 3 to 4% on a molar basis.
- the fluid in conduit 129 is separated into a gas and a liquid phase in a separator 123, in order to ensure proper distribution of gas and liquid in gas / gas heat exchanger 135.
- the fluid in conduit 120 is separated into a gas and a liquid phase in separator 125.
- the resulting gas phase is led in conduit 124, and the liquid phase in conduit 131 , via pump 130, to gas / gas heat exchanger 133 where the two flows are introduced such that both gas and liquid phase are evenly distributed.
- gas / gas heat exchanger 133 is cooled to a temperature slightly above the temperature in conduit 120, such as -87° C.
- pre-cooled gas is received from the pre-cooling part 1 through the conduit 132. Additional interfaces between process parts are gas return from part 2 to part 1 in conduit 136, and natural gas supply from part 1 to part 3, using gas which has been expanded and heated, in conduit 1 19.
- Pre-cooled natural gas in conduit 132 may contain up to 15 to 20% liquids on a molar basis.
- the fluid in conduit 132 is separated into a gas and a liquid phase in a separator 152.
- the resulting gas phase is led in a conduit 138 to a heat exchanger 139.
- a part of the gas in conduit 138 conveniently about 10% on mass basis, is led in a side draw conduit 137 to a heat exchanger 153.
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- Thermal Sciences (AREA)
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Abstract
L'invention concerne un procédé de liquéfaction d'un gaz naturel prétraité, le procédé consistant : à pré-refroidir, à liquéfier et à sous-refroidir le gaz à une pression élevée, à dilater le gaz comprimé et refroidi jusqu'à une pression de 1 à 1,3 bars absolus pour refroidir davantage le gaz afin de produire une phase liquide et une phase gazeuse, à séparer les phases, à retirer la phase gazeuse de l'installation, à retirer et à exporter la phase liquide à partir de l'installation en tant que GNL, le refroidissement du gaz étant effectué dans une partie de pré-refroidissement (1) et dans une partie de liquéfaction (2) reliée en série à la partie de pré-refroidissement, la pression dans la partie de pré-refroidissement (1) étant sensiblement égale à la pression dans la partie de liquéfaction (2), et au moins un courant de gaz partiel étant retiré du courant de gaz introduit à la partie de liquéfaction (2), chauffé dans la partie de liquéfaction (2), retourné à la partie de pré-refroidissement (1), dilaté et utilisé comme agent de refroidissement pour refroidir le courant gazeux entrant dans la partie de pré-refroidissement (1). L'invention concerne également une installation destinée à mettre en œuvre le procédé.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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EP17700922.2A EP3403038A1 (fr) | 2016-01-12 | 2017-01-11 | Procédé et installation de liquéfaction de gaz naturel prétraité |
Applications Claiming Priority (2)
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NO20160052 | 2016-01-12 | ||
NO20160052 | 2016-01-12 |
Publications (1)
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WO2017121751A1 true WO2017121751A1 (fr) | 2017-07-20 |
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PCT/EP2017/050463 WO2017121751A1 (fr) | 2016-01-12 | 2017-01-11 | Procédé et installation de liquéfaction de gaz naturel prétraité |
Country Status (2)
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EP (1) | EP3403038A1 (fr) |
WO (1) | WO2017121751A1 (fr) |
Cited By (2)
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CN110044130A (zh) * | 2018-01-17 | 2019-07-23 | 乔治洛德方法研究和开发液化空气有限公司 | 蒸发气体再液化装置以及具备该装置的lng供给系统 |
FR3083854A1 (fr) * | 2018-07-11 | 2020-01-17 | Engie | Dispositif et procede de liquefaction d'un flux de dioxyde de carbone |
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US20060021378A1 (en) * | 2004-07-29 | 2006-02-02 | Linde Aktiengesellschaft | Method of liquefying a hydrocarbon-rich flow |
WO2007021351A1 (fr) * | 2005-08-09 | 2007-02-22 | Exxonmobil Upstream Research Company | Procede de liquefaction de gaz naturel destine a produire un gnl |
EP2447652A2 (fr) * | 2001-03-06 | 2012-05-02 | Lummus Technology Inc. | Production de gaz naturel liquefié utilisant des systèmes de réfrigération indépendants doubles |
US8640493B1 (en) * | 2013-03-20 | 2014-02-04 | Flng, Llc | Method for liquefaction of natural gas offshore |
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2017
- 2017-01-11 EP EP17700922.2A patent/EP3403038A1/fr active Pending
- 2017-01-11 WO PCT/EP2017/050463 patent/WO2017121751A1/fr active Application Filing
Patent Citations (7)
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US3360944A (en) * | 1966-04-05 | 1968-01-02 | American Messer Corp | Gas liquefaction with work expansion of major feed portion |
US3735600A (en) * | 1970-05-11 | 1973-05-29 | Gulf Research Development Co | Apparatus and process for liquefaction of natural gases |
US5036671A (en) * | 1990-02-06 | 1991-08-06 | Liquid Air Engineering Company | Method of liquefying natural gas |
EP2447652A2 (fr) * | 2001-03-06 | 2012-05-02 | Lummus Technology Inc. | Production de gaz naturel liquefié utilisant des systèmes de réfrigération indépendants doubles |
US20060021378A1 (en) * | 2004-07-29 | 2006-02-02 | Linde Aktiengesellschaft | Method of liquefying a hydrocarbon-rich flow |
WO2007021351A1 (fr) * | 2005-08-09 | 2007-02-22 | Exxonmobil Upstream Research Company | Procede de liquefaction de gaz naturel destine a produire un gnl |
US8640493B1 (en) * | 2013-03-20 | 2014-02-04 | Flng, Llc | Method for liquefaction of natural gas offshore |
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Title |
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RUDOLF BECKER: "Gasverflà 1/4 ssigung in Verbindung mit Speicherung von verflà 1/4 ssigten Gasen", LINDE BERICHTE AUS TECHNIK UND WISSENSCHAFT,, no. 21, 21 May 1966 (1966-05-21), pages 3 - 5, XP001277433 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110044130A (zh) * | 2018-01-17 | 2019-07-23 | 乔治洛德方法研究和开发液化空气有限公司 | 蒸发气体再液化装置以及具备该装置的lng供给系统 |
EP3514466A3 (fr) * | 2018-01-17 | 2019-11-06 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Appareil de reliquéfaction de gaz d'évaporation et système d'alimentation en gaz naturel liquéfié muni d'un tel appareil |
CN110044130B (zh) * | 2018-01-17 | 2021-01-08 | 乔治洛德方法研究和开发液化空气有限公司 | 蒸发气体再液化装置以及具备该装置的lng供给系统 |
FR3083854A1 (fr) * | 2018-07-11 | 2020-01-17 | Engie | Dispositif et procede de liquefaction d'un flux de dioxyde de carbone |
Also Published As
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EP3403038A1 (fr) | 2018-11-21 |
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