WO2017119728A1 - Cosmetic composition having shape memory ability - Google Patents

Cosmetic composition having shape memory ability Download PDF

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WO2017119728A1
WO2017119728A1 PCT/KR2017/000120 KR2017000120W WO2017119728A1 WO 2017119728 A1 WO2017119728 A1 WO 2017119728A1 KR 2017000120 W KR2017000120 W KR 2017000120W WO 2017119728 A1 WO2017119728 A1 WO 2017119728A1
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cosmetic composition
example
weight
water
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PCT/KR2017/000120
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French (fr)
Korean (ko)
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안창하
박나래
문성호
전영현
노은영
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(주)셀트리온
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/02Cosmetics or similar toilet preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/06Emulsions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/30Cosmetics or similar toilet preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toilet preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41Amines
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/30Cosmetics or similar toilet preparations characterised by the composition containing organic compounds
    • A61K8/46Cosmetics or similar toilet preparations characterised by the composition containing organic compounds containing sulfur
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/30Cosmetics or similar toilet preparations characterised by the composition containing organic compounds
    • A61K8/58Cosmetics or similar toilet preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/72Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/87Polyurethanes
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/72Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILET PREPARATIONS
    • A61Q19/00Preparations for care of the skin

Abstract

The present invention relates to a cosmetic composition having shape memory ability. More specifically, the present invention relates to a cosmetic composition provided with shape memory ability by containing siloxane and silicone quaternium in a water-in-oil type and to a cosmetic composition provided with natural association force and pickup force while maintaining shape memory ability by containing an amine-based or sulfone acid-based compound in a shape memory polymer that is conventionally used. A water-in-oil type cosmetic composition in the cosmetic composition of the present invention is a water-in-oil type formulation containing siloxane and silicone quaternium, and can be provided with an immediate skin wrinkle-improving effect or an immediate skin elasticity-improving effect through shape memory ability and can be provided with a skin gloss-improving effect or a skin moisturizing ability-enhancing effect. In addition, an oil-in-water type cosmetic composition in the composition of the present invention is an oil-in-water type formulation containing a shape memory polymer and an amine-based compound or a sulfone-based compound, and can provide effects of excellent pickup force and natural association force while having excellent shape memory ability.

Description

A cosmetic composition having a shape memory ability

The present invention relates to a cosmetic composition having a shape memory ability. More specifically, the shape memory ability by containing siloxane and silicone quaternium given in water-in-oil type cosmetic composition, and shape memory capabilities by including the amine-based or sulfonate-based compound in the shape memory polymer used in the prior art while maintaining a natural time It relates to the resultant force and the pick-up force is applied to the cosmetic composition.

The cosmetics companies have been many efforts to prevent and improve symptoms that interfere as people seek an extrovert beauty, such as dryness, decreased elasticity, wrinkle formation, spots and freckles. The creation of wrinkles, leading to symptoms that interfere with the outward beauty of the people, the cause of wrinkle formation are classified into three kinds. The first cause is genetic factors influenced by genes inherited from the parents. The second cause is the muscle movements of the face. This may result in that occur naturally when a man cut off or laugh or jjinggeu by giving specific force applied consistently for a long time, wrinkles are created. The third cause is the increase of the reduction of collagen and elastin, which accounts for most of the skin, the dermis, and (Matrix metalloproteinase) MMP to disassemble it.

The biggest reason that the main cause of MMP amount of wrinkle formation and increases skin elasticity decrease is UV. Ironically, in the Earth's atmosphere and environment, consumers are not only always be exposed to UV. And therefore an increasing consumer demand for anti-wrinkle formation and skin elasticity improved functional cosmetic formed a large market in the world. But that began to use visual effects to a minimum of three months to receive the product by using the existing functional cosmetics, see wrinkles and skin elasticity improvement. But consumers want a product that can be effective in increasing the short term. Therefore, a situation which increases the affinity with respect to the cosmetic composition that is visually immediate skin wrinkle alleviating effect and tanryeokgam viewed by consumers.

As shown in these cosmetic immediate anti-wrinkle effect as a cosmetic tanryeokgam apply the shape memory (Shape-Memory) polymers have been developed as a product of the different categories. In general, a cosmetic composition having a shape memory ability is given a shape memory ability depending on the nature of the soluble agent incrementally shape memory polymer in-water type.

However, in a cosmetic composition for applying a polymer having a shape memory ability, there is a problem with low moisture because it can be applied to limited to the in-water type, a situation that still not up to give it the shape-memory ability in the water-in-oil type cosmetic composition. . In addition, the formulation is applied to the shape memory polymer has the disadvantage that failure to use a tool is easy to pick-up, it has the limitations of that in cracking and tearing occurs in the course of the meeting the consumer's aesthetic inhibit the formulation.

Therefore, it has a need for a cosmetic composition for shape-memory capacity while having the advantage of immediate tanryeokgam of the cosmetic composition and the shape memory polymer give excellent pick-up force, and that a sense of aesthetics with the natural times the resultant force to the consumer in a water-in-oil type is soybean.

The present inventors have found that the amine-based or sulfonate-based compound as a water type formulation containing the water-in-oil type formulations as siloxane and, by including a silicone quaternium at the same time to make sure that it is possible to manufacture a cosmetic composition having shape memory ability, the shape memory polymer At the same time, thereby completing the present invention was confirmed that it is possible to manufacture a cosmetic composition having the natural times the resultant force and excellent pick-up force, yet the recovery force of the shape similar to the typical shape restoration formulated by including.

Accordingly, an object of the present invention to solve is to provide a cosmetic composition having a shape memory ability.

In addition, the present invention is to provide an immediate wrinkle method, improve the immediate skin elasticity comprises the step of applying the cosmetic composition to the skin.

To solve the above problems, an object of the present invention to solve is to provide a cosmetic composition having a shape memory ability.

The term "shape memory capability" used in the present invention is generally fixed at a specific temperature and the shape of the temporary or suspension state under a physical force (stress) of the outer and after heat, electricity or the original stress due to changes in the environment to remove It means the ability to be relaxed (relax) to the state. Specifically, when the time that has elapsed after the shape was changed by external stimulation such as in the shape-memory capacity is 1 (b) of the present invention also it refers to the ability to be restored to its original state. When having a "shape memory capability" compound when applied to the skin, the skin pulling phenomenon occurs as restored to its original state before the cosmetic composition is applied, and thereby instantly improving the skin wrinkle and skin elasticity.

The present invention also provides an immediate skin wrinkles, and how instant improved skin elasticity or improved immediate skin shine comprising the step of applying the cosmetic composition to the skin.

The term "improved immediate skin wrinkle" as used in the present invention means that the skin anti-wrinkle effect on the skin a short time after a cosmetic is applied visibly represented by.

The term "improved immediate skin elasticity" to be used in the present invention means that the improved skin elasticity in a short time after applying the cosmetic skin effect appears as visible.

Hereinafter, the present invention will be described in detail.

Wherein the cosmetic composition comprises: (a) siloxane; And (b) may be a water-in-oil type cosmetic composition containing a silicone quaternium compounds.

In addition, the water-in-oil type cosmetic composition of the present invention can be a cosmetic composition, characterized in that does not include a shape memory polymer.

The present invention also provides said water-in-oil skin improved immediate anti-wrinkle, skin elasticity of the male immediate cosmetic composition or immediate skin gloss improvement purposes.

Further, the present invention provides a skin gloss improvement of the water-in-oil type cosmetic composition or a skin hydration promote application.

The present invention also provides an immediate skin wrinkles, and how instant improved skin elasticity or improved immediate skin shine comprising the step of applying the water-in-oil type cosmetic composition to the skin.

The present invention also provides a skin gloss improvement or increase skin moisture comprising the step of applying the water-in-oil type cosmetic composition to the skin.

The term "improved immediate skin luster" used in the present invention means that the skin gloss improving effect in a short period of time after applying a cosmetic skin appears as visible.

The present invention the term "improved skin luster" as used refers to the improvement of the smoothness of the skin and also banjil banjil. This is a smooth and shiny skin after rubbing on the eye cosmetics expression known as light I shine and condition, it can be expressed in healthy skin.

As used herein, the term "skin hydration promote" provide for a long time period to keep the moisture in the skin by reducing the inconvenience, such as hot flushes of the skin, dryness, itching, can be evaluated by measuring the water loss of the skin.

In one embodiment of the invention, the shape memory polymer is a polyurethane -59 (Polyurethane-59), blood not -150 / stearyl alcohol / eseuemdi Aiko polymer (PEG-150 / Stearyl Alcohol / SMDIcopolymer) and not avoid -240 / H. DI copolymer / bis-decyl tetradecyl ether access -20 (PEG-240 / HDIcopolymer / decyltetradeceth-bis-20ether) but be at least one selected from the group consisting of such, and the like.

In one embodiment of the invention, the siloxane is cycloalkyl trisiloxane (Cyclotrisiloxane), cyclotetrasiloxane (Cyclotetrasiloxane), Cyclopentasiloxane (Cyclopentasiloxane), cyclohexanone siloxane (Cyclohexasiloxane), cyclohepta siloxane (Cycloheptasiloxane), phenyl trimethicone chikon (phenyl trimethicone), diphenyl siloxy phenyl trimethicone chikon (Diphenylsiloxy phenyl trimethicone), three tilpi not / blood sebum -10/1 dimethoxy chikon (Cetyl PEG / PPG-10/1 dimethicone) and lauryl blood not poly -9 seven dimethicone di methyl siloxy (Lauryl PEG-9 Polydimethylsiloxyethyl dimethicone), but be at least one selected from the group consisting of such, and the like.

In one embodiment, the silicone is a silicone quaternium polyquaternium -1 (Silicone Quaternium-1), silicone quaternium -3 (Silicone Quaternium-3), silicone quaternium -8 (Silicone Quaternium-8), Silicon Quaternium -15 (silicone Quaternium-15), silicone Quaternium -16 (silicone Quaternium-16). Silicone Quaternium -18 (Silicone Quaternium-18), Silicone Quaternium -20 (Silicone Quaternium-20), and silicone quaternium -22 (Sillicone Quaternium-22), but be at least one selected from the group consisting of, such as, limited to It is not.

The silicone quaternium -22, but can use a silicone quaternium -22 itself, there can be employed a commercialized formulations containing them. The commercialized formulation comprising a silicone quaternium -22 to be used in the present invention include, but are such as ABIL ME 45 (Silicone Quaternium -22 30% containing, EVO niksa Ltd.). This is not limited.

In one embodiment of the invention, the siloxane composition may comprise a total of 1 to 50% by weight, based on the weight of the. In one embodiment, the siloxane is from 2 to 50% by weight, 3 to 50% by weight of the total composition weight. 4 to 50% by weight, 5 to 50% by weight, 6 to 50% by weight, 7 to 50% by weight. 8 to 50% by weight, 9 to 50% by weight, 10 to 50% by weight, 1 to 49% by weight, 1 to 48% by weight, 1 to 47% by weight. 1 to 46% by weight, 1 to 45% by weight, 1 to 44% by weight, 1 to 43% by weight. 1 to 42 wt%, 1 to 41% by weight, 1 to 40% by weight, 1 to 39% by weight, 1 to 38% by weight, 1 to 37% by weight. 1 to 36% by weight, 1 to 35% by weight, 1 to 34% by weight, 1 to 33% by weight. 1 to 32% by weight, 1 to 31% by weight, 1 to 30% by weight, 2 to 48% by weight, 2 to 46% by weight, 2 to 45% by weight. 2 to 44% by weight, 2 to 42% by weight, 2 to 40% by weight, 2 to 38% by weight, 2 to 36% by weight, 2 to 35% by weight. 2 to 34% by weight, 2 to 32% by weight, 2 to 30 wt%, 4 to 38% by weight, 4 to 36 wt%, 4 to 35% by weight. 4 to 34 wt%, 4 to 32% by weight, 4 to 30% by weight, 5 to 45% by weight, 5 to 40% by weight, 5 to 35% by weight, 5 to 30% by weight, 10 to 45% by weight, from 10 to 40% by weight, may include 10 to 35 wt% or 10 to 30% by weight. Siloxane is one not exhibit the shape memory ability is less than% by weight, the siloxane is exceeding 50% by weight water-in-oil type formulation stability and shape memory ability is poor.

In one embodiment, the silicone quaternium may comprise a total of 1 to 20% by weight, based on the weight of the composition. In one embodiment, the silicone quaternium is 2 to 20% by weight of the total composition, based on the weight of, 3 to 20% by weight, 4 to 20% by weight, 5 to 20% by weight, 1 to 19% by weight, 1 to 18% by weight, 1 to 17% by weight, 1 to 16 wt%, 1 to 15% by weight, from 1 to 14.0% by weight, 1 to 13% by weight, 1 to 12% by weight, 1 to 11% by weight, 1 to 10% by weight, 1.5 to 20 parts by weight %, 1.5 to 15% by weight, 1.5 to 10% by weight, 1.8 to 18% by weight, 1.8 to 15% by weight, 1.8 to 12% by weight, 2 to 18% by weight, 2 to 16% by weight, 2 to 15% by weight, 2 to 14% by weight, 2 to 12% by weight, 2 to 10% by weight, 4 to 18 wt%, 4 to 16 wt%, 4 to 15 wt%, 4 to 14 wt%, 4 to 12 wt%, or from 4 to It may include 10% by weight. Silicone Quaternium-1 does not exhibit a shape memory ability is less than% by weight, silicone quaternium If this exceeds 20% by weight of a water-in-oil type formulation stability and shape memory capabilities poor.

In one embodiment of the invention, based on the total composition weight of the composition wherein the siloxane is 1 to 50% by weight, and wherein the silicone quaternium is or the siloxanes of 2 to 20% by weight is 5 to 40% by weight, the silicon Quaternium may include 1.8 to 15% by weight.

In one embodiment, the composition comprises a siloxane and silicone quaternium composition ratio 1 may further comprise 0.02 to 1: 20. For example, the composition ratio of the composition the siloxane and silicone quaternium 1: 0.06 to 1:20, 1: 0.1 to 1:20, 1: 0.5 to 1:20, from 1: 1 to 1:20, from 1: 3 to 1:20, 1: 5 to 1:20, 1: 0.02 to 1:18, 1: 0.02 to 1:15, 1: 0.02 to 1:12, 1: 0.02 to 1: 10, 1: 0.02 to 1: 5, 1: 0.02 to 1: 1, 1: 0.02 to 1: 0.5, 1: 0.02 to 1: 0.1, 1: 0.06 to 1:18, 1: 0.06 to 1:15, 1: 0.06 to 1:12, 1: 0.06 to 1: 10, 1: 0.06 to 1: 5, 1: 0.06 to 1: 1, 1: 0.06 to 1: 0.5, 1: 0.06 to 1: 0.1, 1: 0.1 to 1:18, 1: 0.1 to 1:15, 1: 0.1 to 1:12, 1: 0.1 to 1: 10, 1: 0.1 to 1: 5, 1: 0.1 to 1: 1, 1: 0.1 to 1: 0.5, 1: 0.1 to 1: 0.1, 1: 3 to 1:18, 1: 3 to 1:15, 1: 3 to 1:12, 1: 3 to 1: 10, 1: 3 to 1: 5, 1: 3 to 1: 1, 1 may contain from 0.1: 3 to 1: 0.5 or 1: 3 to 1. Compositions comprising the off-rate siloxane and silicone quaternium is a shape memory ability decreases.

In one embodiment, the composition comprises a siloxane and silicone quaternium composition ratio of 1: 0.5 may comprise: 0.02 to 1:20, 1: 0.45 to 1: 3 or 1: 0.06 to 1.

Wherein the cosmetic composition comprises (a) a shape memory polymer; And (b) may be in the in-water type cosmetic composition comprising at least one compound of the amine compound and the sulfonic acid type compound.

In one embodiment of the invention, the shape memory polymer is a polyurethane -59 (Polyurethane-59), blood not -150 / stearyl alcohol / eseuemdi Aiko polymer (PEG-150 / Stearyl Alcohol / SMDIcopolymer) and not avoid -240 / H. DI copolymer / bis-decyl tetradecyl ether access -20 (PEG-240 / HDIcopolymer / decyltetradeceth-bis-20ether) but be at least one selected from the group consisting of such, and the like.

In embodiments of the invention, the amine compound is triethanol amine (Triethanolamine), tromethamine (Tromethamine), ethanolamine (Ethanolamine), stearoyl limiter FIG propyl di methyl amine (Stearamidopropyl Dimethylamine), tetra-hydroxypropyl ethylene diamine ( Tetrahydroxypropyl Ethylenediamine), acetylglucosamine (acetyl glucosamine) and stearic limiter FIG propyl di methyl amine (Stearamidopropyl Dimethylamine) but be at least one selected from the group consisting of such, and the like.

One embodiment of the present invention clerical script, the sulfonic acid-based compound is sodium isobutyl c8-16 alkyl Wuxi City carbonyl lactoglobulin sulfonate (Sodium Sulfonate c8-16Isoalkylsuccinyl Lactoglobulin), sodium xylene sulfonate (Sodium Xylenesulfonate), phenyl benzimidazole sulfonic Acid (Phenylbenzimidazole Sulfonicacid), disodium phenyl dibenzimidazole imidazole tetra sulfonate (disodium Phenyldibenzimidazole Tetrasulfonate), disodium laureth sulfosuccinate (disodium laureth sulfosuccinate), disodium La when pitching lauryl sulfonic carbonate (disodium lauryl sulfosuccinate), Tea yieyi-dodecylbenzenesulfonate (TEA-dodecyl benzenesulfonate), sodium c14-16 olefin sulfonates (c14-16Olefin sodium sulfonate), sodium hexane sulfonate (sodium Hexanesulfonate), sodium benzotriazolyl butylphenol sulfonate (sodium benzotriazolyl Butylphenol sulfonate) and poly FIG decane amino having aminium triazol jadi phenyl ethene sulfonate (Polydodecanamideaminium Triazadiphenyl Ethenesulfonate) but be at least one selected from the group consisting of such, and the like.

In one embodiment of the invention, the hardness value of the in-water type cosmetic composition may be 7.0 g to 10.0 g.

The term "hardness (Hardness, 硬度)" is ripened or of the material (the object), and tested for their definition (appointment) method rigidity to the image of the result to the numerical value, typically the hardness value (applied load weight used in the present invention (unit: g)) is higher it can be said that the physical properties of the hardened material.

In one embodiment of the invention, the (b) an amine compound and a sulfonic acid-based compounds of at least one compound may be a mixture of amine compound and a sulfonic acid-based compound.

In one embodiment of the invention, the (b) When the amine compound and the sulfonic acid type compound is a mixture of one or more compound, an amine-based compound: a ratio of the sulfonic acid-based compound 3: 1 to 1: 3 may be.

In one embodiment, the in-water type cosmetic composition for the (a) a shape memory polymer and the (b) at least one amine compound and a sulfonic acid-based compound compound composition ratio of 1: to contain to 200.0: 0.2 to 1 can. For example (a) the ratio of the shape memory polymer and the (b) an amine-based compound and at least one compound of the sulfonic acid-based compound composition of 1: 0.5 to 1: 200.0, 1: 0.8 to 1: 200.0, 1: 1 to 1: 200.0 , 1: 0.2 to 1: 150.0, 1: 0.2 to 1: 100.0, 1: 0.2 to 1: 80.0, 1: 0.2 to 1: 50.0, 1: 0.2 to 1: 30.0, 1: 0.2 to 1: 10.0, 1 : 0.2 to 1: 6.7, 1: 0.2 to 1: 3.3, 1: 0.2 to 1: 1, 1: 0.5 to 1: 150.0, 1: 0.5 to 1: 100.0, 1: 0.5 to 1: 80.0, 1: 0.5 to 1: 50.0, 1: 0.5 to 1: 30.0, 1: 0.5 to 1: 10.0, 1: 0.5 to 1: 6.7, 1: 0.5 to 1: 3.3, 1: 0.5 to 1: 1, 1: 0.8 to 1 : 150.0, 1: 0.8 to 1: 100.0, 1: 0.8 to 1: 80.0, 1: 0.8 to 1: 50.0, 1: 0.8 to 1: 30.0, 1: 0.8 to 1: 10.0, 1: 0.8 to 1: 6.7 , 1: 0.8 to 1: 3.3, 1: 0.8 to 1: 1, 1: 1 to 1: 150.0, 1: 1 to 1: 100.0, 1: 1 to 1: 80.0, 1: 1 to 1: 50.0, 1 : 1 to 1: 30.0, 1: may comprise a 3.3: 1 to 1: 10.0, 1: 1 to 1: 6.7, 1: 1 to 1. If other than the above composition ratio, there is a problem that significantly reduces the pick-up force.

In one embodiment, the in-water type cosmetic composition comprises (a) the shape memory polymer, and (b) the ratio of the amine compound and the sulfonic acid type at least one compound of the compound composition 1: 0.2 to 1: 200.0, 1: 0.5 to 1: 30.0, 1: may comprise a 6.7: 1 to 1.

In one embodiment, the in-water type cosmetic composition may comprise the step (a) a shape memory polymer based on the weight of the total composition of 0.1 wt% to 5.0 wt%. For example (a) the shape memory polymer to a total composition of 0.2% to 5.0% by weight, based on the weight of the weight, 0.3 wt% to 5.0 wt%, 0.4 wt% to 5.0 wt%, 0.5 wt% to 5.0 wt%, 0.6 wt% to 5.0 wt%, 0.7 wt% to 5.0 wt%, 0.8 wt% to 5.0 wt%, 0.9 wt% to 5.0 wt%, 1.0 wt% to 5.0 wt%, 1.1 wt% to 5.0 wt%, 1.2 wt% to 5.0 wt. %, 1.3 wt% to 5.0 wt%, 1.4 wt% to 5.0 wt%, 1.5 wt% to 5.0 wt%, 1.6 wt% to 5.0 wt%, 1.7 wt% to 5.0 wt%, 1.8 wt% to 5.0 wt%, 1.9 wt% to 5.0 wt%, 2.0 wt% to 5.0 wt%, 0.1 wt% to 4.0 wt%, 0.2 wt% to 4.0 wt%, 0.3 wt% to 4.0 wt%, 0.4 wt% to 4.0 wt%, 0.5 wt. % to 4.0 wt%, 0.6 wt% to 4.0 wt%, 0.7 wt% to 4.0 wt%, 0.8 wt% to 4.0 wt%, 0.9 wt% to 4.0 wt%, 1.0 to 4.0% by weight of %, 1.1 wt% to 4.0 wt%, 1.2 wt% to 4.0 wt%, 1.3 wt% to 4.0 wt%, 1.4 wt% to 4.0 wt%, 1.5 wt% to 4.0 wt%, 1.6 wt% to 4.0 wt.%, 1.7 wt% to 4.0 wt%, 1.8 wt% to 4.0 wt%, 1.9 wt% to 4.0 wt%, 2.0 wt% to 4.0 wt%, 0.1 wt% to 3.0 wt%, 0.2 wt% to 3.0 wt%, 0.3 wt. % to 3.0 wt%, 0.4 wt% to 3.0 wt%, 0.5 wt% to 3.0 wt%, 0.6 wt% to 3.0 wt%, 0.7 wt% to 3.0 wt%, 0.8 wt% to 3.0 wt%, 0.9 wt% to 3.0 wt%, 1.0 wt% to 3.0 wt%, 1.1 wt% to 3.0 wt%, 1.2 wt% to 3.0 wt%, 1.3 wt% to 3.0 wt%, 1.4 wt% to 3.0 wt%, 1.5 wt% to 3.0 wt. %, 1.6 wt% and may include 3.0 wt%, 1.7 wt% to 3.0 wt%, 1.8 wt% to 3.0 wt%, 1.9 wt% to 3.0 wt%, 2.0 wt% to 3.0 wt%. Less than 0.1% by weight, there is a problem in case of showing a low viscosity, like water flowing lack the incremental effect, more than 5.0% by weight is the cumulative effect that is too large is heavy spreadability.

In one embodiment, the in-water type cosmetic composition comprises (a) the shape memory polymer to contain a total composition of 0.1% to 5.0% by weight, based on the weight of the weight, 0.5% to 4.0% by weight, 1.5% by weight to 3.0% by weight can do.

In one embodiment, the in-water type cosmetic composition may include the (b) at least one amine compound and a sulfonic acid-based compound to the compound compared to the total composition by weight 1.0% to 20.0% by weight. As an example of (b) an amine-based compound and a sulfonic acid type total composition of 1.0% to 20.0% by weight, based on the weight of the weight of at least one compound of the compound, 2.0% to 20.0% by weight, 3.0% to 20.0% by weight, 4.0% by weight to 20.0 wt%, 5.0 wt% to 20.0 wt%, 1.0 wt% to 18.0 wt%, 2.0 wt% to 18.0 wt%, 3.0 wt% to 18.0 wt%, 4.0 wt% to 18.0 wt%, 5.0 wt% to 18.0 wt. %, 1.0 wt% to 15.0 wt%, 2.0 wt% to 15.0 wt%, 3.0 wt% to 15.0 wt%, 4.0 wt% to 15.0 wt%, 5.0 wt% to 15.0 wt%, 1.0 wt% to 12.0 wt%, 2.0 wt% to 12.0 wt%, 3.0 wt% to 12.0 wt%, 4.0 wt% to 12.0 wt%, 5.0 wt% to 12.0 wt%, 1.0 wt% to 10.0 wt%, 2.0 wt% to 10.0 wt%, 3.0 wt. % to 10.0 wt%, 4.0 wt% to 10.0 wt%, 5.0 may comprise a% by weight to 10.0% by weight. When 1.0% by weight less than the deficiency that the content is low, adding the amine-based compound or a sulfonic acid-based compound effect, and more than 20.0% by weight, the problem that the pH is higher than a typical cosmetic composition or is to have a low pH reduces the formulation stability there is.

In one embodiment, the in-water type cosmetic composition comprises (b) an amine-based compound and a sulfonic acid type total composition of 1.0% to 20.0% by weight, based on the weight of the weight of at least one compound of the compound, 2.0% to 15.0% by weight, 3.0 It may comprise% by weight to 10.0% by weight.

In one embodiment, the in-water type cosmetic composition may be for correcting skin defects.

The terms used in the present invention "skin defect correction" means that complement the irregularities, blemishes, wrinkles or pores, which is recognized by the consumer as a defect in the skin cover (cover). Irregularities, blemishes, wrinkles or pores of the skin, wherein the skin defect serves to generate the curvature of the skin surface to inhibit the outward beauty of the skin.

In one embodiment, the in-water type cosmetic composition may be for correcting skin defects.

The terms used in the present invention "easy to apply" is here to applying thin layer on the outside of the area of ​​skin to the desired cosmetic composition to the degree that consumers feel are easy.

The term "take in hand Easy" or "pick-up force" used in the present invention means the degree in will be taken by lifting by a cosmetic composition for finger or spatula (spatula) (pick-up) and feel that consumers easily and preferably it means a case of using the finger without tools such as a spatula (spatula).

The present invention, the term "aesthetics of the associated shaped" or "natural times the resultant force" as used refers to the degree of feel beautiful consumer's As the cosmetic composition is a finger or spatula (spatula) that shape is deformed back again associated by contact or the like do.

Clerical script one embodiment, the cosmetic composition of the present invention may further include an aqueous phase component and the oil component.

The aqueous phase component is a purified water, a moisturizing agent as the solvent propanediol (Propanediol), glycerin (Glycerine), butylene glycol (Buthyleneglycol), propylene glycol (Propyleneglycol), dipropylene glycol (Dipropyleneglycol), pentyl rengeul Lai recall (Penthleneglycol), hexyl xylene glycol (Hexyleneglycol), polyethylene glycol (polyethyleneglycol) and sorbitol (sorbitol), etc., but may contain one or more kinds of polyols selected from the group consisting of, but is not limited to such.

The oil phase component is an oil component deca-methylene Cyclopentasiloxane (Decamethyl Cyclopentasiloxane), octa methyl Cyclopentasiloxane (Octamethyl Cyclopentasiloxane) cyclic volatile oil and a vegetable squalane (Phytosqualane) of a silicone oil and 8-20 carbon atoms of hydrocarbons such as, echil hexyl palmitate (ethylhexyl palmitate), Butylene glycol dicarboxylic frill rate / dicarboxylic freight (Butylene glycol Dicaprylate / Dicaprate), caprylic / Capric triglyceride (caprylic / Capric triglyceride), hexamethylene elderly (Triethylhexanoin) hit the tree , di-isostearyl malate (DiisostearylMalate), polyglyceryl -2 tree isostearate (Polyglyceryl-2 triisostearate), dicarboxylic ruffle reel carbonate (Dicaprylyl carbonate), isononyl benzoate is Sono nm (isononyl Isononanoate), such as esters of oils and phenyl trimethoxy chikon (phenyl trimethicone), methyl trimethoxy chikon (methyl trimethicone), dimethoxy chikon (Dimethic one), caprylic rilme chikon (Caprylyl Methicone), diphenyl siloxy phenyl trimethicone chikon (Dipheynylsiloxy Phenyl Trimethicone) silicone oils and ozokerite (Ozokerite), ceresin (Ceresin), Carnauba Wax (Carnauba Wax etc.), candelilla wax (candelilla wax), paraffin wax (paraffin wax), behenyl alcohol (behenyl alcohol), lecithin (lecithin), polyhydroxy stearic Acid (Polyhydroxystearic Acid), isopropyl myristate (isopropyl myristate), isostearate Rick Acid (Isostearic Acid), one of inulin as stearate (stearoyl inulin), dextrin palmitate (dextrin palmitate), glyceryl behenate / eicosyl four video benzoate (glyceryl behenate / Eicosadioate), distearyl dimonium hectorite (Disteardimonium hectorite) , Ste aralkyl benzalkonium hectorite (Stearalkonium hectorite), bentonite (bentonite), silica-di methyl silyl acrylate (silica Dimethylsilylate) such as thickening agents, and acrylate / echil hexyl acrylate / Methoxy chikon methacrylate copolymer (Acrylates / Ethylhexyl Acrylate / Dimethicone Methacrylate Copolymer), fatty alcohols (Fatty Alcohol), fatty acids (Fatty Acid) or a higher alcohol (Higher Alcohol), but can be used a dispersing agent such as, but not limited to, .

In addition, it may include components commonly used in cosmetic compositions of the present invention, one example of a surfactant, pH adjusting agents, dyes, fragrances, pigments, preservatives, disinfectants, thickeners, antioxidants, stabilizers, solubilizers, metal ion chelating agents, refreshing agents, deodorants, emulsifiers, various additives and humectants, ultraviolet absorbers, ultraviolet scattering agents, vitamins, plant extracts, skin astringents, anti-inflammatory agents, cell-activating agents, vasodilators, blood circulation accelerators, skin function such as a solubilizing agent It can include adjuvants and carriers such as agonists, and not the dosage form and the additional component is not limited to the above. In addition, the components can be introduced in an amount commonly used in skin science.

The cosmetic composition of the present invention can include a cosmetic composition in which the ingredients are formulated is not particularly limited, and commonly used in the art to which this invention pertains, depending on the formulation to be manufactured. A cosmetic composition of the present invention is, for example, a liquid product, a lotion, essence, but may be formulated as creams, line lotion, sun block, makeup base, foundation, BB cream, stick onto the product or night (Balm) type products, such as flower, this is not limited. In addition, further in accordance with the formulation to be manufactured selecting the oil, water, surfactants, humectants, lower alcohols, thickeners, chelating agents, preservatives, flavors, etc. may be added in combination. It may also include a sunscreen, light scattering and the like, and not the dosage form and the additional component is not limited to the above. In addition, the components can be introduced in an amount commonly used in skin science.

The cosmetic composition of the present invention is not to add or enhance the functionality and can include anti-wrinkle cosmetic composition, the cosmetic for whitening, sunscreen, light scattering and the like, but is not limited thereto. Water-in-oil type cosmetic composition of the present invention can be used to directly apply or spray to the skin according to its type.

The cosmetic composition of the present invention can be used to directly apply or spray to the skin according to its type. For the amount and per day of application times of the composition, the user's age, sex, purpose, but suitably set depending on the severity of symptoms, for example, a 5 or 6 times / day with an appropriate amount of the composition from once / day It can be applied to the skin as often.

Water-in-oil type cosmetic composition of the cosmetic composition of the present invention is a water-in-oil type formulations, including siloxane and silicone quaternium, shape memory capability immediate skin wrinkles or immediate skin elasticity improving effect is given, skin gloss improving effect or skin moisture through the it is possible to give the enhancement effect. In addition, in-water type cosmetic composition in a composition of the invention is a shape memory polymer and an amine-based compound or a sulfonic acid-based compound as a water type formulation containing, it can give excellent pick-up force and the natural times the resultant force effect along while having an excellent shape memory capability have.

Figure 1 shows the configuration of the comparative formulation of Example 1, Formulation Example 1.

2 illustrates the configuration of Comparative Formulation Example 2 and Example 2 formulations.

The present invention will be described by the following examples in more detail. However, embodiments are not limited by the embodiment of the range of these or another may make a sense to assist the understanding of the present invention.

Examples 1 to 13 and Comparative Examples 1 to 3 Preparation of

And the product was respectively prepared by Examples 1 to 13 and comparative water-in-oil type cosmetic composition of Examples 1 to 3 in the proportion shown in Table 1 (unit: wt%). Siloxane compounds or cyclo penta siloxane was used cyclohexadiene siloxane, silicone quaternium compounds ABIL ME 45: was used (containing 30% -22 titanium silicon quarter, manufacturers niksa EVO).

Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8 Example 9 Example 10 Example 11 Example 12 Example 13 Comparative Example 1 Comparative Example 2 Comparative Example 3
(A) Silicone compound Cyclopentasiloxane 30.00 30.00 30.00 30.00 - - - - 15.00 30.00 - 30.00 - 30.00 - -
Cyclohexadiene siloxane - - - - 30.00 30.00 30.00 30.00 15.00 - 30.00 - 30.00 - 30.00 -
(B) silicone quaternium compounds ABIL ME 45 (in terms of silicone quaternium -22 amount) 40.00 (12.00) 30.00 (9.00) 15.00 (4.50) 6.00 (1.80) 40.00 (12.00) 30.00 (9.00) 15.00 (4.50) 6.00 (1.80) 15.00 (4.50) 50.00 (15.00) 50.00 (15.00) 20.00 (6.00) 20.00 (6.00) - - 30.00 (9.00)
(A) :( b) ratio 1: 0.4 1: 0.3 1: 0.15 1: 0.06 1: 0.4 1: 0.3 1: 0.15 1: 0.06 1: 0.15 1: 0.5 1: 0.5 1: 0.2 1: 0.2 - - -
(C) Other The disodium dt Avon Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount
1,3-butylene glycol 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00
ABIL EM 90 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00
Purified water To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100

Carried out in Table 1. Examples 1-4 are carried out ABIL ME 45 in cyclopenta it includes siloxane 30.00% by weight, and silicone quaternium compounds as Silicone compound of Example 1 is 40.00% by weight, in Example 2, 30.00% by weight, Example 3 is 15.00% by weight, in example 4 containing 6.00% by weight. Examples 5 to 8 is carried out ABIL ME 45 to include cyclohexadiene siloxane 30.00% by weight of a siloxane compound, and silicone quaternium compounds Example 1 40.00 wt% Example 2 30.00% by weight Example 3 15.00 wt. %, example 4 includes 6.00% by weight. Example 9 comprises a siloxane compound Cyclopentasiloxane and a siloxane-cyclohexadiene in each 15.00 15.00 wt% ABIL as ME 45, silicone quaternium compounds include a mixture containing by weight%. Examples 10 and 12 will include a cyclopenta siloxane including 30.00% by weight, ABIL ME 45 with a silicone quaternium compounds Example 10 is 50.00% by weight of Example 12 is 20.00% by weight. Examples 11 and 13 is carried out the ABIL as ME 45 includes a quarter-cyclohexadiene siloxane 30.00% by weight, and silicon titanium compound in Example 10 is 50.00% by weight Example 12 contains 20.00% by weight. Comparative Examples 1 and 2 will not add ABIL ME 45 in Examples 1 and 2, Comparative Example 3 is not added Cyclopentasiloxane or cyclohexadiene siloxane in Example 1.

Test Example 1: Examples 1 to 13 and Comparative Examples 1 to 3 the results of the sensory evaluation

With respect to the Examples 1 to 13 and an immediate improvement of the gloss when Comparative Examples 1 to 3 and applied to the shape memory capabilities of a sensory evaluation was performed.

It was to compare the effectiveness of the product in Comparative Example 1 to 3 and Examples 1 to 13 to the sensory test targets 20-30 female 20 consumers, bad was evaluated as OK, Good, Very Good. Evaluation results of each item are shown in Table 2 below.

Test Items Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8 Example 9 Example 10 Example 11 Example 12 Example 13 Comparative Example 1 Comparative Example 2 Comparative Example 3
Shape memory capacity good Very Good good usually good Very Good good usually good usually usually Very Good Very Good Bad Bad Bad
Immediate improvement of the gloss when applied Very Good Very Good Very Good usually Very Good Very Good Very Good usually Very Good usually usually Very Good Very Good Bad Bad Bad

Table 2 As with all of the siloxane compound and the silicone quaternium compounds according to the present invention produced as exemplary shown in Examples 1 to 13 When Examples Comparative Example 1 [shape memory capabilities, unlike to 3 and the coating containing the respective compound immediate improvement of the gloss was confirmed to appear. In addition, through the excellent shape memory ability, it was confirmed that immediate anti-wrinkle and immediate firmness to be given improvements.

Examples 14 to 19 and Comparative Example 4 Preparation of

Table 2 Sensory evaluation result, siloxane compounds: 1 ratio of silicone quaternium compounds: 0.06 to 1: it was confirmed that the shape memory ability is achieved when 0.5. Silicone compound of them: it was confirmed to show the best effects in the 0.3: 1 ratio of silicone quaternium compounds.

For this purpose, to determine the content range of the siloxane compound, based, 40% by weight amount of the siloxane compound, a siloxane compound 15% by weight, 5% by weight: silicone quaternium compounds to 0.3: the ratio of the silicone quaternium compounds (1) examples 14 to 16 were prepared containing. In addition, by using the silicone quaternium -20 in order to ensure that represents the same effects silicone quaternium compounds other than ABIL ME 45, was prepared in Examples 17 to 19. Finally, was prepared in Comparative Example 4 containing only a silicone quaternium -20 to determine whether its own shape memory effect of the silicone quaternium -20.

To each were prepared for Examples 14 to 19, water-in-oil type cosmetic composition of the composition shown in Table 3 (unit: wt%). Siloxane compounds were cyclopenta siloxane or using cyclohexadiene siloxane, a silicone quaternium compounds were used as 45 or ABIL ME silicone quaternium -20.

Example 14 Example 15 Example 16 Example 17 Example 18 Example 19 Comparative Example 4
(A) Silicone compound Cyclopentasiloxane 40.00 15.00 5.00 30.00 - 30.00 -
Cyclohexadiene siloxane - - - - 30.00 - -
(B) silicone quaternium compounds ABIL ME 45 (in terms of silicone quaternium -22 amount) 40.00 (12.00) 15.00 (4.50) 5.00 (1.50) - - 15.00 -
Silicone Quaternium -20 - - - 9.00 9.00 4.50 9.00
(A) :( b) ratio 1: 0.3 1: 0.3 1: 0.3 1: 0.3 1: 0.3 1: 0.3 -
(C) Other The disodium dt Avon Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount
1,3-butylene glycol 8.00 8.00 8.00 8.00 8.00 8.00 8.00
ABIL EM 90 2.00 2.00 2.00 2.00 2.00 2.00 2.00
Purified water To 100 To 100 To 100 To 100 To 100 To 100 To 100

Carried out in Table 3. Examples 14 to 17 are subjected to Cyclopentasiloxane a siloxane compound Example 14 contains 40.00% by weight, in Example 15 it is 15.00% by weight, in Example 16 is 5.00% by weight, in Example 17 is 30.00% by weight, examples 14 to 16 of a silicone quaternium compounds embodiment wt% ABIL ME 45 40.00, example 17 includes a silicone quaternium -22 to 9.00% by weight. Example 18 is included as the siloxane compound in the cyclohexanone 30.00% by weight siloxane, a silicone Quaternium -22 Quaternium a silicone compound to 9.00% by weight. Example 19 is a mixture including comprising a siloxane compound Cyclopentasiloxane to 30.00% by weight, ABIL ME 45 15.00% by weight and silicone quaternium -22 4.50% by weight of a silicone quaternium compounds. Comparative Example 4 is not added Cyclopentasiloxane in Example 17.

Test Example 2: Sensory evaluation conducted in Example 14 to Example 19 and Comparative Example 4 Results

The sensory evaluation was performed with respect to the instant when the gloss improvement of Examples 14 to 19 and applied to the shape memory capabilities of.

Was to compare the effectiveness of the product Examples 14 to 19 to the sensory test targets 20-30 female 20 consumers, bad was evaluated as OK, Good, Very Good. Evaluation results of each item are shown in Table 4 below.

Test Items Example 14 Example 15 Example 16 Example 17 Example 18 Example 19 Comparative Example 4
Shape memory capacity usually Very Good usually Very Good Very Good Very Good Bad
Immediate improvement of the gloss when applied usually Very Good usually Very Good Very Good Very Good Bad

, The amount of siloxane compound 40% by weight (Example 14) As shown in Table 4, or, 5 wt.% (Example 16) of the case, 15% by weight of the shape memory capabilities, unlike Example 15, and the immediate gloss confirmed that the improvement has reduced all.

Additionally, it can be obtained in Example 17 through to 19, the same excellent shape memory ability and gloss immediate improvement even with the different silicone quaternium compounds Effect with ABIL ME 45 different silicone quaternium compounds, silicone quaternium -20, not It was OK.

Formulation Example 1 and Comparative Example 1 Preparation of Formulation

To the second embodiment of the makeup formulations of Formulation Example 1 and Comparative Example 1, make-up formulations of Comparative Formulation Example 1 of the compositions of Table 5 were prepared.

No division Raw material Formulation Example 1 Comparative Formulation Example 1
One Oily ABIL EM 90 2.00 2.50
2 Cyclopentasiloxane 30.00 30.00
3 Phenyl trimethicone chikon 5.00 5.00
4 Bentonite 0.30 0.30
5 Pigment Titanium dioxide Proper amount Proper amount
6 Yellow iron oxide Proper amount Proper amount
7 Red iron oxide Proper amount Proper amount
8 Black iron oxide Proper amount Proper amount
9 Awards Purified water To 100 To 100
10 The disodium dt Avon Proper amount Proper amount
11 1,3-butylene glycol 8.00 8.00
12 ABIL ME 45 30.00 -
13 additive Spices Proper amount Proper amount

Test Example 3: Shape memory the relevant comparison the shape of the cosmetic composition formulation

Using the comparison formulation as that of Example 1, the formulation in Example 1, to confirm to the shape memory ability was examined visually as follows.

For comparison, the relevant shape, using a spatula which is generally used for cosmetic pickup compared to Formulation Example 1 and Formulation Example 1 are shown the shape of the dosage form after after 5 minutes was added to physical shocks Figure 1.

As the results of 1 and Comparative Formulation Example 1. In the case of ((a) of Fig. 1) Formulation Example 1 ((b in Fig. 1)) compared to that any signs of physical shock remains is restored shape smooth surface it was confirmed that the. With this result was confirmed Formulation Example 1 has a shape memory capability.

Test Example 4: Confirmation promote skin hydration effect of the shape memory cosmetic composition formulation

To check for skin hydration promote the effect of the formulation in Example 1, only 22 were subjected to clinical trials targeting women 19-55 years of age. If confirmed the epidermal water loss change to confirm that the increase skin moisture. If epidermal water loss; in Iran (Trans Epidermal Water Loss TEWL) body means the amount of water through the skin layer of the skin pass through the diffusion and evaporation into the atmosphere from the skin in, for 1 hour at the skin area of ​​one square meter of evaluation region the amount (g) of the water which vaporizes is expressed in g / m 2 h value. Using the formulation in Example 1 of cosmetic use before the cosmetic composition of the formulation of Example 1 after two weeks with the daily application to the face the ball portion moisture transpiration system (Vapometer, Delfin Technologies Ltd, Finland) in order to determine the path epidermal water loss change of the subject If the epidermal water loss was measured in the visible region.

If epidermal water loss measurement of the formulation example 1 was used before 17.02 ± 3.91 g / m 2 in h, it was used as two weeks after 16.02 ± 3.86 g / m 2 h decreased 6.24%. According to Normality Test parametric method of Paired samples t-test when used as a black was less than 2, the value P-value of 0.05 after week. It means that the probability that in not applying gloss group is naturally reduced to 6% and less than 5% of P-value less than 0.05.

Therefore, the formulation in Example 1 was confirmed to promote skin hydration control which lowers the moisture loss of the skin through the experimental results.

Test Example 5: Confirmation skin gloss improvement of the shape memory effect cosmetic composition formulation

To check for improved skin gloss effect of the formulation in Example 1, only 22 were subjected to clinical trials targeting women of 19-55 years old. Skin after two weeks cosmetic use before and cosmetic composition of Formulation Example 1 Formulation Example 1 In order to determine gloss improving effect with the daily application to the face the ball portion glossiness (Skin Gloss Unit, SGU) values ​​skin gloss meter (Skin Gloss Meter It was measured using, Delfin Technologies Ltd, Finland).

Skin gloss measurements of the formulation of Example 1 at 63.03 ± 6.20 before use, increased by 2.24% to 64.44 ± 6.06 after 2 weeks use, used in accordance with the Normality Test hayeoteul black as a parametric method of Paired samples t-test after 2 weeks P-value was less than the value of 0.05. It means that the probability of not applying gloss in the experimental group increased 2% to less than 5% of the natural P-value less than 0.05.

Thus, to the formulation example 1 improve skin shine through the experimental results were confirmed by the statistical results.

Examples 20 to 28 and Comparative Examples 5 to 14 Preparation of

To each were prepared for Examples 20 to 28 and the in-water type cosmetic composition of Comparative Examples 5 to 14 the composition of Table 6 and Table 7 (Unit:% by weight). Examples 20 to 28 and Comparative Example 1 is not of a shape memory polymer P -240 / H DI copolymer of the present invention bis-decyl tetradecyl ether access -20 was used ADEKANOL GT-700 (ADEKA Corporation, Japan).

Wonryomyeong Example 20 Example 21 Example 22 Example 23 Example 24 Example 25 Example 26 Example 27 Example 28
Purified water To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100
The disodium dt Avon 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02
1,3-butylene glycol 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0
Blood not -240 / H DI copolymer bis-decyl tetradecyl ether access -20 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0
Triethanolamine 8.0 - - - - - 3.0 - -
Tromethamine - 6.0 - - - - - - 1.5
Acetylglucosamine - - 5.0 - - - 3.0 - -
Sodium xylene sulfonate - - - 5.0 - - - 3.0 -
Sodium hexane sulfonate - - - - 8.0 - - 3.0 -
Phenyl benzimidazol sulphonic Acid 5.0 3.0
Fiji blood test section -26- -26 / -40 dihydro jeneyi blood not suited castor oil 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2
Spices Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount
antiseptic Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount

Wonryomyeong Comparative Example 5 Comparative Example 6 Comparative Example 7 Comparative Example 8 Comparative Example 9 Comparative Example 10 Comparative Example 11 Comparative Example 12 Comparative Example 13 Comparative Example 14
Purified water To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100
The disodium dt Avon 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02
1,3-butylene glycol 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0
Blood not -240 / H DI copolymer bis-decyl tetradecyl ether access -20 2.0 - - - - - - - - -
Triethanolamine - 8.0 - - - - - 3.0 - -
Tromethamine - - 6.0 - - - - - - 1.5
Acetylglucosamine - - - 5.0 - - - 3.0 - -
Sodium xylene sulfonate - - - - 5.0 - - - 3.0 -
Sodium hexane sulfonate - - - - - 8.0 - - 3.0 -
Phenyl benzimidazol sulphonic Acid - - - - - - 5.0 - - 3.0
Fiji blood test section -26- -26 / -40 dihydro jeneyi blood not suited castor oil 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2
Spices Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount
antiseptic Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount

Table performed at 6 Examples 20 to 22 is the triethanolamine 8.0% by weight of the amine-based compound, a Trojan embodiment include metadata Min 6.0% by weight, the acetylglucosamine 5.0% by weight, and Examples 23 to 25 was sodium xylene as a sulfonic acid-based compound alkylene a sulfonate to 5.0% by weight, sodium hexane sulfonate, 8.0% by weight, benzamide phenyl sulfonic imidazole sulphonic Acid and a 5.0% by weight. Example 26 is a two amine-based compound includes triethanolamine and a mixture mixing acetylglucosamine, respectively 3.0 wt%, Example 27 has two sulfonic acid type compound is sodium xylene sulfonate to carbonate and sodium hexane sulfonate, respectively 3.0% by weight It includes a mixture thereof. Example 28 contains the amine-based compound, tromethamine 1.5% by weight and the sulfonic acid-based compound, phenyl benzimidazole sulfonic Acid mixture of 3.0% by weight.

Example 20 to 28 In the shape memory polymer P not -240 / H DI copolymer bis- content of decyl tetradecyl ether access -20 is 2.0% by weight. Shape memory polymer and the added amine-based compound, the constituents of the mixture, the mixture or other mixture of the amine compound and a sulfonic acid-based compound consisting of sulfonic acid-based compound consisting of amine compounds is the same.

Comparative Example In Table 75 was carried out in Example 20 will not add an amine compound and a sulfonic acid-based compound, it has not been added to Comparative Examples 6 to 14 is a shape memory polymer in Examples 20 to 28.

Experimental Example 6: Sensory evaluation of Examples 20 to 28 and Comparative Examples 5 to 14

Example 20 to 28 and Comparative Examples 5 to 14 to ease the shape memory ability, the coating of, was subjected to the sensory evaluation for easiness to take the hand (pick-up force) and the associated shaped aesthetics (natural times the resultant force).

For the sensory evaluation Examples 20 to 28 and the Comparative Examples 5 to 14 to 20 ~ 30 female 20 a consumer to was to compare the effectiveness of the product, step 6. score of 0 to 5 for each of the items It was given to. To the average scores for each item it is shown in Table 8 and Table 9.

<Evaluation Criteria for Sensory Evaluation>

0: No effect at all, 1: very poor, 2: poor 3: average, 4: Good, 5: Excellent

Test Items Example 20 Example 21 Example 22 Example 23 Example 24 Example 25 Example 26 Example 27 Example 28
Shape memory capacity 4.8 4.5 4.7 4.8 4.5 4.8 4.7 4.5 4.7
Easy to apply 4.3 4.7 4.4 4.5 4.7 4.5 4.3 4.3 4.8
Easy to take in hand (pick-up force) 4.7 4.6 4.7 4.6 4.5 4.6 4.7 4.5 4.6
The associated shape aesthetics (natural times the resultant force) 4.5 4.8 4.7 4.6 4.7 4.7 4.5 4.5 4.8

Test Items Comparative Example 5 Comparative Example 6 Comparative Example 7 Comparative Example 8 Comparative Example 9 Comparative Example 10 Comparative Example 11 Comparative Example 12 Comparative Example 13 Comparative Example 14
Shape memory capacity 4.5 0.8 0.7 0.6 0.7 0.5 0.6 0.7 0.8 0.8
Easy to apply 2.7 4.5 4.7 4.5 4.7 4.6 4.5 4.2 4.4 4.6
Easy to take in hand (pick-up force) 1.8 4.7 4.2 4.5 4.5 4.7 4.8 4.7 4.4 4.5
The associated shape aesthetics (natural times the resultant force) 1.9 1.2 1.5 1.4 1.5 1.2 1.3 1.2 1.4 1.6

As shown in Table 8 and the results are shown in Table 9, the embodiment made in accordance with the invention Examples 20 to 28 were found to Comparative Examples 5 to 14 is equal to or better shape memory capabilities than the composition appears. Also check the Examples 20 to 28 are easy to excellent coating compared to Comparative Example 1, the pick-up force and the natural times the resultant force is was confirmed to appear, the shape in the memory Comparative Examples 6 to 14 the polymer is not included, not the shape memory capabilities not It was.

Test Example 7: Examples 20 to 28 and Comparative Examples hardness

The Test Example 6 Hardness was evaluated to determine the pick-up force and the resultant force of the natural once Examples 20 to 28 and Comparative Example 5 showed a shape-memory ability in.

Hardness measurement was performed using a Sun Rheo Meter Compac-100 (Sun Scientific Co., Japan), adapter is a 10 mm diameter, penetration distance is 15 m, the maximum stress was measured to be 2 kg conditions. It embodiments the cosmetic composition of Examples 20 to 28 and Comparative Example 5 were measured capture constant at 45 mm diameter in a cylindrical container, height 35 mm. The results are shown in Table 10 below (applied load weight (unit: g)).

Comparative Example 5 Example 20 Example 21 Example 22 Example 23 Example 24 Example 25 Example 26 Example 27 Example 28
Hardness (g) 31.0 8.0 10.0 9.0 7.0 8.0 10.0 7.0 9.0 9.0

The cosmetic composition of Table 10, as a result of the compositions of Examples 20 to 28, while showing a hardness value of 7.0 g to 10.0 g, Comparative Example 5 exhibited a high hardness value of 31.0 g. Comparison with a high hardness value, e.g., 5 is very stiff to the said embodiment has a lower hardness value than it was difficult to take in hand, Comparative Example 5 Examples 20 to 28 are not rigid, easy to take in hand (pick-up force even number), the pick-up after it was confirmed that the shape of the cosmetic remaining in the container naturally associated. It was confirmed that with these results Examples 20 to 28 having a pick-up force and the resultant force natural times as compared with Comparative Example 5.

Formulation Example 2 and Comparative Formulation Example 2 Preparation of

To prepare a composition of Table 11 in Example 23 and Comparative Example 5 as compared with the Formulation Example 2, each formulation the composition of the make-up formulation of Example 2 (unit:% by weight).

No. division Wonryomyeong Formulation Example 1 Comparative Formulation Example 1
One Awards Purified water To 100 To 100
2 1,3-Butylene Glycol 10.0 10.0
3 glycerin 5.0 5.0
4 The disodium dt Avon 0.2 0.2
5 Blood not -240 / H DI copolymer bis-decyl tetradecyl ether access -20 2.0 2.0
6 Sodium xylene sulfonate 5.0 -
7 coloring agent Titanium dioxide 8.0 8.0
8 Yellow iron oxide, red iron oxide, black iron oxide 2.0 2.0
9 Oily Dimethicone 4.0 4.0
10 Cyclopentasiloxane 7.0 7.0
11 Emulsifiers 2.0 2.0
12 antiseptic Proper amount Proper amount
13 Spices Proper amount Proper amount

Test Example 8: Formulation Example 2 and Comparative Formulation Example 2 Comparison of the naked eye the shape of a makeup formulation

The formulation in Example 2 using Comparative Formulation Example 2 to determine the phase of the shape memory ability was examined visually as follows.

To the naked eye the shape comparison, Formulation Example 2 and Comparative Formulation Example 2 In general, cosmetic after applying a physical impact using a spatula (spatula) to be used for pick-up, and 5 minutes after shape as it picked up with fingers of the formulation to It shows a state in Fig. 2.

As a result of 2, Comparative Formulation Example 2 (Fig. 2 (a)) showing a very hard, dripping broken tearing and cracking phenomenon (poor pick-up force) taking difficult for the hand contrast, Formulation Example 2 (2 of (b)) were found to be easy to take in hand Possession shape is naturally associated (pickup power excellent). This Formulation Example 2 was confirmed that the pick-up force is superior to the consumer and to provide, aesthetic cosmetic formulations that through.

Test Example 9: Confirmation shape memory polymer content range of the cosmetic compositions according to the invention Test

To confirm the effects according to the content of the shape memory polymer was tested as follows (in% by weight). Shape memory polymers are not blood -240 / H DI copolymer bis-decyl tetradecyl access -20 was used as the ether, an amine-based compound in Example 20 was used as the triethanolamine, sodium xylene sulfonate-based compound of Example 23 the alkylene sulfonate was used.

Wonryomyeong Example 20 Example 23 Example 29 Example 30 Example 31 Example 32 Example 33 Example 34 Example 35 Example 36
Purified water To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100
The disodium dt Avon 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02
1,3-butylene glycol 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0
Blood not -240 / H DI copolymer bis-decyl tetradecyl ether access -20 2.0 2.0 0.5 1.5 3.0 4.0 0.5 1.5 3.0 4.0
Triethanolamine 8.0 - 8.0 8.0 8.0 8.0 - - - -
Sodium xylene sulfonate - 5.0 - - - - 5.0 5.0 5.0 5.0
Fiji blood test section -26- -26 / -40 dihydro jeneyi blood not suited castor oil 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2
Spices Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount
antiseptic Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount

Carried out in Table 12. Examples 29 to 32, including the amine-based compound of triethanolamine to 8.0% by weight Example 29 is not blood -240 / H DI copolymer bis- the content of decyl tetradecyl ether 0.5% by weight of access -20 and, in example 30 is 1.5% by weight, example 31 is a 3.0% by weight, in example 32 was 4.0% by weight. Examples 33 to 36 is a sulfonic acid-based compound is a sodium xylene sulfonate including carbonate with 5.0% by weight, and Example 33 is not blood -240 / H DI copolymer bis-decyl tetradecyl ether access -20 content of 0.5% by weight and of example 34 is 1.5% by weight, in example 35 is 3.0% by weight, in example 36 is 4.0% by weight.

<Evaluation Criteria for Sensory Evaluation>

0: No effect at all, 1: very poor, 2: poor 3: average, 4: Good, 5: Excellent

Test Items Example 20 Example 23 Example 29 Example 30 Example 31 Example 32 Example 33 Example 34 Example 35 Example 36
Shape memory capacity 4.8 4.8 2.8 4.5 4.9 4.9 2.4 4.6 4.9 5.0
Easy to apply 4.3 4.5 4.8 4.7 4.0 1.3 4.9 4.5 3.9 1.5
Easy to take in hand (pick-up force) 4.7 4.6 4.7 4.4 4.1 1.8 4.8 4.6 4.0 1.4
The associated shape aesthetics (natural times the resultant force) 4.5 4.6 4.1 4.5 4.1 3.5 3.9 4.7 4.0 2.8

Table 13 each back subjected to the sensory evaluation for Examples 20, 23 and Examples 29 to ease to 36 shape memory ability, the coating of, taking in hand Easy (pick-up force) and the esthetics of the associated shape (natural times the resultant force) effect scores are average results for the item. Sensory evaluation was to grant 20 to 30 women who were 20 to a consumer to compare the effectiveness of the product, and 6 score of 0-5 points for each item.

As the results in Table 13, page P -240 / H DI copolymer bis-decyl tetradecyl ether to access -20 content of 0.5% by weight and 4.0% by weight of the shape memory ability, ease of application, ease of taking in hand (pick-up force ), and aesthetics of the associated shape (it was confirmed that the effect to give the natural times the resultant force). In particular, blood not -240 / H DI copolymer bis-decyl tetra having access to -20, while the content of ether keeping the existing shape memory capability of from 1.5% by weight and 3.0% by weight of the coating easy, taking in hand Easy (pick-up force ), and aesthetics of the associated shape (natural times the resultant force), which was confirmed to improve-rescue.

Test Example 10: Confirmation cosmetic amine-based compound or a sulfonic acid-based compound content range of the composition according to the invention Test

It was tested to determine the effect, as shown below in accordance with the content of the amine-based compound or a sulfonic acid-based compounds (in% by weight). Amine-based compounds, and sulfonic acid type compound is used the triethanolamine and sodium xylene sulfonate used in the above Test Example 9.

Wonryomyeong Example 20 Example 23 Example 37 Example 38 Example 39 Example 40 Example 41 Example 42 Example 43 Example 44
Purified water To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100
The disodium dt Avon 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02
1,3-butylene glycol 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0
Blood not -240 / H DI copolymer bis-decyl tetradecyl ether access -20 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0
Triethanolamine 8.0 - 2.0 3.0 10.0 15.0 - - - -
Sodium xylene sulfonate - 5.0 - - - - 2.0 3.0 10.0 15.0
Fiji blood test section -26- -26 / -40 dihydro jeneyi blood not suited castor oil 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2
Spices Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount
antiseptic Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount

In Table 14, examples 37 to 40 comprises a triethanolamine as an amine compound and Example 37 had a 2.0% by weight of triethanol amine content, Example 38 is 3.0% by weight, Example 39 is 10.0% by weight, example 40 is 15.0% by weight. Examples 41 to 44 is 2.0% by weight, include sodium xylene sulfonate, a sulfonic acid-based compound and Example 41 was sodium xylene sulfonate content, and Example 42 is 3.0% by weight, Example 43 is 10.0% by weight and it is, example 44 is 15.0% by weight.

<Evaluation Criteria for Sensory Evaluation>

0: No effect at all, 1: very poor, 2: poor 3: average, 4: Good, 5: Excellent

Test Items Example 20 Example 23 Example 37 Example 38 Example 39 Example 40 Example 41 Example 42 Example 43 Example 44
Shape memory capacity 4.8 4.8 4.7 4.5 3.7 3.2 4.8 4.8 3.8 3.2
Easy to apply 4.3 4.5 3.3 3.7 4.5 4.8 3.2 3.4 4.5 4.7
Easy to take in hand (pick-up force) 4.7 4.6 3.5 3.7 4.0 4.5 3.8 3.9 4.5 4.8
The associated shape aesthetics (natural times the resultant force) 4.5 4.6 3.3 3.4 3.5 3.2 3.4 3.8 3.7 3.5

Table 15 is each rear subjected to a sensory test for Examples 20 and 23 and Examples 37 to ease to 44 the shape memory ability of the coating, taking in hand Easy (pick-up force) and the esthetics of the associated shape (natural times the resultant force) effect scores are average results for the item. Sensory evaluation was to grant 20 to 30 women who were 20 to a consumer to compare the effectiveness of the product, and 6 score of 0-5 points for each item.

As the results in Table 15, the amine-based compound and the sulfone, based on the compound, respectively, the content 2.0% by weight to 15.0% by weight of the shape memory ability, easy to apply, taking in hand Easy (pick-up force) and the esthetics of the associated shape (natural it was confirmed that the effect of rendering the rotation resultant force). In particular, an amine-based compound and a sulfone compound for each of the content to 3.0% by weight to 10.0% by weight while retaining the existing shape memory ability of the coating easy, taking in hand Easy (pick-up force) and the associated shape of aesthetics (natural times the resultant force ) it confirmed the improved-rescue.

Test Example 11: Confirmation content range of cosmetic compositions amine compound and a sulfonic acid compound of the mixture according to the invention Test

To determine the amine-based compound and the content of the mixture range when using a mixture of sulfonic acid-based compounds, it was tested as shown below by changing the amount of tromethamine and phenyl benzimidazole sulphonic Acid mixture (in% by weight). Shape memory polymers are not blood -240 / H DI copolymer bis-decyl tetradecyl the access -20 beomwieul ether content 2.0% by weight was used.

Wonryomyeong Example 45 Example 46 Example 47 Example 48
Purified water To 100 To 100 To 100 To 100
The disodium dt Avon 0.02 0.02 0.02 0.02
Butylene glycol 5.0 5.0 5.0 5.0
Blood not -240 / H DI copolymer bis-decyl tetradecyl ether access -20 2.0 2.0 2.0 2.0
Tromethamine 1.5 3.0 5.0 10
Phenyl benzimidazol sulphonic Acid 1.5 3.0 5.0 10
Fiji blood test section -26- -26 / -40 dihydro jeneyi blood not suited castor oil 0.2 0.2 0.2 0.2
Spices Proper amount Proper amount Proper amount Proper amount
antiseptic Proper amount Proper amount Proper amount Proper amount

In Table 16, Example 45 is an amine-based compound, tromethamine and the sulfonic acid-based compound, phenyl benzamide and imidazole sulfonic Acid content, respectively 1.5% by weight, Example 46 is 3.0% by weight, in Example 47, except that 5.0 wt. %, and example 48 is 10.0% by weight.

<Evaluation Criteria for Sensory Evaluation>

0: No effect at all, 1: very poor, 2: poor 3: average, 4: Good, 5: Excellent

Test Items Example 45 Example 46 Example 47 Example 48
Shape memory capacity 4.5 4.7 4.0 3.4
Easy to apply 3.5 4.5 4.6 4.8
Easy to take in hand (pick-up force) 3.7 4.4 4.7 4.8
The associated shape aesthetics (natural times the resultant force) 3.2 4.6 3.5 3.2

Table 17 is a score average results for each item after subjected to the sensory evaluation for Example 45 to 48 the shape memory ability, easy to apply, the taking in hand Easy (pick-up force) and the esthetics of the associated shape (natural times the resultant force) . Sensory evaluation was to grant 20 to 30 women who were 20 to a consumer to compare the effectiveness of the product, and 6 score of 0-5 points for each item.

Table 17, as a result of the amine-based compound and a sulfone with respect to the mixture of the compounds, the content (wt.%) Easy to 3.0% by weight to 10.0 capability, shape memory both in the case of wt.% Is applied, taking in hand Easy ( it was confirmed that the effect of rendering the pick-up force) and the esthetics of the associated shape (natural times the resultant force). However, when the amine content of the mixture of the compound and a sulfone compound, 20% by weight. Shape memory capacity and meet the aesthetic shape (natural times the resultant force) was determined that this reduction.

Test Example 12: Identification: the mixing ratio of the cosmetic composition amine compound and a sulfonic acid compound of the mixture according to the invention

Amine-based compound and the sulfonic acid type When a mixture of the compound amine in the mixture compound and the sulfonic acid type to determine the mixing ratio of the compound, from 6.0% by weight, the content of the embodiment in the above Test Example 11 The effect was good Example 46 tromethamine and phenyl-benzamide were tested as follows with the contrast already imidazole sulfonic Acid mixing ratio (unit: wt%).

Wonryomyeong Example 46 Example 49 Example 50 Example 51 Example 52
Purified water To 100 To 100 To 100 To 100 To 100
The disodium dt Avon 0.02 0.02 0.02 0.02 0.02
Butylene glycol 5.0 5.0 5.0 5.0 5.0
Blood not -240 / H DI copolymer bis-decyl tetradecyl ether access -20 2.0 2.0 2.0 2.0 2.0
Tromethamine 3.0 4.0 4.5 2.0 1.5
Phenyl benzimidazol sulphonic Acid 3.0 2.0 1.5 4.0 4.5
Fiji blood test section -26- -26 / -40 dihydro jeneyi blood not suited castor oil 0.2 0.2 0.2 0.2 0.2
Spices Proper amount Proper amount Proper amount Proper amount Proper amount
antiseptic Proper amount Proper amount Proper amount Proper amount Proper amount

In Table 18, Example 46 is an amine-based compound, tromethamine and the sulfonic acid-based compound, phenyl benzamide the mixing ratio of the imidazole-sulphonic Acid 1: 1, for example 49 was 2: 1, and Example 50 is 3: 1, and example 51 is 1: 2, and example 52 is 1: 3.

<Evaluation Criteria for Sensory Evaluation>

0: No effect at all, 1: very poor, 2: poor 3: average, 4: Good, 5: Excellent

Test Items Example 46 Example 49 Example 50 Example 51 Example 52
Shape memory capacity 4.6 4.3 4.1 4.8 4.6
Easy to apply 4.4 4.6 4.4 4.7 4.4
Easy to take in hand (pick-up force) 4.5 4.5 4.5 4.5 4.5
The associated shape aesthetics (natural times the resultant force) 4.4 4.2 3.8 4.8 4.3

Table 19 Example 46, the shape-memory of 49 to 51 capacity, easy to apply, taking in hand Easy (pick-up force) and the esthetics of the associated shape (natural times the resultant force) after subjected to the sensory evaluation of the effectiveness score of each item is the average results. Sensory evaluation was to grant 20 to 30 women who were 20 to a consumer to compare the effectiveness of the product, and 6 score of 0-5 points for each item.

As the results in Table 19, with respect to the mixture of the amine-based compound and a sulfone compound, the mixing ratio is 3: 1 to 1: 3 embodiment the shape memory ability in, applying easy, taking in hand Easy (pick-up force) and it was confirmed that the effect of rendering the shape of the associated aesthetics (natural times the resultant force).

Claims (18)

  1. A cosmetic composition having a shape memory ability
  2. According to claim 1,
    Wherein the cosmetic composition comprises: (a) siloxane; And (b) a water-in-oil type cosmetic composition characterized in that it comprises a silicone quaternium.
  3. 3. The method of claim 2,
    Characterized in that the (a) siloxane is cycloalkyl trisiloxane (Cyclotrisiloxane), cyclotetrasiloxane (Cyclotetrasiloxane), Cyclopentasiloxane (Cyclopentasiloxane), cyclohexanone siloxane (Cyclohexasiloxane) and cyclohepta siloxane (Cycloheptasiloxane) 1 or more compound selected from the group consisting of water-in-oil type cosmetic composition as set.
  4. 3. The method of claim 2,
    (B) the silicone is silicone Quaternium polyquaternium -1 (Silicone Quaternium-1), silicone quaternium -3 (Silicone Quaternium-3), silicone quaternium -8 (Silicone Quaternium-8), silicone quaternium-15 ( silicone Quaternium-15), silicone Quaternium -16 (silicone Quaternium-16). Silicone Quaternium -18 (Silicone Quaternium-18), Quaternium -20 silicone water-in-oil type cosmetic composition, characterized in that (Silicone Quaternium-20), and silicone quaternium -22 (Sillicone Quaternium-22) 1 or more compound selected from the group consisting of composition.
  5. 3. The method of claim 2,
    The water-in-oil relative to the total composition weight of the male cosmetic composition (a) is a siloxane water-in-oil type cosmetic composition, characterized in that 1 to 50% by weight, and wherein (b) silicone quaternium is a number ranging from 1 to 20% by weight.
  6. 3. The method of claim 2,
    The water-in-oil type cosmetic composition comprises (a) the siloxane and the (b) silicone quaternium composition ratio is 1: water-in-oil type cosmetic composition, characterized in that 0.02 to 1: 20.
  7. The method according to any one of claims 2 to 6,
    The water-in-oil type cosmetic composition is a water-in-oil type cosmetic composition, characterized in that the immediate skin wrinkles, improving skin elasticity or immediate immediate skin gloss improvement tolerated.
  8. The method according to any one of claims 2 to 6,
    The water-in-oil type cosmetic composition is a water-in-oil type cosmetic composition, characterized in that the skin gloss improvement or increase skin moisture tolerated.
  9. According to claim 1,
    The cosmetic composition
    (A) a shape memory polymer; And
    (B) at least one amine compound-based compound and a sulfonic acid-based compound
    In-water type cosmetic composition comprising: a.
  10. 10. The method of claim 9,
    Wherein the shape memory polymer is a polyurethane -59 (POLYURETHANE-59), blood not -150 / stearyl alcohol / eseuemdi Aiko polymer (PEG-150 / STEARYL ALCOHOL / SMDICOPOLYMER) and not avoid -240 / H DI copolymer / Bis- decyl tetradecyl ether access -20-water type cosmetic composition, characterized in that the (PEG-240 / HDICOPOLYMER / BIS-DECYLTETRADECETH-20ETHER) 1 or more compound selected from the group consisting of.
  11. 10. The method of claim 9,
    The amine compound is triethanolamine (TRIETHANOLAMINE), tromethamine (TROMETHAMINE), ethanolamine (ETHANOLAMINE), stearoyl limiter FIG propyl di methyl amine (STEARAMIDOPROPYL DIMETHYLAMINE), tetra-hydroxypropyl ethylene diamine (TETRAHYDROXYPROPYL ETHYLENEDIAMINE), acetylglucosamine ( ACETYL GLUCOSAMINE) and stearic limiter FIG propyl di methyl amine (in-water type cosmetic composition, characterized in that at least one member selected from the group consisting of STEARAMIDOPROPYL DIMETHYLAMINE).
  12. 10. The method of claim 9,
    The sulfonic acid-based compounds are sodium isopropyl C8-16 alkyl Wuxi City carbonyl lactoglobulin sulfonate (C8-16ISOALKYLSUCCINYL LACTOGLOBULIN SODIUM SULFONATE), sodium xylene sulfonate (SODIUM XYLENESULFONATE), phenyl benzimidazole sulfonic Acid (PHENYLBENZIMIDAZOLE SULFONICACID), di sodium phenyl di benzimidazole tetra sulfonate (dISODIUM PHENYLDIBENZIMIDAZOLE TETRASULFONATE), disodium laureth sulfosuccinate (dISODIUM lAURETH sULFOSUCCINATE), disodium La when pitching lauryl sulfonic carbonate (dISODIUM lAURYL sULFOSUCCINATE), tea yieyi-dodecyl benzene sulfonate carbonate (TEA-DODECYL BENZENESULFONATE), sodium C14-16 olefin sulfonate (C14-16OLEFIN sODIUM sULFONATE), sodium hexane sulfonate (sODIUM HEXANESULFONATE), sodium benzotriazolyl butylphenol sulfonate (bENZOTRIAZOLYL bUTYLPHENOL sODIUM sULFONATE) and poly FIG decane amido having aminium triazol jadi phenyl ethene sulfonate (POLYDODECANAMIDEAMINIUM TRIAZADIPHENYL ETHENESULFONATE) In-water type cosmetic composition, characterized in that at least one member selected from the group consisting of.
  13. 10. The method of claim 9,
    Hardness value of the in-water type cosmetic composition is in-water type cosmetic composition, characterized in that 7.0 g to 10.0 g.
  14. 10. The method of claim 9,
    (B) the amine-based compound and a sulfonic acid-based compound is at least one compound of the in-water type cosmetic composition, characterized in that a mixture of amine compound and a sulfonic acid-based compound.
  15. 10. The method of claim 9,
    The mixture is amine compounds: the sulfonic acid type is the mixing ratio of compound 3: 1 to 1: 1-in-water type cosmetic composition, characterized in that 3.
  16. 10. The method of claim 9,
    The in-water type cosmetic composition comprises (a) a shape memory polymer in-water type cosmetic composition comprising from 0.1% to 5.0% by weight, based on the weight of the total composition.
  17. 10. The method of claim 9,
    The in-water type cosmetic composition comprises (b) an amine-based compound and the sulfonic acid type compound in-water type cosmetic composition characterized in that comprises at least one compound of a weight of 1.0% to 20.0% by weight of the total composition.
  18. A method according to any one of claims 9 to 17,
    The in-water type cosmetic composition is in-water type cosmetic composition, characterized in that the skin defect correction.
PCT/KR2017/000120 2016-01-07 2017-01-05 Cosmetic composition having shape memory ability WO2017119728A1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
KR10-2016-0001917 2016-01-07
KR20160001917 2016-01-07
KR10-2016-0038898 2016-03-31
KR20160038898A KR101814379B1 (en) 2016-03-31 2016-03-31 Oil-In-Water Cosmetic Composition with Shape-Memory Ability

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080145428A1 (en) * 2006-12-18 2008-06-19 Avon Products, Inc. Mascara Composition Containing Shape-Memory Polymers, Gels, and Fibers
US20080311050A1 (en) * 2003-07-30 2008-12-18 Mnemoscience Gmbh Method for Producing Shape Memory Effects in Hair in Connection with Hydrophobic Active Ingredients
KR20120078953A (en) * 2011-01-03 2012-07-11 한국콜마 주식회사 Oil-in-water type foundation composition showing shape-memory phenomenon and manufacturing method thereof
EP2712609A1 (en) * 2012-09-26 2014-04-02 Bayer MaterialScience AG Polyurethane-urea compound for skin and hair cosmetics
WO2015067785A1 (en) * 2013-11-08 2015-05-14 L'oreal Cosmetic compositions comprising spiculisporic acid and at least one sulfate and/or sulfonate surfactant

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080311050A1 (en) * 2003-07-30 2008-12-18 Mnemoscience Gmbh Method for Producing Shape Memory Effects in Hair in Connection with Hydrophobic Active Ingredients
US20080145428A1 (en) * 2006-12-18 2008-06-19 Avon Products, Inc. Mascara Composition Containing Shape-Memory Polymers, Gels, and Fibers
KR20120078953A (en) * 2011-01-03 2012-07-11 한국콜마 주식회사 Oil-in-water type foundation composition showing shape-memory phenomenon and manufacturing method thereof
EP2712609A1 (en) * 2012-09-26 2014-04-02 Bayer MaterialScience AG Polyurethane-urea compound for skin and hair cosmetics
WO2015067785A1 (en) * 2013-11-08 2015-05-14 L'oreal Cosmetic compositions comprising spiculisporic acid and at least one sulfate and/or sulfonate surfactant

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