WO2017110535A1

WO2017110535A1 - Composition providing glow and moisturizing feeling

Info

Publication number: WO2017110535A1
Application number: PCT/JP2016/086832
Authority: WO
Inventors: Mari Suda
Original assignee: L'oreal
Priority date: 2015-12-21
Filing date: 2016-12-06
Publication date: 2017-06-29
Also published as: CN108430441A; JP2017114774A; KR20180081607A; JP7066312B2

Abstract

The present invention relates to a composition comprising: (a) at least one film forming agent; (b) at least one non-volatile hydrocarbon-based oil; and (c) at least one water soluble polyol in an amount of 2 % by weight or more, relative to the total weight of the composition; wherein the composition is anhydrous or contains less than 3% by weight of water and preferably less than 1% by weight of water, relative to the total weight of the composition, and can provide a glow and moisturizing feeling and has simultaneously good transfer resistance property and less color changes after being applied to the skin and the like.

Description

DESCRIPTION

COMPOSITION PROVIDING GLOW AND MOISTURIZING FEELING TECHNICAL FIELD

The present invention relates to a composition, in particular a cosmetic composition, for keratin materials such as the skin, the nails and the scalp, or keratin fibres such as the eyelashes, the eyebrows and the hair.

The composition according to the invention may be a makeup composition or a care composition for keratin materials, in particular for the skin and keratin fibres, and preferably a makeup composition.

BACKGROUND ART

Cosmetic compositions are commonly used to give the skin and the like, and especially the face, an aesthetic color. More and more various properties have been required for cosmetic compositions. For example, generally, when people use a makeup product, they want this product to exhibit, after application, good staying power on keratin materials, in particular the skin and the like, and in particular good resistance to grease and to wear, and advantageously good transfer-free properties. Especially in these days, a cosmetic composition which provides a glow and moisturizing feeling, and simultaneously has a good transfer resistance property and less color changes after being applied to the skin and the like, is required. DISCLOSURE OF INVENTION

An objective of the present invention is to provide a composition which can provide a glow and moisturizing feeling and has simultaneously good transfer resistance property and less color changes after bemg apphed to me skin and the like.

The above objective can be achieved by a composition comprising:

(a) at least one film forming agent;

(b) at least one non-volatile hydrocarbon-based oil; and

(c) at least one water soluble polyol in an amount of 2 % by weight or more, relative to the total weight of the composition;

wherein the composition is anhydrous or contains less than 3% by weight of water and preferably less than 1% by weight of water, relative to the total weight of the composition.

The (a) film forming agent may be hydrocarbon-based resin, preferably hydrocarbon-based indene resin, preferably hydrogenated, preferably derived from the polymerization of indene monomer and of a monomer chosen from styrene, methylindene and methylstyrene, and mixtures thereof.

Preferably the hydrocarbon-based resin may be an indene resin chosen from hydrogenated indene/methylstyrene/styrene copolymers.

It is preferable that the (b) non-volatile hydrocarbon-based oil is chosen from non-volatile apolar hydrocarbon-based oils, preferably chosen from polybutenes, polyisobutenes, hydrogenated polyisobutenes, polydecenes and/or hydrogenated polydecenes, and mixtures thereof. The composition according to the present invention may comprise the (b) non-volatile hydrocarbon- based oil having a viscosity of from 10000 to 100000 mPa.s, preferably from 15000 to 80000 m Pa.s, and more preferably from 20000 to 50000 m Pa.s, preferably in a content of 10% by weight or more, and more preferably 15% by weight or more relative to the total weight of the composition.

The (c) water soluble polyol may be chosen from the group consisting of glycerins and glycols, more preferably propylene glycol, butylene glycol, pentylene glycol, hexylene glycol, dipropylene glycol, diethylene glycol, ethylhexylglycerine, caprylyl glycol, glycol ethers, preferably mono-, di- or tripropylene glycol of alkyl(Ci-C₄)efher or mono-, di- or triethylene glycol of alkyl(Ci-C₄)ether, and mixtures thereof.

The (c) water soluble polyol may be chosen from water soluble polyol having 3 or less carbon atoms, preferably chosen from glycerine, butylene glycol and pentylene glycol. It is preferable that the composition further comprises (d) at least one surfactant, preferably chosen from nonionic surfactants and/or silicone surfactants.

The composition may further comprise (e) at least one lipophilic thickener. The composition may further comprise (f) at least one alcohol, preferably chosen from linear or branched lower monoalcohols which more preferably contain from 2 to 5 carbon atoms, and even more preferably chosen from ethanol, isopropanol, n-propanol and mixtures thereof

The (a) film forming agent may be present in the composition in a content ranging from 0.1 % to 10% by weight, preferably ranging from 1 % to 7% by weight and more preferably ranging from 2% to 5% by weight relative to the total weight of the composition.

The (b) non-volatile hydrocarbon-based oil may be present in the composition according to the present invention in a content ranging from 10% to 70% by weight, preferably ranging from 12% to 50% by weight and more preferably ranging from 14% to 40% by weight relative to the total weight of the composition.

The (c) water soluble polyol may be present in the composition in a content ranging from 2% to 10% by weight, preferably ranging from 2.5 to 7% by weight, and more preferably from 3 to 5% by weight, relative to the total weight of the composition.

BEST MODE FOR CARRYING OUT THE INVENTION

After diligent research, the inventors have discovered that it is possible to provide a composition which can provide a glow and moisturizing feeling and has simultaneously good transfer resistance property and less color changes after being applied to the skin and the like.

Thus, the composition according to the present invention is a composition comprising:

(a) at least one film forming agent;

(b) at least one non-volatile hydrocarbon-based oil; and

wherein the composition is anhydrous or contains less than 3% by weight of water and preferably less than 1 % by weight of water, relative to the total weight of the composition. The term "anhydrous" especially means that water is preferably not deliberately added to the composition, but may be present in trace amount in the various compounds used in the composition.

Hereafter, each of the compositions according to the present invention will be described in a detailed manner

[Film Forming Agent]

The composition of the present invention comprises (a) at least one film forming agent. As used herein, "film forming agent" means an agent which is capable of forming a film upon application to keratin materials and which provides the composition with tackiness and/or characteristics resulting from tackiness.

Suitable film forming agents for use in accordance with the present invention include, but are not limited to, polyorganosiloxane containing polymers such as polysilicone polyamides or polysilicone polyurethanes; silicone resins (preferably, MK or MQ resin), silicone/(meth)acrylate copolymers, acrylates/dimethicone copolymers, liquid siloxy silicates and silicone esters such as those disclosed in U.S. Pat. No. 5,334,737 , the disclosure of which is hereby incorporated by reference, silicone polymers comprising a backbone chosen from vinyl polymers, methacrylic polymers, and acrylic polymers and at least one chain chosen from pendant siloxane groups and pendant fluorochemical groups, such as those disclosed in U.S. Pat. Nos. 5,209,924 and 4,972,037 , and WO 01/32737 , the disclosures of which are hereby incorporated by reference in their entirety, a copolymer chosen from vinyl-silicone graft copolymers such as those polymers described in U.S. Pat. No. 5,468,477 , the entire disclosure of which is hereby incorporated by reference.

Specific examples of suitable film forming agents include, but are not limited to, polymers or copolymers comprising monomers selected from the group consisting of acrylic acid, methacrylic acid, acrylate, methacrylate, acrylamide, and mixtures thereof, such as, for example acrylates copolymers (such as, Covacryl A15 and Covacryl E14 by Wackherr), acrylates/ethylhexyl acrylate copolymers (Daitosol 5000SJ by Daito Kasei), butyl acrylate hydroxypropyl dimethicone acrylate copolymers (Granacrysil BAS by Grant Industries, Inc.), acrylates/ rC^ alkylmethacrylate copolymers (Allianz OPT by ISP), isododecane and acrylates copolymers (Giovarez AC-5099M by Phoenix),

acrylates/octylacrylamide copolymers (Dermacryl-79 by National Starch & Chemical Company), sodium polystyrene sulfonates (Flexan 130 by National Starch & Chemical Company),

acrylamides/DMAPA acrylates/methoxy PEG methacrylate copolymer, acrylamide/sodium acrylate copolymer, acrylamide/sodium acryloyldimethyltaurate copolymer, acrylates/acrylamide copolymer, acrylates/t-butylacrylamide copolymers, acrylates/dimethicone copolymer; acrylates/dimethicone methacrylate/ethylhexyl acrylate copolymer; acrylates/dimemylarninoethyl methacrylate copolymer, acrylates/ethylhexyl acrylate copolymer, acrylates/ethylhexylacrylate/lTEMA/styrene copolymer, acrylates/hydroxyesters acrylates copolymer, acrylates/laurylacrylate/stearyl acrylate/ethylamine oxide methacrylate copolymer, acrylates/octylacrylamide copolymer, acrylates/propyl trimethicone methacrylate copolymer, acrylates/stearyl acrylate/dimethicone methacrylate copolymer, acrylates/VP copolymer, and acrylates/VP/dime1hylaniinoethyl methacrylate/diacetone acrylarnide/hydroxypropyl acrylate copolymer.

Other suitable tackifying agents include, but are not limited to, aliphatic hydrocarbon resins, aromatic modified aliphatic hydrocarbon resins, hydrogenated polycyclopentadiene resins, polycyclopentadiene resins, gum rosins, gum rosin esters, wood rosins, wood rosin esters, tall oil rosins, tall oil rosin esters, polyterpenes, aromatic modified polyterpenes, terpene phenolics, aromatic modified hydrogenated polycyclopentadiene resins, hydrogenated aliphatic resin, hydrogenated aliphatic aromatic resins, hydrogenated terpenes and modified terpenes, hydrogenated rosin acids, hydrogenated rosin esters, polyisoprene, partially or fully hydrogenated polyisoprene, polybutenediene, partially or fully hydrogenated polybutenediene, and the like. In some embodiments, preferably, the film forming agents may be chosen from hydrocarbon-based resins.

Preferably, the hydrocarbon-based resin (also known as a tackifying resin) has a number-average molecular weight of less than or equal to 10 000 g/mol, especially ranging from 250 to 5000 g/mol, better still less than or equal to 2000 g mol and especially ranging from 250 to 2000 g/mol.

The number-average molecular weights (Mn) are determined by gel permeation liquid

chromatography (THF solvent, calibration curve established with linear polystyrene standards, refractometric detector). Unless otherwise described, the molecular weight means number-average molecular weight.

The resin of the composition according to the invention is advantageously a tackifying resin. Such resins are described especially in the Handbook of Pressure Sensitive Adhesive Technology, edited by Donatas Satas, 3rd edition, 1989, pp.

Preferably, the hydrocarbon-based resin is chosen from low molecular weight polymers that may be classified, according to the type of monomer they comprise, as:

indene hydrocarbon-based resins, preferably such as resins derived from the polymerization in major proportion of indene monomer and in minor proportion of a monomer chosen from styrene, methylindene and methylstyrene, and mixtures thereof.

These resins may optionally be hydrogenated. These resins may have a molecular weight ranging from 290 to 1150 g/mol. Examples of indene resins that may be mentioned include those sold under the reference Escorez 7105 by the company Exxon Chem., Nevchem 100 and Nevex 100 by the company Neville Chem., Norsolene SI 05 by the company Sartomer, Picco 6100 by the company Hercules and Resinall by the company Resinall Corp., or the hydrogenated indene/methylstyrene/styrene copolymers sold under the name "Regalite" by the company Eastman Chemical, in particular Regalite Rl 100, Regalite Rl 090, Regalite R7100, Regalite R1010 Hydrocarbon Resin and Regalite Rl 125 Hydrocarbon Resin;

aliphatic pentanediene resins such as those derived from the majority polymerization of the 1,3- pentanediene (trans- or cis-piperylene) monomer and of minor monomers chosen from isoprene, butene, 2-methyl-2-butene, pentene and 1,4- pentanediene, and mixtures thereof. These resins may have a molecular weight ranging from 1000 to 2500 g/mol.

Such 1,3 -pentanediene resins are sold, for example, under the references Piccotac 95 by the company Eastman Chemical, Escorez 1304 by the company Exxon Chemicals, Nevtac 100 by the company Neville Chem. or Wingtack 95 by the company Goodyear;

mixed resins of pentanediene and of indene, which are derived from the polymerization of a mixture of pentanediene and indene monomers such as those described above, for instance the resins sold under the reference Escorez 2101 by the company Exxon Chemicals, Nevpene 9500 by the company Neville Chem., Hercotac 1148 by the company Hercules, Norsolene A 100 by the company Sartomer, and Wingtack 86, Wingtack Extra and Wingtack Plus by the company Goodyear;

diene resins of cyclopentanediene dimers such as those derived from the polymerization of first monomers chosen from indene and styrene, and of second monomers chosen from cyclopentanediene (timers such as dicyclopentadiene, methyldicyclopentanediene and other pentanediene dimers, and mixtures thereof. These resins generally have a molecular weight ranging from 500 to 800 g/mol, for instance those sold under the reference Betaprene BR 100 by the company Arizona Chemical Co., Neville LX-685-125 and Neville LX-1000 by the company Neville Chem., Piccodiene 2215 by the company Hercules, Petro-Rez 200 by the company Lawter or Resinall 760 by the company Resinall Corp.;

diene resins of isoprene dimers such as terpenic resins derived from the polymerization of at least one monomer chosen from a-pinene, β-pinene and limonene, and mixtures thereof. These resins can have a molecular weight ranging from 300 to 2000 g/mol. Such resins are sold, for example, under the names Piccolyte Al 15 and SI 25 by the company Hercules or Zonarez 7100 or Zonatac 105 Lite by the company Arizona Chem.

Mention may also be made of certain modified resins such as hydrogenated resins, for instance those sold under the name Eastotac C6-C20 Polyolefin by the company Eastman Chemical Co., under the reference Escorez 5300 by the company Exxon Chemicals, or the resins Nevillac Hard or Nevroz sold by the company Neville Chem., the resins Piccofyn A- 100, Piccotex 100 or Piccovar AP25 sold by the company Hercules or the resin SP-553 sold by the company Schenectady Chemical Co.

According to one preferred embodiment, the hydrocarbon-based resin is chosen from indene hydrocarbon-based resins, aliphatic pentadiene resins, mixed resins of pentanediene and of indene, diene resins of cyclopentanediene dimers and diene resins of isoprene dimers, or mixtures thereof. Preferably, the composition comprises at least one compound chosen from hydrocarbon- based resins as described previously, especially indene hydrocarbon-based resins and aliphatic pentadiene resins, or mixtures thereof. According to one preferred embodiment, the hydrocarbon- based resin is chosen from indene hydrocarbon-based resins.

It is preferable that the (a) film forming agent may be hydrocarbon-based indene resin, preferably hydrogenated, preferably derived from the polymerization of indene monomer and of a monomer chosen from styrene, methylindene and methylstyrene, and mixtures thereof.

According to one preferred embodiment, the resin is chosen from indene/methylstyrene/hydrogenated styrene copolymers.

In particular, use may be made of indene/methylstyrene/hydrogenated styrene copolymers, such as those sold under the name Regalite by the company Eastman Chemical, such as Regalite R 1100, Regalite R 1090, Regalite R-7100, Regalite R 1010 Hydrocarbon Resin and Regalite R 1125

Hydrocarbon Resin.

In other embodiments, the film forming agent can further comprise a copolymer comprising at least one styrene block. For example, a triblock copolymer and in particular those of the

polystyrene/polyisoprene or polystyrene/ polybutadiene type, such as those sold or made under the name "Luvitol HSB" by BASF and those of the polystyrene/copoly(ethylene-propylene) type or alternatively of the polystyrene/copoly(ethylene^tylene) type, such as those sold or made under the brand name "Kraton" by Shell Chemical Co. or Gelled Permethyl 99A by Penreco, may be used. Styrene-methacrylate copolymers can be used.

More specifically, mention may be made, for example, of Kraton (Gl 650 (SEBS), Kraton Gl 651 (SEBS), Kraton G1652 (SEBS), Kraton G1657X (SEBS), Kraton G1701X (SEP), Kraton G1702X (SEP), Kraton G1726X (SEB), Kraton G1750X (EP) multiarm, Kraton G1765X (EP) multiarm, Kraton D-l 101 (SBS), Kraton D-l 102 (SBS), Kraton D-l 107 (SIS), Gelled Permethyl 99A - 750, Gelled Permethyl 99A- 753-58 (mixture of starburst block polymer and triblock polymer), Gelled Permethyl 99A- 753-59 (mixture of starburst block polymer and triblock polymer), Versagel 5970 and Versagel 5960 from Penreco (mixture of starburst polymer and triblock polymer in isododecane), and OS 129880, OS 129881 and OS 84383 from Lubrizol (styrene-methacrylate copolymer).

Preferably, the (a) film forming agent is present in the composition according to the invention in a content ranging from 0.1 % to 10% by weight, preferably ranging from 1 % to 7% by weight and more preferably ranging from 2% to 5% by weight relative to the total weight of the composition. [Non-volatile Hydrocarbon-based Oil]

The composition according to the invention comprises (b) at least one non-volatile hydrocarbon-based oil. The term "oil" means a water-immiscible non-aqueous compound that is liquid at room temperature (25°C) and at atmospheric pressure (760 mmHg).

The term "hydrocarbon-based oil" means an oil formed essentially from, or even constituted by, carbon and hydrogen atoms, and possibly oxygen and nitrogen atoms, and not containing any silicon or fluorine atoms. It may contain alcohol, ester, ether, carboxylic acid, amine and/or amide groups.

The term "non-volatile" oil refers to an oil for which the vapor pressure at room temperature and atmospheric pressure is non-zero and less than 0.02 mmHg (2.66 Pa) and better still less than 10^" ³mmHg (0.13 Pa).

The non-volatile hydrocarbon-based oils may be of vegetable origin, oils of synthetic or mineral origin, or mixtures thereof.

(Apolar oils)

According to a first embodiment, the said non- volatile hydrocarbon-based oil may be an apolar oil.

These oils may be of vegetable, mineral or synthetic origin. For the purposes of the present invention, the term "apolar oil" means an oil whose solubility parameter at 25°C, 5 a, is equal to 0 (J/cm³)^{1 2}-

The definition and calculation of the solubility parameters in the Hansen three-dimensional solubility space are described in the paper by CM. Hansen: "The three-dimensional solubility parameters", J. Paint Technol., 39, 105 (1967).

According to this Hansen space:

- 6D characterizes the London dispersion forces derived from the formation of dipoles induced during molecular impacts;

- δ_ρ characterizes the Debye interaction forces between permanent dipoles and also the Keesom interaction forces between induced dipoles and permanent dipoles;

-5_h characterizes the specific interaction forces (such as hydrogen bonding, acid/base, donor/acceptor,

The parameters δ_ρ, _h, δο and 8_a are expressed in (J/cm ) .

Preferably, the non-volatile apolar hydrocarbon-based oil may be chosen from linear or branched hydrocarbons of mineral or synthetic origin, such as:

- liquid paraffin or derivatives thereof,

- squalane,

- isoeicosane,

- naphthalene oil,

- polybutylenes such as Indopol H-100 (molar mass or MW = 965 g/mol), Indopol H-300 (MW = 1340 g/mol) and Indopol H-1500 (MW = 2160 g/mol) sold or manufactured by the company Amoco,

- polyisobutenes,

- hydrogenated polyisobutylenes such as Parleam® sold by the company Nippon Oil Fats, Panalane H- 300 E sold or manufactured by the company Amoco (MW = 1340 g/mol), Viseal 20000 sold or manufactured by the company Synteal (MW = 6000 g/mol) and Rewopal PEB 1000 sold or manufactured by the company Witco (MW = 1000 g/mol), or alternatively Parleam Lite sold by NOF Corporation,

- decene/butene copolymers, polybutene/polyisobutene copolymers, especially Indopol L-14,

- polydecenes and hydrogenated polydecenes such as: Puresyn 10 (MW = 723 g/mol) and Puresyn 150 (MW = 9200 g/mol) sold or manufactured by the company Mobil Chemicals, or alternatively Puresyn 6 sold by ExxonMobil Chemical),

- and their mixtures.

(Polar oils) The (b) non-volatile hydrocarbon-based oil may be a polar hydrocarbon-based oil. These oils may be of vegetable, mineral or synthetic origin.

Within the meaning of the present invention, the term "polar oil" means an oil for which the solubility parameter at 25°C, 5 a, is other than 0 (J/cm³)^{1 2}.

In particular, the hydrocarbon-based non- volatile polar oil may be chosen from the list of oils below, and mixtures thereof:

- hydrocarbon vegetable oils such as liquid triglycerides of fatty acids containing from 4 to 10 carbon atoms, for instance heptanoic or octanoic acid triglycerides or jojoba oil;

- ester oils, preferably chosen from:

- fatty acid esters, in particular of 4 to 22 carbon atoms, and especially of octanoic acid, heptanoic acid, lanolic acid, oleic acid, lauric acid or stearic acid, for instance propylene glycol dioctanoate, propylene glycol monoisostearate or neopentyl glycol diheptanoate;

- synthetic esters, for instance the oils of formula R₁COOR₂ in which R represents a linear or branched fatty acid residue comprising from 4 to 40 carbon atoms and R₂ represents a hydrocarbon-based chain, which is especially branched, containing from 4 to 40 carbon atoms, on condition that Ri + R₂> 16, for instance purcellin oil (cetostearyl octanoate), isononyl isononanoate, Ci₂to ¾ alkyl benzoate, 2- ethylhexyl palmitate, ethylhexyl methoxycinnamate (as sold under the trade reference Persol® MCX by the company DSM), octyldodecyl neopentanoate, 2-octyldodecyl stearate, 2-octyldodecyl erucate, oleyl erucate, isostearyl isostearate, 2-octyldodecyl benzoate, alcohol or polyalcohol octanoates, decanoates or ricinoleates, isopropyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, 2- ethylhexyl palmitate, 2-hexyldecyl laurate, 2-octyldecyl palmitate, 2-octyldodecyl myristate or 2- diethylhexyl succinate; preferably, the preferred synthetic esters RtCOC^ in which Ri represents a linear or branched fatty acid residue comprising from 4 to 40 carbon atoms and R2 represents a hydrocarbon-based chain, which is especially branched, containing from 4 to 40 carbon atoms are such that Ri and R2 > 20;

- linear fatty acid esters with a total carbon number ranging from 35 to 70, for instance pentaerythrityl tetrapelargonate (MW = 697 g mol);

- glyceryl esters such as the caprylic/capric glyceride sold under the reference Capmul MCM by the company Abitec;

- hydroxylated esters, preferably with a total carbon number ranging from 35 to 70, for instance polyglyceryl-2 triisostearate (MW = 965 g/mol), isostearyl lactate, octyl hydroxystearate, octyldodecyl hydroxystearate, diisostearyl malate, glyceryl stearate; diethylene glycol diisononanoate;

- esters of aromatic acids and of alcohols comprising 4 to 22 atoms, such as tridecyl trimellitate (MW = 757 g/mol);

- C₂₄-C₂₈ esters of branched fatty alcohols or fatty acids such as those described in patent application EP-A-0955 039, and especially triisoarachidyl citrate (MW = 1033.76 g/mol), pentaerythrityl tetraisononanoate (MW = 697 g/mol), glyceryl triisostearate (MM = 891 g/mol), glyceryl tris(2- decyl)tetradecanoate (MW = 1143 g/mol), pentaerythrityl tetraisostearate (MW = 1202 g/mol), polyglyceryl-2 tetraisostearate (MW = 1232 g/mol) or pentaerythrityl tetrakis(2-decyl)tetradecanoate (MW= 1538 g/mol),

- polyesters resulting from the esterification of at least one hydroxylated carboxylic acid triglyceride with an aliphatic monocarboxylic acid and with an aliphatic dicarboxylic acid, which is optionally unsaturated, for instance the succinic acid and isostearic acid castor oil sold under the reference Zenigloss by Zenitech;

- esters of a diol dimer and of a diacid dimer of general formula HO-R^-OCO-R^COO-R'- OH, in which:

R¹ represents a diol dimer residue obtained by hydrogenation of dilinoleic diacid,

R² represents a hydrogenated dilinoleic diacid residue, and

h represents an integer ranging from 1 to 9,

especially the esters of dilinoleic diacids and of dilinoleyl diol dimers sold by the company Nippon Fine Chemical under the trade names Lusplan DD-DA5® and DD-DA7®,

- polyesters obtained by condensation of an unsaturated fatty acid dimer and/or trimer and of diol, such as those described in patent application FR 0 853 634, in particular such as dilinoleic acid and 1 ,4- butanediol. Mention may especially be made in this respect of the polymer sold by Biosynthis under the name Viscoplast 14436H (INCI name: dilinoleic acid/butanediol copolymer), or copolymers of polyols and of diacid dimers, and esters thereof, such as Hailuscent ISDA;

- fatty alcohols containing from 12 to 26 carbon atoms, which are preferably branched, for instance octyldodecanol, 2-butyloctanol, 2-hexyldecanol, 2-undecylpentadecanol and oleyl alcohol;

- C^ higher fatty acids, such as oleic acid, linoleic acid and linolenic acid, and mixtures thereof;

- oils of plant origin such as sesame oil (820.6 g/mol); and the Q₈-C₃₆ acid triglyceride (Dub TGI 24 from Stearineries Dubois);

- fatty acids containing from 12 to 26 carbon atoms, for instance oleic acid;

- dialkyl carbonates, the two alkyl chains possibly being identical or different, such as dicaprylyl carbonate sold under the name Cetiol CC by Cognis; and

- vinylpyrrolidone copolymers such as the vinylpyrrolidone l-hexadecene copolymer, Antaron V-216 sold or manufactured by the company ISP (MW = 7300 g/mol). Preferably, the said non-volatile hydrocarbon-based oil present in the composition is chosen from: -hydrocarbon-based oils, preferably chosen from apolar hydrocarbon-based oils such as polybutenes, polyisobutenes, hydrogenated polyisobutenes, polydecenes and/or hydrogenated polydecenes, and mixtures thereof, and polar hydrocarbon-based oils, preferably chosen from hydrocarbon-based oils from plants or of plant origin, ester oils, fatty alcohols containing from 12 to 26 carbon atoms, fatty acids containing from 12 to 26 carbon atoms and vinylpyrrolidone copolymers, and mixtures thereof, and mixtures thereof.

Preferably, the (b) non-volatile hydrocarbon-based oil may be present in the composition according to the invention in a content ranging from 10% to 70% by weight, preferably ranging from 12% to 50% by weight and more preferably ranging from 14% to 40% by weight relative to the total weight of the composition.

Preferably the composition comprises the (b) non-volatile hydrocarbon-based oil having a viscosity from lOOOO to 100000 mPa.s, preferably from 15000 to 80000 m Pa.s, more preferably from 20000 to 50000 m Pas, preferably in a content of 10% by weight or more, more preferably 15% by weight or more relative to the total weight of the composition. The viscosity is measured at 25°C with a Haake Rheostress RS 150 instrument in flat-cone configuration. [Water Soluble Polyol]

The composition of the present invention may further contain (c) at least one water soluble polyol. A single type of polyol may be used, but two or more different types of polyol may be used in combination.

The term "polyol" here means an alcohol having two or more hydroxy groups, and does not encompass a saccharide or a derivative thereof. The derivative of a saccharide includes a sugar alcohol which is obtained by reducing one or more carbonyl groups of a saccharide, as well as a saccharide or a sugar alcohol in which the hydrogen atom or atoms in one or more hydroxy groups thereof has or have been replaced with at least one substituent such as an alkyl group, a hydroxyalkyl group, an alkoxy group, an acylgroup or a carbonyl group.

The polyol may be a C₂-C₁₂ polyol, preferably a C2-C9 polyol, containing at least 2 hydroxy groups, and preferably 2 to 5 hydroxy groups.

The polyol may be a natural or synthetic polyol. The polyol may have a linear, branched or cyclic molecular structure.

The polyol may be selected from the group consisting of glycerins and glycols, more preferably propylene glycol, butylene glycol, pentylene glycol, hexylene glycol, dipropylene glycol, diethylene glycol, ethylhexylglycerine, caprylyl glycol, glycol ethers, preferably mono-, di- or tripropylene glycol of alky^CrG ether or mono-, di- or Methylene glycol of alkyl(Ci-C₄)ether, and mixtures thereof.

Preferably, the (c) water soluble polyol is chosen from water soluble polyol having 3 or less carbon atoms, preferably chosen from glycerine, butylene glycol and pentylene glycol.

The polyol may be present in an amount ranging from 2% to 10% by weight, and preferably from 2.5%) to 7%) by weight, such as from 3% to 5% by weight, relative to the total weight of the composition.

[Surfactant]

Optionally, the composition of the present invention may further include at least one (d) surfactant; Preferably, the (d) surfactant may be chosen from nonionic surfactants and polyether-modified silicones.

(Nonionic Surfactant)

The composition comprises at least one nonionic surfactant. Two or more nonionic surfactants may be used in combination.

The nonionic surfactants are compounds well known in themselves (see, e.g., in this regard,

"Handbook of Surfactants" by M. R. Porter, Blackie & Son publishers (Glasgow and London), 1991, pp. 116-178). Thus, they can, for example, be chosen from alcohols, alpha-diols, alkylphenols and esters of fatty acids, these compounds being ethoxylated, propoxylated or glycerolated and having at least one fatty chain comprising, for example, from 8 to 30 carbon atoms, it being possible for the number of ethylene oxide or propylene oxide groups to range from 2 to 50, and for the number of glycerol groups to range from 1 to 30. Maltose derivatives may also be mentioned. Non-limiting mention may also be made of copolymers of ethylene oxide and/or of propylene oxide; condensates of ethylene oxide and/or of propylene oxide with fatty alcohols; polyethoxylated fatty amides comprising, for example, from 2 to 30 mol of ethylene oxide; polyglycerolated fatty amides comprising, for example, from 1.5 to 5 glycerol groups, such as from 1.5 to 4; ethoxylated fatty acid esters of sorbitan comprising from 2 to 30 mol of ethylene oxide; ethoxylated oils of plant origin; fatty acid esters of sucrose; fatty acid esters of polyethylene glycol; polyethoxylated fatty acid mono or diesters of glycerol (C₆-C₂₄)alkylpolyglycosides; N-(C₆-C₂₄)alkylglucamine derivatives; amine oxides such as (Cio-C₁4)alkylamine oxides or N-(C_l0-Cl4)acylaminopro y]mo holine oxides; silicone surfactants; and mixtures thereof.

Preferably, the nonionic surfactant may be chosen from lipophilic nonionic surfactants.

Lipophilic nonionic surfactants can be exenplified as sorbitan fatty acid esters such as sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbtian trioleate, diglycerol sorbitan penta-2-ethylhexanoate, and diglycerol sorbitan tetra-2-ethylhexanoate; glycerin polyglycerin fatty acids such as mono-cottonseed oil fatty acid glycerin, monoerucic acid glycerol, sesquioleic acid glycerol, glyceryl monostearate, α,α'- glyceryl oleate pyroglutamate, and glyceryl monostearate malate; propylene glycol fatty acid esters such as propylene glycol monostearate; as well as hardened castor oil derivates, glyceryl alkyl ethers, and polyoxyethylene methylpolysiloxane copolymers.

The HLB of the nonionic surfactant(s) is preferably lower than 12, more preferably lower than 10, and even more preferably lower than 8. If two or more nonionic surfactants are used, the HLB value is determined by the weight average of the HLB values of all the nonionic surfactants. The HLB is the ratio between the hydrophilic part and the lipophilic part in the molecule. This term HLB is well known to those skilled in the art and is described in "The HLB system. A time-saving guide to emulsifier selection" (published by ICI Americas Inc., 1984).

(Polyether-modified Silicone)

The hydrophilic groups of the polyether-modified silicone may preferably be chosen from

polyoxyethylene (POE) or polyoxypropylene (POP).

Preferably, polyether-modified silicone may be chosen from PEG- 10 Dimethicone, PEG-9 polydimethylsiloxyethyl dimethicone, cetyl dimethicone copolyol, lauryl PEG-9 polydimethylsiloxyethyl dimethicone, PEG / PPG-19/19 Dimethicone, (dimethicone / (PEG-10 / 15)) cross polymer, poly-silicone -13, and the like.

The surfactant may be present in an amount ranging from 0.1% to 10% by weight, and preferably from 1 % to 7% by weight, such as from 2% to 5% by weight, relative to the total weight of the composition.

[Lipophilic Thickener]

Optionally, the composition according to the present invention may further includes at least one (e) lipophilic thickener. Two or more lipophilic thickeners may be used in combination. A lipophilic thickener may be inorganic or organic. The lipophilic thickener can thicken the (a) oil of the composition according to the present invention.

The term "lipophilic thickener" means an agent, inorganic or organic, in a particulate form or not, able to gelling the oils of the composition.

The term "particulate lipophilic thickener" means a lipophilic thickener in the form of particles or of crystals (particulate or crystalline). The composition according to the invention comprises at least one lipophilic thickener which is preferably particulate.

The lipophilic thickener according to the invention may be chosen from:

- organomodified clays, which are clays treated with compounds chosen especially from quaternary amines and tertiary amines. Organomodified clays that may be mentioned include organomodified bentonites, such as the product sold under the name Bentone 34 by the company Rheox, and organomodified hectorites such as the products sold under the names Bentone 27 and Bentone 38 by the company Rheox. Mention may be made especially of modified clays such as modified magnesium silicate (Bentone gel^® VS38 from Rheox), modified hectorites such as hectorite modified with a CIO to C22 fatty acid ammonium chloride, for instance hectorite modified with distearyldimethylammonium chloride (disteardimonium hectorite) such as the product sold under the name Bentone 38VCG by the company Elementis or the product sold under the name Bentone 38 CE by the company Rheox, or the product sold under the name Bentone Gel^® V5 5V by the company Elementis, or the product sold under the name Bentone gel^® ISD V by the company Elementis;

- hydrophobic fumed silicas, which may be obtained by modification of the surface of the silica via a chemical reaction that generates a reduction in the number of silanol groups, these groups possibly being substituted especially with hydrophobic groups. The hydrophobic groups can be

trimethylsiloxyl groups, which are obtained especially by treating fumed silica in the presence of hexamethyldisilazane. Silicas thus treated are known as "Silica silylate" according to the CTFA (6th edition, 1995). They are sold, for example, under the references Aerosil R812^® by the company Degussa and Cab-O-Sil TS-530^® by the company Cabot. The hydrophobic groups can be

dimethylsilyloxyl or polydimethylsiloxane groups, which are obtained especially by treating fumed silica in the presence of polydimethylsiloxane or dimethyldichlorosilane. Silicas thus treated are known as "Silica dimethyl silylate" according to the CTFA (6th edition, 1995). They are sold, for example, under the references Aerosil R972^® and Aerosil R974^® by the company Degussa and Cab- O-Sil TS-610^® and Cab-O-Sil TS-720^® by the company Cabot.

- hydrophobic silica aerogels, such as the products sold under the name VM-2260 (ESTCI name: Silica silylate) by the company Dow Corning, the particles of which have a mean size of about 1000 microns and a specific surface area per unit of mass ranging from 600 to 800 m²/g; mention may also be made of the aerogels sold by the company Cabot under the references Aerogel TLD 201 , Aerogel OGD 201, Aerogel TLD 203, Enova^® Aerogel MT 1 100, Enova Aerogel MT 1200;

- and mixtures thereof. In particular, a composition according to the invention is characterized in that the (e) lipophilic thickener is chosen from organomodified clays, in particular organomodified bentonites and organomodified hectorites and mixtures thereof. As the organomodified clay, mention may be made of disteardimonium hectorite. It is preferable that the (e) lipophilic thickener is an organomodified clay which has been modified with quaternary amines or tertiary amines.

The amount of the (e) lipophilic thickener may be present in the composition in a content ranging from 0.01% to 15% by weight, preferably ranging from 0.1% to 10% by weight, and more preferably from 1 to 5% by weight, relative to the total weight of the composition.

[Alcohol]

Optionally, the composition of the present invention may further include at least one (f) alcohol.

Preferably the (f) alcohol may be chosen from linear or branched lower monoalcohols which more preferably contain from 2 to 5 carbon atoms. Even more preferably the (f) alcohol may be chosen from ethanol, isopropanol, n-propanol and mixtures thereof. The (f) alcohol may be present in the composition in a content ranging from 0.01% to 10% by weight, preferably ranging from 0.1% to 5% by weight, and more preferably from 0.5 to 3% by weight, relative to the total weight of the composition.

[Pasty Fatty Substance]

Optionally, the composition of the present invention may further include at least one pasty fatty substance.

For the purposes of the present invention, the term "pasty fatty substance" is intended to denote a lipophilic fatty compound that undergoes a reversible solid/liquid change of state, exhibiting anisotropic crystal organization in the solid state, and that comprises, at a temperature of 23 °C, a liquid fraction and a solid fraction.

In other words, the starting melting point of the pasty fatty substance can be less than 23°C. The liquid fraction of the pasty fatty substance, measured at 23 °C, can represent from 9% to 97%) by weight of the pasty fatty substance. This liquid fraction at 23 °C preferably represents between 15%> and 85%> and more preferably between 40% and 85% by weight.

For the purposes of the invention, the melting point corresponds to the temperature of the most endothermic peak observed in thermal analysis (DSC) as described in the standard ISO 11357-3 ; 1999. The melting point of a pasty fatty substance can be measured using a differential scanning calorimeter (DSC), for example the calorimeter sold under the name MDSC 2920 by TA Instruments.

The measurement protocol is as follows: A sample of 5 mg of pasty fatty substance placed in a crucible is subjected to a first temperature rise ranging from -20°C to 100°C, at a heating rate of 10°C/minute, is then cooled from 100°C to -20°C at a cooling rate of 10°C/minute and is finally subjected to a second temperature rise ranging from -20°C to 100°C at a heating rate of 5°C/minute. During the second temperature rise, the variation in the difference in power absorbed by the empty crucible and by the crucible containing the sample of pasty fatty substance is measured as a function of the temperature. The melting point of the pasty fatty substance is the value of the temperature corresponding to the top of the peak of the curve representing the variation in the difference in power absorbed as a function of the temperature. The liquid fraction by weight of the pasty fatty substance at 23 °C is equal to the ratio of the heat of fusion consumed at 23 °C to the heat of fusion of the pasty fatty substance.

The heat of fusion of the pasty fatty substance is the heat consumed by the latter in order to pass from the solid state to the liquid state. The pasty fatty substance is said to be in the solid state when all of its mass is in crystalline solid form. The pasty fatty substance is said to be in the liquid state when all of its mass is in liquid form.

The enthalpy of fusion of the pasty fatty substance is equal to the area under the curve of the thermogram obtained using a differential scanning calorimeter (DSC), such as the calorimeter sold under the name MDSC 2920 by the company TA Instrument, with a temperature rise of 5°C or 10°C per minute, according to Standard ISO 11357-3; 1999.

The heat of fusion of the pasty fatty substance is the amount of energy required to make the pasty fatty substance change from the solid state to the liquid state. It is expressed in J/g.

The heat of fusion consumed at 23 °C is the amount of energy absorbed by the sample to change from the solid state to the state which it exhibits at 23 °C, consisting of a liquid fraction and a solid fraction.

The liquid fraction of the pasty fatty substance measured at 32°C preferably represents from 30%) to 100%) by weight of the pasty fatty substance, preferably from 50% to 100%), more preferably from 60%> to 100%)) by weight of the pasty fatty substance. When the liquid fraction of the pasty fatty substance measured at 32°C is equal to 100%), the temperature of the end of the melting range of the pasty fatty substance is less than or equal to 32°C. The liquid fraction of the pasty fatty substance measured at 32°C is equal to the ratio of the heat of fusion consumed at 32°C to the heat of fusion of the pasty fatty substance. The heat of fusion consumed at 32°C is calculated in the same way as the heat of fusion consumed at 23°C.

The pasty fatty substance may in particular be chosen from synthetic fatty substances and fatty substances of vegetable origin. A pasty fatty substance may be obtained by synthesis from starting materials of plant origin.

The pasty fatty substance may be chosen from:

- lanolin and its derivatives,

- petroleum j elly (also known as petrolatum),

- polyol ethers chosen from polyalkylene glycol pentaeiythrityl ethers, fatty alcohol ethers of sugars, and mixtures thereof, the polyethylene glycol pentaerythrityl ether comprising five oxy ethylene (5 OE) units (CTFA name: PEG-5 Pentaerythrityl Ether), the polypropylene glycol pentaerythrityl ether comprising 5 oxypropylene (5 OP) units (CTFA name: PPG-5 Pentaerythrityl Ether), and mixtures thereof, and more especially the PEG-5 Pentaerythrityl Ether, PPG-5 Pentaerythrityl Ether and soybean oil mixture, sold under the name Lanolide by Vevy, in which mixture the constituents are in a 46/46/8 ratio by weight: 46% PEG-5 Pentaerythrityl Ether, 46% PPG-5 Pentaerythrityl Ether and 8% soybean oil,

- polymeric or nonpolymeric silicone compounds,

- polymeric or nonpolymeric fluorinated compounds,

- vinyl polymers, in particular:

olefin homopolymers and copolymers,

hydrogenated diene homopolymers and copolymers,

linear or branched oligomers, which are homopolymers or copolymers of alkyl (meth)acrylates preferably containing a C8-C30 alkyl group,

oligomers, which are homopolymers and copolymers of vinyl esters containing C8-C30 alkyl groups, and

oligomers, which are homopolymers and copolymers of vinyl ethers containing C8-C30 alkyl groups,

- fat-soluble polyethers resulting from the polyetherification between one or more C2-C 100 and preferably C2-C50 diols,

- esters,

- and/or mixtures thereof.

Among the fat-soluble polyethers that are particularly considered are copolymers of ethylene oxide and/or of propylene oxide with long-chain C6-C30 alkylene oxides, more preferably such that the weight ratio of the ethylene oxide and or propylene oxide to alkylene oxides in the copolymer is from 5:95 to 70:30. In this family, mention will be made especially of copolymers such that the long-chain alkylene oxides are arranged in blocks having an average molecular weight from 1000 to 10 000, for example a polyoxyethylene/polydodecyl glycol block copolymer such as the ethers of dodecanediol (22 mol) and of polyethylene glycol (45 OE) sold under the brand name Elfacos ST9 by Akzo Nobel.

Among the esters, the following are especially considered:

- esters of an oligomeric glycerol, especially diglycerol esters, in particular condensates of adipic acid and of glycerol, for which some of the hydroxyl groups of the glycerols have reacted with a mixture of fatty acids such as stearic acid, capric acid and isostearic acid, and 12- hydroxystearic acid, for instance bis(diglyceryl) poly(2-acyladipate) sold under the reference Softisan^® 649 by the company Sasol,

- vinyl ester homopolymers containing C8-C30 alkyl groups, such as polyvinyl laurate (sold especially under the reference Mexomer PP by the company Chimex),

- arachidyl propionate, sold under the brand name Waxenol 801 by Alzo,

- phytosterol esters,

- fatty acid triglycerides and their derivatives,

- pentaerythritol esters,

- esters of a diol dimer and of a diacid dimer, where appropriate esterified on their free alcohol or acid functional group(s) with acid or alcohol radicals, especially dimer dilinoleate esters; such esters may be chosen especially from the esters having the following ESfCI nomenclature: Bis- Behenyl/Isostearyl/Phytosteryl Dimer Dilinoleyl Dimer Dilinoleate (Plandool G),

Phytosteryl/Isostearyl/Cetyl Stearyl/Behenyl Dimer Dilinoleate (Plandool H or Plandool S), and mixtures thereof,

- mango butter, such as the product sold under the reference Lipex 203 by the company

AarhusKarlshamn,

- hydrogenated soybean oil, hydrogenated coconut oil, hydrogenated rapeseed oil or mixtures of hydrogenated vegetable oils, such as the soybean, coconut, palm and rapeseed hydrogenated vegetable oil mixture, for example the mixture sold under the reference Akogel <®>by AarhusKarlshamn (INCI name: Hydrogenated Vegetable Oil), - shea butter, in particular that having the I CI name Butyrospermum Parkii Butter, such as that sold under the reference Sheasoft <®>by AarhusKarlshamn,

- and mixtures thereof. According to a preferred embodiment, the pasty fatty substance is chosen from esters and in particular esters of a diol dimer and of a diacid dimer.

Among the pasty compounds, bis-behenyl/isostearyl/phytosteryl dimer dilinoleyl, bis(diglyceryl) poly(2-acyladipate), hydrogenated castor oil dimer dilinoleate, for example Risocast DA-L sold by Kokyu Alcohol Kogyo, and hydrogenated castor oil isostearate, for example Salacos HCIS (V -L) sold by Nisshin Oil, polyvinyl laurate, mango butter, shea butter, hydrogenated soybean oil, hydrogenated coconut oil, hydrogenated rape seed oil and vinylpyrrolidone/eicosene copolymers, or a mixture thereof, will preferably be chosen. The pasty fatty substance may be present in the composition in a content ranging from 0.01 % to 10% by weight, preferably ranging from 0.1% to 5% by weight, and more preferably from 0.5 to 3% by weight, relative to the total weight of the composition.

[Silicone Oil]

Optionally, the composition of the present invention may further include at least one silicone oil, preferably at least on non-volatile silicone oil.

The non-volatile silicone oil that may be used in the invention may be chosen especially from silicone oils especially with a viscosity at 25°C of greater than or equal to 9 centistokes (cSt) (9 x 1 OVW/s) and less than 800000 cSt, preferably between 50 and 600000 cSt and preferably between 100 and 500000 cSt. The viscosity of this silicone may be measured according to standard ASTM D-445.

In particular, the non- volatile silicone oil may be chosen from:

- linear or branched non-volatile polydimethylsiloxanes (PDMS);

- polydimethylsiloxanes comprising alkyl, alkoxy or phenyl groups, which are pendent or at the end of the silicone chain, these groups containing from 2 to 24 carbon atoms, for instance the cetyl dimethicone sold under the reference Abil Wax 9801 by Evonik Goldschmidt;

- phenyl silicone oils, in particular chosen from:

- phenyl trimethicones, especially such as phenyl trimethylsiloxy trisiloxane, sold especially under the reference Dow Corning 556 Cosmetic Grade Fluid;

- phenyl dimethicones;

- phenyl trimethylsiloxy diphenylsiloxanes;

- diphenyl dimethicones;

- diphenyl methyldiphenyl trisiloxanes;

- 2-phenylethyl trimethylsiloxysilicates; and

- trimethyl pentaphenyl trisiloxane, especially such as the silicone oil sold by Dow

Corning under the reference PH-1555 HRI or Dow Corning 555 Cosmetic Fluid (chemical name: l,3,5-trimethyR,l,3,5,5-pentaphenyl trisiloxane; F CI name: trimethyl pentaphenyl trisiloxane); and

- trimethyl siloxyphenyl dimethicones, especially such as the product sold under the reference Belsil PDM 1000 by the company Wacker.

[Other Optional Ingredients] The composition according to the present invention may also comprise one or more standard cosmetic adjuvants chosen from, for example, fillers, softeners, humectants, oils, opacifiers, stabilizers, emollients, silicones, antifoams, fragrances, preserving agents, surfactants, active agents, coloring agents, cationic polymers, propellants, or any other ingredient usually used in cosmetics and/or dermatology.

Needless to say, a person skilled in the art will take care to select the optional adjuvant(s) added to the composition according to the present invention such that the advantageous properties mtrinsically associated with the composition according to the invention are not, or are not substantially, adversely affected by the envisaged addition.

The composition according to the present invention may preferably be used as a cosmetic composition. In particular, the composition according to the present invention may be intended for application onto the skin, scalp and/or lips, preferably the skin, and in particular the skin around eyes. Thus, the composition according to the present invention can be used for a cosmetic process for the skin.

The cosmetic composition may be a skin care or skin makeup composition, for instance a foundation, a concealer, an eye makeup such as an eye shadow, or a body makeup, in particular, a foundation to be applied to the face and/or the neck, or an eye makeup to be applied around eyes.

EXAMPLES

The present invention will be described in a more detailed manner by way of examples. However, these examples should not be construed as limiting the scope of the present invention. The examples below are presented as non-limiting illustrations in the field of the invention.

Examples 1 to 9 and Comparative Examples 1 to 3

[Preparations]

The following compositions according to Examples (Ex.) 1 to 9 shown in Table 1 and Comparative Examples (Comp. Ex.) 1 to 3 shown in Table 2 were prepared by mixing the components shown in the tables. Specifically, "Film former" was mixed with "Oil(a)" at 90°C and cooled to room temperature (part A). Separately, "Thickener" was mixed with "Oil(b)"(part B). Part A and part B were mixed by homogenizer. "Water soluble polyol(s)" was(were) added to the mixture of parts A and B, and mixed by homogenizer. "Pigment" and "Filler" were further added to the mixture and mixed by homogenizer. Alcohol was added to the mixture and mixed by homogenizer. The numerical values for the amounts of the components shown in Table 1 are all based on "% by weight" as active raw materials.

Table 1

Glow O O O O O O O O O

Less color change from bulk shade to applied one O 0 O O ΟΔ O O O ΟΔ

Secondary adhesion free effect ΟΔ ΟΔ ΟΔ o ΟΔ ΟΔ ΟΔ ΟΔ Ο Δ

Less sticky sensation ΟΔ ΟΔ ΟΔ ΟΔ ΟΔ ΟΔ ΟΔ O Ο Δ

Table 2

[Evaluations]

250 mg of each, as a sample, of Examples 1-9 and Comparative Examples 1-3 was applied onto the skin, and spread with the fingers. Glow, moisturizing feeling, color change from bulk shade to applied one, secondary adhesion free effect and sticky sensation were evaluated by 10 panelists and the average score was calculated for each texture property.

The evaluation criteria for glow, moisturizing feeling, color change from bulk shade to applied one, secondary adhesion free effect and sticky sensation are as shown in Table 3.

Table 3. Evaluation Criteria

Average score

The results are shown in Tables 1 and 2.

As shown in Table 1, Examples 1-9, which includes water soluble polyol in an amount more than 2 % by weight relative to the total weight of the composition, provided all the target cosmetic effects (glow, moisturizing feeling, less color change from bulk shade to applied one, secondary adhesion free effect and less sticky sensation) with average scores equal to or more than 3.

On the other hand, Comparative Examples 1-3, which include water soluble polyol in an amount more than 2 % by weight relative to the total weight of the composition, provided but cannot provide all the target cosmetic effects.

Claims

1. A composition comprising:

(a) at least one film forming agent;

(b) at least one non-volatile hydrocarbon-based oil; and

2. The composition according to claim 1, wherein the (a) film forming agent is

hydrocarbon-based resin, preferably hydrocarbon-based indene resin, preferably hydrogenated, preferably derived from the polymerization of indene monomer and of a monomer chosen from styrene, methylindene and methylstyrene, and mixtures thereof.

3. The composition according to claim 2, wherein the hydrocarbon-based resin is an indene resin chosen from hydrogenated indene/methylstyrene/styrene copolymers.

4. The composition according to any one of claims 1 to 3, wherein the (b) non-volatile hydrocarbon-based oil is chosen from non- volatile apolar hydrocarbon-based oils, preferably chosen from polybutenes, polyisobutenes, hydrogenated polyisobutenes, polydecenes and/or hydrogenated polydecenes, and mixtures thereof.

5. The composition according to any one of claims 1 to 4, wherein the composition comprises the (b) non- volatile hydrocarbon-based oil having a viscosity of from 10000 to 100000 mPa.s, preferably from 15000 to 80000 m Pa.s, more preferably from 20000 to 50000 m Pa.s, preferably in a content of 10% by weight or more, more preferably 15% by weight or more relative to the total weight of the composition.

6. The composition according to any one of Claims 1 to 5, wherein the (c) water soluble polyol is chosen from the group consisting of glycerins and glycols, more preferably propylene glycol, butylene glycol, pentylene glycol, hexylene glycol, dipropylene glycol, diethylene glycol, ethylhexylglycerine, caprylyl glycol, glycol ethers, preferably mono-, di- or tripropylene glycol of alkyl(Ci-C₄)ether or mono-, di- or triethylene glycol of alkyl(Ci-C₄)ether, and mixtures thereof.

7. The composition according to any one of Claims 1 to 6, wherein the (c) water soluble polyol is chosen from water soluble polyol having 3 or less carbon atoms, preferably chosen from glycerine, butylene glycol and pentylene glycol.

8. The composition according to any one of Claims 1 to 7, wherein the composition further comprises (d) at least one surfactant, preferably chosen from nonionic surfactants and/or silicone surfactants.

9. The composition according to any one of Claims 1 to 8, wherein the composition further comprises (e) at least one lipophilic thickener.

10. The composition according to any one of Claims 1 to 9, the composition further comprises (f) at least one alcohol, preferably chosen from linear or branched lower monoalcohols which more preferably contain from 2 to 5 carbon atoms, and even more preferably chosen from ethanol, isopropanol, n-propanol and mixtures thereof.

11. The composition according to any one of Claims 1 to 10, wherein the (a) film

forming agent is present in the composition in a content ranging from 0.1% to 10% by weight, preferably ranging from 1% to 7% by weight and more preferably ranging from 2% to 5% by weight relative to the total weight of the composition.

12. The composition according to any one of Claims 1 to 11, wherein the (b) non- volatile hydrocarbon-based oil is present in the composition in a content ranging from 10% to 70% by weight, preferably ranging from 12% to 50% by weight and more preferably ranging from 14% to 40% by weight relative to the total weight of the composition.

13. The composition according to any one of Claims 1 to 12, wherein the (c) water

soluble polyol is present in the composition in a content ranging from 2% to 10% by weight, preferably ranging from 2.5 to 7% by weight, and more preferably from 3 to 5% by weight, relative to the total weight of the composition.