JP7066312B2 - A composition that provides a glow and a feeling of moisture - Google Patents

Description

The present invention relates to compositions for keratin substances such as skin, nails and scalp, or for keratin fibers such as eyelashes, eyebrows and hair, and more specifically cosmetic compositions.

The composition according to the present invention can be a make-up composition or a care composition, preferably a make-up composition, for a keratin substance, specifically for the skin and for keratin fibers.

Cosmetic compositions are commonly used to impart an aesthetic color to the skin and the like, especially to the face. Increasingly diverse properties are needed for cosmetic compositions. For example, in general, when people use make-up products, people say that after application, the product has good retention, especially good resistance to fats and abrasions, on keratin substances, specifically on the skin, etc. , As well as hopefully exhibiting good non-migration. In particular, recently, there has been a demand for a cosmetic composition that brings about a glow and a moisturizing sensation after being applied to the skin and the like, has good migration resistance, and at the same time has little color change.

US Pat. No. 5,334,737 US Pat. No. 5,209,924 US Pat. No. 4972037 WO01 / 32737 US Pat. No. 5,468477 EP-A-0955039 FR-0853634

Handbook of Pressure Sensitive Adhesive Technology, Donatas Satas, 3rd Edition, 1989, p. "Handbook of Surfactants", by M. R. Porter, Blackie & Son publishers (Glasgow and London), 1991, pp. 116-178. CM. Hansen, "The three-dimensional solubility parameters", J. Paint Technol., Vol. 39, p. 105 (1967) "The HLB system. A Time-Saving Guide to Emulsifier Selection" (published by ICI Americas Inc., 1984) CTFA (6th edition, 1995) ISO standard 11357-3, 1999 ASTM D-445 standard

An object of the present invention is to provide a composition which can bring about a glow and a feeling of moisture after application to a skin or the like, has good migration resistance, and at the same time has less color change.

The above purpose is
(a) At least one film-forming agent and
(b) At least one non-volatile hydrocarbon oil,
(c) Containing at least one water-soluble polyol in an amount of 2% by mass or more based on the total mass of the composition.
It can be achieved with a composition that is anhydrous or contains less than 3% by weight, preferably less than 1% by weight of water, based on the total weight of the composition.

(a) The film-forming agent is a hydrocarbon-based resin, preferably hydrogenated, preferably derived from the polymerization of the indene monomer and a monomer selected from styrene, methyl indene and methyl styrene and mixtures thereof. A hydrocarbon-based indene resin can be preferably used.

Preferably, the hydrocarbon resin can be an indene resin selected from hydrogenated indene / methylstyrene / styrene copolymers.

(b) The non-volatile hydrocarbon oil is selected from non-volatile non-polar hydrocarbon oils, preferably from polybutene, polyisobutene, hydrogenated polyisobutene, polydecene and / or hydrogenated polydecene, and mixtures thereof. Is preferable.

The composition according to the present invention has a viscosity of 10,000 to 100,000 mPa.s, preferably 15,000 to 80,000 mPa.s, more preferably 20,000 to 50,000 mPa.s, and preferably a content of 10% by mass based on the total mass of the composition. As described above, (b) non-volatile hydrocarbon-based oil, which is more preferably 15% by mass or more, can be contained.

(c) The water-soluble polyol is glycerin and glycol, more preferably propylene glycol, butylene glycol, pentylene glycol, hexylene glycol, dipropylene glycol, diethylene glycol, ethylhexyl glycerin, caprylyl glycol, glycol ether, preferably alkyl (C). It can be selected from the group consisting of ₁ to C ₄ ) ether mono, di or tripropylene glycol, or alkyl (C ₁ to C ₄ ) ether mono, di or triethylene glycol, and mixtures thereof.

(c) The water-soluble polyol can be selected from water-soluble polyols having 3 or less carbon atoms, preferably glycerin, butylene glycol and pentylene glycol.

The composition preferably further comprises (d) at least one surfactant selected from nonionic surfactants and / or silicone surfactants.

The composition may further include (e) at least one lipophilic thickener.

The composition is preferably selected from linear or branched lower monoalcohols, more preferably containing 2-5 carbon atoms, even more preferably ethanol, isopropanol, n-propanol and mixtures thereof. (F) It may further contain at least one alcohol selected from.

(a) The film-forming agent is contained in the composition in a range of 0.1% by mass to 10% by mass, preferably in the range of 1% by mass to 7% by mass, more preferably 2% by mass, based on the total mass of the composition. It can be present in content ranging from ~ 5% by weight.

(b) The non-volatile hydrocarbon oil is contained in the composition according to the present invention in a range of 10% by mass to 70% by mass, preferably 12% by mass to 50% by mass, based on the total mass of the composition. More preferably, it can be present in a content in the range of 14% by weight to 40% by weight.

(c) The water-soluble polyol is contained in the composition in a range of 2% by mass to 10% by mass, preferably 2.5% by mass to 7% by mass, and more preferably 3% by mass to the total mass of the composition. It can be present in content in the range of 5% by weight.

As a result of diligent studies, the present inventors have been able to provide a composition which can bring about a glow and a feeling of moisture after application to the skin and the like, and has good migration resistance and less color change. I found it possible.

Therefore, the composition according to the present invention is
(a) At least one film-forming agent and
(b) At least one non-volatile hydrocarbon oil,
(c) Containing at least one water-soluble polyol in an amount of 2% by mass or more based on the total mass of the composition.
A composition that is anhydrous or contains less than 3% by weight, preferably less than 1% by weight, water based on the total mass of the composition.

The term "anhydride" specifically means that water is preferably not intentionally added to the composition, but may be present in trace amounts in the various compounds used in the composition.

Hereinafter, each composition according to the present invention will be described in detail.

[Film forming agent]
The composition according to the invention comprises (a) at least one film-forming agent. As used herein, "film-forming agent" means an agent that is capable of forming a film when applied to a keratin substance and imparts tackiness and / or properties resulting from stickiness to the composition. ..

Suitable film-forming agents for use in accordance with the present invention include polyorganosiloxanes containing polymers such as polysilicone polyamide or polysilicone polyurethane; silicone resins (preferably MK or MQ resins), silicones / (meth). ) Acrylic copolymers, acrylate / dimethicone copolymers, liquid silylated siroxy, and silicone esters, such as those described in US Pat. No. 5,334,737 (disclosures incorporated herein by reference), vinyl polymers, methacrylic polymers and acrylic polymers. Silicone polymers comprising a main chain selected from and at least one chain selected from the siloxane group of the pendant and the fluorochemical group of the pendant, eg US Pat. Incorporated herein by reference in its entirety), a polymer selected from vinyl-silicone graft polymers, eg US Pat. No. 5,468477 (the entire disclosure of which is incorporated herein by reference). Examples include, but are not limited to, those described.

Specific examples of suitable film-forming agents include polymers or copolymers containing monomers selected from the group consisting of acrylic acid, methacrylic acid, acrylates, methacrylates, acrylamides, and mixtures thereof, such as acrylate copolymers (eg, by Wackherr). Covacryl A15 and Covacryl E14), acrylate / ethylhexyl acrylate copolymer (Daitosol 5000SJ by Daito Kasei Co., Ltd.), butyl acrylate / hydroxypropyldimethicone acrylate copolymer (Granacrysil BAS by Grant Industries, Inc.), acrylate / C ₁₂ -C ₂₂ Alkyl methacrylate copolymer (Allianz OPT by ISP), copolymer of isodecan and acrylate (Giovarez AC-5099M by Phoenix), acrylate / octylacrylamide copolymer (Dermacryl-79 by National Starch & Chemical Company), polystyrene sulfonic acid Sodium (Flexan 130 by National Starch & Chemical Company), acrylamide / acrylate DMAPA / methoxyPEG methacrylate copolymer, acrylamide / sodium acrylate copolymer, acrylamide / acryloyldimethyltaurate sodium copolymer, acrylate / acrylamide copolymer, acrylate / t-butyl Acrylate copolymer, acrylate / dimethicone copolymer; acrylate / dimethicone methacrylate / ethylhexyl acrylate copolymer; acrylate / dimethylaminoethyl methacrylate copolymer, acrylate / ethylhexyl acrylate copolymer, acrylate / ethylhexyl acrylate / HEMA / styrene copolymer, acrylate / acrylic acid Hydroxy ester copolymer, acrylate / lauryl acrylate / stearyl acrylate / ethylamine methacrylate oxide copolymer, acrylate / octylacrylamide copolymer, acrylate / propyltrimethicone methacrylate copolymer, stearyl acrylate / dimethicone methacrylate copolymer, acrylate / VP copolymer , And acrylic Examples include, but are not limited to, rate / VP / dimethylaminoethyl methacrylate / diacetoneacrylamide / hydroxypropyl acrylate copolymer.

Other suitable tackifiers include aliphatic hydrocarbon resins, aromatic modified aliphatic hydrocarbon resins, hydrogenated polycyclopentadiene resins, polycyclopentadiene resins, gum rosins, gum rosin esters, wood rosins, wood rosin esters, tars. Oil rosin, tar oil rosin ester, polyterpene, aromatic-modified polyterpene, terpene phenol resin, hydrogenated aromatic-modified polycyclopentadiene resin, hydrogenated aliphatic resin, hydrogenated aliphatic aromatic resin, hydrogenated terpene and modified terpen, Examples include, but are not limited to, hydrogenated loginic acid, hydrogenated rosin ester, polyisoprene, partially or fully hydrogenated polyisoprene, polybutendien, partially or fully hydrogenated polybutendien. ..

In some embodiments, preferably the film-forming agent can be selected from hydrocarbon-based resins.

Preferably, the hydrocarbon resin (also known as a pressure-sensitive resin) has a number average molecular weight of 10000 g / mol or less, particularly in the range of 250 to 5000 g / mol, and even better, 2000 g / mol or less. In particular, the range is 250 to 2000 g / mol.

The number average molecular weight (Mn) is determined by gel permeation liquid chromatography (THF solvent, calibration curve prepared with linear polystyrene standard solution, refractive index detector). Unless otherwise stated, molecular weight means number average molecular weight.

The resin of the composition according to the present invention is advantageously a pressure-sensitive resin. These resins are specifically described in the Handbook of Pressure Sensitive Adhesive Technology, edited by Donatas Satas, 3rd Edition, 1989, p.

Preferably, the hydrocarbon resins are selected from low molecular weight polymers that can be classified as follows according to the type of monomer they contain:
Indene hydrocarbon-based resins, preferably resins derived from the polymerization of major proportions of indene monomers and low proportions of monomers selected from styrene, methylindene and methylstyrene and mixtures thereof.

These resins may be optionally hydrogenated. These resins can have a molecular weight in the range of 290 to 1150 g / mol.

Examples of indene resins that can be mentioned are Exxon Chem. With reference name Escorez 7105, Neville Chem. With Nevchem 100 and Nevex 100, Saltomer with Norsolene S105, Hercules with Picco 6100, and Resinall. Hydrocarbon indene / methylstyrene / styrene copolymers sold by Corp. under Resinall or by Eastman Chemical under the name "Regalite", specifically Regalite R1100, Regalite R1090, Regalite R7100, Regalite. R1010 Hydrocarbon Resin and Regalite R1125 Hydrocarbon Resin; aliphatic pentandiene resins such as 1,3-pentanediene (trans-or cis-piperylene) monomers and isoprene, butene, 2-methyl-2-butene, penten and 1, Some are derived from 4-pentanediene, as well as major polymerization with a small amount of monomers selected from their mixtures. These resins can have a molecular weight in the range of 1000-2500 g / mol.

These 1,3-pentanediene resins are sold, for example, by Eastman Chemical under the reference name Piccotac 95, by Exxon Chemicals under the Escorez 1304, by Neville Chem. Under the Nevtac 100, or by Goodyear under the Wingtack 95.
A mixed resin of pentane diene and inden. It is derived from the polymerization of mixtures of pentanediene and indene monomers such as those described above, eg Escorez 2101 by Exxon Chemicals, Nevpene 9500 by Neville Chem., Hercotac 1148 by Hercules. It is a resin sold by Monomer in Norsolene A 100 and by Goodyear in Wingtack 86, Wingtack Extra and Wingtack Plus.
From a diene resin of a cyclopentane diene diene, eg, a first monomer selected from inden and styrene, and cyclopentane diene dimers such as dicyclopentane diene, methyldicyclopentane diene and other pentadiene diene, and mixtures thereof. Derived from polymerization with the second monomer selected. These resins generally have a molecular weight in the range of 500-800 g / mol, eg, Betaprene BR 100 by Arizona Chemical Co., Neville LX-685-125 and Neville LX-1000 by Neville Chem. Sold by Hercules as Piccodiene 2215, by Lawter as Petro-Rez 200, or by Resinall Corp. as Resinall 760.
A terpene-based resin derived from the polymerization of at least one monomer selected from isoprene dimer diene resins such as α-pinene, β-pinene and limonene, and mixtures thereof. These resins can have a molecular weight in the range of 300 to 2000 g / mol. Such resins are sold, for example, by Hercules under the names Piccolyte A 115 and SI 25, or by Arizona Chem. Under the names Zonarez 7100 or Zonatac 105 Lite.

Further mentioned are specific modified resins, such as hydrogenated resins, such as Eastotac C6-C20 Polyolefin by Eastman Chemical Co. and sold by Exxon Chemicals under the reference name Escorez 5300. , Or resin Nevillac Hard or Nevroz sold by Neville Chem., Resin Piccofyn A-100, Piccotex 100 or Piccovar AP25 sold by Hercules, or resin SP sold by Schenectady Chemical Co. It is -553.

According to a preferred embodiment, the hydrocarbon-based resin is an inden hydrocarbon-based resin, an aliphatic pentadiene resin, a mixed resin of pentanediene and inden, a cyclopentane diene diene diene resin, and an isoprene diene diene resin, or It is selected from a mixture of them. Preferably, the composition comprises at least one compound selected from the above-mentioned hydrocarbon-based resins, particularly indene hydrocarbon-based resins, and aliphatic pentadiene resins, or mixtures thereof. According to a preferred embodiment, the hydrocarbon-based resin is selected from indene hydrocarbon-based resins.

(a) The film-forming agent is preferably a hydrogenated hydrocarbon-based indene resin derived from the polymerization of an indene monomer and a monomer selected from styrene, methyl indene and methyl styrene and a mixture thereof. Is preferable.

According to one preferred embodiment, the resin is selected from indene / methylstyrene / hydrogenated styrene copolymers.

Specifically, indene / methylstyrene / hydrocarbonized styrene copolymers, such as those sold by Eastman Chemical under the name Regalite, such as Regalite R 1100, Regalite R 1090, Regalite R-7100, are used. Regalite R 1010 Hydrocarbon Resin and Regalite R 1125 Hydrocarbon Resin.

In other embodiments, the film-forming agent can further comprise a copolymer comprising at least one styrene block. For example, triblock copolymers, specifically polystyrene / polyisoprene or polystyrene / polybutadiene types, such as those sold or manufactured by BASF under the name "Luvitol HSB", and polystyrene / copoly (ethylene-propylene). Type, or polystyrene / copoly (ethylene / butylene) type, eg, sold or manufactured by Shell Chemical Co. under the brand name "Kraton" or by Penreco under Gelled Permethyl 99A. can do. Styrene-methacrylate copolymers can be used.

More specific examples are Kraton G1650 (SEBS), Kraton G1651 (SEBS), Kraton G1652 (SEBS), Kraton G1657X (SEBS), Kraton G1701X (SEP), Kraton G1702X (SEP), Kraton G1726X. (SEB), Kraton G1750X (EP) polymer, Kraton G1765X (EP) multiarm, Kraton D-1101 (SBS), Kraton D-1102 (SBS), Kraton D-1107 (SIS), Gelled Permethyl 99A-750, Gelled Permethyl 99A-753-58 (mixture of star block polymer and triblock polymer), Gelled Permethyl 99A-753-59 (mixture of star block polymer and triblock polymer), Versagel 5970 and Versagel 5960 from Penreco A mixture of stellate polymers and triblock polymers in isododecane), as well as OS 129880, OS 129881 and OS 84383 (styrene-methacrylate copolymers) from Lubrizol.

Preferably, (a) the film-forming agent is contained in the composition according to the present invention in a range of 0.1% by mass to 10% by mass, preferably 1% by mass to 7% by mass, based on the total mass of the composition. More preferably, it is present in a content in the range of 2% by mass to 5% by mass.

[Non-volatile hydrocarbon oil]
The composition according to the invention comprises (b) at least one non-volatile hydrocarbon oil.

The term "oil" means a water-immiscible, non-aqueous compound that is liquid at room temperature (25 ° C) and atmospheric pressure (760 mmHg).

The term "hydrocarbon-based oil" is an oil that is essentially formed or even composed of carbon and hydrogen atoms and, in some cases, oxygen and nitrogen atoms, and contains no silicon or fluorine atoms. Means no oil. It may contain alcohols, esters, ethers, carboxylic acids, amines and / or amide groups.

The term "nonvolatile" oil refers to oils whose vapor pressure at room temperature and atmospheric pressure is non-zero and less than 0.02 mmHg (2.66Pa), and even better less than ^10-3 mmHg (0.13Pa).

The non-volatile hydrocarbon oil can be of plant origin, synthetic or mineral origin, or a mixture thereof.

(Non-polar oil)
According to the first embodiment, the non-volatile hydrocarbon oil may be a non-polar oil.

These oils can be of plant, mineral or synthetic origin.

For the purposes of the present invention, the term "non-polar oil" means an oil whose solubility parameter δ _a at 25 ° C is equal to 0 (J / cm ³ ) ^1/2 .

Definitions and calculations of solubility parameters in Hansen's three-dimensional solubility space are described in CM. Hansen's paper, "The three-dimensional solubility parameters," J. Paint Technol., Vol. 39, p. 105 (1967). There is.

According to this Hansen space
—— δ _D is characterized by the London dispersion force resulting from the formation of dipoles induced during molecular collisions.
—— δ _p is characterized by the Debye interaction force between the permanent dipoles, and further the casem interaction force between the induced dipole and the permanent dipole.
—— δ _h is characterized by specific interaction forces (eg hydrogen bonds, acids / bases, donors / acceptors, etc.) and
--δ _a is calculated by the equation: δ _a = (δ _p ² + δ _h ² ) ^1/2 .

The parameters δ _p , δ _h , δ _D and δ _a are represented by (J / cm ³ ) ^1/2 .

Preferably, can be selected from minerals, or linear or branched hydrocarbons of synthetic origin, such as:
--Liquid paraffin or its derivatives
--Squalene
--Iso Eikosan
--Naphthalene oil
--Polybutylene, for example Indopol H-100 (molar mass or MW = 965g / mol), Indopol H-300 (MW = 1340g / mol) and Indopol H-1500 (MW = 2160g / mol) sold or manufactured by Amoco. )
--Polyisobutene
--Polyisobutylene hydride, for example Parleam® sold by NOF CORPORATION, Panalane H-300 E (MW = 1340g / mol) sold or manufactured by Amoco, sold or manufactured by Synteal. Viseal 20000 (MW = 6000g / mol), Rewopal PIB 1000 (MW = 1000g / mol) sold or manufactured by Witco, or Parleam Lite sold by NOF Corporation.
--Decenes / butene copolymers, polybutene / polyisobutene copolymers, especially Indopol L-14
--Polydecene and hydrogenated polydecene, such as Puresyn 10 (MW = 723g / mol) and Puresyn 150 (MW = 9200g / mol) sold or manufactured by Mobil Chemicals, or Puresyn 6 sold by Exxon Mobil Chemicals.
—— And a mixture of these.

(Polar oil)
(b) The non-volatile hydrocarbon oil may be a polar hydrocarbon oil.

These oils can be of plant, mineral or synthetic origin.

In the sense of the present invention, the term "polar oil" means an oil whose solubility parameter δ _a at 25 ° C. is other than 0 (J / cm ³ ) ^1/2 .

Specifically, hydrocarbon-based non-volatile polar oils can be selected from the following list of oils and mixtures thereof:
—— Hydrocarbon vegetable oils, such as liquid triglycerides of fatty acids containing 4-10 carbon atoms, such as heptanic acid or octanoic acid triglycerides, or jojoba oil.
-Preferably selected from the following, ester oils:
—— Fatty acid esters, especially those with 4 to 22 carbon atoms, especially those of octanoic acid, heptanic acid, lanolinic acid, oleic acid, lauric acid or stearic acid, such as propylene glycol dioctanoate, monoisostearic acid. Propylene glycol or neopentyl glycol diheptanoate
--Synthetic esters, such as formula R ₁ COOR ₂ (where R ₁ represents a linear or branched fatty acid residue containing 4-40 carbon atoms, and R ₂ represents 4-40. Represents a particularly branched hydrocarbon chain containing the carbon atoms of the above, provided that R ₁ + R ₂ > 16) oils such as perserine oil (cetostearyl octanate), isononyl isononanoate, C ₁₂ -C ₁₅ Alkyl benzoate, 2-ethylhexyl palmitate, ethylhexyl methoxycinnamate [sold by DSM under the trade name Persol® MCX], octyldodecyl neopentanoate, 2-octyl stearate Dodecyl, 2-octyldodecyl erucate, oleyl erucate, isostearyl isostearate, 2-octyldodecyl benzoate, alcohol or polyalcohol octanoate, decanoic acid ester or ricinoleic acid ester, isopropyl myristate, isopropyl palmitate, stearic acid Butyl, hexyl laurate, 2-ethylhexyl palmitate, 2-hexyldecyl laurate, 2-octyldecyl palmitate, 2-octyldodecyl myristate or 2-diethylhexyl succinate; preferably the preferred synthetic ester R ₁ COOR ₂ (In the formula, R ₁ represents a linear or branched fatty acid residue containing 4 to 40 carbon atoms, and R ₂ is particularly branched containing 4 to 40 carbon atoms. Represents a hydrocarbon chain that is, however, there is a condition that R ₁ and R ₂ ≧ 20)
--Linear fatty acid esters with a total carbon number in the range of 35 to 70, such as pentaerythrityl tetrapelargonate (MW = 697 g / mol)
--Glyceryl esters, such as caprylic acid / capric acid glycerides sold by Abitec under the reference name Capmul MCM.
—— A hydroxylated ester, preferably one having a total carbon number in the range of 35-70, such as polyglyceryl-2 triisostearate-2 (MW = 965 g / mol), isostearyl lactate, octyl hydroxystearate, octyldodecyl hydroxystearate, Diisostearyl malate, glyceryl stearate; diethylene glycol diisononanoate
--Esters of aromatic acids containing 4 to 22 carbon atoms and alcohols, such as tridecyl trimellitate (MW = 757g / mol)
--C ₂₄ -C ₂₈ esters of branched fatty alcohols or fatty acids, such as those described in patent application EP-A-0955039, in particular triisoaraxyl citrate (MW = 1033.76 g / mol), pentaerythrityl tetraisononanonate. (MW = 697g / mol), glyceryl triisostearate (MW = 891g / mol), tris (2-decyl) glyceryl tetradecanoate (MW = 1143g / mol), pentaerythrityl tetraisostearate (MW = 1122g / mol) , Polyglyceryl-2 tetraisostearate (MW = 1232 g / mol), or Tetrax (2-decyl) pentaerythrityl tetradecanoate (MW = 1538 g / mol)
—— Optional unsaturated polyesters obtained by esterifying at least one hydroxylated carboxylic acid triglyceride with an aliphatic monocarboxylic acid and an aliphatic dicarboxylic acid, for example sold by Zenitech under the reference name Zenigloss. Succinic acid and isostearic acid castor oil
--Ester of diol dimer and diacid dimer, general formula HO-R ¹ -(-OCO-R ² -COO-R ^1- ) _h -OH
(During the ceremony,
R ¹ represents the diol dimer residue obtained by hydrogenation of dilinolene diacid.
R ² represents a hydrogenated dilinolene diacid residue and
h represents an integer in the range 1-9)
Things,
In particular, the ester of dilinol diacid and dilinoleyl diol dimer sold by Nippon Fine Chemical Co., Ltd. under the trade names Lusplan DD-DA5 (registered trademark) and DD-DA7 (registered trademark).
--Polyesters obtained by condensation of unsaturated fatty acid dimers and / or trimmers with diols, such as those described in patent application FR-0853634, especially polyesters obtained by condensation of dilinoleic acid with 1,4-butanediol. .. In this regard, particular mention is made of polymers sold by Biosynthis under the name Viscoplast 14436H (INCI name: dilinolic acid / butanediol copolymer), or copolymers of polyols with diacid dimers, and esters thereof, such as Hailuscent ISDA. Can be
—— Fatty alcohols containing 12 to 26 carbon atoms, preferably branched, such as octyldodecanol, 2-butyloctanol, 2-hexyldecanol, 2-undecylpentadecanol and oleyl alcohol.
--C ₁₂ to C ₂₂ Higher fatty acids such as oleic acid, linoleic acid and linolenic acid, and mixtures thereof.
--Plant-derived oils such as sesame oil (820.6 g / mol); and trifatty acids (C ₁₈ -C ₃₆ ) glyceryl (Dub TGI 24 from Stearineries Dubois)
—— Fatty acids containing 12 to 26 carbon atoms, such as oleic acid
—— Dialkyl carbonate, for example dialkyl carbonate sold by Cognis under the name Cetiol CC®, as well as dialkyl carbonate, where the two alkyl chains are optionally identical or different.
--Vinylpyrrolidone copolymers such as vinylpyrrolidone / 1-hexadecene copolymer, Antaron V-216 (MW = 7300g / mol) sold or manufactured by ISP.

Preferably, the non-volatile hydrocarbon oil present in the composition is selected from:
—— A polar hydrocarbon preferably selected from non-polar hydrocarbon oils such as polybutene, polyisobutene, hydrogenated polyisobutene, polydecene and / or hydrogenated polydecene, and mixtures thereof, and plant-derived or plant-derived hydrocarbon oils. Hydrocarbon-based oils preferably selected from system oils, ester oils, fatty alcohols containing 12-26 carbon atoms, fatty acids containing 12-26 carbon atoms, and vinylpyrrolidone copolymers, and mixtures thereof. , As well as a mixture of these.

Preferably, (b) the non-volatile hydrocarbon oil is in the composition according to the present invention in the range of 10% by mass to 70% by mass, preferably 12% by mass to 50% by mass, based on the total mass of the composition. Can be present in the range of, more preferably in the range of 14% by weight to 40% by weight.

Preferably, the composition has a viscosity of 10,000 to 100,000 mPa.s, preferably 15,000 to 80,000 mPa.s, more preferably 20,000 to 50,000 mPa.s, and the content is preferably 10% by weight based on the total mass of the composition. As described above, it contains (b) non-volatile hydrocarbon oil, which is more preferably 15% by mass or more. The viscosity is measured at 25 ° C. using a Haake Rheostress RS 150 instrument in a flat cone arrangement.

[Water-soluble polyol]
The composition of the present invention may further contain (c) at least one water-soluble polyol. A single type of polyol may be used, but two or more different polyols may be used in combination.

The term "polyol" as used herein means an alcohol having two or more hydroxy groups and does not include saccharides or derivatives thereof. As derivatives of saccharides, sugar alcohols obtained by reducing one or more carbonyl groups of saccharides, and hydrogen atoms in one or more hydroxy groups thereof are alkyl groups, hydroxyalkyl groups, and alkoxy groups. , Saccharides or sugar alcohols that have been replaced by at least one substituent such as an acyl group or a carbonyl group.

The polyol can be a C ₂ to C ₁₂ polyol, preferably a C ₂ to C ₉ polyol, containing at least 2 hydroxy groups, preferably 2 to 5 hydroxy groups.

The polyol can be a natural or synthetic polyol. Polyols can have a linear, branched or cyclic molecular structure.

The polyols are glycerin and glycol, more preferably propylene glycol, butylene glycol, pentylene glycol, hexylene glycol, dipropylene glycol, diethylene glycol, ethylhexyl glycerin, caprylyl glycol, glycol ether, preferably alkyl (C ₁ to C ₄ ). It can be selected from the group consisting of mono, di or tripropylene glycol of ethers, or mono, di or triethylene glycol of alkyl (C ₁ to C ₄ ) ethers, and mixtures thereof.

Preferably, (c) the water-soluble polyol is selected from water-soluble polyols having 3 or less carbon atoms, preferably selected from glycerin, butylene glycol and pentylene glycol.

The polyol is present in an amount in the range of 2% by weight to 10% by weight, preferably 2.5% by weight to 7% by weight, more preferably 3% by weight to 5% by weight, based on the total weight of the composition. can do.

[Surfactant]
Optionally, the composition of the invention may further comprise at least one (d) surfactant.

Preferably, (d) the surfactant can be selected from nonionic surfactants and polyether-modified silicones.

(Nonionic surfactant)
The composition comprises at least one nonionic surfactant. Two or more nonionic surfactants may be used in combination.

Nonionic surfactants are well-known compounds in their own right (in this regard, for example, "Handbook of Surfactants", by MR Porter, Blackie & Son publishers (Glasgow and London), 1991, 116- See page 178). Thus, they can be selected from, for example, esters of alcohols, α-diols, alkylphenols and fatty acids, the compounds of which are ethoxylated, propoxylated or glycerolified, eg, 8-30. It is possible to have at least one fatty chain containing a carbon atom, the number of ethylene oxide groups or propylene oxide groups is in the range of 2-50, and the number of glycerol groups is in the range of 1-30. Maltose derivatives can also be mentioned. Further, but not limited to, copolymers of ethylene oxide and / or propylene oxide; condensates of ethylene oxide and / or propylene oxide with fatty alcohols; polyethoxylated fatty amides containing, for example, 2-30 mol of ethylene oxide; Polyglycerolated fatty acid amides containing, for example, 1.5-5, 1.5-4 glycerol groups; sorbitan ethoxylated fatty acid esters containing 2-30 mol of ethylene oxide; plant-derived ethoxylated fatty acid esters; sucrose fatty acid esters; polyethylene glycol Fatty Acid Esters; Polyethoxylated Fatty Acid Monoesters or Diesters of Gglycerol (C ₆ -C ₂₄ ) Alkyl Polyglycosides; N- (C ₆ -C ₂₄ ) Alkyl Glucamine Derivatives; (C ₁₀ -C ₁₄ ) Alkyl Amine Oxides or Amine oxides such as N- (C ₁₀ -C ₁₄ ) acylaminopropyl morpholine oxides; silicone surfactants; and mixtures thereof.

Preferably, the nonionic surfactant can be selected from lipophilic nonionic surfactants.

The lipophilic nonionic surfactants are sorbitan fatty acid esters such as sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate, di. Glycerin sorbitan penta-2-ethylhexanoate, and diglycerol sorbitan tetra-2-ethylhexanoate; mono-cotton oil fatty acid glycerin polyglycerin fatty acid such as glycerin, glycerol monoerkaate, glycerol sesquioleate, glyceryl α monostearate. Glyceryl oleate oleate, α'-pyroglutamate, and glyceryl monostearate malate; propylene glycol fatty acid esters such as propylene glycol monostearate; and cured castor oil derivatives, glyceryl alkyl ethers and polyoxyethylene methyl polysiloxane copolymers. It can be exemplified.

The HLB of the nonionic surfactant is preferably less than 12, more preferably less than 10, and even more preferably less than 8. When two or more nonionic surfactants are used, their HLB values are determined by the mass average of the HLB values of all nonionic surfactants. HLB is the ratio between the hydrophilic and lipophilic moieties in the molecule. The term HLB is well known to those of skill in the art and is described in "The HLB system. A Time-Saving Guide to Emulsifier Selection" (published by ICI Americas Inc., 1984).

(Polyether modified silicone)
The hydrophilic group of the polyether-modified silicone can preferably be selected from polyoxyethylene (POE) or polyoxypropylene (POP).

Preferably, the polyether-modified silicone is PEG-10 dimethicone, PEG-9 polydimethylsiloxyethyl dimethicone, cetyldimethicone copolypoly, lauryl PEG-9 polydimethylsiloxyethyl dimethicone, PEG / PPG-19 / 19 dimethicone [dimethicone / ( PEG-10 / 15)] Crosspolymer, poly-silicone-13, etc. can be selected.

The surfactant can be present in an amount in the range of 0.1% by weight to 10% by weight, preferably 1% by weight to 7% by weight, for example 2% by weight to 5% by weight, based on the total weight of the composition. ..

[Lipophilic thickener]
Optionally, the composition according to the invention may further comprise at least one (e) lipophilic thickener. Two or more lipophilic thickeners may be used in combination. The lipophilic thickener can be inorganic or organic. The lipophilic thickener can thicken (a) the oil of the composition according to the present invention.

The term "lipophilic thickener" means an agent in the form of inorganic or organic, particulate matter, capable of gelling the oil of the composition.

The term "fine particle lipophilic thickener" means a lipophilic thickener in the form of particles or crystals (fine particles or crystals).

The composition according to the invention comprises at least one lipophilic thickener, preferably fine particles.

The lipophilic thickener according to the invention can be selected from:
-Clays treated with organically modified clays, especially compounds selected from quaternary and tertiary amines. Examples of organically modified clays include organically modified bentonite, such as products sold by Rheox under the name Bentone 34, and organically modified hectorite, such as products sold by Rheox under the names Bentone 27 and Bentone 38. There is. Particularly mentioned are modified hextrilites such as modified magnesium silylated magnesium [Bentone gel® VS38 from Rheox], Hectrite modified with C ₁₀ -C ₂₂ fatty acid ammonium chloride, such as distearyldimethyl. Ammonium chloride-modified Hectrite (Disteardimonium Hectrite), eg, a product sold by Elementis under the name Bentone 38VCG, or by Rheox under the name Bentone 38 CE, or by Elementis. Products sold under the name Bentone Gel® V5 5V, or products sold under the name Bentone gel® ISD V by Elementis.
--Hydrophobic fumed silica that can be obtained by modifying the surface of the silica through a chemical reaction that produces a reduction in the number of silanol groups (these groups are optionally specifically substituted with hydrophobic groups). The hydrophobic group can be a trimethylsiloxyl group, which is obtained in particular by treating fumed silica in the presence of hexamethyldisilazane. Silica treated in this way is known by CTFA (6th edition, 1995) as "silylated silica". They are sold, for example, by Degussa under the reference name Aerosil R812® and by Cabot under the Cab-O-Sil TS-530®. Hydrophobic groups can be dimethylsilyloxyl groups or polydimethylsiloxane groups, which are obtained particularly by treating fumed silica in the presence of polydimethylsiloxane or dimethyldichlorosilane. Silica treated in this way is known by CTFA (6th edition, 1995) as "dimethylsilylated silica". They are, for example, reference names Aerosil R972® and Aerosil R974® by Degussa, and Cab-O-Sil TS-610® and Cab-O-Sil TS-720 (registered trademark) by Cabot. Sold under (registered trademark).
--A hydrophobic silica airgel, for example, a product sold by Dow Corning under the name VM-2260 (INCI name: silylated silica), the average particle size of its particles is about 1000 microns, per unit of mass. Specific surface area ranges from 600 to 800 m ² / g; further can be mentioned by Cabot under the references Airgel TLD 201, Airgel OGD 201, Airgel TLD 203, Enova® Aerogel MT 1 100, Enova Airgel MT 1200 is an airgel sold in
—— And a mixture of these.

In particular, the composition according to the invention is characterized in that (e) the lipophilic thickener is selected from organically modified clay, specifically organically modified bentonite and organically modified hectorite and mixtures thereof. do. Disteardimonium hectorite can be mentioned as an organically modified clay.

(e) The lipophilic thickener is preferably an organically modified clay modified with a quaternary amine or a tertiary amine.

(e) The lipophilic thickener is contained in the composition in a range of 0.01% by mass to 15% by mass, preferably in a range of 0.1% by mass to 10% by mass, more preferably 1 with respect to the total mass of the composition. It can be present in content ranging from% by weight to 5% by weight.

[alcohol]
Optionally, the compositions of the invention may further comprise at least one (f) alcohol.

Preferably, (f) the alcohol can be selected from linear or branched lower monoalcohols, more preferably containing 2-5 carbon atoms. Even more preferably, (f) alcohol can be selected from ethanol, isopropanol, n-propanol and mixtures thereof.

(f) Alcohol in the composition is in the range of 0.01% by mass to 10% by mass, preferably in the range of 0.1% by mass to 5% by mass, more preferably 0.5% by mass to 3 with respect to the total mass of the composition. It can be present in content in the range of% by weight.

[Paste-like fat substance]
Optionally, the compositions of the invention may further comprise at least one pasty fatty substance.

For the purposes of the present invention, the term "paste-like fatty material" undergoes a reversible change of state of solid / liquid, exhibits an anisotropic crystalline structure in the solid state, and exhibits a liquid fraction and a solid fraction at a temperature of 23 ° C. It is intended to indicate a lipophilic fatty compound, including minutes.

In other words, the starting melting point of the pasty fatty substance can be less than 23 ° C. The liquid fraction of the paste-like fatty substance measured at 23 ° C. can occupy 9% by mass to 97% by mass of the paste-like fatty substance. This liquid fraction occupies between 15% by weight and 85% by weight, more preferably between 40% and 85% by weight at 23 ° C.

For the purposes of the present invention, the melting point corresponds to the temperature of the highest endothermic peak observed in thermal analysis (DSC), as described in ISO Standard 11357-3, 1999. The melting point of the pasty fatty material can be measured using a differential scanning calorimeter (DSC), eg, a calorimeter sold by TA Instruments under the name MDSC 2920.

The measurement protocol is as follows:
A 5 mg sample of pasty fatty material placed in a jar was subjected to a first temperature increase in the range of -20 ° C to 100 ° C at a heating rate of 10 ° C / min, and then cooled to 100 ° C to -20 ° C at a cooling rate of 10. Cool at ° C / min and finally apply a second temperature rise in the range of -20 ° C to 100 ° C at a heating rate of 5 ° C / min. The change in the difference between the force absorbed by the empty crucible and the force absorbed by the crucible containing the sample of the pasty fatty substance during the second temperature rise is measured as a function of temperature. The melting point of the pasty fatty substance is a temperature value corresponding to the apex of the peak of the curve representing the change in the difference in absorbed force as a function of temperature.

The liquid fraction by mass of the pasty fatty material at 23 ° C is equal to the ratio of the heat of fusion consumed at 23 ° C to the heat of fusion of the pasty fatty material.

The heat of fusion of a pasty fatty substance is the heat consumed by the pasty fatty substance to transfer from a solid state to a liquid state. A pasty fatty substance is said to be in a solid state when all of its mass is in the crystalline solid form. A pasty fatty substance is said to be in a liquid state when all of its mass is in liquid form.

The melting enthalpy of pasty fatty substances is 5 per minute according to ISO Standard 11357-3, 1999, using a differential scanning calorimeter (DSC) such as a calorimeter sold by TA Instruments under the name MDSC 2920. Equal to the area under the curve of the thermogram obtained by increasing the temperature by ° C or 10 ° C.

The heat of fusion of a pasty fatty substance is the amount of energy required to change the pasty fatty substance from a solid state to a liquid state. It is expressed in J / g.

The heat of fusion consumed at 23 ° C is the amount of energy absorbed by the sample to change from the solid state to the state of the sample, which consists of a liquid fraction and a solid fraction, at 23 ° C.

The liquid fraction of the paste-like fatty substance measured at 32 ° C. preferably occupies 30% by mass to 100% by mass of the paste-like fatty substance, preferably 50% by mass to 100% by mass of the paste-like fatty substance, more preferably. Occupies 60% to 100% by mass. When the liquid fraction of the paste-like fatty substance measured at 32 ° C is equal to 100%, the end point temperature of the melting range of the paste-like fatty substance is 32 ° C or less. The liquid fraction of the pasty fatty material measured at 32 ° C is equal to the ratio of the heat of fusion consumed at 32 ° C to the heat of fusion of the pasty fatty material. The heat of fusion consumed at 32 ° C is calculated in the same way as the heat of fusion consumed at 23 ° C.

The paste-like fatty substance can be selected from synthetic fatty substances and fat substances of plant origin in detail. Paste-like fatty substances can be obtained by synthesis from starting materials of plant origin.

Paste-like fatty substances can be selected from:
—— Lanolin and its derivatives
--Vaseline (petroleum jelly) [also known as petrolatum]
--Polyalkylene glycol pentaerythrityl ether, a polyol ether selected from fatty alcohol ethers of sugars and mixtures thereof, polyethylene glycol pentaerythrityl ether containing 5 oxyethylene (5OE) units (CTFA name: PEG-5 penta) Ellis lithyl ether), polypropylene glycol pentaerythrityl ether containing 5 oxypropylene (5OP) units (CTFA name: PPG-5 pentaerythrityl ether) and mixtures thereof, more particularly sold by Vevy under the name Lanolide. It is a mixture of PEG-5 pentaerythrityl ether, PPG-5 pentaerythrityl ether and soybean oil, and the mass composition ratio in the mixture is 46/46/8, which is 46% by mass of PEG-5 pentaeryth. Lithyl ether, 46% by mass of PPG-5 pentaeryth lithyl ether, and 8% by mass of soybean oil.
—— Polymeric or non-polymeric silicone compounds
—— Polymeric or non-polymeric fluorinated compounds
--Vinyl polymer, specifically:
Olefin homopolymers and copolymers Hydrogenated diene homopolymers and copolymers Linear or branched oligomers, preferably homopolymers or copolymers of alkyl (meth) acrylates containing C ₈ to C ₃₀ alkyl groups.
C ₈ to C ₃₀ Oligomers that are homopolymers and copolymers of vinyl esters containing alkyl groups
C ₈ to C ₃₀ Oligomers that are homopolymers and copolymers of vinyl ethers containing alkyl groups
—— A fat-soluble polyether obtained from polyetheration between one or more C ₂ to C ₁₀₀ and preferably C ₂ to C ₅₀ diols.
--Ester
—— And / or a mixture of these.

Of particular consideration among fat-soluble polyethers are copolymers of ethylene oxide and / or propylene oxide with C ₆ -C ₃₀ long chain alkylene oxides, more preferably ethylene oxide and / or propylene oxide in the copolymers. The mass ratio to alkylene oxide is 5:95 to 70:30. In this family, in particular, copolymers such that long chain alkylene oxides are arranged in blocks with an average molecular weight of 1000-10000, such as dodecanediol (22 mol) and polyethylene glycol sold by Akzo Nobel under the trade name Elfacos ST9. Polyoxyethylene / polydodecyl glycol block copolymers such as ether with (45OE) can be mentioned.

Among the esters, the following are specifically considered:
—— Esters of glycerol oligomers, especially diglycerol esters, specifically condensates of adipic acid and glycerol, in which some of the hydroxyl groups of the glycerol are stearic acid, capric acid and isostearic acid, and 12-hydroxystearic. Bis (diglyceryl) poly (2-acyl adipate) that is reacting with a mixture of fatty acids such as acids, eg, sold by Sasol under the reference name Softisan® 649.
—— Vinyl ester homopolymers containing C ₈ to C ₃₀ alkyl groups, such as polyvinyl laurate (particularly sold by Chimex under the reference name Mexicor PP).
--Arakidil propionate, sold by Alzo under the trade name Waxenol 801
--Phytosterol ester
--Fatty acid triglycerides and their derivatives
--Pentaerythritol ester
--Esters of diol dimers and diic acid dimers, where appropriate in free alcohol or acid functional groups, esterified with acid or alcohol groups, especially dimer dilinoleic acid esters, such esters in particular. The following INCI names can be specifically selected from the esters: Dimerjilinolate Dimerjilinoleylbis (Behenyl / Isostearyl / Phytosteryl) (Plandool-G), Dimerjilinolate Phytosteryl / Isostearyl / Cetyl / Stearyl. / Behenil (Plandool-H or Plandool-S), and mixtures thereof
--Mango butter, for example, a product sold by Aarhus Karlshamn under the reference name Lipex 203.
--Hydrogenated soybean oil, hydrogenated coconut oil, hydrogenated abrana seed oil, or a mixture of hydrogenated vegetable oils, such as hydrogenated vegetable oil mixtures of soybean, coconut, palm and abrana, eg Akogel® by Aarhus Karlshamn. Mixture sold at (INCI name: hydrogenated vegetable oil)
--Shea butter, especially those whose INCI name is Butyrospermum Parkii Butter, such as those sold by Aarhus Karlshamn under the reference name Sheasoft®.
—— And a mixture of these.

According to one preferred embodiment, the paste-like fatty material is selected from esters, particularly esters of diol dimers and diacid dimers.

Among the paste compounds, bis-behenyl / isostearyl / dimer dilinoleyl phytosteryl, bisdiglyceryl polyacyl adipate-2, dimer dilinol acid hydrogenated castor oil, for example sold by Higher Alcohol Industry Co., Ltd. Risocast DA-L and hydrogenated isostearic acid castor oil, such as Salacos HCIS (V-L), polyvinyl laurate, mango butter, shea butter, hydrogenated soybean oil, hydrogenated coconut sold by Nisshin Oillio Group Co., Ltd. Oils, hydrogenated rapeseed oils and vinylpyrrolidone / eicosen copolymers, or mixtures thereof, will be preferably selected.

The paste-like fatty substance in the composition is in the range of 0.01% by mass to 10% by mass, preferably in the range of 0.1% by mass to 5% by mass, and more preferably 0.5% by mass to 3% by mass with respect to the total mass of the composition. Can be present in content in the range of%.

[Silicone oil]
Optionally, the composition of the invention may further comprise at least one silicone oil, preferably at least one non-volatile silicone oil.

The non-volatile silicone oils that can be used in the present invention have a viscosity of 9 centimeters (cSt) (9 × 10) ^-6 m ² / s) or more and less than 800,000 cSt, preferably between 50 cSt and 600000 cSt, particularly at 25 ° C. You can specifically choose from silicone oils that are between 100 cSt and 500000 cSt. The viscosity of this silicone can be measured according to ASTM D-445 standards.

Specifically, the non-volatile silicone oil can be selected from:
--Linear or branched, non-volatile polydimethylsiloxane (PDMS)
—— Polydimethylsiloxane containing an alkyl, alkoxy or phenyl group that is a pendant or at the end of a silicone chain and contains 2 to 24 carbon atoms, such as sold by Evonik Goldschmidt under the reference name Abil Wax 9801. Setil dimethicone
--Phenyl silicone oil, specifically one to choose from:
--Phenyltrimethyloxytrisiloxane, especially the phenyltrimethylsiloxytrisiloxane sold under the reference name Dow Corning 556 Cosmetic Grade Fluid, in particular, for example.
--Phenyldimethicone
--Phenyltrimethylsiloxydiphenylsiloxane
--Diphenyldimethicone
--Diphenylmethyldiphenyltrisiloxane
--2-Phenylethyltrimethylsiloxysilicate, and
--Trimethylpentaphenyltrisiloxane, especially by reference name PH-1555 HRI or Dow Corning 555 Cosmetic Fluid (chemical name: l,3,5-trimethyl-l, l,3,5,5-pentaphenyltri) by Dow Corning, for example. Siloxane, INCI name: trimethylpentaphenyltrisiloxane) silicone oil, and
--Trimethylsiloxyphenyldimethicone, especially the product sold by Wacker, for example under the reference name Belsil PDM 1000.

[Other optional ingredients]
The compositions according to the invention may also include one or more standard cosmetic adjuvants, which are, for example, fillers, softeners, moisturizers, oils, opaque agents, stabilizers, emollients, etc. Selected from silicones, defoamers, fragrances, preservatives, surfactants, activators, colorants, cationic polymers, sprays, or cosmetics and / or any other ingredient commonly used in dermatology. ..

Needless to say, those skilled in the art will add to the composition according to the invention such that the advantageous properties inherently related to the composition according to the invention are not adversely affected at all or substantially by the expected addition. The optional adjuvant to be used will be carefully selected.

The composition according to the present invention can preferably be used as a cosmetic composition. In particular, the compositions according to the invention can be intended for application to the skin, scalp and / or lips, preferably the skin, especially the skin around the eyes. Therefore, the composition according to the present invention can be used in a cosmetic method for the skin.

The cosmetic composition shall be applied to a skin care composition or skin make-up composition, for example, eye make-up such as foundation, concealer, eye shadow, or body make-up, specifically face and / or neck. It can be a foundation that becomes, or an eye makeup that will be applied around the eyes.

The present invention will be described in more detail by way of examples. However, those examples should not be construed as limiting the scope of the invention. The following examples are shown as non-limiting examples in the field of the present invention.

(Examples 1 to 9 and Comparative Examples 1 to 3)
[Preparation]
The following compositions of Examples 1 to 9 shown in Table 1 and the compositions of Comparative Examples 1 to 3 shown in Table 2 were prepared by mixing the constituents shown in the table. Specifically, the "film-forming agent" was mixed with "oil (a)" at 90 ° C. and cooled to room temperature (Part A). Separately, the "thickener" was mixed with the "oil (b)" (Part B). Part A and Part B were mixed with a homogenizer. "Water-soluble polyol" was added to the mixture of Part A and Part B and mixed with a homogenizer. "Pigments" and "fillers" were further added to the mixture and mixed with a homogenizer. Alcohol was added to the mixture and mixed with a homogenizer. The numerical values of the amounts of the constituents shown in Tables 1 and 2 are all based on the "mass%" of the active raw material.

[evaluation]
250 mg each of Examples 1 to 9 and Comparative Examples 1 to 3 were applied to the skin as a sample and spread with fingers. Glow, moisture, color change from bulk shade to application, secondary adhesion-less effect, and stickiness were evaluated by 10 panelists, and average scores were calculated for the characteristics of each texture.

Table 3 shows the evaluation criteria for glow, moisturizing feeling, color change from bulk shade to application, secondary adhesion-less effect and sticky feeling.

The results are shown in Tables 1 and 2.

As shown in Table 1, Examples 1 to 9 containing a water-soluble polyol in an amount of more than 2% by mass based on the total mass of the composition are applied from the target cosmetic effect (glow, moisturizing feeling, bulk shade). It resulted in less color change to, less secondary adhesion less effect and less stickiness), with an average score of 3 or higher.

On the other hand, Comparative Examples 1 to 3 containing a water-soluble polyol in an amount of more than 2% by mass based on the total mass of the composition provided the desired cosmetic effect, but could not achieve all of them.

Claims (13)

(a) At least one film-forming agent and
(b) At least one non-volatile hydrocarbon oil,
(c) With at least one water-soluble polyol in an amount of 2% by mass or more based on the total mass of the foundation .
(d) Containing at least one surfactant
(a) The film-forming agent is selected from hydrocarbon-based indene resins.
A foundation that is anhydrous or contains less than 3% by weight of water based on the total weight of the foundation . (a) The film-forming agent is selected from hydrogenated or non-hydrogenated hydrocarbon-based indene resins derived from the polymerization of indene monomers and monomers selected from styrene, methyl inden and methyl styrene and mixtures thereof. The foundation according to claim 1. The foundation according to claim 2, wherein the hydrocarbon-based indene resin is an indene resin selected from hydrogenated indene / methylstyrene / styrene copolymer. (b) The foundation according to any one of claims 1 to 3, wherein the non-volatile hydrocarbon oil is selected from the non-volatile non-polar hydrocarbon oil. The foundation according to any one of claims 1 to 4, which comprises (b) a non-volatile hydrocarbon oil having a viscosity of 10000 to 100,000 mPa.s. (c) The foundation according to any one of claims 1 to 5, wherein the water-soluble polyol is selected from the group consisting of glycerin and glycol, and a mixture thereof. (c) The foundation according to any one of claims 1 to 6, wherein the water-soluble polyol is selected from water-soluble polyols having 3 or less carbon atoms. (d) The foundation according to any one of claims 1 to 7, wherein the surfactant is selected from a nonionic surfactant and a silicone surfactant. (e) The foundation according to any one of claims 1 to 8, further comprising at least one lipophilic thickener. (f) The foundation according to any one of claims 1 to 9, further comprising at least one alcohol. (a) The foundation according to any one of claims 1 to 10, wherein the film-forming agent is present in the foundation in a content in the range of 0.1% by mass to 10% by mass with respect to the total mass of the foundation . (b) The invention according to any one of claims 1 to 11, wherein the non-volatile hydrocarbon oil is present in the foundation in a content in the range of 10% by mass to 70% by mass with respect to the total mass of the foundation . Foundation . (c) The foundation according to any one of claims 1 to 12, wherein the water-soluble polyol is present in the foundation in a content in the range of 2% by mass to 10% by mass with respect to the total mass of the foundation .