WO2017094030A3 - Active support metal catalyst and its method of preparation thereof - Google Patents

Active support metal catalyst and its method of preparation thereof Download PDF

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Publication number
WO2017094030A3
WO2017094030A3 PCT/IN2016/050432 IN2016050432W WO2017094030A3 WO 2017094030 A3 WO2017094030 A3 WO 2017094030A3 IN 2016050432 W IN2016050432 W IN 2016050432W WO 2017094030 A3 WO2017094030 A3 WO 2017094030A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
preparation
metal catalyst
active
support metal
Prior art date
Application number
PCT/IN2016/050432
Other languages
French (fr)
Other versions
WO2017094030A2 (en
Inventor
Snehesh SHIVANANDA AIL
S Dasappa
Original Assignee
Indian Institute Of Science
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Indian Institute Of Science filed Critical Indian Institute Of Science
Publication of WO2017094030A2 publication Critical patent/WO2017094030A2/en
Publication of WO2017094030A3 publication Critical patent/WO2017094030A3/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/34—Manganese
    • B01J35/615—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing

Abstract

There is provided an active - support metal catalyst, and especially a high dispersion cobalt catalyst, with enhanced active metal sites having desired structural integrity. The present invention also provides a method for the preparation of the metal catalyst, preferably, cobalt catalyst, under combustion. Said method involves a step of preparing a redox mixture of a metal salt precursor and a reducing fuel in water, and contacting the redox mixture with the active support. The catalyst may be used for the conversion of carbon monoxide and hydrogen to higher hydrocarbons.
PCT/IN2016/050432 2015-12-03 2016-12-02 Active support metal catalyst and its method of preparation thereof WO2017094030A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IN6490CH2015 2015-12-03
IN6490/CHE/2015 2015-12-03

Publications (2)

Publication Number Publication Date
WO2017094030A2 WO2017094030A2 (en) 2017-06-08
WO2017094030A3 true WO2017094030A3 (en) 2017-08-17

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IN2016/050432 WO2017094030A2 (en) 2015-12-03 2016-12-02 Active support metal catalyst and its method of preparation thereof

Country Status (1)

Country Link
WO (1) WO2017094030A2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX2019008622A (en) 2019-07-19 2021-01-20 Mexicano Inst Petrol Hydroprocessing of heavy crudes by catalysts in homogenous phase.

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3133029A (en) * 1960-12-27 1964-05-12 Universal Oil Prod Co Method of preparing a copper, cobalt or nickel catalyst
US20110301024A1 (en) * 2009-02-26 2011-12-08 Sasol Technology (Proprietary) Limited Process for the preparation of fischer-tropsch catalysts and their use

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3133029A (en) * 1960-12-27 1964-05-12 Universal Oil Prod Co Method of preparing a copper, cobalt or nickel catalyst
US20110301024A1 (en) * 2009-02-26 2011-12-08 Sasol Technology (Proprietary) Limited Process for the preparation of fischer-tropsch catalysts and their use

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
DATABASE COMPENDEX [online] ENGINEERING INFORMATION, INC., NEW YORK, NY, US; May 2002 (2002-05-01), PRAKASH A S ET AL: "Hexamethylenetetramine: A new fuel for solution combustion synthesis of complex metal oxides", XP002769887, Database accession no. E2003087364387 *
FRANÇOIS DUMOND ET AL: "A Study of Cobalt Speciation in Co/Al 2 O 3 Catalysts Prepared from Solutions of Cobalt-Ethylenediamine Complexes", JOURNAL OF PHYSICAL CHEMISTRY C, vol. 111, no. 12, March 2007 (2007-03-01), US, pages 4780 - 4789, XP055369778, ISSN: 1932-7447, DOI: 10.1021/jp067781w *
JOURNAL OF MATERIALS SYNTHESIS AND PROCESSING MAY 2002 KLUWER ACADEMIC/PLENUM PUBLISHERS US, vol. 10, no. 3, May 2002 (2002-05-01), pages 135 - 141, DOI: 10.1023/A:1021986613158 *
SERGIO L. GONZÁLEZ-CORTÉS ET AL: "Fundamentals, properties and applications of solid catalysts prepared by solution combustion synthesis (SCS)", APPLIED CATALYSIS A: GENERAL, vol. 452, 8 December 2012 (2012-12-08), AMSTERDAM, NL, pages 117 - 131, XP055369771, ISSN: 0926-860X, DOI: 10.1016/j.apcata.2012.11.024 *
ZAVYALOVA ET AL: "Influence of cobalt precursor and fuels on the performance of combustion synthesized Co"3O"4/@c-Al"2O"3 catalysts for total oxidation of methane", APPLIED CATALYSIS A: GENERAL, ELSEVIER, AMSTERDAM, NL, vol. 323, 23 April 2007 (2007-04-23), pages 226 - 233, XP022021815, ISSN: 0926-860X, DOI: 10.1016/J.APCATA.2007.02.021 *

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