WO2017083730A1 - Method of coating a cast alloy wheel providing a two-tone appearance - Google Patents

Method of coating a cast alloy wheel providing a two-tone appearance Download PDF

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Publication number
WO2017083730A1
WO2017083730A1 PCT/US2016/061643 US2016061643W WO2017083730A1 WO 2017083730 A1 WO2017083730 A1 WO 2017083730A1 US 2016061643 W US2016061643 W US 2016061643W WO 2017083730 A1 WO2017083730 A1 WO 2017083730A1
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WO
WIPO (PCT)
Prior art keywords
polymeric coating
metal
polymeric
coating
set forth
Prior art date
Application number
PCT/US2016/061643
Other languages
French (fr)
Inventor
Don Stebbins
Thomas Schwing
Original Assignee
Superior Industries International, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Superior Industries International, Inc. filed Critical Superior Industries International, Inc.
Priority to EP20174615.3A priority Critical patent/EP3722456A1/en
Priority to JP2018524444A priority patent/JP2019503838A/en
Priority to PL16865139T priority patent/PL3374126T3/en
Priority to MX2018005906A priority patent/MX2018005906A/en
Priority to EP16865139.6A priority patent/EP3374126B1/en
Publication of WO2017083730A1 publication Critical patent/WO2017083730A1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/36Successively applying liquids or other fluent materials, e.g. without intermediate treatment
    • B05D1/38Successively applying liquids or other fluent materials, e.g. without intermediate treatment with intermediate treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/007After-treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/12Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by mechanical means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/06Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
    • B05D5/065Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects having colour interferences or colour shifts or opalescent looking, flip-flop, two tones
    • B05D5/066Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects having colour interferences or colour shifts or opalescent looking, flip-flop, two tones achieved by multilayers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/56Three layers or more
    • B05D7/57Three layers or more the last layer being a clear coat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60BVEHICLE WHEELS; CASTORS; AXLES FOR WHEELS OR CASTORS; INCREASING WHEEL ADHESION
    • B60B3/00Disc wheels, i.e. wheels with load-supporting disc body
    • B60B3/02Disc wheels, i.e. wheels with load-supporting disc body with a single disc body integral with rim
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60BVEHICLE WHEELS; CASTORS; AXLES FOR WHEELS OR CASTORS; INCREASING WHEEL ADHESION
    • B60B3/00Disc wheels, i.e. wheels with load-supporting disc body
    • B60B3/10Disc wheels, i.e. wheels with load-supporting disc body apertured to simulate spoked wheels
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/02Pretreatment of the material to be coated
    • C23C14/024Deposition of sublayers, e.g. to promote adhesion of the coating
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14Metallic material, boron or silicon
    • C23C14/16Metallic material, boron or silicon on metallic substrates or on substrates of boron or silicon
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/24Vacuum evaporation
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/58After-treatment
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/58After-treatment
    • C23C14/5873Removal of material
    • C23C14/588Removal of material by mechanical treatment
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D13/00Electrophoretic coating characterised by the process
    • C25D13/04Electrophoretic coating characterised by the process with organic material
    • C25D13/06Electrophoretic coating characterised by the process with organic material with polymers
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D13/00Electrophoretic coating characterised by the process
    • C25D13/12Electrophoretic coating characterised by the process characterised by the article coated
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/56Three layers or more
    • B05D7/57Three layers or more the last layer being a clear coat
    • B05D7/576Three layers or more the last layer being a clear coat each layer being cured, at least partially, separately
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60BVEHICLE WHEELS; CASTORS; AXLES FOR WHEELS OR CASTORS; INCREASING WHEEL ADHESION
    • B60B2310/00Manufacturing methods
    • B60B2310/60Surface treatment; After treatment
    • B60B2310/621Electro-chemical processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60BVEHICLE WHEELS; CASTORS; AXLES FOR WHEELS OR CASTORS; INCREASING WHEEL ADHESION
    • B60B2310/00Manufacturing methods
    • B60B2310/60Surface treatment; After treatment
    • B60B2310/64Effect of treatments
    • B60B2310/652Reflecting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60BVEHICLE WHEELS; CASTORS; AXLES FOR WHEELS OR CASTORS; INCREASING WHEEL ADHESION
    • B60B2310/00Manufacturing methods
    • B60B2310/60Surface treatment; After treatment
    • B60B2310/64Effect of treatments
    • B60B2310/656Decorative
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60BVEHICLE WHEELS; CASTORS; AXLES FOR WHEELS OR CASTORS; INCREASING WHEEL ADHESION
    • B60B2360/00Materials; Physical forms thereof
    • B60B2360/10Metallic materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60BVEHICLE WHEELS; CASTORS; AXLES FOR WHEELS OR CASTORS; INCREASING WHEEL ADHESION
    • B60B2360/00Materials; Physical forms thereof
    • B60B2360/30Synthetic materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60BVEHICLE WHEELS; CASTORS; AXLES FOR WHEELS OR CASTORS; INCREASING WHEEL ADHESION
    • B60B2900/00Purpose of invention
    • B60B2900/20Avoidance of
    • B60B2900/212Damage
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60BVEHICLE WHEELS; CASTORS; AXLES FOR WHEELS OR CASTORS; INCREASING WHEEL ADHESION
    • B60B2900/00Purpose of invention
    • B60B2900/50Improvement of
    • B60B2900/572Visual appearance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60BVEHICLE WHEELS; CASTORS; AXLES FOR WHEELS OR CASTORS; INCREASING WHEEL ADHESION
    • B60B3/00Disc wheels, i.e. wheels with load-supporting disc body
    • B60B3/06Disc wheels, i.e. wheels with load-supporting disc body formed by casting

Definitions

  • the present application relates generally toward a process for coating cast alloy wheels. More specifically, the present application relates toward a method of coating a cast alloy wheel to achieve a unique metallic, two-tone color appearance.
  • Cast alloy wheels have been increasing in market share for many years. Cast alloys provide both weight reduction and unique appearance not available to old style steel wheels decorated with hubcaps. Various methods for providing a durable and aesthetically pleasing coating to cast alloy wheels have varied widely. Early versions of cast alloy wheels were coated with lacquer paint, which provided aesthetically pleasing qualities, but did not provide necessary durability. Later generations of cast alloy wheels were coated with multilayer paint systems that included primers, colorization or base coats, and a clear coat to provide a high level of gloss to the alloy wheel. In some instances, the paint coatings are removed so that the substrate of the cast alloy is exposed to achieve a unique, "bright metallic surface" over which a clear coat is applied.
  • PVD physical vapor deposition
  • a cast alloy wheel includes a primary surface and a secondary surface.
  • the first polymeric coating is applied to the primary surface and to the secondary surface to seal the cast alloy wheel.
  • An intermediate polymeric coating is applied over the first polymeric coating.
  • the intermediate polymeric coating is subsequently coated with a metal using a physical vapor deposition process where the metal is aesthetically distinguishable from the first polymeric coating.
  • a third polymeric coating is applied over the metal.
  • the third polymeric coating, the intermediate polymeric coating, and the metal are removed from the primary cast alloy wheel exposing the first polymeric coating to aesthetically distinguish the primary surface from the secondary surface.
  • a fourth polymeric coating is applied over the primary surface and the secondary surface.
  • Inventive coating method of the present application provides a smooth metallic appearance along with a two-tone quality without having to machine a bright surface of a wheel.
  • the metallic alloy provides an appreciable metallic appearance to the wheel with a two-tone quality after removal of a portion of the metallic coating from the primary surface of the wheel. Therefore, enhanced aesthetic qualities not previously available on cast alloy wheels are now achievable providing that unique two-tone appearance taking advantage of the best features of the PVD applied metal and a polymeric coating.
  • Figure 1 shows a perspective view of a cast alloy wheel
  • Figure 2 shows a front view of a cast alloy wheel
  • Figure 3 shows a cross-sectional view of a cast alloy wheel having been subject to the method of coating of the present application
  • Figure 4 shows a cross-sectional view of an alternative embodiment of the cast alloy wheel subject to the method of coating of the present invention.
  • Figure 5 shows a cross-sectional view of a still further alternative embodiment of the cast alloy wheel subject to the method of coating of the present invention.
  • a cast alloy wheel of the present invention is generally shown at 10.
  • the wheel 10 is cast from an aluminum alloy, a magnesium alloy, a titanium alloy, or an equivalent alloy as is known to those of skill in the art.
  • the wheel 10 includes a rim element 12 that defines an axis a ( Figure 2).
  • a central element 14 extends radially outwardly between the axis a and the rim element 12.
  • the rim element 12 defines a drop surface (or annular wall) 16 extending between a distal bead 18 and a proximal bead 20 at a location that is disposed radially inwardly from the two beads, 18, 20.
  • proximal bead 18 is located outboard of a motor vehicle (not shown) and the distal bead 20 is located inboard of the motor vehicle.
  • the drop surface 16 is defined as a cylindrical surface circumscribing the axis a in a known manner.
  • the central element 14 includes a plurality of spokes
  • Each spoke 22 includes a face or primary surface 24.
  • a secondary surface 26 extends axially toward the distal bead rearward from the primary surface 24. It should be understood that the secondary surface 26 includes all surfaces extending axially in the direction of the distal bead 18 that are visibly apparent. This includes opposing sidewalls 28 of the spokes 22 and inner annular wall surface 30. It should be understood by those of ordinary skill in the art that the configuration of the spokes 22 and of the central element 14 is merely exemplary and that a wide variety of spoke and central element configurations are included within the scope of this invention. Further, the primary surface 24 also includes the central element 14 in some embodiments.
  • FIG. 3 a cross-sectional view of a portion of the primary surface 24 is shown.
  • the wheel 10 is subject to cleaning and pretreatment in a known manner.
  • a first polymeric coating or primer 34 is applied to the cast alloy 32 in a known manner.
  • the first polymeric coating 34 optionally includes one of a powder coating, an autophoretic coating, an electrodeposition coating, or any other coating known to provide environmental durability against defects such as, for example, corrosion or stone chipping.
  • the first polymeric coating 34 is pigmented to provide a desirable color, the purpose of which will be explained further herein below.
  • a film thickness of the first polymeric coating 34 is contemplated to be between 3SS microns and 381 microns. However, if the primary surface 24 is not machined, it is believed the film thickness would be increased.
  • An intermediate polymeric coating 36 is applied over the first polymeric coating
  • the intermediate polymeric coating 36 is contemplated to be applied by way of a spray system, being either powder or liquid.
  • the intermediate polymeric coating 36 is smoother than the first polymeric coating 34 and provides a high gloss appearance.
  • the intermediate polymeric coating 36 includes a film thickness between about 100 microns and ISO microns.
  • the intermediate polymeric coating 36 is not pigmented to provide any visible coloration, but is clear or substantially transparent.
  • the intermediate polymeric coating 36 is pigmented to achieve an identical or similar color as the first polymeric coating 34, or, in the alternative, a distinguishing color from the first polymeric coating 34, the purpose of which will become more evident herein below.
  • a metallic layer 38 is applied over the intermediate polymeric coating 36 using a
  • PVD process to achieve a reflective or mirrored metallic appearance or finish.
  • various metals including, but not limited to, chromium, nickel, aluminum, silver, gold and even alloys are applied by the PVD process set forth in United States Patent Number 5,656,335, or an equivalent process, the contents of which are included herein by reference, and will not be further discussed.
  • the high gloss intermediate polymeric coating 36 enhances the mirrored appearance of the metallic layer 38.
  • the PVD process encapsulates the wheel 10, and the first polymeric coating with the metal. As used herein, encapsulates and encapsulating includes substantial encapsulation where some gaps may exists as part of process variability and further includes encapsulating primary and secondary surfaces 24, 26 of the vehicle wheel 10.
  • the metallic layer 38 can provide a bright, shiny finish achieving a desirable and aesthetically pleasing gloss representative of a machined or polished substrate.
  • the metallic layer 38 includes a film thickness of between 0.1 microns and 0.3 microns. The metal forming the metallic layer 38 forms a physical and molecular bond to the intermediate polymer coating 36 providing desirable adhesion desirable for further processing.
  • a third polymeric coating 40 is applied over the metallic layer 38.
  • the third polymeric coating 40 is a clear coating providing no pigmentation.
  • the coating is contemplated to be a urethane, acrylic, polyester, or any other polymer coating capable of achieving desired performance characteristics.
  • the third polymeric coating 40 provides additional gloss to the metallic layer 38.
  • the third polymeric coating 40 is lightly pigmented to provide alternate color appearance to the metallic layer 38, which is contemplated to include opalescent pigments and other light reflective properties.
  • the wheel 10 is placed in a precision lame, or equivalent machine and at the primary surface 24 a predetermined portion of the intermediate polymeric coating 36, the metallic layer 38, and the third polymeric coating 40 is removed exposing the first polymeric coating 34.
  • the same lathe may be used to remove the various layers 36, 38, and 40 from the primary surface as performs the pre-machining. In one embodiment, between about 12S microns and 180 microns of the first polymeric coating 34 are removed. Therefore, a two-tone appearance is achieved when the first polymeric coating 34 is pigmented in a manner to distinguish the first polymeric coating 34 from the metallic layer 34.
  • Pre-machining the primary surface 24 is believed to reduce fallout where the wheel substrate 32 might be exposed due to undesirable surface roughness when removing 125 microns to 180 microns of the first polymeric coating 34.
  • the intermediate polymeric coating 36 is not visible either by a contour machined at the primary surface 24, or because the pigmentation, or lack of pigmentation makes the intermediate polymeric coating 36 indistinguishable from the first polymeric coating 34.
  • the intermediate polymeric coating 36 is distinguishable from the first polymeric coating 34 providing a bead or appearance of a bead circumscribing the predetermined portion of the primary surface 24.
  • a final clear polymeric coating 42 is applied over, at least the primary surface 24 of the wheel 10.
  • the primary surface 42 and the secondary surface 26 of the wheel 10 are coated with the clear polymeric coating 42 to achieve a consistent gloss level throughout the visible spectrum of the wheel 10.
  • the wheel prior to applying the final clear polymeric coating 42, the wheel is subjected to cleaning and further pretreatment to prevent dirt and contamination from being entrapped in the final clear polymeric coating 42.
  • the combination of paint and metallic layers, after the application of the clear polymeric coating 42 includes a substantially common film thickness at the primary surface 24 of the wheel 10.
  • the combined film thickness at the secondary surface 26 of the wheel 10 is somewhat less than that of the primary surface 24 of the wheel 10. It should be further understood that the intermediate polymeric coating 36 is optional and may not be applied. In this embodiment, the first polymeric coating 34 may include an additional thickness to achieve the desired combined film thickness.
  • FIG. 4 An alternative embodiment is shown in Figure 4 wherein like elements include like element numbers as that of the embodiment disclosed in Figure 3.
  • a second intermediate polymeric coating 44 is applied between the intermediate polymeric coating 36 and the metallic layer 38.
  • the wheel 10 is placed in a mill and a predetermined portion of the third polymeric coating 40, the metallic layer 38, the second intermediate polymeric coating 44, the intermediate polymeric coating 36 are removed exposing the first polymeric coating 34.
  • the second intermediate polymeric coating 44 includes a different pigmentation than that of the first polymeric coating 36 providing further distinguishing beads or circumscribing coloration at the primary surface 24.
  • the second intermediate polymeric coating 44 may be pigmented to match various features or coloration on a motor vehicle (not shown) on which the wheel 10 is mounted.
  • FIG. 4 A further embodiment is shown in Figure 4 where like elements include like element numbers as the prior embodiments.
  • the milling operation removes an entire predetermined portion of the first polymeric coating 34 exposing the cast alloy substrate 32. Further, the milling operation is capable of adding a design feature by changing the contour of the cast alloy substrate 32. Therefore, the clear polymeric coating 42 coats the cast alloy substrate 32 of the wheel 10. As such, machine operation achieves a desired surface roughness of a cast alloy substrate 32 to achieve a "bright" surface further distinguished from the metallic layer 38. In this manner, two different aesthetically distinguished metallic areas are disposed upon the primary surface 24 of the wheel 10 achieving a unique appearance not previously thought obtainable without significantly difficult processing.
  • pigmentation of the optional intermediate polymeric layer 36, the second intermediate polymeric layer 44 can achieve additional distinguishing characteristics as set forth above.
  • Ultraviolet absorbers may also be included in any of the paint layers to prevent degradation of the paint, and even discoloration of the metallic layer 38. As set forth above, different pigmentation may also be included in either one of or both the third polymeric coating 40 or the fourth polymeric coating 42. In addition, multiple metallic affects may be achieved by exposing the cast alloy substrate of the primary surface 24 to be contrasted by a complimentary or distinguishable metal 38 applied by PVD process.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Laminated Bodies (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)

Abstract

A cast wheel having an alloy substrate includes a primary surface and a secondary surface. A first polymeric coating is applied to the primary surface and to the secondary surface sealing the cast alloy wheel within the first polymeric coating. An intermediate polymeric coating is applied over the first polymeric coating. The intermediate polymeric coating is coated with metal using plasma deposition with the metal being esthetically distinguishable from the first polymeric coating. A second polymeric coating is applied over the metal. The second polymeric coating and the metal from the primary surface of the cast alloy wheel are removed aesthetically distinguishing the primary surface from the secondary surface. A third polymeric coating is applied over the primary surface and the secondary surface.

Description

METHOD OF COATING A CAST ALLOY WHEEL
PROVIDING A TWO-TONE APPEARANCE
PRIOR APPLICATIONS
[0001] The present application claims priority to United States Provisional Patent
Application No. 62/253,923 filed November 11, 2015, the contents of which are incorporated herein by reference.
TECHNICAL FIELD
[0002] The present application relates generally toward a process for coating cast alloy wheels. More specifically, the present application relates toward a method of coating a cast alloy wheel to achieve a unique metallic, two-tone color appearance.
BACKGROUND
[0003] Cast alloy wheels have been increasing in market share for many years. Cast alloys provide both weight reduction and unique appearance not available to old style steel wheels decorated with hubcaps. Various methods for providing a durable and aesthetically pleasing coating to cast alloy wheels have varied widely. Early versions of cast alloy wheels were coated with lacquer paint, which provided aesthetically pleasing qualities, but did not provide necessary durability. Later generations of cast alloy wheels were coated with multilayer paint systems that included primers, colorization or base coats, and a clear coat to provide a high level of gloss to the alloy wheel. In some instances, the paint coatings are removed so that the substrate of the cast alloy is exposed to achieve a unique, "bright metallic surface" over which a clear coat is applied.
[0004] Later generations of cast alloy wheels have been provided with a metallic finish without requiring significant machining to provide a metallic aesthetic by exposing the cast alloy substrate. One such example is the use of physical vapor deposition (PVD) used to apply various alloys and metals such as, for example, aluminum, chromium, titanium, silver, nickel, and even gold over one or more layers of paint or primer that are applied to the substrate to provide a sufficiently smooth surface to receive the PVD metal coat. PVD processes have been used to coat wheels and are disclosed in United States Patent Number 5,656,335, the contents of which are enclosed herein by reference.
[0005] However, consumers of vehicles having cast alloy wheels demand ever- improving and unique aesthetic qualities, such as, for example, two-tone or even multi-tone appearance providing various colors to the visible surface of the cast alloy wheel. Therefore, it would be desirable to provide a two-tone appearance to a cast alloy wheel while still making use of the desirable qualities provided by PVD coatings not presently available.
SUMMARY
[0006] A cast alloy wheel includes a primary surface and a secondary surface. The first polymeric coating is applied to the primary surface and to the secondary surface to seal the cast alloy wheel. An intermediate polymeric coating is applied over the first polymeric coating. The intermediate polymeric coating is subsequently coated with a metal using a physical vapor deposition process where the metal is aesthetically distinguishable from the first polymeric coating. A third polymeric coating is applied over the metal. The third polymeric coating, the intermediate polymeric coating, and the metal are removed from the primary cast alloy wheel exposing the first polymeric coating to aesthetically distinguish the primary surface from the secondary surface. A fourth polymeric coating is applied over the primary surface and the secondary surface.
[0007] Inventive coating method of the present application provides a smooth metallic appearance along with a two-tone quality without having to machine a bright surface of a wheel. The metallic alloy provides an appreciable metallic appearance to the wheel with a two-tone quality after removal of a portion of the metallic coating from the primary surface of the wheel. Therefore, enhanced aesthetic qualities not previously available on cast alloy wheels are now achievable providing that unique two-tone appearance taking advantage of the best features of the PVD applied metal and a polymeric coating.
BRIEF DESCRIPTION OF THE DRAWINGS
[0008] Other advantages of the present invention will be readily appreciated as the same becomes better understood by reference to the following detailed description, when considered in connection with the accompanying drawings, wherein:
[0009] Figure 1 shows a perspective view of a cast alloy wheel;
[0010] Figure 2 shows a front view of a cast alloy wheel;
[0011] Figure 3 shows a cross-sectional view of a cast alloy wheel having been subject to the method of coating of the present application;
[0012] Figure 4 shows a cross-sectional view of an alternative embodiment of the cast alloy wheel subject to the method of coating of the present invention; and
[0013] Figure 5 shows a cross-sectional view of a still further alternative embodiment of the cast alloy wheel subject to the method of coating of the present invention. DETAILED DESCRIPTION
[0014] Referring to Figure 1, a cast alloy wheel of the present invention is generally shown at 10. The wheel 10 is cast from an aluminum alloy, a magnesium alloy, a titanium alloy, or an equivalent alloy as is known to those of skill in the art. The wheel 10 includes a rim element 12 that defines an axis a (Figure 2). A central element 14 extends radially outwardly between the axis a and the rim element 12. The rim element 12 defines a drop surface (or annular wall) 16 extending between a distal bead 18 and a proximal bead 20 at a location that is disposed radially inwardly from the two beads, 18, 20. It should be understood by those of ordinary skill in the art that the proximal bead 18 is located outboard of a motor vehicle (not shown) and the distal bead 20 is located inboard of the motor vehicle. Furthermore, the drop surface 16 is defined as a cylindrical surface circumscribing the axis a in a known manner.
[0015] Referring now to Figure 2, the central element 14 includes a plurality of spokes
22. Each spoke 22 includes a face or primary surface 24. A secondary surface 26 extends axially toward the distal bead rearward from the primary surface 24. It should be understood that the secondary surface 26 includes all surfaces extending axially in the direction of the distal bead 18 that are visibly apparent. This includes opposing sidewalls 28 of the spokes 22 and inner annular wall surface 30. It should be understood by those of ordinary skill in the art that the configuration of the spokes 22 and of the central element 14 is merely exemplary and that a wide variety of spoke and central element configurations are included within the scope of this invention. Further, the primary surface 24 also includes the central element 14 in some embodiments.
[0016] Referring now to Figure 3, a cross-sectional view of a portion of the primary surface 24 is shown. A cast alloy 32 defining the primary surface 24 as an unfinished surface that includes an undesirable surface roughness not known to provide aesthetically pleasing qualities without additional processing. Therefore, in one embodiment the primary surface 24 is pre-machined to reduce the surface roughness. However, it is also within the scope of this invention that the primary surface 24 is not pre-machined in alternative embodiments. After forming and pre-machining, the wheel 10 is subject to cleaning and pretreatment in a known manner. A first polymeric coating or primer 34 is applied to the cast alloy 32 in a known manner. The first polymeric coating 34 optionally includes one of a powder coating, an autophoretic coating, an electrodeposition coating, or any other coating known to provide environmental durability against defects such as, for example, corrosion or stone chipping. In addition, the first polymeric coating 34 is pigmented to provide a desirable color, the purpose of which will be explained further herein below. A film thickness of the first polymeric coating 34 is contemplated to be between 3SS microns and 381 microns. However, if the primary surface 24 is not machined, it is believed the film thickness would be increased.
[0017] An intermediate polymeric coating 36 is applied over the first polymeric coating
34. The intermediate polymeric coating 36 is contemplated to be applied by way of a spray system, being either powder or liquid. The intermediate polymeric coating 36 is smoother than the first polymeric coating 34 and provides a high gloss appearance. In addition, the intermediate polymeric coating 36 includes a film thickness between about 100 microns and ISO microns. In one embodiment, the intermediate polymeric coating 36 is not pigmented to provide any visible coloration, but is clear or substantially transparent. In an alternative embodiment, the intermediate polymeric coating 36 is pigmented to achieve an identical or similar color as the first polymeric coating 34, or, in the alternative, a distinguishing color from the first polymeric coating 34, the purpose of which will become more evident herein below.
[0018] A metallic layer 38 is applied over the intermediate polymeric coating 36 using a
PVD process to achieve a reflective or mirrored metallic appearance or finish. As such, various metals including, but not limited to, chromium, nickel, aluminum, silver, gold and even alloys are applied by the PVD process set forth in United States Patent Number 5,656,335, or an equivalent process, the contents of which are included herein by reference, and will not be further discussed. The high gloss intermediate polymeric coating 36 enhances the mirrored appearance of the metallic layer 38. The PVD process encapsulates the wheel 10, and the first polymeric coating with the metal. As used herein, encapsulates and encapsulating includes substantial encapsulation where some gaps may exists as part of process variability and further includes encapsulating primary and secondary surfaces 24, 26 of the vehicle wheel 10. Having achieved a desirable roughness value of the intermediate polymeric coating 36, the metallic layer 38 can provide a bright, shiny finish achieving a desirable and aesthetically pleasing gloss representative of a machined or polished substrate. In one embodiment, the metallic layer 38 includes a film thickness of between 0.1 microns and 0.3 microns. The metal forming the metallic layer 38 forms a physical and molecular bond to the intermediate polymer coating 36 providing desirable adhesion desirable for further processing.
[0019] A third polymeric coating 40 is applied over the metallic layer 38. In one embodiment, the third polymeric coating 40 is a clear coating providing no pigmentation. The coating is contemplated to be a urethane, acrylic, polyester, or any other polymer coating capable of achieving desired performance characteristics. When not pigmented, the third polymeric coating 40 provides additional gloss to the metallic layer 38. In an alternative embodiment, the third polymeric coating 40 is lightly pigmented to provide alternate color appearance to the metallic layer 38, which is contemplated to include opalescent pigments and other light reflective properties.
[0020] After the third polymeric coating has been applied, the wheel 10 is placed in a precision lame, or equivalent machine and at the primary surface 24 a predetermined portion of the intermediate polymeric coating 36, the metallic layer 38, and the third polymeric coating 40 is removed exposing the first polymeric coating 34. It is contemplated that the same lathe may be used to remove the various layers 36, 38, and 40 from the primary surface as performs the pre-machining. In one embodiment, between about 12S microns and 180 microns of the first polymeric coating 34 are removed. Therefore, a two-tone appearance is achieved when the first polymeric coating 34 is pigmented in a manner to distinguish the first polymeric coating 34 from the metallic layer 34. Pre-machining the primary surface 24 is believed to reduce fallout where the wheel substrate 32 might be exposed due to undesirable surface roughness when removing 125 microns to 180 microns of the first polymeric coating 34.
[0021] In another embodiment, the intermediate polymeric coating 36 is not visible either by a contour machined at the primary surface 24, or because the pigmentation, or lack of pigmentation makes the intermediate polymeric coating 36 indistinguishable from the first polymeric coating 34. Alternatively, the intermediate polymeric coating 36 is distinguishable from the first polymeric coating 34 providing a bead or appearance of a bead circumscribing the predetermined portion of the primary surface 24.
[0022] Once the desirable two-tone effect has been achieved, a final clear polymeric coating 42 is applied over, at least the primary surface 24 of the wheel 10. Alternatively, the primary surface 42 and the secondary surface 26 of the wheel 10 are coated with the clear polymeric coating 42 to achieve a consistent gloss level throughout the visible spectrum of the wheel 10. However, prior to applying the final clear polymeric coating 42, the wheel is subjected to cleaning and further pretreatment to prevent dirt and contamination from being entrapped in the final clear polymeric coating 42. It should be understood by those of ordinary skill in the art that the combination of paint and metallic layers, after the application of the clear polymeric coating 42 includes a substantially common film thickness at the primary surface 24 of the wheel 10. However, it is further contemplated that the combined film thickness at the secondary surface 26 of the wheel 10 is somewhat less than that of the primary surface 24 of the wheel 10. It should be further understood that the intermediate polymeric coating 36 is optional and may not be applied. In this embodiment, the first polymeric coating 34 may include an additional thickness to achieve the desired combined film thickness.
[0023] An alternative embodiment is shown in Figure 4 wherein like elements include like element numbers as that of the embodiment disclosed in Figure 3. In this embodiment, a second intermediate polymeric coating 44 is applied between the intermediate polymeric coating 36 and the metallic layer 38. Like in the first embodiment, the wheel 10 is placed in a mill and a predetermined portion of the third polymeric coating 40, the metallic layer 38, the second intermediate polymeric coating 44, the intermediate polymeric coating 36 are removed exposing the first polymeric coating 34. In this embodiment, the second intermediate polymeric coating 44 includes a different pigmentation than that of the first polymeric coating 36 providing further distinguishing beads or circumscribing coloration at the primary surface 24. In this manner, the second intermediate polymeric coating 44 may be pigmented to match various features or coloration on a motor vehicle (not shown) on which the wheel 10 is mounted.
[0024] A further embodiment is shown in Figure 4 where like elements include like element numbers as the prior embodiments. In this embodiment, the milling operation removes an entire predetermined portion of the first polymeric coating 34 exposing the cast alloy substrate 32. Further, the milling operation is capable of adding a design feature by changing the contour of the cast alloy substrate 32. Therefore, the clear polymeric coating 42 coats the cast alloy substrate 32 of the wheel 10. As such, machine operation achieves a desired surface roughness of a cast alloy substrate 32 to achieve a "bright" surface further distinguished from the metallic layer 38. In this manner, two different aesthetically distinguished metallic areas are disposed upon the primary surface 24 of the wheel 10 achieving a unique appearance not previously thought obtainable without significantly difficult processing. In addition, pigmentation of the optional intermediate polymeric layer 36, the second intermediate polymeric layer 44 can achieve additional distinguishing characteristics as set forth above.
[0025] Ultraviolet absorbers may also be included in any of the paint layers to prevent degradation of the paint, and even discoloration of the metallic layer 38. As set forth above, different pigmentation may also be included in either one of or both the third polymeric coating 40 or the fourth polymeric coating 42. In addition, multiple metallic affects may be achieved by exposing the cast alloy substrate of the primary surface 24 to be contrasted by a complimentary or distinguishable metal 38 applied by PVD process.
[0026] Obviously, many modifications and variations of the present invention are possible in light of the above teachings. The foregoing invention has been described in accordance with relevant legal standards; thus, the description is merely exemplary rather than limiting in nature. Variations and modifications to the disclosed embodiment have become apparent to those skilled in the art and do come within the scope of this invention. Accordingly, the scope of the legal protection afforded this invention can only be determined by studying the following claims.

Claims

CLAIMS What is claimed is:
1. A method of coating a cast alloy wheel, comprising the steps of:
providing a cast wheel having an alloy substrate including a primary surface and a secondary surface;
applying a first polymeric coating to said primary surface and to said secondary surface thereby sealing said cast alloy wheel within said first polymeric coating;
applying an intermediate polymeric coating over said first polymeric coating;
coating the intermediate polymeric coating with metal using vapor deposition with said metal being aesthetically distinguishable from said first polymeric coating;
applying a third polymeric coating over said metal;
removing said third polymeric coating, said intermediate coating and said metal from said primary surface of said cast alloy wheel thereby providing aesthetically distinguishing said primary surface from said secondary surface; and
applying a fourth polymeric coating over said primary surface and said secondary surface.
2. The method set forth in claim 1, wherein said step of applying a first polymeric coating to said primary surface and said secondary surface is further defined by providing pigmentation to said first polymeric coating being distinguishable from said metal.
3. The method set forth in claim 1, wherein said step of applying a fourth polymeric coating over said primary surface and said secondary surface is further defined by applying a clear fourth polymeric coating.
4. The method set forth in claim 1, wherein said step of applying a fourth polymeric coating over said primary surface and said secondary surface is further defined by applying a pigmented fourth polymeric coating.
5. The method set form in claim 1, further including the step of removing said first polymeric coating from said primary surface thereby exposing said alloy substrate of said cast wheel.
6. The method set forth in claim 1, wherein said step removing said third polymeric coating and said metal from said primary surface is further defined by removing a portion of said first polymeric coating thereby creating an aesthetic contrast between said metal and said first polymeric coating.
7. The method set forth in claim 1, further including the step of removing said first polymeric coating thereby exposing said alloy substrate thereby creating an aesthetic contrast between said metal and said alloy substrate.
8. The method set forth in claim 7, further including the step of applying a clear polymeric coating over said substrate and said third polymeric coating.
9. The method set forth in claim 1, further including the step of applying an intermediate polymeric coating between said metal and said first polymeric coating, wherein said intermediate polymeric coating includes a higher gloss level than does the first polymeric coating.
10. The method set forth in claim 9, wherein said step of applying a said intermediate polymeric coating is further defined by said intermediate polymeric coating being one of a clear polymeric coating, a pigmented polymeric coating distinguishable from said first polymeric coating, or a pigmented polymeric coating being indistinguishable from said first polymeric coating.
11. A vehicle wheel, comprising:
a cast alloy substrate comprising a first metal and defining a primary surface and a secondary surface;
a second metal defining an encapsulating layer over said first metal and being spaced from said first metal by a first polymeric coating with said first polymeric coating having a first thickness; and
said encapsulating layer of said second metal including an interruption at said primary surface thereby exposing said first polymeric layer, with said first polymeric layer being aesthetically distinguishable from said second metal.
12. The vehicle wheel set forth in claim 1, wherein said first polymeric layer includes a first film thickness disposed beneath said second metal and a second film thickness disposed at said interruption of said encapsulating layer, with said second film thickness being less than said first film thickness.
13. The vehicle wheel set forth in claim 1, wherein said first polymeric layer includes a first polymeric layer interruption disposed at said interruption of said encapsulating layer thereby exposing said first metal.
14. The vehicle wheel set forth in claim 13, wherein said first metal is aesthetically distinguishable from said second metal.
15. The vehicle wheel set forth in claim 1, further including an intermediate polymeric layer disposed between said second metal and said first polymeric material.
16. The vehicle wheel set forth in claim IS, wherein said intermediate polymeric layer includes an intermediate polymeric interruption disposed at said interruption of said metal at said primary surface.
17. The vehicle wheel set forth in claim 1, further including a second polymeric material overlaying said second metal.
18. The vehicle wheel set forth in claim 17, further including a clear polymeric material overlaying the second polymeric material.
19. The vehicle wheel set forth in claim 18, wherein said second polymeric material includes a second polymeric material interruption disposed at said interruption of said metal.
20. The vehicle wheel set forth in claim 1, wherein said encapsulating layer of metal partially encapsulates said vehicle wheel.
PCT/US2016/061643 2015-11-11 2016-11-11 Method of coating a cast alloy wheel providing a two-tone appearance WO2017083730A1 (en)

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JP2018524444A JP2019503838A (en) 2015-11-11 2016-11-11 Method for coating a cast alloy wheel with a two-tone appearance
PL16865139T PL3374126T3 (en) 2015-11-11 2016-11-11 Method of coating a cast alloy wheel providing a two-tone appearance
MX2018005906A MX2018005906A (en) 2015-11-11 2016-11-11 Method of coating a cast alloy wheel providing a two-tone appearance.
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PL3374126T3 (en) 2020-12-14
EP3722456A1 (en) 2020-10-14
JP2019503838A (en) 2019-02-14
EP3374126B1 (en) 2020-06-24
US20190308445A1 (en) 2019-10-10
US20170129279A1 (en) 2017-05-11
EP3374126A1 (en) 2018-09-19

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