WO2017078905A8 - Processes and systems for converting hydrocarbons to cyclopentadiene - Google Patents
Processes and systems for converting hydrocarbons to cyclopentadiene Download PDFInfo
- Publication number
- WO2017078905A8 WO2017078905A8 PCT/US2016/056048 US2016056048W WO2017078905A8 WO 2017078905 A8 WO2017078905 A8 WO 2017078905A8 US 2016056048 W US2016056048 W US 2016056048W WO 2017078905 A8 WO2017078905 A8 WO 2017078905A8
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- cyclopentadiene
- hydrocarbons
- effluent
- acyclic
- reaction zone
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/42—Platinum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
- B01J29/44—Noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/60—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
- B01J29/61—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789 containing iron group metals, noble metals or copper
- B01J29/62—Noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/90—Regeneration or reactivation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/02—Heat treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
- B01J38/10—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using elemental hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
- C07C2529/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
- C07C2529/44—Noble metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2603/00—Systems containing at least three condensed rings
- C07C2603/02—Ortho- or ortho- and peri-condensed systems
- C07C2603/04—Ortho- or ortho- and peri-condensed systems containing three rings
- C07C2603/06—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members
- C07C2603/10—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members containing five-membered rings
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
This invention relates to a process for converting acyclic C5 hydrocarbons to cyclopentadiene including: providing to the at least one adiabatic reaction zone a feedstock comprising acyclic C5 hydrocarbons at a temperature, Ti, wherein the at least one adiabatic reaction zone comprises a first particulate material comprising catalyst material; contacting the feedstock and the first particulate material in the at least one adiabatic reaction zone under reaction conditions to convert at least a portion of the acyclic C5 hydrocarbons to a first effluent comprising cyclopentadiene intermediates, unconverted acyclic C5 hydrocarbons, and, optionally, cyclopentadiene; heating the first effluent to a temperature, T2; providing the first effluent to the at least one diabatic reaction zone; and contacting the first effluent and a second particulate material comprising catalyst material in the at least one diabatic reaction zone under reaction conditions to convert at least a portion of the cyclopentadiene intermediates and the unconverted acyclic C5 hydrocarbons to a second effluent comprising cyclopentadiene.
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP16862675.2A EP3371142A4 (en) | 2015-11-04 | 2016-10-07 | Processes and systems for converting hydrocarbons to cyclopentadiene |
CN201680064160.XA CN108349839B (en) | 2015-11-04 | 2016-10-07 | Method and system for converting hydrocarbons to cyclopentadiene |
JP2018542669A JP6640365B2 (en) | 2015-11-04 | 2016-10-07 | Method and system for converting hydrocarbons to cyclopentadiene |
CA3004332A CA3004332C (en) | 2015-11-04 | 2016-10-07 | Processes and systems for converting hydrocarbons to cyclopentadiene |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201562250697P | 2015-11-04 | 2015-11-04 | |
US62/250,697 | 2015-11-04 | ||
EP16153727 | 2016-02-02 | ||
EP16153727.9 | 2016-02-02 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2017078905A1 WO2017078905A1 (en) | 2017-05-11 |
WO2017078905A8 true WO2017078905A8 (en) | 2017-08-10 |
Family
ID=55304867
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2016/056048 WO2017078905A1 (en) | 2015-11-04 | 2016-10-07 | Processes and systems for converting hydrocarbons to cyclopentadiene |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP3371142A4 (en) |
JP (1) | JP6640365B2 (en) |
CN (1) | CN108349839B (en) |
CA (1) | CA3004332C (en) |
WO (1) | WO2017078905A1 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2018534299A (en) | 2015-11-04 | 2018-11-22 | エクソンモービル ケミカル パテンツ インコーポレイテッド | Method for converting acyclic C5 compound to cyclic C5 compound and catalyst composition used therefor |
US10364200B2 (en) | 2017-05-03 | 2019-07-30 | Exxonmobil Chemical Patents Inc. | Processes and systems for the conversion of acyclic hydrocarbons |
CN110961127A (en) * | 2019-12-09 | 2020-04-07 | 大连理工大学 | Method for preparing loaded DCPD resin hydrogenation catalyst by using hydrotalcite-like compound as precursor |
CN113083360B (en) * | 2019-12-23 | 2023-07-25 | 中国石油化工股份有限公司 | Preparation method of titanium-silicon molecular sieve catalyst taking carbon nanofibers as carrier |
Family Cites Families (51)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2438400A (en) * | 1945-11-24 | 1948-03-23 | Sun Oil Co | Preparation of cyclopentadiene |
US2438404A (en) * | 1948-01-20 | 1948-03-23 | Sun Oil Co | Treatment of hydrocarbons |
US2982798A (en) | 1958-09-08 | 1961-05-02 | Phillips Petroleum Co | Co-current flow dehydrogenation system |
US3354078A (en) | 1965-02-04 | 1967-11-21 | Mobil Oil Corp | Catalytic conversion with a crystalline aluminosilicate activated with a metallic halide |
US3702886A (en) | 1969-10-10 | 1972-11-14 | Mobil Oil Corp | Crystalline zeolite zsm-5 and method of preparing the same |
US3709979A (en) | 1970-04-23 | 1973-01-09 | Mobil Oil Corp | Crystalline zeolite zsm-11 |
US3748255A (en) * | 1971-08-23 | 1973-07-24 | Gulf Research Development Co | Two stage dehydrocyclization process |
US4016245A (en) | 1973-09-04 | 1977-04-05 | Mobil Oil Corporation | Crystalline zeolite and method of preparing same |
DE2535809A1 (en) * | 1974-08-13 | 1976-03-04 | Shell Int Research | Cyclic 5C hydrocarbons from n-pentane feeds - by contact with hydrogen on a platinum-silica catalyst |
US3972832A (en) | 1974-09-23 | 1976-08-03 | Mobil Oil Corporation | Phosphorus-containing zeolite catalyst |
US4016218A (en) | 1975-05-29 | 1977-04-05 | Mobil Oil Corporation | Alkylation in presence of thermally modified crystalline aluminosilicate catalyst |
CA1064890A (en) | 1975-06-10 | 1979-10-23 | Mae K. Rubin | Crystalline zeolite, synthesis and use thereof |
US4229602A (en) * | 1978-12-04 | 1980-10-21 | Phillips Petroleum Company | Dehydrocyclization process |
US4375573A (en) | 1979-08-03 | 1983-03-01 | Mobil Oil Corporation | Selective production and reaction of p-Disubstituted aromatics over zeolite ZSM-48 |
DE3117135A1 (en) | 1981-04-30 | 1982-11-18 | Bayer Ag, 5090 Leverkusen | CRYSTALLINE ALUMOSILICATE, METHOD FOR THE PRODUCTION THEREOF AND THE USE THEREOF FOR CATALYTICALLY CONVERTING METHANOL AND / OR DIMETHYL ETHER IN HYDROCARBONS |
US5336478A (en) | 1982-04-30 | 1994-08-09 | Mobil Oil Corp. | Highly siliceous porous crystalline material |
US4640829A (en) | 1984-04-16 | 1987-02-03 | Mobil Oil Corporation | Synthesis of crystalline silicate ZSM-50 using dibenzyldimethylammonium ions and the product produced |
US4873067A (en) | 1984-08-21 | 1989-10-10 | Mobil Oil Corporation | Zeolite ZSM-57 |
US4698217A (en) | 1985-02-26 | 1987-10-06 | Mobil Oil Corporation | Crystalline silicate ZSM-58 and process for its preparation using a methyltropinium cation |
US4826667A (en) | 1986-01-29 | 1989-05-02 | Chevron Research Company | Zeolite SSZ-25 |
US4954325A (en) | 1986-07-29 | 1990-09-04 | Mobil Oil Corp. | Composition of synthetic porous crystalline material, its synthesis and use |
IT1205681B (en) | 1987-05-26 | 1989-03-31 | Eniricerche Spa | SYNTHETIC POROUS CRYSTALLINE MATERIAL CONTAINING SILICON AND BORON OXIDES |
JPH03501942A (en) * | 1987-11-17 | 1991-05-09 | モービル オイル コーポレーシヨン | Dehydrogenation and dehydrocyclization catalysts, their synthesis and applications |
DE3887990T2 (en) * | 1987-11-17 | 1994-06-01 | Mobil Oil Corp | DEHYDROGENATION CATALYST AND ITS USE. |
US4886926A (en) * | 1988-06-24 | 1989-12-12 | Mobil Oil Corporation | Catalytic dehydrogenation of hydrocarbons over tin-containing crystalline microporous materials |
US4973778A (en) | 1987-12-29 | 1990-11-27 | Mobil Oil Corp. | Continuous swing tubular reactor-regenerator |
US4827066A (en) * | 1988-05-23 | 1989-05-02 | Uop Inc. | Dehydrogenation of dehydrogenatable hydrocarbons |
US5192728A (en) * | 1988-06-24 | 1993-03-09 | Mobil Oil Corporation | Tin-colating microporous crystalline materials and their use as dehydrogenation, dehydrocyclization reforming catalysts |
US5250277A (en) | 1991-01-11 | 1993-10-05 | Mobil Oil Corp. | Crystalline oxide material |
US5236575A (en) | 1991-06-19 | 1993-08-17 | Mobil Oil Corp. | Synthetic porous crystalline mcm-49, its synthesis and use |
US5243122A (en) | 1991-12-30 | 1993-09-07 | Phillips Petroleum Company | Dehydrogenation process control |
IT1254988B (en) | 1992-06-23 | 1995-10-11 | Eniricerche Spa | Process for the dehydrogenation of light paraffins in a fluidised bed reactor |
US5362697A (en) | 1993-04-26 | 1994-11-08 | Mobil Oil Corp. | Synthetic layered MCM-56, its synthesis and use |
ES2124154B1 (en) | 1995-11-08 | 1999-12-01 | Univ Politecnica De Valencia C | PREPARATION METHOD AND CATALYTIC PROPERTIES OF A MICROPOROUS SOLID WITH HIGH EXTERNAL SURFACE. |
ES2105982B1 (en) | 1995-11-23 | 1998-07-01 | Consejo Superior Investigacion | ZEOLITE ITQ-1 |
US5811065A (en) | 1997-04-24 | 1998-09-22 | Ballard Generation Systems Inc. | Burner exhaust gas collection assembly for a catalytic reformer |
US6981994B2 (en) * | 2001-12-17 | 2006-01-03 | Praxair Technology, Inc. | Production enhancement for a reactor |
DE102004055826A1 (en) * | 2004-11-19 | 2006-05-24 | Basf Ag | Process and apparatus for fully hydrogenating a hydrocarbon stream |
JP5179882B2 (en) * | 2006-01-31 | 2013-04-10 | 旭化成ケミカルズ株式会社 | Catalyst for the production of aromatic hydrocarbon compounds |
US7906568B2 (en) * | 2007-09-04 | 2011-03-15 | General Electric Company | Coupling agent composition and associated method |
US7536863B1 (en) | 2008-07-14 | 2009-05-26 | Wylie Inventions, Inc | Combined cycle |
US8178075B2 (en) | 2008-08-13 | 2012-05-15 | Air Products And Chemicals, Inc. | Tubular reactor with jet impingement heat transfer |
DE102009012663B3 (en) | 2009-03-13 | 2010-09-16 | Uhde Gmbh | Process and device for the uniform production of steam from the waste heat of an alkane dehydrogenation |
CN102395524B (en) * | 2009-04-15 | 2015-07-15 | 气体产品与化学公司 | Process for producing a hydrogen-containing product gas |
DE102009034464A1 (en) * | 2009-07-22 | 2011-08-18 | Uhde GmbH, 44141 | Process and apparatus for the dehydrogenation of alkanes with a homogenization of the product composition |
US9248612B2 (en) * | 2011-12-15 | 2016-02-02 | General Electric Company | Containment case and method of manufacture |
EP2855167B1 (en) * | 2012-05-25 | 2017-03-22 | ExxonMobil Chemical Patents Inc. | Dicyclopentadiene based resin compositions and articles manufactured therefrom |
EP2716363A1 (en) | 2012-10-04 | 2014-04-09 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Optimized catalyst shape for steam methane reforming processes |
JP2018531970A (en) * | 2015-11-04 | 2018-11-01 | エクソンモービル ケミカル パテンツ インコーポレイテッド | Integrated gas turbine and conversion system process |
US9849440B2 (en) * | 2015-11-04 | 2017-12-26 | Exxonmobil Chemical Patents Inc. | Process for conversion of acyclic C5 compounds to cyclic C5 compounds and catalyst composition for use therein |
CA3004298C (en) * | 2015-11-04 | 2020-04-28 | Exxonmobil Chemical Patents Inc. | Fired tube conversion system and process |
-
2016
- 2016-10-07 JP JP2018542669A patent/JP6640365B2/en active Active
- 2016-10-07 CA CA3004332A patent/CA3004332C/en active Active
- 2016-10-07 EP EP16862675.2A patent/EP3371142A4/en not_active Withdrawn
- 2016-10-07 WO PCT/US2016/056048 patent/WO2017078905A1/en active Application Filing
- 2016-10-07 CN CN201680064160.XA patent/CN108349839B/en active Active
Also Published As
Publication number | Publication date |
---|---|
EP3371142A1 (en) | 2018-09-12 |
WO2017078905A1 (en) | 2017-05-11 |
JP6640365B2 (en) | 2020-02-05 |
JP2018532794A (en) | 2018-11-08 |
CN108349839B (en) | 2021-04-09 |
CA3004332A1 (en) | 2017-05-11 |
CN108349839A (en) | 2018-07-31 |
EP3371142A4 (en) | 2018-10-24 |
CA3004332C (en) | 2019-12-31 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2017078905A8 (en) | Processes and systems for converting hydrocarbons to cyclopentadiene | |
SA518392257B1 (en) | Catalyst and Method for Synthesis of Aromatic Hydrocarbons Through Direct Conversion of Synthesis Gas | |
WO2016044428A3 (en) | Catalysts for oxidative coupling of methane and oxidative dehydrogenation of ehtane | |
MX341276B (en) | Process for the manufacture of 2,3,3,3- tetrafluoropropene by gas phase fluorination of pentachloropropane. | |
CU20100136A7 (en) | METAL RECOVERY FROM HEAVY CONVERTED EFFLUENT | |
MX347872B (en) | Process for the preparation of 2,3,3,3 tetrafluoropropene. | |
MX2018001489A (en) | Catalytic isomerization of z-1,1,1,4,4,4-hexafluoro-2-butene to e-1,1,1,4,4,4-hexafluoro-2-butene. | |
EA033012B1 (en) | Process and installation for the conversion of crude oil to petrochemicals having an improved ethylene and btx yield | |
PH12020500107A1 (en) | Integrated thermal and catalytic cracking for olefin prodcution | |
MX349999B (en) | Process for the manufacture of hydrofluoroolefins. | |
MX370215B (en) | Improved dehydrogenation process with heat generating material. | |
WO2011008258A3 (en) | Catalysts and processes for the formation of terminal olefins by ethenolysis | |
EP3703854A4 (en) | Catalyst and process for the selective conversion of hydrocarbons | |
MX2017005664A (en) | Method for producing a polyester containing at least one 1,4:3,6-dianhydrohexitol unit with improved colouring. | |
EP3441139A4 (en) | Catalyst for oxidative dehydrogenation reaction, method for producing same, and oxidative dehydrogenation method using same | |
EA201690125A1 (en) | METHOD OF CONVERSION OF HIGH-BURNING HYDROCARBON HYDROCARBON RAW MATERIALS IN MORE EASY HYDROCARBON HYDROCARBON PRODUCTS | |
EP3517499A4 (en) | Porous carbon material, method for producing same, and synthesis reaction catalyst | |
EP3495041A4 (en) | Methanation reaction catalyst, method for producing methanation reaction catalyst, and method for producing methane | |
EP3578257A4 (en) | Methanation reaction catalyst, method for producing methanation reaction catalyst, and method for producing methane | |
MX2014005242A (en) | Process for producing 2,3,3,3-tetrafluoropropene. | |
WO2015161468A8 (en) | Methods and systems for producing isosorbide from biomass | |
MX2013004413A (en) | Process for the manufacture of 2-chloro-3,3,3-trifluropropene by gas phase fluorination of pentachloropropane. | |
WO2011117360A3 (en) | Process for the preparation of 4-cyclohexyl-2-methyl-2-butanol | |
WO2016014348A3 (en) | One-step process for hexafluoro-2-butene | |
EP3655506A4 (en) | Integrated thermal cracking and dehydrogenation process for olefin production |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 16862675 Country of ref document: EP Kind code of ref document: A1 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2018542669 Country of ref document: JP |
|
ENP | Entry into the national phase |
Ref document number: 3004332 Country of ref document: CA |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2016862675 Country of ref document: EP |