WO2017077803A1 - Composition including thermoplastic hollow particle - Google Patents

Composition including thermoplastic hollow particle Download PDF

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Publication number
WO2017077803A1
WO2017077803A1 PCT/JP2016/079558 JP2016079558W WO2017077803A1 WO 2017077803 A1 WO2017077803 A1 WO 2017077803A1 JP 2016079558 W JP2016079558 W JP 2016079558W WO 2017077803 A1 WO2017077803 A1 WO 2017077803A1
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WO
WIPO (PCT)
Prior art keywords
composition
composition according
hollow particle
weight
oil
Prior art date
Application number
PCT/JP2016/079558
Other languages
English (en)
French (fr)
Inventor
Toru Koike
Vèronique SCHWARTZ
Original Assignee
L'oreal
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by L'oreal filed Critical L'oreal
Priority to KR1020187011812A priority Critical patent/KR20180061278A/ko
Priority to EP16790733.6A priority patent/EP3374034A1/de
Priority to CN201680062769.3A priority patent/CN108136231A/zh
Publication of WO2017077803A1 publication Critical patent/WO2017077803A1/en

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0212—Face masks
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/042—Gels
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A61K8/064—Water-in-oil emulsions, e.g. Water-in-silicone emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
    • A61K8/65—Collagen; Gelatin; Keratin; Derivatives or degradation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/08—Anti-ageing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/22—Gas releasing
    • A61K2800/222—Effervescent
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41—Particular ingredients further characterized by their size
    • A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns

Definitions

  • the present invention relates to a composition, preferably a cosmetic composition, and more preferably a skin cosmetic composition, for an aerosol, which includes thermoplastic hollow particle(s), for a keratin substance such as skin.
  • Cosmetic compositions such as skin-care and make-up compositions having matte-effect properties are generally used to solve sheen problems caused by excess sebum and to improve the long-term staying power of, for example, the make-up provided by the compositions, since the make-up has a tendency to degrade visually in the course of the day. They give the skin a matte appearance, resulting from the power to scatter light at the surface of the skin. They may also be used to fade out skin defects such as microreliefs, wrinkles, fine lines and pores or color variations.
  • compositions known as matte-effect compositions, generally contain powders which can absorb sebum (cf. WO 2004/000212 or JP-T-2005-529976).
  • matte-effect powders of natural or synthetic origin which may be mentioned in particular are fillers such as talc, starch, mica, silica, Nylon powders, and poly-(methylmethacrylate). Fillers of this type have the drawback of not giving the skin a natural or transparent appearance, by giving a powdery or even plaster-like appearance and of accentuating defects in the skin.
  • the compositions include oil(s) or oily ingredient(s)
  • the matte effects provided by the powders are in general deteriorated.
  • An objective of the present invention is to provide a composition, preferably a cosmetic composition, and more preferably a skin cosmetic composition, wherein the composition can provide both matte and transparent appearance, even if the composition includes oil(s) or oily ingredient(s), and the composition can be in the form of an aerosol by being sprayed with a spray device without causing clogging the nozzle of the spray device.
  • composition preferably a cosmetic composition, and more preferably a skin cosmetic composition, for an aerosol comprising:
  • thermoplastic hollow particle (a) at least one thermoplastic hollow particle
  • thermoplastic hollow particle may be a hollow particle of expanded homopolymer or copolymer formed from a monomer or mixture of monomers selected from methacrylic acid esters, acrylic acid esters, vinylidene chloride, acrylonitrile, styrene and its derivatives, and butadiene and its derivatives.
  • thermoplastic hollow particle may be a hollow particle of methyl (meth)acrylate homopolymer or copolymer, of copolymer of styrene and acrylonitrile, of copolymer of vinylidene chloride and acrylonitrile or vinyl chloride, or of expanded terpolymer of vinylidene chloride, acrylonitrile and methyl methacrylate.
  • thermoplastic hollow particle may be a hollow particle of an expanded terpolymer of vinylidene chloride, acrylonitrile and methyl methacrylate.
  • thermoplastic hollow particle may have a particle size of from 20 ⁇ to 100 ⁇ .
  • thermoplastic hollow particle may have a density ranging from 20 to 70 kg/m 3 .
  • the amount of the (a) thermoplastic hollow particle in the composition may be from 0.01 to 30% by weight, preferably from 0.05 to 20% by weight, and more preferably from 0.1 to 10% by weight, relative to the total weight of the composition.
  • the amount of the (b) oil in the composition may be from 0.1 to 50% by weight, preferably from 1 to 40% by weight, and more preferably from 5 to 30% by weight, relative to the total weight of the composition.
  • the composition according to the present invention may comprise (d) at least one UV filter.
  • composition according to the present invention may comprise (e) water.
  • the amount of (e) water in the composition may be from 1 to 90% by weight, preferably from 10 to 80%) by weight, and more preferably from 40 to 70%) by weight, relative to the total weight of the composition.
  • the composition according to the present invention may be in the form of a W/O emulsion.
  • the present invention also relates to a cosmetic process for a keratin substance such as skin, comprising the steps of: applying the composition according to the present invention onto the keratin substance.
  • Another aspect of the present invention is an aerosol device, comprising
  • At least one container comprising
  • composition preferably a cosmetic composition, and more preferably a skin cosmetic composition, comprising:
  • thermoplastic hollow particle (a) at least one thermoplastic hollow particle
  • the nozzle is connected with the container via the tube, and the composition in the container can be moved from the container to the nozzle via the tube to be sprayed from the nozzle.
  • compositions preferably a cosmetic composition, and more preferably a skin cosmetic composition, wherein the composition can provide both matte and transparent appearance, even if the composition includes oil(s) or oily ingredient(s), and the composition can be in the form of an aerosol by being sprayed with a spray device without causing clogging of the nozzle of the spray device.
  • composition according to the present invention comprises:
  • thermoplastic hollow particle (a) at least one thermoplastic hollow particle
  • composition according to the present invention comprises at least one (a) thermoplastic hollow particle. If two or more (a) thermoplastic hollow particles are used, they may be the same or different.
  • the (a) thermoplastic hollow particle is made from at least one thermoplastic material. Two or more thermoplastic materials may be used.
  • the thermoplastic material may soften at from 80 to 200°C, preferably from 90 to 190°C, and more preferably from 100 to 180°C.
  • thermoplastic hollow particle which can be used according to the invention may be prepared from ethylenically unsaturated monomers which are non-toxic and non-irritating to the skin.
  • the (a) thermoplastic hollow particle used in the composition according to the present invention may be obtained, for example, according to the processes of European Patents and Patent Applications EP-056 219, EP-348 372, EP-486 080, EP-320 473, and EP- 112 807 and U.S. Pat. No. 3,615,972, the disclosures of which are hereby incorporated by reference.
  • thermoplastic hollow particle there may be mentioned methacrylic or acrylic acid esters such as methyl acrylate or methacrylate;
  • vinylidene chloride acrylonitrile
  • styrene and its derivatives butadiene and its derivatives; and mixtures thereof.
  • thermoplastic hollow particle be a hollow particle of expanded homopolymer or copolymer formed from a monomer or mixture of monomers selected from methacrylic acid esters, acrylic acid esters, vinylidene chloride, acrylonitrile, styrene and its derivatives, and butadiene and its derivatives.
  • methyl acrylate or methacrylate polymers or copolymers the copolymers formed from styrene and acrylonitrile and the copolymers of vinylidene chloride and acrylonitrile or vinyl chloride.
  • thermoplastic hollow particle be a hollow particle of methyl (meth)acrylate homopolymer or copolymer, of copolymer of styrene and acrylonitrile, or of copolymer of vinylidene chloride and acrylonitrile or vinyl chloride, or of expanded terpolymer of vinylidene chloride, acrylonitrile and methyl methacrylate.
  • the (a) thermoplastic hollow particle used in the present invention is a hollow particle of an expanded copolymer of vinylidene chloride and acrylonitrile, or of vinylidene chloride, acrylonitrile and methyl methacrylate. These particles may be dry or hydrated.
  • thermoplastic hollow particle be a hollow particle of an expanded copolymer of vinylidene chloride and acrylonitrile, or an expanded terpolymer of vinylidene chloride, acrylonitrile and methyl methacrylate.
  • thermoplastic hollow particle be any thermoplastic hollow particle. It is even more preferable that the (a) thermoplastic hollow particle be any thermoplastic hollow particle.
  • the (a) thermoplastic hollow particle may have a particle size of from 20 ⁇ to 100 ⁇ , preferably from 25 ⁇ to 70 ⁇ , and more preferably from 30 ⁇ to 50 ⁇ .
  • the (a) thermoplastic hollow particle may have a density ranging from 20 to 70 kg/m , preferably from 25 to 60 kg/m , and more preferably from 30 kg/m to 50 kg/m .
  • the thickness of the wall forming the internal cavity of the (a) thermoplastic hollow particle may be from 0.01 to 1 ⁇ , preferably from 0.05 to 0.9 ⁇ , and more preferably from 0.1 to 0.8 ⁇ .
  • the amount of the (a) thermoplastic hollow particle(s) in the composition according to the present invention may be from 0.01 to 30% by weight, preferably from 0.05 to 20% by weight, and more preferably from 0.1 to 10% by weight, relative to the total weight of the
  • the composition according to the present invention comprises at least one (b) oil. If two or more (b) oils are used, they may be the same or different.
  • oil means a fatty compound or substance which is in the form of a liquid or a paste (non-solid) at room temperature (25°C) under atmospheric pressure (760 mmHg).
  • oils those generally used in cosmetics can be used alone or in combination thereof. These oils may be volatile or non-volatile.
  • the (b) oil may be a non-polar oil such as a hydrocarbon oil, a silicone oil, or the like; a polar oil such as a plant or animal oil and an ester oil or an ether oil; or a mixture thereof.
  • the (b) oil may be selected from the group consisting of oils of plant or animal origin, synthetic oils, silicone oils, hydrocarbon oils and fatty alcohols.
  • the (b) oil be selected from synthetic oils, hydrocarbon oils, and mixtures thereof, more preferably from ester oils, hydrocarbon oils and mixtures thereof, and even more preferably from ester oils.
  • plant oils mention may be made of, for example, linseed oil, camellia oil, macadamia nut oil, corn oil, mink oil, olive oil, avocado oil, sasanqua oil, castor oil, safflower oil, jojoba oil, sunflower oil, almond oil, rapeseed oil, sesame oil, soybean oil, peanut oil, and mixtures thereof.
  • animal oils mention may be made of, for example, squalene and squalane.
  • alkane oils such as isododecane and isohexadecane
  • ester oils preferably liquid esters of saturated or unsaturated, linear or branched C 1 - C 2 6 aliphatic monoacids or polyacids and of saturated or unsaturated, linear or branched C 1 - C 26 aliphatic monoalcohols or polyalcohols, the total number of carbon atoms of the esters being greater than or equal to 10.
  • the esters of monoalcohols at least one from among the alcohol and the acid from which the esters of the present invention are derived is branched.
  • esters of C 4 -C 22 dicarboxylic or tricarboxylic acids and of C 1 -C 22 alcohols, and esters of monocarboxylic, dicarboxylic or tricarboxylic acids and of non-sugar C 4 -C 26 dihydroxy, trihydroxy, tetrahydroxy or pentahydroxy alcohols may also be used. Mention may especially be made of: diethyl sebacate; isopropyl lauroyl sarcosinate;
  • sugar esters and diesters of C 6 -C 30 and preferably C 12 -C 22 fatty acids.
  • sucrose means oxygen-bearing hydrocarbon-based compounds containing several alcohol functions, with or without aldehyde or ketone functions, and which comprise at least 4 carbon atoms. These sugars may be monosaccharides, oligosaccharides or polysaccharides.
  • sugars examples include sucrose (or saccharose), glucose, galactose, ribose, fucose, maltose, fructose, mannose, arabinose, xylose and lactose, and derivatives thereof, especially alkyl derivatives, such as methyl derivatives, for instance methylglucose.
  • the sugar esters of fatty acids may be chosen especially from the group comprising the esters or mixtures of esters of sugars described previously and of linear or branched, saturated or unsaturated C 6 -C 30 and preferably C 12 -C 22 fatty acids. If they are unsaturated, these compounds may have one to three conjugated or non-conjugated carbon-carbon double bonds.
  • the esters according to this variant may also be selected from monoesters, diesters, triesters, tetraesters and polyesters, and mixtures thereof.
  • esters may be, for example, oleates, laurates, palmitates, myristates, behenates, cocoates, stearates, linoleates, linolenates, caprates and arachidonates, or mixtures thereof such as, especially, oleopalmitate, oleostearate and palmitostearate mixed esters, as well as pentaerythrityl tetraethyl hexanoate.
  • monoesters and diesters and especially sucrose, glucose or methylglucose monooleates or dioleates, stearates, behenates, oleopalmitates, linoleates, linolenates and oleostearates.
  • ester oils An example that may be mentioned is the product sold under the name Glucate® DO by the company Amerchol, which is a methylglucose dioleate.
  • preferable ester oils mention may be made of, for example, diisopropyl adipate, dioctyl adipate, 2-ethylhexyl hexanoate, ethyl laurate, cetyl octanoate, octyldodecyl octanoate, isodecyl neopentanoate, myristyl propionate, 2-ethylhexyl 2-ethylhexanoate, 2- ethylhexyl octanoate, 2-ethylhexyl caprylate/caprate, methyl palmitate, ethyl palmitate, isopropyl palmitate, dicaprylyl carbonate, isopropyl lauroyl
  • isononanoate ethylhexyl palmitate, isohexyl laurate, hexyl laurate, isocetyl stearate, isopropyl isostearate, isopropyl myristate, isodecyl oleate, glyceryl tri(2-ethylhexanoate),
  • artificial triglycerides mention may be made of, for example, capryl caprylyl glycerides, glyceryl trimyristate, glyceryl tripalmitate, glyceryl trilinolenate, glyceryl trilaurate, glyceryl tricaprate, glyceryl tricaprylate, glyceryl tri(caprate/caprylate) and glyceryl tri(caprate/caprylate/linolenate).
  • silicone oils mention may be made of, for example, linear
  • organopolysiloxanes such as dimethylpolysiloxane, methylphenylpolysiloxane,
  • dodecamethylcyclohexasiloxane and the like; and mixtures thereof.
  • the silicone oil is chosen from liquid polydialkylsiloxanes, especially liquid polydimethylsiloxanes (PDMS) and liquid polyorganosiloxanes comprising at least one aryl group.
  • PDMS liquid polydimethylsiloxanes
  • silicone oils may also be organomodified.
  • organomodified silicones that can be used according to the present invention are silicone oils as defined above and comprise in their structure one or more organofunctional groups attached via a hydrocarbon-based group.
  • Organopolysiloxanes are defined in greater detail in Walter Noll's Chemistry and Technology of Silicones (1968), Academic Press. They may be volatile or non- volatile.
  • the silicones are more particularly chosen from those having a boiling point of between 60°C and 260°C, and even more particularly from:
  • linear volatile polydialkylsiloxanes containing 2 to 9 silicon atoms and having a viscosity of less than or equal to 5x10 -6 m 2 /s at 25°C.
  • An example is
  • Non-volatile polydialkylsiloxanes may also be used. These non-volatile silicones are more particularly chosen from polydialkylsiloxanes, among which mention may be made mainly of polydimethylsiloxanes containing trimethylsilyl end groups.
  • oils of the 200 series from the company Dow Corning such as DC200 with a viscosity of 60 000 mm 2 /s;
  • CTFA dimethiconol
  • the phenyl silicone oil may be chosen from the phenyl silicones of the following formula:
  • R 1 to R 10 are saturated or unsaturated, linear, cyclic or branched C 1 -C 30 hydrocarbon-based radicals, preferably C 1 -C 12 hydrocarbon-based radicals, and more preferably C 1 -C 6 hydrocarbon-based radicals, in particular methyl, ethyl, propyl or butyl radicals, and
  • n, p and q are, independently of each other, integers from 0 to 900 inclusive, preferably 0 to 500 inclusive, and more preferably 0 to 100 inclusive,
  • oils of the Rhodorsil® 70 633 and 763 series from Rhodia the oils of the Rhodorsil® 70 633 and 763 series from Rhodia; the oil Dow Corning 556 Cosmetic Grade Fluid from Dow Corning; the silicones of the PK series from Bayer, such as the product PK20;
  • oils of the SF series from General Electric such as SF 1023, SF 1154, SF 1250 and SF 1265.
  • the organomodified liquid silicones may especially contain polyethyleneoxy and/or polypropyleneoxy groups. Mention may thus be made of the silicone KF-6017 proposed by Shin-Etsu, and the oils Silwet® L722 and L77 from the company Union Carbide.
  • Hydrocarbon oils may be chosen from:
  • linear or branched, optionally cyclic, C 6 -C 1 lower alkanes examples that may be mentioned include hexane, undecane, dodecane, tridecane, and isoparaffins, for instance isohexadecane, isododecane and isodecane; and
  • linear or branched hydrocarbons containing more than 16 carbon atoms such as liquid paraffins, liquid petroleum jelly, polydecenes and hydrogenated
  • polyisobutenes such as Parleam®, and squalane.
  • hydrocarbon oils As preferable examples of hydrocarbon oils, mention may be made of, for example, linear or branched hydrocarbons such as isohexadecane, isododecane, squalane, mineral oil (e.g., liquid paraffin), paraffin, vaseline or petrolatum, naphthalenes, and the like; hydrogenated .
  • linear or branched hydrocarbons such as isohexadecane, isododecane, squalane, mineral oil (e.g., liquid paraffin), paraffin, vaseline or petrolatum, naphthalenes, and the like; hydrogenated .
  • polyisobutene polyisobutene, isoeicosan, and decene/butene copolymer; and mixtures thereof.
  • fatty in the fatty alcohol means the inclusion of a relatively large number of carbon atoms. Thus, alcohols which have 4 or more, preferably 6 or more, and more preferably 12 or more carbon atoms are encompassed within the scope of fatty alcohols.
  • the fatty alcohol may be saturated or unsaturated.
  • the fatty alcohol may be linear or branched.
  • the fatty alcohol may have the structure R-OH wherein R is chosen from saturated and unsaturated, linear and branched radicals containing from 4 to 40 carbon atoms, preferably from 6 to 30 carbon atoms, and more preferably from 12 to 20 carbon atoms.
  • R may be chosen from C 12 -C 20 alkyl and C 12 -C 20 alkenyl groups. R may or may not be substituted with at least one hydroxyl group.
  • fatty alcohol examples include lauryl alcohol, cetyl alcohol, stearyl alcohol, isostearyl alcohol, behenyl alcohol, undecylenyl alcohol, myristyl alcohol, octyldodecanol, hexyldecanol, oleyl alcohol, linoleyl alcohol, palmitoleyl alcohol, arachidonyl alcohol, erucyl alcohol, and mixtures thereof.
  • the fatty alcohol may be selected from straight or branched, saturated or unsaturated C -C 30 alcohols, preferably straight or branched, saturated C 6 -C 30 alcohols, and more preferably straight or branched, saturated C 12 -C 20 alcohols.
  • saturated fatty alcohol here means an alcohol having a long aliphatic saturated carbon chain. It is preferable that the saturated fatty alcohol be selected from any linear or branched, saturated C 6 -C 30 fatty alcohols. Among the linear or branched, saturated C 6 -C 30 fatty alcohols, linear or branched, saturated C 12 -C 20 fatty alcohols may preferably be used. Any linear or branched, saturated C 16 -C 20 fatty alcohols may be more preferably used.
  • Branched C 16 -C 20 fatty alcohols may be even more preferably used.
  • saturated fatty alcohols mention may be made of lauryl alcohol, cetyl alcohol, stearyl alcohol, isostearyl alcohol, behenyl alcohol, undecylenyl alcohol, myristyl alcohol, octyldodecanol, hexyldecanol, and mixtures thereof.
  • cetyl alcohol, stearyl alcohol, octyldodecanol, hexyldecanol, or a mixture thereof (e.g., cetearyl alcohol) as well as behenyl alcohol can be used as a saturated fatty alcohol.
  • the fatty alcohol used in the composition according to the present invention is preferably chosen from octyldodecanol, hexyldecanol and mixtures thereof.
  • the amount of the (b) oil(s) in the composition according to the present invention may range from 0.1 to 50% by weight, preferably from 1 to 40% by weight, and more preferably from 5 to 30% by weight, relative to the total weight of the composition.
  • composition according to the present invention includes at least one (c) propellant. If two or more (c) propellants are used, they may be the same or different.
  • the term "propellant” means any compound that is gaseous at a temperature of 20°C and at atmospheric pressure, and that can be stored under pressure in liquid or gaseous form in an aerosol container.
  • the (c) propellant may be, for example, any liquefiable gas normally used in aerosol devices, such as dimethyl ether, C3-C5 alkanes, 1,1-difluoroethane, mixtures of dimethyl ether and of C 3 -C 5 alkanes, and mixtures of 1,1-difluoroethane and of dimethyl ether and/or of C 3 -C 5 alkanes.
  • C 3 -C 5 alkanes for example, propane, n-butane, isobutane, and mixtures thereof, such as liquefied petroleum gas (LPG), may be used as propellant.
  • LPG liquefied petroleum gas
  • compressed air may be used as the (c) propellant.
  • carbon dioxide, nitrous oxide, or nitrogen may be used as the (c) propellant.
  • the (c) propellant(s) may be present in the composition according to the present invention in a content ranging from 1 to 90% by weight, preferably ranging from 2 to 85% by weight, and more preferably from 3 to 80% by weight, relative to the total weight of the composition.
  • the composition according to the present invention may include at least one (d) UV filter. If two or more (d) UV filters are used, they may be the same or different.
  • the (d) UV filter may be solid or liquid, preferably liquid.
  • the terms “solid” and “liquid” mean solid and liquid, respectively, at 25°C under 1 atm.
  • the (d) UV filter may be made from at least one organic or inorganic material, preferably at least one organic material. Thus, the (d) UV filter is preferably an organic UV filter.
  • Heliopan E 1000 by Haarmann and Reimer; cinoxate (2-ethoxyethyl-4-methoxy cinnamate); DEA methoxycinnamate; diisopropyl methylcinnamate; and glyceryl ethylhexanoate dimethoxycinnamate.
  • Homosalate homomentyl salicylate
  • Eusolex HMS ethylhexyl salicylate
  • Neo Heliopan OS by Haarmann and Reimer
  • glycol salicylate butyloctyl salicylate
  • phenyl salicylate dipropyleneglycol salicylate
  • TEA salicylate marketed under the trademark "Neo Heliopan TS” by Haarmann and Reimer.
  • benzylidenecamphor derivatives in particular, benzylidenecamphor derivatives: 3-benzylidene camphor, manufactured under the trademark “Mexoryl SD” by Chimex; 4-methylbenzylidene camphor, marketed under the trademark “Eusolex 6300” by Merck; benzylidene camphor sulfonic acid, manufactured under the trademark “Mexoryl SL” by Chimex; camphor benzalkonium methosulfate, manufactured under the trademark "Mexoryl SO” by Chimex; terephthalylidene dicamphor sulfonic acid, manufactured under the trademark "Mexoryl SX” by Chimex; and polyacrylamidomethyl benzylidene camphor, manufactured under the trademark "Mexoryl SW” by Chimex.
  • Benzophenone- 1 (2,4-dihydroxybenzophenone), marketed under the trademark "Uvinul 400" by BASF; benzophenone-2 (Tetrahydroxybenzophenone), marketed under the trademark “Uvinul D50” by BASF; Benzophenone-3 (2-hydroxy-4- me hoxybenzophenone) or oxybenzone, marketed under the trademark "Uvinul M40” by BASF; benzophenone-4 (hydroxymethoxy benzophonene sulfonic acid), marketed under the trademark "Uvinul MS40” by BASF; benzophenone-5 (Sodium hydroxymethoxy
  • benzophenone Sulfonate benzophenone-6 (dihydroxy dimethoxy benzophenone); marketed under the trademark "Helisorb 11 " by Norquay; benzophenone- 8, marketed under the trademark "Spectra-Sorb UV-24” by American Cyanamid; benzophenone-9 (Disodium dihydroxy dimethoxy benzophenonedisulfonate), marketed under the trademark "Uvinul DS- 49” by BASF; benzophenone- 12, and n-hexyl 2-(4-diethylamino-2-hydroxybenzoyl)benzoate.
  • - ⁇ , ⁇ -Diphenylacrylate derivatives Octocrylene, marketed in particular under the trademark "Uvinul N539” by BASF; and Etocrylene, marketed in particular under the trademark "Uvinul N35” by BASF.
  • - Triazine derivatives diethylhexyl butamido triazone, marketed under the trademark
  • Benzotriazole derivatives in particular, phenylbenzotriazole derivatives: 2-(2H- benzotriazole-2-yl)-6-dodecyl-4-methylphenol, branched and linear; and those described in USP 5240975.
  • polyorganosiloxane comprising benzalmalonate functional groups, such as polysilicone-15, marketed under the trademark "Parsol SLX” by Hoffmann-LaRoche.
  • PABA p-aminobenzoic acid
  • ethyl PABA Ethyl dihydroxypropyl PABA
  • pentyl dimethyl PABA ethylhexyl dimethyl PABA
  • glyceryl PABA glyceryl PABA
  • PEG-25 PABA marketed under the trademark "Uvinul P25” by BASF.
  • Dimers derived from a-alkylstyrene The dimers described in DE-19855649.
  • Rutin and derivatives thereof Rutin and glucosylrutin.
  • Flavonoids Robustin (isoflavonoid), genistein (flavonoid), tectochrysin (flavonoid), and hispidone (flavonoid).
  • Phenol Phenol
  • Peptides having an aromatic amino acid residue Peptides having tryptophan, tyrosine or phenylalanine.
  • the preferred organic UV filter may be selected from:
  • Heliopan E 1000 by Haarmann and Reimer; cinoxate (2-ethoxyethyl-4-methoxy cinnamate); DEA methoxycinnamate; diisopropyl methylcinnamate; and glyceryl ethylhexanoate dimethoxycinnamate .
  • - Salicylic derivatives Homosalate (homomentyl salicylate), marketed under the trademark “Eusolex HMS” by Rona/EM Industries; ethylhexyl salicylate, marketed under the trademark “Neo Heliopan OS” by Haarmann and Reimer; glycol salicylate; butyloctyl salicylate; phenyl salicylate; dipropyleneglycol salicylate, marketed under the trademark “Dipsal” by Scher; and TEA salicylate, marketed under the trademark "Neo Heliopan TS” by Haarmann and Reimer.
  • Octocrylene marketed in particular under the trademark "Uvinul N539” by BASF
  • Etocrylene marketed in particular under the trademark "Uvinul N35” by BASF.
  • the preferred organic liquid UV filter(s) may be selected from:
  • the (c) UV filter(s) may be present in the composition according to the present invention in a content ranging from 1 to 30% by weight, preferably ranging from 5 to 25% by weight, and more preferably from 10 to 20% by weight, relative to the total weight of the composition.
  • composition according to the present invention may comprise (e) water.
  • the amount of (e) water is not limited, and may be from 1 to 90% by weight, preferably from 10 to 80%) by weight, and more preferably from 40 to 70% by weight, relative to the total weight of the composition according to the present invention.
  • composition according to the present invention may include at least one filler. If two or more fillers are used, they may be the same or different.
  • the filler be capable of absorbing and/or adsorbing an oil or a liquid fatty substance, for instance sebum (from the skin).
  • This oil-absorbing filler may also advantageously have a BET specific surface area of greater than or equal to 300 m 2 /g, preferably greater than 500 m 2 /g and preferentially greater than 600 m 2 /g, and especially less than 1500 m /g.
  • the BET specific surface area is determined according to the BET (Brunauer-Emmet-Teller) method described in the Journal of the American Chemical Society, vol. 60, page 309, February 1938 and corresponding to the international standard ISO 5794/1 (appendix D).
  • the BET specific surface area corresponds to the total specific surface area (thus including micropores) of the powder.
  • the filler may be characterized in that it has an oil uptake of greater than or equal to 1 ml/g, preferably greater than or equal 1.5 ml/g, especially ranging from 1.5 ml/g to 20 ml/g, or even ranging from 1.5 ml/g to 15 ml/g. It preferably has an oil uptake of greater than or equal to 2 ml/g, especially ranging from 2 ml/g to 20 ml/g, or even ranging from 2 ml/g to 15 ml/g.
  • the filler may be chosen more particularly from silicas, silica silylates (in particular hydrophobic silica aerogel particles), polyamide (in particular Nylon-6) powders, powders of acrylic polymers, especially of polymethylmethacrylate, of polymethyl methacrylate/ethylene glycol dimethacrylate, of polyallyl methacrylate/ethylene glycol dimethacrylate or of ethylene glycol dimethacrylate/lauryl methacrylate copolymer; perlites; magnesium carbonate, silicone elastomers or silicone resins, and mixtures thereof.
  • silica silylates in particular hydrophobic silica aerogel particles
  • polyamide in particular Nylon-6 powders
  • acrylic polymers especially of polymethylmethacrylate, of polymethyl methacrylate/ethylene glycol dimethacrylate, of polyallyl methacrylate/ethylene glycol dimethacrylate or of ethylene glycol dimethacrylate/lauryl methacrylate copolymer
  • perlites magnesium carbonate,
  • the filler may be present in the composition according to the present invention in a content ranging from 0.01 to 10% by weight, preferably ranging from 0.1 to 5% by weight, and more preferably from 0.5 to 2% by weight, relative to the total weight of the composition.
  • composition according to the present invention may also comprise one or more standard cosmetic adjuvants chosen from, for example, fillers, softeners, humectants, opacifiers, stabilizers, emollients, silicones, antifoams, fragrances, preserving agents, surfactants such as nonionic, cationic, anionic and amphoteric surfactants, active agents, colouring agents, cationic, anionic, amphoteric polymers, propellants, or any other ingredient usually used in cosmetics and/or dermatology.
  • standard cosmetic adjuvants chosen from, for example, fillers, softeners, humectants, opacifiers, stabilizers, emollients, silicones, antifoams, fragrances, preserving agents, surfactants such as nonionic, cationic, anionic and amphoteric surfactants, active agents, colouring agents, cationic, anionic, amphoteric polymers, propellants, or any other ingredient usually used in cosmetics
  • composition according to the present invention may be in the form of an O/W emulsion or a W/O emulsion, if the composition includes water. It is preferable that the composition according to the present invention be in the form of a W/O emulsion.
  • composition according to the present invention may preferably be in the form of an aerosol.
  • the composition according to the present invention may be contained in an aerosol device.
  • the present invention also relates to a cosmetic process for a keratin substance such as skin, comprising the steps of:
  • the keratin substance can be in a dry state or in a wet state before applying the composition according to the present invention.
  • composition according to the present invention to be applied onto the keratin substance may be in the form of an aerosol.
  • composition according to the present invention not be rinsed off after being applied onto the keratin substance.
  • the present invention also relates to an aerosol device, comprising
  • At least one container comprising
  • thermoplastic hollow particle (a) at least one thermoplastic hollow particle
  • the nozzle is connected with the container via the tube, and
  • the composition in the container can be moved from the container to the nozzle via the tube to be sprayed from the nozzle.
  • the aerosol device according to the present invention comprises a single container which contains a mixture of a composition comprising the (a) thermoplastic hollow particle(s) and the (b) oil(s), and of the (c) propellant(s), as well as the other ingredients, if present, of the composition according to the present invention.
  • the nozzle is connected with the container via the tube.
  • one end of the tube is connected with the nozzle, and the other end of the tube is immersed into the mixture of the composition and the (c) propellant in the container.
  • the composition including the (a) thermoplastic hollow particle(s) and the oil(s) in the container is pushed to move from the container to the nozzle via the tube.
  • the moved composition can be sprayed from the nozzle toward the keratin substance such as skin.
  • the aerosol device may comprise a push button which is linked with the nozzle.
  • a user of the aerosol device can push the button to spray the composition via the nozzle.
  • the aerosol device may have two compartments which are formed by, for example an inner bag in the container.
  • the (a) thermoplastic hollow particle(s) and the (b) oil(s) as well as the other ingredients, if present, of the composition according to the present invention are introduced into the inner bag, while the (c) propellant is introduced between the inner bag and the container at a sufficient pressure to make the composition come out in the form of a spray through the nozzle.
  • the (c) propellant for example, compressed air may be used.
  • the (c) propellant is preferably used at a pressure of between 1 and 12 bar, and better still between 9 and 11 bar.
  • Such an aerosol device is sold, for example, under the name EP Spray by the company EP- Spray System SA.
  • composition according to the present invention can be discharged from the aerosol device as an aerosol by being sprayed from the nozzle. Even after spraying for a long time, the nozzle of the aerosol device cannot be clogged.
  • composition according to the present invention to be applied onto the keratin substance may be in the form of an aerosol or a spray.
  • compositions according to Examples 1-3 shown in Table 1 were prepared by mixing the ingredients shown in Table 1.
  • the numerical values for the amounts of the ingredients shown in Table 1 are all based on "% by weight" as active raw materials. Table 1
  • compositions according to Comparative Examples 1-7 shown in Table 2 were prepared by mixing the ingredients shown in Table 2.
  • the numerical values for the amounts of the ingredients shown in Table 2 are all based on "% by weight" as active raw materials.
  • compositions according to Comparative Examples 8-14 shown in Table 3 were prepared by mixing the ingredients shown in Table 3.
  • the numerical values for the amounts of the ingredients shown in Table 3 are all based on "% by weight" as active raw materials.
  • compositions according to Examples 1-3 and Comparative Examples 1-14 were evaluated as follows.
  • compositions according to Examples 1-3 and Comparative Examples 1-14 were applied onto a substrate sheet (contrast card) such that the composition formed a layer with a thickness of 100 ⁇ .
  • the gloss intensity was measured by a glossmeter (CM-2600d, Konica Minolta) by reflection intensity at 60 degree of incidence angle. The gloss intensity was categorized in accordance with the following criteria. High: ⁇ 50
  • compositions according to Examples 1-3 and Comparative Examples 1-14 were applied onto a transparent PET sheet (BYK sheet) such that the composition formed a layer with a thickness of 25 ⁇ . After leaving the substrate at room temperature for 24 hours, the light transmittance (%) was measured by a hazemeter (BYK guardner Haze guard plus, Toyo Seiki). The light transmittance was categorized in accordance with the following criteria.
  • compositions according to Examples 1-3 which comprise thermoplastic hollow particles (acrylonitrile/methylmethacrylate/vinylidene chloride copolymer) were able to provide superior matte and transparent appearance although they include oil (isononyl isononanoate). Accordingly, the compositions according to Examples 1-3 were found to have good cosmetic properties for, in particular, the skin. In addition, it can be understood from Examples 1-3 that even a small amount of the thermoplastic hollow particles can provide superior matte and transparent appearance.
  • the compositions according to Comparative Examples 1-4, 7 and 10-12 include
  • compositions according to Comparative Examples 1-4, 7 and 10-12 could not provide superior matte effects.
  • the compositions according to Comparative Examples 5, 6, 8 and 9 include corn starch, trimethylsiloxysilicate, silica, and silica silylate, respectively, instead of the thermoplastic hollow particles in Examples 1-3, and therefore, the compositions according to Comparative Examples 5, 6, 8 and 9 could provide some matte effects. However, the matte effects provided by the compositions according to Comparative Examples 5, 6, 8 and 9 were inferior to those provided by the compositions according to Examples 1-3.
  • composition according to Comparative Example 13 includes titanium dioxide, instead of the thermoplastic hollow particles in Examples 1-3, and therefore, the composition according to Comparative Example 13 could not provide transparency.
  • the composition according to Comparative Example 14 includes zinc oxide, instead of the thermoplastic hollow particles in Examples 1-3, and therefore, the matte and transparency provided by the composition according to Comparative Examples 14 were inferior to those provided by the compositions according to Comparative Examples 1-3.
  • compositions according to Examples 1-3 are subjected to a spray test using a
  • compositions according to Examples 1-3 (30%) is mixed with n-butane as a propellant (70%)The mixture is charged into a container. Then, the container is installed in an aerosol device such that a nozzle of the device is connected with the container via a tube. Specifically, one end of the tube is connected with the nozzle, and the other end of the tube is immersed into the mixture of the composition and the propellant in the container.
  • the composition was discharged from the aerosol device as an aerosol by being sprayed from the nozzle. After spraying for 30 seconds, the nozzle was not clogged.
  • the composition was discharged from the aerosol device as an aerosol by being sprayed from the nozzle as above every day for 1-3 months.
  • the nozzle was not clogged.

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PCT/JP2016/079558 2015-11-02 2016-09-27 Composition including thermoplastic hollow particle WO2017077803A1 (en)

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KR1020187011812A KR20180061278A (ko) 2015-11-02 2016-09-27 열가소성 중공 입자를 포함하는 조성물
EP16790733.6A EP3374034A1 (de) 2015-11-02 2016-09-27 Zusammensetzung mit thermoplastischer hohlpartikel
CN201680062769.3A CN108136231A (zh) 2015-11-02 2016-09-27 包括热塑性空心颗粒的组合物

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