WO2017072076A1 - Gas detection using gas modulation - Google Patents

Gas detection using gas modulation Download PDF

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Publication number
WO2017072076A1
WO2017072076A1 PCT/EP2016/075560 EP2016075560W WO2017072076A1 WO 2017072076 A1 WO2017072076 A1 WO 2017072076A1 EP 2016075560 W EP2016075560 W EP 2016075560W WO 2017072076 A1 WO2017072076 A1 WO 2017072076A1
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WO
WIPO (PCT)
Prior art keywords
gas
filter
sensor
inlet
gas inlet
Prior art date
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Ceased
Application number
PCT/EP2016/075560
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French (fr)
Inventor
Fredrik Enquist
Niclas Edvardsson
Johan Hellgren
Henrik Vennerberg
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Inficon GmbH Deutschland
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Inficon GmbH Deutschland
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Filing date
Publication date
Application filed by Inficon GmbH Deutschland filed Critical Inficon GmbH Deutschland
Priority to US15/771,640 priority Critical patent/US10352848B2/en
Priority to JP2018521905A priority patent/JP6789290B2/en
Priority to CN201680063919.2A priority patent/CN108603871B/en
Publication of WO2017072076A1 publication Critical patent/WO2017072076A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/35—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
    • G01N21/3504—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for analysing gases, e.g. multi-gas analysis
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/0004—Gaseous mixtures, e.g. polluted air
    • G01N33/0009—General constructional details of gas analysers, e.g. portable test equipment
    • G01N33/0026—General constructional details of gas analysers, e.g. portable test equipment using an alternating circulation of another gas
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/01—Arrangements or apparatus for facilitating the optical investigation
    • G01N21/03—Cuvette constructions
    • G01N21/031—Multipass arrangements
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/1717—Systems in which incident light is modified in accordance with the properties of the material investigated with a modulation of one or more physical properties of the sample during the optical investigation, e.g. electro-reflectance
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/39—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using tunable lasers
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/0004—Gaseous mixtures, e.g. polluted air
    • G01N33/0009—General constructional details of gas analysers, e.g. portable test equipment
    • G01N33/0011—Sample conditioning
    • G01N33/0016—Sample conditioning by regulating a physical variable, e.g. pressure or temperature
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/1717—Systems in which incident light is modified in accordance with the properties of the material investigated with a modulation of one or more physical properties of the sample during the optical investigation, e.g. electro-reflectance
    • G01N2021/1723—Fluid modulation
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2201/00—Features of devices classified in G01N21/00
    • G01N2201/06—Illumination; Optics
    • G01N2201/069—Supply of sources
    • G01N2201/0696—Pulsed
    • G01N2201/0698—Using reference pulsed source

Definitions

  • the invention refers to a gas detection system and to a respective method using a gas modulation valve switching between a reference gas inlet and a sample gas inlet.
  • Gas detectors may comprise a sample gas inlet through which the gas to be detected (target gas) is sucked and a reference gas inlet through which gas from the surrounding atmosphere is sucked as a reference gas.
  • the gas modulation valve connects the sample gas inlet and the reference gas inlet to the inlet of a gas sensor, such as an infrared gas sensor.
  • the infrared gas sensor may, for example, have a cuvette comprising the inlet and a respective outlet for the gas to be analyzed, an infrared light source and an infrared detector.
  • the gas flow path from the gas modulation valve to the inlet of the gas sensor (cuvette) is alternately connected to the sample gas inlet and to the reference gas inlet by the gas modulation valve.
  • the switching by the gas modulation valve between the sample gas inlet and the reference gas inlet preferably occurs in a periodical manner at a periodic frequency, as described in US 7,030,381 B2.
  • the reason for this is primarily to protect the public from fires and explosions resulting from gas collecting in buildings and other confined spaces.
  • the leak survey is typically carried out by moving a detector, sensitive to one of the main components of the gas, over the surface of the ground above the pipe carrying the gas.
  • the majority of detectors for this purpose utilize only one inlet and no secondary reference inlet.
  • a typical infrared sensor often used in this type of detector is a non-dispersive infrared absorption detector (NDIR sensor).
  • NDIR sensor non-dispersive infrared absorption detector
  • Another sensor type which might be used for gas detection according to the gas modulation principle is a metal oxide semi-conductor sensor, such as an Sn0 2 sensor.
  • Sn0 2 sensor a metal oxide semi-conductor sensor
  • Both the NDIR and MOS sensors suffer from limited selectivity versus water vapour.
  • the gas sensor reacts when e.g. moving from an asphalt surface onto a grass surface with a higher humidity or from a sunny area into a shady area or vice versa. Similar selectivity problems are observed on most types of gas sensors.
  • the invention is therefore not meant to be restricted to a specific sensor type.
  • filters are known to be used for removing or capturing the humidity and/or non-wanted flammable gases from the gas sample.
  • the filters need to have a large enough capacity to last for an acceptable amount of time.
  • the filter needs to be replaced, baked out or otherwise regenerated quite often.
  • the gas detection system of the invention is defined by independent claim 1.
  • the method of the invention is defined by independent claim 6.
  • the gas detection system of the invention comprises a sample gas inlet, a reference gas inlet and a gas modulation valve alternatingly connecting one of the sample gas inlet and the reference gas inlet to a gas sensor.
  • the system is characterized by a selective transfer filter located in the gas flow path connecting the gas modulation valve and the gas sensor, and may be acting as a low-pass filter for gases of no interest that cause unwanted signals in the system. The most common of such gases is water or humidity.
  • selective transfer filter means that different gas components or gas types are selectively transferred through the filter with different transfer times. Thereby, the gas transfer time of specific gas components is controlled in order to achieve a selectivity of the filter for specific gas components via the respective transfer time of this gas component compared to other gas components.
  • the selective transfer filter may achieve different transfer times for different gas types or components, for example, via a different time behavior of the filter for adsorption and desorption of respective gases or gas species resulting in specific transfer times or passage times of different gas species through the filter.
  • the different transfer times may be expressed by the filtering time constant of the filter for respective gases or species.
  • the selective transfer filter may thus also be named “retention filter” or "physical low-pass filter”.
  • the filtering time constant of the selective transfer filter for disturbing species should be significantly longer, preferably more than five times longer, than the filtering time constant for the target gas or gases and the period of the switching of the gas modulation valve between the sample gas inlet and the reference gas inlet.
  • the selective transfer filter may be a humidity and/or gas filter.
  • the filter may comprise or be made of at least one of a surface-active material, a cigarette filter material, active carbon material and/or silica gel.
  • the gas sensor may be an infrared sensor, and preferably a non-dispersive infrared sensor, optically tuned to detect methane, ethane, propane, butane or LPG gases.
  • the gas sensor may be a combination of a non-dispersive infrared (NDIR) sensor and at least one further gas sensor, such as a metal oxide semiconductor (MOS) sensor.
  • NDIR non-dispersive infrared
  • MOS metal oxide semiconductor
  • the method of the invention for gas detection uses a gas detection system as described above and according to any one of the claims.
  • the gas modulation valve alternatingly connects the reference gas inlet and the sample gas inlet with the gas flow path leading to the gas via the selective transfer filter.
  • the filter is used as a low-pass filter to slow down the changes in, for example, the humidity of the gas when switching between the sample gas inlet and the reference gas inlet.
  • the capacity of the filter does not need to be large enough in order to dry the gas, i.e. reduce the humidity of the gas. Only the changes in humidity during the switching cycles need to be dampened.
  • the general idea is to employ a selective transfer filter, such as a humidity filter, not for removing or capturing the entire humidity from the gas sample, but rather as a low-pass filter in the gas flow path between the gas modulation valve and the gas sensor.
  • a selective transfer filter such as a humidity filter
  • the capacity of the humidity filter only needs to be large enough to dampen changes in humidity when the gas modulation valve switches between the sample gas inlet and the reference gas inlet.
  • the sample gas inlet sucks in humid gas, e.g. when approaching humid ground surfaces, such as grass.
  • the reference gas inlet at the same time does not suck in the same amount of humidity because the reference gas inlet is located to take up gas from the surroundings of the measuring location, that may contain a test gas background that is to be taken into consideration when detecting the test gas taken up at the measuring location by the sample gas inlet.
  • the humidity filter is not used to dry the gas. The low-pass filter effect of the humidity filter only occurs in combination with the gas modulation valve switching between humid gas and reference gas of less humidity.
  • Humidity is only an example of a gas or gas property which is affected by the selective transfer filter when passing therethrough.
  • Humidity is hereby considered as a gas component the transfer time of which is significantly increased by the selective transfer filter as compared to a target gas.
  • the filter thus has a different (significantly longer) time constant for the "gas" humidity than for the target gas, thereby acting as a low-pass filter for the disturbing gas species humidity.
  • the selective transfer filter may be adapted to achieve a longer transfer time for those unwanted gas components than for the target gas. The longer transfer time may be achieved through a larger filtering time constant.
  • Figure 1 shows the general layout of the system of the invention and Figure 2 shows humidity percentage over time in an embodiment employing a humidity filter.
  • a sample gas inlet 12 and a reference gas inlet 14 are connected to a gas modulation valve 16 via respective sample and reference gas conduits 18, 20.
  • the gas modulation valve 16 alternatingly connects the sample gas conduit 18 or the reference gas conduit 20 to the gas flow path 22 connecting the gas modulation valve 16 and the gas sensor 24.
  • the gas sensor 24 may be a non-dispersive infrared sensor comprising an absorption cuvette.
  • the gas flow path 22 contains a sample vacuum pump 26 and a selective transfer filter 28.
  • the selective transfer filter 28 is located between the gas modulation valve 16 and the gas sensor 24.
  • the selective transfer filter 28 is also located between the vacuum pump 26 and the gas sensor 24.
  • the vacuum pump 26 is located between the gas modulation valve 16 and the filter 28.
  • the gas modulation valve 16 is opened and closed in a cyclic manner, thereby alternatingly and periodically connecting the sample gas inlet 12 or the reference gas inlet 14 to the gas flow path 22.
  • the switching occurs at a frequency suitable for the application, depending on the signal update frequency demanded by the application and/or the time constant of the gas detection sensor 24.
  • the selected frequency is typically a compromise between application demands (typically a few hertz or higher) and the time constant of the gas sensor 24 which, in reality, is seconds or minutes for most sensor types.
  • the gas modulation valve 16 is used to create a signal modulation for noise reduction and signal amplification. Thereby, the valve 16 takes gas from the sample gas inlet 12 at the actual point of interest or the reference gas inlet 14 from the background air in an alternating cycle.
  • the output signal of the gas sensor 24 is analyzed in relation to the switching frequency and sometimes also the phase in order to improve the sensitivity and to reduce background noise.
  • An increase in humidity in the ambient air will be suppressed because both the sample gas inlet 12 and the reference gas inlet 14 take gas from the ambient air. Non-gas related noise will also be suppressed as this will normally not coincide with the gas signal in frequency and phase.
  • the major problem with the prior art systems employing gas modulation switching between a sample gas inlet and a reference gas inlet is that ambient conditions may be changing differently between the separated gas inlets. This occurs, for example, when the ground surface is screened with a hand-held probe for gas emerging from underground pipes. This is often done by dragging a carpet-like device on the surface. The sample inlet is then typically placed below the carpet and the reference gas inlet is placed above the carpet. Accordingly, when the carpet is moved between areas of different humidity, there will be an immediate difference in humidity of the sample gas and the reference gas entering the sample gas inlet 12 and the reference gas inlet 14, respectively.
  • the selective transfer filter 28 between the gas modulation valve 16 and the gas sensor 24 is a surface-active humidity filter.
  • the filter 28, through which a continuous flow of air is passing, does not need to have the capacity to remove all of the humidity from the sample. It is rather enough that the filter 28 slows down the changes in humidity due to the gas modulation, thereby acting as a humidity low-pass filter.
  • the time constant of the filter is significantly larger than the time period of the gas modulation cycle. Thereby, the humidity level after the filter will eventually adapt to the average of humidity in the sample gas and the reference gas, but, as the time constant is significantly longer than the gas modulation cycle, this can be suppressed by the signal algorithms.
  • Typical filter materials such as surface-active filter materials, cigarette filter materials, activated carbon material or silica gel not only slow down humidity changes, but also changes in concentration of heavier hydrocarbons or other flammable gases.
  • This invention therefore works best for detection of light gases such as hydrogen and methane when employing conventional surfaces active filtering materials. Using chemically tailored filters it would, however, also be possible to implement this invention for the other gases.
  • Hydrocarbons typically influence most gas sensors including infrared sensors such as the NDIR sensor. Other flammable gases typically influence most general gas sensors but to a lesser extent NDIR sensors.
  • the sensor 24 needs to have a large enough differential sensitivity for the target gas to be detected in the actual average humidity or average gas concentration in the ambient atmosphere.
  • the gas sensor 24 may be specified to detect 1 ppm methane.
  • the gas detection system can work in a background of 50 ppm methane, if the sensing system can distinguish 51 ppm from 50 ppm. The same applies for humidity and other interfering gases.
  • Figure 2 shows different kinds of measurement signals (without filter and with filter) and respective humidity when the gas modulation valve 16 switches between a sample gas having a larger humidity than the reference gas.
  • the humidity of the sample gas increases during the cycle, when the gas modulation valve 16 is switched to the sample gas inlet 12.
  • the measurement signal without the filter 28 would increase accordingly during the cycle when the valve 16 is switched to the sample gas inlet 12, and would decrease when the valve 16 is switched to the reference gas inlet 14.
  • the measurement signal of the gas sensor 24 remains at an almost constant low level with only slight increases during the cycle where the gas modulation valve 16 switches to the sample gas inlet 12.

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Abstract

A gas detection system comprising a sample gas inlet (12), a reference gas inlet (14) and a gas modulation valve (16) alternatingly connecting one of the sample gas inlet (12) and the reference gas inlet (14) to a gas sensor (24) is characterized in that a selective transfer filter (28) is located in the gas flow path (22) connecting the gas modulation valve (16) and the gas sensor (24).

Description

Gas Detection Using Gas Modulation
The invention refers to a gas detection system and to a respective method using a gas modulation valve switching between a reference gas inlet and a sample gas inlet.
Such a gas modulation valve and respective gas modulation is described in US 7,030,381 B2, the contents of which are incorporated herein by reference. Gas detectors according to US 7,030,381 B2 may comprise a sample gas inlet through which the gas to be detected (target gas) is sucked and a reference gas inlet through which gas from the surrounding atmosphere is sucked as a reference gas. The gas modulation valve connects the sample gas inlet and the reference gas inlet to the inlet of a gas sensor, such as an infrared gas sensor. The infrared gas sensor may, for example, have a cuvette comprising the inlet and a respective outlet for the gas to be analyzed, an infrared light source and an infrared detector. The gas flow path from the gas modulation valve to the inlet of the gas sensor (cuvette) is alternately connected to the sample gas inlet and to the reference gas inlet by the gas modulation valve. The switching by the gas modulation valve between the sample gas inlet and the reference gas inlet preferably occurs in a periodical manner at a periodic frequency, as described in US 7,030,381 B2.
Regulations throughout the world require regular survey of gas networks to check for possible leakage. The reason for this is primarily to protect the public from fires and explosions resulting from gas collecting in buildings and other confined spaces. The leak survey is typically carried out by moving a detector, sensitive to one of the main components of the gas, over the surface of the ground above the pipe carrying the gas.
The majority of detectors for this purpose utilize only one inlet and no secondary reference inlet.
A typical infrared sensor often used in this type of detector is a non-dispersive infrared absorption detector (NDIR sensor). Another sensor type which might be used for gas detection according to the gas modulation principle is a metal oxide semi-conductor sensor, such as an Sn02 sensor. Both the NDIR and MOS sensors suffer from limited selectivity versus water vapour. When walking with a handheld probe, it is therefore a common problem that the gas sensor reacts when e.g. moving from an asphalt surface onto a grass surface with a higher humidity or from a sunny area into a shady area or vice versa. Similar selectivity problems are observed on most types of gas sensors. The invention is therefore not meant to be restricted to a specific sensor type. Various filters are known to be used for removing or capturing the humidity and/or non-wanted flammable gases from the gas sample. The filters need to have a large enough capacity to last for an acceptable amount of time. The filter needs to be replaced, baked out or otherwise regenerated quite often.
It is an object of the invention to improve the selectivity for a gas detector of the gas modulation type without the need for regular filter replacement.
The gas detection system of the invention is defined by independent claim 1. The method of the invention is defined by independent claim 6.
According to claim 1, the gas detection system of the invention comprises a sample gas inlet, a reference gas inlet and a gas modulation valve alternatingly connecting one of the sample gas inlet and the reference gas inlet to a gas sensor. The system is characterized by a selective transfer filter located in the gas flow path connecting the gas modulation valve and the gas sensor, and may be acting as a low-pass filter for gases of no interest that cause unwanted signals in the system. The most common of such gases is water or humidity.
The term "selective transfer filter" means that different gas components or gas types are selectively transferred through the filter with different transfer times. Thereby, the gas transfer time of specific gas components is controlled in order to achieve a selectivity of the filter for specific gas components via the respective transfer time of this gas component compared to other gas components. The selective transfer filter may achieve different transfer times for different gas types or components, for example, via a different time behavior of the filter for adsorption and desorption of respective gases or gas species resulting in specific transfer times or passage times of different gas species through the filter. The different transfer times may be expressed by the filtering time constant of the filter for respective gases or species. The selective transfer filter may thus also be named "retention filter" or "physical low-pass filter". The filtering time constant of the selective transfer filter for disturbing species, i.e. unwanted gases or humidity, should be significantly longer, preferably more than five times longer, than the filtering time constant for the target gas or gases and the period of the switching of the gas modulation valve between the sample gas inlet and the reference gas inlet.
In particular, the selective transfer filter may be a humidity and/or gas filter. The filter may comprise or be made of at least one of a surface-active material, a cigarette filter material, active carbon material and/or silica gel.
The gas sensor may be an infrared sensor, and preferably a non-dispersive infrared sensor, optically tuned to detect methane, ethane, propane, butane or LPG gases. The gas sensor may be a combination of a non-dispersive infrared (NDIR) sensor and at least one further gas sensor, such as a metal oxide semiconductor (MOS) sensor.
According to claim 6, the method of the invention for gas detection uses a gas detection system as described above and according to any one of the claims. According to the invention, the gas modulation valve alternatingly connects the reference gas inlet and the sample gas inlet with the gas flow path leading to the gas via the selective transfer filter. The filter is used as a low-pass filter to slow down the changes in, for example, the humidity of the gas when switching between the sample gas inlet and the reference gas inlet. In particular, the capacity of the filter does not need to be large enough in order to dry the gas, i.e. reduce the humidity of the gas. Only the changes in humidity during the switching cycles need to be dampened.
The general idea is to employ a selective transfer filter, such as a humidity filter, not for removing or capturing the entire humidity from the gas sample, but rather as a low-pass filter in the gas flow path between the gas modulation valve and the gas sensor. The capacity of the humidity filter only needs to be large enough to dampen changes in humidity when the gas modulation valve switches between the sample gas inlet and the reference gas inlet. Typically, the sample gas inlet sucks in humid gas, e.g. when approaching humid ground surfaces, such as grass. The reference gas inlet at the same time does not suck in the same amount of humidity because the reference gas inlet is located to take up gas from the surroundings of the measuring location, that may contain a test gas background that is to be taken into consideration when detecting the test gas taken up at the measuring location by the sample gas inlet. The humidity filter is not used to dry the gas. The low-pass filter effect of the humidity filter only occurs in combination with the gas modulation valve switching between humid gas and reference gas of less humidity.
Humidity is only an example of a gas or gas property which is affected by the selective transfer filter when passing therethrough. Humidity is hereby considered as a gas component the transfer time of which is significantly increased by the selective transfer filter as compared to a target gas. In the example of a humidity filter, the filter thus has a different (significantly longer) time constant for the "gas" humidity than for the target gas, thereby acting as a low-pass filter for the disturbing gas species humidity. If the analyzed gas is a mixture of a possible target gas and other gas components different from humidity but still unwanted, the selective transfer filter may be adapted to achieve a longer transfer time for those unwanted gas components than for the target gas. The longer transfer time may be achieved through a larger filtering time constant.
In the following, an embodiment of the invention is discussed with reference to the figures.
Figure 1 shows the general layout of the system of the invention and Figure 2 shows humidity percentage over time in an embodiment employing a humidity filter.
A sample gas inlet 12 and a reference gas inlet 14 are connected to a gas modulation valve 16 via respective sample and reference gas conduits 18, 20. The gas modulation valve 16 alternatingly connects the sample gas conduit 18 or the reference gas conduit 20 to the gas flow path 22 connecting the gas modulation valve 16 and the gas sensor 24. In the embodiment shown in figure 1, the gas sensor 24 may be a non-dispersive infrared sensor comprising an absorption cuvette. The gas flow path 22 contains a sample vacuum pump 26 and a selective transfer filter 28. The selective transfer filter 28 is located between the gas modulation valve 16 and the gas sensor 24. The selective transfer filter 28 is also located between the vacuum pump 26 and the gas sensor 24. The vacuum pump 26 is located between the gas modulation valve 16 and the filter 28.
The gas modulation valve 16 is opened and closed in a cyclic manner, thereby alternatingly and periodically connecting the sample gas inlet 12 or the reference gas inlet 14 to the gas flow path 22. The switching occurs at a frequency suitable for the application, depending on the signal update frequency demanded by the application and/or the time constant of the gas detection sensor 24. The selected frequency is typically a compromise between application demands (typically a few hertz or higher) and the time constant of the gas sensor 24 which, in reality, is seconds or minutes for most sensor types.
The gas modulation valve 16 is used to create a signal modulation for noise reduction and signal amplification. Thereby, the valve 16 takes gas from the sample gas inlet 12 at the actual point of interest or the reference gas inlet 14 from the background air in an alternating cycle. The output signal of the gas sensor 24 is analyzed in relation to the switching frequency and sometimes also the phase in order to improve the sensitivity and to reduce background noise. An increase in humidity in the ambient air will be suppressed because both the sample gas inlet 12 and the reference gas inlet 14 take gas from the ambient air. Non-gas related noise will also be suppressed as this will normally not coincide with the gas signal in frequency and phase.
The major problem with the prior art systems employing gas modulation switching between a sample gas inlet and a reference gas inlet is that ambient conditions may be changing differently between the separated gas inlets. This occurs, for example, when the ground surface is screened with a hand-held probe for gas emerging from underground pipes. This is often done by dragging a carpet-like device on the surface. The sample inlet is then typically placed below the carpet and the reference gas inlet is placed above the carpet. Accordingly, when the carpet is moved between areas of different humidity, there will be an immediate difference in humidity of the sample gas and the reference gas entering the sample gas inlet 12 and the reference gas inlet 14, respectively. This difference in humidity between the sample gas and the reference gas will result in a signal with the same frequency as the modulation and can, therefore, not be adequately suppressed by filtering algorithms. This is at least the case when the humidity difference is large enough to induce a signal in the gas sensor 24.
The selective transfer filter 28 between the gas modulation valve 16 and the gas sensor 24 is a surface-active humidity filter. The filter 28, through which a continuous flow of air is passing, does not need to have the capacity to remove all of the humidity from the sample. It is rather enough that the filter 28 slows down the changes in humidity due to the gas modulation, thereby acting as a humidity low-pass filter. The time constant of the filter is significantly larger than the time period of the gas modulation cycle. Thereby, the humidity level after the filter will eventually adapt to the average of humidity in the sample gas and the reference gas, but, as the time constant is significantly longer than the gas modulation cycle, this can be suppressed by the signal algorithms.
Typical filter materials, such as surface-active filter materials, cigarette filter materials, activated carbon material or silica gel not only slow down humidity changes, but also changes in concentration of heavier hydrocarbons or other flammable gases. This invention therefore works best for detection of light gases such as hydrogen and methane when employing conventional surfaces active filtering materials. Using chemically tailored filters it would, however, also be possible to implement this invention for the other gases.
Hydrocarbons typically influence most gas sensors including infrared sensors such as the NDIR sensor. Other flammable gases typically influence most general gas sensors but to a lesser extent NDIR sensors.
The sensor 24 needs to have a large enough differential sensitivity for the target gas to be detected in the actual average humidity or average gas concentration in the ambient atmosphere. For example, the gas sensor 24 may be specified to detect 1 ppm methane. The gas detection system can work in a background of 50 ppm methane, if the sensing system can distinguish 51 ppm from 50 ppm. The same applies for humidity and other interfering gases.
Figure 2 shows different kinds of measurement signals (without filter and with filter) and respective humidity when the gas modulation valve 16 switches between a sample gas having a larger humidity than the reference gas.
When the sample gas inlet 12 approaches a humid surface, the humidity of the sample gas increases during the cycle, when the gas modulation valve 16 is switched to the sample gas inlet 12. The measurement signal without the filter 28 would increase accordingly during the cycle when the valve 16 is switched to the sample gas inlet 12, and would decrease when the valve 16 is switched to the reference gas inlet 14.
With the selective transfer filter 28, the measurement signal of the gas sensor 24 remains at an almost constant low level with only slight increases during the cycle where the gas modulation valve 16 switches to the sample gas inlet 12.

Claims

Claims
1. Gas detection system comprising a sample gas inlet (12), a reference gas inlet (14) and a gas modulation valve (16) alternatingly connecting one of the sample gas inlet (12) and the reference gas inlet (14) to a gas sensor (24) c h a r a c t e r i z e d i n t h a t a selective transfer filter (28) is located in the gas flow path (22) connecting the gas modulation valve (16) and the gas sensor (24).
2. Gas detection system according to claim 1, wherein the filter (28) has a filtering time constant for disturbing gas species which is significantly longer, preferably more than 5 times longer, than the filtering time constant for the target gas(es) and the period of the switching of the gas modulation valve (16) between the sample gas inlet (12) and the reference gas inlet (14).
3. Gas detection system according to claim 1 or 2, wherein said selective transfer filter (28) comprises or is made of at least one of a surface- active material, a cigarette filter material, active carbon material and/or silica gel.
4. Gas detection system according to any one of claims 1-3, wherein said gas sensor (24) is an infrared sensor (24), preferably a non-dispersive infrared sensor (24), optically tuned to detect methane, ethane, propane, butane or LPG gases.
5. Gas detection system according to any one of claims 1-4, wherein the gas sensor (24) is a combination of a non-dispersive infrared sensor (24) and at least one further gas sensor (24), preferably based on another detection principle.
6. Method for gas detection using a gas detection system according to any one of claims 1-5, wherein said gas modulation valve (16) alternatingly connects the reference gas inlet (12) and the sample gas inlet (14) with the gas flow path (22) leading to the gas sensor (24) via the selective transfer filter (28).
7. Method according to claim 6, wherein the filtering time constant of the selective transfer filter (28) is significantly and preferably more than five times longer than the filtering time constant for the target gas(es) and the period of the gas modulation.
8. Method according to claim 6 or 7, wherein the selective transfer filter (28) is used as a low-pass filter to slow down the changes in specific properties of the gas, such as the humidity, when switching between the sample gas inlet (12) and the reference gas inlet (14).
PCT/EP2016/075560 2015-10-29 2016-10-24 Gas detection using gas modulation Ceased WO2017072076A1 (en)

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US10352848B2 (en) 2019-07-16
EP3163299A1 (en) 2017-05-03
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CN108603871A (en) 2018-09-28
CN108603871B (en) 2021-03-19

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