WO2017071320A1 - Battery utilizing ion exchange membrane and microfluidic technique to realize multi-electrolyte structure - Google Patents
Battery utilizing ion exchange membrane and microfluidic technique to realize multi-electrolyte structure Download PDFInfo
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- WO2017071320A1 WO2017071320A1 PCT/CN2016/090966 CN2016090966W WO2017071320A1 WO 2017071320 A1 WO2017071320 A1 WO 2017071320A1 CN 2016090966 W CN2016090966 W CN 2016090966W WO 2017071320 A1 WO2017071320 A1 WO 2017071320A1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/04—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
- H01M12/06—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
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Abstract
The invention relates to the technical field of batteries. Specially, the invention relates to a battery utilizing ion exchange membranes and a microfluidic technique to realize a multi-electrolyte structure, comprising: an anode plate; a cathode plate; electrolytes, wherein the electrolytes comprise an anode electrolyte, a cathode electrolyte, and a bridge electrolyte; and an anode channel, a cathode channel and a bridge channel for respectively transferring the flowing anode electrolyte, cathode electrolyte and bridge electrolyte. The anode plate is in communication with the anode channel and is in contact with the anode electrolyte. The cathode plate is in communication with the cathode channel and is in contact with the cathode electrolyte. The anode plate and the cathode plate are respectively in contact with the anode electrolyte and the cathode electrolyte to induce electrochemical reactions. The bridge electrolyte selectively conducts ions between itself and the anode electrolyte and between itself and the cathode electrolyte, respectively, thereby greatly expanding ranges of applicable cathode materials and anode materials for the battery, facilitating concurrent achievement of optimal electrochemical reactions at an anode and a cathode of the battery, and significantly improving electrochemical performance of the battery.
Description
本发明涉及电池技术领域,具体涉及一种利用离子交换膜和微流体技术的多电解液结构电池。The present invention relates to the field of battery technology, and in particular to a multi-electrolyte structure battery using an ion exchange membrane and a microfluidic technology.
电池(Battery)指盛有电解质溶液和金属电极以产生电流的杯、槽或其他容器或复合容器的部分空间,能将化学能转化成电能的装置,利用电池作为能量来源,可以得到具有稳定电压,稳定电流,长时间稳定供电,受外界影响很小的电流,并且电池结构简单,携带方便,充放电操作简便易行,不受外界气候和温度的影响,性能稳定可靠,在现代社会生活中的各个方面发挥有很大作用。Battery refers to the space of a cup, tank or other container or composite container containing an electrolyte solution and a metal electrode to generate electric current. A device capable of converting chemical energy into electrical energy, and using the battery as a source of energy, can obtain a stable voltage. Stable current, stable power supply for a long time, small current affected by the outside world, and simple battery structure, easy to carry, easy to charge and discharge, free from external climate and temperature, stable and reliable performance, in modern social life All aspects play a big role.
目前,市场上已商业化的电池,如锂离子电池、铅酸电池、镍锌电池以及金属空气电池,主要以单电解液为主。然而单电解液的电池结构存在两大技术问题:(1)由于电池的阴极、阳极均直接插入同一电解液中,因此电池阴极、阳极材料必须同时与该单电解液兼容,在开发新电池时,大大限制了电池阴极、阳极材料的选择范围;(2)单电解液的成分和浓度很难保证电池使用过程中阴极和阳极的电化学反应同时达到最佳状态(最大活性),不利于电池发挥其最佳的电化学性能。At present, commercially available batteries, such as lithium ion batteries, lead-acid batteries, nickel-zinc batteries, and metal-air batteries, are mainly composed of a single electrolyte. However, there are two technical problems in the battery structure of a single electrolyte: (1) Since the cathode and the anode of the battery are directly inserted into the same electrolyte, the cathode and anode materials of the battery must be compatible with the single electrolyte at the same time, when developing a new battery. , greatly limits the choice of battery cathode and anode materials; (2) the composition and concentration of the single electrolyte is difficult to ensure that the electrochemical reaction of the cathode and anode during the use of the battery simultaneously achieves the best state (maximum activity), which is not conducive to the battery Give full play to its optimal electrochemical performance.
发明内容Summary of the invention
本发明的目的在于针对现有技术的不足提供一种利用离子交换膜和微流体技术的多电解液结构电池,不仅极大的拓展了电池阴、阳极材料的选择范围,而且有利于电池阴、阳极的电化学反应同时达到最佳状态,显著提高其电化学性能。The object of the present invention is to provide a multi-electrolyte structure battery using ion exchange membrane and microfluidic technology for the deficiencies of the prior art, which not only greatly expands the selection range of the anode and anode materials of the battery, but also facilitates the battery cathode, The electrochemical reaction of the anode is simultaneously optimized to significantly improve its electrochemical performance.
本发明通过以下技术方案实现该目的:The present invention achieves the object by the following technical solutions:
一种利用离子交换膜和微流体技术的多电解液结构电池,包括阳极板、阴极板以及处于流动状态的电解液,所述电解液包括阳极电解液、阴极电解液以及桥电解液,还包括分别用于输送阳极电解液、阴极电解液以及桥电解液的阳极管道、阴极管道和桥管道,所述阳极板与阳极管道连通并与阳极电解液接触,所述阴极板与阴极管道连通并与阴极电解液接触,所
A multi-electrolyte structure battery using an ion exchange membrane and a microfluidic technology, comprising an anode plate, a cathode plate and an electrolyte in a flowing state, the electrolyte comprising an anolyte, a catholyte and a bridge electrolyte, and further comprising An anode pipe, a cathode pipe, and a bridge pipe for respectively conveying an anolyte, a catholyte, and a bridge electrolyte, wherein the anode plate is in communication with the anode pipe and is in contact with the anolyte, and the cathode plate is in communication with the cathode pipe and Catholyte contact,
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CN201510726809.7A CN105406154B (en) | 2015-10-29 | 2015-10-29 | It is a kind of to utilize amberplex and more electrolyte structure batteries of micro-fluidic technologies |
CN201510726809.7 | 2015-10-29 |
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CN105355958B (en) * | 2015-10-29 | 2018-03-30 | 广州道动新能源有限公司 | A kind of novel battery that more electrolyte structures are realized using micro-fluidic technologies |
CN105406154B (en) * | 2015-10-29 | 2018-05-25 | 广州道动新能源有限公司 | It is a kind of to utilize amberplex and more electrolyte structure batteries of micro-fluidic technologies |
CN105406153B (en) * | 2015-10-29 | 2018-09-14 | 广州道动新能源有限公司 | A kind of novel battery for realizing more electrolyte structures using amberplex |
CN106711487A (en) * | 2017-03-31 | 2017-05-24 | 重庆大学 | Film-free heat regenerative ammonia cell and manufacturing method |
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