WO2017008269A1 - Electrochemical energy storage device and method for preparing electrochemical energy storage device - Google Patents

Electrochemical energy storage device and method for preparing electrochemical energy storage device Download PDF

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Publication number
WO2017008269A1
WO2017008269A1 PCT/CN2015/084099 CN2015084099W WO2017008269A1 WO 2017008269 A1 WO2017008269 A1 WO 2017008269A1 CN 2015084099 W CN2015084099 W CN 2015084099W WO 2017008269 A1 WO2017008269 A1 WO 2017008269A1
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WIPO (PCT)
Prior art keywords
storage device
energy storage
electrochemical energy
adhesive layer
adhesive
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PCT/CN2015/084099
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French (fr)
Chinese (zh)
Inventor
鲍晋珍
方宏新
阳超
喻鸿钢
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宁德时代新能源科技股份有限公司
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Application filed by 宁德时代新能源科技股份有限公司 filed Critical 宁德时代新能源科技股份有限公司
Priority to PCT/CN2015/084099 priority Critical patent/WO2017008269A1/en
Priority to CN201580080052.7A priority patent/CN107615549B/en
Publication of WO2017008269A1 publication Critical patent/WO2017008269A1/en

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/058—Construction or manufacture
    • H01M10/0587—Construction or manufacture of accumulators having only wound construction elements, i.e. wound positive electrodes, wound negative electrodes and wound separators
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Definitions

  • the present invention relates to the field of battery technologies, and in particular, to an electrochemical energy storage device and a method for preparing the electrochemical energy storage device.
  • an object of the present invention to provide an electrochemical energy storage device and a method of fabricating the same, which can improve its performance without affecting its other properties.
  • Security issues of abuse such as dropping, squeezing, rolling, etc.).
  • the invention provides an electrochemical energy storage device comprising a battery core, an electrolyte, and a package.
  • the battery core comprises a positive electrode sheet, a negative electrode sheet and a separator interposed between the positive electrode sheet and the negative electrode sheet; the electrolyte is impregnated with the battery core; and the package body houses the battery core and the electrolyte.
  • the electrochemical energy storage device also includes an adhesive layer.
  • the adhesive layer is located between the battery core and the package shell and fixes the battery core and the package shell; the adhesive layer is flow dynamic before curing and the adhesion between the adhesive shell and the package shell is less than or equal to 0.1 N/mm, and the adhesive After the adhesive layer is cured, the cell and the package are fixedly connected.
  • the invention provides a method of preparing an electrochemical energy storage device,
  • the electrochemical energy storage device for preparing the first aspect of the invention comprises the steps of: forming a positive electrode sheet, a negative electrode sheet, and a separator separated between the positive electrode sheet and the negative electrode sheet into a battery core; between the battery core and the packaging shell
  • the adhesive layer is set, the adhesive layer is flow dynamic and the adhesive force between the adhesive layer and the package shell is less than or equal to 0.1 N/mm; the battery core is filled into the package shell, the electrolyte is poured and sealed, and then the package is packaged.
  • the outer surface of the shell is heated or pressurized to effect curing of the adhesive layer to securely attach the cell to the package.
  • the method for preparing an electrochemical energy storage device of the invention is simple in process, easy to implement, and can be adapted to different temperature and humidity environments and has low requirements for action conditions.
  • the adhesive layer can be rearranged in the electrochemical energy storage device before curing, which is beneficial to improve the appearance flatness and energy density of the electrochemical energy storage device.
  • the interface between the adhesive layer and the electric core and the packaging shell is better, and the interface bonding problem such as wrinkling of the adhesive layer and wrinkling of the surface of the electric core does not occur. .
  • the adhesion between the adhesive layer and the cell and the package is more uniform, and the surface of the cell is torn during the fall, extrusion, and rolling test.
  • the flowability of the adhesive layer can stick the multi-face junction or the junction of the shaped cell, effectively solving the problem of edge picking at the junction.
  • FIG. 1 is a partially cutaway perspective view of an electrochemical energy storage device in accordance with an embodiment of the present invention
  • FIG. 2 is a partially cutaway perspective view of an electrochemical energy storage device in accordance with another embodiment of the present invention.
  • FIG. 3 is a schematic view showing the structure of an electrochemical energy storage device according to the present invention, which is schematically exaggerated in section, taken along line A-A of FIG. 1.
  • electrochemical energy storage device and method and apparatus for preparing the electrochemical energy storage device according to the present invention, comparative examples, test procedures, and test results are described below.
  • an electrochemical energy storage device includes: a cell 1, an electrolyte, and a package 2.
  • the battery cell 1 includes a positive electrode sheet, a negative electrode sheet, and a separator interposed between the positive electrode sheet and the negative electrode sheet; the electrolyte is impregnated with the battery core 1; and the package body 2 houses the battery core 1 and the electrolyte.
  • the electrochemical energy storage device also includes an adhesive layer 3.
  • the adhesive layer 3 is located between the battery core 1 and the package casing 2 and fixedly connects the battery core 1 and the package casing 2.
  • the adhesive layer 3 is flowable before curing and has a bonding force with the package 2 of 0.1 N/mm or less. After the adhesive layer 3 is cured, the cell 1 and the package 2 are fixedly connected.
  • the adhesive layer 3 is flow dynamic, it can be rearranged in the electrochemical energy storage device before the adhesive layer 3 is cured, which is advantageous. Improve the appearance flatness of the electrochemical energy storage device; since the adhesive layer 3 is flow dynamic, the adhesive will flow to a position where the overall thickness of the electrochemical energy storage device is small, and only a trace amount of adhesive is left at the glue application position.
  • the overall thickness of the electrochemical energy storage device can be increased without increasing the overall thickness of the electrochemical energy storage device, and the overall thickness of the electrochemical energy storage device is reduced, which helps to increase the energy density of the electrochemical energy storage device;
  • the adhesive The flow of the layer 3 makes it better to interface with the cell 1 and the package 2 without interfacial adhesion problems such as wrinkling of the adhesive layer 3, wrinkling of the surface of the cell 1, and an adhesive layer. 3
  • the bonding force between the battery core 1 and the packaging shell 2 is more uniform, and the surface of the battery core 1 is torn during the fall, extrusion and rolling test; the flow characteristics of the adhesive layer 3 are particularly suitable for the special-shaped battery. In the case, the multi-face junction or junction of the shaped cell can be stuck To solve the problem of the edge of the junction.
  • the adhesive layer 3 has a bonding force with the package shell 2 of 0.1 N/mm or less before curing, and is convenient for entering the shell.
  • the adhesive force between the adhesive layer 3 and the packaging shell 2 is greater than 0.1 N/mm, the adhesive layer 3 and the packaging shell 2 are directly bonded when the shell is inserted, and the adhesive layer 3 cannot be electrically charged.
  • the chemical energy storage device is rearranged, and the appearance flatness of the electrochemical energy storage device is not guaranteed.
  • the viscosity of the adhesive layer 3 before curing can be less than or equal to 100,000 mp.s to ensure that the adhesive layer 3 is flow dynamic.
  • the material of the adhesive layer 3 may be selected from a pressure-sensitive adhesive having no initial viscosity at normal temperature, and a heat-sensitive adhesive having no initial viscosity at normal temperature.
  • a pressure-sensitive adhesive having no initial viscosity at normal temperature may be selected from the group consisting of styrene-ethylene-butadiene-styrene block copolymer (SEBS), styrene-butadiene block copolymer (SEPS), and One or more of epoxidized styrene-isoprene-styrene block copolymers (ESIS).
  • SEBS styrene-ethylene-butadiene-styrene block copolymer
  • SEPS styrene-butadiene block copolymer
  • ESIS epoxidized styrene-isoprene-styrene block copolymers
  • the heat-sensitive adhesive having no initial tack at normal temperature may be selected from one or more of polyolefin, polyvinyl butyral (PVB), polyamide (PA), and polyester (PES).
  • the monomer of the polyolefin may be selected from one or more of ethylene, propylene, isoprene, vinyl acetate, butene, acrylic acid, acrylate, butadiene, and styrene.
  • the polyolefin may be selected from the group consisting of polyethylene (PE), polypropylene (PP), polyisoprene (PI), polystyrene (PS), ethylene-vinyl acetate copolymer (EVA), ethylene- Ethyl acrylate copolymer (EEA), ethylene-acrylic acid copolymer (EAA), styrene-isoprene-styrene copolymer (SIS), and styrene-butadiene-styrene block copolymer (SBS) One or several of them.
  • the reactive adhesive may be selected from one or more of an epoxy resin, a phenol resin, and a urea resin.
  • the pressure-sensitive adhesive having no initial tack at normal temperature refers to a pressure which does not cause adhesion to an object when a short-term contact occurs between the object and the pressure-sensitive adhesive under normal pressure at a normal temperature.
  • Sensitive adhesive In the present application, the heat-sensitive adhesive refers to a type of glue which can be melted after heating and can be bonded and solidified after being cooled.
  • the heat-sensitive adhesive having no initial tack at normal temperature refers to a heat-sensitive adhesive which does not cause adhesion to an object when a short-term contact occurs between the object and the heat-sensitive adhesive at normal temperature.
  • Agent refers to a non-adhesive property of the adhesive layer in an initial state, and a chemical reaction occurs between the components of the adhesive layer or the environmental substance in contact under heat, organic solvent or acidic conditions to cause cohesiveness. Adhesive.
  • the adhesive layer 3 may have a single layer structure.
  • the adhesive layer 3 may have an N-layer structure, and N is an integer of 2 or more.
  • the material of the sub-layer 31 of the adhesive layer 3 near the outer surface of the cell 1 may be selected from a pressure-sensitive adhesive having no initial tack at normal temperature or a heat-sensitive adhesive having no initial tack at normal temperature.
  • the outer surface of the battery cell 1 is tempered at room temperature and subsequently heated or pressurized to the outer surface of the package casing 2 to achieve rapid bonding with the outer surface of the battery core 1.
  • the material of the sub-layer 32 of the adhesive layer 3 near the inner surface of the package can be selected from a thermosensitive adhesive having no initial tack at normal temperature.
  • the adhesive or reactive adhesive does not cause adhesion of the sub-layer 32 even when pressed during the sizing process, and is convenient for entering the shell.
  • the material of the sub-layer of the remaining adhesive layer 3 is not limited, and may preferably be selected from a pressure-sensitive adhesive having no initial tack at normal temperature, a heat-sensitive adhesive having no initial tack at normal temperature, and a reactive adhesive. One or more of the agents to enhance adhesion.
  • the pressure-sensitive adhesive having no initial tack at normal temperature may be selected from the group consisting of styrene-ethylene-butadiene-styrene blocks. Copolymer (SEBS).
  • SEBS styrene-ethylene-butadiene-styrene blocks. Copolymer
  • the heat-sensitive adhesive having no initial tack at normal temperature may be selected from the group consisting of styrene-isoprene-styrene block copolymer (SIS), polystyrene (PS) or polyisoprene (PI).
  • the reactive adhesive may be selected from epoxy resins.
  • an electrolyte additive may also be included in the adhesive layer 3.
  • the electrolyte additive may be selected from one or more of ethylene sulfate, propylene sulfate, biphenyl, ethylene carbonate, vinylene carbonate, fluoroethylene carbonate, propane sultone, and adiponitrile. Not only can the electrolyte be infiltrated, but also the electrolyte additive can be gradually released from the adhesive layer 3 into the electrolyte during the cycle to improve the electrochemical performance of the electrochemical energy storage device.
  • the surface area of the adhesive layer 3 facing the outer surface of the battery core 1 may not be larger than the surface area of the outer surface of the battery core 1, and the adhesive layer 3 faces the package casing 2
  • the surface area of the inner surface may be no greater than the surface area of the outer surface of the cell 1.
  • the thickness at the thickest position of the adhesive layer 3 may not be greater than the thickness difference between the thickest position and the thinnest position of the battery core 1 in order to utilize the glue.
  • the flow characteristics of the adhesive layer 3 enhance the appearance flatness of the electrochemical energy storage device.
  • the adhesive layer 3 may be disposed at any position between the battery cell 1 and the package can 2.
  • the adhesive layer 3 may be disposed at one or several positions in the length, width, height direction surface of the battery cell 1, the tab area, and the region of the separator beyond the positive and negative electrode sheets.
  • the thickness of the adhesive layer 3 may be from 2 ⁇ m to 100 ⁇ m.
  • the electrochemical energy storage device may be selected from one of a lithium ion secondary battery, a super capacitor, a fuel cell, and a solar cell.
  • the battery cell 1 may be a coiled type battery Core, laminated battery or stacked roll cells.
  • the battery cell 1 can also be a profiled cell.
  • the package casing 2 may be a flexible package or a hard package.
  • the package 2 may be selected from an aluminum plastic film, a steel plastic film, an aluminum alloy case or a magnesium alloy case.
  • the method for preparing an electrochemical energy storage device for preparing the electrochemical energy storage device of the first aspect of the invention, comprising the steps of: Step 1: separating the positive electrode sheet, the negative electrode sheet, and the positive electrode sheet and the negative electrode The separator between the sheets is made into the cell 1; Step 2: an adhesive layer 3 is disposed between the cell 1 and the package 2, the adhesive layer 3 is flow dynamic and the adhesive layer 3 and the package 2 The bonding force between the two is less than or equal to 0.1 N/mm; Step 3: loading the battery core 1 into the packaging shell 2, injecting the electrolyte and sealing, and then heating or pressurizing the outer surface of the packaging shell 2 to realize the adhesive layer 3 The curing is to securely connect the battery cell 1 and the package case 2.
  • the adhesive layer 3 can be adhered between the cell 1 and the package 2
  • the interface is rearranged, even if the adhesive layer 3 flows to a position where the overall thickness of the electrochemical energy storage device is small, so that the interface is flat, thereby increasing the energy density of the electrochemical energy storage device.
  • the adhesive layer 3 may be disposed on the outer surface or package of the battery cell 1 by coating or dispensing.
  • the coating method has a larger sizing area per unit time, and is advantageous for increasing the productivity of the battery core 1 having a larger surface area; the dispensing method is more flexible, and has no selectivity for the sizing position, and is particularly suitable for use in a shaped battery.
  • the multi-face junction or junction of the shaped cell can be stuck to solve the problem of edge lifting at the junction.
  • the temperature at which the adhesive layer 3 is disposed may be 10 ° C to 200 ° C, and the relative humidity (RH) may be 10 % ⁇ 80%.
  • the temperature at the time of heat curing may be 45 ° C to 90 ° C, and the pressure at the time of pressure curing may be 0.2 MPa to 2 MPa. .
  • LiCoO 2 , conductive carbon, and polyvinylidene fluoride were dispersed in N-methylpyrrolidone in a weight ratio of 95:1:4 to prepare a positive electrode slurry, which was then compacted into a positive electrode sheet having a thickness of 102 ⁇ m.
  • Graphite, conductive carbon, sodium carboxymethylcellulose, styrene-butadiene rubber were dispersed in deionized water at a weight ratio of 96:1:2:1 to prepare a negative electrode slurry, which was then compacted by coating to form a negative electrode having a thickness of 90 ⁇ m. sheet.
  • Ethylene carbonate (EC), propylene carbonate (PC), diethyl carbonate (DEC), and ethyl methyl carbonate (EMC) are formulated into a non-aqueous organic solvent at a weight ratio of 20:20:45:15, and then added to 1.5.
  • the preparation of the electrolyte is completed by mol/L of LiPF 6 as a lithium salt.
  • the prepared positive electrode sheet, PE separator, and negative electrode sheet were sequentially wound to prepare a wound cell having a thickness of 4.0 mm, a width of 52 mm, and a length of 60 mm.
  • An adhesive having a viscosity of nearly 100,000 mp.s prepared from a styrene-isoprene-styrene 1:1:1 block copolymer was coated on a roll at 25 ° C and an RH of 20%.
  • the thickness of the adhesive layer is 50 ⁇ m
  • the adhesion between the adhesive layer and the aluminum film of the package is 0.05 N/mm, after which The battery core is filled into the packaging shell, the electrolyte is poured and sealed, and then the outer surface of the packaging shell is heated to 75 ° C to cure the adhesive layer to fix the battery core and the packaging shell, and then formed into a gas and formed into a lithium. Preparation of an ion secondary battery.
  • a lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
  • the viscosity is 60,000 mp.s and the aluminum alloy is packaged with styrene-ethylene-butadiene-styrene 1:1:1:1 copolymer at 45 ° C and RH of 60%.
  • the adhesion between the films is less than 0.1 N / mm of adhesive is applied to the outer surface of the cell in the winding direction and the tail of the cell in the vertical winding direction, the thickness of the adhesive layer is 50 ⁇ m, and then the cell is loaded into the package
  • the electrolyte is filled and sealed, and then a surface pressure of 1 MPa is applied to the outer surface of the package to cure the adhesive layer to fix the battery core and the package, and then formed into a lithium ion secondary battery by chemical formation and evacuation molding. preparation.
  • a lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
  • the adhesive prepared by epoxy resin, viscosity 80,000 mp.s and the adhesion between the aluminum foil film and the packaging shell is less than 0.1N / mm Covering the two sides of the winding direction of the battery core, the thickness of the adhesive layer is 50 ⁇ m, then the battery core is placed in the packaging shell, the electrolyte is poured and sealed, and a surface pressure of 0.8 MPa is applied to the outer surface of the packaging shell to make the glue The adhesive layer is cured to fix the battery core and the package shell, and then is formed into a lithium ion secondary battery by chemical formation and evacuation molding.
  • a lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
  • the viscosity of the polypropylene is 50,000 at 200 ° C and RH 50%.
  • the adhesive of mp.s and the aluminum-plastic film of the package is less than 0.1N/mm, and the adhesive is applied to the surface of the battery in the winding direction and the head and tail of the vertical winding direction, and the adhesive is adhesive.
  • the thickness of the agent layer is 30 ⁇ m, after which the battery core is filled into the package shell, the electrolyte is poured and sealed, and the outer surface of the outer package is heated to 60 ° C and a surface pressure of 0.5 MPa is applied to cure the adhesive layer to laminate the battery and the package.
  • the shell is fixedly connected, and then subjected to chemical formation and evacuation molding to complete the preparation of the lithium ion secondary battery.
  • a lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
  • the viscosity is 60,000 mp.s, prepared from polystyrene at 180 ° C and 80% RH.
  • the adhesive agent having a bonding force of less than 0.1 N/mm with the aluminum foil of the package is coated on the upper and lower sides of the battery core perpendicular to the winding direction, and the thickness of the adhesive layer is 50 ⁇ m, and then the electricity is charged.
  • the core is filled into the package shell, the electrolyte is poured and sealed, and the outer surface of the outer package is heated to 75 ° C to cure the adhesive layer to fix the battery core and the package shell, and then formed into a lithium ion by chemical formation and evacuation molding. Preparation of secondary batteries.
  • a lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
  • the positive electrode sheet, the separator, and the negative electrode sheet were laminated in this order to prepare a laminated battery core having a thickness of 4.0 mm, a width of 52 mm, and a length of 60 mm.
  • the thickness of the adhesive layer is 50 ⁇ m, and then the laminated battery cell is placed in the packaging shell, the electrolyte is poured and sealed, and the outer surface of the outer packaging is heated to 75 ° C to make the adhesive.
  • the agent layer is cured to fix the cell and the package shell, and then formed into a lithium ion secondary battery by chemical formation and evacuation molding.
  • a lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
  • the positive electrode sheet, the separator, and the negative electrode sheet are sequentially wound to prepare a plurality of bare cells of different sizes, and then combined into a stepped shaped core.
  • the thickness of the adhesive layer is 50 ⁇ m.
  • the shaped cell is placed in the package, the electrolyte is poured and sealed, and the outer surface of the outer package is heated to 75 ° C to cure the adhesive layer.
  • the battery core and the package shell are fixedly connected, and then formed into a lithium ion secondary battery by chemical formation and evacuation molding.
  • a lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
  • the viscosity is 60,000 mp.s and the aluminum alloy is packaged with styrene-ethylene-butadiene-styrene 1:1:1:1 copolymer at 60 ° C and RH of 80%.
  • the adhesive having a bonding force between the films of less than 0.1 N/mm is applied to the outer surface of the wound cell other than the tab, the thickness of the adhesive layer is 50 ⁇ m, and the adhesive
  • the layer is further mixed with an electrolyte additive biphenyl having a mass percentage of 0.01% of the total mass of the adhesive layer, and then the wound cell is placed in the package, the electrolyte is poured and sealed, and then the outer surface of the package is applied.
  • a surface pressure of 1 MPa was applied to cure the adhesive layer to fix the cell and the package, and then formed into a lithium ion secondary battery by chemical formation and evacuation molding.
  • a lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
  • the wound cell At the winding end of the wound cell, it is directly fixed with a 5mm wide and 60mm long acrylic single-sided tape, then filled into the aluminum film of the package, filled with electrolyte and sealed, and then applied 1MPa to the outer surface of the package.
  • the surface pressure is used to fix the battery core and the package body, and then the formation and the extraction of the lithium ion secondary battery are completed.
  • a lithium ion secondary battery was prepared according to the method of Comparative Example 1, except for the following differences:
  • a lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
  • the surface of the wound cell is coated with the tape of the Chinese Patent Application Publication No. CN 102549801 A, and then the aluminum film of the package is filled, the electrolyte is poured and sealed, and a surface pressure of 1 MPa is applied to the outer surface of the package.
  • the battery core and the package shell are fixedly connected, and then formed into a gas and formed into a gas. Preparation of a lithium ion secondary battery.
  • a lithium ion secondary battery was prepared in accordance with the method of Example 7, except for the following:
  • the tape of the Chinese Patent Application Publication No. CN 102549801 A is bonded to the outer surface of the shaped core, and after the adhesive on the surface of the tape is dried, the aluminum plastic film of the package is filled, the electrolyte is poured and sealed, and then the package is sealed.
  • the outer surface of the outer surface is applied with a surface pressure of 1 MPa to fix the battery core and the package casing, and then formed into a lithium ion secondary battery by chemical formation and evacuation molding.
  • the main body of the lithium ion secondary battery is placed in a thickness tester, the tabs are exposed, and the thickness value of the main body of the lithium ion secondary battery is read and recorded, wherein the thickness of the lithium ion secondary battery main body is the thickness of the lithium ion secondary battery.
  • the thickness of the maximum position ie, the coincident area of the tab and the cell).
  • the lithium ion secondary battery was placed in a flatness meter (Shanghai Zhuo Li Li Tian Instrument Equipment Co., Ltd.) to test the flatness of the surface of the lithium ion secondary battery.
  • the package of the lithium ion secondary battery was disassembled, and the interface between the package and the cell was observed to have a poor interface due to wrinkling of the adhesive layer or wrinkling of the outer surface of the cell.
  • the lithium ion secondary battery is fixed in the drop test fixture with double-sided tape, and the six faces of the jig are sequentially numbered 1, 2, 3, 4, 5, and 6, and the four corners of the jig are sequentially numbered C1, C2, and C3. , C4.
  • the fixture was placed on a 1.5 m high test bench, and the lithium ion secondary batteries were sequentially dropped in the order of number 1-6, and then the lithium ion secondary batteries were sequentially dropped in the order of number C1-C4, and the cycle was repeated. 6 times, complete the drop test, after standing for 1h,
  • the pass rate of the lithium ion secondary battery drop test is calculated, and each group is tested with 10 lithium ion secondary batteries.
  • the lithium ion secondary battery was placed in an incubator at 25 ° C, and charged at a constant current of 0.5 C.
  • the cut-off voltage was 4.35 V, and then charged at a constant voltage of 4.35 V.
  • the off current was 0.025 C, and after standing for 3 min, 0.5. C constant current discharge, the cut-off voltage is 3.0V, this is a charge-discharge cycle process, repeating the above charging and discharging process 800 times, recording the initial thickness of the lithium ion secondary battery and the thickness after the cycle, and judging whether the lithium ion secondary battery is deformed
  • Each group was tested with 10 lithium ion secondary batteries.
  • Table 1 gives the performance test results of Examples 1-8 and Comparative Examples 1-4.
  • NA indicates that it is impossible to determine that the shaped cells were used in Example 7 and Comparative Example 4, and thus it was impossible to judge the appearance flatness.
  • the lithium ion secondary battery of the present invention can improve the drop test result without increasing the thickness of the battery, and the adhesive layer can prevent the deformation of the battery, the bonding interface is good, and the appearance of the battery is flat after long-term circulation.
  • the special-shaped battery is used, and the adhesive layer is disposed on the surface of the battery by means of dispensing, which not only facilitates the sizing of the shaped position, but also the fluidity of the adhesive layer can be used for the multi-face junction or junction of the shaped battery. Sticking and also re-bonding the bonding interface makes the bonding interface of the battery good, the surface of the battery is flat and the edge of the junction is not warped.
  • Example 8 It can be seen from Example 8 that a small amount of biphenyl is mixed in the adhesive.
  • the initial battery has better cycle performance, less demand for biphenyl, and the adhesive is used as the battery is used.
  • the biphenyl in the layer will gradually be released into the electrolyte, which can prevent the battery from over-decomposing lithium and the like, improve the cycle life of the battery, and avoid the problem of liquid rising caused by adding a large amount of electrolyte.
  • Comparative Example 1 and Comparative Example 2 respectively used single-sided adhesive tape and double-sided adhesive tape, which not only caused the bonding strength to decrease due to uneven bonding, but also the adhesive tape would tear the surface of the battery during the falling process, resulting in bonding in subsequent dropping. Invalid.
  • the tapes used in Comparative Example 3 and Comparative Example 4 also failed to improve the problem of wrinkling of the bonding interface and tearing of the surface of the core. Especially in Comparative Example 4, the tape used could not stick the multi-face junction or the junction of the shaped cell, resulting in the edge of the multi-face junction of the cell being warped.

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  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Sealing Battery Cases Or Jackets (AREA)
  • Secondary Cells (AREA)

Abstract

Provided are an electrochemical energy storage device and a method for preparing the electrochemical energy storage device. The electrochemical energy storage device comprises a cell, an electrolyte and a packaging shell. The electrochemical energy storage device further comprises an adhesive layer. The adhesive layer is located between the cell and the packaging shell, and fixedly connects the cell to the packaging shell. The adhesive layer is in a flow state before curing and the adhesion to the packaging shell is less than or equal to 0.1 N/mm, and the cell and the packaging shell are fixedly connected after the adhesive layer having been cured. The electrochemical energy storage device can improve the safety problem caused by abuse without influencing other properties thereof.

Description

电化学储能装置及制备电化学储能装置的方法Electrochemical energy storage device and method for preparing electrochemical energy storage device 技术领域Technical field
本发明涉及电池技术领域，尤其涉及一种电化学储能装置及制备电化学储能装置的方法。The present invention relates to the field of battery technologies, and in particular, to an electrochemical energy storage device and a method for preparing the electrochemical energy storage device.
背景技术Background technique
目前的电池几乎很难通过跌落测试，因为在跌落过程中，裸电芯的各层极片之间有时会出现滑动从而正、负极片接触而导致电池内部短路，裸电芯甚至会冲开包装壳的封边(顶封边或侧封边)而导致电解液的泄漏。传统的改进方法常常不能满足新的测试条件，而且从传统的材料体系及制备工艺上进行继续改进的难度和技术成本也大大增加。在裸电芯与包装壳之间设置胶带捆绑和粘接，又会带来增加电池厚度、入壳困难、局部应力不均导致裸电芯表面撕裂等问题。It is almost impossible for the current battery to pass the drop test, because during the falling process, the poles of the bare cell sometimes slide between the positive and negative plates, causing the internal short circuit of the battery, and the bare cell may even open the package. The edge of the shell (top or side seal) causes leakage of electrolyte. Traditional improvements often fail to meet new test conditions, and the difficulty and technical cost of continuing to improve from traditional material systems and manufacturing processes is greatly increased. The tape binding and bonding between the bare cell and the package shell brings problems such as increased battery thickness, difficulty in entering the shell, and uneven local stress causing tearing of the bare cell surface.
有鉴于此，确有必要提供一种在不影响电池其它性能的情况下改善其滥用的安全性问题(如跌落、挤压、滚动等)的电池。In view of this, it is indeed necessary to provide a battery that improves the safety of its abuse (such as dropping, squeezing, rolling, etc.) without affecting other performance of the battery.
发明内容Summary of the invention
鉴于背景技术中存在的问题，本发明的目的在于提供一种电化学储能装置及制备电化学储能装置的方法，所述电化学储能装置能在不影响其其它性能的情况下改善其滥用的安全性问题(如跌落、挤压、滚动等)。In view of the problems in the prior art, it is an object of the present invention to provide an electrochemical energy storage device and a method of fabricating the same, which can improve its performance without affecting its other properties. Security issues of abuse (such as dropping, squeezing, rolling, etc.).
为了实现上述发明目的，在本发明的第一方面，本发明提供了一种电化学储能装置，其包括电芯、电解液以及包装壳。电芯包括正极片、负极片以及间隔于正极片、负极片之间的隔离膜；电解液浸渍电芯；包装壳容纳电芯及电解液。所述电化学储能装置还包括胶黏剂层。胶黏剂层位于电芯和包装壳之间并将电芯和包装壳固定连接；胶黏剂层在固化前为流动态且与包装壳之间的粘结力小于等于0.1N/mm，胶黏剂层固化后将电芯和包装壳固定连接。In order to achieve the above object, in a first aspect of the invention, the invention provides an electrochemical energy storage device comprising a battery core, an electrolyte, and a package. The battery core comprises a positive electrode sheet, a negative electrode sheet and a separator interposed between the positive electrode sheet and the negative electrode sheet; the electrolyte is impregnated with the battery core; and the package body houses the battery core and the electrolyte. The electrochemical energy storage device also includes an adhesive layer. The adhesive layer is located between the battery core and the package shell and fixes the battery core and the package shell; the adhesive layer is flow dynamic before curing and the adhesion between the adhesive shell and the package shell is less than or equal to 0.1 N/mm, and the adhesive After the adhesive layer is cured, the cell and the package are fixedly connected.
在本发明的第二方面，本发明提供了一种制备电化学储能装置的方法， 用于制备本发明第一方面的电化学储能装置，包括步骤：将正极片、负极片以及间隔于正极片、负极片之间的隔离膜制成电芯；在电芯和包装壳之间设置胶黏剂层，胶黏剂层为流动态且胶黏剂层与包装壳之间粘结力小于等于0.1N/mm；将电芯装入包装壳、灌注电解液并封口，再对包装壳的外表面加热或加压实现胶黏剂层的固化以将电芯和包装壳固定连接。In a second aspect of the invention, the invention provides a method of preparing an electrochemical energy storage device, The electrochemical energy storage device for preparing the first aspect of the invention comprises the steps of: forming a positive electrode sheet, a negative electrode sheet, and a separator separated between the positive electrode sheet and the negative electrode sheet into a battery core; between the battery core and the packaging shell The adhesive layer is set, the adhesive layer is flow dynamic and the adhesive force between the adhesive layer and the package shell is less than or equal to 0.1 N/mm; the battery core is filled into the package shell, the electrolyte is poured and sealed, and then the package is packaged. The outer surface of the shell is heated or pressurized to effect curing of the adhesive layer to securely attach the cell to the package.
相对于现有技术，本发明的有益效果为：Compared with the prior art, the beneficial effects of the present invention are:
1.本发明的制备电化学储能装置的方法工艺简单、操作易于实现，可适应不同温湿度环境且作用条件要求较低。1. The method for preparing an electrochemical energy storage device of the invention is simple in process, easy to implement, and can be adapted to different temperature and humidity environments and has low requirements for action conditions.
2.在本发明的电化学储能装置中，在胶黏剂层固化前可以在电化学储能装置内重新排布，有利于提高电化学储能装置的外观平整度和能量密度。2. In the electrochemical energy storage device of the present invention, the adhesive layer can be rearranged in the electrochemical energy storage device before curing, which is beneficial to improve the appearance flatness and energy density of the electrochemical energy storage device.
3.在本发明的电化学储能装置中，胶黏剂层与电芯和包装壳之间的界面更好，不会出现胶黏剂层起皱、电芯表面起皱等界面粘接问题。3. In the electrochemical energy storage device of the invention, the interface between the adhesive layer and the electric core and the packaging shell is better, and the interface bonding problem such as wrinkling of the adhesive layer and wrinkling of the surface of the electric core does not occur. .
4.在本发明的电化学储能装置中，胶黏剂层与电芯和包装壳之间的粘结力更均匀，可避免跌落、挤压、滚动测试过程中撕裂电芯的表面。4. In the electrochemical energy storage device of the present invention, the adhesion between the adhesive layer and the cell and the package is more uniform, and the surface of the cell is torn during the fall, extrusion, and rolling test.
5.在本发明的电化学储能装置中，胶黏剂层的可流动性可以将异型电芯的多面交界处或交接点粘住，有效解决交界处边缘起翘问题。5. In the electrochemical energy storage device of the present invention, the flowability of the adhesive layer can stick the multi-face junction or the junction of the shaped cell, effectively solving the problem of edge picking at the junction.
附图说明DRAWINGS
图1是根据本发明一实施例的电化学储能装置的局部剖开的立体图；1 is a partially cutaway perspective view of an electrochemical energy storage device in accordance with an embodiment of the present invention;
图2是根据本发明另一实施例的电化学储能装置的局部剖开的立体图；2 is a partially cutaway perspective view of an electrochemical energy storage device in accordance with another embodiment of the present invention;
图3是由图1的A-A线作出的以截面夸张示意的根据本发明的电化学储能装置的一实施例的结构示意图。3 is a schematic view showing the structure of an electrochemical energy storage device according to the present invention, which is schematically exaggerated in section, taken along line A-A of FIG. 1.
其中，附图标记说明如下：Among them, the reference numerals are as follows:
1电芯1 battery
11收尾处11 finishing
2包装壳2 package shell
3胶黏剂层3 adhesive layer
31子层31 sublayer
32子层 32 sublayer
具体实施方式detailed description
下面说明根据本发明的电化学储能装置及制备电化学储能装置的方法以及实施例、对比例及测试过程以及测试结果。The electrochemical energy storage device and method and apparatus for preparing the electrochemical energy storage device according to the present invention, comparative examples, test procedures, and test results are described below.
首先说明根据本发明第一方面的电化学储能装置。First, an electrochemical energy storage device according to a first aspect of the invention will be described.
参照图1和图2，根据本发明第一方面的电化学储能装置包括：电芯1、电解液以及包装壳2。电芯1包括正极片、负极片以及间隔于正极片、负极片之间的隔离膜；电解液浸渍电芯1；包装壳2容纳电芯1及电解液。所述电化学储能装置还包括胶黏剂层3。胶黏剂层3位于电芯1和包装壳2之间并将电芯1和包装壳2固定连接。胶黏剂层3在固化前为流动态且与包装壳2之间的粘结力小于等于0.1N/mm，胶黏剂层3固化后将电芯1和包装壳2固定连接。1 and 2, an electrochemical energy storage device according to a first aspect of the present invention includes: a cell 1, an electrolyte, and a package 2. The battery cell 1 includes a positive electrode sheet, a negative electrode sheet, and a separator interposed between the positive electrode sheet and the negative electrode sheet; the electrolyte is impregnated with the battery core 1; and the package body 2 houses the battery core 1 and the electrolyte. The electrochemical energy storage device also includes an adhesive layer 3. The adhesive layer 3 is located between the battery core 1 and the package casing 2 and fixedly connects the battery core 1 and the package casing 2. The adhesive layer 3 is flowable before curing and has a bonding force with the package 2 of 0.1 N/mm or less. After the adhesive layer 3 is cured, the cell 1 and the package 2 are fixedly connected.
在根据本发明第一方面所述的电化学储能装置中，由于胶黏剂层3为流动态，因此在胶黏剂层3固化前可以在电化学储能装置内重新排布，有利于提高电化学储能装置的外观平整度；由于胶黏剂层3为流动态，胶黏剂会流向电化学储能装置整体厚度较小的位置，涂胶位置最后只留下微量胶黏剂，从而可以不增加电化学储能装置的整体厚度，相对于粘贴同等胶量的胶纸，电化学储能装置的整体厚度减小，有助于提高电化学储能装置的能量密度；胶黏剂层3的流动可使得其与电芯1和包装壳2之间的界面更好，不会出现胶黏剂层3起皱、电芯1表面起皱等界面粘接问题，且胶黏剂层3与电芯1和包装壳2之间的粘结力更均匀，可避免跌落、挤压、滚动测试过程中撕裂电芯1的表面；胶黏剂层3的流动特性尤其适用于异型电池中，可以将异型电芯的多面交界处或交接点粘住，解决交界处边缘起翘问题。In the electrochemical energy storage device according to the first aspect of the present invention, since the adhesive layer 3 is flow dynamic, it can be rearranged in the electrochemical energy storage device before the adhesive layer 3 is cured, which is advantageous. Improve the appearance flatness of the electrochemical energy storage device; since the adhesive layer 3 is flow dynamic, the adhesive will flow to a position where the overall thickness of the electrochemical energy storage device is small, and only a trace amount of adhesive is left at the glue application position. Therefore, the overall thickness of the electrochemical energy storage device can be increased without increasing the overall thickness of the electrochemical energy storage device, and the overall thickness of the electrochemical energy storage device is reduced, which helps to increase the energy density of the electrochemical energy storage device; the adhesive The flow of the layer 3 makes it better to interface with the cell 1 and the package 2 without interfacial adhesion problems such as wrinkling of the adhesive layer 3, wrinkling of the surface of the cell 1, and an adhesive layer. 3 The bonding force between the battery core 1 and the packaging shell 2 is more uniform, and the surface of the battery core 1 is torn during the fall, extrusion and rolling test; the flow characteristics of the adhesive layer 3 are particularly suitable for the special-shaped battery. In the case, the multi-face junction or junction of the shaped cell can be stuck To solve the problem of the edge of the junction.
在根据本发明第一方面所述的电化学储能装置中，胶黏剂层3在固化前与包装壳2之间的粘结力小于等于0.1N/mm，方便入壳。当胶黏剂层3与包装壳2之间的粘结力大于0.1N/mm，在入壳时容易造成胶黏剂层3与包装壳2直接粘结，无法使胶黏剂层3在电化学储能装置内重新排布，进而电化学储能装置的外观平整度得不到保证。In the electrochemical energy storage device according to the first aspect of the present invention, the adhesive layer 3 has a bonding force with the package shell 2 of 0.1 N/mm or less before curing, and is convenient for entering the shell. When the adhesive force between the adhesive layer 3 and the packaging shell 2 is greater than 0.1 N/mm, the adhesive layer 3 and the packaging shell 2 are directly bonded when the shell is inserted, and the adhesive layer 3 cannot be electrically charged. The chemical energy storage device is rearranged, and the appearance flatness of the electrochemical energy storage device is not guaranteed.
在根据本发明第一方面所述的电化学储能装置中，胶黏剂层3在固化前的粘度可小于等于10万mp.s，以保证胶黏剂层3为流动态。 In the electrochemical energy storage device according to the first aspect of the present invention, the viscosity of the adhesive layer 3 before curing can be less than or equal to 100,000 mp.s to ensure that the adhesive layer 3 is flow dynamic.
在根据本发明第一方面所述的电化学储能装置中，胶黏剂层3的材料可选自常温下无初粘性的压敏型胶黏剂、常温下无初粘性的热敏型胶黏剂以及反应型胶黏剂中的一种或几种。所述常温下无初粘性的压敏型胶黏剂可选自苯乙烯-乙烯-丁二烯-苯乙烯嵌段共聚物(SEBS)、苯乙烯-丁二烯嵌段共聚物(SEPS)以及环氧化苯乙烯-异戊二烯-苯乙烯嵌段共聚物(ESIS)中的一种或几种。所述常温下无初粘性的热敏型胶黏剂可选自聚烯烃、聚乙烯醇缩丁醛(PVB)、聚酰胺(PA)以及聚酯(PES)中的一种或几种。所述聚烯烃的单体可选自乙烯、丙烯、异戊二烯、醋酸乙烯、丁烯、丙烯酸、丙烯酸酯、丁二烯以及苯乙烯中的一种或几种。具体地，所述聚烯烃可选自聚乙烯(PE)、聚丙烯(PP)、聚异戊二烯(PI)、聚苯乙烯(PS)、乙烯-醋酸乙烯共聚物(EVA)、乙烯-丙烯酸乙酯共聚物(EEA)、乙烯-丙烯酸共聚物(EAA)、苯乙烯-异戊二烯-苯乙烯共聚物(SIS)以及苯乙烯-丁二烯-苯乙烯嵌段共聚物(SBS)中的一种或几种。所述反应型胶黏剂可选自环氧树脂、酚醛树脂以及脲醛树脂中的一种或几种。In the electrochemical energy storage device according to the first aspect of the present invention, the material of the adhesive layer 3 may be selected from a pressure-sensitive adhesive having no initial viscosity at normal temperature, and a heat-sensitive adhesive having no initial viscosity at normal temperature. One or more of an adhesive and a reactive adhesive. The pressure-sensitive adhesive having no initial tack at normal temperature may be selected from the group consisting of styrene-ethylene-butadiene-styrene block copolymer (SEBS), styrene-butadiene block copolymer (SEPS), and One or more of epoxidized styrene-isoprene-styrene block copolymers (ESIS). The heat-sensitive adhesive having no initial tack at normal temperature may be selected from one or more of polyolefin, polyvinyl butyral (PVB), polyamide (PA), and polyester (PES). The monomer of the polyolefin may be selected from one or more of ethylene, propylene, isoprene, vinyl acetate, butene, acrylic acid, acrylate, butadiene, and styrene. Specifically, the polyolefin may be selected from the group consisting of polyethylene (PE), polypropylene (PP), polyisoprene (PI), polystyrene (PS), ethylene-vinyl acetate copolymer (EVA), ethylene- Ethyl acrylate copolymer (EEA), ethylene-acrylic acid copolymer (EAA), styrene-isoprene-styrene copolymer (SIS), and styrene-butadiene-styrene block copolymer (SBS) One or several of them. The reactive adhesive may be selected from one or more of an epoxy resin, a phenol resin, and a urea resin.
所述常温下无初粘性的压敏型胶黏剂是指在常温下，当物体和压敏型胶黏剂之间在指压下发生短暂接触时，不会对物体产生粘结作用的压敏型胶黏剂。热敏型胶黏剂在本申请中是指加热后可以熔融，待冷却后即可粘结固化的一类胶。所述常温下无初粘性的热敏型胶黏剂是指在常温下，当物体和热敏型胶黏剂之间发生短暂接触时，不会对物体产生粘结作用的热敏型胶黏剂。所述反应型胶黏剂是指胶层初始状态无粘结性，在遇热、有机溶剂或酸性条件下，胶层组分之间或与接触的环境物质之间发生化学反应从而产生粘结性的胶黏剂。The pressure-sensitive adhesive having no initial tack at normal temperature refers to a pressure which does not cause adhesion to an object when a short-term contact occurs between the object and the pressure-sensitive adhesive under normal pressure at a normal temperature. Sensitive adhesive. In the present application, the heat-sensitive adhesive refers to a type of glue which can be melted after heating and can be bonded and solidified after being cooled. The heat-sensitive adhesive having no initial tack at normal temperature refers to a heat-sensitive adhesive which does not cause adhesion to an object when a short-term contact occurs between the object and the heat-sensitive adhesive at normal temperature. Agent. The reactive adhesive refers to a non-adhesive property of the adhesive layer in an initial state, and a chemical reaction occurs between the components of the adhesive layer or the environmental substance in contact under heat, organic solvent or acidic conditions to cause cohesiveness. Adhesive.
在根据本发明第一方面所述的电化学储能装置中，胶黏剂层3可为单层结构。In the electrochemical energy storage device according to the first aspect of the invention, the adhesive layer 3 may have a single layer structure.
参照图3，在根据本发明第一方面所述的电化学储能装置中，胶黏剂层3可为N层结构，N为大于等于2的整数。靠近电芯1的外表面的胶黏剂层3的子层31的材料可选自常温下无初粘性的压敏型胶黏剂或常温下无初粘性的热敏型胶黏剂，方便在电芯1的外表面常温施胶和后续通过对包装壳2的外表面进行加热或加压而实现与电芯1的外表面的快速粘接。靠近包装壳2的内表面的胶黏剂层3的子层32的材料可选自常温下无初粘性的热敏型胶 黏剂或反应型胶黏剂，即便在施胶工艺过程中有施压也不会使该子层32产生粘接性，方便入壳。其余的胶黏剂层3的子层的材料不受限制，优选可选自常温下无初粘性的压敏型胶黏剂、常温下无初粘性的热敏型胶黏剂以及反应型胶黏剂中的一种或几种，以起到增强粘接的作用。Referring to FIG. 3, in the electrochemical energy storage device according to the first aspect of the present invention, the adhesive layer 3 may have an N-layer structure, and N is an integer of 2 or more. The material of the sub-layer 31 of the adhesive layer 3 near the outer surface of the cell 1 may be selected from a pressure-sensitive adhesive having no initial tack at normal temperature or a heat-sensitive adhesive having no initial tack at normal temperature. The outer surface of the battery cell 1 is tempered at room temperature and subsequently heated or pressurized to the outer surface of the package casing 2 to achieve rapid bonding with the outer surface of the battery core 1. The material of the sub-layer 32 of the adhesive layer 3 near the inner surface of the package can be selected from a thermosensitive adhesive having no initial tack at normal temperature. The adhesive or reactive adhesive does not cause adhesion of the sub-layer 32 even when pressed during the sizing process, and is convenient for entering the shell. The material of the sub-layer of the remaining adhesive layer 3 is not limited, and may preferably be selected from a pressure-sensitive adhesive having no initial tack at normal temperature, a heat-sensitive adhesive having no initial tack at normal temperature, and a reactive adhesive. One or more of the agents to enhance adhesion.
在根据本发明第一方面所述的电化学储能装置中，优选地，所述常温下无初粘性的压敏型胶黏剂可选自苯乙烯-乙烯-丁二烯-苯乙烯嵌段共聚物(SEBS)。所述常温下无初粘性的热敏型胶黏剂可选自苯乙烯-异戊二烯-苯乙烯嵌段共聚物(SIS)、聚苯乙烯(PS)或聚异戊二烯(PI)。所述反应型胶黏剂可选自环氧树脂。In the electrochemical energy storage device according to the first aspect of the present invention, preferably, the pressure-sensitive adhesive having no initial tack at normal temperature may be selected from the group consisting of styrene-ethylene-butadiene-styrene blocks. Copolymer (SEBS). The heat-sensitive adhesive having no initial tack at normal temperature may be selected from the group consisting of styrene-isoprene-styrene block copolymer (SIS), polystyrene (PS) or polyisoprene (PI). . The reactive adhesive may be selected from epoxy resins.
在根据本发明第一方面所述的电化学储能装置中，胶黏剂层3中还可包括电解液添加剂。电解液添加剂可选自硫酸亚乙酯、硫酸丙烯酯、联苯、碳酸乙烯酯、碳酸亚乙烯酯、氟代碳酸乙烯酯、丙磺酸内酯以及己二腈中的一种或几种，不仅可以促进电解液的浸润，而且在循环过程中电解液添加剂还可以逐步从胶黏剂层3中释放到电解液中以改善电化学储能装置的电化学性能。In the electrochemical energy storage device according to the first aspect of the invention, an electrolyte additive may also be included in the adhesive layer 3. The electrolyte additive may be selected from one or more of ethylene sulfate, propylene sulfate, biphenyl, ethylene carbonate, vinylene carbonate, fluoroethylene carbonate, propane sultone, and adiponitrile. Not only can the electrolyte be infiltrated, but also the electrolyte additive can be gradually released from the adhesive layer 3 into the electrolyte during the cycle to improve the electrochemical performance of the electrochemical energy storage device.
在根据本发明第一方面所述的电化学储能装置中，胶黏剂层3面向电芯1的外表的表面积可不大于电芯1的外表面的表面积，胶黏剂层3面向包装壳2的内表面的表面积可不大于电芯1的外表面的表面积。In the electrochemical energy storage device according to the first aspect of the present invention, the surface area of the adhesive layer 3 facing the outer surface of the battery core 1 may not be larger than the surface area of the outer surface of the battery core 1, and the adhesive layer 3 faces the package casing 2 The surface area of the inner surface may be no greater than the surface area of the outer surface of the cell 1.
在根据本发明第一方面所述的电化学储能装置中，胶黏剂层3的最厚位置处的厚度可不大于电芯1的最厚位置与最薄位置的厚度差，以便于利用胶黏剂层3的流动特性提高电化学储能装置的外观平整度。In the electrochemical energy storage device according to the first aspect of the present invention, the thickness at the thickest position of the adhesive layer 3 may not be greater than the thickness difference between the thickest position and the thinnest position of the battery core 1 in order to utilize the glue The flow characteristics of the adhesive layer 3 enhance the appearance flatness of the electrochemical energy storage device.
在根据本发明第一方面所述的电化学储能装置中，胶黏剂层3可设置于电芯1和包装壳2之间的任何位置。例如，胶黏剂层3可设置于电芯1的长度、宽度、高度方向的表面、极耳区域、隔离膜超出正负极片的区域中的一个或几个位置上。In the electrochemical energy storage device according to the first aspect of the present invention, the adhesive layer 3 may be disposed at any position between the battery cell 1 and the package can 2. For example, the adhesive layer 3 may be disposed at one or several positions in the length, width, height direction surface of the battery cell 1, the tab area, and the region of the separator beyond the positive and negative electrode sheets.
在根据本发明第一方面所述的电化学储能装置中，胶黏剂层3的厚度可为2μm～100μm。In the electrochemical energy storage device according to the first aspect of the invention, the thickness of the adhesive layer 3 may be from 2 μm to 100 μm.
在根据本发明第一方面所述的电化学储能装置中，电化学储能装置可选自锂离子二次电池、超级电容器、燃料电池以及太阳能电池中的一种。In the electrochemical energy storage device according to the first aspect of the present invention, the electrochemical energy storage device may be selected from one of a lithium ion secondary battery, a super capacitor, a fuel cell, and a solar cell.
在根据本发明第一方面所述的电化学储能装置中，电芯1可为卷绕式电 芯、叠片式电芯或叠加卷式电芯。In the electrochemical energy storage device according to the first aspect of the present invention, the battery cell 1 may be a coiled type battery Core, laminated battery or stacked roll cells.
在根据本发明第一方面所述的电化学储能装置中，电芯1还可为异型电芯。In the electrochemical energy storage device according to the first aspect of the invention, the battery cell 1 can also be a profiled cell.
在根据本发明第一方面所述的电化学储能装置中，包装壳2可为软包装壳或硬包装壳。包装壳2可选自铝塑膜、钢塑膜、铝合金壳或镁合金壳。In the electrochemical energy storage device according to the first aspect of the invention, the package casing 2 may be a flexible package or a hard package. The package 2 may be selected from an aluminum plastic film, a steel plastic film, an aluminum alloy case or a magnesium alloy case.
其次说明根据本方面第二方面的制备电化学储能装置的方法。Next, a method of preparing an electrochemical energy storage device according to the second aspect of the present aspect will be described.
根据本方面第二方面的制备电化学储能装置的方法，用于制备本发明第一方面的电化学储能装置，包括步骤：步骤1：将正极片、负极片以及间隔于正极片、负极片之间的隔离膜制成电芯1；步骤2：在电芯1和包装壳2之间设置胶黏剂层3，胶黏剂层3为流动态且胶黏剂层3与包装壳2之间的粘结力小于等于0.1N/mm；步骤3：将电芯1装入包装壳2、灌注电解液并封口，再对包装壳2的外表面加热或加压实现胶黏剂层3的固化以将电芯1和包装壳2固定连接。The method for preparing an electrochemical energy storage device according to the second aspect of the present invention, for preparing the electrochemical energy storage device of the first aspect of the invention, comprising the steps of: Step 1: separating the positive electrode sheet, the negative electrode sheet, and the positive electrode sheet and the negative electrode The separator between the sheets is made into the cell 1; Step 2: an adhesive layer 3 is disposed between the cell 1 and the package 2, the adhesive layer 3 is flow dynamic and the adhesive layer 3 and the package 2 The bonding force between the two is less than or equal to 0.1 N/mm; Step 3: loading the battery core 1 into the packaging shell 2, injecting the electrolyte and sealing, and then heating or pressurizing the outer surface of the packaging shell 2 to realize the adhesive layer 3 The curing is to securely connect the battery cell 1 and the package case 2.
对包装壳2的外表面加热或加压除了使胶黏剂层3固化以将电芯1和包装壳2固定连接，还可以使胶黏剂层3在电芯1和包装壳2之间粘接界面上重新排布，即使胶黏剂层3向电化学储能装置整体厚度较小的位置流动，使界面平整，进而提高电化学储能装置的能量密度。Heating or pressurizing the outer surface of the package 2 In addition to curing the adhesive layer 3 to securely connect the cell 1 and the package 2, the adhesive layer 3 can be adhered between the cell 1 and the package 2 The interface is rearranged, even if the adhesive layer 3 flows to a position where the overall thickness of the electrochemical energy storage device is small, so that the interface is flat, thereby increasing the energy density of the electrochemical energy storage device.
在根据本发明第二方面所述的制备电化学储能装置的方法中，在步骤2中，可通过涂覆或点胶的方式将胶黏剂层3设置在电芯1的外表面或包装壳2的内表面上。其中涂覆方式单位时间施胶面积较大，对于表面积较大的电芯1，有利于提高产能；点胶的方式动作更灵活，对施胶位置无选择性，尤其适合用于异型电池中，可以将异型电芯的多面交界处或交接点粘住，解决交界处边缘起翘问题。In the method of preparing an electrochemical energy storage device according to the second aspect of the present invention, in step 2, the adhesive layer 3 may be disposed on the outer surface or package of the battery cell 1 by coating or dispensing. On the inner surface of the shell 2. The coating method has a larger sizing area per unit time, and is advantageous for increasing the productivity of the battery core 1 having a larger surface area; the dispensing method is more flexible, and has no selectivity for the sizing position, and is particularly suitable for use in a shaped battery. The multi-face junction or junction of the shaped cell can be stuck to solve the problem of edge lifting at the junction.
在根据本发明第二方面所述的制备电化学储能装置的方法中，在步骤2中，设置胶黏剂层3时的温度可为10℃～200℃、相对湿度(RH)可为10％～80％。In the method for preparing an electrochemical energy storage device according to the second aspect of the present invention, in step 2, the temperature at which the adhesive layer 3 is disposed may be 10 ° C to 200 ° C, and the relative humidity (RH) may be 10 %~80%.
在根据本发明第二方面所述的制备电化学储能装置的方法中，在步骤3中，加热固化时的温度可为45℃～90℃，加压固化时的压力可为0.2MPa～2MPa。 In the method for preparing an electrochemical energy storage device according to the second aspect of the present invention, in step 3, the temperature at the time of heat curing may be 45 ° C to 90 ° C, and the pressure at the time of pressure curing may be 0.2 MPa to 2 MPa. .
接下来说明根据本发明的电化学储能装置及制备电化学储能装置的方法的实施例和对比例。Next, examples and comparative examples of the electrochemical energy storage device and the method of preparing the electrochemical energy storage device according to the present invention will be described.
实施例1Example 1
1.正极片的制备1. Preparation of positive electrode sheet
将LiCoO2、导电碳、聚偏氟乙烯按重量比95:1:4分散到N-甲基吡咯烷酮中制成正极浆料，然后经涂布压实成厚度为102μm的正极片。LiCoO 2 , conductive carbon, and polyvinylidene fluoride were dispersed in N-methylpyrrolidone in a weight ratio of 95:1:4 to prepare a positive electrode slurry, which was then compacted into a positive electrode sheet having a thickness of 102 μm.
2.负极片的制备2. Preparation of negative electrode sheet
将石墨、导电碳、羧甲基纤维素钠、丁苯橡胶按重量比96:1:2:1分散在去离子水中制成负极浆料，然后经涂布压实制成厚度为90μm的负极片。Graphite, conductive carbon, sodium carboxymethylcellulose, styrene-butadiene rubber were dispersed in deionized water at a weight ratio of 96:1:2:1 to prepare a negative electrode slurry, which was then compacted by coating to form a negative electrode having a thickness of 90 μm. sheet.
3.电解液的制备3. Preparation of electrolyte
将碳酸乙烯酯(EC)、碳酸丙烯酯(PC)、碳酸二乙酯(DEC)、碳酸甲乙酯(EMC)按重量比20:20:45:15配制成非水有机溶剂，之后加入1.5mol/L的LiPF6作为锂盐，完成电解液的制备。Ethylene carbonate (EC), propylene carbonate (PC), diethyl carbonate (DEC), and ethyl methyl carbonate (EMC) are formulated into a non-aqueous organic solvent at a weight ratio of 20:20:45:15, and then added to 1.5. The preparation of the electrolyte is completed by mol/L of LiPF 6 as a lithium salt.
4.电芯的制备4. Preparation of the battery core
将制备的正极片、PE隔离膜以及负极片依次卷绕制备成厚度为4.0mm、宽度为52mm、长度为60mm的卷绕式电芯。The prepared positive electrode sheet, PE separator, and negative electrode sheet were sequentially wound to prepare a wound cell having a thickness of 4.0 mm, a width of 52 mm, and a length of 60 mm.
5.锂离子二次电池的制备5. Preparation of lithium ion secondary battery
在25℃，RH为20％的条件下，将由苯乙烯-异戊二烯-苯乙烯1:1:1嵌段共聚物制备的、粘度接近10万mp.s的胶黏剂涂覆在卷绕式电芯的外表面的除极耳外的其它位置上，胶黏剂层的厚度为50μm，胶黏剂层与包装壳铝塑膜之间的粘结力为0.05N/mm，之后将电芯装入包装壳，灌注电解液并封口，再对包装壳的外表面加热至75℃使胶黏剂层固化以将电芯和包装壳固定连接，之后经过化成、抽气成型，完成锂离子二次电池的制备。An adhesive having a viscosity of nearly 100,000 mp.s prepared from a styrene-isoprene-styrene 1:1:1 block copolymer was coated on a roll at 25 ° C and an RH of 20%. At a position other than the tab of the outer surface of the wound cell, the thickness of the adhesive layer is 50 μm, and the adhesion between the adhesive layer and the aluminum film of the package is 0.05 N/mm, after which The battery core is filled into the packaging shell, the electrolyte is poured and sealed, and then the outer surface of the packaging shell is heated to 75 ° C to cure the adhesive layer to fix the battery core and the packaging shell, and then formed into a gas and formed into a lithium. Preparation of an ion secondary battery.
实施例2Example 2
依照实施例1的方法制备锂离子二次电池，除以下不同:A lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
5.锂离子二次电池的制备5. Preparation of lithium ion secondary battery
在45℃，RH为60％的条件下，将由苯乙烯-乙烯-丁二烯-苯乙烯1:1:1:1共聚物制备的、粘度为6万mp.s的且与包装壳铝塑膜之间的粘结力小于 0.1N/mm的胶黏剂涂覆在电芯的沿卷绕方向的外表面及其垂直卷绕方向的电芯的尾部，胶黏剂层的厚度为50μm，之后将电芯装入包装壳，灌注电解液并封口，再对包装壳的外表面施加1MPa的面压使胶黏剂层固化以将电芯和包装壳固定连接，之后经过化成、抽气成型，完成锂离子二次电池的制备。The viscosity is 60,000 mp.s and the aluminum alloy is packaged with styrene-ethylene-butadiene-styrene 1:1:1:1 copolymer at 45 ° C and RH of 60%. The adhesion between the films is less than 0.1 N / mm of adhesive is applied to the outer surface of the cell in the winding direction and the tail of the cell in the vertical winding direction, the thickness of the adhesive layer is 50 μm, and then the cell is loaded into the package The electrolyte is filled and sealed, and then a surface pressure of 1 MPa is applied to the outer surface of the package to cure the adhesive layer to fix the battery core and the package, and then formed into a lithium ion secondary battery by chemical formation and evacuation molding. preparation.
实施例3Example 3
依照实施例1的方法制备锂离子二次电池，除以下不同:A lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
5.锂离子二次电池的制备5. Preparation of lithium ion secondary battery
在60℃，RH为80％的条件下，将由环氧树脂制备的、粘度为8万mp.s的且与包装壳铝塑膜之间的粘结力小于0.1N/mm的胶黏剂涂覆在电芯的卷绕方向的两侧面，胶黏剂层的厚度为50μm，之后将电芯装入包装壳，灌注电解液并封口，再对包装壳的外表面施加0.8MPa面压使胶黏剂层固化以将电芯和包装壳固定连接，之后经过化成、抽气成型，完成锂离子二次电池的制备。At 60 ° C, RH is 80%, the adhesive prepared by epoxy resin, viscosity 80,000 mp.s and the adhesion between the aluminum foil film and the packaging shell is less than 0.1N / mm Covering the two sides of the winding direction of the battery core, the thickness of the adhesive layer is 50 μm, then the battery core is placed in the packaging shell, the electrolyte is poured and sealed, and a surface pressure of 0.8 MPa is applied to the outer surface of the packaging shell to make the glue The adhesive layer is cured to fix the battery core and the package shell, and then is formed into a lithium ion secondary battery by chemical formation and evacuation molding.
实施例4Example 4
依照实施例1的方法制备锂离子二次电池，除以下不同:A lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
5.锂离子二次电池的制备5. Preparation of lithium ion secondary battery
在卷绕式电芯的卷绕收尾处粘接一条8mm宽、60mm长的丙烯酸树脂单面胶带后，再在200℃，RH为50％的条件下，将由聚丙烯制备的、粘度为5万mp.s的且与包装壳铝塑膜之间的粘结力小于0.1N/mm的胶黏剂涂覆在电芯沿卷绕方向的表面以及垂直卷绕方向的头部和尾部，胶黏剂层的厚度为30μm，之后将电芯装入包装壳，灌注电解液并封口，再对外包装的外表面加热至60℃并施加0.5MPa面压使胶黏剂层固化以将电芯和包装壳固定连接，之后经过化成、抽气成型，完成锂离子二次电池的制备。After bonding a single 8 mm wide and 60 mm long acrylic tape to the winding end of the wound cell, the viscosity of the polypropylene is 50,000 at 200 ° C and RH 50%. The adhesive of mp.s and the aluminum-plastic film of the package is less than 0.1N/mm, and the adhesive is applied to the surface of the battery in the winding direction and the head and tail of the vertical winding direction, and the adhesive is adhesive. The thickness of the agent layer is 30 μm, after which the battery core is filled into the package shell, the electrolyte is poured and sealed, and the outer surface of the outer package is heated to 60 ° C and a surface pressure of 0.5 MPa is applied to cure the adhesive layer to laminate the battery and the package. The shell is fixedly connected, and then subjected to chemical formation and evacuation molding to complete the preparation of the lithium ion secondary battery.
实施例5Example 5
依照实施例1的方法制备锂离子二次电池，除以下不同:A lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
5.锂离子二次电池的制备5. Preparation of lithium ion secondary battery
在180℃，RH为80％的条件下，将由聚苯乙烯制备的、粘度为6万mp.s 的且与包装壳铝塑膜之间的粘结力小于0.1N/mm的胶黏剂涂覆在电芯的与卷绕方向垂直的上下两面，胶黏剂层的厚度为50μm，之后将电芯装入包装壳，灌注电解液并封口，再对外包装的外表面加热至75℃使胶黏剂层固化以将电芯和包装壳固定连接，之后经过化成、抽气成型，完成锂离子二次电池的制备。The viscosity is 60,000 mp.s, prepared from polystyrene at 180 ° C and 80% RH. The adhesive agent having a bonding force of less than 0.1 N/mm with the aluminum foil of the package is coated on the upper and lower sides of the battery core perpendicular to the winding direction, and the thickness of the adhesive layer is 50 μm, and then the electricity is charged. The core is filled into the package shell, the electrolyte is poured and sealed, and the outer surface of the outer package is heated to 75 ° C to cure the adhesive layer to fix the battery core and the package shell, and then formed into a lithium ion by chemical formation and evacuation molding. Preparation of secondary batteries.
实施例6Example 6
依照实施例1的方法制备锂离子二次电池，除以下不同:A lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
4.电芯的制备4. Preparation of the battery core
将正极片、隔离膜、负极片依次叠片制备成厚度为4.0mm、宽度为52mm、长度为60mm叠片式电芯。The positive electrode sheet, the separator, and the negative electrode sheet were laminated in this order to prepare a laminated battery core having a thickness of 4.0 mm, a width of 52 mm, and a length of 60 mm.
5.锂离子二次电池的制备5. Preparation of lithium ion secondary battery
在180℃，RH为60％的条件下，将由聚异丁烯制备的、粘度为8万mp.s的且与包装壳铝塑膜之间的粘结力小于0.1N/mm的胶黏剂涂覆在叠片式电芯的上下两面，胶黏剂层的厚度为50μm，之后将叠片式电芯装入包装壳，灌注电解液并封口，再对外包装的外表面加热至75℃使胶黏剂层固化以将电芯和包装壳固定连接，之后经过化成、抽气成型，完成锂离子二次电池的制备。Adhesive coated with polyisobutylene at a viscosity of 80,000 mp.s and a bond strength of less than 0.1 N/mm to the aluminum foil film of the package at 180 ° C and RH of 60% On the upper and lower sides of the laminated battery core, the thickness of the adhesive layer is 50 μm, and then the laminated battery cell is placed in the packaging shell, the electrolyte is poured and sealed, and the outer surface of the outer packaging is heated to 75 ° C to make the adhesive. The agent layer is cured to fix the cell and the package shell, and then formed into a lithium ion secondary battery by chemical formation and evacuation molding.
实施例7Example 7
依照实施例1的方法制备锂离子二次电池，除以下不同:A lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
4.电芯的制备4. Preparation of the battery core
将正极片、隔离膜、负极片依次卷绕制备成多个不同大小的裸电芯后，再组合成台阶状异型电芯。The positive electrode sheet, the separator, and the negative electrode sheet are sequentially wound to prepare a plurality of bare cells of different sizes, and then combined into a stepped shaped core.
5.锂离子二次电池的制备5. Preparation of lithium ion secondary battery
在10℃，RH为60％的条件下，将由聚异丁烯制备的、粘度为10万mp.s的且与包装壳铝塑膜之间的粘结力小于0.1N/mm的胶黏剂点胶在异型电芯的表面，胶黏剂层的厚度为50μm，之后将异型电芯装入包装壳，灌注电解液并封口，再对外包装的外表面加热至75℃使胶黏剂层固化以将电芯和包装壳固定连接，之后经过化成、抽气成型，完成锂离子二次电池的制备。 Adhesive dispensing of polyisobutylene with a viscosity of 100,000 mp.s and adhesion to the aluminum-plastic film of the package of less than 0.1 N/mm at 10 ° C and RH of 60% On the surface of the shaped cell, the thickness of the adhesive layer is 50 μm. Then, the shaped cell is placed in the package, the electrolyte is poured and sealed, and the outer surface of the outer package is heated to 75 ° C to cure the adhesive layer. The battery core and the package shell are fixedly connected, and then formed into a lithium ion secondary battery by chemical formation and evacuation molding.
实施例8Example 8
依照实施例1的方法制备锂离子二次电池，除以下不同:A lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
5.锂离子二次电池的制备5. Preparation of lithium ion secondary battery
在60℃，RH为80％的条件下，将由苯乙烯-乙烯-丁二烯-苯乙烯1:1:1:1共聚物制备的、粘度为6万mp.s的且与包装壳铝塑膜之间的粘结力小于0.1N/mm的胶黏剂涂覆在卷绕式电芯的外表面的除极耳外的其它位置上，胶黏剂层的厚度为50μm，且胶黏剂层中还混合有质量百分含量为胶黏剂层总质量0.01％的电解液添加剂联苯，之后将卷绕式电芯装入包装壳，灌注电解液并封口，再对包装壳的外表面施加1MPa的面压使胶黏剂层固化以将电芯和包装壳固定连接，之后经过化成、抽气成型，完成锂离子二次电池的制备。The viscosity is 60,000 mp.s and the aluminum alloy is packaged with styrene-ethylene-butadiene-styrene 1:1:1:1 copolymer at 60 ° C and RH of 80%. The adhesive having a bonding force between the films of less than 0.1 N/mm is applied to the outer surface of the wound cell other than the tab, the thickness of the adhesive layer is 50 μm, and the adhesive The layer is further mixed with an electrolyte additive biphenyl having a mass percentage of 0.01% of the total mass of the adhesive layer, and then the wound cell is placed in the package, the electrolyte is poured and sealed, and then the outer surface of the package is applied. A surface pressure of 1 MPa was applied to cure the adhesive layer to fix the cell and the package, and then formed into a lithium ion secondary battery by chemical formation and evacuation molding.
对比例1Comparative example 1
依照实施例1的方法制备锂离子二次电池，除以下不同:A lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
5.锂离子二次电池的制备5. Preparation of lithium ion secondary battery
在卷绕式电芯的卷绕收尾处直接用一条5mm宽、60mm长的丙烯酸树脂单面胶带固定后装入包装壳铝塑膜、灌注电解液并封口，再对包装壳的外表面施加1MPa的面压以将电芯和包装壳固定连接，之后经过化成、抽气成型，完成锂离子二次电池的制备。At the winding end of the wound cell, it is directly fixed with a 5mm wide and 60mm long acrylic single-sided tape, then filled into the aluminum film of the package, filled with electrolyte and sealed, and then applied 1MPa to the outer surface of the package. The surface pressure is used to fix the battery core and the package body, and then the formation and the extraction of the lithium ion secondary battery are completed.
对比例2Comparative example 2
依照对比例1的方法制备锂离子二次电池，除以下不同:A lithium ion secondary battery was prepared according to the method of Comparative Example 1, except for the following differences:
5.锂离子二次电池的制备5. Preparation of lithium ion secondary battery
使用丙烯酸树脂双面胶带进行固定。Fix with acrylic double-sided tape.
对比例3Comparative example 3
依照实施例1的方法制备锂离子二次电池，除以下不同:A lithium ion secondary battery was prepared in accordance with the method of Example 1, except for the following:
5.锂离子二次电池的制备5. Preparation of lithium ion secondary battery
在卷绕式电芯的表面包覆中国专利申请公开号CN 102549801 A中的胶带，之后装入包装壳铝塑膜、灌注电解液并封口，再对包装壳的外表面施加1MPa的面压以将电芯和包装壳固定连接，之后经过化成、抽气成型，完成 锂离子二次电池的制备。The surface of the wound cell is coated with the tape of the Chinese Patent Application Publication No. CN 102549801 A, and then the aluminum film of the package is filled, the electrolyte is poured and sealed, and a surface pressure of 1 MPa is applied to the outer surface of the package. The battery core and the package shell are fixedly connected, and then formed into a gas and formed into a gas. Preparation of a lithium ion secondary battery.
对比例4Comparative example 4
依照实施例7的方法制备锂离子二次电池，除以下不同:A lithium ion secondary battery was prepared in accordance with the method of Example 7, except for the following:
5.锂离子二次电池的制备5. Preparation of lithium ion secondary battery
将中国专利申请公开号CN 102549801 A中的胶带粘接在异型电芯的外表面，待胶带表面的胶黏剂干燥后，装入包装壳铝塑膜，灌注电解液并封口，再对包装壳的外表面施加1MPa的面压以将电芯和包装壳固定连接，之后经过化成、抽气成型，完成锂离子二次电池的制备。The tape of the Chinese Patent Application Publication No. CN 102549801 A is bonded to the outer surface of the shaped core, and after the adhesive on the surface of the tape is dried, the aluminum plastic film of the package is filled, the electrolyte is poured and sealed, and then the package is sealed. The outer surface of the outer surface is applied with a surface pressure of 1 MPa to fix the battery core and the package casing, and then formed into a lithium ion secondary battery by chemical formation and evacuation molding.
接下来说明根据本发明的锂离子二次电池的测试过程以及测试结果。Next, the test procedure and test results of the lithium ion secondary battery according to the present invention will be explained.
1.锂离子二次电池的厚度测试1. Thickness test of lithium ion secondary battery
将锂离子二次电池主体放入厚度测试仪中，极耳露出，读取锂离子二次电池主体的厚度数值并记录，其中，锂离子二次电池主体的厚度数值为锂离子二次电池厚度最大位置(即极耳与电芯的重合区域)的厚度。The main body of the lithium ion secondary battery is placed in a thickness tester, the tabs are exposed, and the thickness value of the main body of the lithium ion secondary battery is read and recorded, wherein the thickness of the lithium ion secondary battery main body is the thickness of the lithium ion secondary battery. The thickness of the maximum position (ie, the coincident area of the tab and the cell).
2.锂离子二次电池的外观平整度检查2. Appearance flatness inspection of lithium ion secondary battery
将锂离子二次电池置于平整度仪(上海卓致力天仪器设备有限公司)中，测试锂离子二次电池表面的平整度。The lithium ion secondary battery was placed in a flatness meter (Shanghai Zhuo Li Li Tian Instrument Equipment Co., Ltd.) to test the flatness of the surface of the lithium ion secondary battery.
3.锂离子二次电池的粘接界面测试3. Bonding interface test of lithium ion secondary battery
将锂离子二次电池的包装壳拆开，观察包装壳与电芯的粘接界面有无胶黏剂层起皱或电芯外表面起皱导致的界面不良。The package of the lithium ion secondary battery was disassembled, and the interface between the package and the cell was observed to have a poor interface due to wrinkling of the adhesive layer or wrinkling of the outer surface of the cell.
4.锂离子二次电池的跌落测试4. Drop test of lithium ion secondary battery
将锂离子二次电池用双面胶固定在跌落测试夹具中，将夹具的6个面依次编号1、2、3、4、5、6，将夹具的四个角依次编号C1、C2、C3、C4。The lithium ion secondary battery is fixed in the drop test fixture with double-sided tape, and the six faces of the jig are sequentially numbered 1, 2, 3, 4, 5, and 6, and the four corners of the jig are sequentially numbered C1, C2, and C3. , C4.
在25℃下，将夹具置于1.5m高的测试台上，按照编号1-6的顺序依次跌落锂离子二次电池，然后再按照编号C1-C4的顺序依次跌落锂离子二次电池，循环6次，完成跌落测试，静置1h后，At 25 ° C, the fixture was placed on a 1.5 m high test bench, and the lithium ion secondary batteries were sequentially dropped in the order of number 1-6, and then the lithium ion secondary batteries were sequentially dropped in the order of number C1-C4, and the cycle was repeated. 6 times, complete the drop test, after standing for 1h,
(1)观察锂离子二次电池的包装壳是否破损或顶封冲开；(1) Observing whether the package of the lithium ion secondary battery is damaged or the top seal is opened;
(2)拆开锂离子二次电池观察电芯的极耳是否有断裂；(2) Disassemble the lithium ion secondary battery to see if the pole of the battery core is broken;
(3)拆开锂离子二次电池观察电芯的表面是否有撕裂； (3) Disassemble the lithium ion secondary battery and observe whether the surface of the battery core is torn;
(4)拆开锂离子二次电池观察电芯的宽度方向上的两侧隔离膜是否有移位或起皱；(4) Disassembling the lithium ion secondary battery to observe whether the separator on both sides in the width direction of the battery cell is displaced or wrinkled;
(5)拆开锂离子二次电池观察正极片与负极片是否有接触内短路；(5) Disassemble the lithium ion secondary battery and observe whether the positive electrode and the negative electrode have contact internal short circuit;
如无上述情况出现即判断为通过，计算锂离子二次电池跌落测试的通过率，每组测试10只锂离子二次电池。If it is determined that the above conditions are not passed, the pass rate of the lithium ion secondary battery drop test is calculated, and each group is tested with 10 lithium ion secondary batteries.
5.锂离子二次电池的循环性能测试5. Cyclic performance test of lithium ion secondary battery
将锂离子二次电池置于25℃的恒温箱中，以0.5C倍率恒流充电，截至电压为4.35V，然后以4.35V恒压充电，截至电流为0.025C，静置3min后，以0.5C恒流放电，截至电压3.0V，此为一个充放电循环过程，重复800次上述充放电过程，记录锂离子二次电池的初始厚度和循环后的厚度，判断锂离子二次电池是否有变形，每组测试10只锂离子二次电池。The lithium ion secondary battery was placed in an incubator at 25 ° C, and charged at a constant current of 0.5 C. The cut-off voltage was 4.35 V, and then charged at a constant voltage of 4.35 V. The off current was 0.025 C, and after standing for 3 min, 0.5. C constant current discharge, the cut-off voltage is 3.0V, this is a charge-discharge cycle process, repeating the above charging and discharging process 800 times, recording the initial thickness of the lithium ion secondary battery and the thickness after the cycle, and judging whether the lithium ion secondary battery is deformed Each group was tested with 10 lithium ion secondary batteries.
表1给出实施例1-8和对比例1-4的性能测试结果。Table 1 gives the performance test results of Examples 1-8 and Comparative Examples 1-4.
Figure PCTCN2015084099-appb-000001
Figure PCTCN2015084099-appb-000001
注：NA表示无法判定，实施例7和对比例4中使用异型电芯，因此无法判断外观平整度。Note: NA indicates that it is impossible to determine that the shaped cells were used in Example 7 and Comparative Example 4, and thus it was impossible to judge the appearance flatness.
由表1可知，本发明的锂离子二次电池可以改善跌落测试结果、不增加电池的厚度、长期循环后胶黏剂层可以阻止电池的变形、粘接界面良好、且电池外观平整。As can be seen from Table 1, the lithium ion secondary battery of the present invention can improve the drop test result without increasing the thickness of the battery, and the adhesive layer can prevent the deformation of the battery, the bonding interface is good, and the appearance of the battery is flat after long-term circulation.
从实施例5-6中可以看出，在电池本身体积较小或跌落测试要求不苛刻的情况下，在电池的部分表面涂覆本发明的胶黏剂层可以起到全部涂覆胶黏剂层的效果，并且节约材料和成本。It can be seen from Examples 5-6 that in the case where the battery itself is small in volume or the drop test requirement is not critical, coating the adhesive layer of the present invention on a part of the surface of the battery can serve as the entire adhesive. Layer effects and material and cost savings.
实施例7中使用异型电池，通过点胶的方式将胶黏剂层设置在电池表面，不仅异型位置施胶方便，而且胶黏剂层的流动性可将异型电芯的多面交界处或交接点粘住且还可以重整粘接界面使电池的粘结界面良好、电池表面平整且交界处边缘无起翘现象。In the embodiment 7, the special-shaped battery is used, and the adhesive layer is disposed on the surface of the battery by means of dispensing, which not only facilitates the sizing of the shaped position, but also the fluidity of the adhesive layer can be used for the multi-face junction or junction of the shaped battery. Sticking and also re-bonding the bonding interface makes the bonding interface of the battery good, the surface of the battery is flat and the edge of the junction is not warped.
从实施例8中可以看出，胶黏剂中混合少量联苯，在电池的使用过程中，初期电池的循环性能较好，对联苯的需求较少，随着电池使用时间推移，胶黏剂层中的联苯会逐渐释放到电解液中，起到防止电池过充析锂等问题，提高电池的循环寿命，同时可以避免加入大量电解液造成涨液问题。It can be seen from Example 8 that a small amount of biphenyl is mixed in the adhesive. During the use of the battery, the initial battery has better cycle performance, less demand for biphenyl, and the adhesive is used as the battery is used. The biphenyl in the layer will gradually be released into the electrolyte, which can prevent the battery from over-decomposing lithium and the like, improve the cycle life of the battery, and avoid the problem of liquid rising caused by adding a large amount of electrolyte.
对比例1和对比例2分别采用单面胶纸和双面胶纸，不仅由于粘接不均匀导致粘接强度下降，而且跌落过程中胶纸会撕裂电芯表面，导致后续跌落中粘接失效。Comparative Example 1 and Comparative Example 2 respectively used single-sided adhesive tape and double-sided adhesive tape, which not only caused the bonding strength to decrease due to uneven bonding, but also the adhesive tape would tear the surface of the battery during the falling process, resulting in bonding in subsequent dropping. Invalid.
对比例3和对比例4中使用的胶带同样不能改善粘接界面起皱和电芯表面撕裂的问题。尤其在对比例4中，所用的胶带无法将异型电芯多面交界处或交接点粘住，导致电芯多面交界处边缘起翘。 The tapes used in Comparative Example 3 and Comparative Example 4 also failed to improve the problem of wrinkling of the bonding interface and tearing of the surface of the core. Especially in Comparative Example 4, the tape used could not stick the multi-face junction or the junction of the shaped cell, resulting in the edge of the multi-face junction of the cell being warped.

Claims (22)

  1. 一种电化学储能装置，包括：An electrochemical energy storage device comprising:
    电芯(1)，包括正极片、负极片以及间隔于正极片、负极片之间的隔离膜；The battery core (1) comprises a positive electrode sheet, a negative electrode sheet and a separator interposed between the positive electrode sheet and the negative electrode sheet;
    电解液，浸渍电芯(1)；以及Electrolyte, impregnated cell (1);
    包装壳(2)，容纳电芯及电解液；a packaging shell (2) for accommodating a battery core and an electrolyte;
    其特征在于，It is characterized in that
    所述电化学储能装置还包括：The electrochemical energy storage device further includes:
    胶黏剂层(3)，位于电芯(1)和包装壳(2)之间并将电芯(1)和包装壳(2)固定连接；An adhesive layer (3) between the battery core (1) and the packaging shell (2) and fixedly connecting the battery core (1) and the packaging shell (2);
    胶黏剂层(3)在固化前为流动态且与包装壳(2)之间的粘结力小于等于0.1N/mm，胶黏剂层(3)固化后将电芯(1)和包装壳(2)固定连接。The adhesive layer (3) is flow dynamic before curing and the adhesion between the package shell (2) is less than or equal to 0.1 N/mm, and the adhesive layer (3) is cured after the battery (1) and packaging The shell (2) is fixedly connected.
  2. 根据权利要求1所述的电化学储能装置，其特征在于，胶黏剂层(3)在固化前的粘度小于等于10万mp.s。The electrochemical energy storage device according to claim 1, wherein the viscosity of the adhesive layer (3) before curing is less than or equal to 100,000 mp.s.
  3. 根据权利要求1所述的电化学储能装置，其特征在于，The electrochemical energy storage device of claim 1 wherein
    胶黏剂层(3)的材料选自常温下无初粘性的压敏型胶黏剂、常温下无初粘性的热敏型胶黏剂以及反应型胶黏剂中的一种或几种。The material of the adhesive layer (3) is selected from one or more of a pressure-sensitive adhesive having no initial tack at normal temperature, a heat-sensitive adhesive having no initial tack at normal temperature, and a reactive adhesive.
  4. 根据权利要求3所述的电化学储能装置，其特征在于，胶黏剂层(3)为单层结构。The electrochemical energy storage device according to claim 3, characterized in that the adhesive layer (3) has a single layer structure.
  5. 根据权利要求3所述的电化学储能装置，其特征在于，The electrochemical energy storage device according to claim 3, wherein
    胶黏剂层(3)为N层结构，N为大于等于2的整数；The adhesive layer (3) is an N-layer structure, and N is an integer greater than or equal to 2;
    靠近电芯(1)的外表面的胶黏剂层(3)的子层(31)的材料选自常温下无初粘性的压敏型胶黏剂或常温下无初粘性的热敏型胶黏剂；The material of the sub-layer (31) of the adhesive layer (3) near the outer surface of the cell (1) is selected from a pressure-sensitive adhesive having no initial tack at normal temperature or a thermosensitive adhesive having no initial tack at normal temperature. Adhesive
    靠近包装壳(2)的内表面的胶黏剂层(3)的子层(32)的材料选自常温下无初粘性的热敏型胶黏剂或反应型胶黏剂； The material of the sub-layer (32) of the adhesive layer (3) near the inner surface of the packaging shell (2) is selected from a heat-sensitive adhesive or a reactive adhesive having no initial tack at normal temperature;
    其余的胶黏剂层(3)的子层的材料选自常温下无初粘性的压敏型胶黏剂、常温下无初粘性的热敏型胶黏剂以及反应型胶黏剂中的一种或几种。The material of the sub-layer of the remaining adhesive layer (3) is selected from a pressure-sensitive adhesive having no initial tack at normal temperature, a heat-sensitive adhesive having no initial tack at normal temperature, and one of reactive adhesives. Kind or several.
  6. 根据权利要求3所述的电化学储能装置，其特征在于，The electrochemical energy storage device according to claim 3, wherein
    所述常温下无初粘性的压敏型胶黏剂选自苯乙烯-乙烯-丁二烯-苯乙烯嵌段共聚物、苯乙烯-丁二烯嵌段共聚物以及环氧化苯乙烯-异戊二烯-苯乙烯嵌段共聚物中的一种或几种；The pressure-sensitive adhesive having no initial tack at normal temperature is selected from the group consisting of styrene-ethylene-butadiene-styrene block copolymer, styrene-butadiene block copolymer, and epoxidized styrene-different One or more of the pentadiene-styrene block copolymers;
    所述常温下无初粘性的热敏型胶黏剂选自聚烯烃、聚乙烯醇缩丁醛、聚酰胺以及聚酯中的一种或几种；The heat-sensitive adhesive having no initial tack at normal temperature is selected from one or more of polyolefin, polyvinyl butyral, polyamide, and polyester;
    所述反应型胶黏剂选自环氧树脂、酚醛树脂以及脲醛树脂中的一种或几种。The reactive adhesive is selected from one or more of an epoxy resin, a phenol resin, and a urea resin.
  7. 根据权利要求6所述的电化学储能装置，其特征在于，The electrochemical energy storage device of claim 6 wherein:
    所述聚烯烃的单体选自乙烯、丙烯、异戊二烯、丁烯、醋酸乙烯、丙烯酸、丙烯酸酯、丁二烯以及苯乙烯中的一种或几种。The monomer of the polyolefin is selected from one or more of ethylene, propylene, isoprene, butene, vinyl acetate, acrylic acid, acrylate, butadiene, and styrene.
  8. 根据权利要求7所述的电化学储能装置，其特征在于，The electrochemical energy storage device according to claim 7, wherein
    所述聚烯烃选自聚乙烯、聚丙烯、聚异戊二烯、聚苯乙烯、乙烯-醋酸乙烯共聚物、乙烯-丙烯酸共聚物、乙烯-丙烯酸乙酯共聚物、苯乙烯-异戊二烯-苯乙烯共聚物以及苯乙烯-丁二烯-苯乙烯嵌段共聚物中的一种或几种。The polyolefin is selected from the group consisting of polyethylene, polypropylene, polyisoprene, polystyrene, ethylene-vinyl acetate copolymer, ethylene-acrylic acid copolymer, ethylene-ethyl acrylate copolymer, styrene-isoprene One or more of a styrene copolymer and a styrene-butadiene-styrene block copolymer.
  9. 根据权利要求1所述的电化学储能装置，其特征在于，胶黏剂层(3)中还包括电解液添加剂。The electrochemical energy storage device according to claim 1, characterized in that the adhesive layer (3) further comprises an electrolyte additive.
  10. 根据权利要求9所述的电化学储能装置，其特征在于，所述电解液添加剂选自硫酸亚乙酯、硫酸丙烯酯、联苯、碳酸乙烯酯、碳酸亚乙烯酯、氟代碳酸乙烯酯、丙磺酸内酯以及己二腈中的一种或几种。The electrochemical energy storage device according to claim 9, wherein the electrolyte additive is selected from the group consisting of ethylene sulfate, propylene sulfate, biphenyl, ethylene carbonate, vinylene carbonate, and fluoroethylene carbonate. One or more of propane sultone and adiponitrile.
  11. 根据权利要求1所述的电化学储能装置，其特征在于，胶黏剂层(3)与电芯(1)的外表面面向的表面的表面积不大于电芯(1)的外表面的表面 积，胶黏剂层(3)的与包装壳(2)的内表面面向的表面的表面积不大于电芯(1)的外表面的表面积。The electrochemical energy storage device according to claim 1, characterized in that the surface area of the surface of the adhesive layer (3) facing the outer surface of the battery core (1) is not larger than the surface of the outer surface of the battery core (1). The surface area of the surface of the adhesive layer (3) facing the inner surface of the package casing (2) is not larger than the surface area of the outer surface of the battery core (1).
  12. 根据权利要求1所述的电化学储能装置，其特征在于，胶黏剂层(3)的最厚位置处的厚度不大于电芯(1)的最厚位置与最薄位置的厚度差。The electrochemical energy storage device according to claim 1, characterized in that the thickness at the thickest position of the adhesive layer (3) is not greater than the thickness difference between the thickest position and the thinnest position of the battery core (1).
  13. 根据权利要求1所述的电化学储能装置，其特征在于，胶黏剂层(3)的厚度为2μm～100μm。The electrochemical energy storage device according to claim 1, characterized in that the thickness of the adhesive layer (3) is from 2 μm to 100 μm.
  14. 根据权利要求1所述的电化学储能装置，其特征在于，电化学储能装置选自锂离子二次电池、超级电容器、燃料电池以及太阳能电池中的一种。The electrochemical energy storage device according to claim 1, wherein the electrochemical energy storage device is one selected from the group consisting of a lithium ion secondary battery, a super capacitor, a fuel cell, and a solar cell.
  15. 根据权利要求1所述的电化学储能装置，其特征在于，电芯(1)为卷绕式电芯、叠片式电芯或叠加卷式电芯。The electrochemical energy storage device according to claim 1, characterized in that the battery cell (1) is a wound cell, a laminated cell or a stacked coil cell.
  16. 根据权利要求1所述的电化学储能装置，其特征在于，电芯(1)为异型电芯。The electrochemical energy storage device according to claim 1, characterized in that the battery cell (1) is a profiled cell.
  17. 根据权利要求1所述的电化学储能装置，其特征在于，包装壳(2)为软包装壳或硬包装壳。The electrochemical energy storage device according to claim 1, characterized in that the package casing (2) is a flexible package or a hard package.
  18. 根据权利要求1所述的电化学储能装置，其特征在于，包装壳(2)选自铝塑膜、不锈钢包装膜、铝合金壳、钢壳或镁合金壳。The electrochemical energy storage device according to claim 1, characterized in that the packaging shell (2) is selected from the group consisting of an aluminum plastic film, a stainless steel packaging film, an aluminum alloy shell, a steel shell or a magnesium alloy shell.
  19. 一种制备电化学储能装置的方法，用于制备权利要求1-18中任一项所述的电化学储能装置，包括步骤：A method of preparing an electrochemical energy storage device for preparing the electrochemical energy storage device according to any one of claims 1 to 18, comprising the steps of:
    步骤1：将正极片、负极片以及间隔于正极片、负极片之间的隔离膜制成电芯(1)；Step 1: the positive electrode sheet, the negative electrode sheet and the separator between the positive electrode sheet and the negative electrode sheet are made into a battery core (1);
    步骤2：在电芯(1)和包装壳(2)之间设置胶黏剂层(3)，胶黏剂层(3)为流动态且胶黏剂层(3)与包装壳(2)之间粘结力小于等于0.1N/mm； Step 2: Between the battery core (1) and the packaging shell (2), an adhesive layer (3) is provided, and the adhesive layer (3) is flow dynamic and the adhesive layer (3) and the packaging shell (2) The bonding force is less than or equal to 0.1 N/mm;
    步骤3：将电芯(1)装入包装壳(2)、灌注电解液并封口，再对包装壳(2)的外表面加热或加压实现胶黏剂层(3)的固化以将电芯(1)和包装壳(2)固定连接。Step 3: Put the battery core (1) into the packaging shell (2), inject the electrolyte and seal, and then heat or press the outer surface of the packaging shell (2) to cure the adhesive layer (3) to electrify The core (1) and the package (2) are fixedly connected.
  20. 根据权利要求19所述的制备电化学储能装置的方法，其特征在于，在步骤2中，通过涂覆或点胶的方式将胶黏剂层(3)设置在电芯(1)的外表面或包装壳(2)的内表面上。The method of preparing an electrochemical energy storage device according to claim 19, wherein in step 2, the adhesive layer (3) is disposed outside the battery cell (1) by coating or dispensing. On the inner surface of the surface or the package (2).
  21. 根据权利要求19所述的制备电化学储能装置的方法，其特征在于，在步骤2中，设置胶黏剂层(3)时的温度为10℃～200℃、相对湿度为10％～80％。The method for preparing an electrochemical energy storage device according to claim 19, wherein in the step 2, the temperature of the adhesive layer (3) is set to 10 ° C to 200 ° C, and the relative humidity is 10% to 80. %.
  22. 根据权利要求19所述的制备电化学储能装置的方法，其特征在于，在步骤3中，加热固化时的温度为45℃～90℃，加压固化时的压力为0.2MPa～2MPa。 The method of producing an electrochemical energy storage device according to claim 19, wherein in the step 3, the temperature at the time of heat curing is 45 to 90 ° C, and the pressure at the time of pressure curing is 0.2 MPa to 2 MPa.
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