WO2016195245A1 - Method for filling film of phase change material, and film and phase change material filling panel manufactured thereby - Google Patents

Method for filling film of phase change material, and film and phase change material filling panel manufactured thereby Download PDF

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Publication number
WO2016195245A1
WO2016195245A1 PCT/KR2016/004316 KR2016004316W WO2016195245A1 WO 2016195245 A1 WO2016195245 A1 WO 2016195245A1 KR 2016004316 W KR2016004316 W KR 2016004316W WO 2016195245 A1 WO2016195245 A1 WO 2016195245A1
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Prior art keywords
film
phase change
change material
filling
series
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PCT/KR2016/004316
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French (fr)
Korean (ko)
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공진문
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공진문
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Priority claimed from KR1020150078751A external-priority patent/KR101765300B1/en
Priority claimed from KR1020160038296A external-priority patent/KR101830164B1/en
Application filed by 공진문 filed Critical 공진문
Publication of WO2016195245A1 publication Critical patent/WO2016195245A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form
    • B32B3/26Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/30Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/08Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the cooling method
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/74Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
    • E04B1/76Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
    • E04B1/78Heat insulating elements
    • E04B1/80Heat insulating elements slab-shaped
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/02Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
    • E04C2/26Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups
    • E04C2/284Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups at least one of the materials being insulating
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/44Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by the purpose
    • E04C2/52Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by the purpose with special adaptations for auxiliary purposes, e.g. serving for locating conduits

Definitions

  • the present invention relates to a film filling method of a phase change material (PCM) and a film and a PCM filling panel produced by the method, and more particularly, to a method for easily filling the film with a phase change material and a film prepared by the method and
  • the present invention relates to a method for manufacturing a PCM filled panel having a heat insulating layer attached thereto for efficient use of indoor energy without being affected by external temperature changes, and a PCM filled panel manufactured by the method.
  • CO 2 such as a pan-national technology and policy developments correspond to a strengthened environmental regulations, trade barriers due to the regulation of greenhouse gas emissions is being pursued.
  • phase change material refers to a material capable of absorbing or dissipating a lot of heat while changing phase from solid to liquid, liquid to gas, or vice versa without changing the temperature at a specific temperature.
  • Panels filled with phase change materials can be applied to building walls, ceilings, floors, etc. to mitigate rapid changes in room temperature by the heat storage function, which absorbs thermal changes in the room by the latent heat of phase change materials. Savings can be achieved.
  • the latent heat storage method which is a thermal energy storage method using such latent heat, can store a large amount of heat per unit volume or unit weight.
  • the phase change material usually has a melting temperature of -10 ° C to 80 ° C, and it is difficult to apply it to real life by forming and processing due to the outflow of the phase change material due to liquefaction due to temperature change. have.
  • Shape stabilization method to prevent the leakage of phase change material is morphological stability by impregnating, mixing or encapsulating the phase change material in materials such as gypsum board or mixing it with a material such as HDPE (high density poly ethylene). There is a way to make a phase change material
  • phase change materials are generally used in encapsulation.
  • Korean Patent Application No. 2003-88712 and Korean Patent Application No. 2005-133799 disclose a technique relating to an encapsulated phase change material.
  • a separate method for this is required in order to encapsulate the phase change material. Therefore, the encapsulation of the phase change material increases the cost and the use is limited.
  • the capsule is broken during use due to the application temperature and physical impact, there is a problem that the phase change material in the liquid flows out.
  • the present invention is to provide a simple method of filling a film with a phase change material.
  • the present invention provides a method of preventing the outflow of the phase change material by converting the phase change material to a solid using a cooling device during the filling process.
  • the present invention also provides a filler for maintaining the shape stability of the film filled with the phase change material.
  • the present invention is to provide a protective layer for preventing the external contamination of the phase change material and thermal conductivity.
  • the present invention is to provide a heat insulating layer on one side in order to improve the directivity of the heat flow.
  • the present invention provides a film filling method comprising the steps of: preparing a flat film of a constant thickness; Processing the flat film to form an uneven structure characterized by a plurality of acids and valleys; Filling the filler inside the concave-convex structure acid; After filling the filler and bonding the base layer to the lower bone; Filling a phase change material in the bone of the uneven structure; Solidifying the phase change material by using a cooling device of the uneven structure-filled film filled with the phase change material and bonding the protective layer to the top of the acid in the state where the phase change material is solidified. It provides a film filling method.
  • the present invention provides a film filling method of a phase change material, characterized in that the filler is a material having the characteristics of shape and heat resistance, flame retardant and elasticity of the uneven structure film.
  • the present invention is the phase change material, characterized in that the base layer may be composed of at least one of synthetic resin films, metals, metal alloys, stones and wood that can be a structural support band of the uneven structure film. It provides a film filling method.
  • the present invention provides a method for filling a phase change material, characterized in that the phase change material may be composed of any one of an organic compound series, inorganic compound series or eutectic compound series.
  • the present invention is characterized in that the film layer is formed by at least one or more of the PE series, PU series, PP series and PS series films are used, or at least any one or more of these films and nylon films are laminated at least two times. It provides a film filling method of the phase change material.
  • the protective layer is a film filling of the phase change material, characterized in that the phase change material is laminated with a conductive film consisting of a metal material having excellent thermal conductivity on the protective film layer or the protective film layer of the external separation prevention function.
  • the present invention provides a film filling method of a phase change material, characterized in that the conductive layer is composed of at least one metal material of silver, copper, aluminum, chromium, nickel and iron excellent in electrical conductivity.
  • the protective film layer is at least one of the PE series, PU series, PP series and PS series of the film is used, or one or more of the film and the nylon film is laminated two or more, high frequency or Provided is a method for filling a film of a phase change material, characterized in that bonding using a heat fusion process.
  • the present invention also provides a film filled with a phase change material that can be prepared by the above method.
  • the present invention is a film filled with the phase change material is used to make all products using latent heat, such as building materials, refrigerator panels, refrigeration tower insulation filler, heating panels, constant temperature containers, cooling goods or functional textile products It provides a film filled with a phase change material characterized in that it can be.
  • the present invention provides a PCM filled panel manufacturing method that can be further configured to bond the heat insulation layer on the lower surface of the base layer after the bonding of the protective layer.
  • the present invention provides a method for manufacturing a PCM filler panel, characterized in that the protective layer is composed of any one of a protective film layer or a conductive layer laminated on the protective film layer.
  • the present invention provides a PCM filled panel manufacturing method characterized in that the conductive layer is composed of at least one metal material of copper, aluminum, silver, copper, aluminum, chromium, nickel and iron excellent in the conductivity.
  • the protective film layer is at least one of PE series, PU series, PP series and PS series films are used, or at least one film and nylon film of at least two layers are laminated, acid of the uneven structure film
  • a PCM filling panel manufacturing method characterized in that the bonding to the upper by using a high frequency or heat fusion process.
  • the present invention provides a PCM filler panel manufacturing method characterized in that the material is characterized by heat, flame retardant and elasticity and has impact resistance for maintaining the shape of the uneven structure film.
  • the present invention is the PCM filler panel, characterized in that the base layer may be composed of at least one of synthetic resin films, metals, metal alloys, stones and wood that can be a structural support band of the uneven structure film. It provides a manufacturing method.
  • the present invention provides a method for producing a PCM-filled panel, characterized in that the phase change material may be composed of any one of an organic compound series, an inorganic compound series or a eutectic compound series, and has a melting point of 5 to 70 ° C.
  • the present invention is characterized in that the planar film is formed by at least one or more of PE, PU, PP, and PS films, or at least one or more films and nylon films of two or more laminated films. It provides a PCM filling panel manufacturing method.
  • the present invention provides a PCM filled panel manufacturing method characterized in that the air cap is a film containing the bubble.
  • the present invention provides a PCM filling panel that can be prepared by the above method.
  • the PCM filling panel is PCM filling, characterized in that it can be used to make all products using latent heat, such as building materials, refrigerator panels, refrigeration tower insulation filler, heating panels, constant temperature containers or cooling goods (Cooling goods) Provide panels.
  • latent heat such as building materials, refrigerator panels, refrigeration tower insulation filler, heating panels, constant temperature containers or cooling goods (Cooling goods) Provide panels.
  • the phase change material is filled into the bone, and the phase change material in the liquid state is quickly and inexpensively converted into the solid state using a cooling device.
  • the phase change material has an effect of providing a convenient filling technology that prevents in-process leakage and facilitates high frequency or heat welding operations.
  • the present invention has the effect of preventing the filling of the filler inside the structural structural weakness due to the uneven structure of the filling film.
  • the present invention is characterized by preventing the exposure to the external environment of the filled phase change material by bonding the protective layer of the film protective layer and the conductive layer laminated on the film acid portion and the external thermal conductivity is easy to move to the phase change material. .
  • the present invention is bonded to the heat insulating layer on one side to improve the directivity of the heat flow has the effect of efficient use of room energy.
  • FIG. 1 is a flowchart illustrating a method of filling a film with a phase change material of the present invention.
  • Figure 2 shows a flow chart related to the PCM filling panel manufacturing method of the present invention.
  • Figure 3a, 3b is a view showing the irregular structure of the various forms by processing the film used in the present invention.
  • Figure 4 shows a cross-sectional view of the film filled with the phase change material of the present invention.
  • FIG. 5 and 6 is a cross-sectional view of the PCM filling panel which is an embodiment completed by the manufacturing method of the present invention.
  • the present invention relates to a method of filling a film with a phase change material, the step of preparing a flat film of a predetermined thickness (S1); Processing the flat film to create an uneven structure characterized by a plurality of hills and valleys (S2); Filling a filler in the uneven structure acid (S3); Bonding the base layer to the lower portion of the bone after filling the filler (S4); Filling the phase change material in the bone of the uneven structure (S5); Comprising the step of solidifying the phase change material in the film of the concave-convex structure filled with the phase change material using a cooling device (S6) and the step of bonding the protective layer on the top of the acid in the solid state of the phase change material (S7) It relates to a film filling method of a phase change material that can be.
  • the film is a thermoplastic resin material that can be fused by applying high frequency or heat.
  • the film layer is at least one of PE, PU, PP, and PS films. It is used or at least any one or more of the film and nylon film is characterized in that formed by two or more laminated.
  • the characteristics of PP series resin are easy to mold, excellent in strength, chemical resistance, permeability, electrical insulation, etc., and are inexpensive compared to other resins.
  • low density polyethylene LDPE
  • linear low density polyethylene LLDPE
  • high density polyethylene HDPE
  • the film composed of only the PE-based resin may be weak in tensile strength, heat resistance, impact strength, and may be used by stacking several layers of nylon resin that can compensate for this.
  • the flat film 110 is processed to make an uneven structure characterized by a plurality of hills and valleys (S2).
  • the flat film may have a concave-convex structure by using pressure forming molds having a plurality of embossed shapes and applying pressure and heat to the upper and lower surfaces of the film 110.
  • Flat films composed of PP series resins are generally easy to mold.
  • 3A and 3B are perspective views showing examples of processed films.
  • 3A is a perspective view of the concavo-convex shape
  • FIG. 3B is close to a square pillar.
  • Concave-convex shape can be in any form and there is no limitation.
  • the filler 150 and the phase change material 120 only need to secure a space that can be contained on the mountain portion 111a and the bone portion 112a of the uneven portion.
  • the bone depth d of the uneven structure is characterized in that 3 ⁇ 30mm.
  • the bone depth (d) varies depending on the amount of phase change material 120 filled in the bone.
  • the filling space 150 is filled in the empty space inside the valley 112a of the uneven structure (S3).
  • the film 110 may be vulnerable to external pressure or impact when the film 110 filled with the phase change material 120 is stored or used.
  • the film layer may be damaged by external impact, and thus, the filler 150 needs to be filled in the acid 111a in order to alleviate the impact. .
  • the characteristics should be impact resistance for maintaining the shape of the uneven structure film, and materials having characteristics such as heat resistance and flame resistance may be used depending on the intended use.
  • Synthetic resin may be used as the filler material 150 is expanded polystyrene or natural cork material.
  • the foamed polypropylene itself is weak to heat and needs flame retardant treatment.
  • cork material refers to a thick layer of bark between the bark and the bark, and is used as a filler because it is light, elastic, and not easily burned by heat.
  • the base layer 140 is bonded to the bottom of the uneven portion 112 (S4).
  • the base layer is for the purpose of preventing the filler 150 from leaving to the outside, as well as serves as a structural support band of the uneven structure film together with the filler 150. It may be composed of at least one of a synthetic resin film, metal plates, metal alloy plates, stone or wood.
  • the phase change material is filled in the bone portion 112a of the uneven portion (S5).
  • phase change material in the present invention, it may be composed of any one of organic compound series, inorganic compound series or eutectic compound series.
  • phase change material 120 should be provided.
  • thermodynamically 1 melting point in the required operating temperature range, 2 latent heat of fusion per high volume of unit (i.e. loss of required volume of energy storage), 3 high thermal conductivity in solid and liquid phase, 4 energy in heat storage system Absorption and release, 5 small volume change in phase change and small vapor pressure at operating temperature are required.
  • chemically 1 reversible condensation and melting cycles, 2 maintaining a certain quality after several condensation and melting cycles, 3 non-corrosive to building materials and 4 non-toxic, non-flammable and non-explosive substances are not limited.
  • the phase change material 120 filled into the bone 112a is solidified using a cooling device (S5).
  • a protective layer is attached to cover the top of the acid 111 of the uneven structure film to fill the inside of the uneven structure with a liquid phase change material and to prevent the phase change material from flowing out of the film valley 112 to the outside. Go through the process. This is because the phase change material 120 may flow out to the outside due to the vibration or impact during the liquid properties.
  • phase change materials 120 may be used depending on the use, and thus, the spilled phase change material 120 may be harmful to the environment or the human body. In order to prevent this, difficulties in cost and time may occur.
  • the phase change material 120 solidifies the phase change material 120 using a freezing device immediately after filling the phase change material 120 with the concave-convex structure, the fluidity decreases due to the characteristics of the solidified material. The likelihood of a spill is significantly reduced.
  • the protective layer 130 is bonded onto the acid 111 (S7).
  • the phase change material includes a protective film layer 131 having an external separation prevention function or a conductive layer 133 composed of a metal material having excellent thermal conductivity on the protective film layer 131. It is characterized by.
  • the same material or the same material for the film 110 and the protective film layer 131 forming the uneven structure is advantageous to use the same material or the same material for the film 110 and the protective film layer 131 forming the uneven structure. That is, at least one of the PE series, PU series, PP series and PS series films may be used, or one or more films and nylon films of two or more layers thereof may be laminated and used, and a high frequency or It can be adhered using a heat fusion process.
  • the protective film layer 131 is bonded to the top of the uneven structure film 110 layer acid 111 using a high frequency or heat fusion process. Since the components of the film are thermoplastic components, when heat is applied in a molten state by applying heat in a solid state, the two film layers are easily bonded together, and when solidified at room temperature, they are firmly bonded without the need for a separate adhesive.
  • the metal material that may be used for the conductive layer 133 may be composed of any one of an aluminum alloy and a copper alloy.
  • the thermal conductivity (W / m. ° C X 10 2 ) of the metal is about 4.12 silver (C), copper (Cu) 3.17, aluminum (Al) 1.95, chromium (Cr) 0.96, nickel (Ni) 0.84, and iron (Fe) 0.79. .
  • the conductive layer 133 may be used or the protective film layer 131 may be used depending on the use of the phase change material 120.
  • the conductive polymer film having a certain strength may be used for external shock protection and may be used for cooling goods. In this case, only a film filled with a phase change material may be used.
  • Figure 4 shows a cross-sectional view of the film 100 filled with a phase change material completed by the above method.
  • the film is processed into a concave-convex structure and the bone inner portion 112a is filled with the phase change material 120 and the phase change material 120 filled with a protective layer 130 for blocking environmental pollution or harmful to the human body ( 111) Adhesion with parts.
  • the conductive layer 133 may be bonded to the protective film 131 similar to the component of the film 110 by a high frequency or heat fusion method, and may be easily conductive on the outer surface of the protective film depending on the intended use.
  • the filler 150 by filling the filler 150 into the acid 111a of the uneven film 110 to mitigate structural weakness due to the external influence of the film filled with the phase change material 120.
  • the filler 150 has a configuration in which the base material layer is adhered to the bone 112 so that the filler 150 is not in close contact with the acid 111a.
  • the present invention relates to a PCM filled panel manufacturing method that can be further configured to bond the heat insulating layer on the lower surface of the base layer after the bonding of the protective layer.
  • FIG. 2 shows a flow chart related to the PCM filling panel manufacturing method of the present invention.
  • PCM filling panel manufacturing method may further comprise the step of bonding the heat insulating layer to the lower surface of the base layer in the final step (S8) to the film filling method of the phase change material.
  • the heat insulating layer 160 may use an air cap, which is a film containing bubbles in consideration of cost.
  • the air cap is a shape of two or more layers of polyethylene (polyethylene) film is nested between the trapped air bubbles therebetween. In addition to being used for buffer packaging, there is also a heat insulating effect.
  • FIG. 5 shows a cross-sectional view of a PCM filled panel completed by the above method.
  • the flat film 110 is processed into a concave-convex structure and the bone inner portion 112a is filled with a phase change material 120 and filled with a phase change material 120 to prevent environmental pollution or harmful effects of a human body.
  • a protective layer 130 composed of 131 is bonded to the acid 111 portion of the film processed into the uneven structure.
  • the filler 150 is adhered to the valley 112 so that the filler 150 is not in close contact with the mountain 111a, and a heat insulating layer is bonded to the lower surface of the base layer to block the flow of heat to the outside. .
  • FIG. 6 is composed of a plurality of protective layers 130, that is, a protective film layer 131 and a conductive layer 133 in the PCM filling panel of FIG.
  • the PCM filling panel may be mainly used as a built-in drying material, the protective layer 130 to the indoor space when used, the heat insulating layer 160 toward the outer wall surface.
  • the protective layer 130 is made of a material having a good thermal conductivity, so that when the room temperature rises higher than the melting point of the phase change material, the protection layer 130 may prevent the room temperature from increasing further.
  • the role of the heat insulation layer 160 is to concentrate the heat exchange with the indoor heat energy by passing the heat flow toward the phase change material (PCM) through the protective layer 130. If the insulating layer 160 is absent because the exchange function of the indoor heat energy due to the heat energy exchange with the phase change material (PCM) due to the movement of heat from the outside can be reduced.
  • the PCM filling panel of the present invention can use a phase change material (PCM) having a variety of melting point temperature in addition to the building material, and a latent heat such as a panel for a refrigerator, a refrigeration tower insulation filler, a heating panel, a constant temperature container, a cooling product (Cooling goods) Can be used for all products using Therefore, a phase change material having a melting point temperature suitable for the intended use may be selected and used among phase change materials having a melting point of 5 to 70 ° C.

Abstract

The present invention relates to a method for filling a film of a phase change material (PCM), and a method for manufacturing a PCM filling panel. The method for filling a film of a phase change material comprises the steps of: preparing a flat film which has a predetermined thickness; making a concave-convex structure, which is characterized by a plurality of mountains and valleys, by processing the flat film; filling a filler on the inside of the mountain of the concave-convex structure; bonding a base layer on the lower portion of the valley after filling the filler; filling a phase change material on the inside of the valley of the concave-convex structure; solidifying the phase change material of the film, which is filled with the phase change material and has the concave-convex structure, using a cooling apparatus; and bonding a protection layer on the upper portion of the mountain in a state where the phase change material is solidified. In addition, the method for manufacturing a PCM filling panel may comprise a step of bonding a heat insulation layer on the bottom surface of the base layer.

Description

상변화물질의 필름 충진 방법 및 그 방법으로 제조된 필름과 상변환물질충진판넬Film filling method of phase change material and film and phase conversion material filling panel manufactured by the method
본 발명은 상변화물질(PCM)의 필름 충진 방법 및 그 방법으로 제조된 필름 및 PCM충진판넬에 관한 것으로서, 더욱 상세하게는 상변화물질을 필름에 간편하게 충진하는 방법 및 그 방법으로 제조된 필름과 외부 온도변화에 영향을 받지 않고 실내에너지의 효율적 이용을 위하여 단열층이 부착된 PCM충진판넬 제조방법 및 그 방법으로 제조된 PCM충진판넬에 관한 것이다. The present invention relates to a film filling method of a phase change material (PCM) and a film and a PCM filling panel produced by the method, and more particularly, to a method for easily filling the film with a phase change material and a film prepared by the method and The present invention relates to a method for manufacturing a PCM filled panel having a heat insulating layer attached thereto for efficient use of indoor energy without being affected by external temperature changes, and a PCM filled panel manufactured by the method.
근래에 오존층 파괴, CO2 배출에 따른 지구온난화, 기타 각종 환경오염 물질 배출에 따른 자연환경 파괴 등의 환경문제가 범세계적인 공동대처 과제로 대두 되고 있다. 이에 따라, CO2 등 온실가스의 배출 규제로 인한 환경규제, 무역장벽 강화 등에 대응한 범국가적인 기술 및 정책 개발이 추진되고 있다.Recently, environmental issues such as ozone layer destruction, global warming due to CO 2 emissions, and natural environment destruction due to various environmental pollutants are emerging as global cooperative measures. Accordingly, CO 2, such as a pan-national technology and policy developments correspond to a strengthened environmental regulations, trade barriers due to the regulation of greenhouse gas emissions is being pursued.
이러한 개발의 일환으로 에너지의 효율적인 이용을 위한 열에너지의 저장, 변환, 전달 및 이용기술의 개발이 활발하게 진행되고 있다. 이러한 기술 중에는 화학물질로서 에너지를 저장하는 화학적 저장방법 및 열에너지를 에너지의 형태변화 없이 현열 및 잠열을 이용하여 저장하는 방법 등이 있다.As part of this development, the development of technologies for storing, converting, transferring and using thermal energy for efficient use of energy is being actively conducted. Among these technologies, there are chemical storage methods for storing energy as chemicals and methods for storing thermal energy using sensible and latent heat without changing the form of energy.
에너지 효율을 극대화하기 위해서 높은 열용량을 갖는 새로운 열전달 매체를 사용하는 연구가 진행되어 왔으며, 특히, 상변화물질을 이용한 잠열 축열법에 관한 연구가 진행되어 왔다.In order to maximize energy efficiency, studies using a new heat transfer medium having a high heat capacity have been conducted, and in particular, a study on latent heat storage method using a phase change material has been conducted.
한편, 상변화물질(Phase Change Material, PCM)은 특정한 온도에서 온도변화 없이 고체에서 액체, 또는 액체에서 기체로 또는 그 반대방향으로 상이 변하면서 많은 열을 흡수 또는 방출할 수 있는 물질을 의미한다. 이러한 상변화물질로 충진된 판넬을 건물 벽체, 천장, 바닥 등에 적용함으로써 상변화물질의 잠열에 의해 실내의 열적변화를 흡수하는 축열기능에 의해 급속한 실내온도 변화를 완화시킬 수 있으며 이로 인해 건축물의 에너지 절감을 달성할 수 있다.Meanwhile, a phase change material (PCM) refers to a material capable of absorbing or dissipating a lot of heat while changing phase from solid to liquid, liquid to gas, or vice versa without changing the temperature at a specific temperature. Panels filled with phase change materials can be applied to building walls, ceilings, floors, etc. to mitigate rapid changes in room temperature by the heat storage function, which absorbs thermal changes in the room by the latent heat of phase change materials. Savings can be achieved.
이러한 잠열을 이용한 열에너지 저장방법인 잠열 축열법은 단위 부피당 혹은 단위 무게당 많은 양의 열을 저장할 수 있다.The latent heat storage method, which is a thermal energy storage method using such latent heat, can store a large amount of heat per unit volume or unit weight.
그러나, 잠열을 이용한 축열방법에서 상변화물질은 대개 -10℃ 내지 80℃의 용융온도를 가지고 있으며, 온도변화에 따른 액상화로 인한 상변화물질의 유출로 인하여 성형가공하여 실생활에 적용하기 어려운 문제가 있다. However, in the heat storage method using latent heat, the phase change material usually has a melting temperature of -10 ° C to 80 ° C, and it is difficult to apply it to real life by forming and processing due to the outflow of the phase change material due to liquefaction due to temperature change. have.
그러므로, 상변화물질을 건축물에 적용할 경우에는 형태안정을 시켜주어야 한다. 상변화물질의 상변화로 인한 액체 상태에서의 누출과 형태변형이 발생할 우려가 있기 때문이다. 상변화물질의 누출을 막기 위한 형태안정의 방법으로는 석고보드(gypsum board) 등의 재료에 상변화물질을 함침, 혼합 또는 캡슐화를 하거나 HDPE(high density poly ethylene)와 같은 물질과 혼합함으로서 형태 안정성 상변화물질을 만드는 방법이 있다Therefore, shape change should be applied when phase change material is applied to buildings. This is because there is a risk of leakage and deformation in the liquid state due to the phase change of the phase change material. Shape stabilization method to prevent the leakage of phase change material is morphological stability by impregnating, mixing or encapsulating the phase change material in materials such as gypsum board or mixing it with a material such as HDPE (high density poly ethylene). There is a way to make a phase change material
이러한 문제를 해결하기 위해 현재 일반적으로 상변화물질은 캡슐화하여 사용된다. 예를 들면, 한국 특허출원 제2003-88712호 및 한국 특허출원 2005-133799에는 캡슐화된 상변화물질에 관한 기술이 개시되어 있다. 그러나, 상변화물질을 캡슐화하기 위해서는 이를 위한 별도의 공법을 필요로 한다. 따라서, 상변화물질의 캡슐화로 인하여 비용이 증가하며 사용이 제한된다. 뿐만 아니라, 적용 온도 및 물리적인 충격으로 사용 도중에 캡슐이 파손되는 경우에는 액상의 상변화물질이 유출되는 문제가 있다.To solve this problem, phase change materials are generally used in encapsulation. For example, Korean Patent Application No. 2003-88712 and Korean Patent Application No. 2005-133799 disclose a technique relating to an encapsulated phase change material. However, in order to encapsulate the phase change material, a separate method for this is required. Therefore, the encapsulation of the phase change material increases the cost and the use is limited. In addition, when the capsule is broken during use due to the application temperature and physical impact, there is a problem that the phase change material in the liquid flows out.
상기와 같은 문제점을 해결하기 위해 본 발명은 상변화물질을 필름에 충진하는 간편한 방법을 제공하는 것이다.In order to solve the above problems, the present invention is to provide a simple method of filling a film with a phase change material.
또한, 본 발명은 충진과정에서 상변화물질을 냉각장치를 이용하여 고체로 변환시켜 상변화물질의 유출을 방지하는 방법을 제공하는 것이다. In addition, the present invention provides a method of preventing the outflow of the phase change material by converting the phase change material to a solid using a cooling device during the filling process.
또한, 본 발명은 상변화물질이 충진된 필름의 형태안정성을 유지시키기 위한 충진재를 제공하는 것이다. The present invention also provides a filler for maintaining the shape stability of the film filled with the phase change material.
또한, 본 발명은 상변화물질의 외부 오염을 방지하고 열전도성을 위해 보호층을 제공하는 것이다.In addition, the present invention is to provide a protective layer for preventing the external contamination of the phase change material and thermal conductivity.
또한, 본 발명은 열흐름의 방향성을 개선하기 위해 한 면에 단열층을 제공하는 것이다. In addition, the present invention is to provide a heat insulating layer on one side in order to improve the directivity of the heat flow.
상기와 같은 목적을 달성하기 위해, 본 발명은 필름 충진 방법에 있어서,일정한 두께의 평면 필름을 준비하는 단계; 상기 평면 필름을 가공하여 복수의 산과 골로 특징되는 요철구조를 만드는 단계; 상기 요철구조 산 내부에 충진재를 충진하는 단계;상기 충진재를 충진 후 골 하부에 기재층을 합착하는 단계; 상기 요철구조의 골 내부에 상변화물질을 충진하는 단계; 상기 상변화물질이 충진된 요철구조의 필름을 냉각장치를 이용해 상변화물질을 고체화시키는 단계 및 상기 상변화물질이 고체화된 상태에서 산 상부에 보호층을 합착하는 단계로 구성될 수 있는 상변화물질의 필름 충진 방법을 제공한다. In order to achieve the above object, the present invention provides a film filling method comprising the steps of: preparing a flat film of a constant thickness; Processing the flat film to form an uneven structure characterized by a plurality of acids and valleys; Filling the filler inside the concave-convex structure acid; After filling the filler and bonding the base layer to the lower bone; Filling a phase change material in the bone of the uneven structure; Solidifying the phase change material by using a cooling device of the uneven structure-filled film filled with the phase change material and bonding the protective layer to the top of the acid in the state where the phase change material is solidified. It provides a film filling method.
또한 본 발명은 상기 충진재는 상기 요철구조 필름의 형태유지와 내열, 방염 및 탄성의 특징이 있는 물질인 것을 특징으로 하는 상변화물질의 필름 충진 방법을 제공한다.In another aspect, the present invention provides a film filling method of a phase change material, characterized in that the filler is a material having the characteristics of shape and heat resistance, flame retardant and elasticity of the uneven structure film.
또한 본 발명은 상기 기재층은 상기 요철구조의 필름의 구조적인 지지대역할을 할 수 있는 합성수지필름류, 금속류, 금속합금류, 석재류 및 목재류 중 적어도 어느 하나로 구성될 수 있는 것을 특징으로 하는 상변화물질의 필름 충진 방법을 제공한다.In addition, the present invention is the phase change material, characterized in that the base layer may be composed of at least one of synthetic resin films, metals, metal alloys, stones and wood that can be a structural support band of the uneven structure film. It provides a film filling method.
또한 본 발명은 상기 상변화물질은 유기화합물 계열, 무기화합물 계열 또는 공융화합물 계열 중 어느 하나로 구성될 수 있는 것을 특징으로 하는 상변화물질의 필름 충진 방법을 제공한다.In another aspect, the present invention provides a method for filling a phase change material, characterized in that the phase change material may be composed of any one of an organic compound series, inorganic compound series or eutectic compound series.
또한 본 발명은 상기 필름층은 PE계열, PU계열, PP계열 및 PS계열의 필름 중 적어도 어느 하나 이상이 사용되거나 또는 그 중 적어도 어느 하나 이상의 필름과 나일론필름이 2겹 이상 합지되어 형성되는 것을 특징으로 하는 상변화물질의 필름 충진 방법을 제공한다.In another aspect, the present invention is characterized in that the film layer is formed by at least one or more of the PE series, PU series, PP series and PS series films are used, or at least any one or more of these films and nylon films are laminated at least two times. It provides a film filling method of the phase change material.
또한 본 발명은 상기 보호층은 상기 상변화물질이 외부 이탈 방지 기능의 보호필름층 또는 상기 보호필름층에 열전도가 뛰어난 금속물질로 구성되는 전도층이 적층된 것을 특징으로 하는 상변화물질의 필름 충진 방법을 제공한다.In another aspect, the protective layer is a film filling of the phase change material, characterized in that the phase change material is laminated with a conductive film consisting of a metal material having excellent thermal conductivity on the protective film layer or the protective film layer of the external separation prevention function. Provide a method.
또한 본 발명은 상기 전도층은 연전도율이 우수한 은, 구리, 알루미늄, 크롬, 니켈 및 철 중 적어도 어느 하나의 금속물질로 구성되는 것을 특징으로 하는 상변화물질의 필름 충진 방법을 제공한다.In another aspect, the present invention provides a film filling method of a phase change material, characterized in that the conductive layer is composed of at least one metal material of silver, copper, aluminum, chromium, nickel and iron excellent in electrical conductivity.
또한 본 발명은 상기 보호필름층은 PE계열, PU계열, PP계열 및 PS계열의 필름 중 적어도 하나가 사용되거나 또는 그 중 하나 이상의 필름과 나일론필름이 2겹이상 합지되고,상기 필름층에 고주파 또는 열융착 공정을 이용하여 접착시키는 것을 특징으로 하는 상변화물질의 필름 충진 방법을 제공한다.In the present invention, the protective film layer is at least one of the PE series, PU series, PP series and PS series of the film is used, or one or more of the film and the nylon film is laminated two or more, high frequency or Provided is a method for filling a film of a phase change material, characterized in that bonding using a heat fusion process.
또한 본 발명은 상기 방법에 의해 제조될 수 있는 상변화물질이 충진된 필름을 제공한다.The present invention also provides a film filled with a phase change material that can be prepared by the above method.
또한 본 발명은 상기 상변화물질이 충진된 필름은 건축용 자재, 냉장고용 판넬, 냉동탑차 단열충진재, 난방용 판넬, 항온 용기, 쿨링 제품(Cooling goods)또는 기능성 섬유제품등 잠열을 이용한 모든 제품을 만드는데 사용될 수 있는 것을 특징으로 하는 상변화물질이 충진된 필름을 제공한다.In addition, the present invention is a film filled with the phase change material is used to make all products using latent heat, such as building materials, refrigerator panels, refrigeration tower insulation filler, heating panels, constant temperature containers, cooling goods or functional textile products It provides a film filled with a phase change material characterized in that it can be.
또한 본 발명은 상기 보호층을 합착하는 단계 이후 상기 기재층 하면에 단열층을 합착하는 단계로 추가 구성될 수 있는 PCM충진판넬 제조방법을 제공한다.In another aspect, the present invention provides a PCM filled panel manufacturing method that can be further configured to bond the heat insulation layer on the lower surface of the base layer after the bonding of the protective layer.
또한 본 발명은 상기 보호층은 보호필름층 또는 상기 보호필름층 상면에 전도층이 적층된 것중 어느 하나로 구성된 것에 특징이 있는 PCM충진판넬 제조방법을 제공한다.In another aspect, the present invention provides a method for manufacturing a PCM filler panel, characterized in that the protective layer is composed of any one of a protective film layer or a conductive layer laminated on the protective film layer.
또한 본 발명은 상기 전도층은 연전도율이 우수한 구리, 알루미늄, 은, 구리, 알루미늄, 크롬, 니켈 및 철 중 적어도 어느 하나의 금속물질로 구성되는 것을 특징으로 하는 PCM충진판넬 제조방법을 제공한다.In another aspect, the present invention provides a PCM filled panel manufacturing method characterized in that the conductive layer is composed of at least one metal material of copper, aluminum, silver, copper, aluminum, chromium, nickel and iron excellent in the conductivity.
또한 본 발명은 상기 보호필름층은 PE계열, PU계열, PP계열 및 PS계열의 필름 중 적어도 하나가 사용되거나 또는 그 중 하나 이상의 필름과 나일론필름이 2겹이상 합지되고, 상기 요철 구조 필름의 산 상부에 고주파 또는 열융착 공정을 이용하여 접착시키는 것을 특징으로 하는 PCM충진판넬 제조방법을 제공한다.In the present invention, the protective film layer is at least one of PE series, PU series, PP series and PS series films are used, or at least one film and nylon film of at least two layers are laminated, acid of the uneven structure film Provided is a PCM filling panel manufacturing method characterized in that the bonding to the upper by using a high frequency or heat fusion process.
또한 본 발명은 상기 충진재는 내열, 방염 및 탄성의 특징이 있는 물질이며 상기 요철구조 필름의 형태유지의 위한 내충격성이 있는 것에 특징이 있는 PCM충진판넬 제조방법을 제공한다.In another aspect, the present invention provides a PCM filler panel manufacturing method characterized in that the material is characterized by heat, flame retardant and elasticity and has impact resistance for maintaining the shape of the uneven structure film.
또한 본 발명은 상기 기재층은 상기 요철구조의 필름의 구조적인 지지대역할을 할 수 있는 합성수지필름류, 금속류, 금속합금류, 석재류 및 목재류 중 적어도 어느 하나로 구성될 수 있는 것을 특징으로 하는 PCM충진판넬 제조방법을 제공한다.In another aspect, the present invention is the PCM filler panel, characterized in that the base layer may be composed of at least one of synthetic resin films, metals, metal alloys, stones and wood that can be a structural support band of the uneven structure film. It provides a manufacturing method.
또한 본 발명은 상기 상변화물질은 유기화합물 계열, 무기화합물 계열 또는 공융화합물 계열 중 어느 하나로 구성될 수 있고, 융점이 5~70℃ 것을 특징으로 하는 PCM충진판넬 제조방법을 제공한다.In another aspect, the present invention provides a method for producing a PCM-filled panel, characterized in that the phase change material may be composed of any one of an organic compound series, an inorganic compound series or a eutectic compound series, and has a melting point of 5 to 70 ° C.
또한 본 발명은 상기 평면 필름은 PE계열, PU계열, PP계열 및 PS계열의 필름 중 적어도 어느 하나 이상이 사용되거나 또는 그 중 적어도 어느 하나 이상의 필름과 나일론필름이 2겹 이상 합지되어 형성되는 것을 특징으로 하는 PCM충진판넬 제조방법을 제공한다.In another aspect, the present invention is characterized in that the planar film is formed by at least one or more of PE, PU, PP, and PS films, or at least one or more films and nylon films of two or more laminated films. It provides a PCM filling panel manufacturing method.
또한 본 발명은 상기 단열층은 기포가 들어간 필름인 에어캡인 것을 특징으로 하는 PCM충진판넬 제조방법을 제공한다.In another aspect, the present invention provides a PCM filled panel manufacturing method characterized in that the air cap is a film containing the bubble.
또한 본 발명은 상기 제조방법으로 제조될 수 있는 PCM충진판넬을 제공한다.In another aspect, the present invention provides a PCM filling panel that can be prepared by the above method.
또한 본 발명은 상기 PCM충진판넬은 건축용 자재, 냉장고용 판넬, 냉동탑차 단열충진재, 난방용 판넬, 항온 용기 또는 쿨링 제품(Cooling goods)등 잠열을 이용한 모든 제품을 만드는데 사용될 수 있는 것을 특징으로 하는 PCM충진판넬을 제공한다.In addition, the present invention, the PCM filling panel is PCM filling, characterized in that it can be used to make all products using latent heat, such as building materials, refrigerator panels, refrigeration tower insulation filler, heating panels, constant temperature containers or cooling goods (Cooling goods) Provide panels.
본 발명은 상변화물질 충진과정에서 평면필름을 요철구조로 성형을 한 후, 골 내부에 상변화물질을 충진하고, 냉각장치를 이용하여 액체상태의 상변화물질을 신속하고 저렴하게 고체상태로 변환과정을 통해, 상변화물질이 공정 중 유출 방지와 고주파 또는 열융착 작업을 원활하게 하는 간편한 충진기술을 제공하는 효과가 있다. In the present invention, after the flat film is formed into the uneven structure in the process of filling the phase change material, the phase change material is filled into the bone, and the phase change material in the liquid state is quickly and inexpensively converted into the solid state using a cooling device. Through the process, the phase change material has an effect of providing a convenient filling technology that prevents in-process leakage and facilitates high frequency or heat welding operations.
또한, 본 발명은 충진필름의 요철구조에 따른 구조적 취약성을 산 내부에 충진재를 채워 예방하는 효과를 갖는다.In addition, the present invention has the effect of preventing the filling of the filler inside the structural structural weakness due to the uneven structure of the filling film.
또한, 본 발명은 필름 산 부분에 필름보호층 및 전도층이 적층된 보호층을 합착하여 충진된 상변화물질의 외부환경에 노출을 방지 및 외부열전도가 상변화물질로 이동이 용이한 특징을 갖는다.In addition, the present invention is characterized by preventing the exposure to the external environment of the filled phase change material by bonding the protective layer of the film protective layer and the conductive layer laminated on the film acid portion and the external thermal conductivity is easy to move to the phase change material. .
또한, 본 발명은 한쪽 면에 단열층을 합착하여 열흐름의 방향성을 개선하여 실내 에너지의 효율적 이용효과를 갖는다. In addition, the present invention is bonded to the heat insulating layer on one side to improve the directivity of the heat flow has the effect of efficient use of room energy.
도 1은 본 발명인 상변화물질을 필름에 충진하는 방법에 관한 순서도를 나타낸다. 1 is a flowchart illustrating a method of filling a film with a phase change material of the present invention.
도 2은 본 발명인 PCM충진판넬 제조방법에 관한 순서도를 나타낸다. Figure 2 shows a flow chart related to the PCM filling panel manufacturing method of the present invention.
도 3a, 3b는 본 발명에 사용되는 필름을 가공하여 다양한 형태의 요철구조를 나타내는 도면이다.Figure 3a, 3b is a view showing the irregular structure of the various forms by processing the film used in the present invention.
도 4는 본 발명인 상변화물질이 충진된 필름의 단면도를 나타낸다. Figure 4 shows a cross-sectional view of the film filled with the phase change material of the present invention.
도 5과 6는 본 발명의 제조방법으로 완성된 일 실시예인 PCM충진판넬 단면이다.5 and 6 is a cross-sectional view of the PCM filling panel which is an embodiment completed by the manufacturing method of the present invention.
이하 본 발명에 첨부된 도면을 참조하여 본 발명을 상세히 설명하기로 한다.우선, 도면들 중, 동일한 구성요소 또는 부품들은 가능한 한 동일한 참조부호를 나타내고 있음에 유의하여야 한다. 본 발명을 설명함에 있어, 관련된 공지기능 혹은 구성에 대한 구체적인 설명은 본 발명의 요지를 모호하지 않게 하기 위하여 생략한다.DETAILED DESCRIPTION Hereinafter, the present invention will be described in detail with reference to the accompanying drawings. First of all, it should be noted that the same components or parts denote the same reference numerals as much as possible. In describing the present invention, detailed descriptions of related well-known functions or configurations are omitted in order not to obscure the subject matter of the present invention.
본 명세서에서 사용되는 정도의 용어 약, 실질적으로 등은 언급된 의미에 고유한 제조 및 물질 허용오차가 제시될 때 그 수치에서 또는 그 수치에 근접한 의미로 사용되고, 본 발명의 이해를 돕기 위해 정확하거나 절대적인 수치가 언급된 개시 내용을 비양심적인 침해자가 부당하게 이용하는 것을 방지하기 위해 사용된다.As used herein, the terms "about", "substantially", and the like, are used at, or in close proximity to, numerical values as are indicative of preparation and material tolerances inherent in the meanings mentioned, and are intended to be accurate or to facilitate understanding of the invention. Absolute figures are used to prevent unfair use by unscrupulous infringers.
본 발명은 상변화물질을 필름에 충진하는 방법에 관한 것으로, 도1을 보면 일정한 두께의 평면 필름을 준비하는 단계(S1); 상기 평면 필름을 가공하여 복수의 산과 골로 특징되는 요철구조를 만드는 단계(S2); 상기 요철구조 산 내부에 충진재를 충진하는 단계(S3); 상기 충진재를 충진 후 골 하부에 기재층을 합착하는 단계(S4); 상기 요철구조의 골 내부 상변화물질을 충진하는 단계(S5); 상기 상변화물질이 충진된 요철구조의 필름을 냉각장치를 이용해 상변화물질을 고체화시키는 단계(S6) 및 상기 상변화물질이 고체화된 상태에서 산 상부에 보호층을 합착하는 단계(S7)로 구성될 수 있는 상변화물질의 필름 충진 방법에 관한 것이다. The present invention relates to a method of filling a film with a phase change material, the step of preparing a flat film of a predetermined thickness (S1); Processing the flat film to create an uneven structure characterized by a plurality of hills and valleys (S2); Filling a filler in the uneven structure acid (S3); Bonding the base layer to the lower portion of the bone after filling the filler (S4); Filling the phase change material in the bone of the uneven structure (S5); Comprising the step of solidifying the phase change material in the film of the concave-convex structure filled with the phase change material using a cooling device (S6) and the step of bonding the protective layer on the top of the acid in the solid state of the phase change material (S7) It relates to a film filling method of a phase change material that can be.
이하, 본 발명에 대하여 상세히 설명한다. EMBODIMENT OF THE INVENTION Hereinafter, this invention is demonstrated in detail.
첫째, 평면필름을 만드는 단계(S1)에서 필름의 종류는 고주파나 열을 가해서 융착이 가능한 열가소성 수지소재로 상기 필름층은 PE계열, PU계열, PP계열 및 PS계열의 필름 중 적어도 어느 하나 이상이 사용되거나 또는 그 중 적어도 어느 하나 이상의 필름과 나일론필름이 2겹이상 합지되어 형성되는 것을 특징으로 한다.First, in the step (S1) of making a flat film, the film is a thermoplastic resin material that can be fused by applying high frequency or heat. The film layer is at least one of PE, PU, PP, and PS films. It is used or at least any one or more of the film and nylon film is characterized in that formed by two or more laminated.
PP계열수지의 특징은 성형이 쉽고 강도와 내약품성, 내침투성, 전기절연 등이 우수하고 다른 수지에 비해 값이 저렴한 특징이 있다.  The characteristics of PP series resin are easy to mold, excellent in strength, chemical resistance, permeability, electrical insulation, etc., and are inexpensive compared to other resins.
일반적으로 밀도와 분자구조에 따라 저밀도 폴리에틸렌(LDPE), 선형저밀도폴리에틸렌(LLDPE), 고밀도 폴리에틸렌(HDPE) 등으로 구별할 수 있다. Generally, low density polyethylene (LDPE), linear low density polyethylene (LLDPE), and high density polyethylene (HDPE) may be classified according to density and molecular structure.
상기 PE계열수지로만 구성된 필름은 인장강도, 내열성, 충격강도에 약할 수 있으므로 이를 보완할 수 있는 나이론(Nylon)수지를 여러 겹 합지해서 사용할 수 있다. The film composed of only the PE-based resin may be weak in tensile strength, heat resistance, impact strength, and may be used by stacking several layers of nylon resin that can compensate for this.
둘째, 상기 평면 필름(110)을 가공하여 복수의 산과 골로 특징되는 요철구조를 만든다(S2). 상기 평면필름을 요철구조로 만드는 방법은 복수의 엠보싱형상을 갖는 성형틀을 이용하여 상기 필름(110) 상부면과 하부면에 압력과 열을 가하여 성형하는 방법이 있다. PP계열수지로 구성된 평면필름은 일반적으로 성형이 용이하게 이루어진다. Second, the flat film 110 is processed to make an uneven structure characterized by a plurality of hills and valleys (S2). The flat film may have a concave-convex structure by using pressure forming molds having a plurality of embossed shapes and applying pressure and heat to the upper and lower surfaces of the film 110. Flat films composed of PP series resins are generally easy to mold.
도 3a,3b는 가공된 필름의 예를 보여주는 사시도이다. 요철형상이 도3a는 원형에 가깝고 도3b는 사각기둥모양에 가까운 사시도이다. 요철모양은 어떤 형태도 가능하며 그 제한은 없다. 충진재(150)와 상변화물질(120)이 요철부위의 산내부(111a)와 골내부(112a)위에 함유될 수 있는 공간만 확보되면 된다. 3A and 3B are perspective views showing examples of processed films. 3A is a perspective view of the concavo-convex shape, and FIG. 3B is close to a square pillar. Concave-convex shape can be in any form and there is no limitation. The filler 150 and the phase change material 120 only need to secure a space that can be contained on the mountain portion 111a and the bone portion 112a of the uneven portion.
상기 요철구조의 골 깊이(d)는 3~30mm인 것을 특징으로 한다. 골 깊이(d)는 골 내부에 상변화물질(120) 충진하는 양에 따라 다양하다. The bone depth d of the uneven structure is characterized in that 3 ~ 30mm. The bone depth (d) varies depending on the amount of phase change material 120 filled in the bone.
셋째, 상기 요철구조의 골 내부(112a)의 빈공간에는 충진재(150)를 이용하여 충진한다(S3). 요철구조로 가공된 필름의 경우 산 내부(111a)를 빈 공간 상태로 유지하면 상변화물질(120)을 충진한 필름(110)을 보관하거나 사용할 때 외부의 압력이나 충격에 취약한 구조가 될 수 있다. 특히 골 내부(112a)에 충진된 상변화물질이 액체상태로 존재할 경우 외부충격에 의해 필름층이 파손될 수 있기 때문에 충격을 완화하기 위해 충진재(150)를 산 내부(111a)에 충진할 필요가 있다.Third, the filling space 150 is filled in the empty space inside the valley 112a of the uneven structure (S3). In the case of a film processed with a concave-convex structure, if the acid inside 111a is maintained in an empty space, the film 110 may be vulnerable to external pressure or impact when the film 110 filled with the phase change material 120 is stored or used. . In particular, when the phase change material filled in the bone 112a is in a liquid state, the film layer may be damaged by external impact, and thus, the filler 150 needs to be filled in the acid 111a in order to alleviate the impact. .
상기 충진재(150)로써 특성은 요철구조 필름의 형태유지를 위한 내충격성이 있어야하고 사용용도에 따라 내열성, 방염성 등의 특징이 있는 물질을 사용할 수 있다.  As the filler material 150, the characteristics should be impact resistance for maintaining the shape of the uneven structure film, and materials having characteristics such as heat resistance and flame resistance may be used depending on the intended use.
상기 충진재(150)로 합성수지는 발포 폴리스티렌이나 천연물질인 코르크재질을 사용할 수 있다. 다만, 발포 폴리프로필렌자체는 열에 약하므로 방염처리가 필요하다. 대신에 코르크재질은 나무겉껍질과 속껍질 사이의 두꺼운 껍질층을 말하며 가볍고 탄성력이 있으며 열에 쉽게 연소되지 않은 특징이 있어 충진재로 많이 사용한다. Synthetic resin may be used as the filler material 150 is expanded polystyrene or natural cork material. However, the foamed polypropylene itself is weak to heat and needs flame retardant treatment. Instead, cork material refers to a thick layer of bark between the bark and the bark, and is used as a filler because it is light, elastic, and not easily burned by heat.
넷째, 상기 요철부위 골(112) 하부에 기재층(140)을 합착한다(S4). 기재층은 상기 충진재(150)가 외부로 이탈을 방지하기 위한 목적이며, 뿐만 아니라 충진재(150)와 함께 요철구조 필름의 구조적인 지지대역할을 한다. 합성수지필름, 금속판류, 금속합금판류, 석재류 또는 목재류 중 적어도 어느 하나로 구성될 수 있다.Fourth, the base layer 140 is bonded to the bottom of the uneven portion 112 (S4). The base layer is for the purpose of preventing the filler 150 from leaving to the outside, as well as serves as a structural support band of the uneven structure film together with the filler 150. It may be composed of at least one of a synthetic resin film, metal plates, metal alloy plates, stone or wood.
다섯째, 상기 요철부위의 골내부(112a)에 상변화물질을 충진한다(S5). Fifth, the phase change material is filled in the bone portion 112a of the uneven portion (S5).
본 발명에서 상변화물질의 제한은 없다. 따라서, 유기화합물 계열, 무기화합물 계열 또는 공융화합물 계열 중 어느 하나로 구성될 수 있다. 다만, 상변화물질(120) 특성을 갖추어야 한다. There is no limitation of the phase change material in the present invention. Therefore, it may be composed of any one of organic compound series, inorganic compound series or eutectic compound series. However, the phase change material 120 should be provided.
즉, 열역학적으로 ① 요구되는 운전 온도 범위에서의 녹는점, ② 높은 단위체적당 융해잠열 (즉, 주어진 양의 에너지 저장 요구체적 감량), ③ 고상 및 액상에서의 높은 열전도도, ④ 축열 시스템에서의 에너지 흡수 및 방출, ⑤ 상 변화시 작은 체적변화 및 운전 온도에서의 작은 증기압이 요구된다. 또한, 화학적으로 ① 가역적인 응결 및 융해 싸이클, ② 수차례의 응결 및 융해 싸이클 후의 일정한 품질 유지, ③ 건축 자재에 대한 비부식성 및 ④ 비독성, 비인화성 및 비폭발성 물질이면 제한을 두지 않는다. That is, thermodynamically ① melting point in the required operating temperature range, ② latent heat of fusion per high volume of unit (i.e. loss of required volume of energy storage), ③ high thermal conductivity in solid and liquid phase, ④ energy in heat storage system Absorption and release, ⑤ small volume change in phase change and small vapor pressure at operating temperature are required. In addition, chemically ① reversible condensation and melting cycles, ② maintaining a certain quality after several condensation and melting cycles, ③ non-corrosive to building materials and ④ non-toxic, non-flammable and non-explosive substances are not limited.
여섯째, 상기 골 내부(112a)로 충진된 상변화물질(120)을 냉각장치를 사용해서 고체화시킨다(S5). 요철구조의 골내부에 액체상태의 상변화물질을 충진시키고 상변화물질이 필름 골(112) 부분에서 외부로 유출되는 것을 막기 위해 요철구조 필름의 산(111) 상부를 덮을 수 있게 보호층을 접착시키는 공정을 거친다. 이때 액체특성상 공정 중에 진동이나 충격으로 상변화물질(120)이 외부로 유출될 수 있기 때문이다.Sixth, the phase change material 120 filled into the bone 112a is solidified using a cooling device (S5). A protective layer is attached to cover the top of the acid 111 of the uneven structure film to fill the inside of the uneven structure with a liquid phase change material and to prevent the phase change material from flowing out of the film valley 112 to the outside. Go through the process. This is because the phase change material 120 may flow out to the outside due to the vibration or impact during the liquid properties.
용도에 따라 다양한 상변화물질(120)을 사용할 수 있어 유출된 상변화물질(120)이 환경오염이나 인체에 해가 될 수 있으며 이를 방지하기 위해서는 공정상 비용, 시간 등에서 어려움이 생길 수 있다. Various phase change materials 120 may be used depending on the use, and thus, the spilled phase change material 120 may be harmful to the environment or the human body. In order to prevent this, difficulties in cost and time may occur.
따라서 본 발명은 액상으로 상변화물질(120)을 요철구조의 골 내부(112a)에 충진한 후 바로 냉동장치를 이용하여 상기 상변화물질(120)을 응고시키면 고체화된 물질의 특성상 유동성이 줄어들어 외부 유출의 가능성이 현저하게 줄어든다. Therefore, in the present invention, when the phase change material 120 solidifies the phase change material 120 using a freezing device immediately after filling the phase change material 120 with the concave-convex structure, the fluidity decreases due to the characteristics of the solidified material. The likelihood of a spill is significantly reduced.
마직막으로, 상기 상변화물질(120)이 고체화된 상태에서 산(111) 상부에 보호층(130)을 합착한다(S7). 본 발명의 보호층(130)은 상기 상변화물질이 외부 이탈 방지 기능의 보호필름층(131) 또는 상기 보호필름층(131)에 열전도가 뛰어난 금속물질로 구성되는 전도층(133)이 적층된 것을 특징으로 한다.Finally, in the state in which the phase change material 120 is solidified, the protective layer 130 is bonded onto the acid 111 (S7). In the protective layer 130 of the present invention, the phase change material includes a protective film layer 131 having an external separation prevention function or a conductive layer 133 composed of a metal material having excellent thermal conductivity on the protective film layer 131. It is characterized by.
요철구조를 이루는 필름(110) 및 상기 보호필름층(131)은 같은 물질을 사용하거나 동일한 물질을 사용하는 것이 유리하다. 즉, PE계열, PU계열, PP계열 및 PS계열의 필름 중 적어도 하나가 사용되거나 또는 그 중 하나 이상의 필름과 나일론필름이 2겹이상 합지하여 사용할 수 있고, 상기 요철 구조 필름의 산 상부에 고주파 또는 열융착 공정을 이용하여 접착시킬 수 있다. It is advantageous to use the same material or the same material for the film 110 and the protective film layer 131 forming the uneven structure. That is, at least one of the PE series, PU series, PP series and PS series films may be used, or one or more films and nylon films of two or more layers thereof may be laminated and used, and a high frequency or It can be adhered using a heat fusion process.
상기 보호필름층(131)은 상기 요철구조 필름(110)층 산(111) 상부에 고주파 또는 열융착 공정을 이용하여 접착시킨다. 필름의 성분이 열가소성 성분이므로 고체상태에서 열을 가하여 용융된 상태에서 압력을 가하면 두 개의 필름층이 쉽게 합착이 되며 상온에서 고체로 굳히면 별도의 접착제를 사용할 필요없이 단단하게 결합이 된다. The protective film layer 131 is bonded to the top of the uneven structure film 110 layer acid 111 using a high frequency or heat fusion process. Since the components of the film are thermoplastic components, when heat is applied in a molten state by applying heat in a solid state, the two film layers are easily bonded together, and when solidified at room temperature, they are firmly bonded without the need for a separate adhesive.
고주파를 이용하는 경우는 음파의 진동을 이용하여 프라스틱을 접착하는 방법으로 50/60Hz의 전원을 발진기(GEMERATOR)를 통하여 15KHz~20KHz(1sec)의 전기적인 에너지를 콘버터와 부스터를 통해 기계적인 진동에너지로 변환된 후 공구혼을 통하여 가공물에 전달되면 순간적으로 강력한 진동에 의한 마찰열을 발생시켜 가공물의 접합면이 용해 접착되어 분자적결합이 이루어진다 In case of using high frequency, it is a method of bonding plastic by using vibration of sound wave. The power of 50 / 60Hz is converted to mechanical vibration energy through converter and booster by supplying electric power of 50 / 60Hz through GEMERATOR. After being converted and transferred to the workpiece through the tool horn, it generates instantaneous frictional heat due to strong vibration, and the bonding surface of the workpiece is melted and bonded to form a molecular bond.
상기 접착된 보호필름층(131) 다른 면에는 외부의 열이 상변화물질(120)로 전도가 용이하게 하도록 전도층(133)으로 구성될 수 있다. 전도층(133)에 사용될 수 있는 금속물질은 알루미늄 합금 또는 구리합금 중 어느 하나로 구성될 수 있는 것을 특징으로 한다. 금속의 열전도율(W/m.℃X102)은 은(Ag) 4.12, 구리(Cu) 3.17, 알루미늄(Al) 1.95, 크롬(Cr) 0.96, 니켈(Ni) 0.84, 철(Fe) 0.79 정도 된다. On the other side of the bonded protective film layer 131 may be composed of a conductive layer 133 so that external heat is easily conducted to the phase change material 120. The metal material that may be used for the conductive layer 133 may be composed of any one of an aluminum alloy and a copper alloy. The thermal conductivity (W / m. ° C X 10 2 ) of the metal is about 4.12 silver (C), copper (Cu) 3.17, aluminum (Al) 1.95, chromium (Cr) 0.96, nickel (Ni) 0.84, and iron (Fe) 0.79. .
따라서 비용과 전도성을 고려할 때 구리와 알루미늄을 주원료로 다른 금속을 합금으로 사용하는 것이 타당하다. 상변화물질(120)의 사용용도에 따라 전도층(133)을 사용할 수도 있고 보호필름층(131)만 사용할 수도 있다. 예를 들면, 건축용자재, 냉장고용 판넬, 냉동탑차 등에 사용될 경우 함께 사용하는 자재를 고려할 때 외부 충격 보호를 위해서 어느 정도 강도가 있는 상기 전도성이 좋은 고분자 필름을 사용할 수 있고 쿨링(Cooling goods)에 사용할 경우는 상변화물질이 충진된 상태의 필름만 사용할 수 있다. Therefore, considering the cost and conductivity, it is reasonable to use copper and aluminum as the main raw materials and other metals as alloys. The conductive layer 133 may be used or the protective film layer 131 may be used depending on the use of the phase change material 120. For example, when used in building materials, refrigerator panels, refrigeration trucks, etc., the conductive polymer film having a certain strength may be used for external shock protection and may be used for cooling goods. In this case, only a film filled with a phase change material may be used.
도4는 상기 방법으로 완성된 상변화물질이 충진된 필름(100)의 단면도를 나타낸다. 필름은 요철구조로 가공이 되며 골내부(112a)에는 상변화물질(120)이 충진되고 충진된 상변화물질(120)을 환경오염이나 인체의 유해를 차단하기 위한 보호층(130)으로 산(111) 부분과 접착을 한다. 필름(110)의 성분과 유사한 보호필름(131)과 고주파 또는 열융착방법으로 접착을 하고 사용처에 따라 보호필름 외부면에 전도가 용이한 전도층(133)을 사용할 수도 있다. Figure 4 shows a cross-sectional view of the film 100 filled with a phase change material completed by the above method. The film is processed into a concave-convex structure and the bone inner portion 112a is filled with the phase change material 120 and the phase change material 120 filled with a protective layer 130 for blocking environmental pollution or harmful to the human body ( 111) Adhesion with parts. The conductive layer 133 may be bonded to the protective film 131 similar to the component of the film 110 by a high frequency or heat fusion method, and may be easily conductive on the outer surface of the protective film depending on the intended use.
뿐만 아니라, 요철필름(110)의 산 내부(111a)에는 충진재(150)을 함입하여 상변화물질(120)이 충진된 필름의 외부영향에 의한 구조적 취약성을 완화시킨다. 또한, 상기 충진재(150)이 산 내부(111a)에 밀착되어 이탈하지 않도록 기재층을 골(112)부분에 접착된 구성을 갖는다. In addition, by filling the filler 150 into the acid 111a of the uneven film 110 to mitigate structural weakness due to the external influence of the film filled with the phase change material 120. In addition, the filler 150 has a configuration in which the base material layer is adhered to the bone 112 so that the filler 150 is not in close contact with the acid 111a.
또한 본 발명은 상기 보호층을 합착하는 단계 이후 상기 기재층 하면에 단열층을 합착하는 단계로 추가 구성될 수 있는 PCM충진판넬 제조방법에 관한 발명이다.In another aspect, the present invention relates to a PCM filled panel manufacturing method that can be further configured to bond the heat insulating layer on the lower surface of the base layer after the bonding of the protective layer.
도 2는 본 발명인 PCM충진판넬 제조방법에 관한 순서도를 나타낸다. PCM충진판넬 제조방법은 상변화물질의 필름 충진 방법에 마지막 단계(S8)로 상기 기재층 하면에 단열층을 합착하는 단계가 추가 구성될 수 있다.Figure 2 shows a flow chart related to the PCM filling panel manufacturing method of the present invention. PCM filling panel manufacturing method may further comprise the step of bonding the heat insulating layer to the lower surface of the base layer in the final step (S8) to the film filling method of the phase change material.
이하 마지막 단계에 대해 추가 설명을 하면 상기 단열층(160)은 비용면을 고려해서 기포가 들어간 필름인 에어캡을 사용할 수 있다. 상기 에어캡은 형상은 2겹 이상의 폴리에틸렌(polyethylene) 필름을 포개어 그 사이에 공기의 거품을 가둔 것이다. 완충포장용에 사용되는 것 외에, 단열효과도가 있다. Hereinafter, the final step will be described further. The heat insulating layer 160 may use an air cap, which is a film containing bubbles in consideration of cost. The air cap is a shape of two or more layers of polyethylene (polyethylene) film is nested between the trapped air bubbles therebetween. In addition to being used for buffer packaging, there is also a heat insulating effect.
도5는 상기 방법으로 완성된 PCM충진판넬의 단면도를 나타낸다. 평면 필름(110)은 요철구조로 가공이 되며 골내부(112a)에는 상변화물질(120)이 충진되고 충진된 상변화물질(120)을 환경오염이나 인체의 유해를 차단하기 위해 보호필름층(131)으로 구성된 보호층(130)이 요철구조로 가공된 필름의 산(111) 부분과 접착되어 있다. 5 shows a cross-sectional view of a PCM filled panel completed by the above method. The flat film 110 is processed into a concave-convex structure and the bone inner portion 112a is filled with a phase change material 120 and filled with a phase change material 120 to prevent environmental pollution or harmful effects of a human body. A protective layer 130 composed of 131 is bonded to the acid 111 portion of the film processed into the uneven structure.
뿐만 아니라, 요철필름(110)의 산 내부(111a)에는 충진재(150)을 함입하여 상변화물질(120)이 충진된 필름의 외부영향에 의한 구조적 취약성을 완화시킨다. 또한, 상기 충진재(150)가 산내부(111a)에 밀착되어 이탈하지 않도록 기재층이 골(112)부분에 접착어 있으며, 상기 기재층 하면엔 외부와의 열의 흐름을 차단하는 단열층이 합착되어 있다. In addition, by filling the filler 150 into the acid 111a of the uneven film 110 to mitigate structural weakness due to the external influence of the film filled with the phase change material 120. In addition, the filler 150 is adhered to the valley 112 so that the filler 150 is not in close contact with the mountain 111a, and a heat insulating layer is bonded to the lower surface of the base layer to block the flow of heat to the outside. .
도6은 도5의 PCM충진판넬에서 보호층(130)이 복수로 구성된 즉, 보호필름층(131)과 전도층(133)으로 구성되어있다.6 is composed of a plurality of protective layers 130, that is, a protective film layer 131 and a conductive layer 133 in the PCM filling panel of FIG.
본 발명인 PCM충진판넬의 사용에 대한 일 예로 상기 PCM충전판넬은 건출 내장재로 주로 사용될 수 있으며, 사용시 보호층(130)이 실내공간을 향하고, 상기 단열층(160)은 외부벽면으로 향한다. As an example of the use of the PCM filling panel of the present invention, the PCM filling panel may be mainly used as a built-in drying material, the protective layer 130 to the indoor space when used, the heat insulating layer 160 toward the outer wall surface.
상기 보호층(130)은 열전도율이 좋은 물질로 구성되어 실내온도가 상변화물질의 융점보다 높게 올라갈 경우 실내열을 흡수하여 더 이상 실내온도가 상승되는 것을 막을 수 있다. The protective layer 130 is made of a material having a good thermal conductivity, so that when the room temperature rises higher than the melting point of the phase change material, the protection layer 130 may prevent the room temperature from increasing further.
즉, 상변화물질(PCM)의 융점이 25~27℃의 경우 여름철에 실내온도가 상기 온도를 초과시 실내의 열이 보호층(130)으로 전달되고 상변화물질(PCM)로 열이 전달 흡수하여 고체상에서 액체상으로 변화된다. 이때 흡수된 열로 인하여 실내온도의 상승을 막을 수 있다. That is, when the melting point of the phase change material (PCM) is 25 ~ 27 ℃ when the indoor temperature exceeds the temperature in the summer season, the heat of the room is transferred to the protective layer 130 and heat is transferred to the phase change material (PCM) and absorbed Change from solid to liquid phase. At this time, it is possible to prevent the increase in the room temperature due to the absorbed heat.
상기 단열층(160)의 역할은 상변화물질(PCM)로 향하는 열의 흐름을 보호층(130)을 통하게 하여 실내 열에너지와 교환을 집중시키기 위함이다. 단열층(160)이 없을 경우는 실외로부터 열의 이동으로 인한 상변화물질(PCM)과의 열에너지 교환으로 실내 열에너지의 교환 기능이 떨어질 수 있기 때문이다.The role of the heat insulation layer 160 is to concentrate the heat exchange with the indoor heat energy by passing the heat flow toward the phase change material (PCM) through the protective layer 130. If the insulating layer 160 is absent because the exchange function of the indoor heat energy due to the heat energy exchange with the phase change material (PCM) due to the movement of heat from the outside can be reduced.
또한 본 발명인 PCM충진판넬은 상기 건축용 자재 이외에도 다양한 융점온도를 갖는 상변화물질(PCM)를 사용할 수 있으며, 냉장고용 판넬, 냉동탑차 단열충진재, 난방용 판넬, 항온 용기, 쿨링 제품(Cooling goods)등 잠열을 이용한 모든 제품에 사용될 수 있다. 따라서 융점 5~70℃ 갖는 상변화물질 중에서 사용 용도에 맞는 융점온도의 상변화물질을 선택해서 사용하면 된다. In addition, the PCM filling panel of the present invention can use a phase change material (PCM) having a variety of melting point temperature in addition to the building material, and a latent heat such as a panel for a refrigerator, a refrigeration tower insulation filler, a heating panel, a constant temperature container, a cooling product (Cooling goods) Can be used for all products using Therefore, a phase change material having a melting point temperature suitable for the intended use may be selected and used among phase change materials having a melting point of 5 to 70 ° C.
이상에서 설명한 본 발명은 전술한 실시예 및 첨부된 도면에 의해 한정되는 것이 아니고, 본 발명의 기술적 사상을 벗어나지 않는 범위 내에서 여러 가지 치환, 변형 및 변경이 가능함은 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자에게 있어서 명백할 것이다.The present invention described above is not limited to the above-described embodiment and the accompanying drawings, and various substitutions, modifications, and changes are possible within the scope without departing from the technical spirit of the present invention. It will be evident to those who have knowledge of.

Claims (21)

  1. 필름 충진 방법에 있어서,In the film filling method,
    일정한 두께의 평면 필름을 준비하는 단계;Preparing a flat film of constant thickness;
    상기 평면 필름을 가공하여 복수의 산과 골로 특징되는 요철구조를 만드는 단계;Processing the flat film to form an uneven structure characterized by a plurality of acids and valleys;
    상기 요철구조 산 내부에 충진재를 충진하는 단계;Filling a filler into the uneven structure acid;
    상기 충진재를 충진 후 골 하부에 기재층을 합착하는 단계;Bonding the base layer to the lower part of the bone after filling the filler;
    상기 요철구조의 골 내부에 상변화물질을 충진하는 단계;Filling a phase change material in the bone of the uneven structure;
    상기 상변화물질이 충진된 요철구조의 필름을 냉각장치를 이용해 상변화물질을 고체화시키는 단계 및Solidifying the phase change material by using a cooling device on the film having the uneven structure filled with the phase change material, and
    상기 상변화물질이 고체화된 상태에서 산 상부에 보호층을 합착하는 단계로 구성될 수 있는 상변화물질의 필름 충진 방법.A method of filling a film of phase change material, which may include the step of adhering a protective layer on top of an acid while the phase change material is solidified.
  2. 제1항에 있어서,The method of claim 1,
    상기 충진재는 상기 요철구조 필름의 형태유지와 내열, 방염 및 탄성의 특징이 있는 물질인 것을 특징으로 하는 상변화물질의 필름 충진 방법. The filler is a film filling method of the phase change material, characterized in that the shape of the concave-convex structure film and the material characterized by heat resistance, flame retardant and elasticity.
  3. 제1항에 있어서,The method of claim 1,
    상기 기재층은 상기 요철구조의 필름의 구조적인 지지대역할을 할 수 있는 합성수지필름류, 금속류, 금속합금류, 석재류 및 목재류 중 적어도 어느 하나로 구성될 수 있는 것을 특징으로 하는 상변화물질의 필름 충진 방법. The base layer may be formed of at least one of synthetic resin films, metals, metal alloys, stones and wood, which may serve as structural support bands of the uneven structure film. .
  4. 제1항에 있어서,The method of claim 1,
    상기 상변화물질은 유기화합물 계열, 무기화합물 계열 또는 공융화합물 계열 중 어느 하나로 구성될 수 있는 것을 특징으로 하는 상변화물질의 필름 충진 방법. The method of filling a phase change material, characterized in that the phase change material may be composed of any one of organic compound series, inorganic compound series or eutectic compound series.
  5. 제1항에 있어서,The method of claim 1,
    상기 필름층은 PE계열, PU계열, PP계열 및 PS계열의 필름 중 적어도 어느 하나 이상이 사용되거나 또는 그 중 적어도 어느 하나 이상의 필름과 나일론필름이 2겹 이상 합지되어 형성되는 것을 특징으로 하는 상변화물질의 필름 충진 방법. The film layer is a phase change characterized in that at least one or more of the PE series, PU series, PP series and PS series films are used, or at least any one or more of these films and a nylon film are laminated. Method of film filling of materials.
  6. 제1항에 있어서,The method of claim 1,
    상기 보호층은 상기 상변화물질이 외부 이탈 방지 기능의 보호필름층 또는 상기 보호필름층에 열전도가 뛰어난 금속물질로 구성되는 전도층이 적층된 것을 특징으로 하는 상변화물질의 필름 충진 방법. The protective layer is a film filling method of a phase change material, characterized in that the phase change material is laminated with a protective film layer having an external separation prevention function or a conductive layer made of a metal material having excellent thermal conductivity on the protective film layer.
  7. 제6항에 있어서,The method of claim 6,
    상기 전도층은 연전도율이 우수한 은, 구리, 알루미늄, 크롬, 니켈 및 철 중 적어도 어느 하나의 금속물질로 구성되는 것을 특징으로 하는 상변화물질의 필름 충진 방법. The conductive layer is a film filling method of a phase change material, characterized in that composed of at least one metal material of silver, copper, aluminum, chromium, nickel and iron excellent in the conductivity.
  8. 제6항에 있어서,The method of claim 6,
    상기 보호필름층은 PE계열, PU계열, PP계열 및 PS계열의 필름 중 적어도 하나가 사용되거나 또는 그 중 하나 이상의 필름과 나일론필름이 2겹이상 합지되어 사용될 수 있는 것에 특징이 있는 상변화물질의 필름 충진 방법. The protective film layer is a phase change material characterized in that at least one of the PE series, PU series, PP series and PS series films may be used, or one or more of them may be used by laminating two or more layers of the nylon film. Film filling method.
  9. 상기 제1항 내지 제8항 중 어느 한 항에 의해 제조될 수 있는 상변화물질이 충진된 필름.The film filled with a phase change material that can be prepared by any one of claims 1 to 8.
  10. 제9항에 있어서,The method of claim 9,
    상기 상변화물질이 충진된 필름은 건축용 자재, 냉장고용 판넬, 냉동탑차 단열충진재, 난방용 판넬, 항온 용기, 쿨링 제품(Cooling goods) 또는 기능성 섬유제품등 잠열을 이용한 모든 제품을 만드는데 사용될 수 있는 것을 특징으로 하는 상변화물질이 충진된 필름. The film filled with the phase change material can be used to make all the products using latent heat, such as building materials, refrigerator panels, refrigeration tower insulation filler, heating panels, constant temperature containers, cooling goods or functional textile products. Film filled with phase change material.
  11. 제1항에 있어서,The method of claim 1,
    상기 보호층을 합착하는 단계 이후 상기 기재층 하면에 단열층을 합착하는 단계를 추가 구성될 수 있는 PCM충진판넬 제조방법.After the step of bonding the protective layer PCM filling panel manufacturing method which can be further configured to bond the heat insulating layer on the lower surface of the base layer.
  12. 제11항에 있어서, The method of claim 11,
    상기 보호층은 보호필름층 또는 상기 보호필름층 상면에 전도층이 적층된 것중 어느 하나로 구성된 것에 특징이 있는 PCM충진판넬 제조방법.The protective layer is a PCM filled panel manufacturing method characterized in that the protective film layer or any one of the conductive layer is laminated on the protective film layer.
  13. 제12항에 있어서,The method of claim 12,
    상기 전도층은 연전도율이 우수한 은, 구리, 알루미늄, 크롬, 니켈 및 철 중 적어도 어느 하나의 금속물질로 구성되는 것을 특징으로 하는 PCM충진판넬 제조방법.The conductive layer is a PCM filled panel manufacturing method, characterized in that composed of at least one metal material of silver, copper, aluminum, chromium, nickel and iron excellent in electrical conductivity.
  14. 제12항에 있어서,The method of claim 12,
    상기 보호필름층은 PE계열, PU계열, PP계열 및 PS계열의 필름 중 적어도 하나가 사용되거나 또는 그 중 하나 이상의 필름과 나일론필름이 2겹이상 합지되고,The protective film layer is at least one of a PE series, PU series, PP series and PS series of the film is used or at least one film and nylon film of two or more laminated,
    상기 요철 구조 필름의 산 상부에 고주파 또는 열융착 공정을 이용하여 접착시키는 것을 특징으로 하는 PCM충진판넬 제조방법.PCM filled panel manufacturing method characterized in that the adhesion on the top of the acid structure of the uneven structure film using a high frequency or heat welding process.
  15. 제11항에 있어서,The method of claim 11,
    상기 충진재는 내열, 방염 및 탄성의 특징이 있는 물질이며 상기 요철구조 필름의 형태유지의 위한 내충격성이 있는 것에 특징이 있는 PCM충진판넬 제조방법.The filler is a material characterized by heat, flame retardant and elasticity and the PCM filler panel manufacturing method characterized in that the impact resistance for maintaining the shape of the uneven structure film.
  16. 제11항에 있어서,The method of claim 11,
    상기 기재층은 상기 요철구조의 필름의 구조적인 지지대역할을 할 수 있는 합성수지필름류, 금속류, 금속합금류, 석재류 및 목재류 중 적어도 어느 하나로 구성될 수 있는 것을 특징으로 하는 PCM충진판넬 제조방법.The base layer may be made of at least one of synthetic resin film, metals, metal alloys, stone and wood that can be a structural support band of the uneven structure film PCM filling panel manufacturing method.
  17. 제11항에 있어서,The method of claim 11,
    상기 상변화물질은 유기화합물 계열, 무기화합물 계열 또는 공융화합물 계열 중 어느 하나로 구성될 수 있고, 융점이 5~70℃ 것을 특징으로 하는 PCM충진판넬 제조방법.The phase change material may be composed of any one of organic compound series, inorganic compound series or eutectic compound series, melting point 5 ~ 70 ℃ PCM filler panel manufacturing method characterized in that.
  18. 제11항에 있어서,The method of claim 11,
    상기 평면 필름은 PE계열, PU계열, PP계열 및 PS계열의 필름 중 적어도 어느 하나 이상이 사용되거나 또는 그 중 적어도 어느 하나 이상의 필름과 나일론필름이 2겹 이상 합지되어 형성되는 것을 특징으로 하는 PCM충진판넬 제조방법.The flat film is PCM filled, characterized in that at least one or more of the PE series, PU series, PP series and PS series of films are used, or at least any one or more of these films and nylon films are laminated. Panel manufacturing method.
  19. 제11항에 있어서,The method of claim 11,
    상기 단열층은 기포가 들어간 필름인 에어캡인 것을 특징으로 하는 PCM충진판넬 제조방법.The insulating layer is a PCM filling panel manufacturing method characterized in that the air cap is a film containing the bubble.
  20. 상기 제11항 내지 제19항 중 어느 한 항에 의해 제조될 수 있는 PCM충진판넬.PCM filled panel which can be prepared by any one of claims 11 to 19.
  21. 제20항에 있어서,The method of claim 20,
    상기 PCM충진판넬은 건축용 자재, 냉장고용 판넬, 냉동탑차 단열충진재, 난방용 판넬, 항온 용기 또는 쿨링 제품(Cooling goods)등 잠열을 이용한 모든 제품을 만드는데 사용될 수 있는 것을 특징으로 하는 PCM충진판넬.The PCM filling panel is a PCM filling panel, which can be used to make all products using latent heat, such as building materials, refrigerator panels, refrigeration tower insulation filler, heating panels, constant temperature containers or cooling goods (Cooling goods).
PCT/KR2016/004316 2015-06-03 2016-04-26 Method for filling film of phase change material, and film and phase change material filling panel manufactured thereby WO2016195245A1 (en)

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KR1020150078751A KR101765300B1 (en) 2015-06-03 2015-06-03 Film Filling Method Of The Phase Change Material And The Film Manufactured Thereby
KR10-2015-0078751 2015-06-03
KR1020160038296A KR101830164B1 (en) 2016-03-30 2016-03-30 The Method Of A PCM-filled Panel Attached To A Heat Insulating Layer And The PCM-filled Panel Prepared By The Method
KR10-2016-0038296 2016-03-30

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