CN206983414U - A kind of insulation flame-retardant board - Google Patents

A kind of insulation flame-retardant board Download PDF

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CN206983414U
CN206983414U CN201720761777.9U CN201720761777U CN206983414U CN 206983414 U CN206983414 U CN 206983414U CN 201720761777 U CN201720761777 U CN 201720761777U CN 206983414 U CN206983414 U CN 206983414U
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heat
layer
insulation
flame
retardant
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高彦峰
赵起
卢健
危韦
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00Adapting or protecting infrastructure or their operation
    • Y02A30/24Structural elements or technologies for improving thermal insulation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B80/00Architectural or constructional elements improving the thermal performance of buildings
    • Y02B80/10Insulation, e.g. vacuum or aerogel insulation

Abstract

The utility model is related to a kind of insulation flame-retardant board, including heat-insulation layer, and set gradually from the inside to surface in the heat-insulation layer upper and lower surface flame-retardant layer, high-temperature-resistant layer, have heat reflection effect flexible support layers.The utility model is using aeroge as heat insulation core material; with flame-retardant layer covering and heat insulating core; on the basis of the original insulation of heat insulation core material and mechanical performance is not damaged; substantially increase fire retardancy; aeroge heat-insulation layer is effectively protected, and heat-reflecting layer is coated with outermost layer, substantially increases radiation efficiency; so as to be scattered and disappeared from three kinds of heat radiation, heat transfer, thermal convection current approach trap heats, there is excellent heat-proof quality.

Description

A kind of insulation flame-retardant board
Technical field
It the utility model is related to heat-insulating fireproof material preparation field, more particularly to a kind of insulation flame-retardant board.
Background technology
In recent years, global energy crisis makes society propose new active demand to heat-insulating heat-preserving material.In high temperature insulating The field such as field, industry, building, traffic, fire-fighting, active demand is it is also proposed to high temperature resistant heat insulation material.Aeroge is as one Kind high-performance insulation material arises at the historic moment, and this is a kind of flexibility or rigidity for meeting temperature use range at -200 DEG C~400 DEG C High-performance heat-insulating heat-preserving material.The size of the material mesopore can effectively suppress cross-ventilation heat transfer and solid in nanometer scale Phase heat transfer, its thermal conductivity even it is also lower than air, there is splendid heat-insulating property, aerospace craft thermal protection system, The field such as military thermal cell and heating power, chemical industry, metallurgy, fire-fighting all has broad application prospects.But its material typically has Following shortcoming:1st, blocking radiant heat is inefficient 2, poor fire, easily causes fire, causes application field few.And it is current, mainly Reach flame retardant effect by increasing fire retardant in insulation material, but with the addition of fire retardant, aeroge insulation material Mechanical strength can be reduced gradually, while its thermal conductivity factor can gradually increase, and its heat-insulating property can be reduced gradually.
CN101469804A discloses a kind of novel vacuum insulation plate and preparation method, and the patent uses temperature-resistance thermal-insulation undulation degree Material is used as core, and silica aerogel powder is encapsulated in core, and outer packing is formed compound using aluminium foil and plastic film layers compacting Material.But the utility model poor fire, fire is easily caused, and aluminium foil heat transfer is preferable, heat transfer is very fast, causes effect of heat insulation to drop It is low.
CN106244172A discloses a kind of preparation of the fire-retardant aerosil of Halogen synergistic, and the patent is by fire retardant Mixed with aeroge.Fire retardant is mixed into aeroge by the utility model, aeroge performance itself be able to can be had an impact and Lack heat-reflecting layer, can not be lost from heat radiation approach trap heat.
Utility model content
In view of the above-mentioned problems, the purpose of this utility model is to provide a kind of fire-retardant, high reflectivity and does not influence insulation New aerogel heat-proof flame-retardant board.
On the one hand, the utility model provides a kind of insulation flame-retardant board, including heat-insulation layer, and in the heat-insulation layer Flame-retardant layer that upper and lower surface is set gradually from the inside to surface, high-temperature-resistant layer, the flexible support layers with heat reflection effect.
It is preferred that the flame-retardant layer is the thermosetting polymer containing fire retardant;
In terms of parts by weight, the flame-retardant layer includes:80~120 parts of thermosetting polymer, 10~80 parts of curing agent, 10 ~30 parts of fire retardants, 5~20 portions of synergist.
The utility model scatters and disappears from three kinds of heat radiation, heat transfer, thermal convection current approach trap heats, has excellent thermal insulation Can, and on the basis of the original insulation of heat insulation core material and mechanical performance is not damaged, increase one layer of flame-retardant layer.The flame-retardant layer is Thermosetting polymer containing fire retardant, even to be coated on heat insulation core material, curing rate is fast.Because flame-retardant layer also causes containing fire retardant It has stronger anti-flammability, can also substantially increase the fire retardancy of insulation flame-retardant board, be effectively protected airsetting Glue heat-insulation layer.
It is preferred that the thermosetting polymer is at least one of epoxy resin, phenolic resin and unsaturated polyester (UP);Institute Fire retardant is stated as at least one of chemical fire retardant, packing type fire retardant and expansion type flame retardant, preferably APP, first Base dimethyl phosphonate and at least one of melamine and its salt.
It is preferred that the curing agent be diethylenetriamine, trimethylhexamethylenediamine and Versamid in extremely Few one kind, the synergist are at least one of aluminium hydroxide, pentaerythrite.
It is preferred that the thickness of the flame-retardant layer is 0.1~2cm, preferably 0.5~2cm.
Also, it is preferred that the material of the heat-insulation layer includes glass fibre and/or aeroge, the thickness of the heat-insulation layer is 0.5~2cm.
It is preferred that the high-temperature-resistant layer is the high-temperature resistant membrane bag made of polyimides PI, thickness is 200~800 μm.
It is preferred that the flexible support layers are the polyethylene terephthalate film that at least outer surface is coated with metallic film, The metallic film is one kind in silver, aluminium, nickel and copper.
Also, it is preferred that the thickness of the polyethylene terephthalate film be 12~200 μm, the thickness of the metallic film Spend for 10~300nm.
It is preferred that the insulation flame-retardant board also includes the periphery positioned at the heat-insulation layer and for separating two sheets of flexible The edge cold-prevention bridge structure of supporting layer.
The advantages of the utility model:High heat-reflecting layer blocking radiant heat, heat-insulation layer aeroge thermal conductivity factor 0.01~ 0.05W/ (mK), heat transfer is obstructed, both substantially increase heat-insulation and heat-preservation ability at collaboration.High-temperature-resistant layer polyimides is thin simultaneously Film bag high temperature resistant is up to 400 DEG C, 0.1~0.35W/mK of thermal conductivity factor, and it is good to add the ethoxyline resin antiflaming of fire retardant, heat conduction system Number is low, and curing rate is fast, effectively protects heat-insulation layer.The utility model is simple in construction, easily fabricated, is easy to use, cost is low It is honest and clean, it can be widely used in incubator, the exterior wall of building, interior decoration, transportation and communication, ship etc..The utility model Using aeroge as heat insulation core material, with flame-retardant layer covering and heat insulating core, the original insulation of heat insulation core material and mechanical performance are not being damaged On the basis of, fire retardancy is substantially increased, is effectively protected aeroge heat-insulation layer, and heat reflection is coated with outermost layer Layer, substantially increases radiation efficiency, so as to be scattered and disappeared from three kinds of heat radiation, heat transfer, thermal convection current approach trap heats, has excellent Different heat-proof quality.
Brief description of the drawings
Fig. 1 is the fire-retardant plate structure schematic diagram of insulation;
Fig. 2 inserts insulation flame-retardant board in six folder surface layers of double-deck polypropylene plastic box the incubator formed;
Fig. 3 is the temperature curve of the low-temperature receiver thermal and insulating performance test of incubator prepared by the utility model embodiment 1-3 Figure;
The temperature profile of the thermal source thermal and insulating performance test of incubator prepared by Fig. 4 the utility model embodiments 1-3.
Embodiment
The utility model is further illustrated below by way of following embodiments, it should be appreciated that following embodiments are only used for Bright the utility model, and unrestricted the utility model.
Insulation flame-retardant board described in the utility model, including heat reflection supporting layer (have the flexibility of heat reflection effect Supporting layer), high-temperature-resistant layer, flame-retardant layer and heat-insulation layer.Its structure can as described in Figure 1, and middle is heat-insulation layer 1,2 even painting of flame-retardant layer 1 on heat-insulation layer, the overall covering flame-retardant layer 2 of high-temperature-resistant layer 3, outermost layer is heat reflection supporting layer 4.The flame-retardant layer 2 hinders for addition The thermosetting polymer solidification of combustion agent forms.Heat-insulation layer 1 vacuumizes, and carries out briquetting processing.Heat reflection supporting layer 4 can be one Layer, or multilayer.In addition, the insulation flame-retardant board also includes the periphery positioned at the heat-insulation layer and for separating two The edge cold-prevention bridge structure of layer flexible support layers.The material of the edge cold-prevention bridge structure is clay class mineral, thickness can be 5~ 30mm.The clay class mineral can be at least one of sepiolite, kaolin, diatomite and concave convex rod.
The heat reflection supporting layer can be PET (PET) film, can be coated with aluminium on film, silver, copper, nickel or Person and its alloy etc..The thickness of PET (PET) film is about 12-200 μm.The aluminium, silver, copper, nickel or Person and its alloy are attached on PET (PET) film, thickness 10-300nm.The heat reflectivity of heat-reflecting layer >=80%.
Described flame-retardant layer can be the thermosetting polymer of addition fire retardant.The fire retardant added be chemical fire retardant, At least one of packing type fire retardant and expansion type flame retardant, it is preferable that APP, methylphosphonic acid two can be selected in fire retardant Methyl esters and at least one of melamine and its salt.The thermosetting polymer includes but is not limited to epoxy resin, phenolic aldehyde tree Fat, unsaturated polyester (UP).0.1~2cm of the flame-retardant layer thickness.
Described heat-insulation layer can be the aeroge of briquet.The specific surface area 100-1600m of aeroge2/ g, porosity 80%~99.8%, 0.01~0.05W/ of thermal conductivity (mK).Optional aeroge includes but is not limited to SiO2Aeroge, ZrO2 Gel, Al2O3Aeroge, charcoal-aero gel.
Described high-temperature-resistant layer can be the high-temperature resistant membrane bag made of PI (polyimides), and thickness is 200~800 μm, High temperature resistant is up to 400 DEG C.
Illustrate to following exemplary the preparation method of insulation flame-retardant board provided by the utility model.
Vacuumize process, and briquet are carried out to heat-insulation layer.Specifically, by insulation layer material (for example, aeroge Deng) vacuumize process is carried out, sealing is pressed into plate, 0.5~2cm of thickness.The pressure of the compacting is 5~80MPa.The guarantor Warm layer material is preferably aeroge, its specific surface area 100-1600m2/ g, porosity 80%~99.8%, thermal conductivity 0.01~ 0.05W/(m·K).Optional aeroge includes but is not limited to SiO2Aeroge, ZrO2Gel, Al2O3Aeroge, charcoal-aero gel.
The thermosetting polymer of added fire retardant is uniformly coated on heat-insulation layer, after solidification, forms flame-retardant layer.Specifically For, the thermosetting polymer for adding fire retardant is evenly coated in the aeroge surface for being molded and finishing, after to be solidified, aeroge Surface forms one layer of flame-retardant layer.Flame-retardant layer 0.1~2cm of thickness, preferably 0.5~2cm.The wherein preparation method of flame-retardant layer:80~ 120 parts of thermosetting polymer, 10~80 parts of curing agent, 10~30 parts of fire retardants, 5~20 portions of synergist, mixing speed 300~ 1500r/min, 1~5h of mixing time, 30~120 DEG C of solidification temperature.The addition of fire retardant is very few, and fire resistance can not reach Respective standard;The addition of fire retardant is excessive, can influence the original mechanical performance of thermosetting polymer, and adding with fire retardant Dosage increases, and the lifting of fire resistance tends towards stability, or even deteriorates, and unnecessary cost burden is brought to industrial production. So the addition of fire retardant should science, appropriateness, it is and also otherwise varied for different flame-retardant systems, addition.This practicality It is new using chemically expansible system and organic and inorganic synergistic flame-retardant system, fire retardant addition is respectively 10%~30%, 20%~30%.
The high-temperature resistant membrane bag made of PI (polyimides), thickness are 200~800 μm, and sample is put into bag, are carried out Vacuumize process, vacuum≤0.3MPa.
By aluminium, silver, copper, nickel or and its Alloy Plating on PET (PET) film, thickness 10- 300nm, 12-200 μm of PET film thickness, reflectivity >=80%.
Reflectivity PET (PET) film is bonded in the high-temperature resistant membrane made of PI (polyimides) On bag, overall covering.
Embodiment is enumerated further below to describe the utility model in detail.It will similarly be understood that following examples are served only for The utility model is further described, it is impossible to be interpreted as the limitation to scope of protection of the utility model, the technology of this area Some nonessential modifications and adaptations that personnel make according to the above of the present utility model belong to guarantor of the present utility model Protect scope.Following specific technological parameters of example etc. are also only an examples in OK range, i.e. those skilled in the art can Done in suitable scope and selected with the explanation by this paper, and do not really want to be defined in the concrete numerical value of hereafter example.
Embodiment 1
Flame-retardant layer component proportion:100 parts of epoxy resin, 10 parts of diethylenetriamines, 20 parts of pentaerythrites, 20 parts of melamines Amine cyanuric acid, mixing speed 400r/min, mixing time 2h, 100 DEG C of solidification temperature, hardening time 30min;
12.7mm × 12.7 × 3mm is made in flame-retardant layer sample, UL94V-0 is obtained through fire proofing standard UL94-1985 Grade;
Flame-retardant layer sample is made for 100mm × 6.5mm × 3mm, carried out according to ASTM D2863 steps, LOI (limit oxygen Index) it is 29.7%, as shown in table 1.
Heat reflection aeroge insulation flame-retardant board preparation method:
(1) by SiO2Aeroge carries out vacuumize process, sealing, is pressed into plate, thickness 1.2cm.The pressure of the compacting For 20MPa.Wherein described SiO2Aeroge specific surface area 1200m2/ g, porosity 95%, thermal conductivity 0.01W/ (mK);
(2) epoxy resin for adding pentaerythrite and melamine cyanurate is evenly coated in the SiO for being molded and finishing2Airsetting Glue surface, after to be solidified, aeroge surface forms one layer of flame-retardant layer;Flame-retardant layer thickness 0.5cm;
(3) the high-temperature resistant membrane bag made of PI (polyimides), film thickness are 300 μm, and high temperature resistant is up to 400 DEG C; Carry out vacuumize process, vacuum 0.2MPa;
(4) PET to aluminize (PET) film is bonded in high-temperature resistant membrane bag surface, aluminium film thickness 100nm, 100 μm of PET film thickness, reflectivity 97%.
Further, intuitively to embody thermal and insulating performance of the present utility model, the insulation flame-retardant board prepared is inserted In six face interlayers for entering the double-deck polypropylene plastic box that inwall is 37.8cm*28.8cm*32.8cm, as shown in Figure 2.By 6kg Refrigerant be put into, loading about 1/3, ensure container sealing, ambient temperature be 23 degrees Celsius, test refrigerant temperature with Time change, performance curve are as shown in Figure 3;Same method of testing, same test condition, 6kg thermals source are put into, loading About 1/3, test heat source temperature changes with time.Performance curve is as shown in Figure 4.
Embodiment 2
Flame-retardant layer component proportion:100 parts of epoxy resin, 20 parts of trimethylhexamethylenediamines, methyl-phosphoric acid dimethyl ester 20 parts, 10 parts of aluminium hydroxides, mixing speed 500r/min, mixing time 2h, 80 DEG C of solidification temperature, hardening time 1h;
12.7mm × 12.7 × 3mm is made in flame-retardant layer sample, UL94V-0 is obtained through fire proofing standard UL94-1985 Grade;
Flame-retardant layer sample is made for 100mm × 6.5mm × 3mm, carried out according to ASTM D2863 steps, LOI (limit oxygen Index) it is 28.9%, as shown in table 1.
Heat reflection aeroge insulation flame-retardant board preparation method:
(1) by ZrO2Aeroge carries out vacuumize process, sealing, is pressed into plate, thickness 1cm.The pressure of the compacting is 30MPa.Wherein described SiO2Aeroge specific surface area 900m2/ g, porosity 96%, thermal conductivity 0.013W/ (mK);
(2) epoxy resin for adding methyl-phosphoric acid dimethyl ester and aluminium hydroxide is evenly coated in the ZrO for being molded and finishing2Airsetting Glue surface, after to be solidified, aeroge surface forms one layer of flame-retardant layer.Flame-retardant layer thickness 0.6cm;
(3) the high-temperature resistant membrane bag made of PI (polyimides), film thickness are 400 μm, and high temperature resistant is up to 400 DEG C. Carry out vacuumize process, vacuum≤0.1MPa;
(4) PET to aluminize (PET) film is bonded in high-temperature resistant membrane bag surface.Aluminium film thickness 90nm, 110 μm of PET film thickness, reflectivity 98%.
Further, intuitively to embody thermal and insulating performance of the present utility model, the insulation flame-retardant board prepared is inserted In six face interlayers for entering the double-deck polypropylene plastic box that inwall is 37.8cm*28.8cm*32.8cm, as shown in Figure 2.By 6kg Refrigerant be put into, loading about 1/3, ensure container sealing, ambient temperature be 23 degrees Celsius, test refrigerant temperature with Time change, performance curve are as shown in Figure 3;Same method of testing, same test condition, 6kg thermals source are put into, loading About 1/3, test heat source temperature changes with time.Performance curve is as shown in Figure 4.
Embodiment 3
Flame-retardant layer component proportion:100 parts of epoxy resin, 80 parts of Versamids, 30 parts of APPs, 10 parts of seasons penta Tetrol, mixing speed 600r/min, mixing time 3h, 70 DEG C of solidification temperature, hardening time 2h;
12.7mm × 12.7 × 3mm is made in flame-retardant layer sample, UL94V-0 is obtained through fire proofing standard UL94-1985 Grade;
Flame-retardant layer sample is made for 100mm × 6.5mm × 3mm, carried out according to ASTM D2863 steps, LOI (limit oxygen Index) it is 29.3%, as shown in table 1.
Heat reflection aeroge insulation flame-retardant board preparation method:
(1) by Al2O3Aeroge carries out vacuumize process, sealing, is pressed into plate, thickness 1.5cm.The pressure of the compacting For 25MPa.Wherein described Al2O3Aeroge specific surface area 450m2/ g, porosity 98%, thermal conductivity 0.029W/ (mK);
(2) epoxy resin for adding APP and pentaerythrite is evenly coated in the Al for being molded and finishing2O3Aeroge table Face, after to be solidified, aeroge surface forms one layer of flame-retardant layer.Flame-retardant layer thickness 0.5cm;
(3) the high-temperature resistant membrane bag made of PI (polyimides), film thickness are 500 μm, and high temperature resistant is up to 400 DEG C. Carry out vacuumize process, vacuum 0.3MPa;
(4) PET to aluminize (PET) film is bonded in high-temperature-resistant layer surface.Aluminium film thickness 150nm, 120 μm of PET film thickness, reflectivity 97%.
Further, intuitively to embody thermal and insulating performance of the present utility model, the insulation flame-retardant board prepared is inserted In six face interlayers for entering the double-deck polypropylene plastic box that inwall is 37.8cm*28.8cm*32.8cm, as shown in Figure 2.By 6kg Refrigerant be put into, loading about 1/3, ensure container sealing, ambient temperature be 23 degrees Celsius, test refrigerant temperature with Time change, performance curve are as shown in Figure 3;Same method of testing, same test condition, 6kg thermals source are put into, loading About 1/3, test heat source temperature changes with time.Performance curve is as shown in Figure 4.
Table 1 is the flame-retardant layer performance test of insulation flame-retardant board prepared by 1-3 of the embodiment of the present invention
Bright combustion time t for the first time1 Second of bright combustion time t2 UL94 grades are determined Limited oxygen index LOI
Example 1 0.9s 1.1s V0 29.7%
Example 2 2s 2.8s V0 28.9%
Example 3 1.4s 1.9s V0 29.3%
.Wherein, 12.7mm × 12.7 × 12.7mm is made in flame-retardant layer sample prepared by embodiment 1-3, through fire proofing Standard UL94-1985 obtains UL94V rankings.Flame-retardant layer sample prepared by embodiment 1-3 is made for 100mm × 6.5mm × 3mm, carried out according to ASTM D2863 steps, obtain LOI (limited oxygen index).
For above-described embodiment only to illustrate technical concepts and features of the present utility model, its object is to allow be familiar with technique Personage can understand content of the present utility model and be carried out, the scope of protection of the utility model can not be limited with this, All equivalent change or modifications made according to the utility model Spirit Essence, should all cover in the scope of protection of the utility model It is interior.

Claims (7)

  1. A kind of 1. insulation flame-retardant board, it is characterised in that including heat-insulation layer, and the heat-insulation layer upper and lower surface from it is inner to The flame-retardant layer that sets gradually outside, high-temperature-resistant layer, the flexible support layers with heat reflection effect.
  2. 2. insulation flame-retardant board according to claim 1, it is characterised in that the thickness of the flame-retardant layer be 0.1~ 2cm。
  3. 3. insulation flame-retardant board according to claim 2, it is characterised in that the thickness of the flame-retardant layer is 0.5~2 cm。
  4. 4. insulation flame-retardant board according to claim 1, it is characterised in that the thickness of the heat-insulation layer be 0.5~ 2cm。
  5. 5. insulation flame-retardant board according to claim 1, it is characterised in that the high-temperature-resistant layer is by polyimides PI Manufactured high-temperature resistant membrane bag, thickness are 200~800 μm.
  6. 6. insulation flame-retardant board according to claim 1, it is characterised in that the flexible support layers are at least outer surface The polyethylene terephthalate film of metallic film is coated with, the metallic film is one kind in the silver, aluminium, nickel and copper;Institute The thickness for stating polyethylene terephthalate film is 12~200 μm, and the thickness of the metallic film is 10~300 nm.
  7. 7. insulation flame-retardant board according to claim 1, it is characterised in that the insulation flame-retardant board also includes position In the heat-insulation layer periphery and for separating the edge cold-prevention bridge structure of two sheets of flexible supporting layer.
CN201720761777.9U 2017-06-28 2017-06-28 A kind of insulation flame-retardant board Active CN206983414U (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107215035A (en) * 2017-06-28 2017-09-29 高彦峰 A kind of insulation flame-retardant board
CN112726861A (en) * 2020-12-28 2021-04-30 付燕燕 Ultra-thin aerogel heat preservation fire-retardant piece that insulates against heat
CN114516202A (en) * 2022-02-23 2022-05-20 河南爱彼爱和新材料有限公司 Aerogel heat insulation core material and high-performance aerogel composite heat insulation pad

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107215035A (en) * 2017-06-28 2017-09-29 高彦峰 A kind of insulation flame-retardant board
CN112726861A (en) * 2020-12-28 2021-04-30 付燕燕 Ultra-thin aerogel heat preservation fire-retardant piece that insulates against heat
CN114516202A (en) * 2022-02-23 2022-05-20 河南爱彼爱和新材料有限公司 Aerogel heat insulation core material and high-performance aerogel composite heat insulation pad

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