WO2016170000A1 - Procédé de décomposition thermochimique de déchets - Google Patents

Procédé de décomposition thermochimique de déchets Download PDF

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Publication number
WO2016170000A1
WO2016170000A1 PCT/EP2016/058784 EP2016058784W WO2016170000A1 WO 2016170000 A1 WO2016170000 A1 WO 2016170000A1 EP 2016058784 W EP2016058784 W EP 2016058784W WO 2016170000 A1 WO2016170000 A1 WO 2016170000A1
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WO
WIPO (PCT)
Prior art keywords
alkenyl
alkyl
independently selected
optionally substituted
waste
Prior art date
Application number
PCT/EP2016/058784
Other languages
English (en)
Inventor
Pierlorenzo CAPRANICA
Mario Mattia
Original Assignee
Convecom S.R.L.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Convecom S.R.L. filed Critical Convecom S.R.L.
Publication of WO2016170000A1 publication Critical patent/WO2016170000A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/02—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
    • C10G1/083—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts in the presence of a solvent
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/10—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G7/00—Distillation of hydrocarbon oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1003—Waste materials
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Definitions

  • the present invention relates to a method for obtaining a combustible liquid and a carbonaceous solid by way of thermochemical decomposition of waste.
  • thermochemical decomposition of the waste obtaining as end products a combustible liquid or gas and a solid with a residual calorific value.
  • Such methods entail mixing the waste with a vector fluid and with a reaction catalyst and heating it (typically to temperatures lower than 400°C) in the absence of oxygen, so as to prevent any combustion (and therefore the emission of pollutant gaseous compounds).
  • EP 1538191 Bl discloses an apparatus in which the necessary heat for the chemical reaction is supplied to the mixture of dense fuel oil and waste, not by way of an exchanger outside the reactor/reaction duct but by acting directly inside the reaction duct using a mechanical agitator adapted to generate a flow against the current with respect to the pumped flow of the mixture of dense fuel oil and waste. The flow against the current, by friction, causes the heating of the mixture.
  • EP 2113017 Al and WO 2008/102307 Al disclose an apparatus similar to the one disclosed in EP 1538191 Bl , in which the heating of the mixture of dense fuel oil and waste is again achieved by way of conversion of kinetic energy to heat energy (friction) by way of, in this specific case, a pump-turbine which is conceptually similar to the agitator in EP 1538191 Bl .
  • the aim of the present invention is to devise a method for producing a combustible liquid and a carbonaceous solid with residual calorific value, starting from waste materials, which makes it possible to solve the problems and overcome the drawbacks found in the methods and corresponding plants described above.
  • an object of the invention is to devise a method where the combustible liquid and the carbonaceous solid are obtained without combustion reactions of the waste materials.
  • Another object of the invention is to devise a method for producing a combustible liquid and a carbonaceous solid which have a high calorific value.
  • Another object of the present invention is to devise a method for producing a combustible liquid in which determined chemical components are always present, independently of the type of waste used, thus ensuring a final product is obtained that is homogeneous from the viewpoint of the chemical composition and, as a consequence, of the chemical characteristics.
  • Another object of the invention is to devise a method that is highly reliable and efficacious, is easy to implement even on a large scale, and is low cost, for both implementation and running costs.
  • thermochemical decomposition of waste which comprises the steps of:
  • reaction mixture comprising the waste and a vector fluid consisting of an oil selected from the group consisting of: a diathermic oil, a mineral oil and mixtures thereof;
  • the combustible liquid comprises the following components:
  • phenol optionally substituted with one or more groups independently selected from alkyl, alkenyl, alkoxy and hydroxyl;
  • polycyclic aromatic hydrocarbons optionally substituted with one or more groups independently selected from alkyl, alkenyl, alkoxy and hydroxyl;
  • sulfur-containing aromatic compounds optionally substituted with one or more groups independently selected from alkyl, alkenyl, alkoxy and hydroxyl;
  • the present invention relates to a method for preparing a carbonaceous solid and a combustible liquid that comprises determined chemical components, by using the thermochemical decomposition of waste. As described above in more detail, the method comprises the steps of:
  • the reaction mixture prepared in step (a) comprises, together with the waste, a vector fluid; such vector fluid is an oil, and is selected from the group consisting of: a diathermic oil, a mineral oil and mixtures thereof.
  • the mineral oil can be exhausted or not exhausted.
  • diathermic oils that can be used in the reaction mixture are heavy paraffmic oils, preferably solvent-dewaxed.
  • mineral oils that can be used in the reaction mixture are paraffin-based and/or polyalphaolefm-based lubricant oils derived from oil refining.
  • the waste to be processed is usually ground until it reaches a size category of approximately 8-10 mm before being mixed with the vector fluid.
  • the reaction mixture prepared in step (a) can further comprise one or more catalysts in order to increase the speed of the thermochemical decomposition reaction of the waste.
  • the effect of the one or more catalysts in terms of product yield depends on the type of waste, but usually the presence of the one or more catalysts increases conversion of the waste to the form of combustible liquid by approximately 30-40%.
  • the one or more catalysts are independently selected from the group consisting of solid materials whose active site (catalytic site) has acid, basic, or amphoteric characteristics.
  • an amphoter can exhibit both acid and basic behavior according to the chemical conditions in which it happens to be; examples of amphoteric catalysts can be doped acid materials with basic compounds dispersed in the crystalline structure.
  • the acidity and the basicity of the active sites of the catalysts are evaluated according to the Lewis theory or according to the Bronsted-Lowry theory. Since the one or more catalysts and the reagents are present in two different phases (respectively solid and fluid), the catalysis is heterogeneous. When the one or more catalysts are present in the reaction mixture, their quantity is comprised between 0.1% and 1% by weight on the total weight of the mixture.
  • the one or more catalysts can be independently selected from metallic oxides.
  • the catalyst can be aluminum oxide.
  • the catalyst can be magnesium oxide.
  • the reaction mixture prepared in step (a) takes the physical form of a slurry, i.e. a dense form of fluid in which a solid (in this case, the ground-up waste) is pulverized within a liquid (in this case, the vector fluid).
  • the physical form of slurry is particularly advantageous in that it makes it possible for the reaction mixture to be pumped through the reaction circuit of the plant in which the thermochemical decomposition takes place, thus always keeping the reaction circuit active. At the industrial level, therefore, the method of the invention can be carried out in continuous operation.
  • Step (b) of the method consists of keeping the reaction mixture at a temperature comprised between 320°C and 370°C and at a pressure comprised between -200 mbarg and +200 mbarg for a time comprised between 90 and 180 minutes. Since, as mentioned above, the method can be carried out continuously, the reaction time indicated must therefore be considered an estimate of the time necessary for the decomposition reaction of the waste to take place, and therefore of the average time the waste spends inside the reaction system. In the above conditions of temperature and pressure, the thermochemical decomposition reaction of the waste in the mixture takes place. It should be noted that the reaction temperature of the method is kept at a considerably lower value than that of a traditional catalytic cracking process (600-700°C).
  • the reaction temperature can be comprised between 340°C and 360°C; more preferably, the reaction temperature can be comprised between 345°C and 355°C.
  • the end products i.e. the combustible liquid and the carbonaceous solid, can be extracted from the mixture.
  • the combustible liquid is extracted from the reaction mixture and rectified by way of a fractional distillation column (step (c) of the method), into which the vapors of hydrocarbons produced by the thermochemical decomposition reaction are conveyed.
  • the column separates the vapors of hydrocarbons and condenses them into two fractions: (i) light liquid hydrocarbons (for example kerosene) and (ii) combustible liquid comprising heavy liquid hydrocarbons.
  • the light hydrocarbons exit from the head of the distillation column, while the combustible liquid is collected by way of a lateral offtake from the column and filtered in order to retain the solid particulate that may be present.
  • the rectifying of the combustible liquid by way of a distillation column can occur at a head temperature comprised between 150°C and 300°C and at a head pressure comprised between 300 mbar abs and 600 mbar abs.
  • the slurry can be diluted by way of the addition of further vector fluid, or, preferably, it is necessary to eliminate the aforementioned substances from the reaction circuit, in order to prevent clogging.
  • This operation is carried out by drawing some of the slurry from the reaction circuit, and treating it in order to extract the carbonaceous solid from the vector fluid (step (d) of the method) and recovering the latter.
  • the separation of the carbonaceous solid from the vector fluid occurs by way of vacuum flash evaporation and the evaporator used is the thin-layer type.
  • the vector fluid (oil) evaporates, separating from the solid residue, and subsequently the vapors are recondensed and recovered.
  • the solid residue is discharged from the bottom of the evaporator and cooled to a temperature comprised between 70°C and 80°C.
  • the temperature at which the evaporation occurs can be comprised between 280°C and 340°C and the pressure can be comprised between 2 mbar abs and 40 mbar abs.
  • the method according to the present invention makes it possible to prepare a combustible liquid that comprises (i) linear and/or ramified aliphatic hydrocarbons having from 8 to 25 carbon atoms, (ii) phenol, (iii) polycyclic aromatic hydrocarbons, (iv) sulfur-containing aromatic compounds and (v) nitrogenous aromatic compounds, where each one of the components (ii), (iii), (iv) and (v), independently of the others, can be substituted with one or more groups, independently selected from alkyl, alkenyl, alkoxy and hydroxyl.
  • each alkyl group independently of each other, can have a chain having from 1 to 8 carbon atoms. More preferably, such chain can have from 1 to 4 carbon atoms.
  • each alkenyl group independently of each other, can have a chain having from 1 to 8 carbon atoms. More preferably, such chain can have from 1 to 4 carbon atoms.
  • each alkoxy group independently of each other, can have a chain having from 1 to 8 carbon atoms. More preferably, such chain can have from 1 to 4 carbon atoms.
  • the starting raw material which is degraded by way of thermochemical decomposition in the method of the invention is represented by discarded materials of various types, i.e. waste.
  • waste i.e. waste
  • the waste with high calorific value can be, by way of example, refuse-derived fuels (RDF), car fluff, or solid biomasses. It is also possible to use mixtures of such waste with a high calorific value.
  • Refuse-derived fuels are solid fuels obtained from suitably selected and treated waste, and they are usually used to fuel waste-to-energy plants.
  • car fluff indicates the waste obtained from the demolition of cars and pulverized in the form of fluff, i.e. similar to confetti.
  • solid biomasses defines any solid fuel based on organic matter, except for fossil fuels and plastics of petrochemical origin.
  • the following are always present in the combustible liquid produced with the method of the invention: (i) linear and/or ramified aliphatic hydrocarbons having from 8 to 25 carbon atoms, (ii) phenol, (iii) poly cyclic aromatic hydrocarbons, (iv) sulfur-containing aromatic compounds and (v) nitrogenous aromatic compounds, where the components (ii)-(v) can be optionally substituted as described previously.
  • the combustible fluid can contain further components, which can vary according to the initial waste.
  • the combustible liquid can further comprise one or more of the following components:
  • naphthalene optionally substituted with one or more groups independently selected from alkyl and alkenyl;
  • biphenyl optionally substituted with one or more groups independently selected from alkyl and alkenyl.
  • the aliphatic heterocyclic compounds present in the combustible liquid obtained using RDF, car fluff or mixtures thereof as the starting material can comprise one or more heteroatoms independently selected from the group consisting of nitrogen, sulfur and oxygen.
  • the linear and/or ramified aliphatic hydrocarbons present in the combustible liquid obtained using RDF, car fluff or mixtures thereof as the starting material can have from 12 to 22 carbon atoms. More preferably, such linear and/or ramified aliphatic hydrocarbons can have from 16 to 20 carbon atoms.
  • the substituted benzene present in the combustible liquid obtained using RDF, car fluff or mixtures thereof as the starting material can be trimethylbenzene or methylstyrene.
  • alkyl and alkenyl groups that can be present as substituents of the aliphatic heterocyclic compounds, benzene, naphthalene and biphenyl which are present in the combustible liquid obtained using RDF, car fluff or mixtures thereof as the starting material can have a chain with a number of carbon atoms comprised between 1 and 8. More preferably, such chain can have a number of carbon atoms comprised between 1 and 4.
  • the combustible liquid can further comprise one or more of the following components:
  • heterocyclic aromatic compounds in which the heteroatom is nitrogen, optionally substituted with at least one substituent comprising oxygen;
  • the combustible liquid obtained using solid biomasses or mixtures thereof as the starting material can comprise linear fatty acid esters, ramified fatty acid esters, or a mixture of linear and ramified fatty acid esters.
  • such combustible liquid can comprise saturated fatty acid esters, unsaturated fatty acid esters or a mixture of saturated and unsaturated fatty acid esters.
  • the alkyl, alkenyl and alkoxy groups that can be present as substituents of the benzoic acid and its aliphatic esters which are present in the combustible liquid obtained using solid biomasses or mixtures thereof as the starting material can have a chain with a number of carbon atoms comprised between 1 and 8. More preferably, such chain can have a number of carbon atoms comprised between 1 and 4.
  • the aromatic heterocyclic compounds where the heteroatom is nitrogen which are present in the combustible liquid obtained using solid biomasses or mixtures thereof as the starting material, can be substituted by a methoxy group. More preferably, such aromatic heterocyclic compounds where the heteroatom is nitrogen can be substituted by a methoxy group and a hydroxyl group.
  • the method disclosed herein can be carried out in an apparatus of the type disclosed in Italian patent no. 1408057, extended to PCT/EP2012/065532 (WO 2013021011).
  • Another aspect of the invention relates to the combustible liquid obtainable by way of the method described herein.
  • linear and/or ramified aliphatic hydrocarbons having from 8 to 25 carbon atoms, phenol, polycyclic aromatic hydrocarbons, sulfur-containing aromatic compounds and nitrogenous aromatic compounds are always found in the combustible liquid prepared with the method of the invention, irrespective of the type of waste treated.
  • Phenol, polycyclic aromatic hydrocarbons, sulfur-containing aromatic compounds and nitrogenous aromatic compounds can optionally be substituted with one or more groups, independently selected from alkyl, alkenyl, alkoxy and hydroxyl, as described previously with reference to the method.
  • the combustible liquid can further comprise one or more of the following components:
  • Aliphatic heterocyclic compounds, naphthalene and biphenyl can optionally be substituted with one or more groups, independently selected from alkyl and alkenyl, as described previously with reference to the method.
  • the combustible liquid can further comprise one or more of the following components:
  • heterocyclic aromatic compounds in which the heteroatom is nitrogen, optionally substituted with at least one substituent comprising oxygen;
  • Benzoic acid (both as such and in the form of its aliphatic esters) can be optionally substituted with one or more groups independently selected from alkyl, alkenyl, alkoxy and hydroxyl, as described previously with reference to the method.
  • the method according to the present invention makes it possible to prepare a combustible liquid and a carbonaceous solid whose chemical/physical characteristics are exemplified in the examples that follow.
  • Sample 1 dried solid obtained by thermochemical decomposition of solid biomass (sawdust). Solid with presence of small to medium agglomerates, blackish, odorless.
  • Sample 2 carbon obtained by thermochemical decomposition of car fluff. Powdered solid with presence of small to medium agglomerates, black, odorless. Unit of
  • the method according to the present invention fully achieves the set aim in that it makes it possible to obtain a combustible liquid and a carbonaceous solid starting from waste materials, without the problem and drawbacks associated with the methods used to date.
  • the production of the combustible liquid and of the carbonaceous solid occurs without resorting to combustion reactions of the waste materials, thus avoiding the emission of pollutant substances.
  • the combustible liquid and the carbonaceous solid produced with the method described herein have a high residual calorific value.
  • the method of the invention results in a combustible liquid that always comprises some well-determined chemical components, independently of the type of waste used, thus making it possible to maintain the homogeneity of the final product.
  • the method for preparing a combustible liquid and a carbonaceous solid by way of thermochemical decomposition of waste according to the present invention, and the combustible liquid obtainable by such method, thus conceived, are susceptible of numerous modifications and variations, all of which are within the scope of the appended claims; moreover, all the details may be substituted by other, technically equivalent elements, the correspondence of which is known to the person skilled in the art.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Processing Of Solid Wastes (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

L'invention concerne un procédé de préparation de liquide combustible et de solide carboné au moyen d'une décomposition thermochimique de déchets, le liquide combustible comprenant certains composés chimiques bien déterminés, indépendamment du type des déchets traités. L'invention concerne également un liquide combustible à valeur calorifique élevée pouvant être obtenu au moyen du procédé précité, parmi les composants déterminés, des composés chimiques déterminés peuvent à nouveau à être trouvés indépendamment du type de déchets traités.
PCT/EP2016/058784 2015-04-22 2016-04-20 Procédé de décomposition thermochimique de déchets WO2016170000A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITVR2015A000065A ITVR20150065A1 (it) 2015-04-22 2015-04-22 Procedimento di decomposizione termochimica di rifiuti
ITVR2015A000065 2015-04-22

Publications (1)

Publication Number Publication Date
WO2016170000A1 true WO2016170000A1 (fr) 2016-10-27

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WO (1) WO2016170000A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021129395A1 (fr) * 2019-12-25 2021-07-01 浙江工业大学 Procédé et dispositif pour un traitement en continu d'eaux usées organiques fortement concentrées

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Publication number Priority date Publication date Assignee Title
DE10049377A1 (de) 2000-10-05 2002-04-18 Evk Dr Oberlaender Gmbh & Co K Katalytische Erzeugung von Dieselöl und Benzinen aus kohlenwasserstoffhaltigen Abfällen und Ölen
WO2008102307A1 (fr) 2007-02-21 2008-08-28 Vuzeta Brevetti S.R.L. Appareil de production de combustible de synthèse
WO2010149138A2 (fr) 2009-06-26 2010-12-29 Hochschule für Angewandte Wissenschaften Hamburg (HAW Hamburg) Conversion thermochimique de biomasse
WO2010149137A2 (fr) 2009-06-26 2010-12-29 Hochschule für Angewandte Wissenschaften Hamburg (HAW Hamburg) Procédé de bioraffinerie
EP1538191B1 (fr) 2003-12-02 2011-08-31 AlphaKat GmBH Gazole obtenu à partir de déchets par dépolymérisation catalytique où l'apport d'énergie est réalisé par un système de pompe et de mélangeur
WO2013021011A1 (fr) 2011-08-10 2013-02-14 Irle S.R.L. Appareil et procédé de conversion catalytique de déchets en fluides combustibles

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Publication number Priority date Publication date Assignee Title
DE10049377A1 (de) 2000-10-05 2002-04-18 Evk Dr Oberlaender Gmbh & Co K Katalytische Erzeugung von Dieselöl und Benzinen aus kohlenwasserstoffhaltigen Abfällen und Ölen
EP1538191B1 (fr) 2003-12-02 2011-08-31 AlphaKat GmBH Gazole obtenu à partir de déchets par dépolymérisation catalytique où l'apport d'énergie est réalisé par un système de pompe et de mélangeur
WO2008102307A1 (fr) 2007-02-21 2008-08-28 Vuzeta Brevetti S.R.L. Appareil de production de combustible de synthèse
EP2113017A1 (fr) 2007-02-21 2009-11-04 Vuzeta Brevetti S.R.L. Appareil de production de combustible de synthèse
WO2010149138A2 (fr) 2009-06-26 2010-12-29 Hochschule für Angewandte Wissenschaften Hamburg (HAW Hamburg) Conversion thermochimique de biomasse
WO2010149137A2 (fr) 2009-06-26 2010-12-29 Hochschule für Angewandte Wissenschaften Hamburg (HAW Hamburg) Procédé de bioraffinerie
WO2013021011A1 (fr) 2011-08-10 2013-02-14 Irle S.R.L. Appareil et procédé de conversion catalytique de déchets en fluides combustibles

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Title
A A CASAZZA ET AL: "AIChE - Proceedings - Conversion of Organic Waste to Liquid Fuel by Pyrolysis Over Alumina Catalyst (2012 Annual Meeting)", 29 October 2012 (2012-10-29), XP055242910, Retrieved from the Internet <URL:http://www3.aiche.org/proceedings/Abstract.aspx?PaperID=267288> [retrieved on 20160119] *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021129395A1 (fr) * 2019-12-25 2021-07-01 浙江工业大学 Procédé et dispositif pour un traitement en continu d'eaux usées organiques fortement concentrées
US11767232B2 (en) 2019-12-25 2023-09-26 Zhejiang University Of Technology Process and device for continuous treatment of high-concentration organic wastewater

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