WO2016159799A1 - Procédé pour l'obtention d'adhésif à partir de déchets de protéines - Google Patents

Procédé pour l'obtention d'adhésif à partir de déchets de protéines Download PDF

Info

Publication number
WO2016159799A1
WO2016159799A1 PCT/PL2015/000071 PL2015000071W WO2016159799A1 WO 2016159799 A1 WO2016159799 A1 WO 2016159799A1 PL 2015000071 W PL2015000071 W PL 2015000071W WO 2016159799 A1 WO2016159799 A1 WO 2016159799A1
Authority
WO
WIPO (PCT)
Prior art keywords
favourably
hydrolyzate
solution
dry matter
waste
Prior art date
Application number
PCT/PL2015/000071
Other languages
English (en)
Inventor
Piotr Grzybowski
Original Assignee
Przedsiebiorstwo Amed Piotr Grzybowski
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Przedsiebiorstwo Amed Piotr Grzybowski filed Critical Przedsiebiorstwo Amed Piotr Grzybowski
Publication of WO2016159799A1 publication Critical patent/WO2016159799A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J189/00—Adhesives based on proteins; Adhesives based on derivatives thereof
    • C09J189/04—Products derived from waste materials, e.g. horn, hoof or hair
    • C09J189/06—Products derived from waste materials, e.g. horn, hoof or hair derived from leather or skin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08H—DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
    • C08H1/00—Macromolecular products derived from proteins
    • C08H1/06—Macromolecular products derived from proteins derived from horn, hoofs, hair, skin or leather
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08L3/04—Starch derivatives, e.g. crosslinked derivatives
    • C08L3/06—Esters

Definitions

  • the subject of this invention is the method for obtaining adhesive from protein waste, especially leather waste from tanning, meat and fish processing industries, designed for bonding of paper, cardboard and wood. This method allows for environment friendly management of tanning waste ofêtwet blue" type.
  • Waste generated in tanning industry requires special management, is subjected to various utilization processes e.g. to composting. However, most frequently it is burned in specialized plants. Storage of such waste is dangerous for sanitary reasons.
  • the method for preparation of chrome-tanned leather waste for utilization especially for leaching of gelatin and leather glue.
  • the method consists of the following: crushed leather waste is subjected to de-tanning with alkaline substance such as lime, sodium carbonate, ammonia, magnesium hydroxide, magnesium oxide, favourably magnesium oxide, used in the minimum quantity of 4% by weight in relation to the waste matter.
  • the waste is rinsed and subjected to de-chroming with mineral acid, applied in the quantity up to 10% by weight in relation to the waste matter, in the presence of sodium chloride solution.
  • waste is subjected to hydrolysis with the help of sodium hydroxide and further the alkaline pulp is subjected to neutralization first by sodium hydrocarbon applied in the minimum quantity of 12,5% by weight in relation to the waste matter, and after centrifugation, by ammonium chloride applied in the quantity of up to l 5% by weight in relation to the waste matter, after which the obtained pulp rinsed with water and centrifuged.
  • This process does not provide guarantee of removal of the entire quantity of chromium from waste.
  • hydrocarbon organic solvent such as: n- heptane, kerosene or benzene with addition of higher-level aliphatic alcohol, favourably n-decanol.
  • the method for de- chroming leather and/or leather waste which were tanned with chromium components, especially collagen derived waste consists of contacting such waste with salt solutions with addition of acids and/or acid anhydrides which are the original acids of those salts and/or at least medium strong mineral acids.
  • This method leads to recovery of non-tanned collagen of leather with the possibility to preserve its fibrous structure and having high purity.
  • chromium compounds solutions are obtained which can be returned to technological process of obtaining chrome-tanned leather directly or after relevant treatment. This method does not guarantee removal of the entire quantity of chromium contained in waste.
  • Patent US1712077 presents the method for production of water resistant adhesive of animal origin through addition of formaldehyde, and then of acid, favourably oxalic acid, tartaric acid, citric acid, benzoic acid, acetic acid or phosphoric acid to preserve adhesive liquidity.
  • Patent US5210982 presents the method for obtaining adhesive from a partly condensed urea and formaldehyde, used for crosslinking of collagen or polysaccharides and improvement of rheological properties of adhesive.
  • the method for obtaining adhesive from protein waste, especially leather waste from tanning, meat and fish processing industries consists of the following: hydrolyzed proteins are subjected initially to alkaline or acidic or enzymatic or thermal hydrolysis, and then polycondensation reaction is carried out with the use of aldehydes and aliphatic or aromatic amines and mixed with modifying and biocidal additions.
  • plasticizers such as glycerine, polyglycerine, glycols and polyethylene esters, in the quantity from 0,5 % to 5,0 % by weight of dry matter of hydrolyzate.
  • Example 1 Use of the method according to the invention is particularly beneficial for the environment friendly waste management. It allows for the use of protein waste generated in tanning, meat and fish processing industries.
  • the obtained water-based adhesive is environment friendly, and the process of its obtaining is simple, effective and cheap.
  • adhesive due to good adhesion parameters, has wide possibility of application, especially for production of corrugated paper packages.
  • the invention is presented in three examples of execution. Example 1

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Biochemistry (AREA)
  • Materials Engineering (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)

Abstract

L'invention concerne un procédé d'obtention d'adhésif à partir de déchets de protéines, notamment des déchets de cuir provenant du tannage, des industries de traitement de viande et de poisson sous la forme de protéines hydrolysées obtenues par l'intermédiaire d'hydrolyse alcaline ou acide ou enzymatique ou thermique. Les hydrolysats sont soumis à une réaction de polycondensation avec application d'aldéhydes et d'amines aliphatiques ou aromatiques et ils sont mélangés avec des additions d'agents de modification et d'amélioration. De l'aldéhyde, de préférence du formaldéhyde, dans la quantité de 2:1 à 5:1 par rapport à la matière sèche d'hydrolysat, est introduit progressivement dans une solution aqueuse de protéine hydrolysée, de préférence un hydrolysat de collagène. La réaction de condensation est effectuée, de préférence dans un environnement alcalin, en dosant graduellement l'urée dans la solution dans la quantité de 1:1 à 3:1 par rapport à la matière sèche d'hydrolysat pendant une période de 1 heure à 5 heures à une température de 45°C à 75°C, de préférence 70°C. En même temps, on le mélange et la teneur en sel de 1% à 3% en poids de matière sèche d'hydrolysat est supplémentée. Ensuite, le mélange de réaction est évaporé, après que les additions d'agents de modification et de biocides sont introduites dans la solution concentrée et après le mélange, une solution homogène de l'adhésif de protéine est obtenue.
PCT/PL2015/000071 2015-04-01 2015-04-29 Procédé pour l'obtention d'adhésif à partir de déchets de protéines WO2016159799A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
PL411849A PL411849A1 (pl) 2015-04-01 2015-04-01 Sposób otrzymywania kleju z odpadów białkowych
PLP.411849 2015-04-01

Publications (1)

Publication Number Publication Date
WO2016159799A1 true WO2016159799A1 (fr) 2016-10-06

Family

ID=53267537

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/PL2015/000071 WO2016159799A1 (fr) 2015-04-01 2015-04-29 Procédé pour l'obtention d'adhésif à partir de déchets de protéines

Country Status (2)

Country Link
PL (1) PL411849A1 (fr)
WO (1) WO2016159799A1 (fr)

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1712077A (en) 1928-03-14 1929-05-07 Clarence E Hrubesky Water-resistant animal glue
US3475113A (en) * 1962-09-27 1969-10-28 Diamond Shamrock Corp Process for treatment of leather with condensates of aminoplast-sulfonated phenolic compounds
US5210982A (en) 1991-01-22 1993-05-18 Kormanek Ronald S Animal glue hardening composition and article and method of manufacturing thereof
PL315360A1 (en) 1996-07-18 1998-01-19 Wyzsza Szkola Inzynierska Method of dechroming leathers and/or leather waste tanned withic chromium compounds or other substances containing chromium compounds, in particular wastes of collagen origin
PL175363B1 (pl) 1995-01-17 1998-12-31 Politechnika Lodzka Sposób przygotowania odpadów skór chromowych do utylizacji, zwłaszcza do wytapiania z nich żelatyny i kleju skórnego
US6165488A (en) * 1996-10-07 2000-12-26 Societe Anonyme De Developpement Des Utilisations Du Collagene S.A.D.U.C. Adhesive composition with macromolecular polyaldehyde base and method for cross-linking collagen
PL184763B1 (pl) 1997-12-10 2002-12-31 Inst Przemyslu Skorzanego Sposób wydzielania związków Cr(III) ze stałych i ciekłych odpadów przemysłowych
US20030119985A1 (en) * 1995-12-18 2003-06-26 Sehl Louis C. Methods for tissue repair using adhesive materials
US20060210602A1 (en) * 1995-12-18 2006-09-21 Sehl Louis C Compositions and systems for forming crosslinked biomaterials and methods of preparation and use
WO2011107807A2 (fr) * 2010-03-05 2011-09-09 Tigenix Limited Procédé de fabrication

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1712077A (en) 1928-03-14 1929-05-07 Clarence E Hrubesky Water-resistant animal glue
US3475113A (en) * 1962-09-27 1969-10-28 Diamond Shamrock Corp Process for treatment of leather with condensates of aminoplast-sulfonated phenolic compounds
US5210982A (en) 1991-01-22 1993-05-18 Kormanek Ronald S Animal glue hardening composition and article and method of manufacturing thereof
PL175363B1 (pl) 1995-01-17 1998-12-31 Politechnika Lodzka Sposób przygotowania odpadów skór chromowych do utylizacji, zwłaszcza do wytapiania z nich żelatyny i kleju skórnego
US20030119985A1 (en) * 1995-12-18 2003-06-26 Sehl Louis C. Methods for tissue repair using adhesive materials
US20060210602A1 (en) * 1995-12-18 2006-09-21 Sehl Louis C Compositions and systems for forming crosslinked biomaterials and methods of preparation and use
PL315360A1 (en) 1996-07-18 1998-01-19 Wyzsza Szkola Inzynierska Method of dechroming leathers and/or leather waste tanned withic chromium compounds or other substances containing chromium compounds, in particular wastes of collagen origin
US6165488A (en) * 1996-10-07 2000-12-26 Societe Anonyme De Developpement Des Utilisations Du Collagene S.A.D.U.C. Adhesive composition with macromolecular polyaldehyde base and method for cross-linking collagen
PL184763B1 (pl) 1997-12-10 2002-12-31 Inst Przemyslu Skorzanego Sposób wydzielania związków Cr(III) ze stałych i ciekłych odpadów przemysłowych
WO2011107807A2 (fr) * 2010-03-05 2011-09-09 Tigenix Limited Procédé de fabrication

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
MÁRIA SMIDRIAKOVÁ ET AL: "ATR-FTIR spectral analysis of modified UF adhesive", ANNALS OF WARSAW UNIVERSITY OF LIFE SCIENCES - FORESTRY AND WOOD TECHNOLOGY, vol. 76, 1 January 2011 (2011-01-01), pages 49 - 53, XP055233931 *

Also Published As

Publication number Publication date
PL411849A1 (pl) 2016-10-10

Similar Documents

Publication Publication Date Title
CN103061186A (zh) 制浆黑液的处理方法及其产品的应用方法
CN103014191B (zh) 从含铬废皮渣中回收胶原蛋白和铬盐的方法
CN105153316A (zh) 一种金属盐催化甲酸水解制备纳米纤维素的方法
JP2015525313A (ja) 化学パルプ製造方法
CN102603919A (zh) 一种空气汽爆联用生物复合酶技术制备海藻酸及海藻酸钠的方法
CN107735431A (zh) 活化和沉淀木质素的方法
CN102583688B (zh) 制浆黑液酸析木质素废水处理与回用的方法
CN104870713A (zh) 树脂抑制剂、树脂抑制方法、及脱墨纸浆的制造方法
WO2011162420A1 (fr) Procédé de récupération de lignine dans la plage neutre à partir d'une lessive résiduaire de cuisson
CN101012092A (zh) 糠醛废水处理方法
WO2016159799A1 (fr) Procédé pour l'obtention d'adhésif à partir de déchets de protéines
WO2014091512A1 (fr) Matières plastiques contenant des produits isolés à partir d'une biomasse résiduelle et de fossiles et leurs dérivés sulfonés
CN103588903B (zh) 一种分离小麦秸秆生物质原料的绿色工艺
US2201797A (en) Process of producing molding composition from lignin and formaldehyde
CN203440272U (zh) 一种小麦秸秆中生物质原料的分离装置
CN110813983B (zh) 烷基苯酚生产工艺所产固废酚渣的回收处理方法及其装置
CN103709414A (zh) 一种单分散碱木质素分子液体的制备方法及其应用
KR101153283B1 (ko) 알칼리 펄핑 흑액으로부터 아세틸화된 리그닌을 제조하는 방법
CN105481136B (zh) 一种褐藻胶生产中废钙水和废酸水循环利用的综合处理方法
US2576418A (en) Lignin compounds and method for making same
CN105019291A (zh) 一种造纸黑液处理方法
CN109160660B (zh) 一种羧甲基纤维素钠生产废水中羟基乙酸的回收方法
WO2020099657A1 (fr) Procédé de traitement de digestat de biomasse
CN109518507A (zh) 一种水溶助溶剂去除木屑中木质素的方法及木质素微粒的制备方法
CN113788876B (zh) 基于离子液体双水相系统从铬鞣革屑中提取蛋白质的方法

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 15724787

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 15724787

Country of ref document: EP

Kind code of ref document: A1