WO2016147907A1 - Non-alcoholic beer-taste beverage - Google Patents

Non-alcoholic beer-taste beverage Download PDF

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Publication number
WO2016147907A1
WO2016147907A1 PCT/JP2016/056761 JP2016056761W WO2016147907A1 WO 2016147907 A1 WO2016147907 A1 WO 2016147907A1 JP 2016056761 W JP2016056761 W JP 2016056761W WO 2016147907 A1 WO2016147907 A1 WO 2016147907A1
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WO
WIPO (PCT)
Prior art keywords
beer
taste
content
beverage
acid
Prior art date
Application number
PCT/JP2016/056761
Other languages
French (fr)
Japanese (ja)
Inventor
雄人 山内
斎 入内島
Original Assignee
サントリーホールディングス株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2015212646A external-priority patent/JP6647832B2/en
Application filed by サントリーホールディングス株式会社 filed Critical サントリーホールディングス株式会社
Priority to SG11201707374QA priority Critical patent/SG11201707374QA/en
Priority to KR1020177029292A priority patent/KR102166581B1/en
Priority to US15/557,508 priority patent/US10357048B2/en
Priority to CN201680015561.6A priority patent/CN107427036B/en
Publication of WO2016147907A1 publication Critical patent/WO2016147907A1/en
Priority to HK18103865.6A priority patent/HK1244406A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/38Other non-alcoholic beverages
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/52Adding ingredients
    • A23L2/66Proteins
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/52Adding ingredients
    • A23L2/68Acidifying substances

Definitions

  • the present invention relates to a substantially non-alcoholic beer-taste beverage.
  • Collagen has been widely used as a gelatin in the food field.
  • Collagen an animal protein, is the main component of dermis and connective tissue, and has recently attracted attention from the medical and cosmetic fields.
  • Patent Document 1 contains at least two acidulants containing phosphoric acid and has a pH range of 4.0 or less, which has an effect on antiseptic properties by making the pH 4.0 or less. Discloses a beverage composition that achieves moderate acidity and good flavor. On the other hand, a collagen peptide has been tried to be blended into a beer-taste beverage. Patent Document 2 discloses that the foam quality in the sparkling liquor is smoother, the foam hardness is maintained, and the foam disappears over a long period of time. A technique for preserving the taste of Happoshu by disabling it is disclosed.
  • collagen peptides are known to have pH buffering ability. For this reason, when the collagen peptide is contained in the beverage, the influence of the pH buffering ability cannot be ignored.
  • the inventors of the present invention tried to design a beverage containing collagen peptide and having a pH of 4.0 or less from the viewpoint of not giving a large heat load to the beverage for maintaining the flavor. It becomes necessary to use acidulant, and as a result, it becomes a sensory result that begins to feel acidity lately in a flat and unconventional taste, and it has a very uncomfortable taste as a so-called beer-taste beverage. It was also found out.
  • an object of the present invention is to provide a substantially non-alcohol beer-taste beverage that contains a collagen peptide and realizes a good flavor in a pH range of pH 4 or lower.
  • the present invention comprises (A) a collagen peptide having an average molecular weight of 500 to 8000, (B) carbon dioxide gas, (C) isoalpha acid, and (D) an acidulant, and has a pH of 3 or more and 4 or less, and A substantially non-alcohol beer taste having a collagen peptide content of 280 to 1800 mg / 100 mL and an isoalpha acid content of 1.0 ⁇ 10 ⁇ 3 to 3.0 ⁇ 10 ⁇ 3 mass% Regarding beverages.
  • a beer-taste beverage having a good taste of acidity and bitterness in a pH range of pH 4 or less and taste like beer can be provided.
  • the substantially non-alcohol beer-taste beverage according to the present invention is characterized in that it contains a specific amount of iso-alpha acid in a beverage having a pH of 3 or more and 4 or less containing a collagen peptide.
  • the beer-taste beverage according to the present invention contains (A) a collagen peptide.
  • the collagen peptide is a collagen peptide hydrolyzed so that the average molecular weight is 8000 or less.
  • collagen peptide instead of mere collagen, the absorbability into the body when ingested orally is increased, and therefore in the present invention relating to beverages, collagen peptide is used.
  • the average molecular weight of the collagen peptide is 8000 or less, preferably 7000 or less, more preferably 6000 or less, and even more preferably 5500 or less, from the viewpoint of enhancing absorbability into the body when taken orally.
  • the lower limit is 500 or more, preferably 1000 or more, more preferably 1500 or more, and still more preferably 2000 or more. is there.
  • the range may be a combination of any of these.
  • the average molecular weight of the collagen peptide is 500 to 8000, preferably 1000 to 7000, more preferably 1500 to 6000, and still more preferably 2000 to 5500.
  • the average molecular weight of the collagen peptide means a value measured by gel permeation chromatography (GPC: polyethylene glycol (PEG) standard). In the case of a commercial product, it is provided from the supplier. Under product information.
  • the average molecular weight in GPC is calculated based on a calibration curve of the relationship between retention time and molecular weight obtained by measuring several kinds of polyethylene glycol (PEG) having different molecular weights in advance under the same conditions.
  • the average molecular weight in the present invention refers to a weight average molecular weight calculated in terms of PEG according to this method.
  • the collagen peptide of the present invention can be obtained by hydrolyzing gelatin with an enzyme or acid.
  • Collagen peptides are proteins containing a large amount of glycine and hydroxyproline, and are also available as commercial products.
  • the collagen is not particularly limited, whether it is collagen extracted from mammalian collagen tissue or collagen extracted from fish. From the viewpoint of product image and safety, it is preferably a collagen derived from fish.
  • the raw material for collagen derived from fish may be saltwater fish or freshwater fish, and skins of tuna (sharkfin), shark, cod, flounder, flounder, Thailand, tilapia, salmon, catfish and the like. These fish-derived collagens are extracted from fish scales and skins. Examples of the raw material for mammal-derived collagen include pigs and cows.
  • the content of the collagen peptide of the present invention is 280 to 1800 mg per 100 mL of beverage.
  • the content of the collagen peptide exceeds 1800 mg / 100 mL, an unpleasant odor derived from the collagen peptide may be felt in the non-alcohol beer-taste beverage.
  • the content of the collagen peptide is less than 280 mg / 100 mL, the effect of the present invention corresponding to the pH buffering ability of the collagen peptide is reduced.
  • the content of the collagen peptide is preferably 350 mg / 100 mL or more, more preferably 400 mg / 100 mL or more, further preferably 500 mg / 100 mL or more, preferably 1500 mg / 100 mL or less, more preferably 1200 mg / 100 mL or less, and 1000 mg / 100 mL or less. Further preferred. Further, 350 to 1500 mg / 100 mL is preferable, 400 to 1200 mg / 100 mL is more preferable, and 500 to 1000 mg / 100 mL is still more preferable. Further, the content of collagen peptide can be analyzed by the Japan Food Analysis Center, and the concentration of the collagen peptide can also be measured.
  • the beer-taste beverage according to the present invention contains hydroxyproline.
  • Hydroxyproline is an amino acid characteristic of collagen.
  • hydroxyproline is preferably derived from (A) a collagen peptide.
  • the content of hydroxyproline can be measured by various techniques. As an example, the measurement can be performed according to the method of Nayama, Shibata, Ohtuki, Saito (Daizaburo Fujimoto, Yu Nagai (1985), Collagen Experimental Method, pp. 51-56, Kodansha). It can also be measured by entrusting it to a general incorporated foundation, Japan Food Analysis Center.
  • the content of hydroxyproline in the beer-taste beverage of the present invention is preferably 30 mg / 100 mL or more, more preferably 36 mg / 100 mL or more, and further preferably 42 mg / 100 mL or more. Moreover, 193 mg / 100 mL or less is preferable, 161 mg / 100 mL or less is more preferable, and 128 mg / 100 mL or less is still more preferable.
  • the beer-taste beverage of the present invention contains (B) carbon dioxide gas.
  • the carbon dioxide gas to be injected (B) has a carbon dioxide gas concentration of 0. 0 from the viewpoint of suppressing the flatness due to the collagen peptide and imparting a beer taste feeling in general taste. It is preferable that it is 4 w / w% or more. Also, as the carbon dioxide gas concentration increases, the irritation increases and the forehead is inflated, so the carbon dioxide gas concentration is preferably 0.40 to 0.60 w / w%, and more preferably 0.45 to 0.00. More preferably, it is 55 w / w%, still more preferably 0.48 to 0.52 w / w%.
  • the gas concentration can be measured by standard techniques well known to those skilled in the art.
  • a conventional automatic measuring apparatus may be used.
  • a gas volume measuring device GVA-500A Kelvin-500A (Kyoto Electronics Industry Co., Ltd.) can be used.
  • the gas content in a beer-taste beverage can be generally expressed in terms of weight% (w / w% or g / kg) or in gas pressure at 20 ° C. (kgf / cm 2 or MPa).
  • the concentration of carbon dioxide and the gas pressure can be converted as appropriate. In the present specification, unless otherwise specified, the content of carbon dioxide is indicated by concentration (w / w%).
  • the beer-taste beverage according to the present invention contains (C) isoalpha acid.
  • Iso- ⁇ acid is a bitter component derived from hop, which is a raw material used in beer production, and is a component obtained by isolating ⁇ -acid.
  • the bitter taste of iso- ⁇ acid contributes to the beer taste of the beverage.
  • (C) isoalpha acid is mainly derived from hops, but an extract from hops may be blended, or a commercially available isoalpha acid preparation may be blended. Also good.
  • a hop extraction means any known technique can be used without any limitation. Moreover, it can also use combining said 1 type (s) or 2 or more types.
  • the isoalpha acid can be measured in accordance with Method 7.7 of “Analytica-EBC” defined in the analytical method published by EBC (European Brewery Convention). In this specification, the measurement can be performed according to any known method.
  • the content of iso- ⁇ acid in the beer-taste beverage of the present invention is 1.0 ⁇ 10 ⁇ 3 mass% or more and 3.0 ⁇ 10 ⁇ 3 mass% or less. From the viewpoint of realizing a good flavor balance, the content is preferably 1.3 ⁇ 10 ⁇ 3 mass% or more, more preferably 1.5 ⁇ 10 ⁇ 3 mass% or more. Further, from the viewpoint of improving the flavor balance in the last half of the taste, it is preferably 2.5 ⁇ 10 ⁇ 3 mass% or less, more preferably 2.0 ⁇ 10 ⁇ 3 mass% or less.
  • the beer-taste beverage according to the present invention contains (D) a sour agent.
  • a sour agent As the acidulant, it is preferable to use one or more acids selected from the group consisting of citric acid, lactic acid, phosphoric acid, and malic acid.
  • succinic acid, tartaric acid, fumaric acid, glacial acetic acid, and the like can also be used as acids other than the above acids. These can be used without limitation as long as they are permitted to be added to food.
  • the content of the sour agent is preferably 1000 ppm or more, more preferably 1200 ppm or more, and further preferably 1400 ppm or more in terms of citric acid in the beer-taste beverage of the present invention. Moreover, 3000 ppm or less is preferable, 2500 ppm or less is more preferable, and 2000 ppm or less is still more preferable. When a plurality of acids are used, the total content is meant.
  • the citric acid conversion amount is an amount converted from the acidity of each acidulant based on the acidity of citric acid.
  • the citric acid conversion amount corresponding to 100 ppm of lactic acid is The citric acid equivalent corresponding to 120 ppm and phosphoric acid 100 ppm is converted to 200 ppm, and the citric acid equivalent corresponding to malic acid 100 ppm is converted to 125 ppm.
  • the content ratio of iso-alpha acid to acidulant is from the standpoint of imparting a beer-taste to the taste as a whole, and to suppress flatness due to collagen peptides.
  • 0.003 to 0.030 is preferable, 0.003 to 0.019 is more preferable, 0.005 to 0.017 is still more preferable, and 0.008 to 0.014 is still more preferable.
  • the beer-taste beverage according to the present invention can be produced in the same manner as a general non-alcohol beer-taste beverage except that a collagen peptide is used.
  • a general non-fermented non-alcohol beer taste drink is shown below.
  • non-alcohol beer-taste beverages such as non-alcohol beer can be easily produced.
  • General non-fermented non-alcohol beer-taste beverages may or may not use malt as a raw material and can be produced as follows.
  • Non-alcoholic beer-taste beverages produced using malt as a raw material are first made from wheat such as malt, as well as other raw materials such as cereals, starch, sugars, bitters, or colorants and water as required. If necessary, an enzyme such as amylase is added to the mixture to be gelatinized and saccharified, followed by filtration to obtain a saccharified solution. If necessary, add hops, bitters, etc. to the saccharified solution and boil, and remove solids such as coagulated protein in the clarification tank. As an alternative to this saccharified solution, hops may be added to the malt extract added with warm water and boiled. Hops may be mixed at any stage from the start of boiling to the end of boiling.
  • Known conditions may be used as conditions in the saccharification process, boiling process, solid content removal process, and the like. After boiling, the obtained wort is filtered, and carbon dioxide gas is added to the obtained filtrate. Then, the container is filled and the target non-alcohol beer-taste drink is obtained through a sterilization process.
  • the collagen peptide may be mixed at any timing until filling.
  • liquid sugar containing carbon source, nitrogen source as amino acid-containing material other than wheat or malt, hop, pigment, etc. are mixed with warm water And a liquid sugar solution.
  • the liquid sugar solution is boiled.
  • hops may be mixed with the liquid sugar solution during boiling, not before the start of boiling.
  • Carbon dioxide gas is added to the liquid sugar solution after boiling.
  • the container is filled and the target non-alcohol beer-taste drink is obtained through a sterilization process.
  • the collagen peptide may be charged and mixed at any timing until filling.
  • the total amount of the extract is within a predetermined range in order to make a refreshing beer-taste beverage.
  • the “amount of extract” in the present specification refers to the extract in the Japanese liquor tax law when the alcohol content of the beverage is 0.005% or more, that is, the nonvolatile content contained in the original capacity of 100 cubic centimeters at a temperature of 15 degrees. This refers to the number of grams of the sex component.
  • the degassed sample was measured according to the “Beer Analysis Method 7.2 Extract” established by the International Technical Committee of the Brewery Association (BCOJ). The extract value (% by weight).
  • BCOJ International Technical Committee of the Brewery Association
  • the extract value (% by weight).
  • the amount of extract derived from wheat such as malt is obtained by, for example, finding the amount of total extract and measuring the amount of the additive or other raw material obtained separately. Can be obtained.
  • beer-taste beverage refers to a carbonated beverage having a beer-like flavor. That is, the beer-taste beverage of this specification includes all beer-flavored carbonated beverages unless otherwise specified.
  • the present invention is directed to a substantially non-alcoholic type of this beverage, the alcohol content of which is 0.005% or less, and is preferably substantially free of alcohol.
  • the beverage of the present invention that substantially does not contain alcohol does not exclude beverages that contain an extremely small amount of alcohol that cannot be detected. Beverages having an alcohol content of 0.0% by rounding off, and beverages having an alcohol content of 0.00% by rounding off are included in the non-alcoholic beverage of the present invention.
  • examples of the beer-taste beverage of the present invention include non-alcohol beer-taste beverages and beer-taste soft drinks.
  • alcohol content (alcohol content) means the content of ethanol and does not include aliphatic alcohol.
  • the alcohol content of the beer-taste beverage of the present invention means the alcohol content (v / v%) in the beverage, and can be measured by any known method. Can be measured. Specifically, a sample obtained by removing carbon dioxide from a beverage by filtration or ultrasonic waves is prepared, the sample is subjected to direct-fire distillation, and the density of the obtained distillate at 15 ° C. is measured. Converted using “Table 2 Conversion Table of Alcohol Content, Density (15 ° C) and Specific Gravity (15/15 ° C)”, which is an appendix of the 19th National Tax Agency Instructions, revised on June 22, 2007 Can be obtained. When the alcohol concentration is a low concentration of less than 1.0%, a commercially available alcohol measuring device or gas chromatography may be used.
  • an aliphatic alcohol may be added.
  • the aliphatic alcohol is not particularly limited as long as it is a known one, but an aliphatic alcohol having 4 to 5 carbon atoms is preferable.
  • preferable aliphatic alcohols include those having 4 carbon atoms such as 2-methyl-1-propanol and 1-butanol, and those having 5 carbon atoms such as 3-methyl-1-butanol and 1-pentane. Examples include butanol and 2-pentanol. These can be used alone or in combination of two or more.
  • the content of the aliphatic alcohol having 4 to 5 carbon atoms is preferably 0.0002 to 0.0007% by mass, and more preferably 0.0003 to 0.0006% by mass.
  • the content of the aliphatic alcohol can be measured using a headspace gas chromatographic method.
  • the beer-taste beverage according to the present invention is desirably low in calories in accordance with recent low calorie preferences. Therefore, the number of calories in the beer-taste beverage of the present invention is preferably less than 5 kcal / 100 mL, more preferably less than 4 kcal / 100 mL, and even more preferably less than 3 kcal / 100 mL.
  • the number of calories contained in beverages is basically calculated according to “Regarding Methods for Analyzing Nutritional Components, etc. in Nutrition Labeling Standards” published in connection with the Health Promotion Act. That is, as a general rule, the amount of each quantified nutrient component is converted into an energy conversion factor (protein: 4 kcal / g, lipid: 9 kcal / g, carbohydrate: 4 kcal / g, dietary fiber: 2 kcal / g, alcohol: 7 kcal / g, organic acid: 3 kcal / g).
  • an energy conversion factor protein: 4 kcal / g, lipid: 9 kcal / g, carbohydrate: 4 kcal / g, dietary fiber: 2 kcal / g, alcohol: 7 kcal / g, organic acid: 3 kcal / g.
  • the specific method for measuring the amount of each nutritional component contained in the beverage may be in accordance with the various analytical methods described in the health promotion method “Analytical methods for nutritional components and the like in the nutrition labeling standards”. Or if you ask the Japan Food Analysis Center, you can know the amount of heat and / or the amount of each nutrient.
  • the saccharide in the present invention refers to a saccharide based on the nutrition labeling standard for food (2003, Ministry of Health, Labor and Welfare Notification No. 176). Specifically, the saccharide refers to a product obtained by removing protein, lipid, dietary fiber, ash, alcohol and water from food. In addition, the amount of carbohydrate in food is calculated by subtracting the amount of protein, lipid, dietary fiber, ash, and moisture from the weight of the food. In this case, the amounts of protein, lipid, dietary fiber, ash, and moisture are measured by the methods listed in the nutrition labeling standards.
  • the amount of protein is measured by the nitrogen quantitative conversion method
  • the amount of lipid is measured by the ether extraction method, chloroform / methanol mixed solution extraction method, gel bell method, acid decomposition method or rosese gottling method
  • ash content is measured by ashing method with magnesium acetate
  • water content is Karl Fischer method
  • the beer-taste beverage according to the present invention preferably has a low sugar content in accordance with the recent low sugar taste. Therefore, the sugar content of the beer-taste beverage of the present invention is preferably less than 0.5 g / 100 mL, more preferably 0.4 g / 100 mL or less, and still more preferably 0.3 g / 100 mL or less. Moreover, although a minimum in particular is not set, Usually, it is about 0.1g / 100mL, for example, may be 0.15g / 100mL or more, and may be 0.2g / 100mL or more.
  • hops can be used as part of the raw material. Since the flavor tends to resemble beer, it is desirable to use hops as part of the raw material.
  • hops normal pellet hops, powder hops, and hop extracts used in the production of beer and the like can be appropriately selected and used according to the desired flavor.
  • hop processed goods such as an isolation hop and a reduction
  • the amount of hop added is not particularly limited, but is typically about 0.0001 to 1% by weight relative to the total amount of beverage.
  • sweeteners including high-intensity sweeteners
  • flavorings including high-intensity sweeteners
  • yeast extracts colorants such as caramel pigments
  • plant-extracted saponin substances such as soybean saponin and quillaja saponin
  • plant proteins such as corn and soybean
  • peptide-containing substances Protein substances such as bovine serum albumin, dietary fibers (indigestible dextrin, soy dietary fiber, etc.) and seasonings such as amino acids, and antioxidants such as ascorbic acid are required as long as they do not interfere with the effects of the present invention. Can be used accordingly.
  • the beer-taste beverage of the present invention is obtained.
  • the pH of the beer taste drink of this invention should just be pH 3-4, Preferably it is pH3.0 or more, More preferably, it is pH3.6 or more. Moreover, it is preferably pH 4.0 or less, more preferably pH 3.8 or less.
  • the beer-taste beverage of the present invention can be packaged.
  • the form of the container is not limited at all, and can be filled into a sealed container such as a bottle, a can, a barrel, or a plastic bottle to make a beverage with a container.
  • the amount of the extract in the beverage was evaluated by the following method. That is, the extract content was measured according to BCOJ beer analysis method 7.2 extract. The specific gravity at 20 ° C. was measured using a vibrating densimeter, and the extract content was determined from the attached extract table. Among them, the amount of extract derived from wheat (malt) was determined by subtracting the amount of additives and other raw materials extracted separately from the total amount of extract.
  • the flavor of the beer taste drink was evaluated by the sensory test by a scoring method.
  • Six panelists specialize in beer-like flavor in the first half of the taste of the first half of the taste, about 0.5 to 1 second later, As a comprehensive evaluation, it was evaluated on a 5-point scale.
  • the average score is preferably 3.0 points or more.
  • the malt pulverized to an appropriate particle size was placed in a charging tank, and 120 L of warm water was added thereto to make a mash at about 50 ° C. After maintaining at 50 ° C. for 30 minutes, the temperature was gradually raised and saccharification was performed at 65 ° C. to 72 ° C. for 60 minutes. The mash after completion of saccharification was heated to 77 ° C., then transferred to a wort filtration tank and filtered to obtain a filtrate.
  • a portion of the obtained filtrate was taken and warm water was added. At that time, the mixing ratio of the filtrate and warm water was adjusted so that the amount of the extract at the completion of boiling reached the target value.
  • the production scale was 100 L, about 100 g of hops were added, and the mixture was boiled at 100 ° C. for 80 minutes. Ori is separated from the boiled liquid, cooled to about 2 ° C., diluted with wort, and collagen peptide (made by Nitta Gelatin Co., product name: SCP5100) to have the contents shown in Tables 1 and 2 is obtained.
  • Example 6 had the content described in Table 2
  • Example 7 and Comparative Example 5 had Table 2
  • Each sweetener was further added so as to have the content described in 1. above.
  • an appropriate amount of an antioxidant, a fragrance, and if necessary a caramel color is added, and after adding an acidulant so as to have a pH described in Tables 1 and 2, a commercially available iso- ⁇ acid is added to the product. It added so that a density
  • the beer taste drink was obtained through the process of filtration, bottling, and sterilization (heating at 65 degreeC or more for 10 minutes).
  • the content of C4 and C5 aliphatic alcohol in the obtained beer-taste beverage was 0.000467% by mass.
  • Example 8 and Comparative Example 6 ⁇ Production example 2 of non-alcohol beer-taste beverage>
  • the beer taste drink shown in Table 3 was prepared as follows.
  • hops are added to the same ratio as in Example 1 and boiled in the same manner, and the amount of extract at the end of boiling reaches the target value.
  • Add appropriate amount of collagen peptide manufactured by Nitta Gelatin Co., product name: SCP5100, molecular weight: 5100
  • antioxidant antioxidant
  • fragrance caramel color
  • Comparative Example 3 containing no carbon dioxide gas had a low evaluation in both the first half of the taste and the second half of the taste, and the overall evaluation of the flavor was also low.
  • Comparative Example 1 and Comparative Example 6 in which the content of iso ⁇ acid was 0.5 ⁇ 10 ⁇ 3 mass%, the evaluation was low in both the first and second half of the taste, and the overall evaluation of the flavor was also low.
  • Comparative Example 2 Comparative Example 4 and Comparative Example 5 in which the content of iso- ⁇ acid was 3.5 ⁇ 10 ⁇ 3 mass%, the evaluation of the latter half of the taste was low, and the overall evaluation was also low.
  • the beer-taste beverages of the examples were excellent in flavor balance and high overall evaluation in both the first half and the second half of the taste, regardless of whether or not the raw malt was used.
  • the beer-taste beverage of the present invention has a good taste with a good balance between acidity and bitterness, and has a taste like beer, and can provide a new taste as a taste product.

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  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
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  • Food Science & Technology (AREA)
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Abstract

An essentially non-alcoholic beer-taste beverage containing (A) a collagen peptide having an average molecular weight of 500-8000, (B) carbon dioxide gas, (C) iso-α acid, and (D) an acidulant, the pH of the beverage being 3 to 4, the content of the collagen peptide being 280-1800 mg/100 mL, and the content of the iso-α acid being 1.0×10-3 to 3.0×10-3% by mass. This beer-taste beverage has a first taste having a good balance of sourness and bitterness and has the apparent flavor of beer, and can provide a novel taste as a luxury grocery item.

Description

ノンアルコールのビールテイスト飲料Non-alcoholic beer-taste beverage
 本発明は、実質的にノンアルコールのビールテイスト飲料に関する。 The present invention relates to a substantially non-alcoholic beer-taste beverage.
 コラーゲンは、ゼラチンとして、食品分野で従来から広く用いられている。動物性蛋白質であるコラーゲンは、真皮や結合組織などの主成分であることから、近年、医療分野や美容分野の面からも注目を集めている。 Collagen has been widely used as a gelatin in the food field. Collagen, an animal protein, is the main component of dermis and connective tissue, and has recently attracted attention from the medical and cosmetic fields.
 一般に、高分子量のコラーゲンを経口で摂取しても、摂取したコラーゲンを体内で効率的に利用することが難しいとされるが、近年は、体内での摂取に適するよう、高分子のコラーゲンを低分子量化したコラーゲンペプチドが開発され、コラーゲンペプチド入りの飲料も開発されている。 In general, even if high molecular weight collagen is orally ingested, it is difficult to efficiently use the ingested collagen in the body. However, in recent years, high molecular weight collagen has been reduced to be suitable for ingestion in the body. Collagen peptides with molecular weight have been developed, and beverages containing collagen peptides have also been developed.
 このようなコラーゲンペプチドを含有する飲料は、清涼飲料水に分類され、殺菌の目的で加熱処理が行われている。殺菌の条件は、日本における食品衛生法(厚生省告示第213号)では、飲料のpHによって区別されている。食品衛生法には、保存基準がなく殺菌を要するものの製造基準として、pH4.0未満のものの殺菌は、中心部温度を65℃10分間加熱する方法又は同等以上の方法、pH4.0~4.6のものの殺菌は、85℃30分間加熱する方法又は同等以上の方法、と記載されている。 Beverages containing such collagen peptides are classified as soft drinks and are heat-treated for sterilization purposes. The sterilization conditions are distinguished by the pH of the beverage in the Food Sanitation Law in Japan (Ministry of Health and Welfare Notification No. 213). Although the food hygiene law has no storage standards and requires sterilization, as a production standard, sterilization of those with a pH less than 4.0 is a method of heating the center temperature at 65 ° C. for 10 minutes or a method equivalent to or higher, pH 4.0 to 4. The sterilization of No. 6 is described as a method of heating at 85 ° C. for 30 minutes or a method equal to or higher than that.
 コラーゲンペプチド含有飲料に関し、特許文献1には、リン酸を含む2種以上の酸味料を含有させ、pHを4.0以下にすることによって、防腐性に効果のあるpH4.0以下のpH範囲において、適度な酸味と良好な風味を実現した飲料組成物が開示されている。一方、ビールテイスト飲料へのコラーゲンペプチドの配合も試みられており、特許文献2には、発泡酒における泡の質をより肌理こまやかにし、泡の硬さをより保持し、長時間にわたって泡が消えないようにすることにより、発泡酒の味わいを保持する技術が開示されている。 Regarding collagen peptide-containing beverages, Patent Document 1 contains at least two acidulants containing phosphoric acid and has a pH range of 4.0 or less, which has an effect on antiseptic properties by making the pH 4.0 or less. Discloses a beverage composition that achieves moderate acidity and good flavor. On the other hand, a collagen peptide has been tried to be blended into a beer-taste beverage. Patent Document 2 discloses that the foam quality in the sparkling liquor is smoother, the foam hardness is maintained, and the foam disappears over a long period of time. A technique for preserving the taste of Happoshu by disabling it is disclosed.
特開2013-081418号公報JP2013-081418A 特開2008-271942号公報JP 2008-219442 A
 一般に、呈味は、飲料を口に含んだ後の時間経過とともに変化するが、酸味と苦味は、喫食直後から感じる先味として感じられ、先味のなかでも苦味は酸味よりも早く感じられる呈味である。そこで、本発明者らは、コラーゲンペプチドを配合したノンアルコールのビールテイスト飲料に関して、その呈味を詳細に検討したところ、先味を平坦な抑揚のない味わいとしてしまう問題点があることが判明した。 In general, taste changes with the passage of time after the beverage is put in the mouth, but sourness and bitterness are felt as tastes immediately after eating, and bitterness is felt earlier than acidity. It is a taste. Therefore, the present inventors have examined the taste in detail regarding a non-alcohol beer-taste beverage blended with a collagen peptide, and found that there is a problem that the taste is flat and without inflection. .
 また、コラーゲンペプチドには、pH緩衝能を有することが知られている。このため、飲料中にコラーゲンペプチドを含有させる場合は、そのpH緩衝能の影響を無視できなくなる。本発明者らは、香味維持のために飲料に大きな熱負荷を与えたくない観点から、コラーゲンペプチドを含有し、かつ、pH4.0以下という飲料設計を試みたところ、pHを下げるために多くの酸味料を使用する必要が生じ、その結果、平坦で抑揚のない先味の味わいの中で、遅れて酸味を感じ始める官能結果となり、いわゆるビールテイストの飲料としては、極めて違和感のある風味となってしまうことも判明した。 Further, collagen peptides are known to have pH buffering ability. For this reason, when the collagen peptide is contained in the beverage, the influence of the pH buffering ability cannot be ignored. The inventors of the present invention tried to design a beverage containing collagen peptide and having a pH of 4.0 or less from the viewpoint of not giving a large heat load to the beverage for maintaining the flavor. It becomes necessary to use acidulant, and as a result, it becomes a sensory result that begins to feel acidity lately in a flat and unconventional taste, and it has a very uncomfortable taste as a so-called beer-taste beverage. It was also found out.
 従って、本発明においては、コラーゲンペプチドを含有しつつも、pH4以下のpH範囲において、良好な風味を実現した実質的にノンアルコールのビールテイスト飲料を提供することを課題とする。 Therefore, an object of the present invention is to provide a substantially non-alcohol beer-taste beverage that contains a collagen peptide and realizes a good flavor in a pH range of pH 4 or lower.
 本発明者らが鋭意研究を進めたところ、飲料にイソα酸を特定量配合することが先味の呈味改善に大きく影響することが分かった。イソα酸は苦味として先味のなかでも酸味よりも早く感じ始める呈味を付与するが、特定量のイソα酸の添加により先味の前半で抑揚をつける効果を奏すると共に、先味の後半の呈味にも影響し酸味料とあいまって先味の後半のバランスを良くする知見を見出した。 As a result of extensive research by the present inventors, it has been found that blending a specific amount of iso-α acid into a beverage greatly affects the taste improvement of the taste. Iso-α acid gives a bitter taste that begins to feel faster than the sour taste, but the addition of a specific amount of iso-α acid has the effect of inducing the first half of the taste and the latter half of the taste. We found the findings that affect the taste of the taste and improve the balance of the second half of the taste in combination with the acidulant.
 即ち、本発明は、(A)平均分子量が500~8000のコラーゲンペプチド、(B)炭酸ガス、(C)イソα酸、及び(D)酸味料を含有し、pH3以上4以下であり、かつ、コラーゲンペプチドの含有量が280~1800mg/100mLであり、イソα酸の含有量が1.0×10-3~3.0×10-3質量%である、実質的にノンアルコールのビールテイスト飲料に関する。 That is, the present invention comprises (A) a collagen peptide having an average molecular weight of 500 to 8000, (B) carbon dioxide gas, (C) isoalpha acid, and (D) an acidulant, and has a pH of 3 or more and 4 or less, and A substantially non-alcohol beer taste having a collagen peptide content of 280 to 1800 mg / 100 mL and an isoalpha acid content of 1.0 × 10 −3 to 3.0 × 10 −3 mass% Regarding beverages.
 本発明によれば、コラーゲンペプチドを含有した実質的にノンアルコールのビールテイスト飲料において、pH4以下のpH範囲において酸味と苦味のバランスのよい先味を有し、かつビールらしい味わいのビールテイスト飲料を提供することができる。 According to the present invention, in a substantially non-alcohol beer-taste beverage containing a collagen peptide, a beer-taste beverage having a good taste of acidity and bitterness in a pH range of pH 4 or less and taste like beer. Can be provided.
 本発明にかかる、実質的にノンアルコールのビールテイスト飲料は、コラーゲンペプチドを含有するpH3以上4以下のpH範囲内の飲料において、特定量のイソα酸を含有することを特徴とする。 The substantially non-alcohol beer-taste beverage according to the present invention is characterized in that it contains a specific amount of iso-alpha acid in a beverage having a pH of 3 or more and 4 or less containing a collagen peptide.
 本発明にかかるビールテイスト飲料には、(A)コラーゲンペプチドが含まれる。本発明においてコラーゲンペプチドとは、平均分子量が8000以下となるように加水分解処理されたコラーゲンペプチドである。単なるコラーゲンでなくコラーゲンペプチドとすることによって、経口で摂取したときの体内への吸収性が高くなるため、飲料に関する本発明においてはコラーゲンペプチドを使用する。コラーゲンペプチドの平均分子量は、経口で摂取したときの体内への吸収性を高める観点から、上限は8000以下、好ましくは7000以下、より好ましくは6000以下、更に好ましくは5500以下である。また、実質的にノンアルコールのビールテイスト飲料において適度なボディ感を付与する観点から、粘性を考慮して、下限は500以上、好ましくは1000以上、より好ましくは1500以上、更に好ましくは2000以上である。これらいずれの組み合わせによる範囲としてもよい。例えば、コラーゲンペプチドの平均分子量は、500~8000であるが、好ましくは1000~7000であり、より好ましくは1500~6000であり、更に好ましくは2000~5500である。 The beer-taste beverage according to the present invention contains (A) a collagen peptide. In the present invention, the collagen peptide is a collagen peptide hydrolyzed so that the average molecular weight is 8000 or less. By using collagen peptide instead of mere collagen, the absorbability into the body when ingested orally is increased, and therefore in the present invention relating to beverages, collagen peptide is used. The average molecular weight of the collagen peptide is 8000 or less, preferably 7000 or less, more preferably 6000 or less, and even more preferably 5500 or less, from the viewpoint of enhancing absorbability into the body when taken orally. From the viewpoint of imparting an appropriate body feeling in a substantially non-alcoholic beer-taste beverage, considering the viscosity, the lower limit is 500 or more, preferably 1000 or more, more preferably 1500 or more, and still more preferably 2000 or more. is there. The range may be a combination of any of these. For example, the average molecular weight of the collagen peptide is 500 to 8000, preferably 1000 to 7000, more preferably 1500 to 6000, and still more preferably 2000 to 5500.
 本明細書において、コラーゲンペプチドの平均分子量は、ゲルパーミエーションクロマトグラフィー(GPC:ポリエチレングリコール(PEG)標準)にて測定した値を意味するが、市販品の場合には、供給元から提供される製品情報に従えばよい。
GPCでの平均分子量は、あらかじめ分子量が既知で異なるポリエチレングリコール(PEG)数種を同条件で測定して得られたリテンションタイムと分子量の関係の検量線を元に算出する。本発明における平均分子量とは、この手法に従ってPEG換算で算出した重量平均分子量を言う。
In the present specification, the average molecular weight of the collagen peptide means a value measured by gel permeation chromatography (GPC: polyethylene glycol (PEG) standard). In the case of a commercial product, it is provided from the supplier. Follow product information.
The average molecular weight in GPC is calculated based on a calibration curve of the relationship between retention time and molecular weight obtained by measuring several kinds of polyethylene glycol (PEG) having different molecular weights in advance under the same conditions. The average molecular weight in the present invention refers to a weight average molecular weight calculated in terms of PEG according to this method.
 本発明のコラーゲンペプチドは、ゼラチンを酵素や酸などによって加水分解して得ることができる。コラーゲンペプチドは、グリシンやヒドロキシプロリンを多く含むタンパク質であり、市販品としても入手可能である。コラーゲンとしては、哺乳類のコラーゲン組織から抽出したコラーゲンであっても、魚類のコラーゲン組織から抽出したコラーゲンであっても、特に限定されるものではない。商品イメージや安全性等の観点から、魚類由来のコラーゲンであることが好ましい。魚類由来のコラーゲンの原料としては、海水魚であっても淡水魚であってもよく、マグロ(キハダ)、サメ、タラ、ヒラメ、カレイ、タイ、テラピア、サケ、ナマズ等の皮が挙げられる。これらの魚類由来のコラーゲンは、魚類の鱗や皮から抽出したものである。哺乳類由来のコラーゲンの原料としては、ブタ、牛などが挙げられる。 The collagen peptide of the present invention can be obtained by hydrolyzing gelatin with an enzyme or acid. Collagen peptides are proteins containing a large amount of glycine and hydroxyproline, and are also available as commercial products. The collagen is not particularly limited, whether it is collagen extracted from mammalian collagen tissue or collagen extracted from fish. From the viewpoint of product image and safety, it is preferably a collagen derived from fish. The raw material for collagen derived from fish may be saltwater fish or freshwater fish, and skins of tuna (sharkfin), shark, cod, flounder, flounder, Thailand, tilapia, salmon, catfish and the like. These fish-derived collagens are extracted from fish scales and skins. Examples of the raw material for mammal-derived collagen include pigs and cows.
 本発明のコラーゲンペプチドの含有量は、飲料100mLあたり280~1800mgである。コラーゲンペプチドの含有量が1800mg/100mLを超えると、ノンアルコールビールテイスト飲料においては、コラーゲンペプチド由来の不快臭が感じられる場合がある。一方、コラーゲンペプチドの含有量が280mg/100mL未満であると、コラーゲンペプチドの有するpH緩衝能に対応する本発明の効果が小さくなる。コラーゲンペプチドの含有量は、350mg/100mL以上が好ましく、400mg/100mL以上がより好ましく、500mg/100mL以上が更に好ましく、1500mg/100mL以下が好ましく、1200mg/100mL以下がより好ましく、1000mg/100mL以下が更に好ましい。また、350~1500mg/100mLが好ましく、400~1200mg/100mLがより好ましく、500~1000mg/100mLが更に好ましい。また、コラーゲンぺプチドの含有量は一般財団法人・日本食品分析センターで分析することもでき、これによりコラーゲンぺプチドの濃度を測定することもできる。 The content of the collagen peptide of the present invention is 280 to 1800 mg per 100 mL of beverage. When the content of the collagen peptide exceeds 1800 mg / 100 mL, an unpleasant odor derived from the collagen peptide may be felt in the non-alcohol beer-taste beverage. On the other hand, when the content of the collagen peptide is less than 280 mg / 100 mL, the effect of the present invention corresponding to the pH buffering ability of the collagen peptide is reduced. The content of the collagen peptide is preferably 350 mg / 100 mL or more, more preferably 400 mg / 100 mL or more, further preferably 500 mg / 100 mL or more, preferably 1500 mg / 100 mL or less, more preferably 1200 mg / 100 mL or less, and 1000 mg / 100 mL or less. Further preferred. Further, 350 to 1500 mg / 100 mL is preferable, 400 to 1200 mg / 100 mL is more preferable, and 500 to 1000 mg / 100 mL is still more preferable. Further, the content of collagen peptide can be analyzed by the Japan Food Analysis Center, and the concentration of the collagen peptide can also be measured.
 本発明にかかるビールテイスト飲料には、ヒドロキシプロリンが含まれる。ヒドロキシプロリンはコラーゲンに特徴的なアミノ酸であり、本発明においては、(A)コラーゲンペプチドに由来するものであることが好ましい。ヒドロキシプロリンの含有量は、様々な手法で測定することができる。一例として、Nayama,Shibata,Ohtuki,Saitoの方法(藤本大三郎、永井裕(1985)、コラーゲン実験法、pp.51-56、講談社)に準じて測定することができる。また、一般財団法人・日本食品分析センターに委託して測定することもできる。本発明のビールテイスト飲料におけるヒドロキシプロリンの含有量としては、30mg/100mL以上が好ましく、36mg/100mL以上がより好ましく、42mg/100mL以上が更に好ましい。また、193mg/100mL以下が好ましく、161mg/100mL以下がより好ましく、128mg/100mL以下が更に好ましい。 The beer-taste beverage according to the present invention contains hydroxyproline. Hydroxyproline is an amino acid characteristic of collagen. In the present invention, hydroxyproline is preferably derived from (A) a collagen peptide. The content of hydroxyproline can be measured by various techniques. As an example, the measurement can be performed according to the method of Nayama, Shibata, Ohtuki, Saito (Daizaburo Fujimoto, Yu Nagai (1985), Collagen Experimental Method, pp. 51-56, Kodansha). It can also be measured by entrusting it to a general incorporated foundation, Japan Food Analysis Center. The content of hydroxyproline in the beer-taste beverage of the present invention is preferably 30 mg / 100 mL or more, more preferably 36 mg / 100 mL or more, and further preferably 42 mg / 100 mL or more. Moreover, 193 mg / 100 mL or less is preferable, 161 mg / 100 mL or less is more preferable, and 128 mg / 100 mL or less is still more preferable.
 また、本発明のビールテイスト飲料は、(B)炭酸ガスを含有する。圧入する(B)炭酸ガスは、コラーゲンペプチドに起因する先味の平坦さに抑揚をつけ、かつ呈味全般においてビールテイスト感を付与する観点から、本発明の飲料の炭酸ガス濃度は、0.4w/w%以上であることが好ましい。また、炭酸ガス濃度が高くなるにつれて刺激が強くなり先味に抑揚がつくため、炭酸ガス濃度としては、0.40~0.60w/w%であることが好ましく、更に0.45~0.55w/w%であることがより好ましく、更に0.48~0.52w/w%であることが更に好ましい。 The beer-taste beverage of the present invention contains (B) carbon dioxide gas. The carbon dioxide gas to be injected (B) has a carbon dioxide gas concentration of 0. 0 from the viewpoint of suppressing the flatness due to the collagen peptide and imparting a beer taste feeling in general taste. It is preferable that it is 4 w / w% or more. Also, as the carbon dioxide gas concentration increases, the irritation increases and the forehead is inflated, so the carbon dioxide gas concentration is preferably 0.40 to 0.60 w / w%, and more preferably 0.45 to 0.00. More preferably, it is 55 w / w%, still more preferably 0.48 to 0.52 w / w%.
 ガス濃度は当業者に良く知られている標準的な手法で測定することが出来る。測定には、従来技術の自動測定装置を用いても良い。例えば、ガスボリューム測定装置 GVA-500A(京都電子工業社)を用いることができる。ビールテイスト飲料中のガス含有量は、通常、重量%(w/w%またはg/kg)で表すほか、20℃におけるガス圧(kgf/cmまたはMPa)で表すことができる。炭酸ガスの濃度とガス圧は適宜換算可能である。本明細書中では特に断らない限り、炭酸ガス含有量を濃度(w/w%)で示す。 The gas concentration can be measured by standard techniques well known to those skilled in the art. For the measurement, a conventional automatic measuring apparatus may be used. For example, a gas volume measuring device GVA-500A (Kyoto Electronics Industry Co., Ltd.) can be used. The gas content in a beer-taste beverage can be generally expressed in terms of weight% (w / w% or g / kg) or in gas pressure at 20 ° C. (kgf / cm 2 or MPa). The concentration of carbon dioxide and the gas pressure can be converted as appropriate. In the present specification, unless otherwise specified, the content of carbon dioxide is indicated by concentration (w / w%).
 本発明にかかるビールテイスト飲料は、(C)イソα酸を含有する。イソα酸はビール製造に使われる原料であるホップに由来する苦味成分であり、α酸がイソ化した成分である。イソα酸の苦味が、飲料のビールテイスト感の付与に貢献する。本発明のビールテイスト飲料では、(C)イソα酸は、主にホップに由来するものであるが、ホップからの抽出物を配合してもよいし、市販のイソα酸製剤を配合してもよい。ホップの抽出手段としては公知の技術であれば何ら限定されず用いることができる。また、上記の1種又は2種以上を組み合わせて使用することもできる。 The beer-taste beverage according to the present invention contains (C) isoalpha acid. Iso-α acid is a bitter component derived from hop, which is a raw material used in beer production, and is a component obtained by isolating α-acid. The bitter taste of iso-α acid contributes to the beer taste of the beverage. In the beer-taste beverage of the present invention, (C) isoalpha acid is mainly derived from hops, but an extract from hops may be blended, or a commercially available isoalpha acid preparation may be blended. Also good. As a hop extraction means, any known technique can be used without any limitation. Moreover, it can also use combining said 1 type (s) or 2 or more types.
 イソα酸は、EBC(EuropeanBreweryConvention)が発行している分析法の規定「Analytica-EBC」のMethod7.7に従って測定することができる。本明細書においては、公知の方法であればいずれの方法に従っても測定することができる。本発明のビールテイスト飲料におけるイソα酸の含有量としては、1.0×10-3質量%以上3.0×10-3質量%以下であるが、先味前半の平坦さに抑揚をつけ、良質な香味バランスを実現する観点から、1.3×10-3質量%以上が好ましく、1.5×10-3質量%以上がより好ましい。また、先味後半の香味バランスを良好にする観点から、2.5×10-3質量%以下が好ましく、2.0×10-3質量%以下がより好ましい。 The isoalpha acid can be measured in accordance with Method 7.7 of “Analytica-EBC” defined in the analytical method published by EBC (European Brewery Convention). In this specification, the measurement can be performed according to any known method. The content of iso-α acid in the beer-taste beverage of the present invention is 1.0 × 10 −3 mass% or more and 3.0 × 10 −3 mass% or less. From the viewpoint of realizing a good flavor balance, the content is preferably 1.3 × 10 −3 mass% or more, more preferably 1.5 × 10 −3 mass% or more. Further, from the viewpoint of improving the flavor balance in the last half of the taste, it is preferably 2.5 × 10 −3 mass% or less, more preferably 2.0 × 10 −3 mass% or less.
 本発明にかかるビールテイスト飲料は、(D)酸味料を含有する。酸味料としては、クエン酸、乳酸、リン酸、及びリンゴ酸からなる群より選ばれる1種以上の酸を用いることが好ましい。また、本発明においては、前記酸以外の酸として、コハク酸、酒石酸、フマル酸および氷酢酸等も用いることができる。これらは食品に添加することが認められているものであれば制限なく用いることができる。本発明においては、まろやかな酸味を適切に付与する観点から乳酸と、やや刺激感のある酸味を適切に付与する観点からリン酸との組み合わせを用いることが好ましい。 The beer-taste beverage according to the present invention contains (D) a sour agent. As the acidulant, it is preferable to use one or more acids selected from the group consisting of citric acid, lactic acid, phosphoric acid, and malic acid. In the present invention, succinic acid, tartaric acid, fumaric acid, glacial acetic acid, and the like can also be used as acids other than the above acids. These can be used without limitation as long as they are permitted to be added to food. In the present invention, it is preferable to use a combination of lactic acid and phosphoric acid from the viewpoint of appropriately imparting a slightly pungent acidity from the viewpoint of appropriately imparting a mild acidity.
 酸味料の含有量は、本発明のビールテイスト飲料中、クエン酸換算で、1000ppm以上が好ましく、1200ppm以上がより好ましく、1400ppm以上が更に好ましい。また、3000ppm以下が好ましく、2500ppm以下がより好ましく、2000ppm以下が更に好ましい。酸を複数用いる場合は、合計含有量を意味する。なお、本明細書において、クエン酸換算量とは、クエン酸の酸味度を基準として各酸味料の酸味度から換算される量のことであり、例えば、乳酸100ppmに相当するクエン酸換算量は120ppm、リン酸100ppmに相当するクエン酸換算量は200ppm、リンゴ酸100ppmに相当するクエン酸換算量は125ppmとして換算する。 The content of the sour agent is preferably 1000 ppm or more, more preferably 1200 ppm or more, and further preferably 1400 ppm or more in terms of citric acid in the beer-taste beverage of the present invention. Moreover, 3000 ppm or less is preferable, 2500 ppm or less is more preferable, and 2000 ppm or less is still more preferable. When a plurality of acids are used, the total content is meant. In addition, in this specification, the citric acid conversion amount is an amount converted from the acidity of each acidulant based on the acidity of citric acid. For example, the citric acid conversion amount corresponding to 100 ppm of lactic acid is The citric acid equivalent corresponding to 120 ppm and phosphoric acid 100 ppm is converted to 200 ppm, and the citric acid equivalent corresponding to malic acid 100 ppm is converted to 125 ppm.
 イソα酸と酸味料との含有質量比(イソα酸/酸味料)としては、コラーゲンペプチドに起因する先味の平坦さに抑揚をつけ、かつ呈味全般においてビールテイスト感を付与する観点から、0.003~0.030が好ましく、0.003~0.019がより好ましく、0.005~0.017が更に好ましく、0.008~0.014が更に好ましい。 The content ratio of iso-alpha acid to acidulant (iso-alpha acid / acidulant) is from the standpoint of imparting a beer-taste to the taste as a whole, and to suppress flatness due to collagen peptides. 0.003 to 0.030 is preferable, 0.003 to 0.019 is more preferable, 0.005 to 0.017 is still more preferable, and 0.008 to 0.014 is still more preferable.
 本発明に係るビールテイスト飲料は、コラーゲンペプチドを用いる以外は、一般的なノンアルコールビールテイスト飲料と同様にして製造できる。以下に、一般的な非発酵のノンアルコールビールテイスト飲料の製造工程を下記に示す。酵母による発酵工程を有さないことにより、ノンアルコールビール等のノンアルコールビールテイスト飲料を容易に製造することができる。一般的な非発酵のノンアルコールビールテイスト飲料は麦芽を原料として使用するものとしないものとがあり以下のように製造することができる。 The beer-taste beverage according to the present invention can be produced in the same manner as a general non-alcohol beer-taste beverage except that a collagen peptide is used. Below, the manufacturing process of a general non-fermented non-alcohol beer taste drink is shown below. By not having a fermentation process with yeast, non-alcohol beer-taste beverages such as non-alcohol beer can be easily produced. General non-fermented non-alcohol beer-taste beverages may or may not use malt as a raw material and can be produced as follows.
 麦芽を原料として使用して製造されるノンアルコールビールテイスト飲料は、まず、麦芽等の麦の他、必要に応じて他の穀物、でんぷん、糖類、苦味料、又は着色料などの原料及び水を含む混合物に、必要に応じてアミラーゼなどの酵素を添加し、糊化、糖化を行なわせ、ろ過し、糖化液とする。必要に応じてホップや苦味料などを糖化液に加えて煮沸し、清澄タンクにて凝固タンパク質などの固形分を取り除く。この糖化液の代替として、麦芽エキスに温水を加えたものにホップを加えて煮沸してもよい。ホップは煮沸開始から煮沸終了前のどの段階で混合してもよい。糖化工程、煮沸工程、固形分除去工程などにおける条件は、知られている条件を用いればよい。煮沸後、得られた麦汁を濾過し、得られた濾過液に炭酸ガスを加える。その後、容器に充填し殺菌工程を経て目的のノンアルコールビールテイスト飲料を得る。コラーゲンペプチドは、充填までのどのタイミングで混合させてもよい。 Non-alcoholic beer-taste beverages produced using malt as a raw material are first made from wheat such as malt, as well as other raw materials such as cereals, starch, sugars, bitters, or colorants and water as required. If necessary, an enzyme such as amylase is added to the mixture to be gelatinized and saccharified, followed by filtration to obtain a saccharified solution. If necessary, add hops, bitters, etc. to the saccharified solution and boil, and remove solids such as coagulated protein in the clarification tank. As an alternative to this saccharified solution, hops may be added to the malt extract added with warm water and boiled. Hops may be mixed at any stage from the start of boiling to the end of boiling. Known conditions may be used as conditions in the saccharification process, boiling process, solid content removal process, and the like. After boiling, the obtained wort is filtered, and carbon dioxide gas is added to the obtained filtrate. Then, the container is filled and the target non-alcohol beer-taste drink is obtained through a sterilization process. The collagen peptide may be mixed at any timing until filling.
 麦芽を原料として使用しないノンアルコールビールテイスト飲料を製造する場合には、まず、炭素源を含有する液糖、麦又は麦芽以外のアミノ酸含有材料としての窒素源、ホップ、色素等を、温水と共に混合し、液糖溶液とする。該液糖溶液は、煮沸する。原料としてホップを用いる場合、ホップは煮沸開始前ではなく、煮沸中に、該液糖溶液に混合してもよい。煮沸後の液糖溶液に対して、炭酸ガスを加える。その後、容器に充填し殺菌工程を経て目的のノンアルコールビールテイスト飲料を得る。コラーゲンペプチドは、充填までのどのタイミングで投入混合させてもよい。 When producing non-alcohol beer-taste beverages that do not use malt as a raw material, first, liquid sugar containing carbon source, nitrogen source as amino acid-containing material other than wheat or malt, hop, pigment, etc. are mixed with warm water And a liquid sugar solution. The liquid sugar solution is boiled. When using hops as a raw material, the hops may be mixed with the liquid sugar solution during boiling, not before the start of boiling. Carbon dioxide gas is added to the liquid sugar solution after boiling. Then, the container is filled and the target non-alcohol beer-taste drink is obtained through a sterilization process. The collagen peptide may be charged and mixed at any timing until filling.
 コラーゲンペプチドがボディやコクを与えるため、爽快なビールテイスト飲料にするには、エキス分の総量が所定の範囲内であることが好ましい。本明細書における「エキス分の量」は、飲料のアルコール度数が0.005%以上の場合、日本の酒税法におけるエキス分、すなわち、温度15度の時において原容量100立方センチメートル中に含有する不揮発性成分のグラム数をいい、アルコール度数が0.005%未満の飲料においては、脱ガスしたサンプルをビール酒造組合国際技術委員会(BCOJ)が定める「ビール分析法 7.2 エキス」に従い測定したエキス値(重量%)をいう。エキス分全体の内、麦芽等の麦に由来するエキス分の量は、例えば、総エキス分の量を実測で求めた上で、別途求めた添加物や他の原料のエキス分の量を減じることで求めることができる。 Since the collagen peptide gives body and richness, it is preferable that the total amount of the extract is within a predetermined range in order to make a refreshing beer-taste beverage. The “amount of extract” in the present specification refers to the extract in the Japanese liquor tax law when the alcohol content of the beverage is 0.005% or more, that is, the nonvolatile content contained in the original capacity of 100 cubic centimeters at a temperature of 15 degrees. This refers to the number of grams of the sex component. For beverages with an alcohol content of less than 0.005%, the degassed sample was measured according to the “Beer Analysis Method 7.2 Extract” established by the International Technical Committee of the Brewery Association (BCOJ). The extract value (% by weight). Of the whole extract, the amount of extract derived from wheat such as malt is obtained by, for example, finding the amount of total extract and measuring the amount of the additive or other raw material obtained separately. Can be obtained.
 本明細書における「ビールテイスト飲料」とは、ビール様の風味をもつ炭酸飲料をいう。つまり、本明細書のビールテイスト飲料は、特に断わりがない場合、ビール風味の炭酸飲料を全て包含する。本発明は、この飲料の内の、実質的にノンアルコールタイプのものに向けられ、そのアルコール度数は、0.005%以下であり、好ましくは、アルコールを実質的に含まない。ここで、アルコールを実質的に含まない本発明の飲料(ノンアルコール飲料)は、検出できない程度の極く微量のアルコールを含有する飲料を除くものではない。アルコール度数が四捨五入により0.0%となる飲料、中でも、アルコール度数が四捨五入により0.00%となる飲料は、本発明のノンアルコール飲料に包含される。本発明のビールテイスト飲料の種類としては、例えば、ノンアルコールのビールテイスト飲料、ビールテイストの清涼飲料などが含まれる。なお、ここでの「アルコール度数(アルコール含有量)」はエタノールの含有量を意味し、脂肪族アルコールは含まれない。 In this specification, “beer-taste beverage” refers to a carbonated beverage having a beer-like flavor. That is, the beer-taste beverage of this specification includes all beer-flavored carbonated beverages unless otherwise specified. The present invention is directed to a substantially non-alcoholic type of this beverage, the alcohol content of which is 0.005% or less, and is preferably substantially free of alcohol. Here, the beverage of the present invention that substantially does not contain alcohol (non-alcoholic beverage) does not exclude beverages that contain an extremely small amount of alcohol that cannot be detected. Beverages having an alcohol content of 0.0% by rounding off, and beverages having an alcohol content of 0.00% by rounding off are included in the non-alcoholic beverage of the present invention. Examples of the beer-taste beverage of the present invention include non-alcohol beer-taste beverages and beer-taste soft drinks. Here, “alcohol content (alcohol content)” means the content of ethanol and does not include aliphatic alcohol.
 本発明のビールテイスト飲料のアルコール度数は、飲料中のアルコール分の含有量(v/v%)を意味し、公知のいずれの方法によっても測定することができるが、例えば、振動式密度計によって測定することができる。具体的には、飲料から濾過又は超音波によって炭酸ガスを抜いた試料を調製し、そして、その試料を直火蒸留し、得られた留液の15℃における密度を測定し、国税庁所定分析法(平19国税庁訓令第6号、平成19年6月22日改訂)の付表である「第2表アルコール分と密度(15℃)及び比重(15/15℃)換算表」を用いて換算して求めることができる。アルコール度が1.0%未満の低濃度の場合は、市販のアルコール測定装置や、ガスクロマトグラフィーを用いても良い。 The alcohol content of the beer-taste beverage of the present invention means the alcohol content (v / v%) in the beverage, and can be measured by any known method. Can be measured. Specifically, a sample obtained by removing carbon dioxide from a beverage by filtration or ultrasonic waves is prepared, the sample is subjected to direct-fire distillation, and the density of the obtained distillate at 15 ° C. is measured. Converted using “Table 2 Conversion Table of Alcohol Content, Density (15 ° C) and Specific Gravity (15/15 ° C)”, which is an appendix of the 19th National Tax Agency Instructions, revised on June 22, 2007 Can be obtained. When the alcohol concentration is a low concentration of less than 1.0%, a commercially available alcohol measuring device or gas chromatography may be used.
 本発明にかかるビールテイスト飲料に、酒感を付与する観点から、脂肪族アルコールを添加してもよい。脂肪族アルコールとしては、公知のものであれば特に制限されないが、炭素数4~5の脂肪族アルコールが好ましい。本発明において、好ましい脂肪族アルコールとしては、炭素数4のものとして、2-メチル-1-プロパノール、1-ブタノール等が、炭素数5のものとして、3-メチル-1-ブタノール、1-ペンタノール、2-ペンタノール等が挙げられる。これらは1種又は2種以上の組み合せで用いることができる。炭素数4~5の脂肪族アルコールの含有量は好ましくは0.0002~0.0007質量%であり、より好ましくは0.0003~0.0006質量%である。本明細書において、脂肪族アルコールの含有量は、ヘッドスペースガスクロマトグラフ法を用いて測定することができる。 From the viewpoint of imparting a sense of alcohol to the beer-taste beverage according to the present invention, an aliphatic alcohol may be added. The aliphatic alcohol is not particularly limited as long as it is a known one, but an aliphatic alcohol having 4 to 5 carbon atoms is preferable. In the present invention, preferable aliphatic alcohols include those having 4 carbon atoms such as 2-methyl-1-propanol and 1-butanol, and those having 5 carbon atoms such as 3-methyl-1-butanol and 1-pentane. Examples include butanol and 2-pentanol. These can be used alone or in combination of two or more. The content of the aliphatic alcohol having 4 to 5 carbon atoms is preferably 0.0002 to 0.0007% by mass, and more preferably 0.0003 to 0.0006% by mass. In the present specification, the content of the aliphatic alcohol can be measured using a headspace gas chromatographic method.
(カロリー)
 本発明にかかるビールテイスト飲料は、近年の低カロリー嗜好に合わせて、低カロリーであることが望ましい。従って、本発明のビールテイスト飲料のカロリー数は、好ましくは5kcal/100mL未満、より好ましくは4kcal/100mL未満、更に好ましくは3kcal/100mL未満である。
(calorie)
The beer-taste beverage according to the present invention is desirably low in calories in accordance with recent low calorie preferences. Therefore, the number of calories in the beer-taste beverage of the present invention is preferably less than 5 kcal / 100 mL, more preferably less than 4 kcal / 100 mL, and even more preferably less than 3 kcal / 100 mL.
 飲料に含まれるカロリー数は、基本的に健康増進法に関連して公表されている「栄養表示基準における栄養成分等の分析方法等について」に従って算出する。すなわち、原則として、定量した各種栄養成分の量に、それぞれの成分のエネルギー換算係数(タンパク質:4kcal/g、脂質:9kcal/g、糖質:4kcal/g、食物繊維:2kcal/g、アルコール:7kcal/g、有機酸:3kcal/g)を乗じたものの総和として算出することができる。詳細は、「栄養表示基準における栄養成分等の分析方法等について」を参照されたい。 The number of calories contained in beverages is basically calculated according to “Regarding Methods for Analyzing Nutritional Components, etc. in Nutrition Labeling Standards” published in connection with the Health Promotion Act. That is, as a general rule, the amount of each quantified nutrient component is converted into an energy conversion factor (protein: 4 kcal / g, lipid: 9 kcal / g, carbohydrate: 4 kcal / g, dietary fiber: 2 kcal / g, alcohol: 7 kcal / g, organic acid: 3 kcal / g). For details, refer to “Analytical Methods for Nutritional Components, etc. in Nutrition Labeling Standards”.
 飲料に含まれる各栄養成分量の具体的な測定手法は、健康増進法「栄養表示基準における栄養成分等の分析方法等について」に記載の各種分析法に従えばよい。または、財団法人 日本食品分析センターに依頼すれば、このような熱量及び/又は各栄養成分量を知ることができる。 The specific method for measuring the amount of each nutritional component contained in the beverage may be in accordance with the various analytical methods described in the health promotion method “Analytical methods for nutritional components and the like in the nutrition labeling standards”. Or if you ask the Japan Food Analysis Center, you can know the amount of heat and / or the amount of each nutrient.
(糖質)
 本発明でいう糖質とは、食品の栄養表示基準(平成15年厚生労働省告示第176号)に基づく糖質をいう。具体的には、糖質は、食品から、タンパク質、脂質、食物繊維、灰分、アルコール分及び水分を除いたものをいう。また、食品中の糖質の量は、当該食品の重量から、タンパク質、脂質、食物繊維、灰分及び水分の量を控除することにより算定される。この場合に、タンパク質、脂質、食物繊維、灰分及び水分の量は、栄養表示基準に掲げる方法により測定する。具体的には、タンパク質の量は窒素定量換算法で測定し、脂質の量はエーテル抽出法、クロロホルム・メタノール混液抽出法、ゲルベル法、酸分解法またはレーゼゴットリーブ法で測定し、食物繊維の量は高速液体クロマトグラフ法またはプロスキー法で測定し、灰分の量は酢酸マグネシウム添加灰化法、直接灰化法または硫酸添加灰化法で測定し、水分の量はカールフィッシャー法、乾燥助剤法、減圧過熱乾燥法、常圧加熱乾燥法またはプラスチックフィルム法で測定する。
(Sugar)
The saccharide in the present invention refers to a saccharide based on the nutrition labeling standard for food (2003, Ministry of Health, Labor and Welfare Notification No. 176). Specifically, the saccharide refers to a product obtained by removing protein, lipid, dietary fiber, ash, alcohol and water from food. In addition, the amount of carbohydrate in food is calculated by subtracting the amount of protein, lipid, dietary fiber, ash, and moisture from the weight of the food. In this case, the amounts of protein, lipid, dietary fiber, ash, and moisture are measured by the methods listed in the nutrition labeling standards. Specifically, the amount of protein is measured by the nitrogen quantitative conversion method, and the amount of lipid is measured by the ether extraction method, chloroform / methanol mixed solution extraction method, gel bell method, acid decomposition method or rosese gottlieb method, and the amount of dietary fiber Is measured by high performance liquid chromatograph method or Prosky method, ash content is measured by ashing method with magnesium acetate, direct ashing method or ashing method with sulfuric acid, and water content is Karl Fischer method, drying aid Measured by a method, a vacuum heating drying method, a normal pressure heating drying method, or a plastic film method.
 本発明にかかるビールテイスト飲料は、近年の低糖質嗜好に合わせて、低糖質であることが望ましい。従って、本発明のビールテイスト飲料の糖質の含有量は、好ましくは0.5g/100mL未満、より好ましくは0.4g/100mL以下、更に好ましくは0.3g/100mL以下である。また、下限は特に設定されないが、通常、0.1g/100mL程度であり、例えば、0.15g/100mL以上であっても、0.2g/100mL以上であってもよい。 The beer-taste beverage according to the present invention preferably has a low sugar content in accordance with the recent low sugar taste. Therefore, the sugar content of the beer-taste beverage of the present invention is preferably less than 0.5 g / 100 mL, more preferably 0.4 g / 100 mL or less, and still more preferably 0.3 g / 100 mL or less. Moreover, although a minimum in particular is not set, Usually, it is about 0.1g / 100mL, for example, may be 0.15g / 100mL or more, and may be 0.2g / 100mL or more.
(ホップ)
 本発明のビールテイスト飲料においては、原料の一部にホップを用いることができる。香味がビールに類似する傾向にあることから、原料の一部にホップを用いることが望ましい。ホップを使用する際には、ビール等の製造に使用される通常のペレットホップ、粉末ホップ、ホップエキスを、所望の香味に応じて適宜選択して使用することができる。また、イソ化ホップ、還元ホップなどのホップ加工品を用いてもよい。本発明におけるホップには、これらのものが包含される。また、ホップの添加量は特に限定されないが、典型的には、飲料全量に対して0.0001~1重量%程度である。
(hop)
In the beer-taste beverage of the present invention, hops can be used as part of the raw material. Since the flavor tends to resemble beer, it is desirable to use hops as part of the raw material. When using hops, normal pellet hops, powder hops, and hop extracts used in the production of beer and the like can be appropriately selected and used according to the desired flavor. Moreover, you may use hop processed goods, such as an isolation hop and a reduction | restoration hop. These are included in the hops in the present invention. The amount of hop added is not particularly limited, but is typically about 0.0001 to 1% by weight relative to the total amount of beverage.
(その他の原料)
 本発明では、本発明の効果を妨げない範囲で、必要に応じて、その他の原料を用いてもよい。例えば、甘味料(高甘味度甘味料を含む)、香料、酵母エキス、カラメル色素などの着色料、大豆サポニンやキラヤサポニン等の植物抽出サポニン系物質、コーンや大豆などの植物タンパク質およびペプチド含有物、ウシ血清アルブミン等のタンパク質系物質、食物繊維(難消化性デキストリン、大豆食物繊維など)やアミノ酸などの調味料、アスコルビン酸等の酸化防止剤を、本発明の効果を妨げない範囲で必要に応じて用いることができる。
(Other raw materials)
In this invention, you may use another raw material as needed in the range which does not prevent the effect of this invention. For example, sweeteners (including high-intensity sweeteners), flavorings, yeast extracts, colorants such as caramel pigments, plant-extracted saponin substances such as soybean saponin and quillaja saponin, plant proteins such as corn and soybean, and peptide-containing substances , Protein substances such as bovine serum albumin, dietary fibers (indigestible dextrin, soy dietary fiber, etc.) and seasonings such as amino acids, and antioxidants such as ascorbic acid are required as long as they do not interfere with the effects of the present invention. Can be used accordingly.
 かくして本発明のビールテイスト飲料が得られる。本発明のビールテイスト飲料のpHはpH3以上4以下であればよいが、好ましくはpH3.0以上、より好ましくはpH3.6以上である。また、好ましくはpH4.0以下、より好ましくはpH3.8以下である。 Thus, the beer-taste beverage of the present invention is obtained. Although the pH of the beer taste drink of this invention should just be pH 3-4, Preferably it is pH3.0 or more, More preferably, it is pH3.6 or more. Moreover, it is preferably pH 4.0 or less, more preferably pH 3.8 or less.
(容器詰飲料)
 本発明のビールテイスト飲料は、容器詰めとすることができる。容器の形態は何ら制限されず、ビン、缶、樽、またはペットボトル等の密封容器に充填して、容器入り飲料とすることができる。
(Packed beverage)
The beer-taste beverage of the present invention can be packaged. The form of the container is not limited at all, and can be filled into a sealed container such as a bottle, a can, a barrel, or a plastic bottle to make a beverage with a container.
 以下、実施例を示して本発明を具体的に説明するが、本発明は下記実施例に制限されるものではない。 Hereinafter, the present invention will be specifically described with reference to examples, but the present invention is not limited to the following examples.
<エキス分の評価>
 実施例においては、飲料中のエキス分の量を以下の方法により評価した。即ち、エキス分はBCOJビール分析法 7.2 エキス に従って計測した。20℃での比重を振動式密度計を使用して計測し、付属のエキス表によりエキス分を求めた。その中の、麦(麦芽)に由来するエキス分の量は、エキス分の総量から、別途求めた添加物や他の原料のエキス分の量を減じることで求めた。
<Evaluation of extract>
In the examples, the amount of the extract in the beverage was evaluated by the following method. That is, the extract content was measured according to BCOJ beer analysis method 7.2 extract. The specific gravity at 20 ° C. was measured using a vibrating densimeter, and the extract content was determined from the attached extract table. Among them, the amount of extract derived from wheat (malt) was determined by subtracting the amount of additives and other raw materials extracted separately from the total amount of extract.
<脂肪族アルコールの含有量測定>
 ヘッドスペースガスクロマトグラフ法を用いて測定した。
<Measurement of content of aliphatic alcohol>
Measurement was performed using a headspace gas chromatograph method.
<カロリーの評価>
 カロリーは、健康増進法に関連して公表されている「栄養表示基準における栄養成分等の分析方法等について」に従って算出した。
<Evaluation of calories>
The calories were calculated according to “Analytical Methods for Nutritional Components, etc. in Nutrition Labeling Standards” published in connection with the Health Promotion Law.
<糖質の評価>
 糖質の測定は、栄養表示基準(平成15年厚生労働省告示第176号)による計算式を用いた。
<Evaluation of carbohydrates>
For the measurement of sugar, a calculation formula based on nutrition labeling standards (2003, Ministry of Health, Labor and Welfare Notification No. 176) was used.
<香味の評価>
 本明細書において、ビールテイスト飲料の香味を、評点法による官能試験によって評価した。専門パネリスト6名が、ビール様の香味について、口に含んで約0~0.5秒後の先味前半の香味バランス、約0.5~1秒後の先味後半の香味バランス、更に、総合評価として、5点満点で評価した。「非常によい」=5点、「よい」=4点、「ふつう」=3点、「やや劣る」=2点、「劣る」=1点として、評価点の平均点を算出した。平均点が3.0点以上であることが好ましい。
<Evaluation of flavor>
In this specification, the flavor of the beer taste drink was evaluated by the sensory test by a scoring method. Six panelists specialize in beer-like flavor in the first half of the taste of the first half of the taste, about 0.5 to 1 second later, As a comprehensive evaluation, it was evaluated on a 5-point scale. The average score of the evaluation points was calculated with “very good” = 5 points, “good” = 4 points, “normal” = 3 points, “slightly inferior” = 2 points, and “poor” = 1 point. The average score is preferably 3.0 points or more.
実施例1~7及び比較例1~5
<ノンアルコールビールテイスト飲料の製造例1>
 表1及び2に示すビールテイスト飲料を下記のように調製した。
Examples 1 to 7 and Comparative Examples 1 to 5
<Production example 1 of non-alcoholic beer-taste beverage>
The beer-taste beverages shown in Tables 1 and 2 were prepared as follows.
 具体的には、麦芽を適当な粒度に粉砕したものを仕込槽に入れ、これに120Lの温水を加え、約50℃のマッシュを作った。50℃で30分保持後、徐々に昇温して65℃~72℃で60分間、糖化を行った。糖化が完了したマッシュを77℃まで昇温後、麦汁濾過槽に移し濾過を行い、濾液を得た。 Specifically, the malt pulverized to an appropriate particle size was placed in a charging tank, and 120 L of warm water was added thereto to make a mash at about 50 ° C. After maintaining at 50 ° C. for 30 minutes, the temperature was gradually raised and saccharification was performed at 65 ° C. to 72 ° C. for 60 minutes. The mash after completion of saccharification was heated to 77 ° C., then transferred to a wort filtration tank and filtered to obtain a filtrate.
 得られた濾液の一部をとり、温水を加え、その際、濾液と温水の混合割合は、煮沸完了時のエキス分の量が目標とする値になるよう調節した。製造スケールを100Lとし、ホップを約100g添加し、100℃で80分間煮沸をした。煮沸後の液からオリを分離し、約2℃に冷却後、麦汁を希釈し、表1及び表2に記載の含有量となるようにコラーゲンペプチド(新田ゼラチン社製、製品名:SCP5100、分子量:5100)を加え、実施例6は表2に記載の含有量となるように食物繊維(松谷化学社製、製品名:E-ファイバー)を、実施例7と比較例5は表2に記載の含有量となるように甘味料を、それぞれ更に加えた。次いで、いずれのサンプルも、酸化防止剤、香料、必要によりカラメル色素を適量加え、それぞれ表1及び表2に記載のpHとなるように酸味料を添加した後、市販のイソα酸を、製品濃度が表1及び表2に記載の含有量となるように添加して約24時間貯蔵した。その間、炭酸ガスを適量添加した。その後、濾過・瓶詰め・殺菌(65℃以上で10分間加熱)の工程を経て、ビールテイスト飲料を得た。なお、得られたビールテイスト飲料における炭素数4及び炭素数5の脂肪族アルコール含有量は0.000467質量%であった。 A portion of the obtained filtrate was taken and warm water was added. At that time, the mixing ratio of the filtrate and warm water was adjusted so that the amount of the extract at the completion of boiling reached the target value. The production scale was 100 L, about 100 g of hops were added, and the mixture was boiled at 100 ° C. for 80 minutes. Ori is separated from the boiled liquid, cooled to about 2 ° C., diluted with wort, and collagen peptide (made by Nitta Gelatin Co., product name: SCP5100) to have the contents shown in Tables 1 and 2 is obtained. , Molecular weight: 5100), and dietary fiber (manufactured by Matsutani Chemical Co., Ltd., product name: E-fiber) was used so that Example 6 had the content described in Table 2, and Example 7 and Comparative Example 5 had Table 2 Each sweetener was further added so as to have the content described in 1. above. Next, in each sample, an appropriate amount of an antioxidant, a fragrance, and if necessary a caramel color is added, and after adding an acidulant so as to have a pH described in Tables 1 and 2, a commercially available iso-α acid is added to the product. It added so that a density | concentration might become content of Table 1 and Table 2, and it stored for about 24 hours. Meanwhile, an appropriate amount of carbon dioxide gas was added. Then, the beer taste drink was obtained through the process of filtration, bottling, and sterilization (heating at 65 degreeC or more for 10 minutes). In addition, the content of C4 and C5 aliphatic alcohol in the obtained beer-taste beverage was 0.000467% by mass.
実施例8及び比較例6
<ノンアルコールビールテイスト飲料の製造例2>
 表3に示すビールテイスト飲料を下記のように調製した。
Example 8 and Comparative Example 6
<Production example 2 of non-alcohol beer-taste beverage>
The beer taste drink shown in Table 3 was prepared as follows.
 具体的には、実施例1において麦汁を用いる代わりに、実施例1と同じ割合となるようホップを添加して同様に煮沸し、煮沸完了時のエキス分の量が目標とする値になるよう調節した後の液糖溶液に、表3に記載の含有量となるように食物繊維(松谷化学社製、製品名:E-ファイバー)を添加した溶液を調製し、次いで、表3に記載の含有量となるようにコラーゲンペプチド(新田ゼラチン社製、製品名:SCP5100、分子量:5100)と、酸化防止剤、香料、必要によりカラメル色素を適量、それぞれ加え、表3に記載のpHとなるように酸味料を添加した後、市販のイソα酸を、製品濃度が表3に記載の含有量となるように添加して約24時間貯蔵した。その間、炭酸ガスを適量添加した。その後、濾過・瓶詰め・殺菌(65℃以上で10分間加熱)の工程を経て、ビールテイスト飲料を得た。なお、得られたビールテイスト飲料における炭素数4及び炭素数5の脂肪族アルコール含有量は0.000467質量%であった。 Specifically, instead of using wort in Example 1, hops are added to the same ratio as in Example 1 and boiled in the same manner, and the amount of extract at the end of boiling reaches the target value. A solution in which dietary fiber (manufactured by Matsutani Chemical Co., Ltd., product name: E-fiber) was added to the liquid sugar solution after adjustment was adjusted to the content shown in Table 3 was prepared. Add appropriate amount of collagen peptide (manufactured by Nitta Gelatin Co., product name: SCP5100, molecular weight: 5100), antioxidant, fragrance, and caramel color if necessary, so that the pH shown in Table 3 is obtained. After the acidulant was added, commercially available isoα acid was added so that the product concentration was as shown in Table 3 and stored for about 24 hours. Meanwhile, an appropriate amount of carbon dioxide gas was added. Then, the beer taste drink was obtained through the process of filtration, bottling, and sterilization (heating at 65 degreeC or more for 10 minutes). In addition, the content of C4 and C5 aliphatic alcohol in the obtained beer-taste beverage was 0.000467% by mass.
 得られたビールテイスト飲料について、上記評価方法により香味を評価した。結果を表1~3に示す。 For the obtained beer-taste beverage, the flavor was evaluated by the above evaluation method. The results are shown in Tables 1 to 3.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000003
 表1~3から明らかな通り、炭酸ガスを含有しない比較例3は先味前半、先味の後半ともに評価が低く、また香味の総合評価も低いものであった。また、イソα酸の含有量が0.5×10-3質量%の比較例1及び比較例6では、先味の前半後半ともに評価が低く、また香味の総合評価も低いものであった。さらに、イソα酸の含有量が3.5×10-3質量%の比較例2、比較例4及び比較例5では、先味の後半の評価が低くなり、総合評価も低いものであった。一方、実施例のビールテイスト飲料は、原料麦芽の使用有無に関わらず、先味前半、後半共に香味のバランスに優れ、総合評価も高いものであった。 As is apparent from Tables 1 to 3, Comparative Example 3 containing no carbon dioxide gas had a low evaluation in both the first half of the taste and the second half of the taste, and the overall evaluation of the flavor was also low. In Comparative Example 1 and Comparative Example 6 in which the content of isoα acid was 0.5 × 10 −3 mass%, the evaluation was low in both the first and second half of the taste, and the overall evaluation of the flavor was also low. Furthermore, in Comparative Example 2, Comparative Example 4 and Comparative Example 5 in which the content of iso-α acid was 3.5 × 10 −3 mass%, the evaluation of the latter half of the taste was low, and the overall evaluation was also low. . On the other hand, the beer-taste beverages of the examples were excellent in flavor balance and high overall evaluation in both the first half and the second half of the taste, regardless of whether or not the raw malt was used.
 本発明のビールテイスト飲料は、酸味と苦味のバランスのよい先味を有し、かつビールらしい味わいを有するものであり、嗜好品として新たなテイストを提供できる。 The beer-taste beverage of the present invention has a good taste with a good balance between acidity and bitterness, and has a taste like beer, and can provide a new taste as a taste product.

Claims (7)

  1.  (A)平均分子量が500~8000のコラーゲンペプチド、
    (B)炭酸ガス、
    (C)イソα酸、及び
    (D)酸味料、
    を含有し、pH3以上4以下であり、かつコラーゲンペプチドの含有量が280~1800mg/100mLであり、イソα酸の含有量が1.0×10-3~3.0×10-3質量%である、実質的にノンアルコールのビールテイスト飲料。
    (A) a collagen peptide having an average molecular weight of 500 to 8000,
    (B) carbon dioxide,
    (C) isoalpha acid, and (D) acidulant,
    PH 3 or more and 4 or less, the content of collagen peptide is 280 to 1800 mg / 100 mL, and the content of isoalpha acid is 1.0 × 10 −3 to 3.0 × 10 −3 mass% A substantially non-alcoholic beer-taste beverage.
  2.  (A’)ヒドロキシプロリンの含有量が30~193mg/100mLである、請求項1に記載のビールテイスト飲料。 The beer-taste beverage according to claim 1, wherein the content of (A ') hydroxyproline is 30 to 193 mg / 100 mL.
  3.  (A’)ヒドロキシプロリンが(A)コラーゲンペプチドに由来するものを含む、請求項2に記載のビールテイスト飲料。 The beer-taste beverage according to claim 2, wherein (A ′) hydroxyproline includes one derived from (A) collagen peptide.
  4.  (C)イソα酸と(D)酸味料との含有質量比〔(C)/(D)〕が0.003~0.030である、請求項1~3のいずれか1項に記載のビールテイスト飲料。 The content mass ratio [(C) / (D)] of (C) isoalpha acid and (D) acidulant is 0.003 to 0.030, according to any one of claims 1 to 3. Beer taste drink.
  5.  カロリーが5kcal/100mL未満である、請求項1~4のいずれか1項に記載のビールテイスト飲料。 The beer-taste beverage according to any one of claims 1 to 4, wherein the calorie is less than 5 kcal / 100 mL.
  6.  糖質含有量が0.5g/100mL未満である、請求項1~5のいずれか1項に記載のビールテイスト飲料。 The beer-taste beverage according to any one of claims 1 to 5, wherein the sugar content is less than 0.5 g / 100 mL.
  7.  炭素数4及び炭素数5の脂肪族アルコールの含有量が0.0002~0.0007質量%である、請求項1~6のいずれか1項に記載のビールテイスト飲料。 The beer-taste beverage according to any one of claims 1 to 6, wherein the content of the aliphatic alcohol having 4 and 5 carbon atoms is 0.0002 to 0.0007 mass%.
PCT/JP2016/056761 2015-03-13 2016-03-04 Non-alcoholic beer-taste beverage WO2016147907A1 (en)

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JPWO2019193673A1 (en) * 2018-04-04 2021-04-08 サントリーホールディングス株式会社 Beer-taste beverage with suppressed photodegradation and its manufacturing method

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