WO2016139125A1 - Produits cosmétiques contenant une substance bioactive et un dipeptide - Google Patents

Produits cosmétiques contenant une substance bioactive et un dipeptide Download PDF

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Publication number
WO2016139125A1
WO2016139125A1 PCT/EP2016/053978 EP2016053978W WO2016139125A1 WO 2016139125 A1 WO2016139125 A1 WO 2016139125A1 EP 2016053978 W EP2016053978 W EP 2016053978W WO 2016139125 A1 WO2016139125 A1 WO 2016139125A1
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WO
WIPO (PCT)
Prior art keywords
hair
keratinic fibers
weight
derivatives
salts
Prior art date
Application number
PCT/EP2016/053978
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German (de)
English (en)
Inventor
Erik Schulze Zur Wiesche
Original Assignee
Henkel Ag & Co. Kgaa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Henkel Ag & Co. Kgaa filed Critical Henkel Ag & Co. Kgaa
Publication of WO2016139125A1 publication Critical patent/WO2016139125A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/002—Preparations for repairing the hair, e.g. hair cure
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q7/00—Preparations for affecting hair growth

Definitions

  • the invention relates to cosmetic agents, in particular hair treatment compositions with a bio-active substance and a dipeptide for the gentle and effective care of the hair and / or scalp.
  • the hair is treated with special active ingredients, for example quaternary ammonium salts or special polymers, usually in the form of a rinse.
  • special active ingredients for example quaternary ammonium salts or special polymers, usually in the form of a rinse.
  • this treatment improves the combability, the hold and the fullness of the hair and reduces the split rate.
  • a further object was to provide hair-treatment compositions which are irritating and sensitizing, which soothe the scalp and / or exert a positive effect on the hair and / or the hair follicle.
  • a first object of the present invention is a cosmetic composition containing - in each case based on its weight - a) 0.0001 to 20 wt .-% of a bio-active selected from the group consisting of i. L-carnitine and / or its salts and / or its derivatives; ii. the 2-furanone, in particular pantolactone;
  • Vitamins iv. Vitamins, provitamins or vitamin precursors in particular
  • Plant extracts in particular of Echinacea or Moringa plants
  • Xanthines especially caffeine, theophylline and theobromine
  • Flavonoids in particular flavonols
  • the agent having a viscosity of at most 5,000 mPas (determined using a Haake VT 550 rotary viscometer, MVII measuring body, at 20 ° C. and 7.2 s -1 ).
  • the remedy is a cosmetic.
  • Preferred cosmetic agents are selected from the group of shower gels, shower baths, dentifrices and cleansers, mouthwashes, hair shampoos, hair conditioners, conditioning shampoos, hair sprays, hair conditioners, hair treatments, hair wraps, hair tonics, perming solutions, hair dye shampoos, hair dyes, hair fixatives, hair dressings , Hair styling preparations, hair lotions, mousses, hair gels, hair waxes or combinations thereof.
  • Hair treatment compositions in the context of the present invention are, for example, hair shampoos, hair conditioners, conditioning shampoos, hair sprays, hair rinses, hair treatments, hair wraps, hair tonics, perming solutions, hair dye shampoos, hair dyes, Hair fixatives, hair dressings, hair styling preparations, hair lotions, mousses, hair gels, hair waxes or combinations thereof.
  • hair treatment compositions in the form of shampoos, hair conditioners, hair lotions or hair tonics.
  • the first compulsory ingredient contains 0.0001 to 20 wt .-% of a bio-active substance.
  • the bio-active substance is selected from the group consisting of i. L-carnitine and / or its salts and / or its derivatives;
  • Vitamins in particular nicotinamide, biotin, pantothenic acid, panthenol and tocopherol and / or their derivatives;
  • Plant extracts in particular of Echinacea or Moringa plants
  • Xanthines especially caffeine, theophylline and theobromine
  • Flavonoids in particular flavonols
  • L-carnitine and L-carnitine derivatives and / or L-carnitine salts can be used in the cosmetic products.
  • the derivatives and / or salts are especially selected from acetyl-L-carnitine, L-carnitine fumarate, L-carnitine citrate, lauroyl-L-carnitine and particularly preferably L-carnitine tartrate.
  • taurine (2-aminoethanesulfonic acid) and taurine derivatives can be used in the cosmetic products.
  • Derivatives of these are in particular N-alkyl derivatives of taurine such as N-monomethyl-taurine, and N, N-dimethyl-taurine
  • vitamins are preferably the following vitamins, provitamins and
  • Vitamin A the group of substances called vitamin A includes retinol (vitamin Ai) and 3,4-didehydroretinol (vitamin A2).
  • the ß-carotene is the provitamin of retinol.
  • vitamin A component for example, vitamin A acid and its esters, vitamin A aldehyde and vitamin A alcohol and its esters such as palmitate and acetate into consideration.
  • Vitamin B belong to the vitamin B group or to the vitamin B complex u. a.
  • Vitamin B1 (thiamine)
  • Vitamin B2 (riboflavin)
  • Vitamin B3 Under this name, the compounds nicotinic acid and nicotinamide are often performed. Vitamin Bs (pantothenic acid and panthenol). Within this group the panthenol is preferred. Useful derivatives of panthenol are, in particular, the esters and ethers of panthenol, as well as cationically derivatized panthenols. Individual representatives are, for example, panthenol triacetate, panthenol monoethyl ether and its monoacetate, as well as cationic panthenol derivatives.
  • Vitamin ⁇ (pyridoxine and pyridoxamine and pyridoxal).
  • Vitamin C ascorbic acid: use in the form of palmitic acid ester, glucosides or phosphates may be preferred. The use in combination with tocopherols may also be preferred.
  • Vitamin E tocopherols, especially a-tocopherol.
  • Vitamin F is usually understood as meaning essential fatty acids, in particular linoleic acid, linolenic acid and arachidonic acid.
  • Vitamin H is the compound (3aS, 4S, 6aR) -2-oxohexahydrothienol [3,4-d] - imidazole-4-valeric acid, for which, in the meantime, the trivial name biotin has prevailed.
  • vitamins, provitamins and vitamin precursors from groups A, B, E and H.
  • vitamins, provitamins and vitamin precursors from groups B and / or H for example nicotinamide, biotin and / or panthenol.
  • Suitable plant extracts of Echinacea are in particular from Echinacea angustifolia DC, Echinacea paradoxa (NORTON). Echinacea simulata. E. atrorubens. E. tennesiensis, Echinacea strigosa (MCGREGOR). Echinacea laevigata. Echinacea purpurea (L.) Moench and Echinacea pallida (Nutt) were obtained. Especially preferred are extracts of Echinacea purpurea (L.) MOENCH.
  • Suitable xanthines and / or xanthine derivatives are preferably compounds of the following formula
  • radicals R, R 2 and R 3 can be selected independently of one another from -H, C 1 -C 4 -alkyl and / or -OH, the following compounds being preferred:
  • Suitable amino acids may be selected from essential amino acids such as isoleucine, leucine, lysine, methionine, phenylalanine, threonine, thryptophan and / or valine, semi-essential amino acids such as arginine and / or histidine and / or nonessential amino acids such as alanine, aspartic acid, cysteine, Cystine, glutamic acid, glycine, proline, serine and / or tyrosine.
  • essential amino acids such as isoleucine, leucine, lysine, methionine, phenylalanine, threonine, thryptophan and / or valine
  • semi-essential amino acids such as arginine and / or histidine and / or nonessential amino acids
  • alanine aspartic acid
  • cysteine Cystine
  • glutamic acid glycine
  • proline serine and / or t
  • Particularly suitable amino acids are glycine and / or L-arginine.
  • Particularly preferred agents additionally contain panthenol, pantolactone, nicotinamide, biotin, glycine, caffeine, taurine, ectoine, ubiquinone, carnitine and / or a physiologically tolerated salt and / or a derivative of these compounds.
  • the cosmetic agent contains a combination of several bioactive substances.
  • a particularly advantageous combination comprises L-carnitine tartrate, a plant extract of echinacea and taurine.
  • Another particularly advantageous combination comprises L-carnitine tartrate, caffeine and taurine.
  • the agents preferably contain the bioactive agent (s) in an amount of from 0.001 to 10.0% by weight and more preferably from 0.01 to 2.0% by weight, based in each case on the weight of the ready-to-use agent ,
  • the agents contain as the second essential ingredient - based on their weight - 0.0001 to 30 wt .-% methionylmethionine.
  • Methionylmethionine is the dipeptide of methionine and has the following structure:
  • the dipeptide methionylmethionine From the dipeptide methionylmethionine exist the four different stereoisomers DD, LL, DL and LD. Of the four stereoisomers, only the L-methionyl-L-methionine is natural, the three other dipeptides L-methionyl-D-methionine, D-methionyl-L-methionine and D-methionyl-D-methionine are all unnatural.
  • the described positive effects in hair treatment compositions can be achieved with all four stereoisomeric dipeptides.
  • the methionylmethionine can be used as DD / LL / LD / DL- Mixture, as DL / LD mixture or DD / LL mixture are used.
  • stereoisomeric dipeptide alone or in combination with one or two further stereoisomers is conceivable. If only one stereoisomeric dipeptide is used, preference is given to choosing L-methionyl-L-methionine or D-methionyl-D-methionine.
  • the two pairs DD / LL-methionylmethionine and DL / LD-methionylmethionine are diastereomeric and have different physical data.
  • the diastereomeric pair DD / LL at room temperature has a solubility of 21.0 g / l in water, whereas the solubility of the diastereomeric pair DL / LD is 0.4 g / l.
  • These mixtures can be easily incorporated / dissolved in an aqueous phase or an aqueous-surfactant phase of a cosmetic product.
  • the cosmetic agents contain the methionylmethionine preferably in an amount of 0.01 to 5.0 wt .-% and particularly preferably from 0.1 to 3.0 wt .-%, each based on the weight of the ready cosmetic product.
  • the cosmetic products have a viscosity of 5,000 mPas. It is preferred that the cosmetic agents have a viscosity of at most 2,500 mPas, and more preferably of at most 1, 000 mPas.
  • the viscosity is determined using a Haake viscometer VT 550. The determination is performed at 20 ° C, at a shear rate of 7.2 sec -1 with a measuring body MVII.
  • Cosmetics in the form of hair treatment agents can revitalize the hair, activate the energy metabolism in hair follicles to the rain, activate hair follicles / hair roots, promote or enhance hair growth, treat hair loss, affect keratin synthesis, improve the tensile strength of keratinic fibers, especially human hair, the moisture balance of keratinic Stabilizing fibers, in particular human hair, improving the combability of keratinic fibers, in particular human hair, retarding the aging process of keratinic fibers, in particular human hair, improving the restructurability of keratinic fibers, in particular human hair, the decrease in elasticity of keratinic fibers, in particular human hair Reduce damage caused by atmospheric agents and / or sensitive scalp and / or scalp damaged and / or irritated by chemical hair treatment t calm down.
  • the cosmetic agent is preferably a leave-on composition which is not rinsed off after application to the hair and / or the scalp, but remains on the application surface until the next hair cleansing.
  • the agent is particularly preferably a hair tonic or a hair tonic because it has been found that the bio-active substances from hair tonics and / or hair lotions can be deposited on the scalp particularly well, and then in particular can serve to soothe the scalp.
  • a hair tonic or hair tonic preferably has a viscosity of at most 500 mPas (determined with a Haake VT 550 rotary viscometer, MVII measuring body, at 20 ° C. and 7.2 s.
  • Compositions having such a viscosity can be homogeneously mixed in the hair and on the scalp
  • the dosage on hands and the subsequent application with the hands is particularly good at such viscosity values.
  • a cosmetic agent in the form of a hair lotions or hair tonics contains - based on its weight - at least 10 wt .-% of a Ci-C4-alcohol.
  • Suitable C 1 -C 4 -alcohols which may be present in the compositions are preferably selected from ethanol, ethyldiglycol, 1-propanol, 2-propanol, isopropanol, 1, 2-propylene glycol, glycerol, 1-butanol, 2-butanol, 1 , 2-butanediol and / or 1, 3-butanediol.
  • cosmetic compositions based on their total weight - preferably 22.5 to 65 wt .-%, more preferably 25 to 60 wt .-% and in particular 27.5 to 50 wt .-% of at least one alcohol from the group ethanol , Ethyldiglykol, 1-propanol, 2-propanol, isopropanol, 1, 2-propylene glycol, glycerol, 1-butanol, 2-butanol, 1, 2-butanediol and / or 1, 3-butanediol.
  • cosmetic compositions which, based on their total weight, contain at least 20% by weight of a C 1 -C 4 -alcohol, in particular ethanol.
  • a cosmetic agent is formulated as a hair tonic and / or hair tonic, it is preferred if the hair tonic and / or hair tonic is free from anionic, amphoteric / zwitterionic and / or cationic surfactants.
  • substantially free is preferably a total surfactant content in the haaronic or hair tonic of at most 2 wt .-%, more preferably of at most 1 wt .-% and in particular of at most 0.1 wt .-% understood, wherein the amounts are based on refer to the total weight of the hair tonics / hair lotions.
  • the cosmetic agents may include other active ingredients and adjuvants. These will be below described.
  • the scalp-soothing effect of the cosmetic compositions can be enhanced if, based on their total weight, they are preferably from 0.001 to 3% by weight, particularly preferably from 0.005 to 2% by weight and in particular from 0.01 to 1 % By weight of at least one monocyclic monoterpene.
  • Suitable monocyclic monoterpenes are preferably compounds which have a cyclohexane skeleton, for example menthol, limonene, phellandrene, terpinol, terpinene, pulegol, piperitol, carveol, thymol and / or cymene.
  • Particularly suitable monocyclic monoterpenes are menthol, limonene and / or the physiologically tolerated salts and / or derivatives of these compounds.
  • menthol and / or a physiologically acceptable salt and / or derivative of menthol.
  • Preferred cosmetic agents which are not in the form of a hair tonic or hair tonics are characterized in that they contain, based on their weight, from 0.5 to 70% by weight, preferably from 1 to 60% by weight and in particular from 5 to 25% by weight % anionic and / or nonionic and / or cationic and / or amphoteric surfactant (s).
  • Suitable anionic surfactants for the cosmetic compositions are all anionic surfactants suitable for use on the human body. These are characterized by a water-solubilizing, anionic group such as a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group of about 8 to 30 carbon atoms.
  • anionic group such as a carboxylate, sulfate, sulfonate or phosphate group
  • a lipophilic alkyl group of about 8 to 30 carbon atoms.
  • glycol or polyglycol ether groups, ester, ether and amide groups and hydroxyl groups may be present in the molecule.
  • amphoteric surfactants which are often referred to as zwitterionic surfactants, such surface-active compounds are called, which carry in the molecule at least one quaternary ammonium group and at least one -COO (_) - or -S03 (_) group.
  • amphoteric / zwitterionic surfactants are the so-called betaines, such as N-alkyl-N, N-dimethylammonium glycinates, for example cocoalkyldimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammonium glycinates, for example
  • a preferred one Amphoteric / zwitterionic surfactant is the fatty acid amide derivative known by the INCI name Cocamidopropyl Betaine.
  • Amphoteric / zwitterionic surfactants are also understood to mean those surface-active compounds which, apart from a Cs-C24-alkyl or -acyl group, contain at least one free amino group and at least one -COOH or -SCbH group and are capable of forming internal salts.
  • suitable amphoteric / zwitterionic surfactants are N-alkylglycines, N-alkylaminopropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids,
  • N-hydroxyethyl-N-alkylamidopropylglycines N-alkyltaurines, N-alkylsarcosines, 2-
  • Alkylaminopropion Acid and Alkylaminoessigkladren each having about 8 to 24 carbon atoms in the alkyl group.
  • Particularly preferred amphoteric / zwitterionic surfactants are N-cocoalkylaminopropionate, cocoacylaminoethylaminopropionate and C12-C18 acylsarcosine.
  • Nonionic surfactants contain, for example, a polyol group, a polyalkylene glycol ether group or a combination of polyol and polyglycol ether groups as the hydrophilic group.
  • cosmetic compositions which additionally contain fatty alcohol (s) and / or fatty alcohol alkoxylate (s), preferably C 12-22 fatty alcohol (s) and / or C 12-22 fatty alcohol ethoxylate (s) having 10 to 30 EO units, especially preferably Ci6-i8 fatty alcohol (s) and / or C16-18 fatty alcohol ethoxylate (s) having 12 to 20 EO units, preferably in amounts of 5 to 20 wt .-%, preferably from 7.5 to 17.5 wt .-% and in particular from 10 to 15 wt .-%, each based on the weight of the cosmetic product.
  • cosmetic agents in particular hair treatment compositions, which contain, by weight, from 0.1 to 20% by weight, preferably from 0.25 to 17.5% by weight and in particular from 5 to 15% by weight of anionic surfactants.
  • surfactant (s) particularly preferably fatty alcohol ether sulfates of the formula
  • n represents values of from 5 to 21, preferably from 7 to 19, particularly preferably from 9 to 17 and in particular from 1 to 13 and k for values of 1, 2, 3, 4, 5, 6, 7, 8, 9 or 10, preferably represent 1, 2 or 3 and especially 2
  • M is a cation selected from the group Na +, K + NH 4 + 1/2 Mg 2+, 1/2 Zn 2+, preferably for Na + , stand.
  • the cosmetic agents may contain from 0.01 to 10% by weight of at least one polymer from the group of cationic and / or amphoteric polymers.
  • Cationic or amphoteric polymers are to be understood as meaning polymers which have a group in the main and / or side chain which may be “temporary” or “permanent” cationic.
  • Periodently cationic refers to those polymers which have a cationic group regardless of the pH of the agent. These are usually polymers containing a quaternary nitrogen atom, for example in the form of an ammonium group.
  • Preferred cationic Groups are quaternary ammonium groups.
  • those polymers in which the quaternary ammonium group is bonded via a C1-C4 hydrocarbon group to a polymer main chain constructed from acrylic acid, methacrylic acid or derivatives thereof have proven to be particularly suitable.
  • the cosmetic agents may also contain amphoteric polymers. These have in addition to the cationically charged group (s) at least one negatively charged group in the molecule and are also referred to as zwitterionic polymers.
  • the polymer or polymers are used within narrower ranges.
  • cosmetic agents are preferred which - based on their weight - 0.05 to 7.5% by weight, preferably 0, 1 to 5 wt .-%, particularly preferably 0.2 to 3.5 wt .-% and in particular from 0.25 to 2.5% by weight of amphoteric polymer (s).
  • agents contain amphoteric polymers or not
  • further preferred cosmetic agents are characterized in that they contain, based on their weight, from 0.05 to 7.5% by weight, preferably from 0.1 to 5% by weight. -%, particularly preferably 0.2 to 3.5 wt .-% and in particular 0.25 to 2.5 wt .-% cationic (s) polymer (s) included.
  • suitable ingredients include nonionic polymers, anionic polymers, fatty substances, waxes, ester oils, UV screening agents, structurants, thickeners, electrolytes, pH modifiers, swelling agents, dyes, antidandruff agents, chelating agents, opacifiers, pearlescers, pigments, stabilizers, propellants, antioxidants, Perfume oils, silicones and / or preservatives.
  • the cosmetic compositions have advantageous properties and also confer advantageous properties on the hair treated with them. Especially in hair and scalp treatment, benefits have been seen that go beyond the benefits of bio-active ingredients and methionylmethionine alone.
  • Another object of the present invention is accordingly the use of a cosmetic agent containing - each based on its weight - a) 0.0001 to 20 wt .-% of a bio-active selected from the group consisting of i. L-carnitine and / or its salts and / or its derivatives;
  • Vitamins in particular nicotinamide, biotin, pantothenic acid, panthenol and tocopherol and / or derivatives thereof; v. Ubiquinone (coenzyme Q10);
  • Plant extracts in particular of Echinacea or Moringa plants
  • Xanthines especially caffeine, theophylline and theobromine
  • Flavonoids in particular flavonols
  • Another object of the present invention is a method for
  • a cosmetic agent preferably hair treatment composition containing - in each case based on its weight - a) from 0.0001 to 20 wt .-% of a bio-active substance selected from the group consisting of i. L-carnitine and / or its salts and / or its derivatives;
  • Vitamins in particular nicotinamide, biotin, pantothenic acid, panthenol and tocopherol and / or derivatives thereof;
  • Plant extracts in particular of Echinacea or Moringa plants
  • x. Xanthines especially caffeine, theophylline and theobromine;
  • Flavonoids in particular flavonols

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
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Abstract

L'invention concerne un produit cosmétique contenant - dans tous les cas par rapport à son poids - a) 0,0001 à 20 % en poids d'une substance bioactive sélectionnée dans le groupe composé de : i) L-carnitine ou ses sels et/ou ses dérivés ; ii) 2-furanone, en particulier pantolactone ; iii) taurine et/ou ses sels ; iv) vitamines, provitamines ou précurseurs de vitamines, en particulier amide de l'acide nicotinique, biotine, acide pentothénique, panthénol et tocophérol et/ou leurs dérivés ; v) ubiquinone (coenzyme Q10) ; vi) éctoïne ; vii) allantoïne ; viii) extraits de plantes, en particulier des plantes échincée et moringa ; ix) xanthine, en particulier caféine, théophylline et théobromine ; x) flavonoïde, en particulier flavonol ; xi) bisabolol ; xii) créatine ; xiii) acides aminés, en particulier glycine et/ou L-arginine et xiv) mélange de ces derniers, et b) 0,0001 à 30 % en poids de méthylmétionine, le produit présentant une viscosité maximale de 5 000 mPas (définie au moyen d'un viscosimètre rotatif Haake VT 550, élément de mesure MVII, à 20 ° C et pendant 7,2 s-1). Les produits cosmétiques contenant de la méthylmétionine et une substance bioactive déterminée ont un effet positif sur la peau, ainsi que sur les cheveux et les follicules des cheveux.
PCT/EP2016/053978 2015-03-04 2016-02-25 Produits cosmétiques contenant une substance bioactive et un dipeptide WO2016139125A1 (fr)

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DE102015203818.1 2015-03-04
DE102015203818.1A DE102015203818A1 (de) 2015-03-04 2015-03-04 "Kosmetische Mittel mit Bio-Aktivstoff und einem Dipeptid"

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Publication number Priority date Publication date Assignee Title
CN108324610B (zh) * 2018-03-20 2019-09-20 珀莱雅化妆品股份有限公司 一种生发组合物及其pic油包水纳米乳液的制备方法
DE102020125873A1 (de) 2020-10-02 2022-04-07 Dr. Kurt Wolff Gmbh & Co. Kg Zusammensetzung zur Behandlung von Haaren und der Kopfhaut
DE102020125876A1 (de) 2020-10-02 2022-04-07 Dr. Kurt Wolff Gmbh & Co. Kg Zusammensetzung zur Behandlung von Haaren und der Kopfhaut
DE102020125874A1 (de) 2020-10-02 2022-04-07 Dr. Kurt Wolff Gmbh & Co. Kg Zusammensetzung zur Behandlung von Haaren und der Haut

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007039741A1 (de) * 2007-08-22 2009-02-26 Henkel Ag & Co. Kgaa Haarbehandlungsmittel mit Tensid(en) und Melatonin/Agomelatin
WO2012084876A2 (fr) * 2010-12-20 2012-06-28 Henkel Ag & Co. Kgaa Copolymères cationiques de styrène/acrylate dans des agents de traitement capillaire
DE102013214713A1 (de) * 2013-07-29 2015-01-29 Evonik Industries Ag Formulierungen enthaltend Sphinganin
EP2835151A1 (fr) * 2013-08-06 2015-02-11 Evonik Industries AG Stéréo-isomère méthionyl-méthionine et son utilisation en cosmétique

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007039741A1 (de) * 2007-08-22 2009-02-26 Henkel Ag & Co. Kgaa Haarbehandlungsmittel mit Tensid(en) und Melatonin/Agomelatin
WO2012084876A2 (fr) * 2010-12-20 2012-06-28 Henkel Ag & Co. Kgaa Copolymères cationiques de styrène/acrylate dans des agents de traitement capillaire
DE102013214713A1 (de) * 2013-07-29 2015-01-29 Evonik Industries Ag Formulierungen enthaltend Sphinganin
EP2835151A1 (fr) * 2013-08-06 2015-02-11 Evonik Industries AG Stéréo-isomère méthionyl-méthionine et son utilisation en cosmétique

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