WO2016121423A1 - Ozone generator - Google Patents
Ozone generator Download PDFInfo
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- WO2016121423A1 WO2016121423A1 PCT/JP2016/050182 JP2016050182W WO2016121423A1 WO 2016121423 A1 WO2016121423 A1 WO 2016121423A1 JP 2016050182 W JP2016050182 W JP 2016050182W WO 2016121423 A1 WO2016121423 A1 WO 2016121423A1
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- discharge
- ozone generator
- dielectric
- ozone
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/10—Preparation of ozone
- C01B13/11—Preparation of ozone by electric discharge
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01T—SPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
- H01T19/00—Devices providing for corona discharge
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01T—SPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
- H01T23/00—Apparatus for generating ions to be introduced into non-enclosed gases, e.g. into the atmosphere
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2201/00—Preparation of ozone by electrical discharge
- C01B2201/60—Feed streams for electrical dischargers
- C01B2201/64—Oxygen
Definitions
- the present invention relates to an ozone generator that generates creeping discharge along a dielectric surface and generates ozone from oxygen in a space facing the discharge surface.
- FIG. 8 is a diagram illustrating a configuration of a conventional ozone generator 100 (see, for example, Patent Document 1).
- the ozone generating apparatus 100 includes a flat plate portion 101, a first planar conductor 104, and a second planar conductor 105.
- the flat plate portion 101 includes a base layer 102 and a surface layer 103 that are stacked on each other.
- the base layer 102 is made of a ceramic dielectric material such as alumina.
- the surface layer 103 is made of a dielectric material such as glass.
- the first planar conductor 104 and the second planar conductor 105 are provided at the interface between the base layer 102 and the surface layer 103.
- the first planar conductor 104 has a comb shape in plan view and includes a plurality of discharge portions 106 that are parallel to each other.
- the second planar conductor 105 has a comb shape like the first planar conductor 104 and includes a plurality of discharge portions 107 parallel to each other.
- the discharge unit 106 and the discharge unit 107 are alternately arranged with an interval.
- a creeping discharge is generated along the surface (discharge surface) of the surface layer 103 made of a dielectric material by applying an alternating electric field between the discharge unit 106 and the discharge unit 107.
- ozone is generated from oxygen in the space facing the discharge surface.
- the electric field strength can be increased by narrowing the interval between the discharge portions, and the drive voltage can be lowered.
- creeping discharge occurs in each adjacent pair of discharge parts, so the ozone generation efficiency can be improved by increasing the number of discharge parts that can be arranged per unit area by narrowing the width of the discharge part and the adjacent interval. Can be high.
- an object of the present invention is to provide an ozone generator that can suppress power consumption and heat generation even if the width of the discharge part is narrowed.
- the ozone generator of the present invention comprises a dielectric part having a discharge surface that causes creeping discharge, and a conductor provided in the dielectric part, and has a discharge end that is close to and faces the discharge surface, and the discharge A plurality of discharge portions arranged at intervals along the surface, wherein the discharge portion is La in the direction of the discharge surface facing the discharge surface, and is arranged along the discharge surface If Lb is its own dimension, La ⁇ Lb.
- the dielectric part includes a plurality of dielectric layers stacked in the arrangement direction, and the plurality of discharge parts are each composed of a planar conductor provided between the dielectric layers.
- This configuration can be manufactured by simply forming a planar conductor as a discharge portion on a dielectric sheet as a dielectric layer and stacking a plurality of dielectric sheets. Therefore, even a discharge portion whose dimension in the discharge surface direction is larger than that in the arrangement direction can be formed using a method such as screen printing.
- a method with low processing accuracy such as screen printing
- the width and interval of the discharge parts cannot be reduced so much, and the short circuit between the discharge parts due to the processing accuracy, Problems such as breakage and damage due to arc discharge at places where the interval between the discharge portions becomes narrow may occur.
- the width and interval of the discharge part can be set with high accuracy according to the thickness of the dielectric sheet and the planar conductor, and the width and interval of the discharge part are extremely narrow and variation is reduced. Can do. Therefore, the problems that have occurred in the above-described conventional configuration hardly occur.
- the discharge surface is preferably composed of end surfaces of the plurality of dielectric layers.
- the distance between the discharge surface and the discharge end is preferably narrower than the distance between the plurality of discharge portions.
- the dielectric portion has a plurality of outer surfaces including one discharge surface, the discharge portion has a plurality of end portions including one discharge end, and the discharge end and the discharge surface face each other.
- the interval may be narrower than the interval between the other end and the other outer surface.
- the dielectric portion has a plurality of outer surfaces including two or more discharge surfaces
- the discharge portion has a plurality of end portions including two or more discharge ends, each discharge end, each discharge surface, May be configured such that the intervals at which they face each other are equal.
- the total area of the discharge surface can be increased using two or more outer surfaces of the dielectric portion as the discharge surface, and the amount of ozone generated can be increased.
- the dielectric portion may have a peripheral surface corresponding to the discharge surface, and the discharge end may extend while maintaining a constant distance from the peripheral surface of the dielectric portion.
- the total area of the discharge surface can be increased using the entire peripheral surface of the dielectric portion as the discharge surface, and the amount of ozone generated can also be increased.
- the ozone generating device includes a driving voltage source that outputs a driving voltage of N (N ⁇ 3) phase having a repetitive pattern and a circulating phase difference, and the plurality of discharge units are arranged in the order n. It is preferable that the driving voltage of the (1 ⁇ n ⁇ N) phase is input from the driving voltage source.
- the electric field intensity distribution near the discharge surface changes so as to circulate along the arrangement direction.
- the gas in the space moves near the discharge surface along the arrangement direction under the influence of the electric field strength. For this reason, the supply of oxygen to the discharge surface and the detachment of ozone from the discharge surface are promoted, and the amount of ozone generated can be increased. Further, the generation of gas flow makes it difficult for dust and the like to be adsorbed on the discharge surface, and the reliability of the ozone generator is improved.
- the drive voltage is preferably a rectangular wave signal or a pulse wave signal. As a result, the voltage at which discharge is started can be reduced compared to when the alternating signal is a sine wave signal.
- the ozone generating apparatus of the present invention even when the discharge part is thinned in the arrangement direction, the dimension of the discharge part can be sufficiently secured in the discharge surface direction, and an increase in the conductor resistance can be suppressed. . Therefore, an increase in power consumption and heat generation in the ozone generator can be suppressed, and even if a large number of discharge parts are provided to increase the ozone generation efficiency, the ozone decomposition reaction can be prevented from being accelerated by heat.
- FIG. 1 is a perspective view of an ozone generator according to a first embodiment of the present invention. It is the left view, top view, right view, and bottom view of the ozone generator which concerns on the 1st Embodiment of this invention. It is a figure explaining the manufacturing method of the ozone generator which concerns on the 1st Embodiment of this invention. It is the left view and front view of the ozone generator which concern on the 2nd Embodiment of this invention. It is the left view and top view of an ozone generator which concern on the 3rd Embodiment of this invention. It is the left view and top view of an ozone generator which concern on the 4th Embodiment of this invention. It is the wiring diagram of the ozone generator which concerns on the 5th Embodiment of this invention, and the time waveform figure of a drive signal. It is a perspective view of the conventional ozone generator.
- FIG. 1 is a perspective view of an ozone generator 10 according to the first embodiment of the present invention.
- the ozone generator 10 includes a dielectric part 11, internal planar conductors 12 and 13, a terminal electrode 14, a terminal electrode 15, and a drive voltage source 16.
- the dielectric portion 11 has a rectangular parallelepiped shape including a top surface 11A, a bottom surface 11B, a left side surface 11C, a right side surface 11D, a front surface 11E, and a back surface 11F.
- a plurality of inner planar conductors 12 and 13 are provided, and are arranged alternately in the dielectric portion 11 from the left side surface 11C side to the right side surface 11D side.
- the inner planar conductor 12 has a shape extending from the front surface 11E side to the back surface 11F side near the top surface 11A and extending from the top surface 11A side to the bottom surface 11B side close to the back surface 11F inside the dielectric portion 11.
- the inner planar conductor 13 has a shape extending in the vicinity of the top surface 11A from the back surface 11F side to the front surface 11E side and close to the front surface 11E from the top surface 11A side to the bottom surface 11B side inside the dielectric portion 11. .
- the terminal electrodes 14 and 15 are provided on the bottom surface 11B and are formed of a strip-shaped planar conductor extending from the left side surface 11C side to the right side surface 11D side.
- the terminal electrode 14 is provided so as to be close to the side of the bottom surface 11 ⁇ / b> B on the front surface 11 ⁇ / b> E side, and is connected to the plurality of internal planar conductors 13.
- the terminal electrode 15 is provided so as to be close to the side of the bottom surface 11B on the back surface 11F side, and is connected to the plurality of internal planar conductors 12.
- the driving voltage source 16 applies a driving voltage between the terminal electrode 14 and the terminal electrode 15 to generate an alternating electric field between the inner planar conductor 12 and the inner planar conductor 13.
- the inner planar conductor 12 and the inner planar conductor 13 are both close to the top surface 11A of the dielectric part 11; Creeping discharge occurs along the direction connecting the left side surface 11C and the right side surface 11D. Owing to the creeping discharge, ozone is generated from oxygen contained in the gas in the space facing the top surface 11A on the top surface 11A of the dielectric portion 11.
- the top surface 11A is a discharge surface in the present invention.
- the direction from the left side surface 11C of the dielectric portion 11 toward the right side surface 11D is referred to as an arrangement direction.
- a direction from the front surface 11E to the back surface 11F is referred to as a stretching direction.
- the direction from the bottom surface 11B toward the top surface 11A is referred to as a discharge surface direction.
- the length of the dielectric portions 11 in the arrangement direction is, for example, 3.2 mm
- the length in the extending direction is, for example, 2.5 mm
- the length in the discharge surface direction is, for example, 2.5 mm.
- FIG. 2 (A) is a left side view of the ozone generator 10.
- FIG. 2B is a plan view of the ozone generator 10.
- FIG. 2C is a right side view of the ozone generator 10.
- FIG. 2D is a front view of the ozone generator 10.
- the dielectric part 11 includes a plurality of dielectric layers 21.
- Each of the plurality of dielectric layers 21 is a thin flat film having a main surface that faces the left side surface 11C and the right side surface 11D, and is laminated from the left side surface 11C to the right side surface 11D of the dielectric portion 11, The dielectric part 11 is configured.
- the thickness of the dielectric layer 21 is, for example, 20 ⁇ m.
- the thickness of the dielectric layer 21 is preferably 1 ⁇ m or more and 20 ⁇ m or less.
- the inner planar conductors 12 and 13 are alternately arranged on the main surface of each dielectric layer 21, that is, one laminated surface between the dielectric layers 21, and adjacent laminated surfaces inside the dielectric portion 11. ing.
- the inner planar conductors 12 and 13 include discharge portions 12A and 13A and lead portions 12B and 13B.
- the discharge parts 12A and 13A are rectangular parallelepiped plate-like pattern portions extending in the extending direction.
- the lead portions 12B and 13B are band-shaped pattern portions extending in the discharge surface direction.
- the edges on the top surface 11A side of the discharge parts 12A and 13A are separated from the top surface 11A by a certain dimension Lc and face the top surface 11A.
- the dimension Lc is, for example, 10 ⁇ m.
- the edges on the front surface 11E side and the back surface 11F side of the discharge parts 12A and 13A are opposed to the front surface 11E or the back surface 11F by a predetermined dimension Le.
- the dimension Lc is smaller than the dimension Le. That is, in the discharge portions 12A and 13A, the edge on the top surface 11A side is closer to the outer surface of the dielectric portion 11 than the edge on the front surface 11E side and the back surface 11F side.
- the electric field generated between the discharge parts 12A and 13A tends to leak to the outer surface of the dielectric part 11 that is the closest to the discharge parts 12A and 13A. For this reason, in this dielectric part 11, creeping discharge arises not on the front surface 11E or the back surface 11F but on the top surface 11A. Accordingly, the top surface 11A of the dielectric portion 11 functions as a discharge surface that generates ozone, and the edges of the discharge portions 12A and 13A on the top surface 11A side function as discharge ends 12C and 13C. In this embodiment, there is no discharge other than the top surface 11A.
- the arrangement interval between the discharge part 12A and the discharge part 13A is the dimension Ld.
- the dimension Ld is, for example, 20 ⁇ m. This dimension Ld is determined by the thickness of the dielectric layer 21.
- the first planar conductor 104 and the second planar conductor 105 are formed by fine line printing, a portion where the distance between the first planar conductor and the second planar conductor is narrow is short. It was difficult to form the dimension Ld to be 50 ⁇ m or less.
- the ozone generator 10 according to the present embodiment is configured as described above, the arrangement interval between the discharge unit 12A and the discharge unit 13A can be sufficiently narrowed compared to the conventional configuration.
- the discharge start voltage of the ozone generator 10 can be lowered. Further, the electric field strength of the alternating electric field generated between the discharge part 12A and the discharge part 13A can be increased as compared with the conventional configuration. Therefore, in the ozone generating apparatus 10 according to the present embodiment, creeping discharge can be stably generated on the top surface 11A of the dielectric portion 11 even if the driving voltage of the driving voltage source 16 is lower than that of the conventional one.
- the discharge parts 12A and 13A have a dimension Lb in the arrangement direction.
- the dimension Lb is, for example, 5 ⁇ m.
- the dimension Lb is almost equal to the thickness of the inner planar conductors 12 and 13, and the discharge portions 12A and 13A can sufficiently narrow the width in the arrangement direction even when compared with the conventional configuration.
- the ozone generator 10 according to the present embodiment is opposed to the discharge surface (top surface 11A) of the dielectric part 11.
- the number of discharge parts 12A and 13A per unit area that can be arranged can be greatly increased.
- the ozone generation efficiency per unit area on the discharge surface (top surface 11A) can be increased.
- the discharge parts 12A and 13A have a dimension La in the discharge surface direction.
- the dimension La is, for example, 50 ⁇ m.
- the dimension La is equal to or larger than the dimension Lb in the arrangement direction of the discharge parts 12A and 13A. That is, La ⁇ Lb. Therefore, in the discharge parts 12A and 13A, even if the dimension Lb in the arrangement direction is extremely small, the dimension La in the discharge surface direction can be secured more than that. For this reason, the conductor resistances of the discharge portions 12A and 13A do not increase remarkably.
- the ozone generation device 10 can be used even if the dimension Lb in the arrangement direction of the discharge portions 12A and 13A is significantly reduced in order to increase the ozone generation efficiency per unit area in the discharge portion. Power consumption and heat generation can be suppressed. By this, progress of the ozonolysis reaction in a discharge surface (top surface 11A) can be suppressed, and it can prevent that ozone generation efficiency falls by the influence of a heat
- the dimension Ld of the arrangement interval between the discharge part 12A and the discharge part 13A is larger than the dimension Lc between the discharge surface (top surface 11A) and the discharge parts 12A, 13A. That is, since the discharge portions 12A and 13A are closer to the top surface 11A than the distance between the discharge portions 12A and 13A, the electric field generated between the discharge portions 12A and 13A is likely to leak to the top surface 11A. It becomes a state. Also by this, in the ozone generating apparatus 10 according to the present embodiment, the driving voltage (discharge start voltage) necessary for causing creeping discharge on the top surface 11A of the dielectric part 11 can be lowered, Creeping discharge can be stably generated on the top surface 11A of the dielectric portion 11.
- the discharge portions 12A and 13A and the dielectric layer 21 can set the thicknesses (dimensions in the arrangement direction) with high accuracy. Therefore, the dimension Lb in the arrangement direction of the discharge parts 12A and 13A and the dimension Ld of the arrangement interval of the discharge parts 12A and 13A can be made substantially uniform in the discharge surface direction. For this reason, in the ozone production
- FIG. 3 is a flowchart illustrating an example of the manufacturing process of the ozone generator 10.
- a dielectric sheet forming step is performed (S1).
- a glass ceramic slurry is obtained by mixing glass powder, filler powder, crystallinity adjusting agent, solvent, dispersant, organic binder, plasticizer, and the like.
- the glass ceramic green sheet used as the dielectric material layer 21 later is produced from a glass ceramic slurry using a doctor blade etc.
- the glass ceramic green sheet is desirably formed larger than the size of the dielectric layer 21 of the single ozone generator 10.
- a planar conductor forming step is performed (S2).
- a metal paste such as silver, copper, and tungsten, a solvent, an organic binder, and the like are mixed and dispersed using a roll mill or the like to obtain a conductor paste.
- the pattern of the conductor paste which becomes the internal plane conductor 12 or the internal plane conductor 13 later is screen-printed on the glass ceramic green sheet.
- the pattern of the conductor paste that becomes the inner planar conductors 12 and 13 of the single ozone generator 10 is a large glass. It is desirable to print on a ceramic green sheet.
- a lamination process is performed (S3).
- a lamination process for example, a plurality of glass ceramic green sheets on which planar conductors are formed are stacked and a pressure is applied to produce a laminate in which unfired planar conductor patterns and glass ceramic green sheets are laminated over a plurality of layers.
- a firing step is performed (S4).
- the unfired laminate is fired in an oxidizing atmosphere so as to have a predetermined temperature profile.
- the laminated body (ozone generator 10) of the dielectric part 11 and the internal plane conductors 12 and 13 is produced.
- the ozone generator 10 of this embodiment can be manufactured by the above manufacturing method.
- individual pieces to be a plurality of ozone generators 10 are cut from a large-sized ceramic green sheet laminate in any step before or after the firing step. It is desirable to perform a brewing process.
- the discharge portions 12A and 13A having special cross-sectional shapes having dimensions larger in the discharge surface direction than in the arrangement direction are obtained simply by stacking the sheets of the dielectric layer 21 on which the planar conductor is formed. Even the ozone generator 10 can be easily manufactured.
- the thickness of the planar conductor formed on the dielectric sheet is extremely thin compared to the dimension in the planar direction even in a method with low processing accuracy such as a screen printing method.
- the width in the arrangement direction of 12A and 13A can be made extremely narrow.
- the arrangement interval between the discharge portions 12A and 13A can be extremely narrowed. Therefore, in the ozone generation apparatus 10 of the present embodiment, the ozone generation efficiency can be remarkably increased even when a method with low processing accuracy such as a screen printing method is used.
- the thickness of the dielectric sheet and the planar conductor becomes uniform with extremely high accuracy, so the width of the discharge portions 12A and 13A in the arrangement direction of the discharge portions 12A and 13A and the discharge portions 12A, Variation in the arrangement interval of 13A can be remarkably suppressed. For this reason, in the ozone generation apparatus 10 of this embodiment, the discharge part 12A, 13A is disconnected, a short circuit occurs between the discharge parts 12A, 13A, or the arc discharge between the discharge parts 12A, 13A. , 13A can be prevented from being damaged.
- FIG. 4 (A) is a left side view of the ozone generator 30.
- FIG. 4B is a front view of the ozone generator 30.
- the ozone generator 30 unlike the first embodiment described above, not only the top surface of the dielectric part but also the bottom surface functions as a discharge surface.
- the ozone generator 30 according to the second embodiment of the present invention is different from the first embodiment in that the inner plane conductor 32 is replaced with the inner plane conductors 12 and 13 and the terminal electrodes 14 and 15. , 33 and terminal electrodes 34, 35. Since other configurations are the same, the same reference numerals as those in the first embodiment are given, and the description of the configurations is omitted.
- a plurality of internal planar conductors 32 and 33 are provided, and are provided alternately in the dielectric portion 11 from the left side surface 11C side to the right side surface 11D side.
- the inner plane conductors 32 and 33 include rectangular parallelepiped plate-like discharge portions 32A and 33A and line-shaped lead portions 32B and 33B extending from the discharge portions 32A and 33A to the front side or the back side.
- the terminal electrode 34 is provided so as to cover the front surface 11 ⁇ / b> E, and is connected to the plurality of internal planar conductors 32.
- the terminal electrode 35 is provided so as to cover the back surface 11 ⁇ / b> F, and is connected to the plurality of internal planar conductors 33.
- the inner planar conductors 32 and 33 are opposed to the top surface 11A and the bottom surface 11B of the dielectric part 11 at the same interval. Therefore, the edge on the top surface 11A side and the edge on the bottom surface 11B side of the inner planar conductors 32 and 33 both function as discharge ends 32C and 33C, and both the top surface 11A and the bottom surface 11B of the dielectric part 11 It will function as a discharge surface.
- FIG. 5 (A) is a left side view of the ozone generator 40.
- FIG. 5B is a plan view of the ozone generator 40.
- the top surface, bottom surface, front surface, and back surface of the dielectric portion are configured as discharge surfaces.
- the ozone generator 40 according to the third embodiment of the present invention is different from the first embodiment in that the inner planar conductor 42 is replaced with the inner planar conductors 12 and 13 and the terminal electrodes 14 and 15. , 43 and terminal electrodes 44, 45. Since other configurations are the same, the same reference numerals as those in the first embodiment are given, and the description of the configurations is omitted.
- a plurality of inner planar conductors 42 and 43 are provided, and are arranged alternately in the dielectric portion 11 from the left side surface 11C side to the right side surface 11D side.
- the inner planar conductors 42 and 43 include rectangular annular discharge portions 42A and 43A, and line-shaped lead portions 42B and 43B extending to the inner openings of the discharge portions 42A and 43A.
- interlayer connection conductors 42D and 43D are provided in the inner openings of the discharge portions 42A and 43A so as to be connected to the lead portions 42B and 43B.
- the terminal electrode 44 is provided so as to cover the left side surface 11C, and is connected to the plurality of internal planar conductors 42 via the interlayer connection conductor 42D.
- the terminal electrode 45 is provided so as to cover the right side surface 11D, and is connected to the plurality of internal planar conductors 43 through the interlayer connection conductor 43D.
- the inner planar conductors 42 and 43 are opposed to the top surface 11A, the bottom surface 11B, the front surface 11E, and the back surface 11F of the dielectric part 11 at the same interval.
- the outer peripheral edge of the inner planar conductors 42, 43 that is, the edge on the top surface 11A side, the edge on the bottom surface 11B side, the edge on the front surface 11E side, and the edge on the back surface 11F side are all discharged.
- the top surface 11A, the bottom surface 11B, the front surface 11E, and the back surface 11F of the dielectric portion 11 function as discharge surfaces.
- FIG. 6A is a left side view of the ozone generator 50.
- FIG. 6B is a plan view of the ozone generator 50.
- the dielectric portion has a cylindrical shape having a peripheral surface, and the entire peripheral surface is configured as a discharge surface.
- the ozone generation device 50 according to the fourth embodiment of the present invention is different from the first embodiment in that it replaces the dielectric portion 11, the inner planar conductors 12 and 13, and the terminal electrodes 14 and 15.
- the dielectric portion 51, the inner planar conductors 52 and 53, and the terminal electrodes 54 and 55 are provided. Since other configurations are the same, the same reference numerals as those in the first embodiment are given, and the description of the configurations is omitted.
- the dielectric portion 51 has a columnar shape with a column axis extending along the arrangement direction, and has a peripheral surface 51A, a left side surface 11C, and a right side surface 11D (not shown) as outer surfaces.
- a plurality of internal planar conductors 52 and 53 are provided, and are provided alternately inside the dielectric portion 51 from the left side surface 11C side to the right side surface 11D side.
- the inner planar conductors 52 and 53 include annular discharge portions 52A and 53A, and line-shaped lead portions 52B and 53B extending to the inner openings of the discharge portions 52A and 53A.
- interlayer connection conductors 52D and 53D are provided in the inner openings of the discharge parts 52A and 53A so as to be connected to the lead parts 52B and 53B.
- the terminal electrode 54 is provided so as to cover the left side surface 11C, and is connected to the plurality of internal planar conductors 52 via the interlayer connection conductor 52D.
- the terminal electrode 55 is provided so as to cover the right side surface 11D, and is connected to the plurality of internal planar conductors 53 via the interlayer connection conductor 53D.
- the inner planar conductors 52 and 53 face the entire surface of the peripheral surface 51A of the dielectric part 51 at the same interval. Therefore, the outer peripheral edges of the inner planar conductors 52 and 53 function as the discharge ends 52C and 53C, and the entire peripheral surface 51A of the dielectric portion 51 functions as the discharge surface.
- the ozone generating apparatus 50 can also increase the discharge surface, and therefore, the ozone generation amount per unit time can also be increased.
- FIG. 7A is an electrical connection diagram of the ozone generator 60.
- the ozone generator 60 has the same general configuration as that of the above-described embodiment, and includes a dielectric unit 61, a plurality of discharge units 62, and a drive voltage source 63.
- the plurality of discharge parts 62 are grouped into four groups, and the discharge parts 62 of each group are arranged in order.
- the drive voltage source 63 is configured to output the same four-phase drive voltages V 1 to V 4 as the number of sets.
- the discharge units 62 of each set are configured to receive drive voltages V 1 to V 4 having phase numbers corresponding to the set numbers.
- FIG. 7B is a time waveform diagram of the drive voltages V 1 to V 4 .
- the drive voltages V 1 to V 4 have the same repeating pattern and a phase difference of 90 ° in the order of the phase numbers. Therefore, the drive voltages V 1 to V 4 have a relationship in which the phase difference circulates in the order of the phase numbers.
- the distribution of the electric field intensity near the discharge surface changes so as to circulate along the arrangement direction of the discharge portions 62.
- the gas in the space near the discharge surface moves along the arrangement direction under the influence of the electric field strength.
- the supply of oxygen to the discharge surface and the detachment of ozone from the discharge surface are promoted, and the amount of ozone generated can be increased.
- the gas flow is generated, dust and the like are hardly adsorbed on the discharge surface, and the reliability of the ozone generator 60 is improved.
- the drive voltage V 1 ⁇ V 4 is also possible to use a sine wave signal or a rectangular wave signal to other It is. If a pulse wave signal or a rectangular wave signal is used, the voltage at which discharge is started can be lowered compared with the case where a sine wave signal is used, which is more preferable.
- the number of phases of the driving voltage is four is shown, but any integer can be adopted as long as the number of phases of the driving voltage is three or more.
- the pattern waveform of each drive voltage may not be the same. For example, driving voltages having different amplitudes and repetition cycles can be used.
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Abstract
Description
図1は本発明の第1の実施形態に係るオゾン生成装置10の斜視図である。 << First Embodiment >>
FIG. 1 is a perspective view of an
次に、本発明の第2の実施形態に係るオゾン生成装置30について説明する。 << Second Embodiment >>
Next, an
次に、本発明の第3の実施形態に係るオゾン生成装置40について説明する。 << Third Embodiment >>
Next, an
次に、本発明の第4の実施形態に係るオゾン生成装置50について説明する。 << Fourth Embodiment >>
Next, an
次に、本発明の第5の実施形態に係るオゾン生成装置60について説明する。 << Fifth Embodiment >>
Next, an
11…誘電体部
11A…天面
11B…底面
11C…左側面
11D…右側面
11E…正面
11F…背面
12,13…内部平面導体
12A,13A…放電部
12B,13B…引出部
12C,13C…放電端
14,15…端子電極
16…駆動電圧源
21…誘電体層 DESCRIPTION OF
Claims (9)
- 沿面放電を生じさせる放電面を有する誘電体部と、
前記誘電体部に設けた導体からなり、前記放電面に近接して対向する放電端を有し、前記放電面に沿って間隔をあけて並ぶ複数の放電部と、
を備え、
前記放電部は、前記放電面と対向する放電面方向での自らの寸法をLaとし、前記放電面に沿って並ぶ配列方向での自らの寸法をLbとすると、La≧Lbである、
オゾン生成装置。 A dielectric portion having a discharge surface that causes creeping discharge;
A plurality of discharge portions comprising a conductor provided in the dielectric portion, having discharge ends that are close to and opposed to the discharge surface, and arranged at intervals along the discharge surface;
With
The discharge part is La ≧ Lb, where La is the dimension in the direction of the discharge surface facing the discharge surface, and Lb is the dimension in the direction of alignment along the discharge surface.
Ozone generator. - 前記誘電体部は、前記配列方向に積層した複数の誘電体層を備え、前記複数の放電部は、それぞれ誘電体層間に設けた平面導体からなる、
請求項1に記載のオゾン生成装置。 The dielectric portion includes a plurality of dielectric layers stacked in the arrangement direction, and the plurality of discharge portions are each composed of a planar conductor provided between the dielectric layers.
The ozone generator according to claim 1. - 前記放電面は前記複数の誘電体層の端面で構成されている、
請求項2に記載のオゾン生成装置。 The discharge surface is composed of end surfaces of the plurality of dielectric layers,
The ozone generator according to claim 2. - 前記放電面と前記放電端との間隔は、前記複数の放電部が隣接する間隔よりも狭い、
請求項1乃至請求項3のいずれかに記載のオゾン生成装置。 The interval between the discharge surface and the discharge end is narrower than the interval between the plurality of discharge portions,
The ozone generator in any one of Claim 1 thru | or 3. - 前記誘電体部は、1つの前記放電面を含む複数の外面を有し、
前記放電部は、1つの前記放電端を含む複数の端部を有し、
前記放電端と前記放電面とが対向する間隔が、他の端部と他の外面とが対向する間隔よりも狭い、
請求項1乃至請求項4のいずれかに記載のオゾン生成装置。 The dielectric portion has a plurality of outer surfaces including the one discharge surface,
The discharge part has a plurality of ends including one discharge end,
The interval between the discharge end and the discharge surface is narrower than the interval between the other end and the other outer surface,
The ozone generator in any one of Claim 1 thru | or 4. - 前記誘電体部は、2以上の放電面を含む複数の外面を有し、
前記放電部は、2以上の放電端を含む複数の端部を有し、
各放電端と各放電面とが対向する間隔がいずれも等しい、
請求項1乃至請求項4のいずれかに記載のオゾン生成装置。 The dielectric portion has a plurality of outer surfaces including two or more discharge surfaces,
The discharge part has a plurality of ends including two or more discharge ends,
The intervals at which each discharge end and each discharge surface face are equal,
The ozone generator in any one of Claim 1 thru | or 4. - 前記誘電体部は、前記放電面にあたる周面を有し、
前記放電端は、前記誘電体部の周面と一定の間を保ちながら延びる、
請求項1乃至請求項4のいずれかに記載のオゾン生成装置。 The dielectric part has a peripheral surface corresponding to the discharge surface,
The discharge end extends while maintaining a constant gap with the peripheral surface of the dielectric part,
The ozone generator in any one of Claim 1 thru | or 4. - 前記オゾン生成装置は、繰り返しのパターンと循環する位相差とを有するN(N≧3)相の駆動電圧を出力する駆動電圧源を備え、前記複数の放電部は、それらの並び順に従い第n(1≦n≦N)相目の駆動電圧が前記駆動電圧源から入力される、
請求項1乃至請求項7のいずれかに記載のオゾン生成装置。 The ozone generating device includes a driving voltage source that outputs a driving voltage of N (N ≧ 3) phase having a repetitive pattern and a circulating phase difference, and the plurality of discharge units are arranged in the order n. (1 ≦ n ≦ N) phase driving voltage is input from the driving voltage source;
The ozone generator in any one of Claim 1 thru | or 7. - 前記駆動電圧は矩形波信号またはパルス波信号である、
請求項8に記載のオゾン生成装置。 The driving voltage is a rectangular wave signal or a pulse wave signal.
The ozone generator of Claim 8.
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CN201680005482.7A CN107108208B (en) | 2015-01-30 | 2016-01-06 | Ozone generator |
DE112016000283.1T DE112016000283T5 (en) | 2015-01-30 | 2016-01-06 | OZONE GENERATING DEVICE |
JP2016571884A JP6350680B2 (en) | 2015-01-30 | 2016-01-06 | Ozone generator |
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JP2000036369A (en) * | 1998-07-21 | 2000-02-02 | Takuma Co Ltd | Creep discharge electrode |
JP2001019409A (en) * | 1999-07-02 | 2001-01-23 | Toshiaki Akimoto | High voltage ozone generator |
WO2015008559A1 (en) * | 2013-07-19 | 2015-01-22 | 株式会社村田製作所 | Airflow generator |
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CN201442867U (en) * | 2009-07-13 | 2010-04-28 | 安丘奥宗麦克斯设备有限公司 | Creeping discharge tube |
CN201709354U (en) * | 2010-07-13 | 2011-01-19 | 洪昆喨 | Dielectric discharge-based sterilizing device |
US8663569B2 (en) * | 2010-12-21 | 2014-03-04 | Kabushiki Kaisha Toshiba | Ozone generating apparatus |
US9039985B2 (en) * | 2011-06-06 | 2015-05-26 | Mks Instruments, Inc. | Ozone generator |
JP2013166660A (en) * | 2012-02-14 | 2013-08-29 | Murata Mfg Co Ltd | Ozone generating element and method for manufacturing ozone generating element |
JP5983529B2 (en) * | 2013-05-16 | 2016-08-31 | 株式会社村田製作所 | Discharge element |
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JPS6410040U (en) * | 1987-07-04 | 1989-01-19 | ||
JP2000036369A (en) * | 1998-07-21 | 2000-02-02 | Takuma Co Ltd | Creep discharge electrode |
JP2001019409A (en) * | 1999-07-02 | 2001-01-23 | Toshiaki Akimoto | High voltage ozone generator |
WO2015008559A1 (en) * | 2013-07-19 | 2015-01-22 | 株式会社村田製作所 | Airflow generator |
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