WO2016099417A1 - A modular antimicrobial and antiviral face mask and a manufacturing method against epidemics - Google Patents

A modular antimicrobial and antiviral face mask and a manufacturing method against epidemics Download PDF

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Publication number
WO2016099417A1
WO2016099417A1 PCT/TR2015/050197 TR2015050197W WO2016099417A1 WO 2016099417 A1 WO2016099417 A1 WO 2016099417A1 TR 2015050197 W TR2015050197 W TR 2015050197W WO 2016099417 A1 WO2016099417 A1 WO 2016099417A1
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WO
WIPO (PCT)
Prior art keywords
layer
bamboo
mask
manufacturing
filter
Prior art date
Application number
PCT/TR2015/050197
Other languages
French (fr)
Inventor
Cengiz KAYA
Guncem Ozgun EREN
Figen KAYA
Cansu NOBERI
Gizem GURBUZ
Suleyman UNLU
Mehmet SOY
Alican ERGEN
Original Assignee
Kaya Cengiz
Eren Guncem Ozgun
Kaya Figen
Noberi Cansu
Gurbuz Gizem
Unlu Suleyman
Soy Mehmet
Ergen Alican
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kaya Cengiz, Eren Guncem Ozgun, Kaya Figen, Noberi Cansu, Gurbuz Gizem, Unlu Suleyman, Soy Mehmet, Ergen Alican filed Critical Kaya Cengiz
Publication of WO2016099417A1 publication Critical patent/WO2016099417A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62BDEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
    • A62B23/00Filters for breathing-protection purposes
    • A62B23/02Filters for breathing-protection purposes for respirators

Definitions

  • the field of the invention is face masks. More clearly, it is related to a mask providing prevention of viral forms via nanostructured material and bamboo fabric instead of conventional filters that are used in face masks and mask manufacturing method.
  • microorganisms affect human health negatively. Especially, the development of microorganisms' resistance to used medicines day by day, put them into a dangerous position more than ever.
  • viral forms that are still contradictive if they are accepted to the class of microorganisms and threatening human health in higher level.
  • Viral forms are microscopic particles that can infect living cells and can reproduce via only this way. Because the vaccines used against terminal epidemics caused by these forms are effective against only a certain part of viruses, an exact outcome about the solution cannot be obtained.
  • World Health Organization reports show that viral epidemics that can cause holocausts around the world can appear at any time. Accordingly; it is obvious that a design of a new face mask, which provides that critical sectors like defense, health, education, security are not affected in a global virus epidemic, is required.
  • the size of bacteria in a nano technological solution constitutes an advantage in the field of nanotechnology.
  • the produced nanosized materials are generally under 100 nanometers. It provides that bacteria are kept in an area which has a size that bacteria cannot pass through and additionally where overreactive groups are found together. This reactive groups that nanoforms have damage structures of bacteria cell walls and then cause them dying by entering their metabolisms. It is nanostructured filters' disadvantages that not having any response to the viral treats, in the terms of viral epidemics, whereas they can inhibit current possible bacterial activity.
  • the other method is the filters made by using bamboo material.
  • bamboo is configured into coal in the manufacturing step firstly, then it is produced in the form of nanocomposite.
  • the main disadvantages of manufacturing method of this type of masks are that a lot of chemicals are used especially in the process of configuring bamboo into coal and accordingly processes include a long period. The usage of coal in these processes decreases being antibacterial of the system.
  • the purpose of the invention is to remove these known disadvantages of the technique. More clearly, the purpose of the invention is to provide a new antibacterial and antiviral mask to increase effectiveness of the existing face masks and manufacturing method for the disclosed face mask to be produced from bamboo material with the nanotechnological production steps different from the conventional manufacturing methods.
  • Another purpose of the invention is to obtain an antiviral and antibacterial mask which does not still exist in the market by that bamboo material is subjected to process steps nanotechnologically. Another purpose of the invention is that the effectiveness of the mask can be increased by a single layer or more than one layer in accordance with production conditions.
  • Another purpose of this invention is that an effective product against not only bacterial forms but also viral forms can be obtained by supporting filter material with nanostructures.
  • Another purpose of this invention is to obtain a natural antibacterial filter because filter material is bamboo.
  • Another purpose of the invention is to have a manufacturing method applied without being lost antibacterial property of masks in comparison with masks obtained by conventional nanotechnological manufacturing method.
  • nanostructures with different morphologies stick onto zeolite forms in a very short time without reaching any high temperatures.
  • Zeolite is a natural material with porous structure as a result of its structure. With a partial heating, high temperature is out of the question, it is provided that metallic nanostructures hold on to especially around the pore and the other parts of zeolite.
  • covering of the obtained zeolite based powder onto bamboo fabric is realized by immersion and spray methods.
  • bamboo is a plant that has antibacterial property by nature. Thus, it protects this property with the fabric obtained from here. By covering powders whose production is realized onto this fabric which is mainly obtained from China with immersion and spray, antiviral ability is added to its antibacterial property.
  • FIG. 1 Perspective view of the disclosed filter layers in the invention
  • FIG. 1 Perspective view of the filter lid
  • Figure 3 Perspective view of the main body of mask
  • Fabric production from bamboo tree is the point due to its disclosed properties.
  • This fabric that preferred in many different areas, is used as a material which keeps filter(l 11) matrix element's (nanostructures) in the mask(l).
  • Nanostructures with different morphologies are synthesized.
  • the application used during synthesizing is a hydrothermal manufacturing method(lOO).
  • the particles that are metal oxide forms are synthesized in different types and morphologies under a certain temperature and pressure with this method.
  • zeolite is used on the purpose of support for nanoparticles.
  • Zeolites are aluminum silicates exposed to hydration and have a structure like uniform honeycombs. These structures have circles called as window.
  • zeolite solution is prepared by using distilled water and then nano powders are added respectively and they are mixed via magnetic stirrer. Finally, they are exposed to drying process.
  • the disclosed mask(l) of the invention is related to the manufacturing method(lOO) of an antibacterial and antiviral mask(l) as described above which comprises these steps,
  • bamboo layer(1112) is the main element of the filter(l l l) and it performs as the fabric covered by nanostructures.
  • Mask(l) consists of body(l l) and filter(l l l).
  • Filter(l l l) consists of lower layer(l l l l), bamboo layer(1112), meltable (1113), upper layer(1114), gasket(1115) and filter lid(l 116) from bottom to top respectively.
  • Filter lid(l 116) has pores(11161) and it helps that passing is not allowed in the bacteria respiration.
  • Lower layer(l l l l) is the layer obtained as laminated here, behaves as increasing element for strength of the structure and low filtration.
  • meltable(1113) is used as a helper element for providing filtration in a certain percentage. While upper layer(1114) is the layer obtained as laminated here, it behaves as increasing element for strength of the structure and low filtration as well as lower layer(l 111). Gasket(l 115) located under the filter lid(l 116) perform as a holder here.

Abstract

The invention is a new antibacterial and antiviral mask (1) to increase the effectiveness of existing face masks and also a face mask obtained from bamboo material with nanotechnologic manufacturing steps different from conventional manufacturing methods and face mask manufacturing method. It is related to a mask (1) providing prevention of viral forms via bamboo fabric and nanostructured material instead of conventional filters used in face masks and mask manufacturing method (100).

Description

DESCRIPTION
A MODULAR ANTIMICROBIAL AND ANTIVIRAL FACE MASK AND A MANUFACTURING METHOD AGAINST EPIDEMICS
Technical field related to the invention
The field of the invention is face masks. More clearly, it is related to a mask providing prevention of viral forms via nanostructured material and bamboo fabric instead of conventional filters that are used in face masks and mask manufacturing method.
Disadvantages of the prior art
It is an obvious fact that microorganisms affect human health negatively. Especially, the development of microorganisms' resistance to used medicines day by day, put them into a dangerous position more than ever. There are viral forms that are still contradictive if they are accepted to the class of microorganisms and threatening human health in higher level. Viral forms are microscopic particles that can infect living cells and can reproduce via only this way. Because the vaccines used against terminal epidemics caused by these forms are effective against only a certain part of viruses, an exact outcome about the solution cannot be obtained. World Health Organization reports show that viral epidemics that can cause holocausts around the world can appear at any time. Accordingly; it is obvious that a design of a new face mask, which provides that critical sectors like defense, health, education, security are not affected in a global virus epidemic, is required.
There are a lot of preferred mask types. Within these types; while a part of these types has nanostructured filter material, the other part has only a fabric that performs a simple filter duty. The existing face masks have a partial function against bacteria conventionally. However; function of bacteria changes according to their sizes. The property which designates it is that bacteria are approximately in the scale of 1000 nanometers namely 1 micron. In this case it is not enough to kill viruses in the size of 100 nanometers because the pore size of conventional masks is larger. Mask filters made of synthesized nanomaterials deactivate viruses with different mechanisms by damaging their DNAs. In addition, it is prevented that the viruses are breathed by prevention of viruses to pass through pores physically via keeping pore sizes of used filters under 100 nanometers.
On the other hand, the size of bacteria in a nano technological solution constitutes an advantage in the field of nanotechnology. The produced nanosized materials are generally under 100 nanometers. It provides that bacteria are kept in an area which has a size that bacteria cannot pass through and additionally where overreactive groups are found together. This reactive groups that nanoforms have damage structures of bacteria cell walls and then cause them dying by entering their metabolisms. It is nanostructured filters' disadvantages that not having any response to the viral treats, in the terms of viral epidemics, whereas they can inhibit current possible bacterial activity.
This mentioned type of conventional masks has a partial effect against bacterial threats, however; because of sizes of viral forms, it does not have the capacity for prevention of this threat completely.
The other method is the filters made by using bamboo material. Bamboo is configured into coal in the manufacturing step firstly, then it is produced in the form of nanocomposite. The main disadvantages of manufacturing method of this type of masks are that a lot of chemicals are used especially in the process of configuring bamboo into coal and accordingly processes include a long period. The usage of coal in these processes decreases being antibacterial of the system.
The purpose of the invention The special purpose of the invention is to remove these known disadvantages of the technique. More clearly, the purpose of the invention is to provide a new antibacterial and antiviral mask to increase effectiveness of the existing face masks and manufacturing method for the disclosed face mask to be produced from bamboo material with the nanotechnological production steps different from the conventional manufacturing methods.
Another purpose of the invention is to obtain an antiviral and antibacterial mask which does not still exist in the market by that bamboo material is subjected to process steps nanotechnologically. Another purpose of the invention is that the effectiveness of the mask can be increased by a single layer or more than one layer in accordance with production conditions.
Another purpose of this invention is that an effective product against not only bacterial forms but also viral forms can be obtained by supporting filter material with nanostructures.
Another purpose of this invention is to obtain a natural antibacterial filter because filter material is bamboo.
Another purpose of the invention is to have a manufacturing method applied without being lost antibacterial property of masks in comparison with masks obtained by conventional nanotechnological manufacturing method. Brief description of the invention
In this invention, it is provided that nanostructures with different morphologies stick onto zeolite forms in a very short time without reaching any high temperatures. Zeolite is a natural material with porous structure as a result of its structure. With a partial heating, high temperature is out of the question, it is provided that metallic nanostructures hold on to especially around the pore and the other parts of zeolite. Then covering of the obtained zeolite based powder onto bamboo fabric is realized by immersion and spray methods. Bamboo is a plant that has antibacterial property by nature. Thus, it protects this property with the fabric obtained from here. By covering powders whose production is realized onto this fabric which is mainly obtained from China with immersion and spray, antiviral ability is added to its antibacterial property.
Brief description of the figures
Figure 1: Perspective view of the disclosed filter layers in the invention
Figure 2: Perspective view of the filter lid
Figure 3: Perspective view of the main body of mask
Description of the references in the figures:
Parts in the attached figures are numbered one by one for the purpose of this invention and the equivalents of this numbers are given below.
1. Mask
11. Body
111. Filter
1111. Lower layer
1112. Bamboo layer
1113. Meltable
1114. Upper layer
1115. Gasket
1116. Filter lid
11161. Pore
100 Manufacturing method
Detailed description of the invention
Fabric production from bamboo tree is the point due to its disclosed properties. This fabric, that preferred in many different areas, is used as a material which keeps filter(l 11) matrix element's (nanostructures) in the mask(l). Nanostructures with different morphologies are synthesized. The application used during synthesizing is a hydrothermal manufacturing method(lOO). The particles that are metal oxide forms are synthesized in different types and morphologies under a certain temperature and pressure with this method. After this process, zeolite is used on the purpose of support for nanoparticles. Zeolites are aluminum silicates exposed to hydration and have a structure like uniform honeycombs. These structures have circles called as window. With the obtained nano powders it is aimed that these windows are narrowed down, additionally antibacterial and antiviral property is gained to zeolite by covering its surface. For this, zeolite solution is prepared by using distilled water and then nano powders are added respectively and they are mixed via magnetic stirrer. Finally, they are exposed to drying process.
The disclosed mask(l) of the invention is related to the manufacturing method(lOO) of an antibacterial and antiviral mask(l) as described above which comprises these steps,
- Adding sodium chloride (NaCl) into distilled water and raising the temperature to 80°C,
- Adding zeolite at the reached temperature and carrying out mixing process for four hours,
- Cooling at the room temperature and putting into the drying oven to dry,
- Preparing solution by using the dried powder and distilled water and adding titanium tetra isopropoxide (TTIP),
- After addition, performing the mixing process via magnetic stirrer for eight hours,
- Covering the obtained powder after drying onto the bamboo fabric by spray method, performing spray process onto the fabrics in 5x5 cm size.
Bamboo layer(1112) is the main element of the filter(l l l) and it performs as the fabric covered by nanostructures. Mask(l) consists of body(l l) and filter(l l l). Filter(l l l) consists of lower layer(l l l l), bamboo layer(1112), meltable (1113), upper layer(1114), gasket(1115) and filter lid(l 116) from bottom to top respectively. Filter lid(l 116) has pores(11161) and it helps that passing is not allowed in the bacteria respiration. Lower layer(l l l l) is the layer obtained as laminated here, behaves as increasing element for strength of the structure and low filtration. In addition, meltable(1113) is used as a helper element for providing filtration in a certain percentage. While upper layer(1114) is the layer obtained as laminated here, it behaves as increasing element for strength of the structure and low filtration as well as lower layer(l 111). Gasket(l 115) located under the filter lid(l 116) perform as a holder here.

Claims

For usage in the face mask field; a mask comprising antibacterial and antiviral property is characterized by a body(l l) and a filter(l l l) having a bamboo layer(1112) that performs as a fabric covered by nanostructures as main element having antibacterial and antiviral property on this body(l l).
A filter(l l l) according to Claim 1 is characterized by comprising a lower layer(l l l l) at the bottom as an increasing element for strength of the structure and low filtration, a bamboo layer(1112) comprising antibacterial and antiviral property on the lower layer(l l l l), a meltable(1113) as an assist element to provide filtration on the bamboo layer(1112), an upper layer(1114) which is a layer obtained as laminated, used on the purpose of increasing strength of structure and low filtration on the meltable(1113), a gasket(1115) performing as holder on the upper layer(l 116) and a filter lid(l 116) at the top.
A filter lid(l 116) according to Claim 2 is characterized by comprising pores providing respiration filtration.
A manufacturing method(lOO) for bamboo layer(1112) according to Claim 1 is characterized by comprising the steps of,
- Adding sodium chloride (NaCl) into distilled water and raising the temperature to 80°C,
- Adding zeolite at the reached temperature and carrying out mixing process for four hours,
- Cooling at the room temperature and putting into the drying oven to dry,
- Preparing solution by using the dried powder and distilled water and adding titanium tetra isopropoxide (TTIP),
- After addition, performing the mixing process via magnetic stirrer for eight hours,
- Covering the powder obtained after drying, onto the bamboo fabric by spray method, performing spraying process onto the fabrics in 5x5 cm size.
PCT/TR2015/050197 2014-12-16 2015-11-25 A modular antimicrobial and antiviral face mask and a manufacturing method against epidemics WO2016099417A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
TR2014/15204 2014-12-16
TR201415204 2014-12-16

Publications (1)

Publication Number Publication Date
WO2016099417A1 true WO2016099417A1 (en) 2016-06-23

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112522861A (en) * 2020-10-12 2021-03-19 苏州冠洁纳米材料科技有限公司 Application of composite nano particles of carbon and copper in melt-blown non-woven material

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110209710A1 (en) * 2010-02-26 2011-09-01 Spencer Iii Carlos J Filtered bandanas
EP2484409A1 (en) * 2009-09-30 2012-08-08 NBC Meshtec, Inc. Mask
US20130091611A1 (en) * 2006-02-16 2013-04-18 Guogang Ren Anti-viral Formulations Nanomaterials and Nanoparticles

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130091611A1 (en) * 2006-02-16 2013-04-18 Guogang Ren Anti-viral Formulations Nanomaterials and Nanoparticles
EP2484409A1 (en) * 2009-09-30 2012-08-08 NBC Meshtec, Inc. Mask
US20110209710A1 (en) * 2010-02-26 2011-09-01 Spencer Iii Carlos J Filtered bandanas

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112522861A (en) * 2020-10-12 2021-03-19 苏州冠洁纳米材料科技有限公司 Application of composite nano particles of carbon and copper in melt-blown non-woven material

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