TWI705837B - Facial mask and the method of forming the same - Google Patents

Facial mask and the method of forming the same Download PDF

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TWI705837B
TWI705837B TW109103785A TW109103785A TWI705837B TW I705837 B TWI705837 B TW I705837B TW 109103785 A TW109103785 A TW 109103785A TW 109103785 A TW109103785 A TW 109103785A TW I705837 B TWI705837 B TW I705837B
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virus
layer
mask
inhibiting
item
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TW109103785A
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TW202130387A (en
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江國慶
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江國慶
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Abstract

The present invention discloses a substrate for a facial mask, the substrate is formed by Roll to Roll process and to have anti-Virus function. The mask comprises an inner layer, a middle layer and an outer layer, wherein the middle layer or the outer layer comprises a cationic metalloorganic compound for inhibiting the virus.

Description

口罩與其製作方法 Mask and its making method

本發明係關於一種口罩,尤其是有關於一種抗病毒口罩與其製程。 The present invention relates to a mask, in particular to an anti-virus mask and its manufacturing process.

近年來由於流感橫行,特別是對於孩童而言,影響尤其嚴重。目前所有市面口罩只有過濾粉塵、或細菌功能,無防護抑制、殺死病毒功能。而傳統上使用奈米銀不利環境與人體,參看論文:奈米微粒危害測試技術與生物毒性指標之探討,作者:李宥萱等人,發表單位:國立成功大學環境醫學研究所及勞動部勞動及職業安全衛生研究所,勞動及職業安全衛生研究季刊,民國105年9月,第24卷第3期,第330-342頁,該研究載明曝露18或24小時,奈米銀將使得細胞毒性增加,且在每毫升5微克的劑量下,造成細胞百分之58.95的死亡率,因此必須採用非奈米銀技術殺菌,奈米銀雖能抑制病菌,但無法抑制病毒。本發明於是生焉。 In recent years, due to the rampant flu, especially for children, the impact is particularly serious. At present, all masks on the market only have the function of filtering dust or bacteria, and have no function of protecting, inhibiting or killing viruses. The use of nano-silver adverse environmental and human Traditionally, see the paper: Nanoparticles investigate toxicity testing techniques and indicators of biological hazards, author: Li Yu Xuan et al., Published by: National Cheng Kung University Institute of Environmental Medicine and Labor Ministry of Labor and Vocational Institute of Safety and Health, Labor and Occupational Safety and Health Research Quarterly, September 2005, Vol. 24 No. 3, pp. 330-342, the study stated that exposure to 18 or 24 hours, nanosilver will increase cytotoxicity And at a dose of 5 micrograms per milliliter, the cell death rate is 58.95%. Therefore, non-nanosilver technology must be used for sterilization. Although nanosilver can inhibit germs, it cannot inhibit viruses. The present invention is thus made.

本發明係有關於具有下列特性之口罩。本發明提出一種口罩之製作方法,包含:備置浸染溶液,該浸染溶液包含抗病毒(及/或滅菌酵素)與樹脂成分;以轉軸至轉軸式裝置驅動基材移動,藉由通過具有浸染溶液之浸染槽,使該基材吸附該浸染溶液,形成抗病毒成分於該基材上,其中基材包含不織布,基材包含PP。 The present invention relates to a mask with the following characteristics. The present invention proposes a method for making a mask, which includes: preparing a dip solution containing anti-virus (and/or sterilization enzyme) and resin components; a rotating shaft-to-rotation device drives the substrate to move, by passing through an impregnating solution The dip tank makes the substrate absorb the dip solution to form an antiviral component on the substrate, wherein the substrate includes non-woven fabric, and the substrate includes PP.

本發明揭露一種口罩,包含:裏層;中層,配置於該裏層之上;及外層,配置於該中層之上,其中製作外層步驟包含:備置浸染溶液,該浸染溶液包含抗病毒(及/或滅菌酵素)與樹脂成分;以轉軸至轉軸式裝置驅動基材移動, 藉由通過具有浸染溶液之浸染槽,使該基材吸附該浸染溶液,形成抗病毒成分於該基材上,其中基材包含不織布,基材包含PP。 The present invention discloses a mask, comprising: an inner layer; a middle layer disposed on the inner layer; and an outer layer disposed on the middle layer, wherein the step of making the outer layer includes: preparing a dip solution, the dip solution containing anti-virus (and/ Or sterilizing enzyme) and resin components; the substrate is driven to move by a shaft-to-rotation device, By passing through a dip tank with a dip solution, the substrate is made to absorb the dip solution to form an antiviral component on the substrate, where the substrate includes non-woven fabric and the substrate includes PP.

本發明揭露一種口罩,包含:裏層,其中製作該裏層步驟包含:備置浸染溶液,該浸染溶液包含香味分子;以轉軸至轉軸式裝置驅動基材移動,藉由通過具有浸染溶液之浸染槽,使該基材吸附該香味分子,使該基材具有香氣;中層,配置於該裏層之上;及外層,配置於該中層。本發明揭露一種口罩,包含一種口罩,包含:裏層;中層,配置於該裏層之上,包含過濾層;及外層,配置於該中層之上,其中該外層包含陽離子金屬有機化合物,用於抑制病毒。其中該外層包含紫外線吸收劑、光致變色染料、樹脂或上述之任意組合。其中該外層包含溶菌酵素,其中該中層包含奈米微孔聚四氟乙烯(PTFE)薄膜。 The present invention discloses a mask comprising: an inner layer, wherein the step of making the inner layer includes: preparing a dip solution, the dip solution containing fragrance molecules; a rotating shaft-to-rotation device drives the substrate to move, by passing through a dip tank with the dip solution , The substrate is made to absorb the fragrance molecules to make the substrate have fragrance; the middle layer is arranged on the inner layer; and the outer layer is arranged on the middle layer. The present invention discloses a mask, including a mask, comprising: an inner layer; a middle layer disposed on the inner layer and including a filter layer; and an outer layer disposed on the middle layer, wherein the outer layer includes a cationic metal organic compound for Suppress the virus. Wherein the outer layer contains ultraviolet absorber, photochromic dye, resin or any combination of the above. The outer layer contains lysozyme, and the middle layer contains a nanoporous polytetrafluoroethylene (PTFE) film.

本發明揭露一種口罩,包含:裏層;中層,配置於該裏層之上,其中製作該中層步驟包含:備置浸染溶液,該浸染溶液包含抗病毒(及/或滅菌酵素)與樹脂,藉由通過具有浸染溶液之浸染槽,使該中層基材吸附該抗病毒(及/或滅菌酵素);及外層,配置於該中層之上。 The present invention discloses a mask, comprising: an inner layer; a middle layer, arranged on the inner layer, wherein the step of making the middle layer includes: preparing a dip solution, the dip solution containing anti-virus (and/or sterilization enzyme) and resin, by The middle layer substrate is made to adsorb the anti-virus (and/or sterilization enzyme) through the dip tank with the dip solution; and the outer layer is arranged on the middle layer.

一種口罩,包含:裏層;中層,配置於該裏層之上,包含超微孔生技濾淨膜(PTFE);及外層,配置於該中層之上,其中該外層可抗紫外線。其中該外層包含紫外線吸收劑、光致變色染料、樹脂或上述之任意組合。 A mask includes: an inner layer; a middle layer, arranged on the inner layer, including an ultra-microporous biotechnology filter membrane (PTFE); and an outer layer, arranged on the middle layer, wherein the outer layer can resist ultraviolet rays. Wherein the outer layer contains ultraviolet absorber, photochromic dye, resin or any combination of the above.

一種口罩,包含:裏層,包含香味分子,藉由通過浸染溶液,使該裏層基材吸附該香味分子;中層,配置於該裏層之上,包含超微孔生技濾淨膜(PTFE);及外層,配置於該中層之上。 A mask, comprising: an inner layer, containing fragrance molecules, through the dip solution to make the inner substrate absorb the fragrance molecules; a middle layer, arranged on the inner layer, containing ultra-microporous biotechnology filter membrane (PTFE ); and the outer layer, which is arranged on the middle layer.

一種口罩,包含:裏層;中層,配置於該裏層之上,包含抗菌成份,其中該抗菌成份包含溶菌酵素或抗流感藥劑;及外層,配置於該中層之上,其中該外層可抗紫外線。 A mask, comprising: an inner layer; a middle layer arranged on the inner layer and containing antibacterial ingredients, wherein the antibacterial ingredient contains lysozyme or an anti-flu medicine; and an outer layer arranged on the middle layer, wherein the outer layer can resist ultraviolet rays .

一種口罩,包含:裏層;中層,配置於該裏層之上;及外層,配 置於該中層之上,包含抗菌成份,其中該抗菌成份包含溶菌酵素或抗流感藥劑,其中該中層包含超微孔生技濾淨膜(PTFE)。 A mask, comprising: an inner layer; a middle layer arranged on the inner layer; and an outer layer with It is placed on the middle layer and contains an antibacterial component, wherein the antibacterial component contains lysozyme or an anti-influenza agent, and the middle layer contains an ultra-microporous biotechnology filter membrane (PTFE).

一種口罩,包含:裏層;中層,配置於該裏層之上,包含過濾層;及外層,其中至少該裏層或該外層包含抑制病毒活性物,選自以下之一或任意組合(1)表面蛋白破壞有機化合物,藉由化學吸附性改變病毒表面蛋白質;(2)產生羥基金屬化合物,利用自由基反應產生羥基自由基,提取病毒蛋白質中的氫原子,其中該抑制病活性毒物包含有機一無機複合鹽類或陽離子金屬有機化合物。其中該抑制病毒活性物之抑制病毒活性大於標準值為3,較佳為其中該抑制病毒活性物之抑制病毒活性值為3.4。 A mask, comprising: an inner layer; a middle layer arranged on the inner layer and comprising a filter layer; and an outer layer, wherein at least the inner layer or the outer layer contains a virus-inhibiting active substance, selected from one or any combination of (1) The surface protein destroys organic compounds and changes the virus surface protein by chemisorption; (2) produces hydroxyl metal compounds, uses free radical reactions to generate hydroxyl free radicals, and extracts the hydrogen atoms in the viral proteins. The pathogenic active poison includes organic one Inorganic composite salts or cationic metal organic compounds. Wherein, the virus-inhibiting activity of the virus-inhibiting activity is greater than the standard value of 3, and preferably, the virus-inhibiting activity of the virus-inhibiting activity is 3.4.

一種製造抑制病毒活性層之方法,包含:備置抑制病毒活性物,其中該抑制病毒活性物選自以下之一或任意組合(1)表面蛋白抑制有機化合物,藉由化學吸附性改變病毒表面蛋白質;(2)產生羥基金屬化合物,利用自由基反應產生羥基自由基,提取病毒蛋白質中的氫原子;及混和該抑制病毒活性物與一溶劑,使其披覆、塗佈、於該抑制病毒活性層之至少一表面。其中該抑制病活性毒物包含有機一無機複合鹽類或陽離子金屬有機化合物。其中該抑制病毒活性物之抑制病毒活性大於標準值為,較佳為3.4。 A method of manufacturing a virus-inhibiting active layer, comprising: preparing a virus-inhibiting active substance, wherein the virus-inhibiting active substance is selected from one or any combination of the following (1) surface protein inhibitory organic compound, which changes the virus surface protein by chemisorption; (2) Generate hydroxyl metal compounds, use free radical reactions to generate hydroxyl free radicals, and extract hydrogen atoms in viral proteins; and mix the virus-inhibiting active substance with a solvent to coat, coat, and coat the virus-inhibiting active layer At least one surface. The disease-inhibiting active poison includes organic-inorganic composite salts or cationic metal organic compounds. Wherein, the anti-virus activity of the anti-virus activity is greater than the standard value, preferably 3.4.

一種製造抑制病毒活性層之方法,包含:備置抑制病毒活性物,其中該抑制病毒活性物選自以下之一或任意組合(1)表面蛋白抑制有機化合物,藉由化學吸附性改變病毒表面蛋白質;(2)產生羥基金屬化合物,利用自由基反應產生羥基自由基,提取病毒蛋白質中的氫原子;及混和該抑制病毒活性物與一高分子,利用織布或不織布程序使其摻雜於該抑制病毒活性層中。其中該抑制病活性毒物包含有機一無機複合鹽類或陽離子金屬有機化合物。其中該抑制病毒活性物之抑制病毒活性大於標準值為3,較佳為其中該抑制病毒活性物之抑制病毒活性值為3.4。 A method of manufacturing a virus-inhibiting active layer, comprising: preparing a virus-inhibiting active substance, wherein the virus-inhibiting active substance is selected from one or any combination of the following (1) surface protein inhibitory organic compound, which changes the virus surface protein by chemisorption; (2) Generate hydroxyl metal compounds, use free radical reactions to generate hydroxyl free radicals, extract hydrogen atoms in viral proteins; and mix the virus-inhibiting active substance with a polymer, and use the weaving or non-woven process to make it doped in the inhibitor Virus active layer. The disease-inhibiting active poison includes organic-inorganic composite salts or cationic metal organic compounds. Wherein, the virus-inhibiting activity of the virus-inhibiting activity is greater than the standard value of 3, and preferably, the virus-inhibiting activity of the virus-inhibiting activity is 3.4.

102:轉軸 102: shaft

102A:溶液 102A: solution

104:浸染槽 104: dip tank

106:轉軸至轉軸式裝置 106: shaft to shaft device

108:加熱器 108: heater

110:基材 110: Substrate

200:外層 200: Outer layer

220:中間層 220: middle layer

240:裏層 240: inner layer

第一圖為本發明之裝置。 The first figure shows the device of the present invention.

第二圖為本發明之製作。 The second figure is the production of the present invention.

第三圖為本發明之口罩。 The third figure shows the mask of the present invention.

第四圖與第五圖為通過抗病毒檢測圖。 The fourth and fifth pictures are through anti-virus detection pictures.

一般而言,口罩包含至少三層,包含裡層、中層為過濾層,以及外層。本發明口罩包含利用以下製程製作外層之基材,使其具備紫外線防護或抗病毒功效。 Generally speaking, a mask contains at least three layers, including an inner layer, a middle layer as a filter layer, and an outer layer. The mask of the present invention includes a base material with an outer layer made by the following process to make it have ultraviolet protection or anti-virus effects.

一轉軸至轉軸式(roll to roll)裝置106配置,轉軸至轉軸式(roll to roll)裝置106包含至少三個轉軸102,其中至少一轉軸被至於一浸染槽104內,浸染槽104用於承載染料。得藉由驅動裝置,例如馬達等加以驅動轉軸102,使其依據一轉軸旋轉,而牽動軟質基材移動,例示如第一圖中之旋轉箭頭方向旋轉,使得基材110可由一端捲至另一端。於此過程中將帶動基材110移動,並通過浸染槽104內,於其中將防止外線染料或抗病毒成分附著於基材110上。可控制轉軸102之轉速,利於控制移動速率,進而控制材料厚度。加熱裝置108對應配置於水平移動基材110之下側,可以選擇性開啟加熱裝置,提供乾燥所需熱源。加熱裝置108可以為燈泡、熱風、電磁輻射或是紅外線加熱器。 A roll to roll device 106 is configured. The roll to roll device 106 includes at least three rotating shafts 102, of which at least one of the rotating shafts is placed in a dip tank 104, which is used for carrying dye. The rotating shaft 102 must be driven by a driving device, such as a motor, so that it rotates according to a rotating shaft and moves the soft substrate. For example, it rotates in the direction of the rotation arrow in the first figure, so that the substrate 110 can be rolled from one end to the other. . During this process, the substrate 110 will be driven to move and pass through the dip tank 104, where the external dye or antiviral component will be prevented from adhering to the substrate 110. The rotation speed of the rotating shaft 102 can be controlled, which is beneficial to control the moving speed and thus the material thickness. The heating device 108 is correspondingly configured on the lower side of the horizontally moving substrate 110, and the heating device can be selectively turned on to provide a heat source required for drying. The heating device 108 can be a light bulb, hot air, electromagnetic radiation or an infrared heater.

隨著製程進展,基材由未浸染之一端移轉至另一端,此時已完成浸染之基材將被捲至另一端而收取。基於基材具有撓曲性,故可以將其捲曲於另一端。若有必要,則可以開啟加熱裝置提供烘乾所需熱能。隨後可將成捲之基材實施後續加工製作成口罩或其他用品,諸如抗病毒頭套、床單、被套、枕頭套、遮簾、擦拭巾等。 As the process progresses, the substrate is transferred from one end of the unimpregnated end to the other end. At this time, the impregnated substrate will be rolled to the other end and collected. Since the substrate has flexibility, it can be crimped on the other end. If necessary, the heating device can be turned on to provide heat energy for drying. The rolled substrate can then be processed into masks or other products, such as anti-viral headgear, bed sheets, duvet covers, pillow cases, blinds, wipes, etc.

本發明可以採用非金屬或非金屬氧化物材質作為防紫外線材料,以避免環境汙染。利用可撓曲式基材,使得材質得透過本發明之轉軸至轉軸式裝 置,可以大量製作薄膜,製程不污染環境。且利用驅動轉軸之速度控制薄膜成長厚度,且可附著於不規則或不平表面。 The present invention can use non-metal or non-metal oxide materials as the anti-ultraviolet material to avoid environmental pollution. Using a flexible substrate, the material can pass through the shaft of the present invention to the shaft type The film can be produced in large quantities, and the process does not pollute the environment. And the speed of the drive shaft is used to control the thickness of the film, and it can be attached to irregular or uneven surfaces.

實施例參照第二圖,此實施例裝置與第一圖類似,不同者為本實施例採用印刷、塗佈、噴灑或噴墨(inkjet print),將溶液塗佈於所欲之軟質基板上。備置溶液後,則啟動噴墨、噴灑、印刷或塗佈程序,將材質分佈於軟質基材之上,若利用噴墨列印式則可以將染料圖案直接噴塗於軟質基板上,其餘步驟類似上實施例,包含選擇性加熱。 Embodiment Referring to the second figure, the device of this embodiment is similar to the first figure. The difference is that this embodiment uses printing, coating, spraying or inkjet printing to coat the solution on the desired flexible substrate. After preparing the solution, start the inkjet, spray, printing or coating process to distribute the material on the soft substrate. If the inkjet printing method is used, the dye pattern can be directly sprayed on the soft substrate. The other steps are similar. Examples include selective heating.

抗紫外線口罩可以在其表布上噴塗、浸染或塗佈抗紫外線吸收材質或光致變染料,而達到抗紫外線功能。若噴塗有防紫外線可觀察其變化,而得知防護功能,傳統上口罩並無防護紫外線功能,更遑論觀察其防護效果,實際上,傳統口罩無任何防護功能,因此不利於臉部美容術後保養。美容術後保養,其中最重要一環便是防止紫外線照射,因此本發明對於美容術後保養十分重要,傳統口罩完全無法達到此功效。 Anti-ultraviolet masks can be sprayed, impregnated or coated with anti-ultraviolet absorbing materials or photochromic dyes on their surface cloth to achieve the anti-ultraviolet function. If the spray has anti-ultraviolet rays, the changes can be observed, and the protection function is known. Traditionally, masks have no UV protection function, let alone observe its protection effect. In fact, traditional masks have no protection function, so it is not conducive to facial cosmetic surgery. maintenance. The most important aspect of post-cosmetic maintenance is to prevent ultraviolet radiation. Therefore, the present invention is very important for post-cosmetic maintenance, and traditional masks cannot achieve this effect at all.

本發明將光致變色(Photo-Chromic)染料摻雜於樹脂中,例如水性樹脂,可採用微粉狀、膠囊態、液態,將光致變染料與樹脂混合。例如採用水性樹脂與親水性光致變染料混合,以製作上述之浸染溶液。光致變染料與樹脂混合比例可為1:5-1:20,其中可以利用水稀釋,以調整黏度。光致變染料可吸收陽光或紫外線而改變結構,光致變染料經由陽光或紫外線照射後產生可逆化學變化而導致顏色改變。當不受上述陽光或紫外線照射,可恢復原本顏色。光致變染料並可與光安定劑及UV吸收劑等選擇性一起摻雜輔助吸收紫外線。添加抗氧化劑或/及UV吸收劑於可提升抗光疲乏。 In the present invention, a photo-chromic dye is doped into a resin, such as an aqueous resin, which can be in a micropowder, capsule state, or liquid state, and the photo-chromic dye is mixed with the resin. For example, a water-based resin is mixed with a hydrophilic photochromic dye to prepare the above-mentioned impregnation solution. The mixing ratio of photochromic dye and resin can be 1:5-1:20, which can be diluted with water to adjust the viscosity. Photovariable dyes can absorb sunlight or ultraviolet rays to change the structure, and photovariable dyes undergo reversible chemical changes after being irradiated by sunlight or ultraviolet rays to cause color changes. When not exposed to the above sunlight or ultraviolet rays, the original color can be restored. Photovariable dyes can be selectively doped together with light stabilizers and UV absorbers to help absorb ultraviolet rays. Adding antioxidants or/and UV absorbers can improve anti-light fatigue.

因此請參看第三圖,其揭示本發明口罩之截面示意圖,其可包含三層或四層以上,本實施例以三層為例子。外層200為一防紫外線層,其實施方式可參看以上各實施方法。中間層則為過濾層220,用以過濾粉塵、細菌等等,裏層240可以為棉布製作,也可以採用親膚性材質,例如冰絲棉材質或TPE等。利用以上之方法,可以在裏層製作香氛基材,其原理為利用香氛、香 精、精油、香水原料等添加於裏層基材之製作,如此可以得到香氛裏層,提升效果。外層或是中層則可以添加溶菌或除菌酵素,以消除細菌,其方法可以用噴塗、浸染、塗佈或印刷。傳統只能過濾,無法殺死病毒,故本發明除可過濾外,也可以分解細菌、抑制病毒。此外,外層200或是中層220也可添加流感病毒成分或除菌酵素,以消除細菌、抑制病毒,其方法可以用噴塗、浸染、塗佈或印刷。傳統只能過濾細菌,無法殺死細菌,故本發明除可過濾外,也可以分解細菌、抑制病毒。此外,亦可以利用上述噴塗、浸染、塗佈將抗病毒藥劑附著在外層200或是中層220,以抑制流感病毒或腸病毒等等。上述之制流感病毒成分可以採用陽離子有機化合物,陽離子金屬有機金屬化合物(如有機銅化合物、有機鋅化合物有機錫化合物以及一些其他有機金屬化合物)等。為避免洗滌脫落的話,可以於不織布程序中加入熔融態基材內,隨後再利用不織布程序製作不織布,如此便不易流失。基於口罩乃是一次性使用商品,可以採用上述噴塗、浸染、塗佈或印刷方式製作。若是單存採用銅(或銀)離子,則基於捕獲電子形成中性,易於喪失抑制細菌活性,而且奈米銀金屬具有生物毒性。本發明上述陽離子有機金屬化合物可以為有機一無機複合利用具抗病毒有機配體和具抗病毒無機陽離子形成複合鹽類。 Therefore, please refer to the third figure, which shows a schematic cross-sectional view of the mask of the present invention, which may include three or more layers. This embodiment takes three layers as an example. The outer layer 200 is an anti-ultraviolet layer, and its implementation can refer to the above implementation methods. The middle layer is a filter layer 220 for filtering dust, bacteria, etc. The inner layer 240 can be made of cotton cloth, or can be made of skin-friendly materials, such as ice silk cotton or TPE. Using the above method, the fragrance base material can be made in the inner layer. The principle is to use fragrance, fragrance Essences, essential oils, perfume materials, etc. are added to the production of the inner base material, so that the inner layer of fragrance can be obtained and the effect can be improved. The outer layer or the middle layer can be added with bacteriolytic or antibacterial enzymes to eliminate bacteria. The method can be spraying, dip dyeing, coating or printing. Traditionally, it can only filter but cannot kill viruses. Therefore, in addition to filtering, the present invention can also decompose bacteria and inhibit viruses. In addition, the outer layer 200 or the middle layer 220 can also be added with influenza virus components or sterilizing enzymes to eliminate bacteria and inhibit viruses. The method can be spraying, dip-dyeing, coating or printing. Traditionally, bacteria can only be filtered, but bacteria cannot be killed. Therefore, in addition to filtering, the present invention can also decompose bacteria and inhibit viruses. In addition, the above-mentioned spraying, dipping, coating can also be used to attach antiviral agents to the outer layer 200 or the middle layer 220 to inhibit influenza virus or enterovirus, and so on. The above-mentioned influenza virus components can use cationic organic compounds, cationic metal organic metal compounds (such as organic copper compounds, organic zinc compounds, organic tin compounds, and some other organic metal compounds). In order to avoid washing off, you can add the molten base material in the non-woven process, and then use the non-woven process to make the non-woven fabric, so that it is not easy to lose. Based on the fact that masks are disposable products, they can be made by spraying, dipping, coating or printing as described above. If copper (or silver) ions are used for single storage, neutrality is formed based on the trapped electrons, which tends to lose the antibacterial activity, and nanosilver metal is biologically toxic. The cationic organometallic compound of the present invention can be an organic-inorganic compound using an antiviral organic ligand and an antiviral inorganic cation to form a compound salt.

必須注意的是細菌與病毒完全不同,病毒是由一個核酸分子(DNA或RNA)與蛋白質構成的非細胞形態,為類生物,無法自行表現出生命現象,靠寄生生活的介於生命體及非生命體之間的有機物種,它既不是生物亦不是非生物,是由一個保護性外殼包裏的一段DNA或者RNA,藉由感染的機制,這些簡單的有機體可以利用宿主的細胞系統進行自我複製。細菌一般是單細胞,細胞結構簡單,缺乏細胞核以及膜狀胞器,例如粒線體和葉綠體。基於這些特徵,細菌屬於原核生物。細菌的形狀相當多樣,主要有球狀、桿狀,以及螺旋狀。 It must be noted that bacteria are completely different from viruses. Viruses are non-cellular forms composed of a nucleic acid molecule (DNA or RNA) and protein. They are organisms and cannot exhibit life phenomena on their own. An organic species between living organisms. It is neither living nor non-living. It consists of a piece of DNA or RNA in a protective shell. Through the mechanism of infection, these simple organisms can use the host cell system to replicate themselves. . Bacteria are generally single cells with simple cell structure, lacking nuclei and membranous organelles, such as mitochondria and chloroplasts. Based on these characteristics, bacteria belong to prokaryotes. The shape of bacteria is quite diverse, mainly spherical, rod-shaped, and spiral.

過濾層220可以採用超微孔濾淨膜(PTFE生技膜)可以過濾0.1-2.5微米以下之微粒,以抑制PM 2.5危害,可防霾、透氣、好呼吸特性。奈米微孔聚四氟乙烯(PTFE)薄膜,奈米微孔膜孔徑小於一般微孔膜,擁有高度疏水疏油性,所以具有極良好的透濕、透氣和防水防油污性。耐超高水壓和超高水汽 透汽率的PTFE奈米微孔薄膜是由超高結晶態的聚四氟乙烯材料,在超高壓下擠壓成膜並配合極快的拉伸速度,使薄膜具有奈米微孔超高強度三維結構特徵。孔徑可控制在0.03微米(μm)(30奈米(nm))~15微米(μm)之間,厚度為8~50微米(μm),孔隙率高達80~97%。超微孔生技濾淨膜以高分子薄膜濾材取代傳統不織布濾材層,過濾率高達99.9%以上,可將空氣中病毒、過敏原、細懸浮微粒排除,高透氣且不悶。波長100~280奈米(nm)紫外線波長短,所蘊藏能量越強,對皮膚傷害最大的是紫外線C,但大部分被大氣層中臭氧層隔離,幾乎不到達地面。波長280~320奈米,其能量次之,引起皮膚即時曬傷,使皮膚角質增厚、暗沈、變紅、眼膜炎、發痛變得較乾,主要是因UVB所造成。 The filter layer 220 can use an ultra-microporous filter membrane (PTFE biotechnology membrane) that can filter particles below 0.1-2.5 microns to inhibit PM 2.5 hazards, and can prevent haze, air permeability, and good breathing characteristics. Nanoporous polytetrafluoroethylene (PTFE) membrane, the pore diameter of the nanoporous membrane is smaller than that of the general microporous membrane, and it has a high degree of hydrophobic and oleophobicity, so it has very good moisture permeability, air permeability, water and oil resistance. Resistant to ultra-high water pressure and ultra-high water vapor The vapor transmission rate of PTFE nanoporous film is made of ultra-high crystalline polytetrafluoroethylene material, which is extruded under ultra-high pressure to form a film with extremely fast stretching speed, so that the film has ultra-high strength of nanoporous Three-dimensional structural features. The pore size can be controlled between 0.03 microns (μm) (30 nanometers (nm)) and 15 microns (μm), the thickness is 8-50 microns (μm), and the porosity is as high as 80-97%. The ultra-microporous biotechnology filter membrane replaces the traditional non-woven filter layer with a polymer membrane filter material, with a filtration rate of over 99.9%, which can eliminate viruses, allergens, and fine suspended particles in the air, with high air permeability and no stuffiness. Ultraviolet rays with a wavelength of 100~280 nanometers (nm) have shorter wavelengths, and the stronger the energy contained, the most harmful to the skin is ultraviolet C, but most of it is isolated by the ozone layer in the atmosphere and hardly reaches the ground. The wavelength is 280~320nm, and the energy is the second, causing immediate sunburn on the skin, thickening, dullness, reddening, eye inflammation, pain and drying of the skin, mainly caused by UVB.

就本發明製作方法中,首先備置降低病毒活性溶液,例如(1)準備抑制病毒表面蛋白質有機化合物,藉由化學吸附性改變病毒的表面蛋白質,抑制病毒複製;或(2)準備金屬化合物,利用自由基反應產生羥基自由基,提取病毒蛋白質中的氫原子,破壞病毒型態,抑制病毒複製;或(3)利用有機金屬化合物,其包含金屬(包括類金屬)和碳原子鍵結的有機金屬化合物,除傳統金屬元素外,鑭系元素、錒系元素、半金屬、類金屬(如硼、矽、砷、硒)也可以和碳鍵結,形成有機金屬化合物。利用上述物質,可以使病毒表面蛋白質破壞,或破壞核酸,或破壞套膜,而降低病毒活性。舉一例而言,A型流感病毒抑制劑的甲醯胺和異腈類化合物,其包含R基,選自烷基、環烷基、芳香基、雜芳基、氨基酸基及上述基團的取代衍生物。甲醯胺和異腈類化合物是以胺為原料分別通過醯化、脫水等方式製備得到,這些甲醯胺和異腈類化合物及其鹽可用於製備抑制病毒物。另一優選例子是一種基於肽或蛋白質類型化合物,包括一種或多種蛋白質、多肽或者肽、核酸、肽核酸、核酸類似物、核苷、核苷類似物、小的有機分子、聚合物、脂質、留體、脂肪酸、碳水化合物或者以上任意的組合。上述基於肽或蛋白質類型化合物,其為該化合物的主要具有氨基酸構架,其中氨基酸是通過肽鍵連結。一種基於肽或者蛋白質的化合物也可具有附著至該氨基酸構架或骨架的其它化學化合物或基團,包括有助於錨定域的錨定活性的部分。細胞外錨定域或錨定域是指任何能穩定地結合位於或在靶細胞外表面上或者鄰近靶細胞外表面的實體。其次,在另一實施例中,抑制內切酶的高活性金屬化合物團,具有高親和力和結合能力的流感核酸內切酶抑制劑。又如一價銅化合物遇到細菌及病毒時,一價銅 離子與氧氣反應後,產生羥基,銅離子和羥基這兩種物質可減少病毒及細菌的數量水分中分離出一價銅離子,一價銅化合物分離出的一價銅離子與二價銅離子相比,具有更易被氧化的特性,因此可產生羥基。羥基具有抑制微生物繁殖的功效,可發揮抗病毒效果。 In the production method of the present invention, a virus-reducing solution is first prepared, such as (1) preparing an organic compound that inhibits virus surface proteins, and changing the surface protein of the virus by chemisorption to inhibit virus replication; or (2) preparing a metal compound and using Free radical reaction generates hydroxyl free radicals, extracts hydrogen atoms in virus proteins, destroys virus form, and inhibits virus replication; or (3) Use organometallic compounds, which contain metal (including metalloid) and organometal bonded with carbon atoms Compounds, in addition to traditional metal elements, lanthanides, actinides, semi-metals, metalloids (such as boron, silicon, arsenic, selenium) can also bond with carbon to form organometallic compounds. The use of the above substances can destroy the virus surface protein, or destroy the nucleic acid, or destroy the mantle, and reduce the virus activity. For example, the formamide and isonitrile compounds of influenza A virus inhibitors contain R group selected from the group consisting of alkyl, cycloalkyl, aryl, heteroaryl, amino acid and substitutions of the above groups derivative. Formamide and isonitrile compounds are prepared using amines as raw materials through acylation, dehydration, etc., and these formamide and isonitrile compounds and their salts can be used to prepare virus-inhibiting substances. Another preferred example is a peptide or protein-based compound, including one or more proteins, polypeptides or peptides, nucleic acids, peptide nucleic acids, nucleic acid analogs, nucleosides, nucleoside analogs, small organic molecules, polymers, lipids, Steroids, fatty acids, carbohydrates or any combination of the above. The above-mentioned peptide or protein-based compound mainly has an amino acid framework in which the amino acids are linked by peptide bonds. A peptide or protein-based compound may also have other chemical compounds or groups attached to the amino acid framework or backbone, including moieties that contribute to the anchoring activity of the anchoring domain. An extracellular anchoring domain or anchoring domain refers to any entity that can stably bind to an entity located on or on the outer surface of a target cell or adjacent to the outer surface of a target cell. Secondly, in another embodiment, an influenza endonuclease inhibitor with high affinity and binding ability to inhibit the highly active metal compound group of the endonuclease. Another example is when monovalent copper compounds encounter bacteria and viruses, monovalent copper After the ions react with oxygen, hydroxyl groups are produced. These two substances, copper ions and hydroxyl groups, can reduce the number of viruses and bacteria. The monovalent copper ions are separated from the water, and the monovalent copper ions separated from the monovalent copper compounds are phased with the divalent copper ions. Compared with, has the characteristic of being more susceptible to oxidation, so it can produce hydroxyl. Hydroxyl has the effect of inhibiting the reproduction of microorganisms and can exert an antiviral effect.

本發明之陽離子金屬有機化合物係為金屬陽離子與有機材料二者的化合物,亦即二者係經過化合作用或程序而產生陽離子金屬有機化合物,其屬於有機-無機化合抑制病毒劑(材料)。例如,合成酰基吡唑啉酮與Ni +Cu 2+Co 2+Zn 2+的化合物,對大腸桿菌和金黃色葡萄球菌都有一定的抑制作用,化合物的抑菌活性比金屬離子高,說明化合物形成後,過渡金屬離子對配體的抑菌活性起到了增強的效應。又如,合成四縮氨基硫脲和2個縮氨基硫脲與Ni +Cu 2+Zn 2+穩定的螯合物,其抑菌能力遠比配體和單獨之金屬離子都好。因此,本發明之有機-無機化合物兼有個別單獨有機、無機抑制病毒的優點,具有有機抗菌劑的高效性、持續性及無機抗菌劑的安全性、耐熱性,所得產品不僅抗菌效果好,不受紫外線的干擾。有機金屬化合物中,金屬和碳的鍵結性質一般會介於離子鍵和共價鍵之間。當金屬的電負度很低(例如鹼金屬元素)或是含碳的配基為穩定的碳負離子時,其鍵結會類似離子鍵。碳負離子可以因為共振或者是因為有吸電子取代基(例如三苯甲基負離子)而穩定。在另一實施例中,本發明外層或內層包含一種鹼金屬或鹼土金屬的結晶型矽鋁酸鹽,它的結構具有很強陽離子交換能力;金屬-矽酸鹽類例如銀或銀和鋅-矽酸鹽類,與生物具有良好親和性。優點尚包含:高安全性、耐久性、有廣譜抗菌性(改變金屬離子的種類,可殺不同菌種)、不易產生抗藥性。填充形式將上述成分與合成纖維混合製作成纖維。由於被混入纖維內部,因而耐洗滌性好,效果時間長。後加工形式在纖維後加工過程中,將上述成分通過化合鍵或氫鍵結合在纖維表面,與病毒接觸面積較大(相同劑量下)。其可於不同需求而採用不同製程。 The cationic metal organic compound of the present invention is a compound of both metal cations and organic materials, that is, the two are chemically combined or processed to produce cationic metal organic compounds, which belong to organic-inorganic compound antiviral agents (materials). For example, synthetic compounds of acylpyrazolone and Ni + , Cu 2+ , Co 2+ or Zn 2+ have a certain inhibitory effect on Escherichia coli and Staphylococcus aureus, and their antibacterial activity is higher than that of metal ions. This indicates that after the formation of the compound, the transition metal ions have an enhanced effect on the antibacterial activity of the ligand. Another example is the synthesis of tetrathiosemicarbazone and two thiosemicarbazone stable chelate with Ni + , Cu 2+ or Zn 2+ , and its antibacterial ability is far better than that of ligands and metal ions alone. Therefore, the organic-inorganic compound of the present invention has the advantages of individual organic and inorganic virus-inhibiting, and has the high efficiency and sustainability of organic antibacterial agents, and the safety and heat resistance of inorganic antibacterial agents. Interfered by ultraviolet rays. In organometallic compounds, the bonding properties of metal and carbon are generally between ionic bonds and covalent bonds. When the electronegativity of the metal is very low (for example, an alkali metal element) or the carbon-containing ligand is a stable carbanion, the bond will be similar to an ionic bond. Carbanions can be stabilized due to resonance or electron-withdrawing substituents (such as trityl anions). In another embodiment, the outer layer or inner layer of the present invention contains an alkali metal or alkaline earth metal crystalline aluminosilicate, which has a strong cation exchange capacity; metal-silicates such as silver or silver and zinc -Silicates have good affinity with organisms. The advantages also include: high safety, durability, broad-spectrum antibacterial properties (change the type of metal ions, can kill different bacteria), and it is not easy to develop resistance. In the filling form, the above-mentioned components are mixed with synthetic fibers to produce fibers. Because it is mixed into the fiber, it has good washing resistance and long effect time. Post-processing form During the post-processing of the fiber, the above-mentioned components are bonded to the surface of the fiber through chemical bonds or hydrogen bonds, and the contact area with the virus is larger (at the same dose). It can use different processes for different needs.

第四圖與第五圖為本發明口罩透過SGS檢測,通過ISO 18184標準,證明本發明抗病毒效果良好。請參考第四圖,其中載明抗病毒活性良好的標準值為3,而本發明之抗H3N2病毒活性為3.4,遠高於標準值。請參考第五圖,其中載明抗病毒活性良好的標準值為3,而本發明之抗H1N1病毒活性為3.4以 上,遠高於標準值。本發明不僅抑制病菌,且可以消滅病毒,因此,產生質的變化,而有新的功效。由第四圖與第五圖證明本發明抗病毒效果良好(抗H3N2病毒活性為3.4,抗H1N1病毒活性為3.4以上,遠高於標準值),因此,本案具有量的變化,而有功效顯著的提升,具有不可預期的效果。 The fourth and fifth figures show that the mask of the present invention has passed the SGS test and passed the ISO 18184 standard, proving that the present invention has a good anti-virus effect. Please refer to the fourth figure, which states that the standard value of good antiviral activity is 3, and the anti-H 3 N 2 virus activity of the present invention is 3.4, which is much higher than the standard value. Please refer to the fifth figure, which states that the standard value of good antiviral activity is 3, and the anti-H 1 N 1 virus activity of the present invention is above 3.4, which is much higher than the standard value. The invention not only inhibits germs, but also can destroy viruses, so it produces qualitative changes and has new effects. The fourth and fifth diagrams prove that the present invention has a good antiviral effect (anti-H 3 N 2 virus activity is 3.4, anti-H 1 N 1 virus activity is above 3.4, which is much higher than the standard value). Therefore, this case has substantial Changes and significant improvements in efficacy have unexpected effects.

本發明之口罩製造方法採用裡層、外層同質性材質,並且外層單位重量大於或等於內層單位重量,以利使其低於5mmH2O/cm2壓差。其中至少一層(亦可以兩層)塗佈上述抑制病毒活性物,為利於達成此目的,須採用親水性表面(或以親水性表面改質),親水性透過氫鍵和水分子形成鍵結,以附著表面蛋白破壞有機化合物,改變病毒表面蛋白質、產生羥基金屬化合物,或以上兩者。且親水性表面可使細菌、病毒或其他微生物沾黏,提升抑制病毒活性物與病毒、細菌接觸機會,進而抑制病毒與細菌,而傳統表層皆採用撥水性材質,故無法達成此目的,傳統口罩皆為本案之相反教示。此外親水性表面改質,可以利用植酸分子與三價鐵離子的螯合作用,在表面產生交聯複合物,其中有大量親水性的膦酸基團,使表面極端親水。植酸是從植物種籽中提取的一種有機磷酸類化合物,毒性比食鹽更低,其與鐵離子的反應在水中進行、不涉及任何有機溶劑,完全無毒、綠色、環保;不需要複雜儀器設備,整個反應只需幾分鐘即可完成,簡單迅速,表面親水性的調控對於材料在親膚、仿生、潤滑等有所提升。 The mask manufacturing method of the present invention adopts homogeneous materials of the inner layer and the outer layer, and the unit weight of the outer layer is greater than or equal to the unit weight of the inner layer, so that the pressure difference is lower than 5 mmH 2 O/cm 2 . At least one layer (or two layers) is coated with the above-mentioned virus-inhibiting active substance. In order to achieve this goal, a hydrophilic surface (or modified with a hydrophilic surface) must be used. The hydrophilicity forms a bond through hydrogen bonds and water molecules. Destroy organic compounds by attaching surface proteins, change virus surface proteins, produce hydroxyl metal compounds, or both. In addition, the hydrophilic surface can stick bacteria, viruses or other microorganisms, and increase the chance of inhibiting the contact of virus active substances with viruses and bacteria, thereby inhibiting viruses and bacteria. The traditional surface layer is made of water-repellent materials, so this goal cannot be achieved. Traditional masks All are the opposite teachings of this case. In addition, hydrophilic surface modification can use the chelating effect of phytic acid molecules and ferric ions to produce cross-linked complexes on the surface, which has a large number of hydrophilic phosphonic acid groups, making the surface extremely hydrophilic. Phytic acid is an organic phosphoric acid compound extracted from plant seeds. Its toxicity is lower than that of table salt. Its reaction with iron ions is carried out in water and does not involve any organic solvents. It is completely non-toxic, green and environmentally friendly; no complicated equipment is required. The entire reaction can be completed in just a few minutes. It is simple and rapid. The adjustment of surface hydrophilicity has improved the skin-friendly, bionic, lubricating and other aspects of the material.

一種口罩製造方法,包含備置抑制病毒活性物,選自以下之一或任意組合:表面蛋白破壞有機化合物、產生羥基金屬化合物;將抑制病毒活性物塗佈於口罩之至少裏層、外層或兩者;其中裏層、外層為同質性材質,以利吸附抑制病毒活性物,其中抑制病毒活性物可改變或破壞病毒蛋白質,使抑制病毒活性值大於3,其中較佳為抑制病毒活性值為3.4,抑制病活性毒物可包含有機一無機複合鹽類、陽離子金屬有機化合物或兩者之組合,其中更包含混和該抑制病毒活性物與溶劑,其中該裏層、外層為親水性材質,該外層單位重量大於或等於裏層單位重量,口罩壓差低於5mmH2O/cm2A method for manufacturing a mask includes preparing a virus-inhibiting active substance selected from one or any combination of the following: surface protein destroys organic compounds and producing hydroxy metal compounds; coating the virus-inhibiting active substance on at least the inner layer, outer layer or both of the mask ; Wherein the inner layer and the outer layer are homogeneous materials to facilitate the adsorption and inhibition of virus active substances, wherein the virus-inhibiting active substances can change or destroy the virus protein, so that the virus-inhibiting activity value is greater than 3, and the virus-inhibiting activity value is preferably 3.4, The disease-inhibiting active poison can include organic-inorganic composite salts, cationic metal-organic compounds or a combination of the two, which further includes mixing the virus-inhibiting active substance and a solvent, wherein the inner layer and the outer layer are made of hydrophilic materials, and the outer layer has a unit weight It is greater than or equal to the unit weight of the inner layer, and the pressure difference of the mask is less than 5mmH 2 O/cm 2 .

一種口罩製造方法,包含備置抑制病毒活性物,包含有機一無機複合鹽類或陽離子金屬有機化合物;將該抑制病毒活性物,塗佈於口罩之至少裏層、外層或兩者;及其中該裏層、外層為同質性材質,以利吸附該抑制病毒活性 物,該抑制病毒活性物抑制病毒複製,其中抑制病毒活性值大於3,較佳為抑制病毒活性值為3.4。裏層、外層為親水性材質,外層單位重量大於或等於裏層單位重量,俾使口罩壓差低於5mm H2O/cm2A method for manufacturing a mask includes preparing a virus-inhibiting active substance, including organic-inorganic composite salts or cationic metal-organic compounds; coating the virus-inhibiting active substance on at least the inner layer, the outer layer or both of the mask; and the inner layer The layer and the outer layer are made of homogeneous materials to facilitate the adsorption of the virus-inhibiting active substance, which inhibits virus replication, wherein the virus-inhibiting activity value is greater than 3, preferably the virus-inhibiting activity value is 3.4. The inner and outer layers are made of hydrophilic materials, and the unit weight of the outer layer is greater than or equal to the unit weight of the inner layer, so that the pressure difference of the mask is lower than 5mm H 2 O/cm 2 .

在另一實施例中,為使得本案可以承受至少80mmHg液態壓力(例如流體噴濺),本發明可在抑制病毒活性層的內側或外側,配置疏水層,但不織布孔徑必須可使氣體通過,因此可以採用聚四氟乙烯(PTFE)或是聚丙烯(PP),若是採用聚氟乙烯(PTFE)可能可省卻過濾層,而達到過濾0.3微米之效果。一種口罩,包含:抑制病毒活性層,選自以下之一或任意組合:表面蛋白破壞有機化合物、產生羥基金屬化合物;疏水層,配置於該抑制病毒活性層之內側或外側;及過濾層,配置於該抑制病毒活性層之內側;親膚層,配置於該過濾層層之內側,其中該抑制病毒活性層可改變或破壞病毒蛋白質,其中抑制病毒活性值大於3。一實施例中,奈米微孔聚四氟乙烯(PTFE)之奈米微孔之孔徑小於一般微孔,擁有高度疏水疏油性,所以具有極良好的透濕、透氣和防水防油污性。一種口罩,包含:抑制病毒活性層,選自以下之一或任意組合:表面蛋白破壞有機化合物、產生羥基金屬化合物;聚四氟乙烯(PTFE)層,配置於該抑制病毒活性層之內側,可作為過濾層及疏水層;及親膚層,配置於該聚氟乙烯層內側,其中該抑制病毒活性層可改變或破壞病毒蛋白質,其中抑制病毒活性值大於3。 In another embodiment, in order to make the case can withstand at least 80mmHg liquid pressure (such as fluid splashing), the present invention can be provided with a hydrophobic layer on the inner or outer side of the virus-inhibiting active layer, but the aperture of the non-woven fabric must allow gas to pass through. Either polytetrafluoroethylene (PTFE) or polypropylene (PP) can be used. If polyfluoroethylene (PTFE) is used, the filter layer may be omitted and the effect of filtering 0.3 microns can be achieved. A mask, comprising: a virus-inhibiting active layer, selected from one or any combination of the following: surface proteins destroy organic compounds and produce hydroxy metal compounds; a hydrophobic layer arranged on the inside or outside of the virus-inhibiting active layer; and a filter layer, configured On the inner side of the virus-inhibiting active layer; the skin-friendly layer is arranged on the inner side of the filter layer, wherein the virus-inhibiting active layer can change or destroy viral proteins, and the virus-inhibiting activity value is greater than 3. In one embodiment, the pore diameter of the nanopores of nanoporous polytetrafluoroethylene (PTFE) is smaller than that of ordinary micropores, and has a high degree of hydrophobic and oleophobicity, so it has excellent moisture permeability, air permeability, water and oil resistance. A mask, comprising: a virus-inhibiting active layer, selected from one or any combination of the following: surface proteins destroy organic compounds and produce hydroxyl metal compounds; a polytetrafluoroethylene (PTFE) layer, which is arranged inside the virus-inhibiting active layer, can As the filter layer and the hydrophobic layer; and the skin-friendly layer, they are arranged inside the polyvinyl fluoride layer, wherein the virus-inhibiting active layer can change or destroy virus proteins, and the virus-inhibiting activity value is greater than 3.

對熟悉此領域技藝者,本創作雖以較佳實例闡明如上,然其並非用以限定本創作精神。在不脫離本創作之精神與範圍內所作之修改與類似的配置,均應包含在下述之申請專利範圍內,此範圍應覆蓋所有類似修改與類似結構,且應做最寬廣的詮釋。 For those who are familiar with the art in this field, although this creation is illustrated above with a better example, it is not intended to limit the spirit of this creation. Modifications and similar configurations made without departing from the spirit and scope of this creation should be included in the scope of the following patent application, which should cover all similar modifications and similar structures, and should be interpreted in the broadest sense.

102:轉軸 102: shaft

104:浸染槽 104: dip tank

106:轉軸至轉軸式裝置 106: shaft to shaft device

108:加熱器 108: heater

110:基材 110: Substrate

Claims (10)

一種口罩,包含:抑制病毒活性層,選自以下之一或任意組合:表面蛋白破壞有機化合物、產生羥基金屬化合物;聚四氟乙烯(PTFE)層,配置於該抑制病毒活性層之內側,可作為過濾層及疏水層;及親膚層,配置於該聚氟乙烯層內側,其中該抑制病毒活性層可改變或破壞病毒蛋白質,其中抑制病毒活性值大於3。 A mask, comprising: a virus-inhibiting active layer, selected from one or any combination of the following: surface proteins destroy organic compounds and produce hydroxyl metal compounds; a polytetrafluoroethylene (PTFE) layer, which is arranged inside the virus-inhibiting active layer, can As the filter layer and the hydrophobic layer; and the skin-friendly layer, they are arranged inside the polyvinyl fluoride layer, wherein the virus-inhibiting active layer can change or destroy virus proteins, and the virus-inhibiting activity value is greater than 3. 如申請專利範圍第1項所述之口罩,其中該抑制病活性毒物包含有機一無機複合鹽類、陽離子金屬有機化合物或兩者之組合。 The mask described in item 1 of the scope of patent application, wherein the disease-inhibiting active poison comprises organic-inorganic composite salts, cationic metal organic compounds or a combination of the two. 如申請專利範圍第1項所述之口罩,其中抑制病毒活性值為3.4。 The mask described in item 1 of the scope of patent application has a virus-inhibiting activity value of 3.4. 如申請專利範圍第1項所述之口罩,其中該口罩之壓差低於5mmH2O/cm2For the mask described in item 1 of the scope of patent application, the pressure difference of the mask is lower than 5mmH 2 O/cm 2 . 如申請專利範圍第1項所述之口罩,其中該口罩承受至少80mmHg液壓。 The mask described in item 1 of the scope of patent application, wherein the mask bears at least 80mmHg hydraulic pressure. 一種口罩,包含:抑制病毒活性層,選自以下之一或任意組合:表面蛋白破壞有機化合物、產生羥基金屬化合物;疏水層,配置於該抑制病毒活性層之內側或外側;及過濾層,配置於該抑制病毒活性層之內側;親膚層,配置於該過濾層層之內側,其中該抑制病毒活性層可改變或破壞病 毒蛋白質,其中抑制病毒活性值大於3。 A mask, comprising: a virus-inhibiting active layer, selected from one or any combination of the following: surface proteins destroy organic compounds and produce hydroxy metal compounds; a hydrophobic layer arranged on the inside or outside of the virus-inhibiting active layer; and a filter layer, configured On the inner side of the virus-inhibiting active layer; the skin-friendly layer is arranged on the inner side of the filter layer, wherein the virus-inhibiting active layer can change or destroy the disease Toxic protein, in which the value of antivirus activity is greater than 3. 如申請專利範圍第7項所述之口罩,其中該抑制病活性毒物包含有機一無機複合鹽類、陽離子金屬有機化合物或兩者之組合。 The mask described in item 7 of the scope of patent application, wherein the disease-inhibiting active poison comprises organic-inorganic composite salts, cationic metal organic compounds or a combination of both. 如申請專利範圍第7項所述之口罩,其中抑制病毒活性值為3.4。 For the mask described in item 7 of the scope of patent application, the virus-inhibiting activity value is 3.4. 如申請專利範圍第7項所述之口罩,其中該口罩之壓差低於5mmH2O/cm2For the mask described in item 7 of the scope of patent application, the pressure difference of the mask is lower than 5mmH 2 O/cm 2 . 如申請專利範圍第7項所述之口罩,其中該口罩承受至少80mmHg液壓。 Such as the mask described in item 7 of the scope of patent application, wherein the mask bears at least 80mmHg hydraulic pressure.
TW109103785A 2020-02-07 2020-02-07 Facial mask and the method of forming the same TWI705837B (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104397901A (en) * 2014-12-12 2015-03-11 青岛联丰纺织科技有限公司 Low pressure plasma nanometer waterproof mask and treatment process thereof
CN106102863A (en) * 2014-12-23 2016-11-09 盈宗制药有限公司 With the protective mask of coating, the formula constituting described coating and the method making described protective mask that are interweaved by different electrospinning fibres

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104397901A (en) * 2014-12-12 2015-03-11 青岛联丰纺织科技有限公司 Low pressure plasma nanometer waterproof mask and treatment process thereof
CN106102863A (en) * 2014-12-23 2016-11-09 盈宗制药有限公司 With the protective mask of coating, the formula constituting described coating and the method making described protective mask that are interweaved by different electrospinning fibres

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