WO2016098952A1 - Multipurpose functional sanitary cotton and method for preparing same - Google Patents

Multipurpose functional sanitary cotton and method for preparing same Download PDF

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Publication number
WO2016098952A1
WO2016098952A1 PCT/KR2015/002310 KR2015002310W WO2016098952A1 WO 2016098952 A1 WO2016098952 A1 WO 2016098952A1 KR 2015002310 W KR2015002310 W KR 2015002310W WO 2016098952 A1 WO2016098952 A1 WO 2016098952A1
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cotton
functional
composition
nano
weight
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PCT/KR2015/002310
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French (fr)
Korean (ko)
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윤갑호
박영미
서광희
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윤갑호
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Priority to CN201580068631.XA priority Critical patent/CN107208358A/en
Publication of WO2016098952A1 publication Critical patent/WO2016098952A1/en

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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • D06M11/42—Oxides or hydroxides of copper, silver or gold
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/80—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides
    • D06M11/81—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides with boron; with boron halides; with fluoroborates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01—Natural vegetable fibres
    • D10B2201/02—Cotton
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2503/00—Domestic or personal
    • D10B2503/02—Curtains
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2503/00—Domestic or personal
    • D10B2503/04—Floor or wall coverings; Carpets
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2509/00—Medical; Hygiene

Definitions

  • the present invention relates to a multipurpose functional sanitary cotton and a method for producing the sanitary cotton.
  • the conventional hygiene cotton is hygroscopic, there is a problem that easy to breed mold and bacteria, odors, mites, it was difficult to be used in a variety of industrial fields only recognized as used as bedding or clothing.
  • a multi-functional functional cotton and a manufacturing method thereof and a pre-applied invention patent Application No. 10-2013-0141631 of the pre-registered invention patent (registration number 10-1079871)
  • the multi-functional functional mixed cotton and its manufacturing method of mixed fibers of natural cotton (cotton) cotton and hemp fibers cotton is easily broken in impact, so that dust and dust generated during work, natural cotton to compensate for the poor workability
  • the method of infiltrating the composition for preparing a multifunctional functional cotton into the hollow of cotton is disclosed to strengthen tensile strength and bursting strength, and strengthening the cotton to prevent it from breaking down by using an acrylic phosphate-based cuffing agent, and a composition liquid by an anionic surfactant.
  • a method of penetrating and giving flexibility is disclosed.
  • the flame retardant (flame-retardant) of the multi-use functional sanitary cotton is improved to prevent dust from shorting the cotton strands or to break the dust and to generate dust. Because of the softening, the cotton was smoothed, which greatly increased workability and productivity. It does not generate static electricity, and does not damage the cotton wool even after washing, and it is very eco-friendly.
  • the cotton is soft, excellent in touch and warmth, and resilience, and the multifunctional functional hygiene cotton is inserted into the bedding as a core material, and the cotton is broken even when sewing, so there is no fine dust or dust.
  • Complementary improvements can be cited.
  • NANO SILVER mites silver
  • NANO TIO 2 nano-titanium dioxide
  • the multi-functional functional sanitary cotton according to the present invention is a natural cotton (cotton) cotton, mixed miscellaneous cotton, rice straw straw, straw straw, waste paper cotton, natural cotton wool, coconut fiber cotton, silk cotton, silk cotton, bamboo fiber harmless to the human body Cotton, banana fiber cotton, waste cotton regenerated cotton, synthetic fiber cotton, pulp cotton, carbonized carbon fiber cotton, tencel cotton, viscose rayon cotton, cuprammonium rayon cotton, low melting point thermoplastic resin fiber cotton, Natural cotton, mixed cotton, etc.
  • flame retardant flame retardant
  • the strength of the cotton strands are increased, and the oxidation of the cotton is prevented.
  • It can have moisture proof and insect repellent, antibacterial, bactericidal, and sterile.
  • the production cost is low, it can have environmentally friendly features, and the used waste materials or waste materials generated during the production can be recycled and used as raw materials.
  • the multi-functional functional sanitary cotton according to the present invention is thread, rope, processed fabric, non-woven fabric, mat, blast mat, board, panel core material, pipe cover, filter, fire cloth, flame-proof wallpaper, fire curtain, flame retardant carpet, natural cotton, mixed Job cotton, rice straw, straw cotton, waste paper, natural cotton, coconut fiber cotton, silk cotton, silk cotton, bamboo fiber cotton, banana fiber cotton, cotton wool recycling cotton, synthetic fiber cotton, pulp cotton, carbonized cotton, carbon fiber cotton, tencel cotton It can be applied to various industrial fields such as viscose rayon cotton, cupra ammonium rayon cotton, low melting point thermoplastic resin fiber cotton, and carpox cotton. It is expected.
  • the multi-functional functional hygiene cotton according to the present invention can be productized into a thread or processed fabric, and also penetrates the functional composition of the multi-functional functional hygiene cotton to the existing products such as cotton fabrics, cotton blend fabrics, to produce hygienic products as well as flame retardant (flame-retardant) Include more that you can do.
  • flame retardant flame-retardant
  • the present invention provides urea (OLEA), oleic acid (OLEIC ACID), diethylenetriamine (DETA), water, ammonium polyphosphate (APP), boron (B 2 O 3 ), water dispersible polyurethane (PUD), penetrant (anion) Sex), silver nano (NANO SILVER), nano titanium dioxide (NANO TIO 2 ) comprising a composition for producing a multi-functional functional sanitary cotton.
  • the element (UREA) is characterized in that it comprises 5.1 to 5.35% by weight.
  • the oleic acid is characterized in that it comprises 0.11 to 0.18% by weight.
  • the diethylenetriamine is characterized in that 0.13 to 0.18% by weight.
  • the polyammonium phosphate (APP) is characterized in that it comprises 12.1 to 12.20% by weight.
  • the boron (B 2 O 3 ) is characterized in that it comprises 1.62 to 1.70% by weight.
  • the water dispersible polyurethane is characterized in that it comprises 0.25 to 0.32% by weight.
  • the penetrant (Alkyl Succinate anionic) is characterized in that it comprises 0.11 to 0.18% by weight.
  • the silver nano is characterized in that it comprises 2.30 to 2.48% by weight.
  • the silver nano (NANO SILVER) solution is PH 6 to 8, 5 ⁇ 10nm size is characterized in that the desorption is difficult to enter into the cotton in the needle structure, it is not discolored.
  • the nano titanium dioxide (NANO TIO 2 ) is characterized in that it comprises 1.5 to 1.60% by weight.
  • the surface of the nano titanium dioxide (NANO TIO 2 ) is characterized in that it is used by coating silver (Silver).
  • the present invention provides a method for producing a composition for producing a multi-functional functional sanitary cotton comprising the following steps:
  • step b) preparing a composition by adding a water dispersible polyurethane, a penetrant, silver nano, and nano titanium dioxide to the solution of step b);
  • the solution of step a) is characterized in that the heating by stirring for 2 to 3 minutes at a temperature of 70 to 120.
  • the method further comprises cooling for 30 minutes to 1 hour.
  • the present invention provides a multi-functional functional sanitary cotton prepared using the composition.
  • the multi-functional functional sanitary cotton is thread, rope, processed fabric, non-woven fabric, mat, blast mat, board, panel core material, pipe cover, filter, fire fabric, flame resistant wallpaper, fire curtains and flame retardant carpet It is used for the production of a material selected from the group consisting of.
  • the multi-functional functional sanitary cotton is flame retardant material, flame retardant material, thermal insulation material, cold insulation material, heat insulation material, sound absorption material, sound insulation material, shock absorbing material, interlayer sound insulation material, heating floor material, vacuum insulation It is characterized in that it is used in the production of materials selected from the group consisting of materials, interior materials, safety, sanitary materials, blast-proof carbon materials, ceiling materials, finishing materials, clothing materials, and bedding materials.
  • the present invention can provide a method for producing a multipurpose functional sanitary cotton comprising the following steps:
  • the water pressure spray of step (a) is characterized in that it is carried out for 10 to 30 seconds.
  • the dehydration of the step (b) is characterized in that the dehydration so that the moisture content of cotton wool is 70 to 80% using a mangle (Mangle) dehydrator.
  • step (b) the drying of step (b) is characterized in that the cotton wool is dried to a water content of 13% to 15% using a hot air dryer.
  • the present invention is a mixed cotton including the sanitary cotton
  • the mixed cotton is natural cotton, mixed mixed cotton, rice straw straw, straw cotton, waste paper, natural cotton, coconut fiber cotton, silk cotton, silk cotton, Selected from the group consisting of bamboo fiber cotton, banana fiber cotton, waste cotton regenerated cotton, synthetic fiber cotton, pulp cotton, carbonized carbon fiber cotton, tencel cotton, viscose ray cotton, cuprammonium rayon cotton, low melting point thermoplastic resin fiber cotton It is characterized by mixing at least one cotton with a weight ratio of 1: 9 to 4: 6.
  • the present invention may provide a functional sanitary fabric prepared by penetrating and immersing the composition into cotton fabric, cotton blend fabric, or cotton fabric.
  • the functional cotton When the functional cotton is manufactured by applying the flame retardant (flame-retardant) agent of the multi-purpose functional hygienic cotton improved by the present invention, the cotton strands are short-circuited, the dust does not occur, even in a strong impact does not occur dust and also does not occur dust There is this.
  • flame retardant flame-retardant
  • the cotton becomes smooth and has the effect of significantly increasing workability and productivity, and there is no static electricity. Eco-friendly effect can be obtained in that it can be used.
  • the cotton produced by the method of the present invention is excellent in all softness, touch feeling, warmth, and restoring power, so that the multi-functional functional hygiene cotton wool into the bedding, and even if the sewing work, the cotton is broken, fine dust, dust generation There is no advantage in that the working environment is comfortable and productivity is improved.
  • NANO TIO 2 nano titanium dioxide
  • silver nano (NANO SILVER) material and other flame retardant (flame-retardant) powders attached to the cotton become fine powder, dust, powder Even when a small amount is generated, the cotton flies in the fiber state (FIBER), so even if it is inhaled by the human skin or respiratory opening, the cotton is not a nanoparticle but a fiber field, so it is caught on the nose hair or bronchial side, and there is no health hazard.
  • silver nano (NANO SILVER) or nano titanium dioxide (NANO TIO 2 ) is a needle-like crystal structure is not easily detached by being embedded in the cotton, and if it is detached, it is broken with the down and does not have any problem.
  • Figure 2 is a view showing before and after the hollow (Lumen) of the cotton immersed in a natural cotton (cotton) cotton with a composition of the functional hygiene cotton according to the present invention.
  • 3 is a test report showing the results of testing the antimicrobial degree of the comparative example.
  • Figure 4 is a test report showing the results of testing the antimicrobial degree of the multi-functional functional sanitary cotton according to the present invention.
  • FIG. 5 is a test report showing the results of testing the flame resistance of the multi-functional functional sanitary cotton according to the present invention.
  • FIG. 6 is a photograph of a 30-second direct weaving experiment using a torch lamp with a natural hemp mixed cotton ball and a carbon mixed cotton ball mixed with a versatile functional hygiene cotton and a hygienic cotton material according to the present invention.
  • Figure 7 is a photograph of a nonwoven fabric made of a multi-functional functional sanitary cotton material according to the present invention by a torch lamp.
  • FIG. 9 is a test report showing the results of testing the tensile strength, bursting strength of the multi-functional functional sanitary cotton according to the present invention.
  • 11 is a test report showing the results of testing the cold resistance of the multi-functional functional sanitary cotton according to the present invention.
  • Figure 13 is a bedding picture made of the material of the multi-functional functional sanitary cotton in accordance with the present invention.
  • the present invention relates to a multi-functional functional sanitary cotton, specifically, a complementary and improved invention of the applicant's prior art (Registration No. 10-1079871) "Multi-functional functional cotton and its manufacturing method".
  • Natural cotton (cotton) cotton is a versatile functional cotton of the prior art is characterized in that it does not cause harmful components and environmental pollution, while excellent in thermal insulation, heat insulation, ultra-low temperature, sound absorption.
  • the multi-functional functional cotton and manufacturing method of the present invention is for complementary improvement of the multi-functional functional mixed cotton developed in the prior art, and added functionality, improve flame retardant (flame-retardant) properties to provide a more hygienic and comfortable multi-purpose functional hygiene cotton can do.
  • the multi-use functional cotton of the registered patent is 0.1 to 0.3% by weight of anionic surfactant in a solution of stirring for 2 to 3 minutes in a temperature range of 50 to 70 by adding 20 to 25% by weight of ammonium phosphate to 100% by weight of ammonia aqueous solution, 1.5 ⁇ 3.2% by weight of fluorine-based water repellent 0.5-2.5% by weight of di-acrylic-based capping agent, and stirred for 10-30 minutes to obtain a composition (flame retardant, flame retardant) for producing a versatile functional cotton, and the composition is placed on a cotton (cotton) cotton Immerse and impregnate.
  • anionic surfactant in a solution of stirring for 2 to 3 minutes in a temperature range of 50 to 70 by adding 20 to 25% by weight of ammonium phosphate to 100% by weight of ammonia aqueous solution, 1.5 ⁇ 3.2% by weight of fluorine-based water repellent 0.5-2.5% by weight of di-acrylic-based capping agent, and stirred for 10-30 minutes
  • the weight ratio of natural cotton (cotton) cotton and composition (flame retardant, flame retardant) is 5: 1 to 5: 3, impregnated for 1 to 2 minutes, dehydrated at a water content of 70 to 80%, and less than 15% by weight with a high frequency dryer. It is a versatile functional cotton that is dried and then burned.
  • the present invention is a composition (flame retardant, flame retardant) supplemented with the composition, urea (UREA), oleic acid (OLEIC ACID), diethylenetriamine (DETA), water, ammonium polyphosphate (APP), boron (B 2 O 3 ), water dispersible polyurethane (PUD), penetrant (anionic), silver nano (NANO SILVER), nano titanium dioxide (NANO TIO 2 ) to provide a composition for producing a multi-functional functional sanitary cotton .
  • the composition is 5.1 to 5.35% by weight of urea, 0.11 to 0.18% by weight of oleic acid, 0.13 to 0.18% by weight of diethylenetriamine, 12.1 to 12.20% by weight of ammonium polyphosphate (APP), boron ( B 2 O 3 ) 1.62 to 1.70% by weight, water dispersible polyurethane (PUD) 0.25 to 0.32% by weight, penetrant (Alkyl Succinate anionic) 0.11 to 0.18% by weight, silver nano 2.30 to 2.48% by weight, nano titanium dioxide (NANO TIO 2 ) may comprise 1.5 to 1.60% by weight, and the remainder of water.
  • APP ammonium polyphosphate
  • POD water dispersible polyurethane
  • PID water dispersible polyurethane
  • penetrant Alkyl Succinate anionic
  • the silver nano (NANO SILVER) solution is pH 6 to 8, 5 to 10nm size is characterized in that the desorption is difficult to enter into the cotton in the needle structure, it is not discolored.
  • the present invention can provide a method for producing a composition for producing a multi-functional functional hygiene cotton comprising the following steps:
  • step b) preparing a composition by adding a water dispersible polyurethane, a penetrant, silver nano, and nano titanium dioxide to the solution of step b);
  • the method of preparing the composition of the present invention adds 5.1 to 5.35% by weight of urea, 0.11 to 0.18% by weight of oleic acid, 0.13 to 0.18% by weight of diethylenetriamine, and 72.5 to 77.15% by weight of water, and at 70 to 120 Stirring and stirring for 2 to 3 minutes.
  • ammonium polyphosphate (APP) was dissolved by adding 12.1 to 12.20 wt% and boron 1.62 to 1.70 wt%.
  • water dispersible polyurethane (PUD) 0.25 to 0.32% by weight, penetrant 0.11 to 0.18% by weight, 2.30 to 2.48% by weight of NANO SILVER solution, nano titanium dioxide (NANO TIO 2 ) by adding 1.5 to 1.60% by weight
  • the solution was dissolved by stirring for 10 to 30 minutes.
  • the present invention can provide a versatile functional sanitary cotton prepared using the composition.
  • the multi-functional functional sanitary cotton is thread, rope, processed fabric, non-woven fabric, mat, blast mat, board, panel core material, pipe cover, filter, fire fabric, flame-resistant wallpaper, fire curtain or flame-resistant carpet Can be used as a material.
  • the multi-functional functional sanitary cotton is flame retardant material, flame retardant material, thermal insulation material, cold insulation material, heat insulation material, sound absorption material, sound insulation material, shock absorbing material, interlayer sound insulation material, heating floor material, vacuum insulation material It can be used in the manufacture of materials selected from the group consisting of interior materials, safety, hygiene materials, blast-proof carbon materials, ceiling materials, finishing materials, clothing materials, and bedding materials.
  • the present invention can provide a method for producing a multipurpose functional sanitary cotton comprising the following steps:
  • step of infiltrating the above-mentioned flame retardant (flame-proof) liquid composition using a hydraulic spray penetration method to produce a multi-functional functional sanitary cotton; (b) dehydrating and drying the cotton and taking the cotton off; (C) may comprise the step of dehydrating the cotton using a mangle (MANGLE) dehydrator, it may further comprise the step of drying the cotton using a hot air dryer.
  • MMGLE mangle
  • the hydraulic spraying is performed for 10 to 30 seconds, and the dehydration may be performed by using a Mangle dehydrator to dehydrate the cotton so that the water content is 70 to 80%, and the drying may be performed using a hot air dryer.
  • the cotton wool so as to have a water content of 13% to 15%.
  • the weight ratio of the natural cotton and the composition may be 5: 1 to 5: 3.
  • the multi-functional functional sanitary cotton can be used in the manufacture of yarns, ropes, processed fabrics, fabrics, non-woven fabrics, mats, panel core material, boards, fireproof fabrics, flame-retardant wallpaper, fire curtains, flame retardant carpet, pipe cover, filter material,
  • flame retardant materials, flame retardant materials, heat insulating materials, cold insulation materials, insulation materials, sound absorption materials, sound insulation materials, shock absorbing materials, interlayer sound insulation materials, heating floor materials, vacuum insulation materials, interior materials, safety, hygiene materials, blast-proof carbon materials It is used in the manufacture of ceiling materials, finishing materials, clothing materials, bedding materials, and natural hemp fibers can also be used in the production of materials of natural ginseng mixed cotton including hemp, jute, flax, sheep and yam.
  • the mixed cotton is natural cotton (cotton) cotton, mixed cotton, rice straw cotton, straw cotton, waste paper cotton, natural cotton, coconut fiber cotton, silk cotton, silk cotton, bamboo fiber cotton, banana fiber cotton, cotton wool regenerated cotton, synthetic fiber cotton
  • the mixed cotton is natural cotton (cotton) cotton, mixed cotton, rice straw cotton, straw cotton, waste paper cotton, natural cotton, coconut fiber cotton, silk cotton, silk cotton, bamboo fiber cotton, banana fiber cotton, cotton wool regenerated cotton, synthetic fiber cotton
  • Sanitary cotton can be prepared by mixing in a weight ratio of 1: 9 to 4: 6.
  • it may be used in a weight ratio of 2: 8 to 3: 7.
  • the present invention can provide a functional sanitary fabric prepared by penetrating and immersing the composition for producing multi-functional sanitary cotton, cotton fabric, cotton blend fabric or cotton fabric.
  • the sanitary cotton manufacturing composition may be used by applying any of cotton, cotton fabric, cotton blended fabric, or cotton fabric, as well as fabric material.
  • oleic acid is composed of unsaturated fatty acids which are the main components of fats and oils such as olive oil and camellia oil.
  • unsaturated fatty acids such as olive oil and camellia oil.
  • urea (NH 2 ) 2 CO] is strongly basic, and when dissolved in water, a lot of AMIN ions are formed. It is also an antimicrobial agent with the ability to inhibit the growth of microorganisms and functions to soften cotton.
  • the softener diethylenetriamine [DETA] makes the cotton itself soft, smooth and has the strength of the down, so that it does not break under any impact. And cotton's resilience is strong. In addition, resilience and resilience are increased, durability, shrinkage rate and bonding function is strong.
  • Ammonium polyphosphate has the function of preventing the precipitation of flame retardant (flame-retardant) material as a crystal by the safe dispersing action of the chemicals, the prevention of gel (GEL) formation and the prevention of crystal formation. In addition, it prevents the change of pH and produces phosphate amide during flame retardant (flame flame) combustion by promoting carbonization, and gives high flame retardancy to increase efficiency of dehydration and carbon.
  • Boron (B 2 O 3 ) not only has sterilization, insecticidal, antiseptic function, but also functions to prevent fire or to extinguish burning fire and to strengthen cotton strands.
  • Water-dispersed polyurethane is excellent in water resistance, washing resistance, heat resistance, rebound elasticity, etc., and is very soft and touchy when coating natural cotton (cotton) cotton. It is free from various chemicals and troubles and has good adhesion.
  • Milky white anion, PH is about 8 ⁇ 10 and easily soluble in water.
  • Penetrant is a slightly yellow transparent liquid, anion and ALKYL SUCCINATE. Penetrates quickly into natural cotton (cotton) cotton and has good flame retardant (flame retardant) properties and wettability.
  • NANO SILVER has improved the effect of silver (Ag) due to the emergence of silver nanotechnology, especially in the silver nano state, the sterilization ability is changed qualitatively, and the extremely small size of silver is very strong. It will be bactericidal.
  • the silver component has strong sterilizing and antibacterial properties, and is used as an antibiotic in a wide range of fields such as odor removal, electromagnetic wave, UV protection, far infrared rays, anions, and silver ion emission.
  • Natural cotton (cotton) cotton is hygroscopic, it has been pointed out that the growth of mold and bacteria, odors, mites.
  • the nano silver structure is needle-shaped and attached to the inside of the lumen of the multipurpose functional sanitary cotton, so that it is difficult to detach and the surface size is 5 to 10 nm to maximize the surface area.
  • the injection amount of the silver nano solution relates to a method for producing a versatile functional sanitary cotton, which contains 10 to 30 ppm.
  • Nano titanium dioxide (NANO TIO 2 ) photocatalyst is a nano-sized titanium dioxide (TIO 2 ) particles as a catalyst, and refers to a material having a self-cleaning (SELF CLEANING) and super hydrophilic action.
  • Titanium dioxide as a photocatalyst (TIO 2) will receive the ultraviolet rays of sunlight or fluorescent electron (e -) and holes (h ”) the generation and, in particular, a hole (h Among them, the hydroxide with a strong oxidizing action) (OH RADICAL ) To have bactericidal efficacy.
  • the former generates oxygen adsorbed on the photocatalyst into oxygen ions (O 2- ), which are added to the oxidation reaction intermediate as reactive active species, and have an effect of removing odor or degrading organic matter.
  • O 2- oxygen ions
  • it is very important for building finishing materials, new house syndrome, organic compound (VOC S ) problem, and radon gas (Rn- 222 ) solution generated in concrete and cement.
  • Radon gas generates gas by self-decomposition. This gas is alpha, a type of radiation that is the most harmful to the body, 20 times more dangerous than regular X-rays and gamma rays, and 5 times more dangerous than beta rays. This causes the sick house syndrome. Radon gas is a first-class carcinogen that causes lung cancer as a colorless and odorless gas. Radon gas is emitted from a large number of building materials such as gypsum board, concrete, cement, sand, gravel, soil, stone, and rock. . Multipurpose functional sanitary cotton can alleviate sick house syndrome and radon gas if it is constructed with cotton material or mat and board to remove radon gas.
  • nano titanium dioxide is also mentioned above, but the disadvantage is that the effect is insignificant unless visible or fluorescent lights are emitted. Because it is effective in the place where light or fluorescent light is transmitted, it may be very effective if the product is made by using a versatile functional sanitary cotton for curtains, chairs, wallpaper, etc., and installed indoors. Since it is possible to produce products in various industrial fields using multifunctional functional sanitary cotton, it is considered to have the effect of photocatalyst of titanium dioxide, and it is applied to sanitary cotton. As a result, there is no limit to the use for housing, buildings and other industrial purposes. And it also provides a multi-functional functional sanitary cotton including a composition of the multi-use functional mixed cotton and the preparation method thereof of the prior application patent (Application No. 10-2013-0141631) and a method for producing the same.
  • the multi-functional functional sanitary cotton prepared by the above method has a thermal insulation rate, tensile strength, rupture, compared to the cotton including the pre-registered patent (Registration No. 10-1079871) and the prior application patent (Application No. 10-2013-0141631) Strength, flame retardant, washing resistance, antibacterial, radon gas, fire test results have been greatly improved, and is the ideal cotton without breaking the cotton. In addition, it effectively prevents the growth of mold, bacteria, ticks, etc. 99.9% or more has an excellent antibacterial effect.
  • the bedding can be made of natural cotton sanitary cotton bedclothes that can be used by anyone, since it is possible to wash the futon.
  • the volume reduction rate due to external pressure can be greatly reduced, dimensional stability can be secured, and the construction is convenient, and there is no defect after construction, and it is lighter than other materials, and it is lighter than other materials and has various simultaneous effect functions.
  • Som can contribute to carbon reduction by saving energy in buildings and other buildings, and can be widely used as a high value added industry in various industries such as trains, automobiles, home appliances, shipbuilding, aerospace, hospitals, or defense. It can be called sanitary cotton.
  • Sample preparation of the composition for preparing a multi-functional functional sanitary cotton in the present invention is added 0.15% by weight of oleic acid to 5.33% by weight of urea, 0.15% by weight of diethylenetriamine, 76.14% by weight of water and stirred for 2 to 3 minutes at 70 to 120 Heat and cool for 30 minutes to 1 hour. And 12.18% by weight of ammonium polyphosphate (APP) and 1.68% by weight of boron are added to dissolve.
  • APP ammonium polyphosphate
  • the antimicrobial activity of the comparative example and the sanitary cotton of the present invention was applied to KS K 0693: 2011 mutatis mucosa in the comparative example was 70% Staphylococcus aureus, 54.4% pneumococcal, while the multi-functional functional sanitary cotton of the present invention is 99.9% Staphylococcus aureus. , Pneumococcal 99.9%. Therefore, it was found that the antibacterial degree is very excellent (Fig. 3, Fig. 4).
  • Table 1 Test bacteria Comparative example The present invention multifunctional functional hygiene cotton Staphylococcus aureus 70% 99.90% Pneumococcal 54.40% 99.90%
  • the multi-functional functional sanitary cotton prepared in the present invention was subjected to a test result of a carbon screen area of 27.6 cm 2 and a carbonization length of 7.5 cm, and was much more flame retardant than the carbon screen area of 39.6 cm 2 and a carbonization length of 8.2 cm. Passed the test was judged (Fig. 5).
  • a torch lamp was used for 30 seconds of direct abrasion experiments of natural hemp mixed cotton and carbonized mixed cotton respectively mixed with the present invention multi-purpose functional hygiene cotton and multi-functional functional hygiene cotton, and as shown in FIG. All of the mixed cotton blended with the versatile functional sanitary cotton was carbonized only because of its surface area.
  • the non-woven fabric, woven fabric made of a versatile functional hygiene cotton was also found to be excellent in three types of flame retardant (flame retardant).
  • the comparative example measured tensile strength length (direction 1) 71 (7.3) N / 5 cm (kgf / 5 cm) width (direction 2) 149 (15.2) N / 5 cm (kgf / 5 cm).
  • Tensile strength of multi-functional functional sanitary cotton according to the invention measured in length (direction 1) 71N / 5cm (kgf / 5cm), width (direction 2) 300N / 5cm (kgf / 5cm) to achieve a perfect balance of bidirectional (length and width) It can be seen that the tension of the multi-functional functional sanitary cotton by the uniformity is very enhanced.
  • the comparative example was measured for tensile strength by KSK0351: 2006, hydraulic method, hygienic cotton of the present invention was compared by KSKISO13938-1: 2011, hydraulic method (test area 7.3cm 2 ). The results are shown in FIGS. 8 and 9, respectively.
  • the comparative example was measured at 1059.1 KPa and the multipurpose functional sanitary cotton was measured at 4929 KPa, indicating that the burst strength of the multipurpose functional sanitary cotton was excellent.
  • Example 6 Comparison of washing resistance between comparative example and the present invention multipurpose functional sanitary cotton
  • the comparative example was difficult to wash several times as a result of drying after washing.
  • the multi-functional functional hygiene cotton of the present invention was able to wash and dry 10 times was found to be very excellent washing resistance (Fig. 10).

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Abstract

The present invention relates to multipurpose functional sanitary cotton and, specifically, to multipurpose functional sanitary cotton comprising a composition for preparing multipurpose functional sanitary cotton, the composition containing natural cotton (cotton plant), multipurpose functional mixture cotton, an aqueous urea solution, an oleic acid, diethylene triamine, poly ammonium phosphate (APP), boron (B2O3), water-dispersible polyurethane (PUD), a penetrant (alkyl succinate, anionic), a nano-silver solution, and nano titanium dioxide (TIO2), and to a method for preparing the multipurpose functional sanitary cotton.

Description

다용도 기능성 위생 솜 및 이의 제조방법Multipurpose functional sanitary cotton and its manufacturing method
본 발명은 다용도 기능성 위생 솜 및 상기 위생 솜의 제조방법에 관한 것이다.The present invention relates to a multipurpose functional sanitary cotton and a method for producing the sanitary cotton.
종래 개발된 다용도 기능성 솜으로써, 천연면(목화)솜 및 천연마 솜 등은 난연(방염)성이 취약하고, 또한 공기 중에 노출되면 산화되면서, 솜 자체가 미세 먼지를 유발하였으며, 작업 중에 아주 작은 충격에도 잘 부서져 분진 발생으로 작업 환경을 악화시키고, 상기와 같은 미세 분진은 화재의 원인으로 주목 받아왔다.As a conventionally developed multi-functional cotton, natural cotton (cotton) cotton and natural hemp cotton, etc. are weak in flame retardant (flame-retardant), and also oxidized when exposed to the air, the cotton itself caused fine dust, very small during operation It breaks well in impact and deteriorates the working environment due to dust generation, and the above fine dust has been attracting attention as a cause of fire.
또한 종래 위생 솜은 흡습성이 강하여 곰팡이 및 세균, 냄새, 진드기의 번식이 용이하다는 문제가 있어, 침구류나 의류로 사용하는 것으로만 인식될 뿐 다양한 산업 분야에 이용되는 것은 어려웠다.In addition, the conventional hygiene cotton is hygroscopic, there is a problem that easy to breed mold and bacteria, odors, mites, it was difficult to be used in a variety of industrial fields only recognized as used as bedding or clothing.
상기와 같은 단점을 보완 개량하기 위하여, 선 등록 발명 특허(등록번호 10-1079871호)인 다용도 기능성 솜 및 이의 제조 방법과 선 출원 발명 특허(출원번호 제 10-2013-0141631호)의 보완 개량 발명의 혼합섬유의 다용도 기능성 혼합솜 및 이의 제조 방법에서, 천연면(목화)솜과 마섬유류는 충격에 쉽게 솜이 부서져 미세 먼지와 작업시 분진이 발생되므로, 작업성이 나쁜 결점을 보완하기 위하여 천연면 솜의 중공(LUMEN)에 다용도 기능성 솜 제조용 조성물을 침투시켜 인장 강도와 파열 강도를 강화시키는 방법이 개시되었고, 인산아크릴계 커프링제를 이용해서 솜털을 부서지지 않도록 강화하였으며, 음이온계면활성제에 의한 조성물액을 침투 및 유연성 기능을 부여하는 방법이 공개되었다.In order to supplement and improve the above disadvantages, a multi-functional functional cotton and a manufacturing method thereof and a pre-applied invention patent (Application No. 10-2013-0141631) of the pre-registered invention patent (registration number 10-1079871) In the multi-functional functional mixed cotton and its manufacturing method of mixed fibers of natural cotton (cotton) cotton and hemp fibers, cotton is easily broken in impact, so that dust and dust generated during work, natural cotton to compensate for the poor workability The method of infiltrating the composition for preparing a multifunctional functional cotton into the hollow of cotton is disclosed to strengthen tensile strength and bursting strength, and strengthening the cotton to prevent it from breaking down by using an acrylic phosphate-based cuffing agent, and a composition liquid by an anionic surfactant. A method of penetrating and giving flexibility is disclosed.
보완 개량된 다용도 기능성 위생 솜의 난연(방염)제는 솜 가닥이 단락되어 먼지가 발생되거나, 강한 충격에도 전혀 부서지지 않고 분진 발생 또한 일어나지 않도록 보완 개량 되었으며, 그리고 또한 솜 털의 올을 살려 솜을 부드럽게 하므로 솜이 매끄러워져서 작업성, 생산성이 월등히 증가 되었다. 정전기 발생이 없고, 물 세탁을 해도 솜 털이 상하지 않고 세탁 전으로 다시 복원되고 아주 친환경적이다.The flame retardant (flame-retardant) of the multi-use functional sanitary cotton is improved to prevent dust from shorting the cotton strands or to break the dust and to generate dust. Because of the softening, the cotton was smoothed, which greatly increased workability and productivity. It does not generate static electricity, and does not damage the cotton wool even after washing, and it is very eco-friendly.
또한 솜이 소프트함, 터치감과 보온성, 복원력이 뛰어났으며, 이불에 다용도 기능성 위생 솜을 심재로 집어넣고, 미싱 작업을 해도 솜이 깨어져 미세 먼지, 분진 발생이 없어, 작업환경이 쾌적하여 생산성이 향상되어 보완 개량 효과를 크게 꼽을수 있다.In addition, the cotton is soft, excellent in touch and warmth, and resilience, and the multifunctional functional hygiene cotton is inserted into the bedding as a core material, and the cotton is broken even when sewing, so there is no fine dust or dust. Complementary improvements can be cited.
그리고 흡습성으로 솜내부에 번식되는 곰팡이 및 세균, 냄새, 진드기의 번식을 효율적으로 기능성 추가 및 향상시키기 위하여 은나노(NANO SILVER) 용액과 나노이산화티탄(NANO TIO2)을 주입하여 이중 항균성, 살균성, 멸균성, 항진드기성, 냄새제거, 정전기 발생 방지등을 보완 개량이 되었으며, 그리고 솜에 부착된 은나노(NANO SILVER) 물질, 그외 난연(방염)제 분말등이 미세가루나 먼지, 분말이 되어 다소 미량 발생하여도 솜의 섬유장(FIBER) 상태로 날리기 때문에 인체의 피부나 호흡기 개통에 흡입이 된다해도 솜이 나노 입자가 아닌 섬유장이므로 코털이나 기관지 쪽에서 걸리게 되어, 건강에 유해성이 없다. 또한 은나노(NANO SILVER)나 나노이산화티탄(NANO TIO2)은 침상형 결정 구조라 솜에 박혀 탈리가 되지않고 만약 탈리가 된다면 솜털과 함께 부서져서 아무런 문제가 되지 않는다.And fungi that multiply on cotton inside the moisture and bacteria, odor, in order to efficiently add functionality and increase the growth of mites silver (NANO SILVER) solution and nano-titanium dioxide (NANO TIO 2) for injection by a double antibacterial, disinfectant, sterilizing It has been supplemented and improved to prevent aging, anti-mite, odor removal, and prevention of static electricity, and the nano-silver material attached to the cotton and other flame retardant (flame-retardant) powders become fine powder, dust, and powder. Even if it occurs, the cotton flies in the fiber state (FIBER) state, so even if inhaled into the human skin or respiratory opening, cotton is not a nanoparticles, but because the fiber length is caught on the nose hair or bronchial side, there is no harm to health. In addition, silver nano (NANO SILVER) or nano titanium dioxide (NANO TIO 2 ) is a needle-shaped crystal structure is not detached in the cotton and if detached, it is not a problem because it is broken with the down.
또한 본 발명에 따른 다용도 기능성 위생 솜은 인체에 전혀 무해한 기능성 조성물을 천연면(목화)솜, 혼합잡솜, 볏짚솜, 밀짚솜, 폐지솜, 천연마솜, 코코넛섬유솜, 실크솜, 견솜, 대나무섬유솜, 바나나섬유솜, 폐면재생솜, 합성섬유솜, 펄프솜, 탄화,탄소섬유솜, 텐셀솜, 비스코스레이온솜, 큐프라암모늄레이온솜, 저융점 열가소성수지섬유솜의 조직 내에 침투시킴으로서 천연면솜, 천연마솜, 혼합솜등은 보온성, 보냉성, 단열성, 축열(잠열)성, 인장강도, 파열강도 등이 증대 될뿐 아니라, 중공(LUMEN)에 침투시킨 은나노(NANO SILVER)와 나노 이산화티탄(NANO TIO2)을 중공 내부에 침투되어, 적은 양으로도 표면적이 극대화되고, 나노 입자 하나하나가 모여 아주 작은 공기 공간 (도 2)을 구성하여 여러 가지 동시 효과 기능을 가지게 한다.In addition, the multi-functional functional sanitary cotton according to the present invention is a natural cotton (cotton) cotton, mixed miscellaneous cotton, rice straw straw, straw straw, waste paper cotton, natural cotton wool, coconut fiber cotton, silk cotton, silk cotton, bamboo fiber harmless to the human body Cotton, banana fiber cotton, waste cotton regenerated cotton, synthetic fiber cotton, pulp cotton, carbonized carbon fiber cotton, tencel cotton, viscose rayon cotton, cuprammonium rayon cotton, low melting point thermoplastic resin fiber cotton, Natural cotton, mixed cotton, etc. not only increase heat retention, cold insulation, heat insulation, heat storage (latent heat), tensile strength, burst strength, but also nano silver and nano titanium dioxide (NANO) infiltrated into hollow TIO 2 ) penetrates into the hollow interior, maximizing the surface area in a small amount, and each nanoparticle gathers to form a very small air space (FIG. 2) to have various simultaneous effect functions.
그리고 난연(방염)성과 솜 가닥의 강도가 증가되고, 솜의 산화가 방지된다. 방습성 및 방충성, 항균, 살균성, 멸균성을 가질수 있다. 또한 생산비가 저렴하고, 환경친화적 특징을 가질수 있으며, 향후 사용한 폐자재나 생산시 발생하는 폐자재는 다시 재활용 하여 원료로도 사용가능 하다. 그리고 본 발명에 따른 다용도 기능성 위생 솜은 실, 로프, 가공직포, 부직포, 매트, 발파매트, 보드, 판넬심재, 파이프커버, 필터, 방화포, 방염벽지, 방화커텐, 방염카펫트, 천연면솜, 혼합잡솜, 볏짚솜, 밀짚솜, 폐지솜, 천연마솜, 코코넛섬유솜, 실크솜, 견솜, 대나무섬유솜, 바나나섬유솜, 폐면재생솜, 합성섬유솜, 펄프솜, 탄화, 탄소섬유솜, 텐셀솜, 비스코스레이온솜, 큐프라암모늄레이온솜, 저융점 열가소성수지섬유솜, 카폭솜 등의 조직 내에 침투시킴으로서 천연면솜, 천연마솜, 혼합솜 등의 섬유 구조물에 소재로 이용하는등 여러 산업 분야에 응용 될 것으로 기대된다.And flame retardant (flame retardant) and the strength of the cotton strands are increased, and the oxidation of the cotton is prevented. It can have moisture proof and insect repellent, antibacterial, bactericidal, and sterile. In addition, the production cost is low, it can have environmentally friendly features, and the used waste materials or waste materials generated during the production can be recycled and used as raw materials. And the multi-functional functional sanitary cotton according to the present invention is thread, rope, processed fabric, non-woven fabric, mat, blast mat, board, panel core material, pipe cover, filter, fire cloth, flame-proof wallpaper, fire curtain, flame retardant carpet, natural cotton, mixed Job cotton, rice straw, straw cotton, waste paper, natural cotton, coconut fiber cotton, silk cotton, silk cotton, bamboo fiber cotton, banana fiber cotton, cotton wool recycling cotton, synthetic fiber cotton, pulp cotton, carbonized cotton, carbon fiber cotton, tencel cotton It can be applied to various industrial fields such as viscose rayon cotton, cupra ammonium rayon cotton, low melting point thermoplastic resin fiber cotton, and carpox cotton. It is expected.
본 발명에 따른 다용도 기능성 위생 솜을 이용하여 실이나 가공 직물로 제품화 할 수 있고 또한 기존 제품인 면직물, 면혼방 직물 등에 다용도 기능성 위생 솜의 기능성 조성물을 침투시켜, 난연(방염)화뿐 아니라 위생 제품을 제조 할 수 있는 것을 더 포함시킨다.By using the multi-functional functional hygiene cotton according to the present invention can be productized into a thread or processed fabric, and also penetrates the functional composition of the multi-functional functional hygiene cotton to the existing products such as cotton fabrics, cotton blend fabrics, to produce hygienic products as well as flame retardant (flame-retardant) Include more that you can do.
본 발명은 요소(UREA), 올레인산(OLEIC ACID), 디에틸렌트리아민(DETA), 물, 폴리인산암모늄(APP), 붕소(B2O3), 수분산성폴리우레탄(PUD), 침투제(음이온성), 은나노(NANO SILVER), 나노이산화티탄(NANO TIO2)을 포함하는 다용도 기능성 위생솜 제조용 조성물을 제공한다.The present invention provides urea (OLEA), oleic acid (OLEIC ACID), diethylenetriamine (DETA), water, ammonium polyphosphate (APP), boron (B 2 O 3 ), water dispersible polyurethane (PUD), penetrant (anion) Sex), silver nano (NANO SILVER), nano titanium dioxide (NANO TIO 2 ) comprising a composition for producing a multi-functional functional sanitary cotton.
본 발명의 일구현예에 따르면, 상기 요소(UREA)는 5.1 내지 5.35 중량 %를 포함하는 것을 특징으로 한다.According to one embodiment of the invention, the element (UREA) is characterized in that it comprises 5.1 to 5.35% by weight.
본 발명의 다른 구현예에 따르면, 상기 올레인산(OLEIC ACID)은 0.11 내지 0.18중량%를 포함하는 것을 특징으로 한다.According to another embodiment of the present invention, the oleic acid (OLEIC ACID) is characterized in that it comprises 0.11 to 0.18% by weight.
본 발명의 또다른 구현예에 따르면, 상기 디에틸렌트리아민은 0.13 내지 0.18중량%인 것을 특징으로 한다.According to another embodiment of the present invention, the diethylenetriamine is characterized in that 0.13 to 0.18% by weight.
본 발명의 또다른 구현예에 따르면, 상기 폴리인산암모늄(APP)은 12.1 내지 12.20중량 %를 포함하는 것을 특징으로 한다.According to another embodiment of the present invention, the polyammonium phosphate (APP) is characterized in that it comprises 12.1 to 12.20% by weight.
본 발명의 또다른 구현예에 따르면, 상기 붕소(B2O3)는 1.62 내지 1.70 중량%를 포함하는 것을 특징으로 한다.According to another embodiment of the present invention, the boron (B 2 O 3 ) is characterized in that it comprises 1.62 to 1.70% by weight.
본 발명의 또다른 구현예에 따르면, 상기 수분산성폴리우레탄(PUD)는 0.25 내지 0.32 중량 %를 포함하는 것을 특징으로 한다.According to another embodiment of the present invention, the water dispersible polyurethane (PUD) is characterized in that it comprises 0.25 to 0.32% by weight.
본 발명의 또다른 구현예에 따르면, 상기 침투제(Alkyl Succinate 음이온성)는 0.11 내지 0.18 중량 %를 포함하는 것을 특징으로 한다.According to another embodiment of the invention, the penetrant (Alkyl Succinate anionic) is characterized in that it comprises 0.11 to 0.18% by weight.
본 발명의 또다른 구현예에 따르면, 상기 은나노(NANO SILVER)는 2.30 내지 2.48 중량 %를 포함하는 것을 특징으로 한다.According to another embodiment of the present invention, the silver nano (NANO SILVER) is characterized in that it comprises 2.30 to 2.48% by weight.
본 발명의 또다른 구현예에 따르면, 상기 은나노(NANO SILVER) 용액은 PH 6 내지 8 이고, 5~10nm 크기로 침상 구조로 솜 속으로 들어가면 탈리가 어려우며, 변색이 되지 않는 것을 특징으로 한다.According to another embodiment of the present invention, the silver nano (NANO SILVER) solution is PH 6 to 8, 5 ~ 10nm size is characterized in that the desorption is difficult to enter into the cotton in the needle structure, it is not discolored.
본 발명의 또다른 구현예에 따르면, 상기 나노 이산화티탄(NANO TIO2)은 1.5 내지 1.60 중량 %를 포함하는 것을 특징으로 한다.According to another embodiment of the present invention, the nano titanium dioxide (NANO TIO 2 ) is characterized in that it comprises 1.5 to 1.60% by weight.
본 발명의 또다른 구현예에 따르면, 상기 나노 이산화티탄(NANO TIO2)의 표면에 은(Silver)을 코팅하여 사용하는 것을 특징으로 한다.According to another embodiment of the present invention, the surface of the nano titanium dioxide (NANO TIO 2 ) is characterized in that it is used by coating silver (Silver).
또한, 본 발명은 하기 단계를 포함하는 다용도 기능성 위생 솜 제조용 조성물의 제조방법을 제공한다:In addition, the present invention provides a method for producing a composition for producing a multi-functional functional sanitary cotton comprising the following steps:
a) 요소수용액에 올레인산, 디에틸렌트리아민을 첨가하고, 물을 첨가하여 용해액을 제조하는 단계;a) adding oleic acid and diethylenetriamine to the urea aqueous solution, and adding water to prepare a dissolved solution;
b) 상기 용해액에 폴리인산암모늄 및 붕소를 용해시키는 단계;b) dissolving ammonium polyphosphate and boron in the solution;
c) 상기 b) 단계의 용해액에 수분산성폴리우레탄, 침투제, 은나노, 나노이산화티탄을 첨가하여 조성물을 제조하는 단계; 및c) preparing a composition by adding a water dispersible polyurethane, a penetrant, silver nano, and nano titanium dioxide to the solution of step b); And
d) 상기 조성물을 10분 내지 30분간 교반하여 용해하는 단계.d) dissolving the composition by stirring for 10 to 30 minutes.
본 발명의 일구현예에 따르면, 상기 a) 단계의 용해액은 70 내지 120 온도에서 2 내지 3 분 동안 교반하여 가열시키는 것을 특징으로 한다.According to one embodiment of the invention, the solution of step a) is characterized in that the heating by stirring for 2 to 3 minutes at a temperature of 70 to 120.
본 발명의 다른 구현예에 따르면, 상기 d) 단계 이후, 30분 내지 1시간 동안 냉각시키는 것을 더 포함하는 것을 특징으로 한다.According to another embodiment of the present invention, after step d), the method further comprises cooling for 30 minutes to 1 hour.
또한, 본 발명은 상기 조성물을 사용하여 제조된 다용도 기능성 위생솜을 제공한다.In addition, the present invention provides a multi-functional functional sanitary cotton prepared using the composition.
본 발명의 일구현예에 따르면, 상기 다용도 기능성 위생솜은 실, 로프, 가공직포, 부직포, 매트, 발파매트, 보드, 판넬심재, 파이프커버, 필터, 방화포, 방염벽지, 방화커텐 및 방염카펫트로 이루어지는 군으로부터 선택되는 소재의 제조에 사용되는 것을 특징으로 한다.According to one embodiment of the present invention, the multi-functional functional sanitary cotton is thread, rope, processed fabric, non-woven fabric, mat, blast mat, board, panel core material, pipe cover, filter, fire fabric, flame resistant wallpaper, fire curtains and flame retardant carpet It is used for the production of a material selected from the group consisting of.
본 발명의 다른 구현예에 따르면, 상기 다용도 기능성 위생솜은 난연성소재, 방염성소재, 보온성소재, 보냉소재, 단열소재, 흡음소재, 방음소재, 충격흡수소재, 층간차음소재, 난방바닥소재, 진공단열소재, 인테리어소재, 안전,위생소재, 발파방탄소재, 천정재소재, 마감재소재, 의류소재, 및 침구류소재로 이루어지는 군으로부터 선택되는 소재의 제조에 사용되는 것을 특징으로 한다.According to another embodiment of the present invention, the multi-functional functional sanitary cotton is flame retardant material, flame retardant material, thermal insulation material, cold insulation material, heat insulation material, sound absorption material, sound insulation material, shock absorbing material, interlayer sound insulation material, heating floor material, vacuum insulation It is characterized in that it is used in the production of materials selected from the group consisting of materials, interior materials, safety, sanitary materials, blast-proof carbon materials, ceiling materials, finishing materials, clothing materials, and bedding materials.
또한, 본 발명은 하기 단계를 포함하는 다용도 기능성 위생솜의 제조 방법을 제공할 수 있다:In addition, the present invention can provide a method for producing a multipurpose functional sanitary cotton comprising the following steps:
(a) 천연 면솜에 제1항의 조성물을 수압분사 침투시키는 단계;(a) hydraulically infiltrating the composition of claim 1 into natural cotton;
(b) 상기 조성물이 침투된 천연 면솜을 탈수한 후, 건조하는 단계; 및(b) dehydrating the natural cotton infiltrated into the composition, followed by drying; And
(c) 상기 면솜을 타면 하는 단계.(c) taking the cotton wool.
본 발명의 일구현예로, 상기 (a) 단계의 수압분사는 10 내지 30초 동안 수행되는 것을 특징으로 한다.In one embodiment of the present invention, the water pressure spray of step (a) is characterized in that it is carried out for 10 to 30 seconds.
*본 발명의 다른 구현예로, 상기 (b) 단계의 탈수는 망글(Mangle) 탈수기를 이용하여, 면솜의 수분함량이 70 내지 80%가 되도록 탈수하는 것을 특징으로 한다.* In another embodiment of the present invention, the dehydration of the step (b) is characterized in that the dehydration so that the moisture content of cotton wool is 70 to 80% using a mangle (Mangle) dehydrator.
본 발명의 또다른 구현예로, 상기 (b) 단계의 건조는 열풍 건조기를 이용하여, 면솜을 함수율 13% 내지 15%가 되도록 건조하는 것을 특징으로 한다.In another embodiment of the present invention, the drying of step (b) is characterized in that the cotton wool is dried to a water content of 13% to 15% using a hot air dryer.
또한, 본 발명은 상기 위생솜을 포함하는 혼합솜으로써, 상기 혼합솜은 상기 위생솜에 천연 면솜, 혼합잡솜, 볏짚솜, 밀짚솜, 폐지솜, 천연마솜, 코코넛섬유솜, 실크솜, 견솜, 대나무섬유솜, 바나나섬유솜, 폐면재생솜, 합성섬유솜, 펄프솜, 탄화,탄소섬유솜, 텐셀솜, 비스코스레이온솜, 큐프라암모늄레이온솜, 저융점 열가소성수지섬유솜으로 이루어지는 군에서 선택되는 하나 이상의 솜과 1 : 9 내지 4 : 6의 중량비로 혼합한 것을 특징으로 한다.In addition, the present invention is a mixed cotton including the sanitary cotton, the mixed cotton is natural cotton, mixed mixed cotton, rice straw straw, straw cotton, waste paper, natural cotton, coconut fiber cotton, silk cotton, silk cotton, Selected from the group consisting of bamboo fiber cotton, banana fiber cotton, waste cotton regenerated cotton, synthetic fiber cotton, pulp cotton, carbonized carbon fiber cotton, tencel cotton, viscose ray cotton, cuprammonium rayon cotton, low melting point thermoplastic resin fiber cotton It is characterized by mixing at least one cotton with a weight ratio of 1: 9 to 4: 6.
또한, 본 발명은 상기 조성물을 면직물, 면혼방직물, 또는 면원단에 침투 및 침지시켜 제조된 기능성 위생 원단을 제공할 수 있다.In addition, the present invention may provide a functional sanitary fabric prepared by penetrating and immersing the composition into cotton fabric, cotton blend fabric, or cotton fabric.
본원 발명에 의해 보완 개량된 다용도 기능성 위생 솜의 난연(방염)제를 적용하여 기능성 솜을 제조할 경우, 솜 가닥이 단락되어 먼지가 발생되거나, 강한 충격에도 전혀 부서지지 않고 분진 발생 또한 일어나지 않는 장점이 있다. When the functional cotton is manufactured by applying the flame retardant (flame-retardant) agent of the multi-purpose functional hygienic cotton improved by the present invention, the cotton strands are short-circuited, the dust does not occur, even in a strong impact does not occur dust and also does not occur dust There is this.
또한 솜 털의 올을 살려 솜을 부드럽게 하므로 솜이 매끄러워져서 작업성, 생산성이 월등히 증가 되는 효과가 있고, 정전기 발생이 없으며, 물 세탁을 해도 솜 털이 상하지 않고 세탁 전으로 다시 복원되므로, 세탁 후 다시 사용할 수 있다는 점에서 친환경적인 효과를 획득할 수 있다.In addition, by making the cotton softer by using the fluffy oar, the cotton becomes smooth and has the effect of significantly increasing workability and productivity, and there is no static electricity. Eco-friendly effect can be obtained in that it can be used.
또한, 본 발명의 방법으로 제조된 솜은 소프트함, 터치감, 보온성, 및 복원력이 모두 우수하므로, 이불에 다용도 기능성 위생 솜을 심재로 집어넣고, 미싱 작업을 해도 솜이 깨어져 미세 먼지, 분진 발생이 없어, 작업환경이 쾌적하여 생산성이 향상되는 장점이 있다.In addition, the cotton produced by the method of the present invention is excellent in all softness, touch feeling, warmth, and restoring power, so that the multi-functional functional hygiene cotton wool into the bedding, and even if the sewing work, the cotton is broken, fine dust, dust generation There is no advantage in that the working environment is comfortable and productivity is improved.
아울러 흡습성으로 솜내부에 번식되는 곰팡이 및 세균, 냄새, 진드기의 번식을 효율적으로 제거해 기능성 추가 및 향상시키기 위하여 은나노(NANO SILVER) 용액과 나노이산화티탄(NANO TIO2)을 주입하여 이중 항균성, 살균성, 멸균성, 항진드기성, 냄새제거, 정전기 발생 방지 기능 등이 보완 및 추가되었으며, 솜에 부착된 은나노(NANO SILVER) 물질, 그외 난연(방염)제 분말등이 미세가루나 먼지, 분말이 되어 다소 미량 발생하여도 솜의 섬유장(FIBER) 상태로 날리기 때문에 인체의 피부나 호흡기 개통에 흡입이 된다 하여도 솜이 나노 입자가 아닌 섬유장이므로 코털이나 기관지 쪽에서 걸리게 되어, 건강에 유해성이 없다. 또한 은나노(NANO SILVER)나 나노이산화티탄(NANO TIO2)은 침상형 결정 구조라 솜에 박혀 쉽게 탈리가 되지않고 만약 탈리가 된다면 솜털과 함께 부서져서 아무런 문제를 가지지 않는다.In addition, hygroscopically injects silver nano solution and nano titanium dioxide (NANO TIO 2 ) to effectively remove and improve the growth of mold and bacteria, odors, and mites that grow inside the cotton. Sterilization, anti-mite, odor elimination, anti-static function, etc. have been supplemented and added, and silver nano (NANO SILVER) material and other flame retardant (flame-retardant) powders attached to the cotton become fine powder, dust, powder Even when a small amount is generated, the cotton flies in the fiber state (FIBER), so even if it is inhaled by the human skin or respiratory opening, the cotton is not a nanoparticle but a fiber field, so it is caught on the nose hair or bronchial side, and there is no health hazard. In addition, silver nano (NANO SILVER) or nano titanium dioxide (NANO TIO 2 ) is a needle-like crystal structure is not easily detached by being embedded in the cotton, and if it is detached, it is broken with the down and does not have any problem.
도 1은 본 발명에 따른 다용도 기능성 위생 솜의 제조 방법을 나타내는 공정도이다.BRIEF DESCRIPTION OF THE DRAWINGS The process drawing which shows the manufacturing method of the multipurpose functional sanitary cotton which concerns on this invention.
도 2는 천연면(목화)솜을 본 발명에 따른 기능성 위생솜의 조성물로 침지 처리한 솜의 중공(Lumen)의 전, 후를 도시한 그림이다.Figure 2 is a view showing before and after the hollow (Lumen) of the cotton immersed in a natural cotton (cotton) cotton with a composition of the functional hygiene cotton according to the present invention.
도 3은 비교예의 항균도를 시험한 결과를 나타내는 시험성적서이다.3 is a test report showing the results of testing the antimicrobial degree of the comparative example.
도 4는 본 발명에 따른 다용도 기능성 위생솜의 항균도를 시험한 결과를 나타내는 시험성적서이다.Figure 4 is a test report showing the results of testing the antimicrobial degree of the multi-functional functional sanitary cotton according to the present invention.
도 5는 본 발명에 따른 다용도 기능성 위생솜의 방염성을 시험한 결과를 나타낸 시험성적서이다.5 is a test report showing the results of testing the flame resistance of the multi-functional functional sanitary cotton according to the present invention.
도 6은 본 발명에 따른 다용도 기능성 위생솜과 위생솜을 소재로 각각 혼합한 천연 마혼합솜, 탄화혼합솜을 토치램프로 30초간 직화 실험을 한 사진이다.FIG. 6 is a photograph of a 30-second direct weaving experiment using a torch lamp with a natural hemp mixed cotton ball and a carbon mixed cotton ball mixed with a versatile functional hygiene cotton and a hygienic cotton material according to the present invention.
도 7은 본 발명에 따른 다용도 기능성 위생솜 소재로 만든 부직포를 토치램프로 직화 실험 한 사진이다. Figure 7 is a photograph of a nonwoven fabric made of a multi-functional functional sanitary cotton material according to the present invention by a torch lamp.
도 8은 비교예의 인장강도, 파열강도, 내한성을 시험한 결과를 나타내는 시험성적서이다.8 is a test report showing the results of testing the tensile strength, burst strength, and cold resistance of the comparative example.
도 9는 본 발명에 따른 다용도 기능성 위생솜의 인장강도, 파열강도를 시험한 결과를 나타내는 시험성적서이다.9 is a test report showing the results of testing the tensile strength, bursting strength of the multi-functional functional sanitary cotton according to the present invention.
도 10은 본 발명에 따른 다용도 기능성 위생솜의 내세탁성을 시험한 결과를 나타내는 시험성적서이다.10 is a test report showing the results of the test the washing resistance of the multi-functional functional sanitary cotton according to the present invention.
도 11은 본 발명에 따른 다용도 기능성 위생솜의 내한성을 시험한 결과를 나타내는 시험성적서이다.11 is a test report showing the results of testing the cold resistance of the multi-functional functional sanitary cotton according to the present invention.
도 12는 본 발명에 따른 다용도 기능성 위생솜의 보온율을 시험한 결과를 나타내는 시험성적서이다.12 is a test report showing the results of testing the thermal insulation rate of the multi-functional functional sanitary cotton according to the present invention.
도 13은 본 발명에 따른 다용도 기능성 위생솜의 소재로 만든 침구류 사진이다.Figure 13 is a bedding picture made of the material of the multi-functional functional sanitary cotton in accordance with the present invention.
본 발명은 다용도 기능성 위생 솜에 관한 것으로 구체적으로는 본 출원인의 선행기술(등록특허 제10-1079871호)인 "다용도 기능성 솜 및 이의 제조 방법"의 보완 개량 발명이다. 상기 선행기술의 다용도 기능성 솜인 천연면(목화)솜은 보온성, 단열성, 극 저온성, 흡음성이 뛰어나면서도 유해성분과 환경공해는 유발하지 않는 다는 것이 특징이다. 본 발명의 다용도 기능성 솜 및 제조방법은 상기 선행기술에서 개발된 다용도 기능성 혼합 솜의 보완 개량을 위한 것으로, 기능성을 추가하였고, 난연(방염)물성을 개선하여 보다 위생적이고 쾌적한 다용도 기능성 위생 솜을 제공할 수 있다. The present invention relates to a multi-functional functional sanitary cotton, specifically, a complementary and improved invention of the applicant's prior art (Registration No. 10-1079871) "Multi-functional functional cotton and its manufacturing method". Natural cotton (cotton) cotton is a versatile functional cotton of the prior art is characterized in that it does not cause harmful components and environmental pollution, while excellent in thermal insulation, heat insulation, ultra-low temperature, sound absorption. The multi-functional functional cotton and manufacturing method of the present invention is for complementary improvement of the multi-functional functional mixed cotton developed in the prior art, and added functionality, improve flame retardant (flame-retardant) properties to provide a more hygienic and comfortable multi-purpose functional hygiene cotton can do.
상기 등록특허의 다용도 기능성 솜은 암모니아 수용액 100 중량 %에 제1인산암모늄 20~25 중량 %를 첨가하여 50~70 온도 범위에서 2~3 분간교반 용해시킨 용액에 음이온 계면활성제 0.1~0.3 중량 %, 불소계 발수제 1.5~3.2 중량 % 이산 아크릴계 카프링제 0.5~2.5 중량 %로 첨가하여 10~30 분간 교반하여 다용도 기능성 솜 제조용의 조성물(난연, 방염액)을 얻고, 이 조성물을 천연면(목화)솜에 침지, 함침 시킨다. 천연면(목화)솜과 조성물(난연, 방염액)의 중량비가 5:1 내지 5:3되게 하여 1~2 분간 함침 시키고, 함수율 70~80%로 탈수하고, 고주파 건조기로 15 중량% 미만으로 건조시킨 다음 타면해서 제조되는 다용도 기능성 솜이다.The multi-use functional cotton of the registered patent is 0.1 to 0.3% by weight of anionic surfactant in a solution of stirring for 2 to 3 minutes in a temperature range of 50 to 70 by adding 20 to 25% by weight of ammonium phosphate to 100% by weight of ammonia aqueous solution, 1.5 ~ 3.2% by weight of fluorine-based water repellent 0.5-2.5% by weight of di-acrylic-based capping agent, and stirred for 10-30 minutes to obtain a composition (flame retardant, flame retardant) for producing a versatile functional cotton, and the composition is placed on a cotton (cotton) cotton Immerse and impregnate. The weight ratio of natural cotton (cotton) cotton and composition (flame retardant, flame retardant) is 5: 1 to 5: 3, impregnated for 1 to 2 minutes, dehydrated at a water content of 70 to 80%, and less than 15% by weight with a high frequency dryer. It is a versatile functional cotton that is dried and then burned.
즉 본 발명은 상기 조성물을 보완 개량한 조성물(난연, 방염액)로서, 요소(UREA), 올레인산(OLEIC ACID), 디에틸렌트리아민(DETA), 물, 폴리인산암모늄(APP), 붕소(B2O3), 수분산성폴리우레탄(PUD), 침투제(음이온성), 은나노(NANO SILVER), 나노이산화티탄(NANO TIO2)을 포함하는 다용도 기능성 위생솜 제조용 조성물을 제공하는 것을 그 목적으로 한다.In other words, the present invention is a composition (flame retardant, flame retardant) supplemented with the composition, urea (UREA), oleic acid (OLEIC ACID), diethylenetriamine (DETA), water, ammonium polyphosphate (APP), boron (B 2 O 3 ), water dispersible polyurethane (PUD), penetrant (anionic), silver nano (NANO SILVER), nano titanium dioxide (NANO TIO 2 ) to provide a composition for producing a multi-functional functional sanitary cotton .
본 발명의 일구현예에 따르면, 상기 조성물은 요소 5.1 내지 5.35중량%, 올레인산 0.11 내지 0.18중량%, 디에틸렌트리아민 0.13 내지 0.18 중량%, 폴리인산암모늄(APP) 12.1 내지 12.20중량%, 붕소(B2O3) 1.62 내지 1.70 중량%, 수분산성폴리우레탄(PUD) 0.25 내지 0.32 중량%, 침투제(Alkyl Succinate 음이온성)는 0.11 내지 0.18 중량%, 은나노 2.30 내지 2.48 중량%, 나노 이산화티탄(NANO TIO2)은 1.5 내지 1.60 중량 %, 및 나머지 잔부의 물을 포함하는 것일 수 있다.According to one embodiment of the invention, the composition is 5.1 to 5.35% by weight of urea, 0.11 to 0.18% by weight of oleic acid, 0.13 to 0.18% by weight of diethylenetriamine, 12.1 to 12.20% by weight of ammonium polyphosphate (APP), boron ( B 2 O 3 ) 1.62 to 1.70% by weight, water dispersible polyurethane (PUD) 0.25 to 0.32% by weight, penetrant (Alkyl Succinate anionic) 0.11 to 0.18% by weight, silver nano 2.30 to 2.48% by weight, nano titanium dioxide (NANO TIO 2 ) may comprise 1.5 to 1.60% by weight, and the remainder of water.
상기 은나노(NANO SILVER) 용액은 pH 6 내지 8이고, 5 내지 10nm 크기로 침상 구조로 솜 속으로 들어가면 탈리가 어려우며, 변색이 되지 않는 것을 특징으로 한다.The silver nano (NANO SILVER) solution is pH 6 to 8, 5 to 10nm size is characterized in that the desorption is difficult to enter into the cotton in the needle structure, it is not discolored.
또한, 본 발명은 하기 단계를 포함하는 다용도 기능성 위생 솜 제조용 조성물의 제조방법을 제공할 수 있다:In addition, the present invention can provide a method for producing a composition for producing a multi-functional functional hygiene cotton comprising the following steps:
a) 요소수용액에 올레인산, 디에틸렌트리아민을 첨가하고, 물을 첨가하여 용해액을 제조하는 단계;a) adding oleic acid and diethylenetriamine to the urea aqueous solution, and adding water to prepare a dissolved solution;
b) 상기 용해액에 폴리인산암모늄 및 붕소를 용해시키는 단계;b) dissolving ammonium polyphosphate and boron in the solution;
c) 상기 b) 단계의 용해액에 수분산성폴리우레탄, 침투제, 은나노, 나노이산화티탄을 첨가하여 조성물을 제조하는 단계; 및c) preparing a composition by adding a water dispersible polyurethane, a penetrant, silver nano, and nano titanium dioxide to the solution of step b); And
d) 상기 조성물을 10분 내지 30분간 교반하여 용해하는 단계.d) dissolving the composition by stirring for 10 to 30 minutes.
즉 본 발명의 조성물 제조방법은 요소 5.1 내지 5.35 중량%, 올레인산 0.11 내지 0.18 중량%를 첨가하고, 디에틸렌트리아민은 0.13 내지 0.18 중량%, 물 72.5 내지 77.15 중량%를 첨가하고, 70 내지 120 에서 2 내지 3분 동안 교반 가열 반응시키는 단계를 포함한다.That is, the method of preparing the composition of the present invention adds 5.1 to 5.35% by weight of urea, 0.11 to 0.18% by weight of oleic acid, 0.13 to 0.18% by weight of diethylenetriamine, and 72.5 to 77.15% by weight of water, and at 70 to 120 Stirring and stirring for 2 to 3 minutes.
상기 교반 가열 반응 이후 폴리인산암모늄(APP) 12.1 내지 12.20 중량 %, 붕소 1.62 내지 1.70 중량%를 첨가하여 용해시킨다. 그리고 수분산성폴리우레탄(PUD) 0.25 내지 0.32중량 %, 침투제 0.11 내지 0.18중량 %, 은나노(NANO SILVER) 용액 2.30 내지 2.48중량 %, 나노이산화티탄(NANO TIO2)은 1.5 내지 1.60중량 %를 첨가하여, 10 내지 30분간 교반 용해하여, 조성물을 완성하였다. After the stirring heating reaction, ammonium polyphosphate (APP) was dissolved by adding 12.1 to 12.20 wt% and boron 1.62 to 1.70 wt%. And water dispersible polyurethane (PUD) 0.25 to 0.32% by weight, penetrant 0.11 to 0.18% by weight, 2.30 to 2.48% by weight of NANO SILVER solution, nano titanium dioxide (NANO TIO 2 ) by adding 1.5 to 1.60% by weight The solution was dissolved by stirring for 10 to 30 minutes.
또한, 본 발명은 상기 조성물을 사용하여 제조된 다용도 기능성 위생솜을 제공할 수 있다.In addition, the present invention can provide a versatile functional sanitary cotton prepared using the composition.
본 발명의 일실시예로, 상기 다용도 기능성 위생솜은 실, 로프, 가공직포, 부직포, 매트, 발파매트, 보드, 판넬심재, 파이프커버, 필터, 방화포, 방염벽지, 방화커텐 또는 방염카펫트의 소재로 사용될 수 있다.In one embodiment of the present invention, the multi-functional functional sanitary cotton is thread, rope, processed fabric, non-woven fabric, mat, blast mat, board, panel core material, pipe cover, filter, fire fabric, flame-resistant wallpaper, fire curtain or flame-resistant carpet Can be used as a material.
본 발명의 다른 실시예로, 상기 다용도 기능성 위생솜은 난연성소재, 방염성소재, 보온성소재, 보냉소재, 단열소재, 흡음소재, 방음소재, 충격흡수소재, 층간차음소재, 난방바닥소재, 진공단열소재, 인테리어소재, 안전,위생소재, 발파방탄소재, 천정재소재, 마감재소재, 의류소재, 및 침구류소재로 이루어지는 군으로부터 선택되는 소재의 제조에 사용될 수 있다.In another embodiment of the present invention, the multi-functional functional sanitary cotton is flame retardant material, flame retardant material, thermal insulation material, cold insulation material, heat insulation material, sound absorption material, sound insulation material, shock absorbing material, interlayer sound insulation material, heating floor material, vacuum insulation material It can be used in the manufacture of materials selected from the group consisting of interior materials, safety, hygiene materials, blast-proof carbon materials, ceiling materials, finishing materials, clothing materials, and bedding materials.
또한, 본 발명은 하기 단계를 포함하는 다용도 기능성 위생솜의 제조 방법을 제공할 수 있다:In addition, the present invention can provide a method for producing a multipurpose functional sanitary cotton comprising the following steps:
(a) 천연 면솜에 제1항의 조성물을 수압분사 침투시키는 단계;(a) hydraulically infiltrating the composition of claim 1 into natural cotton;
(b) 상기 조성물이 침투된 천연 면솜을 탈수한 후, 건조하는 단계; 및(b) dehydrating the natural cotton infiltrated into the composition, followed by drying; And
(c) 상기 면솜을 타면 하는 단계. (c) taking the cotton wool.
즉, (a) 상기의 솜류를 난연(방염)액 조성물을 수압분사침투법을 이용하여 침투시켜 다용도 기능성 위생 솜을 제조하는 단계; (b) 상기 솜을 탈수 및 건조하는 단계 및 상기 솜을 타면하는 단계; (c) 망글(MANGLE) 탈수기를 이용하여 상기 솜을 탈수시키는 단계를 포함할 수 있고, 열풍건조기를 이용하여 상기 솜을 건조하는 단계를 더 포함할 수 있다. That is, (a) the step of infiltrating the above-mentioned flame retardant (flame-proof) liquid composition using a hydraulic spray penetration method to produce a multi-functional functional sanitary cotton; (b) dehydrating and drying the cotton and taking the cotton off; (C) may comprise the step of dehydrating the cotton using a mangle (MANGLE) dehydrator, it may further comprise the step of drying the cotton using a hot air dryer.
상기 수압분사는 10 내지 30초간 수행되는 것이 바람직하고, 상기 탈수는 망글(Mangle) 탈수기를 이용하여, 면솜의 수분함량이 70 내지 80%가 되도록 탈수하는 것이 바람직하며, 상기 건조는 열풍 건조기를 이용하여, 면솜을 함수율 13% 내지 15%가 되도록 건조하는 것이 바람직하다.Preferably, the hydraulic spraying is performed for 10 to 30 seconds, and the dehydration may be performed by using a Mangle dehydrator to dehydrate the cotton so that the water content is 70 to 80%, and the drying may be performed using a hot air dryer. Thus, it is preferable to dry the cotton wool so as to have a water content of 13% to 15%.
본 발명의 일구현에 따르면, 상기 천연 면솜 및 상기 조성물의 중량비는 5:1 내지 5:3일 수 있다. 또한 상기 다용도 기능성 위생 솜은 실, 로프, 가공직포, 원단, 부직포, 매트, 판넬심재, 보드, 방화포, 방염벽지, 방화커텐, 방염 카펫트, 파이프커버, 필터소재의 제조에 사용 될 수 있고, 또한 난연성소재, 방염성소재, 보온성소재, 보냉소재, 단열소재, 흡음소재, 방음소재, 충격흡수소재, 층간차음소재, 난방바닥소재, 진공단열소재, 인테리어소재, 안전,위생소재, 발파방탄소재, 천정재소재, 마감재소재, 의류소재, 침구류소재의 제조에 사용되고, 또한 천연 삼섬유는 대마, 황마, 아마, 양마, 저마 모두를 포함하는 천연삼 혼합솜의 소재의 제조에 사용될 수 있다.According to one embodiment of the invention, the weight ratio of the natural cotton and the composition may be 5: 1 to 5: 3. In addition, the multi-functional functional sanitary cotton can be used in the manufacture of yarns, ropes, processed fabrics, fabrics, non-woven fabrics, mats, panel core material, boards, fireproof fabrics, flame-retardant wallpaper, fire curtains, flame retardant carpet, pipe cover, filter material, In addition, flame retardant materials, flame retardant materials, heat insulating materials, cold insulation materials, insulation materials, sound absorption materials, sound insulation materials, shock absorbing materials, interlayer sound insulation materials, heating floor materials, vacuum insulation materials, interior materials, safety, hygiene materials, blast-proof carbon materials, It is used in the manufacture of ceiling materials, finishing materials, clothing materials, bedding materials, and natural hemp fibers can also be used in the production of materials of natural ginseng mixed cotton including hemp, jute, flax, sheep and yam.
또한, 본 발명의 위생솜을 포함하는 혼합솜을 제공할 수 있다. 상기 혼합솜은 천연면(목화)솜, 혼합잡솜, 볏짚솜, 밀짚솜, 폐지솜, 천연마솜, 코코넛섬유솜, 실크솜, 견솜, 대나무섬유솜, 바나나섬유솜, 폐면재생솜, 합성섬유솜, 펄프솜, 탄화,탄소섬유솜, 텐셀솜, 비스코스레이온솜, 큐프라암모늄레이온솜, 저융점 열가소성수지섬유솜, 및 카폭솜으로 이루어지는 군에서 선택되는 하나 이상과, 본 발명에서 제조된 다용도 기능성 위생솜을 1 : 9 내지 4 : 6 의 중량비율로 혼합하여 제조될 수 있다. 바람직하게는, 2:8 내지 3:7의 중량비율로 사용될 수 있다.In addition, it is possible to provide a mixed cotton comprising a sanitary cotton of the present invention. The mixed cotton is natural cotton (cotton) cotton, mixed cotton, rice straw cotton, straw cotton, waste paper cotton, natural cotton, coconut fiber cotton, silk cotton, silk cotton, bamboo fiber cotton, banana fiber cotton, cotton wool regenerated cotton, synthetic fiber cotton At least one selected from the group consisting of pulp, carbonized, carbon fiber cotton, tencel cotton, viscose rayon cotton, cupraammonium rayon cotton, low melting point thermoplastic resin fiber cotton, and kapok cotton, and the multipurpose functional prepared in the present invention Sanitary cotton can be prepared by mixing in a weight ratio of 1: 9 to 4: 6. Preferably, it may be used in a weight ratio of 2: 8 to 3: 7.
아울러, 본 발명은 다기능성 위생솜 제조용 조성물을 면직물, 면혼방직물 또는 면원단 등에 침투 및 침지시켜 제조된 기능성 위생원단을 제공할 수 있다. 상기 위생솜 제조용 조성물은 솜, 면직물, 면혼방직물, 또는 면원단 뿐만 아니라, 직물 소재의 그 무엇이건 적용하여 사용하는 것이 가능하다.In addition, the present invention can provide a functional sanitary fabric prepared by penetrating and immersing the composition for producing multi-functional sanitary cotton, cotton fabric, cotton blend fabric or cotton fabric. The sanitary cotton manufacturing composition may be used by applying any of cotton, cotton fabric, cotton blended fabric, or cotton fabric, as well as fabric material.
본 발명에서 올레인산[OLEIC ACID]은 올리브유, 동백유등의 유지류의 주성분인 불포화 지방산으로 이루어져 있다. 또한 섬유 유연제로 솜틀의 가닥을 모아 주므로서 가닥이 단락 되지 않고, 부서짐을 방지하므로 인장강도, 파열강도가 강화 된다.In the present invention, oleic acid [OLEIC ACID] is composed of unsaturated fatty acids which are the main components of fats and oils such as olive oil and camellia oil. In addition, by gathering the strands of cotton with a fabric softener, the strands are not short-circuited, preventing breakage, thereby strengthening the tensile strength and rupture strength.
또한 본 발명에서 요소[(NH2)2CO]는 강염기성으로, 물에 녹으면 AMIN 이온들이 많이 형성되며, 화재시에는 암모니아 가스를 발생시켜 소화기능을 발휘한다. 그리고 미생물의 성장을 억제하는 능력을 가진 항미생물제 이기도 하며 솜을 부드럽게 하는 기능을 한다.Also, in the present invention, urea [(NH 2 ) 2 CO] is strongly basic, and when dissolved in water, a lot of AMIN ions are formed. It is also an antimicrobial agent with the ability to inhibit the growth of microorganisms and functions to soften cotton.
그리고 유연제인 디에틸렌트리아민[DETA]은 솜 자체를 부드럽고, 매끄럽게 하는 기능과 솜털의 강도를 있게 하여, 어떤 충격에도 깨어지지 않게 한다. 그리고 솜의 복원력이 강하다. 또한 반발력과 탄력성이 증가되고 내구성, 수축율 감소와 결합기능이 강하다. In addition, the softener diethylenetriamine [DETA] makes the cotton itself soft, smooth and has the strength of the down, so that it does not break under any impact. And cotton's resilience is strong. In addition, resilience and resilience are increased, durability, shrinkage rate and bonding function is strong.
폴리인산암모늄은 약품의 안전적 분산 작용과 겔(GEL)화 방지 또한 결정 형성 방지 작용에 의해서, 난연(방염)물질이 결정으로서 석출을 방지하는 기능이 있다. 그리고 PH 변화를 막고, 탄화 촉진을 통한 난연(방염) 연소시에 인산아마이드가 생성되고, 탈수, 탄소의 효율을 높이는 고 난연성을 부여 한다.Ammonium polyphosphate has the function of preventing the precipitation of flame retardant (flame-retardant) material as a crystal by the safe dispersing action of the chemicals, the prevention of gel (GEL) formation and the prevention of crystal formation. In addition, it prevents the change of pH and produces phosphate amide during flame retardant (flame flame) combustion by promoting carbonization, and gives high flame retardancy to increase efficiency of dehydration and carbon.
붕소(B2O3)는 살균, 살충, 방부기능을 가질 뿐 아니라 불을 붙지 않게 하거나 타오르는 불을 꺼지게 하는 기능과 솜 가닥을 강화시키는 역할도 한다.Boron (B 2 O 3 ) not only has sterilization, insecticidal, antiseptic function, but also functions to prevent fire or to extinguish burning fire and to strengthen cotton strands.
수분산폴리우레탄(PUD)은 방수성, 내세탁성, 내열성, 반발탄성등이 우수하며, 천연면(목화)솜 코팅시 매우 부드럽고 터치감이 좋다. 여러 가지 약품과 트러블이 없고 접착성이 좋다. 유백색으로 음이온이며 PH는 8~10 정도며 물에 쉽게 용해되는 특성이 있다. 침투제는 미황색 투명 액상으로 음이온이며, ALKYL SUCCINATE 이다. 천연면(목화)솜에 빠른 시간에 침투하여 난연(방염)성과 젖음성이 좋다. Water-dispersed polyurethane (PUD) is excellent in water resistance, washing resistance, heat resistance, rebound elasticity, etc., and is very soft and touchy when coating natural cotton (cotton) cotton. It is free from various chemicals and troubles and has good adhesion. Milky white anion, PH is about 8 ~ 10 and easily soluble in water. Penetrant is a slightly yellow transparent liquid, anion and ALKYL SUCCINATE. Penetrates quickly into natural cotton (cotton) cotton and has good flame retardant (flame retardant) properties and wettability.
은나노(NANO SILVER)는 은(Ag) 은 나노기술의 출현으로 인해 보다 향상된 효과를 가져 왔는데, 특히 은이 나노 상태에서는 살균 능력이 질적으로 우수하게 변화되며, 극히 적은 크기의 나노은(Ag)은 매우 강력한 살균 작용을 하게 된다. 또한 은의 성분은 살균력과 항균력이 강할 뿐 아니라, 냄새제거, 전자파, 자외선차단, 원적외선과 음이온, 은이온 방출등 광범위한 분야에서 항생 물질로 사용되고 있다. 천연면(목화)솜은 흡습성으로 곰팡이 및 세균, 냄새, 진드기의 번식이 문제점으로 지적되어 왔다. 은나노를 주입하여 살균력과 항균력을 통해 세균 감염방지와 냄새제거가 되어 위생과 건강에 도움이 되도록 하는데 보완 개량하는 목적이 있고 다용도 기능성 위생솜의 그 제조 방법에 관한 것이다. 그리고 나노은의 구조는 침상형으로 다용도 기능성 위생솜의 중공(lumen) 내부에 부착이되어, 탈리가 어렵고 그 사이즈는 5~10 nm로 표면적을 극대화 하였다. 은나노 용액의 주입량은 10 내지 30ppm를 함유 시키는 것을 특징으로 하는 다용도 기능성 위생솜의 제조 방법에 관한 것이다.NANO SILVER has improved the effect of silver (Ag) due to the emergence of silver nanotechnology, especially in the silver nano state, the sterilization ability is changed qualitatively, and the extremely small size of silver is very strong. It will be bactericidal. In addition, the silver component has strong sterilizing and antibacterial properties, and is used as an antibiotic in a wide range of fields such as odor removal, electromagnetic wave, UV protection, far infrared rays, anions, and silver ion emission. Natural cotton (cotton) cotton is hygroscopic, it has been pointed out that the growth of mold and bacteria, odors, mites. It is aimed at supplementing and improving the silver nano-injection to prevent bacterial infection and to remove odor through sterilization and antibacterial activity, and to help hygiene and health. The nano silver structure is needle-shaped and attached to the inside of the lumen of the multipurpose functional sanitary cotton, so that it is difficult to detach and the surface size is 5 to 10 nm to maximize the surface area. The injection amount of the silver nano solution relates to a method for producing a versatile functional sanitary cotton, which contains 10 to 30 ppm.
나노이산화티탄(NANO TIO2) 광촉매는 나노 크기의 이산화티탄(TIO2) 입자로 빛을 촉매로 하여, 자정작용(SELF CLEANING)과 초친수 작용을 하는 물질을 말한다. 광촉매로서 이산화티탄(TIO2)은 태양광이나 형광등의 자외선을 받으면 전자(e-)와 정공(h')을 발생하며, 그중에서 특히 정공(h')은 강력한 산화 작용을 가지는 수산화물(OH RADICAL)을 형성하여, 살균 효능을 가지게 된다. 그리고 전자는 광촉매에 흡착되어 있는 산소를 산소이온(O2-)으로 생성 시키는데 이 산소이온은 반응 활성종으로 산화반응 중간체에 부가되어, 냄새 제거나 유기물 분해 효능을 가지게 된다. 특히 최근 문제가 되고 있는 건축 마감 자재 및 건축 시공후 발생되는 새집증후군, 유기화합물(VOCS) 문제나 콘크리트, 시멘트에서 발생되는 라돈가스(Rn-222)해결책으로 매우 중요하게 대두되고 있다.Nano titanium dioxide (NANO TIO 2 ) photocatalyst is a nano-sized titanium dioxide (TIO 2 ) particles as a catalyst, and refers to a material having a self-cleaning (SELF CLEANING) and super hydrophilic action. Titanium dioxide as a photocatalyst (TIO 2) will receive the ultraviolet rays of sunlight or fluorescent electron (e -) and holes (h ") the generation and, in particular, a hole (h Among them, the hydroxide with a strong oxidizing action) (OH RADICAL ) To have bactericidal efficacy. The former generates oxygen adsorbed on the photocatalyst into oxygen ions (O 2- ), which are added to the oxidation reaction intermediate as reactive active species, and have an effect of removing odor or degrading organic matter. In particular, it is very important for building finishing materials, new house syndrome, organic compound (VOC S ) problem, and radon gas (Rn- 222 ) solution generated in concrete and cement.
라돈가스는 자기 붕괴를 하면서 가스를 발생한다. 이 가스는 알파선으로, 방사선 일종으로 가장 몸에 해로운 방사선으로 일반 엑스선, 감마선보다 20 배 더 위험하며, 베타선보다는 5 배가 위험하다. 이것이 새집 증후군에 원인이 된다. 라돈가스는 무색, 무취의 가스로 폐암을 유발하는 1급 발암 물질로서 라돈가스 방출되는 종류들은 석고보드, 콘크리트, 시멘트, 모래, 자갈, 토양, 석재, 암석등 건축 자재 상당수에서 발생 되고 있는 현실이다. 다용도 기능성 위생솜은 라돈가스를 제거하기 위해서 솜소재 또는 매트, 보드화 하여 천정재, 벽체 마감재로 시공 한다면 새집 증후군, 라돈가스 등을 완화 할수있을 것이다. 나노이산화티탄의 장점도 상기에서 언급 했지만, 단점으로는 가시광선이나 형광등 불빛을 쪼이지 않으면, 효과가 미미하다. 빛이나 형광등 빛이 전달되는 곳에 효과가 있기 때문에 커턴, 의자, 벽지 등에 다용도 기능성 위생솜을 소재로 사용해서 제품화 하여 실내에 설치한다면 아주 효과적 일수도 있다. 다용도 기능성 위생솜을 소재로 여러 산업 분야에서 제품 생산이 가능하므로 이산화티탄의 광촉매의 효과가 있을것으로 보고 위생솜에 접목을 하게 되었다. 이로 인해 주택을 비롯한 건축물 그밖에 산업용 용도로 사용에 제한성이 없다. 그리고 또한 선출원 발명 특허 (출원번호 제10-2013-0141631호)의 다용도 기능성 혼합솜 및 이의 제조 방법의 조성물을 포함하는 다용도 기능성 위생솜 및 이의 제조 방법을 제공한다.Radon gas generates gas by self-decomposition. This gas is alpha, a type of radiation that is the most harmful to the body, 20 times more dangerous than regular X-rays and gamma rays, and 5 times more dangerous than beta rays. This causes the sick house syndrome. Radon gas is a first-class carcinogen that causes lung cancer as a colorless and odorless gas. Radon gas is emitted from a large number of building materials such as gypsum board, concrete, cement, sand, gravel, soil, stone, and rock. . Multipurpose functional sanitary cotton can alleviate sick house syndrome and radon gas if it is constructed with cotton material or mat and board to remove radon gas. The advantages of nano titanium dioxide are also mentioned above, but the disadvantage is that the effect is insignificant unless visible or fluorescent lights are emitted. Because it is effective in the place where light or fluorescent light is transmitted, it may be very effective if the product is made by using a versatile functional sanitary cotton for curtains, chairs, wallpaper, etc., and installed indoors. Since it is possible to produce products in various industrial fields using multifunctional functional sanitary cotton, it is considered to have the effect of photocatalyst of titanium dioxide, and it is applied to sanitary cotton. As a result, there is no limit to the use for housing, buildings and other industrial purposes. And it also provides a multi-functional functional sanitary cotton including a composition of the multi-use functional mixed cotton and the preparation method thereof of the prior application patent (Application No. 10-2013-0141631) and a method for producing the same.
이상의 방법으로 제조된 다용도 기능성 위생솜은 선등록 발명특허(등록번호 제10-1079871호)와 선출원 발명특허(출원번호 제10-2013-0141631호)를 포함한 솜에 비해 보온율, 인장강도, 파열강도, 방염성, 내세탁성, 항균도, 라돈가스, 직화실험결과 등이 크게 향상되었으며, 솜의 부서짐이 없는 아주 이상적인 솜이다. 또한 특히 곰팡이 및 세균, 진드기등의 번식을 99.9% 이상 효율적으로 막아 항균성이 월등이 좋아진 효과가 있다. The multi-functional functional sanitary cotton prepared by the above method has a thermal insulation rate, tensile strength, rupture, compared to the cotton including the pre-registered patent (Registration No. 10-1079871) and the prior application patent (Application No. 10-2013-0141631) Strength, flame retardant, washing resistance, antibacterial, radon gas, fire test results have been greatly improved, and is the ideal cotton without breaking the cotton. In addition, it effectively prevents the growth of mold, bacteria, ticks, etc. 99.9% or more has an excellent antibacterial effect.
또한 새집증후군 원인인 유기화합물, 라돈가스, 암모니아, 아세트 알데히드, 황화수소, 질소산화물등을 완화, 제거하여 아토피예방, 탈취, 소취까지 가능하게 개선되었고, 전자파, 자외선을 차단하며, 은이온, 음이온을 방출한다. 그리고 특히 내세탁성이 월등히 개선되어 이불 물세탁이 가능해 누구나 사용할 수 있는 물세탁이 가능한 천연목화 위생솜 침구류가 가능해 졌다. In addition, by relieving and removing organic compounds, radon gas, ammonia, acetaldehyde, hydrogen sulfide, and nitrogen oxides, which are the causes of sick house syndrome, atopy prevention, deodorization, and deodorization have been improved. Release. In particular, since the washing resistance is greatly improved, the bedding can be made of natural cotton sanitary cotton bedclothes that can be used by anyone, since it is possible to wash the futon.
아울러 외압에 의한 부피 감소율을 크게 줄일수 있으며, 치수 안정성을 확보 할 수 있어, 시공이 편리하고, 시공후의 하자가 발생하지 않는 특성과 함께, 다른 소재에 비해 가볍고, 여러 가지 동시 효과 기능이 있는 위생솜으로 주택을 비롯한 각종 건축물의 에너지 절감으로 탄소 저감에 기여할 수 있으며, 기차, 자동차, 가전제품, 조선, 우주항공, 병원, 또는 국방 등의 여러 산업 분야에 고부가 산업으로 광범위하게 이용될수 있는 다용도 기능성 위생솜이라 할 수 있다. In addition, the volume reduction rate due to external pressure can be greatly reduced, dimensional stability can be secured, and the construction is convenient, and there is no defect after construction, and it is lighter than other materials, and it is lighter than other materials and has various simultaneous effect functions. Som can contribute to carbon reduction by saving energy in buildings and other buildings, and can be widely used as a high value added industry in various industries such as trains, automobiles, home appliances, shipbuilding, aerospace, hospitals, or defense. It can be called sanitary cotton.
이하, 본 발명의 이해를 돕기 위하여 바람직한 실시예 및 실험예를 제시한다. 그러나 하기의 실시예 및 실험예는 본 발명을 보다 쉽게 이해하기 위하여 제공되는 것일 뿐, 하기 실시예 및 실험예에 의해 본 발명의 내용이 한정되는 것은 아니다.Hereinafter, preferred examples and experimental examples are presented to help understand the present invention. However, the following Examples and Experimental Examples are provided only to more easily understand the present invention, and the contents of the present invention are not limited by the following Examples and Experimental Examples.
실시예 1. 본 발명의 다용도 기능성 위생솜의 제조Example 1. Preparation of the multi-purpose functional sanitary cotton of the present invention
본 발명 다용도 기능성 위생솜 제조용 조성물의 시료 제조는 요소 5.33 중량 %에 올레인산 0.15 중량 %를 첨가하고, 디에틸렌트리아민 0.15 중량% 첨가하고 물 76.14 중량%를 첨가하고 70 내지 120에서 2 내지 3 분간 교반 가열시키고, 30분 내지 1시간 동안 냉각 시킨다. 그리고 폴리인산암모늄(APP) 12.18 중량%, 붕소 1.68 중량%를 첨가하여 용해시킨다. Sample preparation of the composition for preparing a multi-functional functional sanitary cotton in the present invention is added 0.15% by weight of oleic acid to 5.33% by weight of urea, 0.15% by weight of diethylenetriamine, 76.14% by weight of water and stirred for 2 to 3 minutes at 70 to 120 Heat and cool for 30 minutes to 1 hour. And 12.18% by weight of ammonium polyphosphate (APP) and 1.68% by weight of boron are added to dissolve.
용해 후, 수분산성폴리 우레탄(PUD) 0.30 중량 %, 침투제 0.15 중량 %, 그리고 은나노(NANO SILVER) 2.40 중량 %, 나노이산화티탄(NANO TIO2)은 1.52 중량%를 첨가하여 10 내지 30 분간 교반 용해하여 제조한 조성물을 얻고, 여기에 천연면(목화)솜이 잠기도록 침지하여 10 분간 조성액을 침투 시킨후, 망글 탈수기로 수분 함량 70~80%로 탈수하고, 열풍 건조기로 함수율 13%~15%로 건조시켜, 견면 부직포를 제조 하였다. 상기 공정을 도 1에 나타내었다. 또한 상기 조성물이 침투된 이후의 구조를 도 2에 나타내었다.After dissolution, 0.30% by weight of water-dispersible polyurethane (PUD), 0.15% by weight of penetrant, 2.40% by weight of silver nano (NANO SILVER), and 1.52% by weight of nano titanium dioxide (NANO TIO 2 ) were added and stirred for 10 to 30 minutes. To obtain a composition prepared by dipping to soak the cotton (cotton) cotton soaked in it for 10 minutes, and then dehydrated with a mangle dehydrator at a moisture content of 70 to 80%, and a water content of 13% to 15% with a hot air dryer. By drying, a plush nonwoven fabric was prepared. The process is shown in FIG. In addition, the structure after the composition is penetrated is shown in FIG.
실시예 2. 비교예와 본 발명 다용도 기능성 위생 솜의 항균도의 비교Example 2 Comparison of Antimicrobial Degrees of Comparative Examples and Invention Multifunctional Functional Hygienic Cotton
비교예와 본 발명의 따른 다용도 기능성 위생솜의 항균도를 비교하는 실험을 수행하였다. An experiment was performed to compare the antimicrobial activity of the multipurpose functional sanitary cotton according to the comparative example and the present invention.
비교예와 본 발명 위생솜의 항균도를 KS K 0693:2011 준용 실험한 결과 비교예의 점균감소율은 황색포도상구균 70%, 폐렴균 54.4%이며, 반면 본 발명의 다용도 기능성 위생 솜은 황색포도상구균 99.9%, 폐렴균 99.9 %이다. 따라서 항균도가 매우 우수함을 알 수 있었다(도 3, 도 4).The antimicrobial activity of the comparative example and the sanitary cotton of the present invention was applied to KS K 0693: 2011 mutatis mucosa in the comparative example was 70% Staphylococcus aureus, 54.4% pneumococcal, while the multi-functional functional sanitary cotton of the present invention is 99.9% Staphylococcus aureus. , Pneumococcal 99.9%. Therefore, it was found that the antibacterial degree is very excellent (Fig. 3, Fig. 4).
표 1
시험균 비교예 본 발명 다용도 기능성 위생 솜
황색포도상구균 70% 99.90%
폐렴균 54.40% 99.90%
Table 1
Test bacteria Comparative example The present invention multifunctional functional hygiene cotton
Staphylococcus aureus 70% 99.90%
Pneumococcal 54.40% 99.90%
실시예 3. 비교예와 본 발명의 다용도 기능성 위생 솜 의 난연(방염)성 시 험결과 비교 Example 3. Comparison of the results of flame retardant (flame-retardant) test of the comparative example and the multi-functional functional sanitary cotton of the present invention
비교예와 본 발명 위생 솜의 난연(방염)성을 소방시설설치 및 안정관리에 관한 법률 시행령의 시험기준에 따라 멕컬버어너법에 의한 시험결과를 표 2과 같이 비교하였다.The comparative results and the flame retardant (flame-retardant) properties of the present invention sanitary cotton were compared with the test results by the McCalburner method according to the test standards of the Enforcement Decree of the Act on the Installation and Stability Management of Fire Protection Facilities as shown in Table 2.
표 2
구분 시험기준 비교예 본 발명 다용도 기능성 위생 솜
잔염시간 (S) 10(S)이내 ○ ○
잔진시간 (S) 30(S)이내 ○ ○
탄화면적 () 50(cm2)이내 39.6 27.6
탄화길이 20(cm)이내 8.2 7.5
판정 - 합격 합격
TABLE 2
division Test standard Comparative example The present invention multifunctional functional hygiene cotton
Afterflaming time (S) Within 10 (S) ○ ○
Residual Time (S) Within 30 (S) ○ ○
Ammunition () Within 50 (cm 2 ) 39.6 27.6
Carbonization length Within 20 (cm) 8.2 7.5
Judgment - pass pass
표 2 나타난 바와 같이 본 발명에서 제조된 다용도 기능성 위생 솜은 탄화면적 27.6cm2, 탄화길이 7.5cm 의 시험성적을 받아 다용도 기능성 솜의 탄화면적 39.6cm2, 탄화길이 8.2cm 보다 훨씬 좋은 성적으로 난연성 시험에 합격판정을 받았다(도 5).As shown in Table 2, the multi-functional functional sanitary cotton prepared in the present invention was subjected to a test result of a carbon screen area of 27.6 cm 2 and a carbonization length of 7.5 cm, and was much more flame retardant than the carbon screen area of 39.6 cm 2 and a carbonization length of 8.2 cm. Passed the test was judged (Fig. 5).
또한 토치램프로 본 발명 다용도 기능성 위생솜과 다용도 기능성 위생 솜을 소재로 각각 혼합한 천연 마혼합솜, 탄화혼합솜을 30초간 직화 실험을 한 결과를 도 6에 나타난 바와 같이 다용도 기능성 위생솜 실험체와 다용도 기능성 위생솜을 소재로 혼합한 혼합솜 모두가 표면적만 탄화되어 역시 3종류다 난연(방염)이 우수함을 알 수 있었다. 또한 다용도 기능성 위생 솜으로 만든 부직포, 직포 역시 3종류 다 난연(방염)이 우수함을 알 수 있었다.(도 7)In addition, a torch lamp was used for 30 seconds of direct abrasion experiments of natural hemp mixed cotton and carbonized mixed cotton respectively mixed with the present invention multi-purpose functional hygiene cotton and multi-functional functional hygiene cotton, and as shown in FIG. All of the mixed cotton blended with the versatile functional sanitary cotton was carbonized only because of its surface area. In addition, the non-woven fabric, woven fabric made of a versatile functional hygiene cotton was also found to be excellent in three types of flame retardant (flame retardant).
실시예 4. 비교예와 본 발명 다용도 기능성 위생 솜의 인장 강도 비교 Example 4 Comparison of Tensile Strength between Comparative Example and Invention Multipurpose Functional Sanitary Cotton
비교예는 KS K0521:2006, C, R, E 스트립 법에 의해 인장강도를 측정하였고, 본 발명의 위생 솜은 KS K0521:2011(파지거리:200mm, 인장속도:100mm/min)에 의해 비교하였다. 그 결과는 각각 도 8 및 도 9에 나타내었다.Comparative examples were measured by the tensile strength by the KS K0521: 2006, C, R, E strip method, the sanitary cotton of the present invention was compared by KS K0521: 2011 (grip distance: 200mm, tensile speed: 100mm / min). . The results are shown in FIGS. 8 and 9, respectively.
표 3에서 볼 수 있듯이 비교예는 인장강도 길이(방향 1) 71(7.3)N/5cm(kgf/5cm) 폭(방향 2) 149(15.2)N/5cm(kgf/5cm)로 측정되었고, 본 발명에 의한 다용도 기능성 위생 솜의 인장강도 길이(방향 1) 71N/5cm(kgf/5cm), 폭(방향 2) 300N/5cm(kgf/5cm)로 측정되어 양방향(길이.폭)의 완벽한 균형에 의한 다용도 기능성 위생 솜의 지지력이 균등화되어 인장력이 아주 강화되었음을 알 수 있다.As can be seen in Table 3, the comparative example measured tensile strength length (direction 1) 71 (7.3) N / 5 cm (kgf / 5 cm) width (direction 2) 149 (15.2) N / 5 cm (kgf / 5 cm). Tensile strength of multi-functional functional sanitary cotton according to the invention measured in length (direction 1) 71N / 5cm (kgf / 5cm), width (direction 2) 300N / 5cm (kgf / 5cm) to achieve a perfect balance of bidirectional (length and width) It can be seen that the tension of the multi-functional functional sanitary cotton by the uniformity is very enhanced.
표 3
구분 비교예 본 발명 다용도 기능성 위생 솜
방향 1 (길이) 71(7.3)N/5cm(kgf/5cm) 71N/5cm(kgf/5cm)
방향 2 (폭) 149(15.2)N/5cm(kgf/5cm) 300N/5cm(kgf/5cm)
TABLE 3
division Comparative example The present invention multifunctional functional hygiene cotton
Direction 1 (length) 71 (7.3) N / 5cm (kgf / 5cm) 71 N / 5 cm (kgf / 5 cm)
Direction 2 (width) 149 (15.2) N / 5cm (kgf / 5cm) 300 N / 5 cm (kgf / 5 cm)
실시예 5. 비교예와 본 발명 다용도 기능성 위생솜의 파열강도 비교 Example 5 Comparison of Burst Strength of Comparative Example and Invention Multifunctional Functional Sanitary Cotton
비교예와 본 발명 다용도 기능성 위생솜을 KSK0351:2006, 유압법에 의해 다용도 기능성 솜과 다용도 기능성 위생솜의 파열 강도를 비교하였다(도 8, 도 9).Comparative example and the present invention multi-functional functional sanitary cotton was compared by the burst strength of the multi-use functional cotton and multi-use functional sanitary cotton by KSK0351: 2006, hydraulic method (Fig. 8, Fig. 9).
비교예는 KSK0351:2006, 유압법에 의해 인장강도 측정하였고, 본 발명의 위생 솜은 KSKISO13938-1:2011, 유압법(시험면적 7.3cm2)에 의해 비교하였다. 그 결과는 각각 도 8 및 도 9에 나타내었다.The comparative example was measured for tensile strength by KSK0351: 2006, hydraulic method, hygienic cotton of the present invention was compared by KSKISO13938-1: 2011, hydraulic method (test area 7.3cm 2 ). The results are shown in FIGS. 8 and 9, respectively.
표 4에서 볼 수 있듯이 비교예는 1059.1KPa로 측정되었으며 다용도 기능성 위생 솜은 4929KPa로 측정되어 다용도 기능성 위생솜의 파열강도가 월등히 뛰어남을 알 수 있다.As can be seen in Table 4, the comparative example was measured at 1059.1 KPa and the multipurpose functional sanitary cotton was measured at 4929 KPa, indicating that the burst strength of the multipurpose functional sanitary cotton was excellent.
표 4
구분 비교예 본 발명 다용도 기능성 위생 솜
시험결과 1,059.1KPa 4,929KPa
Table 4
division Comparative example The present invention multifunctional functional hygiene cotton
Test result 1,059.1KPa 4,929 KPa
실시예 6. 비교예와 본 발명 다용도 기능성 위생솜의 내세탁성 비교 Example 6 Comparison of washing resistance between comparative example and the present invention multipurpose functional sanitary cotton
비교예와 본 발명에 따른 다용도 기능성 위생 솜 내세탁성을 실험한 결과, 비교예는 세탁 후 건조한 결과 여러번 세탁이 힘들었다. 반면 본 발명의 다용도 기능성 위생솜은 10회 세탁 건조가 가능하여 내세탁성이 매우 우수함을 알 수 있었다(도 10).As a result of experiments of washing resistance with multi-functional functional sanitary cotton according to the comparative example and the present invention, the comparative example was difficult to wash several times as a result of drying after washing. On the other hand, the multi-functional functional hygiene cotton of the present invention was able to wash and dry 10 times was found to be very excellent washing resistance (Fig. 10).
또한 내한성(의뢰자 자체시험 방법) -40℃ 24시간 조건에서 비교예나 본 발명에 따른 다용도 기능성 위생 솜 모두가 외관상의 조직의 괴사나 파열이 없는 것으로 나타났고(도 11), 보온율(KS K 0560 : 2011, 항온법)도 89.9%로 우수한 것을 확인하였다(도 12).In addition, cold resistance (customer self-test method) -40 ℃ 24 hours under both conditions of the comparative example or the multi-functional functional hygiene cotton according to the present invention showed no necrosis or rupture of the appearance of the tissue (Fig. 11), the thermal insulation rate (KS K 0560 : 2011, constant temperature method) was also confirmed to be excellent (89.9%) (Fig. 12).
전술한 본 발명의 설명은 예시를 위한 것이며, 본 발명이 속하는 기술분야의 통상의 지식을 가진 자는 본 발명의 기술적 사상이나 필수적인 특징을 변경하지 않고서 다른 구체적인 형태로 쉽게 변형이 가능하다는 것을 이해할 수 있을 것이다. 그러므로 이상에서 기술한 실시예 및 실험예들은 모든 면에서 예시적인 것이며 한정적이 아닌 것으로 이해해야만 한다.The foregoing description of the present invention is intended for illustration, and it will be understood by those skilled in the art that the present invention may be easily modified in other specific forms without changing the technical spirit or essential features of the present invention. will be. Therefore, it should be understood that the embodiments and the experimental examples described above are exemplary in all respects and not limiting.

Claims (24)

  1. 요소(UREA), 올레인산(OLEIC ACID), 디에틸렌트리아민(DETA), 물, 폴리인산암모늄(APP), 붕소(B2O3), 수분산성폴리우레탄(PUD), 침투제(음이온성), 은나노(NANO SILVER), 및 나노이산화티탄(NANO TIO2)을 포함하는 다용도 기능성 위생솜 제조용 조성물.Urea (OLEA), oleic acid (OLEIC ACID), diethylenetriamine (DETA), water, ammonium polyphosphate (APP), boron (B 2 O 3 ), water dispersible polyurethane (PUD), penetrant (anionic), Silver nano (NANO SILVER), and nano titanium dioxide (NANO TIO 2 ) comprising a composition for producing a multi-functional functional sanitary cotton.
  2. 제1항에 있어서, The method of claim 1,
    상기 요소(UREA)는 5.1 내지 5.35 중량% 포함되는 것을 특징으로 하는, 조성물.The element (UREA) is characterized in that it comprises 5.1 to 5.35% by weight, composition.
  3. 제1항에 있어서, The method of claim 1,
    상기 올레인산(OLEIC ACID)은 0.11 내지 0.18중량% 포함되는 것을 특징으로 하는, 조성물.The oleic acid (OLEIC ACID) is characterized in that it comprises 0.11 to 0.18% by weight, composition.
  4. 제1항에 있어서, The method of claim 1,
    상기 디에틸렌트리아민은 0.13 내지 0.18중량% 포함되는 것을 특징으로 하는, 조성물.The diethylenetriamine is characterized in that it comprises 0.13 to 0.18% by weight, composition.
  5. 제1항에 있어서, The method of claim 1,
    상기 폴리인산암모늄(APP)은 12.1 내지 12.20 중량% 포함되는 것을 특징으로 하는, 조성물.The ammonium polyphosphate (APP) is characterized in that it comprises 12.1 to 12.20% by weight, composition.
  6. 제1항에 있어서, The method of claim 1,
    상기 붕소(B2O3)는 1.62 내지 1.70 중량%를 포함되는 것을 특징으로 하는, 조성물.The boron (B 2 O 3 ) is characterized in that it comprises 1.62 to 1.70% by weight, the composition.
  7. 제1항에 있어서, The method of claim 1,
    상기 수분산성폴리우레탄(PUD)는 0.25 내지 0.32 중량 % 포함되는 것을 특징으로 하는, 조성물.The water-dispersible polyurethane (PUD) is characterized in that it comprises 0.25 to 0.32% by weight, composition.
  8. 제1항에 있어서, The method of claim 1,
    상기 침투제는 0.11 내지 0.18 중량 % 포함되는 것을 특징으로 하는, 조성물.The penetrant is characterized in that it comprises 0.11 to 0.18% by weight, composition.
  9. 제1항에 있어서, The method of claim 1,
    상기 은나노(NANO SILVER)는 2.30 내지 2.48 중량 % 포함되는 것을 특징으로 하는, 조성물.The silver nano (NANO SILVER), characterized in that it comprises 2.30 to 2.48% by weight.
  10. 제9항에 있어서, The method of claim 9,
    상기 은나노(NANO SILVER)는 pH 6 내지 8 이고, 5~10 nm 크기로 침상 구조로 솜 속으로 들어가면 탈리가 어려우며, 변색이 되지 않는 것을 특징으로 하는, 조성물.The silver nano (NANO SILVER) is pH 6 to 8, 5 to 10 nm in size in the needle structure into the cotton is difficult to desorption, characterized in that the discoloration is not.
  11. 제1항에 있어서, The method of claim 1,
    상기 나노 이산화티탄(NANO TIO2)은 1.5 내지 1.60 중량% 포함되는 것을 특징으로 하는, 조성물.The nano titanium dioxide (NANO TIO 2 ) is characterized in that it comprises 1.5 to 1.60% by weight.
  12. 제11항에 있어서,The method of claim 11,
    상기 나노 이산화티탄(NANO TIO2)의 표면에 은(Silver)을 코팅하여 사용하는 것을 특징으로 하는, 조성물.The nano-titanium dioxide (NANO TIO 2 ), characterized in that to use the coating (silver) on the surface, the composition.
  13. 하기 단계를 포함하는 다용도 기능성 위생 솜 제조용 조성물의 제조 방법:Method for producing a composition for producing a versatile functional hygiene cotton comprising the following steps:
    a) 요소수용액에 올레인산, 디에틸렌트리아민을 첨가하고, 물을 첨가하여 용해액을 제조하는 단계;a) adding oleic acid and diethylenetriamine to the urea aqueous solution, and adding water to prepare a dissolved solution;
    b) 상기 용해액에 폴리인산암모늄 및 붕소를 용해시키는 단계;b) dissolving ammonium polyphosphate and boron in the solution;
    c) 상기 b) 단계의 용해액에 수분산성폴리우레탄, 침투제, 은나노, 나노이산화티탄을 첨가하여 조성물을 제조하는 단계; 및c) preparing a composition by adding a water dispersible polyurethane, a penetrant, silver nano, and nano titanium dioxide to the solution of step b); And
    d) 상기 조성물을 10분 내지 30분간 교반하여 용해하는 단계.d) dissolving the composition by stirring for 10 to 30 minutes.
  14. 제13항에 있어서,The method of claim 13,
    상기 a) 단계의 용해액은 70 내지 120℃ 온도에서 2 내지 3 분 동안 교반하여 가열시키는 것을 특징으로 하는, 제조 방법.The solution of step a) is characterized in that the heating by stirring for 2 to 3 minutes at a temperature of 70 to 120 ℃.
  15. 제13항에 있어서,The method of claim 13,
    상기 d) 단계 이후, 30분 내지 1시간 동안 냉각시키는 것을 더 포함하는 것을 특징으로 하는, 제조방법.After the step d), characterized in that it further comprises cooling for 30 minutes to 1 hour.
  16. 제1항의 조성물을 사용하여 제조된 다용도 기능성 위생솜.Multipurpose functional sanitary cotton prepared using the composition of claim 1.
  17. 제16항에 있어서,The method of claim 16,
    상기 다용도 기능성 위생솜은 실, 로프, 가공직포, 부직포, 매트, 발파매트, 보드, 판넬심재, 파이프커버, 필터, 방화포, 방염벽지, 방화커텐 및 방염카펫트로 이루어지는 군으로부터 선택되는 소재의 제조에 사용되는 것을 특징으로 하는, 다용도 기능성 위생솜.The multi-functional functional sanitary cotton is manufactured of a material selected from the group consisting of yarn, rope, processed fabric, non-woven fabric, mat, blast mat, board, panel core material, pipe cover, filter, fire cloth, flame-proof wallpaper, fire curtain and flame-resistant carpet A versatile functional sanitary cotton, characterized in that used for.
  18. 제16항에 있어서,The method of claim 16,
    상기 다용도 기능성 위생솜은 난연성소재, 방염성소재, 보온성소재, 보냉소재, 단열소재, 흡음소재, 방음소재, 충격흡수소재, 층간차음소재, 난방바닥소재, 진공단열소재, 인테리어소재, 안전,위생소재, 발파방탄소재, 천정재소재, 마감재소재, 의류소재, 및 침구류소재로 이루어지는 군으로부터 선택되는 소재의 제조에 사용되는 것을 특징으로 하는, 다용도 기능성 위생솜.The versatile functional sanitary cotton is flame retardant material, flame retardant material, thermal insulation material, cold insulation material, heat insulation material, sound absorption material, sound insulation material, shock absorbing material, interlayer sound insulation material, heating floor material, vacuum insulation material, interior material, safety, hygiene material Multifunctional functional hygiene cotton, characterized in that it is used in the manufacture of a material selected from the group consisting of blast-proof carbon material, ceiling material, finishing material, clothing material, and bedding materials.
  19. 하기 단계를 포함하는 다용도 기능성 위생솜의 제조 방법:Method for producing a versatile functional hygiene cotton comprising the following steps:
    (a) 천연 면솜에 제1항의 조성물을 수압분사 침투시키는 단계;(a) hydraulically infiltrating the composition of claim 1 into natural cotton;
    (b) 상기 조성물이 침투된 천연 면솜을 탈수한 후, 건조하는 단계; 및(b) dehydrating the natural cotton infiltrated into the composition, followed by drying; And
    (c) 상기 면솜을 타면 하는 단계.(c) taking the cotton wool.
  20. 제19항에 있어서,The method of claim 19,
    상기 (a) 단계의 수압분사는 10 내지 30초 동안 수행되는 것을 특징으로 하는, 제조 방법.Hydraulic spraying of the step (a), characterized in that carried out for 10 to 30 seconds, the manufacturing method.
  21. 제19항에 있어서,The method of claim 19,
    상기 (b) 단계의 탈수는 망글(Mangle) 탈수기를 이용하여, 면솜의 수분함량이 70 내지 80%가 되도록 탈수하는 것을 특징으로 하는, 제조 방법.Dehydration of the step (b) is using a Mangle dehydrator, characterized in that the dehydration so that the moisture content of cotton wool is 70 to 80%.
  22. 제19항에 있어서,The method of claim 19,
    상기 (b) 단계의 건조는 열풍 건조기를 이용하여, 면솜을 함수율이 13% 내지 15%가 되도록 건조하는 것을 특징으로 하는, 제조 방법.The drying of step (b) is characterized in that the cotton wool is dried so that the water content is 13% to 15% using a hot air dryer.
  23. 제16항의 위생솜을 포함하는 혼합솜으로써, 상기 혼합솜은 상기 위생솜에 천연 면솜, 혼합잡솜, 볏짚솜, 밀짚솜, 폐지솜, 천연마솜, 코코넛섬유솜, 실크솜, 견솜, 대나무섬유솜, 바나나섬유솜, 폐면재생솜, 합성섬유솜, 펄프솜, 탄화,탄소섬유솜, 텐셀솜, 비스코스레이온솜, 큐프라암모늄레이온솜, 저융점 열가소성수지섬유솜, 및 카폭솜으로 이루어지는 군에서 선택되는 하나 이상의 솜과 1 : 9 내지 4 : 6의 중량비로 혼합한 것을 특징으로 하는, 혼합솜.The mixed cotton comprising the sanitary cotton of claim 16, wherein the mixed cotton is natural cotton, mixed mixed cotton, straw straw, straw cotton, waste paper, natural cotton, coconut fiber cotton, silk cotton, silk cotton, bamboo fiber cotton , Banana fiber cotton, waste cotton regenerated cotton, synthetic fiber cotton, pulp cotton, carbonized carbon fiber cotton, tencel cotton, viscose rayon cotton, cupraammonium rayon cotton, low melting point thermoplastic resin fiber cotton, and kapox cotton Mixed cotton, characterized in that mixed with a weight ratio of at least one cotton and 1: 9 to 4: 6.
  24. 제1항의 조성물을 면직물, 면혼방직물, 또는 면원단에 침투 및 침지시켜 제조된 기능성 위생 원단.Functional hygiene fabric prepared by infiltrating and immersing the composition of claim 1 into a cotton fabric, cotton blend fabric, or cotton fabric.
PCT/KR2015/002310 2014-12-17 2015-03-10 Multipurpose functional sanitary cotton and method for preparing same WO2016098952A1 (en)

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