WO2016084021A4 - Cast silicon molybdenum aluminium ferritic ductile iron - Google Patents

Cast silicon molybdenum aluminium ferritic ductile iron Download PDF

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Publication number
WO2016084021A4
WO2016084021A4 PCT/IB2015/059131 IB2015059131W WO2016084021A4 WO 2016084021 A4 WO2016084021 A4 WO 2016084021A4 IB 2015059131 W IB2015059131 W IB 2015059131W WO 2016084021 A4 WO2016084021 A4 WO 2016084021A4
Authority
WO
WIPO (PCT)
Prior art keywords
silicon
amount
less
composition
aluminum
Prior art date
Application number
PCT/IB2015/059131
Other languages
French (fr)
Other versions
WO2016084021A1 (en
Inventor
Marc Wilson
Original Assignee
Honeywell International Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Honeywell International Inc. filed Critical Honeywell International Inc.
Publication of WO2016084021A1 publication Critical patent/WO2016084021A1/en
Publication of WO2016084021A4 publication Critical patent/WO2016084021A4/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C1/00Refining of pig-iron; Cast iron
    • C21C1/08Manufacture of cast-iron
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C1/00Refining of pig-iron; Cast iron
    • C21C1/10Making spheroidal graphite cast-iron
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/04Cast-iron alloys containing spheroidal graphite
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/10Cast-iron alloys containing aluminium or silicon

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Supercharger (AREA)
  • Catalysts (AREA)

Abstract

Disclosed is silicon molybdenum aluminum ferritic iron alloy that includes, in addition to greater than about 50.0 wt % iron, the following amounts: from about 2.0 to about 4.0 wt % aluminum and from about 2.0 to about 4.3 wt % silicon, with the proviso that an equivalent silicon amount be greater than about 4.7 wt %. A ratio of the amount of silicon to the amount of aluminum is from about 1.1:0.9 to about 0.9:1.1. The iron alloy further includes greater than about 1.5 wt % carbon, with the proviso that an equivalent carbon amount be less than about 5.2 wt %, and from about 0.2 to about 1.1 wt % molybdenum.

Claims

AMENDED CLAIMS received by the International Bureau on 13 June 2016
1. A cast iron composition consisting of:
from about 2.0 to about 4.0 wt % aluminum;
from about 2.0 to about 4.3 wt % silicon, with the proviso that an equivalent silicon amount, defined as silicon content plus 0.8 times aluminum content, be greater than about 4.7 wt %, wherein a ratio of the amount of silicon to the amount of aluminum is from 1.1:0.9 to 0.9: 1.1; greater than about 1.5 wt % carbon, with the proviso that an equivalent carbon amount, defined as carbon content plus one-third of combined silicon and phosphorous content, be less than about 5.2 wt %;
from about 0.2 to about 1.1 wt % molybdenum;
less than about 0.03 wt % sulfur;
less than 0.005 wt % oxygen;
less than 0.10 wt % phosphorous;
less than about 0.30 wt % manganese;
less than 0.50 wt % nickel;
less than 0.15 wt % of rare earth metals, optionally being cerium or lanthanum; and a balance of iron, and inevitable/unavoidable impurities,
wherein the term "about" is defined as a variance up to 5% with respect to the stated value.
2. The composition of claim 1, consisting of from about 2.5 wt % to about 3.5 wt % aluminum.
3. The composition of claim 2, consisting of about 3.0 wt % aluminum.
4. The composition of claim 1, consisting of from about 2.5 wt % to about 3.8 wt % silicon.
5. The composition of claim 4, consisting of about 3.2 wt % silicon.
6. The composition of claim 1, consisting of about 0.4 wt % to about 0.9 wt %
molybdenum.
7. The composition of claim 6, consisting of about 0.6 wt % molybdenum.
8. The composition of claim 1, consisting of greater than about 2.0 wt % carbon.
9. The composition of claim 1, wherein the equivalent silicon amount is greater than about 5.0 wt %.
10. The composition of claim 9, wherein the equivalent silicon amount is greater than about 5.2 wt %.
11. The composition of claim 1 , wherein the equivalent carbon amount is less than about 4.7 wt %.
12. The composition of claim 11, wherein the equivalent carbon amount is less than about 4.2 wt %.
13. The composition of claim 1, wherein the ratio of the amount of silicon to the amount of aluminum is about 1.0: 1.0, wherein the equivalent silicon amount is greater than about 5.2 wt %, wherein the equivalent silicon amount is less than about 4.2 wt %, and wherein the composition is more narrowly defined as:
from about 2.5 wt % to about 3.5 wt % aluminum;
from about 2.5 wt % to about 3.8 wt % silicon; and
from about 0.4 wt % to about 0.9 wt % molybdenum.
14. A cast article formed of a material that comprises a cast iron composition, wherein the cast iron composition consists of:
from about 2.0 to about 4.0 wt % aluminum;
from about 2.0 to about 4.3 wt % silicon, with the proviso that an equivalent silicon amount, defined as silicon content plus 0.8 times aluminum content, be greater than about 4.7 wt %, wherein a ratio of the amount of silicon to the amount of aluminum is from 1.1:0.9 to 0.9: 1.1; greater than about 1.5 wt % carbon, with the proviso that an equivalent carbon amount, defined as carbon content plus one-third of combined silicon and phosphorous content, be less than about 5.2 wt %;
from about 0.2 to about 1.1 wt % molybdenum;
less than about 0.03 wt % sulfur;
less than 0.005 wt % oxygen;
less than 0.10 wt % phosphorous;
less than about 0.30 wt % manganese;
less than 0.50 wt % nickel;
less than 0.15 wt % of rare earth metals, optionally being cerium or lanthanum; and a balance of iron, and inevitable/unavoidable impurities,
wherein the term "about" is defined as a variance up to 5% with respect to the stated value.
15. The cast article of claim 14, wherein the cast article comprises an automotive exhaust component selected from the group consisting of: exhaust manifolds and catalytic converter cans; a turbocharger component selected from the group consisting of: turbine housings and center housings; an engine component selected from the group consisting of blocks, heads, cylinder liners, cam shafts, crank shafts, dampers, bed plates, valve train components, pistons, piston inserts, bearing caps, and pump housings; or a transmission component selected from the group consisting of: cases, carriers, housings, barring caps, fly wheels, and pump housings.
16. The cast article of claim 14, consisting of from about 2.5 wt % to about 3.5 wt % aluminum.
17. The cast article of claim 14, consisting of from about 2.5 wt % to about 3.8 wt % silicon.
18. The cast article of claim 14, consisting of about 0.4 wt % to about 0.9 wt %
molybdenum.
19. The cast article of claim 14, consisting of greater than about 2.0 wt % carbon.
20. The cast article of claim 14, wherein the equivalent silicon amount is greater than about 5.2 wt %, wherein the equivalent carbon amount is less than about 4.7 wt %, and wherein the ratio of the amount of silicon to the amount of aluminum is about 1.0: 1.0, and wherein the composition is more narrowly defined as:
from about 2.5 wt % to about 3.5 wt % aluminum;
from about 2.5 wt % to about 3.8 wt % silicon; and
from about 0.4 wt % to about 0.9 wt % molybdenum.
PCT/IB2015/059131 2014-11-26 2015-11-25 Cast silicon molybdenum aluminium ferritic ductile iron WO2016084021A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201462084872P 2014-11-26 2014-11-26
US62/084,872 2014-11-26

Publications (2)

Publication Number Publication Date
WO2016084021A1 WO2016084021A1 (en) 2016-06-02
WO2016084021A4 true WO2016084021A4 (en) 2016-08-04

Family

ID=55221452

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2015/059131 WO2016084021A1 (en) 2014-11-26 2015-11-25 Cast silicon molybdenum aluminium ferritic ductile iron

Country Status (1)

Country Link
WO (1) WO2016084021A1 (en)

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2885285A (en) * 1957-08-22 1959-05-05 Allis Chalmers Mfg Co Alloyed nodular iron
US6508981B1 (en) * 2001-05-24 2003-01-21 Wescast Industries, Inc. High temperature oxidation resistant ductile iron
EP1865082A1 (en) * 2006-06-08 2007-12-12 Georg Fischer Eisenguss GmbH Cast iron with good high temperature oxidation resistance
KR20100015118A (en) * 2008-08-04 2010-02-12 현대자동차주식회사 Ductile cast iron for exhaust system components of a vehicle
KR20120012176A (en) * 2010-07-30 2012-02-09 현대자동차주식회사 Spherical graphite cast iron
CN101899609B (en) * 2010-08-31 2012-11-14 卫辉熔金高温材料有限责任公司 Heat-resistant spherical graphite cast iron for steel ladle slide gate mechanism slide and processing method thereof
CN102337452B (en) * 2011-11-09 2012-12-12 中南大学 Low-alloy heat-resisting cast iron and preparation method thereof
KR101845761B1 (en) * 2012-05-22 2018-04-05 현대자동차주식회사 Ferritic spheroidal cast iron for exhaust system
CN102851575B (en) * 2012-09-24 2014-04-23 苏州东海玻璃模具有限公司 Oxidation-resistant alloying grey cast iron and preparation method thereof
CN103898397B (en) * 2014-04-14 2016-03-30 天津新伟祥工业有限公司 Vehicle turbine shell and the high silicon molybdenum ferro-aluminum ferritic heat-proof nodular cast iron of vapor pipe

Also Published As

Publication number Publication date
WO2016084021A1 (en) 2016-06-02

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