WO2016010297A1 - Environment-friendly and biodegradable non-woven fabric, and apparatus and method for producing same - Google Patents

Environment-friendly and biodegradable non-woven fabric, and apparatus and method for producing same Download PDF

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Publication number
WO2016010297A1
WO2016010297A1 PCT/KR2015/007071 KR2015007071W WO2016010297A1 WO 2016010297 A1 WO2016010297 A1 WO 2016010297A1 KR 2015007071 W KR2015007071 W KR 2015007071W WO 2016010297 A1 WO2016010297 A1 WO 2016010297A1
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Prior art keywords
pla
pulp
nonwoven fabric
eco
fiber
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PCT/KR2015/007071
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French (fr)
Korean (ko)
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구기승
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구기승
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Publication of WO2016010297A1 publication Critical patent/WO2016010297A1/en

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    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/542Adhesive fibres
    • D04H1/55Polyesters
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/559Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving the fibres being within layered webs

Definitions

  • An embodiment of the present invention relates to an eco-friendly biodegradable nonwoven fabric, and a manufacturing apparatus and a manufacturing method thereof, more specifically, an eco-friendly biodegradable nonwoven fabric that improves the quality of the product by improving the mechanical properties by absorbing, softness and bulky It relates to an apparatus and a manufacturing method.
  • nonwoven refers to nonwoven fabric. That is, it refers to a fiber aggregate that is not spun, woven, or braided, and refers to a sheet formed by bonding by physical and chemical means.
  • Conventional nonwoven fabrics were prepared by composite injection of high absorbency pulp and high polyethylene (PE) or polypropylene (PP) when used as a hygiene product.
  • PE polyethylene
  • PP polypropylene
  • PE polyethylene
  • PP polypropylene
  • Polylactic acid forms a market of 150,000 tons in the world, and is used not only for disposable products using the biodegradable properties of PLA, but also for general plastics such as food packaging materials, containers, and electronics cases. The scope of application is expanding.
  • polylactic acid is more expensive than polyethylene (PE) or polypropylene (PP), has a rough feel, has a small volume, and has a problem of low elasticity.
  • the present invention has been made to solve the conventional problems
  • An object of the present invention is to laminate the biodegradable polylactic acid (PLA) having excellent physical properties on the outer surface of the pulp having soft properties and absorbency and volume, improving the physical properties while improving the physical properties while absorbing, soft and bulky
  • PLA polylactic acid
  • the present invention provides an eco-friendly biodegradable nonwoven fabric and a manufacturing apparatus and a method of manufacturing the same, improving the manufacturing cost, reducing the manufacturing cost, and performing 100% biodegradation after disposal.
  • Eco-friendly biodegradable nonwoven manufacturing apparatus provided to achieve the above object is a first PLA fiber manufacturing apparatus for fiberizing PLA; A mesh belt provided at a lower portion of the first PLA fiber manufacturing machine to integrate the vertically injected PLA fiber into a web form; A pulp supply unit provided at one side of the first PLA fiber manufacturing machine to stack pulp on top of the PLA fiber integrated on the mesh belt; A second PLA fiber making machine provided on one side of the pulp supply unit and integrating PLA into a web form on top of the pulp; A heat fusion unit for heat-sealing the laminates by applying heat to the laminates stacked in order of the PLA fibers, pulp, and PLA fibers; And electrically connected to the first and second PLA fiber makers, the mesh belt and the pulp supply unit to control the injection amount of the PLA fiber produced in the first and second PLA fiber makers, and to control the pulp supply amount of the pulp supply unit. It is configured to include; a control unit for controlling the feed rate of the mesh belt.
  • the first and second PLA fiber making machine is an extruder for melting and extruding PLA (biodegradable polylactic acid), a spray nozzle formed with hundreds of small orifices (orifice) for spraying the molten PLA in the extruder, and the injection nozzle
  • PLA biological polylactic acid
  • spray nozzle formed with hundreds of small orifices (orifice) for spraying the molten PLA in the extruder
  • injection nozzle A hot air fan for stretching PLA sprayed from the spray nozzle by spraying high-pressure hot air from both sides of the cooler, a cooler for cooling the stretched PLA, a cutter for cutting the PLA fiber determined by the stretching, and spraying the cut PLA fiber Characterized in that configured to include a jet.
  • the extruder and the injection nozzle is characterized in that it further comprises a filter device for filtering the molten biodegradable polylactic acid (Poly lactic acid; PLA).
  • a filter device for filtering the molten biodegradable polylactic acid (Poly lactic acid; PLA).
  • the extruder is divided into first to fifth regions, the first region is 150 to 160 °C, the second region is 200 to 210 °C, the third region is 220 to 230 °C, the fourth region is 230 to 240 °C,
  • the five regions are characterized in that a temperature of 250 to 260 ⁇ is set.
  • the pulp supply unit is characterized in that the carding machine for separating the pulp fibers consisting of sheets or mats into individual fibers are connected.
  • the control unit controls the injection amount of the first PLA fiber manufacturing machine so that 10% by weight to 40% by weight of PLA fiber is sprayed with respect to the total weight of the nonwoven fabric, and pulp is supplied with 25% by weight to 80% by weight with respect to the total weight of the nonwoven fabric. It controls the supply amount of the supply unit, characterized in that for controlling the injection amount of the second PLA fiber manufacturing machine so that the PLA fiber of 10% by weight to 40% by weight relative to the total weight of the nonwoven fabric.
  • Eco-friendly biodegradable nonwoven fabric manufacturing method is put PLA (biodegradable polylactic acid) into an extruder (melt) and then spinning through a spinning nozzle formed with hundreds of small orifices (Orifice) and the sides of the spinning nozzle S10 step of stretching and cooling the fiber to high pressure hot air sprayed at high speed in; S20 step of integrating the fiberized PLA in the form of a web (Web) on the mesh belt; S30 step of laminating the pulp on the PLA integrated in the web form; S40 step of stacking the laminated fiber in the form of a web (Web) on the pulp in the step S10; And S50 step of bonding the laminated PLA, pulp, PLA by heat fusion bonding.
  • PLA biodegradable polylactic acid
  • the extruder has a first region having a temperature of 150 to 160 ° C., a second region having a temperature of 200 to 210 ° C., a third region having a temperature of 220 to 230 ° C., a fourth region having a temperature of 230 to 240 ° C., and a 250 to 260 ° C.
  • the temperature is divided into a fifth region is set, the PLA is characterized in that complete melting through the first to fifth regions.
  • step S10 characterized in that it further comprises the step of filtering the molten PLA.
  • the PLA is characterized in that selected from the group consisting of poly-D-lactic acid, poly-L-lactic acid, copolymers of D-lactic acid and L-lactic acid.
  • the PLA has a melting point of 100 °C to 180 °C, the melt index is 75 to 120g / 10 minutes, the melt density is characterized in that it has a characteristic in the range of 0.98 to 2.24g / cm3 (260 °C).
  • the pulp is characterized in that the pulp fibers made of a sheet or mat put into a carding machine and separated into individual fibers.
  • the PLA is sprayed and integrated 10% to 80% by weight of the total weight of the nonwoven fabric, the pulp is characterized in that the 25% to 80% by weight of the total weight of the nonwoven fabric is supplied.
  • the PLA is injected by 10% by weight to 40% by weight in the step S20 is integrated, it is characterized in that 10% by weight to 40% by weight is injected in the step S40.
  • Eco-friendly biodegradable nonwoven fabric according to an embodiment of the present invention is sprayed on the mesh belt by the manufacturing method of the first PLA fiber layer integrated in the form of a web; A pulp layer laminated on the first PLA fiber layer; The second PLA fiber layer which is sprayed on the pulp layer and integrated in a web form is thermally fused to each other.
  • Embodiment of the present invention by manufacturing the laminated pulp layer and the PLA layer having biodegradation properties to utilize the soft properties and absorbency and volume of the pulp layer, PLA layer to hold and protect the pulp layer to improve the mechanical strength required in actual use It has the effect of improving the quality of the product.
  • the PLA layer can be washed by holding the surface of the pulp layer, which has the effect that can be used repeatedly.
  • FIG. 1 is a schematic diagram for explaining the eco-friendly biodegradable nonwoven fabric manufacturing apparatus according to an embodiment of the present invention.
  • Figure 2 is a block diagram for explaining the overall configuration of the eco-friendly biodegradable nonwoven fabric manufacturing apparatus according to an embodiment of the present invention.
  • Figure 3 is a block diagram for explaining the configuration of the first, second PLA fiber manufacturing apparatus in an eco-friendly biodegradable nonwoven fabric manufacturing apparatus according to an embodiment of the present invention.
  • Figure 4 is a flow chart for explaining a method for producing an eco-friendly biodegradable nonwoven fabric according to an embodiment of the present invention.
  • Figure 5 is a cross-sectional view showing an eco-friendly biodegradable nonwoven fabric according to an embodiment of the present invention.
  • FIG. 1 is a schematic diagram for explaining an eco-friendly biodegradable nonwoven fabric manufacturing apparatus according to an embodiment of the present invention
  • Figure 2 is a block diagram for explaining the overall configuration of an eco-friendly biodegradable nonwoven fabric manufacturing apparatus according to an embodiment of the present invention
  • 3 is a block diagram for explaining the configuration of the first and second PLA fiber manufacturing apparatus in the apparatus for producing an eco-friendly biodegradable nonwoven fabric according to an embodiment of the present invention.
  • the manufacturing apparatus of eco-friendly biodegradable nonwoven fabric is the first, second PLA fiber manufacturing apparatus (100,300), pulp supply unit 200, mesh belt 400, the control unit 500, heat-sealed portion ( 600).
  • the first and second PLA fiber makers 100 and 300 are extruders 110 and 310 for melting and extruding PLA (biodegradable polylactic acid) introduced as shown in FIG. 3, and hundreds of spraying molten PLA from the extruder.
  • Injection nozzles 130 and 330 having two small orifices formed therein, filter devices 120 and 320 provided between the extruder and the injection nozzle to filter the molten PLA, and PLAs which are provided on both sides of the injection nozzles and sprayed by the injection nozzles.
  • It comprises a hot air fan (140,340) for stretching, a cooler (150,350) for cooling the stretched PLA, cutters (160,360) for cutting the PLA fiber determined by the stretching, and injection holes (170,370) for spraying the cut PLA fiber do.
  • the injection port is provided with valves (171, 371) for controlling the injection amount of the PLA fiber is electrically connected to the control unit.
  • the extruders 110 and 310 are partitioned into first to fifth regions. Then, the partitioned first region is 150 to 160 ⁇ , the second region is 200 to 210 ⁇ , the third region is 220 to 230 ⁇ , the fourth region is 230 to 240 ⁇ and the fifth region is 250 to 260 ⁇ . Are set respectively.
  • the injection nozzles 130 and 330 have 0.88 mm per 12 to 16 cm, and high temperature air having a high velocity distribution forms various filaments between 0.1 ⁇ m and 500 ⁇ in diameter.
  • the pulp supply unit 200 is disposed between the first PLA fiber maker 100 and the second PLA fiber maker 300.
  • the pulp supply unit 200 may directly supply pulp, but the pulp supply unit 200 is connected to a carding machine 210 for separating the pulp fibers made of sheets or mats into individual fibers to separate pulp fibers made of sheets or mats. It is also possible to feed pulp of individual fibers.
  • a mesh belt 400 is provided below the first PLA fiber maker 100 and the pulp supply unit 200 and the second PLA fiber maker 300 which are arranged side by side.
  • the mesh belt 400 integrates and transports the first and second PLA fibers and pulp sprayed from the first PLA fiber maker 100, the pulp supply unit 200, and the second PLA fiber maker 300 in a web form. Let's do it.
  • the first PLA fiber maker 100, the pulp supply unit 200, and the second PLA fiber maker 300 are electrically connected to the control unit 500, respectively.
  • the control unit 500 controls the valves 171, 220, 371 of the first PLA fiber maker 100, the pulp supply unit 200, and the second PLA fiber maker 300 to be sprayed onto the mesh belt 400. Control the injection amount of the second PLA fiber and pulp and control the injection time difference so that the first PLA fiber is sprayed first, the pulp is sprayed on the first PLA fiber, the second PLA fiber is sprayed on the pulp .
  • one side of the mesh belt 400 is provided with a heat-sealed portion 600.
  • the heat-sealed portion 600 is composed of a calendar through which the laminate laminated in the order of the first PLA fiber, pulp, the second PLA fiber guided by the mesh belt 400 is passed.
  • the calendar is a compression roller that lubricates paper or paper, and heat-bonds the first PLA fibers, the pulp, and the second PLA fibers of the laminate to be passed in a state where heat is applied.
  • the pattern is engraved on the calendar to increase the bonding force of the first PLA fiber, pulp, the second PLA fiber.
  • Figure 4 is a flow chart for explaining a method for producing an eco-friendly biodegradable nonwoven fabric according to an embodiment of the present invention.
  • a method for manufacturing an eco-friendly biodegradable nonwoven fabric is formed by melting PLA (biodegradable polylactic acid) into an extruder and then spinning through a spinning nozzle in which hundreds of small orifices are formed, and spinning nozzles.
  • PLA biodegradable polylactic acid
  • S10 stretching and cooling the fiber by high pressure hot air sprayed at high speed from both sides;
  • S20 step of integrating the fiberized PLA in the form of a web (Web) on the mesh belt;
  • S30 step of laminating the pulp on the integrated PLA in the web form;
  • S40 step of stacking the laminated fiber in the form of a web (Web) on the pulp in the step S10; It is configured to include; and laminated PLA, pulp, S50 step of bonding the PLA by thermal fusion.
  • Step S10 is made in the first PLA fiber manufacturing machine 100 and the second PLA fiber manufacturing machine 200.
  • PLA biodegradable polylactic acid
  • PLA has a melting point of 100 to 180 °C
  • the melt index is 20 to 40g / 10 minutes level
  • melt density of 0.98 to 2.24g / cm 3 (260 °C) is used that has a characteristic range.
  • PLA is used selected from the group consisting of poly-D-lactic acid, poly-L-lactic acid, copolymers of D-lactic acid and L-lactic acid.
  • the extruder 110 may include a first region having a temperature of 150 to 160 ° C., a second region having a temperature of 200 to 210 ° C., a third region having a temperature of 220 to 230 ° C., and a fourth region having a temperature of 230 to 240 ° C. It is partitioned into the 5th area
  • PLA is completely dissolved while passing through the first to fifth regions of the extruder 110.
  • the completely dissolved PLA is filtered through the filter device 120 and supplied to the injection nozzle 130, and the PLA supplied to the injection nozzle 130 is injected through hundreds of small orifices.
  • the injected PLA is stretched by the high pressure hot air sprayed at high speed by the hot air fan 140 and cooled by the cooler to be fiberized.
  • the fiberized PLA is cut through the cutter 160 is injected through the injection port 170.
  • the first PLA fiber is injected into the injection port 170 is 10% by weight to 40% by weight relative to the total weight of the nonwoven fabric.
  • Step S20 integrates the first PLA fibers sprayed on the mesh belt 400 in the form of a web.
  • the web formed by the Melt-Blown method has an isotrophic formation. That is, since the web is formed for hot air, the fibers are arbitrarily arranged in the machine direction and the machine width direction, and are not sufficiently cooled so that mutual bonding is achieved by thermal bonding between the fibers.
  • Step S30 stacks the pulp sprayed from the pulp supply unit 200 on the first PLA fiber is integrated and transported in the form of a web. At this time, the laminated pulp is sprayed from 25% by weight to 80% by weight relative to the total weight of the nonwoven fabric.
  • step S40 the second PLA fiber is laminated on the pulp.
  • the second PLA fiber is manufactured in the same manner as step S10 through the second PLA fiber manufacturing machine (300).
  • PLA is injected into the extruder 310 of the second PLA fiber maker 300, and PLA is completely dissolved while passing through the first to fifth regions of the extruder 310. And, the complete dissolved PLA is filtered to the filter device 320 is supplied to the injection nozzle 330 and injected through hundreds of small orifices (Orifice). Subsequently, the injected PLA is stretched by the high pressure hot air of the hot air blower 340 and cooled by the cooler 350 to be fiberized. And, the fiberized PLA is cut through the cutter 360 is injected through the injection hole 370. At this time, the second PLA fiber is injected into the injection hole 370 is 10% by weight to 40% by weight relative to the total weight of the nonwoven fabric.
  • the second PLA fiber manufactured in the second PLA fiber maker 300 is integrated in a web form on the pulp.
  • step S50 the laminate laminated in the order of the first PLA fiber, the pulp, and the second PLA fiber on the mesh belt 400 is passed through the heat-sealed portion 600 to thermally bond the laminate to each other.
  • Eco-friendly biodegradable nonwoven fabric produced by the manufacturing method is sprayed on the mesh belt 400 as shown in Figure 5, the first PLA fiber layer integrated in the web form, the pulp layer laminated on the first PLA fiber layer, the It is injected onto the pulp layer and comprises a second PLA fiber layer integrated in the form of a web.
  • 25% by weight of the total weight of the nonwoven fabric is sprayed onto the mesh belt, and the pulp layer and the pulp layer are stacked by spraying 50% by weight of the total weight of the nonwoven fabric on the first PLA fiber layer and the first PLA fiber layer. 25 wt% of the total weight of the nonwoven fabric was sprayed on to form a second PLA fiber layer integrated in a web form, and the nonwoven fabric was manufactured by heat-sealing them.
  • the first pulp fiber layer integrated in the form of a web 40% by weight relative to the total weight of the nonwoven fabric on the mesh belt, the first pulp fiber layer integrated in the form of a web, the pulp layer, pulp layer laminated by 25% by weight relative to the total weight of the nonwoven fabric on the first PLA fiber layer 40 wt% of the total weight of the nonwoven fabric was sprayed on to form a second PLA fiber layer integrated in a web form, and a nonwoven fabric was manufactured by thermally bonding them together.
  • the pulp layer, pulp layer is laminated by spraying 10% by weight relative to the total weight of the nonwoven fabric on the first PLA fiber layer, the first PLA fiber layer integrated in the web form 45 wt% of the nonwoven fabric was sprayed on to form a second PLA fiber layer integrated in a web form, and the nonwoven fabric was thermally fused to each other.
  • Examples 1, 2, and 3 show that the first PLA fiber layer and the second PLA fiber layer wrap the outer surface of the pulp layer to protect the pulp layer, and hold the pulp without breaking the pulp or dust. Played a role. In addition, it could be seen that due to the pulp layer to maintain a proper sense of volume, it was able to feel a soft texture, excellent absorbency.
  • the first PLA fiber layer and the second PLA fiber layer were formed so thick that the breakage of the first PLA fiber layer and the second PLA fiber layer occurred, the texture was rough, and the volume and absorbency were not good. That is, it can be seen that the first PLA fiber layer and the second PLA fiber layer is preferably used 40% by weight or less based on the total weight of the nonwoven fabric.
  • Comparative Example 2 was inferior in volume and feel compared to the examples, and the absorbency was also not good.
  • Example 1 exhibited an elongation of 35.6% at 20.5N before time elapsed of the manufactured nonwoven fabric, exhibited an elongation of 6.5% at 12.9N after 50 hours of nonwoven fabric, and 75 hours of nonwoven fabric. After the corrosion of the pulp proceeds, the first PLA fibers and the second PLA fibers were corrosion due to biodegradation was unable to measure.
  • Example 2 exhibited an elongation of 27.6% at 23.5 N before time elapsed of the manufactured nonwoven fabric, an elongation of 8.5% at 15.9 N after 50 hours of nonwoven fabric, and corrosion of pulp after 75 hours of nonwoven fabric.
  • the first PLA fibers and the second PLA fibers were torn due to the progress of the corrosion was not possible to measure.
  • Example 3 exhibited an elongation of 28.9% at 25.2N before the time-lapse of the manufactured nonwoven fabric, an elongation of 12.0% at 16.3N after 50 hours of nonwoven fabric, and corrosion of the pulp progressed after 75 hours of nonwoven fabric.
  • the first PLA fibers and the second PLA fibers were torn due to the progress of corrosion, and thus could not be measured.
  • the elongation was 8.0% at 5.1N before the time elapsed of the manufactured nonwoven fabric, the elongation was 4.0% at 3.5N after 50 hours of nonwoven fabric, and the corrosion of the pulp progressed after 75 hours of nonwoven fabric.
  • the first PLA fiber and the second PLA fiber could not be measured due to the breakage.
  • the present invention improves the soft properties, absorbency and volume of the pulp layer by laminating the pulp layer and the PLA layer having biodegradable properties, and the PLA layer to hold and protect the pulp layer, thereby improving the mechanical strength required in actual use.
  • the PLA layer can be washed by holding the surface of the pulp layer, thereby enabling repeated use several times.
  • carding machine 300 second PLA fiber manufacturing machine
  • injection nozzle 140,340 hot air fan

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  • Textile Engineering (AREA)
  • Nonwoven Fabrics (AREA)

Abstract

Provided are environment-friendly and biodegradable non-woven fabric, and an apparatus and a method for producing same, the method for producing the non-woven fabric according to an embodiment of the present invention comprising: step S10 for inserting biodegradable PLA into an extruder and melting, spinning by means of a spinning nozzle having hundreds of small orifices, and fiberizing by elongating and cooling by means of heated high-pressure air sprayed from both sides of the spinning nozzle at high speeds; step S20 for accumulating into a web fiberized PLA on a mesh belt; step S30 for stacking pulp on top of the webbed accumulated PLA; step S40 for accumulating the PLA fiberized in step S10 into a web and stacking same on top of the pulp; and step S50 for combining the stacked PLA, pulp and PLA by thermal bonding. According to one embodiment of the present invention, by stacking the biodegradable pulp layer and PLA layer for production, the smoothness, absorbency and volumetric characteristics of the pulp layer are preserved, and as the PLA layer holds and protects the pulp layer to increase the necessary mechanical strength when in actual use, the product quality is improved. Additionally, the production cost can be reduced by using pulp, environmental problems are not incurred as post-disposal biodegradation is 100%, no carcinogenic or hygienically harmful substances are discharged, and due to superb air-permeability and a feeling of freshness, hygiene and safety are enhanced. Because the PLA layer holds onto the surface of the pulp layer, the present invention can be laundered, and thus allows repeated use.

Description

친환경 생분해 부직포 및 그 제조장치 및 제조방법Eco-friendly biodegradable nonwoven fabric and its manufacturing apparatus and manufacturing method
본 발명의 실시 예는 친환경 생분해 부직포 및 그 제조장치 및 제조방법에 관한 것으로서, 좀 더 상세하게는 흡수성과 부드러움과 부피감을 살리고 기계적인 물성을 향상시켜 제품의 품질을 향상시키는 친환경 생분해 부직포 및 그 제조장치 및 제조방법에 관한 것이다.An embodiment of the present invention relates to an eco-friendly biodegradable nonwoven fabric, and a manufacturing apparatus and a manufacturing method thereof, more specifically, an eco-friendly biodegradable nonwoven fabric that improves the quality of the product by improving the mechanical properties by absorbing, softness and bulky It relates to an apparatus and a manufacturing method.
일반적으로 부직포란 짜지 않은 섬유를 말한다. 즉 방적, 제직, 편조에 의하지 않은 섬유 집합제를 뜻하며, 시트화시켜 물리적, 화학적 수단에 의하여 결합시킨 것을 뜻한다.In general, nonwoven refers to nonwoven fabric. That is, it refers to a fiber aggregate that is not spun, woven, or braided, and refers to a sheet formed by bonding by physical and chemical means.
종래 부직포는 위생용품으로 사용시 흡수성이 좋은 펄프와 결합력이 높은 폴리 에틸렌(PE)이나 폴리 프로필렌(PP)을 복합분사하여 제조하였다.Conventional nonwoven fabrics were prepared by composite injection of high absorbency pulp and high polyethylene (PE) or polypropylene (PP) when used as a hygiene product.
그러나, 폴리 에틸렌(PE)이나 폴리 프로필렌(PP)은 유해성분이 분사되고 흡수가 되지 않아서 연약한 피부엔 홍반 가려움증 등 피부질환을 일으킬 수 있는 문제점이 있고, 썩지 않은 특성때문에 폐기 후 환경문제를 유발시키는 문제점이 있었다.However, polyethylene (PE) or polypropylene (PP) is a problem that can cause skin diseases such as itching and erythema in the soft skin because harmful components are not sprayed and absorbed, and the problem of causing environmental problems after disposal due to the non-rotating characteristics There was this.
최근 지구 온난화에 따라 이산화탄소를 줄이고자 하는 노력들이 지속 연구되고 있다. 특히, 화석연료로부터 생산되는 폴리머는 이산화탄소의 배출량을 높일 뿐만 아니라 매장량의 한계가 있기 때문에 천연식물로부터 합성되는 폴리머를 용융분사하여 섬유화할 수 있는 폴리유산 제품에 대한 연구가 진행되고 있다.Recently, efforts to reduce carbon dioxide due to global warming have been continuously studied. In particular, since the polymer produced from fossil fuel not only increases the amount of carbon dioxide emission but also has a limited reserve, research on polylactic acid products that can melt and polymerize the polymer synthesized from natural plants is being conducted.
폴리유산((Poly lactic acid; PLA)은 전세계에 15만톤 규모 시장을 형성하고 있고, PLA의 생분해성 특성을 이용한 일회용 제품은 물론 식품 포장재, 용기, 전자제품 케이스 등의 일반 플라스틱이 사용되었던 분야까지 그 적용 범위가 확대되고 있다. Polylactic acid (PLA) forms a market of 150,000 tons in the world, and is used not only for disposable products using the biodegradable properties of PLA, but also for general plastics such as food packaging materials, containers, and electronics cases. The scope of application is expanding.
그러나, 폴리유산((Poly lactic acid; PLA)는 폴리 에틸렌(PE)이나 폴리 프로필렌(PP)보다 가격이 높고, 감촉이 거칠며, 부피감이 적을 뿐만 아니라 신축성이 낮은 문제점이 있었다.However, polylactic acid (PLA) is more expensive than polyethylene (PE) or polypropylene (PP), has a rough feel, has a small volume, and has a problem of low elasticity.
[선행기술문헌][Preceding technical literature]
한국공개특허: 10-2012-0107092 (공개일 2012. 09. 28)Korean Publication Patent: 10-2012-0107092 (Published 2012. 09. 28)
한국등록특허: 10-1075004 (공고일 2011. 10. 19)Korea Patent Registration: 10-1075004 (Notice date 2011. 10. 19)
본 발명은 종래의 문제점을 해결하기 위해 안출 된 것으로서,The present invention has been made to solve the conventional problems,
본 발명의 목적은 부드러운 특성과 흡수성과 부피감을 갖는 펄프의 외면에 물성이 우수한 생분해성 폴리유산(Poly lactic acid; PLA)을 적층하여 흡수성과 부드러움과 부피감을 살리면서 물리적 성질을 향상시켜 제품의 품질을 향상시키고, 제조비용을 절감시키며, 폐기 후 100% 생분해가 이루어지게 하는 친환경 생분해 부직포 및 그 제조장치 및 제조방법을 제공하는 데 있다.An object of the present invention is to laminate the biodegradable polylactic acid (PLA) having excellent physical properties on the outer surface of the pulp having soft properties and absorbency and volume, improving the physical properties while improving the physical properties while absorbing, soft and bulky The present invention provides an eco-friendly biodegradable nonwoven fabric and a manufacturing apparatus and a method of manufacturing the same, improving the manufacturing cost, reducing the manufacturing cost, and performing 100% biodegradation after disposal.
상기와 같은 목적을 달성하기 위해 제공되는 본 발명의 일 실시 예에 따른 친환경 생분해 부직포 제조장치는 PLA를 섬유화시키는 제 1 PLA섬유제조기; 상기 제 1 PLA섬유제조기의 하부에 구비되어 수직 분사되는 PLA섬유를 웹 형태로 집적하는 메쉬벨트; 상기 제 1 PLA섬유제조기 일측에 구비되어 상기 메쉬벨트 상에 집적된 PLA 섬유 상부에 펄프를 적층시키는 펄프공급부; 상기 펄프공급부의 일측에 구비되고, PLA를 섬유화시켜 상기 펄프의 상부에 웹 형태로 집적시키는 제 2 PLA섬유제조기; 상기 PLA섬유, 펄프, PLA섬유 순으로 적층된 적층물에 열을 가하여 상기 적층물들을 상호 열융착시키는 열융착부; 및 상기 제 1, 제 2 PLA섬유제조기, 메쉬벨트, 펄프공급부와 전기적으로 연결되어 상기 제 1, 제 2 PLA섬유제조기에서 제조되는 PLA섬유의 분사량을 제어하고, 상기 펄프공급부의 펄프공급량을 제어하며, 상기 메쉬벨트의 이송속도를 제어하는 제어부;를 포함하여 구성된다.Eco-friendly biodegradable nonwoven manufacturing apparatus according to an embodiment of the present invention provided to achieve the above object is a first PLA fiber manufacturing apparatus for fiberizing PLA; A mesh belt provided at a lower portion of the first PLA fiber manufacturing machine to integrate the vertically injected PLA fiber into a web form; A pulp supply unit provided at one side of the first PLA fiber manufacturing machine to stack pulp on top of the PLA fiber integrated on the mesh belt; A second PLA fiber making machine provided on one side of the pulp supply unit and integrating PLA into a web form on top of the pulp; A heat fusion unit for heat-sealing the laminates by applying heat to the laminates stacked in order of the PLA fibers, pulp, and PLA fibers; And electrically connected to the first and second PLA fiber makers, the mesh belt and the pulp supply unit to control the injection amount of the PLA fiber produced in the first and second PLA fiber makers, and to control the pulp supply amount of the pulp supply unit. It is configured to include; a control unit for controlling the feed rate of the mesh belt.
상기 제 1, 제 2 PLA섬유제조기는 PLA(생분해성 폴리유산)를 용융 및 압출시키는 압출기와, 상기 압출기에서 용융된 PLA를 분사하는 수백 개의 작은 오리피스(Orifice)가 형성된 분사노즐과, 상기 분사노즐의 양옆에서 고압열풍을 분사하여 분사노즐에서 분사되는 PLA를 연신시키는 열풍기와, 상기 연신된 PLA를 냉각시키는 냉각기와, 상기 연신에 의해 결정된 PLA섬유를 절단하는 절단기와, 상기 절단된 PLA섬유를 분사하는 분사구를 포함하여 구성되는 것을 특징으로 한다.The first and second PLA fiber making machine is an extruder for melting and extruding PLA (biodegradable polylactic acid), a spray nozzle formed with hundreds of small orifices (orifice) for spraying the molten PLA in the extruder, and the injection nozzle A hot air fan for stretching PLA sprayed from the spray nozzle by spraying high-pressure hot air from both sides of the cooler, a cooler for cooling the stretched PLA, a cutter for cutting the PLA fiber determined by the stretching, and spraying the cut PLA fiber Characterized in that configured to include a jet.
상기 압출기와 분사노즐 사이에는 용융된 생분해성 폴리유산(Poly lactic acid; PLA)을 필터링하는 필터장치가 더 포함되는 것을 특징으로 한다.Between the extruder and the injection nozzle is characterized in that it further comprises a filter device for filtering the molten biodegradable polylactic acid (Poly lactic acid; PLA).
상기 압출기는 제 1 내지 제 5 영역으로 구획되고, 제 1 영역은 150∼160℃, 제 2 영역은 200∼210℃, 제 3 영역은 220∼230℃, 제 4 영역은 230∼240℃, 제 5 영역은 250∼260℃의 온도가 설정되는 것을 특징으로 한다.The extruder is divided into first to fifth regions, the first region is 150 to 160 ℃, the second region is 200 to 210 ℃, the third region is 220 to 230 ℃, the fourth region is 230 to 240 ℃, The five regions are characterized in that a temperature of 250 to 260 캜 is set.
상기 펄프공급부에는 시트 또는 매트로 이루어진 펄프섬유를 개별섬유로 분리시키는 소면기가 연결되는 것을 특징으로 한다.The pulp supply unit is characterized in that the carding machine for separating the pulp fibers consisting of sheets or mats into individual fibers are connected.
상기 제어부는 부직포 전체 중량에 대하여 10중량%∼40중량%의 PLA섬유가 분사되도록 제 1 PLA섬유제조기의 분사량을 제어하고, 부직포 전체 중량에 대하여 25중량%∼80중량%의 펄프가 공급되도록 펄프공급부의 공급량을 제어하며, 부직포 전체 중량에 대하여 10중량%∼40중량%의 PLA섬유가 분사되도록 제 2 PLA섬유제조기의 분사량을 제어하는 것을 특징으로 한다.The control unit controls the injection amount of the first PLA fiber manufacturing machine so that 10% by weight to 40% by weight of PLA fiber is sprayed with respect to the total weight of the nonwoven fabric, and pulp is supplied with 25% by weight to 80% by weight with respect to the total weight of the nonwoven fabric. It controls the supply amount of the supply unit, characterized in that for controlling the injection amount of the second PLA fiber manufacturing machine so that the PLA fiber of 10% by weight to 40% by weight relative to the total weight of the nonwoven fabric.
본 발명의 일 실시 예에 따른 친환경 생분해 부직포 제조방법은 PLA(생분해성 폴리유산)를 압출기(Extruder)에 넣어 용융시킨 다음 수백 개의 작은 오리피스(Orifice)가 형성된 방사 노즐을 통해 방사하고 상기 방사 노즐 양옆에서 고속으로 분사되는 고압 열풍으로 연신 및 냉각시켜 섬유화시키는 S10단계; 상기 섬유화된 PLA를 메쉬벨트 상에 웹(Web) 형태로 집적하는 S20단계; 상기 웹 형태로 집적된 PLA 위에 펄프를 적층시키는 S30단계; 상기 펄프 위에 상기 S10단계에서 섬유화된 PLA를 웹(Web) 형태로 집적하여 적층시키는 S40단계; 및 상기 적층된 PLA, 펄프, PLA을 열융착하여 결합시키는 S50단계;를 포함하여 제조된다.Eco-friendly biodegradable nonwoven fabric manufacturing method according to an embodiment of the present invention is put PLA (biodegradable polylactic acid) into an extruder (melt) and then spinning through a spinning nozzle formed with hundreds of small orifices (Orifice) and the sides of the spinning nozzle S10 step of stretching and cooling the fiber to high pressure hot air sprayed at high speed in; S20 step of integrating the fiberized PLA in the form of a web (Web) on the mesh belt; S30 step of laminating the pulp on the PLA integrated in the web form; S40 step of stacking the laminated fiber in the form of a web (Web) on the pulp in the step S10; And S50 step of bonding the laminated PLA, pulp, PLA by heat fusion bonding.
상기 압출기는 150∼160℃ 온도가 설정된 제 1 영역, 200∼210℃ 온도가 설정된 제 2 영역, 220∼230℃ 온도가 설정된 제 3 영역, 230∼240℃ 온도가 설정된 제 4 영역, 250∼260℃ 온도가 설정된 제 5 영역으로 구획되고, 상기 PLA는 제 1 내지 제 5 영역을 통과하여 완전용해가 이루어지는 것을 특징으로 한다.The extruder has a first region having a temperature of 150 to 160 ° C., a second region having a temperature of 200 to 210 ° C., a third region having a temperature of 220 to 230 ° C., a fourth region having a temperature of 230 to 240 ° C., and a 250 to 260 ° C. The temperature is divided into a fifth region is set, the PLA is characterized in that complete melting through the first to fifth regions.
그리고, 상기 S10단계에는 용융된 PLA를 필터링하는 단계가 더 포함되는 것을 특징으로 한다.And, the step S10 characterized in that it further comprises the step of filtering the molten PLA.
또한, 상기 PLA는 폴리-D-유산, 폴리-L-유산, D-유산과 L-유산의 공중합체로 이루어진 군으로부터 선택된 것을 특징으로 한다.In addition, the PLA is characterized in that selected from the group consisting of poly-D-lactic acid, poly-L-lactic acid, copolymers of D-lactic acid and L-lactic acid.
또한, 상기 PLA는 융점이 100℃∼180℃ 이고, 용융지수 75∼120g/10분이며, 용융밀도는 0.98 내지 2.24g/㎤(260℃) 범위의 특성을 갖는 것을 특징으로 한다.In addition, the PLA has a melting point of 100 ℃ to 180 ℃, the melt index is 75 to 120g / 10 minutes, the melt density is characterized in that it has a characteristic in the range of 0.98 to 2.24g / cm3 (260 ℃).
상기 펄프는 시트 또는 매트로 이루어진 펄프섬유를 소면기에 넣어 개별섬유로 분리시킨 것이 사용되는 것을 특징으로 한다.The pulp is characterized in that the pulp fibers made of a sheet or mat put into a carding machine and separated into individual fibers.
상기 PLA는 부직포 전체 중량의 10중량%∼80중량% 분사되어 집적되고, 상기 펄프는 부직포 전체 중량의 25중량%∼80중량% 공급되어 집적되는 것을 특징으로 한다. 좀 더 자세하게는 상기 PLA는 상기 S20단계에서 10중량%∼40중량% 분사되어 집적되고, 상기 S40단계에서 10중량%∼40중량% 분사되어 집적되는 것을 특징으로 한다. The PLA is sprayed and integrated 10% to 80% by weight of the total weight of the nonwoven fabric, the pulp is characterized in that the 25% to 80% by weight of the total weight of the nonwoven fabric is supplied. In more detail, the PLA is injected by 10% by weight to 40% by weight in the step S20 is integrated, it is characterized in that 10% by weight to 40% by weight is injected in the step S40.
본 발명의 일 실시 예에 따른 친환경 생분해 부직포는 상기의 제조방법에 의하여 메쉬벨트 상에 분사되어 웹 형태로 집적된 제 1 PLA섬유층; 상기 제 1 PLA섬유층 상부에 적층되는 펄프층; 상기 펄프층 상부에 분사되어 웹 형태로 집적된 제 2 PLA섬유층이 상호 열융착되어 결합되는 것을 특징으로 한다.Eco-friendly biodegradable nonwoven fabric according to an embodiment of the present invention is sprayed on the mesh belt by the manufacturing method of the first PLA fiber layer integrated in the form of a web; A pulp layer laminated on the first PLA fiber layer; The second PLA fiber layer which is sprayed on the pulp layer and integrated in a web form is thermally fused to each other.
본 발명의 실시 예는 생분해 특성을 갖는 펄프층 및 PLA층을 적층하여 제조함으로써 펄프층의 부드러운 특성과 흡수성과 부피감을 살리고, PLA층이 펄프층을 잡아주고 보호하여 실제 사용시 필요한 기계적 강도를 향상시키게 되어 제품의 품질을 향상시키는 효과가 있다. Embodiment of the present invention by manufacturing the laminated pulp layer and the PLA layer having biodegradation properties to utilize the soft properties and absorbency and volume of the pulp layer, PLA layer to hold and protect the pulp layer to improve the mechanical strength required in actual use It has the effect of improving the quality of the product.
또한, 펄프를 이용함으로써 제조비용을 절감시킬 수 있고, 폐기 후 100% 생분해가 이루어짐에 따라 환경문제를 유발시키지 않는 효과가 있다. In addition, it is possible to reduce the manufacturing cost by using the pulp, there is an effect that does not cause environmental problems as 100% biodegradation is made after disposal.
또한, 발암물질이나 위생에 해로운 물질을 방출하지 않고, 통기성과 청량감이 우수하여 위생성 및 안전성이 향상되는 효과가 있다. In addition, there is an effect that improves hygiene and safety because it is excellent in breathability and refreshing feeling without releasing carcinogens or substances harmful to hygiene.
또한, PLA층이 펄프층의 표면을 잡고 있어서 세척이 가능하고 이로 인하여 여러번 반복 사용할 수 있는 효과가 있다.In addition, the PLA layer can be washed by holding the surface of the pulp layer, which has the effect that can be used repeatedly.
도 1은 본 발명의 일 실시 예에 따른 친환경 생분해 부직포의 제조장치를 설명하기 위한 개략도.1 is a schematic diagram for explaining the eco-friendly biodegradable nonwoven fabric manufacturing apparatus according to an embodiment of the present invention.
도 2는 본 발명의 일 실시 예에 따른 친환경 생분해 부직포의 제조장치의 전체 구성을 설명하기 위한 블럭도.Figure 2 is a block diagram for explaining the overall configuration of the eco-friendly biodegradable nonwoven fabric manufacturing apparatus according to an embodiment of the present invention.
도 3은 본 발명의 일 실시 예에 따른 친환경 생분해 부직포의 제조장치에서 제 1, 제 2 PLA 섬유제조기의 구성을 설명하기 위한 블럭도.Figure 3 is a block diagram for explaining the configuration of the first, second PLA fiber manufacturing apparatus in an eco-friendly biodegradable nonwoven fabric manufacturing apparatus according to an embodiment of the present invention.
도 4는 본 발명의 일 실시 예에 따른 친환경 생분해 부직포의 제조방법을 설명하기 위한 순서도.Figure 4 is a flow chart for explaining a method for producing an eco-friendly biodegradable nonwoven fabric according to an embodiment of the present invention.
도 5는 본 발명의 일 실시 예에 따른 친환경 생분해 부직포를 도시한 단면도.Figure 5 is a cross-sectional view showing an eco-friendly biodegradable nonwoven fabric according to an embodiment of the present invention.
본 발명의 상기와 같은 목적, 특징 및 다른 장점들은 첨부도면을 참조하여 본 발명의 바람직한 실시 예를 상세히 설명함으로써 더욱 명백해질 것이다. 이하, 첨부된 도면을 참조하여 본 발명의 친환경 생분해 부직포 및 그 제조장치 및 제조방법을 상세히 설명하기로 한다. 본 명세서를 위해서, 도면에서의 동일한 참조번호들은 달리 지시하지 않는 한 동일한 구성 부분을 나타낸다.The above objects, features and other advantages of the present invention will become more apparent by describing the preferred embodiments of the present invention in detail with reference to the accompanying drawings. Hereinafter, with reference to the accompanying drawings will be described in detail the eco-friendly biodegradable non-woven fabric and its manufacturing apparatus and manufacturing method of the present invention. For the purposes of this specification, like reference numerals in the drawings denote like parts unless otherwise indicated.
도 1은 본 발명의 일 실시 예에 따른 친환경 생분해 부직포의 제조장치를 설명하기 위한 개략도이고, 도 2는 본 발명의 일 실시 예에 따른 친환경 생분해 부직포의 제조장치의 전체 구성을 설명하기 위한 블럭도이며, 도 3은 본 발명의 일 실시 예에 따른 친환경 생분해 부직포의 제조장치에서 제 1, 제 2 PLA 섬유제조기의 구성을 설명하기 위한 블럭도이다.1 is a schematic diagram for explaining an eco-friendly biodegradable nonwoven fabric manufacturing apparatus according to an embodiment of the present invention, Figure 2 is a block diagram for explaining the overall configuration of an eco-friendly biodegradable nonwoven fabric manufacturing apparatus according to an embodiment of the present invention. 3 is a block diagram for explaining the configuration of the first and second PLA fiber manufacturing apparatus in the apparatus for producing an eco-friendly biodegradable nonwoven fabric according to an embodiment of the present invention.
도 1, 도 2에 도시된 바와 같이 친환경 생분해 부직포의 제조장치는 제 1, 제 2 PLA섬유제조기(100,300), 펄프공급부(200), 메쉬벨트(400), 제어부(500), 열융착부(600)를 포함한다.As shown in Figure 1, Figure 2, the manufacturing apparatus of eco-friendly biodegradable nonwoven fabric is the first, second PLA fiber manufacturing apparatus (100,300), pulp supply unit 200, mesh belt 400, the control unit 500, heat-sealed portion ( 600).
먼저, 제 1, 제 2 PLA섬유제조기(100,300)는 도 3에 도시된 바와 같이 투입되는 PLA(생분해성 폴리유산)를 용융 및 압출시키는 압출기(110,310)와, 압출기에서 용융된 PLA를 분사하는 수백 개의 작은 오리피스(Orifice)가 형성된 분사노즐(130,330)과, 압출기와 분사노즐 사이에 구비되어 용융된 PLA를 필터링하는 필터장치(120,320)와, 분사노즐의 양옆에 구비되어 분사노즐로 분사되는 PLA을 연신시키는 열풍기(140,340)와, 연신된 PLA를 냉각시키는 냉각기(150,350)와, 연신에 의해 결정된 PLA섬유를 절단하는 절단기(160,360)와, 절단된 PLA섬유를 분사하는 분사구(170,370)를 포함하여 구성된다. 그리고, 분사구에는 제어부와 전기적으로 연결되어 분사되는 PLA섬유의 분사량을 조절하는 밸브(171,371)가 구비된다.First, the first and second PLA fiber makers 100 and 300 are extruders 110 and 310 for melting and extruding PLA (biodegradable polylactic acid) introduced as shown in FIG. 3, and hundreds of spraying molten PLA from the extruder. Injection nozzles 130 and 330 having two small orifices formed therein, filter devices 120 and 320 provided between the extruder and the injection nozzle to filter the molten PLA, and PLAs which are provided on both sides of the injection nozzles and sprayed by the injection nozzles. It comprises a hot air fan (140,340) for stretching, a cooler (150,350) for cooling the stretched PLA, cutters (160,360) for cutting the PLA fiber determined by the stretching, and injection holes (170,370) for spraying the cut PLA fiber do. And, the injection port is provided with valves (171, 371) for controlling the injection amount of the PLA fiber is electrically connected to the control unit.
여기서, 압출기(110,310)는 제 1 내지 제 5 영역으로 구획된다. 그리고, 구획된 제 1 영역은 150∼160℃, 제 2 영역은 200∼210℃, 제 3 영역은 220∼230℃, 제 4 영역은 230∼240℃, 제 5 영역은 250∼260℃의 온도가 각각 설정된다.Here, the extruders 110 and 310 are partitioned into first to fifth regions. Then, the partitioned first region is 150 to 160 캜, the second region is 200 to 210 캜, the third region is 220 to 230 캜, the fourth region is 230 to 240 캜 and the fifth region is 250 to 260 캜. Are set respectively.
그리고, 분사노즐(130,330)은 12~16cm당 0.88mm를 갖으며, 높은 속도분배를 갖는고온의 공기는 직경 0.1μ으로부터 500μ 사이의 다양한 필라멘트를 형성시킨다.The injection nozzles 130 and 330 have 0.88 mm per 12 to 16 cm, and high temperature air having a high velocity distribution forms various filaments between 0.1 μm and 500 μ in diameter.
제 1 PLA섬유제조기(100)와 제 2 PLA섬유제조기(300) 사이에는 펄프공급부(200)가 배치된다.The pulp supply unit 200 is disposed between the first PLA fiber maker 100 and the second PLA fiber maker 300.
펄프공급부(200)는 펄프를 직접 공급할 수도 있으나, 펄프공급부(200)에는 시트 또는 매트로 이루어진 펄프섬유를 개별섬유로 분리시키는 소면기(210)가 연결되어 시트 또는 매트로 이루어진 펄프섬유를 분리시킨 개별섬유의 펄프를 공급할 수도 있다. The pulp supply unit 200 may directly supply pulp, but the pulp supply unit 200 is connected to a carding machine 210 for separating the pulp fibers made of sheets or mats into individual fibers to separate pulp fibers made of sheets or mats. It is also possible to feed pulp of individual fibers.
그리고, 나란히 배치되는 제 1 PLA섬유제조기(100)와 펄프공급부(200)와, 제 2 PLA섬유제조기(300)의 하부에는 메쉬벨트(400)가 구비된다.Then, a mesh belt 400 is provided below the first PLA fiber maker 100 and the pulp supply unit 200 and the second PLA fiber maker 300 which are arranged side by side.
메쉬벨트(400)는 제 1 PLA섬유제조기(100)와, 펄프공급부(200)와, 제 2 PLA섬유제조기(300)에서 분사되는 제 1, 제 2 PLA섬유 및 펄프를 웹 형태로 집적하여 이송시킨다. The mesh belt 400 integrates and transports the first and second PLA fibers and pulp sprayed from the first PLA fiber maker 100, the pulp supply unit 200, and the second PLA fiber maker 300 in a web form. Let's do it.
그리고, 제 1 PLA섬유제조기(100)와, 펄프공급부(200)와, 제 2 PLA섬유제조기(300)는 각각 제어부(500)와 전기적으로 연결된다.The first PLA fiber maker 100, the pulp supply unit 200, and the second PLA fiber maker 300 are electrically connected to the control unit 500, respectively.
제어부(500)는 제 1 PLA섬유제조기(100)와, 펄프공급부(200)와, 제 2 PLA섬유제조기(300)의 밸브(171,220,371)를 제어하여 메쉬벨트(400) 상에 분사되는 제 1, 제 2 PLA섬유 및 펄프의 분사량을 제어하고 분사 시간차를 제어하여 제 1 PLA섬유가 가장 먼저 분사되게 하고, 제 1 PLA섬유 위에 펄프가 분사되게 하며, 펄프의 위에 제 2 PLA섬유가 분사되게 제어한다.The control unit 500 controls the valves 171, 220, 371 of the first PLA fiber maker 100, the pulp supply unit 200, and the second PLA fiber maker 300 to be sprayed onto the mesh belt 400. Control the injection amount of the second PLA fiber and pulp and control the injection time difference so that the first PLA fiber is sprayed first, the pulp is sprayed on the first PLA fiber, the second PLA fiber is sprayed on the pulp .
그리고, 메쉬벨트(400)의 일측에는 열융착부(600)가 구비된다.And, one side of the mesh belt 400 is provided with a heat-sealed portion 600.
열융착부(600)는 메쉬벨트(400)에 의해 안내되는 제 1 PLA섬유, 펄프, 제 2 PLA섬유 순으로 적층된 적층물이 통과되는 켈린더로 구성된다. 켈린더는 종이나 피륙에 윤을 내는 압착롤러로서 열이 가해진 상태에서 통과되는 적층물의 제 1 PLA섬유, 펄프, 제 2 PLA섬유를 상호 열융착시킨다. 이때, 켈린더에는 제 1 PLA섬유, 펄프, 제 2 PLA섬유의 결합력을 높이도록 무늬가 조각된다. The heat-sealed portion 600 is composed of a calendar through which the laminate laminated in the order of the first PLA fiber, pulp, the second PLA fiber guided by the mesh belt 400 is passed. The calendar is a compression roller that lubricates paper or paper, and heat-bonds the first PLA fibers, the pulp, and the second PLA fibers of the laminate to be passed in a state where heat is applied. At this time, the pattern is engraved on the calendar to increase the bonding force of the first PLA fiber, pulp, the second PLA fiber.
도 4는 본 발명의 일 실시 예에 따른 친환경 생분해 부직포의 제조방법을 설명하기 위한 순서도이다.Figure 4 is a flow chart for explaining a method for producing an eco-friendly biodegradable nonwoven fabric according to an embodiment of the present invention.
본 발명의 일 실시 예에 따른 친환경 생분해 부직포의 제조방법은 PLA(생분해성 폴리유산)를 압출기(Extruder)에 넣어 용융시킨 다음 수백 개의 작은 오리피스(Orifice)가 형성된 방사 노즐을 통해 방사하고, 방사 노즐 양옆에서 고속으로 분사되는 고압 열풍으로 연신 및 냉각시켜 섬유화시키는 S10단계; 섬유화된 PLA를 메쉬벨트 상에 웹(Web) 형태로 집적하는 S20단계; 웹 형태로 집적된 PLA 위에 펄프를 적층시키는 S30단계; 펄프 위에 상기 S10단계에서 섬유화된 PLA를 웹(Web) 형태로 집적하여 적층시키는 S40단계; 및 적층된 PLA, 펄프, PLA을 열융착하여 결합시키는 S50단계;를 포함하여 구성된다.According to an embodiment of the present invention, a method for manufacturing an eco-friendly biodegradable nonwoven fabric is formed by melting PLA (biodegradable polylactic acid) into an extruder and then spinning through a spinning nozzle in which hundreds of small orifices are formed, and spinning nozzles. S10 step of stretching and cooling the fiber by high pressure hot air sprayed at high speed from both sides; S20 step of integrating the fiberized PLA in the form of a web (Web) on the mesh belt; S30 step of laminating the pulp on the integrated PLA in the web form; S40 step of stacking the laminated fiber in the form of a web (Web) on the pulp in the step S10; It is configured to include; and laminated PLA, pulp, S50 step of bonding the PLA by thermal fusion.
S10단계는 제 1 PLA섬유제조기(100) 및 제 2 PLA 섬유제조기(200)에서 이루어진다. 먼저, 제 1 PLA섬유제조기(100)의 압출기(110)에 PLA(생분해성 폴리유산)를 넣어 용융시킨다. Step S10 is made in the first PLA fiber manufacturing machine 100 and the second PLA fiber manufacturing machine 200. First, PLA (biodegradable polylactic acid) is put into the extruder 110 of the first PLA fiber manufacturing machine 100 and melted.
여기서, PLA는 융점이 100∼180℃이고, 용융지수는 20∼40g/10분 수준이며, 용융밀도는 0.98 내지 2.24g/㎤(260℃) 범위의 특성을 갖는 것이 사용된다. 또한, PLA는 폴리-D-유산, 폴리-L-유산, D-유산과 L-유산의 공중합체로 이루어진 군으로부터 선택된 것이 사용된다.Here, PLA has a melting point of 100 to 180 ℃, the melt index is 20 to 40g / 10 minutes level, melt density of 0.98 to 2.24g / cm 3 (260 ℃) is used that has a characteristic range. In addition, PLA is used selected from the group consisting of poly-D-lactic acid, poly-L-lactic acid, copolymers of D-lactic acid and L-lactic acid.
그리고, 압출기(110)는 150∼160℃ 온도가 설정된 제 1 영역, 200∼210℃ 온도가 설정된 제 2 영역, 220∼230℃ 온도가 설정된 제 3 영역, 230∼240℃ 온도가 설정된 제 4 영역, 250∼260℃ 온도가 설정된 제 5 영역으로 구획되어 있다. The extruder 110 may include a first region having a temperature of 150 to 160 ° C., a second region having a temperature of 200 to 210 ° C., a third region having a temperature of 220 to 230 ° C., and a fourth region having a temperature of 230 to 240 ° C. It is partitioned into the 5th area | region set at 250-260 degreeC temperature.
따라서, PLA는 압출기(110)의 제 1 내지 제 5 영역을 통과하면서 완전용해가 이루어진다. Therefore, PLA is completely dissolved while passing through the first to fifth regions of the extruder 110.
이어, 완전용해가 이루어진 PLA는 필터장치(120)에 필터링되어 분사노즐(130)로 공급되고, 분사노즐(130)로 공급된 PLA는 수백 개의 작은 오리피스(Orifice)를 통해 분사된다. Subsequently, the completely dissolved PLA is filtered through the filter device 120 and supplied to the injection nozzle 130, and the PLA supplied to the injection nozzle 130 is injected through hundreds of small orifices.
이어, 분사된 PLA는 열풍기(140)에서 고속 분사하는 고압 열풍에 의해 연신되고 냉각기에 의해 냉각되어 섬유화된다. Subsequently, the injected PLA is stretched by the high pressure hot air sprayed at high speed by the hot air fan 140 and cooled by the cooler to be fiberized.
그리고 섬유화된 PLA는 절단기(160)에 절단되어 분사구(170)를 통해 분사된다. 이때, 분사구(170)로 분사되는 제 1 PLA섬유는 부직포 전체 중량에 대하여 10중량%∼40중량% 분사된다.And the fiberized PLA is cut through the cutter 160 is injected through the injection port 170. At this time, the first PLA fiber is injected into the injection port 170 is 10% by weight to 40% by weight relative to the total weight of the nonwoven fabric.
S20단계는 메쉬벨트(400) 상에 분사되는 제 1 PLA섬유를 웹 형태로 집적한다. 이때, Melt-Blown 방식에 의해 형성된 웹은 등방향구조(Isotrophic Formation)를 갖는다. 즉, 웹이 고온의 공기에 위해 형성되기 때문에 섬유가 기계방향과 기계 폭 방향으로 임의로 배열되고, 충분히 냉각된 상태가 아니어서 섬유 간 열 접착으로 상호 결합이 이루어진다.Step S20 integrates the first PLA fibers sprayed on the mesh belt 400 in the form of a web. In this case, the web formed by the Melt-Blown method has an isotrophic formation. That is, since the web is formed for hot air, the fibers are arbitrarily arranged in the machine direction and the machine width direction, and are not sufficiently cooled so that mutual bonding is achieved by thermal bonding between the fibers.
S30단계는 웹 형태로 집적되어 이송되는 제 1 PLA섬유 위에 펄프공급부(200)로부터 분사되는 펄프를 적층시킨다. 이때, 적층되는 펄프는 부직포 전체 중량에 대하여 25중량%∼80중량% 분사된다.Step S30 stacks the pulp sprayed from the pulp supply unit 200 on the first PLA fiber is integrated and transported in the form of a web. At this time, the laminated pulp is sprayed from 25% by weight to 80% by weight relative to the total weight of the nonwoven fabric.
S40단계는 펄프의 위에 제 2 PLA 섬유를 적층시킨다. 제 2 PLA 섬유는 제 2 PLA 섬유제조기(300)를 통해 S10단계와 동일한 방법으로 제조된다.In step S40, the second PLA fiber is laminated on the pulp. The second PLA fiber is manufactured in the same manner as step S10 through the second PLA fiber manufacturing machine (300).
보다 자세히 설명하면, 제 2 PLA섬유제조기(300)의 압출기(310)에 PLA가 투입되고, PLA는 압출기(310)의 제 1 내지 제 5 영역을 통과하면서 완전용해가 이루어진다. 그리고, 완전용해가 이루어진 PLA는 필터장치(320)에 필터링되어 분사노즐(330)로 공급되고 수백 개의 작은 오리피스(Orifice)를 통해 분사된다. 이어, 분사된 PLA는 열풍기(340)의 고압 열풍에 의해 연신되고 냉각기(350)에 의해 냉각되어 섬유화된다. 그리고, 섬유화된 PLA는 절단기(360)에 절단되어 분사구(370)를 통해 분사된다. 이때, 분사구(370)로 분사되는 제 2 PLA섬유는 부직포 전체 중량에 대하여 10중량% ∼40중량% 분사된다.In more detail, PLA is injected into the extruder 310 of the second PLA fiber maker 300, and PLA is completely dissolved while passing through the first to fifth regions of the extruder 310. And, the complete dissolved PLA is filtered to the filter device 320 is supplied to the injection nozzle 330 and injected through hundreds of small orifices (Orifice). Subsequently, the injected PLA is stretched by the high pressure hot air of the hot air blower 340 and cooled by the cooler 350 to be fiberized. And, the fiberized PLA is cut through the cutter 360 is injected through the injection hole 370. At this time, the second PLA fiber is injected into the injection hole 370 is 10% by weight to 40% by weight relative to the total weight of the nonwoven fabric.
이처럼 제 2 PLA섬유제조기(300)에서 제조되는 제 2 PLA섬유는 펄프의 위에 웹 형태로 집적된다.As described above, the second PLA fiber manufactured in the second PLA fiber maker 300 is integrated in a web form on the pulp.
S50단계는 메쉬벨트(400) 상에 제 1 PLA섬유, 펄프, 제 2 PLA섬유 순으로 적층된 적층물을 열융착부(600)에 통과시켜 적층물을 상호 열융착시킨다. In step S50, the laminate laminated in the order of the first PLA fiber, the pulp, and the second PLA fiber on the mesh belt 400 is passed through the heat-sealed portion 600 to thermally bond the laminate to each other.
상기의 제조방법으로 제조되는 친환경 생분해 부직포는 도 5에 도시된 바와 같이 메쉬벨트(400) 상에 분사되어 웹 형태로 집적된 제 1 PLA섬유층, 상기 제 1 PLA섬유층 상부에 적층되는 펄프층, 상기 펄프층 상부에 분사되어 웹 형태로 집적된 제 2 PLA섬유층을 포함한다. Eco-friendly biodegradable nonwoven fabric produced by the manufacturing method is sprayed on the mesh belt 400 as shown in Figure 5, the first PLA fiber layer integrated in the web form, the pulp layer laminated on the first PLA fiber layer, the It is injected onto the pulp layer and comprises a second PLA fiber layer integrated in the form of a web.
(실시 예 1)(Example 1)
메쉬벨트 상에 부직포 전체 중량에 대하여 10중량%가 분사되어 웹 형태로 집적된 제 1 PLA섬유층, 제 1 PLA섬유층 상부에 부직포 전체 중량에 대하여 80중량%가 분사되어 적층되는 펄프층, 펄프층 상부에 부직포 전체 중량에 대하여 10중량%가 분사되어 웹 형태로 집적된 제 2 PLA섬유층을 형성하고, 이를 상호 열융착하여 부직포를 제조하였다.10% by weight relative to the total weight of the nonwoven fabric on the mesh belt, the first pulp fiber layer integrated in the form of a web, the pulp layer, the upper pulp layer laminated 80% by weight relative to the total weight of the nonwoven fabric on the first PLA fiber layer 10 wt% of the total weight of the nonwoven fabric was sprayed on to form a second PLA fiber layer integrated in a web form, and the non-woven fabric was manufactured by heat-sealing them.
(실시 예 2)(Example 2)
메쉬벨트 상에 부직포 전체 중량에 대하여 25중량%가 분사되어 웹 형태로 집적된 제 1 PLA섬유층, 제 1 PLA섬유층 상부에 부직포 전체 중량에 대하여 50중량%가 분사되어 적층되는 펄프층, 펄프층 상부에 부직포 전체 중량에 대하여 25중량%가 분사되어 웹 형태로 집적된 제 2 PLA섬유층을 형성하고, 이를 상호 열융착하여 부직포를 제조하였다.25% by weight of the total weight of the nonwoven fabric is sprayed onto the mesh belt, and the pulp layer and the pulp layer are stacked by spraying 50% by weight of the total weight of the nonwoven fabric on the first PLA fiber layer and the first PLA fiber layer. 25 wt% of the total weight of the nonwoven fabric was sprayed on to form a second PLA fiber layer integrated in a web form, and the nonwoven fabric was manufactured by heat-sealing them.
(실시 예 3)(Example 3)
메쉬벨트 상에 부직포 전체 중량에 대하여 40중량%가 분사되어 웹 형태로 집적된 제 1 PLA섬유층, 제 1 PLA섬유층 상부에 부직포 전체 중량에 대하여 25중량%가 분사되어 적층되는 펄프층, 펄프층 상부에 부직포 전체 중량에 대하여 40중량%가 분사되어 웹 형태로 집적된 제 2 PLA섬유층을 형성하고, 이를 상호 열융착하여 부직포를 제조하였다.40% by weight relative to the total weight of the nonwoven fabric on the mesh belt, the first pulp fiber layer integrated in the form of a web, the pulp layer, pulp layer laminated by 25% by weight relative to the total weight of the nonwoven fabric on the first PLA fiber layer 40 wt% of the total weight of the nonwoven fabric was sprayed on to form a second PLA fiber layer integrated in a web form, and a nonwoven fabric was manufactured by thermally bonding them together.
(비교 예 1)(Comparative Example 1)
메쉬벨트 상에 부직포 전체 중량에 대하여 45중량%가 분사되어 웹 형태로 집적된 제 1 PLA섬유층, 제 1 PLA섬유층 상부에 부직포 전체 중량에 대하여 10중량%가 분사되어 적층되는 펄프층, 펄프층 상부에 부직포 전체 중량에 대하여 45중량%가 분사되어 웹 형태로 집적된 제 2 PLA섬유층을 형성하고, 이를 상호 열융착하여 부직포를 제조하였다.45% by weight relative to the total weight of the nonwoven fabric on the mesh belt, the pulp layer, pulp layer is laminated by spraying 10% by weight relative to the total weight of the nonwoven fabric on the first PLA fiber layer, the first PLA fiber layer integrated in the web form 45 wt% of the nonwoven fabric was sprayed on to form a second PLA fiber layer integrated in a web form, and the nonwoven fabric was thermally fused to each other.
(비교 예 2)(Comparative Example 2)
펄프20 중량%와 폴리 에틸렌(PE) 40중량%와, 폴리 프로필렌(PP) 40중량%를 혼합하고 복합분사하여 부직포를 제조하였다.20% by weight of pulp, 40% by weight of polyethylene (PE), and 40% by weight of polypropylene (PP) were mixed and composite sprayed to prepare a nonwoven fabric.
<시험 1><Test 1>
실시 예 1, 2, 3 및 비교 예 1, 2의 부직포 각각에 대하여 부드러움, 부피감, 흡수성을 평가하여 [표 1]에 나타내었다.Softness, volume, and water absorption were evaluated for each of the nonwoven fabrics of Examples 1, 2, and 3 and Comparative Examples 1 and 2, and are shown in [Table 1].
표 1
실시 예 1 실시 예 2 실시 예 3 비교 예 1 비교 예 2
부드러움 ×
부피감
흡수성 ×
Table 1
Example 1 Example 2 Example 3 Comparative Example 1 Comparative Example 2
Soft ×
Bulky
Absorbency ×
[표 1]에 나타낸 바와 같이 실시 예 1, 2, 3은 제 1 PLA섬유층과 제 2 PLA섬유층이 펄프층의 외면을 감싸서 펄프층을 보호하고, 펄프가 깨지거나 분진이 날리지 않게 펄프를 잡아주는 역할을 하였다. 또한, 펄프층으로 인하여 적당한 부피감을 유지시키는 것을 알 수 있었고, 부드러운 감촉을 느낄 수 있었으며, 흡수성이 우수함을 알 수 있었다. As shown in Table 1, Examples 1, 2, and 3 show that the first PLA fiber layer and the second PLA fiber layer wrap the outer surface of the pulp layer to protect the pulp layer, and hold the pulp without breaking the pulp or dust. Played a role. In addition, it could be seen that due to the pulp layer to maintain a proper sense of volume, it was able to feel a soft texture, excellent absorbency.
비교 예 1은 제 1 PLA섬유층과 제 2 PLA섬유층이 너무 두껍게 형성되어 제 1 PLA섬유층과 제 2 PLA섬유층의 부서짐이 발생하였고, 감촉이 거칠었으며, 부피감과 흡수성이 양호하지 못하였다. 즉, 제 1 PLA섬유층과 제 2 PLA섬유층은 각각 부직포 전체 중량에 대하여 40중량% 이하가 사용되는 것이 바람직함을 알 수 있었다. In Comparative Example 1, the first PLA fiber layer and the second PLA fiber layer were formed so thick that the breakage of the first PLA fiber layer and the second PLA fiber layer occurred, the texture was rough, and the volume and absorbency were not good. That is, it can be seen that the first PLA fiber layer and the second PLA fiber layer is preferably used 40% by weight or less based on the total weight of the nonwoven fabric.
또한, 비교 예 2는 부피감과 감촉이 실시 예들에 비하여 떨어졌으며, 흡수성도 양호하지 못하였다.In addition, Comparative Example 2 was inferior in volume and feel compared to the examples, and the absorbency was also not good.
<시험 2> <Test 2>
실시 예 1, 2, 3 및 비교 예 1, 2의 부직포 각각에 대하여 내환경성을 평가하였다. 즉, 부직포가 땅에 매립되었을 때와 동일한 환경의 조건으로 시간경과 전, 50시간(hr)과 75시간(hr) 경과 한 부직포의 전면에서 스프레이를 하여 부직포의 상태를 측정하여 [표 2]에 나타내었다.Environmental resistance was evaluated about each of the nonwoven fabrics of Examples 1, 2 and 3 and Comparative Examples 1 and 2. That is, the state of the nonwoven fabric is measured by spraying the front surface of the nonwoven fabric 50 hours (hr) and 75 hours (hr) before the time elapsed under the same conditions as when the nonwoven fabric is buried in the ground. Indicated.
표 2
실시 예 1 실시 예 2 실시 예 3 비교 예 1 비교 예 2
Force (N) ELong (%) Force (N) ELong (%) Force (N) ELong (%) Force (N) ELong (%) Force (N) ELong (%)
시간경과전 20.5 35.6 23.5 27.6 25.2 28.9 5.1 8.0 19.2 31.6
50시간경과 12.9 6.5 15.9 8.5 16.3 12.0 3.5 4.0 9.0 21.0
75시간경과 측정불가 측정불가 측정불가 측정불가 5.9 9.5
TABLE 2
Example 1 Example 2 Example 3 Comparative Example 1 Comparative Example 2
Force (N) ELong (%) Force (N) ELong (%) Force (N) ELong (%) Force (N) ELong (%) Force (N) ELong (%)
Before time-lapse 20.5 35.6 23.5 27.6 25.2 28.9 5.1 8.0 19.2 31.6
50 hours 12.9 6.5 15.9 8.5 16.3 12.0 3.5 4.0 9.0 21.0
75 hours Not measurable Not measurable Not measurable Not measurable 5.9 9.5
[표 2]에 나타낸 바와 같이 실시 예 1은 제조된 부직포의 시간경과 전 20.5N에서 연신률 35.6%를 나타내었고, 부직포의 50시간 경과 후 12.9N에서 연신률 6.5%을 나타내었으며, 부직포의 75시간 경과 후에는 펄프의 부식이 진행되고, 제 1 PLA섬유와 제 2 PLA 섬유는 생분해로 인한 부식이 진행되어 측정이 불가하였다. As shown in Table 2, Example 1 exhibited an elongation of 35.6% at 20.5N before time elapsed of the manufactured nonwoven fabric, exhibited an elongation of 6.5% at 12.9N after 50 hours of nonwoven fabric, and 75 hours of nonwoven fabric. After the corrosion of the pulp proceeds, the first PLA fibers and the second PLA fibers were corrosion due to biodegradation was unable to measure.
그리고, 실시 예 2는 제조된 부직포의 시간경과 전 23.5N에서 연신률 27.6%를 나타내었고, 부직포의 50시간 경과 후 15.9N에서 연신률 8.5%을 나타내었으며, 부직포의 75시간 경과 후에는 펄프의 부식이 진행되고, 제 1 PLA섬유와 제 2 PLA 섬유는 부식의 진행으로 인한 찢어짐이 발생하여 측정이 불가하였다. In addition, Example 2 exhibited an elongation of 27.6% at 23.5 N before time elapsed of the manufactured nonwoven fabric, an elongation of 8.5% at 15.9 N after 50 hours of nonwoven fabric, and corrosion of pulp after 75 hours of nonwoven fabric. In progress, the first PLA fibers and the second PLA fibers were torn due to the progress of the corrosion was not possible to measure.
그리고, 실시 예 3은 제조된 부직포의 시간경과 전 25.2N에서 연신률 28.9%를 나타내었고, 부직포의 50시간 경과 후 16.3N에서 연신률 12.0%을 나타내었으며, 부직포의 75시간 경과 후 펄프의 부식이 진행되고, 제 1 PLA섬유와 제 2 PLA 섬유는 부식이 진행으로 인한 찢어짐이 발생하여 측정이 불가하였다. In addition, Example 3 exhibited an elongation of 28.9% at 25.2N before the time-lapse of the manufactured nonwoven fabric, an elongation of 12.0% at 16.3N after 50 hours of nonwoven fabric, and corrosion of the pulp progressed after 75 hours of nonwoven fabric. The first PLA fibers and the second PLA fibers were torn due to the progress of corrosion, and thus could not be measured.
그리고, 비교 예 1은 제조된 부직포의 시간경과 전 5.1N에서 연신률 8.0%를 나타내었고, 부직포의 50시간 경과 후 3.5N에서 연신률 4.0%을 나타내었으며, 부직포의 75시간 경과 후 펄프의 부식이 진행되고, 제 1 PLA섬유와 제 2 PLA 섬유는 부서짐으로 인하여 측정이 불가하였다.In Comparative Example 1, the elongation was 8.0% at 5.1N before the time elapsed of the manufactured nonwoven fabric, the elongation was 4.0% at 3.5N after 50 hours of nonwoven fabric, and the corrosion of the pulp progressed after 75 hours of nonwoven fabric. The first PLA fiber and the second PLA fiber could not be measured due to the breakage.
그리고, 비교 예 2는 제조된 부직포의 시간경과 전 19.2N에서 연신률 31.6%를 나타내었고, 부직포의 50시간 경과 후 9.0N에서 연신률 21.0%을 나타내었으며, 부직포의 75시간 경과 후 5.9N에서 연신률 9.5%를 나타내었다. 즉, 펄프의 부식은 진행되었으나, 폴리 에틸렌(PE)과, 폴리 프로필렌(PP)이 그대로 존재하였다.In Comparative Example 2, the elongation was 31.6% at 19.2N before the time elapsed of the manufactured nonwoven fabric, the elongation was 21.0% at 9.0N after 50 hours of nonwoven fabric, and the elongation was 9.5 at 5.9N after 75 hours of nonwoven fabric. % Is indicated. That is, the corrosion of the pulp proceeded, but polyethylene (PE) and polypropylene (PP) were present as they were.
이와 같이 본 발명은 생분해 특성을 갖는 펄프층 및 PLA층을 적층함으로써 펄프층의 부드러운 특성과 흡수성과 부피감이 향상되고, PLA층이 펄프층을 잡아주고 보호하게 되어 실제 사용시 필요한 기계적 강도가 향상된다.As such, the present invention improves the soft properties, absorbency and volume of the pulp layer by laminating the pulp layer and the PLA layer having biodegradable properties, and the PLA layer to hold and protect the pulp layer, thereby improving the mechanical strength required in actual use.
또한, 펄프를 이용함으로써 제조비용을 절감시킬 수 있고, 폐기 후 100% 생분해가 이루어짐에 따라 환경문제를 유발시키지 않게 된다.In addition, by using the pulp it is possible to reduce the manufacturing cost, and 100% biodegradation after disposal does not cause environmental problems.
또한, 발암물질이나 위생에 해로운 물질을 방출하지 않고, 통기성과 청량감이 우수하여 위생성 및 안전성이 향상된다. In addition, without discharging a carcinogen or a substance harmful to hygiene, the hygiene and safety is improved by excellent breathability and refreshing feeling.
또한, PLA층이 펄프층의 표면을 잡고 있어서 세척이 가능하고 이로 인하여 여러번 반복 사용이 가능하게 된다.In addition, the PLA layer can be washed by holding the surface of the pulp layer, thereby enabling repeated use several times.
[부호의 설명][Description of the code]
100: 제 1 PLA섬유제조기 200: 펄프공급부100: first PLA fiber manufacturing machine 200: pulp supply unit
210: 소면기 300: 제 2 PLA섬유제조기210: carding machine 300: second PLA fiber manufacturing machine
110,310: 압출기 120,320: 필터장치110,310: Extruder 120,320: Filter device
130,330: 분사노즐 140,340: 열풍기130,330: injection nozzle 140,340: hot air fan
150,350: 냉각기 160,360: 절단기150,350: cooler 160,360: cutter
170,370: 분사구 171,220,371: 밸브170,370: nozzle 171,220,371: valve
400: 메쉬벨트 500: 제어부400: mesh belt 500: control unit
600: 열융착부600: heat seal

Claims (15)

  1. PLA를 섬유화시키는 제 1 PLA섬유제조기;A first PLA fiber maker for fiberizing PLA;
    상기 제 1 PLA섬유제조기의 하부에 구비되어 수직 분사되는 PLA섬유를 웹 형태로 집적하는 메쉬벨트;A mesh belt provided at a lower portion of the first PLA fiber manufacturing machine to integrate the vertically injected PLA fiber into a web form;
    상기 제 1 PLA섬유제조기 일측에 구비되어 상기 메쉬벨트 상에 집적된 PLA 섬유 상부에 펄프를 적층시키는 펄프공급부;A pulp supply unit provided at one side of the first PLA fiber manufacturing machine to stack pulp on top of the PLA fiber integrated on the mesh belt;
    상기 펄프공급부의 일측에 구비되고, PLA를 섬유화시켜 상기 펄프의 상부에 웹 형태로 집적시키는 제 2 PLA섬유제조기; A second PLA fiber making machine provided on one side of the pulp supply unit and integrating PLA into a web form on top of the pulp;
    상기 PLA섬유, 펄프, PLA섬유 순으로 적층된 적층물에 열을 가하여 상기 적층물들을 상호 열융착시키는 열융착부; 및A heat fusion unit for heat-sealing the laminates by applying heat to the laminates stacked in order of the PLA fibers, pulp, and PLA fibers; And
    상기 제 1, 제 2 PLA섬유제조기, 펄프공급부와 전기적으로 연결되어 상기 제 1, 제 2 PLA섬유제조기에서 제조되는 PLA섬유의 분사량을 제어하고, 상기 펄프공급부의 펄프공급량을 제어하는 제어부;A control unit electrically connected to the first and second PLA fiber makers and the pulp supply unit to control the injection amount of the PLA fiber produced by the first and second PLA fiber makers and to control the pulp supply amount of the pulp supply unit;
    를 포함하는 친환경 생분해 부직포 제조장치.Eco-friendly biodegradable nonwoven manufacturing apparatus comprising a.
  2. 제 1 항에 있어서,The method of claim 1,
    상기 제 1, 제 2 PLA섬유제조기는 PLA(생분해성 폴리유산)를 용융 및 압출시키는 압출기와, 상기 압출기에서 용융된 PLA를 분사하는 수백 개의 작은 오리피스(Orifice)가 형성된 분사노즐과, 상기 분사노즐의 양옆에서 고압열풍을 분사하여 분사노즐에서 분사되는 PLA를 연신시키는 열풍기와, 상기 연신된 PLA를 냉각시키는 냉각기와, 상기 연신에 의해 결정된 PLA섬유를 절단하는 절단기와, 상기 절단된 PLA섬유를 분사하는 분사구를 포함하여 구성되는 것을 특징으로 하는 친환경 생분해 부직포 제조장치.The first and second PLA fiber making machine is an extruder for melting and extruding PLA (biodegradable polylactic acid), a spray nozzle formed with hundreds of small orifices (orifice) for spraying the molten PLA in the extruder, and the injection nozzle A hot air fan for stretching PLA sprayed from the spray nozzle by spraying high-pressure hot air from both sides of the cooler, a cooler for cooling the stretched PLA, a cutter for cutting the PLA fiber determined by the stretching, and spraying the cut PLA fiber Eco-friendly biodegradable nonwoven fabric manufacturing apparatus characterized in that it comprises a nozzle to.
  3. 제 2 항에 있어서,The method of claim 2,
    상기 압출기와 분사노즐 사이에는 용융된 PLA를 필터링하는 필터장치가 더 포함되는 것을 특징으로 하는 친환경 생분해 부직포 제조장치.Eco-friendly biodegradable nonwoven fabric manufacturing apparatus, characterized in that further comprising a filter device for filtering the molten PLA between the extruder and the injection nozzle.
  4. 제 2 항에 있어서,The method of claim 2,
    상기 압출기는 제 1 내지 제 5 영역으로 구획되고, 제 1 영역은 150∼160℃, 제 2 영역은 200∼210℃, 제 3 영역은 220∼230℃, 제 4 영역은 230∼240℃, 제 5 영역은 250∼260℃의 온도가 설정되는 것을 특징으로 하는 친환경 생분해 부직포 제조장치.The extruder is divided into first to fifth regions, the first region is 150 to 160 ℃, the second region is 200 to 210 ℃, the third region is 220 to 230 ℃, the fourth region is 230 to 240 ℃, Eco-friendly biodegradable nonwoven fabric production apparatus, characterized in that the five areas are set the temperature of 250 ~ 260 ℃.
  5. 제 1 항에 있어서,The method of claim 1,
    상기 펄프공급부에는 시트 또는 매트로 이루어진 펄프섬유를 개별섬유로 분리시키는 소면기가 연결되는 것을 특징으로 하는 친환경 생분해 부직포 제조장치.The pulp supply unit is an eco-friendly biodegradable nonwoven fabric manufacturing apparatus, characterized in that the carding machine for separating the pulp fibers made of a sheet or mat into individual fibers are connected.
  6. 제 1 항에 있어서,The method of claim 1,
    상기 제어부는 부직포 전체 중량에 대하여 10중량%∼40중량%의 PLA섬유가 분사되도록 제 1 PLA섬유제조기의 분사량을 제어하고, 부직포 전체 중량에 대하여 25중량%∼80중량%의 펄프가 공급되도록 펄프공급부의 공급량을 제어하며, 부직포 전체 중량에 대하여 10중량%∼40중량%의 PLA섬유가 분사되도록 제 2 PLA섬유제조기의 분사량을 제어하는 것을 특징으로 하는 친환경 생분해 부직포 제조장치.The control unit controls the injection amount of the first PLA fiber manufacturing machine so that 10% by weight to 40% by weight of PLA fiber is sprayed with respect to the total weight of the nonwoven fabric, and pulp is supplied with 25% by weight to 80% by weight with respect to the total weight of the nonwoven fabric. An eco-friendly biodegradable nonwoven fabric manufacturing apparatus characterized by controlling the supply amount of the supply, and controlling the injection amount of the second PLA fiber manufacturing machine so that the PLA fiber of 10% by weight to 40% by weight relative to the total weight of the nonwoven fabric.
  7. PLA(생분해성 폴리유산)를 압출기(Extruder)에 넣어 용융시킨 다음 수백 개의 작은 오리피스(Orifice)가 형성된 방사 노즐을 통해 방사하고 상기 방사 노즐 양옆에서 고속으로 분사되는 고압 열풍으로 연신 및 냉각시켜 섬유화시키는 S10단계; PLA (biodegradable polylactic acid) is put into an extruder and melted, and then spun through a spinning nozzle formed with hundreds of small orifices and drawn and cooled by high-pressure hot air sprayed at high speed from both sides of the spinning nozzle. Step S10;
    상기 섬유화된 PLA를 메쉬벨트 상에 웹(Web) 형태로 집적하는 S20단계; S20 step of integrating the fiberized PLA in the form of a web (Web) on the mesh belt;
    상기 웹 형태로 집적된 PLA 위에 펄프를 적층시키는 S30단계; S30 step of laminating the pulp on the PLA integrated in the web form;
    상기 펄프 위에 상기 S10단계에서 섬유화된 PLA를 웹(Web) 형태로 집적하여 적층시키는 S40단계; 및 S40 step of stacking the laminated fiber in the form of a web (Web) on the pulp in the step S10; And
    상기 적층된 PLA, 펄프, PLA을 열융착하여 결합시키는 S50단계;를 S50 step of thermally bonding the laminated PLA, pulp, PLA;
    포함하는 친환경 생분해 부직포 제조방법.Eco-friendly biodegradable nonwoven fabric containing method.
  8. 제 7 항에 있어서, The method of claim 7, wherein
    상기 압출기는 150∼160℃ 온도가 설정된 제 1 영역, 200∼210℃ 온도가 설정된 제 2 영역, 220∼230℃ 온도가 설정된 제 3 영역, 230∼240℃ 온도가 설정된 제 4 영역, 250∼260℃ 온도가 설정된 제 5 영역으로 구획되고, 상기 PLA는 제 1 내지 제 5 영역을 통과하여 완전용해가 이루어지는 것을 특징으로 하는 친환경 생분해 부직포 제조방법.The extruder has a first region having a temperature of 150 to 160 ° C., a second region having a temperature of 200 to 210 ° C., a third region having a temperature of 220 to 230 ° C., a fourth region having a temperature of 230 to 240 ° C., and a 250 to 260 ° C. Eco-friendly biodegradable non-woven fabric manufacturing method characterized in that partitioned into a fifth zone is set, the PLA is completely dissolved through the first to fifth zones.
  9. 제 7 항에 있어서, The method of claim 7, wherein
    상기 S10단계에는 용융된 PLA를 필터링하는 단계가 더 포함되는 것을 특징으로 하는 친환경 생분해 부직포 제조방법.The step S10 is eco-friendly biodegradable nonwoven fabric manufacturing method characterized in that it further comprises the step of filtering the molten PLA.
  10. 제 7 항에 있어서, The method of claim 7, wherein
    상기 PLA는 폴리-D-유산, 폴리-L-유산, D-유산과 L-유산의 공중합체로 이루어진 군으로부터 선택된 것을 특징으로 하는 친환경 생분해 부직포 제조방법.The PLA is an eco-friendly biodegradable nonwoven fabric manufacturing method, characterized in that selected from the group consisting of poly-D-lactic acid, poly-L-lactic acid, copolymers of D-lactic acid and L-lactic acid.
  11. 제 7 항에 있어서,The method of claim 7, wherein
    상기 PLA는 융점이 100℃∼180℃ 이고, 용융지수 75∼120g/10분이며, 용융밀도는 0.98 내지 2.24g/㎤(260℃) 범위의 특성을 갖는 것을 특징으로 하는 친환경 생분해 부직포 제조방법.The PLA has a melting point of 100 ℃ to 180 ℃, the melt index is 75 to 120 g / 10 minutes, melt density is 0.98 to 2.24 g / cm 3 (260 ℃) characterized in that the eco-friendly biodegradable non-woven fabric manufacturing method.
  12. 제 7 항에 있어서,The method of claim 7, wherein
    상기 펄프는 시트 또는 매트로 이루어진 펄프섬유를 소면기에 넣어 개별섬유로 분리시킨 것이 사용되는 것을 특징으로 하는 친환경 생분해 부직포 제조방법.The pulp is an eco-friendly biodegradable non-woven fabric manufacturing method characterized in that the pulp fibers made of a sheet or mat put into a carding machine and separated into individual fibers.
  13. 제 7 항에 있어서,The method of claim 7, wherein
    상기 PLA는 부직포 전체 중량의 10중량%∼80중량% 분사되어 집적되고, 상기 펄프는 부직포 전체 중량의 25중량%∼80중량% 공급되어 집적되는 것을 특징으로 하는 친환경 생분해 부직포 제조방법.The PLA is sprayed and integrated by 10% to 80% by weight of the total weight of the nonwoven fabric, the pulp is 25 to 80% by weight of the total weight of the nonwoven fabric is environmentally-friendly biodegradable nonwoven fabric manufacturing method characterized in that the supply.
  14. 제 13 항에 있어서,The method of claim 13,
    상기 PLA는 상기 S20단계에서 10중량%∼40중량% 분사되어 집적되고, 상기 S40단계에서 10중량%∼40중량% 분사되어 집적되는 것을 특징으로 하는 친환경 생분해 부직포 제조방법.Wherein the PLA is 10% by weight to 40% by weight injected in the step S20 integrated, the eco-friendly biodegradable nonwoven fabric manufacturing method characterized in that the 10% by weight to 40% by weight injected in the step S40.
  15. 제 7 항 내지 제 14 항 중 어느 한 항의 제조방법에 의하여, 메쉬벨트 상에서 웹 형태로 집적된 제 1 PLA섬유층; 상기 제 1 PLA섬유층 상부에 적층되는 펄프층; 상기 펄프층 상부에 분사되어 웹 형태로 집적된 제 2 PLA섬유층이 상호 열융착되어 제조되는 것을 포함하는 친환경 생분해 부직포.The first PLA fiber layer integrated in the form of a web on the mesh belt by the manufacturing method of any one of claims 7 to 14; A pulp layer laminated on the first PLA fiber layer; Eco-friendly biodegradable nonwoven fabric comprising a second PLA fiber layer is sprayed on the pulp layer integrated in the form of a web is manufactured by mutual heat-sealing.
PCT/KR2015/007071 2014-07-14 2015-07-08 Environment-friendly and biodegradable non-woven fabric, and apparatus and method for producing same WO2016010297A1 (en)

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