WO2015185373A1

WO2015185373A1 - Novel blend

Info

Publication number: WO2015185373A1
Application number: PCT/EP2015/061322
Authority: WO
Inventors: Jochen Klock; Goede Schueler; Volker Rosenberger; Alexander Radspieler
Original assignee: Dsm Ip Assets B.V.
Priority date: 2014-06-06
Filing date: 2015-05-21
Publication date: 2015-12-10

Abstract

The present invention relates to a blend comprising saccharide isomerate, water, citric acid, sodium citrate and an acrylic emulsion polymer obtainable by emulsion polymerization of a monomer composition consisting of a mixture of methacrylic acid, ethyl acrylate and n-butyl methacrylate and optionally panthenol. The premixed blend is particularly suitable for the incorporation into skin cleansing formulations to impart a smooth and soft skin feel.

Description

Novel blend

The present invention relates to a blend comprising saccharide isomerate, water, citric acid, sodium citrate and an acrylic emulsion polymer obtainable by emulsion polymerization of a monomer composition consisting of a mixture of methacrylic acid, ethyl acrylate and n-butyl methacrylate and optionally panthenol. The premixed blend is particularly suitable for the incorporation into skin cleansing formulations to impart a smooth and soft skin feel. Today many consumer goods companies are seeking for premixed blends of cosmetic raw materials with distinct properties in order to facilitate their handling and compounding. Such blends, however, not only have to fulfill the requirements in view of cosmetic performance but also in view of their stability such as e.g. the avoidance of an unwanted discoloration upon blending.

Surprisingly it has been found that a specific premixed blend consisting essentially of saccharide isomerate, water, citric acid, sodium citrate, an acrylic emulsion polymer obtainable by emulsion polymerization of a monomer composition consisting of a mixture of methacrylic acid, ethyl acrylate and n-butyl methacrylate and optionally panthenol is able to provide a smooth and soft skin feel when applied to the skin in a topical composition.

It has additionally be found that this specific premixed blend is only stable against discoloration if the acrylic emulsion polymer is not neutralized with an amine such as 2-amino-2-methyl-1 -propanol incorporated (AMP).

Thus in a first embodiment the present invention relates to a blend consisting essentially of a. ) water,

b. ) an acrylic emulsion polymer obtainable by emulsion polymerization of a monomer composition consisting of a mixture of methacrylic acid, ethyl acrylate and n-butyl methacrylate,

c. ) saccaride isomerate,

d. ) citric acid,

e. ) sodium citrate,

f. ) 0 to 10 wt.-% of panthenol and g.) 0 to 1 wt.-% of a preservative.

with the proviso that the acrylic emulsion polymer is incorporated into the blend either non-neutralised or neutralized with a neutralizing agent which is not an amine. In a preferred embodiment the blend consists essentially of

a. ) 35 to 60 wt.-% of water,

b. ) 15 to 30 wt.-% of the acrylic emulsion polymer,

c. ) 10 to 30 wt.-% saccharide isomerate,

d. ) 0.01 to 1 .0 wt.-% citric acid,

e.) 0.01 to 1 .0 wt.-% sodium citrate,

f. ) 0 to 10 wt.-% of panthenol and

g. ) 0 to 1 wt.-% of a preservative.

In an even more preferred embodiment the blend consists essentially of

a.) 40 to 55 wt.-% of water,

b. ) 20 to 30 wt.-% of the acrylic emulsion polymer,

c. ) 15 to 25 wt.-% saccharide isomerate,

d. ) 0.02 to 0.5 wt.-% citric acid,

e. ) 0.02 to 0.5 wt.-% sodium citrate,

f.) 0 to 8 wt.-% of panthenol, and

g.) 0 to 1 wt.-% of a preservative.

It is well understood that the sum of all ingredients in the blend sums up to 100 wt.-%. If panthenol is present, the amount is preferably selected in the range of 5 to 10 wt.-%, such as more preferably in the range of 6 to 8 wt.-% based on the total weight of the blend.

If a preservative is present the amount is preferably selected in the range of 0 to 50 ppm such as preferably in the range of 10 to 50 ppm.

Saccaride isomerate is a well-known agent with unique binding mechanism to the skin used for short and long-lasting moisturization consisting mainly of glucose, fructose mannose and galactose. Saccaride isomerate is e.g. commercially available under the trademark name PENTAVITIN^® from DSM Nutritional Products Ltd. Panthenol (CAS 81 -13-0) is available as D-Panthenol or DL-Panthenol from DSM Nutritional Products Ltd.

The acrylic emulsion polymers according to the invention are prepared by emulsion polymerization methods according to known methods as e.g. described in EP10193512.0 which is included herein by reference.

The method of free-radically initiated aqueous emulsion polymerization has been described previously on many occasions and is therefore sufficiently known to the person skilled in the art [cf. e.g. Encyclopedia of Polymer Science and Engineering, Vol. 8, pages 659 to 677, John Wiley & Sons, Inc., 1987; D. C. Blackley, Emulsion Polymerization, pages 155 to 465, Applied Science Publishers, Ltd., Essex, 1975; D. C. Blackley, Polymer Latices, 2.sup.nd Edition, Vol. 1 , pages 33 to 415, Chapman & Hall, 1997; H. Warson, The Applications of Synthetic Resin Emulsions, pages 49 to 244 , Ernest Ben n , Ltd . , London, 1972; D. Diederich, Chemie in unserer Zeit [Chemistry of our Time] 1990, 24, pages 135 to 142, Verlag Chemie, Weinheim; J. Piirma, Emulsion Polymerization, pages 1 to 287, Academic Press, 1982; F. Holscher, Dispersionen synthetischer Hochpolymerer [Dispersions of Synthetic High Polymers], pages 1 to 1 60, Springer-Verlag, Berlin , 1969 and DE-A 40 03422]. The free-radically initiated aqueous emulsion polymerization is usually carried out by dispersely distributing the monomers, usually with co-use of dispersants, in the aqueous medium, and polymerizing using at least one free-radical polymerization initiator.

Suitable free-radical polymerization in itiators for the free-radical aqueous emulsion polymerization according to the invention are all those which are able to trigger a free- radical aqueous emulsion polymerization. These may in principle be either peroxides or azo compounds. Redox initiator systems are of course also suitable. Peroxides which may be used are, in principle, inorganic peroxides, such as hydrogen peroxide or peroxodisulfates, such as the mono- or di-alkali metal or ammonium salts of peroxide disulfuric acid, for example, its mono- and di-sodium, -potassium or ammonium salts or organic peroxides, such as alkyl hydroperoxides, for example tert-butyl, p-menthyl or cumyl hydroperoxide, tert-butyl perpivalate, and dialkyi or diaryl peroxides, such as di-tert-butyl or d i-cumyl peroxide, 2,5-dimethyl-2,5-di(t)butyl-peroxy(hexane) or dibenzoyl peroxide. The azo compounds used are essentially 2,2'-azobis(isobutyronitrile), 2,2'-azobis(2,4- dimethylvaleronitrile) and 2,2'-azobis(amidinopropyl) dihydrochloride (AIBA, corresponds to V-50.TM . from Wako Chemicals), 1 , 1 '-azobis(1 -cyclohexanecarbonitrile), 2,2'-azobis(2- amidinopropane)salts, 4,4'-azobis(4-cyanovaleric acid) or 2-(carbamoylazo)isobutyronitrile.

Suitable oxidizing agents for redox initiator systems are essentially the abovementioned peroxides. Corresponding reducing agents which may be used are sulfur compounds with a low oxidation state, such as alkali metal sulfites, for example potassium and/or sodium sulfite, alkali metal hydrogensulfites, for example potassium and/or sodium hydrogen sulfite, alkali metal metabisu lfites , for exam ple potassiu m and/or sod i u m metabisu lfite, formaldehyde sulfoxylates, for example potassium and/or sodium formaldehyde sulfoxylate, alkali metal salts, specifically potassium and/or sodium salts, of aliphatic sulfinic acids (i.e. Bruggolite^® FF6) and alkali metal hydrogen sulfides, such as, for example, potassium and/or sodium hydrogen sulfide, salts of polyvalent metals, such as iron(l l ) sulfate, iron(l l ) ammonium sulfate, iron(l l) phosphate, enediols, such as dihydroxymaleic acid, benzoin and/or (i-) ascorbic acid, and reducing saccharides, such as sorbose, glucose, fructose and/or dihydroxyacetone.

The initiators are usually used in amounts up to 10% by weight, preferably 0.02 to 5% by weight, based on the monomers to be polymerized.

Surfactants can be utilized in order to assist the dispersion of the polymer in water. Suitable surfactants include but are not limited to conventional anionic and/or non-ionic surfactants and mixtures thereof such as Na, K and N H₄ salts of dialkylsulphosuccinates, Na, K and NH₄ salts of sulphated oils, Na, K and N H₄ salts of alkyl sulphonic acids, Na, K and NH₄ alkyl sulphates, alkali metal salts of sulphonic acids; fatty alcohols, ethoxylated fatty acids and/or fatty amides, and Na, K and N H₄ salts of fatty acids such as Na stearate and Na oleate. Other anionic surfactants include alkyl or (alk)aryl groups linked to sulphonic acid groups, sulphuric acid half ester grou ps (linked in turn to polyglycol ether groups), phosphonic acid groups, phosphoric acid analogues and phosphates or carboxylic acid groups. Non-ionic surfactants include polyglycol ether compounds and preferably polyethylene oxide compounds as disclosed in "Non-Ionic Surfactants - Physical Chemistry" edited by M.J. Schick, M. Decker 1987. The amount of surfactant used is preferably 0 to 15 wt.-% by, more preferably 0 to 8 wt-%, still more preferably 0 to 5% wt.-%, especially 0.1 to 3 wt-% and most especially 0.3 to 2 wt-% on the total weight of vinyl monomers required.

Chain transfer agent may be added to control the molecular weight. Suitable chain transfer agents i n c l u d e m e r c a p t a n s s u c h a s n-dodecylmercaptan, n-octylmercaptan, t-dodecylmercaptan, mercaptoethanol, iso-octyl thioglycolate, C₂ to C₈ mercapto carboxylic acids and esters thereof such as 3-mercaptopropionic acid and 2-mercaptopropionic acid. Mixtures of two or more regulators may also be used. Preferably 0.05 to 5 wt-%, more preferably 0.1 to 3 wt-% and most preferably 0.1 to 1 wt-% of chain transfer agent based on the weight of vinyl monomers required is used. The alkanethiols are usually added to the polymerization together with the monomers.

If, in the polymerization, thiols are used, a subsequent hydrogen peroxide treatment could be required in order to obtain polymers with a neutral odor.

The emulsion polymerization usually takes place with the exclusion of oxygen, for example under a nitrogen or argon atmosphere, at temperatures in the range from 20 to 200°C. Polymerization temperatures in the range from 50 to 130°C, in particular 70 to 95°C are advantageous.

The polymerization can be carried out batch-wise, semi-continuously or continuously. The polymerization and the monomer and regulator feed are often carried out semi-continuously by the feed method . Preferably, at least some of the monomers, in itiators and , if appropriate, regulators are metered into the reaction vessel uniformly throughout the polymerization. However, it is also possible to have an initial charge of the monomers and the initiator in the reactor and to polymerize them, with cooling if appropriate. Another option is to carry out the polymerization using seed latex prepared from the polymers to be polymerized in the first polymerization phase. The remainder of the monomer mixture is added, preferably by the feed method.

The polymerization reaction advantageously takes place until the monomer conversion is >95% by weight, preferably >98% by weight or >99% by weight. It is often useful if the aqueous polymer dispersion obtained is subjected to an after- polymerization step in order to reduce further the amount of unreacted monomer. This measure is known to the person skilled in the art (for example EP-B 3957, EP-B 28348, EP- B 563726, EP-A 764699, EP-A 767180, DE-A 3718520, DE-A 3834734, DE-A4232194, DE- A 19529599, DE-A 19741 187, DE-A 19839199, DE-A 19840586, WO 95/33775 or U.S. Pat. No. 4,529,753). It is of course also possible to subject the aqueous polymer dispersion obtained to an inert-gas and/or steam stripping, likewise known to the person skilled in the art, before or after the after-polymerization step. This stripping operation preferably takes place after the after-polymerization step. As is described in EP-A 805169, partial neutralization of the dispersion to a pH in the range from 5 to 7, preferably to a pH in the range from 5.5 to 6.5, is advantageous before the physical deodorization.

If applicable, due to a low monomer content after preparation, these possible additional steps can be omitted and the dispersions can be further used as such providing an economical advantage.

In a preferred embodiment, the aqueous polymer dispersion obtained is subjected to a post initation (post treatment/ after-polymerization) using t-butyl hydroperoxide with iso-ascorbic acid or t-butyl hydroperoxide with aliphatic sulfinic acids (i.e. Bruggolite^® FF6) in water. Particular preferred is a post-treatment with t-butyl hydroperoxide with aliphatic sulfinic acids (i.e. Bruggolite^® FF6) as this reduces possible discoloration of the emulsion polymer as such or when dissolved in the end formulation.

Particularly preferred acrylic emulsion polymers according to the present invention are the ones obtainable by emulsion polymerisation of a monomer composition consisting essentially of 10-30 wt.-% of methacrylic acid, 5-15 wt.-% of ethyl acrylate and 60-80 wt.-% of n-butyl methacrylate, more preferably of 15-25 wt.-% of methacrylic acid, 8-12 wt.-% of ethyl acrylate and 65-75 wt.-% of n-butyl methacrylate, and most preferably of 18-23 wt.-% of methacrylic acid, 9-1 1 wt.-% of ethyl acrylate and 67-72 wt.-% of n-butyl methacrylate.

The term 'a monomer composition consisting essentially of as used according to the present invention means that the total amount of monomers ideally sum up to 100 wt.-%. It is however not excluded that small amounts of impurities or additives may be present in the monomer composition, with the proviso that the total amount of such impurities or additives is preferably less than 5 wt.-%, more preferably less than 3 wt.-% and which are e.g. introduced via the respective raw materials.

Furthermore, the acrylic emulsion polymers according to the present invention preferably have a molecular weight between 30-500 kDalton, more preferably 50 - 250 kDalton and most preferred between 75 and 200 kDalton such as in the range of 100 to 150 kDalton, and a glass transition temperature (Tg) between 40 and 140°C, more preferably between 55 and 130°C and most preferred between 70-120 °C such as e.g. between 70 and 100 °C. The acid value is preferably selected in the range of 100-200 mg KOH/g, such as preferably 120-180 mg KOH/g such as most preferably in the range of 140-160 mg KOH/g.

Advantageously the acrylic emulsion polymers according to the invention have a molecular weight between 75 -200 kDalton, an acid value in the range of 120-180 mg KOH/g and a Tg in the range of 70-120 °C such as in particular a molecular weight between 100-150 kDalton, an acid value in the range of 120-180 mg KOH/g and a Tg in the range of 70- 100 °C.

Preferably an aqueous dispersion of the acrylic emulsion polymer is used, more preferably the aqueous dispersion obtained from emulsion polymerization (eventually comprising a post treatment step) is used directly in the preparation of the blends according to the invention. It is well understood to a person skilled in the art that the amount of the aqueous dispersion to be added to the blend according to the present invention has to be adjusted based on the solid content (i.e. content of the acrylic emulsion polymer).

Preferably the aqueous dispersion used for the preparation of the blend according to the present invention has a solid content selected in the range of 30 to 50 wt.-% such as in the range of 35 to 45 wt.-% and a pH selected in the range of 2 to 3. A particularly suitable aqueous dispersion of an acrylic emulsion polymers according to the present invention is commercially available under the Tradename Tl LAMAR^® Fix A140 (I NCI: acrylates copolymer, Chemical Name: polymer with 2-methyl-2-propenoic acid, butyl 2-methyl-2-propenoate, and ethyl 2-propenoate, CAS Number: 26715-43-5) at DSM Nutritional Products Ltd. Suitable neutralization agents for the acrylic emulsion polymer encompass alkali metal hydroxides such as sodium hydroxide and potassium hydroxide. When the solid content of the acrylic emulsion polymer is > 30 wt.-% the acrylic emulsion polymer is preferably only neutralized after incorporation into the blend in order to avoid unwanted agglomeration of the polymer.

If the solid content of the acrylic emulsion polymer is < 30 wt.-% the acrylic emulsion polymer may advantageously be neutralized before incorporation into the blend.

I n a particularly preferred embodiment, the acrylic emulsion polymer is used without neutralization in the blend according to the present invention. The blend furthermore may contains a preservative in order to enhance the shelf life such as i n pa rticu la r a broad-spectrum bactericide. Advantageously the preservative is methylisothiazolinone [CAS 2682-20-4] and is used at a concentration level of about 1 wt- % or less, preferably at a concentration level of about 50ppm or less, such as at a concentration level of about 1 to 50ppm and in particular at a concentration level of about 30-50ppm, most particular in a concentration level of about 20-40ppm based on the total blend. Methylisothiazolinone is e.g. available as 9.5% methylisothiazolinone formulation in water as N EOLON E™ 950 at DOW. In a particular preferred embodiment the blend is however preservative free. In another embodiment the invention is directed to topical compositions comprising from 0.1 to 6 wt.-%, preferably 0.5 to 4 wt.-%, most preferably 1 to 3 wt.-% (based on the total weight of the topical composition) of the blend according to the present invention with all the preferences and embodiments as outlined above and a cosmetically acceptable carrier. I n an additional embodiment the present invention is directed to a process for the preparation of a topical compositions, which process encompasses the steps of mixing the blend according to the present invention with a cosmetically acceptable carrier. Preferably, the amount of the blend mixed with the cosmetically acceptable carrier is chosen in the range of 0.1 to 6 wt.-%, preferably 0.5 to 4 wt.-%, most preferably 1 to 3 wt.-%, based on the total weight of the topical composition.

The term cosmetically acceptable carrier refers to all carriers and/or excipients and/or diluents conventionally used in cosmetic compositions.

Preferably the topical compositions are in-shower formulation i.e. topical compositions to be applied to the skin and subsequently rinsed away such as skin cleansing compositions or in-shower skin conditioning compositions.

Skin cleansing formulations often contain substantial amounts of anionic surfactants to achieve effective cleansing, which, however, result in a sticky and unpleasant skin feel. It has now surprisingly be found that the blend according to the present invention is suitable to provide a soft and smooth skin feel when used in such skin cleansing formulations.

Thus, the invention also relates to skin cleansing compositions comprising at least one anionic surfactant and from 0.1 to 6 wt.-%, preferably 0.5 to 4 wt.-% such as most preferably 1 to 3 wt.-% .-% (based on the total weight of the skin cleansing composition) of the blend according to the present invention with all the preferences and embodiments as outlined above and a cosmetically acceptable carrier.

The skin cleansing compositions according to the invention preferably comprise from 50 to 90 wt.-%, more preferably from 60 to 80 wt.-% of water, based on the total weight of the skin cleansing compositions.

Particularly suitable skin cleansing formulations according to the invention are liquid soaps, shower gels as well as facial and body cleansers.

The pH of the liquid soaps, shower gels as well as facial and body cleansers is preferably selected in the range of 4.5 to 7 preferably in the range of 5.0 to 6.5.

Examples of suitable anionic surfactants are the alkyl sulfates, alkyl ether sulfates, alkylaryl sulphonates, alkanoyl isothionates, alkyl succinates, alkyl sulphosuccinates, alkyl ether sulphosuccinates, N-alkyl sarcosinates, alkyl phosphates, alkyl ether phosphates, and alkyl ether carboxylic acids and salts thereof, especially their sodium, magnesium, ammonium or mono-, di- or triethanolamine salts. The alkyl and acyl groups generally contain 8 to 18, preferably 10 to 16, carbon atoms and may be unsaturated. The alkyl ether sulfates, alkyl ether sulphosuccinates, alkyl ether phosphates and alkyl ether carboxylic acids and salts thereof may contain 1 to 20 ethylene oxide or propylene oxide units per molecule.

In particular, the anionic surfactants are selected from sodium oleyl succinate, ammonium lauryl sulphosuccinate, sodium lauryl sulfate, sodium lauryl ether sulfate (also known as sodium laureth sulfate, SLES), sodium lauryl ether sulphosuccinate, ammonium lauryl sulfate (ALS), ammonium lauryl ether sulfate (ammoniu m laureth su lfate), sodium dodecylbenzene sulphonate, triethanolamine dodecylbenzene sulphonate, sodium cocoyl isethionate, sodium lauryl isethionate, lauryl ether carboxylic acid and sodium N-lauryl sarcosinate or mixtures thereof. Preferred anionic surfactants are sodium lauryl sulfate, sodium lauryl ether sulfate (n) EO, (where n is from 1 to 4, in particular n is 3), sodium lauryl ether sulphosuccinate (n) EO, (where n is from 1 to 4, in particular n is 3), ammonium lauryl sulfate, ammonium lauryl ether sulfate (n) EO, (where n is from 1 to 4, in particular n is 3) or mixtures thereof.

In the skin cleansing composition of the present i nvention the anionic surfactant is preferably selected from sodium lauryl sulfate, ammonium lauryl sulfate, sodium lauryl ether sulfate, ammonium lauryl ether sulfate, sodium lauroyl sarconisate, sodium oleylsuccinate, ammonium lauryl sulfosuccinate, sodium dodecylbenzol sulfonate and/or triethanolamine dodecylbenzol sulfonate or mixtures thereof. Most preferably in all embodiments of the invention the anionic surfactant is selected from sodium lauryl sulfate, ammonium lauryl sulfate, sodium lauryl ether sulfate (also known as sodium Laureth sulfate) and/or ammonium lauryl ether sulfate. Particularly preferred in all embodiments of the invention is the use sodium lauryl ether sulfate e.g. available as Texapon^® NSO-BZ at Caelo.

Further suitable surfactants are sodium parethC12-13 sulfate and sodium myreth-sulfate sodium laureth-1 1 carboxylate and sodium laureth-6 carboxylate.

The total amount of the anionic surfactant(s) in the skin cleansing compositions according to the present invention is preferably selected in the range of 0.1 to 25 wt.-%, more preferably in the range of 2 to 20 wt.-%, most preferably in the range of 3.5 to 15 wt.-% such as in particular in the range of 3.5 to 7 wt.-% based on the total weight of the skin cleansing compositions.

The skin cleansing compositions according to the present invention preferably includes at least one co-surfactants.

Examples of co-surfactants are nonionic surfactants, which can be included in an amount ranging from 0.5 to 8 wt.-%, preferably from 2 to 5 wt.- % based on the total weight of the skin cleansing composition. For example, representative nonionic surfactants that can be included into skin cleansing compositions according to the invention include condensation products of aliphatic (C₈ - Ci₈) primary or secondary linear or branched chain alcohols with alkylene oxides, usually ethylene oxide and generally having from 6 to 30 ethylene oxide groups. Other representative nonionic surfactants include mono- or di-alkyl alkanolamides such as e.g. coco mono- or di- ethanolamide and coco mono-isopropanolamide. Further nonionic surfactants which can be included in skin cleansing compositions of the invention are the alkyl polyglycosides (APGs). Typically, the APG is one which comprises an alkyl group connected (optionally via a bridging group) to a block of one or more glycosyl groups such as e.g. Oramix™ NS 10 ex Seppic; PLANTACARE^® 818UP, PLANTACARE^® 1200 and PLANTACARE^® 2000 ex Cognis.

Another example of a co-surfactant is an amphoteric or zwitterionic surfactant, which can be included in an amount ranging from 0.5 to about 8 wt.-%, preferably from 1 to 5 wt.-% most preferably in the range of 1 to 2 wt.-% based on the total weight of the skin cleansing composition. Examples of amphoteric or zwitterionic surfactants include alkyl amine oxides, alkyl betaines, alkyl amidopropyl betaines, alkyl sulphobetaines (sultaines), alkyl glycinates, alkyl carboxyglycinates, alkyl amphoacetates, alkyl amphopropionates, alkylamphoglycinates, alkyl amidopropyl hydroxysultaines, acyl taurates and acyl glutamates, wherein the alkyl and acyl groups have from 8 to 19 carbon atoms. Typical amphoteric and zwitterionic surfactants for use in skin cleansing compositions according to the invention include lauryl amine oxide, cocodimethyl sulphopropyl betaine, lauryl betaine, cocamidopropyl betaine (CAPB), sodium cocoamphoacetate and disodium cocoamphodiacetate. Particularly preferred amphoteric or zwitterionic surfactants to be used in the skin cleansing compositions of the present invention are cocamidopropyl betaine, cocoamphoacetate or cocoamphodiacetate such as most preferably sodium cocoamphoacetate.

In a particular advantageous embodiment the skin cleansing composition contains only sodium lauryl ether sulfate and sodium cocoamphoacetate as surfactants.

In another embodiment the invention relates to a process for the preparation of a blend according to the invention, characterized in that said process comprises the step of mixing a n aq u eou s d is persi on of a n acrylic emulsion polymer obtainable by emulsion polymerization of a monomer composition consisting of a mixture of methacrylic acid, ethyl acrylate and n-butyl methacrylate having a solid content selected in the range of 30 to 50 wt.-% such as in the range of 35 to 45 wt.-% and a pH selected in the range of 2 to 3 with saccaride isomerate, water, citric acid, sodium citrate and optionally panthenol and/ or a preservative with all the definitions and preferences as outlined above.

I n a further embodiment the present invention is directed to a method of treating skin comprising the application of the skin cleansing application according to the present invention to the skin followed by rinsing the skin with water. The thus treated skin feels soft and smooth.

The invention is further illustrated with reference to the following, non-limiting examples, in which all percentages are by weight based on total weight unless otherwise specified.

Example 1

A blend consisting of 30 % PENTAVITIN^®, 10% Panthenol (75%) and 60% Tl LAMAR^® Fix A 140 diluted with water 1 : 1 and subsequently neutralized to a degree of 50% either with NaOH or AMP has been prepared by mixing the ingredients. The blend with AMP turned dark whereas the blend neutralized with NaOH remained color stable (slightly yellow). Example 2

2.1 Preparation of a blend according to the present invention

30 % PENTAVITIN^®, 60% TILAMAR^® Fix A140 (non-neutralized) and 10% Panthenol (75%) have been mixed during stirring to give a slightly yellow blend. This blend was then incorporated into the body wash lotion outlined in table 2. Table 1 : Body wash lotion

2.2 Sensory evaluation

The lotions as outlined in Table 1 were tested in a blind study with a sensorial panel consisting of 3 persons under the following conditions:

The evaluation takes part on the inner forearm; the panel leader applies 50 μ Ι_ of the respective sample on pre-wetted skin.

Evaluator spreads the product within a defined circle of 5 cm diameter using index or middle finger, circular motion, rate of 2 rotations/second for 30 seconds in total. Afterwards the product is rinsed off for 30 seconds under running water. The smoothness is scaled on a scale from + to +++ in comparison to the placebo, which leaves a sticky skin feel. All samples showed no stickiness. Furthermore, a s can be retrieved from table 2, the compositions according to the present invention showed a sign ificantly increased smoothness of the skin compared to the base and sample 1 after treatment. Table 2

Product Sample 1 Sample 2 Sample 3

Smoothness of the skin + ++ +++

Claims

Claims:

A blend consisting essentially of

a. ) water,

c. ) saccaride isomerate,

d. ) citric acid,

e. ) sodium citrate,

f. ) 0 to 10 wt.-% of panthenol and

g. ) 0 to 1 wt.-% of a preservative.

with the proviso that the acrylic emulsion polymer is incorporated into the blend either non-neutralised or neutralized with a neutralizing agent which is not an amine.

The blend according to claim 1 , characterized in that the blend consists essentially of a) 35 to 60 wt.-% of water,

b) 15 to 30 wt.-% of the acrylic emulsion polymer,

c) 10 to 30 wt.-% saccharide isomerate,

d) 0.01 to 1 .0 wt.-% citric acid,

e) 0.01 to 1 .0 wt.-% sodium citrate,

f) 0 to 10 wt.-% of panthenol and

g) 0 to 1 wt- of a preservative.

The blend according to claim 1 , characterized in that the blend consists essentially of a) 40 to 55 wt.-% of water,

b) 20 to 30 wt.-% of the acrylic emulsion polymer,

c) 15 to 25 wt.-% saccharide isomerate,

d) 0.02 to 0.5 wt.-% citric acid,

e) 0.02 to 0.5 wt.-% sodium citrate,

f) 0 to 8 wt.-% of panthenol, and

g) 0 to 1 wt.-% of a preservative.

4. The blend according to any one of claims 1 to 3, characterized in that the acrylic emulsion polymer is obtainable by emulsion polymerisation of a m on om er composition consisting essentially of 10-30 wt.-% of methacrylic acid, 5-15 wt.-% of ethyl acrylate and 60-80 wt.-% of n-butyl methacrylate.

5. The blend according to any one of claims 1 to 4, characterized in that the acrylic emulsion polymer is obtainable by emulsion polymerisation of a m on om er composition consisting essentially of 18-23 wt.-% of methacrylic acid, 9-1 1 wt.-% of ethyl acrylate and 67-72 wt.-% of n-butyl methacrylate.

6. The blend according to any one of claims 1 to 5, characterized in that the acrylic emulsion polymer is incorporated as aqueous dispersion having a solid content selected in the range of 30 to 50 wt.-%, such as in the range of 35 to 45 wt.-%, and a pH selected in the range of 2 to 3.

7. A topical composition comprising from 0.1 to 6 wt.-%, preferably 0.5 to 4 wt.-%, such as most preferably 1 to 3 wt.-% of the blend according to any one of claims 1 to 6 and a cosmetically acceptable carrier. 8. The topical composition according to claim 7, which is an in-shower formulation applied to the skin and subsequently rinsed away.

9. The topical composition according to claim 8, characterized in that the topical composition is a skin cleansing composition additionally comprising an anionic surfactant.

10. The skin cleansing composition according to claim 9, characterized in that the anionic surfactant is sodium lauryl ether sulfate. 1 1 . The skin cleansing composition according to claim 9 or 10, characterized in that the total amount of the anionic surfactant(s) is selected in the range of 0.1 to 25 wt.-%.

12. The skin cleansi ng com position accord ing to any one of clai ms 9 to 1 1 , characterized in that an additional co-surfactant is present.

13. The skin cleansing composition according to claim 12, characterized in that the additional co-surfactant is sodium cocoamphoacetate.

14. The skin cleansing composition according to claim 13, characterized in that the skin cleansing composition is a shower gel.

15. A process for the preparation of a blend according to any one of claims 1 to 7, characterized in that said process comprises the step of mixing an aqueous dispersion of an acrylic emulsion polymer obtainable by emulsion polymerization of a monomer composition consisting of a mixture of methacrylic acid, ethyl acrylate and n-butyl methacrylate having a solid content selected in the range of 30 to 50 wt.-% such as in the range of 35 to 45 wt.-% and a pH selected in the range of 2 to 3 with saccaride isomerate, water, citric acid, sodium citrate and optionally panthenol and/ or a preservative.