WO2015173529A1 - Procédé d'isolation de sous-sol - Google Patents
Procédé d'isolation de sous-sol Download PDFInfo
- Publication number
- WO2015173529A1 WO2015173529A1 PCT/FR2015/051281 FR2015051281W WO2015173529A1 WO 2015173529 A1 WO2015173529 A1 WO 2015173529A1 FR 2015051281 W FR2015051281 W FR 2015051281W WO 2015173529 A1 WO2015173529 A1 WO 2015173529A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- subsoil
- insulating material
- injection
- destructuring
- soil
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 26
- 239000002689 soil Substances 0.000 title claims abstract description 21
- 239000011810 insulating material Substances 0.000 claims abstract description 23
- 238000002347 injection Methods 0.000 claims description 23
- 239000007924 injection Substances 0.000 claims description 23
- 238000005553 drilling Methods 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 14
- 239000012530 fluid Substances 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 239000012212 insulator Substances 0.000 claims description 6
- 238000006073 displacement reaction Methods 0.000 claims description 4
- 238000007711 solidification Methods 0.000 claims description 3
- 230000008023 solidification Effects 0.000 claims description 3
- 230000002209 hydrophobic effect Effects 0.000 claims description 2
- 239000004568 cement Substances 0.000 description 26
- 238000009413 insulation Methods 0.000 description 24
- 238000010276 construction Methods 0.000 description 10
- 230000036571 hydration Effects 0.000 description 8
- 238000006703 hydration reaction Methods 0.000 description 8
- 238000003860 storage Methods 0.000 description 8
- 239000007788 liquid Substances 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 5
- 239000010755 BS 2869 Class G Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 239000004567 concrete Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 238000009434 installation Methods 0.000 description 4
- 230000001687 destabilization Effects 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 230000035515 penetration Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 238000010257 thawing Methods 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 229920005830 Polyurethane Foam Polymers 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 239000011440 grout Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000011496 polyurethane foam Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02D—FOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
- E02D19/00—Keeping dry foundation sites or other areas in the ground
- E02D19/06—Restraining of underground water
- E02D19/12—Restraining of underground water by damming or interrupting the passage of underground water
- E02D19/16—Restraining of underground water by damming or interrupting the passage of underground water by placing or applying sealing substances
-
- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02D—FOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
- E02D27/00—Foundations as substructures
- E02D27/32—Foundations for special purposes
- E02D27/35—Foundations formed in frozen ground, e.g. in permafrost soil
-
- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02D—FOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
- E02D3/00—Improving or preserving soil or rock, e.g. preserving permafrost soil
- E02D3/12—Consolidating by placing solidifying or pore-filling substances in the soil
-
- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02D—FOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
- E02D3/00—Improving or preserving soil or rock, e.g. preserving permafrost soil
- E02D3/12—Consolidating by placing solidifying or pore-filling substances in the soil
- E02D3/126—Consolidating by placing solidifying or pore-filling substances in the soil and mixing by rotating blades
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B7/00—Special methods or apparatus for drilling
-
- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02D—FOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
- E02D2200/00—Geometrical or physical properties
- E02D2200/16—Shapes
- E02D2200/1692—Shapes conical or convex
-
- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02D—FOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
- E02D2250/00—Production methods
- E02D2250/0023—Cast, i.e. in situ or in a mold or other formwork
-
- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02D—FOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
- E02D2250/00—Production methods
- E02D2250/003—Injection of material
-
- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02D—FOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
- E02D2300/00—Materials
- E02D2300/0046—Foams
Definitions
- the present invention relates to the field of construction or drilling especially in the case where the soil is made of permafrost.
- Permafrost refers to the part of a ground permanently frozen for at least two years.
- permafrost can get warm because:
- the present invention improves the situation.
- the present invention provides a versatile and economical method to solve the problems posed above.
- the present invention thus aims at a method of isolating a subsoil comprising:
- Said insulating material has a thermal conductivity strictly lower than a thermal conductivity of the subsoil.
- Said insulating material may also have a thermal conductivity less than 2, 3, 4, 5, 10, 20, 30, 40, 50, 100, 200, 300, 400, 500, 1000 times the thermal conductivity of the subsoil.
- the "apparent destruction of a subsoil” is the apparent and / or visual modification of its macroscopic structure with respect to an initial state considered as normal for the considered location. For example, plowing a field can deconstruct the surface of a soil. Destructuring allows the loss of structural consistency that a compacted subsoil can have (on a centimeter or millimeter scale).
- two parts of a destructured basement no longer have resistance to removal (or at least less than the initial resistance): if the minimum force, under laboratory conditions, necessary to dissociate two adjacent volumes isolated from a structured subsoil is F, the minimum force, under laboratory conditions, necessary to dissociate two isolated adjacent volumes from a destructured subsoil is less than F / 2 (the elementary volume may be a cube of 2cm on the side).
- This method thus makes it possible to modify the thermal characteristics of the basement in place without replacing it. This makes it possible in particular: - to reduce as much as possible the cuttings (because the existing basement is not totally extracted but reused in the mixture),
- this method allows in particular to avoid building a load-bearing structure for a construction of a screed or a building, with piles, above the permafrost and thus allows to place the works directly on the ground. This reduces the amount of piles and metal structures to build while facilitating the use and operation of buildings.
- this method can make it possible to have an alternative or complementary solution to the existing insulation solutions in the well.
- the radiant heating systems in the context of the storage of liquefied gas in a buried way, it is possible to overcome, at least partially, the radiant heating systems.
- the mechanical destructuring can be performed using an excavator or with a mechanical part (for example helical) rotating.
- this destructuring can be achieved by means of a high-pressure jet of a liquid capable of destructuring the subsoil.
- the insulating material may advantageously be an insulator of the polyurethane or epoxy foam type conferring the qualities of strength and required strength as well as the desired thermal performance.
- the destructuring of said subsoil can comprise: a drilling of an injection well in the subsoil; - displacement of an injection nozzle in the injection well;
- the injection of said insulator can then be performed during said movement.
- the mixture of said subsoil and said insulating material may comprise a rotation of a mechanical shaft in said subsoil.
- the insulating material may comprise a solidifying material after injection.
- this insulation provides increased strength of the subsoil and a seal.
- the solidification may comprise an exothermic reaction.
- This exothermic reaction can thus temporarily thaw the permafrost in contact with the insulation during solidification and thus increase the area in which the insulation is mixed in the subsoil.
- the insulating material comprises a hydrophobic material.
- the sealing of the parts of the treated subsoil can be increased.
- the temperature of said destructuring fluid may be greater than 20 ° C at a temperature of the soil.
- the method may further include drilling a production well in said sub-soil mixed with said insulating material.
- the mixed subsoil has an inverted cone shape (for example an inverted pyramid).
- FIG. 1 illustrates a particular embodiment of the method of isolating the subsoil according to the invention
- FIG. 2 illustrates a particular form of basement insulation in an embodiment according to the invention
- FIGS. 3a and 3b illustrate the drilling of an exploitation well in the context of an isolated subsoil in one embodiment of the invention
- FIG. 4 illustrates a thermal conductivity ⁇ as a function of the concentration of certain materials
- FIG. 5 illustrates a thermal conductivity ⁇ as a function of the porosity of the cement.
- Figure 1 illustrates a particular embodiment of underground insulation method according to the invention.
- the mechanical destructuring of the subsoil, the injection of an insulating material into this subsoil and the mixing of the assembly can be carried out in multiple ways. As an illustration, it is possible to dig the soil with a shovel or a mechanical shovel type machine to destructure the soil, inject the soil surface dig the desired insulation and manually mix all.
- the liquid for destructuring the basement is, for example, water.
- this liquid is injected at very high pressure so that it is able to destructure the subsoil efficiently.
- the injection is performed by raising the nozzle 103 in the well 101. Due to the effectiveness of the destructuration jet (which is related to the properties of the subsoil and the pressure of the injected destructuring liquid), the mixture between the subsoil and the insulator is effective in a radius r around the axis of the well.
- a column 106 of height h and radius r is “treated” and is thus considered to be an “isolated” basement. It is also possible to add to the device described (possibly replacing the injection of the destructuring fluid) a mechanical mixing device such as a blade or a propeller rotated by the rotation of the shaft 102 and mechanically mixing the basement with insulation.
- a mechanical mixing device such as a blade or a propeller rotated by the rotation of the shaft 102 and mechanically mixing the basement with insulation.
- the insulation may advantageously be a polyurethane foam type insulation or epoxidic conferring the qualities of strength and required strength and the desired thermal performance.
- This insulator can also be perlite (ball of insulation) associated for example with a grout of cement.
- Figure 2 illustrates a particular form of basement insulation in an embodiment according to the invention.
- the process, described in connection with FIG. 1, can be repeated a large number of times in the same zone, the "treated" subsurface parts being able to be connected (ie adjacent) or quasi-related (the horizontal distances between two processed columns being less than r).
- the general shape of the parts of the subsoil 200 "treated" (201 a, 201 b, 201 c, etc.) forms an inverted cone 202 as shown in Figure 2.
- the base of this cone (on the surface of the basement) can be used as a support for the construction of a concrete screed or other construction on the ground.
- This shape may allow better cold penetration under the treated subsoil portions (ie better heat extraction under the treated subsoil portions, arrows 204).
- the subsoil in contact with the inverted cone 202 may remain frozen and thus participate in the strength of the foundations of the yoke 203 or other surface installation.
- FIGS. 3a and 3b illustrate the drilling of an exploitation well in the context of an isolated subsoil in one embodiment of the invention.
- the depth of the portion of the subsoil treated for insulation may, of course, be less than the full depth of the well (eg 2000m).
- Figure 3a it is possible to isolate several basement columns (301, 302, 303) as previously described, these portions being adjacent.
- the drilling 304 is then carried out in an isolated zone of the subsoil. This embodiment is advantageous especially if the mechanical properties of the treated subsoil are more favorable to drilling than the mechanical properties of the untreated subsoil (eg lower density, lower mechanical abrasion, etc.).
- FIG. 3b it is possible to isolate several basement columns (305, 306, 307) as previously described, these parts being adjacent but sub-spacers of - untreated soil exist between these parts.
- the bore 308 is then carried out in one of these untreated zones of the subsoil.
- This embodiment is advantageous especially if the mechanical properties of the treated subsoil are less favorable to drilling than the mechanical properties of the untreated subsoil (eg higher density, higher mechanical abrasion, etc.).
- Figures 3a and 3b show three columns (isolated basement parts) but any other number is possible.
- the chemical reaction transformation of silicates and aluminates into hydrate
- the heat generated will melt the permafrost.
- the fluid from the subsoil is raised to the surface. This fluid is at a high temperature and its heat can dissipate in the well. This can lead again to a destabilization of the permafrost. It is therefore preferable to have a cement with a low heat of hydration. But in the case where the fluid raised to the surface is very hot and the flow is important, the low thermal conductivity of the cement can not suffice. It is then useful to associate it with a material having a very low thermal conductivity.
- the resulting composition may limit the heat exchange between the well and the permafrost. It must thermally isolate the subsoil, while providing, preferably, a mechanical support to the well.
- composition comprising at least one cement and a low thermal conductivity material capable of thermally insulating the subsoil sufficiently to not destabilize the permafrost.
- the invention consists in applying a composite material, for example syntactic foam, to the casing of the well, in order to have good thermal insulation, and to inject a cement between the formation and the syntactic foam.
- the cement is preferably of low heat of hydration, so as not to destabilize the permafrost when it is set and if possible to have a low thermal conductivity to reinforce the insulation.
- the composite material can not be used alone because it is necessary to fill the gap between the permafrost and the material. Cement with low heat of hydration and low thermal conductivity fulfills this role.
- an insulating composite material alone has a low thermal conductivity (of the order of 0.03 - 0.05 W / mK), whereas it is of the order of 0.9 W / mK for a net cement (water + cement class G HSR).
- the following two examples show the impact of the concentration of insulating material on the thermal conductivity and the impact of the porosity. These tests are carried out with a Class G cement that is not low heat of hydration. It can be seen that the higher the concentration of insulating material, the lower the thermal conductivity. On the other hand, beyond 55% of porosity, there is no longer a decrease in conductivity.
- FIG. 4 gives examples of thermal conductivity curves ⁇ as a function of the concentration of certain materials.
- the cement is composed in particular of Class G drill cement (Cemoil), silica, hollow spheres (50 to 60%), an antifoam, a dispersant, a suspensor, and water.
- FIG. 5 gives an example of a thermal conductivity curve ⁇ as a function of the porosity of the cement.
- the cement with a low heat of hydration is different from a conventional cement, for example diluted with another material (such as silica or carbonate), in order to have good mechanical properties.
- another material such as silica or carbonate
Landscapes
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Structural Engineering (AREA)
- Mining & Mineral Resources (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Civil Engineering (AREA)
- Paleontology (AREA)
- Hydrology & Water Resources (AREA)
- Agronomy & Crop Science (AREA)
- Soil Sciences (AREA)
- Geology (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Geochemistry & Mineralogy (AREA)
- Consolidation Of Soil By Introduction Of Solidifying Substances Into Soil (AREA)
- Light Sources And Details Of Projection-Printing Devices (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
RU2016149419A RU2702038C1 (ru) | 2014-05-16 | 2015-05-15 | Способ изоляции подпочвенного слоя |
US15/311,761 US10550538B2 (en) | 2014-05-16 | 2015-05-15 | Method for insulating sub-soil |
CA2949331A CA2949331C (fr) | 2014-05-16 | 2015-05-15 | Procede d'isolation de sous-sol |
NO20161971A NO20161971A1 (en) | 2014-05-16 | 2016-12-13 | Method for insulating sub-soil |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP14305723 | 2014-05-16 | ||
EP14305723.0 | 2014-05-16 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2015173529A1 true WO2015173529A1 (fr) | 2015-11-19 |
Family
ID=50774812
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR2015/051281 WO2015173529A1 (fr) | 2014-05-16 | 2015-05-15 | Procédé d'isolation de sous-sol |
Country Status (5)
Country | Link |
---|---|
US (1) | US10550538B2 (fr) |
CA (1) | CA2949331C (fr) |
NO (1) | NO20161971A1 (fr) |
RU (1) | RU2702038C1 (fr) |
WO (1) | WO2015173529A1 (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109117452B (zh) * | 2018-07-13 | 2019-09-17 | 西安理工大学 | 改进的基于土壤物理基本参数的导热系数模型设计方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3903706A (en) * | 1974-04-11 | 1975-09-09 | Atlantic Richfield Co | Insulating and protective structure for frozen substrates |
WO1995021989A1 (fr) * | 1994-02-11 | 1995-08-17 | Atlas Copco Craelius Ab | Procede de formation dans le sol d'une couche isolante sensiblement etanche, et dispositif pour sa mise en ×uvre |
FR2992671A1 (fr) * | 2012-06-27 | 2014-01-03 | Total Sa | Dispositif de stockage en sol |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3577893A (en) * | 1968-09-27 | 1971-05-11 | William B Davison | Insulation method and constructions |
US3598184A (en) * | 1969-11-05 | 1971-08-10 | Atlantic Richfield Co | Method and apparatus for producing a well through a permafrost zone |
US3618680A (en) * | 1970-05-15 | 1971-11-09 | Atlantic Richfield Co | Method for drilling in permafrost |
SU1733567A1 (ru) * | 1989-11-30 | 1992-05-15 | Специализированный Проектно-Изыскательский И Экспериментально-Конструкторский Институт "Гидроспецпроект" | Способ укреплени грунта |
SU1763572A1 (ru) * | 1990-03-02 | 1992-09-23 | Специализированный Проектно-Изыскательский И Экспериментально-Конструкторский Институт "Гидроспецпроект" | Способ укреплени массива грунта |
RU2054502C1 (ru) * | 1993-11-15 | 1996-02-20 | Санкт-Петербургский государственный архитектурно-строительный университет | Способ изготовления цементогрунтовой сваи в просадочных грунтах |
RU2074928C1 (ru) * | 1994-06-10 | 1997-03-10 | Валентин Георгиевич Кондратьев | Способ укрепления основания земляного полотна на вечномерзлых грунтах |
US5980446A (en) * | 1997-08-12 | 1999-11-09 | Lockheed Martin Idaho Technologies Company | Methods and system for subsurface stabilization using jet grouting |
KR101188866B1 (ko) * | 2011-07-25 | 2012-10-10 | 주식회사 우남케미코 | 유량 및 압력측정 기능을 갖는 우레탄 약액 주입기용 유량계 |
-
2015
- 2015-05-15 US US15/311,761 patent/US10550538B2/en active Active
- 2015-05-15 CA CA2949331A patent/CA2949331C/fr active Active
- 2015-05-15 WO PCT/FR2015/051281 patent/WO2015173529A1/fr active Application Filing
- 2015-05-15 RU RU2016149419A patent/RU2702038C1/ru active
-
2016
- 2016-12-13 NO NO20161971A patent/NO20161971A1/en unknown
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3903706A (en) * | 1974-04-11 | 1975-09-09 | Atlantic Richfield Co | Insulating and protective structure for frozen substrates |
WO1995021989A1 (fr) * | 1994-02-11 | 1995-08-17 | Atlas Copco Craelius Ab | Procede de formation dans le sol d'une couche isolante sensiblement etanche, et dispositif pour sa mise en ×uvre |
FR2992671A1 (fr) * | 2012-06-27 | 2014-01-03 | Total Sa | Dispositif de stockage en sol |
Also Published As
Publication number | Publication date |
---|---|
US20170089026A1 (en) | 2017-03-30 |
US10550538B2 (en) | 2020-02-04 |
CA2949331A1 (fr) | 2015-11-19 |
NO20161971A1 (en) | 2016-12-13 |
RU2702038C1 (ru) | 2019-10-03 |
CA2949331C (fr) | 2020-06-16 |
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