WO2015155631A1 - Waste material process and product - Google Patents
Waste material process and product Download PDFInfo
- Publication number
- WO2015155631A1 WO2015155631A1 PCT/IB2015/052380 IB2015052380W WO2015155631A1 WO 2015155631 A1 WO2015155631 A1 WO 2015155631A1 IB 2015052380 W IB2015052380 W IB 2015052380W WO 2015155631 A1 WO2015155631 A1 WO 2015155631A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- sludge
- dewatering
- aged
- filter cake
- drying
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/24—Treatment of water, waste water, or sewage by flotation
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23K—FODDER
- A23K10/00—Animal feeding-stuffs
- A23K10/20—Animal feeding-stuffs from material of animal origin
- A23K10/26—Animal feeding-stuffs from material of animal origin from waste material, e.g. feathers, bones or skin
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23K—FODDER
- A23K10/00—Animal feeding-stuffs
- A23K10/20—Animal feeding-stuffs from material of animal origin
- A23K10/26—Animal feeding-stuffs from material of animal origin from waste material, e.g. feathers, bones or skin
- A23K10/28—Animal feeding-stuffs from material of animal origin from waste material, e.g. feathers, bones or skin from waste dairy products
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
- C02F11/121—Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
- C02F11/121—Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
- C02F11/123—Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering using belt or band filters
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
- C02F11/121—Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
- C02F11/126—Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering using drum filters
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
- C02F11/121—Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
- C02F11/127—Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering by centrifugation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
- C02F11/13—Treatment of sludge; Devices therefor by de-watering, drying or thickening by heating
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
- C02F11/14—Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents
- C02F11/147—Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents using organic substances
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/22—Nature of the water, waste water, sewage or sludge to be treated from the processing of animals, e.g. poultry, fish, or parts thereof
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/32—Nature of the water, waste water, sewage or sludge to be treated from the food or foodstuff industry, e.g. brewery waste waters
- C02F2103/327—Nature of the water, waste water, sewage or sludge to be treated from the food or foodstuff industry, e.g. brewery waste waters from processes relating to the production of dairy products
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/06—Pressure conditions
- C02F2301/063—Underpressure, vacuum
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
Definitions
- the present invention relates to a process for treating waste material, more specifically dairy processing plant waste water material after dissolved air flotation treatment.
- Modern dairy processing plant produce a large quantity of wastewater which is generally treated by adding a flocculent and passing through a dissolved air flotation (DAF) plant.
- DAF dissolved air flotation
- the DAF plant reduces suspended solids by over 80%, the biological oxygen demand by over 60% and removes over 90% of the oil and grease, this reduces the loading on sewage systems dramatically and so they are often employed.
- micro-bubbles of air are introduced to the flocculent treated wastewater, these bubbles float the flocked material to the surface forming a floated solid which is skimmed from the surface and disposed of.
- the floated solid material is sometimes called sludge in the dairy or meat industry.
- the sludge typically contains between 10% and 20% solids and as such there is still a significant quantity of water present and this increases the volume of material to be disposed of.
- the majority of sludge is ground spread, land filled or drilled into pasture, and though it acts as a fertiliser it has an adverse environmental impact so there is pressure to eliminate the practice.
- processing aid To reduce the volume of material that needs to be disposed of, and recover water from the sludge it is sometimes further treated by processing aid then filtering.
- the filter cake formed can then be disposed of or, in some cases, further treated.
- the most commonly used processing aid is diatomaceous earth or pearlite and this adds an indeterminate amount of silica/silicon to the filter cake which can render it unsuitable for feedstock.
- the high silica/silicon filter cake is unsuitable as a feedstock as only limited amounts of silicon are required in most animals diets, in addition silica can cause undue wear on the teeth of animals to which it is fed. There have been attempts made to dry this sludge but the oils/fats often break from the filter cake creating a messy product which is either uneconomical or unsuitable for any downstream use.
- the present invention provides a method of producing a final product from a wastewater dissolved air flotation (DAF) sludge which includes the following dewatering step:
- the pre-processed is sludge, or aged sludge, that has undergone additional processing steps prior to dewatering and aged sludge is sludge that has been stored for a period of time
- the dewatering is a mechanical dewatering process carried out at a maximum of 30°C which results in a sludge filter cake that does not flow under its own mass.
- the dewatering step is carried out at no more than 20°C.
- the temperature is between 2 e C and 18 e C.
- the pre-processed sludge is sludge or aged sludge that has been diluted with water and/or filtrate.
- the temperature of the water and/or filtrate is below 20°C, or in a highly preferred form 10°C.
- the wastewater is dairy wastewater or abattoir/meat/fish/poultry processing plant waste.
- the sludge is high in protein.
- the pre-processed sludge is a sludge or aged sludge that has had a proportion of the oils and fats removed.
- the dewatering step is carried out using a vacuum filtration unit.
- the vacuum filtration unit includes a screen or filter cloth with 50 micron or less apertures.
- the dewatering step is carried out in the presence of a processing aid.
- said processing aid is fibrous.
- the processing aid is a cellulosic or lignocellulosic material, often a filter aid.
- the processing aid is not mineral based.
- the aged sludge is sludge that has been stored in a tank from 0 to 40 days.
- the dewatering step occurs in the presence of an organic processing aid.
- the dewatering step is a mechanical dewatering step that includes the use of a vacuum filtration step.
- the vacuum step includes the use of a rotary drum vacuum filter (RDV) or horizontal vacuum filtration table (HVFT).
- RSV rotary drum vacuum filter
- HVFT horizontal vacuum filtration table
- the mechanical dewatering step creates a filtrate and a retentate, where the filtrate is an aqueous liquid and the retentate is the sludge filter cake.
- the mechanical dewatering step is carried out with the sludge or aged sludge at a temperature of below 40 e C.
- the mechanical dewatering step is carried out with the sludge or aged sludge at a temperature of below 14 e C.
- the temperature of the sludge or aged sludge is between 2 e C and 18 e C.
- the sludge filter cake is processed to form a PD sludge, where the PD sludge has a maximum thickness of about 10mm and a surface area to volume ratio of 3:5 or greater.
- the dewatering step is followed by extrusion of the sludge filter cake step to form a PD sludge, , where the PD sludge has a maximum thickness of about 10mm and a surface area to volume ratio of 3:5 or greater.
- this extrusion is a low shear extrusion step.
- an organic processing aid is added to the sludge filter cake to form a sludge putty.
- this sludge putty is extruded to form a PD sludge, where the PD sludge has a maximum thickness of about 10mm and a surface area to volume ratio of 3:5 or greater.
- the extrusion step is carried out using an extruder which includes a die which has one or more die apertures that have a maximum trans-axial cross sectional dimension of between 0.1 mm and 40mm.
- the maximum trans-axial cross sectional dimension is between 1 mm and 10mm.
- the maximum trans-axial cross sectional dimension is between 1 mm and 5mm.
- the extrusion step is followed by a drying step to form a dried product from the PD sludge.
- the drying step is a low temperature drying process using a high volume of low temperature air, below 70°C, air passing over the PD sludge.
- the drying is carried out using air at or below 50°C, or even more preferably using air at or below 30°C.
- the dried product has greater than 90% solids and, in a highly preferred form, greater than 95% solids.
- the dried product is further processed to form a final product.
- the final product is a feed or feed supplement for animals.
- the final product is a fuel or fuel supplement for energy or heat production.
- the organic processing aid is cellulose, lignocellulose or lignin based.
- the organic processing aid is a fibrous cellulosic material.
- the cellulosic content of the sludge filter cake is adjusted.
- the present invention also includes a final product which is an animal feed product or supplement, or a fuel or fuel supplement for energy or heat production.
- the invention also includes a final product produced by the method described earlier.
- the present invention also includes a processing plant that includes a mechanical dewatering unit, an extruder and a drier.
- the dewatering unit includes a perforated surface and a filter with a pre-coat formed from an organic processing aid.
- the organic processing aid is cellulose or based on a cellulosic material.
- the organic processing aid is fibrous.
- the mechanical dewatering unit is a vacuum filter that includes a perforated drum or belt.
- the organic processing aid is used to form a pre-coat onto the perforated drum or belt.
- the sludge retained on the pre-coat is the retentate and the liquid phase passing through the pre-coat is the filtrate, such that the retentate and a proportion of the pre-coat forms the sludge filter cake.
- the extruder has one or more die apertures that have a maximum transaxial cross sectional dimension of between 0.1 mm and 40mm. In a highly preferred form the maximum trans-axial cross sectional dimension is between 1 mm and 10mm. In a still more preferred form the maximum trans-axial cross sectional dimension is between 1 mm and 5mm. .
- the drier operates at a temperature below 200°C at a predetermined humidity, for a predetermined time.
- the present invention further includes an alternative method of producing a final product from a wastewater dissolved air flotation (DAF) sludge which includes an extrusion step which is:
- DAF wastewater dissolved air flotation
- the extrusion step is carried out using an extruder which includes a die which has one or more die apertures that have a maximum trans-axial cross sectional dimension of between 0.1 mm and 40mm, and preferably the PD sludge has a maximum thickness of about 10mm, and a surface area to volume ratio of 3:5 or greater.
- the maximum trans-axial cross sectional dimension is between 1 mm and 10mm. In a still more preferred form the maximum trans-axial cross sectional dimension is between 1 mm and 5mm.
- the extrusion step is followed by a drying step to produce the final product.
- the drying step is a low temperature drying process using a high volume of low temperature air, below 70°C, air passing over the PD sludge.
- the drying is carried out using air at or below 50°C, or even more preferably using air at or below 30°C.
- the dried product has greater than 90% solids and, in a highly preferred form, greater than 95% solids.
- the alternative method includes a dewatering step prior to the extrusion step similar to that detailed in the first method.
- the dewatering step is a mechanical dewatering step that includes the use of a vacuum filtration step.
- the vacuum step includes the use of a rotary drum vacuum filter (RDV) or horizontal vacuum filtration table (HVFT).
- RSV rotary drum vacuum filter
- HVFT horizontal vacuum filtration table
- the mechanical dewatering creates a filtrate and a retentate, where the filtrate is an aqueous liquid and the retentate is the sludge filter cake.
- the dewatering step is carried out with the sludge or aged sludge at a temperature of below 40 e C.
- the dewatering step is carried out with the sludge or aged sludge at a temperature of below 14 e C.
- the temperature of the sludge or aged sludge is between 2 e C and 18 e C.
- the wastewater is dairy wastewater or abattoir/meat/fish/poultry processing plant waste.
- the sludge is high in protein.
- Figure 1 is a process diagram
- Figure 2 is a flow chart of a preferred method of using the processing equipment
- Figure 3 is a process diagram of a second embodiment
- Figure 4 is a flow chart of a preferred method of using the second embodiment of the processing equipment
- Figure 5 is a flow chart of a third embodiment of the method which has only an extrusion step, with the other steps optional.
- Breaking when referring to 'breaking of the oil/fat refers to a proportion of the oil/fat content of the material in question being released as unbound oil/fat.
- Cellulosic This is intended to include lignocellulosic materials as well.
- Mechanical dewaterinq A mechanical or physical, rather than chemical or thermal, process for removing some or all of the water from a material containing solids and water.
- Tube This is intended to include hollow elongate members which have a cross sectional shape, of either the outer surface or the void within, other than circular or oval, for example triangular, rectangular, star shaped, hexagonal, octagonal, elliptical, oval, so a tube includes rectangular hollow section as well as pipe.
- the method and plant will be described with reference to a dairy plant but it could equally refer to other processing plants that include a dissolved air flotation unit to process some or all of their wastewater.
- the dairy waste material process plant includes:
- the DAF plant (2) will often be part of the standard dairy wastewater treatment apparatus and it is expected this will operate in the normal way. This said the DAF plant (2) may have specific flocculants or other additives excluded or added to optimise the operation of the dairy waste material process plant (1 ).
- the DAF plant (2) creates a sludge (10) by introducing fine air bubbles to a dairy wastewater stream (1 1 ) which has often been pre-treated with one or more flocculants (12).
- the fine air bubbles suspend the flocculated material (which includes acid coagulated proteins) to form the sludge (10).
- the sludge (10) is skimmed from the surface of the treated wastewater, and/or removed from the base of the processing vessel, in the DAF plant (2) and transferred to the sludge tank (3).
- the sludge tank (3) is already present.
- the contents of the sludge tank (3) are normally between 10% and 30% solids and they are allowed to age for a period of time to 'stiffen' and form an aged sludge (20) suitable for further processing.
- This aged sludge (20) does develop specific properties desirable for some forms of the final product (21 ) and the aging period will depend on the final product (21 ) and one or more of the following components in the sludge (10) protein, fat/oil and dissolved salts.
- This aging may affect the ratio between the various components and/or overall composition of the contents of the sludge tank (3) as fermentation and other microbiological processes will occur over time. It should be noted that this step is optional and it is expected that in some cases the aged sludge (20) will simply be the contents of the sludge tank (3) essentially as removed from the DAF plant (2).
- the aged sludge (20) is then filtered using a vacuum filter (4) with a pre-coat filter formed from an organic processing aid (22).
- a processing aid (22) manufactured from fibrous cellulose is particularly suitable.
- fibrous organic processing aid (22) rather than a mineral based processing aid (22) there is little or no silica or silicon addition to the filter cake.
- the use of a processing aid (22) is optional.
- An RDV filter (4) operates by having a low pressure cavity surrounded by a perforated surface, the perforated surface may have a filter cloth applied or be fine enough to allow the processing aid (22) to form the pre-coat without a filter cloth. In some embodiments there may simply be a filter cloth with no added processing aid (22).
- the aged sludge (20) to be filtered is made available to the high pressure (atmospheric in most cases) side of the pre-coated perforated surface, a proportion (up to 100%) of the liquid phase passes through the pre coat or filter cloth to the low pressure void as filtrate (23) and a low water content solid rich phase is retained by the pre-coat as retentate (24).
- the perforated surface is either the perforated surface of a moving drum or a moving belt which passes through a tank containing the aged sludge (20) then back into the air.
- the low pressure void pulls first liquid then air through the retentate (24) on the perforated surface reducing the liquid content still further.
- the retentate (24) and a proportion of the pre-coat filter (where present) is removed from the perforated surface by a blade as a sludge filter cake (30).
- the blade is normally a fixed or stationary blade as the drum or belt is moving, the blade is intended to cover any member used to remove the filter cake (30) from the drum, filter cloth or belt.
- the perforated surface, with the remaining pre-coat or filter cloth passes back into the tank containing the tank containing the aged sludge (20).
- the filter is described as a RDV filter (4), it is a perforated surface vacuum filtration unit which may be a horizontal belt vacuum filter or any other suitable form of vacuum filtration.
- the aged sludge (20) may be diluted with water and/or filtrate (23) to be sufficiently fluid to be processed.
- Trials are ongoing to determine the useful range of added water and it may be that the amount added is related to the concentration of one or more chemical species in the sludge (10) or aged sludge (20), the breakdown of flocculated material allowing interstitial water to be removed, reduced viscosity of the material to be processed, or a combination of these and other parameters, but this has not been determined.
- the aged sludge (20) has a variable composition which includes low melting point species, likely to be triglycerides of fatty acids. It has been found that this variable composition affects this filtration, and to prevent breaking of the oil /fat it is best carried out below 30 e C. The best processing conditions are below 20 e C, possibly between 2 e C and 18 e C. This low temperature filtration has been found surprisingly effective, and the industry has been carrying out filtration at elevated, >45°C with limited success so it was not expected.
- the sludge filter cake (30) is normally over 30% solids and the filtrate (23) is typically low (less than about 1 %) in protein, fats and ash.
- the cellulose content from the processing aid (22) of the sludge filter cake (30) is between about 1 % and 5%, though it is thought that up to 50% may be advantageous. However, whether this cellulose content is accomplished by adding the organic processing aid (22) to the aged sludge (20), later added to the sludge filter cake (30) or a combination of these is likely to be dependent upon the feed material.
- the sludge filter cake (30) is then optionally blended with a variety of additives (31 ) in the additive unit (5) to form a sludge putty (40).
- the additives (31 ) could include silica, modified starch, modified carbohydrates, carbohydrates, marine or rice hulls, cellulose, high surface binding agents, minerals, micronutrients, anti-caking agents, absorbents, etc.
- the full range of additives (31 ) is yet to be determined but cellulose and various absorbents have been found to assist with the later drying and handling stages. It is felt that organic additives (31 ) are preferably.
- the sludge putty (40) is then extruded through the extrusion apparatus (6) to form PD sludge (50) as the extrudate.
- PD sludge 50
- the extrusion apparatus used is, or includes, a low shear extruder (for example a forming extruder).
- the sludge putty (40) should optimally be sufficiently coherent to not flow under its own mass, it can to a certain extent deform, break or crumble, but not flow.
- the extrusion apparatus (6) should have a die with a maximum trans-axial die aperture cross sectional dimension of between 0.1 mm and 40mm, where a solid rather than tubular extrudate is being formed. The optimum range believed to be between 1 mm and 5mm unless hollow/tubular extrudate is formed.
- the sludge putty (40) is extruded it expands forming the PD sludge (50).
- corrugations on the surface of the PD sludge (50) though these can be formed purely by the expansion upon exit from the die, be part of the die aperture shape or a combination of these.
- PD sludge 50
- the maximum thickness of material when processing dairy DAF, is about 10mm (say up to 12.5mm or 0.5") and the surface area to volume ratio is preferably 3:5 or greater.
- a tubular extrudate has an interior surface area which improves this ratio, but this improvement will most likely depend on the dimensions of the void.
- a surface area to volume ratio of 4:5 is greater than a surface area to volume ratio of 3:5 as the surface area has increased relative to the volume.
- extrusion apparatus (6) may simply involve pushing the sludge putty (40) through a mesh with apertures of the required shape and dimensions.
- the extrusion apparatus (6) may also form the PD sludge (50) into predetermined, fixed or random lengths to aid with later processing.
- the temperature should be kept relatively low, below 35 e C is preferred.
- the PD sludge (50) needs to be dried in a drier (61 ) to form a dried product (60) prior to any further processing and packaging required to form the final product (21 ).
- This drying may be possible by natural air drying but air drying with a high volume of low temperature (below 200°C) air is one preferred method.
- low temperature drying options are being investigated.
- Fluidised bed drying is being investigated as are a variety of infra-red/solar/dehumidification/rf/microwave/low pressure drying technologies and the final solution is likely to be a combination of these. It has been found that drying to 20% or below moisture content is preferred, but less than 5% appears to have additional benefits. Typically when the raw feedstock is dairy DAF this is around 96% solids
- the present invention also includes a preferred method of using the dairy waste material process plant (1 ). The steps in dashed boxes are optional and may not always be present.
- the method includes the following steps in order:
- the fat to protein ratio of the aged sludge (20) is determined by any known means. It is possible that the sludge (10) fat to protein ratio is used but this may not take into account any changes that occur during aging, so is unlikely to be used except where the aging is between 0 and 3 days.
- step B the aged sludge (20), which can be simply the sludge (10) from the DAF plant (2), is mechanically dewatered, preferably by some form of vacuum filter, but any mechanical dewatering process, including centrifuges and vacuum filtration units, can be used. Essentially this creates a sludge filter cake (30). This sludge filter cake (30) will contain a certain amount of any organic processing aid (22) used to pre-coat the filter surface.
- the preferred organic processing aid (22), where present, is a fibrous cellulosic material. Please note that a processing aid (22) is optional and if it is not used it will not be present in any downstream material.
- step C which is optional, at least one additive (31 ) is added to bring the level of cellulosic material up to a predetermined level, this level is expected to be between 0.1 % and 50%.
- This cellulosic material aids drying and improves the handling characteristics of the final product.
- At least one additive (31 ) and sludge filter cake (30) are blended/mixed to form a sludge putty (40) ready for extrusion.
- the at least one additives (31 ) added can be nutrient supplements, micronutrients, drying or anti- caking agents, colourants, odour modifiers, minerals, stabilisers for example.
- step D the sludge putty (40), which will be the sludge filter cake (30) when step C is not undertaken, is extruded to form PD sludge (50).
- This extrusion uses an extruder with one or more apertures with a maximum trans-axial cross sectional dimension in the range of between 0.1 mm and 40mm.
- the sludge putty (40) may be passed through a mesh like structure to form a multitude of bars of PD sludge (50), though the cross-section of these bars may not be oval or round. These bars expand with the drop in pressure on exit from the die.
- This extrusion process is normally a low shear extrusion process that occurs at a low, less than 50°C, and preferably below 35°C, temperature to minimise or eliminate any breaking of the oil/fat.
- step E the sludge putty (50) is dried to a pre-determined moisture content to form a dried product (60).
- This drying is an important part of the process as the wrong conditions can cause breaking of the oil/fats.
- One method of carrying out this low temperature drying uses high volumes of air of low temperature (below 50°C) air passing over the PD sludge (50). It is thought that some of the drying technology used for pasta drying may be successful but this is yet to be confirmed.
- step E additional steps may be undertaken to further process, size and package the dried product (50) to form the final product (21 ). These steps may include the addition of silica, absorbents, palatability aids or other additives. It is likely that prior to packaging the moisture content of the final product will be determined.
- the RDV filter (4) can be replaced by an alternative vacuum filtration or mechanical water removal device.
- organic processing aid (22) may be, or contain, an inorganic processing aid which is does not detrimentally affect the resultant final product (21 ) quality.
- the final product (21 ) has been described with reference to the creation of an animal food or feed supplement it is believed that by using a cellulosic or lignocellulosic processing aid the final product (21 ) can be used as a fuel for part or all of the onsite energy demands. Where mineral based processing aids are used they can cause undesirable deposits or serve as a flux to lower the melting point of fire bricks used inside furnaces/boilers. It is believed that other organic processing aids will also be suitable for the formation of a fuel or fuel supplement as a final product (21 ).
- an organic processing aid (22) is used in the RDV filtration step it may be possible to filter/dewater the aged sludge (20) by simply using a filter cloth without this.
- the organic processing aid (22) may be omitted from the filtration/dewatering step and added as a specific additive to form the sludge putty (40).
- a temperature is provided, and it is indicated that the temperature should be no more than this, it is intended that a lower temperature may be substituted, for example below about 50°C could be replaced by any temperature between 0°C and 49°C as the process will operate with that maximum bounding temperature as it is below the initially specified temperature.
- a temperature of no more than, or below, or a maximum of, 35°C can be replaced by 30°C, 25°C, 20°C, 18°C, 15°C, 10°C or below (or any temperature between).
- the same applies for the percentage of a specific ingredient, less than or up to about 35% can be replaced by 30%, 25%, 20%, 15% 10% or any other figure below 35%.
- the dairy waste material process plant (1 ) includes:
- the sludge (10) or aged sludge (20) is filtered using a dewatering unit (70).
- This dewatering unit (70) is preferably a horizontal vacuum filter table.
- the dewatering unit (70) can be used with a 50 micron or less filter cloth, with or without a processing aid (22).
- the dewatering unit (70) processes the sludge (10) or the aged sludge (20) to form a sludge filter cake (30).
- the feed material (10,20) may be diluted with water and/or filtrate (23) to be sufficiently fluid to be processed. It has been found that this addition of water and/or filtrate (23) can improve the effectiveness of this filtration/dewatering stage.
- the water or filtrate added is preferably at a low temperature, below about 25 e C or 30°C or lower. As with the first embodiment above it is not yet understood what the added water or filtrate (23) does. Trials so far have shown that the addition of up to about 35% water (chilled) can improve the dewatering step, why this addition of water improves the removal of water during the filtration stage is not yet understood. Trials are ongoing to determine the useful range of added water and it may be that the amount added is related to the concentration of one or more chemical species in the aged sludge (20), the breakdown of flocculated material allowing interstitial water to be removed, reduced viscosity of the material to be processed, or a combination of these and other parameters, but this has not been determined.
- the sludge (10) and aged sludge (20) has a variable composition which includes low melting point species, likely to be triglycerides of fatty acids. It has been found that this variable composition affects this filtration, and to prevent breaking of the oil /fat it is best carried out below 30 e C. The optimum processing conditions are expected to be below 20 e C, possibly between 2 e C and 18 e C. This low temperature filtration has been found surprisingly effective, and the industry has been carrying out filtration at elevated temperatures, >45°C with limited or no success, so success at low temperatures was not expected.
- a particular advantage of using a horizontal belt vacuum filter or rotary drum vacuum filter (or any other suitable vacuum/low pressure filter) as the dewatering unit (70) is that the resultant sludge filter cake (30) can be dried directly without extrusion, providing the thickness of the sludge filter cake (30) does not exceed about 10mm. To further process the sludge filter cake (30) needs to be sufficiently coherent to not flow under its own mass, it can to a certain extent deform, break or crumble, but not flow.
- the sludge filter cake (30) is then optionally blended with one or more additives (31 ) in additive unit (5) to form a sludge putty (40). Then consistency of the sludge filter cake (30) is less important and the sludge putty (40) needs to have the required coherency.
- the additives (31 ) could include silica, modified starch, modified carbohydrates, carbohydrates, marine or rice hulls, cellulose, high surface binding agents, minerals, micronutrients, anti-caking agents, absorbents, etc.
- the full range of additives (31 ) is yet to be determined but cellulose and various absorbents have been found to assist with the later drying and handling stages. It is felt that organic additives (31 ) are preferable.
- sludge putty (40) If sludge putty (40) is formed then it can be directly dried if it has a maximum thickness of material, when processing dairy DAF, of about 10mm (say up to 12.5mm or 0.5") and the surface area to volume ratio is preferably 3:5 or greater.
- the sludge putty (40) is then extruded through the extrusion apparatus (6) it forms the PD sludge (50) as the extrudate. It has been found that the sludge putty (40) should optimally be sufficiently coherent to not flow under its own mass, it can to a certain extent deform, break or crumble, but not flow.
- the extrusion apparatus (6) should have a die with a maximum trans-axial die aperture cross sectional dimension of between 0.1 mm and 40mm, where a solid rather than tubular extrudate is being formed. The optimum range believed to be between 1 mm and 5mm unless hollow/tubular extrudate is formed.
- the sludge putty (40) is extruded it expands forming the PD sludge (50).
- corrugations on the surface of the PD sludge (50) though these can be formed purely by the expansion upon exit from the die, be part of the die aperture shape or a combination of these.
- the maximum thickness of material, when processing dairy DAF, is about 10mm (say up to 12.5mm or 0.5") and the surface area to volume ratio is preferably 3:5 or greater
- the PD sludge (50) should be dried in a drier (61 ) to form a dried product (60) prior to any further processing and packaging required to form the final product (21 ).
- the undried sludge filter cake (30), sludge putty (40) or PD sludge (50) can be the final product (21 ), or used to prepare the final product (21 ).
- This drying may be possible by natural air drying but air drying with a high volume of low temperature (below 200°C) air is one preferred method. It should be noted that this low temperature air is most likely to be below 50°C but may include an initial burst of air at a temperature of up to say 200°C/250°C. A variety of other low temperature drying options could also be used. Fluidised bed drying is being investigated as are a variety of infra-red/solar/dehumidification/rf/microwave/low pressure drying technologies and the final solution is likely to be a combination of these. It has been found that drying to 20% or below moisture content is preferred, but less than 5% appears to have additional benefits. Typically when the raw feedstock is dairy DAF this is around 96% solids
- the present invention also includes a preferred method of using the second embodiment of the dairy waste material process plant (1 ).
- the steps in dashed boxes are optional and may not always be present.
- the method includes the following steps in order:
- the fat to protein ratio of the aged sludge (20) is determined by any known means. It is possible that the sludge (10) fat to protein ratio is used but this may not take into account any changes that occur during aging, so is unlikely to be used except where the aging is between 0 and 3 days, or the sludge (10) is directly processed.
- step B the sludge (10) or aged sludge (20) is mechanically dewatered, preferably by some form of vacuum filter, but any suitable mechanical dewatering process, including centrifuges and vacuum filtration units, can be used. Essentially this creates a sludge filter cake (30). This sludge filter cake (30) may contain a certain amount of any organic processing aid (22) if this is used. This dewatering occurs with the sludge (10) or aged sludge (20) at 30°C or lower. Prior to this mechanical dewatering using the dewatering unit (70) chilled water and/or filtrate (23) may be added.
- dewatering unit (70) produces a flat sheet of sludge filter cake (30) about 10mm or less thick then this can be divided into portions with a surface area to volume ratio of 3:5 or greater.
- This sludge filter cake (30) may be the final product or, if desired, step B can be followed by any of steps C to E directly.
- Step B is optional if the sludge (10) or aged sludge (20) has undergone a preprocessing step that results in the formation of a pre-processed sludge which is sufficiently coherent to not flow under its own mass, it can to a certain extent deform, break or crumble, but not flow.
- step C which is optional, at least one additive (31 ) is added to bring the level of cellulosic material up to a predetermined level, this level is expected to be between 0.1 % and 50%.
- This cellulosic material aids drying and improves the handling characteristics of the final product.
- the at least one additive (31 ) and sludge filter cake (30) are blended/mixed to form a sludge putty (40) ready for extrusion.
- the at least one additives (31 ) added can be nutrient supplements, micronutrients, drying or anti-caking agents, colourants, odour modifiers, minerals, stabilisers for example.
- step D the sludge putty (40), which will be the sludge filter cake (30) when step C is not undertaken, is extruded to form PD sludge (50).
- This extrusion uses a an extruder (for example a forming extruder) with one or more apertures with a maximum trans-axial cross sectional dimension in the range of between 0.1 mm and 40mm.
- the sludge putty (40) may be passed through a mesh like structure to form a multitude of bars of PD sludge (50), though the cross-section of these bars may not be oval or round. These bars expand with the drop in pressure on exit from the die.
- This extrusion process is carried out at a temperature of less than about 50°C, and preferably below 35°C (this temperature may be 30°C, 25°C, 20°C or even 15°C), to minimise or eliminate any breaking of the oil/fat.
- step E the sludge putty (50), or alternatively the sludge filter cake (30), is dried to a pre-determined moisture content to form a dried product (60).
- This drying can cause the fats/oils to break from the drying material which is undesirable; as such the drying stage should be a low temperature drying stage.
- One method of carrying out this low temperature drying uses high volumes of air of low temperature (below about 50°C) air passing over the PD sludge (50), or if not present the sludge filter cake (30) or sludge putty (40).
- additional steps may be undertaken to further process, size and package the dried product (50) to form the final product (21 ). These steps may include the addition of absorbents, palatability aids or other additives. It is likely that prior to packaging the moisture content of the final product will be determined.
- the sludge filter cake (30), sludge putty (40), PD sludge (50) or dried product (60) could all be the final product (21 ).
- the method or process plant (1 ) may produce more than one final product (21 ) selected from sludge filter cake (30), sludge putty (40), PD sludge (50), dried product (60) or these materials further processed.
- a step uses aged sludge (20) it could equally be sludge (10) or a pre-processed sludge.
- the pre-processed sludge may for example be sludge (10) or aged sludge (20) blended with an additive, had some of the oils and/or fats removed or been otherwise mechanically and/or chemically treated.
- the pre-processing steps most likely to have been undertaken are one or more of the following: the mechanical (centrifuging for example) removal of a proportion of the fats or oils, the addition of water and/or filtrate and the addition of a additive.
- a third alternative embodiment of the method is shown as a flowchart, in this case the sludge (10) or aged sludge (20) or pre-processed sludge is sufficiently coherent to not flow under its own mass, as such step A and the low temperature filtration, step B, can be omitted.
- step A and the low temperature filtration, step B can be omitted.
- step C or step C and D are undertaken.
- This method is likely to be used where the low temperature fat and/or oil concentration has been reduced so that this level of coherency has been achieved.
- This alternative may be limited to where an upstream process has removed a proportion (up to 100%) of the fats and oils.
- DAF dissolved air flotation
Landscapes
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Biomedical Technology (AREA)
- Biotechnology (AREA)
- Molecular Biology (AREA)
- Physiology (AREA)
- Animal Husbandry (AREA)
- Zoology (AREA)
- Health & Medical Sciences (AREA)
- Food Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Treatment Of Sludge (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA2980509A CA2980509A1 (en) | 2014-04-07 | 2015-04-01 | Waste material process and product |
AU2015245265A AU2015245265B9 (en) | 2014-04-07 | 2015-04-01 | Waste material process and product |
US15/127,685 US11220442B2 (en) | 2014-04-07 | 2015-04-01 | Waste material process and product |
CN201580018841.8A CN106163998A (en) | 2014-04-07 | 2015-04-01 | Waste disposal and product |
EP15776971.2A EP3129327A4 (en) | 2014-04-07 | 2015-04-01 | Waste material process and product |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NZ623538 | 2014-04-07 | ||
NZ62353814 | 2014-04-07 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2015155631A1 true WO2015155631A1 (en) | 2015-10-15 |
Family
ID=54287363
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/IB2015/052380 WO2015155631A1 (en) | 2014-04-07 | 2015-04-01 | Waste material process and product |
Country Status (6)
Country | Link |
---|---|
US (1) | US11220442B2 (en) |
EP (1) | EP3129327A4 (en) |
CN (1) | CN106163998A (en) |
AU (1) | AU2015245265B9 (en) |
CA (1) | CA2980509A1 (en) |
WO (1) | WO2015155631A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2023033660A1 (en) * | 2021-09-06 | 2023-03-09 | Protein Plus Limited | Daf stream processes and products |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11518699B2 (en) | 2019-03-29 | 2022-12-06 | Aqua-Terra Consultants | Wastewater treatment system and methods utilizing chemical pre-treatment and foam fractionation |
CN112010517B (en) * | 2020-09-09 | 2022-06-03 | 远贺(佛山)新材料科技有限公司 | Environment-friendly method for treating industrial sludge |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2772234A (en) * | 1953-05-14 | 1956-11-27 | Process Engineers Inc | Sludge treatment |
JPH1034199A (en) * | 1996-07-24 | 1998-02-10 | Nkk Corp | Treatment of tap water sludge |
US6919027B2 (en) * | 2002-11-01 | 2005-07-19 | N-Viro Systems Canada, Inc. | Method for treating bio-organic and wastewater sludges |
US7497956B2 (en) * | 2001-11-29 | 2009-03-03 | Corporation Biolix | Method for stabilizing and conditioning urban and industrial wastewater sludge |
WO2009059163A1 (en) * | 2007-11-01 | 2009-05-07 | Oberon Fmr, Inc. | Biosolids-based food additive for animal feed and methods of production |
Family Cites Families (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3093572A (en) | 1960-03-14 | 1963-06-11 | Phillips Petroleum Co | Wax filtration process |
US3951795A (en) | 1975-04-16 | 1976-04-20 | Alar Engineering Corporation | Process and apparatus for treating fatty waste water |
US4282256A (en) | 1979-10-22 | 1981-08-04 | Star-Kist Foods, Inc. | Preparation of an animal feed supplement from fish cannery process waste water |
DE3165180D1 (en) | 1980-04-03 | 1984-09-06 | Oxfam | Treatment of activated or humus sludge |
JPS6434199A (en) | 1987-07-27 | 1989-02-03 | Mitsubishi Electric Corp | Exciting device for synchronous machine |
FR2621136A1 (en) * | 1987-09-24 | 1989-03-31 | Lyonnaise Eaux | |
US4969928A (en) * | 1989-03-03 | 1990-11-13 | The United States Of America As Represented By The United States Department Of Energy | Combined method for simultaneously dewatering and reconstituting finely divided carbonaceous material |
SK90494A3 (en) * | 1992-01-30 | 1995-04-12 | Chemring Group Plc | Method of treatment of effluent waste |
US5507954A (en) | 1994-02-28 | 1996-04-16 | Carrillo; Danny | Process for separating grease and solid materials from a waste material |
US5514282A (en) * | 1994-04-01 | 1996-05-07 | Hibbard; David C. | Food processing wastewater treatment and recovery process |
US5540836A (en) | 1994-06-16 | 1996-07-30 | Coyne; Thomas J. | Wastewater treatment system and method |
US5759568A (en) | 1996-05-31 | 1998-06-02 | Amcol International Corporation | Method for producing animal foodstuff from waste |
US7692050B2 (en) * | 2003-03-28 | 2010-04-06 | Ab-Cwt, Llc | Apparatus and process for separation of organic materials from attached insoluble solids, and conversion into useful products |
EP1678995B1 (en) | 2004-12-29 | 2007-12-12 | Meri Entsorgungstechnik für die Papierindustrie GmbH | Apparatus and method for processing of animal manure wastewater |
WO2008068820A1 (en) | 2006-12-01 | 2008-06-12 | Shinzo Ishikawa | Method of treating excess active sludge for volume reduction |
CN101671106B (en) | 2009-09-28 | 2012-11-07 | 广州普得环保设备有限公司 | Method and device for sludge filter cake aerobic air drying |
US8835155B2 (en) | 2009-11-25 | 2014-09-16 | Dvo Licensing, Inc. | Biosolids digester and process for biosolids production |
US8435409B2 (en) * | 2010-05-28 | 2013-05-07 | Ecolab Usa Inc. | Activated sludge process in wastewater treatment |
US20120329138A1 (en) * | 2010-12-23 | 2012-12-27 | Shell Oil Company | Process for separation of a mixture containing a microbial substance and a liquid |
EP2828213A1 (en) | 2012-03-22 | 2015-01-28 | Xtract GmbH | Method for treating sludge by adding an organic polymer, as well as granules obtained from said method |
DE202012012605U1 (en) * | 2012-09-10 | 2013-10-11 | Huber Se | Extruder unit and thus equipped drying plant |
CN103539315A (en) * | 2013-09-25 | 2014-01-29 | 安徽省绿巨人环境技术有限公司 | Printing wastewater treatment equipment and process |
CN103508642B (en) * | 2013-10-28 | 2015-05-06 | 波鹰(厦门)科技有限公司 | Device for treating high-fat food processing wastewater |
CN103553257B (en) | 2013-11-11 | 2015-10-28 | 北京纬纶华业环保科技股份有限公司 | A kind of circulating disposal process of RE waste water and system |
-
2015
- 2015-04-01 AU AU2015245265A patent/AU2015245265B9/en active Active
- 2015-04-01 EP EP15776971.2A patent/EP3129327A4/en active Pending
- 2015-04-01 US US15/127,685 patent/US11220442B2/en active Active
- 2015-04-01 CN CN201580018841.8A patent/CN106163998A/en active Pending
- 2015-04-01 CA CA2980509A patent/CA2980509A1/en not_active Abandoned
- 2015-04-01 WO PCT/IB2015/052380 patent/WO2015155631A1/en active Application Filing
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2772234A (en) * | 1953-05-14 | 1956-11-27 | Process Engineers Inc | Sludge treatment |
JPH1034199A (en) * | 1996-07-24 | 1998-02-10 | Nkk Corp | Treatment of tap water sludge |
US7497956B2 (en) * | 2001-11-29 | 2009-03-03 | Corporation Biolix | Method for stabilizing and conditioning urban and industrial wastewater sludge |
US6919027B2 (en) * | 2002-11-01 | 2005-07-19 | N-Viro Systems Canada, Inc. | Method for treating bio-organic and wastewater sludges |
WO2009059163A1 (en) * | 2007-11-01 | 2009-05-07 | Oberon Fmr, Inc. | Biosolids-based food additive for animal feed and methods of production |
Non-Patent Citations (2)
Title |
---|
"Dissolved Air Flotation (DAF", TRADE WASTE GUIDELINE., 1 March 2013 (2013-03-01), XP055359412, Retrieved from the Internet <URL:www sawater.com.au> [retrieved on 20150730] * |
See also references of EP3129327A4 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2023033660A1 (en) * | 2021-09-06 | 2023-03-09 | Protein Plus Limited | Daf stream processes and products |
Also Published As
Publication number | Publication date |
---|---|
US20180170782A1 (en) | 2018-06-21 |
AU2015245265B2 (en) | 2019-05-16 |
CN106163998A (en) | 2016-11-23 |
CA2980509A1 (en) | 2015-10-15 |
AU2015245265B9 (en) | 2019-05-23 |
AU2015245265A1 (en) | 2016-11-24 |
EP3129327A1 (en) | 2017-02-15 |
EP3129327A4 (en) | 2017-10-25 |
US11220442B2 (en) | 2022-01-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6045507B2 (en) | Method for producing granular organic inorganic fertilizer from organic waste and device for implementing the same | |
AU2015245265B9 (en) | Waste material process and product | |
JP2014508090A5 (en) | ||
EP2481293A1 (en) | Method for processing distillery spent grains and device for producing a protein containing product | |
JP4577911B2 (en) | Animal and vegetable oil waste liquid recycling system | |
MX2013010126A (en) | System and method for treating waste. | |
DE1810032A1 (en) | Process and device for hydrolysis | |
CN1977013A (en) | Method for producing and purifying gelatin | |
JP5839333B2 (en) | Solidification method of floating oils and fats in garbage wastewater | |
EP2874957B1 (en) | Method of treating a digestate from a biogas process | |
DE4229986A1 (en) | Anaerobic treatment of high-fat substances | |
KR101131870B1 (en) | Method for drying materials containing water and method for manufacturing solid fuel | |
JP2018093766A (en) | Method for producing desalted and dried product of microalga belonging to genus aurantiochytrium cultured in culture liquid containing salt | |
RU2307155C2 (en) | Processing line for producing of protein-vitamin feed product from distiller's spent grains | |
RU2720866C1 (en) | Method and device for processing dung slurry | |
US20150196046A1 (en) | Animal Feed Composition | |
RU2547135C2 (en) | Method for disposal of distillery dregs to produce concentrated fodder protein containing no less than 50% of protein | |
RU2728467C1 (en) | Conveyor press for bird droppings dehydration | |
JPS6255917B2 (en) | ||
RU2486955C1 (en) | Method of producing sorbent | |
JP2003053182A (en) | Dewatering aid and dewatering method using the same | |
JPH01208385A (en) | Production of organic fertilizer by processed marine waste or the like | |
RU2076077C1 (en) | Method of treatment of organic sediment | |
AU2004253609A1 (en) | Process for clarifying and deodorizing water comprising suspended solids | |
WO2018020534A1 (en) | Method for processing palm oil waste, and composition for fertilizers or feed |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 15776971 Country of ref document: EP Kind code of ref document: A1 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 15127685 Country of ref document: US |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
REEP | Request for entry into the european phase |
Ref document number: 2015776971 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2015776971 Country of ref document: EP |
|
ENP | Entry into the national phase |
Ref document number: 2015245265 Country of ref document: AU Date of ref document: 20150401 Kind code of ref document: A |
|
ENP | Entry into the national phase |
Ref document number: 2980509 Country of ref document: CA |